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Moran’sDictionaryofChemical

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SeanMoran

Elsevier

Radarweg29,POBox211,1000AEAmsterdam,Netherlands

TheBoulevard,LangfordLane,Kidlington,OxfordOX51GB,UnitedKingdom

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ThisbookandtheindividualcontributionscontainedinitareprotectedundercopyrightbythePublisher(otherthanas maybenotedherein).

Notices

Knowledgeandbestpracticeinthisfieldareconstantlychanging.Asnewresearchandexperiencebroadenour understanding,changesinresearchmethods,professionalpractices,ormedicaltreatmentmaybecomenecessary.

Practitionersandresearchersmustalwaysrelyontheirownexperienceandknowledgeinevaluatingandusingany information,methods,compounds,orexperimentsdescribedherein.Inusingsuchinformationormethodstheyshould bemindfuloftheirownsafetyandthesafetyofothers,includingpartiesforwhomtheyhaveaprofessional responsibility.

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Preface

Theauthorofanynonfictionworkshouldinmyviewhaveacleardefinitionof theintendedscopeofthatwork,andtheirtitleshouldmatchthatscope,otherwisetheyarejustsettingthereaderupfordisappointment.So,thisis Moran’s DictionaryofChemicalEngineeringPractice,alexiconofmyprofession,Chemical Engineering,inwhichIdefinethemeaningofthetermsusedprofessionallyby myfellowpractitionersofthedesignandoperationofprocessplants.

However,itisnotreallyjust“Moran’sDictionary.”Thatwouldnotbemuch use,asIalreadyknowwhat I mean!Thepurposeofthebookistohelpchemicalengineerstocommunicateunambiguouslywitheachother,andwithmembersoftheotherprofessionsandtradeswithwhomweinteractinprofessional life.Bothmyfellowchemicalengineersandthoseothersusethesamewordsto meandifferentthingsanddifferentwordstomeanthesamethings.So,when writingthisbook,IhavefollowedtheapproachIhavedevelopedinwritingmy previousbooks,seekingandconsideringthecontributionsofhundredsof chemicalengineersworldwideonthecontent,toensurethatitrepresentsa complete,currentconsensusview.

Evenwithinengineering,therearetermswhicharecommonlyusedinerror,or easilyconfused.Thiscanhappenforanumberofreasons,includingthepresence ofsub-sub-languages,usagedifferencesbetweenindustrysectors,anddifferences betweenthejargonofchemicalengineeringandthatoftheotherprofessionsand tradeswhichweworkwith.Thereforethis dictionaryalsocontainssometerms frommoregeneralengineering,management,quality,etc.Practicedoesnotexist inavacuum:engineeringisamultidisciplinaryeffort.

Let’salsobeclearonwhatthisdictionaryis not.

Firstly,thisisnotanencyclopedia(asetofshortarticlesonawiderangeofsubjects,summarizingfactualknowledge).Therearenoarticles,historiesorbiographiesinthisdictionary,thoughthereareafewshortdiscussionsofselected termswhichmeritedamorediscursiveapproach.

Thisisatechnicaldictionary,ratherthanageneraldictionarysuchastheOED. Asatechnicaldictionary,thisbookdoesnotdefine“words”assuch.Theelementsoftechnicalvocabularyare‘terms’,ortoputitanotherway,theelements ofasub-languageorjargon—theshorthandusedwithinagroup.Technical termsmay,confusingly,meandifferentthingsfromtheeverydaywordsthey resemble.

Thisisnotadictionaryofscience.Itisadictionaryofengineering,andengineeringisnotappliedscience.Howcanitbewhenengineeringpredatesit? Theengineeringscienceswhichprofessionalengineersutilize,suchasthermodynamics,weredevisedposthoctoexplainwhatengineeringhadalready achieved,andthenaturalsciencesareverylittletodowithengineeringpractice.Wherescientifictermsdoappearinthisdictionary,itisbecausetheyare relevanttopractice.

Bythesametoken,thisisnotadictionarywrittentoaccompanytheacademic studyofchemicalengineering,thoughIbelievemanyacademicswouldbenefit fromusingit.Inmyview(havingpracticedinbothareas),academiaand ChemicalEngineeringareentirelydifferentprofessions.Ihavethereforeleftout ofthisbookallthatistaught—orhelddear—inacademia,butwhichisofno practicalutility,aswellasthemajorityofthosetermswhichshouldbewell understoodbyanygraduateofchemicalengineering.Ihavehowevermadean exceptionforthoseelementsoftheoreticalknowledgewhichweallpassed examsin,butexperiencesuggestsmanyofusdonotremember,orperhaps didnotreallyunderstandinthefirstplace.

Ihopethatmyfellowpractitionerswillfindthisdictionaryusefulintheirprofessionaljourney,whetherpreparingforprofessionalexaminations,enteringa newsector,progressingintheirown,workinginanewterritory,orcollaboratingwithotherdisciplines.

Acknowledgments

Ittookmorethan3yearstocompilethisdictionary,andmuchofitwaspreparedunderpandemicconditions.Agoodpartofthemanuscriptwasdrafted whilstIwasworking(andlockeddown)inthePanamanianjungleduringthe Springof2020,onaminingsitewherefacilitieswherebasicbutdecentWi-Fi wasnonethelessavailable.

