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HandbookofRadioactivity Analysis

Volume2:RadioanalyticalApplications

FourthEdition

AcademicPressisanimprintofElsevier 125LondonWall,LondonEC2Y5AS,UnitedKingdom

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ThisbookandtheindividualcontributionscontainedinitareprotectedundercopyrightbythePublisher(otherthanasmay benotedherein).

Notices

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Practitionersandresearchersmustalwaysrelyontheirownexperienceandknowledgeinevaluatingandusingany information,methods,compounds,orexperimentsdescribedherein.Inusingsuchinformationormethodstheyshouldbe mindfuloftheirownsafetyandthesafetyofothers,includingpartiesforwhomtheyhaveaprofessionalresponsibility.

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Contributors

NicoleBarthe,Univ.Bordeaux,bioingénierietissulaire, Bordeaux,France;INSERM,bioingénierietissulaire, Bordeaux,France

MariaBetti,DirectorateG-NuclearSafetyandSecurity, EuropeanCommission,DGJointResearchCentre, Karlsruhe,Germany;FormerlyattheInternational AtomicEnergyAgency,EnvironmentalLaboratories, Monaco

AnaCardona(InMemoriam),InstitutPasteur,Paris, France

NicolasCarvou,BiospaceLabUK,Warwick,United Kingdom

XiongxinDai,ChinaInstituteforRadiationProtection, Taiyuan,ShanxiProvince,China

OlegB.Egorov,Medvio,LLC,WestRichland,WA, UnitedStates

KonstantinosEleftheriadis,EnvironmentalRadioactivity Laboratory,InstituteofNuclearandRadiologicalScience & Technology,Energy & Safety,N.C.S.R. “Demokritos ”,Ag.Paraskevi,Attiki,Greece

RudolfEngelbrecht,Radiochemistry,SeibersdorfLabor GmbH,Seibersdorf,Austria;Currently-Austrian AgencyforHealthandFoodSecurity,GmbH,Vienna

MatsEriksson,SwedishRadiationSafetyAuthority, DepartmentofRadiationProtection,Stockholm,Sweden;FormerlyattheInternationalAtomicEnergy Agency,EnvironmentalLaboratories,Monaco

WilliamGeist,LosAlamosNationalLaboratory,SafeguardsScienceTechnologyGroup,LosAlamos,NM, UnitedStates

ZeljkoGrahek,LaboratoryforRadioecology,RuC er BoskovicInstitute,Zagreb,Croatia

JayW.Grate,Paci ficNorthwestNationalLaboratory, Richland,WA,UnitedStates

AgustínGrauCarles,AcademiaBIC,Madrid,Spain

AgustínGrauMalonda,CIEMAT,Madrid,Spain

XiaolinHou,TechnicalUniversityofDenmark,DepartmentofEnvironmentalEngineering,Roskilde, Denmark;LanzhouUniversity,SchoolofNuclear ScienceandTechnology,Lanzhou,China

PhilipHypes,LosAlamosNationalLaboratory,HazardousMaterialsManagementGroup,LosAlamos,NM, UnitedStates

AlexandraIoannidou,AristotleUniversityofThessaloniki,PhysicsDepartment,NuclearPhysicsLaboratory, Thessaloniki,Greece

MiroslavJeskovský,ComeniusUniversity,Facultyof Mathematics,PhysicsandInformatics,Departmentof NuclearPhysicsandBiophysics,Bratislava,Slovakia

JakubKaizer,ComeniusUniversity,FacultyofMathematics,PhysicsandInformatics,DepartmentofNuclear PhysicsandBiophysics,Bratislava,Slovakia

IvanKontul’,ComeniusUniversity,FacultyofMathematics,PhysicsandInformatics,DepartmentofNuclear PhysicsandBiophysics,Bratislava,Slovakia

MichaelJ.Kristo,LawrenceLivermoreNationalLaboratory,Livermore,CA,UnitedStates

MichaelF.L’Annunziata,TheMontagueGroup,Oceanside,CA,UnitedStates

GalinaLujaniené,SRICenterforPhysicalSciencesand Technology,Vilnius,Lithuania

SergeMaîtrejean,SMTJConsulting,Paris,France

MonikaMüllerová,ComeniusUniversity,Facultyof Mathematics,PhysicsandInformatics,Departmentof NuclearPhysicsandBiophysics,Bratislava,Slovakia

MatthewJ.O’Hara,Pacifi cNorthwestNationalLaboratory,Richland,WA,UnitedStates

PavelP.Povinec,ComeniusUniversity,Facultyof Mathematics,PhysicsandInformatics,Departmentof NuclearPhysicsandBiophysics,Bratislava,Slovakia; FormerlyattheInternationalAtomicEnergyAgency, EnvironmentalLaboratories,Monaco

PeterSanti,LosAlamosNationalLaboratory,Safeguards ScienceTechnologyGroup,LosAlamos,NM,United States

JanScholten,InstituteofGeosciences,KielUniversity, Kiel,Germany;FormerlyattheInternationalAtomic EnergyAgency,EnvironmentalLaboratories,Monaco NatasaTodorovic,UniversityofNoviSad,Facultyof Sciences,DepartmentofPhysics,NuclearPhysics Laboratory,NoviSad,Serbia

AbouttheFoundingEditor

MichaelF.L’Annunziata,PhD,isthefoundingeditor andcoauthorofthe HandbookofRadioactivityAnalysis. HemajoredinchemistrywithaBScdegreefrom St.Edward’sUniversityin1965,andhewasawardedMSc andPhDdegreesfromtheUniversityofArizona,Tucson, in1967and1970,respectively.Hisgraduatethesisresearch inthe1960s, financedbythethenUSAtomicEnergy Commission,dealtwiththeanalysisoftheradionuclides 89Srand 90Srandtheremediationofsoilscontaminated withradiostrontiumintheeventofnuclearfallout,publishedasathesisin1967(https://repository.arizona.edu/ handle/10150/318640).Afterashortstintinthechemical industry(AmchemProducts,Inc,Ambler,Pennsylvania) during1970 71as 14C-tracerchemist,hejoinedthe facultyatthePostgraduateCollegeinChapingo,Mexico, asaprofessorandthesisadvisorduring1972 75,and during1975 77,L’AnnunziatawasaseniorresearchscientistattheNuclearCenteroftheNationalInstituteof NuclearResearch(ININ),Mexico,whereheservedalsoas athesisresearchadvisortograduatestudentsofchemistry oftheAutonomousUniversityoftheStateofMexicoin Toluca,Mexico,inthe fieldofradionuclideanalysisand applications.During1977 91,hewasascientificofficerin theDepartmentsofResearchandIsotopesandTechnical CooperationoftheInternationalAtomicEnergyAgency

(IAEA)inVienna,Austria,whereheservedasIAEAHead ofFellowshipsandTrainingduring1987 91.From1977 to2007,heservedasIAEAExpertinfact- finding,planning,andimplementationassignmentsinpeacefulapplicationsofnuclearenergyfordevelopmentinmorethan50 countriesoftheworldinAsia,Africa,Europe,Latin America,andtheMiddleEast.L’AnnunziatawasamemberoftheBoardofGovernors,InternationalScience ProgramsatUppsalaUniversity,between1988and1991. Hismainresearchinterestshavebeenfocusedonthe developmentofchemicalandinstrumentalmethodsforthe detectionandmeasurementofradioactivenuclidesas tracersinresearch.Hewasthe fi rsttopostulatethesoil microbialepimerizationofmyo-inositoltootherinositol stereoisomersasasourceofthestereoisomersofinositol phosphatesinsoils(PhDdissertation,1970, https:// dissexpress.proquest.com/dxweb/results.html?QryTxt¼&By¼ L%27Annunziata&Title¼&pubnum ¼ )andin1975(SSSA Journal 39(2),377 379)and firsttodemonstratein1977, withtheuseoftheradioisotopecarbon-14,thesoilmicrobialepimerizationofmyo-inositoltochiro-inositolasa mechanisminvolvedintheoriginoftheuniquesoilinositol phosphatestereoisomers(SSSAJournal 41(4),733 736, https://dl.sciencesocieties.org/publications/sssaj/abstracts/ 41/4/SS0410040733).The firsteditionofthe Handbookof RadioactivityAnalysis wasplannedbyL’Annunziatain 1995,andheeditedandcoauthoredthesubsequenteditions,includingthecurrentfourtheditionpublishedby Elsevierin2019.Hehasauthoredandcoauthored11books since1979onradionuclideanalysisandradiationphysics amongwhichhisbookentitled Radioactivity:Introduction andHistory,FirstEdition,publishedbyElsevierin2007, wasincludedontheBestSellersListinPhysics(LibraryJournalAcademicNewswire)in2008.Hismuch expandedSecondEditionentitled Radioactivity:IntroductionandHistory,FromtheQuantumtoQuarks (https:// www.sciencedirect.com/book/9780444634894/radioactivity), publishedbyElsevierin2016,wasawardedanHonorary Mentioninthe2017PROSEAWARDSinthecategoryof ChemistryandPhysics.

MichaelF.L’Annunziata

Foreword

Radioactivesourcesplayasignifi cantroleinpromotinghumandevelopmentandhealthworldwide.Whetherthroughits applicationtotreatcancer,diagnosevariousdiseases,developnewcropvarieties,sterilizemedicalsupplies,orprovide cleanenergy,peacefulusesofradioactivesourcesareubiquitousinourdailylives.Thesewide-rangingapplicationscan onlybeimplementedappropriatelywhenradioactivityismeasuredprecisely.Thus,theaccuratemeasurementofnuclear radiationisindispensableforthepeacefulapplicationsofradioactivematerials.Forexample,in fieldssuchasnuclear medicine,whetherforthetreatmentordiagnosisofdisease,accuratemeasurementsofradionuclidesareessential. Dosimetricmeasurementsarethecornerstoneofsafeandeffectiveradiationtherapyforthetreatmentofcancerwhetherfor brachytherapy,protonbeamtherapy,orothersourcesofradiationtherapy.

Withmorethan170MemberStatesinallcontinentsoftheworld,theInternationalAtomicEnergyAgency(IAEA) servesastheglobalfocalpointfornuclearcooperation.The HandbookofRadioactivityAnalysis willserveMemberStates asoneofmanytoolsavailableintheapplicationofnuclearscienceandtechnologyforpeacefulpurposes.Theimportance ofthisguidanceisdemonstratedbythewiderangeofareasinwhichtheIAEAsupportsMemberStatestocontributeto theirwell-beinganddevelopment.Suchexamplesincludebiologicalsciencesresearch,insectpestcontrol,health,fertilizer andwateruseefficiency,waterresourcesandtheenvironmentincludingmarinescienceandclimatechange,radiation technology,neutrondiffraction,radiographyandactivationanalysis,radiationprocessinginindustry,radiationprotection, nuclearpower,nuclearsafeguards,radiationpreparednessandresponse,andresearchinthe fieldofnuclearfusion,among others.

The HandbookofRadioactivityAnalysis isnowinitsfourtheditionsincethesuccessful firsteditionin1998.Overthe pasttwodecades,thisbookhasexpandedinitsscopefromaninitial12chapterstothecurrent22chapters,encompassing thenumerousmodernapplicationsandmethodsofradiationdetectionandmeasurement.Thechaptersinthisbookare writtenbyexpertsfrom16countriesaroundtheworld.Thisneweditionwillcontinuetoserveasanimportantresourcein oursearchtooptimizeradioactivitymeasurementsbothinresearchandinitsapplications,leadingtothepeacefulutilizationofradioactivesourcesforhealthanddevelopment.

MayAbdel-Wahab,MD,PhD,FACR Director,DivisionofHumanHealth DepartmentofNuclearSciencesandApplications InternationalAtomicEnergyAgency,Vienna

Prefacetothefourthedition

In1996,IproposedtoAcademicPresstheideaofabookthatwouldprovidereaderswithareferencesourcetostate-of-theartradiationdetectorsandmethodsofanalysisofradionuclidesandothersourcesofnuclearradiation.Thus,the fi rst editionofthisbookwaspublishedin1998asasinglevolumewithonly12chapters,andthebookhasexpandedinscope anddepthoverthepasttwodecadeswiththecurrentfourtheditionandits22chaptersintwovolumes.

