Functionalized Nanomaterial-Based Electrochemical Sensors
Woodhead Publishing Series in Electronic and Optical Materials
Functionalized Nanomaterial-Based Electrochemical Sensors
Principles, Fabrication Methods, and Applications
Edited by
Chaudhery Mustansar Hussain Department of Chemistry and Environmental Science, New Jersey Institute of Technology, Newark, NJ, United States
Jamballi G. Manjunatha Department of Chemistry, FMKMC College, Constituent College of Mangalore University, Madikeri, Karnataka, India
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ISBN: 978-0-12-824185-1
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Section B Fabrication of functionalized nanomaterial-based
3 Application of hybrid nanomaterials for development of electrochemical sensors
Thiago C. Canevari
3.1 Introduction
3.2 SiO2/MWCNTs, SiO2/MWCNTs/AgNPS, and GO/Sb2O5
3.3 Carbon dots/Fe3O4 and rGO/carbon dots
3.4 rGO/carbon dots/AuNPs
3.5
4 Biofunctionalization of functionalized nanomaterials for electrochemical sensors
Muhammed Bekmezci, Ramazan Bayat, Vildan Erduran, and Fatih Sen
4.1
4.3
5
Sankararao Mutyala, P. Hari Krishna Charan, Rajendran Rajaram, and K. Naga Mahesh
5.1
5.2
5.3
6 Functionalized carbon material-based electrochemical sensors for day-to-day applications
Vildan Erduran, Muhammed Bekmezci, Ramazan Bayat, and Fatih Sen
6.1 Introduction
6.2
6.3
6.4
7
6.5
9
Parisa Nasr-Esfahani and Ali A. Ensafi
7.1
7.2
Balaji Maddiboyina, OmPrakash Sunaapu, Sandeep Chandrashekharappa, and Gandhi Sivaraman
Section
10
A.H. Sneharani
10.1
10.2
10.3
10.4
10.5
10.6
11
Masoud Reza Shishehbore and Mohadeseh Safaei
12
Ramazan Bayat, Muhammed Bekmezci, Vildan Erduran, and Fatih Sen
12.1
12.2
14
15
Hilmi Kaan Kaya, Tahsin Çağlayan, and Filiz Kuralay
S. Nandini, S. Nalini, S. Bindhu, S. Sandeep, C.S. Karthik, K.S. Nithin, P. Mallu, and J.G. Manjunatha
15.1
A. Priyadharsan, S. Shanavas, S. Boobas, Tansir Ahamad, R. Acevedo, P.M. Anbarasan, and R. Ramesh
H.C. Ananda Murthy, Ararso Nagari Wagassa, C.R. Ravikumar, and H.P. Nagaswarupa
17.3
18 Functionalized
Vildan Erduran, Muhammed Bekmezci, Ramazan Bayat, Zübeyde Bayer Altuntaş, and Fatih Sen
18.1
19
Celina M. Miyazaki, Flavio M. Shimizu, and Marystela Ferreira
19.1
19.3
19.5
21
Waleed A. El-Said, Naeem Akhtar, and Mostafa M. Kamal
Álvaro Torrinha, Thiago M.B.F. Oliveira, Francisco W.P. Ribeiro, Simone Morais, Adriana N. Correia, and Pedro de Lima-Neto
21.1
21.2
21.3
Moslehifard, and Farzad Nasirpouri 22.1
22.3
Contributors
R. Acevedo Faculty of Engineering and Technology, San Sebastian University, Santiago, Chile
Tansir Ahamad Department of Chemistry, College of Science, King Saud University, Riyadh, Saudi Arabia
Naeem Akhtar Interdisciplinary Research Center in Biomedical Materials (IRCBM), COMSATS University Islamabad, Lahore, Pakistan
Zübeyde Bayer Altuntaş Sen Research Group, Department of Biochemistry, Dumlupınar University, Kutahya, Turkey
H.C. Ananda Murthy Department of Applied Chemistry, School of Natural Science, Adama Science and Technology University, Adama, Ethiopia
P.M. Anbarasan Nano and Hybrid Materials Laboratory, Department of Physics, Periyar University, Salem, Tamil Nadu, India
Ramazan Bayat Sen Research Group, Department of Biochemistry, Dumlupınar University, Kutahya; Department of Materials Science & Engineering, Faculty of Engineering, Dumlupınar University, Kütahya, Turkey
Muhammed Bekmezci Sen Research Group, Department of Biochemistry, Dumlupınar University, Kutahya; Department of Materials Science & Engineering, Faculty of Engineering, Dumlupınar University, Kütahya, Turkey
