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1.1

1.2

1.3

1.4

1.5

1.6

1.4.1

1.4.2

1.5.1

1.5.2

1.5.3

1.5.4

1.5.5

1.5.6

1.5.7

1.5.8

1.5.9

1.5.10

1.5.11

1.5.12

1.5.13

1.6.1

1.6.2

1.6.3

1.6.4

1.6.5

1.7

1.8

1.9

2.2

1.5.9.1

1.5.9.2

2.2.2 Directional Total Emissivity ϵ(θ,ϕ,T ) ................................................53

2.2.3 Hemispherical Spectral Emissivity ϵ λ(T ) ..........................................54

2.2.4 Hemispherical Total Emissivity ϵ(T ) ................................................55

2.3 Absorptivity .....................................................................................................59

2.3.1 Directional Spectral Absorptivity αλ(θi , ϕi , T ) ...................................59

2.3.2 Kirchhoff’s Law ................................................................................60

2.3.3 Directional Total Absorptivity α (θi , ϕi , T ) .........................................61

2.3.4 Kirchhoff’s Law for Directional Total Properties .............................61

2.3.5 Hemispherical Spectral Absorptivity αλ(T ) ......................................62

2.3.6 Hemispherical Total Absorptivity α (T ).............................................63

2.3.7 Diffuse-Gray Surface ........................................................................65

2.4 Reflectivity.......................................................................................................66

2.4.1 Spectral Reflectivities ........................................................................66

2.4.1.1 Bidirectional Spectral Reflectivity ρ(θr, ϕr, θi , ϕi) ...............66

2.4.1.2 Reciprocity for Bidirectional Spectral Reflectivity ..........66

2.4.1.3 Directional Spectral Refelctivities ....................................68

2.4.1.4 Reciprocity for Directional Spectral Reflectivity .............68

2.4.1.5 Hemispherical Spectral Reflectivity ρλ ..............................69

2.4.1.6 Limiting Cases for Spectral Surfaces ...............................69

2.4.2 Total Reflectivities .............................................................................71

2.4.2.1 Bidirectional Total Reflectivity ρ(θr, ϕr, θi , ϕi) ...................71

2.4.2.2 Reciprocity for Bidirectional Total Reflectivity ................71

2.4.2.3 Directional Total Reflectivity ρ(θi , ϕi) or θr, ϕr) .................71

2.4.2.4 Reciprocity for Directional Total Reflectivity ...................72

2.4.2.5 Hemispherical Total Reflectivity, ρ ...................................72

2.4.3 Summary of Restrictions on Reflectivity Reciprocity Relations.......72

2.5 Transmissivity at an Interface .........................................................................72

2.5.1 Spectral Transmissivities ...................................................................73

2.5.1.1 Bidirectional Spectral Transmissivity τλ

2.5.1.2 Directional Spectral Transmissivities τλ(θ i, ϕi)...................73

2.5.1.3 Hemispherical Spectral Transmissivity τλ ........................74

2.5.2 Total Transmissivities ........................................................................74

2.5.2.1 Bidirectional Total Transmissivity τλ(θ i, ϕ

2.5.2.2 Directional Total Transmissivities τ(θ i, ϕi) .........................75

2.5.2.3 Hemispherical-Directional Total Transmissivity τ(θ t, ϕt) ................................................................................75

2.5.2.4 Hemispherical Total Transmissivity τ ..............................76

2.6 Relations among Reflectivity, Absorptivity, Emissivity, and Transmissivity ...........................................................................................76

3.1 Introduction

3.2 Electromagnetic Wave Theory Predictions .....................................................87

3.2.1 Dielectric Materials ..........................................................................88

3.2.1.1 Reflection and Refraction at the Interface between Two Perfect Dielectrics (k → 0) .........................................88

