Lab+Life Scientist Oct/Nov 2023

Page 31

materials testing

Scientists witness metal healing itself Green marks the spot where a fissure formed, then fused back together in this artistic rendering of nanoscale self-healing in metal, discovered at Sandia National Laboratories. Red arrows indicate the direction of the pulling force that unexpectedly triggered the phenomenon. Image credit: Dan Thompson

Scientists from Sandia National Laboratories and Texas A&M University have witnessed pieces of metal crack and then fuse back together without any human intervention, overturning fundamental scientific theories in the process.

I

f this newly discovered phenomenon could

be harnessed, it could usher in an engineering revolution — one in which self-healing engines, bridges and airplanes could reverse damage caused by wear and tear. Fatigue damage is one way machines wear out and eventually break. Repeated stress or motion causes microscopic cracks to form; over time, these cracks grow and spread until the whole device fails. “From solder joints in our electronic devices to our vehicle’s engines to the bridges that we drive

From theory to reality

injury. Over time, the crack regrew along a

In 2013, Michael Demkowicz — then an

different direction.

assistant professor at Massachusetts Institute of Technology, now a full professor at Texas A&M

“This was absolutely stunning to watch firsthand,” Boyce said.

— published a theory in Physical Review Letters,

“What we have confirmed is that metals

based on findings in computer simulations,

have their own intrinsic, natural ability to heal

that under certain conditions metal should be

themselves, at least in the case of fatigue damage

able to weld shut cracks formed by wear and

at the nanoscale.”

tear. The discovery that his theory was true

Boyce, who was aware of Demkowicz’s

came inadvertently at the Center for Integrated

theory, contacted the professor to share the

Nanotechnologies, a Department of Energy user

team’s findings. Demkowicz then recreated the

facility jointly operated by Sandia and Los Alamos

experiment on a computer model, substantiating

national laboratories.

that the phenomenon witnessed at Sandia was the

Khalid Hattar, now an associate professor at

same one he had theorised years earlier.

over, these structures often fail unpredictably due

the University of Tennessee, and Chris Barr, who

A lot remains unknown about the self-healing

to cyclic loading that leads to crack initiation and

now works for the Department of Energy’s Office

process, including whether it will become a practical

eventual fracture,” said Sandia materials scientist

of Nuclear Energy, were running an experiment at

tool in a manufacturing setting. As noted by Boyce,

Brad Boyce. “When they do fail, we have to contend

Sandia when the discovery was made. They only

“We show this happening in nanocrystalline metals

with replacement costs, lost time and, in some cases,

meant to evaluate how cracks formed and spread

in vacuum, but we don’t know if this can also be

even injuries or loss of life.”

through a nanoscale piece of platinum using a

induced in conventional metals in air.”

Although scientists have created some self-healing

specialised electron microscope technique they

Yet for all the unknowns, the discovery —

materials — mostly plastics — the notion of a self-

had developed to repeatedly pull on the ends of

which has been published in the journal Nature

healing metal has largely been the domain of science

the metal 200 times per second.

— provides a leap forward for the field of materials

fiction. As noted by Boyce, “Cracks in metals were only

Surprisingly, about 40 minutes into the

science. Demkowicz concluded, “My hope is that

ever expected to get bigger, not smaller. Even some of

experiment, the damage reversed course. One

this finding will encourage materials researchers

the basic equations we use to describe crack growth

end of the crack fused back together as if it was

to consider that, under the right circumstances,

preclude the possibility of such healing processes.”

retracing its steps, leaving no trace of the former

materials can do things we never expected.”

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