REPORT NO.
210061
SOIL INVESTIGATION AND PRELIMINARY REMEDIATION STUDY FOR 20 GORDON PARADE AND 28 SALISBURY STREET, YARRAVILLE, VICTORIA
ENVIRONMENTAL EARTH SCIENCES VIC REPORT TO FASTNET CONSULTING PTY LTD DATE OCT 2010 VERSION 2
EXECUTIVE SUMMARY Environmental Earth Sciences VIC was requested by Fastnet Consulting (Fastnet) to undertake a soil investigation and preliminary remediation feasibility study for 20 Gordon Parade and 28 Salisbury Street, Yarraville, Victoria (the site). The site also covers the Salisbury Street road reserve which is owned by Maribyrnong City Council and separates the two properties. Fastnet have requested this work to determine the chemical status of soil at the site and compare it to previous data. We further understand that Fastnet are looking to potentially develop the site for medium density residential land use. As such, this work will also be used to determining the feasibility of the proposed development. The site is part of the Stony Creek flood plain and, based on the information available, it has been historically used for the disposal of municipal and construction waste, which was generated during the construction of the Westgate Bridge. The fill material disposed in the area was never capped however, after 1970 it was landscaped to create the Westgate Golf Course (located immediately east of the site) and the vacant properties at Gordon Parade and Salisbury Street. During filling activities, the bed of Stony Creek was relocated to approximately 30 metres east of the site and enclosed within a bluestone cobble lined drain (now concrete lined). Several previous environmental investigations have been undertaken at the site, including an environmental site assessment undertaken by Site Remediation Services (SRS) at 20 Gordon Parade and 28 Salisbury Street in 2002. The investigation indicated that soil concentrations of heavy metals, total petroleum hydrocarbons (TPH) and polycyclic aromatic hydrocarbons (PAH) were in excess of applicable guidelines. Additionally, potential for acid sulfate soils and the presence of asbestos were indentified onsite. Our investigation included sampling from 14 test pits across the site and laboratory analysis of selected samples for chemicals of potential concern (CoPC). Laboratory results indicated that concentrations of heavy metals (arsenic, copper and lead in particular), TPH, benzo(a)pyrene (BaP) and total PAH in soil were above human health guidelines. The identified volume of contaminated soil is approximately 7,400 m3, and ranges in depth between 0.5 and 3.3 mBGL across the site. Asbestos was identified at depths between 0.1 and 1.5 mBGL in four of seven samples analysed. Several samples were reported with high sulfur concentrations, however their actual and potential acidity was demonstrated to be very low due to the self buffering capacity of the soil. Samples collected from within the Salisbury Street road reserve reported the second highest concentration of total PAH (162.6 mg/kg) and the highest concentration of TPH (82,500 mg/kg). It is estimated that the road reserve alone contains approximately 1,560 m3 of impacted material. A feasibility study determined that the most viable and likely successful remediation option for the site is a cap and containment system. A cap and containment system would see contaminated soil remain in-situ beneath an engineered clay cap constructed across the surface of the entire site. This cap would remove the potential exposure pathways of soil, minimise infiltration of water through fill material and effectively manage leachate through a leachate collection system. This option is considered to be the most viable for remediation of
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the site as it: •
successfully removes potential exposure pathways of soil;
•
meets the requirements of Melbourne Water for development in areas prone to inundation;
•
effectively manages potential contaminant migration within the perched water table; and
•
is more cost effective than the other remediation options.
It is highly likely however, that further environmental investigations will be required in addition to implementation of the cap and containment system (if undertaken). The further works, as well as their estimated costs and timeframe are outlined below:
TABLE 1
FURTHER ENVIRONMENTAL WORKS
Works
Importance
Costs
Timing
mandatory
$75,000.00 $100,000.00
Month 1 to Month 13
possible (based on auditor’s requirements)
$5,000.00 $10,000.00
Month 2
mandatory
$35,000.00 $45,000.00
Month 2 to Month 6
likely
$20,000.00 $25,000.00
Month 6
Human health & ecological risk assessment
likely (based on auditor’s requirements)
$20,000.00
Month 7
Development of a Cleanup Plan
mandatory
$20,000.00 $25,000.00
Month 8
Development of an environmental management plan (EMP)
mandatory
$5,000.00
Month 11
desirable
$400,000.00 to $450,000.00
Month 11 to Month 12
Environmental audit of the site Additional soil sampling Detailed groundwater assessment Soil vapour assessment
Cap and containment system
Undertaking the works listed above, followed by the construction of the cap and containment system, is considered the most practical approach in successfully developing the site for its proposed medium density residential land use. The costs associated with undertaking the above scope of works is estimated at between $580,000.00 and $680,000.00 (excluding GST). The timeframe for undertaking the works, from the time of engaging an auditor to completion of the cap and containment system, is estimated at a minimum of 13 months. This investigation has been conducted for and is the property of Fastnet Consulting as per Environmental Earth Sciences VIC proposal PO210102 V2 dated 16 July 2010, with written confirmation to proceed with the assessment received on 26 July 2010.
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Project Manager Jordan Fraser Environmental Engineer Project Director / Internal Reviewer Averyll Spinks Senior Environmental Scientist 210061_ReportV2.doc
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TABLE OF CONTENTS 1
INTRODUCTION .......................................................................................................... 1
2
OBJECTIVES .............................................................................................................. 1
3
SITE INFORMATION ................................................................................................... 2
4
3.1
SITE LOCATION
2
3.2
HISTORICAL INFORMATION
2
3.3
PROPOSED DEVELOPMENT
2
GEOLOGY AND HYDROGEOLOGY ........................................................................... 3 4.1
GEOLOGY
3
4.2
HYDROGEOLOGY
3
5
PREVIOUS INVESTIGATIONS .................................................................................... 4
6
ENVIRONMENTAL EARTH SCIENCES VIC INVESTIGATION................................... 5
7
8
9
6.1
SITE INSPECTION
5
6.2
SOIL INVESTIGATION
5
6.2.1 Stratigraphy
6
6.3
GROUNDWATER
6
6.4
LABORATORY ANALYSIS
6
6.4.1 Analytical program
6
6.4.2 Quality assurance and quality control
7
DISCUSSION OF RESULTS ....................................................................................... 8 7.1
ASSESSMENT GUIDELINES
8
7.2
SOIL RESULTS
8
7.2.1 Inorganics
9
7.2.2 Organics
10
7.2.3 Asbestos
11
7.2.4 PASS
12
7.2.5 Salisbury Street road reserve
12
7.2.6 Comparison of results to previous data
12
REMEDIAL OBJECTIVES AND RESTRAINTS ..........................................................13 8.1
REGULATORY FRAMEWORK
13
8.2
REMEDIATION CONSTRAINTS
14
EVALUATION OF REMEDIAL OPTIONS ...................................................................15 9.1
DO NOTHING
15
9.2
HUMAN HEALTH AND ECOLOGICAL RISK ASSESSMENT
15
9.2.1 Summary
15
9.2.2 Limitations
16
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9.2.3 Cost estimation
16
9.2.4 Viability
16
OFFSITE LANDFILL DISPOSAL
16
9.3.1 Summary
16
9.3.2 Limitations
16
9.3.3 Cost estimation
16
9.3.4 Viability
17
ONSITE TREATMENT
17
9.4.1 Biological treatment
17
9.4.2 Thermal treatment
18
9.4.3 In-situ stabilisation
18
9.5
OFFSITE TREATMENT
18
9.6
ONSITE SOIL CAPPING AND CONTAINMENT (RECOMMENDED)
18
9.6.1 Summary
18
9.6.2 Limitations
19
9.6.3 Cost estimation
19
9.6.4 Viability
19
9.3
9.4
10
LIKELY REQUIRED WORKS .....................................................................................20 10.1 REQUIRED WORKS
20
10.1.1 Environmental audit
20
10.1.2 Additional soil sampling
20
10.1.3 Groundwater assessment
20
10.1.4 Soil vapour assessment
21
10.1.5 Risk assessment
21
10.2 LIKELY SCHEDULE OF WORKS
21
11
SUMMARY .................................................................................................................21
12
LIMITATIONS .............................................................................................................23
13
REFERENCES............................................................................................................24
FIGURES TABLES APPENDICES A
PRELIMINARY SITE DEVELOPMENT PLANS
B
PHOTOGRAPHIC LOG
C
GEOLOGICAL BORELOGS
D
LABORATORY TRANSCRIPTS & CHAIN OF CUSTODY FORMS
E
QUALITY ASSURANCE AND CONTROL PROCEDURES
F
PROVISIONAL TIMEFRAME
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1
INTRODUCTION
Environmental Earth Sciences VIC was requested by Fastnet Consulting (Fastnet) to undertake a soil investigation and preliminary remediation study for 20 Gordon Parade and 28 Salisbury Street, Yarraville, Victoria (the site). The site also covers the Salisbury Street road reserve which separates the two properties. The site is part of the Stony Creek flood plain and, based on the information available, it has been historically used for the disposal of municipal and construction waste which was generated during the construction of the Westgate Bridge. The fill material disposed in the area was never capped however, after 1970 it was landscaped to create the Westgate Golf Course (located immediately east of the site) and the vacant properties at Gordon Parade and Salisbury Street. During filling activities, the bed of Stony Creek was relocated to approximately 30 metres east of the site and enclosed within a bluestone cobble lined drain (now concrete lined). Before proceeding with the proposed development (potentially medium density residential), Fastnet have requested further delineation of fill material, particularly beneath the Salisbury Street road reserve. The findings of our investigation will be used to estimate the potential remediation requirements to assist in determining the feasibility of the development. This investigation has been conducted for, and is the property of Fastnet Consulting, as per Environmental Earth Sciences VIC proposal PO210102 V2 dated 16 July 2010, with written confirmation to proceed received on 26 July 2010. Environmental Earth Sciences VIC is not responsible for variations due to alterations of site conditions since the time of inspection, for example through illegal dumping of chemicals.
2
OBJECTIVES
•
The objective is to determine the chemical status of soil at the site and compare it to previous data. We further aim to determine the feasibility of any remediation options.
•
To achieve this objective, the scope included:
•
review of previous environmental site investigation reports undertaken by SRS Australia Pty Ltd (SRS);
•
further investigation into the extent and contamination status of fill and natural material at 11 borehole locations across the site;
•
investigation into the extent and contamination status of fill and natural material at 3 targeted borehole locations beneath the proposed Salisbury Street extension footprint; and
•
preparation of a preliminary feasibility study.
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1
3 3.1
SITE INFORMATION Site location
The location of the site is shown on Figure 1, and the area of investigation is presented in Figure 2. The site is generally rectangular in shape and covers three separate parcels of land. The following details are provided for the site: Address:
20 Gordon Parade & 28 Salisbury Street
Suburb/State:
Yarraville, Victoria
Lot/Plan or Crown:
Lot 4 of land plan 76315 & Lots 1 and 2 of town plans 857507 and 908004
Council:
Maribyrnong
Land area:
3,752 m2
Planning Zone:
Residential 1 Zone (R1Z)
Planning Overlays:
Development Contributions Plan Overlay (DCPO) Land Subject to Inundation Overlay (LSIO)
The area of investigation also included the Salisbury Street road reserve, which covers approximately 700 m2 and is situated between the two properties. The total area under investigation was approximately 4,452 m2.
3.2
Historical information
Detailed descriptions of site history have been given in several previous environmental reports (see Section 5). Based on a review of the available historical information, aerial photographs and Royal Historical Society of Victoria (RHSV) records, the site was originally located within a shallow gully formed by the flow of Stoney Creek. Sometime after 1921, the site and the surrounding area (now comprising some 15 hectares including the Westgate Golf Course) was filled with municipal waste from the municipalities of Maribyrnong and Hobson’s Bay. During the construction of the Westgate Bridge in the late 1960s and early 1970’s, additional fill, mostly construction waste, was again disposed of in the area. The fill material was not capped however, it was landscaped to create the Westgate Golf Course after 1970. During either the filling with municipal waste or the construction of the Westgate Golf Course, the bed of Stony Creek was moved approximately 30 metres east from the site and enclosed within a bluestone cobble lined drain (now concrete lined). No records relating to residential properties or other former developments at the site were identified.
3.3
Proposed development
It is proposed that the site be developed for medium-density residential land use. The site is subject to inundation and as such, the proposed development must meet Melbourne Water’s requirements for development in flood prone areas. It is a requirement of Melbourne Water that finished floor levels are a minimum of 600 mm above the applicable flood level (4.25 210061_ReportV2.doc
2
metres AHD). According to recent survey information, the current surface level of the site is between 2.61 – 3.61 mAHD, therefore extensive filling will be required. A review of the preliminary conceptual development plans drawn by DPS Engineers (presented in Appendix A) indicated approximately 3,175 m3 of fill will be required across the site to meet the finished floor levels set by Melbourne Water. This fill may potentially act as part of an engineered cap across the site if this remediation option is pursued.
4 4.1
GEOLOGY AND HYDROGEOLOGY Geology
The geology of the Yarraville area has been described in the Geological Survey of Victoria (1974), 1:63 360 Geological Map – Melbourne as predominantly consisting of Newer Volcanics basalt with sedimentary deposits of Coode Island Silt following the Stoney Creek and Yarra River systems. The Newer Volcanics formation is the major surface geological formation at the site and is described as olivine basalt, dark to light grey and coarsely vesicular with minor interbedded silty sand and baked soils. The basalt flow is part of the late Quaternary period of approximately 2 to 5 million years ago and is expected to be the major surface aquifer at the site. The recent Coode Island Silt (CIS) formation is identified to the east of the site and consists of silt, silty clay, sandy clay which is often dark grey with minor peat and shell beds. The CIS sediments are extensive in the area and in many places contain sufficient iron sulphides to produce a potential acid sulfate soil (PASS) when drained and exposed to oxidation. The regional topography is relatively flat with a gentle slope in an eastern direction towards the Yarra River. Site topography reflects that of the Yarraville area, sloping east toward the Stoney Creek canal.
4.2
Hydrogeology
The Department of Natural Resources and Environment (DNRE) (1995) South Eastern Victoria Regional Aquifer Systems defines groundwater in the Upper Tertiary Aquifer System at the site as Segment C, with a Total Dissolved Solids (TDS) range of 3,501-13,000 mg/L. According to the State Environment Protection Policy (SEPP) (2002) Prevention and Management of Contaminated Land, the site requires the protection of the following beneficial uses: •
maintenance of ecosystems;
•
stock watering;
•
industrial water use;
•
primary contact recreation; and
•
buildings and structures.
Groundwater movement within this system occurs through fractures in the basalt and within partially weathered zones, formed between different lava flows of the Newer Volcanics 210061_ReportV2.doc
3
formation. Yields within bores situated in the Newer Volcanics basalt of this area are relatively low. They are generally between 0.5 and 3.0 L/sec due to the limited and varying weathering of the Quaternary basalt. Regional groundwater flow is expected to be in an east/south eastern direction.
5
PREVIOUS INVESTIGATIONS
Previous environmental assessments relating to the site include: •
Dames & Moore (1993), Report on a Preliminary Environmental Assessment of Lot 4, Salisbury Street, Yarraville;
•
Dames & Moore (1996), Environmental Site Assessment, Vacant Land, lot 4 Salisbury Street, Yarraville;
•
SRS Australia Pty Ltd (2002), Environmental Site Investigation Report of Residential 3 Zoned, Land on Titles: Vol. 8780 Fol. 549 & Vol. 8780 Fol. 550, End of Gordon Parade, Yarraville, Victoria; and
•
SRS Australia Pty Ltd (2002), Environmental Site Investigation Report of Residential 3 Zoned, Lot No. 3, End of Salisbury Street, Yarraville, Victoria.
Environmental Earth Sciences VIC conducted a review of the investigations undertaken by SRS in 2002. Test-pitting works conducted by SRS in 15 locations indicated that the natural surface was encountered at approximately 1.0 metre below ground level (mBGL) in the south western corner and approximately 3.2 mBGL in the north eastern corner of the Salisbury Street property. No sub-surface investigation was undertaken within the Salisbury Street road reserve. Fill material was found to consist of a wide variety of soild wastes including plastics, wood, metal, bricks, bluestone and general municipal garbage with varying amounts of soil, gravel and clay. Laboratory analysis of soil samples reported concentrations of heavy metals in excess of the National Environmental Protection Measure 1999 (NEPM) Health Investigation Levels (HILs) “A” for low density residential setting and “D” for medium to high density residential settings. Total petroleum hydrocarbons (TPH) and polycyclic aromatic hydrocarbons (PAH) were found in excess of the NSW Department of Climate Change (DECC) and NEPM HIL A guidelines, respectively. Additionally, potential acid sulfate soils and the presence of asbestos were indentified onsite. Grab samples were collected from the perched water table which was encountered between 1.5 and 2.4 mBGL. Laboratory analysis reported concentrations of cobalt (Co), copper (Cu) and TPH in excess of applicable guidelines. Using the data obtained, SRS provided recommendations and cost estimates for the remediation of both the Gordon Parade and Salisbury Street properties. In order to develop the site for low density residential use, it was outlined that the contaminated material would require excavation and offsite disposal with additional monitoring and management, at a cost of approximately $ 2.85 million. In order to develop the properties for low density residential use, it was recommended that contaminated material be buried onsite and capped, with additional management and a groundwater investigation, at an estimated cost of $ 590,000.00.
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6
ENVIRONMENTAL EARTH SCIENCES VIC INVESTIGATION
Environmental Earth Sciences VIC personnel undertook an initial site inspection on 5 August 2010 prior to site works. The inspection included a site walkover, visual inspection and service location undertaken by J.U.L.S. The field works, conducted on 9 August 2010, included targeted soil test pit investigation and sampling. A photographic log of site works is presented in Appendix B.
6.1
Site inspection
At the time of our site inspection, the site was bound by residential properties to the north of Gordon Parade, the West Gate Golf Course to the east, commercial properties to the south and residential properties to the west. Primary site access was via the end of Gordon Parade. The site was vacant with no indications of former infrastructure. Grass covered the majority of the site and the only other vegetation present was a row of gum trees offsite to the east. Cut and fill activities are expected to have occurred at the site due to an abrupt change in surface level within the north eastern boundary of the site. Two stockpiles of soil were also present onsite at the time of inspection. Material within the stockpiles consisted of loose, grey/brown silty clay with sand and gravel.
6.2
Soil investigation
On 9 August 2010, Environmental Earth Sciences VIC undertook a soil investigation which consisted of the excavation of fourteen test pits (TP1 – TP14) across the site using a subcontracted excavator. Three of the fourteen test pit locations were located within the Salisbury Street road reserve. Samples were collected at the surface, at 0.5 m intervals or at distinct changes in lithology. Sixty-six discrete samples were collected from the test pits as well as six quality control samples. Soil samples for analysis were placed into laboratory prepared glass jars or sealable plastic bags, depending on the analyte to be tested. The jars and bags were labelled with the borehole number, depth of discrete sample collection, site reference and date before being placed in a cooler with ice. Samples were also selectively analysed in the field using a photoionisation detector (PID), which gives an indication of the likely presence of volatile hydrocarbons. The PID readings were generally low across the site (ranging between 0.0 ppm and 10.2 ppm), however elevated readings of 20.8 ppm and 25.4 ppm were recorded within test pits TP5 and TP9, at which strong hydrocarbon odours were noted. Following sampling, material from each test pit was reinstated at the depth from which it was excavated to reduce cross contamination between soil profiles. A small volume of soil not able to be reinstated was added to the two existing stockpiles onsite. All sampling procedures were undertaken in accordance with Environmental Earth Sciences Soil, gas and groundwater sampling manual (2009) and other relevant guidelines. 210061_ReportV2.doc
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6.2.1
Stratigraphy
Field observations such as soil colour, texture, pH and odour were used to identify changes in lithology. These observations are detailed within the geological borelogs presented in Appendix C. Several cross sections were developed using borelogs from the 2010 field investigation and those developed by SRS in 2001 (Figures 3-5). Fill material was encountered across the site to a depth ranging from approximately 1.8 to 3.8 mBGL. The depth of fill generally increased toward the east/south east of the site, with depth of fill greatest at test pit locations TP5 (3.8 m) and TP11 (>3.2 m). This material comprised of loose, brown silty clay with solid waste inclusions (plastics, wood, metal, bricks, bluestone and general municipal garbage) below a layer of stiff, brown silty clay. Underlying this infilled material in several locations was reworked natural silty clay with minor rubble (glass and wood) and weathered basalt floaters. The natural soil was generally described as being medium dense, grey clay with minor silt. This natural soil is considered to be primarily derived from weathered Newer Volcanics basalt, which was encountered at several test pits between approximately 2.2 and 3.4 mBGL. Soil considered to be derived from the CIS formation was encountered between 1.5 and 1.8 mBGL in test pits TP3, TP4, TP5, TP8, TP9 and TP10. Note that the loose, black, slightly clayey silt was saturated in the majority of these locations. Soil pH generally ranged between 6.0 and 8.0 at these locations. Inclusions of glass and timber in some locations indicated that the CIS sediments were likely to be reworked natural material. Soft, silty clay with dark staining and strong hydrocarbon odour was identified within the saturated zone at approximately 1.9 mBGL in test pits TP5, TP9 and TP11. Fill material immediately above the impacted zone within TP9 (within the Salisbury Street road reserve) was found to contain oily rags, rubber, damaged tins/drums and machinery parts.
6.3
Groundwater
Groundwater at the site is expected to occur within the Newer Volcanics basalt at a depth of less than 10 mBGL. No groundwater was collected or analysed during the investigation. A perched water table was observed in the majority of the test pits at depths between 1.8 and 2.3 mBGL. This perched water table is believed to be due to the low permeability of natural clay limiting downward migration of infiltrated water.
6.4
Laboratory analysis
The schedule for laboratory analysis was defined by the scope of our proposal and review of the previous environmental assessments. Soil samples were selected for analysis on the basis of their location, depth, field observations such as texture, colour, pH and PID reading, and location on the site relative to former sampling locations. Generally, samples from the fill material were selected for a wider range of analytes including CoPC identified in the previous investigations.
6.4.1
Analytical program
Sixty-six discrete soil samples were collected from fourteen test pits during the soil investigation. Of these, fifty-nine samples were selectively analysed for a range of chemicals of potential concern (CoPC). Three blind duplicate (intra-laboratory) samples and three split
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6
duplicate (inter-laboratory) samples were also collected and analysed for quality control purposes at a rate of 5.1 %. All soil analysis was undertaken by Australian Laboratory Services (ALS), Labmark and Australian Safer Environment & Technology (ASET), which are all NATA accredited for the methods used. Laboratory transcripts for soil samples are presented in Appendix D. Soil samples were selectively analysed for the following: •
heavy metals (silver [Ag], arsenic [As], cadmium [Cd], chromium [Cr], cobalt [Co], copper [Cu], mercury [Hg], molybdenum [Mo], nickel [Ni], lead [Pb], selenium [Se], tin [Sn] and zinc [Zn]);
•
total and free cyanide;
•
TPH;
•
benzene, toluene, ethylbenzene, xylene (BTEX);
•
PAH;
•
phenols;
•
asbestos;
•
other analytes listed in the IWRG 621 screen; and
•
PASS analytes (including cation exchange capacity [CEC], organic carbon [OC], net acid generating potential [NAGP], chromium suite and SPOCAS suite).
Following the initial laboratory analysis, the following additional analysis was undertaken on selected samples: •
Australian Standard Leachate Procedure (ASLP) for benzo(a)pyrene (BaP) on samples TP6(0.0-0.1) and TP9(2.0-2.1);
•
ASLP for PAH on sample TP1(1.5-1.6);
•
ASLP for As on samples TP2(3.2-3.3) and TP7(2.0-2.1);
•
ASLP for Cu on sample TP10(1.8-1.9); and
•
TPH speciation on samples TP5(2.0-2.1), TP9(2.0-2.1) and TP11(1.9-2.0).
6.4.2
Quality assurance and quality control
Quality control is achieved by utilising NATA accredited laboratories, using standard methods supported by internal duplicates, the checking of high, abnormal or otherwise anomalous results against background and other chemical results for the sample concerned. Quality assurance is achieved by confirming field or anticipated results based upon the comparison of field observations with laboratory results. In addition, the laboratory undertakes additional duplicate analysis as part of their internal quality assurance program on the basis of one duplicate for every 20 analysed. Field observations are compared with laboratory results when they are not as expected and confirmation, re-sampling and re-analysis are undertaken if results cannot be correlated. In brief, field duplicate results were generally within the acceptable range of reproducibility and all duplicates and standards were within the acceptable reproducibility range. Further to laboratory quality assurance, intra-laboratory comparison is achieved through comparison of analytical results of samples with their corresponding blind duplicate (BD). The split 210061_ReportV2.doc
7
duplicates were sent to Labmark and the results are the basis for the inter-laboratory comparison. The potential for cross contamination of samples from sampling equipment is considered to be very low due to sampling decontamination procedures. Full laboratory transcripts and chain of custody forms are presented in Appendix D, while further discussion on QA/QC is provided in Appendix E.
7 7.1
DISCUSSION OF RESULTS Assessment guidelines
The results of the soil investigation have been assessed in reference to the following assessment guidelines: •
National Environmental Protection Council (NEPC) (1999) – NEPM Ecological Investigation Levels (EILs); o
•
NEPC (1999) – NEPM Health Based Soil Investigation Levels (HILs); o
•
the IWMP (WASS) outlines the requirements for management of WASS, including reuse and disposal. Publication 655 provides an outline of WASS identification, assessment, classification and management requirements and methodologies; and
West Australian Department of Health (WA DoH) (2009) – Guidelines for the Assessment and Remediation and Management of Asbestos-Contaminated Sites in Western Australia; o
7.2
IWRG621 outlines the soil hazard categorisation threshold concentrations for soil for offsite disposal;
Industrial Waste Management Policy (IWMP) on waste acid sulfate soils (WASS) & EPA Victoria Publication 655.1 (1999); o
•
this document provides guidelines for contaminants commonly associated with service station sites for which HILs have not been provided;
Victorian EPA Industrial Waste Resource Guidelines (IWRG) (2009) – Publication IWRG621 - Soil hazard categorisation and management; o
•
HILs provide guidelines for maximum allowable concentrations for a variety of contaminants depending on land use. Refer to Table 1 for a copy of these guidelines;
NSW DECC (1994) – Guidelines for Assessing Service Stations; o
•
EILs provide guidance in relation to phytotoxic parameters for urban settings;
this publication is the adopted asbestos management document due to a lack of Victorian and National legislation.
Soil results
The soil on the site has been impacted by historical activities, namely the placement of fill material containing solid municipal and construction waste. A summary of soil laboratory
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results is presented in Table 2 and described below. Complete laboratory transcripts are presented in Appendix D.
7.2.1
Inorganics
Soil samples were analysed for Ag, As, Cd, Cr, Co, Cu, Hg, Mo, Ni, Pb, Se, Sn and Zn in both fill and natural material across the site. Concentrations of Cr (III & VI), Ag, Mo, Se and Sn were reported below the laboratory limit of reporting (LOR) or the applicable guidelines in each sample analysed. Concentrations of As, Cd, Co, Cu, Hg, Ni, Pb and Zn were reported in excess of the applicable guidelines as detailed below. Samples exceeding NEPM HIL A and NEPM HIL D guidelines for the heavy metals of highest concentrations (As, Cu and Pb) are presented in Figures 6 to 8. Arsenic •
detectable As concentrations ranged from 5 mg/kg to 590 mg/kg;
•
As was reported to be in excess of NEPM EIL and ‘fill material’ guidelines in 34 of the 55 samples analysed;
•
As was in excess of NEMP HIL A guidelines in samples TP1(0.4-0.5), TP3(2.0-2.1), TP5(0.4-0.5), TP6(0.4-0.5), TP7(0.0-0.1), TP8(1.9-2.0), TP9B(2.5-2.6), TP10(1.4-1.5), TP12(1.9-2.0), TP13(1.5-1.6), TP14(0.9-1.0) and TP14(2.8-2.9);
•
As was in excess of NEPM HIL D guidelines in samples TP2(3.2-3.3) and TP7(2.0-2.1) only; and
•
As was in excess of IWRG guidelines for ‘Category C Contaminated Soil’ in TP2(3.23.3).
Cadmium •
detectable Cd concentrations ranged from 2 mg/kg to 16 mg/kg; and
•
Cd was found to be in excess of NEPM EIL and IWRG guidelines for ‘fill material’ in samples TP2(3.2-3.3), TP4(1.4-1.5), TP9B(2.5-2.6) and TP11(1.9-2.0).
Cobalt •
detectable Co concentrations ranged from 46 mg/kg to 320 mg/kg; and
•
Co was reported in excess of NEPM HIL A guidelines in samples TP2(0.4-0.5), TP5(1.4-1.5), TP10(1.4-1.5), TP11(0.9-1.0) and TP14(0.4-0.5).
Copper •
detectable Cu concentrations ranged from 7 mg/kg to 2,000 mg/kg;
•
Cu was in excess of NEPM EIL and IWRG guidelines for ‘fill material’ in 29 of the 55 samples analysed; and
•
Cu was in excess of NEPM HIL A guidelines in samples TP10(1.4-1.5), TP10(1.9-2.0 – split duplicate sample) and TP11(1.9-2.0).
Mercury •
detectable Hg concentrations ranged from 0.1 mg/kg to 2.6 mg/kg; and
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•
Hg was in excess of NEPM EIL and IWRG guidelines for ‘fill material’ in samples TP5(2.0-2.1), TP8(0.2-0.3), TP9B(2.5-2.6) and TP11(1.9-2.0);
Nickel •
detectable Ni concentrations ranged from 5 mg/kg to 141 mg/kg; and
•
Ni was in excess of NEPM EIL and IWRG guidelines for ‘fill material’ in 18 of the 55 samples analysed.
Lead •
detectable Pb concentrations ranged from 14 mg/kg to 822 mg/kg;
•
Pb was reported in excess of NEPM EIL guidelines in samples TP3(0.4-0.5), TP3(1.41.5), TP9B(2.5-2.6) and TP11(1.9-2.0); and
•
Pb was in excess of NEPM HIL A and IWRG guidelines for ‘fill material’ in samples TP2(3.2-3.3), TP3(0.4-0.5), TP3(1.4-1.5), TP4(1.4-1.5), TP5(0.4-0.5), TP8(0.2-0.3), TP9B(2.5-2.6), TP10(1.4-1.5), TP11(0.0-0.1), TP11(1.9-2.0), TP12(0.4-0.5) TP13(0.00.1) and TP14(0.9-1.0).
Zinc •
detectable Zn concentrations ranged from 44 mg/kg to 3,960 mg/kg; and
•
Zn was found to be in excess of NEPM EIL and IWRG guidelines for ‘fill material’ in 28 of the 55 samples analysed.
Following the initial analysis, selected samples underwent ASLP analysis in order to determine the potential bioavailability (See Table 3). Analysis indicates that As and Cu in the samples analysed have some potential to become bioavailable however, they are either on or below the upper ASLP limits for categorisation as ‘Category C Contaminated Soil’. Bioavailability factors (BF) were not determined for Cu due to the lack of a total concentration in soil, however BFs of 2.4 % and 2.5 % determined for As, confirmed the low bioavailability of As in soil.
7.2.2
Organics
Soil samples analysed for polychlorinated biphenyls (PCB), phenolic compounds, monocyclic aromatic hydrocarbons (MAH), organophosphorus pesticides (OPP) and volatile halogenated compounds (VHC) each revealed concentrations that were below the laboratory LOR or applicable guidelines in both fill and natural material. Concentrations of BaP, total PAH and TPH were reported in excess of the applicable guidelines as detailed below. Note that samples exceeding NEPM HIL A, NEPM HIL D and NSW DECC guidelines are presented in Figures 9 to 11: PAHs •
detectable BaP concentrations ranged from 0.6 mg/kg to 20.0 mg/kg;
•
BaP was reported to be in excess of NEPM HIL A guidelines in samples TP5(1.4-1.5), TP8(0.9-1.0), TP9(1.9-2.0), TP11(2.9-3.0) and TP12(1.4-1.5);
•
BaP was in excess of NEPM HIL D guidelines in samples TP1(1.5-1.6), TP3(1.4-1.5), TP6(0.0-0.1) and TP9(2.0-2.1);
•
detectable total PAH concentrations ranged from 0.6 mg/kg to 210.5 mg/kg;
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•
total PAH was found to be in excess of NEPM HIL A guidelines in samples TP3(1.41.5), TP5(1.4-1.5), TP11(2.9-3.0) and TP12(1.4-1.5); and
•
total PAH was in excess of NEPM HIL D guidelines in samples TP1(1.5-1.6), TP6(0.00.1) and TP9(2.0-2.1).
TPH •
detectable TPH (C6-C9) concentrations ranged from 30 mg/kg to 106 mg/kg;
•
detectable TPH (C10-C36) concentrations ranged from 140 mg/kg to 82,500 mg/kg;
•
TPH (C6-C9) was in excess of NSW DECC guidelines in sample TP9(2.0-2.1); and
•
TPH (C10-C36) was reported to be in excess of NSW DECC guidelines in samples TP2(3.2-3.2), TP3(1.4-1.5), TP5(2.0-2.1), TP5(2.9-3.0), TP9(2.0-2.1), TP9B(2.5-2.6), TP11(1.7-1.8), TP11(1.9-2.0) and TP11(2.9-3.0).
Further analysis was undertaken in order to determine the potential bioavailability of BaP, total PAH and TPH within soil. Results indicate that BaP had a leachate concentration lower than the laboratory LOR in each of the three samples analysed. Phenanthrene was the only PAH to report a leachate concentration above the laboratory LOR, at 2.2 µg/L. The determined BF of 0.05% indicates that total PAHs in soil have a very low potential to become bioavailable. The leachate concentration for TPH was reported to be above the laboratory LOR for TPH (C16-C28) only in one of the two samples analysed. The determined BF of 18.5% indicates that TPH in soil also has a moderate to low potential to become bioavailable. Samples TP5(2.0-2.1), TP9(2.0-2.1) and TP11(1.9-2.0) underwent TPH speciation to determine the concentrations of aromatic and aliphatic hydrocarbon fractions for assessment against NEPM HIL A and NEPM HIL D guidelines (See Table 4). Speciation results indicate that each sample was in excess of NEPM HIL A and NEPM HIL D guidelines for the aromatic TPH (>C16-C35) fraction, with concentrations ranging between 660 mg/kg and 8,590 mg/kg. Additionally, sample TP9(2.0-2.1) reported concentrations of the aliphatic TPH (>C16-C35) fraction in excess of NEPM HIL A guidelines. A soil silica gel cleanup (SGC) was undertaken on samples TP3(1.4-1.5) and TP11(1.9-2.0) to remove any polar natural organic carbons and display only non-polar components related to petroleum products. Results of the SGC are presented against the primary TPH results in Table 5. The results indicate that the samples contain some polar natural organic carbons, however the majority of TPH reported initially relate to petroleum products in soil.
7.2.3
Asbestos
Asbestos was not visibly identified during the field soil investigation however, due to historical activities, seven soil samples were forwarded to ASET and analysed for the presence of asbestos. Results indicated that asbestos was detected in the following samples: •
crysotile asbestos was identified in samples TP5(0.4-0.5), TP7(1.4-1.5), TP9(0.4-0.5) and TP11(0.0-0.1); and
•
crocidolite asbestos was identified in sample TP7(1.4-1.5).
The presence of crysotile asbestos in sample TP11(0.0-0.1) indicates that the site does not comply with the WA DoH remediation objectives for asbestos impacted sites, which require the top 10 cm of soil to be completely free of visible asbestos. Asbestos was also identified in the top 10 cm of soil in the SRS (2002) investigation at sample locations V5 and V6. 210061_ReportV2.doc
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A review of the concentration of asbestos (%w/w) across the site against the WA DoH soil asbestos investigation criteria was beyond the scope of this investigation. However, the presence of asbestos to a depth of 1.5 mBGL will result in the soil (at the affected locations) being classified as ‘Category C Contaminated Soil’ (minimum) for potential offsite disposal purposes.
7.2.4
PASS
Soil samples collected from the material representative of CIS sediments were selectively analysed for a range of PASS indicators. A summary of laboratory results for PASS samples are presented in Tables 6 and 7, with full laboratory transcripts presented in Appendix D. Five soil samples were analysed for total sulfur and compared to criteria for classification of acid sulfate soil (ASS) outlined in the EPA Victoria Publication 655.1. Results demonstrated that samples TP4(2.1-2.2), TP8(2.0-2.1), TP10(1.8-1.9) and TP11(1.9-2.0) contained elevated concentrations of sulfur. The sulfur concentrations between 0.13 and 0.73 % S indicated that the soil had the potential to become ASS when excavated (exposed to oxygen). Additional laboratory analysis was undertaken on samples TP4(2.1-2.2) and TP10(1.8-1.9), including peroxide oxidisable sulfur and chromium reducing sulfur suites, to determine the net acidity and actual risk of ASS production. Based on the results presented in Table 7, and comparison against the risk criteria listed in Table 8, sample TP4(2.1-2.2) is classified as ‘Class 1 No Risk – No Sulfur’. Please note that Class 1 soil is not ASS. Sample TP10(1.8-1.9) is classified as ‘Class 2 No Risk – Non Reactive’. Class 2 soil, while containing elevated sulfur levels, is completely self buffering and requires no form of management for PASS. These findings are confirmed by the complete absence of any actual acidity (reported as TAA) or potential acidity (reported as TPA) in both samples analysed for these parameters.
7.2.5
Salisbury Street road reserve
The Salisbury Street road reserve covers approximately 700 m2 between the Gordon Parade and Salisbury Street properties. The area is owned by the Maribyrnong City Council and is intended to be developed as an extension of Salisbury Street (see Appendix A). Three test pits (TP7 – TP9) were excavated within the road reserve with samples analysed for a range of CoPC. The results reported elevated concentrations of heavy metals, PAH and TPH (outlined in Sections 7.2.1 and 7.2.2), as well as the presence of asbestos (Section 7.2.3). Samples analysed from test pit TP9 reported the second highest concentration of total PAH (162.6 mg/kg) and the highest concentration of TPH (82,500 mg/kg). It is estimated that the road reserve contains approximately 1,560 m3 of impacted material.
7.2.6
Comparison of results to previous data
Test pits TP5, TP10 and TP12 were assessed to target the former test pit locations. This enabled some comparison between the soil chemical data obtained during each investigation. Generally, results obtained from targeted borehole locations indicated the following;
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•
As and Pb were reported to have slightly higher concentrations in the recent investigation;
•
Co and Cu were reported to have significantly lower concentrations in this latest sampling event when compared to previous investigations;
•
Zn was reported in significantly higher concentrations during this investigation;
•
total PAH was reported to have a much higher concentration in TP12(1.4-1.5) than its comparison sample X7(1.5); and
•
TPH was reported to have a much higher concentration in TP5(2.0-2.1) than its comparison sample V8(2.0).
Analysis of the data across the entire site indicates that there are significant variations in contaminant concentrations reported in each investigation. Concentrations presented in Figures 6 to 11 demonstrate the following: •
there are greater occurrences of BaP, total PAH and TPH (and at much higher concentrations) in this investigation;
•
elevated TPH concentrations were generally reported at greater depths in this investigation when compared to previous assessments; and
•
fewer locations reported concentrations of Cu in excess of applicable guidelines during this investigation.
The differences between chemical concentrations reported in each investigation are considered to be due to the heterogeneity of fill material across the site. Additionally, the lack of survey data of previous test pit locations meant that targeted locations were estimated and samples may therefore not be representative of the material analysed in 2002.
8 8.1
REMEDIAL OBJECTIVES AND RESTRAINTS Regulatory framework
The investigation levels for this site are dictated by the ultimate requirement for remediation of soil to a level that provides protection to potential beneficial users of land. In accordance with the SEPP, and the most likely future land use being residential with minimum soil access, the following beneficial uses are to be protected. •
maintenance of highly modified ecosystems;
•
human health;
•
buildings and structures; and
•
aesthetics.
The maintenance of natural and modified ecosystems, and production of food and fibre, are not considered relevant beneficial uses for this site due to the highly modified nature of the site (impacted by historical filling) and the current status of Edgars Creek (diverted and concrete lined). While all potential beneficial uses of land should be considered, these beneficial uses are not likely to require future protection.
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The SEPP lists indicators and objectives for each beneficial use to be protected and in turn, lists the relevant guidelines. The NEPM HIL D investigation levels for soil are to be used in the assessment of contamination for the protection of human health and ecosystems at the site. The provisional NEPM EILs are derived from values supplied in ANZECC 1992a and from soil survey data from four Australian capital cities. The EILs for soil are limited and interim in nature and, although widely adopted, are based on total metal concentrations in soil, which bears little relevance to the protection of plant and soil fauna. In light of this, EIL values should be used as an indicator for potential ecological impact, with other factors considered in determining the potential for ecological impact.
8.2
Remediation constraints
Prior to the assessment of available remedial technologies, it is important to identify the restraints of the site that will potentially impact on remediation. These are outlined as follows: •
the subject site includes the Salisbury Street road reserve, which separates the Gordon Parade and Salisbury Street properties. The road reserve covers approximately 700 m2 and contains a large volume of fill material, which is reported to contain concentrations of organic and inorganic chemicals above the adopted guidelines. The area is owned by the Maribyrnong City Council and would need to be included in any remediation activities undertaken prior to development of the site;
•
the presence of CIS sediments across the site indicates the potential for acid sulfate soils to be generated during excavation activities (if any). Two soil samples analysed for PASS indicated that no risk exists within that material, however the inconsistent deposition of fill and natural material across the site may require some form of PASS management if excavation is to be undertaken;
•
the variety of soil contaminants identified may influence which remediation techniques could be effectively implemented at the site. Treatment of inorganic and organic chemicals is generally undertaken using different methods, however integrating different types of remediation is a widely adopted practice. The presence of asbestos and inert waste (concrete, brick, etc) will also require remediation or management in order to protect the beneficial uses of the site;
•
a perched water table was observed at approximately 1.8 to 1.9 mBGL, with relatively high recharge toward the east/south east of the site. This water may impact any remediation activities, as contamination has been identified within and below this saturated zone;
•
no detailed investigations have been undertaken at the site to determine the chemical status of groundwater or its potential influence on future land use;
•
site access occurs via Gordon Parade or Salisbury Street, which are both restricted for heavy vehicle access due to the narrow streets and low overhead power lines; and
•
the size of the site also limits remediation technologies, as full excavation of the impacted material is likely to be extensive. Furthermore, the local residential setting requires strict environmental controls for several potential remediation options, as air quality, noise and aesthetic impacts (among others) will need to be managed.
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9
EVALUATION OF REMEDIAL OPTIONS
The SEPP outlines that where a state of pollution exists, the land must be cleaned up and/or managed so that: •
there is no immediate threat to human health (onsite or offsite) or the environment offsite;
•
contamination does not preclude protected beneficial uses of the relevant land use; and
•
the risk of contamination from the site adversely affecting any beneficial use protected under any SEPP offsite is reduced to a level acceptable to the Authority.
The assessment of the practicability of remediation of soil contamination identified within the site boundary is provided in the following sections. The assessment includes the consideration of financial, logistical, technical and environmental issues.
9.1
Do nothing
The “do nothing” option involves the site being left in its current condition with no remediation or management implemented. Onsite contamination has been identified in excess of the health investigation levels outlined for each potential land use, and ecological guidelines. If no remediation or management of land is undertaken, the current status of the site will not be acceptable for any land use outlined in the SEPP, including the proposed medium density residential. Additionally, the historic use of the site for the disposal of municipal and construction waste, as well as the extent of contamination identified onsite, ‘may’ trigger the EPA to require the site be cleaned up to reduce the risk to human health and the environment. Due to the reasons listed above, the “do nothing” option is not considered viable for the site.
9.2 9.2.1
Human Health and Ecological Risk Assessment Summary
Assessment of current chemical levels in soil would be evaluated from a human health and ecological perspective to determine whether soil is safe to remain in-situ with no further management. A quantitative risk assessment would be achieved through: •
a toxicity assessment involving research into the CoPC, their behavioural properties, toxicology (including carcinogenicity) and dose-response relationships;
•
an exposure assessment that would consider different exposure scenarios for low-level contaminants remaining in place, and provision of a series of settings to allow risk characterisation;
•
a risk characterisation, which would aim to arrive at a series of site specific criteria values for soil, based on factors such as depth and position on the site; and
•
a flora and fauna baseline study (if needed).
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9.2.2
Limitations
The high concentrations of several contaminants are such that they are likely to present a risk to human health and the environment if they remain in-situ without management following a risk assessment. Note however, that no groundwater or soil vapour assessments have been conducted at the site. Additionally, the site remains between 1.67 and 0.64 m below the applicable flood level, so further works would be required to meet the requirements of Melbourne Water.
9.2.3
Cost estimation
The cost to undertake a Human Health & Ecological Risk Assessment is estimated at approximately $20,000.00. It is likely that further investigations are required at the site in order to determine the risks to human health and the environment (i.e. groundwater and soil vapour). These further works would be in addition to the estimated cost of a Human Health & Ecological Risk Assessment, and could potentially range between $20,000.00 and $50,000.00.
9.2.4
Viability
This risk assessment may determine that no unacceptable risk exists with some identified contaminants remaining in place. However, it is likely that several contaminants, TPH and PAH in particular, are likely to remain a risk to human health and the environment if no further remediation or management is undertaken. In that instance, the site would remain unacceptable for any land use outlined in the SEPP, including the proposed medium density residential. The risk assessment is a viable option however, it may need to be incorporated with additional remediation and/or management works (such as soil capping [Section 9.6])..
9.3 9.3.1
Offsite landfill disposal Summary
Contaminated soil would be excavated and transported to an offsite landfill facility for disposal to allow development of the site following importation of clean fill material. The identified volume of contaminated soil is approximately 7,400 m3 (or approximately 11,100 tonnes).
9.3.2
Limitations
One ‘Category A’ hotspot was identified in test pit TP9, which cannot be disposed offsite until it has been demonstrated to be immobile or has been immobilised (where required) with EPA approval. Additional leachability testing would be required prior to acceptance of the material by landfill. Landfill space for the disposal of 7,400 m3 may not be readily available. Further, offsite disposal would also result in up to 500 truck movements.
9.3.3
Cost estimation
It is estimated that, on average, the top 1.95 m of soil across the site would require excavation and disposal. The depth of excavation in some areas, particularly the north east of the site, would be as shallow as 0.5 mBGL, while more impacted zones would require excavation down to 3.3 mBGL. The depth of impacted soil classified as ‘Category C’ material for offsite disposal is presented in Figure 12. The majority of contaminated soil would likely be disposed offsite as ‘Category C’ material, with an additional 90 m3 (135 tonne approximately) excavated and disposed from ‘Category 210061_ReportV2.doc
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B’ hotspots (Refer to Figure 13 for these locations). The single ‘Category A’ hotspot (approximately 10 m3) would require onsite treatment and/or reclassification prior to offsite disposal. Based on current landfill disposal fees and estimated earthworks fees, the approximate cost of landfill disposal within Victoria would be in excess of $1.65 million. Approximately 10,575 m3 of imported clean fill material would then be required to bring the site surface level to a minimum of 600 mm above the applicable flood level (4.25 mAHD). The costs associated with acquiring, transporting and reinstating this amount of ‘fill material’ are estimated to be in excess of $210,000.00. Additional costs would be associated with the development of an environmental management plan (EMP) to provide controls during excavation and offsite transport, the supervision of remediation works and a soil validation program undertaken prior to soil reinstatement to ensure no contaminated material remains onsite.
9.3.4
Viability
Offsite disposal to landfill is available in Victoria, however the waste hierarchy detailed in the SEPP states that offsite disposal is amongst the least preferred management options. Additionally, this volume of soil may not be readily accepted at metropolitan landfills, in particular the 100 m3 of ‘Category B’ material. This may result in greater costs associated with transport to an alternate landfill if required.
9.4
Onsite treatment
Several physical, chemical and biological treatment options are available as onsite soil remediation techniques. The options detailed in the following sections have been proven effective in Victoria, however their viability is dependent on site conditions and the nature of soil contaminants. The implementation of any onsite treatment options would be undertaken following the development of a Cleanup Plan.
9.4.1
Biological treatment
Biological treatment techniques, including bioremediation and phytoremediation, are cost effective treatment options which have been proven capable of effectively treating organic contaminants, particularly hydrocarbons, in soil. Additionally, the recovery and re-use of heavy metals is possible using phytoremediation techniques. The size of the site is the major limitation for biological treatment, as it may not be large enough to treat up to 7,400 m3 of impacted soil. Additionally, the presence of asbestos at depths between 0.1 and 1.5 mBGL would require additional management. Its inert characteristics prevent it from being effectively treated in-situ and, as such, it may require further delineation and management during any biological treatment. Environmental Earth Sciences VIC have extensive experience in biological treatment, including large phytoremediation projects. We consider this option potentially viable for the site, dependant on the following: •
if the site does not have sufficient surface area for excavation and treatment activities, a staged treatment approach may be required;
•
a risk assessment should be undertaken to assess the risk of heavy metal concentrations in soil. If a risk is present, a biological method effective in heavy metal treatment (i.e. phytoremediation) or an alternate remediation option (i.e. stabilisation) should be integrated into the biological treatment process;
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•
asbestos impact should be delineated and effectively managed; and
•
odour, vapour and dust emissions must be managed due to the residential setting;
9.4.2
Thermal treatment
Again, asbestos is a major limitation for thermal treatment, which involves heating the soil through steam injection or vitrification to increase the volatility of contaminants. Other limitations for the use of thermal treatment at the site include its high cost, high energy use, the presence of a perched water table within the impacted area and the production of volatile gas by-products during treatment. In-situ thermal treatment is considered a potentially viable remediation option for the site, however greater research into the option, with the above limitations considered, would be required.
9.4.3
In-situ stabilisation
Soil stabilisation involves the addition of stabilising agents to soil to reduce the mobility of contaminants. Stabilisation is effective for inorganics such as heavy metals and asbestos, however it is less effective for the treatment of TPH and PAHs. Other limitations to the technique include the presence of a perched water table potentially requiring dewatering, and the risk (considered low) of solidified soil impacting future site use. In-situ stabilisation is also considered a potentially viable remediation option for the site, however as we are dealing with a range of organic and inorganic contaminants greater research would be required.
9.5
Offsite treatment
The treatment options described above may also be undertaken offsite following the excavation and transport of impacted soil. Successful offsite treatment of impacted soil may result in it being available for beneficial reuse. Offsite treatment is considered potentially viable for this site subject to similar limitations as those relating to onsite treatment. However, the addition of increased cost and energy expenditure relating to the excavation and transport of approximately 7,400 m3 of soil mean that offsite treatment options are not favourable for the site.
9.6 9.6.1
Onsite soil capping and containment (recommended) Summary
The construction of a cap and containment system would allow impacted soil to remain insitu beneath an engineered soil cap across the surface of the entire site. This cap would aim to remove the potential exposure pathways and minimise infiltration of water through fill material. Its design would also be modified to meet the requirements of Melbourne Water. Design details of the cap and containment system will be developed within a Cleanup Plan. Initial design specifications include the following: •
a topsoil layer above the clay cap in unpaved areas;
•
guidelines outlined within EPA Publication 788 – Siting, design, operation and rehabilitation of landfills indicate a minimum cap thickness of 1.0 m. However, at this stage, we consider a minimum cap thickness of 0.6 m across the site suitable.
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•
this will require the importation of approximately 2,670 m3 of material and will meet Melbourne Water’s requirements for finished surface levels within any open carports. In order to meet Melbourne Water’s requirements for finished surface levels beneath the proposed building areas (see DPS plans in Appendix A), an additional 970 m3 of material will be required. This will mean a total of approximately 3,640 m3 of clean fill material would need to be imported for the construction of the cap;
•
an effective leachate collection system may need to be installed prior to the construction of the cap to manage the potentially contaminated perched water table. If needed, this system would include a leachate interception drain extending along the eastern boundary of the site, ending in a leachate sump. This sump would need to be pumped out and disposed to trade waste regularly; and
•
an EMP to provide guidance during the construction and ongoing use of the cap.
9.6.2
Limitations
•
a minimum cap thickness of 0.6 m across the site would result in higher surface levels than some of those shown in the DPS plans (access roads and eastern boundary). If these designs are final, excavation and management of soil in these areas would be required, thereby resulting in cost increases;
•
the unconsolidated nature of fill material onsite may require geotechnical assessment and compaction prior to capping to ensure there is no risk of land subsidence;
•
a groundwater investigation would be required to determine whether an ongoing source of contamination exists from the material remaining in-situ.
9.6.3
Cost estimation
It is anticipated that the design of an engineered cap (detailed in the Cleanup Plan) would be undertaken by a suitably qualified engineer and will cost approximately $20,000.00 to $25,000.00. The preparation of an EMP will be undertaken by an environmental consultant and it is estimated to cost approximately $5,000.00. Both the Cleanup Plan and the EMP will be reviewed by an appointed Site Auditor for approval. The costs associated with the construction of the cap and containment system would be detailed within the Cleanup Plan, however preliminary estimates indicate that the construction may range from approximately $400,000.00 to approximately $450,000.00.
9.6.4
Viability
This option is considered to be the most viable option for remediation of the site as it: •
successfully removes potential exposure pathways to future onsite users;
•
meets the requirements of Melbourne Water for development in areas prone to inundation;
•
effectively manages potential contaminant migration within the perched water table; and
•
is more cost effective than the other remediation options.
This option may not remove the risk of future impact to groundwater (and potentially surface water). Infiltration and leachate migration will be managed, however if an existing source of groundwater contamination is identified within the groundwater investigation and risk assessment, it may require ongoing monitoring and/or management.
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10 LIKELY REQUIRED WORKS Based on the findings of our historical investigation, our site observations and reported soil chemical concentrations across the site, it is highly likely that further environmental investigations will be required in addition to any soil remediation or management undertaken at the site.
10.1 Required works 10.1.1
Environmental audit
The site is currently zoned residential (R1Z) and will not require re-zoning for the proposed medium density residential development. However, the historical use of the site for disposal of municipal and construction waste means that it is likely that the Maribyrnong City Council will require an environmental audit of land to be undertaken by an EPA accredited environmental auditor prior to any future development. It is likely that this will be in the form of a 53V audit, which relates to “the risk of any possible harm or detriment to a segment of the environment caused by any industrial process or activity, waste, substance or noise” (EPA Publication 952.2, 2007). The costs of the Auditor’s component would be in addition to the costs of any further investigations required and may range between $75,000.00 and $100,000.00. This component of additional works is largely dependent on the required scope and the appointed Auditor.
10.1.2
Additional soil sampling
The recommended sampling density outlined within Australian Standard AS4482.1 (1997) Guide to the sampling and investigation of potentially contaminated soil, Part 1: Non-volatile and semi-volatile compounds has already been met for the site. The observed discrepancies in soil data reported in the 2002 and 2010 investigations (detailed in Section 7.2.6) may cause the Auditor to request additional soil sampling and analysis to confirm the chemical status of soil at the site. Additionally, the Auditor may request targeted sampling to confirm the presence of highly elevated PAH and TPH concentrations. The scope of any additional soil sampling is likely to be relatively minor, with costs estimated at between $5,000.00 and $10,000.00.
10.1.3
Groundwater assessment
No detailed groundwater investigations have been undertaken to determine the hydrological conditions and chemical status of groundwater beneath the site. A detailed groundwater investigation will be required to determine whether the site has impacted local groundwater conditions. The investigation would most likely involve: •
preparation of a sampling and analysis plan (SAP);
•
the installation of a minimum of three groundwater bores;
•
a minimum of two rounds of groundwater sampling;
•
laboratory analysis for CoPC; and
•
assessment of groundwater conditions in relation to the potential future land use and potential offsite receptors.
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The costs associated with undertaking a detailed groundwater investigation at the site are likely to be between $35,000.00 and $45,000.00.
10.1.4
Soil vapour assessment
The low concentration of volatile contaminants (BTEX, TPH[C6-C9]) across the site indicates that soil vapour intrusion at the site may not pose a great risk. However, the high concentrations of semi-volatile contaminants (PAH and TPH [C10-C36]) and the proposed residential land use mean that a soil vapour assessment would likely be required prior to any construction works. This is also dependent on the chemical status of groundwater beneath the site. A soil vapour assessment at the site is likely to cost between approximately $20,000.00 and $25,000.00.
10.1.5
Risk assessment
If an onsite capping and retention system was developed at the site, a quantitative risk assessment would be required to ensure that contaminants do not pose a risk to human health or the environment if they were to remain in-situ. As detailed in Section 9.2, chemical levels in soil would be evaluated from a human health and ecological perspective. The costs associated with a Human Health & Ecological Risk Assessment are estimated at approximately $20,000.00.
10.2 Likely schedule of works The potential timeframe presented in Appendix F is based on our recommended remediation strategy (also detailed in Section 9.6) and estimates that completion of construction of the cap can occur within 13 months. This anticipated timeline allows for the majority of environmental works to be completed in 6 months following 1 month for an Environmental Auditor to be engaged and review the site history. The cap design and implementation is likely to then take 6 months, including approximately 6 weeks for construction. This timeframe presents the ‘best-case’ time estimate and is largely provisional as timing is dependent on the potential scope of required works. Furthermore, any additional works will require the approval by an appointed auditor before being undertaken as well as a review upon completion. Ongoing management would also likely be required following the development of the site to ensure the beneficial uses of land and groundwater remain protected. The scope of ongoing management will likely be detailed within an EMP and approved by the appointed auditor.
11 SUMMARY The soil investigation undertaken by Environmental Earth Sciences VIC demonstrated that soil at the site contains concentrations of heavy metals (As, Cu and Pb in particular), TPH, BaP and total PAH above human health and ecological guidelines. Laboratory results generally aligned with the data presented in the previous SRS (2002) soil investigations however, higher concentrations of PAHs and TPH were identified. Of note, was total PAH concentrations which ranged from 0.6 mg/kg to 210.5 mg/kg, and TPH (C10-C36) concentrations which ranged from 140 mg/kg to 82,500 mg/kg.
210061_ReportV2.doc
21
Asbestos was identified at depths between 0.1 and 1.5 mBGL in four of the seven samples analysed. Several samples were reported with high sulfur concentrations, however their actual and potential acidity was demonstrated to be very low due to the self buffering capacity of the soil. Several potential remediation and management options, including offsite landfill disposal, onsite treatment and offsite treatment were considered potentially viable options. However, they were not considered favourable due to their limitations and requirements for greater research and development. Limitations included factors such as minimal reduction of risk to human health or the environment, not complying with Melbourne Water requirements, poor financial viability and poor environmental outcome. A capping and containment system is considered the most viable option for remediation of the site. Impacted soil would remain in-situ beneath an engineered soil cap constructed across the surface of the entire site. This option is considered to be the most viable for remediation of the site as it: •
successfully removes potential exposure pathways to future site users;
•
meets the requirements of Melbourne Water for development in areas prone to inundation;
•
effectively manages potential contaminant migration within the perched water table; and
•
is more cost effective than the other remediation options.
Please note however, that it is highly likely that further environmental investigations will be required in addition to implementation of the cap and containment system (if undertaken). The further works, as well as their estimated costs and timeframe are outlined in Table 1. Undertaking the works listed in Table 1, followed by the construction of the cap and containment system, is considered the most practical approach in successfully developing the site for its proposed medium density residential land use. The costs associated with undertaking the scope of works is estimated at between $580,000.00 and $680,000.00 (excluding GST). The timeframe for undertaking the works, from the time of engaging an auditor to completion of the cap and containment system, is estimated at a minimum of 13 months.
210061_ReportV2.doc
22
TABLE 1
FURTHER ENVIRONMENTAL WORKS
Works
Importance
Costs
Timing
mandatory
$75,000.00 $100,000.00
Month 1 to Month 13
possible (based on auditor’s requirements)
$5,000.00 $10,000.00
Month 2
mandatory
$35,000.00 $45,000.00
Month 2 to Month 6
likely
$20,000.00 $25,000.00
Month 6
Human health & ecological risk assessment
likely (based on auditor’s requirements)
$20,000.00
Month 7
Development of a Cleanup Plan
mandatory
$20,000.00 $25,000.00
Month 8
Development of an environmental management plan (EMP)
mandatory
$5,000.00
Month 11
desirable
$400,000.00 to $450,000.00
Month 11 to Month 12
Environmental audit of the site Additional soil sampling Detailed groundwater assessment Soil vapour assessment
Cap and containment system
12 LIMITATIONS This report has been prepared by Environmental Earth Sciences VIC ABN 13 109 404 024 in response to and subject to the following limitations: 1. The specific instructions received from Fastnet Consulting; 2. The specific scope of works set out in PO210102 V2 issued by Environmental Earth Sciences VIC for and on behalf of Fastnet Consulting, is included in Section 2 (Objectives) of this report; 3. May not be relied upon by any third party not named in this report for any purpose except with the prior written consent of Environmental Earth Sciences VIC (which consent may or may not be given at the discretion of Environmental Earth Sciences VIC); 4. This report comprises the formal report, documentation sections, tables, figures and appendices as referred to in the index to this report and must not be released to any third party or copied in part without all the material included in this report for any reason; 5. The report only relates to the site referred to in the scope of works being located at 20 Gordon Parade and 28 Salisbury Street, Yarraville (“the site”); 6. The report relates to the site as at the date of the report as conditions may change thereafter due to natural processes and/or site activities; 7. No warranty or guarantee is made in regard to any other use than as specified in the scope of works and only applies to the depth tested and reported in this report, 8. Fill, soil and rock to the depth tested on the site may be fit for the use specified in this report. Unless it is expressly stated in this report, the fill, soil and/or rock may not be suitable for classification as clean fill if deposited off site; and
210061_ReportV2.doc
23
9. Our General Limitations set out at the back of the body of this report.
13 REFERENCES ANZECC, 1992a, Australian and New Zealand Guidelines for the Assessment and Management of Contaminated Sites. Department of Natural Resources and Environment (DNRE), 1995, Victorian Groundwater Beneficial Map Series. South Eastern Victoria regional aquifer systems. Department of Primary Industries (DPI), 2003, Acid Sulfate Soil Hazard Maps and Guidelines for Coastal Victoria. Department of Sustainability and Environment (DSE), 2009, Victorian coastal acid sulfate soils strategy. Environmental Earth Sciences Pty Ltd (2007) Quality Assurance and Environmental Management Manual. Environmental & Earth Sciences Pty Ltd, 2005b, Soil, gas & groundwater sampling manual. Work Instruction 01. EPA Victoria, 1999, Publication 655.1 – Information Bulletin Acid Sulfate Soil and Rock. EPA Victoria, 2001, Publication 788 Best Practice Environmental Management – Siting, design, operation and rehabilitation of landfills. EPA Victoria, 2007, Publication 952.2 Environmental Auditor Guidelines for the Preparation of Environmental Audit Reports on Risk to the Environment. Geological Survey of Victoria (GSV) (1974) Melbourne 1:63 360 Geological Series Map Part 7822, Zone 55, Sheet SJ 55-1. Industrial Waste Resource Guidelines – Publication IWRG621 ‘Soil Hazard Categorisation and Management’. National Environment Protection Council (NEPC), 1999, National Environment Protection (Assessment of Site Contamination) Measure. NSW Department of Environment and Climate Change, 2008, Service station sites: assessment & remediation. SRS Australia Pty Ltd, 2002, Environmental Site Investigation Report of Residential 3 Zoned, Land on Titles: Vol. 8780 Fol. 549 & Vol. 8780 Fol. 550, End of Gordon Parade, Yarraville, Victoria; and SRS Australia Pty Ltd, 2002, Environmental Site Investigation Report of Residential 3 Zoned, Lot No. 3, End of Salisbury Street, Yarraville, Victoria. Standards Australia, 2005, Guide to the investigation and sampling of sites with potentially contaminated soil. Part 1: Non-volatile and semi-volatile compounds. AS 4482.1. Standards Australia, 1999, Guide to the investigation and sampling of sites with potentially contaminated soil. Part 2: Volatile Substances. AS 4482.1. Victorian Government, 2002, State Environment Protection Policy (Prevention and Management of Contamination of Land). Victorian Government Printer. Victorian Government Gazette (1999). Industrial Waste Management Policy (IWMP) Waste Acid Sulfate Soils (WASS).
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West Australian Department of Health (WA DoH), 2009, Guidelines for the Assessment and Remediation and Management of Asbestos-Contaminated Sites in Western Australia.
210061_ReportV2.doc
25
ENVIRONMENTAL EARTH SCIENCES GENERAL LIMITATIONS Scope of services The work presented in this report is Environmental Earth Sciences response to the specific scope of works requested by, planned with and approved by the client. It cannot be relied on by any other third party for any purpose except with our prior written consent. Client may distribute this report to other parties and in doing so warrants that the report is suitable for the purpose it was intended for. However, any party wishing to rely on this report should contact us to determine the suitability of this report for their specific purpose.
Data should not be separated from the report A report is provided inclusive of all documentation sections, limitations, tables, figures and appendices and should not be provided or copied in part without all supporting documentation for any reason, because misinterpretation may occur.
Subsurface conditions change Understanding an environmental study will reduce exposure to the risk of the presence of contaminated soil and or groundwater. However, contaminants may be present in areas that were not investigated, or may migrate to other areas. Analysis cannot cover every type of contaminant that could possibly be present. When combined with field observations, field measurements and professional judgement, this approach increases the probability of identifying contaminated soil and or groundwater. Under no circumstances can it be considered that these findings represent the actual condition of the site at all points. Environmental studies identify actual sub-surface conditions only at those points where samples are taken, when they are taken. Actual conditions between sampling locations differ from those inferred because no professional, no matter how qualified, and no sub-surface exploration program, no matter how comprehensive, can reveal what is hidden below the ground surface. The actual interface between materials may be far more gradual or abrupt than an assessment indicates. Actual conditions in areas not sampled may differ from that predicted. Nothing can be done to prevent the unanticipated. However, steps can be taken to help minimize the impact. For this reason, site owners should retain our services.
Problems with interpretation by others Advice and interpretation is provided on the basis that subsequent work will be undertaken by Environmental Earth Sciences VIC. This will identify variances, maintain consistency in how data is interpreted, conduct additional tests that may be necessary and recommend solutions to problems encountered on site. Other parties may misinterpret our work and we cannot be responsible for how the information in this report is used. If further data is collected or comes to light we reserve the right to alter their conclusions.
Obtain regulatory approval The investigation and remediation of contaminated sites is a field in which legislation and interpretation of legislation is changing rapidly. Our interpretation of the investigation findings should not be taken to be that of any other party. When approval from a statutory authority is required for a project, that approval should be directly sought by the client.
Limit of liability This study has been carried out to a particular scope of works at a specified site and should not be used for any other purpose. This report is provided on the condition that Environmental Earth Sciences VIC disclaims all liability to any person or entity other than the client in respect of anything done or omitted to be done and of the consequence of anything done or omitted to be done by any such person in reliance, whether in whole or in part, on the contents of this report. Furthermore, Environmental Earth Sciences VIC disclaims all liability in respect of anything done or omitted to be done and of the consequence of anything done or omitted to be done by the client, or any such person in reliance, whether in whole or any part of the contents of this report of all matters not stated in the brief outlined in Environmental Earth Sciences VIC’s proposal number and according to Environmental Earth Sciences general terms and conditions and special terms and conditions for contaminated sites. To the maximum extent permitted by law, we exclude all liability of whatever nature, whether in contract, tort or otherwise, for the acts, omissions or default, whether negligent or otherwise for any loss or damage whatsoever that may arise in any way in connection with the supply of services. Under circumstances where liability cannot be excluded, such liability is limited to the value of the purchased service.