TherewasnowayIcouldhaveproducedmorethan10,000definitionsofterms whichallengineersweregoingtoagreewithonmyown.Beingascorrectas possibleinvolvesengagementwiththepeoplewhousetheseterms,sincethe termsultimatelymeanwhatwethinktheymean.So,duringaperiodwhenwe weresociallydistancedfromoneanother,theextentoftheengagementofmy fellowengineersinthisprojectwasparticularlytouching.

Somepeoplewhowouldnotnormallyhavehadtimetohelpfoundthedictionaryaworthwhiledistractionfromglobalevents.Otherswhosincerelywanted tohelpfoundthemselves,understandably,withotherpriorities.Nevertheless,I wouldliketothankthegreatmanyengineerswhoassistedwithcorrections,opinions,andnecessaryadditionstothedrafttext,nonemoreprolificallythan ClaudioArato,MartinArmstrong,LaurenceAshley,WarwickBagnall,Christopher Davis,PeterElstner,AndyGelbart,SusanJaques,BhavikMehta,TristanReimann, RickRhead,CharlesSanderson,andFelixSirovski:theirinvaluableadvicehada significantimpactonthecontentandpresentationofthedictionary.Special thanksmustalsogotoTomNicholsonatSulzer,whokindlyarrangedpermission formetoreproduceseveralillustrations.

Inaddition,Iamgratefultothemanyotherengineersandspecialistswhotook timetooffercomments,includingMuhammadMuhammadAatiq,DanielAli, HassaanAli,SayedAmmar,YacobBanitaha,DavidBaird,YinkeBankole,Sanjay Bhagat,MuhammadButt,FabioCapezzuoli,VMChenthil,MukundChiplunkar, MarcClithero,PukhrajDaga,HarveyDearden,RogerFreestone,RonaldFrend, DavidGladman,Pier-PaoloGreco,MatthewGreen,TimHighfield,Soran Hoseini,SatishInamdar,ChaitanyaKalipatnapu,NareshKandlapalli,Mohan Karmarkar,MykeKing,SteveLancaster,GertLubbe,MiriamAbigailManibo, MohamedNadine,PabbaNavya,MarkNellist,BNurfarahin,PeterOwoade, RossiriPacheco,NachoPalacios,DayangRadiahBintiAwangBiak,Alejandro RamirezDeLoza,AlunRees,RickRhead,XimenaRodriguez,MorganRodwell, VenkataKrishnanSampath,NarinderSingh,KatherineSmith,AchintyaSujan, JairoVidal,JimWarrell,andStevenWoolley.

Manyotherswhogaveessentialassistancearenotmentioned—myapologies andthanksinequalmeasuretoallofyou.

Thenatureofthebookmeansthatpublicdiscussionhasalsobeenakeypartof theprocess,asIhavebeenabletodrawonmanyusefulsocialmediainteractionstoclarifythemeaningofwords,forexamplearoundthedifference between“slips”and“dogs”(thanksduetoTylerHelmetal).Iamgratefulto everyonewhogotinvolvedwiththesediscussionsbutparticularlytoChris Brookes-Mann,PaddyKitching,VijaySarathy,GrantLukies,andStuartSmart whoallengagedregularlyandthoughtfully.Thesediscussionswereessentialto myaimsinwritingthebook,buttheywereparticularlyusefulinunderstanding theissuesaround“risk”(thereweremanycontributorsthere,butIwouldlike tosingleoutMiguelPiedras,whosignpostedmetoaninvaluablearticleby ChrisParisonthemanyandvariedISOdefinitionswhichprovedveryhelpful).

Finally,IwouldliketothanktheteamatmypublisherElsevierfortheirongoing support.MyeditorCostasMarinakis,alongsideprojectmanagementfrom EmeraldLi,tookthisprojectfromdevelopmentthroughtopublicationwith reliableprofessionalism.IamparticularlypleasedthatElsevierarecurrently planningtosupportcontinuinginteractionsbetweenengineersthroughadedicated forum1 afterpublicationofthedictionary.

1https://booksite.elsevier.com/9780128195994/

SeanMoran

Introduction

1Commonplace,Generic,and SpecificDefinitions

Atechnicaldictionarysuchasthisshouldbydefinitioncontainonly“words” withspecificmeaningswithinafieldofexpertise—properlycalledindustry terms.Thecommonplacemeaningsofthewordsareexcluded.Thisispotentiallyproblematic,asmisunderstandingsmayarisewhensomeoneusesaword initscommonplacesense,butisunderstoodtobeusingatechnicalterm,or viceversa.

Severaltermsaremarkedinthisbookashavingboth“generic”and“specific” meanings.“Generic”meaningsarethoseusedprofessionallyinthesameway acrossallindustries,ratherthanbeingcommonplacemeanings.Ihaveusually developedagenericmeaningfromaconsensusofmyunderstanding,thatof mycorrespondents,andpossiblyanumberofcodesandstandards.Ageneric meaningisintendedtoconveyasuccinctviewofwhatIunderstandtobethe coremeaninggenericallygiventotheterminourprofession.“Specific”meaningsarenotofferedasanillustrationofthegenericmeaning;indeed,theymay actuallyclashwiththegenericmeaning.Ifinyourpractice,youcomeacrossa termbeingusedinthecontext(usuallyindustrysector)Ireference,thenitsuse couldeasilybeinthespecificsenseratherthanthegenericorcommonplace ones.

