SolutionManual for Organic Chemistry 9th EditionMcMurry
1305080483 9781305080485
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I. Polar covalent bonds (Sections 2.1–2.3).
A. Electronegativity (Section 2.1).
1. Although some bonds are totally ionic and some are totally covalent, most chemical bonds are polar covalent bonds.
a. In these bonds, electrons are attracted to one atom more than to the other atom
2. Bond polarity is due to differences in electronegativity (EN).
a. Elements on the right side of the periodic table are more electronegative than elements on the left side.
b. Carbon has an EN of 2.5.
c. Elements with EN > 2.5 are more electronegative than carbon.
d. Elements with EN < 2.5 are less electronegative than carbon.
3. The difference in EN between two elements can be used to predict the polarity of a bond.
a. If ∆ΕΝ < 0.4, a bond is nonpolar covalent.
b. If ∆ΕΝ is between 0.4 and 2.0, a bond is polar covalent.
c. If ∆ΕΝ > 2.0, a bond is ionic.
d. The symbols ∆+ and ∆– are used to indicate partial charges.
e. A crossed arrow is used to indicate bond polarity.
i. The tail of the arrow is electron-poor, and the head of the arrow is electronrich.
4. Electrostatic potential maps are also used to show electron-rich (red) and electronpoor (blue) regions of molecules.
5. An inductive effect is an atom’s ability to polarize a bond.
B. Dipole moment (Section 2.2).
1. Dipole moment is the measure of a molecule’s overall polarity.
2. Dipole moment (μ) = Q x r, where Q = charge and r = distance between charges.
a. Dipole moment is measured in debyes (D).
3. Dipole moment can be used to measure charge separation.
4. Water and ammonia have large values of D; methane and ethane have D = 0.
C. Formal charge (Section 2.3).
1. Formal charge (FC) indicates electron “ownership” in a molecule.
2. FC # of valence #of bonding electrons # nonbonding electrons 2 electrons
II. Resonance (Sections 2.4–2.6).
A. Chemical structures and resonance (Section 2.4).
1. Some molecules (acetate ion, for example) can be drawn as two (or more) different electron-dot structures.
a. These structures are called resonance structures.
b. The true structure of the molecule is intermediate between the resonance structures.
c. The true structure is called a resonance hybrid.
2. Resonance structures differ only in the placement of π and nonbonding electrons.
a. All atoms occupy the same positions.
3. Resonance is an important concept in organic chemistry.
B. Rules for resonance forms (Section 2.5).
1. Individual resonance forms are imaginary, not real.
2. Resonance forms differ only in the placement of their π or nonbonding electrons.
a. A curved arrow is used to indicate the movement of electrons, not atoms.
3. Different resonance forms of a molecule don’t have to be equivalent.
a. If resonance forms are nonequivalent, the structure of the actual molecule resembles the more stable resonance form(s).
4. Resonance forms must obey normal rules of valency.
5. The resonance hybrid is more stable than any individual resonance form
C. A useful technique for drawing resonance forms (Section 2.6).
1. Any three-atom grouping with a multiple bond adjacent to a nonbonding p orbital has two resonance forms.
2. One atom in the grouping has a lone electron pair, a vacant orbital or a single electron.
3. By recognizing these three-atom pieces, resonance forms can be generated.
III. Acids and bases (Sections 2.7–2 11).
A. Brønsted–Lowry definition (Section 2.7).
1. A Brønsted–Lowry acid donates an H+ ion; a Brønsted–Lowry base accepts H+
2. The product that results when a base gains H+ is the conjugate acid of the base; the product that results when an acid loses H+ is the conjugate base of the acid.
3. Water can act either as an acid or as a base.
B. Acid and base strength (Section 2.8–2.10).
1. A strong acid reacts almost completely with water (Section 2.8).
2. The strength of an acid in water is indicated by Ka, the acidity constant
3. Strong acids have large acidity constants, and weaker acids have smaller acidity constants.
4. The pKa is normally used to express acid strength.
a. pKa = –log Ka
b. A strong acid has a small pKa, and a weak acid has a large pKa
c. The conjugate base of a strong acid is a weak base, and the conjugate base of a weak acid is a strong base.
