Optical thin films and coatings 2e : from materials to applications. 2nd ed. edition flory - Own the

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FromMaterialstoApplications

SecondEdition

AngelaPiegari
Franc ¸ oisFlory

PARTIDESIGNANDMANUFACTURINGOFOPTICAL

1.1

1.2

1.3

2.2.1FourierTransformMethod.................................................27

2.2.2InhomogeneousRefinement...............................................30

2.2.3NeedleMethod...................................................................32

2.2.4GlobalOptimization...........................................................34

2.3 ManufacturabilityIssues...............................................................37

4.6

PARTIIUNCONVENTIONALFEATURESOFOPTICALTHIN FILMSANDCOATINGS

CHAPTER5Complexmaterialswithsubwavelengthinclusions foropticalthinfilmapplications 143 AnnaSytchkova

5.1 Introduction.................................................................................143

5.2 PhysicsofSomeClassesofNovelMaterialswith SubwavelengthInclusions..........................................................145

5.3 CeramicMatrixWithEmbeddedNanostructures......................147

5.3.1MaterialsWithQuantumDots.........................................148

5.3.2NanoclustersinPeriodicArrays(Metamaterials)............149

5.3.3EffectofSmallRandomDisordersandImperfections inMetamaterials...............................................................154

5.3.4CompositesofRandomElements....................................154

5.3.5CoatingsContainingThinandUltrathinMetalLayers andCoatingsContainingMetasurfaces............................155

5.4 SearchingforAlternativeMaterialsforResonating Inclusions....................................................................................156

5.4.1AlloysandIntermetallics:NovelMetalMaterials..........157

5.4.2SemiconductorsandDielectrics.......................................160

5.5 CharacterizationofNovelMaterialswithSubwavelength Inclusions....................................................................................162

5.5.1OpticalCharacterizationTechniquesforComplex Materials...........................................................................163

5.5.2LocalPropertiesofNanostructuredMaterials.................165

5.5.3EffectiveMacroscopicParameters...................................166

5.5.4ComplexMaterialsandUltrathinMetalsinMultilayers.168

5.6 Conclusions.................................................................................172 References...................................................................................173

CHAPTER6Scatteringpropertiesofrandomstructures inthinfilms 187

6.1 Introduction.................................................................................187

6.2 NumericalSolutionofReducedRayleighEquations forScatteringofLightFromDielectricFilmsWith1D RoughSurfaces...........................................................................189

6.2.1AFilmWitha1DRandomlyRoughVacuum-Dielectric InterfaceDepositedonthePlanarSurfaceofaPerfect Conductor..........................................................................190

8.4.3CoatingsforControlofRadiativeExchangeWiththe Atmosphere.......................................................................377 8.5 Conclusion..................................................................................384

9.2.1IsaacNewton(1642–1727)...............................................390

9.2.2ThomasYoung(1773–1829)............................................392

9.2.3LeopoldoNobili(1784–1835)..........................................393

9.2.4DavidBrewster(1781–1868)...........................................394

9.2.5AugusteMichel-Levy(1844–1911).................................394

9.2.6J.F.GabrielLippmann(1845–1921)................................398

9.2.7SoapBubbles....................................................................398

9.2.8LensOpticalCoatings......................................................398

9.2.9ThinFilmAnticounterfeitingCoatings............................399

9.3 OverviewofBasicColorimetry.................................................399

9.3.1PsychophysicalColorimetryofColorStimuli.................400

9.3.2PsychophysicalColorimetryofLightSources andNonself-LuminousSurfaces......................................406

9.3.3PsychometricColorimetry................................................408 9.4 OpticalCoatingColorimetry......................................................410

9.4.1Gonio-ApparentColorMeasurement...............................411

9.4.2OpticalCoatingColor......................................................413 9.5 Conclusion..................................................................................419

PARTIIINOVELMATERIALSFOROPTICALTHIN

13.6 SourcesofFurtherInformationandAdvice..............................533 References...................................................................................533 FurtherReading..........................................................................537

CHAPTER14Protectivecoatingsfordurabilityenhancement ofopticalsurfaces .................................................... 539