S. Bindhu Department of Chemistry, SJCE, JSS Science and Technology University, Mysuru, Karnataka, India
S. Boobas Department of Physics, Sri Vasavi College, Bhavani, Tamil Nadu, India
Tahsin Çağlayan Defense Industries Research and Development Institute, The Scientific and Technological Research Council of Turkey, Ankara, Turkey
Thiago C. Canevari Chemistry Course, Engineering School, Mackenzie Presbyterian University, São Paulo, SP, Brazil
Sandeep Chandrashekharappa Institute for Stem Cell Biology and Regenerative Medicine (InStem), Bangalore, Karnataka, India
Hamed Cheshideh Faculty of Materials Engineering, Sahand University of Technology, Tabriz, Iran; Department of Materials Science and Engineering, National Taiwan University of Science and Technology, Taipei, Taiwan
Adriana N. Correia Departamento de Química Analítica e Físico-Química, Centro de Ciências, Universidade Federal do Ceará, Fortaleza, Ceará, Brazil
Pedro de Lima-Neto Departamento de Química Analítica e Físico-Química, Centro de Ciências, Universidade Federal do Ceará, Fortaleza, Ceará, Brazil
Waleed A. El-Said Department of Chemistry, Faculty of Science, Assiut University, Assiut, Egypt; Department of Chemistry, College of Science, University of Jeddah, Jeddah, Saudi Arabia
Ali A. Ensafi Department of Chemistry, Isfahan University of Technology, Isfahan, Iran; Department of Chemistry & Biochemistry, University of Arkansas, Fayetteville, AR, United States
Vildan Erduran Sen Research Group, Department of Biochemistry, Dumlupınar University, Kutahya; Department of Materials Science & Engineering, Faculty of Engineering, Dumlupınar University, Kütahya, Turkey
Marystela Ferreira Centre of Science and Technology for Sustainability, Federal University of São Carlos, Sorocaba, São Paulo, Brazil
P. Hari Krishna Charan Department of Chemistry, Aditya Institute of Technology and Management, Srikakulam, Andhra Pradesh, India
Gururaj Kudur Jayaprakash School of Advanced Chemical Sciences, Shoolini University, Solan, Himachal Pradesh, India
Shankramma Kalikeri Division of Nanoscience and Technology, Department of Water and Health (Faculty of Life Sciences), JSS Academy of Higher Education & Research (Deemed to be University), Mysore, Karnataka, India
Mostafa M. Kamal Department of Chemistry, Faculty of Science, Assiut University, Assiut, Egypt
Deepak Kapoor Department of Pharmaceutical Chemistry, Delhi Pharmaceutical Sciences Research University, New Delhi, India
C.S. Karthik Department of Chemistry, SJCE, JSS Science and Technology University, Mysuru, Karnataka, India
Hilmi Kaan Kaya Department of Chemistry, Faculty of Science, Hacettepe University, Ankara, Turkey
N. Kazemifard Department of Chemistry, Isfahan University of Technology, Isfahan, Iran
Deepak Kumar School of Pharmaceutical Sciences, Shoolini University, Solan, Himachal Pradesh, India
Filiz Kuralay Department of Chemistry, Faculty of Science, Hacettepe University, Ankara, Turkey
Balaji Maddiboyina Department of Pharmacy, Vishwabharathi College of Pharmaceutical Sciences, Guntur, Andhra Pradesh, India
P. Mallu Department of Chemistry, SJCE, JSS Science and Technology University, Mysuru, Karnataka, India
J.G. Manjunatha Department of Chemistry, FMKMC College, Constituent College of Mangalore University, Madikeri, Karnataka, India
Celina M. Miyazaki Centre of Science and Technology for Sustainability, Federal University of São Carlos, Sorocaba, São Paulo, Brazil
Yaamini Mohan School of Biosciences and Technology, Vellore Institute of Technology, Vellore, India