5. Predicting acid–base reactions from pKa (Section 2.9).
a. An acid with a low pKa (stronger acid) reacts with the conjugate base of an acid with a high pKa (stronger base).
b. In other words, the products of an acid–base reaction are more stable than the reactants.
6. Organic acids and organic bases (Section 2.10).
a. There are two main types of organic acids:
i. Acids that contain hydrogen bonded to oxygen.
ii. Acids that have hydrogen bonded to the carbon next to a C=O group.
b. The main type of organic base contains a nitrogen atom with a lone electron pair.
C. Lewis acids and bases (Section 2.11).
1. A Lewis acid accepts an electron pair.
a. A Lewis acid may have either a vacant low-energy orbital or a polar bond to hydrogen.
b. Examples include metal cations, halogen acids, group 3 compounds and transition-metal compounds.
2. A Lewis base has a pair of nonbonding electrons.
a. Most oxygen- and nitrogen-containing organic compounds are Lewis bases.
b. Many organic Lewis bases have more than one basic site.
3. A curved arrow shows the movement of electrons from a Lewis base to a Lewis acid.
IV. Noncovalent interactions in molecules (Section 2.12).
A. Dipole–dipole interactions occur between polar molecules as a result of electrostatic interactions among dipoles.
1. These interactions may be either attractive or repulsive.
2. The attractive geometry is lower in energy and predominates.
B. Dispersion forces result from the constantly changing electron distribution within molecules.
1. These forces are transient and weak, but their cumulative effect may be important.
C. Hydrogen bonds.
1. Hydrogen bonds form between a hydrogen bonded to an electronegative atom and an unshared electron pair on another electronegative atom
2. Hydrogen bonds are extremely important in living organisms.
3. Hydrophilic substances dissolve in water because they are capable of forming hydrogen bonds.
4. Hydrophobic substances don’t form hydrogen bonds and usually don’t dissolve in water.
2.1 After solving this problem, use Figure 2.2 to check your answers. The larger the number, the more electronegative the element.
More electronegative Less electronegative
(a) H (2.1) Li (1.0)
(b) Br (2.8) B (2.0)
(c) Cl (3.0) I (2.5)
(d) C (2.5) H (2.1)
Carbon is slightly more electronegative than hydrogen.
2.2 As in Problem 2.1, use Figure 2.2. The partial negative charge is placed on the more electronegative atom, and the partial positive charge is placed on the less electronegative atom
(a) (b) (c) (d) (e) (f)
2.3 Use Figure 2.2 to find the electronegativities of each element. Calculate ΔEN and rank the answers in order of increasing ∆EN.
The most polar bond has the largest ΔEN. Thus, in order of increasing bond polarity:
2.4 In an electrostatic potential map, the color red indicates regions of a molecule that are electron-rich. The map shows that chlorine is the most electronegative atom in chloromethane, and the direction of polarity of the C–Cl bond is:
The dipole moment of ethylene glycol is zero because the bond polarities of the two carbon–oxygen bonds cancel.
2.6 For each bond, identify the more electronegative element, and draw an arrow that points from the less electronegative element to the more electronegative element. Estimate the sum of the individual dipole moments to arrive at the dipole moment for the entire molecule.
(a)
(c)
(b)
(d)
2.7 To find the formal charge of an atom in a molecule, follow these two steps:
(1) Draw an electron-dot structure of the molecule.
(2) Use the formula in Section 2.3 (shown below) to determine formal charge for each atom. The periodic table shows the number of valence electrons of the element, and the electron-dot structure shows the number of bonding and nonbonding electrons.
(a)
Remember: Valence electrons are the electrons characteristic of a specific element. Bonding electrons are those electrons involved in bonding to other atoms Nonbonding electrons are those electrons in lone pairs.
(b)
(c)
Oxygen atoms 3 and 4 each have a formal charge of –1, and oxygen atoms 1 and 2 have a formal charge of 0.
2.9 Try to locate the three-atom groupings that are present in resonance forms.
(a) These two structures represent resonance forms. The three-atom grouping (C–C double bond and an adjacent vacant p orbital) is pictured on the right.
(b) These two structures represent different compounds, not resonance structures.
2.10 Look for three-atom groupings that contain a multiple bond next to an atom with a p orbital. Exchange the positions of the bond and the electrons in the p orbital to draw the resonance form of each grouping.