TjhayW.Boentoro,BerndSzyszka,LudvikMartinu

14.1 Introduction.................................................................................539

14.2 Plasma-andIon-BasedDepositionofFunctionalCoatings......540

14.3 TestingMethods.........................................................................544

14.3.1TaberAbraserTestofAbrasionResistance..................545

14.3.2SandTricklingTest........................................................546

14.3.3ScratchTest....................................................................546

14.3.4CrackOnsetStrain..........................................................547

14.3.5AdhesionTests................................................................547

14.3.6WeatheringTest..............................................................549

14.3.7CharacterizationoftheOpticalProperties.....................550

14.3.8Haze................................................................................551

14.4 CoatingConcepts........................................................................551

14.4.1CoatingSystemsonGlassSubstrate..............................552

14.4.2CoatingSystemonPolycarbonateSubstrate.................552

14.4.3NumericalSimulation.....................................................553

14.4.4MultifunctionalCoatings................................................553

14.5 ExamplesofProtectiveCoatingApplications...........................556

14.5.1Low-ECoatingsonWindshield.....................................556

14.5.2PolycarbonateinAutomotiveGlazing...........................557

14.6 Conclusion..................................................................................559 References...................................................................................561

CHAPTER15Opticalcoatingsfordisplaysandlighting ............... 565 Cheng-ChungLee,Chien-ChengKuo

15.1 Introduction.................................................................................565

15.2 OpticalCoatingsforFlatPanelDisplay(FPD).........................566

15.3 OpticalCoatingsforProjectors..................................................568

15.4 OpticalCoatingsforProjectorsUsingLight-EmittingDiode(LED) LightSource................................................................................571

15.5 OpticalCoatingforAutomobilesHeadUpDisplay(HUD).....583

15.6 OpticalCoatingsforLEDs.........................................................586

15.7 Conclusion..................................................................................589 Acknowledgments......................................................................591 References...................................................................................591 FurtherReading..........................................................................594

CHAPTER16Innovativeapproachesinthin-filmphotovoltaic cells .......................................................................... 595 NicolasBarreau,DavidDuche,CarmenM.Ruiz, LudovicEscoubas,Jean-JacquesSimon,JudikaelLeRouzo, VeronicaBermudez

16.1 Introduction.................................................................................595

16.2 InorganicNanostructuresforPhotovoltaicSolarCells.............599

16.2.1NewConceptsofSolarCells.........................................599

16.2.2LightTrappingandPhoto-CarrierCollection................600

16.2.3QuantumDotsandNanowiresIncludedinThin-Film SolarCells.......................................................................601

16.3 OrganicThin-FilmSolarCells...................................................604

16.3.1WorkingPrinciplesofanOrganicSolarCell................605

16.3.2LightTrappingStrategiesforOrganicSolar Cells(OSCS)...................................................................608

16.4 ChalcogenideMaterialsinThin-FilmSolarCells.....................611

16.4.1TheSubstrates.................................................................612

16.4.2TheDeviceStackforCells............................................613

16.4.3State-of-the-ArtTechnologiesatIndustryLevel...........617

16.4.4NovelChalcogenideAbsorbers......................................617

16.4.5Vacuum-FreeDeposition................................................618

OrganometallicPerovskite-BasedSolarCells...........................618

17.2 BasicPrinciplesandStructuresCurrentlyApplied...................634

17.2.1All-DielectricFilters.......................................................636

17.2.2Metal-DielectricFilters..................................................638

17.2.3OpticallyVariablePigments..........................................643

17.3 SpecificOpticalEffectsSuitableforSecurityDevices.............644

17.3.1Metamerism....................................................................644

17.3.2MagneticFilms...............................................................648

17.3.3CombiningInterferenceandDiffraction........................649

17.3.4OtherColorShiftingTechnologies................................651

17.4 ActiveDevices............................................................................652

17.4.1ApplicationofActiveMaterials.....................................652

17.4.2ElectrochromicDevices..................................................654

17.5 FilmFunctionalityandStructurallyControlledOptical Coatings......................................................................................656

17.6 Conclusion..................................................................................658 References...................................................................................659

CHAPTER18Opticalcoatingsforhigh-intensityfemtosecond lasers ........................................................................ 667 VolodymyrPervak

18.1 IntroductiontotheFieldofUltrafastOptics.............................667

18.2 MirrorDesignApproaches.........................................................669

18.2.1DispersiveMirrors..........................................................669

