Mechanical Seal Secondary Sealing Elements

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Mechanical Seal Secondary Sealing Elements

FSA Knowledge Series

DISCLAIMER

While the FSA makes every reasonable attempt to ensure that the information contained in this document is accurate and current, the FSA, its officers, directors, volunteers, and authorized agents are not responsible for any errors or omissions contained therein nor are they responsible for any results obtained from the use of or reliance upon its content. All information is provided “AS IS,” with no guarantee of completeness, accuracy, timeliness or of the results obtained, and without warranty of any kind, express or implied. In no event shall FSA or its officers, directors, volunteers, or authorized agents be liable to you or anyone else for any decision made or action taken in reliance on the information con tained herein or for any for any consequential, indirect, special, or similar damages, even if advised of the possibility of such damages. The informa tion contained in this document is for informational purposes only and does not constitute professional advice. It also includes references to certa in standards that may change over time and should be interpreted only in light of particular circumstances. It is your sole responsibility to confi rm the current state of any referred to standards. FSA reserves the right to modify or update the document content and to modify this Disclaimer at any t ime, effective upon posting of an updated version of this Disclaimer.

© (April, 2023), Fluid Sealing Association. All Rights Reserved.

This Fluid Sealing Association Knowledge Series training presentation introduces secondary sealing elements. Secondary sealing elements or secondary seals are the elements that provide sealing between the primary and mating rings to the drive/shaft and gland/housing components. A description is provided on:​

▪ Elastomeric O-ring secondary seal design parameters

▪ ​Elastomeric/PTFE material and configuration options (including back-up rings)

▪ Common secondary seal failure modes

▪ ​Thermoplastic and other material options

Mechanical Seal Basic Components

Rotating Assembly

Sleeve

Rotating Primary Ring

Stationary Mating Ring

Secondary Sealing Elements

Stationary Gland Plate

Locking Collar

O-Ring in Groove

High Pressure Side Low Pressure Side

Groove OD
Groove ID
Groove Width
Extrusion Gap

Elastomeric O-ring Design Parameters

Groove / O-ring Geometry

▪ Installed Stretch

▪ Installed Compression / Squeeze

▪ Cavity Fill

▪ Extrusion Gap

Physical Properties

▪ O-ring Hardness (Durometer)

▪ Coefficient of Thermal Expansion (CTE)

▪ Chemical Swell

▪ Compression Set

O-Ring Stretch

▪ Example case: AS-568 size 226 (2.000” Nominal ID O-ring)

▪ O-ring Cross section changes in non-linear relationship with stretch

▪ Excessive stretch may cause O-ring breakage or failure due to high internal stresses (Gow-Joule Effect)

Installed Compression / Squeeze

▪ Squeeze is required for the O-ring to effectively seal

▪ Pre-loads the O-ring against the sealing surfaces

▪ Typical squeeze:

▪ 10% – 15% for static O-rings

▪ 5% – 10% for dynamic O-rings

▪ Depends on O-ring cross section, use, tolerances of O-ring and Groove

▪ Specialty designs may deviate from these typical numbers

Cavity Fill

▪ The percentage of free volume or cavity fill of an Oring is affected by thermal growth and chemical swell in operation

▪ Normal fill range is highly design dependent

▪ High fill conditions can limit ability of O-ring to flex or move as required

▪ Overfill can cause seal failure through:

▪ Extrusion of O-ring

▪ Component failure due to high stresses

Linear Coefficient of Thermal Expansion (CTE)

▪ Elastomers grow at a substantially higher rate than steels or ceramics, resulting in an effective increase in squeeze and a reduction in free volume

▪ Perfluoroelastomer (FFKM) ~ 170 x 10-6 in/in/°F (300 x 10-6 m/m/°C)

▪ Fluorocarbon (FKM) ~ 95 x 10-6 in/in/°F (170 x 10-6 m/m/°C)

▪ Ethylene Propylene (EPDM) ~ 89 x 10-6 in/in/°F (160 x 10-6 m/m/°C)

▪ Nitrile (NBR) ~ 62 x 10-6 in/in/°F (110 x 10-6 m/m/°C)

▪ Stainless Steel ~ 9 x 10-6 in/in/°F (16 x 10-6 m/m/°C)

Elastomer Materials

▪ NBR – Nitrile

▪ HNBR – Hydrogenated Nitrile

▪ EPR/EPDM – Ethylene Propylene

▪ FKM – Fluorocarbon (Viton®)

▪ FEPM – Fluorinated Ethylene Propylene (Fluoraz®, Aflas®)

▪ FFKM – Perfluoroelastomer (Chemraz®, Kalrez®)

▪ Chloroprene (Neoprene®)

Viton ® is a registered trademark of Chemours

Neoprene ® and Kalrez ® are registered trademarks of DuPont Performance Elastomers

Aflas ® is a registered trademark of Asahi Glass Company, Limited

Fluoraz ® and Chemraz ® are registered trademarks of Greene Tweed & Co.

