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Smart Materials in Additive

Table of Contents

Cover

Title page

Copyright

Dedication

Contributors

Editors biography

Preface

Acknowledgments

1: 4D printing principles and manufacturing

Abstract

Introduction

Series I: Smart materials and structure: 4D printing principles and manufacturing

References

2: 4D-printed dielectric elastomer soft robots: Modeling and fabrications

Abstract

Introduction

Configurations

Modeling

Fabrication

Conclusion

References

3: 4D-printed light-responsive structures

Abstract

Introduction

Design principles and activation mechanisms

Light-responsive materials used for 4D printing

4D-printed light-responsive behaviors and emerging applications

Conclusion

References

4: 4D-printed low-voltage electroactive polymers modeling and fabrication

Abstract

Introduction

Direct ink writing technology

Measurement of polymer sensors and actuators

4D-printed low-voltage electroactive polymers

Integrated polymer sensor and actuator via multi-material DIW

Conclusions

References

5: 4D-printed stimuli-responsive hydrogels modeling and fabrication

Abstract

Acknowledgments

Introduction

4D stimuli in hydrogels

Smart hydrogels design strategies

Fabrication techniques

Smart polymers for responsive hydrogels

Conclusions

References

6: 4D bioprinting: Fabrication approaches and biomedical applications

Abstract

Introduction

4D bioprinting

Current limitations and future perspectives of 4D bioprinting

Conclusions

References

7: 4D Microprinting

Abstract

Introduction to 4D printing at the microscale

4D microstructures based on stimuli-responsive hydrogels

Shape memory in 4D microprinting

Liquid crystalline 4D microstructures

Composite materials in 4D microprinting

Conclusion and outlook

References

8: 4D printing of gels and soft materials

Abstract

Introduction

Different types of soft materials in 4D printing

4D printing with hydrogel-based system

Applications of 4D printing based on soft materials

References

9: 4D printing of natural fiber composite

Abstract

Introduction

Natural fibers and their composites: A background

Hygromorph biocomposites (HBCs): Novel functionality for natural fiber biocomposite inspired from adaptive biological structure

4D printing of HBC

Conclusion

References

10: Functionalized 4D-printed sensor systems

Abstract

Additive fabrication technologies

Applications

Outlook for additive manufacturing

4D-printed sensor development

Conclusion

References

Further reading

11: Origami-inspired 4D printing

Abstract

Introduction

Materials and methods

Design concepts and fabrication techniques

Conclusion

References

12: Reversible 4D printing

Abstract

Introduction

Reversible shape memory polymers (SMPs)

Reversible 4D printing

Challenges and the future

References

13: Roadmapping 4D printing through disruptive ideas

Abstract

Introduction

A matter of definition

Where are we in 4D printing?

A survey to break the deadlock?

Toward a roadmap?

Conclusion

References

Further reading

Index

Copyright

Elsevier

Radarweg 29, PO Box 211, 1000 AE Amsterdam, Netherlands

The Boulevard, Langford Lane, Kidlington, Oxford OX5 1GB, United Kingdom

50 Hampshire Street, 5th Floor, Cambridge, MA 02139, United States

Copyright © 2022 Elsevier Inc. All rights reserved.

No part of this publication may be reproduced or transmied in any form or by any means, electronic or mechanical, including photocopying, recording, or any information storage and retrieval system, without permission in writing from the publisher. Details on how to seek permission, further information about the Publisher’s permissions policies and our arrangements with organizations such as the Copyright Clearance Center and the Copyright Licensing Agency, can be found at our website: www.elsevier.com/permissions.

This book and the individual contributions contained in it are protected under copyright by the Publisher (other than as may be noted herein).

Notices

Knowledge and best practice in this field are constantly changing. As new research and experience broaden our understanding, changes in research methods, professional practices, or medical treatment may become necessary.

Practitioners and researchers must always rely on their own experience and knowledge in evaluating and using any information, methods, compounds, or experiments described herein. In using such information or methods they should be mindful of their own safety and the safety of others, including parties for whom they have a professional responsibility.

To the fullest extent of the law, neither the Publisher nor the authors, contributors, or editors, assume any liability for any injury and/or damage to persons or property as a maer of products liability, negligence or otherwise, or from any use or operation of any methods, products, instructions, or ideas contained in the material herein.