2Sector-specificTerminology

Oneofthekeywaysinwhichterminologydifferswithinourprofessionisacross sectors.Ihavethereforedividedourprofessioninto10nominalsectorsforthe purposeofcategorizingterms:Hygienic,BiochemicalEngineering,OilandGas, BulkChemicals,FineChemicals,Environmental,Products,GeneralEngineering, NuclearandSafety.

Thesesectorclassificationsare,tosomeextent,subjective,andIamawarethat engineersindifferentdisciplines(especiallyoilandgas!)mightwelldisagree withmyclassifications.However,theseareintendedsimplytoalignapproximatelywithmyunderstandingofboththeprofessionalandlinguisticdistinctions.Someoneinoilrefiningorpetrochemicalsmightobjecttoatermbeing lumpedinwiththoseinvolvedinprimaryproduction,buttheyunderstand

mostofthejargonofthatrelatedfieldinawaythatsomeoneinvolvedinpharmaceuticalswillnot.(Imentionoilandgasbecauseadisproportionateamount ofthejargoninthisdictionary,someofitquitecoarse,emanatesfromthis sector!)

Wemightaddan11thcategory,engineeringscience,aheadingunderwhich thosefewtermsfromacademiawhichhavemadetheirwayintothisdictionary wouldtendtofall.Whereithasprovennecessarytodifferentiatesuchacademicterminologyfromprofessionalterminology,Ihaveflaggedthisup.

InsomecasesImaynotrefertoanindustrysectordirectly,butIsignpostaformaldefinitioninanindustry-specificstandard,suchasforexampleanAPIstandard.APIstandardsareusedinmanysectorsotherthanoilandgas,especially thoseinfluencedbytheUnitedStates.However,aswithmyindustryclassifications,theboundariesofmysectorsarelinguisticratherthanabsolute.

Itisreasonablyfrequentthatdifferentsectorsuseatermindifferentways. WhereIamawareofthis,Ihaveflaggedthisinthedefinition.Forexample, chemicallycombinedwater meansdifferentthingstochemists,cementandceramic-specialists.

3Swearing,Jokes,andInsults

Ihaveincludedsomecoarselanguage,asisnormalpracticeinlexicography. Dictionaries(otherthanthoseintendedforyoungchildren)routinelycontain termsconsideredvulgaroroffensiveso,wherethesetermsarepartofengineeringpractice,Ihaveincludedthem,markingthemaseither potentiallyoffensive, or offensive.

ItisarguablyeasiertocauseoffensenowadaysthanwhenIfirststartedintheprofession,somyapproachwillprobablynotsatisfyallreaders,someofwhomare boundtoconsidertheinclusionofanycoarselanguageatall“unprofessional.” Iwouldsuggesthoweverthatswearingandslangcanbeprofessional,even whenitisobscene.Engineersoftenuseswearingforwhatresearchshowsitis goodfor,inthesamewayasdoctors:forstressrelief(aneffectcalledlalochezia), tobuildgroupsolidarity,andforaddingemphasis.Likedoctors,wemayuse in-jokeacronymstohelpusdisguisefromoutsidersthatweareswearing;someof theseacronymsappearinthisdictionary.

Thesetermshoweverconstituteatinyfractionofonepercentofthecontent. Onlypeoplelookingfortheminthemannerofan11-year-oldboylookingfor thenaughtywordsinhisfirstrealdictionaryarelikelytofindthem,unlessthey havealreadyheardthetermandarewonderingwhatitmeans.

Ihavealsoincludedsomedefinitionswhichare“engineerjokes”:acertainflavorofwrycommentarywhichdefineswordscommonlyusedinengineeringin awaywhichreflectssomeofthecultureoftheprofession,andsomeofthe nuanceofthecommonunderstandingofthesetermsinthemindsofprofessionalengineers.Ihavehowevermarkedtheseas jocular,foravoidanceof doubt.

4Formaldefinitions

Throughoutthedictionary,Ireferencethe“formaldefinitions”oftermsas foundincodesandstandards,thoughinalmostallcasesIhavebeenunableto reproducethemforcopyrightreasons.Thiswasinitiallyadisappointment,until itbecameclearthatmany“formaldefinitions”bearthehallmarksofdesignby committee.Manyofthemlacksuccinctness.Someappeartocontainerrors. Fewofthemarewellwritten.Inmanycasesthereferencestoastandardand itsformaldefinitionareincludedbecausethestandardisthesourceofthe term,inothersitisbecausethereisadifferentmeaningfortheterminthat context.Termsarenotcopyright,onlydefinitions.

Thepointofincludingreferencetotheformaldefinitionsisnotthattheyare “correct,”evenintheirlimitedsphereofapplication.Thepointisthatthey haveagoodchanceofbeingtheconsensusterminthatsphere,oratleast representingacommonly-heldview.Thismaywellprovecrucialintheeventof adispute,andbeingunfamiliarwiththedefinitiongiveninrelevantcodesand standardsisthereforesomethingtobeavoided.