(a) Methyl phosphate anion has 3 three-atom groupings and thus has 3 resonance forms.
Recall from Chapter 1 that phosphorus, a third-row element, can form more than four covalent bonds
(b)
(c)
(d)
2.11 When an acid loses a proton, the product is the conjugate base of the acid. When a base gains a proton, the product is the conjugate acid of the base.
2.12 Recall from Section 2.8 that a stronger acid has a smaller pKa and a weaker acid has a larger pKa Accordingly, phenylalanine (pKa = 1.83) is a stronger acid than tryptophan (pKa = 2.83).
2.13 HO–H is a stronger acid than H2N–H. Since H2N– is a stronger base than HO–, the conjugate acid of H2N– (H2N–H) is a weaker acid than the conjugate acid of HO– (HO–H).
2.14 Use Table 2.3 to find the strength of each acid. A reaction takes place as written if the stronger acid is the reactant.
(a)
Remember that the lower the pKa, the stronger the acid. Thus CH3CO2H, not HCN, is the stronger acid, and the above reaction will not take place to a significant extent in them direction written.
2.15
(b)
Using the same reasoning as in part (a), we can see that the above reaction will not occur to a significant extent.
As written, the above reaction will take place to virtual completion due to the large difference in pKa values.
2.16 Enter –9.31 into a calculator and use the INV LOG function to arrive at the answer Ka = 4.9 x 10–10 .
2.17 Locate the electron pair(s) of the Lewis base and draw a curved arrow from the electron pair to the Lewis acid. The electron pair moves from the atom at the tail of the arrow (Lewis base) to the atom at the point of the arrow (Lewis acid).(Note: electron dots have been omitted from Cl– to reduce clutter.)
(a)
(b)
2.18 (a) The nitrogen on the left is more electron-rich and more basic. The indicated hydrogen is most electron-poor (bluest) and is most acidic.
(b)
2.19
Vitamin C is water-soluble (hydrophilic) because it has several polar –OH groups that can form hydrogen bonds with water. Vitamin A is fat-soluble (hydrophobic) because most of its atoms can’t form hydrogen bonds with water.
2.20 Naphthalene has three resonance forms.
2.22 Electrostatic potential maps show that the electron-rich regions of the cis isomer lie on the same side of the double bond, leading to a net dipole moment. Because the electron-rich regions of the trans isomer are symmetrical about the double bond, the individual bond dipole moments cancel, and the isomer has no overall dipole moment.
MechanismProblems
(b)
(c)
(b)
(c)
(d)
2.26 (a)
(c)
2.27 (a) (b)
(c)
Additional Problems
Electronegativity and Dipole Moments
2.28 Use Figure 2.2 if you need help. The most electronegative element is starred.
2.29 More polar
(a)
Less polar
(b) (c)
(d)
2.30 (a) (b) (c) (d)
2.31 (a) In Section 2.2, we found that μ = Q x r. For a proton and an electron separated by 100 pm, μ = 4.80 D. If the two charges are separated by 136 pm, μ = 6.53 D.
(b) Since the observed dipole moment is 1.08 D, the H–Cl bond has (1.08 D / 6.53 D) x 100 % = 16.5 % ionic character.
2.32 In phosgene, the individual bond polarities tend to cancel, but in formaldehyde, the bond polarities add to each other. Thus, phosgene has a smaller dipole moment than form aldehyde.
2.33 The magnitude of a dipole moment depends on both charge and distance between atoms. Fluorine is more electronegative than chlorine, but a C–F bond is shorter than a C–Cl bond. Thus, the dipole moment of CH3F is smaller than that of CH3Cl.