ISBN: 978-0-12-824082-3

For information on all Elsevier publications visit our website at hps://www.elsevier.com/books-and-journals

Publisher: Mahew Deans

Acquisitions Editor: Dennis McGonagle

Editorial Project Manager: Rachel Pomery

Production Project Manager: Surya Narayanan Jayachandran

Cover Designer: Christian Bilbow

Typeset by STRAIVE, India

Dedication

This book is dedicated to my great parents, Mohammad and Kokab, who raised me with love, compassion, and a sense of appreciation for knowledge and innovation; and to my lovely wife for her patience, support, and adventurous spirit.

Mahdi Bodaghi

This book is dedicated to my parents and sisters for their consistent support, to my wife for her patience and company, and to my son, Alan, for motivating me to keep going.

Contributors

Kumkum Ahmed College of Engineering, Shibaura Institute of Technology, Tokyo, Japan

Mohammad Alshawabkeh FH Kärnten Campus Villach, Villach, Austria

Jia An Singapore Centre for 3D Printing, School of Mechanical and Aerospace Engineering, Nanyang Technological University, Jurong West, Singapore

Jean-Claude André LRGP 7274 UMR CNRS, University of Lorraine, Nancy, France

Mohsen Askari

Department of Engineering, School of Science and Technology, Noingham Trent University, Noingham, United Kingdom

Department of Textile Engineering, School of Material Engineering & Advanced Processes, Amirkabir University of Technology, Tehran, Iran

Changsheng Bian Shaanxi Key Laboratory of Intelligent Robots, School of Mechanical Engineering, Xi’an Jiaotong University, Xi’an, Shaanxi, P.R. China

Eva Blasco Organisch-Chemisches Institut, Ruprecht-KarlsUniversität Heidelberg, Heidelberg, Germany

Mahdi Bodaghi Department of Engineering, School of Science and Technology, Noingham Trent University, Noingham, United Kingdom

Chee Kai Chua Engineering Product Development Pillar, Singapore University of Technology and Design, Tampines, Singapore

David Correa School of Architecture, University of Waterloo, Cambridge, ON, Canada

Frédéric Demoly ICB UMR 6303 CNRS, Université Bourgogne Franche-Comté, UTBM, Belfort, France

Lisa-Marie Faller ADMiRE Lab-Additive Manufacturing, Intelligent Robotics, Sensors and Engineering, School of Engineering and IT, Carinthia University of Applied Sciences, Villach, Austria

Rui Guo State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, People’s Republic of China

Khan Rajib Hossain State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, People’s Republic of China

Li-Yun Hsu Organisch-Chemisches Institut, Ruprecht-KarlsUniversität Heidelberg, Heidelberg, Germany

Wei Min Huang School of Mechanical and Aerospace Engineering, Nanyang Technological University, Jurong West, Singapore

Zhongying Ji State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, People’s Republic of China

Pan Jiang State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, People’s Republic of China

Daewon Kim Embry-Riddle Aeronautical University, Aerospace Engineering, Daytona Beach, FL, United States

Antoine Le Duigou Univ. Bretagne Sud, UMR CNRS 6027, IRDL, Lorient, France

Amelia Yilin Lee

Engineering Product Development Pillar, Singapore University of Technology and Design, Tampines

HP-NTU Digital Manufacturing Corporate Lab, School of Mechanical and Aerospace Engineering, Nanyang Technological University, Jurong West, Singapore

Bin Luo

Shaanxi Key Laboratory of Intelligent Robots, School of Mechanical Engineering, Xi’an Jiaotong University, Xi’an, Shaanxi School of Mechanical and Electrical Engineering, Hohai University, Changzhou Campus, Changzhou, Jiangsu, P.R. China

Mehrshad Mehrpouya Faculty of Engineering Technology, University of Twente, Enschede, The Netherlands

Moqaddaseh Afzali Naniz

Department of Engineering, School of Science and Technology, Noingham Trent University, Noingham, United Kingdom

Department of Textile Engineering, School of Material Engineering & Advanced Processes, Amirkabir University of Technology, Tehran, Iran

