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SugarcaneBiorefinery, Technologyand Perspectives

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SugarcaneBiorefinery, Technologyand Perspectives

Editedby

FERNANDOSANTOS

RioGrandedoSulStateUniversity, PortoAlegre,Brazil

SARITACÂNDIDARABELO

CollegeofAgriculturalSciences, SãoPauloStateUniversity(UNESP/BotucatuCampus), Botucatu,Brazil

MARIODEMATOS

SeniorAssociate,Schaffer/Africaglobal

PAULOEICHLER

PontificalCatholicUniversityofRioGrandedoSul, PortoAlegre,Brazil

AcademicPressisanimprintofElsevier

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1.Sugarcaneworldscenario1

MariodeMatos,FernandoSantosandPauloEichler

Introduction1

Historicalitineraryofsugarcane3

Historyofthemainproductsofsugarcane7

Worldscenarioofsugarcaneanditsmainproducts8

Socioeconomicandenvironmentalbenefitsofusingethanolfromsugarcane16 Perspectives17

References19

2.By-productsofthesugarcaneindustry21

FernandoSantos,PauloEichler,GrazielleMachado,JaquelineDeMattia andGuilhermeDeSouza

Introduction21

Sugarandethanolproductionprocess22

Bagasseandstraw26 Molasses29 Vinasse30 Filtercake31 Yeasts33

Otherby-productsofthesugarcanesector34

Chemicalpotentialofsugarcaneresidues36 Futureperspectivesforsugarcanebiorefinery42 References45 Furtherreading47

3.Sugarcane:biorefinery,technology,andperspectives49

SauloPhilipeSebastiãoGuerra,MarceloScantamburloDenadai, AndréLuizMerthanSaad,EmanuelRangelSpadimand MarciusXavierRodriguesdaCosta

Introduction49

Sugarcanestrawbalesashcontent53

Watercontentinsugarcanestrawbales58

References64 Furtherreading64

4.Sugarcane:foodproduction,energy,andenvironment67

EvaristoE.deMirandaandMarceloF.Fonseca

Introduction67

Sugarcane:themainagriculturalproductofBrazil68

Sugarcane:foodandenergyproduction70

SugarcaneinSãoPauloState75 Sugarcaneandtheenvironment79 Conclusion85 References86 Furtherreading87

5.Sustainabilityofsugarcaneforenergypurposes89

CarlaSilva,RuiPacheco,DaniloArcentalesandFernandoSantos Introduction89

Flex-fuelvehicletechnologiesandwell-to-wheels97 Conclusions100 Acknowledgments100 References100

6.Energycanebreeding103

GeraldoVeríssimodeSouzaBarbosa,JoãoMessiasdosSantos, CarlosAssisDiniz,DaniloEduardoCursiandHermannPauloHoffmann Introduction103 Sugarcane104 Energycane108 References115

7.Energyfromsugarcane117

LuísAugustoBarbosaCortez,RicardoBaldassin,Jr.andEduardodeAlmeida

Sugarcane:mainBrazilianenergycrop118

Residuesenergyfromsugar/ethanolmills122

Mainconversionroutesforsugarcanebioenergy130

Energycane:anopportunitytoimproveagriculturalproductivity135 Thefuturemarketsofsugarcanebioenergy135

Finalcomments136

References137

Furtherreading139

8.Chemicalandenergypotentialofsugarcane141

SaritaCândidaRabelo,LíviaBeatrizBrenellidePaiva,ThaynaraCoradiniPin, LuisaFernandaRiosPinto,LauraPlazasTovarand PedroYoritomoSouzaNakasu

Introduction141

Energypotentialofsugarcane:technologyplatformsofenergyproduction basedonenergyform142

Chemicalpotentialofsugarcane148

Conclusion159

References159

9.Sugarcaneforrenewablechemistry165

SílvioVazJr.