Thenumerousadvancesthathavebeenmadesincethepublicationofthepreviousthirdeditionwarrantedthepartition ofthe HandbookofRadioactivityAnalysis intotwovolumes.Itwasdecidedtoseparatethechaptersintotwocategories, namely,Volume1, RadiationPhysicsandDetectors andVolume2, RadioanalyticalApplications.Thetwovolumesofthis bookwereexpandedgreatlytoprovidematerial,whichwouldserveasavaluableresourceinteachingandareference sourcetotheresearcherinhisorheruniqueanalyticalrequirementsinthemeasurementofradioactivematerials.

The fi rstchapterinVolume1,whichwaspreviouslyentitled RadiationPhysicsandRadionuclideDecay,was expandedtoalmostdoubleinvolumewithacorrespondingchangeinthechaptertitleto TheAtomicNucleus,Nuclear Radiation,andtheInteractionofRadiationwithMatter,whichincludesadditionalmaterialhelpfultosupplementthe academiccurriculaandaidinthedecisionsandcalculationsmadebyresearchersintheirmeasurementofnuclearradiation andradionuclideanalysis.Currentprinciplesofoperationofallclassesofradiationdetectorsandtheirapplicationshave beenexpandedandupdated,includingsemiconductordetectors,gasionizationdetectors,liquidandsolidscintillation detectors,solid-statenucleartrackdetectors,Cherenkovdetectors,calorimetersandbolometers,aswellasadvancesin atomcounting(i.e.,massspectrometry)forthemeasurementofradioactiveandstablenuclidesandradiationfromother sourcessuchascosmicradiation,synchrotronradiation,andparticleemissionsfromnuclearreactions.

Inlightofincreasedconcernforradioactivityintheenvironment,achapterwasaddedonthe AnalysisofEnvironmentalRadionuclides inVolume2.Also,allchaptersinVolume2havebeenexpandedandupdatedwithmaterialrequired intheanalysisofradionuclidesandradiationinourland,air,andwaterresources,includingthemarineenvironment,as wellasparticleidentificationandmeasurementbyCherenkovcounting,radiationcountingstatistics,radionuclidestandardization,imagingtechniquesrequiredintheapplicationsofradionuclidesinbiologicalresearchandnuclearmedicine, flow-cellanalyticaltechniques,automationinradiochemicalanalysistogetherwithanalyticaltechniquesrequiredinthe fieldsofnuclearsafeguardsandnuclearforensics.

Again,wehavecompletedthisbookasaninternationaleffortbydrawingupontheexpertiseofresearchersandteachers from16countriesoftheworld.Althoughcomingfrommanybranchesofscience,chapterauthorsallshareonecommon objective,thatbeingthemostaccuratemeasurementofradiationsourcesandradionuclidesbothnaturalandman-made, vitaltoallbranchesofscienceandhumandevelopment.Readersinterestedinradiationphysics,theapplicationsofradionuclidesandradiationsources,andhowthesehavebeenvitaltoourwell-beinganddevelopmentmayrefertoanother textbythewriterentitled “Radioactivity:IntroductionandHistory,FromtheQuantumtoQuarks” (ISBN:978-0-44463489-4),publishedin2016byElsevier(https://www.elsevier.com/books/radioactivity/lannunziata/978-0-444-63489-4).

Womenaretheseniorauthorsofthreechaptersinthisnewedition,whichisevidenceoftheincreasingroleofwomen asleadersinthis fieldofscience.Wemayexpecttoseeyetinthefutureanever-increasingnumberofwomen,whowill makegreatadvancesinthis fieldofsciencefollowingthepioneeringexamplesofMarieCurie,LiseMeitner,Maria Goeppert-Mayer,RosalindFranklin,MariettaBlau,andChien-ShiungWu,amongothers.

Mentionofcommercialproductsinthisbookdoesnotimplyrecommendationorendorsementbythechapterauthorsor editor.Otherormoresuitableproductsmaybeavailable.Namesofproductsareincludedforconvenienceorinformation purposesonly.

Iwouldliketothanktheauthorsofeachchapter,whohavecoveredtheir fi eldsofexpertisewithanunwavering commitmenttomeettheobjectivesofthisbook.AcknowledgmentisextendedtoKathrynEryilmaz(neeMorrissey),

AquisitionEditor,atElsevierinCambridgeforapproachingmewiththesuggestionthatweconsiderafourtheditionand forworkingwithmeduringtheplanningstageofthisbook.ManythanksgotoHilaryCarr,ElsevierEditorialProject Manager,forherconstantsupportandadvicethroughoutthewritingandproductionofthisbook.IthankalsoAshwathiP. AravindakshanofElsevierforherassistanceincompletingthelegalrequirementsforthepublicationofthisbook. AppreciationisalsoextendedtoPremKumarKaliamoorthi,ElsevierProductionProjectManager,forhismeticulous attentiontoeverydetailthroughouttheproductionprocessofthisbook.ThanksarealsoextendedtoSusanDennis, PublisherofElsevierChemistryandChemicalEngineeringBooks,andMonaZahir,ElsevierEditorialProjectManager, fortheirguidanceandsupportduringthisproject.Aboveall,IthankmywifeMariadelCarmen(akaReyna)forher understanding,encouragement,andunflaggingpatience.

Acronyms,Abbreviations,andSymbols

A Massnumber

A Ampere(1A ¼ 1C/s),amplifier

a Year(s)

Å Angstrom(10 10 m ¼ 0.1nm)

AABW AntarcticBottomWater

AAIW AntarcticIntermediateWater

AAS Atomicabsorptionspectrometry

AASI Advancedalpha-spectrometricsimulation

ATTA Atomtraptraceanalysis

ABACC Brazilian ArgentineAgencyforAccountingandControl ofNuclearMaterials

ABEC aqueousbiphasicextractionchromatography

AC Alternatingcurrent

ACC AntarcticCircumpolarCurrent

ACFM Actualcubicfeetperminute(28.3L/min.)

ADC Analog-to-digitalconverter

ADF Advanceddigital filter

ADME Absorption,distribution,metabolism,andexcretion

ADS Accelerator-drivensubcriticalreactor

AEC Automaticefficiencycompensation,AtomicEnergy Commission

AES Atomicemissionspectrometry,Augerelectronspectroscopy

AF AgulhasFront

AFM Atomicforcemicroscope

AFS Atomic fluorescencespectrometry

a Alphaparticle,internalconversioncoefficient

f Proportionalto

ag Attogram ¼ 10 18 g

AGeV GeVpernucleon

AkeV keVpernucleon

A2LA AmericanAssociationforLaboratoryAccreditation

AM b-artemether,arithmeticmean

AMAD Activitymedianaerodynamicdiameter

AMANDA AntarcticMuonandNeutrinoDetectorArray,South Pole

AMANDE AcceleratorforMetrologyandNeutronApplicationsin ExternalDosimetry,IRSN,France

AMAP ArcticMonitoringandAssessmentProgramme

AMeV MeVpernucleon

AMP Adenosinemonophosphate,ammoniummolybdophosphate, amplifier

amp. Amplifier

AMS Acceleratormassspectrometry

amu Atomicmassunits

ANDA 7-Amino-1,3-naphthalenedisulfonicacid

ANFESH Ferricpotassiumhexacyanoferrateonacellulosecarrier

ANITA ANtarcticImpulsiveTransientAntenna

ANL ArgonneNationalLaboratory

ANN Arti ficialneuralnetwork

ANSI AmericanNationalStandardsInstitute

ANSTO AustralianNuclearScienceandTechnologyOrganisation

ANTARES ANTArcticRESearch,AstronomywithaNeutrino TelescopeandAbyssEnvironmentalRESearch,Mediterranean Sea

ANZECC AustralianandNewZealandEnvironmentConservation Council

APCI Atmosphericpressurechemicalionization

APD Avalanchephotodiode

APDC Ammoniumpyrrolidinedithiocarbamate

APE Alkylphenolethoxylate

APMP Asia PacificMetrologyProgram

APS AdvancedPhotonSource,ArgonneNationalLaboratory

AQC Automaticquenchcompensation

AQCS AnalyticalQualityControlServices(ofIAEA)

AQP(I) Asymmetricquenchparameteroftheisotope

ARC AgulhasReturnCurrent

ARMCANZ AgricultureandResourceManagementCouncilof AustraliaandNewZealand

AS Alphaspectrometry

ASTAR Alphastoppingpowerandrange

ASTM AmericanSocietyforTestingandMaterials

atm Atmosphere(standard) ¼ 1.01325 105 Pa

at% Atompercent

ATP Adenosinetriphosphate

ATSDR AgencyforToxicSubstancesandDiseaseRegistry

AUV Autonomousunderwatervehicle

AWCC ActiveWellCoincidenceCounter

AWE UnitedKingdomAtomicWeaponsEstablishment

b Particlerelativephasevelocity,betaparticle

bb Double-betadecay

b Negatron,negativebetaparticle

bþ Positron,positivebetaparticle

b Barn ¼ 10 28 m 2 ¼ 10 24 cm 2

BAC N,N0 -bisacrylylcystamine

bar 105 N/m2 ¼ 100 103 Pa

BBD 2,5-Di-(4-biphenylyl)-1,3,4-oxadiazole

BBO 2,5-Di(4-biphenylyl)oxazole

BBOT 2,5-Bis-2-(5-t-butyl-benzoxazolyl)thiophene

BCC Burstcountingcircuitry,Braggcurvecounter

BDs Bubbledetectors

BDE Bonddissociationenergy

BE Bindingenergy

BEAGLE BlueOceanGlobalExpedition

BEGe Broad-energygermaniumdetector

BGO Bismuthgermanate(Bi4Ge3O12)

BIPM Bureauinternationaldespoidsetmesures,Sèvres,France

bis-MSB p-Bis-(o-methylstyryl)benzene

BK K-shellelectronbindingenergy

bkg,BKG Background

BNCT boronneutroncapturetherapy

BNL BrookhavenNationalLaboratory,Upton,NewYork

BOD Biologicaloxygendemand

BOMARC BoeingMichiganAeronauticalResearchCenter

BOREXINO BOronEXperiment,solarneutrinodetector,Italy

Bq Becquerel ¼ 1dps

BQM Bqmeter(ConsortiumBQM,CzechRepublic)

BR Branchingratio

BS Backscatter

BSA Bovineserumalbumin

BSI TheBritishStandardsInstitute

BSO Bismuthsilicate(Bi4Si3O12)

BSS Bonnerspherespectrometer,BoardofSafetyStandards

BT Boundtritium

BTP Bistriazinylpyridine

butyl-PBD 2-(4-t-Butylphenyl)-5-(4-biphenylyl)1,3,4-oxadiazole

BWR Boilingwaterreactor

c Speedoflightinvacuum(2.9979 108 m/s)

C Coulomb(1C ¼ 1As)

o C DegreesCelsius

CAI Calcium aluminum-richinclusions

CaF2(Eu) Europium-activatedcalcium fluoride

CALEX CalorimetryExchangeProgram

CAM Continuousairmonitoring

CAMAC Computer-automatedmeasurementandcontrol

CANDLES CAlcium fluorideforthestudyofNeutrinosandDark matterbyLowEnergySpectrometer

CANDU Canadiandeuteriumuraniumreactor

CART Classificationandregressiontreealgorithm

CAVE CountinglAboratoryforenVironmentalradionuclidEs, Monaco

CC Chargedcurrent(interaction),chargecomparison,carbonate carbon

CCD Charge-coupleddevice

CCRI ConsultativeCommitteeforIonizingRadiation

CDROM Compactdiscread-onlymemory

CDW CircumpolarDeepWater

CE Chemicaletching,capillaryelectrophoresis

CEA Commissariatàl’EnergieAtomique

CEFAS CentreforEnvironment,FisheriesandAquacultureScience(UK)