Elastomer Materials – NBR (Nitrile)

Exhibits good compression set, tear and abrasion resistance

Use in Avoid in Petroleum based fluids, water, silicone fluids, ethylene glycols

Phosphate ester, steam, halogenated

hydrocarbons, ketones, acids, brake fluids, ozone and H2S

"Vulnerable" double covalent bond

Electronegative Nitrogen (Polar –ve)

Butadiene
Acrylonitrile

Elastomer Materials – NBR (Hydrogenated Nitrile)

Better high temperature and chemical resistance than standard Nitrile. Still exhibits good compression set, tear and abrasion resistance.

Use in Avoid in Mineral oils and greases; diluted acid, caustic, H2S and amines

Aromatic HC, chlorinated HC, ketones, high concentration H2S

"Vulnerable" double covalent bond replaced with hydrogen

Elastomer Materials – EPR/EPDM (Ethylene Propylene)

Excellent compression set and resistance, limited temperature range.

Use in Avoid in Water/steam, acetone, diluted acids and caustics, ketones

Mineral oil, solvents, aromatic HC

Elastomer Materials – FKM (Fluorocarbon)

Excellent high temperature resistance with good chemical resistance and compression set properties. Use in Avoid in Mineral oils, some acids and bases, HC, low concentration H2S

Amines, ketones, steam, and selected acids

Hexafluoropropylene

Elastomer Materials – FEPM

Excellent heat and chemical resistance.

Use in

Water/steam, mineral oils, thermal oils, hydraulic fluids, H2S up to 35%, amines, radiation

Avoid in

Aromatic hydrocarbons, chlorinated HC, ketones, acetone

Elastomer Materials – FFKM (Perfluoroelastomer)

Most extensive heat and chemical resistance.

Use in

Water/steam, mineral oils, thermal oils, hydraulic fluids, harsh chemicals

Avoid in

Perfluorinated solvents and alkali metals

Relative Performance of Elastomers

Chemical

Compatibility

Toughness

Toughness

Chemical Compatibility

Chemical Compatability

Toughness

High-performance Sealing Solutions

O-rings

Advantages

▪ Relatively easy to design

▪ Seals effectively

▪ Economical

▪ Availability

Disadvantages

▪ Temperature (high / low)

▪ Service Pressure

▪ Limited dynamic use

Advantages

▪ Easier to install

▪ Less chance of spiral damage

Disadvantages

▪ Non-standard Groove

▪ Less space for expansion

Advantages

▪ Lower friction

▪ Bidirectional

Disadvantages

▪ Stretch affects performance

▪ More prone to nibbling

▪ Poor availability High-performance

High-performance Sealing Solutions - Back up Rings

Reduces extrusion gap for High Pressure Applications

Back-up Ring component

Elastomer component

High-performance Sealing Solutions - Back up Rings

Design Variations

Straight Cut
Concave
Tapered

High-performance Sealing Solutions - Energized PTFE Seals

Advantages

▪ Chemically inert

▪ Low breakout and running friction

▪ Wide range of usable temperature (-450°F to 600°F)

▪ Precision machined

Disadvantages

▪ Finer surface finishes required

▪ Must be pressurized

▪ Unidirectional

▪ Metal spring exposed to fluid

High-performance Sealing Solutions - Energized PTFE Seals

Custom Engineered Solutions

▪ Bi-directional sealing

▪ Tall and Narrow Glands

▪ Extreme Pressure/Motion

▪ Blind installation

Failure Modes

Elastomeric Secondary Seal

Common Elastomeric Secondary Seal Failure Modes

▪ Installation Errors

▪ Spiral Failure

▪ Compression Set

▪ Chemical Attack

▪ Polymerization

▪ Extrusion/Nibbling Damage

▪ Thermal Degradation

▪ Rapid Gas (Explosive) Decompression

* It is recognized that this list is not all inclusive but covers the most common failure modes

Common Seal Failure Modes

Installation Damage

▪ Shearing of a seal during installation

▪ Hardware must

▪ Results in missing material and possible leak paths

▪ Very short life

Common Seal Failure Modes

Spiral Failure

Identifiers:

▪ Spiral cuts in elastomer

▪ O-ring is twisted

▪ Mold Part lines follow a spiral pattern around seal

Causes:

▪ Inadequate lubrication during installation

▪ Installation causes o-ring to become pinched and roll

▪ Uneven o-ring squeeze

▪ Dynamic motion

▪ Out of perpendicularity

Recommendations:

▪ Use adequate lubrication and care

▪ Use higher durometer elastomer

▪ Check for out-of-round components

▪ Use an alternate seal design

Common Seal Failure Modes

Compression Set/Stress Relaxation

Identifiers:

▪ Flat sided cross-section which correspond to the sealing surfaces

Causes:

▪ Improper gland design

▪ Excessive temperature

▪ Media incompatibly

▪ Incomplete curing of the o-ring

▪ Length of time in compressed state

Recommendations:

▪ Verify o-ring squeeze (account for swell)

▪ Reduce system temperature

▪ Ensure correct compound for application

Common Seal Failure Modes

▪ Recovery of seal after being compressed

▪ Results in reduced sealing force

Amount of Compression

LOAD

Compression Set + TIME

Common Seal Failure Modes

Chemical Attack

Identifiers:

▪ Swelling

▪ Hardening

▪ Blistering/Bubbling

▪ Visual degradation on process side

Causes:

▪ Incompatible elastomer and process fluid (at temp.)