General Limitations
6 April 2009
Page 1 of 1
FIGURES
210061_ReportV2.doc
N
GORDO N
SALISB
URY ST REET
PARAD E
SITE LOCATION
Source: Nearmap.com.au
Title:
ENVIRONMENTAL EARTH SCIENCES
THE KNOW AND THE HOW
0
20
40
60
Horizontal Scale in Metres
80
100
Location: 20 Gordon Pde.and
28 Salisbury St. Yarraville, VIC.
Fastnet Consulting Project Man: JF Scale: As Shown Drawn By: LB Date: Sept. 2010 Client:
Locality Map Job No: 210061
Figure
1
N
V13
A
GORDON PARADE
TP1 V2
V1
TP2
TP4
V5
Westgate Golf Course
V3
V4
20 Gordon Parade TP3 V8
Sto
TP5
mer
V7
For
V6
C
TP13 XP1 TP14
XP3
TP12
TP11 28 Salisbury Street XP4
XP6
TP10
l ana ek C
XP2
TP9
C’
C re
TP7 Salisbury Street Road Reserve
B’
Ston y
TP8
XP7 XP5
N ew
B
Cr ee k
e urs Co
SALISBURY STREET
ny
TP6
XP11
A’ 0
5
10
15
20
25
Scale in Metres
LEGEND: EES test pit locations (2010) SRS test pit locations (2001) Site boundary Cross section location (refer Figures 3, 4 and 5)
Title:
ENVIRONMENTAL EARTH SCIENCES
THE KNOW AND THE HOW
Site Plan and Sampling Locations
Location: 20 Gordon Pde.and
28 Salisbury St. Yarraville, VIC.
Fastnet Consulting Project Man: JF Scale: As Shown Drawn By: LB Date: Sept. 2010 Client:
Job No: 210061
Figure
2
A
A’
TP1
V77I-4
TP3
V77I-7
TP1
SRS-XP4
0
FILL - Loose, sandy clayey silt
FILL - Loose silty clay matrix with solid waste (plastic, glass, wood, bluestone, rubbish etc.)
(m BGL)
1
FILL - Loose, black silt with minor clay (reworked Coode Island Silt sediments)
Perched water table
2
NATURAL - Medium dense, grey/green clay
3
NATURAL - Weathered, brown, vesicular basalt (Newer Volcanics)
? ?
4
? ?
? ?
Title:
ENVIRONMENTAL EARTH SCIENCES
Location: 20 Gordon Pde.and
THE KNOW AND THE HOW
0
10
20
30
40
Horizontal Scale in Metres
50
Client:
Conceptual Cross Section A - A’
28 Salisbury St. Yarraville, VIC.
Fastnet Consulting
Project Man: JF
Scale: As Shown
LB
Date: Sept. 2010
Drawn By:
Job No: 210061
Figure
3
B
B’ TP7
0
TP8
TP9
FILL - Loose, brown clayey silt
FILL - Loose black silt (Coode Island Silt) 1
FILL - Loose, brown silty clay with solid waste (bluestone, wood, plastic, paper, rubbish etc.)
(m BGL)
Oil drum and machinery inclusion Perched water table 2
NATURAL
- Dens
e, gre y/blu e
clay FILL - Loose, black silt with minor clay and wood, paper inclusions (reworked Coode Island Silt sediments)
3
NATURAL - Weathered, brown, vesicular basalt (Newer Volcanics)
? ?
?
4
?
? ?
Title:
ENVIRONMENTAL EARTH SCIENCES
Location: 20 Gordon Pde.and
THE KNOW AND THE HOW
0
2
4
6
8
Horizontal Scale in Metres
10
Client:
Conceptual Cross Section B - B’
28 Salisbury St. Yarraville, VIC.
Fastnet Consulting
Project Man: JF
Scale: As Shown
LB
Date: Sept. 2010
Drawn By:
Job No: 210061
Figure
4
C
C’ TP13
TP11
TP10
0
FILL - Loose, brown clayey silt with roots
1
Rubbish inclusions (plastic, paper, glass)
FILL - Loose, brown silty clay with building rubble (bluestone and concrete)
(m BGL)
Perched water table 2
FILL - Soft, black silty clay with reeds. Reworked Coode Island Silt
FILL - Soft, dark, reworked natural silty clay
NATURAL - Dense, grey/blue clay 3
NATURAL - Weathered, brown, vesicular basalt (Newer Volcanics)
?
?
? 4
?
? ?
Title:
ENVIRONMENTAL EARTH SCIENCES
Location: 20 Gordon Pde.and
THE KNOW AND THE HOW
0
2
4
6
8
10
Horizontal Scale in Metres
Client:
Conceptual Cross Section C - C’
28 Salisbury St. Yarraville, VIC.
Fastnet Consulting
Project Man: JF
Scale: As Shown
LB
Date: Sept. 2010
Drawn By:
Job No: 210061
Figure
5
N
GORDON PARADE
TP1 113(05)
V13
V2 120(0.1)
V1
TP2 540(3.3)
TP4 180(2.0) V5
Westgate Golf Course
V3
V4 20 Gordon Parade
TP3 158(2.1)
TP6 114(0.5)
TP8 174(2.0) Salisbury Street Road Reserve
TP14 148(1.0) 119(2.9)
28 Salisbury Street XP4
TP10 103(1.5)
C re e
XP6 XP3 130(1.0) TP12 111(2..0) 1501.5) TP13 TP11 112(1.6)
ek
k Ca
TP9 278(2.6)
XP2
XP1
Cr e
XP7
XP5 140(1.0)
N ew
TP7 101(0.1) 406(2.1)
y
e ur s Co
SALISBURY STREET
ton er S
TP5 166(0.5)
n al
V8
Ston y
V7 190(0.2)
m For
V6 130(0.5)
XP11
0
5
10
15
20
25
Scale in Metres
LEGEND: EES test pit locations (2010) SRS test pit locations (2001) Site boundary
148(1.0)
As concentration (mg/kg) / (sample depth in m) in excess of NEPM HIL A guidelines
406(2.9)
As concentration (mg/kg) / (sample depth in m) in excess of NEPM HIL D guidelines
Elevated Arsenic (As) Concentrations
Title:
ENVIRONMENTAL EARTH SCIENCES
20 Gordon Pde.and 28 Salisbury St. Yarraville, VIC.
Location:
THE KNOW AND THE HOW
Client:
Fastnet Consulting
Project Man: JF
Scale: As Shown
LB
Date: Sept. 2010
Drawn By:
Job No: 210061
Figure
6
N
GORDON PARADE
V13
TP1
V1
V2 2200(0.1) 1700(0.5) TP2
TP4
V5
Westgate Golf Course
V3
V4 20 Gordon Parade TP3
TP8 Salisbury Street Road Reserve
28 Salisbury Street XP1 TP14
XP6
TP11 1190(2.0)
XP4 1600(0.5)
TP10 1890(1.5)
C re e
TP13
XP3 2100(0.1) 2400(05)
XP7 1900(0.5)
Ston y
TP12
TP9
N ew
XP2
ek
e ur s Co
TP7
Cr e
n al
y
k Ca
TP5
ton er S
SALISBURY STREET
V7 V8 2700(0.5) 2400 (0.5) 4900 (1.0) TP6 3200(2.0)
m For
V6 1300(0.5)
XP5 1800(0.5)
XP11
0
5
10
15
20
25
Scale in Metres
LEGEND: EES test pit locations (2010) SRS test pit locations (2001) Site boundary
1600(0.3)
Cu concentration (mg/kg) / (sample depth in m) in excess of NEPM HIL A guidelines
4900(1.0)
Cu concentration (mg/kg) / (sample depth in m) in excess of NEPM HIL D guidelines
Elevated Copper (Cu) Concentrations
Title:
ENVIRONMENTAL EARTH SCIENCES
20 Gordon Pde.and 28 Salisbury St. Yarraville, VIC.
Location:
THE KNOW AND THE HOW
Client:
Fastnet Consulting
Project Man: JF
Scale: As Shown
LB
Date: Sept. 2010
Drawn By:
Job No: 210061
Figure
7
N
GORDON PARADE
TP1
V13
V2
V1 390(10.5)
TP2 485(3.3)
TP4 337(1.5)
Westgate Golf Course
V3
V5 420(05)
V4 3300(0.5)
20 Gordon Parade
28 Salisbury Street
XP1
TP14 354(1.0)
XP4
XP6 520(0.5) TP11 514(0.1) 683(2.0
n al k Ca
XP3
TP9 773(2.6)
TP10 325(1.5)
C re e
TP12 431(0.5)
ek
Ston y
TP13 326(0.1)
Salisbury Street Road Reserve
Cr e
XP7 XP5
N ew
T3 358(0.3)
TP7
XP2
y
e ur s Co
SALISBURY STREET
ton er S
TP6
V7 V8 530(1.0) 840(2.0) TP5 394(0.5)
m For
V6 3600(0.5) 420(1.0)
TP3 731(0.5) 822(1.5)
XP11
0
5
10
15
20
25
Scale in Metres
LEGEND: EES test pit locations (2010) SRS test pit locations (2001) Site boundary
337(1.5)
Pb concentration (mg/kg) / sample depth (m) in excess of NEPM HIL A guidelines
3600(0.5)
Pb concentration (mg/kg) / sample depth (m) in excess of NEPM HIL D guidelines
Elevated Lead (Pb) Concentrations
Title:
ENVIRONMENTAL EARTH SCIENCES
20 Gordon Pde.and 28 Salisbury St. Yarraville, VIC.
Location:
THE KNOW AND THE HOW
Client:
Fastnet Consulting
Project Man: JF
Scale: As Shown
LB
Date: Sept. 2010
Drawn By:
Job No: 210061
Figure
8
N
GORDON PARADE
TP1 20.0(1.5)
V13
V1
V2
TP2
TP4
V5
Westgate Golf Course
V3
V4 20 Gordon Parade
TP3 4.7(1.5)
Salisbury Street Road Reserve
XP2 TP12 2.2(1.5) 2.3(1.5)
28 Salisbury Street
XP1 4.5(1.5) TP14
XP6
XP3
TP13
TP9 1.1(1.5) 6.0(1.5)
TP11 1.8(1.5)
XP4
ek
n al
TP7
Cr e
TP10 1.0(1.5) XP7
XP5
N ew
TP8 1.6(1.5)
k Ca
y
e ur s Co
SALISBURY STREET
ton er S
TP6 2.4(1.5)
TP5 1.5(1.5)
C re e
V8
Ston y
V7
m For
V6 1.1(1.5)
XP11
0
5
10
15
20
25
Scale in Metres
LEGEND: EES test pit locations (2010) SRS test pit locations (2001) Site boundary
1.1(1.5)
BaP concentration (mg/kg) / sample depth (m) in excess of NEPM HIL A guidelines
6.0(1.5)
BaP concentration (mg/kg) / sample depth (m) in excess of NEPM HIL D guidelines
Title:
ENVIRONMENTAL EARTH SCIENCES
20 Gordon Pde.and 28 Salisbury St. Yarraville, VIC.
Location:
THE KNOW AND THE HOW
Client:
Benzo(a)Pyrene Concentrations >1.0 mg/kg
Fastnet Consulting
Project Man: JF
Scale: As Shown
LB
Date: Sept. 2010
Drawn By:
Job No: 210061
Figure
9
N
GORDON PARADE
V13
TP1 210.5(1.5)
V1
V2
TP2
TP4
V5
Westgate Golf Course
V3
V4 20 Gordon Parade
TP3 44.0(1.5)
y
TP8
TP10
TP13 28 Salisbury Street
XP1 39.0(1.50) TP14
XP6
XP3
TP11 27.6(3.0)
XP4
Ston y
TP12 26.8(1.5) XP2 21.9(1.0)
TP9 162.6(2.1)
k Ca
Salisbury Street Road Reserve
ek
XP7 XP5
N ew
TP7
Cr e
e ur s Co
SALISBURY STREET
ton er S
TP5 22.6(1.5)
TP6 102.9(0.1)
n al
V8
C re e
V7
m For
V6
XP11
0
5
10
15
20
25
Scale in Metres
LEGEND: EES test pit locations (2010) SRS test pit locations (2001) Site boundary
39.0(1.0)
PAH concentration (mg/kg) / sample depth (m) in excess of NEPM HIL A guidelines
102.9(0.1)
PAH concentration (mg/kg) / sample depth (m) in excess of NEPM HIL D guidelines
Title:
ENVIRONMENTAL EARTH SCIENCES
20 Gordon Pde.and 28 Salisbury St. Yarraville, VIC.
Location:
THE KNOW AND THE HOW
Client:
Total PAH Concentrations >20 mg/kg
Fastnet Consulting
Project Man: JF
Scale: As Shown
LB
Date: Sept. 2010
Drawn By:
Job No: 210061
Figure
10
N
GORDON PARADE
V13
TP1
V1
V2
TP2
TP4
V5
1220(3.3)
V4
Westgate Golf Course
V3
2100(1.0) 25,540(0.5) 2580(2.0) 20 Gordon Parade
TP3
4760(1.5)
y
TP8 Salisbury Street Road Reserve
TP12 XP2
TP13 28 Salisbury Street
XP1
XP4
1090(1.0) TP14
TP9
82,500(2.1) 3050(2.6)
XP6
XP3
TP10
1040(0.5) 1490(1.0)
21,260(1.0) 1400(1.5)
TP11
2390(1.8) 4910(2.0) 2580(3.0)
ek
XP7 XP5
N ew
TP7
e ur s Co
SALISBURY STREET
Cr e
n al
TP6
k Ca
ton er S
TP5
4420(3.0) 11,900(2.1)
C re e
V8
Ston y
V7
4065(1.0)
m For
V1310
1310(0.2)
XP11
0
5
10
15
20
25
Scale in Metres
LEGEND: EES test pit locations (2010) SRS test pit locations (2001) Site boundary
102.9(0.1)
TPH (C6-C36) in mg/kg (sample depth in m)
Title: TPH (C10-C36) Concentrations
in Excess of NSW DECC Guidelines
ENVIRONMENTAL EARTH SCIENCES
20 Gordon Pde.and 28 Salisbury St. Yarraville, VIC.
Location:
THE KNOW AND THE HOW
Client:
Fastnet Consulting
Project Man: JF
Scale: As Shown
LB
Date: Sept. 2010
Drawn By:
Job No: 210061
Figure
11
N
GORDON PARADE
TP1 2.1 V2 0.5
V1 1.0
TP2 3.3
TP4 2.0
Westgate Golf Course
V3 3.3
V4 2.0
V5 0.5
20 Gordon Parade
TP3 2.1
T3
2.0 TP7 2.1 Salisbury Street Road Reserve
28 Salisbury Street
XP1 2.5
XP4 0.5
XP6 1.0
k Ca
XP3 1.5
TP10 2.0
TP11 3.0
C re e
TP13 1.6
TP12 2.5
XP7 1.0 XP5 2.0
N ew
XP2 2.0
TP9 2.6
ek
e ur s Co
SALISBURY STREET
Cr e
n al
y
Ston y
TP5 3.0
TP6 3.0
ton er S
V8 2.0
V7
m For
V6 1.0
TP14 2.9
0
5
10
15
20
25
Scale in Metres
LEGEND: EES test pit locations (2010) SRS test pit locations (2001) Site boundary
2.9
Depth (mBGL)
Depth of ‘Category C’ Classified Soil
Title:
ENVIRONMENTAL EARTH SCIENCES
20 Gordon Pde.and 28 Salisbury St. Yarraville, VIC.
Location:
THE KNOW AND THE HOW
Client:
Fastnet Consulting
Project Man: JF
Scale: As Shown
LB
Date: Sept. 2010
Drawn By:
Job No: 210061
Figure
12
N
GORDON PARADE
TP1 1.5 (PAH & BaP) V2
V1
TP2 3.3 (As)
TP4
V4 0.5 (Pb)
V5
Westgate Golf Course
V3
20 Gordon Parade TP3
y
T3
XP2
TP13
TP12
XP3 1.0 (TPH)
28 Salisbury Street
XP1
TP9 2.1 (TPH)
k Ca
Salisbury Street Road Reserve
ek
XP6 TP10 XP7
TP11
XP4
XP5
N ew
TP7
e ur s Co
SALISBURY STREET
Cr e
C re e
TP6 0.1 (PAH & BaP)
ton er S
TP5 2.1 (TPH)
n al
V8
Ston y
V7
m For
V6 0.5 (Pb)
TP14
0
5
10
15
20
25
Scale in Metres
LEGEND: EES test pit locations (2010) SRS test pit locations (2001) Site boundary
2.1 (TPH)
Depth of hotspot (m) - (Category B contaminant)
2.1 (TPH)
Depth of hotspot (m) - (Category A contaminant)
Title:
ENVIRONMENTAL EARTH SCIENCES
20 Gordon Pde.and 28 Salisbury St. Yarraville, VIC.
Location:
THE KNOW AND THE HOW
Client:
Locations of ‘Category B’ and ‘Category A’ Hotspot
Fastnet Consulting
Project Man: JF
Scale: As Shown
LB
Date: Sept. 2010
Drawn By:
Job No: 210061
Figure
13
TABLES
210061_ReportV2.doc
TABLE 2
NEPM HEALTH BASED INVESTIGATION LEVELS (1999)
Substance
Health-based Soil Investigation Levels (mg/kg)
Exposure Settings
A
Aldrin + Dieldrin Arsenic (total)
a
a
D
E
F
10
40
20
50
100
400
200
500
Benzo (a) pyrene
1
4
2
5
Beryllium
20
80
40
100
3,000
12,000
6,000
15,000
Cadmium
20
80
40
100
Chlordane
50
200
100
250
Chromium (III)
12%
48%
24%
60%
Chromium (VI)
100
400
200
500
Cobalt
100
400
200
500
Copper
1,000
4,000
2,000
5,000
Cyanides (complexed)
500
2,000
1,000
2,500
Cyanides (free)
250
1,000
500
1,250
DDT + DDD + DDE
200
800
400
1,000
Heptachlor
10
40
20
50
Lead
300
1,200
600
1,500
1,500
6,000
3,000
7,500
Methyl Mercury
10
40
20
50
Mercury (inorganic)
15
60
30
75
Nickel
600
2,400
600
3,000
Total PAH
20
80
40
100
PCB’s (total)
10
40
20
50
8,500
34,000
17,000
42,500
TPH C16-C35 aromatics
90
360
180
450
TPH C16-C35 aliphatics
5,600
22,400
11,200
28,000
TPH>C35
56,000
224,000
112,000
280,000
Zinc
7,000
28,000
14,000
35,000
Boron
Manganese
Phenol
B
C
Exposure Setting(s): 1. ‘Standard’ residential with garden/accessible soil (less than 10% intake of home grown produce; no poultry): this category includes children’s day-care, pre-schools etc. 2. Residential with substantial vegetable garden (contributing up to 50% of vegetable and fruit intake) and poultry providing all dietary egg intake and 25% poultry meat intake. 3. Residential with substantial vegetable garden (contributing up to 50% of vegetable and fruit intake); poultry excluded. 4. Residential with minimal opportunities for soil access includes high-rise apartments and flats. 5. Parks, recreational open space and playing fields: includes secondary schools. 6. Commercial/Industrial: includes premises such as shops and offices as well as factories and industrial sites. (If, however, a commercial site is also used for residential purposes or regular soil access by children if possible then the appropriate ‘residential’ setting should be used.) It is assumed that thirty years is the duration of exposure. a Site and contaminant specific. 7. 8. Shaded column specifies the relevant guidelines for this investigation.
210061_ReportV2.doc
T1
TABLE 3
ORGANIC AND INORGANIC SOIL RESULTS SUMMARY
Analyte
Units
LOR
NSW DECC
NEPM 1999 EIL
NEPM 1999 HIL A
NEPM 1999 HIL D
Fill Material
Cat C
Cat B
Aluminium
mg/kg
1
-
-
-
-
-
-
Arsenic
mg/kg
5
-
20
100
400
20
Cadmium
mg/kg
1
-
3
20
80
Chromium (III+VI)
mg/kg
2
-
-
-
Chromium (hexavalent)
mg/kg
0.5
-
1
Cobalt
mg/kg
2
-
Copper
mg/kg
5
Lead
mg/kg
Manganese
TP1
TP1
TP1
TP1
TP2
TP2
TP2
TP2
TP3
TP3
TP3
TP3
TP3
(0.4-0.5)
(1.0-1.1)
(1.5-1.6)
(2.0-2.1)
(0.4-0.5)
(1.4-1.5)
(1.9-2.0)
(3.2-3.3)
(0.4-0.5)
(0-0.1)
(1.4-1.5)
(2.0-2.1)
(2.4-2.5)
-
-
-
-
-
-
-
-
-
-
-
-
<1
-
500
2000
113
<5
37
30
42
73
24
590
53
5
77
158
19
3
100
400
2
<1
<1
<1
<1
1
<1
16
2
<1
2
2
<1
-
-
-
-
59
31
-
28
29
47
-
126
92
20
-
65
36
100
400
1
500
2000
-
-
<0.5
-
-
-
<0.5
-
-
-
<0.5
-
-
-
100
400
-
-
-
-
-
-
-
183
-
-
-
46
-
-
-
-
-
100
1000
4000
100
5000
20000
265
7
23
15
728
115
106
358
463
26
474
202
16
5
300
600
300
1200
300
1,500
6,000
191
14
60
32
155
108
87
485
731
21
822
198
26
mg/kg
0.1
-
500
1500
6000
-
-
-
-
-
-
-
-
-
-
-
-
-
-
<0.1
-
Mercury
mg/kg
0.1
-
1
15
60
1
75
300
0.5
<0.1
0.1
<0.1
0.1
0.2
0.3
1
0.7
<0.1
0.5
0.4
0.2
Molybdenum
mg/kg
2
-
-
-
-
40
1,000
4,000
-
-
<2
-
-
-
<2
-
-
-
7
-
-
Nickel
mg/kg
2
-
60
600
2400
60
3,000
12,000
76
17
39
27
141
41
41
122
76
13
77
52
27
Selenium
mg/kg
5
-
-
-
-
10
50
200
-
-
<5
-
-
-
<5
-
-
-
<5
-
-
Silver
mg/kg
2
-
-
-
-
10
180
720
-
-
<2
-
-
-
<2
-
-
-
<2
-
-
Tin
mg/kg
5
-
-
-
-
50
500
-
-
-
<5
-
-
-
202
-
-
-
268
-
-
Zinc
mg/kg
5
-
200
7000
28000
200
35,000
140,000
496
52
133
93
127
413
414
3960
810
50
1170
587
53
Cyanide (Free)
mg/kg
1
-
-
250
1000
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
Cyanide Total
mg/kg
1
-
-
500
2000
50
2,500
10,000
-
-
<1
-
-
-
1
-
-
-
8
-
-
Fluoride
mg/kg
40
-
-
-
-
450
10,000
40,000
-
-
80
-
-
-
180
-
-
-
120
-
-
Acenaphthene
mg/kg
0.5
-
-
-
-
-
-
-
-
<0.5
<0.6
-
-
<0.5
<0.5
<0.5
-
-
<0.5
<0.5
-
Acenaphthylene
mg/kg
0.5
-
-
-
-
-
-
-
-
<0.5
3.1
-
-
<0.5
<0.5
<0.5
-
-
0.5
<0.5
-
Anthracene
mg/kg
0.5
-
-
-
-
-
-
-
-
<0.5
4.4
-
-
<0.5
<0.5
<0.5
-
-
0.8
<0.5
-
Benz(a)anthracene
mg/kg
0.5
-
-
-
-
-
-
-
-
<0.5
18.1
-
-
<0.5
<0.5
<0.5
-
-
4.1
<0.5
-
Benzo(a) pyrene
mg/kg
0.5
-
-
1
4
1
5
20
-
<0.5
20
-
-
<0.5
<0.5
<0.5
-
-
4.7
<0.5
-
Benzo(b) & (k)fluoranthene
mg/kg
0.5
-
-
-
-
-
-
-
-
<0.5
30.3
-
-
<0.5
<0.5
0.7
-
-
7.5
<0.5
-
Benzo(g,h,i)perylene
mg/kg
0.5
-
-
-
-
-
-
-
-
<0.5
15.5
-
-
<0.5
<0.5
<0.5
-
-
3.2
<0.5
-
Chrysene
mg/kg
0.5
-
-
-
-
-
-
-
-
<0.5
15
-
-
<0.5
<0.5
<0.5
-
-
3.2
<0.5
-
Dibenz(a,h)anthracene
mg/kg
0.5
-
-
-
-
-
-
-
-
<0.5
3.5
-
-
<0.5
<0.5
<0.5
-
-
0.7
<0.5
-
Fluoranthene
mg/kg
0.5
-
-
-
-
-
-
-
-
<0.5
38.2
-
-
<0.5
<0.5
0.9
-
-
7.6
<0.5
-
Fluorene
mg/kg
0.5
-
-
-
-
-
-
-
-
<0.5
<0.6
-
-
<0.5
<0.5
<0.5
-
-
<0.5
<0.5
-
Indeno(1,2,3-c,d)pyrene
mg/kg
0.5
-
-
-
-
-
-
-
-
<0.5
12.2
-
-
<0.5
<0.5
<0.5
-
-
2.7
<0.5
-
Naphthalene
mg/kg
0.5
-
-
-
-
-
-
-
-
<0.5
0.8
-
-
<0.5
<0.5
<0.5
-
-
<0.5
<0.5
-
Phenanthrene
mg/kg
0.5
-
-
-
-
-
-
-
-
<0.5
12.2
-
-
<0.5
<0.5
<0.5
-
-
2.5
<0.5
-
Pyrene
mg/kg
0.5
-
-
-
-
-
-
-
-
<0.5
37.2
-
-
0.6
<0.5
1.2
-
-
6.5
<0.5
-
210061_ReportV2.doc
T2
TABLE 2
ORGANIC AND INORGANIC SOIL RESULTS SUMMARY (CONTINUED)
Analyte
Units
LOR
NSW DECC
NEPM 1999 EIL
NEPM 1999 HIL A
NEPM 1999 HIL D
Fill Material
Cat C
Cat B
Sum of PAH
mg/kg
0.5
-
-
20
80
20
100
TPH C6 - C9
mg/kg
10
65
-
-
-
100
TPH C10 - C14
mg/kg
50
-
-
-
-
TPH C15 - C28
mg/kg
100
-
-
-
TPH C29-C36
mg/kg
100
-
-
TPH+C10 - C36 (sum)
mg/kg
50
1000
Benzene
mg/kg
0.2
Ethylbenzene
mg/kg
Toluene
TP1
TP1
TP1
TP1
TP2
TP2
TP2
TP2
TP3
TP3
TP3
TP3
TP3
(0.4-0.5)
(1.0-1.1)
(1.5-1.6)
(2.0-2.1)
(0.4-0.5)
(1.4-1.5)
(1.9-2.0)
(3.2-3.3)
(0.4-0.5)
(0-0.1)
(1.4-1.5)
(2.0-2.1)
(2.4-2.5)
400
-
<0.5
210.5
-
-
0.6
<0.5
2.8
-
-
44
<0.5
-
650
2,600
-
<10
<10
-
-
<10
<10
<10
-
-
<10
<10
-
-
-
-
-
<50
<50
-
-
<50
<50
<50
-
-
<50
<50
-
-
-
-
-
-
<100
330
-
-
250
<100
590
-
-
1690
120
-
-
-
-
-
-
-
<100
460
-
-
390
<100
630
-
-
3070
240
-
-
-
-
1,000
10,000
40,000
-
<50
790
-
-
640
<50
1220
-
-
4760
360
-
1
-
-
-
1
4
16
-
<0.2
<0.2
-
-
<0.2
<0.2
<0.2
-
-
<0.2
<0.2
-
0.5
3.1
-
-
-
-
-
-
-
<0.5
<0.5
-
-
<0.5
<0.5
<0.5
-
-
<0.5
<0.5
-
mg/kg
0.5
1.4
-
-
-
-
-
-
-
<0.5
<0.5
-
-
<0.5
<0.5
<0.5
-
-
<0.5
<0.5
-
Xylene (m & p)
mg/kg
0.5
-
-
-
-
-
-
-
-
<0.5
<0.5
-
-
<0.5
<0.5
<0.5
-
-
<0.5
<0.5
-
Xylene (o)
mg/kg
0.5
-
-
-
-
-
-
-
-
<0.5
<0.5
-
-
<0.5
<0.5
<0.5
-
-
<0.5
<0.5
-
Aldrin + Dieldrin
mg/kg
0.03
-
-
10
40
-
1.2
4.8
-
-
<0.61
-
-
-
<0.06
-
-
-
<0.3
-
-
chlordane
mg/kg
0.03
-
-
50
200
-
4
16
-
-
<0.61
-
-
-
<0.06
-
-
-
<0.3
-
-
DDT+DDE+DDD
mg/kg
0.05
-
-
200
800
-
50
50
-
-
<0.61
-
-
-
<0.06
-
-
-
<0.3
-
-
Organochlorine pesticides (sum)
mg/kg
0.03
-
-
-
-
1
-
-
-
-
<0.61
-
-
-
<0.06
-
-
-
<0.3
-
-
Other organochlorine pesticides (sum)
mg/kg
0.03
-
-
-
-
-
10
50
-
-
<0.61
-
-
-
<0.06
-
-
-
<0.3
-
-
Phenol
mg/kg
0.5
-
-
8500
34000
-
-
-
-
-
<1
-
-
<0.5
<1
-
-
-
<1
-
-
Phenols (halogenated) (sum)
mg/kg
0.03
-
-
-
-
1
10
320
-
-
<0.61
-
-
-
<0.06
-
-
-
<0.3
-
-
Phenols (non-halogenated) (sum)
mg/kg
1
-
-
-
-
60
560
2,200
-
-
<1
-
-
-
<1
-
-
-
<1
-
-
Note(s): 1. 2. 3. 4. 5. 6. 7. 8. 9. 10.
- = not analysed or no guideline available; LOR = laboratory limit of reporting; Italic = result in excess of NSW DECC guidelines; Bold = result in excess of NEPM EIL guidelines; Underlined = result in excess of NEPM HIL A guidelines; Shaded = result in excess of NEPM HIL D guidelines Orange – in excess of ‘Fill Material’ guidelines; Red = in excess of ‘Catergory C’ guidelines; Blue = in excess of ‘Category B’ guidelines; and Refer to Appendix D for complete transcripts.
210061_ReportV2.doc
T3
TABLE 2
ORGANIC AND INORGANIC SOIL RESULTS SUMMARY (CONTINUED)
Analyte
Units
LOR
NSW DECC
NEPM 1999 EIL
NEPM 1999 HIL A
NEPM 1999 HIL D
Fill Material
Cat C
Cat B
Aluminium
mg/kg
1
-
-
-
-
-
-
Arsenic
mg/kg
5
-
20
100
400
20
Cadmium
mg/kg
1
-
3
20
80
Chromium (III+VI)
mg/kg
2
-
-
-
Chromium (hexavalent)
mg/kg
0.5
-
1
Cobalt
mg/kg
2
-
Copper
mg/kg
5
Lead
mg/kg
Manganese
TP4
TP4
TP4
TP4
TP5
TP5
TP5
TP5
TP5
TP6
TP6
TP6
TP6
(0.4-0.5)
(0-0.1)
(1.4-1.5)
(2.1-2.2)
(0.4-0.5)
(1.4-1.5)
(2.0-2.1)
(2.9-3.0)
(3.9-4.0)
(0.4-0.5)
(0-0.1)
(1.4-1.5)
(1.9-2.0)
-
-
-
-
<1
-
-
-
-
-
-
-
-
-
500
2000
-
<5
15
10
166
6
28
-
7
114
43
<5
55
3
100
400
-
<1
13
<1
3
<1
2
-
<1
1
1
<1
<1
-
-
-
-
-
21
21
-
55
10
-
-
70
56
38
32
31
100
400
1
500
2000
-
-
-
<0.5
-
-
<0.5
-
-
-
-
-
-
-
100
400
-
-
-
-
-
-
-
61
184
-
-
-
-
-
-
-
-
100
1000
4000
100
5000
20000
-
28
334
22
553
118
171
-
24
242
247
18
38
5
300
600
300
1200
300
1,500
6,000
-
31
337
15
394
56
104
-
33
147
175
26
90
mg/kg
0.1
-
500
1500
6000
-
-
-
-
-
-
<0.1
-
-
-
-
-
-
-
-
-
Mercury
mg/kg
0.1
-
1
15
60
1
75
300
-
<0.1
0.2
0.3
0.7
0.9
2.6
-
0.4
0.3
0.4
<0.1
0.2
Molybdenum
mg/kg
2
-
-
-
-
40
1,000
4,000
-
-
-
<2
-
-
<2
-
-
-
-
-
-
Nickel
mg/kg
2
-
60
600
2400
60
3,000
12,000
-
29
54
17
80
14
7
-
34
69
48
47
28
Selenium
mg/kg
5
-
-
-
-
10
50
200
-
-
-
<5
-
-
<5
-
-
-
-
-
-
Silver
mg/kg
2
-
-
-
-
10
180
720
-
-
-
<2
-
-
<2
-
-
-
-
-
-
Tin
mg/kg
5
-
-
-
-
50
500
-
-
-
-
6
-
-
10
-
-
-
-
-
-
Zinc
mg/kg
5
-
200
7000
28000
200
35,000
140,000
-
54
745
76
717
579
310
-
52
472
439
92
251
Cyanide (Free)
mg/kg
1
-
-
250
1000
-
-
-
-
<1
-
-
-
-
-
-
-
-
-
<1
-
Cyanide Total
mg/kg
1
-
-
500
2000
50
2,500
10,000
-
1
-
1
-
-
19
-
-
-
-
<1
-
Fluoride
mg/kg
40
-
-
-
-
450
10,000
40,000
-
-
-
120
-
-
190
-
-
-
-
-
-
Acenaphthene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
<0.5
-
<0.5
<0.5
<0.5
<1
-
<0.5
<0.5
-
Acenaphthylene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
<0.5
-
<0.5
<0.5
<0.5
<1
-
<0.5
<0.5
-
Anthracene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
<0.5
-
0.9
<0.5
<0.5
<1
-
1.8
<0.5
-
Benz(a)anthracene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
<0.5
-
2.3
<0.5
<0.5
<1
-
9.4
<0.5
-
Benzo(a) pyrene
mg/kg
0.5
-
-
1
4
1
5
20
<0.5
-
<0.5
<0.5
-
1.5
<0.5
<0.5
<1
-
12.4
<0.5
-
Benzo(b) & (k)fluoranthene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
<0.5
-
2.6
<0.5
<0.5
<1
-
17.9
<0.5
-
Benzo(g,h,i)perylene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
<0.5
-
0.8
<0.5
<0.5
<1
-
7.4
<0.5
-
Chrysene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
<0.5
-
1.9
<0.5
0.6
<1
-
8.6
<0.5
-
Dibenz(a,h)anthracene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
<0.5
-
<0.5
<0.5
<0.5
<1
-
1.7
<0.5
-
Fluoranthene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
<0.5
-
4.5
<0.5
0.5
<1
-
15
<0.5
-
Fluorene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
<0.5
-
<0.5
<0.5
<0.5
<1
-
<0.5
<0.5
-
Indeno(1,2,3-c,d)pyrene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
<0.5
-
0.8
<0.5
<0.5
<1
-
6.4
<0.5
-
Naphthalene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
<0.5
-
<0.5
<0.5
<0.5
<1
-
<0.5
<0.5
-
Phenanthrene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
<0.5
-
2.9
<0.5
<0.5
<1
-
4.8
<0.5
-
Pyrene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
<0.5
-
4.4
<0.5
1.4
<1
-
17.5
<0.5
-
210061_ReportV2.doc
T4
TABLE 2
ORGANIC AND INORGANIC SOIL RESULTS SUMMARY (CONTINUED)
Analyte
Units
LOR
NSW DECC
NEPM 1999 EIL
NEPM 1999 HIL A
NEPM 1999 HIL D
Fill Material
Cat C
Cat B
Sum of PAH
mg/kg
0.5
-
-
20
80
20
100
TPH C6 - C9
mg/kg
10
65
-
-
-
100
TPH C10 - C14
mg/kg
50
-
-
-
-
TPH C15 - C28
mg/kg
100
-
-
-
TPH C29-C36
mg/kg
100
-
-
TPH+C10 - C36 (sum)
mg/kg
50
1000
Benzene
mg/kg
0.2
Ethylbenzene
mg/kg
Toluene
TP4
TP4
TP4
TP4
TP5
TP5
TP5
TP5
TP5
TP6
TP6
TP6
TP6
(0.4-0.5)
(0-0.1)
(1.4-1.5)
(2.1-2.2)
(0.4-0.5)
(1.4-1.5)
(2.0-2.1)
(2.9-3.0)
(3.9-4.0)
(0.4-0.5)
(0-0.1)
(1.4-1.5)
(1.9-2.0)
400
<0.5
-
<0.5
<0.5
-
22.6
<0.5
2.5
<1
-
102.9
<0.5
-
650
2,600
<10
-
<10
-
-
<10
30
42
<10
-
<10
<10
-
-
-
-
<50
-
<50
<50
-
<50
150
100
<100
-
<50
<50
-
-
-
-
-
<100
-
<100
<100
-
150
4760
1810
<200
-
220
<100
-
-
-
-
-
-
<100
-
<100
<100
-
120
7010
2510
<200
-
430
<100
-
-
-
-
1,000
10,000
40,000
<50
-
<50
<50
-
270
11,900
4420
<100
-
650
<50
-
1
-
-
-
1
4
16
<0.2
-
<0.2
-
-
<0.2
<0.2
<0.2
<0.2
-
<0.2
<0.2
-
0.5
3.1
-
-
-
-
-
-
<0.5
-
<0.5
-
-
<0.5
<0.5
<0.5
<0.5
-
<0.5
<0.5
-
mg/kg
0.5
1.4
-
-
-
-
-
-
<0.5
-
<0.5
-
-
<0.5
<0.5
<0.5
<0.5
-
<0.5
<0.5
-
Xylene (m & p)
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
-
-
<0.5
<0.5
<0.5
<0.5
-
<0.5
<0.5
-
Xylene (o)
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
-
-
<0.5
<0.5
<0.5
<0.5
-
<0.5
<0.5
-
Aldrin + Dieldrin
mg/kg
0.03
-
-
10
40
-
1.2
4.8
-
-
-
<0.03
-
-
<0.12
-
-
-
-
-
-
chlordane
mg/kg
0.03
-
-
50
200
-
4
16
-
-
-
<0.03
-
-
<0.12
-
-
-
-
-
-
DDT+DDE+DDD
mg/kg
0.05
-
-
200
800
-
50
50
-
-
-
<0.05
-
-
<0.12
-
-
-
-
-
-
Organochlorine pesticides (sum)
mg/kg
0.03
-
-
-
-
1
-
-
-
-
-
<0.03
-
-
<0.12
-
-
-
-
-
-
Other organochlorine pesticides (sum)
mg/kg
0.03
-
-
-
-
-
10
50
-
-
-
<0.03
-
-
<0.12
-
-
-
-
-
-
Phenol
mg/kg
0.5
-
-
8500
34000
-
-
-
-
-
-
<1
-
-
<1
<0.5
<1
<0.5
-
-
-
Phenols (halogenated) (sum)
mg/kg
0.03
-
-
-
-
1
10
320
-
-
-
<0.03
-
-
<0.12
-
-
-
-
-
-
Phenols (non-halogenated) (sum)
mg/kg
1
-
-
-
-
60
560
2,200
-
-
-
<1
-
-
<1
-
-
-
-
-
-
1,2-dichlorobenzene
mg/kg
0.02
-
-
-
-
-
-
-
<0.02
-
-
0.03
-
-
-
-
-
-
1,4-dichlorobenzene
mg/kg
0.02
-
-
-
-
-
-
-
<0.02
-
-
0.04
-
-
-
-
-
-
Note(s): 1. 2. 3. 4. 5. 6. 7. 8. 9. 10.
- = not analysed or no guideline available; LOR = laboratory limit of reporting; Italic = result in excess of NSW DECC guidelines; Bold = result in excess of NEPM EIL guidelines; Underlined = result in excess of NEPM HIL A guidelines; Shaded = result in excess of NEPM HIL D guidelines Orange – in excess of ‘Fill Material’ guidelines; Red = in excess of ‘Catergory C’ guidelines; Blue = in excess of ‘Category B’ guidelines; and Refer to Appendix D for complete transcripts.
210061_ReportV2.doc
T5
TABLE 2
ORGANIC AND INORGANIC SOIL RESULTS SUMMARY (CONTINUED)
Analyte
Units
LOR
NSW DECC
NEPM 1999 EIL
NEPM 1999 HIL A
NEPM 1999 HIL D
Fill Material
Cat C
Cat B
Aluminium
mg/kg
1
-
-
-
-
-
-
Arsenic
mg/kg
5
-
20
100
400
20
Cadmium
mg/kg
1
-
3
20
80
Chromium (III+VI)
mg/kg
2
-
-
-
Chromium (hexavalent)
mg/kg
0.5
-
1
Copper
mg/kg
5
-
Lead
mg/kg
5
Manganese
mg/kg
Mercury
TP7
TP7
TP7
TP8
TP8
TP8
TP8
TP8
TP8
TP9
TP9
TP9
TP9
TP9B
(0.9-1.0)
(0-0.1)
(2.0-2.1)
(0.2-0.3)
(0.9-1.0)
(1.9-2.0)
(2.0-2.1)
(2.4-2.5)
(2.9-3.0)
(0.4-0.5)
(0.9-1.0)
(1.9-2.0)
(2.0-2.1)
(2.5-2.6)
-
-
-
-
-
-
-
<1
-
-
-
-
-
-
-
500
2000
16
101
406
23
9
174
-
-
14
6
20
19
-
278
3
100
400
<1
1
<1
1
<1
2
-
-
<1
<1
<1
<1
-
10
-
-
-
-
-
37
28
22
24
59
-
-
44
45
12
-
-
188
100
400
1
500
2000
<0.5
-
-
-
-
-
-
-
-
-
-
<0.5
-
-
100
1000
4000
100
5000
20000
22
230
40
80
28
132
-
-
12
59
157
484
-
255
300
600
300
1200
300
1,500
6,000
29
190
198
358
26
144
-
-
21
34
34
43
-
773
0.1
-
500
1500
6000
-
-
-
-
-
-
-
-
-
0.9
-
-
-
-
-
-
-
mg/kg
0.1
-
1
15
60
1
75
300
0.1
0.5
0.8
1.7
0.1
0.2
-
-
<0.1
<0.1
0.1
0.1
-
1.8
Molybdenum
mg/kg
2
-
-
-
-
40
1,000
4,000
<2
-
-
-
-
-
-
-
-
-
-
10
-
-
Nickel
mg/kg
2
-
60
600
2400
60
3,000
12,000
39
47
53
17
25
94
-
-
24
75
80
54
-
79
Selenium
mg/kg
5
-
-
-
-
10
50
200
<5
-
-
-
-
-
-
-
-
-
-
<5
-
-
Silver
mg/kg
2
-
-
-
-
10
180
720
<2
-
-
-
-
-
-
-
-
-
-
<2
-
-
Tin
mg/kg
5
-
-
-
-
50
500
-
13
-
-
-
-
-
-
-
-
-
-
<5
-
-
Zinc
mg/kg
5
-
200
7000
28000
200
35,000
140,000
58
307
122
114
45
614
-
-
75
48
76
175
-
1810
Cyanide (Free)
mg/kg
1
-
-
250
1000
-
-
-
-
-
-
-
<1
-
-
-
-
-
-
-
-
-
Cyanide Total
mg/kg
1
-
-
500
2000
50
2,500
10,000
<1
-
-
-
22
-
-
-
-
-
-
<1
-
-
Fluoride
mg/kg
40
-
-
-
-
450
10,000
40,000
180
-
-
-
-
-
-
-
-
-
-
50
-
-
Acenaphthene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
-
<0.5
<0.5
-
-
-
-
<0.5
<0.6
4.2
<0.5
Acenaphthylene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
-
<0.5
<0.5
-
-
-
-
<0.5
<0.6
<2.5
<0.5
Anthracene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
-
<0.5
<0.5
-
-
-
-
<0.5
<0.6
13
<0.5
Benz(a)anthracene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
0.7
-
2.1
<0.5
-
-
-
-
<0.5
0.9
13.1
0.7
Benzo(a) pyrene
mg/kg
0.5
-
-
1
4
1
5
20
<0.5
-
0.6
-
1.6
<0.5
-
-
-
-
<0.5
1.1
6
0.7
Benzo(b) & (k)fluoranthene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
0.7
-
3
<0.5
-
-
-
-
<0.5
1.9
13
1
Benzo(g,h,i)perylene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
-
1
<0.5
-
-
-
-
<0.5
0.9
4.8
0.9
Chrysene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
0.6
-
1.8
<0.5
-
-
-
-
<0.5
0.7
15.1
0.8
Dibenz(a,h)anthracene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
-
<0.5
<0.5
-
-
-
-
<0.5
<0.6
<2.5
<0.5
Fluoranthene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
1.3
-
3.9
<0.5
-
-
-
-
<0.5
1.9
40.4
1
Fluorene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
-
<0.5
<0.5
-
-
-
-
<0.5
<0.6
3.1
<0.5
Indeno(1,2,3-c,d)pyrene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
-
0.9
<0.5
-
-
-
-
<0.5
0.7
3.5
0.7
Naphthalene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
-
<0.5
<0.5
-
-
-
-
5
<0.6
<2.5
<0.5
Phenanthrene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
0.5
-
1.7
<0.5
-
-
-
-
<0.5
0.6
8.8
<0.5
Pyrene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
1.4
-
3.6
<0.5
-
-
-
-
<0.5
1.8
37.2
1.4
Sum of PAH
mg/kg
0.5
-
-
20
80
20
100
400
<0.5
-
5.8
-
19.6
<0.5
-
-
-
-
5
10.5
162.2
7.2
210061_ReportV2.doc
T6
TABLE 2
ORGANIC AND INORGANIC SOIL RESULTS SUMMARY (CONTINUED)
Analyte
Units
LOR
NSW DECC
NEPM 1999 EIL
NEPM 1999 HIL A
NEPM 1999 HIL D
Fill Material
Cat C
Cat B
TPH C6 - C9
mg/kg
10
65
-
-
-
100
650
TPH C10 - C14
mg/kg
50
-
-
-
-
-
TPH C15 - C28
mg/kg
100
-
-
-
-
TPH C29-C36
mg/kg
100
-
-
-
TPH+C10 - C36 (sum)
mg/kg
50
1000
-
Benzene
mg/kg
0.2
1
Ethylbenzene
mg/kg
0.5
Toluene
mg/kg
Xylene (m & p)
TP7
TP7
TP7
TP8
TP8
TP8
TP8
TP8
TP8
TP9
TP9
TP9
TP9
TP9B
(0.9-1.0)
(0-0.1)
(2.0-2.1)
(0.2-0.3)
(0.9-1.0)
(1.9-2.0)
(2.0-2.1)
(2.4-2.5)
(2.9-3.0)
(0.4-0.5)
(0.9-1.0)
(1.9-2.0)
(2.0-2.1)
(2.5-2.6)
2,600
<10
-
<10
-
<10
<10
-
-
-
-
<10
<10
106
<10
-
-
<50
-
<50
-
<50
<50
-
-
-
-
<50
<50
1160
<50
-
-
-
<100
-
<100
-
<100
<100
-
-
-
-
<100
<100
32,700
1320
-
-
-
-
<100
-
<100
-
<100
140
-
-
-
-
190
<100
48,600
1730
-
-
1,000
10,000
40,000
<50
-
<50
-
<50
140
-
-
-
-
190
<50
82,500
3050
-
-
-
1
4
16
<0.2
-
<0.2
-
<0.2
<0.2
-
-
-
-
0.3
<0.2
<0.2
<0.2
3.1
-
-
-
-
-
-
<0.5
-
<0.5
-
<0.5
<0.5
-
-
-
-
<0.5
<0.5
<0.5
<0.5
0.5
1.4
-
-
-
-
-
-
<0.5
-
<0.5
-
<0.5
<0.5
-
-
-
-
<0.5
<0.5
<0.5
<0.5
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
-
<0.5
<0.5
-
-
-
-
<0.5
<0.5
<0.5
<0.5
Xylene (o)
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
-
<0.5
-
<0.5
<0.5
-
-
-
-
<0.5
<0.5
<0.5
<0.5
Aldrin + Dieldrin
mg/kg
0.03
-
-
10
40
-
1.2
4.8
<0.06
-
-
-
-
-
-
-
-
-
-
<0.6
-
-
chlordane
mg/kg
0.03
-
-
50
200
-
4
16
<0.06
-
-
-
-
-
-
-
-
-
-
<0.6
-
-
DDT+DDE+DDD
mg/kg
0.05
-
-
200
800
-
50
50
<0.06
-
-
-
-
-
-
-
-
-
-
<0.6
-
-
Organochlorine pesticides (sum)
mg/kg
0.03
-
-
-
-
1
-
-
<0.06
-
-
-
-
-
-
-
-
-
-
<0.6
-
-
Other organochlorine pesticides (sum)
mg/kg
0.03
-
-
-
-
-
10
50
<0.06
-
-
-
-
-
-
-
-
-
-
<0.6
-
-
Phenol
mg/kg
0.5
-
-
8500
34000
-
-
-
<1
-
-
-
-
-
-
<0.5
-
-
-
<1
<2.5
<0.5
Phenols (halogenated) (sum)
mg/kg
0.03
-
-
-
-
1
10
320
<0.06
-
-
-
-
-
-
-
-
-
-
<0.6
-
-
Phenols (non-halogenated) (sum)
mg/kg
1
-
-
-
-
60
560
2,200
<1
-
-
-
-
-
-
-
-
-
-
<1
-
-
Note(s): 1. 2. 3. 4. 5. 6. 7. 8. 9. 10.
- = not analysed or no guideline available; LOR = laboratory limit of reporting; Italic = result in excess of NSW DECC guidelines; Bold = result in excess of NEPM EIL guidelines; Underlined = result in excess of NEPM HIL A guidelines; Shaded = result in excess of NEPM HIL D guidelines Orange – in excess of ‘Fill Material’ guidelines; Red = in excess of ‘Catergory C’ guidelines; Blue = in excess of ‘Category B’ guidelines; and Refer to Appendix D for complete transcripts.
210061_ReportV2.doc
T7
TABLE 2
ORGANIC AND INORGANIC SOIL RESULTS SUMMARY (CONTINUED)
Analyte
Units
LOR
NSW DECC
NEPM 1999 EIL
NEPM 1999 HIL A
NEPM 1999 HIL D
Fill Material
Category C
Category B
TP10
TP10
TP10
TP10
TP10
TP11
TP11
TP11
TP11
TP11
TP12
TP12
TP12
(0.1-0.2)
(1.4-1.5)
(1.8-1.9)
(1.9-2.0)
(2.4-2.5)
(0-0.1)
(0.9-1.0)
(1.7-1.8)
(1.9-2.0)
(2.9-3.0)
(0.4-0.5)
(1.4-1.5)
(1.9-2.0)
Aluminium
mg/kg
1
-
-
-
-
-
-
-
-
-
<1
-
-
-
-
-
<1
-
-
-
-
Arsenic
mg/kg
5
-
20
100
400
20
500
2000
48
103
-
33
9
10
-
98
100
15
42
36
111
Cadmium
mg/kg
1
-
3
20
80
3
100
400
1
1
-
2
<1
<1
-
2
6
<1
2
<1
<1
Chromium (III+VI)
mg/kg
2
-
-
-
-
-
-
-
43
30
-
136
44
26
-
-
119
6
33
22
38
Chromium (hexavalent)
mg/kg
0.5
-
1
100
400
1
500
2000
-
-
-
-
-
-
-
<0.5
-
-
-
-
-
Cobalt
mg/kg
2
-
-
100
400
-
-
-
-
-
-
-
-
-
109
-
-
-
111
-
-
Copper
mg/kg
5
-
100
1000
4000
100
5000
20000
377
1890
-
641
12
66
-
593
1190
53
343
33
19
Lead
mg/kg
5
300
600
300
1200
300
1,500
6,000
144
325
-
231
17
514
-
288
688
24
431
60
30
Manganese
mg/kg
0.1
-
500
1500
6000
-
-
-
-
-
5.6
-
-
-
-
-
<0.1
-
-
-
-
Mercury
mg/kg
0.1
-
1
15
60
1
75
300
0.3
0.6
-
0.4
<0.1
0.2
-
0.6
1.2
0.9
0.6
0.1
0.1
Molybdenum
mg/kg
2
-
-
-
-
40
1,000
4,000
-
-
-
-
-
-
-
<2
-
-
-
-
-
Nickel
mg/kg
2
-
60
600
2400
60
3,000
12,000
56
120
-
70
17
23
-
55
84
5
69
48
27
Selenium
mg/kg
5
-
-
-
-
10
50
200
-
-
-
-
-
-
-
<5
-
-
-
-
-
Silver
mg/kg
2
-
-
-
-
10
180
720
-
-
-
-
-
-
-
<2
-
-
-
-
-
Tin
mg/kg
5
-
-
-
-
50
500
-
-
-
-
-
-
-
-
170
-
-
-
-
-
Zinc
mg/kg
5
-
200
7000
28000
200
35,000
140,000
288
297
-
720
52
492
-
917
2080
79
2550
200
44
Cyanide (Free)
mg/kg
1
-
-
250
1000
-
-
-
-
<1
-
<1
-
-
-
-
-
-
-
-
<1
Cyanide Total
mg/kg
1
-
-
500
2000
50
2,500
10,000
-
<1
-
2
-
-
-
<1
-
-
-
-
<1
Fluoride
mg/kg
40
-
-
-
-
450
10,000
40,000
-
-
-
-
-
-
-
320
-
-
-
-
-
Acenaphthene
mg/kg
0.5
-
-
-
-
-
-
-
-
-
-
<0.5
-
-
-
<0.5
<0.5
<0.5
-
<0.5
<0.5
Acenaphthylene
mg/kg
0.5
-
-
-
-
-
-
-
-
-
-
<0.5
-
-
-
<0.5
<0.5
0.5
-
<0.5
<0.5
Anthracene
mg/kg
0.5
-
-
-
-
-
-
-
-
-
-
<0.5
-
-
-
<0.5
<0.5
1
-
0.7
<0.5
Benz(a)anthracene
mg/kg
0.5
-
-
-
-
-
-
-
-
-
-
1.2
-
-
-
<0.5
<0.5
2
-
2.4
<0.5
Benzo(a) pyrene
mg/kg
0.5
-
-
1
4
1
5
20
-
-
-
1
-
-
-
<0.5
<0.5
1.8
-
2.3
<0.5
Benzo(b) & (k)fluoranthene
mg/kg
0.5
-
-
-
-
-
-
-
-
-
-
2
-
-
-
<0.5
<0.5
3
-
3.6
<0.5
Benzo(g,h,i)perylene
mg/kg
0.5
-
-
-
-
-
-
-
-
-
-
0.9
-
-
-
<0.5
<0.5
1.3
-
1.6
<0.5
Chrysene
mg/kg
0.5
-
-
-
-
-
-
-
-
-
-
1.1
-
-
-
<0.5
<0.5
2.1
-
2.4
<0.5
Dibenz(a,h)anthracene
mg/kg
0.5
-
-
-
-
-
-
-
-
-
-
<0.5
-
-
-
<0.5
<0.5
<0.5
-
<0.5
<0.5
Fluoranthene
mg/kg
0.5
-
-
-
-
-
-
-
-
-
-
2
-
-
-
<0.5
<0.5
4.3
-
5
<0.5
Fluorene
mg/kg
0.5
-
-
-
-
-
-
-
-
-
-
<0.5
-
-
-
<0.5
<0.5
1.3
-
<0.5
<0.5
Indeno(1,2,3-c,d)pyrene
mg/kg
0.5
-
-
-
-
-
-
-
-
-
-
0.8
-
-
-
<0.5
<0.5
1
-
1.3
<0.5
Naphthalene
mg/kg
0.5
-
-
-
-
-
-
-
-
-
-
<0.5
-
-
-
<0.5
<0.5
0.8
-
<0.5
<0.5
Phenanthrene
mg/kg
0.5
-
-
-
-
-
-
-
-
-
-
0.7
-
-
-
<0.5
<0.5
4.3
-
2.6
<0.5
Pyrene
mg/kg
0.5
-
-
-
-
-
-
-
-
-
-
1.9
-
-
-
<0.5
0.7
4.2
-
4.9
<0.5
210061_ReportV2.doc
T8
TABLE 2
ORGANIC AND INORGANIC SOIL RESULTS SUMMARY (CONTINUED)
Analyte
Units
LOR
NSW DECC
NEPM 1999 EIL
NEPM 1999 HIL A
NEPM 1999 HIL D
Fill Material
Category C
Category B
TP10
TP10
TP10
TP10
TP10
TP11
TP11
TP11
TP11
TP11
TP12
TP12
TP12
(0.1-0.2)
(1.4-1.5)
(1.8-1.9)
(1.9-2.0)
(2.4-2.5)
(0-0.1)
(0.9-1.0)
(1.7-1.8)
(1.9-2.0)
(2.9-3.0)
(0.4-0.5)
(1.4-1.5)
(1.9-2.0)
Sum of PAH
mg/kg
0.5
-
-
20
80
20
100
400
-
-
-
11.6
-
-
-
<0.5
0.7
27.6
-
26.8
<0.5
TPH C6 - C9
mg/kg
10
65
-
-
-
100
650
2,600
-
-
-
<10
-
-
-
<10
<10
<10
-
<10
<10
TPH C10 - C14
mg/kg
50
-
-
-
-
-
-
-
-
-
-
<50
-
-
-
<50
70
<50
-
<50
<50
TPH C15 - C28
mg/kg
100
-
-
-
-
-
-
-
-
-
-
340
-
-
-
680
1760
1050
-
240
130
TPH C29-C36
mg/kg
100
-
-
-
-
-
-
-
-
-
-
540
-
-
-
1710
3080
1530
-
500
120
TPH+C10 - C36 (sum)
mg/kg
50
1000
-
-
-
1,000
10,000
40,000
-
-
-
880
-
-
-
2390
4910
2580
-
740
250
Benzene
mg/kg
0.2
1
-
-
-
1
4
16
-
-
-
<0.2
-
-
-
<0.2
<0.2
<0.2
-
<0.2
<0.2
Ethylbenzene
mg/kg
0.5
3.1
-
-
-
-
-
-
-
-
-
<0.5
-
-
-
<0.5
<0.5
<0.5
-
<0.5
<0.5
Toluene
mg/kg
0.5
1.4
-
-
-
-
-
-
-
-
-
<0.5
-
-
-
<0.5
<0.5
<0.5
-
<0.5
<0.5
Xylene (m & p)
mg/kg
0.5
-
-
-
-
-
-
-
-
-
-
<0.5
-
-
-
<0.5
<0.5
<0.5
-
<0.5
<0.5
Xylene (o)
mg/kg
0.5
-
-
-
-
-
-
-
-
-
-
<0.5
-
-
-
<0.5
<0.5
<0.5
-
<0.5
<0.5
Aldrin + Dieldrin
mg/kg
0.03
-
-
10
40
-
1.2
4.8
-
-
-
-
-
-
-
<0.12
-
-
-
-
-
chlordane
mg/kg
0.03
-
-
50
200
-
4
16
-
-
-
-
-
-
-
<0.12
-
-
-
-
-
DDT+DDE+DDD
mg/kg
0.05
-
-
200
800
-
50
50
-
-
-
-
-
-
-
<0.12
-
-
-
-
-
Organochlorine pesticides (sum)
mg/kg
0.03
-
-
-
-
1
-
-
-
-
-
-
-
-
-
<0.12
-
-
-
-
-
Other organochlorine pesticides (sum)
mg/kg
0.03
-
-
-
-
-
10
50
-
-
-
-
-
-
-
<0.12
-
-
-
-
-
Phenol
mg/kg
0.5
-
-
8500
34000
-
-
-
-
-
-
<0.5
<0.5
-
-
<1
<0.5
-
-
-
<0.5
Phenols (halogenated) (sum)
mg/kg
0.03
-
-
-
-
1
10
320
-
-
-
-
-
-
-
<0.12
-
-
-
-
-
Phenols (non-halogenated) (sum)
mg/kg
1
-
-
-
-
60
560
2,200
-
-
-
-
-
-
-
<1
-
-
-
-
-
Note(s): 1. 2. 3. 4. 5. 6. 7. 8. 9. 10.
- = not analysed or no guideline available; LOR = laboratory limit of reporting; Italic = result in excess of NSW DECC guidelines; Bold = result in excess of NEPM EIL guidelines; Underlined = result in excess of NEPM HIL A guidelines; Shaded = result in excess of NEPM HIL D guidelines Orange – in excess of ‘Fill Material’ guidelines; Red = in excess of ‘Catergory C’ guidelines; Blue = in excess of ‘Category B’ guidelines; and Refer to Appendix D for complete transcripts.
210061_ReportV2.doc
T9
TABLE 2
ORGANIC AND INORGANIC SOIL RESULTS SUMMARY (CONTINUED)
Analyte
Units
LOR
NSW DECC
NEPM 1999 EIL
NEPM 1999 HIL A
NEPM 1999 HIL D
Fill Material
Category C
Category B
TP12
TP13
TP13
TP13
TP13
TP14
TP14
TP14
(2.4-2.5)
(0.4-0.5)
(0-0.1)
(1.5-1.6)
(2.0-2.1)
(0.9-1.0)
(1.6-1.7)
(2.8-2.9)
Aluminium
mg/kg
1
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
Arsenic
mg/kg
5
-
20
100
400
20
500
2000
74
8
90
112
7
148
<5
119
Cadmium
mg/kg
1
-
3
20
80
3
100
400
1
<1
3
<1
<1
4
<1
2
Chromium (III+VI)
mg/kg
2
-
-
-
-
-
-
-
97
36
85
-
97
92
<2
68
Chromium (hexavalent)
mg/kg
0.5
-
1
100
400
1
500
2000
-
-
-
<0.5
-
-
-
-
Cobalt
mg/kg
2
-
-
100
400
-
-
-
-
-
-
-
-
66
-
-
Copper
mg/kg
5
-
100
1000
4000
100
5000
20000
98
24
267
60
21
568
<5
175
Lead
mg/kg
5
300
600
300
1200
300
1,500
6,000
142
38
320
93
38
354
<5
233
Manganese
mg/kg
0.1
-
500
1500
6000
-
-
-
-
-
-
-
-
-
-
-
Mercury
mg/kg
0.1
-
1
15
60
1
75
300
0.3
<0.1
0.5
0.4
0.1
0.6
0.6
0.5
Molybdenum
mg/kg
2
-
-
-
-
40
1,000
4,000
-
-
-
<2
-
-
-
-
Nickel
mg/kg
2
-
60
600
2400
60
3,000
12,000
49
49
66
44
17
107
<2
69
Selenium
mg/kg
5
-
-
-
-
10
50
200
-
-
-
<5
-
-
-
-
Silver
mg/kg
2
-
-
-
-
10
180
720
-
-
-
<2
-
-
-
-
Tin
mg/kg
5
-
-
-
-
50
500
-
-
-
-
33
-
-
-
-
Zinc
mg/kg
5
-
200
7000
28000
200
35,000
140,000
472
88
560
147
109
1130
<5
804
Cyanide (Free)
mg/kg
1
-
-
250
1000
-
-
-
-
-
-
-
-
-
<1
-
Cyanide Total
mg/kg
1
-
-
500
2000
50
2,500
10,000
-
-
-
1
-
-
<1
-
Fluoride
mg/kg
40
-
-
-
-
450
10,000
40,000
-
-
-
160
-
-
-
-
Acenaphthene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
<0.5
-
<0.5
<0.5
<0.5
<0.5
-
Acenaphthylene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
<0.5
-
<0.5
<0.5
<0.5
<0.5
-
Anthracene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
<0.5
-
<0.5
<0.5
<0.5
<0.5
-
Benz(a)anthracene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
<0.5
-
<0.5
<0.5
<0.5
<0.5
-
Benzo(a) pyrene
mg/kg
0.5
-
-
1
4
1
5
20
<0.5
<0.5
-
<0.5
<0.5
<0.5
<0.5
-
Benzo(b) & (k)fluoranthene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
<0.5
-
<0.5
<0.5
0.5
<0.5
-
Benzo(g,h,i)perylene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
<0.5
-
<0.5
<0.5
<0.5
<0.5
-
Chrysene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
<0.5
-
<0.5
<0.5
<0.5
<0.5
-
Dibenz(a,h)anthracene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
<0.5
-
<0.5
<0.5
<0.5
<0.5
-
Fluoranthene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
<0.5
-
<0.5
<0.5
0.8
<0.5
-
Fluorene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
<0.5
-
<0.5
<0.5
<0.5
<0.5
-
Indeno(1,2,3-c,d)pyrene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
<0.5
-
<0.5
<0.5
<0.5
<0.5
-
Naphthalene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
<0.5
-
<0.5
<0.5
<0.5
<0.5
-
210061_ReportV2.doc
T10
TABLE 2
ORGANIC AND INORGANIC SOIL RESULTS SUMMARY (CONTINUED)
Analyte
Units
LOR
NSW DECC
NEPM 1999 EIL
NEPM 1999 HIL A
NEPM 1999 HIL D
Fill Material
Category C
Category B
TP12
TP13
TP13
TP13
TP13
TP14
TP14
TP14
(2.4-2.5)
(0.4-0.5)
(0-0.1)
(1.5-1.6)
(2.0-2.1)
(0.9-1.0)
(1.6-1.7)
(2.8-2.9)
Phenanthrene
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
<0.5
-
<0.5
<0.5
<0.5
<0.5
-
Pyrene
mg/kg
0.5
-
-
-
-
-
-
-
0.6
<0.5
-
<0.5
<0.5
0.7
<0.5
-
Sum of PAH
mg/kg
0.5
-
-
20
80
20
100
400
0.6
<0.5
-
<0.5
<0.5
2
<0.5
-
TPH C6 - C9
mg/kg
10
65
-
-
-
100
650
2,600
<10
<10
-
<10
<10
<10
<10
-
TPH C10 - C14
mg/kg
50
-
-
-
-
-
-
-
<50
<50
-
<50
<50
<50
<50
-
TPH C15 - C28
mg/kg
100
-
-
-
-
-
-
-
170
<100
-
<100
140
270
110
-
TPH C29-C36
mg/kg
100
-
-
-
-
-
-
-
130
<100
-
<100
140
540
280
-
TPH+C10 - C36 (sum)
mg/kg
50
1000
-
-
-
1,000
10,000
40,000
300
<50
-
<50
280
810
390
-
Benzene
mg/kg
0.2
1
-
-
-
1
4
16
<0.2
<0.2
-
<0.2
<0.2
<0.2
<0.2
-
Ethylbenzene
mg/kg
0.5
3.1
-
-
-
-
-
-
<0.5
<0.5
-
<0.5
<0.5
<0.5
<0.5
-
Toluene
mg/kg
0.5
1.4
-
-
-
-
-
-
<0.5
<0.5
-
<0.5
<0.5
<0.5
<0.5
-
Xylene (m & p)
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
<0.5
-
<0.5
<0.5
<0.5
<0.5
-
Xylene (o)
mg/kg
0.5
-
-
-
-
-
-
-
<0.5
<0.5
-
<0.5
<0.5
<0.5
<0.5
-
Aldrin + Dieldrin
mg/kg
0.03
-
-
10
40
-
1.2
4.8
-
-
-
<0.12
-
-
-
-
chlordane
mg/kg
0.03
-
-
50
200
-
4
16
-
-
-
<0.12
-
-
-
-
DDT+DDE+DDD
mg/kg
0.05
-
-
200
800
-
50
50
-
-
-
<0.12
-
-
-
-
Organochlorine pesticides (sum)
mg/kg
0.03
-
-
-
-
1
-
-
-
-
-
<0.12
-
-
-
-
Other organochlorine pesticides (sum)
mg/kg
0.03
-
-
-
-
-
10
50
-
-
-
<0.12
-
-
-
-
Phenol
mg/kg
0.5
-
-
8500
34000
-
-
-
<0.5
-
-
<1
<0.5
-
-
-
Phenols (halogenated) (sum)
mg/kg
0.03
-
-
-
-
1
10
320
-
-
-
<0.12
-
-
-
-
Phenols (non-halogenated) (sum)
mg/kg
1
-
-
-
-
60
560
2,200
-
-
-
<1
-
-
-
-
Note(s): 1. 2. 3. 4. 5. 6. 7. 8. 9. 10.