CE-ICP-MS Capillaryelectrophoresis inductivelycoupledplasma massspectrometry

CELLAR CollaborationofEuropeanLow-levelUnderground Laboratories

CENTA CentreforNuclearandAcceleratorTechnologies, Bratislava

CERN EuropeanOrganizationforNuclearResearch,Geneva

CET Comptonefficiencytracingmethod

CF Feedbackcapacitor

CF Calibrationfactor,correctionfactor

CFD Constantfractiondiscriminator

cfm Cubicfeetperminute

CFN Cross-flownebulizer

CGE ChamberGramEstimator

Ch Channel

CHEREN2 AnisotropydetectionmodelforCherenkovcounting efficiency

CHU Centrehospitalieruniversitaire

Ci Curie ¼ 2.22 1012 dpm ¼ 3.7 1010 dps ¼ 37GBq

CIAE ChinaInstituteofAtomicEnergy

CICM Conventionalintegralcountingmethod

CID Collision-induceddissociation

CIEMAT CentrodeInvestigacionesEnergéticas,Medioambientales yTechnológicas,Madrid

CIRIA ConstructionIndustryResearchandInformation Association

cm Centimeter

cm/d Unitof fluxfromcm3/cm2 perday

CMB Cosmicmicrowavebackground

CMOS Complementarymetal-oxide-semiconductor

CMPO Octyl(phenyl)-N,N-di-isobutylcarbamoylmethylphosphine oxide

CMX-4 CollaborativeMaterialsExercise(fourthbytheITWG)

C/N CIEMAT/NIST(efficiencytracingmethod)

CN Cellulosenitrate

CN* Unstablecompoundnucleus

CNC Condensationnucleicounter

CNET CIEMAT/NISTefficiencytracing

CNRS CentreNationaldelaRechercheScientifique,France

CNS Centralnervoussystem

COG Centerofgravity

COMPASS CommunityPentascaleProjectforAcceleratorScience andSimulation

COTS Commercialoff-the-shelf(system)

cph,CPH Countsperhour

cpm,CPM Countsperminute,channelphotomultiplier

cps,CPS Countspersecond

CR-39 PolyallyldiglycolcarbonateplasticSSNTD

CRESST CryogenicRareEventSearchwithSuperconducting Thermometers

CRL Compoundrefractivelens

CRM Certifiedreferencematerial

CS Calibrationsource

CSDA ContinuousSlowingDownApproximationrange

CSIC InstitutodeFísicaFundamental,Madrid

CsI(Na) Sodium-activatedcesiumiodide

CsI(Tl) Thallium-activatedcesiumiodide

CT Computerizedtomography

CTBT ComprehensiveNuclear-Test-BanTreaty

CTBTO ComprehensiveNuclear-Test-BanTreatyOrganization

CTD Conductivity/temperature/densitydetector

CTF Contrasttransferfunction

CTFE Chlorotri fluoroethylene

CTR Controlledthermonuclearreactor

cts Counts

CV Corevalence

cv Columnvolume

CWOSL Continuouswaveopticallystimulatedluminescence

CZT Cadmiumzinctelluride(semiconductordetectors)

D Deuterium

d Days,deuteron,downquark

d Antidownquark

2D Two-dimensional

DA Destructiveanalysis

Da Dalton(unifiedatomicmassunit,alsoabbreviatedasu)

DAC Derivedairconcentration

DAP Diallylphthalate

DASE LeDépartementanalyse,surveillance,environnement, France

DATDA Diallyltartardiamide

DBD Double-betadecay

DC Directcurrent

DCC Digitalcoincidencecounting

dc-GDMS Directcurrent glowdischargemassspectrometry

DDCP Dibutyl-N,N-diethylcarbamylphosphonate

DDTC Diethyldithiocarbamate

DE Doubleescape

DEF Delayedettringiteformation

d Deltarays

DEMO DemonstrationPowerPlant(fusion)

DESR Doubleexternalstandardrelation

DESY DeutschesElektronenSynchrotron

Det. Detector

DF Decontaminationfactor

DF-ICP-MS DoublefocusingICP-MS

DGA Diglycolamide

DIC Dissolvedinorganiccarbon

DIHEN Directinjectionhigh-efficiencynebulizer

DIM Datainterpretationmodule

dimethylPOPOP 1,4-Bis-2-(4-methyl-5-phenyloxazolyl)benzene

DiMF Decayinamagnetic field(method)

DIN Diisopropylnaphthalene

DIPE Diisopropylether

DIPEX Bis(2-ethylhexyl)methane-diphosphonicacid

DIRC DetectorofinternallyreflectedCherenkovlight

DJD Diffusedjunctiondetector

DLU Digitallightunits

DMCA Digitalmultichannelanalyzer

DMF Digitalmicrofluidics

DMG Dimethylglyoxime

DMM Directmatricesmultiplication

DMSO Dimethylsulfoxide

DNA Deoxyribonucleicacid

D2O Heavywater

DOC Dissolvedorganiccarbon

DOE USDepartmentofEnergy

DOELAP DepartmentofEnergyLaboratoryAccreditationProgram

DOM Digitalopticalmodule

DOP Dioctylphthalate

DOT Digitaloverlaytechnique

dpm,DPM Disintegrationsperminute

dps,DPS Disintegrationspersecond

DPSD Digitalpulseshapediscrimination

dpy,DPY Disintegrationsperyear

DQP Doublequenchparameter

DRAM Dynamicrandomaccessmemory

DSA Definedsolidangle

DSES Deepseaechosounder

DSP Digitalsignalprocessing

DT Deadtime

DTPA Diethylenetriaminepentaaceticacid

DTSA Desktopspectrumanalyzer(software)

DU Depleteduranium

DWL Drinkingwaterlimit

DWPF Defensewasteprocessingfacility

E Countingefficiency,energy

Eb Bindingenergy

e D Positron

e Electron,negatron

e hD ore h Electron holepair

EBq Exabecquerel(1018 Bq)

EC Electroncapture,extractionchromatography,EuropeanCommunity,elementalcarbon

ECD Effectivecutoffdiameter

ECDL Extendedcavitydiodelaser

ECE Electrochemicaletching

ECR Electroncyclotronresonance

ED Exponentialdecrease

EDS Energydispersivespectrometer

EDTA Ethylenediaminetetraaceticacid

EDX EnergydispersiveX-ray(spectrometer)

EDXRF EnergydispersiveX-ray fluorescence

EESI-MS Extractiveelectrosprayionizationtandemmass spectrometry

EeV Exaelectronvolts(1018 eV)

EF Fermilevel

EF Enrichmentfactor

Eh Oxidationpotential

EI Electronimpact(e.g.,inmassspectrometry)

EIA Enzymeimmunoassay

EM Electromagnetic

EMA Extramuralabsorber

EMCCD ElectronmultiplierCCD

EML EnvironmentalMeasurementLaboratory,USA

EMPA Electronmicroprobeanalysis

ENEA ItalianNationalAgencyforNewTechnologies,Energyand SustainableEconomicDevelopment

ENSDF EvaluatedNuclearStructureDataFile

EO Ethyleneoxide

EPA USEnvironmentalProtectionAgency

EPCRA EmergencyPlanningandCommunityRight-to-KnowAct

EPR Electronparamagneticresonance

ERBSS Extended-rangeBonnerspherespectrometer

erg Energyunit(1erg ¼ 6.2415 1011 eV ¼ 10 7 J)

ES Elasticscattering,externalstandard

ESA EuropeanSpaceAgency,Paris;electrostaticanalyzer

ESCR Externalstandardchannelsratio

ESI Electrosprayionization

ESIRWG ExtendedSIRWorkingGroup

ESP Externalstandardpulse

ESTAR Electronstoppingpowerandrange

esu Electrostaticunit

ET Efficiencytracing

ET-DPM Efficiencytracingdisintegrationsperminute(method)

ETH EidgenössischeTechnischeHochschule,Zurich

ETV-ICP-MS Electrothermalvaporization inductivelycoupled plasmamassspectrometry

Eav Averageenergy(betaparticle)

Emax Maximumenergy(betaparticle),Comptonelectronenergy maximum

Ea Alpha-particleenergy

Ep Protonenergy

Eth Thresholdenergy

EU EuropeanUnion

EUChemS EuropeanChemicalSociety

EURACHEM Europeanorganizationfortraceabilityofchemical measurements

EURADOS EuropeanRadiationDosimetryGroup

EURATOM EuropeanAtomicEnergyCommunity

EUROMET EuropeanCollaborationinMeasurementStandards

eV Electronvolt ¼ 1.602176 10 19 J ¼ 1.602176 10 12 erg)

EXAFS X-rayabsorption finestructure

o F DegreesFahrenheit

FADC Fastanalogdigitalconverter

fC Fractionofcontemporarycabon

FDA USFoodandDrugAdministration

FDG Fluorodeoxyglucose

FDNPP FukushimaDai-ichiNuclearPowerPlant,Japan

FDNPS FukushimaDai-ichiNuclearPowerStation,Japan

FEP Fullenergypeak

FET Fieldeffecttransistor

FFF Field flowfractionation

fg Femtogram(10 15 g)

FGRM Flow-throughgaseousradiochemicalmethod

FI Flowinjection

fm Fermiorfemtometer(10 15 m)

fM Fractionofmoderncarbon

fmol Femtomole(10 15 mol)

FNTD Fluorescentnucleartrackdetector

FOM Figureofmerit

fov Fieldofview

fp Fissionproducts

FPGA Fieldprogrammablegatearray

FSA Flowscintillationanalysis

FS-DPM Full-spectrumdisintegrationsperminute(method)

FT Fissiontrack

FTD Fissiontrackdating

FT-ICR Fouriertransform ioncyclotronresonance

FTIR Fouriertransforminfraredspectroscopy

FWHM Fullwidthathalf-maximum

FWT Freewatertritium

FWTM Fullwidthat10thmaximum

g Gram,gluon

G# G-number(Grau’s-number,quench-indicatingparameter)

g Gammaradiation

G-8 GroupofEightCountries(IAEAMemberStates)

GBq Gigabecquerels(109 Bq)

GC Gaschromatography

GC/MS Gaschromatography/massspectrometry

GCR Galacticcosmicrays

GD Glowdischarge

GDMS Glowdischargemassspectrometry

GEANT GeometryANdTrackingMonteCarlocode

Ge(Li) Lithium-compensatedgermanium

GEM Gaselectronmultiplier

GEOSECS GeochemicalOceanSectionsProgramme

GEOTRACES InternationalStudyonMarineBiogeochemical CyclingofTraceElementsandtheirIsotopes

GERDA GERmaniumDetectorArray

GeV Gigaelectronvolts(109 eV)

GHz Gigahertz(109 Hz)

GICNT GlobalInitiativetoCombatNuclearTerrorism

GIS GeographicalInformationSystem

GISP GreenlandIceSheetProjects

GLOMARD GlobalMarineRadioactivityDatabase

GLP Goodlaboratorypractice

GM Geiger Müller

GM-APD Geiger-modeavalanchephotodiode

GPa Gigapascal

GPC Gasproportionalcounting(counter)

GPD Geometricprogressiondecrease

CPG Coplanargrid

GPS Globalpositioningsystem

GRB Gammarayburst

GS-20 Glassscintillator

GSD Geometricstandarddeviation

GSI GesellschaftfürSchwerionenforschungmbH,Darmstadt, Germany

GSO:Ce Cerium-activatedgadoliniumorthosilicate(Gd2SiO5:Ce)

GUM GuidetotheExpressionofUncertaintyinMeasurement

GW Groundwater,gatewidth

GWe Gigawattelectrical(109 We)

Gy Gray(1Gy ¼ 1J/kg ¼ 6.24 1012 MeV/kg)

GZK Greisen-Zatsepin-Kuz ’minprocessof proton-photon interactions

h Hours

h Plank’sconstant(6.626 10 34 Js),hours

h Plank’sconstantreduced(h/2p)

H # Horrock’snumber(quenchindicatingparameter)

HBT 2-(2-Hydroxyphenyl)-benzothiazole

HDE Heatdistributionerror

HDEHP Bis(2-ethylhexyl)phosphoricacid

HDPE High-densitypolyethylene(moderator)

