Pharmaceutical & Cosmetic Review March 2018

Page 38

SKIN CARE

Natural mushroom enzyme for mild exfoliation Healthy skin is characterised by efficient cell renewal. Exfoliation, be it chemical, mechanical or enzymatic, helps the cell renewal process but some types are harsher on the skin than others. Lipotec has developed an active botanical ingredient that is effective yet mild on skin. By Alicia Gimenez, Olga Laporta, Marie Ollagnier, Laia González, Raquel Delgado

D

esquamation is necessary

Tight control

Mushroom enzyme

for effective skin renewal.

The endogenous enzymes responsible for

Some organisms have been found to

A variety of endogenous

natural desquamation in the epidermis

produce proteases that mimic skin’s

proteases breakdown cell-

are pH-dependent, so their activity varies

natural enzymes, making them interesting

cell junctions in the epidermis, allowing

based on location. The epidermis exhibits

candidates for topical exfoliants. Actizyme

dead cells to desquamate. Lipotec’s

a pH gradient from about pH 7.4 at the

advanced botanical ingredient is a fungi-

Actizyme advanced botanical ingredient,

basal layer to around pH 5.5 at the stratum

derived protease that mimics cathepsin D,

available in South Africa from Savannah

corneum (SC) surface1.

as it exhibits a pH activity profile very similar

Fine Chemicals, contains a fungi-derived

to that of the endogenous enzyme.

protease that mimics a key epidermal protein in exfoliation. When applied to skin, it helps improve the complexion with a brightening effect. Cell renewal is slowed down by the ageing process and exposure to wind, air pollution, heat and sunlight or the use of detergents, resulting in dull and dry skin. Exfoliation removes pigmented cells that accumulate on skin’s surface. It also increases skin’s clarity and gives it a healthy looking glow. One form of exfoliation is chemical

When formulated in an acidic buffer

Application of the active ingredient at one and five percent proved to increase cell turnover by 11.1 and 16.4 percent

and applied on skin, the enzyme begins exfoliation. As the skin’s natural buffering capacity raises its pH, it reaches deeper layers of the SC and becomes inactive. Consequently, exfoliation is maintained specifically at the SC surface. This effective and controlled exfoliation produces little irritation and skin barrier disruption compared to AHAs. The brightening efficacy of this natural exfoliant has been tested on photoptye IV skins with notable results.

peeling where acids are applied on the

Irritation and damage control

skin to reduce cohesion between the corneocytes. Suitable acids include alpha-

In the deepest layers of the SC, serine

The epidermis on the volar forearm of 10

hydroxy acids (AHAs) such as glycolic or

proteases participate in the degradation

volunteers (aged between 20 and 50) was

lactic acid, or beta hydroxy acids (BHAs)

of intercellular junctions as their optimal

stained with the fluorescent dye, dansyl

like salicylic acid. The main disadvantage

activity is at neutral pH2. In contrast,

chloride. Actizyme advanced botanical

of chemical peeling is skin irritation.

cysteine and aspartic proteases are active

ingredient was applied twice a day.

Enzymatic exfoliation offers a gentler

in an acidic environment promoting

Removal of the stain was monitored daily

approach with minor risk of irritation. This

desquamation in the most superficial SC.

using a UV light until complete elimination

process is based on the application of

Cathepsin D is an aspartic protease

and changes in cell renewal were

proteases that break cell-cell interactions

that is active at acidic pH between 3.5

calculated in comparison to untreated

and promote desquamation.

and 5.0. It can break corneodesmosomes

skin (control).

in the low pH environment of the SC Figure 1: Measurement of induced skin reactivity

surface, causing desquamation. However, in deeper layers

cell turnover by 11.1 and 16.4 percent

(with a higher pH) it

respectively, with these values being

cannot degrade the

statistically significant (p<0.05).

junctions between

38

| MARCH 2018 | P C Review

Application of the active ingredient at one and five percent proved to increase

In order to confirm the absence of side

cells as efficiently.

effects, higher doses than required for

The pH-activity profile

exfoliation were used and compared to

and the location of

the application of an AHA. Volunteers

this enzyme limit its

(aged between 35 and 65) applied 15 or

activity specifically to

30 percent Actizyme advanced botanical

the superficial layers

ingredient, or eight percent lactic acid

of the SC.

to half the face. After four weeks, the


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