Application of Piezoelectric Technology in TDLAS Gas Detection

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TDLAStechnologyismainlyusedtodetectgasbydetectingasinglevibrationalabsorptionlineof thegasmoleculeWhendetectinglowconcentrationgas,becausetheabsorptionsignalisweak, itisusuallynecessarytocombinelongopticalpathtechnologyandharmonicdetectionmethod toimprovethesensitivityofgasdetectionAccordingtotheLambertBeerlaw,whenabeamof lightwilldecaywhenpassesthroughgas.

Gasdetectorisacommongasconcentrationdetectioninstrument,mainlyusinggassensorto detectthetypesofgasesintheenvironment.Itcandetecthydrogensulfide,carbonmonoxide, oxygen,sulfurdioxide,phosphine,ammonia,nitrogendioxide,hydrogencyanide,chlorine, chlorinedioxide,ozoneandcombustiblegas,etc.,whichiswidelyusedinpetrochemical,coal, metallurgy,chemicalindustry,municipalgas,environmentalmonitoring,agricultureandother sitesforsitetesting.Inaddition,itcanalsousedforthespecialoccasionmeasurementneeds, suchasconcentrationdetectionorleakageintunnel,pipe,tank,confinedspaceandsoon TunableDiodeLaserAbsorptionSpectroscopy(TDLAS)isatechnologythatusesaTunableDiode LaserandLaserAbsorptionSpectroscopytomeasuretheconcentrationofcertainsubstances (suchasmethaneandwatervapor)inagasmixtureTheadvantageofTDLASoverother concentrationmeasurementisitsabilitytoachieveverylowdetectionlimits(PPBclass).In additiontotheconcentration,thetemperature,pressure,velocity,andmassfluxoftheobserved gascanbealsodetermined.TDLASisbyfarthemostcommonlaserbasedabsorptiontechnique usedtoquantitativelyassesssubstancesinthegasphase

PrincipleofTDLASGasDetectionTechnology

SchematicdiagramofTDLASgasdetection

Whenlaserdiodelightgoesthroughgaschamber,PDlightdetectorwillreceiveLDopticalpower. Withthemodulation,theoutputopticalpowerandwavelengthofthelaserwillchange accordinglyAfterpassingthroughthegascavity,thecorrespondingoutputopticalpowerand wavelengthwillalsochange.Ifthelightisnotabsorbedbythegaswithinthewavelengthsweep

ApplicationofPiezoelectricTechnologyinTDLASGasDetection

TDLAStunablediodelaserabsorptionspectroscopytechnologyisusedtomeasuresingleor severalabsorptionlinesofmoleculesthatareveryclosetoeachotheranddifficulttoresolveby usingthecharacteristicsofnarrowlinewidthandwavelengthoftunablesemiconductorlaser withmodulation.

ApplicationofPiezoelectricTechnologyinTDLASGas Detection

Adjustingthecurrentdrivingthelaserdiodechangestherefractiveindexofthesemiconductor andthereforethefrequencyThetypicaltuningfactorisabout01GHz/mAThemodulation currentallowsmodulationoflaserfrequencieswithabandwidthofseveralMHzTherefore,itisa typical"actuator"forreducinglaserlinewidth

Inordertoreflectreallightabsorption,laserwavelengthorfrequencycurvemustbescanned

TheintracavitaryEOMmethodislesscommonandcanchangetherefractiveindexquickly,but therangeoffrequencyadjustmentsisusuallyverysmall.

ApplicationofPiezoelectricTechnologyinTDLASGasDetection

Piezoelectricadjustmentisaveryfastadjustment,whichcanadjustthegratingpositionand Angleinmillisecondorevensubmillisecondtomeettherequirementsofrapidfrequencychange. Moreover,thefrequencycanbeadjustedoverawiderange,fromafewHztokHz,by piezoelectricadjustmentmethod.

