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AbouttheAuthor

Prof.MiklasScholz,CandIng,BEng(equiv),PgC,MSc,PhD,CWEM,CEnv, CSci,CEng,FHEA,FIEMA,FCIWEM,FICE,FellowofIWA,holdstheChair inCivilEngineeringatTheUniversityofSalford(Figure1).HeistheHeadof theCivilEngineeringResearchGroup.Prof.Scholzhasshownindividual excellenceevidencedbyworld-leadingpublications,postgraduatesupervision, andresearchimpact.Hismainresearchareas(Figure2)intermsofpublication outputareasfollows:treatmentwetlands(20%),integratedconstructedwetlands(ICW;15%),sustainablefloodretentionbasins(SFRB;5%),permeable pavementsystems(5%),decisionsupportsystems(5%),ponds(5%),and capillarysuctiontime(5%).About45%and40%ofhisresearchareinwater resourcesmanagementandwastewatertreatment,respectively.Theremaining 10%isincapillaryprocessesandwatertreatment.

Hehaspublishedfourbooksandmorethan176journalarticlescovering awiderangeoftopics(Figure2).Between2009and2015,hetoppedthe publicationlistintermsofnumbersforallmembersofthestaffat TheUniversityofSalford.Prof.Scholz’stotaljournalarticlepublicationsin

FIGURE1 MiklasScholzontopofasustainablefloodretentionbasinnearPerth,Scotland,UK. (Picturetakenby AsaHedmark.)

Sustainability

Civil Engineering

Drainage Systems

FIGURE2 Overviewofresearchareasandtheircorrespondingrelativeimportanceandlinkages betweenthem.

recentyearsareasfollows:2009,13articles;2010,19articles;2011,13 articles;2012,21articles;2013,17articles; and2014,15articles.

Hepublishesregularlyinthefollowingjournalswithhighimpactfactors: BioresourceTechnology,BuildingandEnvironment,ConstructionandBuilding Materials,Desalination,EcologicalEngineering,EnvironmentalModelling& Software,EnvironmentalPollution,Industrial&EngineeringChemistry Research,JournalofChemicalTechnologyandBiotechnology,Journalof EnvironmentalManagement,LandscapeandUrbanPlanning,Scienceofthe TotalEnvironmentandWaterResearch

Prof.Scholzhastotalcitationsofmorethan2845(above2122citations since2010),resultinginanh-indexof28andani10-Indexof64.Prof.Scholz isEditor-in-Chiefof13journals,includingtheWebofScience-listedjournal Water(impactfactorsfor2014:1.428).Hehasmembershipexperienceon35 influentialeditorialboards.Prof.ScholzwasamemberoftheInstituteof EnvironmentalManagementandAssessment(IEMA)Councilbetween2008 and2015.

Miklashasacurrentlyactive(on-going)grantincomeofusually £270,000. Hisgrantincomeoveranypastsixyearsistypically £1,500,000.Thesefigures includeresearchandothergrants,aswellasconsultancy.

Hissustainablefloodretentionbasin(SFRB)conceptassessesthemultifunctionalityofalllargewaterbodies,withparticularreferencetotheirflood

Thetextbookisessentialforundergraduateandpostgraduatestudents,lecturers,andresearchersinthecivilandenvironmentalengineering,environmental science,agriculture,andecologicalfieldsofsustainablewatermanagement.It shouldbeusedasareferenceforthedesign,operation,andmanagementof wetlandsbyengineersandscientistsworkingforthewaterindustry,localauthorities,nongovernmentalorganizations,andgovernmentalbodies.Moreover, consultingengineersshouldbeabletoapplypracticaldesignrecommendations andtorefertoalargevarietyofpracticalinternationalcasestudies,including large-scalefieldstudies.

Thebasicscientificprinciplesoutlinedintherevisededitionshouldbeof interesttoallconcernedwiththebuiltenvironment,includingtownplanners, developers,engineeringtechnicians,agriculturalengineers,andpublichealth workers.Thebookiswrittenforawidereadership,butsufficienthotresearch topicsarealsoaddressedinninecompletelynewchapterstoguaranteealong shelf-lifeforthebook.