- = not analysed or no guideline available; LOR = laboratory limit of reporting; Italic = result in excess of NSW DECC guidelines; Bold = result in excess of NEPM EIL guidelines; Underlined = result in excess of NEPM HIL A guidelines; Shaded = result in excess of NEPM HIL D guidelines Orange – in excess of ‘Fill Material’ guidelines; Red = in excess of ‘Catergory C’ guidelines; Blue = in excess of ‘Category B’ guidelines; and Refer to Appendix D for complete transcripts.
210061_ReportV2.doc
T11
TABLE 3
SOIL ASLP RESULTS
Analyte
LOR
Cat C
Arsenic
0.1
Copper
TP1
TP2
(1.51.6)
(3.2-3.3)
0.7
-
0.7
0.1
200
-
Naphthalene
1
-
Acenaphthylene
1
Acenaphthene
TP5 (2-2.1)
TP6
TP7
TP9
TP9B (2.5-2.6)
TP10
(0-0.1)
(2-2.1)
(2-2.1)
-
-
0.5
-
-
-
-
-
-
-
-
-
2.6
<1.0
-
-
-
-
-
-
-
-
<1.0
-
-
-
-
-
-
-
1
-
<1.0
-
-
-
-
-
-
-
Fluorene
1
-
<1.0
-
-
-
-
-
-
-
Phenanthrene
1
-
2.2
-
-
-
-
-
-
-
Anthracene
1
-
<1.0
-
-
-
-
-
-
-
Fluoranthene
1
-
<1.0
-
-
-
-
-
-
-
Pyrene
1
-
<1.0
-
-
-
-
-
-
-
Benz(a)anthracene
1
-
<1.0
-
-
-
-
-
-
-
Chrysene
1
-
<1.0
-
-
-
-
-
-
-
Benzo(b)fluoranthene
1
-
<1.0
-
-
-
-
-
-
-
Benzo(k)fluoranthene
1
-
<1.0
-
-
-
-
-
-
-
0.5
1.0
<0.5
-
-
<0.5
-
<0.5
-
-
Indeno(1.2.3.cd)pyrene
1
-
<1.0
-
-
-
-
-
-
-
Dibenz(a.h)anthracene
1
-
<1.0
-
-
-
-
-
-
-
Benzo(g.h.i)perylene
1
-
<1.0
-
-
-
-
-
-
-
TPH C10 - C14
50
-
-
-
<50
-
-
-
<50
-
TPH C15 - C28
100
-
-
-
110
-
-
-
<100
-
TPH C29-C36
50
-
-
-
<50
-
-
-
<50
-
TPH+C10 - C36 (sum)
50
-
-
-
110
-
-
-
<50
-
Benzo(a)pyrene
Note(s): 1. 2. 3. 4.
(1.8-1.9)
- = not analysed or no guideline available; all units in Âľg/L, except As and Cu (reported in mg/L); LOR = laboratory limit of reporting; and Refer to Appendix D for complete transcripts.
210061_ReportV2.doc
T12
TABLE 4
TPH SPECIATION RESULTS
Analyte
Units
LOR
NEPM HIL A
NEPM HIL D
TP6
TP9
TP1
TP5
TP11
(0-0.1)
(2.0-2.1)
(1.5-1.6)
(2.0-2.1)
(1.9-2.0)
Aliphatic C16-C35
mg/kg
100
5,600
22,400
-
16,600
-
3,000
1,000
Aliphatic > C35
mg/kg
100
56,000
224,000
-
9,600
-
1,900
700
Aromatic C16-C35
mg/kg
90
90
360
-
8,590
-
2,160
660
Aromatic > C35
mg/kg
100
-
-
-
7,400
-
2,700
700
Note(s): 1. Bold = in excess of NEPM HIL A guidelines; 2. Shaded in excess of NEPM HIL D guidelines; and 3. Refer to Appendix D for complete transcripts.
TABLE 5
TPH SILICA GEL CLEANUP RESULTS Primary Result
Analyte
Units
LOR
SGC Result
Primary Result
SGC Result
TP3
TP3
TP11
TP11
(1.4-1.5)
(1.4-1.5)
(1.9-2.0)
(1.9-2.0)
TPH C10 - C14
mg/kg
50
<50
<50
70
<50
TPH C15 - C28
mg/kg
100
1,690
1,090
1,760
790
TPH C29-C36
mg/kg
100
3,070
2,070
3,080
1,120
TPH+C10 - C36 (sum)
mg/kg
50
4,760
3,160
4,910
1,910
Note(s): 1. Refer to Appendix D for complete transcripts.
TABLE 6
SUMMARY OF PASS RESULTS
Sample
Net acidity criteria (1-1000 tonnes) Depth Total sulphur - %S (oven-dry)
Acid trail - mol H+ /tonne (oven-dry)
TP3
1
2.0-2.1
0.06
37.46
TP4
2
2.1-2.2
0.13
81.16
TP8
1
2.0-2.1
0.13
81.16
TP10
1
1.8-1.9
0.59
368.33
TP11
1
1.9-2.0
0.73
EPA 665.1 criteria
2
0.1 /0.06
455.73 1
2
1
62 /36
Note(s): 1. 1 criteria derived for medium to heavy clays and silty clays with approximate clay content > 40%; 2. 2 criteria derived for sandy loams to light clays with approximate clay content 5-40%; and 3. bold indicates concentration exceeds adopted EPA 665.1 criteria.
210061_ReportV2.doc
T13
TABLE 7 Sample ID
Units TP3
SUMMARY OF PASS RESULTS CONTINUED Depth
Texture
Interval
Group
Acid^ TAA
Sulfur
TPA
A - SPOS
Buffering B - SCR
m 2.0-2.1
ANC
Ca + Mg
NAA
NAB
LR
SPOS
SCR
NA x 1.02 x 1.5 x BD 3
kg H2SO4/T 3
---
---
---
---
kg CaCO3/m
41.30
4
---
---
---
---
8.87
1.22
-21.58
0
TP4
2.1-2.2
2
<0.10
<0.10
1.22
0.18
26.26
5
TP8
2.0-2.1
3
---
---
---
---
50.00
4
---
---
---
---
TP10
1.8-1.9
3
<0.10
<0.10
8.26
4.68
14.10
5
19.88
8.26
-9.43
0
---
---
---
---
TP11
1.9-2.0
3
---
---
---
---
214.00
4
Note(s): 1. TAA total actual acidity; TPA titratable potential acidity (TSA = TPA-TAA); SCR chromium reducible sulfur; SPOS peroxide oxidisable sulfur; TOS total oxidisable sulfur; ANC acid neutralizing capacity; NA net acidity (sulfur + acid – buffering); OP oxidation potential; LR lime requirement; 2. *includes accounting for fineness factor (FF); ^ if pHKCl <4.5 determine retained acidity (SNAS) and determine NA as sulfur + acid + retained acidity– buffering; and 3. texture groups are: 1. Coarse = sands; 2. Medium = sandy loams/silts to light clays; 3. Fine = medium to heavy clays, silty clays 4. laboratory calculated ANC; and 5. ANC values derived from primary ANC value reported in %CaCO3.
210061_ReportV2.doc
T14
TABLE 8
SOIL SULFIDE HAZARD CLASSES
Risk Hazard Class Texture Group
No risk
Risk
Class 1
Class 2
Class 3
Class 4
‘No-sulfur’
‘Non-reactive’
‘Moderate Risk’
‘High Risk’
Sulfur
NA
Sulfur
1 (Coarse)
1
N/A
>1 (<10)
2 (Medium)
2
N/A
>2 (<20)
3 (Fine)
3
N/A
NA
Sulfur
NA
Sulfur
NA
4
<3
>1
>3
>10
>5
4
<6
>2
>6
>20
>10
4
<9
>3
>9
>30
>15
>3 (<30)
Note(s): 1. all units in kg H2SO4 generated per tonne of soil 2. NA net acidity (sulfur + acid – buffering capacity) 3. Texture groups are: 1. Coarse: sands; 2. Medium: loams/silts-light clays; 3. Fine: medium to heavy clays, silty clays 4. sulfur levels exceeding the values in brackets require confirmation through incubation tests or weathering trials
210061_ReportV2.doc
T15
APPENDIX A
210061_ReportV2.doc
PRELIMINARY SITE DEVELOPMENT PLANS
APPENDIX B
210061_ReportV2.doc
PHOTOGRAPHIC LOG
Plate 1 -
View of the site prior to works. Note the existing soil stockpiles and test pit marker flags
Plate 2 -
Excavation for test pit TP1
210061_Report.doc
Plate 3 -
View of excavated test pit TP1
Plate 4 -
View of perched water infiltration within test pit TP7
210061_Report.doc
Plate 5 -
Hydrocarbon impacted fill material excavated from test pit TP9. Note the presence of oil drums, rags and machine parts
Plate 6 -
Perched water within test pit TP9 with a visible sheen on the surface
210061_Report.doc
Plate 7 -
210061_Report.doc
View of the site following test pit reinstatement
APPENDIX C
210061_ReportV2.doc
GEOLOGICAL BORELOGS
Geological Borelog Logged by JF
PROJECT: Fastnet
Proj. Manager JF
pH
Fill: Loose, light brown/grey CLAYEY SILT with organic matter
pH - water
Reading
PID/FID
Moisture Content
Duplicate
Lost
Undisturbed
Disturbed
Depth metres
STRATIGRAPHY
GRAPHIC LOG
SAMPLES
Borehole Log: TP1
pH - soil
JOB NUMBER 210061 DATUM DATE 9 August 2010
Background
LOCATION Gordon Pde Lot SURFACE ELEVATION GROUNDWATER NGWE DRILL METHOD TP
Odour
Comments
No odour throughout M1
Fill: Soft, grey SILTY CLAY with roots
0
0
0
0
Fill: Loose, brown SILTY CLAY with large bluestone and rubble inclusions
1.0
D
8.0
Minor rubbish (paper, glass, timber and steel) inclusions
D
Natural: Medium dense, brown SILTY CLAY with iron oxide staining
2.0
M1
Hole collapsing between 1.5 and 1.9 mBGL
7.5
Becoming very moist
Natural: Saturated, grey/dark brown SILTY CLAY with weathered basalt rock inclusions
W EOH at 2.7 mBGL refusal on basalt
3.0
NOTE: This bore log is for environmental purposes only and is not intended to provide geotechnical information.
Geological Borelog Logged by JF
PROJECT: Fastnet
Proj. Manager JF
pH
Fill: Loose, brown CLAYEY SILT with sand and roots
pH - water
Reading
PID/FID
Moisture Content
Duplicate
Lost
Undisturbed
Disturbed
Depth metres
STRATIGRAPHY
GRAPHIC LOG
SAMPLES
Borehole Log: TP2
pH - soil
JOB NUMBER 210061 DATUM DATE 9 August 2010
Background
LOCATION Gordon Pde Lot SURFACE ELEVATION GROUNDWATER NGWE DRILL METHOD TP
Odour
Comments
No odour
D
Fill: Stiff, weathered, brown CLAY
Fill: Loose, brown SILTY CLAY with rubble and rubbish (glass, paper, steel)
1.0
D
0
0.8
M1
0
1.5 9.0
Natural: Soft, grey/dark blue SILTY CLAY 2.0
Organic odour
0
1.9
0
3.3
Weathered basalt rock inclusions
Becoming saturated in clay lenses
3.0
W
EOH at 3.4 mBGL refusal on basalt
NOTE: This bore log is for environmental purposes only and is not intended to provide geotechnical information.
Geological Borelog
Fill: Loose, brown SANDY SILT with grass and roots
Logged by JF
PROJECT: Fastnet
Proj. Manager JF
pH
pH - water
Reading
PID/FID
Moisture Content
Duplicate
Lost
Undisturbed
Disturbed
Depth metres
STRATIGRAPHY
GRAPHIC LOG
SAMPLES
Borehole Log: TP3
pH - soil
JOB NUMBER 210061 DATUM DATE 9 August 2010
Background
LOCATION Gordon Pde Lot SURFACE ELEVATION GROUNDWATER NGWE DRILL METHOD TP
Odour
Comments
D No odour throughout
Fill: Loose, brow SILTY CLAY with weathered basalt floaters and rubbish (paper, glass bottles, rubber, wood) D
1.0
0
4.5
0
1.4 8.0
Fill: Loose, black, fine grained CLAYEY SILT M2
Becoming moist
2.0
M2
M3
Natural: Dense, grey/dark blue CLAY with minor silt and weathered basalt inclusions
7.5 Point of water strike difficult to measure due to collapse of hole and amount of water
Extremely saturated W
3.0
NOTE: This bore log is for environmental purposes only and is not intended to provide geotechnical information.
Geological Borelog Logged by JF
PROJECT: Fastnet
Proj. Manager JF
pH
Fill: Loose, light brown SANDY SILT with grass and roots
pH - water
Reading
PID/FID
Moisture Content
Duplicate
Lost
Undisturbed
Disturbed
Depth metres
STRATIGRAPHY
GRAPHIC LOG
SAMPLES
Borehole Log: TP4
pH - soil
JOB NUMBER 210061 DATUM DATE 9 August 2010
Background
LOCATION Gordon Pde Lot SURFACE ELEVATION GROUNDWATER NGWE DRILL METHOD TP
Odour
Comments
No odour throughout
Fill: Stiff, brown SILTY CLAY sand, gravel, bluestone and steel inclusions
Becoming loose
Natural: Medium loose, dark grey/black, fine grained SILT
D
0
1.2
BD1 D SP1
0
1.8 7.0
M2
0
0.6 6.0
1.0
2.0
EOH at 2.4 mBGL refusal on basalt
3.0
NOTE: This bore log is for environmental purposes only and is not intended to provide geotechnical information.
Geological Borelog JOB NUMBER 210061 DATUM DATE 9 August 2010
Logged by JF
PROJECT: Fastnet
Proj. Manager JF
pH
0
0.6 7.5
M1
0
1.8 8.0
W
0 12.6
HC odour
W
0 20.8
HC odour
M2
0
No odour
pH - water
D
pH - soil
Background
PID/FID
Borehole Log: TP5
Moisture Content
Duplicate
Lost
Undisturbed
Disturbed
Depth metres
STRATIGRAPHY
GRAPHIC LOG
SAMPLES
Reading
LOCATION Gordon Pde Lot SURFACE ELEVATION GROUNDWATER NGWE DRILL METHOD TP
Odour
Comments
Fill: Loose, brown SILTY CLAY with grass Fill: Stiff, grey/brown CLAY with bluestone rocks and rubble
Fill: Loose, brown SILTY CLAY with rubbish (plastic, glass, wood and paper) and bluestone and brick rubble
Fill: Soft, saturated, grey/dark grey CLAYEY SILT with dark staining and rubbish (paper, wood) inclusions
No odour
D 1.0
Water strike at approx 1.8 mBGL 2.0
3.0
Natural: Firm, grey/dark blue CLAY with minor silt
6.4
4.0
EOH at 4.5 mBGL target depth NOTE: This bore log is for environmental purposes only and is not intended to provide geotechnical information.
Geological Borelog
Fill: Loose, brown CLAYEY SILT with roots
Logged by JF
PROJECT: Fastnet
Proj. Manager JF
pH
pH - water
Reading
PID/FID
Moisture Content
Duplicate
Lost
Undisturbed
Disturbed
Depth metres
STRATIGRAPHY
GRAPHIC LOG
SAMPLES
Borehole Log: TP6
pH - soil
JOB NUMBER 210061 DATUM DATE 9 August 2010
Background
LOCATION Gordon Pde Lot SURFACE ELEVATION GROUNDWATER NGWE DRILL METHOD TP
Odour
Comments
D No odour throughout
Fill: Loose, light brown SILTY CLAY with plastic and paper rubbish and concrete and bluestone rubble
Fill: Becoming stiff, weathered CLAY with rubble
D
0
1.2 7.5
D
0
2.8 8.0
W
0
1.7
1.0
Natural: Medium dense, grey CLAY Water strike at 1.9 mBGL
2.0
Weathered basalt floaters
Natural: Weathered BASALT with dense grey clay
W EOH at 2.5 mBGL refusal on basalt
3.0
NOTE: This bore log is for environmental purposes only and is not intended to provide geotechnical information.
Geological Borelog PROJECT: Fastnet
Proj. Manager JF
Reading
pH
Background
PID/FID
Logged by JF
Moisture Content
Fill: Loose, brown CLAYEY SILT with grass and roots
Duplicate
Lost
Undisturbed
Disturbed
Depth metres
STRATIGRAPHY
GRAPHIC LOG
SAMPLES
Borehole Log: TP7
D
0
0.6
D
0
1.2
D
0
0.1 8.0
pH - water
JOB NUMBER 210061 DATUM DATE 9 August 2010
pH - soil
LOCATION Salisbury St - road reserve SURFACE ELEVATION GROUNDWATER NGWE DRILL METHOD TP
Odour
Comments
No odour throughout
Fill: Firm, brown SILTY CLAYwith gravel
Large bluestone and building rubble inclusions
1.0
Large weathered basalt floater inclusions
Plastic, paper and wood rubbish
Natural: Soft, grey CLAY with weathered basalt inclusions
Water strike at 1.9 mBGL 2.0
W
0
1.2 7.5 EOH at 2.2 mBGL refusal on basalt
3.0
NOTE: This bore log is for environmental purposes only and is not intended to provide geotechnical information.
Geological Borelog Logged by JF
PROJECT: Fastnet
Proj. Manager JF
pH
pH - water
Reading
PID/FID
Moisture Content
Duplicate
Lost
Undisturbed
Disturbed
Depth metres
STRATIGRAPHY
GRAPHIC LOG
SAMPLES
Borehole Log: TP8
pH - soil
JOB NUMBER 210061 DATUM DATE 9 August 2010
Background
LOCATION Salisbury St - road reserve SURFACE ELEVATION GROUNDWATER NGWE DRILL METHOD TP
Odour
Comments
Fill: Loose, brown CLAYEY SILT with roots No odour throughout
Fill: Loose, brown SILTY CLAY with bluestone and brick rubble
D
7.5
D
0
1.4 8.0
W
0
2.1
1.0
Fill: Medium loose, dark grey/black SILT with brown, weathered silty clay lenses, minor wood and paper inclusions 2.0
Natural: Dense, grey/blue CLAY with minor silt and weathered basalt inclusions
Water strike at 1.9 mBGL 8.0
W
0
0.8
M2
0
1.1
PASS sample
3.0
EOH at 3.2 mBGL target depth
NOTE: This bore log is for environmental purposes only and is not intended to provide geotechnical information.
Geological Borelog Logged by JF
PROJECT: Fastnet
Proj. Manager JF
pH
Fill: Loose, brown CLAYEY SILT with roots and sand
pH - water
Reading
PID/FID
Moisture Content
Duplicate
Lost
Undisturbed
Disturbed
Depth metres
STRATIGRAPHY
GRAPHIC LOG
SAMPLES
Borehole Log: TP9
pH - soil
JOB NUMBER 210061 DATUM DATE 9 August 2010
Background
LOCATION Salisbury St - road reserve SURFACE ELEVATION GROUNDWATER NGWE DRILL METHOD TP
Odour
Comments
No odour
Fill: Stiff, brown and grey CLAY with roots
D
Fill: Loose, black, fine grained SILT
Fill: Loose, brown SILTY CLAY with bricks, bluestone rubble and minor rubbish (paper and glass)
7.0
D
0
0.6 8.0
W
0 25.4
1.0
Oily rag, foam, rubber and drum parts within silty clay
Fill: Soft, grey/black silty clay with oil staining and weathered basalt floaters 2.0
Very strong HC/oil odour
Water strike at approx 1.9 mBGL PASS sample Lithology hard to distinguish due to hole collapse and water presence
Natural: Dense, grey/blue CLAY with minor silt M2
No odour EOH at 2.6 mBGL at target depth
3.0
NOTE: This bore log is for environmental purposes only and is not intended to provide geotechnical information.
Geological Borelog
Fill: Loose, dark brown CLAYEY SILT with roots and sand
Logged by JF
PROJECT: Fastnet
Proj. Manager JF
pH
D
pH - water
Reading
PID/FID
Moisture Content
Duplicate
Lost
Undisturbed
Disturbed
Depth metres
STRATIGRAPHY
GRAPHIC LOG
SAMPLES
Borehole Log: TP10
pH - soil
JOB NUMBER 210061 DATUM DATE 9 August 2010
Background
LOCATION Salisbury St Lot SURFACE ELEVATION GROUNDWATER NGWE DRILL METHOD TP
Odour
Comments
No odour
Fill: Medium dense, brown, weathered CLAY
Fill: Loose, dark brown SILTY CLAY with brick and bluestone rubble and rubbish (plastic, paper and glass)
D
0
0
8.0
1.0
D
M1
Fill: Soft, black SILTY CLAY with organic material (reeds)
2.0
PASS sample
BD2 W SP2
0
0.8 7.5
M2
0
1.2
Minor organic odour
Natural: Firm, grey/blue CLAY with minor silt
3.0
NOTE: This bore log is for environmental purposes only and is not intended to provide geotechnical information.
EOH at 3.0 mBGL target depth
Geological Borelog
Fill: Loose, brown SILTY CLAY with grass and roots
Logged by JF
PROJECT: Fastnet
Proj. Manager JF
pH
D
pH - water
Reading
PID/FID
Moisture Content
Duplicate
Lost
Undisturbed
Disturbed
Depth metres
STRATIGRAPHY
GRAPHIC LOG
SAMPLES
Borehole Log: TP11
pH - soil
JOB NUMBER 210061 DATUM DATE 9 August 2010
Background
LOCATION Salisbury St Lot SURFACE ELEVATION GROUNDWATER NGWE DRILL METHOD TP
Odour
Comments
No odour
Fill: Stiff, brown SILTY CLAY with bluestone and concrete rubble
Becoming loose
D
0
0.8 7.5
1.0
M1
Fill: Soft, dark grey SILTY CLAY with dark staining
W
0 10.2
HC odour
2.0
8.0
Water strike at approx 1.9 mBGL PASS sample Difficult to distinguish lithology at depth due to hole collapse and saturation
Natural: Dense, grey/green CLAY
3.0
EOH at 3.2 mBGL hole collapse
NOTE: This bore log is for environmental purposes only and is not intended to provide geotechnical information.
Geological Borelog Logged by JF
PROJECT: Fastnet
Proj. Manager JF
pH
Fill: Loose, light brown SILTY CLAY with rubbish (plastic, glass) and concrete rubble with steel wire
Shell inclusions
pH - water
Reading
PID/FID
Moisture Content
Duplicate
Lost
Undisturbed
Disturbed
Depth metres
STRATIGRAPHY
GRAPHIC LOG
SAMPLES
Borehole Log: TP12
pH - soil
JOB NUMBER 210061 DATUM DATE 9 August 2010
Background
LOCATION Salisbury St Lot SURFACE ELEVATION GROUNDWATER NGWE DRILL METHOD TP
Odour
Comments
No odour
D
0
0.1 7.5
D
0
0.8
W
0
9.2 8.0
Slight HC odour
BD3 M2 SP3
0
1.2 8.5
No odour
1.0
Fill: Medium dense, brown and orange weathered basaltic CLAY
Fill: Soft, grey and brown SILTY CLAY with weathered basalt floaters and glass and wood inclusions 2.0
Natural: Medium dense, grey CLAY with minor silt
PASS sample
Weathered basalt inclusions 3.0
EOH at 3.1 mBGL target depth
NOTE: This bore log is for environmental purposes only and is not intended to provide geotechnical information.
Geological Borelog Logged by JF
PROJECT: Fastnet
Proj. Manager JF
pH
pH - water
Reading
PID/FID
Moisture Content
Duplicate
Lost
Undisturbed
Disturbed
Depth metres
STRATIGRAPHY
GRAPHIC LOG
SAMPLES
Borehole Log: TP13
pH - soil
JOB NUMBER 210061 DATUM DATE 9 August 2010
Background
LOCATION Salisbury St Lot SURFACE ELEVATION GROUNDWATER NGWE DRILL METHOD TP
Odour
Comments
Fill: Loose, brown CLAYEY SILT with roots No odour throughout Fill: Stiff, brown SILTY CLAY with minor concrete and bluestone rubble D
8.0
Becoming loose
1.0
0
Fill: Soft SILTY CLAY with weathered basalt floaters
Natural: Medium dense, grey/blue CLAY
1.2 8.5
W
2.0
M2
Water strike at approx 1.8 mBGL
0
0.9
EOH at 2.4 mBGL refusal on basalt
3.0
NOTE: This bore log is for environmental purposes only and is not intended to provide geotechnical information.
Geological Borelog Logged by JF
PROJECT: Fastnet
Proj. Manager JF
pH
pH - water
Reading
PID/FID
Moisture Content
Duplicate
Lost
Undisturbed
Disturbed
Depth metres
STRATIGRAPHY
GRAPHIC LOG
SAMPLES
Borehole Log: TP14
pH - soil
JOB NUMBER 210061 DATUM DATE 9 August 2010
Background
LOCATION Salisbury St Lot SURFACE ELEVATION GROUNDWATER NGWE DRILL METHOD TP
Odour
Comments
Fill: Loose, brown SANDY SILT with grass roots D
Fill: Stiff, brown CLAY with weathered basalt floaters and roots
No odour throughout
Garbage (plastic, glass, wood etc) in a loose, brown clay matrix
D
0
0.6 7.5
1.0
M2
Fill: Medium dense, brown/grey CLAY with minor gravel
Water strike at approx 1.8 mBGL
Natural: Medium dense, grey/green/blue CLAY with minor silt
2.0
W
0
1.2 7.5
Weathered basalt inclusions EOH at 2.9 mBGL refusal on basalt 3.0
NOTE: This bore log is for environmental purposes only and is not intended to provide geotechnical information.
APPENDIX D
210061_ReportV2.doc
LABORATORY TRANSCRIPTS AND CHAIN OF CUSTODY FORMS
EM1008731 False
CERTIFICATE OF ANALYSIS :
Page
: 1 of 78
Amendment
EM1008731 :1
Client
: ENVIRONMENTAL EARTH SCIENCES
Laboratory
: Environmental Division Melbourne
Contact
: MR JORDAN FRASER
Contact
: Steven McGrath
Address
: P.O.BOX 2253
Address
: 4 Westall Rd Springvale VIC Australia 3171
Work Order
FOOTSCRAY VIC, AUSTRALIA 3011 E-mail
: jfraser@eesi.biz
: steven.mcgrath@alsenviro.com
Telephone
: +61 03 96871666
Telephone
: +61-3-8549 9600
Facsimile
: +61 03 96871844
Facsimile
: +61-3-8549 9601
Project
: 210061
QC Level
: NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Order number
: ----
C-O-C number
: ----
Date Samples Received
: 11-AUG-2010
Sampler
: JF
Issue Date
: 27-AUG-2010
Site
: YARRAVILLE
Quote number
: EN/010/10
No. of samples received
: 71
No. of samples analysed
: 63
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. All pages of this report have been checked and approved for release. This Certificate of Analysis contains the following information: l General Comments l Analytical Results l Surrogate Control Limits
NATA Accredited Laboratory 825 This document is issued in accordance with NATA accreditation requirements. Accredited for compliance with ISO/IEC 17025.
Signatories This document has been electronically signed by the authorized signatories indicated below. Electronic signing has been carried out in compliance with procedures specified in 21 CFR Part 11. Signatories
Position
Accreditation Category
Emily Yuen Myles.Clark Myles.Clark Nancy Wang Nikki Stepniewski Stephen Hislop Stephen Hislop Xingbin Lin
Senior Organic Instrument Chemist Acid Sulfate Soils Supervisor Acid Sulfate Soils Supervisor Senior Semivolatile Instrument Chemist Non-metallic Supervisor Senior Inorganic Chemist Senior Inorganic Chemist Senior Organic Chemist
Organics Bne Acid Sulphate Soils Inorganics Organics Inorganics Inorganics Stafford Minerals - AY Organics
Environmental Division Melbourne 4 Westall Rd Springvale VIC Australia 3171 Tel. +61-3-8549 9600 Fax. +61-3-8549 9601 www.alsglobal.com
Page Work Order Client Project
: : : :
3 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
General Comments The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, developed procedures are employed in the absence of documented standards or by client request. Where moisture determination has been performed, results are reported on a dry weight basis. Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insuffient sample for analysis. Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference. When date(s) and/or time(s) are shown bracketed, these have been assumed by the laboratory for processing purposes. If the sampling time is displayed as 0:00 the information was not provided by client. Key :
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society. LOR = Limit of reporting ^ = This result is computed from individual analyte detections at or above the level of reporting
l
'Am'
Amosite (brown asbestos)
l
'Ch'
Chrysotile (white asbestos)
l
'Cr'
Crocidolite (blue asbestos)
l
Legend for Asbestos Type:
l
't' Trace levels
l
'UMF' Unknown mineral fibres
l
ANC Fizz Rating: 0- None; 1- Slight; 2- Moderate; 3- Strong; 4- Very Strong.
l
Asbestos analysis was subcontracted to ASET.
l
Asbestos Identification: Samples were analysed by Polarised Light Microscopy including dispersion staining.
l
Confirmation by alternative techniques is recommended for samples where unknown mineral fibres are detected.
l
EG048: EM1008731 #8 matrix spike failed for Total Hexavalent Chromium by Alkaline Digestion due to possible sample matrix interference. This has been confirmed by re-digestion and
l
re-analysis. EP066-EM/075-EM: Particular samples required dilution prior to analysis due to matrix interferences (dark colour). LOR values have been adjusted accordingly.
l
EP071: EM1008731_24 LOR for particular sample raised due to high moisture content.
l
EP071: Poor matrix spike recovery due to high level contaminants present in sample EM1008731-069.
l
EP074-UT: particular sample ( EM-1008731-020) shows poor surrogates recovery due to matrix interferrence. Confirmed by re-analysis.
l
EP074-UT: Particular sample ( EM-1008731-068) shows minor hit of 1,4 dichlorobenzene & 1,2 dichloro benzene. Confirmed by re-analysis.
l
EP074-UT: particular smaple ( EM-1008731-MB,003,008,013,020,031,041,052,061,068), LOR has been raised for DCM due to laboratory background level.
l
EP075(SIM): EM1008731-042 required dilution prior to analysis due to matrix interferences (internal standard responses could not be determined from neat). LOR values have been
l
adjusted accordingly. EP075(SIM): LOR for particular sample EM1008371-024 raised due to high moisture content.
l
EP075(SIM): Sample EM1008731-018 shows poor surrogate recoveries. Confirmed by re-extraction and re-analysis.
l
EP075(SIM): Sample EM1008731-025 shows poor duplicate results due to sample heterogeneity. Confirmed by re-extraction and re-analysis.
l
EP075-EM: Poor recovery for some surrogates due to dilution required to analyse the sample.
l
EP080/075(SIM): Sample EM1008731-040 shows poor surrogate recoveries due to the nature of the sample (charcoal). Confirmed by re-extraction and re-analysis.
l
EP080: Poor surrogate recoveries for sample EM1008783-053 due to high moisture content.
l
Liming rate is calculated and reported on a dry weight basis assuming use of fine agricultural lime (CaCO3) and using a safety factor of 1.5 to allow for non-homogeneous mixing and
l
poor reactivity of lime. For conversion of Liming Rate from 'kg/t dry weight' to 'kg/m3 in-situ soil', multiply 'reported results' x 'wet bulk density of soil in t/m3'. NAGP, Chromium Suite, SPOCAS and CEC conducted by ALS Brisbane, NATA Site No. 818.
l
Retained Acidity not required because pH KCl greater than or equal to 4.5
APHA, AS and NEPM. In house
Page Work Order Client Project
l
: : : :
4 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
This report has been amended as a result of a request to correct sample identification numbers (IDs) received by ALS from Jordan Fraser on 27/08/10. All analysis results are as per the previous report.
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: : : :
5 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP1 (0.4-0.5)
TP1 (1.0-1.1)
TP1 (1.5-1.6)
TP1 (2.0-2.1)
TP2 (0.4-0.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-001
EM1008731-002
EM1008731-003
EM1008731-004
EM1008731-005
1.0
%
20.7
26.7
15.1
22.8
12.5
EA055: Moisture Content ----
^ Moisture Content (dried @ 103째C)
EG005T: Total Metals by ICP-AES Arsenic
7440-38-2
5
mg/kg
----
----
----
7440-43-9
1
mg/kg
----
----
37 <1
----
Cadmium
----
----
Copper
7440-50-8
5
mg/kg
----
----
23
----
----
Lead
7439-92-1
5
mg/kg
----
----
60
----
----
Molybdenum
7439-98-7
2
mg/kg
----
----
<2
----
----
Nickel
7440-02-0
2
mg/kg
----
----
39
----
----
Selenium
7782-49-2
5
mg/kg
----
----
<5
----
----
Silver
7440-22-4
2
mg/kg
----
----
<2
----
----
Tin
7440-31-5
5
mg/kg
----
----
<5
----
----
Zinc
7440-66-6
5
mg/kg
----
----
133
----
----
Arsenic
7440-38-2
5
mg/kg
113
<5
----
30
Cadmium
7440-43-9
1
mg/kg
2
<1
----
<1
42 <1
Chromium
7440-47-3
2
mg/kg
59
31
----
28
29
Copper
7440-50-8
5
mg/kg
265
7
----
15
728
Lead
7439-92-1
5
mg/kg
191
14
----
32
155
Nickel
7440-02-0
2
mg/kg
76
17
----
27
141
Zinc
7440-66-6
5
mg/kg
496
52
----
93
127
7439-97-6
0.1
mg/kg
0.5
<0.1
0.1
<0.1
0.1
0.5
mg/kg
----
----
<0.5
----
----
57-12-5
1
mg/kg
----
----
<1
----
----
16984-48-8
40
mg/kg
----
----
80
----
----
----
0.10
mg/kg
----
----
<5.00
----
----
Benzene
71-43-2
0.2
mg/kg
----
----
<0.2
----
----
Toluene
108-88-3
0.5
mg/kg
----
----
<0.5
----
----
Ethylbenzene
100-41-4
0.5
mg/kg
----
----
<0.5
----
----
108-38-3 106-42-3
0.5
mg/kg
----
----
<0.5
----
----
100-42-5
0.5
mg/kg
----
----
<0.5
----
----
95-47-6
0.5
mg/kg
----
----
<0.5
----
----
EG035T: Total Recoverable Mercury by FIMS Mercury
EG048: Hexavalent Chromium (Alkaline Digest) Hexavalent Chromium
18540-29-9
EK026G: Total Cyanide By Discrete Analyser Total Cyanide
EK040T: Fluoride Total Fluoride
EP066: Polychlorinated Biphenyls (PCB) Total Polychlorinated biphenyls
EP074A: Monocyclic Aromatic Hydrocarbons
meta- & para-Xylene Styrene ortho-Xylene
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6 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP1 (0.4-0.5)
TP1 (1.0-1.1)
TP1 (1.5-1.6)
TP1 (2.0-2.1)
TP2 (0.4-0.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-001
EM1008731-002
EM1008731-003
EM1008731-004
EM1008731-005
----
0.2
mg/kg
----
----
<0.2
----
----
----
0.2
mg/kg
----
----
<0.2
----
----
Vinyl chloride
75-01-4
0.02
mg/kg
----
----
<0.02
----
----
1.1-Dichloroethene
75-35-4
0.01
mg/kg
----
----
<0.01
----
----
Methylene chloride
75-09-2
0.4
mg/kg
----
----
<0.6
----
----
trans-1.2-Dichloroethene
156-60-5
0.02
mg/kg
----
----
<0.02
----
----
cis-1.2-Dichloroethene
156-59-2
0.01
mg/kg
----
----
<0.01
----
----
Chloroform
67-66-3
0.02
mg/kg
----
----
<0.02
----
----
1.1.1-Trichloroethane
71-55-6
0.01
mg/kg
----
----
<0.01
----
----
Carbon Tetrachloride
56-23-5
0.01
mg/kg
----
----
<0.01
----
----
107-06-2
0.02
mg/kg
----
----
<0.02
----
----
Trichloroethene
79-01-6
0.02
mg/kg
----
----
<0.02
----
----
1.1.2-Trichloroethane
79-00-5
0.04
mg/kg
----
----
<0.04
----
----
Tetrachloroethene
127-18-4
0.02
mg/kg
----
----
<0.02
----
----
1.1.1.2-Tetrachloroethane
630-20-6
0.01
mg/kg
----
----
<0.01
----
----
1.1.2.2-Tetrachloroethane
79-34-5
0.02
mg/kg
----
----
<0.02
----
----
Hexachlorobutadiene
87-68-3
0.02
mg/kg
----
----
<0.02
----
----
Chlorobenzene
108-90-7
0.02
mg/kg
----
----
<0.02
----
----
1.4-Dichlorobenzene
106-46-7
0.02
mg/kg
----
----
<0.02
----
----
1.2-Dichlorobenzene
95-50-1
0.02
mg/kg
----
----
<0.02
----
----
120-82-1
0.01
mg/kg
----
----
<0.01
----
----
----
0.01
mg/kg
----
----
<0.01
----
----
----
0.01
mg/kg
----
----
<0.01
----
----
----
0.01
mg/kg
----
----
<0.01
----
----
----
0.01
mg/kg
----
----
<0.01
----
----
1330-20-7
0.50
mg/kg
----
----
<0.50
----
----
Compound
CAS Number
EP074A: Monocyclic Aromatic Hydrocarbons - Continued ^ Sum of monocyclic aromatic hydrocarbons ^ Sum of monocyclic aromatic hydrocarbons
EP074I: Volatile Halogenated Compounds
1.2-Dichloroethane
1.2.4-Trichlorobenzene ^ Sum of volatile chlorinated hydrocarbons ^ Sum of other chlorinated hydrocarbons (VIC EPA 448.3) ^ Sum of volatile chlorinated hydrocarbons ^ Sum of other chlorinated hydrocarbons (VIC EPA 448.3) ^ Total Xylenes
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons 91-20-3
0.5
mg/kg
----
<0.5
----
----
----
208-96-8
0.5
mg/kg
----
<0.5
----
----
----
Acenaphthene
83-32-9
0.5
mg/kg
----
<0.5
----
----
----
Fluorene
86-73-7
0.5
mg/kg
----
<0.5
----
----
----
Naphthalene Acenaphthylene
Page Work Order Client Project
: : : :
7 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
TP1 (0.4-0.5)
TP1 (1.0-1.1)
TP1 (1.5-1.6)
TP1 (2.0-2.1)
TP2 (0.4-0.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
Unit
EM1008731-001
EM1008731-002
EM1008731-003
EM1008731-004
EM1008731-005
Client sampling date / time Compound
CAS Number
LOR
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons - Continued 85-01-8
0.5
mg/kg
----
<0.5
----
----
----
Anthracene
120-12-7
0.5
mg/kg
----
<0.5
----
----
----
Fluoranthene
206-44-0
0.5
mg/kg
----
<0.5
----
----
----
Pyrene
129-00-0
0.5
mg/kg
----
<0.5
----
----
----
56-55-3
0.5
mg/kg
----
<0.5
----
----
----
Chrysene
218-01-9
0.5
mg/kg
----
<0.5
----
----
----
Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
----
<0.5
----
----
----
Benzo(k)fluoranthene
207-08-9
0.5
mg/kg
----
<0.5
----
----
----
50-32-8
0.5
mg/kg
----
<0.5
----
----
----
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
----
<0.5
----
----
----
Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
----
<0.5
----
----
----
191-24-2
0.5
mg/kg
----
<0.5
----
----
----
Phenanthrene
Benz(a)anthracene
Benzo(a)pyrene
Benzo(g.h.i)perylene
EP075A: Phenolic Compounds (Halogenated) 95-57-8
0.03
mg/kg
----
----
<0.61
----
----
2.4-Dichlorophenol
120-83-2
0.03
mg/kg
----
----
<0.61
----
----
2.6-Dichlorophenol
87-65-0
0.03
mg/kg
----
----
<0.61
----
----
4-Chloro-3-Methylphenol
59-50-7
0.03
mg/kg
----
----
<0.61
----
----
2.4.5-Trichlorophenol
95-95-4
0.05
mg/kg
----
----
<0.61
----
----
2.4.6-Trichlorophenol
88-06-2
0.05
mg/kg
----
----
<0.61
----
----
935-95-5
0.03
mg/kg
----
----
<0.61
----
----
4901-51-3/58-90-2
0.05
mg/kg
----
----
<1.22
----
----
87-86-5
0.2
mg/kg
----
----
<0.6
----
----
----
0.03
mg/kg
----
----
<0.61
----
----
108-95-2
1
mg/kg
----
----
<1
----
----
95-48-7
1
mg/kg
----
----
<1
----
----
1319-77-3
1
mg/kg
----
----
<1
----
----
88-75-5
1
mg/kg
----
----
<1
----
----
105-67-9
1
mg/kg
----
----
<1
----
----
51-28-5
5
mg/kg
----
----
<49
----
----
100-02-7
5
mg/kg
----
----
<49
----
----
8071-51-0
5
mg/kg
----
----
<49
----
----
88-85-7
5
mg/kg
----
----
<49
----
----
131-89-5
5
mg/kg
----
----
<49
----
----
----
1
mg/kg
----
----
<1
----
----
0.5
mg/kg
----
----
0.8
----
----
2-Chlorophenol
2.3.5.6-Tetrachlorophenol 2.3.4.5 & 2.3.4.6-Tetrachlorophenol Pentachlorophenol ^ Sum of Phenols (halogenated)
EP075A: Phenolic Compounds (Non-halogenated) Phenol 2-Methylphenol 3- & 4-Methylphenol 2-Nitrophenol 2.4-Dimethylphenol 2.4-Dinitrophenol 4-Nitrophenol 2-Methyl-4.6-dinitrophenol Dinoseb 2-Cyclohexyl-4.6-Dinitrophenol ^ Sum of Phenols (non-halogenated)
EP075B: Polynuclear Aromatic Hydrocarbons Naphthalene
91-20-3
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: : : :
8 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP1 (0.4-0.5)
TP1 (1.0-1.1)
TP1 (1.5-1.6)
TP1 (2.0-2.1)
TP2 (0.4-0.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-001
EM1008731-002
EM1008731-003
EM1008731-004
EM1008731-005
EP075B: Polynuclear Aromatic Hydrocarbons - Continued 83-32-9
0.5
mg/kg
----
----
<0.6
----
----
208-96-8
0.5
mg/kg
----
----
3.1
----
----
Fluorene
86-73-7
0.5
mg/kg
----
----
<0.6
----
----
Phenanthrene
85-01-8
0.5
mg/kg
----
----
12.2
----
----
Anthracene
120-12-7
0.5
mg/kg
----
----
4.4
----
----
Fluoranthene
206-44-0
0.5
mg/kg
----
----
38.2
----
----
Pyrene
129-00-0
0.5
mg/kg
----
----
37.2
----
----
56-55-3
0.5
mg/kg
----
----
18.1
----
----
218-01-9
0.5
mg/kg
----
----
15.0
----
----
205-99-2 207-08-9
0.5
mg/kg
----
----
30.3
----
----
Acenaphthene Acenaphthylene
Benz(a)anthracene Chrysene Benzo(b) & Benzo(k)fluoranthene Benzo(a)pyrene
50-32-8
0.5
mg/kg
----
----
20.0
----
----
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
----
----
12.2
----
----
Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
----
----
3.5
----
----
191-24-2
0.5
mg/kg
----
----
15.5
----
----
----
0.5
mg/kg
----
----
210
----
----
alpha-BHC
319-84-6
0.03
mg/kg
----
----
<0.61
----
----
Hexachlorobenzene (HCB)
118-74-1
0.03
mg/kg
----
----
<0.61
----
----
beta-BHC
319-85-7
0.03
mg/kg
----
----
<0.61
----
----
58-89-9
0.03
mg/kg
----
----
<0.61
----
----
delta-BHC
319-86-8
0.03
mg/kg
----
----
<0.61
----
----
Heptachlor
76-44-8
0.03
mg/kg
----
----
<0.61
----
----
309-00-2
0.03
mg/kg
----
----
<0.61
----
----
Heptachlor epoxide
1024-57-3
0.03
mg/kg
----
----
<0.61
----
----
cis-Chlordane
5103-71-9
0.03
mg/kg
----
----
<0.61
----
----
trans-Chlordane
5103-74-2
0.03
mg/kg
----
----
<0.61
----
----
959-98-8
0.03
mg/kg
----
----
<0.61
----
----
4.4`-DDE
72-55-9
0.05
mg/kg
----
----
<0.61
----
----
Dieldrin
60-57-1
0.03
mg/kg
----
----
<0.61
----
----
7421-93-4
0.03
mg/kg
----
----
<0.61
----
----
72-20-8
0.03
mg/kg
----
----
<0.61
----
----
33213-65-9
0.03
mg/kg
----
----
<0.61
----
----
72-54-8
0.05
mg/kg
----
----
<0.61
----
----
1031-07-8
0.03
mg/kg
----
----
<0.61
----
----
4.4`-DDT
50-29-3
0.05
mg/kg
----
----
<0.61
----
----
Methoxychlor
72-43-5
0.03
mg/kg
----
----
<0.61
----
----
Benzo(g.h.i)perylene ^ Sum of polycyclic aromatic hydrocarbons
EP075I: Organochlorine Pesticides
gamma-BHC
Aldrin
Endosulfan 1
Endrin aldehyde Endrin Endosulfan 2 4.4`-DDD Endosulfan sulfate
Page Work Order Client Project
: : : :
9 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP1 (0.4-0.5)
TP1 (1.0-1.1)
TP1 (1.5-1.6)
TP1 (2.0-2.1)
TP2 (0.4-0.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-001
EM1008731-002
EM1008731-003
EM1008731-004
EM1008731-005
EP075I: Organochlorine Pesticides - Continued ----
0.03
mg/kg
----
----
<0.61
----
----
309-00-2/60-57-1
0.03
mg/kg
----
----
<0.61
----
----
----
0.05
mg/kg
----
----
<0.61
----
----
57-74-9
0.03
mg/kg
----
----
<0.61
----
----
----
0.03
mg/kg
----
----
<0.61
----
----
C6 - C9 Fraction
----
10
mg/kg
----
----
<10
----
----
C6 - C9 Fraction
----
10
mg/kg
----
<10
----
----
----
C10 - C14 Fraction
----
50
mg/kg
----
<50
<50
----
----
C15 - C28 Fraction
----
100
mg/kg
----
<100
330
----
----
C29 - C36 Fraction
----
100
mg/kg
----
<100
460
----
----
^ C10 - C36 Fraction (sum)
----
50
mg/kg
----
<50
790
----
----
Benzene
71-43-2
0.2
mg/kg
----
<0.2
----
----
----
Toluene
108-88-3
0.5
mg/kg
----
<0.5
----
----
----
Ethylbenzene
100-41-4
0.5
mg/kg
----
<0.5
----
----
----
108-38-3 106-42-3
0.5
mg/kg
----
<0.5
----
----
----
95-47-6
0.5
mg/kg
----
<0.5
----
----
----
2051-24-3
0.1
%
----
----
55.8
----
----
17060-07-0
0.1
%
----
----
100
----
----
2037-26-5
0.1
%
----
----
90.4
----
----
460-00-4
0.1
%
----
----
95.5
----
----
Phenol-d6
13127-88-3
0.1
%
----
67.6
----
----
----
2-Chlorophenol-D4
93951-73-6
0.1
%
----
103
----
----
----
118-79-6
0.1
%
----
104
----
----
----
2-Fluorobiphenyl
321-60-8
0.1
%
----
95.9
----
----
----
Anthracene-d10
1719-06-8
0.1
%
----
93.1
----
----
----
4-Terphenyl-d14
1718-51-0
0.1
%
----
108
----
----
----
^ Sum of organochlorine pesticides ^ Sum of Aldrin + Dieldrin ^ Sum of DDD + DDE + DDT ^ Chlordane ^ Sum of other organochlorine pesticides
EP080/071: Total Petroleum Hydrocarbons
EP080: BTEX
meta- & para-Xylene ortho-Xylene
EP066S: PCB Surrogate Decachlorobiphenyl
EP074S: VOC Surrogates 1.2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene
EP075(SIM)S: Phenolic Compound Surrogates
2.4.6-Tribromophenol
EP075(SIM)T: PAH Surrogates
EP075S: Acid Extractable Surrogates 367-12-4
0.1
%
----
----
Not Determined
----
----
Phenol-d6
13127-88-3
0.1
%
----
----
Not Determined
----
----
2-Chlorophenol-D4
93951-73-6
0.1
%
----
----
Not Determined
----
----
2-Fluorophenol
Page Work Order Client Project
: : : :
10 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP1 (0.4-0.5)
TP1 (1.0-1.1)
TP1 (1.5-1.6)
TP1 (2.0-2.1)
TP2 (0.4-0.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-001
EM1008731-002
EM1008731-003
EM1008731-004
EM1008731-005
118-79-6
0.1
%
----
----
Not Determined
----
----
Nitrobenzene-D5
4165-60-0
0.1
%
----
----
Not Determined
----
----
1.2-Dichlorobenzene-D4
2199-69-1
0.1
%
----
----
Not Determined
----
----
2-Fluorobiphenyl
321-60-8
0.1
%
----
----
Not Determined
----
----
Anthracene-d10
1719-06-8
0.1
%
----
----
Not Determined
----
----
4-Terphenyl-d14
1718-51-0
0.1
%
----
----
Not Determined
----
----
17060-07-0
0.1
%
----
82.6
----
----
----
2037-26-5
0.1
%
----
97.2
----
----
----
460-00-4
0.1
%
----
105
----
----
----
Compound
CAS Number
EP075S: Acid Extractable Surrogates - Continued 2.4.6-Tribromophenol
EP075T: Base/Neutral Extractable Surrogates
EP080S: TPH(V)/BTEX Surrogates 1.2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene
Page Work Order Client Project
: : : :
11 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP2 (1.4-1.5)
TP2 (1.9-2.0)
TP2 (3.2-3.3)
TP3 (0-0.1)
TP3 (0.4-0.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-007
EM1008731-008
EM1008731-010
EM1008731-011
EM1008731-012
1.0
%
28.6
28.4
47.8
18.5
19.2
EA055: Moisture Content ----
^ Moisture Content (dried @ 103째C)
EG005T: Total Metals by ICP-AES Arsenic
7440-38-2
5
mg/kg
----
----
----
7440-43-9
1
mg/kg
----
24 <1
----
Cadmium
----
----
----
Copper
7440-50-8
5
mg/kg
----
106
----
----
----
Lead
7439-92-1
5
mg/kg
----
87
----
----
----
Molybdenum
7439-98-7
2
mg/kg
----
<2
----
----
----
Nickel
7440-02-0
2
mg/kg
----
41
----
----
----
Selenium
7782-49-2
5
mg/kg
----
<5
----
----
----
Silver
7440-22-4
2
mg/kg
----
<2
----
----
----
Tin
7440-31-5
5
mg/kg
----
202
----
----
----
Zinc
7440-66-6
5
mg/kg
----
414
----
----
----
Arsenic
7440-38-2
5
mg/kg
73
----
590
5
53
Cadmium
7440-43-9
1
mg/kg
1
----
16
<1
2
Chromium
7440-47-3
2
mg/kg
47
----
126
20
92
Copper
7440-50-8
5
mg/kg
115
----
358
26
463
Lead
7439-92-1
5
mg/kg
108
----
485
21
731
Nickel
7440-02-0
2
mg/kg
41
----
122
13
76
Zinc
7440-66-6
5
mg/kg
413
----
3960
50
810
7439-97-6
0.1
mg/kg
0.2
0.3
1.0
<0.1
0.7
0.5
mg/kg
----
<0.5
----
----
----
57-12-5
1
mg/kg
----
1
----
----
----
16984-48-8
40
mg/kg
----
180
----
----
----
----
0.10
mg/kg
----
<0.50
----
----
----
Benzene
71-43-2
0.2
mg/kg
----
<0.2
----
----
----
Toluene
108-88-3
0.5
mg/kg
----
<0.5
----
----
----
Ethylbenzene
100-41-4
0.5
mg/kg
----
<0.5
----
----
----
108-38-3 106-42-3
0.5
mg/kg
----
<0.5
----
----
----
100-42-5
0.5
mg/kg
----
<0.5
----
----
----
95-47-6
0.5
mg/kg
----
<0.5
----
----
----
EG035T: Total Recoverable Mercury by FIMS Mercury
EG048: Hexavalent Chromium (Alkaline Digest) Hexavalent Chromium
18540-29-9
EK026G: Total Cyanide By Discrete Analyser Total Cyanide
EK040T: Fluoride Total Fluoride
EP066: Polychlorinated Biphenyls (PCB) Total Polychlorinated biphenyls
EP074A: Monocyclic Aromatic Hydrocarbons
meta- & para-Xylene Styrene ortho-Xylene
Page Work Order Client Project
: : : :
12 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP2 (1.4-1.5)
TP2 (1.9-2.0)
TP2 (3.2-3.3)
TP3 (0-0.1)
TP3 (0.4-0.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-007
EM1008731-008
EM1008731-010
EM1008731-011
EM1008731-012
----
0.2
mg/kg
----
<0.2
----
----
----
----
0.2
mg/kg
----
<0.2
----
----
----
Vinyl chloride
75-01-4
0.02
mg/kg
----
<0.02
----
----
----
1.1-Dichloroethene
75-35-4
0.01
mg/kg
----
<0.01
----
----
----
Methylene chloride
75-09-2
0.4
mg/kg
----
<0.6
----
----
----
trans-1.2-Dichloroethene
156-60-5
0.02
mg/kg
----
<0.02
----
----
----
cis-1.2-Dichloroethene
156-59-2
0.01
mg/kg
----
<0.01
----
----
----
Chloroform
67-66-3
0.02
mg/kg
----
<0.02
----
----
----
1.1.1-Trichloroethane
71-55-6
0.01
mg/kg
----
<0.01
----
----
----
Carbon Tetrachloride
56-23-5
0.01
mg/kg
----
<0.01
----
----
----
107-06-2
0.02
mg/kg
----
<0.02
----
----
----
Trichloroethene
79-01-6
0.02
mg/kg
----
<0.02
----
----
----
1.1.2-Trichloroethane
79-00-5
0.04
mg/kg
----
<0.04
----
----
----
Tetrachloroethene
127-18-4
0.02
mg/kg
----
<0.02
----
----
----
1.1.1.2-Tetrachloroethane
630-20-6
0.01
mg/kg
----
<0.01
----
----
----
1.1.2.2-Tetrachloroethane
79-34-5
0.02
mg/kg
----
<0.02
----
----
----
Hexachlorobutadiene
87-68-3
0.02
mg/kg
----
<0.02
----
----
----
Chlorobenzene
108-90-7
0.02
mg/kg
----
<0.02
----
----
----
1.4-Dichlorobenzene
106-46-7
0.02
mg/kg
----
<0.02
----
----
----
1.2-Dichlorobenzene
95-50-1
0.02
mg/kg
----
<0.02
----
----
----
120-82-1
0.01
mg/kg
----
<0.01
----
----
----
----
0.01
mg/kg
----
<0.01
----
----
----
----
0.01
mg/kg
----
<0.01
----
----
----
----
0.01
mg/kg
----
<0.01
----
----
----
----
0.01
mg/kg
----
<0.01
----
----
----
1330-20-7
0.50
mg/kg
----
<0.50
----
----
----
Compound
CAS Number
EP074A: Monocyclic Aromatic Hydrocarbons - Continued ^ Sum of monocyclic aromatic hydrocarbons ^ Sum of monocyclic aromatic hydrocarbons
EP074I: Volatile Halogenated Compounds
1.2-Dichloroethane
1.2.4-Trichlorobenzene ^ Sum of volatile chlorinated hydrocarbons ^ Sum of other chlorinated hydrocarbons (VIC EPA 448.3) ^ Sum of volatile chlorinated hydrocarbons ^ Sum of other chlorinated hydrocarbons (VIC EPA 448.3) ^ Total Xylenes
EP075(SIM)A: Phenolic Compounds 108-95-2
0.5
mg/kg
<0.5
----
----
----
----
2-Chlorophenol
95-57-8
0.5
mg/kg
<0.5
----
----
----
----
2-Methylphenol
95-48-7
0.5
mg/kg
<0.5
----
----
----
----
1319-77-3
1.0
mg/kg
<1.0
----
----
----
----
Phenol
3- & 4-Methylphenol
Page Work Order Client Project
: : : :
13 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP2 (1.4-1.5)
TP2 (1.9-2.0)
TP2 (3.2-3.3)
TP3 (0-0.1)
TP3 (0.4-0.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-007
EM1008731-008
EM1008731-010
EM1008731-011
EM1008731-012
EP075(SIM)A: Phenolic Compounds - Continued 88-75-5
0.5
mg/kg
<0.5
----
----
----
----
2.4-Dimethylphenol
105-67-9
0.5
mg/kg
<0.5
----
----
----
----
2.4-Dichlorophenol
120-83-2
0.5
mg/kg
<0.5
----
----
----
----
2.6-Dichlorophenol
87-65-0
0.5
mg/kg
<0.5
----
----
----
----
4-Chloro-3-Methylphenol
59-50-7
0.5
mg/kg
<0.5
----
----
----
----
2.4.6-Trichlorophenol
88-06-2
0.5
mg/kg
<0.5
----
----
----
----
2.4.5-Trichlorophenol
95-95-4
0.5
mg/kg
<0.5
----
----
----
----
Pentachlorophenol
87-86-5
2.0
mg/kg
<2.0
----
----
----
----
2-Nitrophenol
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons 91-20-3
0.5
mg/kg
<0.5
----
<0.5
----
----
208-96-8
0.5
mg/kg
----
----
<0.5
----
----
83-32-9
0.5
mg/kg
----
----
<0.5
----
----
208-96-8
0.5
mg/kg
<0.5
----
----
----
----
Acenaphthene
83-32-9
0.5
mg/kg
<0.5
----
----
----
----
Fluorene
86-73-7
0.5
mg/kg
----
----
<0.5
----
----
Fluorene
86-73-7
0.5
mg/kg
<0.5
----
----
----
----
Phenanthrene
85-01-8
0.5
mg/kg
----
----
<0.5
----
----
120-12-7
0.5
mg/kg
----
----
<0.5
----
----
85-01-8
0.5
mg/kg
<0.5
----
----
----
----
Anthracene
120-12-7
0.5
mg/kg
<0.5
----
----
----
----
Fluoranthene
206-44-0
0.5
mg/kg
----
----
0.9
----
----
Fluoranthene
206-44-0
0.5
mg/kg
<0.5
----
----
----
----
Pyrene
129-00-0
0.5
mg/kg
----
----
1.2
----
----
56-55-3
0.5
mg/kg
----
----
<0.5
----
----
129-00-0
0.5
mg/kg
0.6
----
----
----
----
56-55-3
0.5
mg/kg
<0.5
----
----
----
----
Chrysene
218-01-9
0.5
mg/kg
----
----
<0.5
----
----
Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
----
----
0.7
----
----
Chrysene
218-01-9
0.5
mg/kg
<0.5
----
----
----
----
Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
<0.5
----
----
----
----
Benzo(k)fluoranthene
207-08-9
0.5
mg/kg
----
----
<0.5
----
----
50-32-8
0.5
mg/kg
----
----
<0.5
----
----
207-08-9
0.5
mg/kg
<0.5
----
----
----
----
50-32-8
0.5
mg/kg
<0.5
----
----
----
----
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
----
----
<0.5
----
----
Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
----
----
<0.5
----
----
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
<0.5
----
----
----
----
Benzo(g.h.i)perylene
191-24-2
0.5
mg/kg
----
----
<0.5
----
----
Naphthalene Acenaphthylene Acenaphthene Acenaphthylene
Anthracene Phenanthrene
Benz(a)anthracene Pyrene Benz(a)anthracene
Benzo(a)pyrene Benzo(k)fluoranthene Benzo(a)pyrene
Page Work Order Client Project
: : : :
14 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
TP2 (1.4-1.5)
TP2 (1.9-2.0)
TP2 (3.2-3.3)
TP3 (0-0.1)
TP3 (0.4-0.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
Unit
EM1008731-007
EM1008731-008
EM1008731-010
EM1008731-011
EM1008731-012
Client sampling date / time Compound
CAS Number
LOR
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons - Continued Dibenz(a.h)anthracene Benzo(g.h.i)perylene
53-70-3
0.5
mg/kg
<0.5
----
----
----
----
191-24-2
0.5
mg/kg
<0.5
----
----
----
----
EP075A: Phenolic Compounds (Halogenated) 95-57-8
0.03
mg/kg
----
<0.06
----
----
----
2.4-Dichlorophenol
120-83-2
0.03
mg/kg
----
<0.06
----
----
----
2.6-Dichlorophenol
87-65-0
0.03
mg/kg
----
<0.06
----
----
----
4-Chloro-3-Methylphenol
59-50-7
0.03
mg/kg
----
<0.06
----
----
----
2.4.5-Trichlorophenol
95-95-4
0.05
mg/kg
----
<0.06
----
----
----
2.4.6-Trichlorophenol
88-06-2
0.05
mg/kg
----
<0.06
----
----
----
935-95-5
0.03
mg/kg
----
<0.06
----
----
----
4901-51-3/58-90-2
0.05
mg/kg
----
<0.12
----
----
----
87-86-5
0.2
mg/kg
----
<0.2
----
----
----
----
0.03
mg/kg
----
<0.06
----
----
----
108-95-2
1
mg/kg
----
<1
----
----
----
95-48-7
1
mg/kg
----
<1
----
----
----
1319-77-3
1
mg/kg
----
<1
----
----
----
88-75-5
1
mg/kg
----
<1
----
----
----
105-67-9
1
mg/kg
----
<1
----
----
----
51-28-5
5
mg/kg
----
<5
----
----
----
100-02-7
5
mg/kg
----
<5
----
----
----
8071-51-0
5
mg/kg
----
<5
----
----
----
88-85-7
5
mg/kg
----
<5
----
----
----
131-89-5
5
mg/kg
----
<5
----
----
----
----
1
mg/kg
----
<1
----
----
----
2-Chlorophenol
2.3.5.6-Tetrachlorophenol 2.3.4.5 & 2.3.4.6-Tetrachlorophenol Pentachlorophenol ^ Sum of Phenols (halogenated)
EP075A: Phenolic Compounds (Non-halogenated) Phenol 2-Methylphenol 3- & 4-Methylphenol 2-Nitrophenol 2.4-Dimethylphenol 2.4-Dinitrophenol 4-Nitrophenol 2-Methyl-4.6-dinitrophenol Dinoseb 2-Cyclohexyl-4.6-Dinitrophenol ^ Sum of Phenols (non-halogenated)
EP075B: Polynuclear Aromatic Hydrocarbons Naphthalene
91-20-3
0.5
mg/kg
----
<0.5
----
----
----
Acenaphthene
83-32-9
0.5
mg/kg
----
<0.5
----
----
----
208-96-8
0.5
mg/kg
----
<0.5
----
----
----
Fluorene
86-73-7
0.5
mg/kg
----
<0.5
----
----
----
Phenanthrene
85-01-8
0.5
mg/kg
----
<0.5
----
----
----
Anthracene
120-12-7
0.5
mg/kg
----
<0.5
----
----
----
Fluoranthene
206-44-0
0.5
mg/kg
----
<0.5
----
----
----
Pyrene
129-00-0
0.5
mg/kg
----
<0.5
----
----
----
56-55-3
0.5
mg/kg
----
<0.5
----
----
----
218-01-9
0.5
mg/kg
----
<0.5
----
----
----
Acenaphthylene
Benz(a)anthracene Chrysene
Page Work Order Client Project
: : : :
15 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP2 (1.4-1.5)
TP2 (1.9-2.0)
TP2 (3.2-3.3)
TP3 (0-0.1)
TP3 (0.4-0.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-007
EM1008731-008
EM1008731-010
EM1008731-011
EM1008731-012
205-99-2 207-08-9
0.5
mg/kg
----
<0.5
----
----
----
Compound
CAS Number
EP075B: Polynuclear Aromatic Hydrocarbons - Continued Benzo(b) & Benzo(k)fluoranthene Benzo(a)pyrene
50-32-8
0.5
mg/kg
----
<0.5
----
----
----
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
----
<0.5
----
----
----
Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
----
<0.5
----
----
----
191-24-2
0.5
mg/kg
----
<0.5
----
----
----
----
0.5
mg/kg
----
<0.5
----
----
----
alpha-BHC
319-84-6
0.03
mg/kg
----
<0.06
----
----
----
Hexachlorobenzene (HCB)
118-74-1
0.03
mg/kg
----
<0.06
----
----
----
beta-BHC
319-85-7
0.03
mg/kg
----
<0.06
----
----
----
58-89-9
0.03
mg/kg
----
<0.06
----
----
----
delta-BHC
319-86-8
0.03
mg/kg
----
<0.06
----
----
----
Heptachlor
76-44-8
0.03
mg/kg
----
<0.06
----
----
----
309-00-2
0.03
mg/kg
----
<0.06
----
----
----
Heptachlor epoxide
1024-57-3
0.03
mg/kg
----
<0.06
----
----
----
cis-Chlordane
5103-71-9
0.03
mg/kg
----
<0.06
----
----
----
trans-Chlordane
5103-74-2
0.03
mg/kg
----
<0.06
----
----
----
959-98-8
0.03
mg/kg
----
<0.06
----
----
----
4.4`-DDE
72-55-9
0.05
mg/kg
----
<0.06
----
----
----
Dieldrin
60-57-1
0.03
mg/kg
----
<0.06
----
----
----
7421-93-4
0.03
mg/kg
----
<0.06
----
----
----
72-20-8
0.03
mg/kg
----
<0.06
----
----
----
33213-65-9
0.03
mg/kg
----
<0.06
----
----
----
72-54-8
0.05
mg/kg
----
<0.06
----
----
----
1031-07-8
0.03
mg/kg
----
<0.06
----
----
----
4.4`-DDT
50-29-3
0.05
mg/kg
----
<0.06
----
----
----
Methoxychlor
72-43-5
0.03
mg/kg
----
<0.06
----
----
----
----
0.03
mg/kg
----
<0.06
----
----
----
309-00-2/60-57-1
0.03
mg/kg
----
<0.06
----
----
----
----
0.05
mg/kg
----
<0.06
----
----
----
57-74-9
0.03
mg/kg
----
<0.06
----
----
----
----
0.03
mg/kg
----
<0.06
----
----
----
C6 - C9 Fraction
----
10
mg/kg
----
<10
----
----
----
C6 - C9 Fraction
----
10
mg/kg
<10
----
<10
----
----
Benzo(g.h.i)perylene ^ Sum of polycyclic aromatic hydrocarbons
EP075I: Organochlorine Pesticides
gamma-BHC
Aldrin
Endosulfan 1
Endrin aldehyde Endrin Endosulfan 2 4.4`-DDD Endosulfan sulfate
^ Sum of organochlorine pesticides ^ Sum of Aldrin + Dieldrin ^ Sum of DDD + DDE + DDT ^ Chlordane ^ Sum of other organochlorine pesticides
EP080/071: Total Petroleum Hydrocarbons
Page Work Order Client Project
: : : :
16 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP2 (1.4-1.5)
TP2 (1.9-2.0)
TP2 (3.2-3.3)
TP3 (0-0.1)
TP3 (0.4-0.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
EM1008731-008
EM1008731-010
EM1008731-011
EM1008731-012
LOR
Unit
EM1008731-007
EP080/071: Total Petroleum Hydrocarbons - Continued C10 - C14 Fraction
----
50
mg/kg
<50
<50
<50
----
----
C15 - C28 Fraction
----
100
mg/kg
250
<100
590
----
----
C29 - C36 Fraction
----
100
mg/kg
390
<100
630
----
----
^ C10 - C36 Fraction (sum)
----
50
mg/kg
640
<50
1220
----
----
Benzene
71-43-2
0.2
mg/kg
<0.2
----
<0.2
----
----
Toluene
108-88-3
0.5
mg/kg
<0.5
----
<0.5
----
----
Ethylbenzene
100-41-4
0.5
mg/kg
<0.5
----
<0.5
----
----
108-38-3 106-42-3
0.5
mg/kg
<0.5
----
<0.5
----
----
95-47-6
0.5
mg/kg
<0.5
----
<0.5
----
----
2051-24-3
0.1
%
----
80.1
----
----
----
17060-07-0
0.1
%
----
127
----
----
----
2037-26-5
0.1
%
----
112
----
----
----
460-00-4
0.1
%
----
118
----
----
----
Phenol-d6
13127-88-3
0.1
%
67.6
----
65.3
----
----
2-Chlorophenol-D4
93951-73-6
0.1
%
106
----
103
----
----
118-79-6
0.1
%
116
----
88.6
----
----
2-Fluorobiphenyl
321-60-8
0.1
%
89.8
----
91.6
----
----
Anthracene-d10
1719-06-8
0.1
%
96.9
----
99.2
----
----
4-Terphenyl-d14
1718-51-0
0.1
%
109
----
107
----
----
EP080: BTEX
meta- & para-Xylene ortho-Xylene
EP066S: PCB Surrogate Decachlorobiphenyl
EP074S: VOC Surrogates 1.2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene
EP075(SIM)S: Phenolic Compound Surrogates
2.4.6-Tribromophenol
EP075(SIM)T: PAH Surrogates
EP075S: Acid Extractable Surrogates 367-12-4
0.1
%
----
72.2
----
----
----
Phenol-d6
13127-88-3
0.1
%
----
71.2
----
----
----
2-Chlorophenol-D4
93951-73-6
0.1
%
----
75.1
----
----
----
118-79-6
0.1
%
----
58.4
----
----
----
Nitrobenzene-D5
4165-60-0
0.1
%
----
80.0
----
----
----
1.2-Dichlorobenzene-D4
2199-69-1
0.1
%
----
79.5
----
----
----
2-Fluorobiphenyl
321-60-8
0.1
%
----
78.4
----
----
----
Anthracene-d10
1719-06-8
0.1
%
----
101
----
----
----
4-Terphenyl-d14
1718-51-0
0.1
%
----
85.3
----
----
----
17060-07-0
0.1
%
103
----
101
----
----
2-Fluorophenol
2.4.6-Tribromophenol
EP075T: Base/Neutral Extractable Surrogates
EP080S: TPH(V)/BTEX Surrogates 1.2-Dichloroethane-D4
Page Work Order Client Project
: : : :
17 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
TP2 (1.4-1.5)
TP2 (1.9-2.0)
TP2 (3.2-3.3)
TP3 (0-0.1)
TP3 (0.4-0.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-007
EM1008731-008
EM1008731-010
EM1008731-011
EM1008731-012
2037-26-5
0.1
%
100
----
92.0
----
----
460-00-4
0.1
%
109
----
104
----
----
CAS Number
EP080S: TPH(V)/BTEX Surrogates - Continued Toluene-D8 4-Bromofluorobenzene
Page Work Order Client Project
: : : :
18 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP3 (1.4-1.5)
TP3 (2.0-2.1)
TP3 (2.4-2.5)
TP4 (0-0.1)
TP4 (0.4-0.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-013
EM1008731-014
EM1008731-015
EM1008731-016
EM1008731-017
----
0.5
kg H2SO4/t
----
-39.4
----
----
----
----
0.5
kg H2SO4 equiv./t
----
41.3
----
----
----
----
1.0
%
25.4
30.6
33.4
26.5
17.7
^ Exchangeable Calcium
----
0.1
meq/100g
----
26.7
----
----
----
^ Exchangeable Magnesium
----
0.1
meq/100g
----
16.8
----
----
----
^ Exchangeable Potassium
----
0.1
meq/100g
----
1.8
----
----
----
^ Exchangeable Sodium
----
0.1
meq/100g
----
2.4
----
----
----
^ Cation Exchange Capacity
----
0.1
meq/100g
----
47.7
----
----
----
^ Exchangeable Aluminium
----
0.1
meq/100g
----
<0.1
----
----
----
^ Exchangeable Calcium Percent
----
0.1
%
----
55.9
----
----
----
^ Exchangeable Sodium Percent
----
0.1
%
----
5.1
----
----
----
^ Exchangeable Magnesium Percent
----
0.1
%
----
35.2
----
----
----
^ Exchangeable Potassium Percent
----
0.1
%
----
3.8
----
----
----
^ Calcium/Magnesium Ratio
----
0.1
.