Introduction165

Sugarcaneasarawmaterialforrenewablechemistry168 Perspectivesforsugarcanebioproducts170 Challengesinvolved175 Conclusion176 References177

10.Useofsugarcanevinassetobiogas,bioenergy,andbiofertilizer production179

AndersonCarlosMarafon,KarinaRibeiroSalomon, EduardoLucenaCavalcanteAmorimandFernandaSantanaPeiter

SugarcanecropandbioethanolproductioninBrazil179

Characterizationandchemicalcompositionofsugarcanevinasse180 Alternativesfortheuseofsugarcanevinasse182 PerspectivesofthevinassesugarcaneuseinBrazil191 References193

Furtherreading194

11.Productionofsecond-generationethanolfromsugarcane195

FernandoSantos,PauloEichler,JoséHumbertodeQueirozand FernandoGomes

Structuralorganizationoflignocellulosicbiomass197

Recalcitranceoflignocellulosicbiomass200

Productionofsecond-generationethanolfromsugarcane202

Pretreatments204

Typesofpretreatments206

Hydrolysis212

Fermentation217

Inclusionofsecond-generationethanolproductionannextostandarddistillery221 References223

Furtherreading227

12.Biopolymersofsugarcane229

ThalitaMendonçadeResendeandMarceloMoreiradaCosta

Introduction229

Sugarcane231

Biopolymer232

Sugarcanebagasse233

Cellulose236

Perspectivesandchallengesfortheproductionofbiopolymerfromsugarcane249

References251

Furtherreading254

13.Bioelectricityofsugarcane:acasestudyfromBraziland perspectives255

ZilmarJosédeSouza

Introduction256 Whatisbioelectricity?256

Theelectricmatrixandpowerinstalledbybioelectricity257

SãoPaulo:responsiblefor44%ofbioelectricityin2018261

Productivityinthegenerationofsugarcanebioelectricity263

Onepointofattention:thedecontractingofbioelectricityinthecomingyears269

Thepotentialofbioelectricityyettoenjoy272

Expansionofbiomassisfarfromindicatedinthe10-yearplaninBrazil272

ThepotentialofbioelectricityandtheRenovaBio273

Anagendaforbioelectricity275 References278 Furtherreading279

281

Listofcontributors

EduardoLucenaCavalcanteAmorim

TechnologyCenter,FederalUniversityofAlagoas,Maceió,Alagoas

DaniloArcentales

DomLuizInstitute(IDL),FacultyofSciences,UniversityofLisbon,Lisbon,Portugal; FacultyofEngineeringinEarthSciences,HigherPolytechnicSchoolofCoastline (ESPOL),Guayaquil,Ecuador

LuísAugustoBarbosaCortez

InterdisciplinaryCenterforEnergyPlanning-NIPE,UniversityofCampinas-UNICAMP, Campinas,Brazil

DaniloEduardoCursi

SugarcaneBreedingProgram,RIDESA/UFSCar,Araras,Brazil

MarceloMoreiradaCosta

FederalUniversityofViçosa,Viçosa,Brazil

MarciusXavierRodriguesdaCosta

SãoPauloStateScientificPolice,SãoPaulo,Brazil

EduardodeAlmeida

SchoolofChemicalEngineering-FEQ,UniversityofCampinas-UNICAMP,Campinas, Brazil

MariodeMatos

SeniorAssociate,Schaffer/Africaglobal

JaquelineDeMattia

RioGrandedoSulStateUniversity,PortoAlegre,Brazil

EvaristoE.deMiranda

BrazilianAgriculturalResearchCorporation(Embrapa),Brasilia,Brazil

MarceloScantamburloDenadai

BotucatuCollegeofTechnology,Botucatu,Brazil

LíviaBeatrizBrenellidePaiva

InterdisciplinaryCenterofEnergyPlanning,UniversityofCampinas-UNICAMP, Campinas,Brazil

JoséHumbertodeQueiroz

DepartmentofBiochemistryandMolecularBiology,FederalUniversityofViçosa,Viçosa, Brazil

ThalitaMendonçadeResende

AdfertAdditivesIndustryandTrade,Uberlandia,Brazil

GuilhermeDeSouza

StateSecretariatofEnvironmentandInfrastructure,PortoAlegre,Brazil

ZilmarJosédeSouza

FGV,RiodeJaneiro,Brazil,SugarcaneIndustryUnion(UNICA),SãoPaulo,Brazil

GeraldoVeríssimodeSouzaBarbosa

FederalUniversityofAlagoas,Maceió,Brazil;SugarcaneBreedingProgram,RIDESA/ UFAL,Campinas,Brazil

CarlosAssisDiniz

SugarcaneBreedingProgram,RIDESA/UFAL,Campinas,Brazil

JoãoMessiasdosSantos

FederalUniversityofAlagoas,Maceió,Brazil;SugarcaneBreedingProgram,RIDESA/ UFAL,Campinas,Brazil

PauloEichler

PontificalCatholicUniversityofRioGrandedoSul,PortoAlegre,Brazil

MarceloF.Fonseca

BrazilianAgriculturalResearchCorporation(Embrapa),Brasilia,Brazil

FernandoGomes

FederalRuralUniversityofRiodeJaneiro,RiodeJaneiro,Brazil

SauloPhilipeSebastiãoGuerra

PaulistaStateUniversityJuliodeMesquitaFilho,SãoPaulo,Brazil

HermannPauloHoffmann

FederalUniversityofSãoCarlos,SãoCarlos,Brazil;SugarcaneBreedingProgram, RIDESA/UFSCar,Araras,Brazil

RicardoBaldassinJr.