WhereIhavefoundtermsformallydefinedindifferentapplications,Iquote multiplestandards.WhereIamaware—throughmyexperienceorthatofmy collaborators—ofwiderapplicationsofaterm,Icitethose.

Forsometerms,myreferencesmaynotalwaysbetothemostcurrentedition ofacodeorstandard.Mostoftenthisisbecausethecodeorstandardwas updatedduringthewritingprocess.Ireferencemorethan200codesandstandardsinthisbook,andittookthreeandahalfyearstowriteit.Sometimes,the morerecentversionnolongerdefinestheterm.Occasionally,theversionIhad onhandwasnotthemostcurrentevenonthedayIstartedwriting.Inafew cases,theoriginalstandardwaswithdrawnsometimeagoandnotreplaced, butneverthelesscontinuestobecommonlyused.

Therearealsoseveralcasesinthedictionaryofclashesbetweentheformaldefinitionsofterms.Thevariationbetweenthemrangesfromsubtledifferencesin terminologytocompletedifferencesinmeaning(see risk foranextremecase). Ihaveflaggedwherethisisthecase.

5Erroneous,Deprecated,and ContestedTerms

Ihaveincludedtermswhicharecommonlyusedinerror,markedassuch,as wellasalargernumberoftermswhicharebestnotusedatall,inorderto avoidconfusion;thesearemarkedas deprecated

However,whilecompilingthisdictionary,Ialsofoundseveralterms,orclusters ofinterrelatedterms,whichweresoambiguousthatasuccinctdefinitionsimplycouldnotbewritten.Thiswasnosurprise—infactIwasratherexpecting thisbasedonmyexperienceofwritingpreviousbooks.

Myapproachhasbeentoavoidrelyingonthedefinitionsincodes,standards andotherdictionaries,especiallynon-technicaldictionariesasbeing“correct.”I havealsoresistedfallingbackonwhattheword/termusedtomeanwhenit wasfirstcoined,oronwhattherootversionofthewordmeantintheclassical languageitwasderivedfrom.

Instead,Ihavetakenadescriptivist,ratherthanprescriptivist,approachreflectingwhatis,ratherthanwhatshouldbe.Itdoesnotmatterwhataterm “should”mean.The raisond’eˆtre ofthisdictionary,afterall,isthatdifferent groupsofengineersusetermstomeandifferentthings.Ihavetherefore includedmoredetaileddiscussiononsuchterms—thoughtheseareinsome casesverymuchmyownviewonthematter,insomecasesexpressedinmy characteristicoccasionallysomewhatprovocativetone.Ididsayitwas Moran’s dictionary!

Youareofcoursefreetodifferonwhatyouthinkthecorrectmeaningtobe andwhethermyviewiscorrect,orwideofthemark.Mypointisthatthereare arangeofopinions—notthatmineistheonlycorrectonebutthatthereisno correctone.

6Disclaimersandapologies

IamalltooawarethatthisbookfallsshortofperfectioninwayswhichIwill notbeabletoaddressbeforepublication.Codesandstandardsareupdated, popularcultureandprofessionalsubculturescreatenewterms,andworld eventsshapeourpriorities.

Thecontenthasbeencheckedthoroughlybymyselfforcompletenessand reviewedbyhundredsofotherengineerstohelpensurecorrectnessandaconsensusposition.Ithasbeenrecheckedrepeatedlyduringthecourseofcopyeditingandtypesetting.However,Iknowthattheremustbeasmallresidueof errors,andindeedomissions,inadictionarywithover10,000entries.

Ifyoufindone,pleasedoletmeknow.IcanbecontactedthroughElsevier, socialmediaordirectlyat sean.moran@expertise-limited.co.uk.

A&E

1.Architectandengineer

2.Accidentandemergency

A/G see aboveground

A/Gtank see abovegroundtank

A/Oprocess see anoxic/oxicprocess

A0

A1

A2

A2flask

A3

A4

AnISOpapersizesimilartoANSI‘E’

AnISOpapersizesimilartoANSI‘D’

AnISOpapersizesimilartoANSI‘C’

TheshippingcontainerusedintheUKtotransportspentnuclearfuel frompowerstationstoreprocessing/storageatSellafield

AnISOpapersizesimilartoUS’Tabloid’/’Ledger’andANSI’B’

AnISOpapersizesimilarToUS’Letter’andANSI‘A’

AACE AssociationfortheAdvancementofCostEngineering

AAPM Artificialadvancedprojectmanagement

AB (drawingnotation) Anchorbolt

abandonment

1.Inthecontextofpipelines,permanentlyshuttingdowntheoperation ofapipelineorfacilitywhereregulatoryapprovalhasbeenreceivedto doso;alternatively,itmayrefertotheactionstogainsuchapproval

2.Inthecontextofoilwells,theactivitiesperformedtoplugawellto preventfluidsfrommigratingup-holefromareservoirandcontaminatingotherformationsand/orfreshwateraquifers abatement