Inaddition,piezoadjustmentmethodsareoftenusedtocounteractslowerfrequencyshifts.

range,thatis,thereisnogasabsorptionline,thentheopticalpowerreceivedbyPDisthesame astheopticalpoweroutputbyLDIfthereisanabsorptionlineinthewavelengthrange,theline spectrumoftheopticalpowerreceivedbythePDterminalwillhaveadepression,andthetype andintensityofthegascanbedeterminedbythewavelengthanddepthofthedepression

Ingeneral,therearefourbasicwaystoadjustthefrequencyoflightcomingoutofalaser,namely, changingthetemperatureofthediode,changingthevoltageofthepiezoelectricactuator(which controlsthepositionandAngleofthegrating),adjustingthecurrentdrivingthelaserdiode,and changingthevoltageoftheEOMinsidethecavity

BasicMethodofFrequencyControlinTDLASGasDetection

Bychangingthetemperatureofthediode,thelaserfrequency(tuningcoefficientisgenerally 01nm/K)canbegreatlychanged,soastoachievethepurposeofwavelengthscanningButit takesalongtimeforthediodetemperaturetochange,usuallyafewseconds,whichisonly suitableforadjustingtheapproximaterangeofwavelengths

PiezoactuatorsarenotonlyusedinTDLASgasdetectiontechnology,butalsoinOPLAS opencircuitgasdetectionandanalysis

Typically,piezoactuatorsareactuatorcomponentsusedtolockphaseandfrequencyfeedback loopsItperformsphaseandfrequencyadjustmentsbasedoncontrolsignals

SelectionofPiezoActuatorsforTDLASGasDetection

CoreMorrowhasthousandsofpiezoactuatorsandthecorrespondingdrivecontrolproductsThe selectionofpiezoactuatorsmainlydependsonthespecificstructureofthecorrespondingTDLAS gasdetectionandthecorrespondingneedtoadjusttheopticalpathparameters

OPLAS(OpenPathLaserAbsorptionSpectroscopy)issimilartoTDLAS,butOPLASdoesnotneed topumpthesamplegasintothegasabsorptionunitforanalysisTheOPLASsystemhashigher requirementsforlaserpointqualityandopticalequipment.Forexample,thedetectionoflow concentrationofammoniaisrelativelydifficult,inthedetectionoflowconcentrationof ammoniagasenvironment,thepiezoactuatorcanbeusedtoadjustthedirectionofthelight source,quicklylocatethelaserscanningcenterposition,andthentakefastlaserscanningina certainrangeThemethodcanevendetectgasconcentrationsoveradistanceof1,000meters

ApplicationofPiezoelectricTechnologyinTDLASGasDetection

1)CoreMorrowPiezoStackActuator

OPLASBasicStructureDrawing

CoreMorrowPZTstackactuatorscomeinawiderangeofsizesandmodels,withthesmallestsize upto122x13x17mm^3anddisplacementupto1μmThecrosssectionalareaofthepiezo stackis1.22x1.3mm^2,1.66x1.72mm^2,2x3mm^2,3.5x3.5mm^2,5x5mm^2,7x7 mm^225x25mm^2,thelargerthecrosssectionalarea,thehighertheoutputTheheightcan beselectedaccordingtothedesireddisplacementrangevalue.Thehighertheheight,thegreater

Usually,thevolumeofthegasdetectorissmall,sothesmallerthecomponentsize,thebetter

Becausetheabsorptionspectrallinesofdifferentgasestobemeasuredaredifferent,theoutput laserwavelengthofthelaserneedstochangeperiodically,sothatthecentralwavelengthofthe laserisadjustedtotheabsorptionspectrallineofthegastobemeasured,andselective absorptionisgenerated.Theperiodicchangeoftheoutputwavelengthofthelasercanbe adjustedbythepiezoactuatorThepiezoactuatorhasthecharacteristicsoffastresponsespeed andhighprecision,andisverysuitableforadjustingtheoutputspectralline.