Ana P. Piedade University of Coimbra, CEMMPRE, Department of Mechanical Engineering, Coimbra, Portugal

Ana C. Pinho University of Coimbra, CEMMPRE, Department of Mechanical Engineering, Coimbra, Portugal

MD Nahin Islam Shiblee Department of Mechanical Systems Engineering, Graduate School of Science and Engineering, Yamagata University, Yamagata, Japan

Stanislav Sikulskyi Embry-Riddle Aeronautical University, Aerospace Engineering, Daytona Beach, FL, United States

Christoph Alexander Spiegel Organisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Heidelberg, Germany

Xiaolong Wang

State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of

Sciences, Lanzhou, People’s Republic of China

Xuejie Xu Shaanxi Key Laboratory of Intelligent Robots, School of Mechanical Engineering, Xi’an Jiaotong University, Xi’an, Shaanxi, P.R. China

Yi Zhang

Singapore Centre for 3D Printing, School of Mechanical and Aerospace Engineering, Nanyang Technological University, Jurong West, Singapore

School of Electronic Science and Engineering, University of Electronic Science and Technology of China, Chengdu, Sichuan, China

Zicai Zhu Shaanxi Key Laboratory of Intelligent Robots, School of Mechanical Engineering, Xi’an Jiaotong University, Xi’an, Shaanxi, P.R. China

Ali Zolfagharian School of Engineering, Deakin University, Geelong, VIC, Australia

Editors biography

Dr.Mahdi Bodaghi, BSc, MSc, PhD, PGCAP, FHEA, CEng, MIMechE, is Senior Lecturer in the Department of Engineering, School of Science and Technology at Noingham Trent University. Mahdi heads the 4D Materials and Printing Laboratory (4DMPL) that hosts a broad portfolio of projects focusing on the electrothermo-mechanical multiscale behaviors of smart materials, soft robots, and 3D/4D printing technologies. In the recent 12 years, he has been working toward the advancement of state-of-the-art smart materials and additive manufacturing, which has led him to cofound the 4D Printing Society and to coedit the Smart Materials in Additive Manufacturing book series. His research has led to the publication of more than 120 scientific papers in prestigious journals on mechanics, manufacturing, and materials science as well as the presentation of his work at major international conferences. Mahdi has also served as Chairman and Member of Scientific Commiees for 10 International Conferences, as Guest Editor for 10 journals, as Editorial Board Member for 8 scientific journals, and as Reviewer for more than 130 journals. Mahdi’s research awards include the Best Doctoral Thesis Award (2015), the CUHK Postdoctoral Fellowship (2016), the Annual Best Paper Award in Mechanics and Material Systems presented by the American Society of Mechanical Engineers (2017), Horizon Postdoctoral Fellowship Award (2018), and the IJPEM-GT Contribution Award (2021) recognized by the Korea Society for Precision Engineering.

Dr. Ali Zolfagharian, BSc, MSc, PhD, ADPRF, GCHE, is Senior Lecturer in the Faculty of Science, Engineering and Built Environment, School of Engineering at Deakin University, Australia. He has been among the 2% top-cited scientists listed by Stanford University and Elsevier (2020), the Alfred Deakin Medallist for Best Doctoral Thesis (2019), and the Alfred Deakin Postdoctoral Fellowship Awardee (2018). He has been directing the 4D Printing and Robotic Materials laboratory at Deakin University since 2018. Ali is the cofounder of the 4D Printing Society, the coeditor of the Smart

Materials in Additive Manufacturing book series published by Elsevier, and a technical commiee member of five international conferences. From 2020 to 2022, he has received more than AUD 200k research funds from academic and industrial firms. Ali’s research outputs on flexible manipulators, soft grippers, robotic materials 3D/4D printing, and bioprinting include 71 articles, being editor of 2 journals, 15 special issues, and 5 books.

Preface

We thank you for choosing this book series that is intended to create an intellectual niche for smart materials in the additive manufacturing community. This book, the first in the series, demonstrates the principles that frontline academics and engineers have developed for four-dimensional (4D) printing in a manner that will be useful for students and early career researchers in the field at a higher education level.