Recommendations:

▪ Evaluate o-ring selection and media

▪ Lower system temperature

▪ Energized PTFE Seal

Common Seal Failure Modes

Polymerization

Identifiers:

▪ Hardening

▪ Solid, foreign particles inside o-ring

▪ Clear-to-white skin

▪ Compression Set

Causes:

▪ Sealing media is an easy polymerizing fluid.

▪ Low elastomer hardness

▪ Polymerization catalysis in elastomer (i.e. metal oxides)

▪ Non-reported or unexpected mix of media

Recommendations:

▪ Use highest hardness elastomer possible.

▪ Ensure compatibility between fluid and elastomer type

▪ Consider a spring energized C-ring

Common Seal Failure Modes

Extrusion/Nibbling

Identifiers:

▪ Ragged edges that correspond to mating hardware gap.

▪ Chewed “nibbled” appearance

▪ Generally occurs on the low-pressure side corner

Causes:

▪ Too Large of extrusion gap and high-pressure system

▪ Low elastomer hardness

▪ Pressure pulsations/vibration nibble extruded material.

▪ Non-reported or unexpected mix of media.

▪ Softening of the o-ring

Recommendations:

▪ Reduce e-gap

▪ Use higher durometer elastomer

▪ Ensure adequate free void space at op. temp

▪ Anti-extrusion ring (Back-up Ring)

Common Seal Failure Modes

Extrusion/Nibbling

▪ Seal material is pushed into the mating hardware gap by higher pressure or dynamic motion

▪ Vibrations and/or pressure pulsations can “nibble” and remove material

Extrusion

Common Seal Failure Modes

Thermal Degradation

Identifiers:

▪ Radial cracking

▪ Brittleness and hardened elastomer

▪ Dull color

▪ Compression set

Causes:

▪ Temperature exceeds elastomer rating

▪ Inadequate heat removal in mechanical seals

Recommendations:

▪ Match elastomer type and service temperature

▪ If temperatures are outside elastomer service range use an alternate seal

▪ Lower service temperature.

▪ Check API seal piping plan

Common Seal Failure Modes

Rapid Gas Decompression (RGD)

Identifiers:

▪ Surface Blisters

▪ Internal tears and splits in elastomer substrate

▪ High vapor pressure fluid

▪ High number of decompression cycles

Causes:

▪ Rapid system depressurization

▪ Sudden temperature spike resulting in phase change

▪ Low elastomer modulus

▪ Elastomer with inclusions, voids and/or agglomerates

Recommendations:

▪ Select an RGD resistant seal material

▪ For extreme services use thermoplastic seal

▪ High gland fill (~90%) (thermal expansion and swell must be considered

▪ Seal cross-section as small as possible

Common Seal Failure Modes

Rapid Gas Decompression (RGD)

None of these seals failed !

Other Materials

Elastomeric Secondary Seal

Advanced

Engineered Thermoplastics: (PTFE)

Mostly PTFE-based (PFA, MFA)

▪ FDA

▪ USP Class VI

▪ Wear Resistant

▪ Cryogenic

▪ Most Fit Standard O-ring Grooves

Advanced

Engineered Thermoplastics: (PTFE)

Advantages:

▪ Superior chemical resistance

▪ Low breakout Friction

▪ Low running friction

▪ Wide thermal capabilities

▪ Cryogenic service

Disadvantages:

No memory

Low strength

Low wear factor

Radiation Resistance

Advanced Engineered Thermoplastics: (PTFE)

Filled PTFE

▪ Material Properties – Carbon Fiber, Glass Fiber.

▪ Friction and Wear – Graphite, other thermoplastics

▪ Electrical, CTE, etc.

Advanced

Engineered Thermoplastics: (PEEK)

▪ Mostly PEEK-based (PEK, PEKEKK)

▪ Many production grades

▪ Food contact approved

▪ Friction and Wear

▪ High Strength

▪ Compression and Injection Molding

Advanced Engineered Thermoplastics: (PEEK)

Advantages:

▪ High Physical Properties ▪ Good Wear Properties

Radiation Resistance

Disadvantages:

Strong concentrated acids

Sealability

Aromatic HC’s

Advanced Engineered Thermoplastics: (PEEK)

Filled PEEK

▪ Like PTFE, PEEK can be processed with fillers

▪ Strength and Stiffness – Fibers, Minerals

▪ Increase friction/wear properties – PTFE, graphite, etc.

▪ Other properties – Electrical and thermal conductivity

Acknowledgement

The FSA wishes to acknowledge Greene, Tweed & Co who provided some of the content included in this presentation.

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