HEDPA 1-Hydroxyethane-1,1-diphosphonicacid

HEN Highefficiencynebulizer

HEP High-energyparticle

HEPES N-2-hydroxyethylpiperazine-N 0 -2-ethanesulfonicacid

HERA-BRICH ParticledetectoroftheHadron-Elektron-Ringanlage,Hamburg,Germany

HERM High-energyradiomonitor

HEU Highlyenricheduranium

HEX-ICP-MS HexapolecollisioncellICP-MS

HEX-ICP-QMS Hexapolecollisioncellquadrupolemass spectrometry

3HF 3-Hydroxy flavone

hg Hectograms(102 g)

h-index Hirshindex

HIBA Hydroxy-i-butyricacid

HKG Housekeepinggene

HLNC High-levelneutroncoincidencecounter

HLW High-levelwaste

HPB High-pressureBridgman

HPGe High-puritygermanium

HPIC High-performanceionicchromatography

HPLC High-performanceliquidchromatography

HPMT Hybridphotomultipliertube

HRAS High-resolutionalphaspectrometry

HRGS High-resolutiongammaspectrometry

HR-ICP-MS High-resolutioninductivelycoupledplasmamass spectrometry

HT Hightension

HV Highvoltage

HWHM Halfwidthathalf-maximum

HWZPR Heavywaterzeropowerreactor

Hz Hertz(cyclespersecond)

iin Currentpulse

IAEA InternationalAtomicEnergyAgency,Vienna

IAEA-EL IAEAMarineEnvironmentLaboratory,Monaco

IC Internalconversion,ionchromatography

ICC Icecondenserchamber

IC-ICP-MS Ionchromatography inductivelycoupledplasmamass spectrometry

IC# Isotopecenternumber

IceCube NeutrinoObservatory,SouthPole

IceTop SurfacearrayofstationsforIceCube

ICF Inertialconfinementfusion

ICP Inductivelycoupledplasma

ICP-CC-QMS Quadrupoleinductivelycoupledplasmamassspectrometrywithhexapolecollisioncell

ICP-FT-ICR-MS InductivelycoupledplasmaFouriertransform ioncyclotronresonancemassspectrometry

ICP-MS Inductivelycoupledplasmamassspectrometry

ICP-OES Inductivelycoupledplasmaopticalemissionspectrometer(spectra)

ICP-QMS Inductivelycoupledplasmaquadrupolemass spectrometry

ICP-SFMS Double-focusingsector fieldinductivelycoupled plasmamassspectrometry

ICRP InternationalCommissiononRadiologicalProtection

ICRU InternationalCommissiononRadiationUnitsand Measurements

IDori.d. Innerdiameter,innerdetector

IDA Isotopedilutionanalysis

IDMS Isotopedilutionmassspectrometry

ID-TIMS Isotopedilutionthermalionizationmassspectrometry

IE Ionexchange

IEC InternationalElectrotechnicalCommission,inertialelectrostatic confinement

IECF Inertialelectrostaticconfinementfusion

IEEE InstituteofElectricalandElectronicsEngineers

IEF Isoelectricfocusinggelelectrophoresis

IFIN-HH HoriaHulubeiNationalInstituteofPhysicsandNuclear Engineering,Romania

IGPC Internalgasproportionalcounting

IL-5 Interleukin-5

IMS InternationalMonitoringSystemoftheCTBT in. Inch ¼ 2.54cm ¼ 25.4mm

INES InternationalNuclearandRadiologicalEventScale

INFN InstitutoNazionalediFisicaNucleare(Italy)

Acronyms,Abbreviations,andSymbols

INGE InternationalNobleGasExperiment

INP InstituteofNuclearPhysics,Tirana,Albania

IN2P3 InstitutNationaldePhysiqueNucléaireetdePhysiquedes Particules,France

INSERM Institutnationaldelasantéetdelarecherchémédicale. France

I/O Input/output

IPA Instrumentperformanceassessment,isopropylalcohol

IPRI LaboratoirePrimairedesRayonnementsIonisants,France

IPT Intramolecularprotontransfer

IR Infrared(spectroscopy)

IRA InstitutUniversitairedeRadiophysique,Lausanne,Switzerland

IRMM InstituteforReferenceMaterialsandMeasurements,Geel

IRMS Isotoperatiomassspectrometry

IRSN InstituteofRadiationProtectionandNuclearSafety,France

IS Internalstandard

ISH Insitu hybridization

ISO InternationalOrganizationforStandardization

ISOCS In-Situobjectcalibrationsoftware

IS-SCR Internalstandardandsamplechannelsratio

IT Isomericorinternaltransition

ITER InternationalThermonuclearExperimentalReactor

ITU InstituteforTransuraniumElements,Europe

ITWG NuclearForensicsInternationalTechnicalWorkingGroup

IUPAC InternationalUnionofPureandAppliedChemistry

IUPAP InternationalUnionofPureandAppliedPhysics

J Joule ¼ 1Nm ¼ 1kgm2/s2 ¼ 1Ws

JAERI JapanAtomicEnergyResearchInstitute

JET JointEuropeanTorusreactor

JFET Junction fieldeffecttransistor

JCGM JointCommitteeforGuidelinesinMetrology

JINR JointInstituteforNuclearResearch,Dubna,MoscowOblast

JRC JointResearchCentre(ofEuropeanCommission)

K particlekineticenergy

KD , K , K0 Kaonsor K mesons

K DegreesKelvin

ka Kiloannum(103 years)

KamLAND KamiokaLiquidScintillatorAnti-NeutrinoDetector, Japan

KATRIN KarlsruheTRItiumNeutrinoexperiment

kBq Kilobecquerels(103 Bq)

KCFC Potassiumcobaltferrocyanide

kcps Kilocountspersecond

KCRV Keycomparisonreferencevalue

KEK TheHighEnergyAcceleratorResearchOrganization,Japan

keV Kiloelectronvolts(103 eV)

kg Kilograms

kGy Kilogray

kHz Kilohertz

km.w.e km-water-equivalent

KNN knearestneighboralgorithm

KRISS NationalMetrologyInstituteofKorea

KSTAR KoreaSuperconductingTokamakAdvancedResearch fusionreactor

kt Kilotons

kV Kilovolts(103 V)

kW Kilowatts(103 W)

ky Kiloyears(103 y)

L,l Liters

LA Linearanode

LAAPD Largeareaavalanchephotodiode

LAB Linearalkylbenzene,dodecylbenzene

LA-ICP-MS Laserablationinductivelycoupledplasmamass spectrometry

LA-MC-ICP-MS LaserablationmultiplecollectorICP-MS

l Wavelength,decayconstant,microliter(10 6 L),freeparameter

lnr Nonrelativisticwavelength

lr Relativisticwavelength

LAMMA Lasermicroprobemassanalysis

LAN Localareanetwork

LANL LosAlamosNationalLaboratory

LAr Liquidargon

LARA laser-assistedisotoperatioanalysis

LAW Low-activitywaste

LBD Ligand-bindingdomain

LBNL LawrenceBerkeleyNationalLaboratory

LC Liquidchromatography

LCDW Lowercircumpolardeepwater

LCMS Liquidchromatographymassspectrometry

LD50 Medianlethaldose

LED Light-emittingdiode

LEGE Low-energygermaniumdetector

LENA Low-energyneutrinoastrophysicsdetector

LET Linearenergytransfer

LEU Lowenricheduranium

LHCbRICH LargeHadronColliderbeautyexperimentdetectorat CERN

LHD LargeHadronCollider

LiI(Eu) Europium-activatedlithiumiodide

LIMS LaboratoryInformationManagementSystem

LINACorlinac Linearaccelerator

LIST Laserionsourcetrap

LL Lowerlevel

LL-BSS Large 6LiI(Eu)Bonnerspherespectrometer

LLC Liquid(mobile) liquid(onsolidphase)chromatography

LLCM Low-levelcountmode

LLD Lowerlimitofdetection,lowerleveldiscriminator

LLE Liquid liquidextraction

LLNL LawrenceLivermoreNationalLaboratory

LLR Long-livedradionuclide

LMD Lasermicrodissection

LM-OSL Linearmodulationopticallystimulatedluminescence

LN2 Liquidnitrogen

LNE LaboratoireNationaldeMétrologieetdeE’ssais,France

LNGS LaboratoriNazionalidelGranSasso,Italy

LNHB LaboratoireNationalHenriBecquerel,Saclay

LNMRI NationalMetrologyLaboratoryofIonizingRadiation, Brazil

LOD Limitofdetection

LOV lab-on-valve(system)

lp Linepairs

LPB Low-pressureBridgman

LPI low-pressurecascadeimpactor

LPRI LaboratoirePrimairedesIonizants,Paris

LPS Lipopolysaccharide

LRAD Long-rangealphadetector

LS Liquidscintillation,liquidscintillator, “linear-to-square” curve

LSA Liquidscintillationanalysis(analyzer)

LSC Liquidscintillationcounting(counter)

LSO Cerium-activatedlutetiumoxyorthosilicate(Ce:Lu2SiO5)

LSS Liquidscintillationspectrometer

LTC Live-timecorrection

LuAP Cerium-activatedlutetiumaluminumperovskite(Ce:LuAlO3)

LY Lightyield

LXe Liquidxenon

M Molar(solutionconcentration)

m Particlemass

m0 Particlerestmass

mr Speed-dependentparticlemass

m Mass,meters,minutes

mA Milliampere(10 3 ampere)

Ma Megayear(106 years)

mAbs Monoclonalantibodies

MACS Magneticallyassistedchemicalseparations

MALDI Matrix-assistedlaserdesorption/ionization

MAPD Micropixelavalanchephotodiode

MAPMT Multianodephotomultipliertube

MARG Microautoradiography

MARIS Marineinformationsystem

MARSSIM Multi-AgencyRadiationSurveyandSiteInvestigation Manual

MATLAB MATrixLABoratory(numericalcomputingandprogramminglanguage)

mb Millibarn(10 3 b)

mBq Millibecquerels(10 3 Bq)

MBq Megabecquerels(106 Bq)

mCi Millicurie(10 3 Ci) ¼ 2.22

MBq

MC Multipleioncounting

MCA Multichannelanalyzer

MCF Movingcurve fitting

MC-ICP-MS Multipleioncollector-ICP-MS

MCN Microconcentricnebulizer

MCNP MonteCarloN-Particlecode

MCNP-CP MonteCarloN-Particle-CorrelatedParticlecode

MCP Microchannelplate

MCP-PM Microchannelplatephotomultiplier

MC-TIMS Multiplecollectorthermalionizationmassspectrometry

MD Moleculardynamics

MDA Minimaldetectableactivity

MDOA Methyldiooctylamine

METAS FederalInstituteofMetrology,Berne-Wabern, Switzerland

METEPC Multielementtissue-equivalentproportionalcounter

MeV Megaelectronvolts

MeVee Electronequivalentenergy

MHSP Microholeandstripplate(imager)

MHz Megahertz(106 Hz)

MIBK Methylisobutylketone

MICAD MicrochannelArrayDetector

MICM Modifiedintegralcountingmethod

MICROMEGAS Micromeshgasdetector

mg Milligram(10 3 g)

mGy Milligray

MIBK Methylisobutylketone

min Minutes

mK MilliKelvin(10 3 K)

mL,ml Milliliter(10 3 L)

MLR Multiplelinearregression

mM Millimolar(10 3 M)

mm Millimeter(10 3 m)

MM Magneticmonopoles

MMAD Massmedianaerodynamicdiameter

MMC Metallicmagneticcalorimeter

mmol Millimole(10 3 mol)

MNP Magneticnanoparticle

mol Mole(gram-molecularweight)

MU Megaohm(106 U)

MOX Mixedoxidefuel

MP Multipurpose

M-P MandelandPaulemean

MPa Megapascal(106 Pa)

MPGD Micropatterngasdetector

MPPC Multipixelphotoncounter

mrad Millirad(1mrad ¼ 10 mGy)

MRI Magneticresonanceimaging

mRNA MessengerRNA

MS Massspectrometry

ms,msec Milliseconds(10 3 s)

MSAP Microscalesampleautomationplatform

MSB Methylstyrylbenzene

MSC Microplatescintillationcounting

MSD Meanstandarddeviation

MSE Multisiteevents

MSGC Microstripgascounter

MSI Massspectrometryimaging

MS/MS Tandemmassspectrometry

mSv Millisievert

MW Megawatt(106 W)

Mt Megaton(106 t)

MTO Magnetoopticaltrap

m D , m Muons

m Attenuationcoefficient

mA Microampere(10 6 A)

mCi Microcurie(10 6 Ci) ¼ 2.22 106 dpm ¼ 3.7 104 dps ¼ 37kBq

mg Microgram(10 6 g)

mL Microliter(10 6 L)

mm Micrometer(10 6 m)

mPIC Micropixelgaschamber

ms, msec Microseconds(10 6 s)

m-XANES MicrofocusedX-rayabsorptionnearedgestructure

m-XRF MicrofocusedX-ray fluorescence

MEK Methylethylketone

MW Megawatt(106 W)

MWe Megawattelectrical

m.w.e. Meterwaterequivalent

MWPC Multiwireproportionalchamber

MV Megavolts(106 V)

MVC Multivariatecalibration

N Newton ¼ 1kgm/s2

N Neutronnumber

n Neutron

n Indexofrefraction

NA Avogadro’sconstant(6.022 1023/mol)

nA Nanoampere(10 9 A)

NAA Neutronactivationanalysis

NAC N-acetylcystein

NADW NorthAtlanticDeepWater

NaI(Tl) Thallium-activatedsodiumiodide

NARC NeutrinoArrayRadioCalibration

NASA NationalAeronauticsandSpaceAdministration,Washington,D.C.

