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Radiocarbon Dates for upper Eem and Würm-interstadial samples By H L . DE VRIES, Physical L a b o r a t o r y , U n i v e r s i t y of G r o n i n g e n , N e t h e r l a n d s 1 text-fig. 14
Z u s a m m e n f a s s u n g : Es wird eine Obersicht gegeben von C - D a t e n von Eem-interglazialen und Würm-interstadialen Proben von Loopstedt (Schleswig-Holstein), Amersfoort (Nie derlande), Lebenstedt, Roggendorf, Karrestobel, Geesthacht, Upton Warren (England), Fladbury (England) und von einer Serie von Holzkohle-Proben aus den Lößgebieten. Sogar die jüngsten Eem-Proben zeigten keine signifikante Aktivität (Alter mehr als 53 000 Jahre). Die Daten stellen das Interstadial Würm I I / I I I (fossiler Boden von Paudorf) auf rund 26 000 Jahre vor heute. Die Daten für das Interstadial I/II sind noch teilweise unzuverlässig, weil Verunreinigung mit rezentem Material (Wurzeln, Humus) für diese alten Proben relativ viel für die totale Aktivität beiträgt. Obwohl die Periode zwischen 33 000 und 42 000 Jahren (vor heute) ziemlich kalt war, ist es nicht unmöglich, daß es sich hier um das Interstadial W I/II handelt. Ein wärmeres Interstadial endete vor ungefähr 48 000 Jahren. Die Daten stimmen mit EMILIANIS Paläotemperaturkurve (und MILANKOVITCHS Zeitskala) überein. S u m m a r y : Radiocarbon dates have been obtained for Eem-interglacial and Würm-inter stadial sections from L o o p s t e d t (Germany) and A m e r s f o o r t (Netherlands), for a few isolated peat samples from North-Western Europe and for charcoal samples from Austrian loess regions. Even the upper part of the Eemian proved to be too old to give a significant activity (age more than 53000 years). According to the present results the interstadial Würm I I / I I I (fossil soil of P a u d o r f ) occurred at about 26000 years ago. Because of various contaminations of the samples (infiltrated humus, rootlets etc.) the results for the interstadial Würm I/II are somewhat controversial, but it is not impossible that it should be identified with the fairly cool period between 33 000 and 42 000 before present. A somewhat warmer interstadial ended about 48 000 years ago. The results fit well with EMILIANIS paleotemperature curve. 1 The
measurements
T h e measurements described below w e r e m a d e in o u r large counter. T h e net count for recent carbon is 36.9 per m i n u t e . T h e present b a c k g r o u n d is 2.4 per m i n u t e . I t varies 0.05/min for a v a r i a t i o n in b a r o m e t e r pressure of 1 cm H g . F o r details see (1,2). In t h e calculations a half life of C of 5570 years has been used. T h e error given is the s t a n d a r d d e v i a t i o n ; it includes the error in the background as well as the error in t h e sample c o u n t . Since the background, corrected for b a r o m e t e r effect, w a s very c o n s t a n t , several back g r o u n d measurements could be a v e r a g e d . This leads to a relatively small error in t h e background. T h e dates given represent the average result of a t least t w o measurements, which, as a rule, are n o t r e p o r t e d s e p a r a t e l y . 1 4
O u r measurements of old samples h a v e d e m o n s t r a t e d the i m p o r t a n c e of an a p p r o p r i a t e p r e t r e a t m e n t , developed to r e m o v e infiltrated o r g a n i c m a t e r i a l . A l l samples w e r e boiled first w i t h a one per cent solution of hydrochloric acid. After w a s h i n g w i t h distilled w a t e r they w e r e heated a t least one n i g h t at 90° C w i t h o n e per cent sodium h y d r o x y d e . T h e sample w a s w a s h e d then, one p e r cent hydrochloric acid added, h e a t e d again a n d w a s h e d u p to a p H of 4 or m o r e . T h e e x t r a c t e d h u m u s w a s precipitated w i t h hydrochloric acid, washed a n d dried. Before considering the dates o b t a i n e d , the i n d i v i d u a l samples will be discussed. d e V o o r s t , N o r t h E a s t e r n P o l d e r (former Zuidersee). T h i s series of samples w a s collected from a well exposed section of the E e m i a n a t de V o o r s t (3). Dates f r o m 43000 to "infinite" were o b t a i n e d f r o m samples b e t w e e n the beginning of the climatic o p t i m u m of the E e m Interglacial a n d the end of the Riss Glacial. T h e samples have been