3.2.1.2 Reflectivity ........................................................................90

3.2.1.3 Emissivity .........................................................................91

3.2.2 Radiative Properties of Metals ..........................................................94

3.2.2.1 Electromagnetic Relations for Incidence on an Absorbing Medium

3.2.2.2

3.2.2.3

3.3

3.4

3.4.1

3.5.1

3.5.2

3.5.3

3.5.4

3.5.5

3.6

4.2.2.2

4.3.3

4.3.3.1

4.3.3.3

4.3.4

4.3.5

4.3.6

4.4

5.1

5.2

5.2.1

5.2.2

5.3

5.3.1.1

5.3.1.2

5.3.2

5.3.3

5.4.1.1

5.4.1.2

5.4.1.3

5.4.2

6.2.2

6.4

6.5

6.5.1

6.5.2

6.6

6.6.1

6.6.2

7.9

7.8.2

7.8.3

7.9.1

7.9.2

7.8.1.2

7.8.1.3

7.8.2.1

7.8.2.2 Accelerated

7.9.3

7.9.4

7.9.5

7.9.6

7.9.2.1

7.9.2.2

7.9.2.3

7.9.2.4

7.9.3.1

7.9.3.2

7.9.6.1

7.9.6.2

7.9.6.3

9.2.4

10.3 Radiative Transfer and Source Function Equations ...................................... 495

10.3.1 Radiative Transfer Equation 495

10.3.2 Source Function Equation ............................................................... 497

10.4 Radiative Flux and Its Divergence within a Medium .................................... 50 0

10.4.1 Radiative Flux Vector 501

10.4.2 Divergence of Radiative Flux without Scattering (Absorption Alone) 50 4

10.4.3 Divergence of Radiative Flux Including Scattering ........................ 505

10.5 Summary of Relations for Radiative Transfer in Absorbing, Emitting, and Scattering Media..................................................................................... 507

10.5.1 Energy Equation 507

10.5.2 Radiative Energy Source ................................................................. 507

10.5.3 Source Function 507

10.5.4 Radiative Transfer Equation ........................................................... 508

10.5.5 Relations for a Gray Medium 508

10.6 Net-Radiation Method for Enclosures Filled with an Isothermal Medium of Uniform Composition 509

10.6.1 Definitions of Spectral Geometric-Mean Transmission and Absorption Factors 511

10.6.1.1 Definitions of Spectral Geometric-Mean Transmission and Absorption Factors.............................. 511

10.6.2

10.7 Evaluation of Spectral Geometric-Mean Transmittance and Absorptance Factors ...............................................................................

10.8 Mean Beam-Length Approximation for Spectral Radiation from an Entire Volume of a Medium to All or Part of Its Boundary ......................... 518

10.8.1 Mean Beam Length for a Medium between Parallel Plates Radiating to Area on Plate .............................................................. 519

10.8.2 Mean Beam Length for Sphere of Medium Radiating to Any Area on Its Boundary ...................................................................... 520

10.8.3 Radiation from Entire Medium Volume to Its Entire Boundary for Optically Thin Medium ............................................................. 520

10.8.4 Correction to Mean Beam Length When Medium Is Not Optically Thin ................................................................................. 521

10.9 Exchange of Total Radiation in an Enclosure by Use of Mean Beam Length 526

10.9.1 Total Radiation from Entire Medium Volume to All or Part of its Boundary 527

10.9.2 Exchange between Entire Medium Volume and Emitting Boundary 527 Homework ................................................................................................................ 529 1Chapter 1 Energy Transfer in Plane Layers and Multidimensional Geometries: Participating Media with and without Conduction .................................................. 535

11.1 Introduction ................................................................................................... 535

11.2 Equations for Radiative Intensity, Flux, Flux Divergence, and Source Function in a Plane Layer .............................................................................. 535

11.2.1 Radiative Transfer Equation and Radiative Intensity for a Plane Layer 535

11.2.2 Local Radiative Flux in a Plane Layer ............................................ 537

11.2.3 Divergence of the Radiative Flux—Radiative Energy Source ...........538

11.2.4 Equation for the Source Function in a Plane Layer 539

11.2.5 Relations for Isotropic Scattering .................................................... 539

11.2.6 Diffuse Boundary Fluxes for a Plane Layer with Isotropic Scattering ......................................................................................... 541

11.3 Gray Plane Layer of Absorbing and Emitting Medium with Isotropic Scattering ............................................................................... 541

11.4 Gray Plane Layer in Radiative Equilibrium 545

11.4.1 Energy Equation .............................................................................. 545

11.4.2 Absorbing Gray Medium in Radiative Equilibrium with Isotropic Scattering ......................................................................... 546

11.4.3 Isotropically Scattering Medium with Zero Absorption 546

11.4.4 Gray Medium with dq r /dx = 0 between Opaque Diffuse-Gray Boundaries 547

11.4.5 Solution for Gray Medium with dq r /dx = 0 between Black or Diffuse-Gray Walls at Specified Temperatures 548

11.4.5.1 Gray Medium between Black Walls ................................ 548

11.4.5.2 Gray Medium between Diffuse-Gray Walls .................... 551

11.5 Radiation Combined with Conduction 552 11.5.1 Energy Balance................................................................................ 554