2.34 The observed dipole moment is due to the lone pair electrons on sulfur.
Cambridge Gulf Tribes, x, 51, 62, 65, 74, 93, 99, 101, 226, 238, 282, 288, 375, 377, 405
camel, ochre drawing of, 329
Campbell, John, 344
camp, clearing a site for, 100; life, 100-119; occupations while in, 112, 113; selection of, 91
camptocnemia, 15 cannibalism, 21, 189
canoes, 160-164; dug-outs, 164; housing of, 162; with outriggers, 164; with sail, 164
capacity of skull, 37
Cape York, 93, 104
caravan travelling, 1 caries, 31
Carpentaria Gulf, 50, 93, 128, 129, 151, 160, 161, 162, 164, 189, 201, 266, 287, 375
carpentry taught boys, 85 carrying, dogs, 67; infants, methods of, 66, 67 carved bone, 313; grave posts, 207, 309-310; pearl shell, 313;
trees, 308, 309;
weapons, 310
carvings in rock, 299-308
Cassia, branch used as an emblem of peace, 2; used for headgear, 280
casus belli, 183
caterpillar, 122; totemic designs of, 350, 352
Caucasian, 58, 59; derived from Australoid, 59
cave drawings, 314, 315, 322 et seq.; of Glenelg River, 333, 343-345; inspiration given by natural feature, 331, 332
celestial “walk-about,” 296
ceremonial dance, drawing of, 332, 338
ceremony of welcome, 379 character of aboriginal, 227
characteristics of race, 5-17
charcoal drawing, method of, 323; of ceremonial dance, 338, 332; of crows, 319, 335, 336; of buffalo hunter, 325, 337; of kangaroo hunter, 326, 337
cheek bone, 30 chief of tribe, 226
chignon, 47
child decorations, 84, 85
childhood, 69-90
children, entertainment of, 69, 70, 71; position of at ceremonials, 84, 85; playing with sand and mud, 73-75; running after wind-driven seeds, 76; taught to sing and dance, 70; taught to draw and imitate tracks, 71, 72, 73; tobogganing, 75 chin, 29
Christianity, 257
cicadae and crickets, musical powers envied, 384 cicatrices, 236-238, 250
circle-within-circle designs, 351, 353
circumcision, 239-244; drastic treatment of shirkers, 243
clubbing the initiate, 242
clubs, 168, 169, 170; in warfare, 188
club-rule, 222-223
“coal sack,” 332
cockatoo, kept as pet, 89 colour, artificially applied to body when hunting, 142; of aboriginal’s skin, 40-45; affected by climate, 45, 49, 59 composition, in aboriginal art, 338
conception, ideas about, 284, 285
conventional designs, 346 et seq. conventional representation of human figure, 353-358 conversation, actions aiding, 395; by song, 385
conversationalist, the aboriginal as, 371, 395
Coo-ee, 2. See also “käu,” 142
cooking, methods of, 108
cooleman, 92
Coopers Creek, 50, 83, 92, 102, 114 (Barcoo), 121, 127, 150, 155, 169, 170, 190 (Barcoo), 200, 237, 362, 376
cores, stone, 364
corrobboree, 377
cosmetics, 115
Cossus moth (witchedy), 122, 204
cotton tree (Bombatt malabaricum), 249 council of old men, 225, 226
Crocker Island, 131, 191
Crocodile, carvings of, 331; ceremony of, 377; eggs of, 126; floating log to simulate, 159; hunting the, 134 cradle, food-carrier taking the place of, 65 “cratch-cradle,” 84 crawfish, 128
cremation, not practised, 204
crossed boomerangs, the symbol of strife, 347, 351
crows, ceremony of, 378, 379; drawing of, 319, 335, 336
“cutting” the shadow, 175
Cunningham, Professor D. J., 24
Cyperus rotundus (“yelka”), 148
Cyrena, acting as a pigment dish, 319; used as a scraper, 162
D
“dabba,” stone knife, 367 daggers, 172
Daly River spear types, 196, 197, 198
“damatba” throwing weapon, 170
“dangorra,” the great emu in the sky, 315, 333, 349 Darwin, Charles, 33
dead person’s name not mentioned, 211, 212 death, tracing the cause of a, 208, 209
dental rudiments, 33 de Rougemont, 133
desert surroundings, 1 dialects, variety of, 387, 388
“didjeridoo” drone pipe, 375, 376, 379, 380
Dieri Tribe, xiv, 4, 76, 82, 83, 92, 111, 121, 150, 155, 170, 172, 190, 205, 206, 218, 237, 242, 271, 282, 289, 290, 361, 362, 376, 386, 396, 400
diminutive expressions, 396, 400
“dindula,” hair ornament, 47 dingo, the wild dog of Australia, 119; hunting the, 141; mythical dingo or “knullia” people, 342