NBL NewBrunswickLaboratoryoftheUSDOE

NBR Naturalbackgroundrejection

NBS NationalBureauofStandards(nowNIST)

NC Neutralcurrent(interaction)

NCD Neutralcurrentdetector

nCi Nanocurie(10 9 Ci)

NCM Normalcountmode

NCRP NationalCouncilonRadiationProtectionand Measurements

NDA Nondestructiveanalysis

NEA NuclearEnergyAgencyoftheOECD

Ne/h Numberofelectron holepairs

NEMO NauticEnvironmentMarineObservatoire

NE-OBT Nonexchangeableorganicallyboundtritium

NF-LA-ICP-MS Near- fieldlaserablationinductivelycoupled plasmamassspectrometry

ng Nanograms(10 9 g)

NHMRC NationalHealthandMedicalResearchCouncil,Australia

NIDW NorthIndianDeepWater

NIM Nuclearinstrumentmodule

NIMH Nickelmetalhydride

NIST NationalInstituteofStandardsandTechnology,Gaithersburg

nm Nanometer(10 9 m)

NMI NationalMetrologyInstitute

NMM Neutronmoisturemeter

NMR Nuclearmagneticresonance

NNDC NationalNuclearDataCenter

NOI Nuclideofinterest

NORM Naturallyoccurringradioactivematerials

NP Nanoparticle

NPD 2-(1-Naphthyl)-5-phenyl-1,3,4-oxadiazole

NPE Nonylphenolethoxylate

NPL NationalPhysicalLaboratory,UK

NPO 2-(1-Naphthyl)-5-phenyloxazole

NPP Nuclearpowerplant

NRC UnitedStatesNuclearRegulatoryCommission

n Neutrino,photonfrequency,particlevelocity

n Antineutrino

0nbb Neutrinolessdouble-betadecay

2nbb Two-neutrinodouble-betadecay

nM Nanomolar(10 9 M)

nm Nanometer(10 9 m)

NMM Neutronmoisturemeter

NMR Nuclearmagneticresonance

NNDC NationalNuclearDataCenter,BNL,Upton,NewYork

NNFL Nationalnuclearforensicslibrary

NORM Naturallyoccurringradioactivematerial

NPT NonproliferationTreaty

NRC NuclearRegulatoryCommission

ns,nsec Nanosecond(10 9 s)

NSTAR Neutronsandwichtransmitter/activation- g radiator

NT200 Neutrinotelescope,LakeBaikal,Siberia

NTD-Ge Neutrontransmutation-dopedGe

N-TIMS Negativeionthermalionizationmassspectrometry

NTP Normaltemperatureandpressure

NTS Nevadatestsite

NU Naturaluranium

NUDAT NuclearDatabaseoftheNNDC

NWT Nuclearweaponstest

N/Z Neutron/protonratio

OC Organiccarbon

ODoro.d. Outerdetector,outerdiameter

OECD OrganizationforEconomicCooperationandDevelopment

OES Opticalemissionspectrometry

OFHC Oxygen-freehighthermalconductivity

OGE Optogalvaniceffect

OHM NationalOfficeofMeasurement,Budapest

OLLSC Onlineliquidscintillationcounting

OM Opticalmodule

OSL Opticallystimulatedluminescence

OTPC Opticaltimeprojectionchamber

P Parityquantumnumber

p Particlemomentum

p,pD Proton

Pa Pascal ¼ 1N/m2 ¼ 1kg/m,s 2

PAC Pulseamplitudecomparison(comparator)

PADC Polyallyldiglycolcarbonate

PAGE Polyacrylamidegelelectrophoresis

PAN Polyacrylonitrile

PANDA Particlesandnondestructiveanalysis

PAW PhysicsAnalysisWorkstation

PAZ Partialannealingzone

PBBO 2-(40 -Biphenylyl)-6-phenylbenzoxazole

PBD 2-Phenyl-5-(4-biphenylyl)-1,3,4-oxadiazole

PBO 2-(4-Biphenylyl)-5-phenyloxazole

PBq Petabecquerel(1015 Bq)

PBS Phosphatebufferedsaline

PC Proportionalcounter(ing),personalcomputer,paperchromatogram,polycarbonate

PCA Principalcomponentanalysis

PCB Polychlorinatedbiphenyl

pCi Picocurie(10 12 Ci)

PCR Principlecomponentregression

PD Photodiode

PDA Pulsedecayanalysis

PDB PeeDeeBelemnite(standard)

PDD Pulsedecaydiscriminator

PE Phosphateester,polyethylene

PEC Powerandeventcontroller

PENELOPE PENetrationandEnergyLossofPositronsandElectronsMonteCarlocode

PERALS PhotonElectronRejectingAlphaLiquidScintillation

PET Positronemissiontomography,polyethyleneterephthalate

PETAC Pentaerythritoltetrakisallylcarbonate

PeV Petaelectronvolts(1015 eV)

pF Picofarad(10 12 F)

PF Polarfront

PFA Perfluoroalkoxy

PFZ Polarfrontalzone

pg Picogram(10 12 g)

PGA Pulsegradientanalysis

ph Photons

PHA Pulseheightanalysis

PHITS Particleandheavyiontransportcodesystem

PHOSWICH PHOSphorsandWICH(detector)

p Piconstant ¼ 3.14159

pD , p , p 0 Pionsorpimesons

PI Polyimide,pressurizedinjection

PID Particleidentification

PIM Parallelionizationmultiplier

PIMS Positive-ionmassspectrometry

PIPS,PIPSi Passivatedimplantedplanarsilicon

PIXE Proton-inducedX-rayemission

PKC ProteinkinaseC

PLC Proportionallongcounter

PLI Pulselengthindex

PLS Partialleastsquares

PLS-DA Partialleastsquaresdiscriminantanalysis

PLSR Partialleastsquaresregression

PM Photomultiplier,particulatematter

PMM Power-moderatedweightedmean

PMBP 1-Phenyl-3-methyl-4-benzoylpyrazolone-5

pMC Percentmoderncarbon

PMMA Polymethylmethacrylate

PMP 1-Phenyl-3-mesityl-2-pyrazoline

PMT Photomultipliertube

PN Pneumaticnebulizers

PNNL PacificNorthwestNationalLaboratory

PNX PacificNorthwesteXtractionsystem

POM Polyoxymethylene

POPOP 1,4-Bis-2-(5-phenyloxazolyl)benzene

PPAC Parallelplateavalanchechamber

ppb Partsperbillion

PPC P-typepointcontact

PPD 2,5-Diphenyl-1,3,4-oxadiazole

PPE Personalprotectiveequipment

ppm Partspermillion

ppmw Partspermillionbyweight

PPO 2,5-Diphenyloxazole

PS Plasticscintillator,polystyrene

ps Picosecond(10 12 s)

PSA Pulseshapeanalysis

PSD Pulseshapediscrimination

PSf Plasticscintillatorfoils

psi 6.895 103 Pa ¼ 68.95 10 3 bar ¼ 51.715torr

PSL Photostimulablelight(orluminescence)

PSm Plasticscintillatormicrospheres

PSPC Position-sensitiveproportionalcounter

PSr Plasticscintillatorresins

PSUP PhotomultiplierSUPportstructure

P/T Peak-to-totalratio

PTB Physikalisch-TechnischeBundesanstalt,Braunschweig

PTBT PartialTest-BanTreaty

PTFE Polytetrafluoroethylene

P-TIMS Positiveionthermalionizationmassspectrometry

PTP p-Terphenyl

PUR Pileuprejector

PUREX PlutoniumURaniumEXtraction

PVC Polyvinylchloride

PVD Physicalvapordeposition

PVDF Polyvinyldifluoride

PVT Polyvinyltoluene

PWR Pressurizedwaterreactor

PXE Phenyl-ortho-xylylethane

Q Q valueofnuclearreactions

QA Qualityassurance

QC Qualitycontrol

QC-CPM Quench-correctedcountrate

QCD Quantumchromodynamics

QD Quadrupole

QDC Charge-to-digitalconverter

QE Quantumefficiency

QIP Quench-indicatingparameter

QWBA Quantitativewhole-bodyautoradiography

R Roentgen(1R ¼ 2.58 10 4 C/kg)

RAC Radonactivityconcentration

rad Radiation-absorbeddose(1rad ¼ 10mGy ¼ 100erg/g)

RAD Radon-in-airmonitor

RAST Radioallergosorbenttest

RBE Relativebiologicaleffectiveness

RDC Remotedetectorchamber

RDD Radiologicaldispersaldevice(“dirtybomb”)

RE Recoveryefficiency

REE Rareearthelements

REFIT Radialelectron fluencearoundiontracks

REGe Reverse-electrodecoaxialGedetector

REL Restrictedenergyloss

rem Roentgenequivalentmammal(1rem ¼ 10mSv)

RF Radiofrequency

RF Feedbackresister

RFQ Radiofrequencyquadruple

RH Relativehumidity

r Density(gcm 3),neutronabsorptioncrosssection,resistivity

RIA Radioimmunoassay

RICE RadioIceCherenkovExperiment

RICH RingimagingCherenkov(counters/detectors)

RIMS Resonanceionizationmassspectrometry

RIS Resonantionization

RM Referencematerial

RMS Rosettemultibottlesamplers

RMT Radiometrictechnique

RNA Ribonucleicacid

Ro5 RingofFive(Europeanradionuclidemonitoringlabs)

ROI Regionofinterest(spectral)

ROSEBUD TheRareObjectsSearchwithBolometersUndergrounDcollaboration

ROV Remotelyoperatingvehicle

RPC Resistiveplatechamber

RPH Relativepulseheight

RSC Renewableseparationcolumn,relativesensitivitycoefficient

RSD Relativestandarddeviation

RSF Relativesensitivityfactor

RST Reversespectraltransform

s Seconds

SAF Subantarcticfront

SAH S-adenosyl-homocysteine

SalSa Saltsensorarray

SAM Standardanalysismethod, S-adenosyl-methionine

SAMAD Surfaceareameanaerodynamicdiameter

SAS Semiconductor a-spectrometry

SBD Surfacebarrierdetector

SCA Singlechannelanalyzer

SCC Softwarecoincidencecounting,squamouscellcarcinoma

SCI ScienceCitationIndex

SCR Samplechannelsratio,solarcosmicrays

SCX Strongcationexchange

SD Standarddeviation

SDCC Simplifieddigitalchargecomparison

SDD Silicondriftdetector

SDP Silicondriftphotodiode

SDT Shareddeadtime

SE Singleescape,secondaryelectron

sec Seconds

SEC Sizeexclusionchromatography

SEGe StandardelectrodecoaxialGedetector

SEM Scanningelectronmicroscopy

SF Spontaneous fission

SFC Supercritical fluidextraction

SFD Scintillation fiberdetector

SF-ICP-MS Sector field inductivelycoupledplasmamass spectrometry

SFU Stacked filterunit

SGD Submarinegroundwaterdischarge

SHE Superheavyelements

SHOTS SouthernHemisphereOceansTracerStudies

SHRIMP Sensitivehighmassresolutionionmicroprobe

SI InternationalSystemofUnits,sequentialinjection,spray ionization

SIA Sequentialinjectionanalysis

SIE Spectralindexoftheexternalstandard

s Reactioncrosssection,thermalneutroncrosssection

Si(Li) Lithium-compensatedsilicon

SIMS Secondaryionizationmassspectrometry

SiPIN Siliconp-i-ndiode

SiPM Siliconphotomultiplier

SIR InternationalReferenceSystem(SystèmeInternationalede Référence)