11.5.2 Plane Layer with Conduction and Radiation 554

11.5.2.1 Absorbing-Emitting Medium without Scattering ............ 554

11.5.2.2 Absorbing-Emitting Medium with Scattering 556

11.6 Multidimensional Radiation in a Participating Gray Medium with Isotropic Scattering 559

11.6.1 Radiation Relations in Three Dimensions ....................................... 559

11.6.2 Two-Dimensional Transfer in a Rectangular Region 561

11.6.3 Rectangular Region with Conduction and Radiation ...................... 56 4

11.6.4 One-Dimensional

11.6.5

11.8 Discussion of Solution Procedures

11.8.1 Simultaneous Solution of Energy and Radiative Transfer Relations .....572

11.8.2 Outline of Solution Methods for the Radiative Transfer Equation 573

11.8.2.1 Solution Methods for the Differential RTE .................... 573

11.8.2.2 Solution

12.2.2 Optically Thin Media with Cold Boundaries or Small Incident Radiation; the Emission Approximation 585

12.2.3 Cold Medium with Weak Scattering ............................................... 587

12.3 Optically Thick Medium : Radiative Diffusion ............................................

12.3.1 Simplified Derivation of the Radiative Diffusion Approximation .................................................................................

12.3.2 General Radiation-Diffusion Relations in a Medium .....................

12.3.2.1 Rosseland Diffusion Equation for Local Radiative Flux ..................................................................................

12.3.2.2 Emissive Power Jump Boundary Condition in the Limit without Heat Conduction .............................

12.3.2.3 Gray Stagnant Medium between Parallel Gray Walls

12.3.2.4 Other Radiative Diffusion Solutions for Gray Media without Heat Conduction

12.4 Approximations for Combined Radiation and Conduction ...........................

12.4.1

12.4.2

12.5 Approximate

12.6 Use

12.6.2

13.2.6

13.3

13.3.3

13.3.4

13.3.4.1

13.3.4.2

13.3.5

13.4

13.5

13.6 Finite-Difference

13.6.1

13.7

13.7.1

13.7.2

13.7.3

13.8

13.8.3.1

13.9

13.11

13.9.3

15.6.3

16.2.2

16.2.3

16.4.1

16.4.2

17.5

17.5.1

17.5.2

17.5.3

17.5.3.1 Layer with Nondiffuse or Specular Surfaces

17.5.3.2

17.5.5 Emission from a Translucent Layer (n > 1) at Uniform Temperature with Specular or Diffuse Boundaries.........................

17.6.3.1

17.6.3.2

Preface to the Fifth Edition

In the years since publication of the fourth edition of Thermal Radiation Heat Transfer in 2002, the subject has continued to develop at a rapid pace. The requirements remain for thermal design of devices operating in outer space; the design of engines and combustion chambers to operate at increased temperatures to raise thermal efficiency; developments for utilization of solar energy; various manufacturing processes including growth of translucent crystals, semiconductor wafer processing, and forming and tempering of glass; and many other applications. In addition, an explosion of interest in microscale and nanoscale structures and their interaction with radiation has opened an extensive research effort that stretches traditional engineering radiative transfer into new regimes.

Since the publication of the fourth edition, Dr. Robert Siegel has moved to a well-deserved retirement. Bob’s contributions to the first four editions were immense, and to prepare a new edition without his guidance and counsel is a daunting task. Professor Pinar Mengüç has brought his extensive expertise in radiative transfer to help fill the gap in this new edition.

Extensive revisions have been made in this edition to incorporate instruction on the significant developments in radiative transfer that have occurred. The overall subject arrangement of previous editions has been retained. This consists of three chapter groupings. The first grouping (Chapters 1-3) presents blackbody radiative properties, and the radiative properties of opaque materials as predicted by electromagnetic theory and obtained by measurements. The second grouping (Chapters 4-8) is on radiative exchange in enclosures without any radiating medium between the surfaces; heat conduction is included within the boundaries, such as for analysis of radiating fins. The final grouping (Chapters 9-17) deals with the radiative properties of gases, and with energy exchange when gases and other participating materials are present that interact with radiative energy, such as in furnaces. Within this basic framework, many changes have been made from the fourth edition. The nomenclature has been revised to agree with the common nomenclature adopted by the major heat transfer journals. Previous material has been condensed and consolidated. A considerable amount of material has been removed from the main flow of the text and incorporated as appendices to aid in readability. Four new chapters have been added (Inverse Methods, Electromagnetic Theory, Scattering, and Absorption by Particles, and Near-Field Radiative Transfer), and references have been updated and expanded. References are now alphabetized and gathered in Appendix E rather than at the end of each chapter.