18.2.2ResonantStructureorGires-TournoisInterferometer Mirror..............................................................................670

18.2.3Double-ChirpedMirrors.................................................671

18.2.4Brewster-AngleCM........................................................672

18.2.5Back-Side-CoatedCM....................................................673

18.2.6Tilted-Front-InterfaceCM..............................................673

18.2.7ComplementaryPairsofCMs........................................674

18.2.8TheTime-DomainDM...................................................676

18.2.9Double-AngleDM..........................................................677

18.2.10PulseCompressionandAnalysis.................................677

18.3 TheHighestPossibleValueofGDD.........................................678

18.4 ProductionofDM.......................................................................679

18.5 PulseCompressionWithDM.....................................................680

18.6 MeasurementofGroupDelayWithWhiteLight Interferometer.............................................................................684

18.7 ApplicationofDMintheHigh-IntensityLasers.......................687

18.8 Conclusions.................................................................................691 References...................................................................................691

CHAPTER19Opticalcoatingsforlargefacilities

697 CatherineGre ` zes-Besset,GregoryChauveau,LaurentPinard

19.1 Introduction.................................................................................697

19.2 DomainsofApplicationsandMajorPrograms.........................697

19.2.1ScientificLargeInstruments..........................................698

19.2.2Laser................................................................................699

19.2.3Space...............................................................................701

19.2.4Astronomy.......................................................................702

19.2.5SolarPlants.....................................................................702

19.3 ReviewofTechnologicalSolutions...........................................703

19.3.1ThermalandElectronGunEvaporation........................703

19.3.2Sputtering........................................................................704

Contributors

TatianaV.Amotchkina

Ludwig-Maximilians-UniversitatMunchen,Garching,Germany

BillBaloukas

DepartmentofEngineeringPhysics,PolytechniqueMontreal,Montreal,QC, Canada

NicolasBarreau

NantesUniversity,CNRS,InstitutdesMateriauxJeanRouxel(IMN),(UMR6502), Nantes,France

GerardBerginc

Thales,LaDefense,France

VeronicaBermudez

Nexcis,Rousset,France

TjhayW.Boentoro

FraunhoferInstituteforSurfaceEngineeringandThinFilms—IST,Braunschweig, Germany

ClarkI.Bright

BrightThinFilmSolutionsLLC,Tucson,AZ,UnitedStates

GregoryChauveau

CILAS,Aubagne,France

Yu-JenChen

NationalCentralUniversity,Taoyuan,Taiwan

DavidDuche

Aix-MarseilleUniversity,UniversityToulon,CNRS,IM2NP,Marseille,France

HenrikEhlers

LaserZentrumHannover,Hannover,Germany

LudovicEscoubas

Aix-MarseilleUniversity,UniversityToulon,CNRS,IM2NP,Marseille,France

MuhammadFaryad

DepartmentofEngineeringScienceandMechanics,ThePennsylvaniaState University,UniversityPark,PA,UnitedStates

Franc ¸ oisFlory

EcoleCentraleMarseille,Marseille,France

CatherineGre ` zes-Besset

CILAS,Aubagne,France

thanthirtyyears.Severalchaptersareauthoredbyexpertswhotookpartintheearly developmentsinthespecificsectors,andpublishedmanyfundamentalworks.

Wehopethebookwillbeusefulforscientistsandtechnicalpeople,providingan overviewofthekeyroleofopticalcoatingsindifferentfieldsandstimulatingthe reader’sinteresttogodeeperineachtopic,takingadvantageofthebibliographic materialinallchapters.

Thepotentialreadersofthisbookmaybephysicists,chemistsandengineers, includingseniorstudents,interestedinbothresearchdevelopmentsandpractical applications.Newcomerstothefieldofopticalthinfilmsandcoatingscouldbe attractedbytheextremelywiderangeofapplications,whilespecialistsofaparticular fieldcouldfindinformationonthenewtrendsintheirareaofinterest.

Wewishtothankallauthorsfortheirvaluablecontributionsandeffortsandwe arealsogratefultothePublishersfortheirassistanceduringthepreparationof thebook.

Rome,Italy

Franc ¸oisFlory Marseille,France

March2013

AngelaPiegari

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