Solutionstopressingwaterqualityproblemsassociatedwithconstructed treatmentwetlands,integratedconstructedwetlands,farmconstructedwetlands andstormwaterponds,andothersustainablebiologicalfiltrationandtreatment technologieslinkedtopublichealthengineeringareexplained.Casestudytopics arediverse:wetlands,includingnaturalwetlandsandconstructedtreatment wetlands;sustainablewatermanagement,includingsustainabledrainagesystems;andspecificapplicationssuchaswetlandstreatinghydrocarbonandpiggerywastewater.Theresearchprojectsaremultidisciplinary,holistic, experimental,andmodeling-oriented.

Thebookispredominantlybasedonexperiencesgainedbytheauthorover thelast14years.Originalmaterialpublishedinarticlesinmorethan170highrankingjournalsandpresentedin200keyconferencepapershasbeenrevisited andanalyzed.Experiencetheauthorgainedasaneditorialboardmemberof morethan30relevantpeer-reviewedjournalsguaranteesthatthetextbook containssufficientmaterialthatfillsgapsinknowledgeandunderstanding,and thatitdocumentsthelatestcutting-edgeresearchinareassuchassustainable drainage.

Thebooktriestointegratenaturalandconstructedwetlandsandsustainable drainagetechniquesintotraditionalwaterandwastewatersystemsusedtotreat surfacerunoffandassociateddiffusepollution.Chapters1 4introducewater qualitymanagementandwaterandwastewatertreatmentfundamentalstothe inexperiencedreader.

Chapters5 9reviewpreliminaryandpredominantlyprimarytreatment unitsthatcanbecombinedwithwetlandsystems.Chapters10 15summarize predominantlysecondarybutalsotertiarytreatmenttechnologiesthatcanbe usedincombinationwithwetlandtechnologiesorasalternativesincases wherelandavailabilityisrestrictedduetocosts.UsuallynonessentialtraditionaltechnologiesarebrieflypresentedinChapters16and17forthereasonof completeness.

CommonAcronyms andAbbreviations

A Coefficient (unknownfunctionofvariousvariablesincluding rainfallintensityandinfiltrationrate)

A Cross-sectionofflowarea(m2)

Al Cross-sectionalareaoflysimeter(m2)

AEAICAD Aestheticandeducationalappreciationandinspirationfor culture,art,anddesign(%)

AFTW Aestheticfloodtreatmentwetland

ANN Artificialneuralnetwork

ANOVA Analysisofvariance

AS Activatedsludge

ATV-DVWK Germanabbreviationfor GermanAssociationforWater, WastewaterandWaste

Avg. Average(mean)

B Maximumexperimentaldepth(mm)withintheinfiltration basinduringanindividualstorm

BC Biologicalcontrol(%)

BMP Bestmanagementpractice

BMU Best-matchingunit

BOD Biochemicaloxygendemand(mg/l)(usuallyfivedays at 20 C)

BP Back-propagation

BP-MLL Back-propagationformultilabellearning

BRE BritishResearchEstablishment (company)

C Carbonorcombinedapproachorcontrolorchili

Ce Outflowconcentration (ofcontaminantinwetlandcell) (g/m)

Cf Contaminantconcentrationininfiltrationwater(g/m3)

C0 Inflowconcentration (ofcontaminantinwetlandcell) (g/m)

CBR Case-basedreasoning

CE Communityandenvironmentapproach

CFU Colony-formingunit

CIRIA (British) ConstructionIndustryResearchandInformation Association

COD Chemicaloxygendemand(mg/l)

CSS Carbonsequestrationandstorage(%)

xxxii CommonAcronymsandAbbreviations

SVM Supportvectormachine

T(ort) Infiltrationtime(s)ortemperature( C)

TAV Tourismandareavalue(%)

TE Topographicerror (usuallyin%)

TFRB Traditionalfloodretentionbasin

TOC Totalorganiccarbon(mg/l)

TS Totalsolids(mg/l)

UK UnitedKingdom

U-matrix Unifieddistancematrix

USA UnitedStatesofAmerica

UV Ultraviolet (light)

W West

WTW WissenschaftlichTechnischeWerkstatten (company)