The first chapter on fundamentals of radiation and the blackbody has been augmented with an introduction to the propagation of radiation in participating media and the radiative transfer equation. The second and third chapters provide information on the definition and characteristics of radiative surface properties, and on comparisons with the behavior of real properties as required for applying the methods for analysis that are developed. This foundation on properties must be established because choosing the best procedure for analysis depends on the nature of the radiative properties involved. Derivations of the electromagnetic theory predictions have been moved to the new Chapter 14 that provides a comprehensive overview of the use of electromagnetic (EM) relations. The analysis of radiative exchange among multiple surfaces separated by transparent media is developed in Chapters 4 through 8. This material includes surfaces with black, gray, spectral, diffuse, directional, and specular properties. For enclosures with diffuse surfaces the geometric configuration factors must be obtained. A short appendix provides convenient analytical expressions for some configuration factors that are useful for homework problems and basic geometries. However, a greatly extended catalog of factors has been posted on a Web site at www.engr. uky.edu/rtl/Catalog.

A new Chapter 8 has been added that describes inverse problems, how they appear in radiative transfer and design of radiating systems, and various solution techniques available for inverse solutions.

Chapter 9 introduces the radiative properties of gases and liquids, including references and descriptions of contemporary methods for calculating the spectral and total properties of gases. Information on scattering coefficients and phase functions for particles is transferred to a new comprehensive Chapter 15.

The development of radiative transfer in semitransparent media is contained in Chapters 10 through 13 with an emphasis on gaseous media. As noted, the new Chapters 14 and 15 deal with electromagnetic theory in radiative transfer and with scattering, and the new Chapter 16 is dedicated to the important area of near-field radiation effects and ultrafast radiative interactions with matter. The authors wish to acknowledge the contributions of Mathieu Francoeur, who contributed greatly to the material in Chapter 16.

Chapter 17 considers media that have a refractive index larger than unity such as glass, where reflections and other important effects at interfaces must be included.

Some material remains useful, but of less direct importance than previously due to the increasing availability of computer-based mathematical programs. Material on geometric mean beam lengths, for example, is less used. To shorten the written text, this material has been moved to the publisher’s Web site at www.crcpress.com /product/ISBN/9781439805336 and is available for download. Additionally, material on applications such as radiation in porous media has also been placed on the Web site.

The authors hope that this new edition continues the tradition of providing both a comprehensive textbook for those interested in the study of radiative transfer as well as a source of important references to the literature for the serious researcher.

M atlab® is a registered trademark of The MathWorks, Inc. For product information, please contact:

The MathWorks, Inc.

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Tel: 508-647-7000

Fax: 508-647-7001

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Web: http://www.mathworks.com

List of Symbols

This is a consolidated list of symbols for the entire text. Some symbols that are used in only a local development are defined where they are used and are not included here. The symbols used in radiative transfer have evolved from many different disciplines where radiation is important. This has led to the same quantity being defined by a variety of symbols, and to multiple quantities designated with the same symbol. The symbols listed here are typical of those used for engineering heat transfer, and follow where possible those adopted formally by the major heat transfer journals [Howell (1999)]. The study of radiative transfer combined with conduction and convection involves many types of applications, and hence requires definitions for a large number of different quantities and parameters. There is an insufficient number of convenient symbols that can be used, so some symbols must be used for multiple quantities. Attention has been devoted to making the particular definition clear from the context of its use. Some typical units have been indicated. Some care must be observed as quantities have multiple units, such as a spectral bandwidth that can be in terms of wavelength, wave number, or frequency; some of these are designated by (mu) meaning “multiple units.” A length could, for example, be in m, cm, μm, or other units, so that only a typical unit is shown. Some quantities are nondimensional; these are designated by (nd).

a quantity in reflectivity relations (nd); spacing between surfaces, m; thickness, m; coefficient in phase velocity of electromagnetic wave (nd)

a 0 autocorrelation distance of surface roughness, m

akj matrix elements (mu or nd)

a matrix of elements akj

a 1 inverse matrix (mu or nd)

A surface area, m 2 , absorptance of a translucent plane layer (nd)

A, B, C, D field amplitude coefficients

A r aspect ratio of rectangle (nd)

Alm coefficients in spherical harmonics expansion

Aij equivalent spectral line width (mu, wavelength, wave number, frequency)