During the past few years, significant progress has been made in 4D printing by researchers in top institutions and laboratories worldwide, combining advances in 3D printing of dynamic structures with stimuli-responsive materials, known as smart materials, to create additively manufactured smart structures. However, 4D printing technology is only in the early stages of research and development, so industries will probably learn more about it in the coming years. With the Fourth Industrial Revolution well underway, industries that take advantage of its unprecedented possibilities will undoubtedly have an economic advantage. With this knowledge, institutions, researchers, and students investing in 4D printing technology are the ones with radical potential.

Additive manufacturing technology through layered building of materials, also known as 3D printing, was developed in the late 1970s and early 1980s by different scientists and engineers around the world. Since then, the basic process and technology have evolved from the typical 3D printing processes to develop objects and structures mainly using functional materials in diverse applications

benefiting from their robust mechanical and geometric properties. In 2013, the term “4D printing” was introduced, in which the fourth dimension refers to time-related changes in the shape, properties, color, or functions of 3D-printed smart materials in response to external stimuli. In other words, 4D printing is defined as the 3D printing of smart materials to work as dynamic structures and mechanisms as opposed to merely static but functional constructs conventionally made via 3D printing.

A series of books on smart materials in additive manufacturing has been announced to beer serve the purpose. This book, the first in the series, provides readers with a quick overview of the current smart materials and techniques to process them via 4D printing. Different types of smart materials, including shape memory polymers (SMPs), hydrogels, shape memory alloys (SMAs), biomaterials, natural fibers, dielectric elastomers (DEs), liquid crystal elastomers (LCEs), electroactive polymers (EAPs), soft materials, and their composites, used in 4D printing based on their response to stimuli, fabrication, multiphysics modeling, control techniques, and applications, are discussed. After reading the chapters in this book, readers will hopefully learn the basics of current smart materials used in 4D printing and their processing strategies. Smart Materials in Additive Manufacturing, Volume 1 is suitable for new researchers, scientists, industrial designers, and students entering the field to further familiarize themselves with the concepts and principles of 4D printing technology.

This book is the result of years of collective research by experts in 4D printing and additive manufacturing of smart materials and structures. The editors and authors hope you will benefit from the time and effort it took to put it together and believe it was a worthwhile endeavor. Editing this book has led to the formation of a bigger network of experts in 4D printing, with whom we have initiated collaborations to further advance the field.

Acknowledgments

The coeditors express their sincere gratitude and deep appreciation to all the authors for their significant and excellent contributions to this book. Their enthusiasm, commitment, and technical expertise have made this pioneering book possible. We are also grateful to Elsevier for supporting this book project, and we extend our special thanks to the Editorial Team, Dennis, Mariana, and Surya, for their proactive support and cooperative aitude, with both the publishing initiative in general and the editorial aspects.

1: 4D printing principles and manufacturing

b a Department of Engineering, School of Science and Technology, Nottingham Trent University, Nottingham, United Kingdom b School of Engineering, Deakin University, Geelong, VIC, Australia

Abstract

Four-dimensional (4D)-printed smart materials and structures are engineered, complex-shaped mechanisms that behave by sensing external stimuli and responding by adapting to their environment, without any need for computerized control systems. These revolutionary products are no longer relegated to the realm of science fiction and have implications for 4D printing (4DP). This chapter overviews the first book in series, “Smart Materials and Structures: 4D Printing Principles and Manufacturing” and provides a preliminary information on 4Dprinted smart materials and structures as well as their significance.

Keywords

4D printing; 3D printing; Theories; Principles; Additive manufacturing; Smart materials

Introduction

Four-dimensional (4D) printing was initially demonstrated at the Technology, Entertainment, and Design (TED) conference (Tibbits, 2013) and in a journal article (Ge, Qi, & Dunn, 2013) in 2013. It is a combination of three-dimensional (3D) printing, stimuli-responsive smart materials, design, and a modeling-based programming technology, which results in the evolution in shape, properties, color, and functionality of a 3D-printed structure over time (referred to as fourth dimension “D”) when it is exposed to stimuli, such as heat, light, humidity, magnetic fields, stress, and pH. A 4D-printed object produced using smart materials reacts and dynamically changes its form and size as planned when meeting external stimuli over time (Fig. 1.1).

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