X Variable (here,costunit)

X Domainofinstances

xi Aninstance i

Y Setoflabels

yi Label i

Z1 Factor (definedbytheBREmethod)

Z2 Growthfactor (definedbytheBREmethod)

G Biasparameterofafeed-forwardnetwork

D Symmetricdifferenceoftwosets

1.2WATERQUALITYSTANDARDSANDTREATMENT OBJECTIVES

Itiscommonlyagreedthattherearethreebasicobjectivesofwatertreatment:

1. Productionofwaterthatissafeforhumanconsumption; 2. Productionofwaterthatisappealingtothecustomer;and 3. Productionofwatertreatmentfacilitiesthatcanbeconstructedand operatedatareasonablecost.

Thefirstoftheseobjectivesimpliesthatthewaterisbiologicallysafefor humanconsumption.Ithasalreadybeenshownhowdifficultitistodetermine what“safe”actuallymeansinpractice.Aproperlydesignedplantisnota guaranteeofsafety,standardswillchange,andplantmanagementmustbe flexibletoensurecontinuedcompliance.

Thesecondbasicobjectiveofwatertreatmentistheproductionofwater thatisappealingtothecustomer.Ideally,appealingwaterisclearandcolorless,pleasanttotaste,odorless,andcool.Itshouldbenonstaining,noncorrosive,non-scale-forming,andreasonablysoft.Theconsumerisprincipally interestedinthequalityofthewaterdeliveredtothetap,notthequalityatthe treatmentplant.Therefore,storageanddistributionneedtobeaccomplished withoutaffectingthequalityofthewater;inotherwords,distributionsystems shouldbedesignedandoperatedtopreventbiologicalgrowth,corrosion,and contamination.

Thethirdbasicobjectiveofwatertreatmentisthatitcanbeaccomplished usingfacilitieswithreasonablecapitalandoperatingcosts.Variousalternativesinplantdesignshouldbeevaluatedforcost-effectivenessandwater qualityproduced.

Theobjectivesoutlinedhereneedtobeconvertedintostandardssothat properqualitycontrolmeasurescanbeused.Therearevariousdrinkingwater standards.Thekeyvariablesareasfollows:

l Organolepticparameters:color,turbidity,odor,andtaste;

l Physicalandchemicalparameters:temperature,pH,conductivity,dissolvedoxygen,dissolvedsolids,chlorides,sulfate,aluminum,potassium, silica,calcium,magnesium,sodium,alkalinity,hardness,andfreecarbon dioxide(CO2);

l Parametersconcerningundesirablesubstances:nitrate,ammonium,total organiccarbon(TOC),hydrogensulfide,phenols,dissolvedhydrocarbons, iron,manganese,suspendedsolids,andchlorinatedorganiccompounds otherthanpesticides;

l Parametersconcerningtoxicsubstancessuchasarsenic,mercury,lead,and pesticides;and

l Microbiologicalparameters:totalcoliforms,fecalcoliforms,fecalstreptococci,sulfite-reducingclostridium,andtotalbacterialcount.

Standardsusuallygivetwovalues:aguidelevel(GL)andamaximum admissibleconcentration(MAC).TheGListhevaluethatisconsidered satisfactoryandconstitutesatargetvalue.TheMACisthevaluethatthe correspondingconcentrationinthedistributedwatermustnotexceed.Treatmentmustbeprovidedwhentheconcentrationintherawwaterexceedsthe MAC.

Standardsalsospecifythemethods,frequencies,andnatureoftheanalysis. Fortotalhardnessandalkalinity,thestandardsspecifyminimumvaluestobe respectedwhenwaterundergoessoftening.

Moststandardsgroupsubstancesintofivecategories:

l Microbiological;

l Inorganicwithconsequencesonhealth;

l Organicwithconsequencesonhealth;

l Appearance;and

l Radioactivecomponents.

Oneofthemainsourcesofconfusionregardingwaterstandardsandtheir interpretationisthelackofanyclearindicationastohowthestandardwas derived.Thisresultsintheinterpretationofallstandardsas“healthstandards” bythepublicand,subsequently,inthedifficultyofassessingwhatshouldbe donebythewatersupplierifathresholdisexceeded.