AA l , equivalent spectral bandwidth (mu)

b spacing, m; width of a base, m; a dimension, m; coefficient in phase velocity of electromagnetic wave (nd); quantity in reflectivity relations (nd); pressure parameter in Table 9.2 (nd)

B pressure broadening parameter (nd); length dimension, m

B magnetic induction vector, Wb/m 2

c speed of electromagnetic radiation propagation in medium other than a vacuum, m/s

c 0 speed of electromagnetic radiation propagation in vacuum , m/s

c, cp, cv specific heat, J/(kg K)

C a coefficient or constant (mu or nd); clearance between particles, m; particle volume fraction (nd)

C1 constant in Planck’s spectral energy distribution (Table A.4), W · μm4/(m 2 · sr)

C2 constant in Planck’s spectral energy distribution (Table A.4), μm K

C3 constant in Wien’s displacement law (Table A.4), μm · K

Ci concentrations of the i components in a mixture (nd)

Ckj matrix elements (mu or nd)

C CO 2 , C H 2 O pressure-correction coefficients (nd)

d number of diffuse surfaces (nd); a dimension, m

dA* differential element on the same surface area as dA, m 2

D thickness of a layer or plate, m; a dimension, m; diameter of tube or hole, m; diameter of atom or molecule, m; number of dimensions (nd)

D f fractal dimension (nd)

Dp particle diameter, m

D electric displacement, C/m 2

e energy level of a quantized state or photon, J

E emissive power (usually with a subscript), W/m 2; amplitude of electric intensity wave, N/C; overall emittance of a translucent layer (nd); the quantity (1 − ϵ)/ϵ, (nd)

E n exponential integral (Appendix D), (nd)

Ew weighted error (nd)

Eff absorption efficiency for a grooved directional absorber (nd)

E electric field vector, V/m

f (ξ) frequency distribution of events occurring at ξ (nd)

F configuration factor (nd); objective function in optimization (mu); separation variable in Equation 11.39

F0 →λ fraction of total blackbody intensity or emissive power in spectral region 0 to λ (nd)

F transfer factors in enclosure (nd)

g gravitational acceleration, m/s2

g(κη) cumulative distribution function in k-distribution method, Equation 9.46

gggs , gas-gas and gas-surface direct exchange areas, m 2

g Weyl component of the dyadic Green’s function, m

G incident radiative flux onto a surface, W/m 2; Green’s function

G dyadic Green’s function, 1/m

h Planck’s constant, J·s (Table A.1); height dimension, m; convective heat transfer coefficient, W/(m 2 K); enthalpy, J/kg

hv volumetric heat transfer coefficient, W/(m 3 · K)

H wave amplitude of magnetic intensity, C/(m s); convection-radiation parameter (nd)

H magnetic field vector, C/(m · s)

I λ spectral radiation intensity, W/(m 2 μm sr)

I radiation intensity, W/(m 2 · sr)

i, j, k unit vectors in x, y, z coordinate directions (nd)

i number of increments (nd)

ˆ

I source function, W/m 2

Im imaginary part

J radiosity; outgoing radiative flux from a surface; auxiliary variational function (mu or nd); number of increments (nd)

J current density vector, A/m 2

Jr random current density vector, A/m 2

k thermal conductivity, W/(m K); extinction coefficient for electromagnetic radiation, m−1; wave vector () = ′ + ′′ kik rad/m

k B Boltzmann constant (Table A.1), J/K;

K dielectric constant () = ′ + ′′ KiK (nd); kernel of integral equation (mu or nd)

Kij finite element function defined in Equation 13.128

l a length, m, or a dimensionless length (nd)

l, m, n direction cosines for normal direction used in contour integration method (nd)

l1, l2 , l 3 direction cosines for rectangular coordinates designated as x1, x 2 , x 3 (nd)

lm mean penetration distance, m

L length dimension, m

L e mean beam length of gas volume, m

L

e,0

mean beam length for limit of very small absorption, m

L Ladenberg-Reiche function (nd)

M mass of a molecule or atom; molecular weight

Mkj minor of matrix element akj (mu or nd)

n index of refraction of a lossless material c 0/c (nd); ratio n 2 /n1 in a few equations (nd); index in summation (nd); sample index (nd); number of a surface (nd); pressure parameter in Table 9.2 (nd); ordinate directions in Sn approximation (nd); normal direction (nd)

n complex refractive index n − ik (nd)

n unit normal vector (nd)

N number of surfaces in an enclosure (nd); number of sample bundles per unit time, s−1; number of particles per unit volume, m−3; density of electromagnetic states, s/(m3 · rad)