Diprotodon, 52, 54; associated with other bones, 119; carving of spoor, 307 disc throwing, 76 discipline, 85
diseases, the cause of rapid decline of aborigines, xiv dog, the constant companion of aboriginal, 118, 119 dolichocephaly, 35
dolls, 79, 80
down-decoration of ground, 282, 326
Dravidians, 58
drawings, in sand, 70-73; of “totem,” 339-343
dress, mode of, 113, 114, 115
drinking, methods of, 98, 99 drone pipe, 375, 376, 379, 380
drought, trying conditions of, 117
Dubois, Professor, 55
Duboisia Hopwoodi, 155
Duckworth, Professor, W. L. H., 33
duels, 165-174;
boomerang, 168;
chivalry displayed in, 174; club, 168-170; damatba, 170; heavy spear, 172, 173; kutturu, 165-168; reed spears, 171; stone dagger, 172; shield used in, 173 dugong, hunting the, 134-137; sung to during initiation, 19 dugout canoes, 164
Durham Downs, 237
E
ear, 29, 30 echidna designs, 336, 346, 347 eggs, of birds, 125, 126; of reptiles, 126
“Elaija,” a sacred ancestor, 283
“elbola,” bark headgear, 280
“elenba,” wooden hair pins, 47 elopement, 223
emu, in the sky, 315, 332, 333, 334, 349; carved in boabab, 309, 330; carving on boomerang, 317;
ceremony, 274-280, 377, 378; game, 81, 82; gum leaves imitating the rustle of, 374; hunting the, 129-140; neck in the sky (“Yirrerri”), 334
enemy, corrobboree portraying the slaying of, 383, 384
“engulba,” pitjuri, 155
ensellure, 7
epipteric bone, 36
“Erinnja,” an evil spirit, 294
“erriakutta” (yelka) ceremonial drawing, 282, 327
erythrism, 48
escort of natives, 2
Etheridge, R., x ethmoid, 25
“Etominja,” sacred ground design, 282, 326
Eucalyptus corymbosa (Bloodwood), 98, 152; dumosa (water mallee), 98; miniata (woolly butt), 161; rostrata (red gum), 147; tetradonta (stringy bark), 161
Eugenia, leaf poultice applied to breast, 20 evil spirit, 291, 292, 294, 299, 314, 385
exchange of wives, 224
exclamations, 398, 399
external angular process, 25
extremities, length of, 10
eye, 23, 25
F
Face, 22-30
fat of emu and goanna, 115
fatty tissue scant in aboriginal, 5, 6
fatty tumours, 6
feather wig, 50
femur, 14, 15
feet, evolution and use of, 10 et seq.; “hand-like” form of Berringin tribesman, 11
fibula, 16
fight, corrobboree of, 382
figure contrast between aboriginal and European, 5 et seq.
fire-fly, artificial, 376
fire ceremony (“Ngardaddi”), 261, 263
fire, 108; shovels, 109, 110; saw, 111, 202; sores, 110; stick, 110, 112; whisk, 110, 111; the precursor of civilization, 258, 260; legend concerning origin on earth, 259, 260 fireless cooking, 80
fire walking, 236
firewood, gathered by women, 107 fish, barriers, 129; designs, 350; hooks, 132; nets, 129, 130, 131; nooses, 129; ochre drawings of, 328; spears, 131, 132
fishing, in parties, 127, 128, 129; line, 132; methods, 127, 128; races, 128
flatfoot, 12
Flinders, Matthew, 117
Flinders Ranges, burial customs in the, 206; ochre mine, 316;
rock carvings, 299, 303-308
flying fox design, 345, 350
foetal elements (“rattappa”), 287
food-carrier, used as cradle, 64, 65, 66
food restrictions, 250, 251
foot of Tasmanian, 14
footmarks in caves, 322
fourth molar, 32, 33
forehead, 23, 35
Fowler’s Bay, 64, 76, 295, 383
Fraipont’s method, 28, 29
frog, corrobboree of, 379
frog dance of children, 70
frog designs, 335, 346
frontal bone, 35, 36
frontal suture, 34
Frontispiece, 145
funeral chant, 211
G
gagging the initiate, 242, 246
Garner, Professor, 405
Genyornis, carving of track, 308
geological antiquity, 49, 52, 53, 54
gesture language, 388-394
“
gibba,” chewed bone, 176
“Gibberi,” circumcision, 242
Gibraltar skull, 23, 32
Ginmu Tribe, 4, 253
girls accompany women instructors, 85
Glenelg River, xi, 159, 288, 312, 333, 344
goanna, 127
Gondwana, 55, 56
Good Spirit, 294, 295
goose hunting, 138, 139
“gorri,” a game played on the Humbert River, 76, 77
gouge, bone, 314
grasshopper, 387
grass tree, cover when emu hunting, 140; flower stalks used for making spear shafts, 195
grave posts, 207
Great Australian Bight, 66, 141, 169, 192, 199
great emu ceremony, 274 et seq.