----
1.6
----
----
----
----
0.01
%
----
0.06
----
----
----
Compound
CAS Number
EA009: Nett Acid Production Potential ^ Net Acid Production Potential
EA013: Acid Neutralising Capacity ANC as H2SO4
EA055: Moisture Content ^ Moisture Content (dried @ 103째C)
ED007: Exchangeable Cations
ED042T: Total Sulfur by LECO Sulfur - Total as S (LECO)
ED093S: Soluble Major Cations Calcium
7440-70-2
10
mg/kg
----
100
----
----
----
Magnesium
7439-95-4
10
mg/kg
----
90
----
----
----
Sodium
7440-23-5
10
mg/kg
----
220
----
----
----
Potassium
7440-09-7
10
mg/kg
----
40
----
----
----
EG005S : Soluble Metals by ICPAES Aluminium
7429-90-5
1
mg/kg
----
<1
----
----
----
Manganese
7439-96-5
0.1
mg/kg
----
<0.1
----
----
----
Arsenic
7440-38-2
5
mg/kg
77
----
----
----
----
Cadmium
7440-43-9
1
mg/kg
2
----
----
----
----
Copper
7440-50-8
5
mg/kg
474
----
----
----
----
Lead
7439-92-1
5
mg/kg
822
----
----
----
----
Molybdenum
7439-98-7
2
mg/kg
7
----
----
----
----
Nickel
7440-02-0
2
mg/kg
77
----
----
----
----
Selenium
7782-49-2
5
mg/kg
<5
----
----
----
----
Silver
7440-22-4
2
mg/kg
<2
----
----
----
----
EG005T: Total Metals by ICP-AES
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: : : :
19 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
LOR
Unit
TP3 (1.4-1.5)
TP3 (2.0-2.1)
TP3 (2.4-2.5)
TP4 (0-0.1)
TP4 (0.4-0.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
EM1008731-013
EM1008731-014
EM1008731-015
EM1008731-016
EM1008731-017
EG005T: Total Metals by ICP-AES - Continued Tin
7440-31-5
5
mg/kg
268
----
----
----
----
Zinc
7440-66-6
5
mg/kg
1170
----
----
----
----
Arsenic
7440-38-2
5
mg/kg
----
158
19
<5
----
Cadmium
7440-43-9
1
mg/kg
----
2
<1
<1
----
Chromium
7440-47-3
2
mg/kg
----
65
36
21
----
Copper
7440-50-8
5
mg/kg
----
202
16
28
----
Lead
7439-92-1
5
mg/kg
----
198
26
31
----
Nickel
7440-02-0
2
mg/kg
----
52
27
29
----
Zinc
7440-66-6
5
mg/kg
----
587
53
54
----
7439-97-6
0.1
mg/kg
0.5
0.4
0.2
<0.1
----
0.5
mg/kg
<0.5
----
----
----
----
----
1
mg/kg
----
----
----
<1
----
57-12-5
1
mg/kg
8
----
----
1
----
16984-48-8
40
mg/kg
120
----
----
----
----
----
0.5
%
----
2.4
----
----
----
----
0.10
mg/kg
<2.50
----
----
----
----
Benzene
71-43-2
0.2
mg/kg
<0.2
----
----
----
----
Toluene
108-88-3
0.5
mg/kg
<0.5
----
----
----
----
Ethylbenzene
100-41-4
0.5
mg/kg
<0.5
----
----
----
----
108-38-3 106-42-3
0.5
mg/kg
<0.5
----
----
----
----
100-42-5
0.5
mg/kg
<0.5
----
----
----
----
95-47-6
0.5
mg/kg
<0.5
----
----
----
----
----
0.2
mg/kg
<0.2
----
----
----
----
----
0.2
mg/kg
<0.2
----
----
----
----
Vinyl chloride
75-01-4
0.02
mg/kg
<0.02
----
----
----
----
1.1-Dichloroethene
75-35-4
0.01
mg/kg
<0.01
----
----
----
----
EG035T: Total Recoverable Mercury by FIMS Mercury
EG048: Hexavalent Chromium (Alkaline Digest) Hexavalent Chromium
18540-29-9
EK025G: Free cyanide by Discrete Analyser Free Cyanide
EK026G: Total Cyanide By Discrete Analyser Total Cyanide
EK040T: Fluoride Total Fluoride
EP004: Organic Matter ^ Total Organic Carbon
EP066: Polychlorinated Biphenyls (PCB) Total Polychlorinated biphenyls
EP074A: Monocyclic Aromatic Hydrocarbons
meta- & para-Xylene Styrene ortho-Xylene ^ Sum of monocyclic aromatic hydrocarbons ^ Sum of monocyclic aromatic hydrocarbons
EP074I: Volatile Halogenated Compounds
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: : : :
20 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
LOR
Unit
TP3 (1.4-1.5)
TP3 (2.0-2.1)
TP3 (2.4-2.5)
TP4 (0-0.1)
TP4 (0.4-0.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
EM1008731-013
EM1008731-014
EM1008731-015
EM1008731-016
EM1008731-017
EP074I: Volatile Halogenated Compounds - Continued 75-09-2
0.4
mg/kg
<0.6
----
----
----
----
trans-1.2-Dichloroethene
156-60-5
0.02
mg/kg
<0.02
----
----
----
----
cis-1.2-Dichloroethene
156-59-2
0.01
mg/kg
<0.01
----
----
----
----
Chloroform
67-66-3
0.02
mg/kg
<0.02
----
----
----
----
1.1.1-Trichloroethane
71-55-6
0.01
mg/kg
<0.01
----
----
----
----
Carbon Tetrachloride
56-23-5
0.01
mg/kg
<0.01
----
----
----
----
107-06-2
0.02
mg/kg
<0.02
----
----
----
----
Trichloroethene
79-01-6
0.02
mg/kg
<0.02
----
----
----
----
1.1.2-Trichloroethane
79-00-5
0.04
mg/kg
<0.04
----
----
----
----
Tetrachloroethene
127-18-4
0.02
mg/kg
<0.02
----
----
----
----
1.1.1.2-Tetrachloroethane
630-20-6
0.01
mg/kg
<0.01
----
----
----
----
1.1.2.2-Tetrachloroethane
79-34-5
0.02
mg/kg
<0.02
----
----
----
----
Hexachlorobutadiene
87-68-3
0.02
mg/kg
<0.02
----
----
----
----
Chlorobenzene
108-90-7
0.02
mg/kg
<0.02
----
----
----
----
1.4-Dichlorobenzene
106-46-7
0.02
mg/kg
<0.02
----
----
----
----
1.2-Dichlorobenzene
95-50-1
0.02
mg/kg
<0.02
----
----
----
----
120-82-1
0.01
mg/kg
<0.01
----
----
----
----
----
0.01
mg/kg
<0.01
----
----
----
----
----
0.01
mg/kg
<0.01
----
----
----
----
----
0.01
mg/kg
<0.01
----
----
----
----
----
0.01
mg/kg
<0.01
----
----
----
----
1330-20-7
0.50
mg/kg
<0.50
----
----
----
----
Methylene chloride
1.2-Dichloroethane
1.2.4-Trichlorobenzene ^ Sum of volatile chlorinated hydrocarbons ^ Sum of other chlorinated hydrocarbons (VIC EPA 448.3) ^ Sum of volatile chlorinated hydrocarbons ^ Sum of other chlorinated hydrocarbons (VIC EPA 448.3) ^ Total Xylenes
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons 91-20-3
0.5
mg/kg
----
<0.5
----
----
<0.5
208-96-8
0.5
mg/kg
----
<0.5
----
----
<0.5
Acenaphthene
83-32-9
0.5
mg/kg
----
<0.5
----
----
<0.5
Fluorene
86-73-7
0.5
mg/kg
----
<0.5
----
----
<0.5
Phenanthrene
85-01-8
0.5
mg/kg
----
<0.5
----
----
<0.5
Anthracene
120-12-7
0.5
mg/kg
----
<0.5
----
----
<0.5
Fluoranthene
206-44-0
0.5
mg/kg
----
<0.5
----
----
<0.5
Pyrene
129-00-0
0.5
mg/kg
----
<0.5
----
----
<0.5
56-55-3
0.5
mg/kg
----
<0.5
----
----
<0.5
Chrysene
218-01-9
0.5
mg/kg
----
<0.5
----
----
<0.5
Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
----
<0.5
----
----
<0.5
Naphthalene Acenaphthylene
Benz(a)anthracene
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: : : :
21 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
TP3 (1.4-1.5)
TP3 (2.0-2.1)
TP3 (2.4-2.5)
TP4 (0-0.1)
TP4 (0.4-0.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
Unit
EM1008731-013
EM1008731-014
EM1008731-015
EM1008731-016
EM1008731-017
Client sampling date / time Compound
CAS Number
LOR
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons - Continued 207-08-9
0.5
mg/kg
----
<0.5
----
----
<0.5
50-32-8
0.5
mg/kg
----
<0.5
----
----
<0.5
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
----
<0.5
----
----
<0.5
Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
----
<0.5
----
----
<0.5
191-24-2
0.5
mg/kg
----
<0.5
----
----
<0.5
Benzo(k)fluoranthene Benzo(a)pyrene
Benzo(g.h.i)perylene
EP075A: Phenolic Compounds (Halogenated) 95-57-8
0.03
mg/kg
<0.30
----
----
----
----
2.4-Dichlorophenol
120-83-2
0.03
mg/kg
<0.30
----
----
----
----
2.6-Dichlorophenol
87-65-0
0.03
mg/kg
<0.30
----
----
----
----
4-Chloro-3-Methylphenol
59-50-7
0.03
mg/kg
<0.30
----
----
----
----
2.4.5-Trichlorophenol
95-95-4
0.05
mg/kg
<0.30
----
----
----
----
2.4.6-Trichlorophenol
88-06-2
0.05
mg/kg
<0.30
----
----
----
----
935-95-5
0.03
mg/kg
<0.30
----
----
----
----
4901-51-3/58-90-2
0.05
mg/kg
<0.60
----
----
----
----
87-86-5
0.2
mg/kg
<0.3
----
----
----
----
----
0.03
mg/kg
<0.30
----
----
----
----
108-95-2
1
mg/kg
<1
----
----
----
----
95-48-7
1
mg/kg
<1
----
----
----
----
1319-77-3
1
mg/kg
<1
----
----
----
----
88-75-5
1
mg/kg
<1
----
----
----
----
105-67-9
1
mg/kg
<1
----
----
----
----
51-28-5
5
mg/kg
<24
----
----
----
----
100-02-7
5
mg/kg
<24
----
----
----
----
8071-51-0
5
mg/kg
<24
----
----
----
----
88-85-7
5
mg/kg
<24
----
----
----
----
131-89-5
5
mg/kg
<24
----
----
----
----
----
1
mg/kg
<1
----
----
----
----
2-Chlorophenol
2.3.5.6-Tetrachlorophenol 2.3.4.5 & 2.3.4.6-Tetrachlorophenol Pentachlorophenol ^ Sum of Phenols (halogenated)
EP075A: Phenolic Compounds (Non-halogenated) Phenol 2-Methylphenol 3- & 4-Methylphenol 2-Nitrophenol 2.4-Dimethylphenol 2.4-Dinitrophenol 4-Nitrophenol 2-Methyl-4.6-dinitrophenol Dinoseb 2-Cyclohexyl-4.6-Dinitrophenol ^ Sum of Phenols (non-halogenated)
EP075B: Polynuclear Aromatic Hydrocarbons Naphthalene
91-20-3
0.5
mg/kg
<0.5
----
----
----
----
Acenaphthene
83-32-9
0.5
mg/kg
<0.5
----
----
----
----
208-96-8
0.5
mg/kg
0.5
----
----
----
----
Fluorene
86-73-7
0.5
mg/kg
<0.5
----
----
----
----
Phenanthrene
85-01-8
0.5
mg/kg
2.5
----
----
----
----
Anthracene
120-12-7
0.5
mg/kg
0.8
----
----
----
----
Fluoranthene
206-44-0
0.5
mg/kg
7.6
----
----
----
----
Pyrene
129-00-0
0.5
mg/kg
6.5
----
----
----
----
Acenaphthylene
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: : : :
22 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP3 (1.4-1.5)
TP3 (2.0-2.1)
TP3 (2.4-2.5)
TP4 (0-0.1)
TP4 (0.4-0.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-013
EM1008731-014
EM1008731-015
EM1008731-016
EM1008731-017
EP075B: Polynuclear Aromatic Hydrocarbons - Continued 56-55-3
0.5
mg/kg
4.1
----
----
----
----
218-01-9
0.5
mg/kg
3.2
----
----
----
----
205-99-2 207-08-9
0.5
mg/kg
7.5
----
----
----
----
Benz(a)anthracene Chrysene Benzo(b) & Benzo(k)fluoranthene Benzo(a)pyrene
50-32-8
0.5
mg/kg
4.7
----
----
----
----
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
2.7
----
----
----
----
Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
0.7
----
----
----
----
191-24-2
0.5
mg/kg
3.2
----
----
----
----
----
0.5
mg/kg
44.0
----
----
----
----
alpha-BHC
319-84-6
0.03
mg/kg
<0.30
----
----
----
----
Hexachlorobenzene (HCB)
118-74-1
0.03
mg/kg
<0.30
----
----
----
----
beta-BHC
319-85-7
0.03
mg/kg
<0.30
----
----
----
----
58-89-9
0.03
mg/kg
<0.30
----
----
----
----
delta-BHC
319-86-8
0.03
mg/kg
<0.30
----
----
----
----
Heptachlor
76-44-8
0.03
mg/kg
<0.30
----
----
----
----
309-00-2
0.03
mg/kg
<0.30
----
----
----
----
Heptachlor epoxide
1024-57-3
0.03
mg/kg
<0.30
----
----
----
----
cis-Chlordane
5103-71-9
0.03
mg/kg
<0.30
----
----
----
----
trans-Chlordane
5103-74-2
0.03
mg/kg
<0.30
----
----
----
----
959-98-8
0.03
mg/kg
<0.30
----
----
----
----
4.4`-DDE
72-55-9
0.05
mg/kg
<0.30
----
----
----
----
Dieldrin
60-57-1
0.03
mg/kg
<0.30
----
----
----
----
7421-93-4
0.03
mg/kg
<0.30
----
----
----
----
72-20-8
0.03
mg/kg
<0.30
----
----
----
----
33213-65-9
0.03
mg/kg
<0.30
----
----
----
----
72-54-8
0.05
mg/kg
<0.30
----
----
----
----
1031-07-8
0.03
mg/kg
<0.30
----
----
----
----
4.4`-DDT
50-29-3
0.05
mg/kg
<0.30
----
----
----
----
Methoxychlor
72-43-5
0.03
mg/kg
<0.30
----
----
----
----
----
0.03
mg/kg
<0.30
----
----
----
----
309-00-2/60-57-1
0.03
mg/kg
<0.30
----
----
----
----
----
0.05
mg/kg
<0.30
----
----
----
----
57-74-9
0.03
mg/kg
<0.30
----
----
----
----
----
0.03
mg/kg
<0.30
----
----
----
----
Benzo(g.h.i)perylene ^ Sum of polycyclic aromatic hydrocarbons
EP075I: Organochlorine Pesticides
gamma-BHC
Aldrin
Endosulfan 1
Endrin aldehyde Endrin Endosulfan 2 4.4`-DDD Endosulfan sulfate
^ Sum of organochlorine pesticides ^ Sum of Aldrin + Dieldrin ^ Sum of DDD + DDE + DDT ^ Chlordane ^ Sum of other organochlorine pesticides
EP080/071: Total Petroleum Hydrocarbons
Page Work Order Client Project
: : : :
23 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP3 (1.4-1.5)
TP3 (2.0-2.1)
TP3 (2.4-2.5)
TP4 (0-0.1)
TP4 (0.4-0.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
EM1008731-014
EM1008731-015
EM1008731-016
EM1008731-017
LOR
Unit
EM1008731-013
EP080/071: Total Petroleum Hydrocarbons - Continued C6 - C9 Fraction
----
10
mg/kg
<10
----
----
----
----
C6 - C9 Fraction
----
10
mg/kg
----
<10
----
----
<10
C10 - C14 Fraction
----
50
mg/kg
<50
<50
----
----
<50
C15 - C28 Fraction
----
100
mg/kg
1690
120
----
----
<100
C29 - C36 Fraction
----
100
mg/kg
3070
240
----
----
<100
^ C10 - C36 Fraction (sum)
----
50
mg/kg
4760
360
----
----
<50
Benzene
71-43-2
0.2
mg/kg
----
<0.2
----
----
<0.2
Toluene
108-88-3
0.5
mg/kg
----
<0.5
----
----
<0.5
Ethylbenzene
100-41-4
0.5
mg/kg
----
<0.5
----
----
<0.5
108-38-3 106-42-3
0.5
mg/kg
----
<0.5
----
----
<0.5
95-47-6
0.5
mg/kg
----
<0.5
----
----
<0.5
2051-24-3
0.1
%
56.8
----
----
----
----
17060-07-0
0.1
%
100
----
----
----
----
2037-26-5
0.1
%
87.8
----
----
----
----
460-00-4
0.1
%
97.1
----
----
----
----
Phenol-d6
13127-88-3
0.1
%
----
67.5
----
----
64.7
2-Chlorophenol-D4
93951-73-6
0.1
%
----
107
----
----
102
118-79-6
0.1
%
----
85.1
----
----
82.4
2-Fluorobiphenyl
321-60-8
0.1
%
----
94.1
----
----
92.7
Anthracene-d10
1719-06-8
0.1
%
----
96.3
----
----
90.6
4-Terphenyl-d14
1718-51-0
0.1
%
----
111
----
----
108
EP080: BTEX
meta- & para-Xylene ortho-Xylene
EP066S: PCB Surrogate Decachlorobiphenyl
EP074S: VOC Surrogates 1.2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene
EP075(SIM)S: Phenolic Compound Surrogates
2.4.6-Tribromophenol
EP075(SIM)T: PAH Surrogates
EP075S: Acid Extractable Surrogates 367-12-4
0.1
%
Not Determined
----
----
----
----
Phenol-d6
13127-88-3
0.1
%
Not Determined
----
----
----
----
2-Chlorophenol-D4
93951-73-6
0.1
%
Not Determined
----
----
----
----
118-79-6
0.1
%
Not Determined
----
----
----
----
Nitrobenzene-D5
4165-60-0
0.1
%
Not Determined
----
----
----
----
1.2-Dichlorobenzene-D4
2199-69-1
0.1
%
Not Determined
----
----
----
----
2-Fluorobiphenyl
321-60-8
0.1
%
Not Determined
----
----
----
----
Anthracene-d10
1719-06-8
0.1
%
Not Determined
----
----
----
----
4-Terphenyl-d14
1718-51-0
0.1
%
Not Determined
----
----
----
----
2-Fluorophenol
2.4.6-Tribromophenol
EP075T: Base/Neutral Extractable Surrogates
Page Work Order Client Project
: : : :
24 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
TP3 (1.4-1.5)
TP3 (2.0-2.1)
TP3 (2.4-2.5)
TP4 (0-0.1)
TP4 (0.4-0.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-013
EM1008731-014
EM1008731-015
EM1008731-016
EM1008731-017
17060-07-0
0.1
%
----
87.4
----
----
112
2037-26-5
0.1
%
----
80.2
----
----
119
460-00-4
0.1
%
----
98.0
----
----
127
CAS Number
EP080S: TPH(V)/BTEX Surrogates 1.2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene
Page Work Order Client Project
: : : :
25 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP4 (1.4-1.5)
DUP1
TP4 (2.1-2.2)
TP5 (0.4-0.5)
TP5 (1.4-1.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-018
EM1008731-019
EM1008731-020
EM1008731-021
EM1008731-022
----
0.5
kg H2SO4/t
----
----
-23.5
----
----
----
0.5
kg H2SO4 equiv./t
----
----
27.4
----
----
pH KCl (23A)
----
0.1
pH Unit
----
----
7.5
----
----
pH OX (23B)
----
0.1
pH Unit
----
----
6.6
----
----
Titratable Actual Acidity (23F)
----
2
mole H+ / t
----
----
<2
----
----
Titratable Peroxide Acidity (23G)
----
2
mole H+ / t
----
----
<2
----
----
Titratable Sulfidic Acidity (23H)
----
2
mole H+ / t
----
----
<2
----
----
sulfidic - Titratable Actual Acidity (s-23F)
----
0.02
% pyrite S
----
----
<0.02
----
----
sulfidic - Titratable Peroxide Acidity
----
0.02
% pyrite S
----
----
<0.02
----
----
----
0.02
% pyrite S
----
----
<0.02
----
----
KCl Extractable Sulfur (23Ce)
----
0.02
%S
----
----
0.06
----
----
Peroxide Sulfur (23De)
----
0.02
%S
----
----
0.10
----
----
Peroxide Oxidisable Sulfur (23E)
----
0.02
%S
----
----
0.04
----
----
acidity - Peroxide Oxidisable Sulfur
----
10
mole H+ / t
----
----
26
----
----
KCl Extractable Calcium (23Vh)
----
0.02
% Ca
----
----
0.25
----
----
Peroxide Calcium (23Wh)
----
0.02
% Ca
----
----
0.47
----
----
Acid Reacted Calcium (23X)
----
0.02
% Ca
----
----
0.21
----
----
acidity - Acid Reacted Calcium (a-23X)
----
10
mole H+ / t
----
----
106
----
----
sulfidic - Acid Reacted Calcium (s-23X)
----
0.02
%S
----
----
0.17
----
----
KCl Extractable Magnesium (23Sm)
----
0.02
% Mg
----
----
0.12
----
----
Peroxide Magnesium (23Tm)
----
0.02
% Mg
----
----
0.22
----
----
Acid Reacted Magnesium (23U)
----
0.02
% Mg
----
----
0.09
----
----
Acidity - Acid Reacted Magnesium (a-23U)
----
10
mole H+ / t
----
----
77
----
----
sulfidic - Acid Reacted Magnesium
----
0.02
%S
----
----
0.12
----
----
----
0.02
% CaCO3
----
----
0.07
----
----
Compound
CAS Number
EA009: Nett Acid Production Potential ^ Net Acid Production Potential
EA013: Acid Neutralising Capacity ANC as H2SO4
EA029-A: pH Measurements
EA029-B: Acidity Trail
(s-23G) sulfidic - Titratable Sulfidic Acidity (s-23H)
EA029-C: Sulfur Trail
(a-23E)
EA029-D: Calcium Values
EA029-E: Magnesium Values
(s-23U)
EA029-F: Excess Acid Neutralising Capacity Excess Acid Neutralising Capacity (23Q)
Page Work Order Client Project
: : : :
26 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
TP4 (1.4-1.5)
DUP1
TP4 (2.1-2.2)
TP5 (0.4-0.5)
TP5 (1.4-1.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-018
EM1008731-019
EM1008731-020
EM1008731-021
EM1008731-022
----
10
mole H+ / t
----
----
14
----
----
----
0.02
%S
----
----
0.02
----
----
CAS Number
EA029-F: Excess Acid Neutralising Capacity - Continued acidity - Excess Acid Neutralising Capacity (a-23Q) sulfidic - Excess Acid Neutralising Capacity (s-23Q)
EA029-H: Acid Base Accounting ANC Fineness Factor
----
0.5
-
----
----
----
----
0.02
%S
----
----
1.5 <0.02
----
Net Acidity (sulfur units)
----
----
Net Acidity (acidity units)
----
10
mole H+ / t
----
----
<10
----
----
Liming Rate
----
1
kg CaCO3/t
----
----
<1
----
----
pH KCl (23A)
----
0.1
pH Unit
----
----
7.5
----
----
Titratable Actual Acidity (23F)
----
2
mole H+ / t
----
----
<2
----
----
sulfidic - Titratable Actual Acidity (s-23F)
----
0.02
% pyrite S
----
----
<0.02
----
----
Chromium Reducible Sulfur (22B)
----
0.005
%S
----
----
0.006
----
----
acidity - Chromium Reducible Sulfur
----
10
mole H+ / t
----
----
<10
----
----
Acid Neutralising Capacity (19A2)
----
0.01
% CaCO3
----
----
2.68
----
----
acidity - Acid Neutralising Capacity
----
10
mole H+ / t
----
----
536
----
----
----
0.01
% pyrite S
----
----
0.86
----
----
EA033-A: Actual Acidity
EA033-B: Potential Acidity
(a-22B)
EA033-C: Acid Neutralising Capacity
(a-19A2) sulfidic - Acid Neutralising Capacity (s-19A2)
EA033-E: Acid Base Accounting ANC Fineness Factor
----
0.5
-
----
----
----
----
0.02
%S
----
----
1.5 <0.02
----
Net Acidity (sulfur units)
----
----
Net Acidity (acidity units)
----
10
mole H+ / t
----
----
<10
----
----
Liming Rate
----
1
kg CaCO3/t
----
----
<1
----
----
----
1.0
%
27.9
20.4
47.2
12.7
35.7
^ Exchangeable Calcium
----
0.1
meq/100g
----
----
19.2
----
----
^ Exchangeable Magnesium
----
0.1
meq/100g
----
----
14.5
----
----
^ Exchangeable Potassium
----
0.1
meq/100g
----
----
0.5
----
----
^ Exchangeable Sodium
----
0.1
meq/100g
----
----
7.4
----
----
^ Cation Exchange Capacity
----
0.1
meq/100g
----
----
41.6
----
----
^ Exchangeable Aluminium
----
0.1
meq/100g
----
----
<0.1
----
----
EA055: Moisture Content ^ Moisture Content (dried @ 103째C)
ED007: Exchangeable Cations
Page Work Order Client Project
: : : :
27 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP4 (1.4-1.5)
DUP1
TP4 (2.1-2.2)
TP5 (0.4-0.5)
TP5 (1.4-1.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-018
EM1008731-019
EM1008731-020
EM1008731-021
EM1008731-022
ED007: Exchangeable Cations - Continued ^ Exchangeable Calcium Percent
----
0.1
%
----
----
46.1
----
----
^ Exchangeable Sodium Percent
----
0.1
%
----
----
17.8
----
----
^ Exchangeable Magnesium Percent
----
0.1
%
----
----
34.9
----
----
^ Exchangeable Potassium Percent
----
0.1
%
----
----
1.2
----
----
^ Calcium/Magnesium Ratio
----
0.1
.
----
----
1.3
----
----
----
0.01
%
----
----
0.13
----
----
ED042T: Total Sulfur by LECO Sulfur - Total as S (LECO)
ED093S: Soluble Major Cations Calcium
7440-70-2
10
mg/kg
----
----
40
----
----
Magnesium
7439-95-4
10
mg/kg
----
----
60
----
----
Sodium
7440-23-5
10
mg/kg
----
----
930
----
----
Potassium
7440-09-7
10
mg/kg
----
----
<10
----
----
EG005S : Soluble Metals by ICPAES Aluminium
7429-90-5
1
mg/kg
----
----
<1
----
----
Manganese
7439-96-5
0.1
mg/kg
----
----
<0.1
----
----
Arsenic
7440-38-2
5
mg/kg
----
----
----
7440-43-9
1
mg/kg
----
----
10 <1
----
Cadmium
----
----
Copper
7440-50-8
5
mg/kg
----
----
22
----
----
Lead
7439-92-1
5
mg/kg
----
----
15
----
----
Molybdenum
7439-98-7
2
mg/kg
----
----
<2
----
----
Nickel
7440-02-0
2
mg/kg
----
----
17
----
----
Selenium
7782-49-2
5
mg/kg
----
----
<5
----
----
Silver
7440-22-4
2
mg/kg
----
----
<2
----
----
Tin
7440-31-5
5
mg/kg
----
----
6
----
----
Zinc
7440-66-6
5
mg/kg
----
----
76
----
----
Arsenic
7440-38-2
5
mg/kg
15
60
----
166
Cadmium
7440-43-9
1
mg/kg
13
<1
----
3
6 <1
Chromium
7440-47-3
2
mg/kg
21
58
----
55
10
Copper
7440-50-8
5
mg/kg
334
59
----
553
118
Lead
7439-92-1
5
mg/kg
337
73
----
394
56
Nickel
7440-02-0
2
mg/kg
54
47
----
80
14
Zinc
7440-66-6
5
mg/kg
745
286
----
717
579
7439-97-6
0.1
mg/kg
0.2
0.2
0.3
0.7
0.9
0.5
mg/kg
----
----
<0.5
----
----
EG005T: Total Metals by ICP-AES
EG035T: Total Recoverable Mercury by FIMS Mercury
EG048: Hexavalent Chromium (Alkaline Digest) Hexavalent Chromium
18540-29-9
Page Work Order Client Project
: : : :
28 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP4 (1.4-1.5)
DUP1
TP4 (2.1-2.2)
TP5 (0.4-0.5)
TP5 (1.4-1.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-018
EM1008731-019
EM1008731-020
EM1008731-021
EM1008731-022
57-12-5
1
mg/kg
----
----
1
----
----
16984-48-8
40
mg/kg
----
----
120
----
----
----
0.5
%
----
----
9.9
----
----
----
0.10
mg/kg
----
----
<0.10
----
----
Benzene
71-43-2
0.2
mg/kg
----
----
<0.2
----
----
Toluene
108-88-3
0.5
mg/kg
----
----
<0.5
----
----
Ethylbenzene
100-41-4
0.5
mg/kg
----
----
<0.5
----
----
108-38-3 106-42-3
0.5
mg/kg
----
----
<0.5
----
----
100-42-5
0.5
mg/kg
----
----
<0.5
----
----
95-47-6
0.5
mg/kg
----
----
<0.5
----
----
----
0.2
mg/kg
----
----
<0.2
----
----
----
0.2
mg/kg
----
----
<0.2
----
----
Vinyl chloride
75-01-4
0.02
mg/kg
----
----
<0.02
----
----
1.1-Dichloroethene
75-35-4
0.01
mg/kg
----
----
<0.01
----
----
Methylene chloride
75-09-2
0.4
mg/kg
----
----
<0.8
----
----
trans-1.2-Dichloroethene
156-60-5
0.02
mg/kg
----
----
<0.02
----
----
cis-1.2-Dichloroethene
156-59-2
0.01
mg/kg
----
----
<0.01
----
----
Chloroform
67-66-3
0.02
mg/kg
----
----
<0.02
----
----
1.1.1-Trichloroethane
71-55-6
0.01
mg/kg
----
----
<0.01
----
----
Carbon Tetrachloride
56-23-5
0.01
mg/kg
----
----
<0.01
----
----
107-06-2
0.02
mg/kg
----
----
<0.02
----
----
Trichloroethene
79-01-6
0.02
mg/kg
----
----
<0.02
----
----
1.1.2-Trichloroethane
79-00-5
0.04
mg/kg
----
----
<0.04
----
----
Tetrachloroethene
127-18-4
0.02
mg/kg
----
----
<0.02
----
----
1.1.1.2-Tetrachloroethane
630-20-6
0.01
mg/kg
----
----
<0.01
----
----
1.1.2.2-Tetrachloroethane
79-34-5
0.02
mg/kg
----
----
<0.02
----
----
Hexachlorobutadiene
87-68-3
0.02
mg/kg
----
----
<0.02
----
----
Chlorobenzene
108-90-7
0.02
mg/kg
----
----
<0.02
----
----
1.4-Dichlorobenzene
106-46-7
0.02
mg/kg
----
----
<0.02
----
----
1.2-Dichlorobenzene
95-50-1
0.02
mg/kg
----
----
<0.02
----
----
Compound
CAS Number
EK026G: Total Cyanide By Discrete Analyser Total Cyanide
EK040T: Fluoride Total Fluoride
EP004: Organic Matter ^ Total Organic Carbon
EP066: Polychlorinated Biphenyls (PCB) Total Polychlorinated biphenyls
EP074A: Monocyclic Aromatic Hydrocarbons
meta- & para-Xylene Styrene ortho-Xylene ^ Sum of monocyclic aromatic hydrocarbons ^ Sum of monocyclic aromatic hydrocarbons
EP074I: Volatile Halogenated Compounds
1.2-Dichloroethane
Page Work Order Client Project
: : : :
29 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
TP4 (1.4-1.5)
DUP1
TP4 (2.1-2.2)
TP5 (0.4-0.5)
TP5 (1.4-1.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-018
EM1008731-019
EM1008731-020
EM1008731-021
EM1008731-022
120-82-1
0.01
mg/kg
----
----
<0.01
----
----
----
0.01
mg/kg
----
----
<0.01
----
----
----
0.01
mg/kg
----
----
<0.01
----
----
----
0.01
mg/kg
----
----
<0.01
----
----
----
0.01
mg/kg
----
----
<0.01
----
----
1330-20-7
0.50
mg/kg
----
----
<0.50
----
----
CAS Number
EP074I: Volatile Halogenated Compounds - Continued 1.2.4-Trichlorobenzene ^ Sum of volatile chlorinated hydrocarbons ^ Sum of other chlorinated hydrocarbons (VIC EPA 448.3) ^ Sum of volatile chlorinated hydrocarbons ^ Sum of other chlorinated hydrocarbons (VIC EPA 448.3) ^ Total Xylenes
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons 91-20-3
0.5
mg/kg
<0.5
<0.5
----
----
<0.5
208-96-8
0.5
mg/kg
<0.5
<0.5
----
----
<0.5
Acenaphthene
83-32-9
0.5
mg/kg
<0.5
<0.5
----
----
<0.5
Fluorene
86-73-7
0.5
mg/kg
<0.5
<0.5
----
----
<0.5
Phenanthrene
85-01-8
0.5
mg/kg
<0.5
<0.5
----
----
2.9
Anthracene
120-12-7
0.5
mg/kg
<0.5
<0.5
----
----
0.9
Fluoranthene
206-44-0
0.5
mg/kg
<0.5
0.8
----
----
4.5
Pyrene
129-00-0
0.5
mg/kg
<0.5
0.9
----
----
4.4
56-55-3
0.5
mg/kg
<0.5
<0.5
----
----
2.3
Chrysene
218-01-9
0.5
mg/kg
<0.5
<0.5
----
----
1.9
Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
<0.5
<0.5
----
----
1.9
Benzo(k)fluoranthene
207-08-9
0.5
mg/kg
<0.5
<0.5
----
----
0.7
50-32-8
0.5
mg/kg
<0.5
<0.5
----
----
1.5
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
<0.5
<0.5
----
----
Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
<0.5
<0.5
----
----
0.8 <0.5
191-24-2
0.5
mg/kg
<0.5
<0.5
----
----
0.8
Naphthalene Acenaphthylene
Benz(a)anthracene
Benzo(a)pyrene
Benzo(g.h.i)perylene
EP075A: Phenolic Compounds (Halogenated) 95-57-8
0.03
mg/kg
----
----
<0.03
----
----
2.4-Dichlorophenol
120-83-2
0.03
mg/kg
----
----
<0.03
----
----
2.6-Dichlorophenol
87-65-0
0.03
mg/kg
----
----
<0.03
----
----
4-Chloro-3-Methylphenol
59-50-7
0.03
mg/kg
----
----
<0.03
----
----
2.4.5-Trichlorophenol
95-95-4
0.05
mg/kg
----
----
<0.05
----
----
2.4.6-Trichlorophenol
88-06-2
0.05
mg/kg
----
----
<0.05
----
----
935-95-5
0.03
mg/kg
----
----
<0.03
----
----
4901-51-3/58-90-2
0.05
mg/kg
----
----
<0.05
----
----
87-86-5
0.2
mg/kg
----
----
<0.2
----
----
2-Chlorophenol
2.3.5.6-Tetrachlorophenol 2.3.4.5 & 2.3.4.6-Tetrachlorophenol Pentachlorophenol
Page Work Order Client Project
: : : :
30 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
TP4 (1.4-1.5)
DUP1
TP4 (2.1-2.2)
TP5 (0.4-0.5)
TP5 (1.4-1.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-018
EM1008731-019
EM1008731-020
EM1008731-021
EM1008731-022
0.03
mg/kg
----
----
<0.03
----
----
108-95-2
1
mg/kg
----
----
<1
----
----
95-48-7
1
mg/kg
----
----
<1
----
----
1319-77-3
1
mg/kg
----
----
<1
----
----
88-75-5
1
mg/kg
----
----
<1
----
----
105-67-9
1
mg/kg
----
----
<1
----
----
51-28-5
5
mg/kg
----
----
<5
----
----
100-02-7
5
mg/kg
----
----
<5
----
----
8071-51-0
5
mg/kg
----
----
<5
----
----
88-85-7
5
mg/kg
----
----
<5
----
----
131-89-5
5
mg/kg
----
----
<5
----
----
----
1
mg/kg
----
----
<1
----
----
CAS Number
EP075A: Phenolic Compounds (Halogenated) - Continued ----
^ Sum of Phenols (halogenated)
EP075A: Phenolic Compounds (Non-halogenated) Phenol 2-Methylphenol 3- & 4-Methylphenol 2-Nitrophenol 2.4-Dimethylphenol 2.4-Dinitrophenol 4-Nitrophenol 2-Methyl-4.6-dinitrophenol Dinoseb 2-Cyclohexyl-4.6-Dinitrophenol ^ Sum of Phenols (non-halogenated)
EP075B: Polynuclear Aromatic Hydrocarbons Naphthalene
91-20-3
0.5
mg/kg
----
----
<0.5
----
----
Acenaphthene
83-32-9
0.5
mg/kg
----
----
<0.5
----
----
208-96-8
0.5
mg/kg
----
----
<0.5
----
----
Fluorene
86-73-7
0.5
mg/kg
----
----
<0.5
----
----
Phenanthrene
85-01-8
0.5
mg/kg
----
----
<0.5
----
----
Anthracene
120-12-7
0.5
mg/kg
----
----
<0.5
----
----
Fluoranthene
206-44-0
0.5
mg/kg
----
----
<0.5
----
----
Pyrene
129-00-0
0.5
mg/kg
----
----
<0.5
----
----
56-55-3
0.5
mg/kg
----
----
<0.5
----
----
218-01-9
0.5
mg/kg
----
----
<0.5
----
----
205-99-2 207-08-9
0.5
mg/kg
----
----
<0.5
----
----
Acenaphthylene
Benz(a)anthracene Chrysene Benzo(b) & Benzo(k)fluoranthene Benzo(a)pyrene
50-32-8
0.5
mg/kg
----
----
<0.5
----
----
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
----
----
<0.5
----
----
Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
----
----
<0.5
----
----
191-24-2
0.5
mg/kg
----
----
<0.5
----
----
----
0.5
mg/kg
----
----
<0.5
----
----
alpha-BHC
319-84-6
0.03
mg/kg
----
----
<0.03
----
----
Hexachlorobenzene (HCB)
118-74-1
0.03
mg/kg
----
----
<0.03
----
----
beta-BHC
319-85-7
0.03
mg/kg
----
----
<0.03
----
----
58-89-9
0.03
mg/kg
----
----
<0.03
----
----
319-86-8
0.03
mg/kg
----
----
<0.03
----
----
Benzo(g.h.i)perylene ^ Sum of polycyclic aromatic hydrocarbons
EP075I: Organochlorine Pesticides
gamma-BHC delta-BHC
Page Work Order Client Project
: : : :
31 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP4 (1.4-1.5)
DUP1
TP4 (2.1-2.2)
TP5 (0.4-0.5)
TP5 (1.4-1.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-018
EM1008731-019
EM1008731-020
EM1008731-021
EM1008731-022
EP075I: Organochlorine Pesticides - Continued 76-44-8
0.03
mg/kg
----
----
<0.03
----
----
309-00-2
0.03
mg/kg
----
----
<0.03
----
----
Heptachlor epoxide
1024-57-3
0.03
mg/kg
----
----
<0.03
----
----
cis-Chlordane
5103-71-9
0.03
mg/kg
----
----
<0.03
----
----
trans-Chlordane
5103-74-2
0.03
mg/kg
----
----
<0.03
----
----
959-98-8
0.03
mg/kg
----
----
<0.03
----
----
4.4`-DDE
72-55-9
0.05
mg/kg
----
----
<0.05
----
----
Dieldrin
60-57-1
0.03
mg/kg
----
----
<0.03
----
----
7421-93-4
0.03
mg/kg
----
----
<0.03
----
----
72-20-8
0.03
mg/kg
----
----
<0.03
----
----
33213-65-9
0.03
mg/kg
----
----
<0.03
----
----
72-54-8
0.05
mg/kg
----
----
<0.05
----
----
1031-07-8
0.03
mg/kg
----
----
<0.03
----
----
4.4`-DDT
50-29-3
0.05
mg/kg
----
----
<0.05
----
----
Methoxychlor
72-43-5
0.03
mg/kg
----
----
<0.03
----
----
----
0.03
mg/kg
----
----
<0.03
----
----
309-00-2/60-57-1
0.03
mg/kg
----
----
<0.03
----
----
----
0.05
mg/kg
----
----
<0.05
----
----
57-74-9
0.03
mg/kg
----
----
<0.03
----
----
----
0.03
mg/kg
----
----
<0.03
----
----
C6 - C9 Fraction
----
10
mg/kg
----
----
<10
----
----
C6 - C9 Fraction
----
10
mg/kg
<10
<10
----
----
<10
C10 - C14 Fraction
----
50
mg/kg
<50
<50
<50
----
<50
C15 - C28 Fraction
----
100
mg/kg
<100
140
<100
----
150
C29 - C36 Fraction
----
100
mg/kg
<100
230
<100
----
120
^ C10 - C36 Fraction (sum)
----
50
mg/kg
<50
370
<50
----
270
Benzene
71-43-2
0.2
mg/kg
<0.2
<0.2
----
----
<0.2
Toluene
108-88-3
0.5
mg/kg
<0.5
<0.5
----
----
<0.5
Ethylbenzene
100-41-4
0.5
mg/kg
<0.5
<0.5
----
----
<0.5
108-38-3 106-42-3
0.5
mg/kg
<0.5
<0.5
----
----
<0.5
95-47-6
0.5
mg/kg
<0.5
<0.5
----
----
<0.5
2051-24-3
0.1
%
----
----
63.1
----
----
17060-07-0
0.1
%
----
----
98.9
----
----
Heptachlor Aldrin
Endosulfan 1
Endrin aldehyde Endrin Endosulfan 2 4.4`-DDD Endosulfan sulfate
^ Sum of organochlorine pesticides ^ Sum of Aldrin + Dieldrin ^ Sum of DDD + DDE + DDT ^ Chlordane ^ Sum of other organochlorine pesticides
EP080/071: Total Petroleum Hydrocarbons
EP080: BTEX
meta- & para-Xylene ortho-Xylene
EP066S: PCB Surrogate Decachlorobiphenyl
EP074S: VOC Surrogates 1.2-Dichloroethane-D4
Page Work Order Client Project
: : : :
32 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP4 (1.4-1.5)
DUP1
TP4 (2.1-2.2)
TP5 (0.4-0.5)
TP5 (1.4-1.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-018
EM1008731-019
EM1008731-020
EM1008731-021
EM1008731-022
2037-26-5
0.1
%
----
----
74.1
----
----
460-00-4
0.1
%
----
----
41.0
----
----
Phenol-d6
13127-88-3
0.1
%
50.5
64.8
----
----
67.1
2-Chlorophenol-D4
93951-73-6
0.1
%
45.6
104
----
----
107
118-79-6
0.1
%
9.6
88.0
----
----
115
2-Fluorobiphenyl
321-60-8
0.1
%
90.9
93.9
----
----
95.6
Anthracene-d10
1719-06-8
0.1
%
98.6
92.8
----
----
97.0
4-Terphenyl-d14
1718-51-0
0.1
%
91.6
109
----
----
109
Compound
CAS Number
EP074S: VOC Surrogates - Continued Toluene-D8 4-Bromofluorobenzene
EP075(SIM)S: Phenolic Compound Surrogates
2.4.6-Tribromophenol
EP075(SIM)T: PAH Surrogates
EP075S: Acid Extractable Surrogates 367-12-4
0.1
%
----
----
17.8
----
----
Phenol-d6
13127-88-3
0.1
%
----
----
24.7
----
----
2-Chlorophenol-D4
93951-73-6
0.1
%
----
----
26.0
----
----
118-79-6
0.1
%
----
----
Not Determined
----
----
Nitrobenzene-D5
4165-60-0
0.1
%
----
----
59.7
----
----
1.2-Dichlorobenzene-D4
2199-69-1
0.1
%
----
----
62.4
----
----
2-Fluorobiphenyl
321-60-8
0.1
%
----
----
66.7
----
----
Anthracene-d10
1719-06-8
0.1
%
----
----
55.2
----
----
4-Terphenyl-d14
1718-51-0
0.1
%
----
----
68.8
----
----
17060-07-0
0.1
%
104
96.3
----
----
107
2037-26-5
0.1
%
96.1
108
----
----
100
460-00-4
0.1
%
97.8
117
----
----
111
2-Fluorophenol
2.4.6-Tribromophenol
EP075T: Base/Neutral Extractable Surrogates
EP080S: TPH(V)/BTEX Surrogates 1.2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene
Page Work Order Client Project
: : : :
33 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP5 (2.9-3.0)
TP5 (3.9-4.0)
TP6 (0-0.1)
TP6 (0.4-0.5)
TP6 (1.4-1.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-023
EM1008731-024
EM1008731-025
EM1008731-026
EM1008731-027
1.0
%
47.7
53.0
43.9
17.9
25.0
EA055: Moisture Content ----
^ Moisture Content (dried @ 103째C)
EG005T: Total Metals by ICP-AES Arsenic
7440-38-2
5
mg/kg
----
114
<5
7440-43-9
1
mg/kg
----
7 <1
43
Cadmium
1
1
<1
Chromium
7440-47-3
2
mg/kg
----
70
38
56
32
Copper
7440-50-8
5
mg/kg
----
24
247
242
18
Lead
7439-92-1
5
mg/kg
----
33
175
147
26
Nickel
7440-02-0
2
mg/kg
----
34
48
69
47
Zinc
7440-66-6
5
mg/kg
----
52
439
472
92
7439-97-6
0.1
mg/kg
----
0.4
0.4
0.3
<0.1
----
1
mg/kg
----
----
----
----
<1
57-12-5
1
mg/kg
----
----
----
----
<1
EG035T: Total Recoverable Mercury by FIMS Mercury
EK025G: Free cyanide by Discrete Analyser Free Cyanide
EK026G: Total Cyanide By Discrete Analyser Total Cyanide
EP075(SIM)A: Phenolic Compounds 108-95-2
0.5
mg/kg
<0.5
<1.0
----
<0.5
----
2-Chlorophenol
95-57-8
0.5
mg/kg
<0.5
<1.0
----
<0.5
----
2-Methylphenol
95-48-7
0.5
mg/kg
<0.5
<1.0
----
<0.5
----
1319-77-3
1.0
mg/kg
<1.0
<2.0
----
<1.0
----
88-75-5
0.5
mg/kg
<0.5
<1.0
----
<0.5
----
2.4-Dimethylphenol
105-67-9
0.5
mg/kg
<0.5
<1.0
----
<0.5
----
2.4-Dichlorophenol
120-83-2
0.5
mg/kg
<0.5
<1.0
----
<0.5
----
2.6-Dichlorophenol
87-65-0
0.5
mg/kg
<0.5
<1.0
----
<0.5
----
4-Chloro-3-Methylphenol
59-50-7
0.5
mg/kg
<0.5
<1.0
----
<0.5
----
2.4.6-Trichlorophenol
88-06-2
0.5
mg/kg
<0.5
<1.0
----
<0.5
----
2.4.5-Trichlorophenol
95-95-4
0.5
mg/kg
<0.5
<1.0
----
<0.5
----
Pentachlorophenol
87-86-5
2.0
mg/kg
<2.0
<4.0
----
<2.0
----
Phenol
3- & 4-Methylphenol 2-Nitrophenol
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons 91-20-3
0.5
mg/kg
<0.5
<1.0
<0.5
----
<0.5
208-96-8
0.5
mg/kg
----
----
<0.5
----
<0.5
83-32-9
0.5
mg/kg
----
----
<0.5
----
<0.5
208-96-8
0.5
mg/kg
<0.5
<1.0
----
----
----
Acenaphthene
83-32-9
0.5
mg/kg
<0.5
<1.0
----
----
----
Fluorene
86-73-7
0.5
mg/kg
----
----
<0.5
----
<0.5
Fluorene
86-73-7
0.5
mg/kg
<0.5
<1.0
----
----
----
Phenanthrene
85-01-8
0.5
mg/kg
----
----
4.8
----
<0.5
Naphthalene Acenaphthylene Acenaphthene Acenaphthylene
Page Work Order Client Project
: : : :
34 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
LOR
Unit
TP5 (2.9-3.0)
TP5 (3.9-4.0)
TP6 (0-0.1)
TP6 (0.4-0.5)
TP6 (1.4-1.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
EM1008731-023
EM1008731-024
EM1008731-025
EM1008731-026
EM1008731-027
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons - Continued 120-12-7
0.5
mg/kg
----
----
1.8
----
<0.5
85-01-8
0.5
mg/kg
<0.5
<1.0
----
----
----
Anthracene
120-12-7
0.5
mg/kg
<0.5
<1.0
----
----
----
Fluoranthene
206-44-0
0.5
mg/kg
----
----
15.0
----
<0.5
Fluoranthene
206-44-0
0.5
mg/kg
0.5
<1.0
----
----
----
Pyrene
129-00-0
0.5
mg/kg
----
----
17.5
----
<0.5
Anthracene Phenanthrene
56-55-3
0.5
mg/kg
----
----
9.4
----
<0.5
129-00-0
0.5
mg/kg
1.4
<1.0
----
----
----
56-55-3
0.5
mg/kg
<0.5
<1.0
----
----
----
Chrysene
218-01-9
0.5
mg/kg
----
----
8.6
----
<0.5
Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
----
----
14.6
----
<0.5
Chrysene
218-01-9
0.5
mg/kg
0.6
<1.0
----
----
----
Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
<0.5
<1.0
----
----
----
Benzo(k)fluoranthene
207-08-9
0.5
mg/kg
----
----
3.3
----
<0.5
Benz(a)anthracene Pyrene Benz(a)anthracene
50-32-8
0.5
mg/kg
----
----
12.4
----
<0.5
207-08-9
0.5
mg/kg
<0.5
<1.0
----
----
----
50-32-8
0.5
mg/kg
<0.5
<1.0
----
----
----
193-39-5
0.5
mg/kg
----
----
6.4
----
<0.5
Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
----
----
1.7
----
<0.5
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
<0.5
<1.0
----
----
----
Benzo(g.h.i)perylene
191-24-2
0.5
mg/kg
----
----
7.4
----
<0.5
Benzo(a)pyrene Benzo(k)fluoranthene Benzo(a)pyrene Indeno(1.2.3.cd)pyrene
53-70-3
0.5
mg/kg
<0.5
<1.0
----
----
----
191-24-2
0.5
mg/kg
<0.5
<1.0
----
----
----
C6 - C9 Fraction
----
10
mg/kg
42
<10
<10
----
<10
C10 - C14 Fraction
----
50
mg/kg
100
<100
<50
----
<50
C15 - C28 Fraction
----
100
mg/kg
1810
<200
220
----
<100
C29 - C36 Fraction
----
100
mg/kg
2510
<200
430
----
<100
^ C10 - C36 Fraction (sum)
----
50
mg/kg
4420
<100
650
----
<50
Benzene
71-43-2
0.2
mg/kg
<0.2
<0.2
<0.2
----
<0.2
Toluene
108-88-3
0.5
mg/kg
<0.5
<0.5
<0.5
----
<0.5
Ethylbenzene
100-41-4
0.5
mg/kg
<0.5
<0.5
<0.5
----
<0.5
108-38-3 106-42-3
0.5
mg/kg
<0.5
<0.5
<0.5
----
<0.5
95-47-6
0.5
mg/kg
<0.5
<0.5
<0.5
----
<0.5
Phenol-d6
13127-88-3
0.1
%
70.4
66.9
99.8
66.0
72.9
2-Chlorophenol-D4
93951-73-6
0.1
%
112
107
105
106
116
Dibenz(a.h)anthracene Benzo(g.h.i)perylene
EP080/071: Total Petroleum Hydrocarbons
EP080: BTEX
meta- & para-Xylene ortho-Xylene
EP075(SIM)S: Phenolic Compound Surrogates
Page Work Order Client Project
: : : :
35 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP5 (2.9-3.0)
TP5 (3.9-4.0)
TP6 (0-0.1)
TP6 (0.4-0.5)
TP6 (1.4-1.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-023
EM1008731-024
EM1008731-025
EM1008731-026
EM1008731-027
118-79-6
0.1
%
93.7
89.7
91.7
86.1
91.2
2-Fluorobiphenyl
321-60-8
0.1
%
98.7
96.6
93.6
95.5
104
Anthracene-d10
1719-06-8
0.1
%
103
86.2
91.5
97.4
94.5
4-Terphenyl-d14
1718-51-0
0.1
%
115
111
94.8
108
122
17060-07-0
0.1
%
99.3
110
90.3
----
113
2037-26-5
0.1
%
123
102
98.0
----
106
460-00-4
0.1
%
117
112
104
----
114
Compound
CAS Number
EP075(SIM)S: Phenolic Compound Surrogates - Continued 2.4.6-Tribromophenol
EP075(SIM)T: PAH Surrogates
EP080S: TPH(V)/BTEX Surrogates 1.2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene
Page Work Order Client Project
: : : :
36 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP6 (1.9-2.0)
TP7 (0-0.1)
TP7 (0.9-1.0)
TP7 (2.0-2.1)
TP8 (0.2-0.3)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-028
EM1008731-030
EM1008731-031
EM1008731-033
EM1008731-034
1.0
%
32.2
16.0
17.4
26.2
23.8
EA055: Moisture Content ----
^ Moisture Content (dried @ 103째C)
EG005T: Total Metals by ICP-AES Arsenic
7440-38-2
5
mg/kg
----
----
----
7440-43-9
1
mg/kg
----
----
16 <1
----
Cadmium
----
----
Copper
7440-50-8
5
mg/kg
----
----
22
----
----
Lead
7439-92-1
5
mg/kg
----
----
29
----
----
Molybdenum
7439-98-7
2
mg/kg
----
----
<2
----
----
Nickel
7440-02-0
2
mg/kg
----
----
39
----
----
Selenium
7782-49-2
5
mg/kg
----
----
<5
----
----
Silver
7440-22-4
2
mg/kg
----
----
<2
----
----
Tin
7440-31-5
5
mg/kg
----
----
13
----
----
Zinc
7440-66-6
5
mg/kg
----
----
58
----
----
Arsenic
7440-38-2
5
mg/kg
55
101
----
406
23
Cadmium
7440-43-9
1
mg/kg
<1
1
----
<1
1
Chromium
7440-47-3
2
mg/kg
31
37
----
28
22
Copper
7440-50-8
5
mg/kg
38
230
----
40
80
Lead
7439-92-1
5
mg/kg
90
190
----
198
358
Nickel
7440-02-0
2
mg/kg
28
47
----
53
17
Zinc
7440-66-6
5
mg/kg
251
307
----
122
114
7439-97-6
0.1
mg/kg
0.2
0.5
0.1
0.8
1.7
0.5
mg/kg
----
----
<0.5
----
----
57-12-5
1
mg/kg
----
----
<1
----
----
16984-48-8
40
mg/kg
----
----
180
----
----
----
0.10
mg/kg
----
----
<0.50
----
----
Benzene
71-43-2
0.2
mg/kg
----
----
<0.2
----
----
Toluene
108-88-3
0.5
mg/kg
----
----
<0.5
----
----
Ethylbenzene
100-41-4
0.5
mg/kg
----
----
<0.5
----
----
108-38-3 106-42-3
0.5
mg/kg
----
----
<0.5
----
----
100-42-5
0.5
mg/kg
----
----
<0.5
----
----
95-47-6
0.5
mg/kg
----
----
<0.5
----
----
EG035T: Total Recoverable Mercury by FIMS Mercury
EG048: Hexavalent Chromium (Alkaline Digest) Hexavalent Chromium
18540-29-9
EK026G: Total Cyanide By Discrete Analyser Total Cyanide
EK040T: Fluoride Total Fluoride
EP066: Polychlorinated Biphenyls (PCB) Total Polychlorinated biphenyls
EP074A: Monocyclic Aromatic Hydrocarbons
meta- & para-Xylene Styrene ortho-Xylene
Page Work Order Client Project
: : : :
37 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP6 (1.9-2.0)
TP7 (0-0.1)
TP7 (0.9-1.0)
TP7 (2.0-2.1)
TP8 (0.2-0.3)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-028
EM1008731-030
EM1008731-031
EM1008731-033
EM1008731-034
----
0.2
mg/kg
----
----
<0.2
----
----
----
0.2
mg/kg
----
----
<0.2
----
----
Vinyl chloride
75-01-4
0.02
mg/kg
----
----
<0.02
----
----
1.1-Dichloroethene
75-35-4
0.01
mg/kg
----
----
<0.01
----
----
Methylene chloride
75-09-2
0.4
mg/kg
----
----
<0.6
----
----
trans-1.2-Dichloroethene
156-60-5
0.02
mg/kg
----
----
<0.02
----
----
cis-1.2-Dichloroethene
156-59-2
0.01
mg/kg
----
----
<0.01
----
----
Chloroform
67-66-3
0.02
mg/kg
----
----
<0.02
----
----
1.1.1-Trichloroethane
71-55-6
0.01
mg/kg
----
----
<0.01
----
----
Carbon Tetrachloride
56-23-5
0.01
mg/kg
----
----
<0.01
----
----
107-06-2
0.02
mg/kg
----
----
<0.02
----
----
Trichloroethene
79-01-6
0.02
mg/kg
----
----
<0.02
----
----
1.1.2-Trichloroethane
79-00-5
0.04
mg/kg
----
----
<0.04
----
----
Tetrachloroethene
127-18-4
0.02
mg/kg
----
----
<0.02
----
----
1.1.1.2-Tetrachloroethane
630-20-6
0.01
mg/kg
----
----
<0.01
----
----
1.1.2.2-Tetrachloroethane
79-34-5
0.02
mg/kg
----
----
<0.02
----
----
Hexachlorobutadiene
87-68-3
0.02
mg/kg
----
----
<0.02
----
----
Chlorobenzene
108-90-7
0.02
mg/kg
----
----
<0.02
----
----
1.4-Dichlorobenzene
106-46-7
0.02
mg/kg
----
----
<0.02
----
----
1.2-Dichlorobenzene
95-50-1
0.02
mg/kg
----
----
<0.02
----
----
120-82-1
0.01
mg/kg
----
----
<0.01
----
----
----
0.01
mg/kg
----
----
<0.01
----
----
----
0.01
mg/kg
----
----
<0.01
----
----
----
0.01
mg/kg
----
----
<0.01
----
----
----
0.01
mg/kg
----
----
<0.01
----
----
1330-20-7
0.50
mg/kg
----
----
<0.50
----
----
Compound
CAS Number
EP074A: Monocyclic Aromatic Hydrocarbons - Continued ^ Sum of monocyclic aromatic hydrocarbons ^ Sum of monocyclic aromatic hydrocarbons
EP074I: Volatile Halogenated Compounds
1.2-Dichloroethane
1.2.4-Trichlorobenzene ^ Sum of volatile chlorinated hydrocarbons ^ Sum of other chlorinated hydrocarbons (VIC EPA 448.3) ^ Sum of volatile chlorinated hydrocarbons ^ Sum of other chlorinated hydrocarbons (VIC EPA 448.3) ^ Total Xylenes
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons 91-20-3
0.5
mg/kg
----
----
----
<0.5
----
208-96-8
0.5
mg/kg
----
----
----
<0.5
----
Acenaphthene
83-32-9
0.5
mg/kg
----
----
----
<0.5
----
Fluorene
86-73-7
0.5
mg/kg
----
----
----
<0.5
----
Naphthalene Acenaphthylene
Page Work Order Client Project
: : : :
38 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
TP6 (1.9-2.0)
TP7 (0-0.1)
TP7 (0.9-1.0)
TP7 (2.0-2.1)
TP8 (0.2-0.3)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
Unit
EM1008731-028
EM1008731-030
EM1008731-031
EM1008731-033
EM1008731-034
Client sampling date / time Compound
CAS Number
LOR
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons - Continued 85-01-8
0.5
mg/kg
----
----
----
120-12-7
0.5
mg/kg
----
----
----
0.5 <0.5
----
Anthracene Fluoranthene
206-44-0
0.5
mg/kg
----
----
----
1.3
----
Pyrene
129-00-0
0.5
mg/kg
----
----
----
1.4
----
56-55-3
0.5
mg/kg
----
----
----
0.7
----
Chrysene
218-01-9
0.5
mg/kg
----
----
----
0.6
----
Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
----
----
----
0.7
----
Benzo(k)fluoranthene
207-08-9
0.5
mg/kg
----
----
----
<0.5
----
50-32-8
0.5
mg/kg
----
----
----
0.6
----
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
----
----
----
<0.5
----
Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
----
----
----
<0.5
----
191-24-2
0.5
mg/kg
----
----
----
<0.5
----
Phenanthrene
Benz(a)anthracene
Benzo(a)pyrene
Benzo(g.h.i)perylene
----
EP075A: Phenolic Compounds (Halogenated) 95-57-8
0.03
mg/kg
----
----
<0.06
----
----
2.4-Dichlorophenol
120-83-2
0.03
mg/kg
----
----
<0.06
----
----
2.6-Dichlorophenol
87-65-0
0.03
mg/kg
----
----
<0.06
----
----
4-Chloro-3-Methylphenol
59-50-7
0.03
mg/kg
----
----
<0.06
----
----
2.4.5-Trichlorophenol
95-95-4
0.05
mg/kg
----
----
<0.06
----
----
2.4.6-Trichlorophenol
88-06-2
0.05
mg/kg
----
----
<0.06
----
----
935-95-5
0.03
mg/kg
----
----
<0.06
----
----
4901-51-3/58-90-2
0.05
mg/kg
----
----
<0.12
----
----
87-86-5
0.2
mg/kg
----
----
<0.2
----
----
----
0.03
mg/kg
----
----
<0.06
----
----
108-95-2
1
mg/kg
----
----
<1
----
----
95-48-7
1
mg/kg
----
----
<1
----
----
1319-77-3
1
mg/kg
----
----
<1
----
----
88-75-5
1
mg/kg
----
----
<1
----
----
105-67-9
1
mg/kg
----
----
<1
----
----
51-28-5
5
mg/kg
----
----
<5
----
----
100-02-7
5
mg/kg
----
----
<5
----
----