Nc conduction-radiation parameter (nd)

Nx , Ny number of x and y grid points (nd)

Nu Nusselt number hD/k (nd)

p partial pressure of gas in mixture, atm

ˆ

p TM-polarized unit vector

P perimeter, m; probability density function (nd); total pressure of gas, atm

P, Q, R functions used in contour integration, m−1

P0 pressure of 1 atm

Pe effective broadening pressure (nd)

Pl m associated Legendre polynomials (nd)

Pr Prandtl number cp μ f /k (nd)

q energy flux, energy per unit area and per unit time, W/m 2

q internal energy generation per unit volume, W/m 3

qc energy per unit area per unit time resulting from heat conduction, W/m 2

ql radiative flux in a spectral band (mu)

qr net radiant energy per unit area per unit time leaving a surface element, W/m 2

qr radiative flux vector, W/m 2

Q energy per unit time, W; ray origin point

Qa absorption efficiency factor (nd)

Qs scattering efficiency factor (nd)

r radial coordinate, m; radius, m

re electrical resistivity, N · m 2 · s/C2 = Ω · m

rij Fresnel’s reflection coefficient at interface i-j

r position vector (mu or nd)

R radius, m; overall reflectance of translucent plane layer or group of multiple layers (nd); random number in range 0 to 1 (nd)

Re Reynolds number Du mρf /μ f (nd); real part

s λ scattering cross section, m 2

s unit vector in S direction (nd)

ˆ

s TE-polarized unit vector

s j γ γ surface-gas direct exchange area in zonal method

ssjk surface-surface direct-exchange area in zonal method

S coordinate along path of radiation, m; distance between two locations or areas, m; surface, m 2; number of sample energy bundles per unit time, s−1

S Poynting vector, W/m 2; energy per unit area and time, W/m 2

S dimensionless internal energy source (nd)

Sc collisional line intensity (mu)

SdV number of energy bundles absorbed per unit time in volume dV (nd)

Sij spectral line intensity (mu)

S kj geometric-mean beam length from Ak to Aj, m

Sn two-dimensional radiation integral functions (Appendix D) (nd); singular values from matrix decomposition

Sr dimensionless radiative heat source (nd)

St Stanton number, Nu/(Re · Pr) (nd)

t time, s

tij Fresnel’s transmission coefficient at interface i-j

� t dimensionless time (nd)

t (S ) transmittance of a medium (nd)

t jk geometric-mean transmittance (nd)

T absolute temperature, K; overall transmittance of a plane layer or group of multiple layers (nd)

Tl mean transmission in a spectral band (nd)

Tw1, Tw2 temperatures of walls 1 and 2, K

u fluid velocity, m/s; the variable Χα /ω (nd); energy density, J/m 3

uk spectral band parameter hc ηk /kT (nd)

uum , mean fluid velocity, m/s

u, v velocity, m/s

U, V orthogonal matrices resulting from singular value decomposition

U total number of unknowns for an enclosure (nd); radiant energy density, J/m 3

U(x, y) approximate solution in finite element method (mu)

Uv spectral radiant energy density, J/(m 3 μm)

V volume, m 3; voltage signal, V = N/C

Vγ volume of element γ in zoning method, m 3

w width, m; energy carried by sample Monte Carlo bundle, J; weighting factors (nd)

W weighting function in finite element method (nd); width dimension, m

x, y, z coordinates in cartesian system, m

X coordinate, m, or dimensionless coordinate (nd); mass path length, g/m 2

X, Y, Z optical or dimensionless coordinates (nd)

Yl m normalized spherical harmonics (nd)

z height of surface roughness, m

Greek symbols

α absorptivity (nd); thermal diffusivity, m 2 /s; coefficient in soot scattering correlations

α(S ) absorptance of a medium (nd)

α , α0 band parameters in Tables 9.2 to 9.4, m 2 /(g · cm); regularization parameter in Tikhonov regularization

α , β, γ direction cosines (nd)

α , δ, γ angles measured from normal direction in contour integration method, rad

α jk geometric-mean absorptance, m−1

β extinction or attenuation coefficient κ + σs, m−1; angle in x-y plane, rad; coefficient of volume expansion, K−1; the parameter πγc /δ (nd)

βR Rosseland mean attenuation coefficient, m−1

ßi coefficients in shape function in finite-element method (nd)

γ electrical permittivity, C2 /(N·m 2); polynomial coefficients (nd); half-width of a spectral line (mu)

γ 2 variance in a statistical solution (nd)