AgronomicInstitute – IAC,Campinas,Brazil

GrazielleMachado

PontificalCatholicUniversityofRioGrandedoSul,PortoAlegre,Brazil

AndersonCarlosMarafon

EmbrapaCoastalBoards,RioLargoResearchandDevelopmentUnit,RioLargo,Brazil

PedroYoritomoSouzaNakasu

FacultyofChemicalEngineering,UniversityofCampinas-UNICAMP,Campinas,Brazil

RuiPacheco

InstituteofBioengineeringandBiosciences,HigherTechnicalInstitute,Universityof Lisbon,Lisbon,Portugal

FernandaSantanaPeiter

SãoCarlosSchoolofEngineering,UniversityofSãoPaulo,SãoCarlos,Brazil

ThaynaraCoradiniPin

FacultyofChemicalEngineering,UniversityofCampinas-UNICAMP,Campinas,Brazil

LuisaFernandaRiosPinto

FacultyofChemicalEngineering,UniversityofCampinas-UNICAMP,Campinas,Brazil

SaritaCândidaRabelo CollegeofAgriculturalSciences,SãoPauloStateUniversity(UNESP/BotucatuCampus), Botucatu,Brazil

AndréLuizMerthanSaad PaulistaStateUniversityJuliodeMesquitaFilho,SãoPaulo,Brazil

KarinaRibeiroSalomon TechnologyCenter,FederalUniversityofAlagoas,Maceió,Brazil

FernandoSantos

RioGrandedoSulStateUniversity,PortoAlegre,Brazil

CarlaSilva DomLuizInstitute(IDL),FacultyofSciences,UniversityofLisbon,Lisbon,Portugal

EmanuelRangelSpadim PaulistaUniversity,SãoPaulo,Brazil

LauraPlazasTovar InstituteofEnvironmental,ChemicalandPharmaceuticalSciences,Departmentof ChemicalEngineering,FederalUniversityofSãoPaulo(UNIFESP/DiademaCampus), Diadema,Brazil

SílvioVazJr.

BrazilianAgriculturalResearchCorporation – NationalResearchCenterforAgroenergy (EmbrapaAgroenergy),Brasilia,Brazil

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Preface

Theconceptofsustainability,muchsoughtinrecentyears,islinkedto thepartialandgradualreplacementofexhaustiblesourcesbyrenewable energysources.Thissustainabilitypathfitstheconceptofbiorefinery, whichaimstoconvertbiomassintobiofuelsaswellasbioenergyandbioproductsofcommercialinterest,inordertofindasolutionthatcombines economicviabilitywithenvironmentallyfriendlyproduction.

Inthecontextofthemostcultivatedagroenergybiomassintheworld, sugarcaneisoneofthemostecologicalandsustainable,beingfundamental fortheeconomy.Inaddition,itisimportantforthereductionofcarbon dioxideemissions,qualityoflifeinurbancenters,andglobalimprovementoftheenvironment.Thoughitsoriginisunknown,manybelieve thatsugarcanewasfirstcultivatedinNewGuinea,whereitwasconsideredawildandornamentalplant.

Sugarcaneconsistsofthestalk formedbyseveralculmsandmadeup offibers(cellulose,hemicelluloses,andlignin),sugars(sucrose,fructose, andglucose),andleaves composedofgreenleavesanddriedleaves/ sheaths,alsocalledstraw.Withregardtosugarcanemasscomposition,the threemaincomponents(straw,bagasse,andjuice)arepracticallyinthe sameproportionsandtogetherrepresent43%oftheplantmasscontent, andtheremaining57%arerepresentedbywater.Inenergyterms,the sameproportionalityisverifiedamongthesugarcaneconstituents,giving about7400MJofenergycontent.

Strawandbagassearemostlyusedforanumberofagronomicbenefits, forexample,weedcontrol,moistureretention,animalfeed,andimprovingphysical,chemical,andbiologicalpropertiesofsoil.However,dueto thesignificantamountthatisgenerated,itscompositionand,consequently,thechemicalandenergeticpotentialofthevegetablefiber,itis possibletousepartofthesematerialsinamorenobleuse,bothchemicallyandenergetically,withoutanydamagetoagronomicbenefits throughprocessesinvolvingthedifferentbiorefineryplatforms chemical route,biochemicalroute,andthermochemicalroute.