Reducinganuisancesuchaspollutionornoise ABEfermentation aka theWeizmannprocess.ABE(acetonebutanolethanol)fermentation isusedtoproduceacetone,n-butanol,andethanolfromcarbohydrates bybacterialfermentationwitha Clostridium species,mostcommonly C.acetobutylicum

abioticresources

Thenon-livingpartsofanecosystem ablation

Inanengineeringcontext,theremovalofmaterialbyerosion,which findspracticalapplicationincoatingswhichprotectagainstbiological foulingandthermaleffects ablimation

Theoppositeof sublimation (qv)i.e.directtransitionfromvaporto solidphase abortdamper see abortgate

abortgate aka abortdamper.Asafetydevicewhichautomaticallyventsfire, harmfulgasesandburningmaterialtoatmosphere;definedformally in NFPA654:StandardforthePreventionofFireandDustExplosions fromtheManufacturing,Processing,andHandlingofCombustible ParticulateSolids,2017Edition .Maythereforebedescribedas ‘NFPAcompliant’

aboveground aka A/G.Acommondesignationona P&ID (qv)orpipinglayoutdrawingtoindicateifacomponentisaboveorbelowthesurfaceofthe Earth;cf underground(U/G) abovegroundpiping

abovegroundstorage tank

Pipingwhichislocatedabovepiperacksorsupportsaccordingtostandards(e.g. ASMEStandardB.31.3)

Astationary(oftencylindrical)fluidcontainingvessel,withmorethan 90%ofworkingvolumeabovelocalgrade

abovegroundtank aka A/Gtank.Astationary(oftencylindrical)fluidcontainingvessel installed(ratherconfusingly)above,at,orbelowgrade(withoutbackfill),accordingto NFPA30:FlammableandCombustibleLiquidsCode, 2018Edition

absolutealcohol aka absoluteethanol.Ahighpuritygradeofethanol

absolutedensity 1.Inthecontextofionexchange,theweightingramsofwetresinthatdisplacesagivenunitvolume;cf relativedensity and specificgravity 2.(Otherthaninthecontextofionexchange)theratioofmasstounit volume

absoluteerror

Thedifferencebetweenameasuredorinferredquantityanditstrue value;see BoxA1

absoluteethanol see absolutealcohol absolutefilter

Afilterwhichremoves100%ofhardsphericalparticlesgreaterthanits ratedporesizeunderconstantlowpressureinalaboratory;thismeasureshouldnothoweverbeassumedtopredictrealworldbehavior;cf nominalfilter

absolutehumidity

absolutepressure

Thewatercontentofairwithoutallowancefortemperature,calculated asthemassofwaterpresentdividedbythetotalvolume(sometimes mass)ofairandwater

Fluidpressurerelativetoabsolutevacuum;cf gaugepressure absoluteroughness (symbol ε)Ameasureofthedeviationofasurfacefromabsolutely planar.Commonlyusedmeasuresofabsoluteroughnessinclude RMS and Ra; N.B.notthesameas hydraulicroughness (qv);cf relative roughness, roughness

absolutetemperature see Kelvin or Rankine absoluteviscosity aka dynamicviscosity;see viscosity

absorbance see opticaldensity absorbent aka absorbentmaterial.Aliquidorsolidinwhichanothermaterialis dissolved/dispersed absorbentmaterial see absorbent absorber

1.Innuclearreactors,slightlycontested,butmaybeamaterialwhich absorbsalphaparticles,neutronsandionisingradiation,orsolelya neutronabsorber (qv),themoregeneral’absorber’beingreferredto as shielding (qv)

2.Aunitoperationdependentuponabsorption,alsosometimesused tomean absorbent (qv) absorption

Amasstransferprocessinwhichonefluidcomponentistakenintothe bulkofanabsorbentmaterial;cf adsorption absorptiontower aka column.Generically,averticalvesselwithahighaspectratioin whichabsorptionisusedtoseparateafluidmixture.Innaturalgas treatmentitcommonlyrefersonlytoacidgasscrubbingtowers

ABV Alcoholbyvolume;cf proof

AC see alternatingcurrent

ACC AmericanChemistryCouncil

accelerant

Generally,asubstancewhichaltersasecondsubstancetoincreasethe speedofachemicalprocess,suchase.g.,acatalyst.Themostcommon useofthewordishoweverinthecontextoffiresafety,inwhichan accelerantacceleratesfiredevelopment

accelerationdueto gravity (symbol g)thenominalgravitationalaccelerationofanobjectinavacuumnearthesurfaceoftheEarth.DefinedinISO/IEC80000as 9.80665m/s2

accelerationphase

Inthecontextofbiologicalgrowth,thephaseofincreasinggrowthin numbersoforganismsprecedingthe logphase (qv) acceleration transducer see accelerometer accelerator see accelerant accelerometer

Atransducerwhichconvertsaninputaccelerationtoaproportional electricalorelectronicoutput;definedformallyin BSISO2041:2018 Mechanicalvibration,shockandconditionmonitoring.Vocabulary acceptancecertificate

Acertificateformallyconfirmingonbehalfofapurchaserthatasupplier hassuccessfullymetallcontractualacceptancecriteria acceptancenumber