8071-51-0
5
mg/kg
----
----
<5
----
----
88-85-7
5
mg/kg
----
----
<5
----
----
131-89-5
5
mg/kg
----
----
<5
----
----
----
1
mg/kg
----
----
<1
----
----
0.5
mg/kg
----
----
<0.5
----
----
2-Chlorophenol
2.3.5.6-Tetrachlorophenol 2.3.4.5 & 2.3.4.6-Tetrachlorophenol Pentachlorophenol ^ Sum of Phenols (halogenated)
EP075A: Phenolic Compounds (Non-halogenated) Phenol 2-Methylphenol 3- & 4-Methylphenol 2-Nitrophenol 2.4-Dimethylphenol 2.4-Dinitrophenol 4-Nitrophenol 2-Methyl-4.6-dinitrophenol Dinoseb 2-Cyclohexyl-4.6-Dinitrophenol ^ Sum of Phenols (non-halogenated)
EP075B: Polynuclear Aromatic Hydrocarbons Naphthalene
91-20-3
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: : : :
39 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP6 (1.9-2.0)
TP7 (0-0.1)
TP7 (0.9-1.0)
TP7 (2.0-2.1)
TP8 (0.2-0.3)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-028
EM1008731-030
EM1008731-031
EM1008731-033
EM1008731-034
EP075B: Polynuclear Aromatic Hydrocarbons - Continued 83-32-9
0.5
mg/kg
----
----
<0.5
----
----
208-96-8
0.5
mg/kg
----
----
<0.5
----
----
Fluorene
86-73-7
0.5
mg/kg
----
----
<0.5
----
----
Phenanthrene
85-01-8
0.5
mg/kg
----
----
<0.5
----
----
Anthracene
120-12-7
0.5
mg/kg
----
----
<0.5
----
----
Fluoranthene
206-44-0
0.5
mg/kg
----
----
<0.5
----
----
Pyrene
129-00-0
0.5
mg/kg
----
----
<0.5
----
----
56-55-3
0.5
mg/kg
----
----
<0.5
----
----
218-01-9
0.5
mg/kg
----
----
<0.5
----
----
205-99-2 207-08-9
0.5
mg/kg
----
----
<0.5
----
----
Acenaphthene Acenaphthylene
Benz(a)anthracene Chrysene Benzo(b) & Benzo(k)fluoranthene Benzo(a)pyrene
50-32-8
0.5
mg/kg
----
----
<0.5
----
----
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
----
----
<0.5
----
----
Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
----
----
<0.5
----
----
191-24-2
0.5
mg/kg
----
----
<0.5
----
----
----
0.5
mg/kg
----
----
<0.5
----
----
alpha-BHC
319-84-6
0.03
mg/kg
----
----
<0.06
----
----
Hexachlorobenzene (HCB)
118-74-1
0.03
mg/kg
----
----
<0.06
----
----
beta-BHC
319-85-7
0.03
mg/kg
----
----
<0.06
----
----
58-89-9
0.03
mg/kg
----
----
<0.06
----
----
delta-BHC
319-86-8
0.03
mg/kg
----
----
<0.06
----
----
Heptachlor
76-44-8
0.03
mg/kg
----
----
<0.06
----
----
309-00-2
0.03
mg/kg
----
----
<0.06
----
----
Heptachlor epoxide
1024-57-3
0.03
mg/kg
----
----
<0.06
----
----
cis-Chlordane
5103-71-9
0.03
mg/kg
----
----
<0.06
----
----
trans-Chlordane
5103-74-2
0.03
mg/kg
----
----
<0.06
----
----
959-98-8
0.03
mg/kg
----
----
<0.06
----
----
4.4`-DDE
72-55-9
0.05
mg/kg
----
----
<0.06
----
----
Dieldrin
60-57-1
0.03
mg/kg
----
----
<0.06
----
----
7421-93-4
0.03
mg/kg
----
----
<0.06
----
----
72-20-8
0.03
mg/kg
----
----
<0.06
----
----
33213-65-9
0.03
mg/kg
----
----
<0.06
----
----
72-54-8
0.05
mg/kg
----
----
<0.06
----
----
1031-07-8
0.03
mg/kg
----
----
<0.06
----
----
4.4`-DDT
50-29-3
0.05
mg/kg
----
----
<0.06
----
----
Methoxychlor
72-43-5
0.03
mg/kg
----
----
<0.06
----
----
Benzo(g.h.i)perylene ^ Sum of polycyclic aromatic hydrocarbons
EP075I: Organochlorine Pesticides
gamma-BHC
Aldrin
Endosulfan 1
Endrin aldehyde Endrin Endosulfan 2 4.4`-DDD Endosulfan sulfate
Page Work Order Client Project
: : : :
40 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP6 (1.9-2.0)
TP7 (0-0.1)
TP7 (0.9-1.0)
TP7 (2.0-2.1)
TP8 (0.2-0.3)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-028
EM1008731-030
EM1008731-031
EM1008731-033
EM1008731-034
EP075I: Organochlorine Pesticides - Continued ----
0.03
mg/kg
----
----
<0.06
----
----
309-00-2/60-57-1
0.03
mg/kg
----
----
<0.06
----
----
----
0.05
mg/kg
----
----
<0.06
----
----
57-74-9
0.03
mg/kg
----
----
<0.06
----
----
----
0.03
mg/kg
----
----
<0.06
----
----
C6 - C9 Fraction
----
10
mg/kg
----
----
<10
----
----
C6 - C9 Fraction
----
10
mg/kg
----
----
----
<10
----
C10 - C14 Fraction
----
50
mg/kg
----
----
<50
<50
----
C15 - C28 Fraction
----
100
mg/kg
----
----
<100
<100
----
C29 - C36 Fraction
----
100
mg/kg
----
----
<100
<100
----
^ C10 - C36 Fraction (sum)
----
50
mg/kg
----
----
<50
<50
----
Benzene
71-43-2
0.2
mg/kg
----
----
----
<0.2
----
Toluene
108-88-3
0.5
mg/kg
----
----
----
<0.5
----
Ethylbenzene
100-41-4
0.5
mg/kg
----
----
----
<0.5
----
108-38-3 106-42-3
0.5
mg/kg
----
----
----
<0.5
----
95-47-6
0.5
mg/kg
----
----
----
<0.5
----
2051-24-3
0.1
%
----
----
87.0
----
----
17060-07-0
0.1
%
----
----
116
----
----
2037-26-5
0.1
%
----
----
104
----
----
460-00-4
0.1
%
----
----
116
----
----
Phenol-d6
13127-88-3
0.1
%
----
----
----
65.1
----
2-Chlorophenol-D4
93951-73-6
0.1
%
----
----
----
104
----
118-79-6
0.1
%
----
----
----
107
----
2-Fluorobiphenyl
321-60-8
0.1
%
----
----
----
93.7
----
Anthracene-d10
1719-06-8
0.1
%
----
----
----
88.0
----
4-Terphenyl-d14
1718-51-0
0.1
%
----
----
----
108
----
^ Sum of organochlorine pesticides ^ Sum of Aldrin + Dieldrin ^ Sum of DDD + DDE + DDT ^ Chlordane ^ Sum of other organochlorine pesticides
EP080/071: Total Petroleum Hydrocarbons
EP080: BTEX
meta- & para-Xylene ortho-Xylene
EP066S: PCB Surrogate Decachlorobiphenyl
EP074S: VOC Surrogates 1.2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene
EP075(SIM)S: Phenolic Compound Surrogates
2.4.6-Tribromophenol
EP075(SIM)T: PAH Surrogates
EP075S: Acid Extractable Surrogates 367-12-4
0.1
%
----
----
92.5
----
----
Phenol-d6
13127-88-3
0.1
%
----
----
88.2
----
----
2-Chlorophenol-D4
93951-73-6
0.1
%
----
----
89.1
----
----
2-Fluorophenol
Page Work Order Client Project
: : : :
41 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP6 (1.9-2.0)
TP7 (0-0.1)
TP7 (0.9-1.0)
TP7 (2.0-2.1)
TP8 (0.2-0.3)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-028
EM1008731-030
EM1008731-031
EM1008731-033
EM1008731-034
118-79-6
0.1
%
----
----
65.8
----
----
Nitrobenzene-D5
4165-60-0
0.1
%
----
----
99.6
----
----
1.2-Dichlorobenzene-D4
2199-69-1
0.1
%
----
----
91.4
----
----
2-Fluorobiphenyl
321-60-8
0.1
%
----
----
97.7
----
----
Anthracene-d10
1719-06-8
0.1
%
----
----
110
----
----
4-Terphenyl-d14
1718-51-0
0.1
%
----
----
102
----
----
17060-07-0
0.1
%
----
----
----
89.8
----
2037-26-5
0.1
%
----
----
----
98.8
----
460-00-4
0.1
%
----
----
----
108
----
Compound
CAS Number
EP075S: Acid Extractable Surrogates - Continued 2.4.6-Tribromophenol
EP075T: Base/Neutral Extractable Surrogates
EP080S: TPH(V)/BTEX Surrogates 1.2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene
Page Work Order Client Project
: : : :
42 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP8 (0.9-1.0)
TP8 (1.9-2.0)
TP8 (2.4-2.5)
TP8 (2.9-3.0)
TP9 (0.4-0.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-035
EM1008731-036
EM1008731-037
EM1008731-038
EM1008731-039
1.0
%
13.6
27.1
35.5
40.3
26.9
174
----
2
----
14 <1
6 <1
EA055: Moisture Content ----
^ Moisture Content (dried @ 103째C)
EG005T: Total Metals by ICP-AES Arsenic
7440-38-2
5
mg/kg
Cadmium
7440-43-9
1
mg/kg
9 <1
Chromium
7440-47-3
2
mg/kg
24
59
----
44
45
Copper
7440-50-8
5
mg/kg
28
132
----
12
59
Lead
7439-92-1
5
mg/kg
26
144
----
21
34
Nickel
7440-02-0
2
mg/kg
25
94
----
24
75
Zinc
7440-66-6
5
mg/kg
45
614
----
75
48
7439-97-6
0.1
mg/kg
0.1
0.2
----
<0.1
<0.1
----
1
mg/kg
<1
----
----
----
----
57-12-5
1
mg/kg
22
----
----
----
----
EG035T: Total Recoverable Mercury by FIMS Mercury
EK025G: Free cyanide by Discrete Analyser Free Cyanide
EK026G: Total Cyanide By Discrete Analyser Total Cyanide
EP075(SIM)A: Phenolic Compounds 108-95-2
0.5
mg/kg
----
----
<0.5
----
----
2-Chlorophenol
95-57-8
0.5
mg/kg
----
----
<0.5
----
----
2-Methylphenol
95-48-7
0.5
mg/kg
----
----
<0.5
----
----
1319-77-3
1.0
mg/kg
----
----
<1.0
----
----
88-75-5
0.5
mg/kg
----
----
<0.5
----
----
2.4-Dimethylphenol
105-67-9
0.5
mg/kg
----
----
<0.5
----
----
2.4-Dichlorophenol
120-83-2
0.5
mg/kg
----
----
<0.5
----
----
2.6-Dichlorophenol
87-65-0
0.5
mg/kg
----
----
<0.5
----
----
4-Chloro-3-Methylphenol
59-50-7
0.5
mg/kg
----
----
<0.5
----
----
2.4.6-Trichlorophenol
88-06-2
0.5
mg/kg
----
----
<0.5
----
----
2.4.5-Trichlorophenol
95-95-4
0.5
mg/kg
----
----
<0.5
----
----
Pentachlorophenol
87-86-5
2.0
mg/kg
----
----
<2.0
----
----
Phenol
3- & 4-Methylphenol 2-Nitrophenol
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons 91-20-3
0.5
mg/kg
<0.5
<0.5
----
----
----
208-96-8
0.5
mg/kg
<0.5
<0.5
----
----
----
Acenaphthene
83-32-9
0.5
mg/kg
<0.5
<0.5
----
----
----
Fluorene
86-73-7
0.5
mg/kg
<0.5
<0.5
----
----
----
Phenanthrene
85-01-8
0.5
mg/kg
1.7
<0.5
----
----
----
Anthracene
120-12-7
0.5
mg/kg
<0.5
<0.5
----
----
----
Fluoranthene
206-44-0
0.5
mg/kg
3.9
<0.5
----
----
----
Pyrene
129-00-0
0.5
mg/kg
3.6
<0.5
----
----
----
Naphthalene Acenaphthylene
Page Work Order Client Project
: : : :
43 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
TP8 (0.9-1.0)
TP8 (1.9-2.0)
TP8 (2.4-2.5)
TP8 (2.9-3.0)
TP9 (0.4-0.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
Unit
EM1008731-035
EM1008731-036
EM1008731-037
EM1008731-038
EM1008731-039
Client sampling date / time Compound
CAS Number
LOR
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons - Continued 56-55-3
0.5
mg/kg
2.1
<0.5
----
----
----
Chrysene
218-01-9
0.5
mg/kg
1.8
<0.5
----
----
----
Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
2.2
<0.5
----
----
----
Benzo(k)fluoranthene
207-08-9
0.5
mg/kg
0.8
<0.5
----
----
----
50-32-8
0.5
mg/kg
1.6
<0.5
----
----
----
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
0.9
<0.5
----
----
----
Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
<0.5
<0.5
----
----
----
191-24-2
0.5
mg/kg
1.0
<0.5
----
----
----
C6 - C9 Fraction
----
10
mg/kg
<10
<10
----
----
----
C10 - C14 Fraction
----
50
mg/kg
<50
<50
----
----
----
C15 - C28 Fraction
----
100
mg/kg
<100
<100
----
----
----
C29 - C36 Fraction
----
100
mg/kg
<100
140
----
----
----
^ C10 - C36 Fraction (sum)
----
50
mg/kg
<50
140
----
----
----
Benzene
71-43-2
0.2
mg/kg
<0.2
<0.2
----
----
----
Toluene
108-88-3
0.5
mg/kg
<0.5
<0.5
----
----
----
Ethylbenzene
100-41-4
0.5
mg/kg
<0.5
<0.5
----
----
----
108-38-3 106-42-3
0.5
mg/kg
<0.5
<0.5
----
----
----
95-47-6
0.5
mg/kg
<0.5
<0.5
----
----
----
Phenol-d6
13127-88-3
0.1
%
64.9
95.6
94.1
----
----
2-Chlorophenol-D4
93951-73-6
0.1
%
104
78.1
94.2
----
----
118-79-6
0.1
%
110
79.3
82.0
----
----
2-Fluorobiphenyl
321-60-8
0.1
%
93.5
99.7
106
----
----
Anthracene-d10
1719-06-8
0.1
%
93.3
100
96.5
----
----
4-Terphenyl-d14
1718-51-0
0.1
%
104
94.7
101
----
----
17060-07-0
0.1
%
113
90.3
----
----
----
2037-26-5
0.1
%
102
96.6
----
----
----
460-00-4
0.1
%
112
106
----
----
----
Benz(a)anthracene
Benzo(a)pyrene
Benzo(g.h.i)perylene
EP080/071: Total Petroleum Hydrocarbons
EP080: BTEX
meta- & para-Xylene ortho-Xylene
EP075(SIM)S: Phenolic Compound Surrogates
2.4.6-Tribromophenol
EP075(SIM)T: PAH Surrogates
EP080S: TPH(V)/BTEX Surrogates 1.2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene
Page Work Order Client Project
: : : :
44 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP9 (0.9-1.0)
TP9 (1.9-2.0)
TP9 (2.0-2.1)
TP9B (2.5-2.6)
TP10 (0.1-0.2)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-040
EM1008731-041
EM1008731-042
EM1008731-043
EM1008731-044
1.0
%
38.5
26.0
43.5
46.4
21.9
EA055: Moisture Content ----
^ Moisture Content (dried @ 103째C)
EG005T: Total Metals by ICP-AES Arsenic
7440-38-2
5
mg/kg
----
----
----
7440-43-9
1
mg/kg
----
19 <1
----
Cadmium
----
----
----
Copper
7440-50-8
5
mg/kg
----
484
----
----
----
Lead
7439-92-1
5
mg/kg
----
43
----
----
----
Molybdenum
7439-98-7
2
mg/kg
----
10
----
----
----
Nickel
7440-02-0
2
mg/kg
----
54
----
----
----
Selenium
7782-49-2
5
mg/kg
----
<5
----
----
----
Silver
7440-22-4
2
mg/kg
----
<2
----
----
----
Tin
7440-31-5
5
mg/kg
----
<5
----
----
----
Zinc
7440-66-6
5
mg/kg
----
175
----
----
----
Arsenic
7440-38-2
5
mg/kg
20
----
----
278
48
Cadmium
7440-43-9
1
mg/kg
<1
----
----
10
1
Chromium
7440-47-3
2
mg/kg
12
----
----
188
43
Copper
7440-50-8
5
mg/kg
157
----
----
255
377
Lead
7439-92-1
5
mg/kg
34
----
----
773
144
Nickel
7440-02-0
2
mg/kg
80
----
----
79
56
Zinc
7440-66-6
5
mg/kg
76
----
----
1810
288
7439-97-6
0.1
mg/kg
0.1
0.1
----
1.8
0.3
0.5
mg/kg
----
<0.5
----
----
----
57-12-5
1
mg/kg
----
<1
----
----
----
16984-48-8
40
mg/kg
----
50
----
----
----
----
0.10
mg/kg
----
<5.00
----
----
----
Benzene
71-43-2
0.2
mg/kg
----
<0.2
----
----
----
Toluene
108-88-3
0.5
mg/kg
----
<0.5
----
----
----
Ethylbenzene
100-41-4
0.5
mg/kg
----
<0.5
----
----
----
108-38-3 106-42-3
0.5
mg/kg
----
<0.5
----
----
----
100-42-5
0.5
mg/kg
----
<0.5
----
----
----
95-47-6
0.5
mg/kg
----
<0.5
----
----
----
EG035T: Total Recoverable Mercury by FIMS Mercury
EG048: Hexavalent Chromium (Alkaline Digest) Hexavalent Chromium
18540-29-9
EK026G: Total Cyanide By Discrete Analyser Total Cyanide
EK040T: Fluoride Total Fluoride
EP066: Polychlorinated Biphenyls (PCB) Total Polychlorinated biphenyls
EP074A: Monocyclic Aromatic Hydrocarbons
meta- & para-Xylene Styrene ortho-Xylene
Page Work Order Client Project
: : : :
45 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP9 (0.9-1.0)
TP9 (1.9-2.0)
TP9 (2.0-2.1)
TP9B (2.5-2.6)
TP10 (0.1-0.2)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-040
EM1008731-041
EM1008731-042
EM1008731-043
EM1008731-044
----
0.2
mg/kg
----
<0.2
----
----
----
----
0.2
mg/kg
----
<0.2
----
----
----
Vinyl chloride
75-01-4
0.02
mg/kg
----
<0.02
----
----
----
1.1-Dichloroethene
75-35-4
0.01
mg/kg
----
<0.01
----
----
----
Methylene chloride
75-09-2
0.4
mg/kg
----
<0.6
----
----
----
trans-1.2-Dichloroethene
156-60-5
0.02
mg/kg
----
<0.02
----
----
----
cis-1.2-Dichloroethene
156-59-2
0.01
mg/kg
----
<0.01
----
----
----
Chloroform
67-66-3
0.02
mg/kg
----
<0.02
----
----
----
1.1.1-Trichloroethane
71-55-6
0.01
mg/kg
----
<0.01
----
----
----
Carbon Tetrachloride
56-23-5
0.01
mg/kg
----
<0.01
----
----
----
107-06-2
0.02
mg/kg
----
<0.02
----
----
----
Trichloroethene
79-01-6
0.02
mg/kg
----
<0.02
----
----
----
1.1.2-Trichloroethane
79-00-5
0.04
mg/kg
----
<0.04
----
----
----
Tetrachloroethene
127-18-4
0.02
mg/kg
----
<0.02
----
----
----
1.1.1.2-Tetrachloroethane
630-20-6
0.01
mg/kg
----
<0.01
----
----
----
1.1.2.2-Tetrachloroethane
79-34-5
0.02
mg/kg
----
<0.02
----
----
----
Hexachlorobutadiene
87-68-3
0.02
mg/kg
----
<0.02
----
----
----
Chlorobenzene
108-90-7
0.02
mg/kg
----
<0.02
----
----
----
1.4-Dichlorobenzene
106-46-7
0.02
mg/kg
----
<0.02
----
----
----
1.2-Dichlorobenzene
95-50-1
0.02
mg/kg
----
<0.02
----
----
----
120-82-1
0.01
mg/kg
----
<0.01
----
----
----
----
0.01
mg/kg
----
<0.01
----
----
----
----
0.01
mg/kg
----
<0.01
----
----
----
----
0.01
mg/kg
----
<0.01
----
----
----
----
0.01
mg/kg
----
<0.01
----
----
----
1330-20-7
0.50
mg/kg
----
<0.50
----
----
----
Compound
CAS Number
EP074A: Monocyclic Aromatic Hydrocarbons - Continued ^ Sum of monocyclic aromatic hydrocarbons ^ Sum of monocyclic aromatic hydrocarbons
EP074I: Volatile Halogenated Compounds
1.2-Dichloroethane
1.2.4-Trichlorobenzene ^ Sum of volatile chlorinated hydrocarbons ^ Sum of other chlorinated hydrocarbons (VIC EPA 448.3) ^ Sum of volatile chlorinated hydrocarbons ^ Sum of other chlorinated hydrocarbons (VIC EPA 448.3) ^ Total Xylenes
EP075(SIM)A: Phenolic Compounds 108-95-2
0.5
mg/kg
----
----
<2.5
<0.5
----
2-Chlorophenol
95-57-8
0.5
mg/kg
----
----
<2.5
<0.5
----
2-Methylphenol
95-48-7
0.5
mg/kg
----
----
<2.5
<0.5
----
1319-77-3
1.0
mg/kg
----
----
<5.0
<1.0
----
Phenol
3- & 4-Methylphenol
Page Work Order Client Project
: : : :
46 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP9 (0.9-1.0)
TP9 (1.9-2.0)
TP9 (2.0-2.1)
TP9B (2.5-2.6)
TP10 (0.1-0.2)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-040
EM1008731-041
EM1008731-042
EM1008731-043
EM1008731-044
EP075(SIM)A: Phenolic Compounds - Continued 88-75-5
0.5
mg/kg
----
----
<2.5
<0.5
----
2.4-Dimethylphenol
105-67-9
0.5
mg/kg
----
----
<2.5
<0.5
----
2.4-Dichlorophenol
120-83-2
0.5
mg/kg
----
----
<2.5
<0.5
----
2.6-Dichlorophenol
87-65-0
0.5
mg/kg
----
----
<2.5
<0.5
----
4-Chloro-3-Methylphenol
59-50-7
0.5
mg/kg
----
----
<2.5
<0.5
----
2.4.6-Trichlorophenol
88-06-2
0.5
mg/kg
----
----
<2.5
<0.5
----
2.4.5-Trichlorophenol
95-95-4
0.5
mg/kg
----
----
<2.5
<0.5
----
Pentachlorophenol
87-86-5
2.0
mg/kg
----
----
<10.0
<2.0
----
2-Nitrophenol
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons 91-20-3
0.5
mg/kg
<2.5
<0.5
----
0.5
mg/kg
5.0 <0.5
----
208-96-8
----
----
----
----
83-32-9
0.5
mg/kg
<0.5
----
----
----
----
208-96-8
0.5
mg/kg
----
----
<2.5
<0.5
----
Acenaphthene
83-32-9
0.5
mg/kg
----
----
4.2
<0.5
----
Fluorene
86-73-7
0.5
mg/kg
<0.5
----
----
----
----
Fluorene
86-73-7
0.5
mg/kg
----
----
3.1
<0.5
----
Phenanthrene
85-01-8
0.5
mg/kg
<0.5
----
----
----
----
120-12-7
0.5
mg/kg
<0.5
----
----
----
----
85-01-8
0.5
mg/kg
----
----
8.8
<0.5
----
Anthracene
120-12-7
0.5
mg/kg
----
----
13.0
<0.5
----
Fluoranthene
206-44-0
0.5
mg/kg
<0.5
----
----
----
----
Fluoranthene
206-44-0
0.5
mg/kg
----
----
40.4
1.0
----
Pyrene
129-00-0
0.5
mg/kg
<0.5
----
----
----
----
56-55-3
0.5
mg/kg
<0.5
----
----
----
----
129-00-0
0.5
mg/kg
----
----
37.2
1.4
----
56-55-3
0.5
mg/kg
----
----
13.1
0.7
----
Chrysene
218-01-9
0.5
mg/kg
<0.5
----
----
----
----
Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
<0.5
----
----
----
----
Chrysene
218-01-9
0.5
mg/kg
----
----
15.1
0.8
----
Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
----
----
10.2
1.0
----
Benzo(k)fluoranthene
207-08-9
0.5
mg/kg
<0.5
----
----
----
----
50-32-8
0.5
mg/kg
<0.5
----
----
----
----
207-08-9
0.5
mg/kg
----
----
2.8
<0.5
----
50-32-8
0.5
mg/kg
----
----
6.0
0.7
----
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
<0.5
----
----
----
----
Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
<0.5
----
----
----
----
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
----
----
3.5
0.7
----
Benzo(g.h.i)perylene
191-24-2
0.5
mg/kg
<0.5
----
----
----
----
Naphthalene Acenaphthylene Acenaphthene Acenaphthylene
Anthracene Phenanthrene
Benz(a)anthracene Pyrene Benz(a)anthracene
Benzo(a)pyrene Benzo(k)fluoranthene Benzo(a)pyrene
Page Work Order Client Project
: : : :
47 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
TP9 (0.9-1.0)
TP9 (1.9-2.0)
TP9 (2.0-2.1)
TP9B (2.5-2.6)
TP10 (0.1-0.2)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
Unit
EM1008731-040
EM1008731-041
EM1008731-042
EM1008731-043
EM1008731-044
Client sampling date / time Compound
CAS Number
LOR
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons - Continued Dibenz(a.h)anthracene Benzo(g.h.i)perylene
53-70-3
0.5
mg/kg
----
----
<2.5
<0.5
----
191-24-2
0.5
mg/kg
----
----
4.8
0.9
----
EP075A: Phenolic Compounds (Halogenated) 95-57-8
0.03
mg/kg
----
<0.60
----
----
----
2.4-Dichlorophenol
120-83-2
0.03
mg/kg
----
<0.60
----
----
----
2.6-Dichlorophenol
87-65-0
0.03
mg/kg
----
<0.60
----
----
----
4-Chloro-3-Methylphenol
59-50-7
0.03
mg/kg
----
<0.60
----
----
----
2.4.5-Trichlorophenol
95-95-4
0.05
mg/kg
----
<0.60
----
----
----
2.4.6-Trichlorophenol
88-06-2
0.05
mg/kg
----
<0.60
----
----
----
935-95-5
0.03
mg/kg
----
<0.60
----
----
----
4901-51-3/58-90-2
0.05
mg/kg
----
<1.19
----
----
----
87-86-5
0.2
mg/kg
----
<0.6
----
----
----
----
0.03
mg/kg
----
<0.60
----
----
----
108-95-2
1
mg/kg
----
<1
----
----
----
95-48-7
1
mg/kg
----
<1
----
----
----
1319-77-3
1
mg/kg
----
<1
----
----
----
88-75-5
1
mg/kg
----
<1
----
----
----
105-67-9
1
mg/kg
----
<1
----
----
----
51-28-5
5
mg/kg
----
<48
----
----
----
100-02-7
5
mg/kg
----
<48
----
----
----
8071-51-0
5
mg/kg
----
<48
----
----
----
88-85-7
5
mg/kg
----
<48
----
----
----
131-89-5
5
mg/kg
----
<48
----
----
----
----
1
mg/kg
----
<1
----
----
----
2-Chlorophenol
2.3.5.6-Tetrachlorophenol 2.3.4.5 & 2.3.4.6-Tetrachlorophenol Pentachlorophenol ^ Sum of Phenols (halogenated)
EP075A: Phenolic Compounds (Non-halogenated) Phenol 2-Methylphenol 3- & 4-Methylphenol 2-Nitrophenol 2.4-Dimethylphenol 2.4-Dinitrophenol 4-Nitrophenol 2-Methyl-4.6-dinitrophenol Dinoseb 2-Cyclohexyl-4.6-Dinitrophenol ^ Sum of Phenols (non-halogenated)
EP075B: Polynuclear Aromatic Hydrocarbons Naphthalene
91-20-3
0.5
mg/kg
----
<0.6
----
----
----
Acenaphthene
83-32-9
0.5
mg/kg
----
<0.6
----
----
----
208-96-8
0.5
mg/kg
----
<0.6
----
----
----
Fluorene
86-73-7
0.5
mg/kg
----
<0.6
----
----
----
Phenanthrene
85-01-8
0.5
mg/kg
----
0.6
----
----
----
Anthracene
120-12-7
0.5
mg/kg
----
<0.6
----
----
----
Fluoranthene
206-44-0
0.5
mg/kg
----
1.9
----
----
----
Pyrene
129-00-0
0.5
mg/kg
----
1.8
----
----
----
56-55-3
0.5
mg/kg
----
0.9
----
----
----
218-01-9
0.5
mg/kg
----
0.7
----
----
----
Acenaphthylene
Benz(a)anthracene Chrysene
Page Work Order Client Project
: : : :
48 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP9 (0.9-1.0)
TP9 (1.9-2.0)
TP9 (2.0-2.1)
TP9B (2.5-2.6)
TP10 (0.1-0.2)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-040
EM1008731-041
EM1008731-042
EM1008731-043
EM1008731-044
205-99-2 207-08-9
0.5
mg/kg
----
1.9
----
----
----
Compound
CAS Number
EP075B: Polynuclear Aromatic Hydrocarbons - Continued Benzo(b) & Benzo(k)fluoranthene Benzo(a)pyrene
50-32-8
0.5
mg/kg
----
1.1
----
----
----
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
----
0.7
----
----
----
Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
----
<0.6
----
----
----
191-24-2
0.5
mg/kg
----
0.9
----
----
----
----
0.5
mg/kg
----
10.5
----
----
----
alpha-BHC
319-84-6
0.03
mg/kg
----
<0.60
----
----
----
Hexachlorobenzene (HCB)
118-74-1
0.03
mg/kg
----
<0.60
----
----
----
beta-BHC
319-85-7
0.03
mg/kg
----
<0.60
----
----
----
58-89-9
0.03
mg/kg
----
<0.60
----
----
----
delta-BHC
319-86-8
0.03
mg/kg
----
<0.60
----
----
----
Heptachlor
76-44-8
0.03
mg/kg
----
<0.60
----
----
----
309-00-2
0.03
mg/kg
----
<0.60
----
----
----
Heptachlor epoxide
1024-57-3
0.03
mg/kg
----
<0.60
----
----
----
cis-Chlordane
5103-71-9
0.03
mg/kg
----
<0.60
----
----
----
trans-Chlordane
5103-74-2
0.03
mg/kg
----
<0.60
----
----
----
959-98-8
0.03
mg/kg
----
<0.60
----
----
----
4.4`-DDE
72-55-9
0.05
mg/kg
----
<0.60
----
----
----
Dieldrin
60-57-1
0.03
mg/kg
----
<0.60
----
----
----
7421-93-4
0.03
mg/kg
----
<0.60
----
----
----
72-20-8
0.03
mg/kg
----
<0.60
----
----
----
33213-65-9
0.03
mg/kg
----
<0.60
----
----
----
72-54-8
0.05
mg/kg
----
<0.60
----
----
----
1031-07-8
0.03
mg/kg
----
<0.60
----
----
----
4.4`-DDT
50-29-3
0.05
mg/kg
----
<0.60
----
----
----
Methoxychlor
72-43-5
0.03
mg/kg
----
<0.60
----
----
----
----
0.03
mg/kg
----
<0.60
----
----
----
309-00-2/60-57-1
0.03
mg/kg
----
<0.60
----
----
----
----
0.05
mg/kg
----
<0.60
----
----
----
57-74-9
0.03
mg/kg
----
<0.60
----
----
----
----
0.03
mg/kg
----
<0.60
----
----
----
C6 - C9 Fraction
----
10
mg/kg
----
<10
----
----
----
C6 - C9 Fraction
----
10
mg/kg
<10
----
106
<10
----
Benzo(g.h.i)perylene ^ Sum of polycyclic aromatic hydrocarbons
EP075I: Organochlorine Pesticides
gamma-BHC
Aldrin
Endosulfan 1
Endrin aldehyde Endrin Endosulfan 2 4.4`-DDD Endosulfan sulfate
^ Sum of organochlorine pesticides ^ Sum of Aldrin + Dieldrin ^ Sum of DDD + DDE + DDT ^ Chlordane ^ Sum of other organochlorine pesticides
EP080/071: Total Petroleum Hydrocarbons
Page Work Order Client Project
: : : :
49 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
LOR
Unit
TP9 (0.9-1.0)
TP9 (1.9-2.0)
TP9 (2.0-2.1)
TP9B (2.5-2.6)
TP10 (0.1-0.2)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
EM1008731-040
EM1008731-041
EM1008731-042
EM1008731-043
EM1008731-044
EP080/071: Total Petroleum Hydrocarbons - Continued C10 - C14 Fraction
----
50
mg/kg
<50
<50
1160
<50
----
C15 - C28 Fraction
----
100
mg/kg
<100
<100
32700
1320
----
C29 - C36 Fraction
----
100
mg/kg
190
<100
48600
1730
----
^ C10 - C36 Fraction (sum)
----
50
mg/kg
190
<50
82500
3050
----
Benzene
71-43-2
0.2
mg/kg
<0.2
<0.2
----
108-88-3
0.5
mg/kg
0.3 <0.5
----
Toluene
----
<0.5
<0.5
----
Ethylbenzene
100-41-4
0.5
mg/kg
<0.5
----
<0.5
<0.5
----
108-38-3 106-42-3
0.5
mg/kg
<0.5
----
<0.5
<0.5
----
95-47-6
0.5
mg/kg
<0.5
----
<0.5
<0.5
----
2051-24-3
0.1
%
----
56.5
----
----
----
17060-07-0
0.1
%
----
109
----
----
----
2037-26-5
0.1
%
----
92.2
----
----
----
460-00-4
0.1
%
----
99.1
----
----
----
Phenol-d6
13127-88-3
0.1
%
49.7
----
79.6
96.1
----
2-Chlorophenol-D4
93951-73-6
0.1
%
43.6
----
102
99.2
----
118-79-6
0.1
%
25.4
----
79.6
92.6
----
2-Fluorobiphenyl
321-60-8
0.1
%
86.0
----
98.7
98.8
----
Anthracene-d10
1719-06-8
0.1
%
33.8
----
101
91.7
----
4-Terphenyl-d14
1718-51-0
0.1
%
54.4
----
103
103
----
EP080: BTEX
meta- & para-Xylene ortho-Xylene
EP066S: PCB Surrogate Decachlorobiphenyl
EP074S: VOC Surrogates 1.2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene
EP075(SIM)S: Phenolic Compound Surrogates
2.4.6-Tribromophenol
EP075(SIM)T: PAH Surrogates
EP075S: Acid Extractable Surrogates 367-12-4
0.1
%
----
Not Determined
----
----
----
Phenol-d6
13127-88-3
0.1
%
----
Not Determined
----
----
----
2-Chlorophenol-D4
93951-73-6
0.1
%
----
Not Determined
----
----
----
118-79-6
0.1
%
----
Not Determined
----
----
----
Nitrobenzene-D5
4165-60-0
0.1
%
----
Not Determined
----
----
----
1.2-Dichlorobenzene-D4
2199-69-1
0.1
%
----
Not Determined
----
----
----
2-Fluorobiphenyl
321-60-8
0.1
%
----
Not Determined
----
----
----
Anthracene-d10
1719-06-8
0.1
%
----
Not Determined
----
----
----
4-Terphenyl-d14
1718-51-0
0.1
%
----
Not Determined
----
----
----
17060-07-0
0.1
%
101
----
82.9
95.3
----
2-Fluorophenol
2.4.6-Tribromophenol
EP075T: Base/Neutral Extractable Surrogates
EP080S: TPH(V)/BTEX Surrogates 1.2-Dichloroethane-D4
Page Work Order Client Project
: : : :
50 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
TP9 (0.9-1.0)
TP9 (1.9-2.0)
TP9 (2.0-2.1)
TP9B (2.5-2.6)
TP10 (0.1-0.2)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-040
EM1008731-041
EM1008731-042
EM1008731-043
EM1008731-044
2037-26-5
0.1
%
32.6
----
103
94.1
----
460-00-4
0.1
%
21.1
----
102
101
----
CAS Number
EP080S: TPH(V)/BTEX Surrogates - Continued Toluene-D8 4-Bromofluorobenzene
Page Work Order Client Project
: : : :
51 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP10 (1.4-1.5)
TP10 (1.9-2.0)
DUP2
TP10 (2.4-2.5)
TP11 (0-0.1)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-046
EM1008731-047
EM1008731-048
EM1008731-049
EM1008731-050
1.0
%
10.5
32.7
29.7
39.6
19.7
EA055: Moisture Content ----
^ Moisture Content (dried @ 103째C)
EG005T: Total Metals by ICP-AES Arsenic
7440-38-2
5
mg/kg
103
33
<5
Cadmium
7440-43-9
1
mg/kg
1
2
<1
9 <1
10 <1
Chromium
7440-47-3
2
mg/kg
30
136
<2
44
26
Copper
7440-50-8
5
mg/kg
1890
641
8
12
66
Lead
7439-92-1
5
mg/kg
325
231
<5
17
514
Nickel
7440-02-0
2
mg/kg
120
70
<2
17
23
Zinc
7440-66-6
5
mg/kg
297
720
6
52
492
7439-97-6
0.1
mg/kg
0.6
0.4
0.5
<0.1
0.2
----
1
mg/kg
<1
<1
<1
----
----
57-12-5
1
mg/kg
<1
2
<1
----
----
EG035T: Total Recoverable Mercury by FIMS Mercury
EK025G: Free cyanide by Discrete Analyser Free Cyanide
EK026G: Total Cyanide By Discrete Analyser Total Cyanide
EP075(SIM)A: Phenolic Compounds 108-95-2
0.5
mg/kg
----
<0.5
<0.5
<0.5
----
2-Chlorophenol
95-57-8
0.5
mg/kg
----
<0.5
<0.5
<0.5
----
2-Methylphenol
95-48-7
0.5
mg/kg
----
<0.5
<0.5
<0.5
----
1319-77-3
1.0
mg/kg
----
<1.0
<1.0
<1.0
----
88-75-5
0.5
mg/kg
----
<0.5
<0.5
<0.5
----
2.4-Dimethylphenol
105-67-9
0.5
mg/kg
----
<0.5
<0.5
<0.5
----
2.4-Dichlorophenol
120-83-2
0.5
mg/kg
----
<0.5
<0.5
<0.5
----
2.6-Dichlorophenol
87-65-0
0.5
mg/kg
----
<0.5
<0.5
<0.5
----
4-Chloro-3-Methylphenol
59-50-7
0.5
mg/kg
----
<0.5
<0.5
<0.5
----
2.4.6-Trichlorophenol
88-06-2
0.5
mg/kg
----
<0.5
<0.5
<0.5
----
2.4.5-Trichlorophenol
95-95-4
0.5
mg/kg
----
<0.5
<0.5
<0.5
----
Pentachlorophenol
87-86-5
2.0
mg/kg
----
<2.0
<2.0
<2.0
----
Phenol
3- & 4-Methylphenol 2-Nitrophenol
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons 91-20-3
0.5
mg/kg
----
<0.5
<0.5
----
----
208-96-8
0.5
mg/kg
----
<0.5
<0.5
----
----
Acenaphthene
83-32-9
0.5
mg/kg
----
<0.5
<0.5
----
----
Fluorene
86-73-7
0.5
mg/kg
----
<0.5
<0.5
----
----
Phenanthrene
85-01-8
0.5
mg/kg
----
0.7
<0.5
----
----
Anthracene
120-12-7
0.5
mg/kg
----
<0.5
<0.5
----
----
Fluoranthene
206-44-0
0.5
mg/kg
----
2.0
<0.5
----
----
Pyrene
129-00-0
0.5
mg/kg
----
1.9
<0.5
----
----
Naphthalene Acenaphthylene
Page Work Order Client Project
: : : :
52 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
TP10 (1.4-1.5)
TP10 (1.9-2.0)
DUP2
TP10 (2.4-2.5)
TP11 (0-0.1)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
Unit
EM1008731-046
EM1008731-047
EM1008731-048
EM1008731-049
EM1008731-050
Client sampling date / time Compound
CAS Number
LOR
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons - Continued 56-55-3
0.5
mg/kg
----
1.2
<0.5
----
----
Chrysene
218-01-9
0.5
mg/kg
----
1.1
<0.5
----
----
Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
----
1.4
<0.5
----
----
Benzo(k)fluoranthene
207-08-9
0.5
mg/kg
----
0.6
<0.5
----
----
50-32-8
0.5
mg/kg
----
1.0
<0.5
----
----
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
----
0.8
<0.5
----
----
Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
----
<0.5
<0.5
----
----
191-24-2
0.5
mg/kg
----
0.9
<0.5
----
----
C6 - C9 Fraction
----
10
mg/kg
----
<10
<10
----
----
C10 - C14 Fraction
----
50
mg/kg
----
<50
<50
----
----
C15 - C28 Fraction
----
100
mg/kg
----
340
<100
----
----
C29 - C36 Fraction
----
100
mg/kg
----
540
<100
----
----
^ C10 - C36 Fraction (sum)
----
50
mg/kg
----
880
<50
----
----
Benzene
71-43-2
0.2
mg/kg
----
<0.2
<0.2
----
----
Toluene
108-88-3
0.5
mg/kg
----
<0.5
<0.5
----
----
Ethylbenzene
100-41-4
0.5
mg/kg
----
<0.5
<0.5
----
----
108-38-3 106-42-3
0.5
mg/kg
----
<0.5
<0.5
----
----
95-47-6
0.5
mg/kg
----
<0.5
<0.5
----
----
Phenol-d6
13127-88-3
0.1
%
----
116
99.4
93.2
----
2-Chlorophenol-D4
93951-73-6
0.1
%
----
95.6
99.9
100
----
118-79-6
0.1
%
----
96.4
86.5
80.1
----
2-Fluorobiphenyl
321-60-8
0.1
%
----
98.6
99.7
96.6
----
Anthracene-d10
1719-06-8
0.1
%
----
92.9
99.1
102
----
4-Terphenyl-d14
1718-51-0
0.1
%
----
102
93.9
95.6
----
17060-07-0
0.1
%
----
88.9
89.0
----
----
2037-26-5
0.1
%
----
84.8
87.6
----
----
460-00-4
0.1
%
----
90.6
94.6
----
----
Benz(a)anthracene
Benzo(a)pyrene
Benzo(g.h.i)perylene
EP080/071: Total Petroleum Hydrocarbons
EP080: BTEX
meta- & para-Xylene ortho-Xylene
EP075(SIM)S: Phenolic Compound Surrogates
2.4.6-Tribromophenol
EP075(SIM)T: PAH Surrogates
EP080S: TPH(V)/BTEX Surrogates 1.2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene
Page Work Order Client Project
: : : :
53 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP11 (1.7-1.8)
TP11 (1.9-2.0)
TP12 (0.4-0.5)
TP12 (1.4-1.5)
TP12 (1.9-2.0)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-052
EM1008731-053
EM1008731-054
EM1008731-055
EM1008731-056
----
0.5
kg H2SO4/t
----
-191
----
----
----
----
0.5
kg H2SO4 equiv./t
----
214
----
----
----
----
1.0
%
29.5
41.9
11.4
22.9
27.6
^ Exchangeable Calcium
----
0.1
meq/100g
----
33.2
----
----
----
^ Exchangeable Magnesium
----
0.1
meq/100g
----
17.1
----
----
----
^ Exchangeable Potassium
----
0.1
meq/100g
----
0.9
----
----
----
^ Exchangeable Sodium
----
0.1
meq/100g
----
2.6
----
----
----
^ Cation Exchange Capacity
----
0.1
meq/100g
----
53.7
----
----
----
^ Exchangeable Aluminium
----
0.1
meq/100g
----
<0.1
----
----
----
^ Exchangeable Calcium Percent
----
0.1
%
----
61.7
----
----
----
^ Exchangeable Sodium Percent
----
0.1
%
----
4.8
----
----
----
^ Exchangeable Magnesium Percent
----
0.1
%
----
31.8
----
----
----
^ Exchangeable Potassium Percent
----
0.1
%
----
1.7
----
----
----
^ Calcium/Magnesium Ratio
----
0.1
.
----
1.9
----
----
----
----
0.01
%
----
0.73
----
----
----
Compound
CAS Number
EA009: Nett Acid Production Potential ^ Net Acid Production Potential
EA013: Acid Neutralising Capacity ANC as H2SO4
EA055: Moisture Content ^ Moisture Content (dried @ 103째C)
ED007: Exchangeable Cations
ED042T: Total Sulfur by LECO Sulfur - Total as S (LECO)
ED093S: Soluble Major Cations Calcium
7440-70-2
10
mg/kg
----
60
----
----
----
Magnesium
7439-95-4
10
mg/kg
----
240
----
----
----
Sodium
7440-23-5
10
mg/kg
----
520
----
----
----
Potassium
7440-09-7
10
mg/kg
----
90
----
----
----
EG005S : Soluble Metals by ICPAES Aluminium
7429-90-5
1
mg/kg
----
<1
----
----
----
Manganese
7439-96-5
0.1
mg/kg
----
<0.1
----
----
----
Arsenic
7440-38-2
5
mg/kg
98
----
----
----
----
Cadmium
7440-43-9
1
mg/kg
2
----
----
----
----
Copper
7440-50-8
5
mg/kg
593
----
----
----
----
Lead
7439-92-1
5
mg/kg
288
----
----
----
----
Molybdenum
7439-98-7
2
mg/kg
<2
----
----
----
----
Nickel
7440-02-0
2
mg/kg
55
----
----
----
----
Selenium
7782-49-2
5
mg/kg
<5
----
----
----
----
Silver
7440-22-4
2
mg/kg
<2
----
----
----
----
EG005T: Total Metals by ICP-AES
Page Work Order Client Project
: : : :
54 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP11 (1.7-1.8)
TP11 (1.9-2.0)
TP12 (0.4-0.5)
TP12 (1.4-1.5)
TP12 (1.9-2.0)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-052
EM1008731-053
EM1008731-054
EM1008731-055
EM1008731-056
----
EG005T: Total Metals by ICP-AES - Continued Tin
7440-31-5
5
mg/kg
170
----
----
----
Zinc
7440-66-6
5
mg/kg
917
----
----
----
----
Arsenic
7440-38-2
5
mg/kg
----
100
42
36
111
Cadmium
7440-43-9
1
mg/kg
----
6
2
<1
<1
Chromium
7440-47-3
2
mg/kg
----
119
33
22
38
Copper
7440-50-8
5
mg/kg
----
1190
343
33
19
Lead
7439-92-1
5
mg/kg
----
688
431
60
30
Nickel
7440-02-0
2
mg/kg
----
84
69
48
27
Zinc
7440-66-6
5
mg/kg
----
2080
2550
200
44
7439-97-6
0.1
mg/kg
0.6
1.2
0.6
0.1
0.1
0.5
mg/kg
<0.5
----
----
----
----
----
1
mg/kg
----
----
----
----
<1
57-12-5
1
mg/kg
<1
----
----
----
<1
16984-48-8
40
mg/kg
320
----
----
----
----
----
0.5
%
----
6.1
----
----
----
----
0.10
mg/kg
<5.00
----
----
----
----
Benzene
71-43-2
0.2
mg/kg
<0.2
----
----
----
----
Toluene
108-88-3
0.5
mg/kg
<0.5
----
----
----
----
Ethylbenzene
100-41-4
0.5
mg/kg
<0.5
----
----
----
----
108-38-3 106-42-3
0.5
mg/kg
<0.5
----
----
----
----
100-42-5
0.5
mg/kg
<0.5
----
----
----
----
95-47-6
0.5
mg/kg
<0.5
----
----
----
----
----
0.2
mg/kg
<0.2
----
----
----
----
----
0.2
mg/kg
<0.2
----
----
----
----
Vinyl chloride
75-01-4
0.02
mg/kg
<0.02
----
----
----
----
1.1-Dichloroethene
75-35-4
0.01
mg/kg
<0.01
----
----
----
----
EG035T: Total Recoverable Mercury by FIMS Mercury
EG048: Hexavalent Chromium (Alkaline Digest) Hexavalent Chromium
18540-29-9
EK025G: Free cyanide by Discrete Analyser Free Cyanide
EK026G: Total Cyanide By Discrete Analyser Total Cyanide
EK040T: Fluoride Total Fluoride
EP004: Organic Matter ^ Total Organic Carbon
EP066: Polychlorinated Biphenyls (PCB) Total Polychlorinated biphenyls
EP074A: Monocyclic Aromatic Hydrocarbons
meta- & para-Xylene Styrene ortho-Xylene ^ Sum of monocyclic aromatic hydrocarbons ^ Sum of monocyclic aromatic hydrocarbons
EP074I: Volatile Halogenated Compounds
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: : : :
55 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
LOR
Unit
TP11 (1.7-1.8)
TP11 (1.9-2.0)
TP12 (0.4-0.5)
TP12 (1.4-1.5)
TP12 (1.9-2.0)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
EM1008731-052
EM1008731-053
EM1008731-054
EM1008731-055
EM1008731-056
EP074I: Volatile Halogenated Compounds - Continued 75-09-2
0.4
mg/kg
<0.6
----
----
----
----
trans-1.2-Dichloroethene
156-60-5
0.02
mg/kg
<0.02
----
----
----
----
cis-1.2-Dichloroethene
156-59-2
0.01
mg/kg
<0.01
----
----
----
----
Chloroform
67-66-3
0.02
mg/kg
<0.02
----
----
----
----
1.1.1-Trichloroethane
71-55-6
0.01
mg/kg
<0.01
----
----
----
----
Carbon Tetrachloride
56-23-5
0.01
mg/kg
<0.01
----
----
----
----
107-06-2
0.02
mg/kg
<0.02
----
----
----
----
Trichloroethene
79-01-6
0.02
mg/kg
<0.02
----
----
----
----
1.1.2-Trichloroethane
79-00-5
0.04
mg/kg
<0.04
----
----
----
----
Tetrachloroethene
127-18-4
0.02
mg/kg
<0.02
----
----
----
----
1.1.1.2-Tetrachloroethane
630-20-6
0.01
mg/kg
<0.01
----
----
----
----
1.1.2.2-Tetrachloroethane
79-34-5
0.02
mg/kg
<0.02
----
----
----
----
Hexachlorobutadiene
87-68-3
0.02
mg/kg
<0.02
----
----
----
----
Chlorobenzene
108-90-7
0.02
mg/kg
<0.02
----
----
----
----
1.4-Dichlorobenzene
106-46-7
0.02
mg/kg
<0.02
----
----
----
----
1.2-Dichlorobenzene
95-50-1
0.02
mg/kg
<0.02
----
----
----
----
120-82-1
0.01
mg/kg
<0.01
----
----
----
----
----
0.01
mg/kg
<0.01
----
----
----
----
----
0.01
mg/kg
<0.01
----
----
----
----
----
0.01
mg/kg
<0.01
----
----
----
----
----
0.01
mg/kg
<0.01
----
----
----
----
1330-20-7
0.50
mg/kg
<0.50
----
----
----
----
Methylene chloride
1.2-Dichloroethane
1.2.4-Trichlorobenzene ^ Sum of volatile chlorinated hydrocarbons ^ Sum of other chlorinated hydrocarbons (VIC EPA 448.3) ^ Sum of volatile chlorinated hydrocarbons ^ Sum of other chlorinated hydrocarbons (VIC EPA 448.3) ^ Total Xylenes
EP075(SIM)A: Phenolic Compounds 108-95-2
0.5
mg/kg
----
<0.5
----
----
<0.5
2-Chlorophenol
95-57-8
0.5
mg/kg
----
<0.5
----
----
<0.5
2-Methylphenol
95-48-7
0.5
mg/kg
----
<0.5
----
----
<0.5
1319-77-3
1.0
mg/kg
----
<1.0
----
----
<1.0
88-75-5
0.5
mg/kg
----
<0.5
----
----
<0.5
2.4-Dimethylphenol
105-67-9
0.5
mg/kg
----
<0.5
----
----
<0.5
2.4-Dichlorophenol
120-83-2
0.5
mg/kg
----
<0.5
----
----
<0.5
2.6-Dichlorophenol
87-65-0
0.5
mg/kg
----
<0.5
----
----
<0.5
4-Chloro-3-Methylphenol
59-50-7
0.5
mg/kg
----
<0.5
----
----
<0.5
2.4.6-Trichlorophenol
88-06-2
0.5
mg/kg
----
<0.5
----
----
<0.5
2.4.5-Trichlorophenol
95-95-4
0.5
mg/kg
----
<0.5
----
----
<0.5
Phenol
3- & 4-Methylphenol 2-Nitrophenol
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: : : :
56 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP11 (1.7-1.8)
TP11 (1.9-2.0)
TP12 (0.4-0.5)
TP12 (1.4-1.5)
TP12 (1.9-2.0)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-052
EM1008731-053
EM1008731-054
EM1008731-055
EM1008731-056
2.0
mg/kg
----
<2.0
----
----
<2.0
EP075(SIM)A: Phenolic Compounds - Continued Pentachlorophenol
87-86-5
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons 91-20-3
0.5
mg/kg
----
<0.5
----
<0.5
<0.5
208-96-8
0.5
mg/kg
----
----
----
<0.5
----
83-32-9
0.5
mg/kg
----
----
----
<0.5
----
208-96-8
0.5
mg/kg
----
<0.5
----
----
<0.5
Acenaphthene
83-32-9
0.5
mg/kg
----
<0.5
----
----
<0.5
Fluorene
86-73-7
0.5
mg/kg
----
----
----
<0.5
----
Fluorene
86-73-7
0.5
mg/kg
----
<0.5
----
----
<0.5 ----
Naphthalene Acenaphthylene Acenaphthene Acenaphthylene
85-01-8
0.5
mg/kg
----
----
----
2.6
120-12-7
0.5
mg/kg
----
----
----
0.7
----
85-01-8
0.5
mg/kg
----
<0.5
----
----
<0.5
Anthracene
120-12-7
0.5
mg/kg
----
<0.5
----
----
<0.5
Fluoranthene
206-44-0
0.5
mg/kg
----
----
----
5.0
----
Fluoranthene
206-44-0
0.5
mg/kg
----
<0.5
----
----
<0.5
Pyrene
129-00-0
0.5
mg/kg
----
----
----
4.9
----
56-55-3
0.5
mg/kg
----
----
----
2.4
----
129-00-0
0.5
mg/kg
----
0.7
----
----
<0.5
Phenanthrene Anthracene Phenanthrene
Benz(a)anthracene Pyrene
56-55-3
0.5
mg/kg
----
<0.5
----
----
<0.5
Chrysene
218-01-9
0.5
mg/kg
----
----
----
2.4
----
Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
----
----
----
2.8
----
Chrysene
218-01-9
0.5
mg/kg
----
<0.5
----
----
<0.5
Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
----
<0.5
----
----
<0.5
Benzo(k)fluoranthene
207-08-9
0.5
mg/kg
----
----
----
0.8
----
50-32-8
0.5
mg/kg
----
----
----
2.3
----
207-08-9
0.5
mg/kg
----
<0.5
----
----
<0.5
Benz(a)anthracene
Benzo(a)pyrene Benzo(k)fluoranthene
50-32-8
0.5
mg/kg
----
<0.5
----
----
<0.5
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
----
----
----
1.3
----
Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
----
----
----
<0.5
----
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
----
<0.5
----
----
<0.5
Benzo(g.h.i)perylene
191-24-2
0.5
mg/kg
----
----
----
1.6
----
53-70-3
0.5
mg/kg
----
<0.5
----
----
<0.5
191-24-2
0.5
mg/kg
----
<0.5
----
----
<0.5
Benzo(a)pyrene
Dibenz(a.h)anthracene Benzo(g.h.i)perylene
EP075A: Phenolic Compounds (Halogenated) 95-57-8
0.03
mg/kg
<0.12
----
----
----
----
2.4-Dichlorophenol
120-83-2
0.03
mg/kg
<0.12
----
----
----
----
2.6-Dichlorophenol
87-65-0
0.03
mg/kg
<0.12
----
----
----
----
4-Chloro-3-Methylphenol
59-50-7
0.03
mg/kg
<0.12
----
----
----
----
2-Chlorophenol
Page Work Order Client Project
: : : :
57 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP11 (1.7-1.8)
TP11 (1.9-2.0)
TP12 (0.4-0.5)
TP12 (1.4-1.5)
TP12 (1.9-2.0)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-052
EM1008731-053
EM1008731-054
EM1008731-055
EM1008731-056
EP075A: Phenolic Compounds (Halogenated) - Continued 2.4.5-Trichlorophenol
95-95-4
0.05
mg/kg
<0.12
----
----
----
----
2.4.6-Trichlorophenol
88-06-2
0.05
mg/kg
<0.12
----
----
----
----
935-95-5
0.03
mg/kg
<0.12
----
----
----
----
4901-51-3/58-90-2
0.05
mg/kg
<0.24
----
----
----
----
87-86-5
0.2
mg/kg
<0.2
----
----
----
----
----
0.03
mg/kg
<0.12
----
----
----
----
108-95-2
1
mg/kg
<1
----
----
----
----
95-48-7
1
mg/kg
<1
----
----
----
----
1319-77-3
1
mg/kg
<1
----
----
----
----
88-75-5
1
mg/kg
<1
----
----
----
----
105-67-9
1
mg/kg
<1
----
----
----
----
51-28-5
5
mg/kg
<9
----
----
----
----
100-02-7
5
mg/kg
<9
----
----
----
----
8071-51-0
5
mg/kg
<9
----
----
----
----
88-85-7
5
mg/kg
<9
----
----
----
----
131-89-5
5
mg/kg
<9
----
----
----
----
----
1
mg/kg
<1
----
----
----
----
2.3.5.6-Tetrachlorophenol 2.3.4.5 & 2.3.4.6-Tetrachlorophenol Pentachlorophenol ^ Sum of Phenols (halogenated)
EP075A: Phenolic Compounds (Non-halogenated) Phenol 2-Methylphenol 3- & 4-Methylphenol 2-Nitrophenol 2.4-Dimethylphenol 2.4-Dinitrophenol 4-Nitrophenol 2-Methyl-4.6-dinitrophenol Dinoseb 2-Cyclohexyl-4.6-Dinitrophenol ^ Sum of Phenols (non-halogenated)
EP075B: Polynuclear Aromatic Hydrocarbons Naphthalene
91-20-3
0.5
mg/kg
<0.5
----
----
----
----
Acenaphthene
83-32-9
0.5
mg/kg
<0.5
----
----
----
----
208-96-8
0.5
mg/kg
<0.5
----
----
----
----
Fluorene
86-73-7
0.5
mg/kg
<0.5
----
----
----
----
Phenanthrene
85-01-8
0.5
mg/kg
<0.5
----
----
----
----
Anthracene
120-12-7
0.5
mg/kg
<0.5
----
----
----
----
Fluoranthene
206-44-0
0.5
mg/kg
<0.5
----
----
----
----
Pyrene
129-00-0
0.5
mg/kg
<0.5
----
----
----
----
56-55-3
0.5
mg/kg
<0.5
----
----
----
----
218-01-9
0.5
mg/kg
<0.5
----
----
----
----
205-99-2 207-08-9
0.5
mg/kg
<0.5
----
----
----
----
Acenaphthylene
Benz(a)anthracene Chrysene Benzo(b) & Benzo(k)fluoranthene Benzo(a)pyrene
50-32-8
0.5
mg/kg
<0.5
----
----
----
----
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
<0.5
----
----
----
----
Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
<0.5
----
----
----
----
191-24-2
0.5
mg/kg
<0.5
----
----
----
----
----
0.5
mg/kg
<0.5
----
----
----
----
Benzo(g.h.i)perylene ^ Sum of polycyclic aromatic hydrocarbons
Page Work Order Client Project
: : : :
58 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP11 (1.7-1.8)
TP11 (1.9-2.0)
TP12 (0.4-0.5)
TP12 (1.4-1.5)
TP12 (1.9-2.0)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
CAS Number
LOR
Unit
EM1008731-052
EM1008731-053
EM1008731-054
EM1008731-055
EM1008731-056
alpha-BHC
319-84-6
0.03
mg/kg
<0.12
----
----
----
----
Hexachlorobenzene (HCB)
118-74-1
0.03
mg/kg
<0.12
----
----
----
----
beta-BHC
319-85-7
0.03
mg/kg
<0.12
----
----
----
----
58-89-9
0.03
mg/kg
<0.12
----
----
----
----
delta-BHC
319-86-8
0.03
mg/kg
<0.12
----
----
----
----
Heptachlor
76-44-8
0.03
mg/kg
<0.12
----
----
----
----
309-00-2
0.03
mg/kg
<0.12
----
----
----
----
Heptachlor epoxide
1024-57-3
0.03
mg/kg
<0.12
----
----
----
----
cis-Chlordane
5103-71-9
0.03
mg/kg
<0.12
----
----
----
----
trans-Chlordane
5103-74-2
0.03
mg/kg
<0.12
----
----
----
----
959-98-8
0.03
mg/kg
<0.12
----
----
----
----
4.4`-DDE
72-55-9
0.05
mg/kg
<0.12
----
----
----
----
Dieldrin
60-57-1
0.03
mg/kg
<0.12
----
----
----
----
7421-93-4
0.03
mg/kg
<0.12
----
----
----
----
72-20-8
0.03
mg/kg
<0.12
----
----
----
----
33213-65-9
0.03
mg/kg
<0.12
----
----
----
----
72-54-8
0.05
mg/kg
<0.12
----
----
----
----
1031-07-8
0.03
mg/kg
<0.12
----
----
----
----
4.4`-DDT
50-29-3
0.05
mg/kg
<0.12
----
----
----
----
Methoxychlor
72-43-5
0.03
mg/kg
<0.12
----
----
----
----
----
0.03
mg/kg
<0.12
----
----
----
----
309-00-2/60-57-1
0.03
mg/kg
<0.12
----
----
----
----
----
0.05
mg/kg
<0.12
----
----
----
----
57-74-9
0.03
mg/kg
<0.12
----
----
----
----
----
0.03
mg/kg
<0.12
----
----
----
----
C6 - C9 Fraction
----
10
mg/kg
<10
----
----
----
----
C6 - C9 Fraction
----
10
mg/kg
----
<10
----
<10
<10
C10 - C14 Fraction
----
50
mg/kg
<50
70
----
<50
<50
C15 - C28 Fraction
----
100
mg/kg
680
1760
----
240
130
C29 - C36 Fraction
----
100
mg/kg
1710
3080
----
500
120
^ C10 - C36 Fraction (sum)
----
50
mg/kg
2390
4910
----
740
250
Benzene
71-43-2
0.2
mg/kg
----
<0.2
----
<0.2
<0.2
Toluene
108-88-3