Thebiorefineryconceptisgainingmoreprominencewithgreat investmentpotentialandhasbeenidentifiedasoneofthemostpromising routesforthecreationofnewindustries.Thisvisionoftechnological developmentwillhavegreatrelevanceandimportanceregardingthe

evolutionoftheworldagriculturalandindustrialsectors,directlyreflectingonthegenerationofjobsandincomeindifferentsegmentsofsociety. Thinkingaboutthisoptimisticscenario,whichinvolvestheintegral andsustainableuseofsugarcanethroughthedifferentbiorefineryplatforms,wedecidedtopublishthebook SugarcaneBiorefinery, Technology, andPerspectives.Thebookisdividedinto13chaptersandispreparedby someoftheleadingauthoritiesoneachofthetopicsaddressed.Thework isanimportantcontributiontothedisseminationofknowledgeandthe consolidationofsugarcanebiorefineryintheworld.Thefutureofbiorefineryhasbegun!

Goodreading!

FernandoSantos

CHAPTER1

Sugarcaneworldscenario

MariodeMatos,FernandoSantosandPauloEichler

Contents

Introduction1

Historicalitineraryofsugarcane3

Historyofthemainproductsofsugarcane7

Worldscenarioofsugarcaneanditsmainproducts8

Approximatevaluesforthe2016/17harvest11

Approximatevaluesforthe2017/18harvest12

ThesugarandethanolsectorsinAfrica12

Thesugar,ethanol,andenergysectorsinBrazil14

Socioeconomicandenvironmentalbenefitsofusingethanolfromsugarcane16

Perspectives17

References19

Introduction

Sugarcane,nowknownworldwideforitshighproductivity,participation inhightechnologyprocesses,high-qualityrawmaterial,and,especially forthepotentialofsugarandethanolproduction,hasundergoneseveral modificationsthroughouthistory.Itisasemiperennialplantofthegrass family,originatingfromhottotropicaltemperateregionsofAsia,especiallyIndia.Itsmaincharacteristicistheproductionofsugars(mainly sucrose,glucose,andfructose),concentratingonitsculm.Theaerialpart oftheplantconsistsofstalk,greenleaves,anddryleaves.Theupperpart oftheplanthasahigherhumidityandthelowerparthasalowerhumidity,withdry(ordead)leaves(Fig.1.1).ThesugarcanepresentsaC4photosyntheticcycle,withleavesintheformofspears,sproutinginstalks, andabundanttilleringintheinitialphaseofdevelopment(Santosetal., 2013).Theplanthasapproximately57%ofwaterinitsmasscomposition, theremainderbeingdividedbetweenstraw,bagasse,andsugar.

Thisculturehasbeenshown,throughouthistory,asanimportant product,widelymarketed,andofgreatinterestduringseveralperiods

Figure1.1 Sugarcaneplantillustration. AlexanderAG(1985)Theenergycanealternative.Amsterdam:ElsevierSciencePublishersB.V.,509pp.

ofhistory.Sincesugarcanewasusedforsugarproductionitwas responsibleforthecreationofnewcommercialroutesintheold Mediterraneanuntilitsestablishm entintheAmericas,whenitisused forethanolproduction.

Inthischapter,weshowthehistoryofsugarcane,fromitsprobable origininSoutheastAsiatothepresentdaywheresugarcaneispresenton allcontinents;beingoneofthemostimportantcropsintheworld,generatinghundredsofthousandsofdirectandindirectjobs.Duetotheimportanceofitsmainproducts(sugar,ethanol,andenergy),sugarcanehas becomeacrucialsourceofincomeanddevelopmentforseveraltropical countrieslikeBrazil.Thusitisimportanttoshowthedevelopmentof thesecountrieswiththeuseofsugarcane,sothatispossibletoknowhow impactingitisforhumanity.