Themaximumallowablenumberofdefectsinabatchofproductforit topassacceptancecriteria

acceptancesampling Theprocessoftestingasamplefromabatchforqualityassessment purposes

accessdoors

accessgauge

Doorsallowingaccessformaintenance

Thespacearoundanitemofequipmentwhichmustremainunobstructedtoenablesafeaccess;definedformallyin BSENISO14122 Safetyofmachinery.Permanentmeansofaccesstomachinery.Working platformsandwalkways

accessplatform

Aplatformusedforapersontoaccessmachinery;definedformallyin BSENISO14122Safetyofmachinery.Permanentmeansofaccessto machinery.Workingplatformsandwalkways accessible see easilyorreadilyaccessible accessibledesign product

Adesignproductintendedtomaximizethenumberofpotentialusers; definedformallyin BSEN82079-1:2012Preparationofinstructionsfor use.Structuring,contentandpresentation.Generalprinciplesanddetailed requirements

accessways

Routesforaccess accident

Anunexpectedoccurrencethateitherleadstodeathorinjury,orhasa highprobabilityofcausingthese;cf incident.Somesafetyspecialists thinkthattherearenotrueaccidents/incidents,asthereshouldbeno unexpectedoccurrences

AccountablePipeline SafetyandPartnership Actof1996

accumulation

accumulator

A(USA)lawintendedtoreducetherisktopublicsafetyandtheenvironmentassociatedwithpipelinetransportationofnaturalgasandhazardousliquids

1.Theallowedpressureincreaseoverthe maximumallowable workingpressure (qv)ofavesselduringoperationofa pressure reliefdevice (qv);definedformally(andveryslightlydifferently)in API RP520P17thEdition,January2000Sizing,Selection,andInstallationof Pressure-RelievingDevicesinRefineries;PartI-SizingandSelection,API Standard521.Pressure-relievingandDepressuringSystems.SixthEdition| January2014 and APIRP576-InspectionofPressureRelievingDevices; 2.Buildupofamaterialinsideamassbalanceenvelope

1. aka pulsationdamper.Adevicewhichequalizesflowandpressure variationintheoutputofareciprocatingfluidtransferdevice 2.Atankinpulpandpapermanufacturingusedforenergyrecovery fromcondensedsteam

3.Equipmentthatstoresmaterialinrelativelyminorquantitiestoeliminatefluctuationinacontinuousprocess,suchasa refluxdrum (qv) accuracy Theclosenessofameasuredorinferredvaluetoitstruevalue; cf absoluteerror, precision;see BoxA1

BoxA1AccuracyorPrecision?

ISOstandard5725-1 1 providesdefinitionsoftrueness,accuracyandprecisionwhichare foundedinstatistics,butasmydiscussionof‘ risk’ ( BoxR2 .)shows,thatisnottheendof thestory.ThisdiscussionishoweverinformedbytheISOstandard,aswellasprofessional usageatvaryingdegreesofformality.Its houldbenotedthatengineersmightuse thesetermsinanyofthefollowingsenses,orinthecommonplaceway,soifindoubt, check!

Idefine accuracy inthisbookas“theclosenessofameasuredorinferredvaluetoitstruevalue”, absoluteerror as“thedifferencebetweenameasuredorinferredquantityanditstruevalue”, and precision as“whetheraninstrumentwillgivethesamereadingagainstthesametruevalue thenexttimeitistested”.However,Ihavewrittenelsewhere2 abouthowprecisionisoften defined(bymathematicians)tomeanwhatengineerscallresolution,whilstprecisionisusedby engineerstomeanallkindsofthings,includingaccuracy.

Inengineering,weareusingthelanguageofmathematics3 whenwetalkabout‘impliedprecision’:forexample,ifweneedcontrolofpHtowithin0.1pHunits,thisisnotthesameassaying thatweneedcontroltowithin0.10pHunits,whichimplies10timesthe(mathematician’s)precision.Whensomeonegivesusallofthefiguresontheircalculatordisplaywithoutconsidering howmanyaresignificant,theimpliedprecisionisspurious,hencewecallit‘spurious precision’.Thenumberofsignificantdigitsissometimescalledresolution,andisalwaysrelated toit,butthistermismorecommonlyusedforthesmallestchangeinthemeasuredvaluewhich aninstrumentcandetect.

Accuracy (alsoknownas,orcloselyrelatedtotrueness)isaboutthegapbetweenthetrue valueandthevalueindicatedbytheinstrument.Intheexampleabove,IneedpHtobecontrolledwithintherangearoundthesetpoint 6 0.05pHunits,thereforemymeasurement accuracyneedstobereliablyatleastthisgood.

Precision inengineering,ontheotherhand,isnotus uallythemathematician’sprecision, nortodowithanengineer’sdefinitionofaccuracyorresolution.Engineeringprecision reliesuponreproducibilityandrepeatability ,thefirstencompassingvariabilityovertime, andthesecondbeingprecisionundertight lycontrolledconditionsoverashorttime period.