0.5
mg/kg
----
<0.5
----
<0.5
<0.5
Ethylbenzene
100-41-4
0.5
mg/kg
----
<0.5
----
<0.5
<0.5
108-38-3 106-42-3
0.5
mg/kg
----
<0.5
----
<0.5
<0.5
Compound
EP075I: Organochlorine Pesticides
gamma-BHC
Aldrin
Endosulfan 1
Endrin aldehyde Endrin Endosulfan 2 4.4`-DDD Endosulfan sulfate
^ Sum of organochlorine pesticides ^ Sum of Aldrin + Dieldrin ^ Sum of DDD + DDE + DDT ^ Chlordane ^ Sum of other organochlorine pesticides
EP080/071: Total Petroleum Hydrocarbons
EP080: BTEX
meta- & para-Xylene
Page Work Order Client Project
: : : :
59 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP11 (1.7-1.8)
TP11 (1.9-2.0)
TP12 (0.4-0.5)
TP12 (1.4-1.5)
TP12 (1.9-2.0)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-052
EM1008731-053
EM1008731-054
EM1008731-055
EM1008731-056
95-47-6
0.5
mg/kg
----
<0.5
----
<0.5
<0.5
2051-24-3
0.1
%
41.0
----
----
----
----
17060-07-0
0.1
%
92.2
----
----
----
----
2037-26-5
0.1
%
79.8
----
----
----
----
460-00-4
0.1
%
83.9
----
----
----
----
Phenol-d6
13127-88-3
0.1
%
----
85.0
----
95.1
88.3
2-Chlorophenol-D4
93951-73-6
0.1
%
----
91.1
----
82.7
95.1
118-79-6
0.1
%
----
80.4
----
87.4
84.6
2-Fluorobiphenyl
321-60-8
0.1
%
----
87.9
----
99.6
92.5
Anthracene-d10
1719-06-8
0.1
%
----
87.0
----
99.6
86.4
4-Terphenyl-d14
1718-51-0
0.1
%
----
84.6
----
97.4
90.1
Compound
CAS Number
EP080: BTEX - Continued ortho-Xylene
EP066S: PCB Surrogate Decachlorobiphenyl
EP074S: VOC Surrogates 1.2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene
EP075(SIM)S: Phenolic Compound Surrogates
2.4.6-Tribromophenol
EP075(SIM)T: PAH Surrogates
EP075S: Acid Extractable Surrogates 367-12-4
0.1
%
Not Determined
----
----
----
----
Phenol-d6
13127-88-3
0.1
%
Not Determined
----
----
----
----
2-Chlorophenol-D4
93951-73-6
0.1
%
Not Determined
----
----
----
----
118-79-6
0.1
%
Not Determined
----
----
----
----
Nitrobenzene-D5
4165-60-0
0.1
%
Not Determined
----
----
----
----
1.2-Dichlorobenzene-D4
2199-69-1
0.1
%
Not Determined
----
----
----
----
2-Fluorobiphenyl
321-60-8
0.1
%
Not Determined
----
----
----
----
Anthracene-d10
1719-06-8
0.1
%
Not Determined
----
----
----
----
4-Terphenyl-d14
1718-51-0
0.1
%
Not Determined
----
----
----
----
17060-07-0
0.1
%
----
80.6
----
88.6
95.2
2037-26-5
0.1
%
----
74.8
----
81.9
87.2
460-00-4
0.1
%
----
71.6
----
83.9
89.8
2-Fluorophenol
2.4.6-Tribromophenol
EP075T: Base/Neutral Extractable Surrogates
EP080S: TPH(V)/BTEX Surrogates 1.2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene
Page Work Order Client Project
: : : :
60 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP12 (2.4-2.5)
DUP3
TP13 (0-0.1)
TP13 (0.4-0.5)
TP13 (1.5-1.6)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-057
EM1008731-058
EM1008731-059
EM1008731-060
EM1008731-061
1.0
%
33.6
36.5
35.4
17.4
24.0
EA055: Moisture Content ----
^ Moisture Content (dried @ 103째C)
EG005T: Total Metals by ICP-AES Arsenic
7440-38-2
5
mg/kg
----
----
----
----
112
Cadmium
7440-43-9
1
mg/kg
----
----
----
----
<1
Copper
7440-50-8
5
mg/kg
----
----
----
----
60
Lead
7439-92-1
5
mg/kg
----
----
----
----
Molybdenum
7439-98-7
2
mg/kg
----
----
----
----
93 <2
Nickel
7440-02-0
2
mg/kg
----
----
----
----
Selenium
7782-49-2
5
mg/kg
----
----
----
----
44 <5
Silver
7440-22-4
2
mg/kg
----
----
----
----
<2
Tin
7440-31-5
5
mg/kg
----
----
----
----
33
Zinc
7440-66-6
5
mg/kg
----
----
----
----
147
Arsenic
7440-38-2
5
mg/kg
74
1
mg/kg
1
3
8 <1
----
7440-43-9
54 <1
90
Cadmium Chromium
7440-47-3
2
mg/kg
97
32
85
36
----
Copper
7440-50-8
5
mg/kg
98
47
267
24
----
Lead
7439-92-1
5
mg/kg
142
122
320
38
----
Nickel
7440-02-0
2
mg/kg
49
39
66
49
----
Zinc
7440-66-6
5
mg/kg
472
378
560
88
----
7439-97-6
0.1
mg/kg
0.3
0.4
0.5
<0.1
0.4
0.5
mg/kg
----
----
----
----
<0.5
57-12-5
1
mg/kg
----
----
----
----
1
16984-48-8
40
mg/kg
----
----
----
----
160
----
0.10
mg/kg
----
----
----
----
<5.00
Benzene
71-43-2
0.2
mg/kg
----
----
----
----
<0.2
Toluene
108-88-3
0.5
mg/kg
----
----
----
----
<0.5
Ethylbenzene
100-41-4
0.5
mg/kg
----
----
----
----
<0.5
108-38-3 106-42-3
0.5
mg/kg
----
----
----
----
<0.5
100-42-5
0.5
mg/kg
----
----
----
----
<0.5
95-47-6
0.5
mg/kg
----
----
----
----
<0.5
----
EG035T: Total Recoverable Mercury by FIMS Mercury
EG048: Hexavalent Chromium (Alkaline Digest) Hexavalent Chromium
18540-29-9
EK026G: Total Cyanide By Discrete Analyser Total Cyanide
EK040T: Fluoride Total Fluoride
EP066: Polychlorinated Biphenyls (PCB) Total Polychlorinated biphenyls
EP074A: Monocyclic Aromatic Hydrocarbons
meta- & para-Xylene Styrene ortho-Xylene
Page Work Order Client Project
: : : :
61 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP12 (2.4-2.5)
DUP3
TP13 (0-0.1)
TP13 (0.4-0.5)
TP13 (1.5-1.6)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-057
EM1008731-058
EM1008731-059
EM1008731-060
EM1008731-061
----
0.2
mg/kg
----
----
----
----
<0.2
----
0.2
mg/kg
----
----
----
----
<0.2
Vinyl chloride
75-01-4
0.02
mg/kg
----
----
----
----
<0.02
1.1-Dichloroethene
75-35-4
0.01
mg/kg
----
----
----
----
<0.01
Methylene chloride
75-09-2
0.4
mg/kg
----
----
----
----
<0.6
trans-1.2-Dichloroethene
156-60-5
0.02
mg/kg
----
----
----
----
<0.02
cis-1.2-Dichloroethene
Compound
CAS Number
EP074A: Monocyclic Aromatic Hydrocarbons - Continued ^ Sum of monocyclic aromatic hydrocarbons ^ Sum of monocyclic aromatic hydrocarbons
EP074I: Volatile Halogenated Compounds
156-59-2
0.01
mg/kg
----
----
----
----
<0.01
Chloroform
67-66-3
0.02
mg/kg
----
----
----
----
<0.02
1.1.1-Trichloroethane
71-55-6
0.01
mg/kg
----
----
----
----
<0.01
Carbon Tetrachloride
56-23-5
0.01
mg/kg
----
----
----
----
<0.01
107-06-2
0.02
mg/kg
----
----
----
----
<0.02
Trichloroethene
79-01-6
0.02
mg/kg
----
----
----
----
<0.02
1.1.2-Trichloroethane
79-00-5
0.04
mg/kg
----
----
----
----
<0.04
Tetrachloroethene
127-18-4
0.02
mg/kg
----
----
----
----
<0.02
1.1.1.2-Tetrachloroethane
630-20-6
0.01
mg/kg
----
----
----
----
<0.01
1.1.2.2-Tetrachloroethane
79-34-5
0.02
mg/kg
----
----
----
----
<0.02
Hexachlorobutadiene
87-68-3
0.02
mg/kg
----
----
----
----
<0.02
Chlorobenzene
108-90-7
0.02
mg/kg
----
----
----
----
<0.02
1.4-Dichlorobenzene
106-46-7
0.02
mg/kg
----
----
----
----
<0.02
1.2-Dichlorobenzene
95-50-1
0.02
mg/kg
----
----
----
----
<0.02
120-82-1
0.01
mg/kg
----
----
----
----
<0.01
----
0.01
mg/kg
----
----
----
----
<0.01
----
0.01
mg/kg
----
----
----
----
<0.01
----
0.01
mg/kg
----
----
----
----
<0.01
----
0.01
mg/kg
----
----
----
----
<0.01
1330-20-7
0.50
mg/kg
----
----
----
----
<0.50
1.2-Dichloroethane
1.2.4-Trichlorobenzene ^ Sum of volatile chlorinated hydrocarbons ^ Sum of other chlorinated hydrocarbons (VIC EPA 448.3) ^ Sum of volatile chlorinated hydrocarbons ^ Sum of other chlorinated hydrocarbons (VIC EPA 448.3) ^ Total Xylenes
EP075(SIM)A: Phenolic Compounds 108-95-2
0.5
mg/kg
<0.5
<0.5
----
----
----
2-Chlorophenol
95-57-8
0.5
mg/kg
<0.5
<0.5
----
----
----
2-Methylphenol
95-48-7
0.5
mg/kg
<0.5
<0.5
----
----
----
1319-77-3
1.0
mg/kg
<1.0
<1.0
----
----
----
Phenol
3- & 4-Methylphenol
Page Work Order Client Project
: : : :
62 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP12 (2.4-2.5)
DUP3
TP13 (0-0.1)
TP13 (0.4-0.5)
TP13 (1.5-1.6)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-057
EM1008731-058
EM1008731-059
EM1008731-060
EM1008731-061
EP075(SIM)A: Phenolic Compounds - Continued 88-75-5
0.5
mg/kg
<0.5
<0.5
----
----
----
2.4-Dimethylphenol
105-67-9
0.5
mg/kg
<0.5
<0.5
----
----
----
2.4-Dichlorophenol
120-83-2
0.5
mg/kg
<0.5
<0.5
----
----
----
2.6-Dichlorophenol
87-65-0
0.5
mg/kg
<0.5
<0.5
----
----
----
4-Chloro-3-Methylphenol
59-50-7
0.5
mg/kg
<0.5
<0.5
----
----
----
2.4.6-Trichlorophenol
88-06-2
0.5
mg/kg
<0.5
<0.5
----
----
----
2.4.5-Trichlorophenol
95-95-4
0.5
mg/kg
<0.5
<0.5
----
----
----
Pentachlorophenol
87-86-5
2.0
mg/kg
<2.0
<2.0
----
----
----
2-Nitrophenol
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons 91-20-3
0.5
mg/kg
<0.5
<0.5
----
<0.5
----
208-96-8
0.5
mg/kg
----
----
----
<0.5
----
83-32-9
0.5
mg/kg
----
----
----
<0.5
----
208-96-8
0.5
mg/kg
<0.5
<0.5
----
----
----
Acenaphthene
83-32-9
0.5
mg/kg
<0.5
<0.5
----
----
----
Fluorene
86-73-7
0.5
mg/kg
----
----
----
<0.5
----
Fluorene
86-73-7
0.5
mg/kg
<0.5
<0.5
----
----
----
Phenanthrene
85-01-8
0.5
mg/kg
----
----
----
<0.5
----
120-12-7
0.5
mg/kg
----
----
----
<0.5
----
85-01-8
0.5
mg/kg
<0.5
<0.5
----
----
----
Anthracene
120-12-7
0.5
mg/kg
<0.5
<0.5
----
----
----
Fluoranthene
206-44-0
0.5
mg/kg
----
----
----
<0.5
----
Fluoranthene
206-44-0
0.5
mg/kg
<0.5
0.6
----
----
----
Pyrene
129-00-0
0.5
mg/kg
----
----
----
<0.5
----
56-55-3
0.5
mg/kg
----
----
----
<0.5
----
129-00-0
0.5
mg/kg
0.6
1.0
----
----
----
56-55-3
0.5
mg/kg
<0.5
<0.5
----
----
----
Chrysene
218-01-9
0.5
mg/kg
----
----
----
<0.5
----
Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
----
----
----
<0.5
----
Chrysene
218-01-9
0.5
mg/kg
<0.5
0.5
----
----
----
Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
<0.5
0.5
----
----
----
Benzo(k)fluoranthene
207-08-9
0.5
mg/kg
----
----
----
<0.5
----
50-32-8
0.5
mg/kg
----
----
----
<0.5
----
207-08-9
0.5
mg/kg
<0.5
<0.5
----
----
----
50-32-8
0.5
mg/kg
<0.5
<0.5
----
----
----
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
----
----
----
<0.5
----
Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
----
----
----
<0.5
----
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
<0.5
<0.5
----
----
----
Benzo(g.h.i)perylene
191-24-2
0.5
mg/kg
----
----
----
<0.5
----
Naphthalene Acenaphthylene Acenaphthene Acenaphthylene
Anthracene Phenanthrene
Benz(a)anthracene Pyrene Benz(a)anthracene
Benzo(a)pyrene Benzo(k)fluoranthene Benzo(a)pyrene
Page Work Order Client Project
: : : :
63 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
TP12 (2.4-2.5)
DUP3
TP13 (0-0.1)
TP13 (0.4-0.5)
TP13 (1.5-1.6)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
Unit
EM1008731-057
EM1008731-058
EM1008731-059
EM1008731-060
EM1008731-061
Client sampling date / time Compound
CAS Number
LOR
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons - Continued Dibenz(a.h)anthracene Benzo(g.h.i)perylene
53-70-3
0.5
mg/kg
<0.5
<0.5
----
----
----
191-24-2
0.5
mg/kg
<0.5
<0.5
----
----
----
EP075A: Phenolic Compounds (Halogenated) 95-57-8
0.03
mg/kg
----
----
----
----
<0.12
2.4-Dichlorophenol
120-83-2
0.03
mg/kg
----
----
----
----
<0.12
2.6-Dichlorophenol
87-65-0
0.03
mg/kg
----
----
----
----
<0.12
4-Chloro-3-Methylphenol
59-50-7
0.03
mg/kg
----
----
----
----
<0.12
2.4.5-Trichlorophenol
95-95-4
0.05
mg/kg
----
----
----
----
<0.12
2.4.6-Trichlorophenol
88-06-2
0.05
mg/kg
----
----
----
----
<0.12
935-95-5
0.03
mg/kg
----
----
----
----
<0.12
4901-51-3/58-90-2
0.05
mg/kg
----
----
----
----
<0.23
87-86-5
0.2
mg/kg
----
----
----
----
<0.2
----
0.03
mg/kg
----
----
----
----
<0.12
108-95-2
1
mg/kg
----
----
----
----
<1
95-48-7
1
mg/kg
----
----
----
----
<1
1319-77-3
1
mg/kg
----
----
----
----
<1
88-75-5
1
mg/kg
----
----
----
----
<1
105-67-9
1
mg/kg
----
----
----
----
<1
51-28-5
5
mg/kg
----
----
----
----
<9
100-02-7
5
mg/kg
----
----
----
----
<9
8071-51-0
5
mg/kg
----
----
----
----
<9
88-85-7
5
mg/kg
----
----
----
----
<9
131-89-5
5
mg/kg
----
----
----
----
<9
----
1
mg/kg
----
----
----
----
<1
2-Chlorophenol
2.3.5.6-Tetrachlorophenol 2.3.4.5 & 2.3.4.6-Tetrachlorophenol Pentachlorophenol ^ Sum of Phenols (halogenated)
EP075A: Phenolic Compounds (Non-halogenated) Phenol 2-Methylphenol 3- & 4-Methylphenol 2-Nitrophenol 2.4-Dimethylphenol 2.4-Dinitrophenol 4-Nitrophenol 2-Methyl-4.6-dinitrophenol Dinoseb 2-Cyclohexyl-4.6-Dinitrophenol ^ Sum of Phenols (non-halogenated)
EP075B: Polynuclear Aromatic Hydrocarbons Naphthalene
91-20-3
0.5
mg/kg
----
----
----
----
<0.5
Acenaphthene
83-32-9
0.5
mg/kg
----
----
----
----
<0.5
208-96-8
0.5
mg/kg
----
----
----
----
<0.5
Fluorene
86-73-7
0.5
mg/kg
----
----
----
----
<0.5
Phenanthrene
85-01-8
0.5
mg/kg
----
----
----
----
<0.5
Anthracene
120-12-7
0.5
mg/kg
----
----
----
----
<0.5
Fluoranthene
206-44-0
0.5
mg/kg
----
----
----
----
<0.5
Pyrene
129-00-0
0.5
mg/kg
----
----
----
----
<0.5
56-55-3
0.5
mg/kg
----
----
----
----
<0.5
218-01-9
0.5
mg/kg
----
----
----
----
<0.5
Acenaphthylene
Benz(a)anthracene Chrysene
Page Work Order Client Project
: : : :
64 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP12 (2.4-2.5)
DUP3
TP13 (0-0.1)
TP13 (0.4-0.5)
TP13 (1.5-1.6)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-057
EM1008731-058
EM1008731-059
EM1008731-060
EM1008731-061
205-99-2 207-08-9
0.5
mg/kg
----
----
----
----
<0.5
Compound
CAS Number
EP075B: Polynuclear Aromatic Hydrocarbons - Continued Benzo(b) & Benzo(k)fluoranthene Benzo(a)pyrene
50-32-8
0.5
mg/kg
----
----
----
----
<0.5
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
----
----
----
----
<0.5
Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
----
----
----
----
<0.5
191-24-2
0.5
mg/kg
----
----
----
----
<0.5
----
0.5
mg/kg
----
----
----
----
<0.5
alpha-BHC
319-84-6
0.03
mg/kg
----
----
----
----
<0.12
Hexachlorobenzene (HCB)
118-74-1
0.03
mg/kg
----
----
----
----
<0.12
beta-BHC
319-85-7
0.03
mg/kg
----
----
----
----
<0.12
58-89-9
0.03
mg/kg
----
----
----
----
<0.12
delta-BHC
319-86-8
0.03
mg/kg
----
----
----
----
<0.12
Heptachlor
76-44-8
0.03
mg/kg
----
----
----
----
<0.12
309-00-2
0.03
mg/kg
----
----
----
----
<0.12
Heptachlor epoxide
1024-57-3
0.03
mg/kg
----
----
----
----
<0.12
cis-Chlordane
5103-71-9
0.03
mg/kg
----
----
----
----
<0.12
trans-Chlordane
5103-74-2
0.03
mg/kg
----
----
----
----
<0.12
959-98-8
0.03
mg/kg
----
----
----
----
<0.12
4.4`-DDE
72-55-9
0.05
mg/kg
----
----
----
----
<0.12
Dieldrin
60-57-1
0.03
mg/kg
----
----
----
----
<0.12
7421-93-4
0.03
mg/kg
----
----
----
----
<0.12
72-20-8
0.03
mg/kg
----
----
----
----
<0.12
33213-65-9
0.03
mg/kg
----
----
----
----
<0.12
72-54-8
0.05
mg/kg
----
----
----
----
<0.12
1031-07-8
0.03
mg/kg
----
----
----
----
<0.12
4.4`-DDT
50-29-3
0.05
mg/kg
----
----
----
----
<0.12
Methoxychlor
72-43-5
0.03
mg/kg
----
----
----
----
<0.12
----
0.03
mg/kg
----
----
----
----
<0.12
309-00-2/60-57-1
0.03
mg/kg
----
----
----
----
<0.12
----
0.05
mg/kg
----
----
----
----
<0.12
57-74-9
0.03
mg/kg
----
----
----
----
<0.12
----
0.03
mg/kg
----
----
----
----
<0.12
C6 - C9 Fraction
----
10
mg/kg
----
----
----
----
<10
C6 - C9 Fraction
----
10
mg/kg
<10
<10
----
<10
----
Benzo(g.h.i)perylene ^ Sum of polycyclic aromatic hydrocarbons
EP075I: Organochlorine Pesticides
gamma-BHC
Aldrin
Endosulfan 1
Endrin aldehyde Endrin Endosulfan 2 4.4`-DDD Endosulfan sulfate
^ Sum of organochlorine pesticides ^ Sum of Aldrin + Dieldrin ^ Sum of DDD + DDE + DDT ^ Chlordane ^ Sum of other organochlorine pesticides
EP080/071: Total Petroleum Hydrocarbons
Page Work Order Client Project
: : : :
65 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP12 (2.4-2.5)
DUP3
TP13 (0-0.1)
TP13 (0.4-0.5)
TP13 (1.5-1.6)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
EM1008731-058
EM1008731-059
EM1008731-060
EM1008731-061
LOR
Unit
EM1008731-057
EP080/071: Total Petroleum Hydrocarbons - Continued C10 - C14 Fraction
----
50
mg/kg
<50
<50
----
<50
<50
C15 - C28 Fraction
----
100
mg/kg
170
<100
----
<100
<100
C29 - C36 Fraction
----
100
mg/kg
130
<100
----
<100
<100
^ C10 - C36 Fraction (sum)
----
50
mg/kg
300
<50
----
<50
<50
Benzene
71-43-2
0.2
mg/kg
<0.2
<0.2
----
<0.2
----
Toluene
108-88-3
0.5
mg/kg
<0.5
<0.5
----
<0.5
----
Ethylbenzene
100-41-4
0.5
mg/kg
<0.5
<0.5
----
<0.5
----
108-38-3 106-42-3
0.5
mg/kg
<0.5
<0.5
----
<0.5
----
95-47-6
0.5
mg/kg
<0.5
<0.5
----
<0.5
----
2051-24-3
0.1
%
----
----
----
----
62.2
17060-07-0
0.1
%
----
----
----
----
101
2037-26-5
0.1
%
----
----
----
----
89.8
460-00-4
0.1
%
----
----
----
----
101
Phenol-d6
13127-88-3
0.1
%
96.3
93.4
----
92.3
----
2-Chlorophenol-D4
93951-73-6
0.1
%
98.9
80.8
----
94.7
----
118-79-6
0.1
%
86.0
85.7
----
78.5
----
2-Fluorobiphenyl
321-60-8
0.1
%
99.1
96.7
----
98.5
----
Anthracene-d10
1719-06-8
0.1
%
88.3
87.2
----
99.0
----
4-Terphenyl-d14
1718-51-0
0.1
%
93.0
89.6
----
91.6
----
EP080: BTEX
meta- & para-Xylene ortho-Xylene
EP066S: PCB Surrogate Decachlorobiphenyl
EP074S: VOC Surrogates 1.2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene
EP075(SIM)S: Phenolic Compound Surrogates
2.4.6-Tribromophenol
EP075(SIM)T: PAH Surrogates
EP075S: Acid Extractable Surrogates 367-12-4
0.1
%
----
----
----
----
Not Determined
Phenol-d6
13127-88-3
0.1
%
----
----
----
----
Not Determined
2-Chlorophenol-D4
93951-73-6
0.1
%
----
----
----
----
Not Determined
118-79-6
0.1
%
----
----
----
----
Not Determined
Nitrobenzene-D5
4165-60-0
0.1
%
----
----
----
----
Not Determined
1.2-Dichlorobenzene-D4
2199-69-1
0.1
%
----
----
----
----
Not Determined
2-Fluorobiphenyl
321-60-8
0.1
%
----
----
----
----
Not Determined
Anthracene-d10
1719-06-8
0.1
%
----
----
----
----
Not Determined
4-Terphenyl-d14
1718-51-0
0.1
%
----
----
----
----
Not Determined
17060-07-0
0.1
%
88.8
96.0
----
89.2
----
2-Fluorophenol
2.4.6-Tribromophenol
EP075T: Base/Neutral Extractable Surrogates
EP080S: TPH(V)/BTEX Surrogates 1.2-Dichloroethane-D4
Page Work Order Client Project
: : : :
66 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
TP12 (2.4-2.5)
DUP3
TP13 (0-0.1)
TP13 (0.4-0.5)
TP13 (1.5-1.6)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-057
EM1008731-058
EM1008731-059
EM1008731-060
EM1008731-061
2037-26-5
0.1
%
84.9
88.2
----
89.0
----
460-00-4
0.1
%
86.8
92.3
----
90.1
----
CAS Number
EP080S: TPH(V)/BTEX Surrogates - Continued Toluene-D8 4-Bromofluorobenzene
Page Work Order Client Project
: : : :
67 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP13 (2.0-2.1)
TP14 (0.9-1.0)
TP14 (1.6-1.7)
TP14 (2.8-2.9)
TP5 (2.0-2.1)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-062
EM1008731-064
EM1008731-065
EM1008731-067
EM1008731-068
1.0
%
35.8
13.7
26.6
26.8
41.3 28
EA055: Moisture Content ----
^ Moisture Content (dried @ 103째C)
EG005T: Total Metals by ICP-AES Arsenic
7440-38-2
5
mg/kg
----
----
----
----
Cadmium
7440-43-9
1
mg/kg
----
----
----
----
2
Copper
7440-50-8
5
mg/kg
----
----
----
----
171
Lead
7439-92-1
5
mg/kg
----
----
----
----
104
Molybdenum
7439-98-7
2
mg/kg
----
----
----
----
<2
Nickel
7440-02-0
2
mg/kg
----
----
----
----
Selenium
7782-49-2
5
mg/kg
----
----
----
----
7 <5
Silver
7440-22-4
2
mg/kg
----
----
----
----
<2
Tin
7440-31-5
5
mg/kg
----
----
----
----
10
Zinc
7440-66-6
5
mg/kg
----
----
----
----
310
Arsenic
7440-38-2
5
mg/kg
<5
119
----
7440-43-9
1
mg/kg
7 <1
148
Cadmium
4
<1
2
----
Chromium
7440-47-3
2
mg/kg
97
92
<2
68
----
Copper
7440-50-8
5
mg/kg
21
568
<5
175
----
Lead
7439-92-1
5
mg/kg
38
354
<5
233
----
Nickel
7440-02-0
2
mg/kg
17
107
<2
69
----
Zinc
7440-66-6
5
mg/kg
109
1130
<5
804
----
7439-97-6
0.1
mg/kg
0.1
0.6
0.6
0.5
2.6
0.5
mg/kg
----
----
----
----
<0.5
----
1
mg/kg
----
----
<1
----
----
57-12-5
1
mg/kg
----
----
<1
----
19
16984-48-8
40
mg/kg
----
----
----
----
190
----
0.10
mg/kg
----
----
----
----
<5.00
Benzene
71-43-2
0.2
mg/kg
----
----
----
----
<0.2
Toluene
108-88-3
0.5
mg/kg
----
----
----
----
<0.5
Ethylbenzene
100-41-4
0.5
mg/kg
----
----
----
----
<0.5
108-38-3 106-42-3
0.5
mg/kg
----
----
----
----
<0.5
100-42-5
0.5
mg/kg
----
----
----
----
<0.5
EG035T: Total Recoverable Mercury by FIMS Mercury
EG048: Hexavalent Chromium (Alkaline Digest) Hexavalent Chromium
18540-29-9
EK025G: Free cyanide by Discrete Analyser Free Cyanide
EK026G: Total Cyanide By Discrete Analyser Total Cyanide
EK040T: Fluoride Total Fluoride
EP066: Polychlorinated Biphenyls (PCB) Total Polychlorinated biphenyls
EP074A: Monocyclic Aromatic Hydrocarbons
meta- & para-Xylene Styrene
Page Work Order Client Project
: : : :
68 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP13 (2.0-2.1)
TP14 (0.9-1.0)
TP14 (1.6-1.7)
TP14 (2.8-2.9)
TP5 (2.0-2.1)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-062
EM1008731-064
EM1008731-065
EM1008731-067
EM1008731-068
95-47-6
0.5
mg/kg
----
----
----
----
<0.5
----
0.2
mg/kg
----
----
----
----
<0.2
----
0.2
mg/kg
----
----
----
----
<0.2
Vinyl chloride
75-01-4
0.02
mg/kg
----
----
----
----
<0.02
1.1-Dichloroethene
75-35-4
0.01
mg/kg
----
----
----
----
<0.01
Methylene chloride
75-09-2
0.4
mg/kg
----
----
----
----
<0.8
trans-1.2-Dichloroethene
156-60-5
0.02
mg/kg
----
----
----
----
<0.02
cis-1.2-Dichloroethene
Compound
CAS Number
EP074A: Monocyclic Aromatic Hydrocarbons - Continued ortho-Xylene ^ Sum of monocyclic aromatic hydrocarbons ^ Sum of monocyclic aromatic hydrocarbons
EP074I: Volatile Halogenated Compounds
156-59-2
0.01
mg/kg
----
----
----
----
<0.01
Chloroform
67-66-3
0.02
mg/kg
----
----
----
----
<0.02
1.1.1-Trichloroethane
71-55-6
0.01
mg/kg
----
----
----
----
<0.01
Carbon Tetrachloride
56-23-5
0.01
mg/kg
----
----
----
----
<0.01
107-06-2
0.02
mg/kg
----
----
----
----
<0.02
Trichloroethene
79-01-6
0.02
mg/kg
----
----
----
----
<0.02
1.1.2-Trichloroethane
79-00-5
0.04
mg/kg
----
----
----
----
<0.04
Tetrachloroethene
127-18-4
0.02
mg/kg
----
----
----
----
<0.02
1.1.1.2-Tetrachloroethane
630-20-6
0.01
mg/kg
----
----
----
----
<0.01
1.1.2.2-Tetrachloroethane
79-34-5
0.02
mg/kg
----
----
----
----
<0.02
Hexachlorobutadiene
87-68-3
0.02
mg/kg
----
----
----
----
<0.02
Chlorobenzene
108-90-7
0.02
mg/kg
----
----
----
----
<0.02
1.4-Dichlorobenzene
106-46-7
0.02
mg/kg
----
----
----
----
0.04
1.2-Dichlorobenzene
95-50-1
0.02
mg/kg
----
----
----
----
120-82-1
0.01
mg/kg
----
----
----
----
0.03 <0.01
----
0.01
mg/kg
----
----
----
----
0.07
----
0.01
mg/kg
----
----
----
----
0.07
----
0.01
mg/kg
----
----
----
----
0.07
----
0.01
mg/kg
----
----
----
----
0.07
1330-20-7
0.50
mg/kg
----
----
----
----
<0.50
1.2-Dichloroethane
1.2.4-Trichlorobenzene ^ Sum of volatile chlorinated hydrocarbons ^ Sum of other chlorinated hydrocarbons (VIC EPA 448.3) ^ Sum of volatile chlorinated hydrocarbons ^ Sum of other chlorinated hydrocarbons (VIC EPA 448.3) ^ Total Xylenes
EP075(SIM)A: Phenolic Compounds 108-95-2
0.5
mg/kg
<0.5
----
----
----
----
2-Chlorophenol
95-57-8
0.5
mg/kg
<0.5
----
----
----
----
2-Methylphenol
95-48-7
0.5
mg/kg
<0.5
----
----
----
----
Phenol
Page Work Order Client Project
: : : :
69 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP13 (2.0-2.1)
TP14 (0.9-1.0)
TP14 (1.6-1.7)
TP14 (2.8-2.9)
TP5 (2.0-2.1)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-062
EM1008731-064
EM1008731-065
EM1008731-067
EM1008731-068
1319-77-3
1.0
mg/kg
<1.0
----
----
----
----
88-75-5
0.5
mg/kg
<0.5
----
----
----
----
2.4-Dimethylphenol
105-67-9
0.5
mg/kg
<0.5
----
----
----
----
2.4-Dichlorophenol
120-83-2
0.5
mg/kg
<0.5
----
----
----
----
2.6-Dichlorophenol
87-65-0
0.5
mg/kg
<0.5
----
----
----
----
4-Chloro-3-Methylphenol
59-50-7
0.5
mg/kg
<0.5
----
----
----
----
2.4.6-Trichlorophenol
88-06-2
0.5
mg/kg
<0.5
----
----
----
----
2.4.5-Trichlorophenol
95-95-4
0.5
mg/kg
<0.5
----
----
----
----
Pentachlorophenol
87-86-5
2.0
mg/kg
<2.0
----
----
----
----
Compound
CAS Number
EP075(SIM)A: Phenolic Compounds - Continued 3- & 4-Methylphenol 2-Nitrophenol
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons 91-20-3
0.5
mg/kg
<0.5
<0.5
<0.5
----
----
208-96-8
0.5
mg/kg
----
<0.5
<0.5
----
----
83-32-9
0.5
mg/kg
----
<0.5
<0.5
----
----
208-96-8
0.5
mg/kg
<0.5
----
----
----
----
Acenaphthene
83-32-9
0.5
mg/kg
<0.5
----
----
----
----
Fluorene
86-73-7
0.5
mg/kg
----
<0.5
<0.5
----
----
Fluorene
86-73-7
0.5
mg/kg
<0.5
----
----
----
----
Phenanthrene
85-01-8
0.5
mg/kg
----
<0.5
<0.5
----
----
120-12-7
0.5
mg/kg
----
<0.5
<0.5
----
----
85-01-8
0.5
mg/kg
<0.5
----
----
----
----
Anthracene
120-12-7
0.5
mg/kg
<0.5
----
----
----
----
Fluoranthene
206-44-0
0.5
mg/kg
----
0.8
<0.5
----
----
Fluoranthene
206-44-0
0.5
mg/kg
<0.5
----
----
----
----
Pyrene
129-00-0
0.5
mg/kg
----
0.7
<0.5
----
----
56-55-3
0.5
mg/kg
----
<0.5
<0.5
----
----
129-00-0
0.5
mg/kg
<0.5
----
----
----
----
56-55-3
0.5
mg/kg
<0.5
----
----
----
----
Chrysene
218-01-9
0.5
mg/kg
----
<0.5
<0.5
----
----
Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
----
0.5
<0.5
----
----
Chrysene
218-01-9
0.5
mg/kg
<0.5
----
----
----
----
Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
<0.5
----
----
----
----
Benzo(k)fluoranthene
207-08-9
0.5
mg/kg
----
<0.5
<0.5
----
----
50-32-8
0.5
mg/kg
----
<0.5
<0.5
----
----
207-08-9
0.5
mg/kg
<0.5
----
----
----
----
50-32-8
0.5
mg/kg
<0.5
----
----
----
----
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
----
<0.5
<0.5
----
----
Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
----
<0.5
<0.5
----
----
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
<0.5
----
----
----
----
Naphthalene Acenaphthylene Acenaphthene Acenaphthylene
Anthracene Phenanthrene
Benz(a)anthracene Pyrene Benz(a)anthracene
Benzo(a)pyrene Benzo(k)fluoranthene Benzo(a)pyrene
Page Work Order Client Project
: : : :
70 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
LOR
Unit
TP13 (2.0-2.1)
TP14 (0.9-1.0)
TP14 (1.6-1.7)
TP14 (2.8-2.9)
TP5 (2.0-2.1)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
EM1008731-062
EM1008731-064
EM1008731-065
EM1008731-067
EM1008731-068
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons - Continued Benzo(g.h.i)perylene Dibenz(a.h)anthracene Benzo(g.h.i)perylene
191-24-2
0.5
mg/kg
----
<0.5
<0.5
----
----
53-70-3
0.5
mg/kg
<0.5
----
----
----
----
191-24-2
0.5
mg/kg
<0.5
----
----
----
----
EP075A: Phenolic Compounds (Halogenated) 95-57-8
0.03
mg/kg
----
----
----
----
<0.12
2.4-Dichlorophenol
120-83-2
0.03
mg/kg
----
----
----
----
<0.12
2.6-Dichlorophenol
87-65-0
0.03
mg/kg
----
----
----
----
<0.12
4-Chloro-3-Methylphenol
59-50-7
0.03
mg/kg
----
----
----
----
<0.12
2.4.5-Trichlorophenol
95-95-4
0.05
mg/kg
----
----
----
----
<0.12
2.4.6-Trichlorophenol
88-06-2
0.05
mg/kg
----
----
----
----
<0.12
935-95-5
0.03
mg/kg
----
----
----
----
<0.12
4901-51-3/58-90-2
0.05
mg/kg
----
----
----
----
<0.24
87-86-5
0.2
mg/kg
----
----
----
----
<0.2
----
0.03
mg/kg
----
----
----
----
<0.12
108-95-2
1
mg/kg
----
----
----
----
<1
95-48-7
1
mg/kg
----
----
----
----
<1
1319-77-3
1
mg/kg
----
----
----
----
<1
88-75-5
1
mg/kg
----
----
----
----
<1
105-67-9
1
mg/kg
----
----
----
----
<1
51-28-5
5
mg/kg
----
----
----
----
<10
2-Chlorophenol
2.3.5.6-Tetrachlorophenol 2.3.4.5 & 2.3.4.6-Tetrachlorophenol Pentachlorophenol ^ Sum of Phenols (halogenated)
EP075A: Phenolic Compounds (Non-halogenated) Phenol 2-Methylphenol 3- & 4-Methylphenol 2-Nitrophenol 2.4-Dimethylphenol 2.4-Dinitrophenol 4-Nitrophenol 2-Methyl-4.6-dinitrophenol Dinoseb 2-Cyclohexyl-4.6-Dinitrophenol ^ Sum of Phenols (non-halogenated)
100-02-7
5
mg/kg
----
----
----
----
<10
8071-51-0
5
mg/kg
----
----
----
----
<10
88-85-7
5
mg/kg
----
----
----
----
<10
131-89-5
5
mg/kg
----
----
----
----
<10
----
1
mg/kg
----
----
----
----
<1
EP075B: Polynuclear Aromatic Hydrocarbons Naphthalene
91-20-3
0.5
mg/kg
----
----
----
----
<0.5
Acenaphthene
83-32-9
0.5
mg/kg
----
----
----
----
<0.5
208-96-8
0.5
mg/kg
----
----
----
----
<0.5
Fluorene
86-73-7
0.5
mg/kg
----
----
----
----
<0.5
Phenanthrene
85-01-8
0.5
mg/kg
----
----
----
----
<0.5
Anthracene
120-12-7
0.5
mg/kg
----
----
----
----
<0.5
Fluoranthene
206-44-0
0.5
mg/kg
----
----
----
----
<0.5
Pyrene
129-00-0
0.5
mg/kg
----
----
----
----
<0.5
56-55-3
0.5
mg/kg
----
----
----
----
<0.5
218-01-9
0.5
mg/kg
----
----
----
----
<0.5
Acenaphthylene
Benz(a)anthracene Chrysene
Page Work Order Client Project
: : : :
71 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP13 (2.0-2.1)
TP14 (0.9-1.0)
TP14 (1.6-1.7)
TP14 (2.8-2.9)
TP5 (2.0-2.1)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-062
EM1008731-064
EM1008731-065
EM1008731-067
EM1008731-068
205-99-2 207-08-9
0.5
mg/kg
----
----
----
----
<0.5
Compound
CAS Number
EP075B: Polynuclear Aromatic Hydrocarbons - Continued Benzo(b) & Benzo(k)fluoranthene Benzo(a)pyrene
50-32-8
0.5
mg/kg
----
----
----
----
<0.5
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
----
----
----
----
<0.5
Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
----
----
----
----
<0.5
191-24-2
0.5
mg/kg
----
----
----
----
<0.5
----
0.5
mg/kg
----
----
----
----
<0.5
alpha-BHC
319-84-6
0.03
mg/kg
----
----
----
----
<0.12
Hexachlorobenzene (HCB)
118-74-1
0.03
mg/kg
----
----
----
----
<0.12
beta-BHC
319-85-7
0.03
mg/kg
----
----
----
----
<0.12
58-89-9
0.03
mg/kg
----
----
----
----
<0.12
delta-BHC
319-86-8
0.03
mg/kg
----
----
----
----
<0.12
Heptachlor
76-44-8
0.03
mg/kg
----
----
----
----
<0.12
309-00-2
0.03
mg/kg
----
----
----
----
<0.12
Heptachlor epoxide
1024-57-3
0.03
mg/kg
----
----
----
----
<0.12
cis-Chlordane
5103-71-9
0.03
mg/kg
----
----
----
----
<0.12
trans-Chlordane
5103-74-2
0.03
mg/kg
----
----
----
----
<0.12
959-98-8
0.03
mg/kg
----
----
----
----
<0.12
4.4`-DDE
72-55-9
0.05
mg/kg
----
----
----
----
<0.12
Dieldrin
60-57-1
0.03
mg/kg
----
----
----
----
<0.12
7421-93-4
0.03
mg/kg
----
----
----
----
<0.12
72-20-8
0.03
mg/kg
----
----
----
----
<0.12
33213-65-9
0.03
mg/kg
----
----
----
----
<0.12
72-54-8
0.05
mg/kg
----
----
----
----
<0.12
1031-07-8
0.03
mg/kg
----
----
----
----
<0.12
4.4`-DDT
50-29-3
0.05
mg/kg
----
----
----
----
<0.12
Methoxychlor
72-43-5
0.03
mg/kg
----
----
----
----
<0.12
----
0.03
mg/kg
----
----
----
----
<0.12
309-00-2/60-57-1
0.03
mg/kg
----
----
----
----
<0.12
----
0.05
mg/kg
----
----
----
----
<0.12
57-74-9
0.03
mg/kg
----
----
----
----
<0.12
----
0.03
mg/kg
----
----
----
----
<0.12
C6 - C9 Fraction
----
10
mg/kg
----
----
----
----
C6 - C9 Fraction
----
10
mg/kg
<10
<10
<10
----
30 ----
Benzo(g.h.i)perylene ^ Sum of polycyclic aromatic hydrocarbons
EP075I: Organochlorine Pesticides
gamma-BHC
Aldrin
Endosulfan 1
Endrin aldehyde Endrin Endosulfan 2 4.4`-DDD Endosulfan sulfate
^ Sum of organochlorine pesticides ^ Sum of Aldrin + Dieldrin ^ Sum of DDD + DDE + DDT ^ Chlordane ^ Sum of other organochlorine pesticides
EP080/071: Total Petroleum Hydrocarbons
Page Work Order Client Project
: : : :
72 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP13 (2.0-2.1)
TP14 (0.9-1.0)
TP14 (1.6-1.7)
TP14 (2.8-2.9)
TP5 (2.0-2.1)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00 EM1008731-068
LOR
Unit
EM1008731-062
EM1008731-064
EM1008731-065
EM1008731-067
EP080/071: Total Petroleum Hydrocarbons - Continued C10 - C14 Fraction
----
50
mg/kg
<50
<50
<50
----
150
C15 - C28 Fraction
----
100
mg/kg
140
270
110
----
4760
C29 - C36 Fraction
----
100
mg/kg
140
540
280
----
7010
^ C10 - C36 Fraction (sum)
----
50
mg/kg
280
810
390
----
11900
Benzene
71-43-2
0.2
mg/kg
<0.2
<0.2
<0.2
----
----
Toluene
108-88-3
0.5
mg/kg
<0.5
<0.5
<0.5
----
----
Ethylbenzene
100-41-4
0.5
mg/kg
<0.5
<0.5
<0.5
----
----
108-38-3 106-42-3
0.5
mg/kg
<0.5
<0.5
<0.5
----
----
95-47-6
0.5
mg/kg
<0.5
<0.5
<0.5
----
----
2051-24-3
0.1
%
----
----
----
----
44.4
17060-07-0
0.1
%
----
----
----
----
106
2037-26-5
0.1
%
----
----
----
----
88.0
460-00-4
0.1
%
----
----
----
----
98.8
Phenol-d6
13127-88-3
0.1
%
89.4
88.7
92.2
----
----
2-Chlorophenol-D4
93951-73-6
0.1
%
96.4
93.7
93.6
----
----
118-79-6
0.1
%
81.8
78.4
80.2
----
----
2-Fluorobiphenyl
321-60-8
0.1
%
96.2
95.6
96.3
----
----
Anthracene-d10
1719-06-8
0.1
%
97.0
85.2
95.0
----
----
4-Terphenyl-d14
1718-51-0
0.1
%
92.7
91.1
91.3
----
----
EP080: BTEX
meta- & para-Xylene ortho-Xylene
EP066S: PCB Surrogate Decachlorobiphenyl
EP074S: VOC Surrogates 1.2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene
EP075(SIM)S: Phenolic Compound Surrogates
2.4.6-Tribromophenol
EP075(SIM)T: PAH Surrogates
EP075S: Acid Extractable Surrogates 367-12-4
0.1
%
----
----
----
----
Not Determined
Phenol-d6
13127-88-3
0.1
%
----
----
----
----
Not Determined
2-Chlorophenol-D4
93951-73-6
0.1
%
----
----
----
----
Not Determined
118-79-6
0.1
%
----
----
----
----
Not Determined
Nitrobenzene-D5
4165-60-0
0.1
%
----
----
----
----
Not Determined
1.2-Dichlorobenzene-D4
2199-69-1
0.1
%
----
----
----
----
Not Determined
2-Fluorobiphenyl
321-60-8
0.1
%
----
----
----
----
Not Determined
Anthracene-d10
1719-06-8
0.1
%
----
----
----
----
Not Determined
4-Terphenyl-d14
1718-51-0
0.1
%
----
----
----
----
Not Determined
17060-07-0
0.1
%
91.2
98.9
93.0
----
----
2-Fluorophenol
2.4.6-Tribromophenol
EP075T: Base/Neutral Extractable Surrogates
EP080S: TPH(V)/BTEX Surrogates 1.2-Dichloroethane-D4
Page Work Order Client Project
: : : :
73 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
TP13 (2.0-2.1)
TP14 (0.9-1.0)
TP14 (1.6-1.7)
TP14 (2.8-2.9)
TP5 (2.0-2.1)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1008731-062
EM1008731-064
EM1008731-065
EM1008731-067
EM1008731-068
2037-26-5
0.1
%
85.3
91.8
87.8
----
----
460-00-4
0.1
%
85.7
93.0
91.2
----
----
CAS Number
EP080S: TPH(V)/BTEX Surrogates - Continued Toluene-D8 4-Bromofluorobenzene
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74 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP11 (2.9-3.0)
TP8 (2.0-2.1)
TP10 (1.8-1.9)
----
----
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
----
----
EM1008731-070
EM1008731-071
----
----
LOR
Unit
EM1008731-069
----
0.5
kg H2SO4/t
----
-46.0
9.2
----
----
----
0.5
kg H2SO4 equiv./t
----
50.0
8.9
----
----
pH KCl (23A)
----
0.1
pH Unit
----
----
8.6
----
----
pH OX (23B)
----
0.1
pH Unit
----
----
7.5
----
----
Titratable Actual Acidity (23F)
----
2
mole H+ / t
----
----
<2
----
----
Titratable Peroxide Acidity (23G)
----
2
mole H+ / t
----
----
<2
----
----
Titratable Sulfidic Acidity (23H)
----
2
mole H+ / t
----
----
<2
----
----
sulfidic - Titratable Actual Acidity (s-23F)
----
0.02
% pyrite S
----
----
<0.02
----
----
sulfidic - Titratable Peroxide Acidity
----
0.02
% pyrite S
----
----
<0.02
----
----
----
0.02
% pyrite S
----
----
<0.02
----
----
KCl Extractable Sulfur (23Ce)
----
0.02
%S
----
----
0.30
----
----
Peroxide Sulfur (23De)
----
0.02
%S
----
----
0.57
----
----
Peroxide Oxidisable Sulfur (23E)
----
0.02
%S
----
----
0.27
----
----
acidity - Peroxide Oxidisable Sulfur
----
10
mole H+ / t
----
----
170
----
----
KCl Extractable Calcium (23Vh)
----
0.02
% Ca
----
----
0.47
----
----
Peroxide Calcium (23Wh)
----
0.02
% Ca
----
----
1.10
----
----
Acid Reacted Calcium (23X)
----
0.02
% Ca
----
----
0.62
----
----
acidity - Acid Reacted Calcium (a-23X)
----
10
mole H+ / t
----
----
312
----
----
sulfidic - Acid Reacted Calcium (s-23X)
----
0.02
%S
----
----
0.50
----
----
KCl Extractable Magnesium (23Sm)
----
0.02
% Mg
----
----
0.05
----
----
Peroxide Magnesium (23Tm)
----
0.02
% Mg
----
----
0.16
----
----
Acid Reacted Magnesium (23U)
----
0.02
% Mg
----
----
0.11
----
----
Acidity - Acid Reacted Magnesium (a-23U)
----
10
mole H+ / t
----
----
92
----
----
sulfidic - Acid Reacted Magnesium
----
0.02
%S
----
----
0.15
----
----
----
0.02
% CaCO3
----
----
0.94
----
----
Compound
CAS Number
EA009: Nett Acid Production Potential ^ Net Acid Production Potential
EA013: Acid Neutralising Capacity ANC as H2SO4
EA029-A: pH Measurements
EA029-B: Acidity Trail
(s-23G) sulfidic - Titratable Sulfidic Acidity (s-23H)
EA029-C: Sulfur Trail
(a-23E)
EA029-D: Calcium Values
EA029-E: Magnesium Values
(s-23U)
EA029-F: Excess Acid Neutralising Capacity Excess Acid Neutralising Capacity (23Q)
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75 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
TP11 (2.9-3.0)
TP8 (2.0-2.1)
TP10 (1.8-1.9)
----
----
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
----
----
EM1008731-070
EM1008731-071
----
----
LOR
Unit
EM1008731-069
----
10
mole H+ / t
----
----
188
----
----
----
0.02
%S
----
----
0.30
----
----
CAS Number
EA029-F: Excess Acid Neutralising Capacity - Continued acidity - Excess Acid Neutralising Capacity (a-23Q) sulfidic - Excess Acid Neutralising Capacity (s-23Q)
EA029-H: Acid Base Accounting ANC Fineness Factor
----
0.5
-
----
----
----
----
0.02
%S
----
----
1.5 <0.02
----
Net Acidity (sulfur units)
----
----
Net Acidity (acidity units)
----
10
mole H+ / t
----
----
<10
----
----
Liming Rate
----
1
kg CaCO3/t
----
----
<1
----
----
pH KCl (23A)
----
0.1
pH Unit
----
----
8.6
----
----
Titratable Actual Acidity (23F)
----
2
mole H+ / t
----
----
<2
----
----
sulfidic - Titratable Actual Acidity (s-23F)
----
0.02
% pyrite S
----
----
<0.02
----
----
Chromium Reducible Sulfur (22B)
----
0.005
%S
----
----
0.153
----
----
acidity - Chromium Reducible Sulfur
----
10
mole H+ / t
----
----
95
----
----
Acid Neutralising Capacity (19A2)
----
0.01
% CaCO3
----
----
1.44
----
----
acidity - Acid Neutralising Capacity
----
10
mole H+ / t
----
----
287
----
----
----
0.01
% pyrite S
----
----
0.46
----
----
EA033-A: Actual Acidity
EA033-B: Potential Acidity
(a-22B)
EA033-C: Acid Neutralising Capacity
(a-19A2) sulfidic - Acid Neutralising Capacity (s-19A2)
EA033-E: Acid Base Accounting ANC Fineness Factor
----
0.5
-
----
----
----
----
0.02
%S
----
----
1.5 <0.02
----
Net Acidity (sulfur units)
----
----
Net Acidity (acidity units)
----
10
mole H+ / t
----
----
<10
----
----
Liming Rate
----
1
kg CaCO3/t
----
----
<1
----
----
----
1.0
%
30.5
1.5
<1.0
----
----
^ Exchangeable Calcium
----
0.1
meq/100g
----
30.8
23.4
----
----
^ Exchangeable Magnesium
----
0.1
meq/100g
----
14.1
3.6
----
----
^ Exchangeable Potassium
----
0.1
meq/100g
----
1.6
0.3
----
----
^ Exchangeable Sodium
----
0.1
meq/100g
----
0.9
0.9
----
----
^ Cation Exchange Capacity
----
0.1
meq/100g
----
47.4
28.3
----
----
^ Exchangeable Aluminium
----
0.1
meq/100g
----
<0.1
<0.1
----
----
EA055: Moisture Content ^ Moisture Content (dried @ 103째C)
ED007: Exchangeable Cations
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76 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP11 (2.9-3.0)
TP8 (2.0-2.1)
TP10 (1.8-1.9)
----
----
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
----
----
EM1008731-070
EM1008731-071
----
----
LOR
Unit
EM1008731-069
ED007: Exchangeable Cations - Continued ^ Exchangeable Calcium Percent
----
0.1
%
----
64.9
82.6
----
----
^ Exchangeable Sodium Percent
----
0.1
%
----
2.0
3.3
----
----
^ Exchangeable Magnesium Percent
----
0.1
%
----
29.7
12.9
----
----
^ Exchangeable Potassium Percent
----
0.1
%
----
3.3
1.2
----
----
^ Calcium/Magnesium Ratio
----
0.1
.
----
2.2
6.4
----
----
----
0.01
%
----
0.13
0.59
----
----
ED042T: Total Sulfur by LECO Sulfur - Total as S (LECO)
ED093S: Soluble Major Cations Calcium
7440-70-2
10
mg/kg
----
160
2360
----
----
Magnesium
7439-95-4
10
mg/kg
----
120
330
----
----
Sodium
7440-23-5
10
mg/kg
----
120
160
----
----
Potassium
7440-09-7
10
mg/kg
----
70
70
----
----
EG005S : Soluble Metals by ICPAES Aluminium
7429-90-5
1
mg/kg
----
<1
<1
----
----
Manganese
7439-96-5
0.1
mg/kg
----
0.9
5.6
----
----
Arsenic
7440-38-2
5
mg/kg
----
----
----
7440-43-9
1
mg/kg
15 <1
----
Cadmium
----
----
----
----
Chromium
7440-47-3
2
mg/kg
6
----
----
----
----
Copper
7440-50-8
5
mg/kg
53
----
----
----
----
Lead
7439-92-1
5
mg/kg
24
----
----
----
----
Nickel
7440-02-0
2
mg/kg
5
----
----
----
----
Zinc
7440-66-6
5
mg/kg
79
----
----
----
----
7439-97-6
0.1
mg/kg
0.9
----
----
----
----
----
0.5
%
----
1.2
1.5
----
----
EG005T: Total Metals by ICP-AES
EG035T: Total Recoverable Mercury by FIMS Mercury
EP004: Organic Matter ^ Total Organic Carbon
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons 91-20-3
0.5
mg/kg
0.8
----
----
----
----
208-96-8
0.5
mg/kg
0.5
----
----
----
----
Acenaphthene
83-32-9
0.5
mg/kg
<0.5
----
----
----
----
Fluorene
86-73-7
0.5
mg/kg
1.3
----
----
----
----
Phenanthrene
85-01-8
0.5
mg/kg
4.3
----
----
----
----
Anthracene
120-12-7
0.5
mg/kg
1.0
----
----
----
----
Fluoranthene
206-44-0
0.5
mg/kg
4.3
----
----
----
----
Pyrene
129-00-0
0.5
mg/kg
4.2
----
----
----
----
56-55-3
0.5
mg/kg
2.0
----
----
----
----
Naphthalene Acenaphthylene
Benz(a)anthracene
Page Work Order Client Project
: : : :
77 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Results Client sample ID
Sub-Matrix: SOIL
TP11 (2.9-3.0)
TP8 (2.0-2.1)
TP10 (1.8-1.9)
----
----
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
----
----
Unit
EM1008731-069
EM1008731-070
EM1008731-071
----
----
Client sampling date / time Compound
CAS Number
LOR
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons - Continued Chrysene
218-01-9
0.5
mg/kg
2.1
----
----
----
----
Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
2.3
----
----
----
----
Benzo(k)fluoranthene
207-08-9
0.5
mg/kg
0.7
----
----
----
----
50-32-8
0.5
mg/kg
1.8
----
----
----
----
Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
1.0
----
----
----
----
Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
<0.5
----
----
----
----
191-24-2
0.5
mg/kg
1.3
----
----
----
----
C6 - C9 Fraction
----
10
mg/kg
<10
----
----
----
----
C10 - C14 Fraction
----
50
mg/kg
<50
----
----
----
----
C15 - C28 Fraction
----
100
mg/kg
1050
----
----
----
----
C29 - C36 Fraction
----
100
mg/kg
1530
----
----
----
----
^ C10 - C36 Fraction (sum)
----
50
mg/kg
2580
----
----
----
----
Benzene
71-43-2
0.2
mg/kg
<0.2
----
----
----
----
Toluene
108-88-3
0.5
mg/kg
<0.5
----
----
----
----
Ethylbenzene
100-41-4
0.5
mg/kg
<0.5
----
----
----
----
108-38-3 106-42-3
0.5
mg/kg
<0.5
----
----
----
----
95-47-6
0.5
mg/kg
<0.5
----
----
----
----
Phenol-d6
13127-88-3
0.1
%
102
----
----
----
----
2-Chlorophenol-D4
93951-73-6
0.1
%
88.3
----
----
----
----
118-79-6
0.1
%
89.9
----
----
----
----
2-Fluorobiphenyl
321-60-8
0.1
%
100
----
----
----
----
Anthracene-d10
1719-06-8
0.1
%
91.9
----
----
----
----
4-Terphenyl-d14
1718-51-0
0.1
%
100
----
----
----
----
17060-07-0
0.1
%
100
----
----
----
----
2037-26-5
0.1
%
93.2
----
----
----
----
460-00-4
0.1
%
95.8
----
----
----
----
Benzo(a)pyrene
Benzo(g.h.i)perylene
EP080/071: Total Petroleum Hydrocarbons
EP080: BTEX
meta- & para-Xylene ortho-Xylene
EP075(SIM)S: Phenolic Compound Surrogates
2.4.6-Tribromophenol
EP075(SIM)T: PAH Surrogates
EP080S: TPH(V)/BTEX Surrogates 1.2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene
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78 of 78 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Surrogate Control Limits Sub-Matrix: SOIL
Recovery Limits (%)
CAS Number
Low
High
2051-24-3
42.4
131
17060-07-0
80.0
120
2037-26-5
81.0
117
460-00-4
74.0
121
Phenol-d6
13127-88-3
48.5
123.5
2-Chlorophenol-D4
93951-73-6
51.8
129.7
118-79-6
26.8
126.6
2-Fluorobiphenyl
321-60-8
57.9
125.2
Anthracene-d10
1719-06-8
62.6
135.5
4-Terphenyl-d14
1718-51-0
63.7
135.2
Compound
EP066S: PCB Surrogate Decachlorobiphenyl
EP074S: VOC Surrogates 1.2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene
EP075(SIM)S: Phenolic Compound Surrogates
2.4.6-Tribromophenol
EP075(SIM)T: PAH Surrogates
EP075S: Acid Extractable Surrogates 367-12-4
16.0
142.2
Phenol-d6
13127-88-3
20.1
125.8
2-Chlorophenol-D4
93951-73-6
19.9
122.9
118-79-6
10.0
134.6
Nitrobenzene-D5
4165-60-0
24.5
123.2
1.2-Dichlorobenzene-D4
2199-69-1
24.3
122.9
2-Fluorobiphenyl
321-60-8
35.1
125.3
Anthracene-d10
1719-06-8
40.8
129.9
4-Terphenyl-d14
1718-51-0
39.1
141.3
17060-07-0
59.0
126.2
2037-26-5
59.5
128.6
460-00-4
56.4
129.9
2-Fluorophenol
2.4.6-Tribromophenol
EP075T: Base/Neutral Extractable Surrogates
EP080S: TPH(V)/BTEX Surrogates 1.2-Dichloroethane-D4 Toluene-D8 4-Bromofluorobenzene
False
QUALITY CONTROL REPORT :
Page
: 1 of 28
Amendment
EM1008731 :1
Client
: ENVIRONMENTAL EARTH SCIENCES
Laboratory
: Environmental Division Melbourne
Contact
: MR JORDAN FRASER
Contact
: Steven McGrath
Address
: P.O.BOX 2253
Address
: 4 Westall Rd Springvale VIC Australia 3171
Work Order
FOOTSCRAY VIC, AUSTRALIA 3011 E-mail
: jfraser@eesi.biz
: steven.mcgrath@alsenviro.com
Telephone
: +61 03 96871666
Telephone
: +61-3-8549 9600
Facsimile
: +61 03 96871844
Facsimile
: +61-3-8549 9601
Project
: 210061
QC Level
: NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Site
: YARRAVILLE
C-O-C number
: ----
Date Samples Received
: 11-AUG-2010
Sampler
: JF
Issue Date
: 27-AUG-2010
Order number
: ----
Quote number
: EN/010/10
No. of samples received
: 71
No. of samples analysed
: 63
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. All pages of this report have been checked and approved for release. This Quality Control Report contains the following information: l Laboratory Duplicate (DUP) Report ; Relative Percentage Difference (RPD) and Acceptance Limits l Method Blank (MB) and Laboratory Control Spike (LCS) Report ; Recovery and Acceptance Limits l Matrix Spike (MS) Report ; Recovery and Acceptance Limits
NATA Accredited Laboratory 825 This document is issued in accordance with NATA accreditation requirements. Accredited for compliance with ISO/IEC 17025.