Historicalitineraryofsugarcane

Forafewyears,IndiaandPapuaNewGuineadisputedtheoriginofthis plantasanativeofthesecountries.Thefactthatsomeofthespontaneous speciesof Saccharumspontaneum and Saccharumrobostun stillbeingfoundin PapuaNewGuineaendedupgivingreasonforchoosingthiscountrythat isnowofficiallyconsideredtheirhomeland.Thedomesticationofthis specieswouldgive Saccharumbarberi widespreadinIndiaand Saccharum sinensis implantedinChinaaftermanyyears.ThusIndianswouldhave beenthefirsttoextractthesugarcanejuicetoproducerawsugararound 500BCE.Atthattime,EmperorDarius,uponarrivinginIndia,observed thattherewere “plantsthatproducedhoneywithouttheneedofbees” (Santosetal.,2018).

Thename Saccharum attributedtosugarcanehasitsoriginintheword ofTranskrit,KarkaraofIndiathatwaslatercalledSakkarorSukkarby theArabsafterhavingintroducedsugarcanefromIndiatotheMiddle EastthroughPersia.

Afewcenturieslater,afterbeingbroughtfromPersiatoEuropeby AlexandertheGreat,theRomanswouldcallitmuchlater Saccharum namewithwhichitwouldbeadoptedandlaterattributedbyLinnaeusin 1753foritsbotanicalclassificationthatlastsuntilourdays.

However,sugarcanehasbeenwidelycultivated,inadditiontoEgypt, inSpain(wherethereisstilltheoldestknownsugarcanemillinthe world)whichusesstonegrinders,andalsointroducedandcultivatedin otherpartsoftheMediterranean,suchasVenice,fromwhichlaterto transitinthe15thand6thcenturiesfortheMadeiraIslandsandthe CanaryIslands.Notoriously,fromtheCanaryIslandsitwasintroducedin theNewWorldtoHispaniolaIsland(DominicanRepublic)inCE1493 andtoBrazilinCE1532.

Inthemid-14thcentury,therearerecordsthattheproductionof sugarcaneintheMediterraneanregion(Crete,Greece,NorthAfrica, andCyprus)wasrelatedtotheuseofslavelabor.Liketheotheragriculturalproductivemeans,theeconomyoftheregionwasbased ontheslaveworkasproductiveforce.Atthistime,theregions aroundtheMediterraneanSeahadlargetradesandwereconsidered developedforthetime,influencingEuropeancountrieslikePortugal andItaly.Later,thesemethodsofproductionandmanagementof sugarcaneweretransferredtoBrazilinthecolonialperiod( Schwartz, 1988 ).

AfterthetakeoverofConstantinople,therewasamonopolyonthe productionandsaleofsugar.Toendthemonopoly,thePortuguese crowndecides,asanalternative,tostimulatetheproductionofsugarcane initscoloniesoftheAmericancontinent.Favorabletropicalclimate,fertilesoil,andabundanceofwaterpointedtoBrazilasalandoffavorable, evenideal,conditionsforthecultivationof Saccharumofficinarum,which originallycamefromtheSouthPacificandIndia(LeCouterand Burreson,2006).Brazilwouldthenaffirmatthebeginningastheplaceof preferenceforexcellenceofthisculturethatquicklyexpandedand becamethemainexportwealthofthe,then,PortugueseEmpire,constitutingamonopolythatwouldonlybecompetedwiththeDutchinthe 17thcenturyafteritsintroductionintheCaribbean. Fig.1.2 illustratesthe passageofsugarculturearoundtheworld,startingfromitsoriginsinNew Guinea,throughIndia,theMediterraneanuntilitsarrivalinBrazil, aroundCE1500.

InadditiontothestrongtradecompetitionintheMediterranean region,Portugalsawtheneedtoeffectivelyoccupythecoloniesofthe Americas,whichnecessarilyrequiredthedevelopmentofproductive activitiestojustifytheinvestmentsofthePortuguesecrown.Inthisway, sugarcaneproduction,asinmanyothercountries,hasbeenespecially rootedinthehistoryofBrazilianterritoryandinitseconomysincethe 16thcentury.SugarcanewasavaluablePortuguesesettlementthat

Figure1.2 Thepathofsugarcaneculture:fromitsbeginningtoitsarrivalin America.

enabledthemercantilistcolonizingprojectofPortugal.Unfortunately,in additiontothedevastationofforests,thecolonialsugareconomyalso reliedontheproductionmodeladoptedbytheEuropeansinthenew world.Thismodelwasbasedonthetripodlandowner,thatis,thelandscapesdominatedbysugarcaneplantationswerebasedonlargelandusage, monoculture,andslavelabor(Prado,2006).Inthisway,howevergood, thetradeinvolvedinsugarcaneanditsproductsbroughtsocialimpactsin Brazilthatarestillfelttoday.