SI-RSC Sequentialinjectionrenewableseparationcolumn

SIS Spectralindexofthesample

SJD Siliconjunctiondetector

SLAC StanfordLinearAcceleratorCenter

SLIM SystemforLaboratoryInformationManagement

SLM Standardlaboratorymodule

SLSD Scintillator-Lucitesandwichdetector

SMAD Surfacemedianaerodynamicdiameter

SMDA Speci ficminimumdetectableactivity

S/N Signal-to-noise

SNAP SystemsNuclearAuxiliaryPower

SNICS SourceofNegativeIonsbyCesiumSputtering

SNF Spentnuclearfuel

SNM Specialnuclearmaterial

SNMS Secondaryneutralmassspectrometry

SNO SudburyNeutrinoObservatory,Canada

SNR Signal-to-noiseratio

SNS Spallationneutronsource

SNTS Semipalatinsknucleartestsite,EasternKazakhstan

SOA Secondaryorganicaerosol

SOI Silicon-on-insulator

SOP Standardoperatingprocedure

SPA Scintillationproximityassay

SPC Singlephotoncounting

SPD Self-powereddetector

SPE Singlephotonevent,solidphaseextraction,solidpolymer electrolyte

SPECT Singlephotonemissioncomputedtomography

SPME Solidphasemicroextraction

SQM Strangequarkmatter

SQP(E) Spectralquenchparameteroftheexternalstandard

SQP(I) Spectralquenchparameteroftheisotope

SQS Self-quenchedstreamer

SQUID Superconductingquantuminterferencedevice

SR Superresolution,synchrotronradiation

sr Steradian

SRAM Staticrandomaccessmemory

SRM Standardreferencematerial

SRS SavannahRiverSite

SSB Siliconsurfacebarrierdetector

SSDD Segmentedsilicondriftdetector

SSE Singlesiteevents

SSM Standardservicemodule,selectivescintillatingmicrosphere

SSNTD Solid-statenucleartrackdetector

ST Supersensitive

STD Shareddeadtimeconcept

STE Self-trappedexcitation

STF Subtropicalfront

STM Scanningtunnelingmicroscope

STNTD Solid-statenucleartrackdetection(detectors)

STP Standardtemperatureandpressure

STS Semipalatinsktestsite

STUK RadiationandNuclearSafetyAuthority,Finland

Sv Sievert(1Sv ¼ 1Gy ¼ 100rem ¼ 1J/kg)

SVOC Semivolatileorganiccarbon

t Ton(s)

t½, T½ Half-life

T Particlekineticenergy

T Tritium,tesla ¼ 1Vs/m2

TAEK TurkishAtomicEnergyAuthority

TALSPEAK TrivalentActinide LanthanideSeparationbyPhosphorusExtractantsandAqueousKomplexantsprocess

TAR Tissue airratio

TAT Targetedalphatherapy

TBP Tributylphosphate

TBq Terabecquerel(1012 Bq)

TC Totalcarbon

TCA Trichloroaceticacid

TCS Truecoincidencesumming

TD Timediscriminator

TDCR Triple-to-doublecoincidenceratio(method)

TDS Totaldissolvedsolids

TEA Triethylamine

TEM Transmissionelectronmicroscopy

TENORM Technologicallyenhancednaturallyoccurringradioactivematerials

TEPC Tissue-equivalentproportionalcounter

TES Transitionedgesensor

TBAB Tetrabutylammoniumbromide

TeV Teraelectronvolts(1012 eV)

Tf Transferfactor(radionuclide)

TFTR Tokamakfusiontestreactor

TFWT Tissue-freewatertritium

THGEM Thickgaselectronmultiplier

THM Travelingheatermethod

tHMy 1 Metrictonsofheavymetalperyear

TI Transferinstrument

w Approximately

TIMS Thermalionizationmassspectrometry

TINCLE Track-in-cleavage(technique)

TINT Track-in-track(technique)

TIOA Triisooctylamine

TL Thermoluminescence

TLA Trilaurylamine

TLC Thin-layerchromatography(chromatogram)

TLD Thermoluminescencedosimeter

TMA Trimethylamine

TMI ThreeMileIsland

TMOS Tetramethoxysilane

TMS Tetramethylsilane

TNOA Tri-n-octylamine

TNSA Targetnormalsheathacceleration

TNT Trinitrotoluene

TOA Topoftheatmosphere,trioctylamine

TOF Time-of- flight

TOP Time-of-propagation

TOPO Trioctylphosphineoxide

torr 133.3224Pa

TP p-Terphenyl

TPPS Triphenylphosphinesulfide

TR Tritiumsensitive

TRACOS Automaticsystemfornucleartrackevaluations

TRE 12-O-Tetradecanoylphorbol-13-acetateresponsiveelement

TRI Toxicreleaseinventory

TR-LSC Time-resolvedliquidscintillationcounting

TR-PDA Time-resolvedpulsedecayanalysis

TRPO Trialkylphosphineoxide

TSC Tasksequencecontroller

TSCA ToxicSubstanceControlAct

TSEE Thermallystimulatedexoelectronemission

tSIE Transformedspectralindexoftheexternalstandard

tSIS Transformedspectralindexofthesample

TSP Totalsuspendedparticle

TTA Tenoyl-tri- fluoroacetone

TTL Transistor transistorlogic

TU Tritiumunit(0.119Bq 3Hkg 1 H2Oor7.14DPMof 3HL 1 H2Oorratioof1atom 3H:1018 atomsof 1H)

u Atomicmassunit(1/12massof 12C ¼ 1.66054 10 27 kg),up quark

u Antiupquark

u Particlespeed

unr Nonrelativisticparticlespeed

ur Relativisticparticlespeed

UCN Ultracoldneutrons

UHE Ultrahighenergy

UL Upperlevel

ULB Ultralowbackground

ULD Upperleveldiscriminator

ULEGE Ultralow-energyGe

UNSCEAR UNScienti ficCommitteeontheEffectsofNuclear Radiation

UOC Uraniumoreconcentrate

U.S.A.E.C. USAtomicEnergyCommission(nowNRC)

U.S.DOE USDepartmentofEnergy

USEPA USEnvironmentalProtectionAgency

USN Ultrasonicnebulizers

UV Ultraviolet

V Volts

V0 Stepvoltage

VAX DigitalEquipmentCorporationtradename

VCCI Variableconfigurationcascadeimpactor

VHPLC Very-high-pressureliquidchromatography

VMEbus VersaModuleEuropabus

VSiPMT Vacuumsiliconphotomultipliertube

VUV Vacuumultraviolet(spectralregion)

VYNS Vinylacetateandvinylchloridecopolymer

W Watt(1W ¼ 1J/s)

w/w Weight/weight

WAK Wiederaufarbeitungsanlage(nuclealfuelreprocessingplant), Karlruhe

WBA Whole-bodyautoradiography

WBEC Weakbaseextractionchromatography

WCVB Wasteconcentrationvaporbody

WDS Wavelengthdispersivespectrometer

WDX WavelengthdispersiveX-ray(analyzer)

WHO WorldHealthOrganization

WIMP Weaklyinteractingmassiveparticle

WIPP WasteIsolationPowerPlant

WM Weightedmean

WMO WorldMeteorologicalOrganization,Geneva

WNO WorldNuclearOrganization,London

WOCE WorldOceanCirculationExperiment

WOMARS WorldwideMarineRadioactivityStudies

WRA Warfareradioactiveagent

WSF Wavelengthshifting fiber

WSOC Water-solubleorganiccarbon

wt% Weightpercent

XAF X-rayabsorptionspectroscopy

XANES X-rayabsorptionnearedgestructure

XRD X-raydiffraction

XRF X-ray fluorescence

XtRA Extendedrange

y Years

YAG:Yb Yb-dopedY3Al5O12

YAP:Ce Cerium-activatedyttriumaluminumperovskite (Ce:YAlO3)

YG Yttriumglass

YSi(Ce) Cerium-activatedyttriumsilicate

Z Atomicnumber

Z2 Averageatomicnumber

Zef or Zeff Effectiveatomicnumber

ZCH CentralAnalyticalLaboratory,Jülich

ZnS(Ag) Silver-activatedzincsulfide

Chapter1

Environmentalradioactivitymonitoring

RudolfEngelbrecht

Radiochemistry,SeibersdorfLaborGmbH,Seibersdorf,Austria;Currently-AustrianAgencyforHealthandFoodSecurity,GmbH,Vienna

Chapteroutline

I.Introduction:objectiveofenvironmentalmonitoring1

II.Typesofmonitoringprograms2

A.Routinemonitoring2

B.Emergencypreparedness3

C.Emergencymonitoring3

III.Fundamentalsofenvironmentalmonitoring4

A.Designofenvironmentalmonitoringprograms4

B.Samplingstrategies7

C.Samplepreparation9

D.Measurementandquantification10

E.Qualityassurance/qualitycontrol12

IV.Monitoringforinternalexposure14

A.Air14

1.Aerosols14

2.Onlineversusofflinesystems14

3.Gaseouseffluents15

B.Soil,sediments,vegetation,anddeposits17

1.Laboratorybased17

2.Insitugammaspectroscopy19

C.Water20

I.Introduction:objectiveof environmentalmonitoring

Asrecenthistory(e.g., IAEA,2011;UNSCEAR,2014; IAEA,2015;IRSN,2018)hasshowntoscientistsandthe public,transparentandcomprehensibledoseassessments, includingestimationofdosesascloselyaspossibletothose actuallyreceived,areafundamentalbasisofmanaging radiationprotection.Themostrealisticassessmentofdoses isobtainedbyusingmeasuredactivityconcentrationsin environmentalmediaandmeasurementsofexternaldose rates.Environmentalmonitoringprovidesdatathatpermit theanalysisandevaluationofradiation fieldsandradionuclideactivityconcentrationsinenvironmentalsamples relevanttohumanexposure,primarilyinair,drinking

1.Wastewater23

2.Rain23

3.Groundwater23

4.Surfacewater24

5.Drinkingwater24

D.Foodstuff24

1.Milk24

2.Meatandfish25

3.Vegetables,fruits,andcereals26

4.Mixeddiet26

V.Monitoringforexternalexposure26

A.Doseratemonitoring26

B.Dosemonitoring27

VI.Mobilemonitoring27

A.Aerialmeasurements27

B.Mobilelaboratories28 References32 Furtherreading40 RudolfEngelbrecht40

water,agriculturalproducts,andnaturalfoodstuffs,aswell asinbioindicatorsthatconcentrateradionuclidesandprovideameasureoftrendsinactivitylevels.

Thus,environmentalmonitoringcanbedescribedasthe expositionscenario basedsystematicsamplingandanalysisofair,water,soil,andbiotatoassessenvironmental conditions.Theobjectiveofsuchmonitoringistoobtain solidinformationthatwillserveasthebasisformeasures andpoliticaldecisions.Environmentalmonitoringassessmentscaninvolveestablishingbaselinequality,uncovering environmentaltrends,identifyinganyvariations,detecting newenvironmentalissues,anddeterminingtheprogress madetoachieveenvironmentalgoals.

Itisimportanttodistinguishthespecificaspectsof environmentalmonitoringdataobtainedundernormal

operatingconditionsfromthoseobtainedunderemergency conditionssincethecriteriaforevaluationarecompletely different.Undernormaloperatingconditions,dataareoften importantforthestatutorycontrolofreleases,butthelevels setaretoberelatedtohumantissuedoses.Incaseofa possibleaccidentalreleaseofradioactivity,themonitoring programaimsatansweringquestions,suchasHasan abnormalreleaseoccurred?Isthereactiontobetaken?and Whichremedialmeasuresshouldbebroughtabout?Thus, distinctioncanbemadebetweenthefollowingdifferent situations:

Routinemonitoring emergencypreparedness emergencymonitoring.