FrequencyControlBasedonPiezoelectricTechnology

Note:Duetoalargenumberofproductmodels,onlypartofthemareshownhereFormore

information,pleasecontactoursalesengineer.

ApplicationofPiezoelectricTechnologyinTDLASGasDetection

Thefinalselectionwilldependonfactorssuchasoutputrequirement,displacementrequirement andspacelimitation CoreMorrowPiezoStackActuator TechnicaldataofCoreMorrowPiezoStacks

thedisplacement.

Inaddition,thepiezoactuatorispreloadedinternallytomakeitmoresuitablefordynamic applications.

ApplicationofPiezoelectricTechnologyinTDLASGasDetection

Themovingendofthepreloadedpiezoactuatorscanbeconnectedwithflathead,ballhead, internalthread,externalthread,orcustomizedconnection.

Inordertogetbetterprotectionandapplication,CoreMorrowprovidespreloadedpiezo actuators,withpiezoceramicstackedandencapsulatedintheinterior,sothattheyareprotected fromtheimpactofknock,humidityandsoon

CoreMorrowPreloadedPiezoActuators

2)CoreMorrowPreloadedPiezoActuators

ApplicationofPiezoelectricTechnologyinTDLASGasDetection TechnicaldataofCoreMorrowPreloadedPiezoActuators Note:Duetoalargenumberofproductmodels,onlypartofthemareshownhereFormore information,pleasecontactoursalesengineer.

Forthedetectionoflowerconcentrationsofgases,highergasabsorptionsensitivityisrequired.

Ofcourse,theaboveisjustoneoftheTDLASstructures,andthestructureofeachTDLASdevice willbedifferent

ListofGasSensitiveWavelengths Gassensitivewavelengthparametersinthefollowingtableforyourreference: Molecule MIR NIR TypicalApplication (ppb) WaveLength (nm) (ppb) WaveLength (nm) H2O 20 5940 60 1390 ProcessControl CO2 0.13 4230 3000 1960 Combustionsystem,coa

ApplicationofPiezoelectricTechnologyinTDLASGasDetection

Note:Forreferenceonly,differentsystemshavedifferentstructures

Thesensitivityofgasabsorptioncanbeimprovedbyincreasingthelengthofthegaschamber, butthiswillresultinthevolumeofthegasdetectionequipmentbecominglargerTosolvethis problem,manygasdetectiondeviceshavespeciallowlossmirrorsatbothendsofthegas chamberThelightemittedbythelaserisreflectedbackandforthinthegascavitybythe reflectionlens,sothatthelighthasmorecontactwiththegas,andthedistanceofthelight throughthegasbecomeslonger,soastoimprovethehighsensitivityofthetest,andtheweak absorptionlinecanalsobedetected.

AbsorptionSensitivitycanbeImprovedbyIncreasingLengthofGas Chamber

Lightoscillatesbackandforthinthegaschamber,sotheLDlinewidthneedstobeasnarrowas possible

ApplicationofPiezoelectricTechnologyinTDLASGasDetection lmine,hypoxiaprotecti Con,smokecontrol O 075 4600 30000 1570 500 2330 NO 5.8 5250 60000 1800 1000 2650 NO2 30 6140 340 680 N2O 044 4470 1000 2260 SO2 14 7280 CH4 17 3260 600 1650 Naturalgasextractiona Cndpipelines 2H2 35 7400 80 1520 HF 10 1310 ProcessControl HCl 0.83 3400 150 1790 HOilRefinery Br 72 3820 600 1960 HI 2100 1540 HCN 12 6910 290 1540 ProcessControl H2S 20000 1570 O3 11 9500 Air contamination measurement NH3 08 10300 800 1500 Refrigeratedfoodmanuf acturing,processingand preservation, beverageproduction, iceskatingrink CH2O 84 3550 50000 1930 ProcessControl PH3 6.2 10100 1000 2150 O2 78000 760 Hypoxiaprotection

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