Relatedterms

impliedprecision,limitofdetection,limitofquantification,resolution

1BSISO5725 1:1994Accuracy(truenessandprecision)ofmeasurementmethodsandresults.Generalprinciplesand definitions

2Moran,S.(2019) AnAppliedGuidetoProcessandPlantDesign,2nd Ed.Oxford:Elsevier

3By‘thelanguageofmathematics’,Iamexcludingstatistics.Statisticiansdefineprecisionasthereciprocalofvariance

acentricfactor A fudgefactor (qv)usedinthermodynamicstoaccountforthe degreetowhichmoleculesarenotspherical,andthereforedonot behaveaspredictedbytheprincipleofcorrespondingstates(whichis basedonanassumptionofsphericalmolecules)

acetylene

acetylenes

ACFM

Thesimplest alkyne (qv),agasusedalongwithoxygenforwelding andcutting.Explosivelyunstableasacompressedgas,sonormallysuppliedinanacetonesolutionunderpressure

Ageneric(non-IUPAC)namefor alkynes(qv)stillincommonusein industry

1.Alternatingcurrentmagneticfluxleakagetesting,aplantinspection testmethod;definedformallyin APIRP571-DamageMechanism AffectingFixedRefineryEquipment

2.Actualcubicfeetperminute

ACGIH see AmericanConferenceofGovernmentalIndustrial Hygienists

ACI AmericanConcreteInstitute

acicularcoke see needlecoke

acid

Asubstancewhichcanactasaprotondonor,orlesscommonlycan formacovalentbondwithanelectronpair acidegg

Anovoidceramicvesselusedtotransportsmallquantitiesofacids acidgas Oilandgasterminologyforanypetroleumderivedgas,suchas producedgas (qv),containingsignificantquantitiesofgaseswhich arethemselvesacidinaqueoussolutionsuchasCO2 andH2S. Sometimesextended(incorrectlyinmostpeople’sview)togaseswith acidiccombustionproductssuchH2S,moreproperlyknownassour gases;cf sourgas, sweetgas

acidgasrespirator aka organicvaporrespirator.PPEwhichprovidesprotectionagainst acidicvapors,chlorineandcertainorganicsaswell.Oftenalimited-life, highlyportableitemusedonrefineriesandchemicalsiteshandling chlorine

acidnumber aka acidvalue,AV,neutralizationnumber,acidity,totalacidnumber.A measureoftheamountofcarboxylicacidicgroupsinasubstance,measuredasthemassofpotassiumhydroxide(KOH)inmilligramsrequired toneutralizeonegramofthesubstance,especiallyanoil.Inthecaseof edibleoils,itisanindicatorofrancidity.Inthecaseofmineraloil,a measureofcorrosiveness

acidvalue see acidnumber

acidified

acidity

Treatedwithacid,commonlytoneutralisealkalipresent,ortooccupy bindingsitesinionexchangemediaoracidifiedzeolitecatalyst

1.see acidnumber

2.Abilitytodonateaproton,theoppositeof basicity (qv)

acidogenesis

ACM

Generically,aprocessofacidformation.Inenvironmentalengineering, thestageof anaerobicdigestion inwhichfattyacidsareproduced frommorecomplexsubstances

Asbestos-containingmaterial

ACOchannel Agenericizedtrademarkforasunkencoveredfloordrain;therearea largenumberofmanufacturersandstyles;see Fig.A1

acousticemission testing aka AET.Amethodfordetectingcracksinmetalliccomponents,discussedin APIRP571-DamageMechanismAffectingFixedRefinery Equipment

ACS Automationcontrolsystems

ACT see automaticcustodytransfer actinides Elements90 103(thoriumtolawrencium),namedafter actinium actinium Element89

activatedcarbon

Anadsorbentmaterialproducedfromvarioushigh-carbonmaterials suchascoal,coconutshellsorvegetablematter

activatedsludge see activatedsludgeprocess activatedsludge process Along-establishedprocessusedtotreatwastewaterbyrecirculating sludgerecoveredbysettlementafterbiologicaltreatmenttomixwith incomingfeed

activationenergy (symbol Ea)Theenergyrequiredtoinitiateachemicalreaction. Catalysts (qv)workbyreducingthis activehotstandby Havingparallel standby (qv)unit(s)inservice,ratherthanidling activeoptoelectronic protectivedevice Machinesafetydevicebasedonlightsensing;definedformallyin BSEN ISO12100:2010Safetyofmachinery.Generalprinciplesfordesign.Risk assessmentandriskreduction

activepharmaceutical ingredient aka API.Themedicinalcontentinapharmaceuticalproduct;cf active pharmaceuticalintermediate activepharmaceutical intermediate aka API.Acompoundformingastepinthechainofsyntheseswhich produce activepharmaceuticalingredients(qv) activesite Thepartofacatalystwhichbindstoasubstratetofacilitateareaction. Almostexclusivelyusedinthecontextofenzymes

FigureA1 ACOchannels.

activity

1.Inprojectmanagement,thesmallestincrementofwork;defined moreformallyin BSENISO9000Qualitymanagementsystems Fundamentalsandvocabulary

2.Theratioofthechangeintworelatedconditions,suchase.g. water activity (qv)