Γ number of gas elements (nd)

Γ factors in Gebhart’s method (fraction of energy leaving one surface that is absorbed by another (nd); separation variable in Equation 11.39; function in integral equation (Equation 11.49), W/m 2

δ propagation angle in medium, rad; boundary layer thickness, m; average spacing between lines in absorption band (mu); penetration distance of evanescent waves, m

δkj Kronecker delta; = 1 when j = k; = 0 when j ≠ k

δ () ′ ′′ rr Dirac delta function

Δ distance above a radiating body

Δϵ correction for spectral overlap (nd)

Δφ intermediate function in alternating direction implicit method (mu)

ϵ emissivity of a surface (nd)

ϵ(S ) emittance of a medium (nd)

ϵ h eddy diffusivity for turbulent flow, m 2 /s

ϵ

ρ porosity (nd)

ζ arbitrary direction (nd); the quantity C2 / λT (nd)

η fin efficiency (nd); Blasius similarity variable (nd); wave number, l/ λ , m−1

θ polar or cone angle measured from normal of surface, rad

θo scattering angle, rad

Θ dimensionless temperature, T(σ/qmax)1/4; separation variable in Equation 11.39; mean energy of a Planck oscillator, J

ϑ dimensionless temperature T/Tref (nd)

κ absorption coefficient, m−1

κe effective mean absorption coefficient, m−1

κi incident mean absorption coefficient; absorption coefficients in weighted-sum-ofgray-gases emittance model, m−1

κP Planck mean absorption coefficient, m−1

κR Rosseland mean absorption coefficient

κλ spectral absorption coefficient, m−1

λ wavelength, m

λ m wavelength in a medium other than vacuum, m

μ magnetic permeability, N/A 2; dimensionless fin conduction parameter (nd); the quantity cosθ (nd); the quantity SSc / δ (mu)

μf fluid viscosity, kg/m·s

ν frequency, cc c m 00 0 1 // /s Hz λλ λ == = ,

ξ length coordinate, m; parameter πD/ λ for scattering (nd); parameter SSij /2πγc for equivalent line width

ξ, η dimensionless coordinates (nd)

ξC clearance parameter for particle separation criteria, πC/ λ

ρ reflectivity (nd); gas density, kg/m 3

ρe electric charge density, C/m 3

ρij reflectivity at interface i-j

ρf density of a fluid, kg/m 3

ρM density of a material, kg/m 3

ρs specular reflectivity, (nd)

ρ* , ρ0 distances between points, m or (nd)

σ Stefan-Boltzmann’s constant, Equation 1.27 and Table A.4, W/(m 2 K4)

σs scattering coefficient, m−1

σ0 root-mean-square height of surface roughness, m

τ roughness correlation length, m; optical thickness (nd); transmittance (Chapter 17) (nd)

τD optical thickness for path length D (nd)

ϕ

circumferential or azimuthal angle, rad; dimensionless function, Equation 11.55 (nd)

Φ scattering phase function (nd); shape function in finite-element method (nd); function in integral equation (mu or nd); function in Equation 9.33d (nd)

Φd viscous dissipation function, J/(kg · m 2)

χ angle of refraction, rad

ψ dimensionless heat flux (nd); stream function

ψ1 temperature jump coefficient (nd)

ψ(3) pentagamma function (nd)

ψb dimensionless energy flux for black walls (nd)

ψ function in Equation 9.33c (nd)

ω albedo for scattering (nd); angular frequency, rad/s; width of spectral band (mu); band width parameter, cm−1

ω o parameter in Tables 9.2 to 9.4, cm−1

Ω solid angle, sr

Ωi incident solid angle, sr

F transfer factor, Equation 5.41

Subscripts

α absorbed; absorption; absorber; apparent value

α0, α1, … coefficients

abs absorbed

A property of surface A

b on a base surface; at base of a fin; bottom

b, black blackbody condition

bi-d bidirectional

c evaluated at cutoff wavelength; corrected values; collision broadening; at a collector (absorber) plate; cylinder; cross section

cond conduction

c coating

CO2 carbon dioxide

d disk

d, dif diffuse

d1, d 2 evaluated at differential elements d1, d 2

d-h directional hemispherical

D Doppler broadening

e emitted or emitting; entering; environment; element of area; energy input; electrical; effective value