InBrazil,sugarproductionwasestablishedbetweenCE1530and 1540,withtheformationofsmallmills,ofthe “trapiche ” type,moved byoxenandhorsesorhydraulicforce(Fig.1.3).Initially,astherewas notsufficientslavelabor,indigenousworkerswereused,whowerethe nativepopulation.Asthemillsgrew,therewasaneedtoincreasethe laborforce,withthetransitiontoslavelabor.Inthisway,thousandsof AfricansweretakentoBraziltoworkinthemills.Thefirstmerchants,

Figure1.3 HydropoweredmilldescribedbyJeanBaptisteonhisvoyageinIndia between1693and1706. Labat,J.B., 1742.Nouveauvoyageauxislesdel’Amerique. Paris.

membersofFernandodeNoronha’sgroup,duringtripsandstopson MadeiraIsland,Azores,andSãoTomé,negotiatedthefirstsugarcane plantcultivatedinBrazil.InordertoimplantthesugarcultureinBrazil, thelandwasdividedintolotsanddonatedtonobles,accordingtothe wishesofthePortuguesecrown.In1516thePortuguesemonarchD. ManuelI,the Venturoso,decreedthateveryonefromPortugaltoBrazil shouldbringinstructionandequipmentforlarge-scalesugarcaneproduction.Tothisend,largeamountsofmoneyweretradedonloansfrom PortugalandHollandtothelanddonorswhoweretoproducethecane (Novinskyetal.,2016 ).

CanegrowingsuccessivelypassedfromtheSpanishIslandtoCubain 1760assoonasthisislandisoccupiedbyEnglandwhereitalsoknowsa greatexpansionfavoredbythedemandofthesugaroftheAmericasin Europe.WiththerevolutioninHaitiin1795,afewyearslater,and destructionofcaneplantationsinSpanishterritories,theFrenchinstalled thecultureinLouisianainthelate17thcentury,thusinitiatingthe Americansugarindustry.

ThegrowthofsugarcanecultureintheNewWorldandinothercontinentshasalsoseendifferentadvancesintheareaofbreedingafterthe creationofthenoblevarietyPOJ2878inIndonesia,whichformany yearshasbeenthegeneticreferenceinthehybridizationcrossesofmany breedersfromdifferentresearchcentersandvarietalselectionfromseveral countries.Alsogoingthroughthecreationofmanyvarietiesofthe CoimbatoreResearchInstituteinIndiain1912.Theintroductionofnew varietiesfromtheCoimbatoreResearchInstitutealsocontributetothe growthofthesugarindustryworldwidenamelybyusingfuzzfrom CoimbatoretoselectedthewellknownNCovarietiesfromMount EdgecombeinSouthAfrica.

Themaincontributiontotheenormoussuccessofthegrowthand expansionofthisculturegoesmainlytothegeneticvalorizationand introductionofirrigationtechniques,whereinformationaboutthefirst Java productionsin1840from2000kgofcaneperhectareisincreasedto 10tonsin1910and20tonsin1940.

Also,intheearly20thcentury,withtheincreasedproductionofinternalcombustionvehicles,fuelethanolbegantobecomeextremelyinteresting.Asaresult,Brazil,whichalreadyhadlargesugarcaneproduction, createdincentivesfortheproductionofethanolfromthecrop,which helpedsolidifysugarcanecultivation.

Historyofthemainproductsofsugarcane

Bothsugarandcaneculturehaveaverysimilarhistory.Sugarcaneextractiontakesplaceapproximately8000BCEinSoutheastAsia. Approximately100 500BCEinIndia,amanufacturingprocessisdiscoveredthatdrivestheuseandcommercializationofsugar:thetransformationofsugarcanejuiceintosugarcrystals.Thusitispossibleto commercializetheproductovergreatdistances,becauseitimprovesits conservationandreducesthevolumeoftransportandalsothewayof transport.Withtheprogressofcommercialization,Chinaissoonalso interestedinthepracticeofsugarproduction,wherereports(betweenCE 600and700)describeChinesevisitstoIndiatolearntheprocessesof sugarproduction.Bythe7thcentury,itwasreportedthatoneoftheearliestdocumentedplantationsofsugarcaneinChina,broughtbythehelp ofBuddhistmonksinspecialmissionsofChineseemperors(Sen,2003).