Signatories This document has been electronically signed by the authorized signatories indicated below. Electronic signing has been carried out in compliance with procedures specified in 21 CFR Part 11. Signatories
Position
Accreditation Category
Emily Yuen Myles.Clark Myles.Clark Nancy Wang Nikki Stepniewski Stephen Hislop Stephen Hislop Xingbin Lin
Senior Organic Instrument Chemist Acid Sulfate Soils Supervisor Acid Sulfate Soils Supervisor Senior Semivolatile Instrument Chemist Non-metallic Supervisor Senior Inorganic Chemist Senior Inorganic Chemist Senior Organic Chemist
Organics Bne Acid Sulphate Soils Inorganics Organics Inorganics Inorganics Stafford Minerals - AY Organics
Page Work Order Client Project
: : : :
3 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
General Comments The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, developed procedures are employed in the absence of documented standards or by client request. Where moisture determination has been performed, results are reported on a dry weight basis. Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insuffient sample for analysis. Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference. Key :
Anonymous = Refers to samples which are not specifically part of this work order but formed part of the QC process lot CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society. LOR = Limit of reporting RPD = Relative Percentage Difference # = Indicates failed QC
APHA, AS and NEPM. In house
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4 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Laboratory Duplicate (DUP) Report The quality control term Laboratory Duplicate refers to a randomly selected intralaboratory split. Laboratory duplicates provide information regarding method precision and sample heterogeneity. The permitted ranges for the Relative Percent Deviation (RPD) of Laboratory Duplicates are specified in ALS Method QWI -EN/38 and are dependent on the magnitude of results in comparison to the level of reporting: Result < 10 times LOR:No Limit; Result between 10 and 20 times LOR:- 0% - 50%; Result > 20 times LOR:- 0% - 20%. Laboratory Duplicate (DUP) Report
Sub-Matrix: SOIL Laboratory sample ID
Client sample ID
CAS Number
LOR
Unit
Original Result
Duplicate Result
RPD (%)
Recovery Limits (%)
EA013: ANC as H2SO4
----
0.5
kg H2SO4/t
<0.5
<0.5
0.0
No Limit
EA029: pH KCl (23A)
----
0.1
pH Unit
7.5
7.7
2.6
0% - 20%
EA029: pH OX (23B)
----
0.1
pH Unit
6.6
6.6
0.0
0% - 20%
EA029: sulfidic - Titratable Actual Acidity (s-23F)
----
0.02
% pyrite S
<0.02
<0.02
0.0
No Limit
EA029: sulfidic - Titratable Peroxide Acidity (s-23G)
----
0.02
% pyrite S
<0.02
<0.02
0.0
No Limit
EA029: sulfidic - Titratable Sulfidic Acidity (s-23H)
----
0.02
% pyrite S
<0.02
<0.02
0.0
No Limit
EA029: Titratable Actual Acidity (23F)
----
2
mole H+ / t
<2
<2
0.0
No Limit
EA029: Titratable Peroxide Acidity (23G)
----
2
mole H+ / t
<2
<2
0.0
No Limit
EA029: Titratable Sulfidic Acidity (23H)
----
2
mole H+ / t
<2
<2
0.0
No Limit
EA029: KCl Extractable Sulfur (23Ce)
----
0.02
%S
0.06
0.07
23.2
No Limit
EA029: Peroxide Sulfur (23De)
----
0.02
%S
0.10
0.10
0.0
No Limit
EA029: Peroxide Oxidisable Sulfur (23E)
----
0.02
%S
0.04
0.03
36.4
No Limit
EA029: acidity - Peroxide Oxidisable Sulfur (a-23E)
----
10
mole H+ / t
26
18
36.4
No Limit
EA029: KCl Extractable Calcium (23Vh)
----
0.02
% Ca
0.25
0.35
30.7
0% - 50%
EA029: Peroxide Calcium (23Wh)
----
0.02
% Ca
0.47
0.49
4.3
0% - 20%
EA029: Acid Reacted Calcium (23X)
----
0.02
% Ca
0.21
0.14
40.4
No Limit
EA029: sulfidic - Acid Reacted Calcium (s-23X)
----
0.02
%S
0.17
0.11
40.4
No Limit
EA029: acidity - Acid Reacted Calcium (a-23X)
----
10
mole H+ / t
106
71
40.4
No Limit
EA029: KCl Extractable Magnesium (23Sm)
----
0.02
% Mg
0.12
0.16
24.4
No Limit
EA029: Peroxide Magnesium (23Tm)
----
0.02
% Mg
0.22
0.23
5.5
0% - 50%
EA029: Acid Reacted Magnesium (23U)
----
0.02
% Mg
0.09
0.07
27.4
No Limit
EA029: sulfidic - Acid Reacted Magnesium (s-23U)
----
0.02
%S
0.12
0.09
27.4
No Limit
EA029: Acidity - Acid Reacted Magnesium (a-23U)
----
10
mole H+ / t
77
58
27.4
No Limit
----
0.02
% CaCO3
0.07
0.06
17.5
No Limit
Method: Compound
EA013: Acid Neutralising Capacity (QC Lot: 1456094) EM1008659-001
Anonymous
EA029-A: pH Measurements (QC Lot: 1456095) EM1008731-020
TP4 (2.1-2.2)
EA029-B: Acidity Trail (QC Lot: 1456095) EM1008731-020
TP4 (2.1-2.2)
EA029-C: Sulfur Trail (QC Lot: 1456095) EM1008731-020
TP4 (2.1-2.2)
EA029-D: Calcium Values (QC Lot: 1456095) EM1008731-020
TP4 (2.1-2.2)
EA029-E: Magnesium Values (QC Lot: 1456095) EM1008731-020
TP4 (2.1-2.2)
EA029-F: Excess Acid Neutralising Capacity (QC Lot: 1456095) EM1008731-020
TP4 (2.1-2.2)
EA029: Excess Acid Neutralising Capacity (23Q)
Page Work Order Client Project
: : : :
5 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Laboratory Duplicate (DUP) Report
Sub-Matrix: SOIL Laboratory sample ID
Client sample ID
CAS Number
LOR
Unit
Original Result
Duplicate Result
RPD (%)
Recovery Limits (%)
EA029: sulfidic - Excess Acid Neutralising Capacity (s-23Q)
----
0.02
%S
0.02
<0.02
0.0
No Limit
EA029: acidity - Excess Acid Neutralising Capacity (a-23Q)
----
10
mole H+ / t
14
12
17.5
No Limit
EA033: sulfidic - Titratable Actual Acidity (s-23F)
----
0.02
% pyrite S
<0.02
<0.02
0.0
No Limit
EA033: Titratable Actual Acidity (23F)
----
2
mole H+ / t
<2
<2
0.0
No Limit
EA033: pH KCl (23A)
----
0.1
pH Unit
7.5
7.7
2.6
0% - 20%
EA033: Chromium Reducible Sulfur (22B)
----
0.005
%S
0.006
0.006
0.0
No Limit
EA033: acidity - Chromium Reducible Sulfur (a-22B)
----
10
mole H+ / t
<10
<10
0.0
No Limit
EA033: Acid Neutralising Capacity (19A2)
----
0.01
% CaCO3
2.68
2.59
3.6
0% - 20%
EA033: sulfidic - Acid Neutralising Capacity (s-19A2)
----
0.01
% pyrite S
0.86
0.83
3.6
0% - 20%
EA033: acidity - Acid Neutralising Capacity (a-19A2)
----
10
mole H+ / t
536
517
3.6
0% - 20%
Method: Compound
EA029-F: Excess Acid Neutralising Capacity (QC Lot: 1456095) - continued EM1008731-020
TP4 (2.1-2.2)
EA033-A: Actual Acidity (QC Lot: 1456096) EM1008731-020
TP4 (2.1-2.2)
EA033-B: Potential Acidity (QC Lot: 1456096) EM1008731-020
TP4 (2.1-2.2)
EA033-C: Acid Neutralising Capacity (QC Lot: 1456096) EM1008731-020
TP4 (2.1-2.2)
EA055: Moisture Content (QC Lot: 1449403) EM1008731-001
TP1 (0.4-0.5)
EA055-103: Moisture Content (dried @ 103°C)
----
1.0
%
20.7
17.6
16.5
0% - 50%
EM1008731-013
TP3 (1.4-1.5)
EA055-103: Moisture Content (dried @ 103°C)
----
1.0
%
25.4
23.0
9.9
0% - 20%
EA055: Moisture Content (QC Lot: 1449404) EM1008731-023
TP5 (2.9-3.0)
EA055-103: Moisture Content (dried @ 103°C)
----
1.0
%
47.7
49.3
3.1
0% - 20%
EM1008731-035
TP8 (0.9-1.0)
EA055-103: Moisture Content (dried @ 103°C)
----
1.0
%
13.6
17.0
22.5
0% - 50%
EA055: Moisture Content (QC Lot: 1449405) EM1008731-046
TP10 (1.4-1.5)
EA055-103: Moisture Content (dried @ 103°C)
----
1.0
%
10.5
10.8
3.1
0% - 50%
EM1008731-057
TP12 (2.4-2.5)
EA055-103: Moisture Content (dried @ 103°C)
----
1.0
%
33.6
33.5
0.0
0% - 20%
EA055-103: Moisture Content (dried @ 103°C)
----
1.0
%
30.5
28.1
8.2
0% - 20%
EA055: Moisture Content (QC Lot: 1449406) EM1008731-069
TP11 (2.9-3.0)
EA055: Moisture Content (QC Lot: 1451184) EB1014189-015
Anonymous
EA055-103: Moisture Content (dried @ 103°C)
----
1.0
%
15.1
14.6
3.8
0% - 50%
EB1014189-041
Anonymous
EA055-103: Moisture Content (dried @ 103°C)
----
1.0
%
13.4
13.6
1.8
0% - 50%
ED007: Exchangeable Calcium
----
0.1
meq/100g
26.7
28.0
5.0
0% - 20%
ED007: Exchangeable Magnesium
----
0.1
meq/100g
16.8
17.6
4.6
0% - 20%
ED007: Exchangeable Potassium
----
0.1
meq/100g
1.8
1.9
6.1
0% - 50%
ED007: Exchangeable Sodium
----
0.1
meq/100g
2.4
2.5
4.1
0% - 20%
ED007: Exchangeable Aluminium
----
0.1
meq/100g
<0.1
<0.1
0.0
No Limit
ED007: Exchangeable Cations (QC Lot: 1454744) EM1008731-014
TP3 (2.0-2.1)
ED042T: Total Sulfur by LECO (QC Lot: 1451827)
Page Work Order Client Project
: : : :
6 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Laboratory Duplicate (DUP) Report
Sub-Matrix: SOIL Laboratory sample ID
Client sample ID
Method: Compound
CAS Number
LOR
Unit
Original Result
Duplicate Result
RPD (%)
Recovery Limits (%)
----
0.01
%
0.06
0.07
0.0
No Limit 0% - 50%
ED042T: Total Sulfur by LECO (QC Lot: 1451827) - continued EM1008731-014
TP3 (2.0-2.1)
ED042T: Sulfur - Total as S (LECO)
ED093S: Soluble Major Cations (QC Lot: 1449452) EM1008731-014
TP3 (2.0-2.1)
ED093S: Calcium
7440-70-2
10
mg/kg
100
100
0.0
ED093S: Magnesium
7439-95-4
10
mg/kg
90
90
0.0
No Limit
ED093S: Sodium
7440-23-5
10
mg/kg
220
230
5.1
0% - 20%
ED093S: Potassium
7440-09-7
10
mg/kg
40
50
0.0
No Limit
ED093S: Calcium
7440-70-2
10
mg/kg
160
160
0.0
0% - 50%
ED093S: Magnesium
7439-95-4
10
mg/kg
120
120
0.0
0% - 50%
ED093S: Sodium
7440-23-5
10
mg/kg
120
120
0.0
0% - 50%
ED093S: Potassium
7440-09-7
10
mg/kg
70
80
0.0
No Limit
EG005S: Manganese
7439-96-5
0.1
mg/kg
<0.1
<0.1
0.0
No Limit
EG005S: Aluminium
7429-90-5
1
mg/kg
<1
<1
0.0
No Limit
EG005S: Manganese
7439-96-5
0.1
mg/kg
0.9
0.9
0.0
No Limit
EG005S: Aluminium
7429-90-5
1
mg/kg
<1
<1
0.0
No Limit
EG005T: Cadmium
7440-43-9
1
mg/kg
2
2
0.0
No Limit
EG005T: Chromium
7440-47-3
2
mg/kg
59
51
14.2
0% - 20%
EG005T: Molybdenum
7439-98-7
2
mg/kg
4
5
0.0
No Limit
EG005T: Nickel
7440-02-0
2
mg/kg
76
71
6.0
0% - 20%
EG005T: Silver
7440-22-4
2
mg/kg
13
11
18.0
No Limit
EG005T: Arsenic
7440-38-2
5
mg/kg
113
96
16.4
0% - 50%
EG005T: Copper
7440-50-8
5
mg/kg
265
300
12.3
0% - 20%
EG005T: Lead
7439-92-1
5
mg/kg
191
217
12.9
0% - 20%
EG005T: Selenium
7782-49-2
5
mg/kg
<5
<5
0.0
No Limit
EG005T: Tin
7440-31-5
5
mg/kg
355
331
7.0
0% - 20%
EG005T: Zinc
7440-66-6
5
mg/kg
496
527
6.0
0% - 20%
EG005T: Cadmium
7440-43-9
1
mg/kg
2
2
0.0
No Limit
EG005T: Chromium
7440-47-3
2
mg/kg
92
82
10.3
0% - 20%
EG005T: Molybdenum
7439-98-7
2
mg/kg
10
11
0.0
No Limit
EG005T: Nickel
7440-02-0
2
mg/kg
76
84
10.0
0% - 20%
EG005T: Silver
7440-22-4
2
mg/kg
5
5
0.0
No Limit
EG005T: Arsenic
7440-38-2
5
mg/kg
53
42
23.6
No Limit
EG005T: Copper
7440-50-8
5
mg/kg
463
520
11.6
0% - 20%
EG005T: Lead
7439-92-1
5
mg/kg
731
828
12.4
0% - 20%
EG005T: Selenium
7782-49-2
5
mg/kg
<5
<5
0.0
No Limit
EG005T: Tin
7440-31-5
5
mg/kg
176
183
4.2
0% - 20%
ED093S: Soluble Major Cations (QC Lot: 1454735) EM1008731-070
TP8 (2.0-2.1)
EG005S : Soluble Metals by ICPAES (QC Lot: 1449451) EM1008731-014
TP3 (2.0-2.1)
EG005S : Soluble Metals by ICPAES (QC Lot: 1454734) EM1008731-070
TP8 (2.0-2.1)
EG005T: Total Metals by ICP-AES (QC Lot: 1449037) EM1008731-001
EM1008731-012
TP1 (0.4-0.5)
TP3 (0.4-0.5)
Page Work Order Client Project
: : : :
7 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Laboratory Duplicate (DUP) Report
Sub-Matrix: SOIL Laboratory sample ID
Client sample ID
LOR
Unit
Original Result
Duplicate Result
RPD (%)
Recovery Limits (%)
7440-66-6
5
mg/kg
810
930
13.8
0% - 20%
EG005T: Cadmium
7440-43-9
1
mg/kg
1
1
0.0
No Limit
EG005T: Chromium
7440-47-3
2
mg/kg
38
37
0.0
0% - 50%
EG005T: Molybdenum
7439-98-7
2
mg/kg
8
7
0.0
No Limit
EG005T: Nickel
7440-02-0
2
mg/kg
48
42
12.6
0% - 20%
EG005T: Silver
7440-22-4
2
mg/kg
12
8
36.6
No Limit
EG005T: Arsenic
7440-38-2
5
mg/kg
43
40
9.2
No Limit
EG005T: Copper
7440-50-8
5
mg/kg
247
238
3.4
0% - 20%
EG005T: Lead
7439-92-1
5
mg/kg
175
173
1.3
0% - 20%
EG005T: Selenium
7782-49-2
5
mg/kg
<5
<5
0.0
No Limit
EG005T: Tin
7440-31-5
5
mg/kg
95
97
1.9
0% - 50%
EG005T: Zinc
7440-66-6
5
mg/kg
439
425
3.2
0% - 20%
EG005T: Cadmium
7440-43-9
1
mg/kg
2
2
0.0
No Limit
EG005T: Chromium
7440-47-3
2
mg/kg
59
52
12.7
0% - 20%
EG005T: Molybdenum
7439-98-7
2
mg/kg
<2
<2
0.0
No Limit
EG005T: Nickel
7440-02-0
2
mg/kg
94
93
0.0
0% - 20%
EG005T: Silver
7440-22-4
2
mg/kg
4
4
0.0
No Limit
EG005T: Arsenic
7440-38-2
5
mg/kg
174
148
16.5
0% - 20%
EG005T: Copper
7440-50-8
5
mg/kg
132
116
13.2
0% - 20%
EG005T: Lead
7439-92-1
5
mg/kg
144
167
15.1
0% - 20%
EG005T: Selenium
7782-49-2
5
mg/kg
<5
<5
0.0
No Limit
EG005T: Tin
7440-31-5
5
mg/kg
799
680
16.1
0% - 20%
EG005T: Zinc
7440-66-6
5
mg/kg
614
595
3.3
0% - 20%
EG005T: Cadmium
7440-43-9
1
mg/kg
<1
<1
0.0
No Limit
EG005T: Chromium
7440-47-3
2
mg/kg
26
27
4.2
0% - 50%
EG005T: Molybdenum
7439-98-7
2
mg/kg
<2
<2
0.0
No Limit
EG005T: Nickel
7440-02-0
2
mg/kg
23
24
0.0
0% - 50%
EG005T: Silver
7440-22-4
2
mg/kg
5
6
0.0
No Limit
EG005T: Arsenic
7440-38-2
5
mg/kg
10
11
0.0
No Limit
EG005T: Copper
7440-50-8
5
mg/kg
66
68
4.2
0% - 50%
EG005T: Lead
7439-92-1
5
mg/kg
514
536
4.2
0% - 20%
EG005T: Selenium
7782-49-2
5
mg/kg
<5
<5
0.0
No Limit
EG005T: Tin
7440-31-5
5
mg/kg
15
15
0.0
No Limit
EG005T: Zinc
7440-66-6
5
mg/kg
492
514
4.2
0% - 20%
EG005T: Cadmium
7440-43-9
1
mg/kg
<1
<1
0.0
No Limit
EG005T: Chromium
7440-47-3
2
mg/kg
36
38
3.2
0% - 50%
EG005T: Molybdenum
7439-98-7
2
mg/kg
<2
<2
0.0
No Limit
Method: Compound
CAS Number
EG005T: Total Metals by ICP-AES (QC Lot: 1449037) - continued EM1008731-012
TP3 (0.4-0.5)
EG005T: Zinc
EG005T: Total Metals by ICP-AES (QC Lot: 1449039) EM1008731-025
EM1008731-036
TP6 (0-0.1)
TP8 (1.9-2.0)
EG005T: Total Metals by ICP-AES (QC Lot: 1449200) EM1008731-050
EM1008731-060
TP11 (0-0.1)
TP13 (0.4-0.5)
Page Work Order Client Project
: : : :
8 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Laboratory Duplicate (DUP) Report
Sub-Matrix: SOIL Laboratory sample ID
Client sample ID
Method: Compound
CAS Number
LOR
Unit
Original Result
Duplicate Result
RPD (%)
Recovery Limits (%)
EG005T: Total Metals by ICP-AES (QC Lot: 1449200) - continued EM1008731-060
TP13 (0.4-0.5)
EG005T: Nickel
7440-02-0
2
mg/kg
49
48
0.0
0% - 20%
EG005T: Silver
7440-22-4
2
mg/kg
4
3
35.2
No Limit
EG005T: Arsenic
7440-38-2
5
mg/kg
8
9
12.4
No Limit
EG005T: Copper
7440-50-8
5
mg/kg
24
22
8.9
No Limit
EG005T: Lead
7439-92-1
5
mg/kg
38
32
17.8
No Limit
EG005T: Selenium
7782-49-2
5
mg/kg
<5
<5
0.0
No Limit
EG005T: Tin
7440-31-5
5
mg/kg
11
17
40.5
No Limit
EG005T: Zinc
7440-66-6
5
mg/kg
88
67
26.7
0% - 50%
EG035T: Total Recoverable Mercury by FIMS (QC Lot: 1449038) EM1008731-001
TP1 (0.4-0.5)
EG035T: Mercury
7439-97-6
0.1
mg/kg
0.5
0.4
28.8
No Limit
EM1008731-012
TP3 (0.4-0.5)
EG035T: Mercury
7439-97-6
0.1
mg/kg
0.7
0.5
34.6
No Limit
EG035T: Total Recoverable Mercury by FIMS (QC Lot: 1449040) EM1008731-025
TP6 (0-0.1)
EG035T: Mercury
7439-97-6
0.1
mg/kg
0.4
0.3
0.0
No Limit
EM1008731-036
TP8 (1.9-2.0)
EG035T: Mercury
7439-97-6
0.1
mg/kg
0.2
0.2
0.0
No Limit
EG035T: Total Recoverable Mercury by FIMS (QC Lot: 1449201) EM1008731-050
TP11 (0-0.1)
EG035T: Mercury
7439-97-6
0.1
mg/kg
0.2
0.1
0.0
No Limit
EM1008731-060
TP13 (0.4-0.5)
EG035T: Mercury
7439-97-6
0.1
mg/kg
<0.1
<0.1
0.0
No Limit
EG048: Hexavalent Chromium (Alkaline Digest) (QC Lot: 1449399) EM1008731-003
TP1 (1.5-1.6)
EG048: Hexavalent Chromium
18540-29-9
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EM1008780-004
Anonymous
EG048: Hexavalent Chromium
18540-29-9
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
----
1
mg/kg
<1
<1
0.0
No Limit
EK025G: Free cyanide by Discrete Analyser (QC Lot: 1449301) EM1008731-016
TP4 (0-0.1)
EK025G: Free Cyanide
EK026G: Total Cyanide By Discrete Analyser (QC Lot: 1449415) EM1008731-003
TP1 (1.5-1.6)
EK026G: Total Cyanide
57-12-5
1
mg/kg
<1
<1
0.0
No Limit
EM1008731-046
TP10 (1.4-1.5)
EK026G: Total Cyanide
57-12-5
1
mg/kg
<1
<1
0.0
No Limit
16984-48-8
40
mg/kg
80
80
0.0
No Limit
EP004: Total Organic Carbon
----
0.5
%
2.4
2.5
0.0
No Limit
EP004: Total Organic Carbon
----
0.5
%
6.6
6.5
0.0
0% - 50%
----
0.10
mg/kg
<5.00
<5.00
0.0
No Limit
EP074-UT: Benzene
71-43-2
0.2
mg/kg
<0.2
<0.2
0.0
No Limit
EP074-UT: Toluene
108-88-3
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP074-UT: Ethylbenzene
100-41-4
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EK040T: Fluoride Total (QC Lot: 1449032) EM1008731-003
TP1 (1.5-1.6)
EK040T: Fluoride
EP004: Organic Matter (QC Lot: 1448903) EM1008731-014
TP3 (2.0-2.1)
EP004: Organic Matter (QC Lot: 1451345) EB1014155-001
Anonymous
EP066: Polychlorinated Biphenyls (PCB) (QC Lot: 1449129) EM1008731-003
TP1 (1.5-1.6)
EP066-EM: Total Polychlorinated biphenyls
EP074A: Monocyclic Aromatic Hydrocarbons (QC Lot: 1449031) EM1008731-003
TP1 (1.5-1.6)
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9 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Laboratory Duplicate (DUP) Report
Sub-Matrix: SOIL Laboratory sample ID
Client sample ID
Method: Compound
CAS Number
LOR
Unit
Original Result
Duplicate Result
RPD (%)
Recovery Limits (%)
108-38-3 106-42-3 100-42-5
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
95-47-6
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP074A: Monocyclic Aromatic Hydrocarbons (QC Lot: 1449031) - continued EM1008731-003
TP1 (1.5-1.6)
EP074-UT: meta- & para-Xylene EP074-UT: Styrene EP074-UT: ortho-Xylene
EP074I: Volatile Halogenated Compounds (QC Lot: 1449031) EM1008731-003
TP1 (1.5-1.6)
75-35-4
0.01
mg/kg
<0.01
<0.01
0.0
No Limit
EP074-UT: cis-1.2-Dichloroethene
156-59-2
0.01
mg/kg
<0.01
<0.01
0.0
No Limit
EP074-UT: 1.1.1-Trichloroethane
71-55-6
0.01
mg/kg
<0.01
<0.01
0.0
No Limit
EP074-UT: Carbon Tetrachloride
56-23-5
0.01
mg/kg
<0.01
<0.01
0.0
No Limit
EP074-UT: 1.1.1.2-Tetrachloroethane
630-20-6
0.01
mg/kg
<0.01
<0.01
0.0
No Limit
EP074-UT: 1.2.4-Trichlorobenzene
120-82-1
0.01
mg/kg
<0.01
<0.01
0.0
No Limit
75-01-4
0.02
mg/kg
<0.02
<0.02
0.0
No Limit
156-60-5
0.02
mg/kg
<0.02
<0.02
0.0
No Limit
67-66-3
0.02
mg/kg
<0.02
<0.02
0.0
No Limit
107-06-2
0.02
mg/kg
<0.02
<0.02
0.0
No Limit
79-01-6
0.02
mg/kg
<0.02
<0.02
0.0
No Limit
127-18-4
0.02
mg/kg
<0.02
<0.02
0.0
No Limit
EP074-UT: 1.1.2.2-Tetrachloroethane
79-34-5
0.02
mg/kg
<0.02
<0.02
0.0
No Limit
EP074-UT: Hexachlorobutadiene
87-68-3
0.02
mg/kg
<0.02
<0.02
0.0
No Limit
EP074-UT: Chlorobenzene
108-90-7
0.02
mg/kg
<0.02
<0.02
0.0
No Limit
EP074-UT: 1.4-Dichlorobenzene
106-46-7
0.02
mg/kg
<0.02
<0.02
0.0
No Limit
EP074-UT: 1.2-Dichlorobenzene
95-50-1
0.02
mg/kg
<0.02
<0.02
0.0
No Limit
EP074-UT: 1.1.2-Trichloroethane
79-00-5
0.04
mg/kg
<0.04
<0.04
0.0
No Limit
EP074-UT: Methylene chloride
75-09-2
0.4
mg/kg
<0.6
<0.6
0.0
No Limit
EP074-UT: 1.1-Dichloroethene
EP074-UT: Vinyl chloride EP074-UT: trans-1.2-Dichloroethene EP074-UT: Chloroform EP074-UT: 1.2-Dichloroethane EP074-UT: Trichloroethene EP074-UT: Tetrachloroethene
EP075(SIM)A: Phenolic Compounds (QC Lot: 1449269) EM1008731-002
TP1 (1.0-1.1)
108-95-2
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2-Chlorophenol
95-57-8
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2-Methylphenol
95-48-7
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2-Nitrophenol
88-75-5
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2.4-Dimethylphenol
105-67-9
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2.4-Dichlorophenol
120-83-2
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2.6-Dichlorophenol
87-65-0
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 4-Chloro-3-Methylphenol
59-50-7
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2.4.6-Trichlorophenol
88-06-2
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2.4.5-Trichlorophenol
95-95-4
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
1319-77-3
1.0
mg/kg
<1.0
<1.0
0.0
No Limit
87-86-5
2.0
mg/kg
<2.0
<2.0
0.0
No Limit
108-95-2
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
95-57-8
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Phenol
EP075(SIM): 3- & 4-Methylphenol EP075(SIM): Pentachlorophenol EM1008731-025
TP6 (0-0.1)
EP075(SIM): Phenol EP075(SIM): 2-Chlorophenol
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10 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Laboratory Duplicate (DUP) Report
Sub-Matrix: SOIL Laboratory sample ID
Client sample ID
CAS Number
LOR
Unit
Original Result
Duplicate Result
RPD (%)
Recovery Limits (%)
EP075(SIM): 2-Methylphenol
95-48-7
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2-Nitrophenol
88-75-5
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2.4-Dimethylphenol
105-67-9
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2.4-Dichlorophenol
120-83-2
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2.6-Dichlorophenol
87-65-0
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 4-Chloro-3-Methylphenol
59-50-7
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2.4.6-Trichlorophenol
88-06-2
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2.4.5-Trichlorophenol
95-95-4
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
1319-77-3
1.0
mg/kg
<1.0
<1.0
0.0
No Limit
87-86-5
2.0
mg/kg
<2.0
<2.0
0.0
No Limit
Method: Compound
EP075(SIM)A: Phenolic Compounds (QC Lot: 1449269) - continued EM1008731-025
TP6 (0-0.1)
EP075(SIM): 3- & 4-Methylphenol EP075(SIM): Pentachlorophenol
EP075(SIM)A: Phenolic Compounds (QC Lot: 1449271) EM1008731-036
TP8 (1.9-2.0)
108-95-2
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2-Chlorophenol
95-57-8
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2-Methylphenol
95-48-7
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2-Nitrophenol
88-75-5
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2.4-Dimethylphenol
105-67-9
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2.4-Dichlorophenol
120-83-2
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2.6-Dichlorophenol
87-65-0
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 4-Chloro-3-Methylphenol
59-50-7
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2.4.6-Trichlorophenol
88-06-2
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2.4.5-Trichlorophenol
95-95-4
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
1319-77-3
1.0
mg/kg
<1.0
<1.0
0.0
No Limit
87-86-5
2.0
mg/kg
<2.0
<2.0
0.0
No Limit
108-95-2
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2-Chlorophenol
95-57-8
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2-Methylphenol
95-48-7
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2-Nitrophenol
88-75-5
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2.4-Dimethylphenol
105-67-9
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2.4-Dichlorophenol
120-83-2
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2.6-Dichlorophenol
87-65-0
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 4-Chloro-3-Methylphenol
59-50-7
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2.4.6-Trichlorophenol
88-06-2
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): 2.4.5-Trichlorophenol
95-95-4
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
1319-77-3
1.0
mg/kg
<1.0
<1.0
0.0
No Limit
87-86-5
2.0
mg/kg
<2.0
<2.0
0.0
No Limit
EP075(SIM): Phenol
EP075(SIM): 3- & 4-Methylphenol EP075(SIM): Pentachlorophenol EM1008731-056
TP12 (1.9-2.0)
EP075(SIM): Phenol
EP075(SIM): 3- & 4-Methylphenol EP075(SIM): Pentachlorophenol
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QC Lot: 1449269) EM1008731-002
TP1 (1.0-1.1)
EP075(SIM): Naphthalene EP075(SIM): Acenaphthylene EP075(SIM): Acenaphthene
91-20-3
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
208-96-8
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
83-32-9
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
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11 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Laboratory Duplicate (DUP) Report
Sub-Matrix: SOIL Laboratory sample ID
Client sample ID
CAS Number
LOR
Unit
Original Result
Duplicate Result
RPD (%)
Recovery Limits (%)
EP075(SIM): Fluorene
86-73-7
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Phenanthrene
85-01-8
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Anthracene
120-12-7
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Fluoranthene
206-44-0
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Pyrene
129-00-0
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
56-55-3
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Chrysene
218-01-9
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Benzo(k)fluoranthene
207-08-9
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
50-32-8
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
191-24-2
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
91-20-3
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
208-96-8
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Acenaphthene
83-32-9
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Fluorene
86-73-7
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Phenanthrene
85-01-8
0.5
mg/kg
4.8
2.8
52.7
No Limit
EP075(SIM): Anthracene
120-12-7
0.5
mg/kg
1.8
1.0
53.8
No Limit
EP075(SIM): Fluoranthene
206-44-0
0.5
mg/kg
15.0
8.4
# 57.1
0% - 50%
EP075(SIM): Pyrene
129-00-0
0.5
mg/kg
17.5
8.8
# 65.7
0% - 50%
56-55-3
0.5
mg/kg
9.4
5.1
# 59.0
0% - 50%
EP075(SIM): Chrysene
218-01-9
0.5
mg/kg
8.6
4.6
# 61.0
No Limit
EP075(SIM): Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
14.6
6.4
# 78.2
0% - 50%
EP075(SIM): Benzo(k)fluoranthene
207-08-9
0.5
mg/kg
3.3
1.8
58.1
No Limit
50-32-8
0.5
mg/kg
12.4
5.2
# 82.9
0% - 50%
EP075(SIM): Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
6.4
2.9
# 76.4
No Limit
EP075(SIM): Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
1.7
0.8
76.1
No Limit
191-24-2
0.5
mg/kg
7.4
3.3
# 76.8
No Limit
Method: Compound
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QC Lot: 1449269) - continued EM1008731-002
TP1 (1.0-1.1)
EP075(SIM): Benz(a)anthracene
EP075(SIM): Benzo(a)pyrene
EP075(SIM): Benzo(g.h.i)perylene EM1008731-025
TP6 (0-0.1)
EP075(SIM): Naphthalene EP075(SIM): Acenaphthylene
EP075(SIM): Benz(a)anthracene
EP075(SIM): Benzo(a)pyrene
EP075(SIM): Benzo(g.h.i)perylene
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QC Lot: 1449271) EM1008731-036
TP8 (1.9-2.0)
91-20-3
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
208-96-8
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Acenaphthene
83-32-9
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Fluorene
86-73-7
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Phenanthrene
85-01-8
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Anthracene
120-12-7
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Fluoranthene
206-44-0
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Pyrene
129-00-0
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
56-55-3
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Naphthalene EP075(SIM): Acenaphthylene
EP075(SIM): Benz(a)anthracene
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12 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Laboratory Duplicate (DUP) Report
Sub-Matrix: SOIL Laboratory sample ID
Client sample ID
CAS Number
LOR
Unit
Original Result
Duplicate Result
RPD (%)
Recovery Limits (%)
EP075(SIM): Chrysene
218-01-9
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Benzo(k)fluoranthene
207-08-9
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
50-32-8
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
191-24-2
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
91-20-3
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
208-96-8
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Acenaphthene
83-32-9
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Fluorene
86-73-7
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Phenanthrene
85-01-8
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Anthracene
120-12-7
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Fluoranthene
206-44-0
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Pyrene
129-00-0
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
56-55-3
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Chrysene
218-01-9
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Benzo(k)fluoranthene
207-08-9
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
50-32-8
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
191-24-2
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
Method: Compound
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QC Lot: 1449271) - continued EM1008731-036
TP8 (1.9-2.0)
EP075(SIM): Benzo(a)pyrene
EP075(SIM): Benzo(g.h.i)perylene EM1008731-056
TP12 (1.9-2.0)
EP075(SIM): Naphthalene EP075(SIM): Acenaphthylene
EP075(SIM): Benz(a)anthracene
EP075(SIM): Benzo(a)pyrene
EP075(SIM): Benzo(g.h.i)perylene
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QC Lot: 1449481) EM1008775-021
Anonymous
91-20-3
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
208-96-8
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Acenaphthene
83-32-9
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Fluorene
86-73-7
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Phenanthrene
85-01-8
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Anthracene
120-12-7
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Fluoranthene
206-44-0
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Pyrene
129-00-0
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
56-55-3
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Chrysene
218-01-9
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Benzo(k)fluoranthene
207-08-9
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
50-32-8
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Naphthalene EP075(SIM): Acenaphthylene
EP075(SIM): Benz(a)anthracene
EP075(SIM): Benzo(a)pyrene
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13 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Laboratory Duplicate (DUP) Report
Sub-Matrix: SOIL Laboratory sample ID
Client sample ID
CAS Number
LOR
Unit
Original Result
Duplicate Result
RPD (%)
Recovery Limits (%)
191-24-2
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
91-20-3
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
208-96-8
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Acenaphthene
83-32-9
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Fluorene
86-73-7
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Phenanthrene
85-01-8
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Anthracene
120-12-7
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Fluoranthene
206-44-0
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Pyrene
129-00-0
0.5
mg/kg
0.6
<0.5
25.4
No Limit
56-55-3
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Chrysene
218-01-9
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Benzo(k)fluoranthene
207-08-9
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
50-32-8
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP075(SIM): Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
191-24-2
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
Method: Compound
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QC Lot: 1449481) - continued EM1008775-021
Anonymous
EP075(SIM): Benzo(g.h.i)perylene
EM1008796-018
Anonymous
EP075(SIM): Naphthalene EP075(SIM): Acenaphthylene
EP075(SIM): Benz(a)anthracene
EP075(SIM): Benzo(a)pyrene
EP075(SIM): Benzo(g.h.i)perylene
EP075A: Phenolic Compounds (Halogenated) (QC Lot: 1449128) EM1008731-003
TP1 (1.5-1.6)
95-57-8
0.03
mg/kg
<0.61
<0.61
0.0
No Limit
EP075-EM: 2.4-Dichlorophenol
120-83-2
0.03
mg/kg
<0.61
<0.61
0.0
No Limit
EP075-EM: 2.6-Dichlorophenol
87-65-0
0.03
mg/kg
<0.61
<0.61
0.0
No Limit
EP075-EM: 4-Chloro-3-Methylphenol
59-50-7
0.03
mg/kg
<0.61
<0.61
0.0
No Limit
EP075-EM: 2.3.5.6-Tetrachlorophenol
935-95-5
0.03
mg/kg
<0.61
<0.61
0.0
No Limit
EP075-EM: 2.4.5-Trichlorophenol
95-95-4
0.05
mg/kg
<0.61
<0.61
0.0
No Limit
EP075-EM: 2.4.6-Trichlorophenol
88-06-2
0.05
mg/kg
<0.61
<0.61
0.0
No Limit
4901-51-3/58-9 0-2 87-86-5
0.05
mg/kg
<1.22
<1.22
0.0
No Limit
0.2
mg/kg
<0.6
<0.6
0.0
No Limit
108-95-2
1
mg/kg
<1
<1
0.0
No Limit
95-48-7
1
mg/kg
<1
<1
0.0
No Limit
1319-77-3
1
mg/kg
<1
<1
0.0
No Limit
88-75-5
1
mg/kg
<1
<1
0.0
No Limit
105-67-9
1
mg/kg
<1
<1
0.0
No Limit
51-28-5
5
mg/kg
<49
<49
0.0
No Limit
100-02-7
5
mg/kg
<49
<49
0.0
No Limit
8071-51-0
5
mg/kg
<49
<49
0.0
No Limit
88-85-7
5
mg/kg
<49
<49
0.0
No Limit
131-89-5
5
mg/kg
<49
<49
0.0
No Limit
EP075-EM: 2-Chlorophenol
EP075-EM: 2.3.4.5 & 2.3.4.6-Tetrachlorophenol EP075-EM: Pentachlorophenol
EP075A: Phenolic Compounds (Non-halogenated) (QC Lot: 1449128) EM1008731-003
TP1 (1.5-1.6)
EP075-EM: Phenol EP075-EM: 2-Methylphenol EP075-EM: 3- & 4-Methylphenol EP075-EM: 2-Nitrophenol EP075-EM: 2.4-Dimethylphenol EP075-EM: 2.4-Dinitrophenol EP075-EM: 4-Nitrophenol EP075-EM: 2-Methyl-4.6-dinitrophenol EP075-EM: Dinoseb EP075-EM: 2-Cyclohexyl-4.6-Dinitrophenol
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14 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Laboratory Duplicate (DUP) Report
Sub-Matrix: SOIL Laboratory sample ID
Client sample ID
CAS Number
LOR
Unit
EP075-EM: Naphthalene
91-20-3
0.5
EP075-EM: Acenaphthene
83-32-9
0.5
208-96-8
EP075-EM: Fluorene EP075-EM: Phenanthrene
Original Result
Duplicate Result
RPD (%)
Recovery Limits (%)
mg/kg
0.8
<0.6
21.9
No Limit
mg/kg
<0.6
<0.6
0.0
No Limit
0.5
mg/kg
3.1
1.1
95.6
No Limit
86-73-7
0.5
mg/kg
<0.6
<0.6
0.0
No Limit
85-01-8
0.5
mg/kg
12.2
3.0
# 120
No Limit
EP075-EM: Anthracene
120-12-7
0.5
mg/kg
4.4
1.3
108
No Limit
EP075-EM: Fluoranthene
206-44-0
0.5
mg/kg
38.2
11.6
# 107
0% - 20%
EP075-EM: Pyrene
129-00-0
0.5
mg/kg
37.2
10.3
# 113
0% - 20%
56-55-3
0.5
mg/kg
18.1
5.6
# 105
0% - 50%
EP075-EM: Chrysene
218-01-9
0.5
mg/kg
15.0
4.5
# 108
No Limit
EP075-EM: Benzo(b) & Benzo(k)fluoranthene
0.5
mg/kg
30.3
12.3
# 84.3
0% - 20%
EP075-EM: Benzo(a)pyrene
205-99-2 207-08-9 50-32-8
0.5
mg/kg
20.0
6.7
# 99.6
0% - 50%
EP075-EM: Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
12.2
4.0
# 101
No Limit
EP075-EM: Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
3.5
1.1
105
No Limit
191-24-2
0.5
mg/kg
15.5
5.0
# 102
0% - 50%
EP075-EM: alpha-BHC
319-84-6
0.03
mg/kg
<0.61
<0.61
0.0
No Limit
EP075-EM: Hexachlorobenzene (HCB)
118-74-1
0.03
mg/kg
<0.61
<0.61
0.0
No Limit
EP075-EM: beta-BHC
319-85-7
0.03
mg/kg
<0.61
<0.61
0.0
No Limit
58-89-9
0.03
mg/kg
<0.61
<0.61
0.0
No Limit
EP075-EM: delta-BHC
319-86-8
0.03
mg/kg
<0.61
<0.61
0.0
No Limit
EP075-EM: Heptachlor
76-44-8
0.03
mg/kg
<0.61
<0.61
0.0
No Limit
309-00-2
0.03
mg/kg
<0.61
<0.61
0.0
No Limit
EP075-EM: Heptachlor epoxide
1024-57-3
0.03
mg/kg
<0.61
<0.61
0.0
No Limit
EP075-EM: cis-Chlordane
5103-71-9
0.03
mg/kg
<0.61
<0.61
0.0
No Limit
EP075-EM: trans-Chlordane
5103-74-2
0.03
mg/kg
<0.61
<0.61
0.0
No Limit
959-98-8
0.03
mg/kg
<0.61
<0.61
0.0
No Limit
60-57-1
0.03
mg/kg
<0.61
<0.61
0.0
No Limit
7421-93-4
0.03
mg/kg
<0.61
<0.61
0.0
No Limit
72-20-8
0.03
mg/kg
<0.61
<0.61
0.0
No Limit
33213-65-9
0.03
mg/kg
<0.61
<0.61
0.0
No Limit
1031-07-8
0.03
mg/kg
<0.61
<0.61
0.0
No Limit
EP075-EM: Methoxychlor
72-43-5
0.03
mg/kg
<0.61
<0.61
0.0
No Limit
EP075-EM: 4.4`-DDE
72-55-9
0.05
mg/kg
<0.61
<0.61
0.0
No Limit
EP075-EM: 4.4`-DDD
72-54-8
0.05
mg/kg
<0.61
<0.61
0.0
No Limit
EP075-EM: 4.4`-DDT
50-29-3
0.05
mg/kg
<0.61
<0.61
0.0
No Limit
10
mg/kg
<10
<10
0.0
No Limit
Method: Compound
EP075B: Polynuclear Aromatic Hydrocarbons (QC Lot: 1449128) EM1008731-003
TP1 (1.5-1.6)
EP075-EM: Acenaphthylene
EP075-EM: Benz(a)anthracene
EP075-EM: Benzo(g.h.i)perylene
EP075I: Organochlorine Pesticides (QC Lot: 1449128) EM1008731-003
TP1 (1.5-1.6)
EP075-EM: gamma-BHC
EP075-EM: Aldrin
EP075-EM: Endosulfan 1 EP075-EM: Dieldrin EP075-EM: Endrin aldehyde EP075-EM: Endrin EP075-EM: Endosulfan 2 EP075-EM: Endosulfan sulfate
EP080/071: Total Petroleum Hydrocarbons (QC Lot: 1449013) EM1008731-002
TP1 (1.0-1.1)
EP080: C6 - C9 Fraction
----
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15 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Laboratory Duplicate (DUP) Report
Sub-Matrix: SOIL Laboratory sample ID
Client sample ID
Method: Compound
CAS Number
LOR
Unit
Original Result
Duplicate Result
RPD (%)
Recovery Limits (%)
----
10
mg/kg
<10
<10
0.0
No Limit
EP080/071: Total Petroleum Hydrocarbons (QC Lot: 1449013) - continued EM1008731-025
TP6 (0-0.1)
EP080: C6 - C9 Fraction
EP080/071: Total Petroleum Hydrocarbons (QC Lot: 1449025) EM1008731-053
TP11 (1.9-2.0)
EP080: C6 - C9 Fraction
----
10
mg/kg
<10
<10
0.0
No Limit
EM1008780-004
Anonymous
EP080: C6 - C9 Fraction
----
10
mg/kg
<10
<10
0.0
No Limit
----
10
mg/kg
<10
<10
0.0
No Limit
EP071: C15 - C28 Fraction
----
100
mg/kg
<100
<100
0.0
No Limit
EP071: C29 - C36 Fraction
----
100
mg/kg
<100
<100
0.0
No Limit
EP071: C10 - C14 Fraction
----
50
mg/kg
<50
<50
0.0
No Limit
EP071: C15 - C28 Fraction
----
100
mg/kg
220
130
49.1
No Limit
EP071: C29 - C36 Fraction
----
100
mg/kg
430
330
25.2
No Limit
EP071: C10 - C14 Fraction
----
50
mg/kg
<50
<50
0.0
No Limit
EP071: C15 - C28 Fraction
----
100
mg/kg
<100
<100
0.0
No Limit
EP071: C29 - C36 Fraction
----
100
mg/kg
140
120
15.2
No Limit
EP071: C10 - C14 Fraction
----
50
mg/kg
<50
<50
0.0
No Limit
EP071: C15 - C28 Fraction
----
100
mg/kg
130
<100
24.9
No Limit
EP071: C29 - C36 Fraction
----
100
mg/kg
120
120
0.0
No Limit
EP071: C10 - C14 Fraction
----
50
mg/kg
<50
<50
0.0
No Limit
EP071: C15 - C28 Fraction
----
100
mg/kg
<100
<100
0.0
No Limit
EP071: C29 - C36 Fraction
----
100
mg/kg
<100
<100
0.0
No Limit
EP071: C10 - C14 Fraction
----
50
mg/kg
<50
<50
0.0
No Limit
EP071: C15 - C28 Fraction
----
100
mg/kg
<100
<100
0.0
No Limit
EP071: C29 - C36 Fraction
----
100
mg/kg
110
<100
11.8
No Limit
EP071: C10 - C14 Fraction
----
50
mg/kg
<50
<50
0.0
No Limit
EP080: Benzene
71-43-2
0.2
mg/kg
<0.2
<0.2
0.0
No Limit
EP080: Toluene
108-88-3
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP080: Ethylbenzene
100-41-4
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP080: meta- & para-Xylene
108-38-3 106-42-3 95-47-6
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP080: Benzene
71-43-2
0.2
mg/kg
<0.2
<0.2
0.0
No Limit
EP080: Toluene
108-88-3
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP080: Ethylbenzene
100-41-4
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP080: meta- & para-Xylene
108-38-3 106-42-3
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP080/071: Total Petroleum Hydrocarbons (QC Lot: 1449031) EM1008731-003
TP1 (1.5-1.6)
EP074-UT: C6 - C9 Fraction
EP080/071: Total Petroleum Hydrocarbons (QC Lot: 1449268) EM1008731-002
EM1008731-025
TP1 (1.0-1.1)
TP6 (0-0.1)
EP080/071: Total Petroleum Hydrocarbons (QC Lot: 1449270) EM1008731-036
EM1008731-056
TP8 (1.9-2.0)
TP12 (1.9-2.0)
EP080/071: Total Petroleum Hydrocarbons (QC Lot: 1449480) EM1008775-021
EM1008796-018
Anonymous
Anonymous
EP080: BTEX (QC Lot: 1449013) EM1008731-002
TP1 (1.0-1.1)
EP080: ortho-Xylene EM1008731-025
TP6 (0-0.1)
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16 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Laboratory Duplicate (DUP) Report
Sub-Matrix: SOIL Laboratory sample ID
Client sample ID
CAS Number
LOR
Unit
Original Result
Duplicate Result
RPD (%)
Recovery Limits (%)
95-47-6
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP080: Benzene
71-43-2
0.2
mg/kg
<0.2
<0.2
0.0
No Limit
EP080: Toluene
108-88-3
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP080: Ethylbenzene
100-41-4
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP080: meta- & para-Xylene
108-38-3 106-42-3 95-47-6
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP080: Benzene
71-43-2
0.2
mg/kg
<0.2
<0.2
0.0
No Limit
EP080: Toluene
108-88-3
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP080: Ethylbenzene
100-41-4
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
EP080: meta- & para-Xylene
108-38-3 106-42-3 95-47-6
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
0.5
mg/kg
<0.5
<0.5
0.0
No Limit
Method: Compound
EP080: BTEX (QC Lot: 1449013) - continued EM1008731-025
TP6 (0-0.1)
EP080: ortho-Xylene
EP080: BTEX (QC Lot: 1449025) EM1008731-053
TP11 (1.9-2.0)
EP080: ortho-Xylene EM1008780-004
Anonymous
EP080: ortho-Xylene
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17 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Method Blank (MB) and Laboratory Control Spike (LCS) Report The quality control term Method / Laboratory Blank refers to an analyte free matrix to which all reagents are added in the same volumes or proportions as used in standard sample preparation. The purpose of this QC parameter is to monitor potential laboratory contamination. The quality control term Laboratory Control Sample (LCS) refers to a certified reference material, or a known interference free matrix spiked with target analytes. The purpose of this QC parameter is to monitor method precision and accuracy independent of sample matrix. Dynamic Recovery Limits are based on statistical evaluation of processed LCS. Method Blank (MB) Report
Sub-Matrix: SOIL
Spike Recovery (%)
Concentration
LCS
Low
Recovery Limits (%) High
LOR
Unit
----
0.5
kg H2SO4/t
----
9.9 kg H2SO4/t
108
75
127
EA029: Titratable Actual Acidity (23F)
----
2
mole H+ / t
<2
----
----
----
----
EA029: Titratable Peroxide Acidity (23G)
----
2
mole H+ / t
<2
----
----
----
----
EA029: Titratable Sulfidic Acidity (23H)
----
2
mole H+ / t
<2
----
----
----
----
EA029: sulfidic - Titratable Actual Acidity (s-23F)
----
0.02
% pyrite S
<0.02
----
----
----
----
EA029: sulfidic - Titratable Peroxide Acidity (s-23G)
----
0.02
% pyrite S
<0.02
----
----
----
----
EA029: sulfidic - Titratable Sulfidic Acidity (s-23H)
----
0.02
% pyrite S
<0.02
----
----
----
----
EA029: KCl Extractable Sulfur (23Ce)
----
0.02
%S
<0.02
----
----
----
----
EA029: Peroxide Sulfur (23De)
----
0.02
%S
<0.02
----
----
----
----
EA029: Peroxide Oxidisable Sulfur (23E)
----
0.02
%S
<0.02
----
----
----
----
EA029: acidity - Peroxide Oxidisable Sulfur (a-23E)
----
10
mole H+ / t
<10
----
----
----
----
EA029: KCl Extractable Calcium (23Vh)
----
0.02
% Ca
<0.02
----
----
----
----
EA029: Peroxide Calcium (23Wh)
----
0.02
% Ca
<0.02
----
----
----
----
EA029: Acid Reacted Calcium (23X)
----
0.02
% Ca
<0.02
----
----
----
----
EA029: acidity - Acid Reacted Calcium (a-23X)
----
10
mole H+ / t
<10
----
----
----
----
EA029: sulfidic - Acid Reacted Calcium (s-23X)
----
0.02
%S
<0.02
----
----
----
----
EA029: KCl Extractable Magnesium (23Sm)
----
0.02
% Mg
<0.02
----
----
----
----
EA029: Peroxide Magnesium (23Tm)
----
0.02
% Mg
<0.02
----
----
----
----
EA029: Acid Reacted Magnesium (23U)
----
0.02
% Mg
<0.02
----
----
----
----
EA029: Acidity - Acid Reacted Magnesium (a-23U)
----
10
mole H+ / t
<10
----
----
----
----
EA029: sulfidic - Acid Reacted Magnesium (s-23U)
----
0.02
%S
<0.02
----
----
----
----
EA029: Excess Acid Neutralising Capacity (23Q)
----
0.02
% CaCO3
<0.02
----
----
----
----
EA029: acidity - Excess Acid Neutralising Capacity (a-23Q)
----
10
mole H+ / t
<10
----
----
----
----
EA029: sulfidic - Excess Acid Neutralising Capacity (s-23Q)
----
0.02
%S
<0.02
----
----
----
----
Method: Compound
CAS Number
Laboratory Control Spike (LCS) Report Spike
Result
EA013: Acid Neutralising Capacity (QCLot: 1456094) EA013: ANC as H2SO4
EA029-B: Acidity Trail (QCLot: 1456095)
EA029-C: Sulfur Trail (QCLot: 1456095)
EA029-D: Calcium Values (QCLot: 1456095)
EA029-E: Magnesium Values (QCLot: 1456095)
EA029-F: Excess Acid Neutralising Capacity (QCLot: 1456095)
EA033-A: Actual Acidity (QCLot: 1456096) EA033: Titratable Actual Acidity (23F)
----
2
mole H+ / t
<2
----
----
----
----
EA033: sulfidic - Titratable Actual Acidity (s-23F)
----
0.02
% pyrite S
<0.02
----
----
----
----
EA033-B: Potential Acidity (QCLot: 1456096)
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: : : :
18 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Method Blank (MB) Report
Sub-Matrix: SOIL Method: Compound
CAS Number
LOR
Unit
Result
Laboratory Control Spike (LCS) Report Spike
Spike Recovery (%)
Concentration
LCS
Low
Recovery Limits (%) High
EA033-B: Potential Acidity (QCLot: 1456096) - continued EA033: Chromium Reducible Sulfur (22B)
----
0.005
%S
<0.005
----
----
----
----
EA033: acidity - Chromium Reducible Sulfur (a-22B)
----
10
mole H+ / t
<10
----
----
----
----
EA033: Acid Neutralising Capacity (19A2)
----
0.01
% CaCO3
<0.01
----
----
----
----
EA033: acidity - Acid Neutralising Capacity (a-19A2)
----
10
mole H+ / t
<10
----
----
----
----
EA033: sulfidic - Acid Neutralising Capacity (s-19A2)
----
0.01
% pyrite S
<0.01
----
----
----
----
ED007: Exchangeable Calcium
----
0.1
meq/100g
<0.1
1.47 meq/100g
84.6
70.2
106
ED007: Exchangeable Magnesium
----
0.1
meq/100g
<0.1
0.77 meq/100g
89.4
76.4
112
ED007: Exchangeable Potassium
----
0.1
meq/100g
<0.1
0.20 meq/100g
73.8
70
100
ED007: Exchangeable Sodium
----
0.1
meq/100g
<0.1
0.51 meq/100g
80.6
70
104
ED007: Cation Exchange Capacity
----
0.1
meq/100g
----
2.95 meq/100g
84.4
70.1
104
ED007: Exchangeable Aluminium
----
0.1
meq/100g
<0.1
----
----
----
----
----
0.01
%
<0.01
100 %
101
70
130
EA033-C: Acid Neutralising Capacity (QCLot: 1456096)
ED007: Exchangeable Cations (QCLot: 1454744)
ED042T: Total Sulfur by LECO (QCLot: 1451827) ED042T: Sulfur - Total as S (LECO)
ED093S: Soluble Major Cations (QCLot: 1449452) ED093S: Calcium
7440-70-2
10
mg/kg
<10
25 mg/kg
105
87
121
ED093S: Magnesium
7439-95-4
10
mg/kg
<10
25 mg/kg
89.0
85
115
ED093S: Sodium
7440-23-5
10
mg/kg
<10
250 mg/kg
103
86
110
ED093S: Potassium
7440-09-7
10
mg/kg
<10
250 mg/kg
105
87
109
ED093S: Calcium
7440-70-2
10
mg/kg
<10
----
----
----
----
ED093S: Magnesium
7439-95-4
10
mg/kg
<10
----
----
----
----
ED093S: Sodium
7440-23-5
10
mg/kg
<10
----
----
----
----
ED093S: Potassium
7440-09-7
10
mg/kg
<10
----
----
----
----
EG005S: Aluminium
7429-90-5
1.00
mg/kg
<1
5 mg/kg
104
80.0
120
EG005S: Manganese
7439-96-5
0.10
mg/kg
<0.1
5 mg/kg
107
80.0
120
EG005S: Aluminium
7429-90-5
1.00
mg/kg
<1
----
----
----
----
EG005S: Manganese
7439-96-5
0.10
mg/kg
<0.1
----
----
----
----
EG005T: Arsenic
7440-38-2
5
mg/kg
<5
13.6 mg/kg
113
80
119
EG005T: Cadmium
7440-43-9
1
mg/kg
<1
2.8 mg/kg
104
85
117
EG005T: Chromium
7440-47-3
2
mg/kg
<2
60.9 mg/kg
101
81
119
EG005T: Copper
7440-50-8
5
mg/kg
<5
55.1 mg/kg
109
80
120
EG005T: Lead
7439-92-1
5
mg/kg
<5
54.9 mg/kg
102
81
119
EG005T: Molybdenum
7439-98-7
2
mg/kg
<2
8.5 mg/kg
112
80
120
ED093S: Soluble Major Cations (QCLot: 1454735)
EG005S : Soluble Metals by ICPAES (QCLot: 1449451)
EG005S : Soluble Metals by ICPAES (QCLot: 1454734)
EG005T: Total Metals by ICP-AES (QCLot: 1449037)
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19 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Method Blank (MB) Report
Sub-Matrix: SOIL Method: Compound
CAS Number
LOR
Unit
Result
Laboratory Control Spike (LCS) Report Spike
Spike Recovery (%)
Concentration
LCS
Recovery Limits (%) Low
High
117
EG005T: Total Metals by ICP-AES (QCLot: 1449037) - continued EG005T: Nickel
7440-02-0
2
mg/kg
<2
55.1 mg/kg
110
81
EG005T: Selenium
7782-49-2
5
mg/kg
<5
----
----
----
----
EG005T: Silver
7440-22-4
2
mg/kg
<2
5.23 mg/kg
113
80
119
EG005T: Tin
7440-31-5
5
mg/kg
<5
26.3 mg/kg
105
80
120
EG005T: Zinc
7440-66-6
5
mg/kg
<5
105 mg/kg
105
81
111
EG005T: Arsenic
7440-38-2
5
mg/kg
<5
13.6 mg/kg
115
80
119
EG005T: Cadmium
7440-43-9
1
mg/kg
<1
2.8 mg/kg
110
85
117
EG005T: Chromium
7440-47-3
2
mg/kg
<2
60.9 mg/kg
102
81
119
EG005T: Copper
7440-50-8
5
mg/kg
<5
55.1 mg/kg
108
80
120
EG005T: Lead
7439-92-1
5
mg/kg
<5
54.9 mg/kg
102
81
119
EG005T: Molybdenum
7439-98-7
2
mg/kg
<2
8.5 mg/kg
114
80
120
EG005T: Nickel
7440-02-0
2
mg/kg
<2
55.1 mg/kg
109
81
117
EG005T: Selenium
7782-49-2
5
mg/kg
<5
----
----
----
----
EG005T: Silver
7440-22-4
2
mg/kg
<2
5.23 mg/kg
103
80
119
EG005T: Tin
7440-31-5
5
mg/kg
<5
26.3 mg/kg
108
80
120
EG005T: Zinc
7440-66-6
5
mg/kg
<5
105 mg/kg
108
81
111
EG005T: Arsenic
7440-38-2
5
mg/kg
<5
13.6 mg/kg
95.7
80
119
EG005T: Cadmium
7440-43-9
1
mg/kg
<1
2.8 mg/kg
90.8
85
117
EG005T: Chromium
7440-47-3
2
mg/kg
<2
60.9 mg/kg
84.8
81
119
EG005T: Copper
7440-50-8
5
mg/kg
<5
55.1 mg/kg
89.0
80
120
EG005T: Lead
7439-92-1
5
mg/kg
<5
54.9 mg/kg
88.0
81
119
EG005T: Molybdenum
7439-98-7
2
mg/kg
<2
8.5 mg/kg
102
80
120
EG005T: Nickel
7440-02-0
2
mg/kg
<2
55.1 mg/kg
92.3
81
117
EG005T: Selenium
7782-49-2
5
mg/kg
<5
----
----
----
----
EG005T: Silver
7440-22-4
2
mg/kg
<2
5.23 mg/kg
108
80
119
EG005T: Tin
7440-31-5
5
mg/kg
<5
26.3 mg/kg
89.8
80
120
EG005T: Zinc
7440-66-6
5
mg/kg
<5
105 mg/kg
89.0
81
111
0.1
mg/kg
<0.1
1.47 mg/kg
102
71.9
119
0.1
mg/kg
<0.1
1.47 mg/kg
96.4
71.9
119
0.1
mg/kg
<0.1
1.47 mg/kg
84.7
71.9
119
0.5
mg/kg
<0.5
40 mg/kg
83.1
80
120
EG005T: Total Metals by ICP-AES (QCLot: 1449039)
EG005T: Total Metals by ICP-AES (QCLot: 1449200)
EG035T: Total Recoverable Mercury by FIMS (QCLot: 1449038) 7439-97-6
EG035T: Mercury
EG035T: Total Recoverable Mercury by FIMS (QCLot: 1449040) 7439-97-6
EG035T: Mercury
EG035T: Total Recoverable Mercury by FIMS (QCLot: 1449201) 7439-97-6
EG035T: Mercury
EG048: Hexavalent Chromium (Alkaline Digest) (QCLot: 1449399) EG048: Hexavalent Chromium
18540-29-9
EK025G: Free cyanide by Discrete Analyser (QCLot: 1449301)
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: : : :
20 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Method Blank (MB) Report
Sub-Matrix: SOIL
Spike Recovery (%)
Concentration
LCS
Low
Recovery Limits (%) High
LOR
Unit
----
1
mg/kg
<1
5 mg/kg
79.9
78.4
119
57-12-5
1
mg/kg
<1
20 mg/kg
118
87
123
16984-48-8
40
mg/kg
<40
950 mg/kg
83.8
80
120
----
0.5
%
<0.5
43.5 %
103
80.3
120
----
0.5
%
<0.5
1.3 %
99.9
89
115
----
0.1
mg/kg
<0.10
0.5 mg/kg
103
43
139
EP074-UT: Benzene
71-43-2
0.2
mg/kg
<0.2
2.1 mg/kg
92.6
80.0
120
EP074-UT: Toluene
108-88-3
0.5
mg/kg
<0.5
2.1 mg/kg
87.8
80.0
120
EP074-UT: Ethylbenzene
100-41-4
0.5
mg/kg
<0.5
2.1 mg/kg
86.7
80.0
120
EP074-UT: meta- & para-Xylene
108-38-3 106-42-3 100-42-5
0.5
mg/kg
<0.5
4.2 mg/kg
86.1
80.0
120
0.5
mg/kg
<0.5
0.1 mg/kg
93.1
76.0
117
95-47-6
0.5
mg/kg
<0.5
2.1 mg/kg
88.3
80.0
120
EP074-UT: Vinyl chloride
75-01-4
0.02
mg/kg
<0.02
0.1 mg/kg
108
65.6
112
EP074-UT: 1.1-Dichloroethene
75-35-4
0.01
mg/kg
<0.01
0.1 mg/kg
96.4
70.8
122
EP074-UT: Methylene chloride
75-09-2
0.4
mg/kg
<0.6
2.1 mg/kg
90.3
75.3
131
EP074-UT: trans-1.2-Dichloroethene
156-60-5
0.02
mg/kg
<0.02
0.1 mg/kg
95.9
79.0
121
EP074-UT: cis-1.2-Dichloroethene
156-59-2
0.01
mg/kg
<0.01
0.1 mg/kg
93.4
80.0
122
EP074-UT: Chloroform
67-66-3
0.02
mg/kg
<0.02
0.1 mg/kg
94.8
70.4
115
EP074-UT: 1.1.1-Trichloroethane
71-55-6
0.01
mg/kg
<0.01
0.1 mg/kg
93.8
72.0
120
EP074-UT: Carbon Tetrachloride
56-23-5
0.01
mg/kg
<0.01
0.1 mg/kg
88.5
65.5
120
107-06-2
0.02
mg/kg
<0.02
0.1 mg/kg
92.7
71.6
128
EP074-UT: Trichloroethene
79-01-6
0.02
mg/kg
<0.02
0.1 mg/kg
99.7
75.7
124
EP074-UT: 1.1.2-Trichloroethane
79-00-5
0.04
mg/kg
<0.04
0.1 mg/kg
95.6
80.0
120
EP074-UT: Tetrachloroethene
127-18-4
0.02
mg/kg
<0.02
0.1 mg/kg
89.2
70.0
130
EP074-UT: 1.1.1.2-Tetrachloroethane
630-20-6
0.01
mg/kg
<0.01
0.1 mg/kg
89.9
70.0
130
EP074-UT: 1.1.2.2-Tetrachloroethane
79-34-5
0.02
mg/kg
<0.02
0.1 mg/kg
87.4
75.7
126
EP074-UT: Hexachlorobutadiene
87-68-3
0.02
mg/kg
<0.02
0.1 mg/kg
# 66.4
68.4
118
EP074-UT: Chlorobenzene
108-90-7
0.02
mg/kg
<0.02
0.1 mg/kg
108
79.7
124
EP074-UT: 1.4-Dichlorobenzene
106-46-7
0.02
mg/kg
<0.02
0.1 mg/kg
84.9
72.3
116
EP074-UT: 1.2-Dichlorobenzene
95-50-1
0.02
mg/kg
<0.02
0.1 mg/kg
87.8
80.0
120
Method: Compound
CAS Number
Laboratory Control Spike (LCS) Report Spike
Result
EK025G: Free cyanide by Discrete Analyser (QCLot: 1449301) - continued EK025G: Free Cyanide
EK026G: Total Cyanide By Discrete Analyser (QCLot: 1449415) EK026G: Total Cyanide
EK040T: Fluoride Total (QCLot: 1449032) EK040T: Fluoride
EP004: Organic Matter (QCLot: 1448903) EP004: Total Organic Carbon
EP004: Organic Matter (QCLot: 1451345) EP004: Total Organic Carbon
EP066: Polychlorinated Biphenyls (PCB) (QCLot: 1449129) EP066-EM: Total Polychlorinated biphenyls
EP074A: Monocyclic Aromatic Hydrocarbons (QCLot: 1449031)
EP074-UT: Styrene EP074-UT: ortho-Xylene
EP074I: Volatile Halogenated Compounds (QCLot: 1449031)
EP074-UT: 1.2-Dichloroethane
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: : : :
21 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Method Blank (MB) Report
Sub-Matrix: SOIL Method: Compound
CAS Number
Laboratory Control Spike (LCS) Report Spike
Spike Recovery (%)
Concentration
LCS
Low
Recovery Limits (%) High
LOR
Unit
120-82-1
0.01
mg/kg
<0.01
0.1 mg/kg
81.2
73.0
118
Result
EP074I: Volatile Halogenated Compounds (QCLot: 1449031) - continued EP074-UT: 1.2.4-Trichlorobenzene
EP075(SIM)A: Phenolic Compounds (QCLot: 1449269) 108-95-2
0.5
mg/kg
<0.5
10 mg/kg
77.2
63
125
EP075(SIM): 2-Chlorophenol
95-57-8
0.5
mg/kg
<0.5
10 mg/kg
84.6
61
127
EP075(SIM): 2-Methylphenol
95-48-7
0.5
mg/kg
<0.5
10 mg/kg
81.5
61
127
1319-77-3
1.0
mg/kg
<1.0
20 mg/kg
80.5
67
123
88-75-5
0.5
mg/kg
<0.5
10 mg/kg
85.0
54
124
EP075(SIM): 2.4-Dimethylphenol
105-67-9
0.5
mg/kg
<0.5
10 mg/kg
82.0
60
128
EP075(SIM): 2.4-Dichlorophenol
120-83-2
0.5
mg/kg
<0.5
10 mg/kg
86.0
61
121
EP075(SIM): 2.6-Dichlorophenol
87-65-0
0.5
mg/kg
<0.5
10 mg/kg
90.4
65
123
EP075(SIM): 4-Chloro-3-Methylphenol
59-50-7
0.5
mg/kg
<0.5
10 mg/kg
83.7
64
120
EP075(SIM): 2.4.6-Trichlorophenol
88-06-2
0.5
mg/kg
<0.5
10 mg/kg
88.9
60
120
EP075(SIM): 2.4.5-Trichlorophenol
95-95-4
0.5
mg/kg
<0.5
10 mg/kg
82.9
62
124
EP075(SIM): Pentachlorophenol
87-86-5
2.0
mg/kg
<2.0
10 mg/kg
59.7
10.4
114
EP075(SIM): Phenol
EP075(SIM): 3- & 4-Methylphenol EP075(SIM): 2-Nitrophenol
EP075(SIM)A: Phenolic Compounds (QCLot: 1449271) 108-95-2
0.5
mg/kg
<0.5
10 mg/kg
102
63
125
EP075(SIM): 2-Chlorophenol
95-57-8
0.5
mg/kg
<0.5
10 mg/kg
99.8