Thisisparticularlytrueofdrinkingwaterqualitydirectivesbecause insufficientexplanationofthederivationoftheactualnumbersisoftengiven. Thereareeventhresholdsforvariablesregardedastoxicthatarebasedon politicalorotherconsiderations,andtheyarethereforeonlylooselybasedon science(e.g.,pesticides).Theuseofsuchapproachesisacceptableaslongas thereasoningbehindthemiscleartoall.

Internationalguidelinesareusuallyintendedtoenablegovernmentstouse themasabasisforstandards,takingintoaccountlocalconditions.Theyare intendedtobeprotectiveofpublichealth,andtheyshouldbeabsolutelyclear, evendowntodetailedscientificconsiderationssuchasthederivationofuncertaintyfactorsandtheroundingofnumbers.Itisthereforeincumbentonthe expertgroupstojustifytheirthinkingandpresentitopenlyforalltosee.Such adisciplineavoidsthe“fudging”ofissueswhilegivingtheimpressionof scientificprecision,anditcanonlybeofvalueinincreasingpublicconfidence intheresultingguidelines.

Itisclearthat,atpresent,standardsforwaterqualityareasfollows:

l Looselybasedonscience(althoughthesituationisimproving);

l Notstatic(thescienceofmonitoringaswellasourunderstandingofthe healthimplicationsofchronicexposureofmanycontaminantsare improving);and

l Importantinthequalitycontrolofpotablewater(forbothsupplierand consumer).

Concerningtheoutflowwaterqualityofmostwetlandsystems,standards eitherareunclearorarecurrentlybeingdeveloped.Thelocalenvironment regulatorusuallysetsstandardsforspecificwetlandsystemapplications.

1.3BIOCHEMICALOXYGENDEMAND

Whenwastewater,includingurbanrunoff,isdischargedintoawatercourse,it exertsapollutingloadonthatwaterbody.Microorganismspresentinthe naturalwaterandthewastewaterbreakdown(stabilize)theorganicmatter.In permittingdischargestowatercourses,theEnvironmentAgencyintheUK,for example,triestoensurethattheconditionsareaerobicsothatallotherlife formsintheriver(e.g.,fish)cancontinuetosurvive.Theearlyformsof wastewatertreatmentdevelopedareaerobic,andsothesimplestwayof estimatingthebiodegradabilityofawastewatersampleistoestimatethe amountofoxygenrequiredtostabilizethewaste.

Todeviseaneasyandsimplemethodofassessingtheoxygendemand,the followingconstituentsofaclosedsystemshouldbeconsidered:

l Air(inexcess);

l Asmallnumberofbacteria;and

l Afiniteamountofsubstrate(wasterepresentingfood).

Thefollowingphasesofbiologicalgrowthanddeclinecanbeidentifiedin suchasystem:

l Lagphase:Bacteriaareacclimatizingtosystemconditions,inparticular thesubstrate;verylittleincreaseinnumbers.

l Loggrowth:Bacteriaareacclimatized;foodisnotalimitingfactor;rapidly increasingpopulationofbacteria.

l Declininggrowth:Foodeventuallybecomeslimiting;declininggrowth rates.

l Endogenousrespiration:Asthesubstrateconcentrationbecomesdepleted, competitionincreases;bacteriastartconsumingdeadbacterialcellsand eventuallystartconsuminglivecells.

Itisasystemofthistypethatisusedtoassesstheoxygendemandof wastes,includingorganicmatterfromurbanrunoff.Thetestdevelopedfrom thissystemisthebiochemicaloxygendemand(BOD)test.

TheBODtestiscarriedoutasfollows:aknownquantityofawastewater sample(suitablydilutedwithpreparedwater)isplacedina300-mlBOD bottle.Thepreparedwaterissaturatedwithdissolvedoxygen(DO),andnutrientsandabufferareadded.Thebottlesarethensealedairtight.Thebottles aresubsequentlyincubatedat20 Cinthedark(Clescerietal.,1998).

Initially,thebacteriabreakdownthecarbon-basedmolecules.Inpractice,a secondoxygendemandisobserved.Inthecaseofrawsewage,thisstage usuallybecomesapparentafterapproximately8daysofincubationat20 C.