Simone Morais REQUIMTE-LAQV, Instituto Superior de Engenharia do Porto, Instituto Politécnico do Porto, Porto, Portugal
Elnaz Moslehifard Department of Prosthodontics, Faculty of Dentistry, Tabriz University of Medical Sciences, Tabriz, Iran
Sankararao Mutyala Nanosol Energy Pvt Ltd, Hyderabad, Telangana, India
K. Naga Mahesh Nanosol Energy Pvt Ltd, Hyderabad, Telangana, India
H.P. Nagaswarupa Department of Studies in Chemistry, Davangere University, Shivagangothri, Davangere, Karnataka, India
S. Nalini Department of Biochemistry, Bangalore City University, Bengaluru, Karnataka, India
S. Nandini Department of Biochemistry, Bangalore City University, Bengaluru, Karnataka, India
Farzad Nasirpouri Faculty of Materials Engineering, Sahand University of Technology, Tabriz, Iran
Parisa Nasr-Esfahani Department of Chemistry, Isfahan University of Technology, Isfahan, Iran
K.S. Nithin Department of Chemistry, The National Institute of Engineering, Mysuru, Karnataka, India
Thiago M.B.F. Oliveira Centro de Ciência e Tecnologia, Universidade Federal do Cariri, Juazeiro do Norte, Ceará, Brazil
Rajat Kumar Pandey School of Pharmaceutical Sciences, Shoolini University, Solan, Himachal Pradesh, India
A. Priyadharsan Department of Physics, E.R.K. Arts and Science College, Erumiyampatti, Tamil Nadu, India
Rajendran Rajaram Department of Metallurgical and Materials Engineering, Indian Institute of Technology Madras, Chennai, Tamil Nadu, India
Shashanka Rajendrachari Department of Metallurgical and Materials Engineering, Bartin University, Bartin, Turkey
Dileep Ramakrishna Department of Chemistry, School of Engineering, Presidency University, Bangalore, India
R. Ramesh Department of Physics, Periyar University, Salem, Tamil Nadu, India
Srilatha Rao Department of Chemistry, Nitte Meenakshi Institute of Technology, Bangalore, Karnataka, India
C.R. Ravikumar Research Centre, Department of Science, East West Institute of Technology, VTU, Bangalore, Karnataka, India
Francisco W.P. Ribeiro Instituto de Formação de Educadores, Universidade Federal do Cariri, Brejo Santo, Ceará, Brazil
Z. Saberi Department of Chemistry, Isfahan University of Technology, Isfahan, Iran
Mohadeseh Safaei Department of Chemistry, Yazd Branch, Islamic Azad University, Yazd, Iran
S. Sandeep Department of Chemistry, SJCE, JSS Science and Technology University, Mysuru, Karnataka, India
Fatih Sen Sen Research Group, Department of Biochemistry, Dumlupınar University, Kutahya, Turkey
S. Shanavas Nano and Hybrid Materials Laboratory, Department of Physics, Periyar University, Salem, Tamil Nadu, India
Flavio M. Shimizu Department of Applied Physics, “Gleb Wataghin” Institute of Physics (IFGW), University of Campinas (UNICAMP), Campinas, São Paulo, Brazil
Masoud Reza Shishehbore Department of Chemistry, Yazd Branch, Islamic Azad University, Yazd, Iran
Gandhi Sivaraman Department of Chemistry, Gandhigram Rural Institute Deemed University, Dindigul, Tamil Nadu, India
A.H. Sneharani DoS in Biochemistry, Jnana Kaveri P.G. Center, Mangalore University, Kodagu, India
OmPrakash Sunaapu Department of Chemistry, University College of Engineering, Anna University, Dindigul, Tamil Nadu, India
Puchakayala Swetha State Key Laboratory of Chemo/Bio-Sensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, People’s Republic of China
Rajiv Tonk Department of Pharmaceutical Chemistry, Delhi Pharmaceutical Sciences Research University, New Delhi, India
Álvaro Torrinha REQUIMTE-LAQV, Instituto Superior de Engenharia do Porto, Instituto Politécnico do Porto, Porto, Portugal