ForsometimeintheMiddleEast,theuseofcanesugarformedicinal purposes(aroundthe1stcentury)wasalsoknown,betweenGreeksand Romans.WithincreasingconsumptionofsugarbyEuropeancountries viaMediterraneanroutes,theirpriceandimportanceincreased;leading countriessuchasCyprus,Crete,Zanzibar,andGreecetoalsohavesugarcaneproductiontoexportsugar,aroundthe10thcentury.Atthetimeof theCrusades,therewerealsoreportsfromthe “HolyLand” ofcaravans carryingwhatwascalled “sweetsalt.”

InBrazil,sugarwasthefirstproducttobeexportedinlargequantities. ItsgreatdemandbeginsinthecolonialperiodinCE1520,havinggreat importanceforthedevelopmentofthecountry.Duringthedecadesof 1530 40,theproductionofsugarwascharacterizedbysmallsugarmills (Fig.1.3).Atthebeginningofthefirstmills,themainproductwaswhat wenowcallbrownsugar,aless-refinedsugarthatwasthemainproduct ofsugarcaneatthetime.DespitebeingthelargestBrazilianeconomyin colonialtimes,thisindustryisnotexhaustedduringthisperiod,andits effectscanbeseenthroughoutthe17th,18th,19th,and20thcenturies, enteringthetropicalterritoryofthecontinentsofAmericaandAfrica.In themid-19thcentury,duetotheincreaseofsugarbeetintheinternationalmarket,thesugarcanecropsufferedafinancialcrisis.Inadditionto competition,sugarcanefarmingwasextremelydependentonslavelabor and,duetotheextinctionofAfricantrafficandtheemergenceofemancipationistlaws,attheendofthe19thcentury,themaincolonialcrops wereincrisis. Table1.1 showstheoccupationofslavesattheendofthe

Table1.1 OccupationofslavesinBrazilbetween1870and1887.

OccupationFrequencyPercentual

Craftsman223.9

Domestic264.7 Carriagedriver223.9

Nurse40.8 Foreman20.4

Worker81.4 Herdsman40.8

Seaworker101.8 Agriculture45982.3 Total557100

Source:AdaptedfromFilho,W.F., 2006.CrossroadsofFreedom(inPortuguese: EncruzilhadasdaLiberdade).UnicampPublishing,SãoPaulo,Brazil.

19thcenturyinBrazil.Itisnotedthatmorethan80%oftheslaveshad agricultureasoccupation,mainlytheplantationsofsugarcane.

Thefermentationofsugarforalcoholproductiondatesbackmorethan 9000years,bytheChinese,whousedthetechniquetomakealcoholic beverages.Thetechniqueoffermentationwaspassedovertheyears,being usedinseveraldrinksinhistoryasbeer,wine,and “sake.” Bythe9thcentury, anArabchemist,Al-Kindi,describedthedistillationofwine.From there,thedistillationisusedinseveralotherdrinks,withreportsfromthe 12thcenturyuntilthe14thcentury.Onlyinthelate18thcentury,a German-Russianchemist,JohannTobias,obtainedpureethanolfrom chemicalsynthesis.Inthefollowingyears,withadvancesinthechemical area,itbecamepossibletousealcoholonalargerscale,wherein1840in theUnitedStates,ethanolwasusedinlanterns.Then,intheearly1990s, ethanolwasusedinfuel-injectedengines,primarilyinearlyFordmodels suchastheFordModelT,whichcouldusebothgasolineandethanol. ThenBrazilwouldfollowthesameUSmodel,usingcarswithethanol combustionengines,wherethefuelwasproducedfromsugarcane. Alcoholdevelopmentandincentiveprograms,suchasthepro-alcohol programinBrazil,madepossiblethegreatgrowthinsugarcanecultivation,aswellasanincreaseinethanolproduction,makingthecountryone ofthelargestproducersofethanoltodate(Santosetal.,2018).

Worldscenarioofsugarcaneanditsmainproducts

Fromahistoricalappreciationofthepastofculture,wenowturntoa comparativeexerciseofworldsugarcaneproductionsinthefourth

Table1.2 Sugarcaneproduction,inthousandsoftonsofsugarcane(TS),harvested area,inhectares(Ha),andsugarcaneproductivity,intonsperhectare(TH),between 1961and2014forthefourlargestproducersintheworld. Year1961197420002014

(TS)Tonsofsugarcane( 3 103)

Brazil59,37795,6243,27,7057,36,109 India1,10,0011,40,8052,99,3253,52,142 China12,41625,57869,2991,26,153 Thailand200013,33954,0521,03,697 World4,47,9776,48,51612,558,8818,842,46 (Ha)Hectaresharvested

