Afton Chemical presents The role of TBN in Engine Oil

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The role of TBN in Engine Oil

What makes up an engine oil additive package?

The majority of the engine oil additive package is made of dispersants and detergents. Dispersants prevent sludge and enable soot handling, whilst detergents improve engine cleanliness by preventing deposits forming.

What is TBN (Total Base Number)?

TBN is an important part of the detergent in an engine oil. It is designed to react and neutralize acids in the engine. Acid can be caused by sulphur in diesel fuel or from oxidation of the oil. TBN works to prevent both by neutralizing acids as they form by creating a neutral salt. Without this neutralisation reaction, the acids would attack the metals in the engine. This reaction isn’t reversible, so the acid remains permanently neutralised.

How does sulphur in fuel affect the engine?

If there is less sulphur in fuel, then less sulphuric acid will be created in the engine. Today, the average sulphur level is 60% to 90% less than it was historically. This means your TBN needs today should also be proportionately lower. That’s because the sulphur level in diesel used to be a lot higher and >5,000ppm was the norm. Some markets are currently at 2,000ppm with further reductions planned, but most markets are now <500ppm.

Africa as an example

Fuel sulphur levels across the continent are reducing and this trend has been seen across many countries over the past 20+ years.

How are harsh conditions a factor for TBN?

Countries that still have a significant proportion of unpaved roads, or where road quality is poor, means mechanical problems - like sand and water in the engine oil - are more common and happen faster than in more developed countries. This means the engine oil is changed more frequently and possibly before the TBN is really used up.

Its important to note that an antioxidant can often be more important than TBN to maintain oil quality over the oil’s lifetime, as these types of harsh conditions may promote oil oxidation.

Do Minimum Engine Oil Standards also play a role?

Many African countries have their own regulatory requirements to help ensure oil quality and to stop issues such as oil counterfeiting.

For example, in Nigeria’s 2006 SON (Standards Organisation of Nigeria) specification for API S and C claims, there was a TBN minimum of 6.5 for multi-grades and 5.0 for monogrades. However, the most recent SON specification does not contain a TBN requirement, as it was removed in the 2017 update. Elsewhere in Africa, Kenya has a TBN minimum of 10 for diesel engine oils, whereas in Tanzania, there is a TBN minimum of 7.

Regulations are not consistent, but they are beginning to change. People are beginning to recognise that TBN is not the only concern in engine oils.

What about Industry and OEM specs?

API and ILSAC have never mandated a TBN level in any of their specifications. However, ACEA and some OEMs do have TBN requirements in their specifications:

• Daimler Truck DTFR 15B110 spec has an 8 TBN minimum.

• Cummins’ 20078 spec has a 10 TBN minimum.

• Deutz’s DQC III-18 has a 9 TBN minimum.

• MTU’s category 2 spec has an 8 TBN minimum.

There is no one number all OEMs agree on, because different OEMs use different test methods and have different drain intervals, so they adjust their TBN needs accordingly.

The role of TBN in Engine Oil

How does TBN work?

Your starting TBN isn’t what’s most important - it’s still having TBN left when it’s time to change the engine oil. If you have excess TBN at the start, then you will have left-over TBN when you get to your oil change, so you’re paying for detergent that never gets used. We used to measure this by looking at TBN level and TBN/TAN (Total Acid Number) crossover but those aren’t the only indicators. We also use more direct and accurate measurements such as measuring the metal levels in the oil (to check for wear) and spectroscopic analysis of oil oxidation/nitration (e.g. the Mack T13- new engine test uses this technique).

What is TBN / TAN crossover?

This measures when the acid number has exceeded the base number in the oil. It’s an approximate indicator of when your TBN is ‘used up’.

TBN decreases over time and TAN increases. Iron (Fe) levels start to increase after TBN/TAN crossover so it’s better to measure the metal levels in the oil directly.

Summary

What about oil oxidation measures?

Oil oxidation takes time after TBN limit is reached. The Volvo T-13 Test directly measures oil oxidation instead of relying on TBN.

How do we know TBN protects engines?

Afton runs field trials of new products under extreme conditions to validate performance. Field trials look at start and end TBN levels, but they also look at engine wear and engine corrosion. Some engine tests also do this by monitoring the metal levels in oil over test lifetime – for example Pb, Cu and the oxidation and nitration levels in oils over test lifetime.

Why should I worry about excess TBN?

TBN is designed to provide a continual level of base in the oil to protect against acids. If you have more TBN than you need in your oil, then the extra base has no acid to react with. TBN is a contributor to S/ASH and excess TBN may turn into extra ash deposits in the engine or after-treatment device. This means you are paying for detergent you don’t need.

Afton understands TBN and develops engine oil additive packages to work in the markets and conditions a customer needs to optimize their engine oil needs. This stops customers paying for more chemistry than they need and helps to ensure longer drain intervals.

Afton has a comprehensive range of Passenger Car and Heavy Duty engine oil products that can be boosted so the TBN level meets specific market requirements.

Contact your local Afton Chemical representative for more information.

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