Ararso Nagari Wagassa Department of Applied Chemistry, School of Natural Science, Adama Science and Technology University, Adama, Ethiopia
Preface
Since the last decade, utility of nanomaterials and functionalized nanostructures has become significant in multidisciplinary fields including biomedical, environmental, food and beverages, textiles, pharmaceutical, cosmetics, agricultural, sensors, energy storage management, electronic materials, etc. Specifically, new methods in the synthesis of functionalized nanomaterials (FNMs) and their applications in different areas of science have been developed. Functionalization of nanomaterials is a method of inserting a particular material onto the surface of the nanomaterial to boost its properties and reduce its toxicity. Functionalized nanomaterials can be synthesized through covalent, noncovalent, grafting, physical methods, etc. They have a great impact on the fabrication of electrochemical sensors and biosensors for the determination of a wide spectrum of molecules, toxic ions, and even disease diagnosis applications. Their real-time applications are extensive due to their unique characteristics like high electrical, thermal, mechanical, and electronic properties and biocompatibility, large surface, etc. Electrochemical sensors and devices are well known for their versatile applications and advantages like simple handling procedure, quick results, high sensitivity and selectivity, low consumption of sample, etc.
This book gives the readers a holistic insight into functionalized nanomaterial-based electrochemical sensors from design to application. This book is categorized into several sections: Section A explains “Modern Perspectives in Electrochemical-Based Sensors: Functionalized Nanomaterials (FNMs)”; Section B deals with “Fabrication of Functionalized Nanomaterial-Based Electrochemical Sensor Platforms”; Section C describes “Functionalized Carbon Nanomaterial-Based Electrochemical Sensors”; Section D provides “Noble Metals, Non-Noble Metal Oxides, and Noncarbon-Based Electrochemical Sensors”; Section E conveys “Functionalized Nanomaterial-Based Electrochemical Sensors for Environmental Applications”; Section F emphasizes on “Functionalized Nanomaterial-Based Electrochemical Sensor Technology for Food and Beverage Applications”; Section G focuses on “Functionalized NanomaterialBased Electrochemical Sensors for Point-of-Care Applications”; Section H deals with “Health, Safety, and Regulation Issues for Functionalized Nanomaterials”; Section I describes “Economics and Commercialization of Functionalized NanomaterialBased Electrochemical Sensors”; and Section J explains “Future of Functionalized Nanomaterial-Based Electrochemical Sensors.”
The goal of this book is to provide a comprehensive insight from the basic level to the application of FNMs for the fabrication of electrochemical sensors and biosensors. I hope this book will be a great asset to electrochemists, material scientists, college and university graduates, chemists, biologists, pharmacists, engineers,
xx Preface physicists, industrial researchers, and analytical scientists. The editor and contributors are eminent researchers and experts from universities and various industries. On behalf of Elsevier, we thank all the authors of this book for their valuable contributions. We are extremely thankful to John Leonard (editorial project manager) at Elsevier for his tremendous support and assistance throughout this assignment.
J.G. Manjunatha, Editor
Section A Modern perspective in electrochemical-based sensors: Functionalized nanomaterials (FNMs)