Thissecondstageisduetotheoxidationofammoniapresentinthewaste;this iscallednitrification.Alargepercentageofthenitrogeninthewastewater originatesfromproteins;theproteinmoleculesaredegradedtorelease ammonia.Theoxidationprocessisdescribedin Eqs.(1.3.1)and(1.3.2):

Nitrificationconsumesasignificantamountofoxygensothatthetotal demandfornitrificationisoftencomparablewiththecarbonaceousdemand. Nitrificationalsogeneratesprotons(Hþ ions),whichincreasetheacidity(pH) ofthewaste.

Traditionally,theBODtestiscarriedoutfor5days;theresultingoxygen demandisreferredtoastheBOD5.TheBODiscalculatedasfollows (Eqs.(1.3.3)and(1.3.4)):

ðmg=lÞ¼ InitialDOinbottle

where:

Dilutionratio ¼ Volumeofwastewater VolumeofBODbottle

Inpractice,thetestisoftenmodifiedslightlyinthataquantityofseed microorganismsareaddedtotheBODbottletoovercometheinitiallag period.Inthisvariant,theBODiscalculatedfrom Eq.(1.3.5):

where:

D1 ¼ dissolvedoxygeninitiallyinseedandwastebottle;

D2 ¼ dissolvedoxygenattimeTinseedandwastebottle; B1 ¼ dissolvedoxygeninitiallyinseed-onlybottle; B2 ¼ dissolvedoxygenattimeTinseed-onlybottle; f ¼ ratioofseedvolumeinseededwastewatertoseedvolumeintheBOD testonseedonly;and DR ¼ dilutionratio.

Additionalbottlesareincubated.Thesecontainonlyseedmicroorganisms anddilutionwatertogettheBODoftheseed,whichisthenremovedfromthe BODobtainedforwasteandseed.

However,theBODtesthastwomajordisadvantages:ittakes5daysto obtainthestandardtestresult,andtheresultscanbeaffectedbytheprocessof nitrification(seeabove).Therefore,anitrificationinhibitorisoftenused (Chapter24).

2NH4
BOD
BOD ¼ ðD1 D2 Þ f ðB1 B2 Þ DR (1.3.5)

l Lime(burntCaO;slakedCa(OH)2);and

l Polyelectrolytes(long-chainorganicmoleculesnormallyusedinconjunctionwithaconventionalcoagulant).

Forthecoagulanttofunctionefficiently,itmustberapidlyanduniformly mixedthroughtherawwater.Thisusuallytakesplaceinahigh-shear(turbulent) environmentsuchasoneinducedbyahydraulicjump(low-costoption),a pump,ajetmixer,orapropellermixer.

Afterthecoagulantisuniformlydistributedinthewater,itrequirestimeto reactwiththecolloid,andthenfurthertime(andgentleagitation)topromote thegrowth(agglomeration)ofsettleablematerial(flocks).Thisisgenerally accomplishedeitherinatankwithpaddles(mechanicalmixing)orthrougha serpentinebaffledtank(hydraulicmixing).Onceflowsofasettleablesizehave formed,theyareremovedusuallybysedimentation(sometimesbyflotation).

IncountriessuchastheUKandIreland,developmentsinthe1940sledto theintroductionofthesludgeblanketclarifier(Chapter8).Thisisasingleunit thatencompassesrapidmixing,flocculation,andsettling.

Toremoveeithersolidscarriedoverfromsettlingtanksand/orany uncoagulatedmaterial(organicorinorganic),asandbedfilterisprovided.The waterflowsdownwardsthroughthebed,andtheimpuritiesareremovedby attachmenttothesandgrains.Thesandgrainsthereforerequireperiodic cleaning.Thefrequencyofcleaningdependsonthetypeoffilterused.The twocommonlyusedtypesarethefollowing(Chapters10and11):

l Slowsandfilter(slowloadingrate:approximatelyone-tenthofthatfora rapidgravitysandfilter)and

l Rapidgravitysandfilter(highloadingrate).