Grey, Sir George, xi, 219, 272, 340, 343, 344
Gribble, E. R., 17
Groote Island, 101, 164, 197
ground drawings, 282, 326, 327
grubs, 122-125
gruesome rite, 247, 290
“gummanda,” cicatrices, 238
H
habitations, 101-105
half-castes, 59, 60
hailstone (“Imbodna”), mythical stone, 264 hair, 46, 47; belts, 116; cutting of, 117; pins (wooden), 47
Hakea bark, charcoal used for blackening hair, 285 hammers, stone, 360
hand-ball, 77
hand-like feet, 10-12
hand-prints in caves, 321, 322
hand-mills, 319, 361
hardening the child, 236
hatchets, stone, 362, 363
hawk traps, 137, 138
head-biting during initiation, 244, 245
head-dress, of emu ceremony, 277; of “tjilba purra” (phallic) ceremony, 287
head-rests, 105
height of aboriginal, 16, 17
Helix perinflata, 121
Hickson, Sydney, 49
hide and seek, 78, 79
Higgin, A. J., 157
hollow trees used as shelters, 102
honey, wild bees’, 145; drink, 153, 154
honey-ant, 146, 147
Howitt, Dr. A. W., 295
human chain-pattern, 353, 354, 355
human form, pictographic representation of, 353-358
Humbert River, 76, 320, 324, 336, 337, 352, 353, 403
Humboldt, Alexander von, 20
humerus, 16
hunt, objects of the, 121
hunting, 120-147; buffalo, 144, 145; crocodile, 134; dingo, 141; dugong, 134-137; emu, 129-140; geese, 138, 139; hawks, 137, 138; kangaroo, 141-144; opossum, 140, 141; turtle, 132, 133; whistling duck, 139; wallaby, 141; wombat, 141
hunting instinct, 120, 121
hunting with fire, 126
huts, 102-105
Huxley, Thomas, 24
hypertrichosis, 46 I
“ilbarinam,” tjuringa, xi
“ilja-imbadja,” hand marks in caves, 321
“ilgarukna,” venesection, 275
“illiya tjuringa,” emu ceremony, 274 et seq.
“ilpalinja,” sun worship, 265-267
“Iltdana,” evil spirit, 292 Ilyauarra Tribe, 4, 205
“Imbodna,” a mythical hailstone, 264
“Imboromba,” a spirit father’s mate, 287 imitation, of the plovers’ call, 70, 265, 379, 386; of the dingo’s howl, 70; of the jungle fowl’s call, 380; of the crow’s call, 378; of the crocodile, 377; of the emu, 279, 378
“Indorida,” the mate of Rukkutta, 291 infant betrothal, 221 infant, treatment of, 64-68; rubbing milk and charcoal over body of, 65; singeing hair of, with fire stick, 65 “ingada,” a chief, 226
Ingada Ladjia Knaninja, leader of yam ceremony, 281 “ingwitega,” munyeroo, 150 inion, 36 initiation, 230-256; amputation of finger-joints, 253, 254; of the female, 252, 253; origin of, 251, 252; without mutilation, 249 instinct for locating water, 96
interment, 205-207
internal angular process, 25 interrogatives, 403
intitjuma, ceremonies, 274
intoxicating drink, 153, 154
introduction to a tribe, 1-3
iris, 25
“irr,” 171; expression of disgust, 118
“irriakutta,” yelka, 149 J
“jarrulge,” mulga apple, 152
Jewish features, 26
“jingardti,” a chief, 226
Joyce, Capt. T. A., x judge of character, 228
“judja,” a chief, 226
jungle fowl, corrobboree of, 380, 381
jus primae noctis, 256
justice, idea of, 227 K
“kadabba,” phallus, 283, 284
Kai Kai, an old medicine man, 180
“kaidi,” tjuringa, 270
kaili (boomerang), used as musical instrument, 383; miniature, for practice, 82