Foreachofthesesituations,thetypeofmonitoring programtobeestablishedisinfluencedbythesourceof radioactivityaswellasthescaleofthespatialandtemporal boundariesoftheenvironmenttobemonitored.Intheend, thegoalofmonitoringtheenvironmentalwaysistoobtain aprofoundsetofdatathatwillserveasabasisthatenables authoritiestoimplementmeasuresforeitherpreserving environmentalvaluesorpreventingtheirdeterioration.

II.Typesofmonitoringprograms

A.Routinemonitoring

Routinemonitoringprogramsaimatprovidinginformation ontheoveralldosereceivedbythepopulationatlarge.The setupofthemonitoringistheresultofanoptimization processinwhichtheavailabilityofmeasurementresources, therelativeimportanceofdifferentexposurepathways,and thelevelsofactivityanddoseinrelationtotheregulatory constraintsaretakenintoconsideration.Routineenvironmentalradiationmonitoringprogramsaredesignedspecificallyforeachfacility,takingintoaccountsite-specifi c factors,suchasclimate,sitelocation,thedesignofthe facilityanditsbarriers,geologicalandgeomorphological conditions,theoff-siteenvironment,andthepopulation distribution(IAEA,2004);theseprogramsareconducted bothonandoutsidethesitegivingrisetopotentialexposureofthepublictoradionuclidesintheenvironment.

Thelifecycleoftheroutineprogramsforenvironmental monitoringcomprisespreoperationalstudies,performedto establish “baseline” environmentalradiationlevelsand activityconcentrationsforthepurposeofsubsequently determiningtheimpactsofthesource,monitoringduring theoperationalphase,anddecommissioningorpostoperationmonitoring,performedaslongasthefacilityremainsapotentialsourceofradionuclidesthatcouldbe releasedtotheenvironment.Thecomplexityoftheprogramdependsontheidentities,quantities,andchemical andphysicalformsofradionuclidesthatmaybereleased andonthecharacteristicsofthemonitoredenvironment.

Onceamonitoringprogramhasbeenimplemented,it shouldbereviewedperiodicallytoensurethatitcontinually fulfi llstheobjectives.

Thepurposeofroutineenvironmentalmonitoringof airborneradioactivityistomonitordomesticandforeign facilities.Samplingofsoils,sediments,ordepositsserves asanindicatoroflong-termbuildupofradioactivityinthe environment.Measurementofingredientsinfoodstuffand waterisintendedtocompletethemonitoringprogramfor themigrationofradionuclidesinthefoodchainortocheck thecontaminationofthepublicatlargebyingestion. Monitoringlocationsforground-andsurfacewater,sediment,biota,andfoodstuffsarerelatedtothepotential migrationpathwaysdeterminedbypreoperationalstudies, andthefrequenciesofsamplingandmeasurementsare specifi edwithaviewtothetimelydetectionofsigni ficant changesinthereleaseratesandconcentrationsofradionuclidesandtheassociatedlevelsofhumanexposurein accordancewiththemonitoringobjectives.

Ithastobenotedthatradonmonitoring,whichforms themainexposuretoradioactivesourcestomembersofthe public(UNSCEAR,2000b),isnotimplementedinenvironmentalmonitoringprogramsbutconductedinspecial radonsurveyprograms(e.g., Friedmannetal.,2007).

Recentattentionhasbeenpaidtoradiationrisktothe peopleandtheenvironmentcausedbyexposuretoionizing radiationoriginatingfromnaturallyoccurringradioactive materials(NORMs).NORMstouchmanyaspectsoflife, startingwithoccupationalrisk,throughsome “contaminated” goods,leisureactivitiesincludingspavisitsand endingwithahugeamountofbulkwasteoftendumpedin ourvicinity(Kathren,1998; IAEA,2003).Suchalterations tothenaturalstateresultinanincrementofradiationriskto thepeopleaswellastononhumanbiota.Eachparticular typeofNORMdeterminesauniquescenarioofexposure usuallydifferingfromthosecausedbytheartificialradionuclides(Martinetal.,1997).

Themeasurementsmustbeadequatetodetermineradiationlevelsandtrendsofenvironmentalradioactivityat levelsjustdetectable,theparametersneededforsubsequent doseassessment,andcompliancewithnationalorinternationalstandards,constraints,orlimitslaiddownforthe protectionofthepopulation.Theselimitsandconstraints havevaluesthataretypicallylessthanexposuredueto naturalbackgroundradiation.Itis,thus,necessarytobe abletoidentifythesourceandtocircumscribetheextentof theradioactivematerialwithreasonableaccuracy.

Theobjectivesofroutinemonitoringprogramsareto l provideinformationtoassesstheadequacyofprotectionofthepublic, l meetrequirementsofregulatoryagencies, l verifyradionuclidecontainmentand/orwastemanagementpractices,

l meetlegalliabilityobligations,and l providepublicassurance.

B.Emergencypreparedness

Environmentalmonitoringmaybeconductedcontinuously toserveasadetectionsystem.Emergencypreparedness monitoringispartofastrategyfordataandinformation acquisition.Theoverallemergencystrategyincludestwo differentmodesofinformation,namely,(1)acquisition,as therearephysicalmeasurementsofrelevantdataonone handand(2)modelingofsituationsasatoolforinterpolationandextrapolationintimeandspacewheremeasurementdataaresparseontheotherhand.Itisusually moresatisfactorytomakeprovisionfordetectingan emergencyatitssource,butdetectionbyenvironmental monitoringmayberequiredinsomesituations,for example,nearfrontiers.Inanuclearaccident,theprompt monitoringofalargeareamaybeneeded.Forthisreason, automaticmeasuringstationsthatwillcontinuouslymeasurethedoserateintheenvironmentinstalledaroundmajor facilitiesarecapableofearlymonitoring.Continuously operatedoff-sitesystemshavetheadvantagethattheycan providerapidindication,notonlythatareleasetothe environmenthastakenplacebutalsoofthedirectionin whichthereleasedmaterialismoving.Off-sitesystemsdo havethedisadvantagethatthedetectorsneedtobe considerablymoresensitivethanifsitedneartothe possiblepointofreleaseandalsoneedtobeextremely reliableifduplicationistobeavoided.

Allofthesesystemsmayincludesuchdevicesascontinuousairsamplerscapableofmeasuringconcentrationsof airborneparticles,gaseousiodine,andanyotherradionuclides ofparticularconcernorwatersamplersforcontinuously scanningtheskyorbodiesofwaterforradiation.Ifafacility maycontainlargeamountsoftritium,somespecialdeviceto measuretritiummaywellbeinstalled.Ineachcase,the readingsbeingtelemeteredbacktoacontrolcenter.

Systemsintendedtodetectairbornereleasesbytheuse ofairsamplersintroducecomplextechniques,ifearly warningisrequired,becauseofthepresenceofthenatural decayproductsofradonandthoron.However,iftimecan beallowedforthesetodecay,asimplemeasurementof grossalpha-orgrossbeta-activitywillindicatewhether conditionsareseriouslyabnormal,althoughitmustalways berememberedthatgrossactivityresultscannotbeinterpretedintermsofhazardtoman.Theintendeduseofthe resultantinformationgivesguidancetothechoiceof monitoringprioritiesofsuchnetworks.

Theobjectivesofemergencypreparednessmonitoring areasfollows:

l Detectinganyrelease

l Predictingplumetrajectory

l Earlygovernmentandpublicinformation

l Planningofurgentpopulationprotection countermeasures

l Planningofagriculturalcountermeasuresandfood restrictions

C.Emergencymonitoring

Underemergencyconditions,environmentalmonitoringis themostinformativesourceofdata.Themeasurementsof theradiationlevelsorthelevelsofradioactivecontaminationarerequiredforrapidassessmentsofthesituationto informthoseresponsibleforcontrollingtheemergencyso thatcountermeasurescanbeputinhandasamatterof urgency.Monitoringinemergencysituationsisalsoa valuableandfundamentaltooltoverifytheeffectivenessof theactionstaken,forexample,evacuation,closingthe areas,useofstableiodinetablets,orbanningtheconsumptionoffoodstuffsorwaterfromdefinedareas.

Historyhasshownthattherequirementsfortheemergencymonitoringprogramandthenatureofrelevantdata willevolvewithtime.Theproceduresusedinemergency monitoringcanconvenientlybegroupedintothreephases, namely,detection,initialsurvey,andsubsequentsurveys.

Intheinitialemergencyresponsefollowinganaccident, whereinformationisrequiredwithaslittledelayas possible,rapidandrelativelysimple,albeitcrude,analytical methodsmaybepreferred.Thisusuallymeansalesser sensitivityandthusagreaterriskforerrors.However,in anyemergencysituation,itisimportantthattheresultscan beobtainedrelativelyquickly.Undermostconditions,this wouldamounttotheuseofdoserateandsurvey instruments.

Nevertheless,itshouldbeensuredthatthetypesofinstrumentsavailablearesuitableforthemeasurementpurposes.Forexample,ifthereleasedmaterialconsistsofonly tritiumorplutonium,thenthetypicalbeta gammasurvey instrumentsarenotofmuchuseandappropriatespecial instrumentsand/ormonitoringtechniquesshouldbeused.

Attheearlystageofanaccidentalatmosphericrelease, externalexposureincludesthecontributionofradiation fromtheplume.Thus,initialsurveysinthereleasephaseof theaccidentwillbefocusedonmeasurementsofcloud shineandonthesamplingofradionuclidesfromtheplume toassessdosesfromexternalexposureandinhalation.In thepostreleasephase,externalgammadoseratemeasurementsareattributablemainlytoradiationfromdepositson theground.Closetotheinstallation,thesemeasurements mayalsoincludethecontributionofradiationfromthe source.

Theexternaldoseratemeasurementsshouldbesupplementedassoonaspossiblebynuclide-speci ficanalysis ofrepresentativesamplesofmobileenvironmentalmedia andbiotathroughwhichradionuclidescouldmigrateand

reachthehumanhabitatandtherebyenterthehumanbody. Theseareatmosphericair,soilwaterandgroundwater, surfacewater,sediments,biota,andfoodstuffs.Groundwatershouldbemonitoredthroughmonitoringwells locatedatasuf ficientdeptharoundanddownstreamofthe facility.Thesemeasurementsmaybepursuedoverlonger periodsoftime.However,theassessmentoftheimpactof short-livednuclidessuchasiodineandrutheniumisotopes willbepossibleonlyifmeasurementsareperformedwithin afewweeksaftertheaccident.

Onceareleasehasceasedanddepositionlevelshave stabilized,nuclide-speci fi cdepositiondensitiesofall gamma-emittingradionuclidescanbeacquiredrapidlyby theuseof insitu gammaspectrometry.Nevertheless,laboratoryanalysisofalargenumberofsamplesofsoil, plants,water,agriculturalproducts,andnaturalfoodstuffs willbenecessarytosupplementthedataprovidedbythe in situ measurements.

Duringsuchsubsequentsurveys,italsowillbenecessarytoperformalargenumberofmeasurementsin differentmediainviewofanaccurateaposterioriassessmentoftheradiologicalimpact.Suchanassessmentfulfi lls theneedforadequateinformationofthepublicandmay servealsofurtherscienti ficinvestigations.

Thespeci ficobjectivesofemergencyradiationmonitoringintheenvironmentareto

l provideaccurateandtimelydataonthelevels,extent, anddurationofradiationandenvironmentalcontaminationwithradionuclides,

l providedetailofthephysicalandchemicalcharacteristicsofthehazard,

l assistinpreventingandcontrollingthespreadof contamination,

l assistdecision-makersontheimplementationofurgent, intermediate-,andrecovery-phasepopulationprotection countermeasures,agriculturalcountermeasures,and foodrestrictions

l provideinformationfortheprotectionofemergency andrecoveryworkers,

l provideinformationforthepubliconthedegreeofthe hazard,

l provideinformationneededtoidentifyanypeoplefor whomlong-termmedicalscreeningiswarranted,

l confirmtheefficiencyofprotectiveactions.