Brazil13,666,4020,566,9148,459,90104,196,78 India24,13,00027,52,10042,19,70050,12,000 China2,92,6005,96,80011,885,8917,683,88 Thailand63,0002,58,6098,93,35313,53,025 World89,118,7911,932,31319,397,90227,124,723

(TH)Tonsofsugarcaneperhectares

Brazil43.446.567.670.6 India45.651.170.970.2 China42.442.858.358.3

Thailand31.751.660.576.6

Source:AdaptedfromFAOSTAT,2019.FoodandAgricultureOrganizationoftheUnitedNations. FAOSTATStatisticsDatabase.FAO,Rome.

countriesresponsiblefor70%oftheworld’sproductions(Brazil,India, China,andThailand),whereBrazilaccountsforabout30%ofproduction (Table1.2 and Fig.1.4).Thesedatahavesimplyinformative,economical, andquantitativevalue,sincedifferentecologicalsystemsofproduction, cropwaterregimes,extensivism(LISA),intensivism(HISA),etc.,are compared.In Fig.1.5,itispossibletoobservetheworldproductionof sugarcanefromthe1960suntillastrecorded.Thesteadyincreaseinproductionisevident,assugarcaneproductsareincreasinglyinsertedintothe worldeconomy(Table1.3).

Thesefiguresindicatea21.3%globalconsumptionincreaseforecastin theindicateddecade(Fig.1.3).Ifweconsiderthat80%ofsugarisproduced fromsugarcane,wecansaythatifthisproportionremainslinear,therewill beaverifiedsurplusof36milliontonsofsugar.Thiscorrespondsto316 milliontonsofsugarcane,whichatanaverageof9tonsofsugarcaneper tonofsugarandanaverageproductionyieldof70t/haofsugarcane,

Figure1.4 Evolutionofworldproductionforthefourmajorsugarcane-producing countries,inthousandsoftonsofsugarcane,from1961to2014. Adaptedfrom FAOSTAT, 2019.FoodandAgricultureOrganizationoftheUnitedNations.FAOSTAT StatisticsDatabase.FAO,Rome.

Figure1.5 Worldsugarcaneproductionthroughtime. AdaptedfromFAOSTAT,2019. FoodandAgricultureOrganizationoftheUnitedNations.FAOSTATStatisticsDatabase. FAO,Rome.

willrepresentanincreaseof4.5millionhectaresaboveofthecurrentsugarcaneareainBrazil.Thisprovidesforaplantationof450,000haperyearto beplantedbetween2015and2025.With667,000haplantedbetween 2013/15and2017accordingtothesamestatistics,wewillhave3.5million hectarestobeplantedbetween2017and2025,withBrazilalready accountingformorethanathirdofworldsugarproduction.

Table1.3 Estimatesofsugarproductionincreases(inmillion tons)from2015to2025.

YearThousandtons%Increase 2015169 20161732.4 20171751.2 20181781.7 20191822.2 20201862.2 20211902.2 20221942.1 20231971.5 20242012.0 20252052.0

Source:AdaptedfromOECD/FAO, 2018.OECD-FAOAgriculturalOutlook 2018 2027.OECDPublishingParis/FAO,Rome.

Approximatevaluesforthe2016/17harvest

ThevolumeofthecropinBrazil(2016/17)wassignificantlylowerthan inthepreviousyear,althoughthepercentageofsugarcanedestinedfor sugarproductionwashigherinthisharvest 46.4%in2016/17compared to40%ofthepreviousharvest.

InIndia,sugarproductionreached12.9milliontonnesattheendof January2017,10%belowthepreviousharvest.

SugarproductioninChinainthe2016/17harvestwasestimatedtobe about9.9milliontonnes,or13.8%aboveproductionintheprevious year.

InThailand,the2016/17cropbegan11dayslaterthantheprevious year.OfficialThaistatisticsrevealedonFebruary8,2017,that46.82 milliontonneshadalreadybeenproduced,afiguresignificantlylowerthanthe 2015/16cropwhichatthesametimeannouncedaproductionof5.43million tonnes.Itisbelievedthatthisfallinproductionwasmainlyduetotheworst droughtinrecentyears,asseeninthepreviousyear.

Insub-SahelianAfrica,theestimationforthisharvestwas7.58million tons,representinganincreaseof223,000tonsdueinparticular:

• thepositiveprogressnotedinthisharvestintheGrandExpansionPlan ofEthiopiaand

• tothegradualimprovementofproductionverifiedinSouthernAfrica, wheretheclimatewasmorestableafter2yearsofdrought.

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