eq at thermal equilibrium

evan evanescent wave

E electric

f fluid

fc free convection

fd fully developed

F final

g gas

h hemispherical

H magnetic

H 2O water vapor

i incident; inner; incoming

i, j energy states

I initial

j, k property of surface Aj or Ak

l spectral band; layer index

L long wavelength region

LO longitudinal optical

m mean value; in a medium; maximum value; metal

m, m ′ outgoing and incoming angular directions

m, n number of identical semitransparent plates in a system

mc metal on cold side

mh metal on hot side

mP evaluated at midpoint

max corresponding to maximum energy; maximum value; maximum refraction angle

min minimum

M maximum value; material

n normal direction; natural broadening

nd nondiffuse

N, S, E, W directions in Figures 13.8 and 13.9

o outer; outgoing; evaluated in vacuum

p projected; particle

prop propagating wave

P Planck mean value; perimeter; point in discrete ordinates method

r reflected; reduced temperature; reservoir; radiative

rad radiation

ref reference value

R radiator; radiating source; Rosseland mean value; radiative

s surface of a sphere; sun; scattering; surroundings; source; solid; specular

sol solar

sub substrate

S short wavelength region

t transmitted; top

TE transverse electric

TM transverse magnetic

TO transverse optical

u uniform conditions

w wall; window

x, y, z components in x, y, z directions

η wave number dependent

λ wavelength (spectrally) dependent

Δλ for a wavelength band Δλ

λ1 → λ2 in wavelength region from λ1 to λ2

λT evaluated at λT

ν frequency dependent

ω angular frequency dependent

0 in vacuum

1, 2 surface or medium 1 or 2

⊥ perpendicular component

|| parallel component

∩ hemisphere of solid angles

Superscripts

i inside of an interface

n nth time interval

o inlet value; outside of an interface

s specular exchange factor

(0), (1), (2) zeroth-, first-, or second-order term; designation for moments

+ along directions having positive cos θ along directions having negative cos θ (overbar) averaged over all incident or outgoing directions; mean value; complex value

~ dimensionless quantity

* complex conjugate

1 Introduction to Radiative Transfer

Radiative transfer is the most common energy transport phenomenon that we feel around us every day. The Sun’s energy travels to the earth in the form of electromagnetic waves, is selectively absorbed, and scattered as it goes through atmospheric layers, before eventually heating up everything around us. Radiation allows us to see and sense everything in our surroundings as light or heat. In this process, it is not only the strength of radiative energy that is important, but also how it interacts with matter and how it energizes all the living organisms.

Attenuation of radiation by the atmosphere protects us against the heat of the Sun; a small change in the properties of the atmospheric layers may change the radiation balance of the earth significantly. Photosynthesis—the starting mechanism for life on the earth and the source for producing oxygen in the atmosphere, is the direct result of solar radiation. Radiative transfer is important in several natural and human-made processes, including energy transport in oceans, forests, wild-fires, solar collectors, spacecraft reentry problems, industrial furnaces, internal combustion engines, materials processing, laser-tissue interactions, and diagnostic tools for analysing structures of matter.

Practically all objects emit electromagnetic radiation. The intricate relationship between the electronic, vibrational, and rotational energy levels of atoms and molecules that make up matter governs the laws of radiative emission. The strength of the emitted energy is correlated with the internal energy state of the emitter. If the size of the object is relatively large compared to the size of the atoms and molecules, the object’s internal energy can be described starting from the principles of statistical thermodynamics. Statistical averaging allows the definition of average thermodynamic and thermophysical properties, including internal energy and temperature. Each emitting object exchanges radiant energy with the others that it can “see.” A fraction of the energy that it receives from other bodies is converted into its internal energy via the mechanism of radiation absorption. Absorption also depends on the energy levels of atoms and molecules of the object. Emitted light propagates within the medium (which may be a vacuum) between the emitting and the absorbing object. Along its path, it may change its energy and direction due to the presence of molecules, particles, discontinuities, or any inhomogeneities, before its energy is absorbed and becomes a part of the internal energy of another absorbing body.

A systematic study of absorption, emission, and scattering of electromagnetic waves by matter allows us to achieve a better design of experimental and industrial applications where the power of radiative transport can be tapped effectively. For thorough understanding of radiative transfer, these three fundamental phenomena must be carefully explored. The first two are the emission and absorption of electromagnetic energy by matter. The third one is the propagation of electromagnetic waves between different objects and includes the effects of scattering, which encompasses diffraction, interference, reflection, and transmission. Radiative transfer in any given physical system—from nanoscale objects up to stars—is effectively governed by the same laws and requires applications of these three principles. Yet, depending on the size of an object and the wavelength of radiation, different physical and/or mathematical approximations can be introduced to make a given problem more tractable.

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