Sometimesfluorideisaddedtothewatertoreducetheincidenceofdental caries.Thisisaprocessthatprovokespublicdebate.IntheUnitedStatesand UK,chlorineisusuallyaddedtothewatertodisinfectit(Chapter19).It followsthatthewaterisbacteriologicallysafewhenitleavesthetreatment works,andexcesschlorineisaddedtoprotectthewaterfromcontamination duringthedistributionprocess.

Thereareseveralothercommonlyusedprocesses.Theirusagedependson thenatureoftherawwater.Aircanbeintroducedtothewatertooxidize impurities(e.g.,iron,manganese,orchemicalcompoundsaffectingthetasteof water).pHcontrolisacommonprocesssincemanyofthechemicaltreatment processesarepHdependent.Softeningreducesthehardnessand/oralkalinity ofwatertoimproveitsaestheticacceptability.Thisisacomplexchemical processdependingonthenatureofboththeanion ðHCO3 ; CO 2 3 ; orOH Þ andthecation(Ca2þ orMg2þ).

2.3BASICWATERCHEMISTRY

ThemostimportantchemicalvariablesofrawwaterareusuallytakenaspH andalkalinity.Alkalinityconsistsofthosechemicalspeciesthatcanneutralize

acid.Inotherwords,thesespeciesallowthewatertoresistchangesandprovide bufferingcapacity.Themajorconstituentsofalkalinityarethehydroxyl(OH ), carbonate ðCO 2 3 Þ,andbicarbonate ðHCO3 Þ ions.Therelativequantitiesof eachareafunctionofpH.

NosignificantconcentrationofhydroxylionsexistsbelowpH10,andno significantcarbonateconcentrationcanbedetectedbelowpH8.5.Formost waters,alkalinitythusconsistsofthebicarbonateion.Theotherspeciesmay beformedinthetreatmentprocess.Thebicarbonateandcarbonateionsinthe waterresultfromthedissolutionofcarbonaterocks.

ThepHisameasureofthefreehydrogenionconcentrationinwater. Water,andotherchemicalsinsolution,willionizetoagreaterorlesserdegree. Theionizationreactionisgivenin Eq.(2.3.1).

Inneutralsolutions,the[OH ]activityisequaltothe[Hþ]activity.Hence, thepHandpOH(ameasureofalkalinity)arebothequalandhavethe numericalvalueof7.Anincreaseinacidity,forexample,leadstohigher valuesof[Hþ],thusloweringthepH.

Thevariouschemicalreactionsthatoccurinnaturalwatersandinprocessed wateraregenerallyconsideredtooccurindilutesolutions.Thispermitstheuse ofsimplifiedequilibriumequationsinwhichmolarconcentrationsareconsideredtobeequaltochemicalactivities.

Theassumptionofdiluteconditionsisnotalwaysjustified,buttheerror introducedbythesimplificationisnogreaterthantheerrorthatmightbe introducedbycompetingreactionswithspeciesthatarenotnormallymeasured inwatertreatment.

Concentrationsofdifferentchemicalspeciesinwatermaybeexpressedin molesperliter,inequivalentsperliter,orinmassperunitvolume(typically, mg/l).Theequivalentofaspeciesisitsmolecularweightdividedbythenet valenceorbythenetchangeinvalenceinthecaseofoxidationandreduction reactions.

Thenumberofequivalentsperliter(normality)istheconcentration dividedbytheequivalentweight.Thenumberofmolesperliteriscalledthe molarity.

H2 O 5 Hþ þ OH
(2.3.1)

stages.However,innormalpractice,theworksareorganizedsuchthatallsludge iscollectedcentrally.

Wetlandsystemscanbedesignedforeachengineeringstageandforsludge treatment.However,constructedtreatmentwetlands(fordefinitions,referto Section20.2)areusuallyappliedforsecondaryortertiarytreatmentstages. Wetlandsintegratedinsustainabledrainagesystems(SuDS;previouslycalled sustainableurbandrainagesystems(SUDS))arefrequentlyusedforpreliminaryandprimarytreatmentpurposes.Urbanrunoffrequiresfulltreatment, whichisusuallynotthecaseinpractice,unlessforcombinedsewersystems andminorstorms.

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