III.Fundamentalsofenvironmental monitoring

A.Designofenvironmentalmonitoring programs

Monitoringdesignprovidesanswerstothefollowingquestions:Whatwillbemonitored?Whataretheparameterstobe

measured?Howwilltheseparametersbemonitored?Where, when,andhowfrequentlywilltheparametersbemeasured.A monitoringprogramwillbeasvaluableandeffectiveasthe questionsidentifiedarespecificandfocusedandcanbeusedto guidethedevelopmentofamonitoringplan.

Tobeconsistentwiththeobjectivesandthedesignof anymonitoringprogram,onehastoconsidertypesand characteristicsofcriticalradionuclides,modesoftheir releasetotheenvironment,includingmechanismsforthe transferofradionuclidesthroughenvironmentalmedia, dispersionandreconcentrationmechanisms,andtheirseasonalvariation,existinglevelsofradionuclidesinthe environmentandtheirvariability,andexposurepathways thatmakethemajorcontributionstoindividualdoses, leadingtorequirementsintermsofsampling,sample treatment,measurementtechnique,andthelowerlimitof detectionorminimaldetectableactivity(IAEA,2005). Moreover,thenatureoftheenvironment,asthelocationof thefacilityinrelationtopopulationcentersandtheir compositionanddensities,surfacewaters,oceans, geological,meteorological,hydrological,andothernatural conditions,whichmightinfl uencethedispersalofreleased radionuclides,hastobetakenintoaccount.

Akeyfeatureindesigningenvironmentalmonitoringprogramsistheidentificationofpotentiallycriticalradionuclides, pathways,andgroupsorindividualspotentiallyaffected.

Intheconsiderationsofthelimitationofdosetothe generalpublicfromionizingradiation,dosestoindividuals, tocriticalgroups,andtothegeneralpopulationare distinguished.Asearlyas1965,the ICRP(1965) defineda criticalgroupasthat “whoseexposureishomogeneousand typicalofthatofthemosthighlyexposedindividualsinthe exposedpopulation.” In2006,theICRPintroducedthenew conceptofarepresentativeperson,definingitas “anindividualreceivingadosethatisrepresentativeofthemore highlyexposedindividualsinthepopulation” (ICRP, 2006).Theterm “representativeperson” describesanindividualwithcharacteristicsthatreflectthoseofthegroup thatreceivesthehighestdosesfromaparticularsource, knownastherepresentativepersonfortheradionuclidein question,andreplacesthe “averagememberofthecritical group” definedinpreviouspublicationsoftheICRP.Inany case,criticalgroupsortherepresentativepersonmaybein thevicinityoftheinstallationoratsomedistantlocation. Toassesstheannualeffectivedosesforbothcriticalgroup andrepresentativeperson,methodsrecommendedbythe InternationalAtomicEnergyAgency(IAEA,1982;IAEA, 2001)canbeused.Amoreconservativeconcepttoassess dosestothepublicisgiveninUSRegulatoryGuide1.109 andbasedontheindividualofmaximumdose(USNRC, 1977).

Routesfromasourceofradionuclidesand/orradiation toatargetindividualorapopulationthroughmediainthe environmentaredefinedintheexposurepathways.

Therearetwomaincategoriesofexposurepathway:

l Externalexposurefromradionuclidespresentintheair orinmaterialincorporatedin,forexample,soilsorsediment,determinedbydirectmeasurementsofexternal doseorbysoilanalysis.

l Internalexposurefromtheinhalation,ingestion,orimmersionofradionuclidespresentinairorincorporated inwaterorfoods,respectively.Immersionandinhalationaremonitoredbyairsampling.Ingestionofradioactivityismonitoredbymeansoffoodsampling,for example,milk, fish,andshellfish,orindicatororganismsormaterials.

Generally,arangeofpotentialpathwaysthatmaybe morecomplicatedinrealityneedtobeconsidered (Table1.1).Therelativeimportanceofdifferentexposure pathwayswillbedependentupon

l themagnitudeofthedischarge,

l therouteofdischargeandfactorsaffectingit(e.g.,stack height,meteorologicalconditions,etc.),

l thephysicalstateorproperties(e.g.,emissiontype,energy,physicalhalf-life,gas,liquid,orsolid),

l thechemicalcharacteristics(e.g.,organicorinorganic form,oxidationstate,speciation,etc.)

l thedosimetricimportanceofradionuclides,

l environmentalcharacteristics(e.g.,climate,typeof biota,agriculturalproduction ,etc.);locations,ages,diets,andhabitsoftheexposedindividualsor population.

Underconditionsofnormaldischargesandchronic(prolonged)exposure,thepathwaysareusuallypermanentand welldefined.Incaseofemergencyreleases,thecontributions viadifferentpathwaystothedosesreceivedbyworkersand thepublicmaybedifferentfromthenormalandtransient. Thesedifferencesshouldbeconsideredwhenestablishingthe monitoringprogram.Toprotectthepublicandworkersfrom deterministichealtheffectsfollowingmajoraccidents,radiologicalcriteriainemergenciesmaybedifferentfromthose appliedunderconditionsofnormaldischarges(e.g.,additional monitoringdatamaybenecessary).

Undernormaloperationconditions,thatis,forroutine environmentalmonitoring,thoseradionuclidesaretobe considered,whicharelimitedindischargepermitsorare significantcomponentsofagrouplimit(e.g.,strontium-90 limitedunderanyotherbeta/gamma-emittingradionuclide grouplimit).Otherradionuclidesmayberequiredasaresult ofinternationalobligationsorbackgrounds.Provensurrogateradionuclidesmaybeused(e.g.,wheretheradionuclide fingerprintisrelativelystable).Sinceroutinemonitoring programsaredesignedtoverifycompliancewithenvironmentalstandardsatlevelsjustdetectableandwhicharefor recordsonlybylow-levelmeasurements,itisessentialtobe abletoidentifythesourceandtocircumscribetheextentof theradioactivematerialwithreasonableaccuracy.

Preoperationalassessmentsoftheexpectedinventoriesof radionuclidesduringoperationofafacility,thepossible dischargepathwaysandthelikelyamountsthatwillbe dischargedtotheenvironment,withdueconsiderationofthe

TABLE1.1 Importantexposurepathwaystobeconsideredinthemonitoringprogram.

Externalexposurepathways

Sourceofradiation / human Directexposurefromasource

Sourceofradionuclides/ atmosphereorwaterbody / human Exposureduetotheplumeorwater

Sourceofradionuclides / atmosphereorwaterbody / humanskin Skincontactexposure

Sourceofradionuclides / atmosphereorwaterbody / soilor sedimentorbuildingsurfaceorvegetation / human

Internalexposurepathways

Exposurefromdepositedradionuclidesontheground,onthe shoresofrivers,lakes,orthesea;onwalls,roofs,andfloors;oron trees,bushes,andgrass

Sourceofradionuclides / atmosphere / human Inhalationofradionuclidesintheplume;

Sourceofradionuclides / waterbody / human Ingestionofradionuclidesindrinkingwater

Sourceofradionuclides / atmosphereorwaterbody / (soil orsediment) / vegetation / meat,milk,eggs,vegetables,or marinefood / human

Ingestionofradionuclidesinfoodorbeverages

Soilorsediment / human Inhalationofresuspendedradionuclides

Sourceoftritium / atmosphere / human Absorptionoftritiumoxidethroughtheskin

effluenttreatmentsystemsthatwillbeinstalled,willhelpto definespatialandtemporalboundariesandselecttypesand numbersofsamplesandmeasurementmethods.Apreoperationalprogramintendedtoestablishbaselinesmightalso identifysuitableindicatororganismsorindicatormaterials forparticularradionuclides.Indicatorssuchasseaweeds, lichen,orsuspendedparticulatematterareselectednot becausetheyrepresentacomponentofthehumandietbut becausetheyconcentrateradionuclidesandprovideameasureoftrendsinactivitylevelsandhencemayprovidemore sensitiveinformationofenvironmentalcontamination.

Environmentalmonitoringduringthedecommissioning ofafacility,suchasuraniumminesandmills,uranium enrichmentplants,fuelfabricationfacilities,nuclearreactors(IAEA,1998,1999;2001,2002a,2002b),nuclear fuelreprocessingplants,andotherradionuclideprocessing facilities,willbesimilartothatfortheoperationalstage, modifi edtotakeaccountofchangesinthesourceterm,all materialsexhibitingsignificantlevelsofactivity(FAO, 1996)areremovedasdecommissioningproceeds.Forboth currentandhistoricaldischarges,in-growthofdaughters mayneedtobeconsidered(e.g., 241Amfrom 241Pu).

Themostimportantradionuclidestobeassessed followingareleaseofradionuclidesfromauranium-fueled reactortotheenvironmentare 134Cs, 137Cs(137mBa), 131I, andothergammaemitters;thebetaemitters 89Sr, 90Sr,and tritium;andthealphaemitters 238Pu, (239 þ 240)Pu, 241Am, and 242Cm.Thisgroupofradionuclidesismostlikelytobe ofconcernduetointernalexposurefrominhalationand ingestionoffoodandwaterandtothecontaminationof environmentalmaterials,whicharepartoftheimmediate pathways,leadingtocontaminationoffood(Table1.2). Biologicalconcentrationinfreshwaterandmarinesystems canresultinveryrapidtransferandenrichmentofspeci fic radionuclides.Radionuclidesthatentersuchsystemscan, incertaincases,berapidlyaccumulatedbyplanktonand algae,whichserveasfoodforhighertrophiclevels;thus, theradionuclidesbecomeconcentratedinorganismssuch asoysters,clams,shrimp,etc.

Radionuclidesofparticularconcerninfreshwaterand marinefoodchainsinclude 54Mn, 55Fe, 59Fe, 60Co, 65Zn, 95Zr, 95Nb, 103Ru, 106Ru, 110mAg, 125Sb, 131I, 134Cs, 137Cs, 141Ce, 144Ce,andsomeofthetransuranicelements.

Manyotherradionuclideswouldbepresentindebrisfrom anuclearaccident;theirpotentialcontributiontohuman exposuredependsonthetypeofaccidentandthecircumstancesatthetimeoftheaccident.Sincethereareseveraltypes offuel,thespectraofradionuclidesthatwouldbepresentin accidentalreleasescouldbesomewhatdifferent.

Thelevelsofradionuclidesintheenvironmentandfood andtheirvariabilityhavebeenextensivelycompiledbythe UnitedNationsScienti ficCommitteeontheEffectsof AtomicRadiation(UNSCEAR,2000b,2000c ).Thesereportscontaininformationaboutthetransferofradionuclidesbetweenatmospheres,waters,soils,biota,andperson andabouthumanexposuretothevariousnuclides (UNSCEAR,2000a,2008).

Whatsiteorenvironmentwillbemonitored,whatwill bemeasured,wherewillitbemeasured,andwhenand howfrequentlywillitbemeasuredareessentialelements ofamonitoringdesign.However,asthedevelopmentof themonitoringdesignalmostalwaysrequiresclari fi cation andprioritization,documentingthedesign,including rationalefordecisions,iscriticalwhenthedesignis implementedandwhenthecollecteddataareusedfor reportingtonationalpolicymakers,internationalforums, andthepublic.

Identi ficationandassessmentofthepotentiallycritical radionuclides,pathways,andgroupsorindividualsisa substantialprerequisiteindesigningenvironmentalmonitoringprograms,directlyaffectingthenatureandextentof themeasurements.Theselectionofthemajorcontributing radionuclidesandtheirsignifi cantpathwaystothepredefinedtargetpopulationorindividualdirectthemonitoringprogramstothemostimportantsubjects.The followingprinciplesforthedevelopmentofapractical monitoringprograminvolvestepsthatarereasonablyindependentoflocalcircumstances:

Air 131I, 134Cs, 137Cs

Water 3H, 89Sr, 90Sr, 131I, 134Cs, 137Cs

Milk 89Sr, 90Sr, 131I, 134Cs, 137Cs

Meat 134Cs, 137Cs

Otherfoods

Vegetation

Soil

89Sr, 90Sr, 134Cs, 137Cs

89Sr, 90Sr, 95Zr, 95Nb, 103Ru, 106Ru, 131I, 134Cs, 137Cs, 144Ce

89Sr, 90Sr, 134Cs, 137Cs, 238Pu, (239þ240)Pu, 241Am, 242Cm

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