3.Inthecontextoftechnicaldocumentation,aprocess,procedureor partsofthem;definedformallyin ISO10209:2012Technicalproduct documentation—Vocabulary—Termsrelatingtotechnicaldrawings,productdefinitionandrelateddocumentation

activitycoefficient aka fugacitycoefficient.Afiddlefactor(UK)orfudgefactor(USA)used inthermodynamicstoaccountfordeviationsfromidealbehaviorina mixtureofchemicals

activitycoefficient model see Margules’activitymodel

activitymatrix

Adocumentsimilartoaprojectprogram,placingactivitiesinphasesof aproductlifecycle;definedformallyin ISO10209:2012Technicalproductdocumentation-Vocabulary-Termsrelatingtotechnicaldrawings, productdefinitionandrelateddocumentation

ACTR see actuatingelement

ACTS see AsbestosContractorTrackingSystem actualcubicfeetper minute aka ACFM.AUSAcustomarymeasureofgasflowdefinedinanumber ofways;cf standardcubicfeetperminute actualdischargearea aka actualorificearea.Theminimumareathatdeterminestheflow throughapressurereliefdevice;definedformallyin APIRP520P17th Edition,January2000Sizing,Selection,andInstallationofPressureRelievingDevicesinRefineries;PartI-SizingandSelection actualflowrate Theflowrateunderrealworking/flowingconditions;definedformally in BSENISO13705:2012/ISO13705:2012(E)Petroleum,petrochemical andnaturalgasindustries.Firedheatersforgeneralrefineryservice actualinside diameter Theinsidediameterofanewheatexchangertube,definedformallyin APISTD530-CalculationofTubeHeaterThickness actualorificearea see actualdischargearea actuatedliquid withdrawalexcess flowvalve

AnadapteroperatedvalveusedtowithdrawliquidfromanLPGcontainer,withintegratedexcess-flowvalve;definedformallyin NFPA58: LiquefiedPetroleumGasCode,2017Edition actuatedvalve aka AV,CV,motoroperatedvalve.Avalvecontrolledbyan actuating element (qv);cf manualvalve actuatingelement aka ACTR,actuator.Anitemofinstrumentationequipmentwhichreceivesa signal(pneumatic,hydraulic,orelectrical)andadjustsacontrolelement (e.g.valve,motorcontroller)accordingtothatsignal;definedformallyin BS1646-1SymbolicRepresentationforProcessMeasurementControlFunctions andInstrumentationPart1:BasicRequirements,ISO3511/1(W/D) and BS 1646 3:1984Symbolicrepresentationforprocessmeasurementcontrolfunctionsandinstrumentation.Specificationfordetailedsymbolsforinstrument interconnectiondiagrams

actuator see actuatingelement

actuatorvalve see actuatedvalve

AD see anaerobicdigestion

ADC see analoguetodigitalconverter additive

1.Generally,asmallamountofsomethingaddedtoenhance performance

2.Specifically,inthecaseoffireprotection,foamconcentrates,emulsifiers,andsoonaddedtowatertoenhancefirefightingperformance; definedformallyin NFPA20:StandardfortheInstallationofStationary PumpsforFireProtection,2019Edition additivepump

1.Generally,apumpusedtointroduceadditives,inwhichcasesynonymouswith dosingpump

2.Inafirefightingcontext,definedformallyin NFPA20:Standardfor theInstallationofStationaryPumpsforFireProtection,2019Edition adequaterisk reduction Riskreductionmeetinglegalrequirementsattheveryminimum; definedformallyin BSENISO12100:2010Safetyofmachinery.General principlesfordesign.Riskassessmentandriskreduction

adequateventilation

adiabatic

adiabaticefficiency

adiabaticflame temperature

1.Sufficientventilationtopreventtheaccumulationofsignificantquantitiesoffuelairmixturesat . 20%oftheir LEL (qv)/LFL (qv);defined formallyin APIRP5052ndEdition,August2018RecommendedPractice forClassificationofLocationsforElectricalInstallationsatPetroleum FacilitiesClassifiedasClassI,Zone0,Zone1,andZone2

2.Mayalsosometimesbeusedinabroadersense,ofventilationsufficienttomaintainaworkareaasasafeplace;cf inadequate ventilation

Strictly,aconditioninwhichheatdoesnotenterorleavethesystem concerned;definedformallyin APIRP2510A-FireProtection ConsiderationsfortheDesignandOperationofLiquefiedPetroleumGas (LPG)StorageFacilities

Inthecontextofcompressorsandfans,thepowertheoreticallynecessarytocompressanddeliveragasadiabaticallydividedbythepower suppliedatthedriveshaft

Thetheoreticalflametemperatureunderadiabaticconditionsdefined formallyin APIRP535-BurnersforFiredHeatersatRefineries

adiabaticflash see flashevaporation

adiabaticsaturation temperature

adjustableguard

adjustedsetpressure

Thetheoreticaltemperatureofavolumeofairifcooledadiabaticallyto saturationbytheevaporationofwater.Itisapproximatelyequaltothe wetbulbtemperature (qv)

Amachinesafetydevicewhichcanbeadjusted;definedformallyin BS ENISO12100:2010Safetyofmachinery.Generalprinciplesfordesign. Riskassessmentandriskreduction

Thestaticinletpressureatwhichapressurereliefvalveisadjustedto openontheteststand;definedformallyin API2000,Venting AtmosphericandLowPressureStorageTank,7thEd adjuster (jocular)Hammer

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