Kaitidji (Kaitish) Tribe, 4, 92, 364
Kakera, marriage group, 220
Kakatu Tribe, 4, 267
“kaleya pubanye,” the sitting emu (coal sack), 332
“kaloa,” raft, 160; toy models of, 82
“kalumba,” nardoo, 150
“kalunuinti,” phallus, 288
“kanbanna,” paddles, 159
kangaroo, charcoal drawings of, 321, 326, 336, 337; conventional representation of, 350; corrobboree of, 381; hunt, 141-144; ochre drawings of, 327, 328; origin of “arre,” its name, 387; tjuringa design of, 349, 352
“kapa” or “kadje,” water lily, 151
“kapi wiyinna,” magic water stick, 264
“karru,” milky way, 349
“karwinnunga,” shield, 173
“käu,” vide Coo-ee, 142
“käu-käu,” chewed bone, 176
“kaula,” native pear, 152
Keith, Sir Arthur, x
kidney fat and marrow of dead warriors eaten, 189
Killalpaninna, 290;
“killa wulpanna,” 290, 291
King Sound natives, 50, 82, 88, 132, 151, 159, 283, 309, 311, 330, 358, 363, 396
kitchen-middens, 121, 122
Klaatsch, Professor Hermann, x, 25, 28, 29, 42, 50
“Knaninja,” xi, 265, 271, 274, 280, 281, 282, 285, 327, 341, 352, 353
“Knaninja Arrerreka,” mythical sun creature, 265; ceremonies of, 274
knives, stone, 364
“knudda” (fat) of witchedy, 342
“Knurriga Tjilba Purra” (phallus), 286; head of the Kukadja, 285
kobong, xi, 219, 226, 232, 269, 271, 272, 340
Kochia bush, used for making vegetable-down, 276
Kolaia Tribe, 4, 65
“kolldürr,” stone spear-head, 370
Kukadja, 285, 286, 292, 293
Kukata Tribe, 4, 32, 81, 82, 87, 184, 200, 205, 236, 241, 242, 248, 255, 288, 296, 318, 361, 362
“kukerra,” playing stick, 82, 83
Kumara marriage group, 220
Kunapippi, a mythical witch, 271
Kurdaitja, an evil creature, 71, 72
“kurreke tata,” the plover, 70, 265, 386
“kutturu,” fighting stick, practice, 87; duels, 165-168; embodied in head-gear, 280
Kuyanni Tribe, 4, 362
“Kwatje,” water, ceremonies, 274
“Kwatje purra,” magic water stick, 264
L
lachrymal bone, 25
lactation, artificial, 20
“ladjia,” or yam tjuringa, 280 et seq., 337; design of, 347
Lake Eyre, 50 lances, 193
“langa langa,” a shell knife used for “cutting the shadow,” 175
“langu,” native pear, 152 language, xii, 386-405
lanugo, 46, 49
La Perouse, 107
Larrekiya Tribe, 4, 62, 77, 111, 130, 131, 139, 142, 163, 164, 170, 196, 201, 202, 205, 207, 208, 210, 230, 249, 252, 332, 374, 379, 384
legs, 14
Lemuria, 55, 56
lerp manna, 147
leucoderma, 43
licentiousness, 224, 254
“lionila,” a club, 170
lipomas, 6
lips, 31
living skeletons, 21 lizards, 126; designs of, 334, 335
lobulus, piercing of, 30 log rafts, 158-160
“lorngai,” feather wig, 50
lumbo-sacral curve, 9
“lurra,” a lipoma, 6 M
MacDonnell Ranges, 50, 92, 127, 146, 153, 155, 218, 226, 285, 291, 341, 362, 364, 405
Maiyarra’s conception, 61; accouchement, 63
Malay bêche-de-mer fishers, 57 manna, 147 mastoid process, 30
“marimba,” wallaby bone used for loosening a tooth, 236 marine molluscs, 121, 122
marital relationships between man and woman, 222, 223
marriage systems, 218, 219, 220, 221; allotment of infant, 221, 222
“marriwirri,” wooden sword, 170