Synthetic Coloured Stones - Some cases and ‘reflections’ about synthetic stones

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Synthetic Coloured Stones

Some cases and ‘reflections’ about synthetic stones

Dr. Michael S. Krzemnicki, FGA

Director, Swiss Gemmological Institute SSEF

Photos and figures © M.S. Krzemnicki and SSEF, except where indicated otherwise.

| A hot issue in the past… and today ?

Production of Verneuil-synthetic spinel and corundum at Djeva SA in Monthey (Switzerland)

• Synthetic: Artificial (manufactured) stone with basically the same chemistry and structure as its’ natural counterpart.

• Imitation: Any stone that imitates the visual appearance of a natural gemstone (different chemistry and structure).

• An imitation can be either a cheaper natural stone, a treated or a synthetic stone, or even an artificial product without a natural counterpart (e.g. cubic zirconia).

| Synthetic spinel

light purplish pink Verneuil-synthetic spinel:

Numerous tiny inclusions.

Unexpectedly, this synthetic spinel contains no chromium. The colour is due to tetrahedrally coordinated Fe2+.

| Synthetic spinel

Vivid blue Verneuil-synthetic Cobalt-spinel:

Fine veils giving the stone a natural appearance.

Pure cobalt colour, no iron present !

| Synthetic spinel

Natural spinel
Flux-melt synthetic spinel

| Synthetic spinel

Natural spinel
Flux-melt synthetic spinel

| Synthetic spinel

Layout of flux-melt synthetic spinel analysed at SSEF.

11 synthetic spinels from 1.1 to 2.0 ct

| Synthetic corundum

Flame-fusion synthetic padparadschas

• Coloured by traces of chromium and nickel !

ED-XRF chemical analysis

| Synthetic corundum

flux-melt synthetic ruby

• Contains inclusions resembling ‘zircon’-clusters

• Such synthetic rubies are known for more than 15 years!

• with lab report claiming to be a natural ruby!

Synthetic ruby (flux-melt) of 4.27 ct

| Synthetic corundum

Natural ruby from Vatomandry (Madagascar) with numerous zircon clusters

Flux-melt synthetic ruby with similar clusters, however they are not zircons!

| Synthetic corundum

Flux-melt synthetic ruby of 6 ct with lab reports as natural ruby!

| Synthetic corundum

Orange residues could be misinterpreted as iron hydroxide, but is flux residue from Ramaura synthesis process.

| Bad surprises for our client

Necklace containing about 50 flux-melt synthetic rubies

Due to the presence of many inclusions, an unexperienced gemmologist may consider them to be heated but natural.

| Even worse…

Jewellery containing heated Verneuil synthetic rubies and natural diamonds

An unexperienced gemmologist may consider them to be heated and flux-filled natural stones.

| Synthetic emerald

Flux-melt synthetic emerald grown on natural beryl crystals

• Research experiments (Russia).

• Easy to detect for experienced gemmologist/mineralogist

• Many small platinum flakes at surface and within synthetic emerald layer.

Deep green flux-melt synthetic on-growth.

heavily included low quality whitish beryl

| Synthetic alexandrite

flux-melt synthetic alexandrite

• Visually similar to Russian alexandrite.

• Full of tiny inclusions resembling natural alexandrite.

• Detection only after careful microscopic observation and spectroscopic and chemical analysis.

Platinum flakes from crucible
Flux residues in healed fissures

| Melée testing (coloured stones):

Batch of small flux-melt synthetic rubies recently analysed at SSEF.

| Melée testing (coloured stones):

Synthetic ruby mixed in a batch of calibrated rubies.

| Melée testing (coloured stones):

• Usually very small stones (1-4 mm).

• Often submitted in larger batches.

• Calibrated or specifically designated cut for a specific place in the setting.

• Contain often no or only very few inclusions.

| Melée testing (coloured stones):

• Testing requires analytical protocol specifically adapted for each colour variety.

• Time-consuming, requires often highly advanced methods (e.g. Raman and LAICPMS).

• Unfortunately, this testing can not be done just for few pennies…

Beryllium in melée size fancy sapphires

https://www.brilliantearth.com

https://www.mevisto.com

Curved banding of Verneuilsynthetic sapphire!

https://anabelachan.com

• Identification of synthetic coloured stones is usually quite straightforward.

• Even detectable for an experienced dealer.

• Few cases need advanced analytical methods. These stones may come with reports calling them ‘natural’.

• Melée size coloured stones can be separated (natural vs. synthetic), however this requires adapted testing methods and is often challenging (quantity and small size).

• Correct labelling is mandatory for synthetic stones (synthetic, lab-grown, lab-created) and imitations. A synthetic stone cannot be called gemstone (CIBJO)!

• Trade organisations and consumer protection agencies need to ensure correct labelling.

• Gem labs support by detecting synthetic stones and by using clear wording on reports.

www.ssef.ch/ssef-facette

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