61
127
EP075(SIM): 2-Methylphenol
95-48-7
0.5
mg/kg
<0.5
10 mg/kg
82.8
61
127
1319-77-3
1.0
mg/kg
<1.0
20 mg/kg
82.1
67
123
88-75-5
0.5
mg/kg
<0.5
10 mg/kg
100
54
124
EP075(SIM): 2.4-Dimethylphenol
105-67-9
0.5
mg/kg
<0.5
10 mg/kg
80.9
60
128
EP075(SIM): 2.4-Dichlorophenol
120-83-2
0.5
mg/kg
<0.5
10 mg/kg
77.2
61
121
EP075(SIM): 2.6-Dichlorophenol
87-65-0
0.5
mg/kg
<0.5
10 mg/kg
105
65
123
EP075(SIM): 4-Chloro-3-Methylphenol
59-50-7
0.5
mg/kg
<0.5
10 mg/kg
99.7
64
120
EP075(SIM): 2.4.6-Trichlorophenol
88-06-2
0.5
mg/kg
<0.5
10 mg/kg
90.7
60
120
EP075(SIM): 2.4.5-Trichlorophenol
95-95-4
0.5
mg/kg
<0.5
10 mg/kg
89.3
62
124
EP075(SIM): Pentachlorophenol
87-86-5
2.0
mg/kg
<2.0
10 mg/kg
59.8
10.4
114
EP075(SIM): Phenol
EP075(SIM): 3- & 4-Methylphenol EP075(SIM): 2-Nitrophenol
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 1449269) 91-20-3
0.5
mg/kg
<0.5
10 mg/kg
91.4
70
118
208-96-8
0.5
mg/kg
<0.5
10 mg/kg
84.7
68
120
EP075(SIM): Acenaphthene
83-32-9
0.5
mg/kg
<0.5
10 mg/kg
117
71
117
EP075(SIM): Fluorene
86-73-7
0.5
mg/kg
<0.5
10 mg/kg
105
71
125
EP075(SIM): Phenanthrene
85-01-8
0.5
mg/kg
<0.5
10 mg/kg
96.6
68
120
EP075(SIM): Anthracene
120-12-7
0.5
mg/kg
<0.5
10 mg/kg
96.5
69
119
EP075(SIM): Fluoranthene
206-44-0
0.5
mg/kg
<0.5
10 mg/kg
96.7
69
119
EP075(SIM): Pyrene
129-00-0
0.5
mg/kg
<0.5
10 mg/kg
97.0
69
119
56-55-3
0.5
mg/kg
<0.5
10 mg/kg
102
64
122
EP075(SIM): Chrysene
218-01-9
0.5
mg/kg
<0.5
10 mg/kg
101
67
123
EP075(SIM): Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
<0.5
10 mg/kg
95.8
63
121
EP075(SIM): Naphthalene EP075(SIM): Acenaphthylene
EP075(SIM): Benz(a)anthracene
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22 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Method Blank (MB) Report
Sub-Matrix: SOIL Method: Compound
CAS Number
LOR
Unit
Result
Laboratory Control Spike (LCS) Report Spike
Spike Recovery (%)
Concentration
LCS
Low
Recovery Limits (%) High
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 1449269) - continued 207-08-9
0.5
mg/kg
<0.5
10 mg/kg
93.3
66
126
50-32-8
0.5
mg/kg
<0.5
10 mg/kg
94.9
67
121
EP075(SIM): Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
<0.5
10 mg/kg
100
59
125
EP075(SIM): Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
<0.5
10 mg/kg
99.1
59
125
191-24-2
0.5
mg/kg
<0.5
10 mg/kg
99.2
59
123
EP075(SIM): Benzo(k)fluoranthene EP075(SIM): Benzo(a)pyrene
EP075(SIM): Benzo(g.h.i)perylene
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 1449271) 91-20-3
0.5
mg/kg
<0.5
10 mg/kg
95.6
70
118
208-96-8
0.5
mg/kg
<0.5
10 mg/kg
96.0
68
120
EP075(SIM): Acenaphthene
83-32-9
0.5
mg/kg
<0.5
10 mg/kg
91.8
71
117
EP075(SIM): Fluorene
86-73-7
0.5
mg/kg
<0.5
10 mg/kg
89.2
71
125
EP075(SIM): Phenanthrene
85-01-8
0.5
mg/kg
<0.5
10 mg/kg
92.0
68
120
EP075(SIM): Anthracene
120-12-7
0.5
mg/kg
<0.5
10 mg/kg
91.1
69
119
EP075(SIM): Fluoranthene
206-44-0
0.5
mg/kg
<0.5
10 mg/kg
92.9
69
119
EP075(SIM): Pyrene
129-00-0
0.5
mg/kg
<0.5
10 mg/kg
92.4
69
119
56-55-3
0.5
mg/kg
<0.5
10 mg/kg
92.7
64
122
EP075(SIM): Chrysene
218-01-9
0.5
mg/kg
<0.5
10 mg/kg
89.0
67
123
EP075(SIM): Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
<0.5
10 mg/kg
90.8
63
121
EP075(SIM): Benzo(k)fluoranthene
207-08-9
0.5
mg/kg
<0.5
10 mg/kg
100
66
126
50-32-8
0.5
mg/kg
<0.5
10 mg/kg
101
67
121
EP075(SIM): Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
<0.5
10 mg/kg
121
59
125
EP075(SIM): Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
<0.5
10 mg/kg
117
59
125
191-24-2
0.5
mg/kg
<0.5
10 mg/kg
# 134
59
123
EP075(SIM): Naphthalene EP075(SIM): Acenaphthylene
EP075(SIM): Benz(a)anthracene
EP075(SIM): Benzo(a)pyrene
EP075(SIM): Benzo(g.h.i)perylene
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 1449481) 91-20-3
0.5
mg/kg
<0.5
10 mg/kg
98.2
70
118
208-96-8
0.5
mg/kg
<0.5
10 mg/kg
101
68
120
EP075(SIM): Acenaphthene
83-32-9
0.5
mg/kg
<0.5
10 mg/kg
98.2
71
117
EP075(SIM): Fluorene
86-73-7
0.5
mg/kg
<0.5
10 mg/kg
97.8
71
125
EP075(SIM): Phenanthrene
85-01-8
0.5
mg/kg
<0.5
10 mg/kg
96.0
68
120
EP075(SIM): Anthracene
120-12-7
0.5
mg/kg
<0.5
10 mg/kg
96.8
69
119
EP075(SIM): Fluoranthene
206-44-0
0.5
mg/kg
<0.5
10 mg/kg
97.0
69
119
EP075(SIM): Pyrene
129-00-0
0.5
mg/kg
<0.5
10 mg/kg
99.0
69
119
56-55-3
0.5
mg/kg
<0.5
10 mg/kg
98.4
64
122
EP075(SIM): Chrysene
218-01-9
0.5
mg/kg
<0.5
10 mg/kg
99.6
67
123
EP075(SIM): Benzo(b)fluoranthene
205-99-2
0.5
mg/kg
<0.5
10 mg/kg
98.2
63
121
EP075(SIM): Benzo(k)fluoranthene
207-08-9
0.5
mg/kg
<0.5
10 mg/kg
97.3
66
126
50-32-8
0.5
mg/kg
<0.5
10 mg/kg
96.3
67
121
EP075(SIM): Indeno(1.2.3.cd)pyrene
193-39-5
0.5
mg/kg
<0.5
10 mg/kg
93.9
59
125
EP075(SIM): Dibenz(a.h)anthracene
53-70-3
0.5
mg/kg
<0.5
10 mg/kg
94.9
59
125
191-24-2
0.5
mg/kg
<0.5
10 mg/kg
92.7
59
123
EP075(SIM): Naphthalene EP075(SIM): Acenaphthylene
EP075(SIM): Benz(a)anthracene
EP075(SIM): Benzo(a)pyrene
EP075(SIM): Benzo(g.h.i)perylene
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23 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Method Blank (MB) Report
Sub-Matrix: SOIL Method: Compound
CAS Number
LOR
Unit
Result
Laboratory Control Spike (LCS) Report Spike
Spike Recovery (%)
Concentration
LCS
Low
Recovery Limits (%) High
EP075A: Phenolic Compounds (Halogenated) (QCLot: 1449128) 95-57-8
0.03
mg/kg
<0.03
0.5 mg/kg
89.5
39.8
139
EP075-EM: 2.4-Dichlorophenol
120-83-2
0.03
mg/kg
<0.03
0.5 mg/kg
89.2
35
135
EP075-EM: 2.6-Dichlorophenol
87-65-0
0.03
mg/kg
<0.03
0.5 mg/kg
91.1
36.7
136
EP075-EM: 4-Chloro-3-Methylphenol
59-50-7
0.03
mg/kg
<0.03
0.5 mg/kg
99.8
45.2
141
EP075-EM: 2.4.5-Trichlorophenol
95-95-4
0.05
mg/kg
<0.05
0.5 mg/kg
90.9
41.4
137
EP075-EM: 2.4.6-Trichlorophenol
88-06-2
0.05
mg/kg
<0.05
0.5 mg/kg
91.8
42.2
143
935-95-5
0.03
mg/kg
<0.03
0.5 mg/kg
57.1
41
139
4901-51-3/5 8-90-2 87-86-5
0.05
mg/kg
<0.05
1.0 mg/kg
72.1
23.6
145
0.2
mg/kg
<0.2
0.5 mg/kg
41.6
25
144
108-95-2
0.1 1
mg/kg mg/kg
---<1
0.5 mg/kg ----
87.8 ----
44 ----
144 ----
95-48-7
0.1 1
mg/kg mg/kg
---<1
0.5 mg/kg ----
88.0 ----
39.1 ----
135 ----
1319-77-3
0.1 1
mg/kg mg/kg
---<1
1 mg/kg ----
80.2 ----
33.8 ----
176 ----
88-75-5
0.1 1
mg/kg mg/kg
---<1
0.5 mg/kg ----
85.5 ----
25.6 ----
145 ----
105-67-9
0.1 1
mg/kg mg/kg
---<1
0.5 mg/kg ----
48.8 ----
10 ----
138 ----
51-28-5
0.1 5
mg/kg mg/kg
---<5
3 mg/kg ----
26.7 ----
15.9 ----
136 ----
100-02-7
0.1 5
mg/kg mg/kg
---<5
3 mg/kg ----
96.4 ----
41.1 ----
155 ----
8071-51-0
0.1 5
mg/kg mg/kg
---<5
3 mg/kg ----
54.7 ----
15.4 ----
133 ----
88-85-7
0.1 5
mg/kg mg/kg
---<5
3 mg/kg ----
71.6 ----
32 ----
136 ----
131-89-5
0.1 5
mg/kg mg/kg
---<5
3 mg/kg ----
38.3 ----
10 ----
169 ----
EP075-EM: 2-Chlorophenol
EP075-EM: 2.3.5.6-Tetrachlorophenol EP075-EM: 2.3.4.5 & 2.3.4.6-Tetrachlorophenol EP075-EM: Pentachlorophenol
EP075A: Phenolic Compounds (Non-halogenated) (QCLot: 1449128) EP075-EM: Phenol EP075-EM: 2-Methylphenol EP075-EM: 3- & 4-Methylphenol EP075-EM: 2-Nitrophenol EP075-EM: 2.4-Dimethylphenol EP075-EM: 2.4-Dinitrophenol EP075-EM: 4-Nitrophenol EP075-EM: 2-Methyl-4.6-dinitrophenol EP075-EM: Dinoseb EP075-EM: 2-Cyclohexyl-4.6-Dinitrophenol
EP075B: Polynuclear Aromatic Hydrocarbons (QCLot: 1449128) EP075-EM: Naphthalene
91-20-3
0.1 0.5
mg/kg mg/kg
---<0.5
0.5 mg/kg ----
90.8 ----
41.2 ----
136 ----
EP075-EM: Acenaphthene
83-32-9
0.1 0.5
mg/kg mg/kg
---<0.5
0.5 mg/kg ----
92.9 ----
48 ----
133 ----
208-96-8
0.1 0.5
mg/kg mg/kg
---<0.5
0.5 mg/kg ----
100 ----
45.2 ----
137 ----
86-73-7
0.1 0.5
mg/kg mg/kg
---<0.5
0.5 mg/kg ----
95.1 ----
49.6 ----
136 ----
EP075-EM: Acenaphthylene EP075-EM: Fluorene
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24 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Method Blank (MB) Report
Sub-Matrix: SOIL
Spike Recovery (%)
Concentration
LCS
Low
Recovery Limits (%) High
LOR
Unit
85-01-8
0.1 0.5
mg/kg mg/kg
---<0.5
0.5 mg/kg ----
93.2 ----
61.8 ----
132 ----
EP075-EM: Anthracene
120-12-7
0.1 0.5
mg/kg mg/kg
---<0.5
0.5 mg/kg ----
91.7 ----
61.3 ----
127 ----
EP075-EM: Fluoranthene
206-44-0
0.1 0.5
mg/kg mg/kg
---<0.5
0.5 mg/kg ----
94.5 ----
66.2 ----
134 ----
EP075-EM: Pyrene
129-00-0
0.1 0.5
mg/kg mg/kg
---<0.5
0.5 mg/kg ----
93.8 ----
67.5 ----
132 ----
56-55-3
0.1 0.5
mg/kg mg/kg
---<0.5
0.5 mg/kg ----
92.6 ----
64.9 ----
133 ----
EP075-EM: Chrysene
218-01-9
0.1 0.5
mg/kg mg/kg
---<0.5
0.5 mg/kg ----
92.5 ----
66.2 ----
136 ----
EP075-EM: Benzo(b) & Benzo(k)fluoranthene
0.1 0.5
mg/kg mg/kg
---<0.5
1.0 mg/kg ----
93.6 ----
65.4 ----
133 ----
EP075-EM: Benzo(a)pyrene
205-99-2 207-08-9 50-32-8
0.1 0.5
mg/kg mg/kg
---<0.5
0.5 mg/kg ----
91.3 ----
62.4 ----
131 ----
EP075-EM: Indeno(1.2.3.cd)pyrene
193-39-5
0.1 0.5
mg/kg mg/kg
---<0.5
0.5 mg/kg ----
94.1 ----
31.5 ----
148 ----
EP075-EM: Dibenz(a.h)anthracene
53-70-3
0.1 0.5
mg/kg mg/kg
---<0.5
0.5 mg/kg ----
96.2 ----
33.3 ----
145 ----
191-24-2
0.1 0.5
mg/kg mg/kg
---<0.5
0.5 mg/kg ----
94.8 ----
28.9 ----
153 ----
EP075-EM: alpha-BHC
319-84-6
0.03
mg/kg
<0.03
0.5 mg/kg
95.8
54.9
137
EP075-EM: Hexachlorobenzene (HCB)
118-74-1
0.03
mg/kg
<0.03
0.5 mg/kg
95.6
24.4
133
EP075-EM: beta-BHC
319-85-7
0.03
mg/kg
<0.03
0.5 mg/kg
96.6
47
138
58-89-9
0.03
mg/kg
<0.03
0.5 mg/kg
95.0
60.3
135
EP075-EM: delta-BHC
319-86-8
0.03
mg/kg
<0.03
0.5 mg/kg
93.8
68.1
132
EP075-EM: Heptachlor
76-44-8
0.03
mg/kg
<0.03
0.5 mg/kg
94.9
61.4
132
309-00-2
0.03
mg/kg
<0.03
0.5 mg/kg
96.3
63.1
131
EP075-EM: Heptachlor epoxide
1024-57-3
0.03
mg/kg
<0.03
0.5 mg/kg
93.5
67.9
129
EP075-EM: cis-Chlordane
5103-71-9
0.03
mg/kg
<0.03
0.5 mg/kg
94.1
38.8
137
EP075-EM: trans-Chlordane
5103-74-2
0.03
mg/kg
<0.03
0.5 mg/kg
94.1
65
133
959-98-8
0.03
mg/kg
<0.03
0.5 mg/kg
95.8
63.5
136
EP075-EM: 4.4`-DDE
72-55-9
0.05
mg/kg
<0.05
0.5 mg/kg
90.1
62.3
133
EP075-EM: Dieldrin
60-57-1
0.03
mg/kg
<0.03
0.5 mg/kg
94.3
67.6
134
7421-93-4
0.03
mg/kg
<0.03
0.5 mg/kg
95.7
25.1
177
72-20-8
0.03
mg/kg
<0.03
0.5 mg/kg
116
60.7
137
33213-65-9
0.03
mg/kg
<0.03
0.5 mg/kg
93.5
67.8
138
72-54-8
0.05
mg/kg
<0.05
0.5 mg/kg
94.7
66.5
135
Method: Compound
CAS Number
Laboratory Control Spike (LCS) Report Spike
Result
EP075B: Polynuclear Aromatic Hydrocarbons (QCLot: 1449128) - continued EP075-EM: Phenanthrene
EP075-EM: Benz(a)anthracene
EP075-EM: Benzo(g.h.i)perylene
EP075I: Organochlorine Pesticides (QCLot: 1449128)
EP075-EM: gamma-BHC
EP075-EM: Aldrin
EP075-EM: Endosulfan 1
EP075-EM: Endrin aldehyde EP075-EM: Endrin EP075-EM: Endosulfan 2 EP075-EM: 4.4`-DDD
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25 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Method Blank (MB) Report
Sub-Matrix: SOIL Method: Compound
CAS Number
LOR
Unit
Result
Laboratory Control Spike (LCS) Report Spike
Spike Recovery (%)
Concentration
LCS
Low
Recovery Limits (%) High
EP075I: Organochlorine Pesticides (QCLot: 1449128) - continued 1031-07-8
0.03
mg/kg
<0.03
0.5 mg/kg
94.6
60
140
EP075-EM: 4.4`-DDT
50-29-3
0.05
mg/kg
<0.05
0.5 mg/kg
92.4
61
139
EP075-EM: Methoxychlor
72-43-5
0.03
mg/kg
<0.03
0.5 mg/kg
98.4
64.2
138
----
10
mg/kg
<10
32 mg/kg
124
71
133
----
10
mg/kg
<10
32 mg/kg
99.3
71
133
----
10
mg/kg
<10
33.1 mg/kg
98.2
73.2
120
EP075-EM: Endosulfan sulfate
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1449013) EP080: C6 - C9 Fraction
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1449025) EP080: C6 - C9 Fraction
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1449031) EP074-UT: C6 - C9 Fraction
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1449268) EP071: C10 - C14 Fraction
----
50
mg/kg
<50
479 mg/kg
97.7
54
123
EP071: C15 - C28 Fraction
----
100
mg/kg
<100
1669 mg/kg
88.6
74
134
EP071: C29 - C36 Fraction
----
100
mg/kg
<100
436 mg/kg
84.9
63
143
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1449270) EP071: C10 - C14 Fraction
----
50
mg/kg
<50
479 mg/kg
104
54
123
EP071: C15 - C28 Fraction
----
100
mg/kg
<100
1669 mg/kg
76.3
74
134
EP071: C29 - C36 Fraction
----
100
mg/kg
<100
436 mg/kg
68.3
63
143
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1449480) EP071: C10 - C14 Fraction
----
50
mg/kg
<50
479 mg/kg
95.5
54
123
EP071: C15 - C28 Fraction
----
100
mg/kg
<100
1669 mg/kg
81.6
74
134
EP071: C29 - C36 Fraction
----
100
mg/kg
<100
436 mg/kg
78.6
63
143
EP080: Benzene
71-43-2
0.2
mg/kg
<0.2
2 mg/kg
108
70
122
EP080: Toluene
108-88-3
0.5
mg/kg
<0.5
2 mg/kg
112
72
122
EP080: Ethylbenzene
100-41-4
0.5
mg/kg
<0.5
2 mg/kg
110
68
124
EP080: meta- & para-Xylene
108-38-3 106-42-3 95-47-6
0.5
mg/kg
<0.5
4 mg/kg
125
69
131
0.5
mg/kg
<0.5
2 mg/kg
114
72
124
EP080: Benzene
71-43-2
0.2
mg/kg
<0.2
2 mg/kg
101
70
122
EP080: Toluene
108-88-3
0.5
mg/kg
<0.5
2 mg/kg
99.5
72
122
EP080: Ethylbenzene
100-41-4
0.5
mg/kg
<0.5
2 mg/kg
95.6
68
124
EP080: meta- & para-Xylene
108-38-3 106-42-3 95-47-6
0.5
mg/kg
<0.5
4 mg/kg
97.2
69
131
0.5
mg/kg
<0.5
2 mg/kg
96.6
72
124
EP080: BTEX (QCLot: 1449013)
EP080: ortho-Xylene
EP080: BTEX (QCLot: 1449025)
EP080: ortho-Xylene
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26 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Matrix Spike (MS) Report The quality control term Matrix Spike (MS) refers to an intralaboratory split sample spiked with a representative set of target analytes. The purpose of this QC parameter is to monitor potential matrix effects on analyte recoveries. Static Recovery Limits as per laboratory Data Quality Objectives (DQOs). Ideal recovery ranges stated may be waived in the event of sample matrix interference. Matrix Spike (MS) Report
Sub-Matrix: SOIL Laboratory sample ID
Client sample ID
Spike
Spike Recovery (%)
Concentration
MS
Low
Recovery Limits (%) High
Method: Compound
CAS Number
EG005T: Arsenic
7440-38-2
50 mg/kg
86.4
70
130
EG005T: Cadmium
7440-43-9
50 mg/kg
102
70
130
EG005T: Chromium
7440-47-3
50 mg/kg
86.4
70
130
EG005T: Copper
7440-50-8
50 mg/kg
103
70
130
EG005T: Lead
7439-92-1
50 mg/kg
92.6
70
130
EG005T: Molybdenum
7439-98-7
50 mg/kg
87.7
70
130
EG005T: Nickel
7440-02-0
50 mg/kg
109
70
130
EG005T: Selenium
7782-49-2
50 mg/kg
96.7
70
130
EG005T: Zinc
7440-66-6
50 mg/kg
94.1
70
130
EG005T: Arsenic
7440-38-2
50 mg/kg
77.7
70
130
EG005T: Cadmium
7440-43-9
50 mg/kg
99.4
70
130
EG005T: Chromium
7440-47-3
50 mg/kg
75.5
70
130
EG005T: Copper
7440-50-8
50 mg/kg
# Not Determined
70
130
EG005T: Lead
7439-92-1
50 mg/kg
97.2
70
130
EG005T: Molybdenum
7439-98-7
50 mg/kg
94.0
70
130
EG005T: Nickel
7440-02-0
50 mg/kg
84.6
70
130
EG005T: Selenium
7782-49-2
50 mg/kg
105
70
130
EG005T: Zinc
7440-66-6
50 mg/kg
# Not Determined
70
130
EG005T: Arsenic
7440-38-2
50 mg/kg
116
70
130
EG005T: Cadmium
7440-43-9
50 mg/kg
96.3
70
130
EG005T: Chromium
7440-47-3
50 mg/kg
77.4
70
130
EG005T: Copper
7440-50-8
50 mg/kg
# Not Determined
70
130
EG005T: Lead
7439-92-1
50 mg/kg
# Not Determined
70
130
EG005T: Molybdenum
7439-98-7
50 mg/kg
103
70
130
EG005T: Nickel
7440-02-0
50 mg/kg
71.8
70
130
EG005T: Selenium
7782-49-2
50 mg/kg
111
70
130
EG005T: Zinc
7440-66-6
50 mg/kg
# Not Determined
70
130
EG035T: Mercury
7439-97-6
5.0 mg/kg
84.2
70
130
EG035T: Mercury
7439-97-6
5.0 mg/kg
86.6
70
130
EG005T: Total Metals by ICP-AES (QCLot: 1449037) EM1008731-002
TP1 (1.0-1.1)
EG005T: Total Metals by ICP-AES (QCLot: 1449039) EM1008731-026
TP6 (0.4-0.5)
EG005T: Total Metals by ICP-AES (QCLot: 1449200) EM1008731-052
TP11 (1.7-1.8)
EG035T: Total Recoverable Mercury by FIMS (QCLot: 1449038) EM1008731-002
TP1 (1.0-1.1)
EG035T: Total Recoverable Mercury by FIMS (QCLot: 1449040) EM1008731-026
TP6 (0.4-0.5)
EG035T: Total Recoverable Mercury by FIMS (QCLot: 1449201)
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27 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Matrix Spike (MS) Report
Sub-Matrix: SOIL Laboratory sample ID
Client sample ID
Spike
Spike Recovery (%)
Concentration
MS
Low
High
7439-97-6
5.0 mg/kg
81.7
70
130
EG048: Hexavalent Chromium
18540-29-9
40 mg/kg
# 39.5
70
130
EK025G: Free Cyanide
----
5 mg/kg
79.2
70
130
EK026G: Total Cyanide
57-12-5
20 mg/kg
95.7
70
130
EP066-EM: Total Polychlorinated biphenyls
----
0.5 mg/kg
# 45.0
67
123
EP074-UT: Benzene
71-43-2
2 mg/kg
115
70
130
EP074-UT: Toluene
108-88-3
2 mg/kg
110
70
130
EP074-UT: 1.1-Dichloroethene
75-35-4
2 mg/kg
105
70
130
EP074-UT: Trichloroethene
79-01-6
2 mg/kg
96.3
70
130
EP074-UT: Chlorobenzene
108-90-7
2 mg/kg
110
70
130
EP075(SIM): Phenol
108-95-2
10 mg/kg
80.3
70
130
EP075(SIM): 2-Chlorophenol
95-57-8
10 mg/kg
88.3
70
130
EP075(SIM): 2-Nitrophenol
88-75-5
10 mg/kg
75.7
70
130
EP075(SIM): 4-Chloro-3-Methylphenol
59-50-7
10 mg/kg
75.0
70
130
EP075(SIM): Pentachlorophenol
87-86-5
10 mg/kg
90.0
70
130
EP075(SIM): Phenol
108-95-2
10 mg/kg
93.2
70
130
EP075(SIM): 2-Chlorophenol
95-57-8
10 mg/kg
93.6
70
130
EP075(SIM): 2-Nitrophenol
88-75-5
10 mg/kg
83.8
70
130
EP075(SIM): 4-Chloro-3-Methylphenol
59-50-7
10 mg/kg
94.5
70
130
EP075(SIM): Pentachlorophenol
87-86-5
10 mg/kg
75.9
70
130
EP075(SIM): Acenaphthene
83-32-9
10 mg/kg
115
70
130
EP075(SIM): Pyrene
129-00-0
10 mg/kg
95.9
70
130
EP075(SIM): Acenaphthene
83-32-9
10 mg/kg
93.4
70
130
EP075(SIM): Pyrene
129-00-0
10 mg/kg
100
70
130
83-32-9
10 mg/kg
85.1
70
130
Method: Compound
CAS Number
Recovery Limits (%)
EG035T: Total Recoverable Mercury by FIMS (QCLot: 1449201) - continued EM1008731-052
TP11 (1.7-1.8)
EG035T: Mercury
EG048: Hexavalent Chromium (Alkaline Digest) (QCLot: 1449399) EM1008731-008
TP2 (1.9-2.0)
EK025G: Free cyanide by Discrete Analyser (QCLot: 1449301) EM1008731-027
TP6 (1.4-1.5)
EK026G: Total Cyanide By Discrete Analyser (QCLot: 1449415) EM1008731-008
TP2 (1.9-2.0)
EP066: Polychlorinated Biphenyls (PCB) (QCLot: 1449129) EM1008731-013
TP3 (1.4-1.5)
EP074A: Monocyclic Aromatic Hydrocarbons (QCLot: 1449031) EM1008731-008
TP2 (1.9-2.0)
EP074I: Volatile Halogenated Compounds (QCLot: 1449031) EM1008731-008
TP2 (1.9-2.0)
EP075(SIM)A: Phenolic Compounds (QCLot: 1449269) EM1008731-007
TP2 (1.4-1.5)
EP075(SIM)A: Phenolic Compounds (QCLot: 1449271) EM1008731-037
TP8 (2.4-2.5)
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 1449269) EM1008731-007
TP2 (1.4-1.5)
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 1449271) EM1008731-037
TP8 (2.4-2.5)
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 1449481) EM1008775-026
Anonymous
EP075(SIM): Acenaphthene
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28 of 28 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Matrix Spike (MS) Report
Sub-Matrix: SOIL Laboratory sample ID
Client sample ID
Method: Compound
CAS Number
Spike
Spike Recovery (%)
Concentration
MS
Low
Recovery Limits (%) High
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 1449481) - continued EM1008775-026
Anonymous
EP075(SIM): Pyrene
129-00-0
10 mg/kg
78.4
70
130
EP075-EM: 2-Chlorophenol
95-57-8
0.5 mg/kg
# 63.8
70
130
EP075-EM: 4-Chloro-3-Methylphenol
59-50-7
0.5 mg/kg
# 69.8
70
130
EP075-EM: Pentachlorophenol
87-86-5
0.5 mg/kg
# 13.3
70
130
EP075-EM: Phenol
108-95-2
0.5 mg/kg
# 58.9
70
130
EP075-EM: 2-Nitrophenol
88-75-5
0.5 mg/kg
# 48.6
70
130
EP075-EM: Acenaphthene
83-32-9
0.5 mg/kg
# 65.2
70
130
EP075-EM: Pyrene
129-00-0
0.5 mg/kg
93.4
70
130
EP080: C6 - C9 Fraction
----
28 mg/kg
99.3
70
130
EP080: C6 - C9 Fraction
----
28 mg/kg
73.7
70
130
EP074-UT: C6 - C9 Fraction
----
28 mg/kg
86.5
70
130
EP071: C10 - C14 Fraction
----
479 mg/kg
87.8
60
130
EP071: C15 - C28 Fraction
----
1669 mg/kg
111
60
130
EP071: C29 - C36 Fraction
----
436 mg/kg
123
60
130
EP071: C10 - C14 Fraction
----
479 mg/kg
93.5
60
130
EP071: C15 - C28 Fraction
----
1669 mg/kg
81.1
60
130
EP071: C29 - C36 Fraction
----
436 mg/kg
70.7
60
130
EP071: C10 - C14 Fraction
----
479 mg/kg
100
60
130
EP071: C15 - C28 Fraction
----
1669 mg/kg
73.2
60
130
EP071: C29 - C36 Fraction
----
436 mg/kg
# Not Determined
60
130
EP080: Benzene
71-43-2
2 mg/kg
119
70
130
EP080: Toluene
108-88-3
2 mg/kg
124
70
130
EP080: Benzene
71-43-2
2 mg/kg
87.3
70
130
EP080: Toluene
108-88-3
2 mg/kg
89.9
70
130
EP075A: Phenolic Compounds (Halogenated) (QCLot: 1449128) EM1008731-008
TP2 (1.9-2.0)
EP075A: Phenolic Compounds (Non-halogenated) (QCLot: 1449128) EM1008731-008
TP2 (1.9-2.0)
EP075B: Polynuclear Aromatic Hydrocarbons (QCLot: 1449128) EM1008731-008
TP2 (1.9-2.0)
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1449013) EM1008731-007
TP2 (1.4-1.5)
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1449025) EM1008731-055
TP12 (1.4-1.5)
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1449031) EM1008731-008
TP2 (1.9-2.0)
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1449268) EM1008731-003
TP1 (1.5-1.6)
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1449270) EM1008731-040
TP9 (0.9-1.0)
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1449480) EM1008731-069
TP11 (2.9-3.0)
EP080: BTEX (QCLot: 1449013) EM1008731-007
TP2 (1.4-1.5)
EP080: BTEX (QCLot: 1449025) EM1008731-055
TP12 (1.4-1.5)
True
INTERPRETIVE QUALITY CONTROL REPORT Work Order
: EM1008731
Amendment
:1
Client
: ENVIRONMENTAL EARTH SCIENCES : MR JORDAN FRASER : P.O.BOX 2253
Contact Address
Page
: 1 of 22
Laboratory Address
: Environmental Division Melbourne : Steven McGrath : 4 Westall Rd Springvale VIC Australia 3171
Contact
FOOTSCRAY VIC, AUSTRALIA 3011 E-mail Telephone Facsimile
: jfraser@eesi.biz : +61 03 96871666 : +61 03 96871844
E-mail Telephone Facsimile
: steven.mcgrath@alsenviro.com : +61-3-8549 9600 : +61-3-8549 9601
Project Site C-O-C number Sampler Order number
: 210061 : YARRAVILLE : ---: JF : ----
QC Level
: NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Date Samples Received Issue Date
: 11-AUG-2010 : 27-AUG-2010
Quote number
: EN/010/10
No. of samples received No. of samples analysed
: 71 : 63
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. All pages of this report have been checked and approved for release. This Interpretive Quality Control Report contains the following information: l Analysis Holding Time Compliance
l Quality Control Parameter Frequency Compliance l Brief Method Summaries l Summary of Outliers
Environmental Division Melbourne 4 Westall Rd Springvale VIC Australia 3171 Tel. +61-3-8549 9600 Fax. +61-3-8549 9601 www.alsglobal.com
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: : : :
2 of 22 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analysis Holding Time Compliance The following report summarises extraction / preparation and analysis times and compares with recommended holding times. Dates reported represent first date of extraction or analysis and precludes subsequent dilutions and reruns. Information is also provided re the sample container (preservative) from which the analysis aliquot was taken. Elapsed period to analysis represents number of days from sampling where no extraction / digestion is involved or period from extraction / digestion where this is present. For composite samples, sampling date is assumed to be that of the oldest sample contributing to the composite. Sample date for laboratory produced leachates is assumed as the completion date of the leaching process. Outliers for holding time are based on USEPA SW 846, APHA, AS and NEPM (1999). A listing of breaches is provided in the Summary of Outliers. Holding times for leachate methods (excluding elutriates) vary according to the analytes being determined on the resulting solution. For non -volatile analytes, the holding time compliance assessment compares the leach date with the shortest analyte holding time for the equivalent soil method. These soil holding times are: Organics (14 days); Mercury (28 days) & other metals (180 days). A recorded breach therefore does not guarantee a breach for all non-volatile parameters. Evaluation: û = Holding time breach ; ü = Within holding time.
Matrix: SOIL Method
Sample Date
Container / Client Sample ID(s)
Extraction / Preparation
Analysis
Date extracted
Due for extraction
Evaluation
Date analysed
Due for analysis
Evaluation
EA013: Acid Neutralising Capacity Pulp Bag TP3 (2.0-2.1), TP11 (1.9-2.0), TP10 (1.8-1.9)
TP4 (2.1-2.2), TP8 (2.0-2.1),
09-AUG-2010
19-AUG-2010
09-AUG-2011
ü
19-AUG-2010
15-FEB-2011
ü
TP10 (1.8-1.9)
09-AUG-2010
19-AUG-2010
10-AUG-2010
û
19-AUG-2010
17-NOV-2010
ü
TP10 (1.8-1.9)
09-AUG-2010
19-AUG-2010
10-AUG-2010
û
19-AUG-2010
17-NOV-2010
ü
TP10 (1.8-1.9)
09-AUG-2010
19-AUG-2010
10-AUG-2010
û
19-AUG-2010
17-NOV-2010
ü
TP10 (1.8-1.9)
09-AUG-2010
19-AUG-2010
10-AUG-2010
û
19-AUG-2010
17-NOV-2010
ü
TP10 (1.8-1.9)
09-AUG-2010
19-AUG-2010
10-AUG-2010
û
19-AUG-2010
17-NOV-2010
ü
TP10 (1.8-1.9)
09-AUG-2010
19-AUG-2010
10-AUG-2010
û
19-AUG-2010
17-NOV-2010
ü
TP10 (1.8-1.9)
09-AUG-2010
19-AUG-2010
10-AUG-2010
û
19-AUG-2010
17-NOV-2010
ü
TP10 (1.8-1.9)
09-AUG-2010
19-AUG-2010
10-AUG-2010
û
19-AUG-2010
17-NOV-2010
ü
EA029-A: pH Measurements Snap Lock Bag TP4 (2.1-2.2), EA029-B: Acidity Trail Snap Lock Bag TP4 (2.1-2.2), EA029-C: Sulfur Trail Snap Lock Bag TP4 (2.1-2.2), EA029-D: Calcium Values Snap Lock Bag TP4 (2.1-2.2), EA029-E: Magnesium Values Snap Lock Bag TP4 (2.1-2.2), EA029-F: Excess Acid Neutralising Capacity Snap Lock Bag TP4 (2.1-2.2), EA029-G: Retained Acidity Snap Lock Bag TP4 (2.1-2.2), EA029-H: Acid Base Accounting Snap Lock Bag TP4 (2.1-2.2),
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3 of 22 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Evaluation: û = Holding time breach ; ü = Within holding time.
Matrix: SOIL Method
Sample Date
Container / Client Sample ID(s)
Extraction / Preparation
Analysis
Date extracted
Due for extraction
Evaluation
Date analysed
Due for analysis
Evaluation
EA033-A: Actual Acidity Snap Lock Bag TP4 (2.1-2.2),
TP10 (1.8-1.9)
09-AUG-2010
19-AUG-2010
10-AUG-2010
û
19-AUG-2010
17-NOV-2010
ü
TP10 (1.8-1.9)
09-AUG-2010
19-AUG-2010
10-AUG-2010
û
19-AUG-2010
17-NOV-2010
ü
TP10 (1.8-1.9)
09-AUG-2010
19-AUG-2010
10-AUG-2010
û
19-AUG-2010
17-NOV-2010
ü
TP10 (1.8-1.9)
09-AUG-2010
19-AUG-2010
10-AUG-2010
û
19-AUG-2010
17-NOV-2010
ü
TP10 (1.8-1.9)
09-AUG-2010
19-AUG-2010
10-AUG-2010
û
19-AUG-2010
17-NOV-2010
ü
EA033-B: Potential Acidity Snap Lock Bag TP4 (2.1-2.2), EA033-C: Acid Neutralising Capacity Snap Lock Bag TP4 (2.1-2.2), EA033-D: Retained Acidity Snap Lock Bag TP4 (2.1-2.2), EA033-E: Acid Base Accounting Snap Lock Bag TP4 (2.1-2.2),
Page Work Order Client Project
: : : :
4 of 22 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Evaluation: û = Holding time breach ; ü = Within holding time.
Matrix: SOIL Method
Extraction / Preparation
Sample Date
Container / Client Sample ID(s)
Analysis
Date extracted
Due for extraction
Evaluation
Date analysed
Due for analysis
Evaluation
EA055: Moisture Content Snap Lock Bag TP8 (2.0-2.1), Soil Glass Jar - Unpreserved TP1 (0.4-0.5), TP1 (1.5-1.6), TP2 (0.4-0.5), TP2 (1.9-2.0), TP3 (0-0.1), TP3 (1.4-1.5), TP3 (2.4-2.5), TP4 (0.4-0.5), DUP1, TP5 (0.4-0.5), TP5 (2.9-3.0), TP6 (0-0.1), TP6 (1.4-1.5), TP7 (0-0.1), TP7 (2.0-2.1), TP8 (0.9-1.0), TP8 (2.4-2.5), TP9 (0.4-0.5), TP9 (1.9-2.0), TP9B (2.5-2.6), TP10 (1.4-1.5), TP10 (2.4-2.5), TP11 (0-0.1), TP11 (1.9-2.0), TP12 (1.4-1.5), TP12 (2.4-2.5), TP13 (0-0.1), TP13 (1.5-1.6), TP14 (0.9-1.0), TP14 (2.8-2.9), TP11 (2.9-3.0)
TP10 (1.8-1.9)
09-AUG-2010
----
----
----
16-AUG-2010
16-AUG-2010
ü
TP1 (1.0-1.1), TP1 (2.0-2.1), TP2 (1.4-1.5), TP2 (3.2-3.3), TP3 (0.4-0.5), TP3 (2.0-2.1), TP4 (0-0.1), TP4 (1.4-1.5), DUP2, TP4 (2.1-2.2), TP5 (1.4-1.5), TP5 (3.9-4.0), TP6 (0.4-0.5), TP6 (1.9-2.0), TP7 (0.9-1.0), TP8 (0.2-0.3), TP8 (1.9-2.0), TP8 (2.9-3.0), TP9 (0.9-1.0), TP9 (2.0-2.1), TP10 (0.1-0.2), TP10 (1.9-2.0),
09-AUG-2010
----
----
----
13-AUG-2010
16-AUG-2010
ü
TP4 (2.1-2.2), TP8 (2.0-2.1),
09-AUG-2010
19-AUG-2010
05-FEB-2011
ü
20-AUG-2010
05-FEB-2011
ü
TP4 (2.1-2.2), TP8 (2.0-2.1),
09-AUG-2010
16-AUG-2010
05-FEB-2011
ü
18-AUG-2010
05-FEB-2011
ü
TP11 (1.7-1.8), TP12 (0.4-0.5), TP12 (1.9-2.0), DUP3, TP13 (0.4-0.5), TP13 (2.0-2.1), TP14 (1.6-1.7), TP5 (2.0-2.1),
ED007: Exchangeable Cations Snap Lock Bag TP3 (2.0-2.1), TP11 (1.9-2.0), TP10 (1.8-1.9) ED042T: Total Sulfur by LECO Pulp Bag TP3 (2.0-2.1), TP11 (1.9-2.0), TP10 (1.8-1.9)
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5 of 22 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Evaluation: û = Holding time breach ; ü = Within holding time.
Matrix: SOIL Method
Sample Date
Container / Client Sample ID(s)
Extraction / Preparation
Analysis
Date extracted
Due for extraction
Evaluation
Date analysed
Due for analysis
Evaluation
ED093S: Soluble Major Cations Snap Lock Bag TP8 (2.0-2.1), Soil Glass Jar - Unpreserved TP3 (2.0-2.1), TP11 (1.9-2.0)
TP10 (1.8-1.9)
09-AUG-2010
19-AUG-2010
05-FEB-2011
ü
20-AUG-2010
05-FEB-2011
ü
TP4 (2.1-2.2),
09-AUG-2010
13-AUG-2010
05-FEB-2011
ü
20-AUG-2010
05-FEB-2011
ü
TP10 (1.8-1.9)
09-AUG-2010
19-AUG-2010
05-FEB-2011
ü
20-AUG-2010
05-FEB-2011
ü
TP4 (2.1-2.2),
09-AUG-2010
13-AUG-2010
05-FEB-2011
ü
20-AUG-2010
05-FEB-2011
ü
TP1 (1.0-1.1), TP1 (2.0-2.1), TP2 (1.4-1.5), TP2 (3.2-3.3), TP3 (0.4-0.5), TP3 (2.0-2.1), TP4 (0-0.1), DUP1, DUP2, TP5 (0.4-0.5), TP5 (3.9-4.0), TP6 (0.4-0.5), TP6 (1.9-2.0), TP7 (0.9-1.0), TP8 (0.2-0.3), TP8 (1.9-2.0), TP9 (0.4-0.5), TP9 (1.9-2.0), TP10 (0.1-0.2), TP10 (1.9-2.0),
09-AUG-2010
13-AUG-2010
05-FEB-2011
ü
19-AUG-2010
05-FEB-2011
ü
EG005S : Soluble Metals by ICPAES Snap Lock Bag TP8 (2.0-2.1), Soil Glass Jar - Unpreserved TP3 (2.0-2.1), TP11 (1.9-2.0) EG005T: Total Metals by ICP-AES Soil Glass Jar - Unpreserved TP1 (0.4-0.5), TP1 (1.5-1.6), TP2 (0.4-0.5), TP2 (1.9-2.0), TP3 (0-0.1), TP3 (1.4-1.5), TP3 (2.4-2.5), TP4 (1.4-1.5), TP4 (2.1-2.2), TP5 (1.4-1.5), TP6 (0-0.1), TP6 (1.4-1.5), TP7 (0-0.1), TP7 (2.0-2.1), TP8 (0.9-1.0), TP8 (2.9-3.0), TP9 (0.9-1.0), TP9B (2.5-2.6), TP10 (1.4-1.5), TP10 (2.4-2.5), TP11 (0-0.1), TP11 (1.9-2.0), TP12 (1.4-1.5), TP12 (2.4-2.5), TP13 (0-0.1), TP13 (1.5-1.6), TP14 (0.9-1.0), TP14 (2.8-2.9), TP11 (2.9-3.0)
TP11 (1.7-1.8), TP12 (0.4-0.5), TP12 (1.9-2.0), DUP3, TP13 (0.4-0.5), TP13 (2.0-2.1), TP14 (1.6-1.7), TP5 (2.0-2.1),
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: : : :
6 of 22 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Evaluation: û = Holding time breach ; ü = Within holding time.
Matrix: SOIL Method
Sample Date
Container / Client Sample ID(s)
Extraction / Preparation
Analysis
Date extracted
Due for extraction
Evaluation
Date analysed
Due for analysis
Evaluation
EG035T: Total Recoverable Mercury by FIMS Soil Glass Jar - Unpreserved TP11 (0-0.1), TP11 (1.9-2.0), TP12 (1.4-1.5), TP12 (2.4-2.5), TP13 (0-0.1), TP13 (1.5-1.6), TP14 (0.9-1.0), TP14 (2.8-2.9), TP11 (2.9-3.0) Soil Glass Jar - Unpreserved TP1 (0.4-0.5), TP1 (1.5-1.6), TP2 (0.4-0.5), TP2 (1.9-2.0), TP3 (0-0.1), TP3 (1.4-1.5), TP3 (2.4-2.5), TP4 (1.4-1.5), TP4 (2.1-2.2), TP5 (1.4-1.5), TP6 (0-0.1), TP6 (1.4-1.5), TP7 (0-0.1), TP7 (2.0-2.1), TP8 (0.9-1.0), TP8 (2.9-3.0), TP9 (0.9-1.0), TP9B (2.5-2.6), TP10 (1.4-1.5), TP10 (2.4-2.5)
TP11 (1.7-1.8), TP12 (0.4-0.5), TP12 (1.9-2.0), DUP3, TP13 (0.4-0.5), TP13 (2.0-2.1), TP14 (1.6-1.7), TP5 (2.0-2.1),
09-AUG-2010
13-AUG-2010
06-SEP-2010
ü
17-AUG-2010
06-SEP-2010
ü
TP1 (1.0-1.1), TP1 (2.0-2.1), TP2 (1.4-1.5), TP2 (3.2-3.3), TP3 (0.4-0.5), TP3 (2.0-2.1), TP4 (0-0.1), DUP1, DUP2, TP5 (0.4-0.5), TP5 (3.9-4.0), TP6 (0.4-0.5), TP6 (1.9-2.0), TP7 (0.9-1.0), TP8 (0.2-0.3), TP8 (1.9-2.0), TP9 (0.4-0.5), TP9 (1.9-2.0), TP10 (0.1-0.2), TP10 (1.9-2.0),
09-AUG-2010
13-AUG-2010
06-SEP-2010
ü
20-AUG-2010
06-SEP-2010
ü
TP2 (1.9-2.0), TP4 (2.1-2.2), TP9 (1.9-2.0), TP13 (1.5-1.6),
09-AUG-2010
13-AUG-2010
06-SEP-2010
ü
17-AUG-2010
20-AUG-2010
ü
TP6 (1.4-1.5), TP10 (1.4-1.5), DUP2, TP14 (1.6-1.7)
09-AUG-2010
13-AUG-2010
16-AUG-2010
ü
13-AUG-2010
27-AUG-2010
ü
EG048: Hexavalent Chromium (Alkaline Digest) Soil Glass Jar - Unpreserved TP1 (1.5-1.6), TP3 (1.4-1.5), TP7 (0.9-1.0), TP11 (1.7-1.8), TP5 (2.0-2.1) EK025G: Free cyanide by Discrete Analyser Soil Glass Jar - Unpreserved TP4 (0-0.1), TP8 (0.9-1.0), TP10 (1.9-2.0), TP12 (1.9-2.0),
Page Work Order Client Project
: : : :
7 of 22 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Evaluation: û = Holding time breach ; ü = Within holding time.
Matrix: SOIL Method
Sample Date
Container / Client Sample ID(s)
Extraction / Preparation
Analysis
Date extracted
Due for extraction
Evaluation
Date analysed
Due for analysis
Evaluation
EK026G: Total Cyanide By Discrete Analyser Soil Glass Jar - Unpreserved TP1 (1.5-1.6), TP3 (1.4-1.5), TP4 (2.1-2.2), TP7 (0.9-1.0), TP9 (1.9-2.0), TP10 (1.9-2.0), TP11 (1.7-1.8), TP13 (1.5-1.6), TP5 (2.0-2.1)
TP2 (1.9-2.0), TP4 (0-0.1), TP6 (1.4-1.5), TP8 (0.9-1.0), TP10 (1.4-1.5), DUP2, TP12 (1.9-2.0), TP14 (1.6-1.7),
09-AUG-2010
13-AUG-2010
16-AUG-2010
ü
16-AUG-2010
27-AUG-2010
ü
TP2 (1.9-2.0), TP4 (2.1-2.2), TP9 (1.9-2.0), TP13 (1.5-1.6),
09-AUG-2010
13-AUG-2010
16-AUG-2010
ü
13-AUG-2010
16-AUG-2010
ü
TP10 (1.8-1.9)
09-AUG-2010
16-AUG-2010
16-AUG-2010
ü
16-AUG-2010
16-AUG-2010
ü
TP4 (2.1-2.2),
09-AUG-2010
13-AUG-2010
16-AUG-2010
ü
13-AUG-2010
16-AUG-2010
ü
TP2 (1.9-2.0), TP4 (2.1-2.2), TP9 (1.9-2.0), TP13 (1.5-1.6),
09-AUG-2010
13-AUG-2010
23-AUG-2010
ü
17-AUG-2010
22-SEP-2010
ü
TP2 (1.9-2.0), TP4 (2.1-2.2), TP9 (1.9-2.0), TP13 (1.5-1.6),
09-AUG-2010
13-AUG-2010
23-AUG-2010
ü
13-AUG-2010
23-AUG-2010
ü
TP2 (1.9-2.0), TP4 (2.1-2.2), TP9 (1.9-2.0), TP13 (1.5-1.6),
09-AUG-2010
13-AUG-2010
23-AUG-2010
ü
13-AUG-2010
23-AUG-2010
ü
EK040T: Fluoride Total Soil Glass Jar - Unpreserved TP1 (1.5-1.6), TP3 (1.4-1.5), TP7 (0.9-1.0), TP11 (1.7-1.8), TP5 (2.0-2.1) EP004: Organic Matter Snap Lock Bag TP8 (2.0-2.1), Soil Glass Jar - Unpreserved TP3 (2.0-2.1), TP11 (1.9-2.0) EP066: Polychlorinated Biphenyls (PCB) Soil Glass Jar - Unpreserved TP1 (1.5-1.6), TP3 (1.4-1.5), TP7 (0.9-1.0), TP11 (1.7-1.8), TP5 (2.0-2.1) EP074A: Monocyclic Aromatic Hydrocarbons Soil Glass Jar - Unpreserved TP1 (1.5-1.6), TP3 (1.4-1.5), TP7 (0.9-1.0), TP11 (1.7-1.8), TP5 (2.0-2.1) EP074I: Volatile Halogenated Compounds Soil Glass Jar - Unpreserved TP1 (1.5-1.6), TP3 (1.4-1.5), TP7 (0.9-1.0), TP11 (1.7-1.8), TP5 (2.0-2.1)
Page Work Order Client Project
: : : :
8 of 22 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Evaluation: û = Holding time breach ; ü = Within holding time.
Matrix: SOIL Method
Sample Date
Container / Client Sample ID(s)
Extraction / Preparation
Analysis
Date extracted
Due for extraction
Evaluation
Date analysed
Due for analysis
Evaluation
EP075(SIM)A: Phenolic Compounds Soil Glass Jar - Unpreserved TP2 (1.4-1.5), TP5 (3.9-4.0), TP8 (2.4-2.5), TP9B (2.5-2.6), DUP2, TP11 (1.9-2.0), TP12 (2.4-2.5), TP13 (2.0-2.1)
TP5 (2.9-3.0), TP6 (0.4-0.5), TP9 (2.0-2.1), TP10 (1.9-2.0), TP10 (2.4-2.5), TP12 (1.9-2.0), DUP3,
09-AUG-2010
13-AUG-2010
23-AUG-2010
ü
16-AUG-2010
22-SEP-2010
ü
TP2 (1.4-1.5), TP3 (2.0-2.1), TP4 (1.4-1.5), TP5 (1.4-1.5), TP5 (3.9-4.0), TP6 (1.4-1.5), TP8 (0.9-1.0), TP9 (0.9-1.0), DUP2,
09-AUG-2010
13-AUG-2010
23-AUG-2010
ü
16-AUG-2010
22-SEP-2010
ü
TP2 (1.9-2.0), TP4 (2.1-2.2), TP9 (1.9-2.0), TP13 (1.5-1.6),
09-AUG-2010
13-AUG-2010
23-AUG-2010
ü
17-AUG-2010
22-SEP-2010
ü
TP2 (1.9-2.0), TP4 (2.1-2.2), TP9 (1.9-2.0), TP13 (1.5-1.6),
09-AUG-2010
13-AUG-2010
23-AUG-2010
ü
17-AUG-2010
22-SEP-2010
ü
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons Soil Glass Jar - Unpreserved TP1 (1.0-1.1), TP2 (3.2-3.3), TP4 (0.4-0.5), DUP1, TP5 (2.9-3.0), TP6 (0-0.1), TP7 (2.0-2.1), TP8 (1.9-2.0), TP9 (2.0-2.1), TP9B (2.5-2.6), TP10 (1.9-2.0), TP12 (1.9-2.0), DUP3, TP13 (2.0-2.1), TP14 (1.6-1.7),
TP11 (1.9-2.0), TP12 (2.4-2.5), TP13 (0.4-0.5), TP14 (0.9-1.0), TP11 (2.9-3.0)
TP12 (1.4-1.5),
EP075A: Phenolic Compounds (Halogenated) Soil Glass Jar - Unpreserved TP1 (1.5-1.6), TP3 (1.4-1.5), TP7 (0.9-1.0), TP11 (1.7-1.8), TP5 (2.0-2.1) EP075A: Phenolic Compounds (Non-halogenated) Soil Glass Jar - Unpreserved TP1 (1.5-1.6), TP3 (1.4-1.5), TP7 (0.9-1.0), TP11 (1.7-1.8), TP5 (2.0-2.1)
Page Work Order Client Project
: : : :
9 of 22 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Evaluation: û = Holding time breach ; ü = Within holding time.
Matrix: SOIL Method
Sample Date
Container / Client Sample ID(s)
Extraction / Preparation
Analysis
Date extracted
Due for extraction
Evaluation
Date analysed
Due for analysis
Evaluation
EP075B: Polynuclear Aromatic Hydrocarbons Soil Glass Jar - Unpreserved TP1 (1.5-1.6), TP3 (1.4-1.5), TP7 (0.9-1.0), TP11 (1.7-1.8), TP5 (2.0-2.1)
TP2 (1.9-2.0), TP4 (2.1-2.2), TP9 (1.9-2.0), TP13 (1.5-1.6),
09-AUG-2010
13-AUG-2010
23-AUG-2010
ü
17-AUG-2010
22-SEP-2010
ü
TP2 (1.9-2.0), TP4 (2.1-2.2), TP9 (1.9-2.0), TP13 (1.5-1.6),
09-AUG-2010
13-AUG-2010
23-AUG-2010
ü
17-AUG-2010
22-SEP-2010
ü
EP075I: Organochlorine Pesticides Soil Glass Jar - Unpreserved TP1 (1.5-1.6), TP3 (1.4-1.5), TP7 (0.9-1.0), TP11 (1.7-1.8), TP5 (2.0-2.1)
Page Work Order Client Project
: : : :
10 of 22 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Evaluation: û = Holding time breach ; ü = Within holding time.
Matrix: SOIL Method
Sample Date
Container / Client Sample ID(s)
Extraction / Preparation
Analysis
Date extracted
Due for extraction
Evaluation
Date analysed
Due for analysis
Evaluation
09-AUG-2010
13-AUG-2010
23-AUG-2010
ü
13-AUG-2010
23-AUG-2010
ü
09-AUG-2010
13-AUG-2010
23-AUG-2010
ü
16-AUG-2010
22-SEP-2010
ü
EP080/071: Total Petroleum Hydrocarbons Soil Glass Jar - Unpreserved TP1 (1.0-1.1), TP2 (1.4-1.5), TP2 (3.2-3.3), TP3 (2.0-2.1), TP4 (1.4-1.5), TP4 (2.1-2.2), TP5 (2.9-3.0), TP6 (0-0.1), TP7 (0.9-1.0), TP7 (2.0-2.1), TP8 (0.9-1.0), TP9 (0.9-1.0), TP9 (2.0-2.1), TP10 (1.9-2.0), TP12 (1.4-1.5), TP12 (2.4-2.5), TP13 (0.4-0.5), TP13 (2.0-2.1), TP14 (1.6-1.7), TP11 (2.9-3.0) Soil Glass Jar - Unpreserved TP1 (1.0-1.1), TP2 (1.4-1.5), TP2 (3.2-3.3), TP3 (2.0-2.1), TP4 (1.4-1.5), TP4 (2.1-2.2), TP5 (2.9-3.0), TP6 (0-0.1), TP7 (0.9-1.0), TP7 (2.0-2.1), TP8 (0.9-1.0), TP9 (0.9-1.0), TP9 (2.0-2.1), TP10 (1.9-2.0), TP12 (1.4-1.5), TP12 (2.4-2.5), TP13 (0.4-0.5), TP13 (2.0-2.1), TP14 (1.6-1.7), TP11 (2.9-3.0)
TP1 (1.5-1.6), TP2 (1.9-2.0), TP3 (1.4-1.5), TP4 (0.4-0.5), DUP1, TP5 (1.4-1.5), TP5 (3.9-4.0), TP6 (1.4-1.5), DUP2, TP8 (1.9-2.0), TP9 (1.9-2.0), TP9B (2.5-2.6), TP11 (1.7-1.8), TP12 (1.9-2.0), DUP3, TP13 (1.5-1.6), TP14 (0.9-1.0), TP5 (2.0-2.1),
TP11 (1.9-2.0),
TP1 (1.5-1.6), TP2 (1.9-2.0), TP3 (1.4-1.5), TP4 (0.4-0.5), DUP1, TP5 (1.4-1.5), TP5 (3.9-4.0), TP6 (1.4-1.5), DUP2, TP8 (1.9-2.0), TP9 (1.9-2.0), TP9B (2.5-2.6), TP11 (1.7-1.8), TP12 (1.9-2.0), DUP3, TP13 (1.5-1.6), TP14 (0.9-1.0), TP5 (2.0-2.1),
TP11 (1.9-2.0),
Page Work Order Client Project
: : : :
11 of 22 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Evaluation: 短 = Holding time breach ; 端 = Within holding time.
Matrix: SOIL Method
Sample Date
Container / Client Sample ID(s)
Extraction / Preparation
Analysis
Date extracted
Due for extraction
Evaluation
Date analysed
Due for analysis
Evaluation
13-AUG-2010
23-AUG-2010
端
13-AUG-2010
23-AUG-2010
端
EP080: BTEX Soil Glass Jar - Unpreserved TP1 (1.0-1.1), TP2 (3.2-3.3), TP4 (0.4-0.5), DUP1, TP5 (2.9-3.0), TP6 (0-0.1), TP7 (2.0-2.1), TP8 (1.9-2.0), TP9 (2.0-2.1), TP9B (2.5-2.6), TP10 (1.9-2.0), TP12 (1.9-2.0), DUP3, TP13 (2.0-2.1), TP14 (1.6-1.7),
TP2 (1.4-1.5), TP3 (2.0-2.1), TP4 (1.4-1.5), TP5 (1.4-1.5), TP5 (3.9-4.0), TP6 (1.4-1.5), TP8 (0.9-1.0), TP9 (0.9-1.0), DUP2, TP11 (1.9-2.0), TP12 (2.4-2.5), TP13 (0.4-0.5), TP14 (0.9-1.0), TP11 (2.9-3.0)
09-AUG-2010
TP12 (1.4-1.5),
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12 of 22 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Quality Control Parameter Frequency Compliance The following report summarises the frequency of laboratory QC samples analysed within the analytical lot(s) in which the submitted sample(s) was(where) processed. Actual rate should be greater than or equal to the expected rate. A listing of breaches is provided in the Summary of Outliers. Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Matrix: SOIL Quality Control Sample Type
Analytical Methods Laboratory Duplicates (DUP) Acid Neutralising Capacity (ANC) Cations - soluble by ICP-AES Chromium Suite for Acid Sulphate Soils Exchangeable Cations Free Cyanide By Discrete Analyser Moisture Content Organic Matter PAH/Phenols (SIM) PCB - VIC EPA 448.3 Screen Semivolatile Organic Compounds - Waste Classification Soluble Metals by ICPAES Sulfur - Total as S (LECO) Suspension Peroxide Oxidation-Combined Acidity and Sulphate Total Cyanide By Discrete Analyser Total Fluoride Total Hexavalent Chromium by Alkaline Digestion Total Mercury by FIMS Total Metals by ICP-AES TPH - Semivolatile Fraction TPH Volatiles/BTEX Volatile Organic Compounds - Ultra-trace Laboratory Control Samples (LCS) Acid Neutralising Capacity (ANC) Cations - soluble by ICP-AES Exchangeable Cations Free Cyanide By Discrete Analyser Organic Matter PAH/Phenols (SIM) PCB - VIC EPA 448.3 Screen Semivolatile Organic Compounds - Waste Classification Soluble Metals by ICPAES Sulfur - Total as S (LECO) Total Cyanide By Discrete Analyser Total Fluoride Total Hexavalent Chromium by Alkaline Digestion Total Mercury by FIMS Total Metals by ICP-AES TPH - Semivolatile Fraction
Count QC
Regular
Actual
Rate (%) Expected
EA013 ED093S EA033 ED007 EK025G EA055-103 EP004 EP075(SIM) EP066-EM EP075-EM EG005S ED042T EA029
1 2 1 1 1 9 2 6 1 1 2 1 1
7 6 2 5 9 83 7 42 9 9 5 5 7
14.3 33.3 50.0 20.0 11.1 10.8 28.6 14.3 11.1 11.1 40.0 20.0 14.3
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
ü ü ü ü ü ü ü ü ü ü ü ü ü
NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999
Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement
EK026G EK040T EG048 EG035T EG005T EP071 EP080 EP074-UT
2 1 2 6 6 6 4 1
18 9 10 60 60 51 36 9
11.1 11.1 20.0 10.0 10.0 11.8 11.1 11.1
10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0
ü ü ü ü ü ü ü ü
NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999
Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement
EA013 ED093S ED007 EK025G EP004 EP075(SIM) EP066-EM EP075-EM EG005S ED042T EK026G EK040T EG048 EG035T EG005T EP071
1 1 1 1 2 3 1 1 2 1 1 1 1 3 3 3
7 4 5 9 7 42 9 9 3 5 18 9 10 60 60 51
14.3 25.0 20.0 11.1 28.6 7.1 11.1 11.1 66.7 20.0 5.6 11.1 10.0 5.0 5.0 5.9
5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 10.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0
ü ü ü ü ü ü ü ü ü ü ü ü ü ü ü ü
NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999
Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement
Method
Quality Control Specification Evaluation
Page Work Order Client Project
: : : :
13 of 22 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061 Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Matrix: SOIL Quality Control Sample Type
Analytical Methods Laboratory Control Samples (LCS) - Continued TPH Volatiles/BTEX Volatile Organic Compounds - Ultra-trace Method Blanks (MB) Cations - soluble by ICP-AES Chromium Suite for Acid Sulphate Soils Exchangeable Cations Free Cyanide By Discrete Analyser Organic Matter PAH/Phenols (SIM) PCB - VIC EPA 448.3 Screen Semivolatile Organic Compounds - Waste Classification Soluble Metals by ICPAES Sulfur - Total as S (LECO) Suspension Peroxide Oxidation-Combined Acidity and Sulphate Total Cyanide By Discrete Analyser Total Fluoride Total Hexavalent Chromium by Alkaline Digestion Total Mercury by FIMS Total Metals by ICP-AES TPH - Semivolatile Fraction TPH Volatiles/BTEX Volatile Organic Compounds - Ultra-trace Matrix Spikes (MS) Free Cyanide By Discrete Analyser PAH/Phenols (SIM) PCB - VIC EPA 448.3 Screen Semivolatile Organic Compounds - Waste Classification Total Cyanide By Discrete Analyser Total Hexavalent Chromium by Alkaline Digestion Total Mercury by FIMS Total Metals by ICP-AES TPH - Semivolatile Fraction TPH Volatiles/BTEX Volatile Organic Compounds - Ultra-trace
Count QC
Regular
Actual
Rate (%) Expected
EP080 EP074-UT
2 1
36 9
5.6 11.1
5.0 5.0
ü ü
NEPM 1999 Schedule B(3) and ALS QCS3 requirement NEPM 1999 Schedule B(3) and ALS QCS3 requirement
ED093S EA033 ED007 EK025G EP004 EP075(SIM) EP066-EM EP075-EM EG005S ED042T EA029
2 1 1 1 2 3 1 1 2 1 1
6 2 5 9 7 42 9 9 5 5 7
33.3 50.0 20.0 11.1 28.6 7.1 11.1 11.1 40.0 20.0 14.3
5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0
ü ü ü ü ü ü ü ü ü ü ü
NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999
Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement
EK026G EK040T EG048 EG035T EG005T EP071 EP080 EP074-UT
1 1 1 3 3 3 2 1
18 9 10 60 60 51 36 9
5.6 11.1 10.0 5.0 5.0 5.9 5.6 11.1
5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0
ü ü ü ü ü ü ü ü
NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999 NEPM 1999
Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement Schedule B(3) and ALS QCS3 requirement
EK025G EP075(SIM) EP066-EM EP075-EM EK026G EG048 EG035T EG005T EP071 EP080 EP074-UT
1 3 1 1 1 1 3 3 3 2 1
9 42 9 9 18 10 60 60 51 36 9
11.1 7.1 11.1 11.1 5.6 10.0 5.0 5.0 5.9 5.6 11.1
5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0
ü ü ü ü ü ü ü ü ü ü ü
ALS QCS3 requirement ALS QCS3 requirement ALS QCS3 requirement ALS QCS3 requirement ALS QCS3 requirement ALS QCS3 requirement ALS QCS3 requirement ALS QCS3 requirement ALS QCS3 requirement ALS QCS3 requirement ALS QCS3 requirement
Method
Quality Control Specification Evaluation
Page Work Order Client Project
: : : :
14 of 22 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Brief Method Summaries The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the US EPA, APHA, AS and NEPM. In house developed procedures are employed in the absence of documented standards or by client request. The following report provides brief descriptions of the analytical procedures employed for results reported in the Certificate of Analysis. Sources from which ALS methods have been developed are provided within the Method Descriptions.
Analytical Methods
Method
Matrix
Method Descriptions
ASB-SOL EA009
SOIL SOIL
Acid Neutralising Capacity (ANC)
EA013
SOIL
Suspension Peroxide Oxidation-Combined Acidity and Sulphate
EA029
SOIL
Chromium Suite for Acid Sulphate Soils
EA033
SOIL
EA055-103
SOIL
ED007
SOIL
Sulfur - Total as S (LECO)
ED042T
SOIL
Cations - soluble by ICP-AES
ED093S
SOIL
Soluble Metals by ICPAES
EG005S
SOIL
Total Metals by ICP-AES
EG005T
SOIL
Total Mercury by FIMS
EG035T
SOIL
Asbestos Count on solid matrices using PLM conducted by Subcontracting Laboratory Coastech Research (Canada)(Mod.). NAPP = Acid Production Potential (APP or MAP- Maximum Acid Potential) minus Neutralising Capacity (ANC). NAPP may be +ve, zero or -ve. USEPA 600/2-78-054, I. Miller (2000). A fizz test is done to semiquanititatively estimate the likely reactivity. The soil is then reacted with an known excess quanitity of an appropriate acid. Titration determines the acid remaining, and the ANC can be calculated from comparison with a blank titration. Ahern et al 2004 - a suspension peroxide oxidation method following the 'sulfur trail' by determining the level of 1M KCL extractable sulfur and the sulfur level after oxidation of soil sulphides. The 'acidity trail' is followed by measurement of TAA, TPA and TSA. Liming Rate is based on results for samples as submitted and incorporates a minimum safety factor of 1.5. Ahern et al 2004. This method covers the determination of Chromium Reducible Sulfur (SCR); pHKCl; titratable actual acidity (TAA); acid neutralising capacity by back titration (ANC); and net acid soluble sulfur (SNAS) which incorporates peroxide sulfur. It applies to soils and sediments (including sands) derived from coastal regions. Liming Rate is based on results for samples as submitted and incorporates a minimum safety factor of 1.5. A gravimetric procedure based on weight loss over a 12 hour drying period at 103-105 degrees C. This method is compliant with NEPM (1999) Schedule B(3) (Method 102) Rayment & Higginson (1992) Method 15A1. Cations are exchanged from the sample by contact with Ammonium Chloride. They are then quantitated in the final solution by ICPAES and reported as meq/100g of original soil. This method is compliant with NEPM (1999) Schedule B(3) (Method 301) In-house. Dried and pulverised sample is combusted in a LECO furnace at 1350C in the presence of strong oxidants / catalysts. The evolved S (as SO2) is measured by infra-red detector APHA 21st ed., 3120; USEPA SW 846 - 6010 (ICPAES) Water extracts of the soil are analyzed for major cations by ICPAES. The ICPAES technique ionises samples in a plasma, emitting a characteristic spectrum based on metals present. Intensities at selected wavelengths are compared against those of matrix matched standards. This method is compliant with NEPM (1999) Schedule B(3) (APHA 21st ed., 3120; USEPA SW 846 - 6010) (ICPAES) Soluble metals are determined following an appropriate soil / water extraction of the soil. The ICPAES technique ionises samples in a plasma, emitting characteristic spectrums based on metals present. Intensities at selected wavelengths are compared against those of matrix matched standards. (APHA 21st ed., 3120; USEPA SW 846 - 6010) (ICPAES) Metals are determined following an appropriate acid digestion of the soil. The ICPAES technique ionises samples in a plasma, emitting a characteristic spectrum based on metals present. Intensities at selected wavelengths are compared against those of matrix matched standards. This method is compliant with NEPM (1999) Schedule B(3) AS 3550, APHA 21st ed., 3112 Hg - B (Flow-injection (SnCl2)(Cold Vapour generation) AAS) FIM-AAS is an automated flameless atomic absorption technique. Mercury in solids are determined following an appropriate acid digestion. Ionic mercury is reduced online to atomic mercury vapour by SnCl2 which is then purged into a heated quartz cell. Quantification is by comparing absorbance against a calibration curve. This method is compliant with NEPM (1999) Schedule B(3)
Asbestos - Count (Solid) Net Acid Production Potential
Moisture Content Exchangeable Cations
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15 of 22 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Analytical Methods
Method
Matrix
Method Descriptions
Total Hexavalent Chromium by Alkaline Digestion
EG048
SOIL
Free Cyanide By Discrete Analyser
EK025G
SOIL
Total Cyanide By Discrete Analyser
EK026G
SOIL
Total Fluoride
EK040T
SOIL
Organic Matter
EP004
SOIL
EP066-EM
SOIL
EP071
SOIL
Volatile Organic Compounds - Ultra-trace
* EP074-UT
SOIL
Volatile Organic Compounds - Ultra-trace - Summations PAH/Phenols (SIM)
EP074-UT-SUM
SOIL
USEPA SW846, Method 3060A. Hexavalent chromium is extracted by alkaline digestion. The digest is determined by UV-VIS spectrophotometer following pH adjustment and colour development using dephenylcarbazide. Each run of samples is measured against a five-point calibration curve. This method is compliant with NEPM (1999) Schedule B(3) (Appdx. 2) APHA 21st 4500 CN- C & N. Caustic leach extracts of the sample are distilled at natural pH. The distillates are analyzed for CN by Discrete Analyser. APHA 21st 4500 CN - C & N. Caustic leach extracts of the sample are distilled with sulphuric acid, converting all CN species to HCN. The distillates are analyzed for CN by Discrete Analyser. This method is compliant with NEPM (1999) Schedule B(3) (Method 403) (In-house) Total fluoride is determined by ion specific electrode (ISE) in a solution obtained after a Sodium Carbonate / Potassium Carbonate fusion dissolution. AS1289.4.1.1 - 1997., Dichromate oxidation method after Walkley and Black. This method is compliant with NEPM (1999) Schedule B(3) (Method 105) (USEPA SW 846 - 8270B) Extracts are analysed by Capillary GC/MS and quantification is by comparison against an established 5 point calibration curve. This method is compliant with NEPM (1999) Schedule B(3) (Method 504) (USEPA SW 846 - 8015A) Sample extracts are analysed by Capillary GC/FID and quantified against alkane standards over the range C10 - C36. This method is compliant with NEPM (1999) Schedule B(3) (Method 506.1) (USEPA SW 846 - 8260B) Extracts are analysed by Purge and Trap, Capillary GC/MS in partial SIM/Scan mode. Quantification is by comparison against an established multi-point calibration curves. This method is compliant with NEPM (1999) Schedule B(3) (Method 501) Summation of MAHs and VHCs
EP075(SIM)
SOIL
* EP075-EM
SOIL
EP075-EM-SUM EP080
SOIL SOIL
PCB - VIC EPA 448.3 Screen TPH - Semivolatile Fraction
Semivolatile Organic Compounds Waste Classification SVOC - Waste Classification (Sums) TPH Volatiles/BTEX
Preparation Methods
Exchangeable Cations Preparation Method Alkaline digestion for Hexavalent Chromium Free Cyanide Preparation Method NaOH leach for TCN in Soils Total Fluoride Drying at 85 degrees, bagging and labelling (ASS)
(USEPA SW 846 - 8270B) Extracts are analysed by Capillary GC/MS in Selective Ion Mode (SIM) and quantification is by comparison against an established 5 point calibration curve. This method is compliant with NEPM (1999) Schedule B(3) (Method 502 and 507) (USEPA SW 846 - 8270B) Extracts are analysed by Capillary GC/MS and quantification is by comparison against an established 5 point calibration curve. This technique is compliant with NEPM (1999) Schedule B(3) (Method 502) Summations for EP075 (EM variation) (USEPA SW 846 - 8260B) Extracts are analysed by Purge and Trap, Capillary GC/MS. Quantification is by comparison against an established 5 point calibration curve. This method is compliant with NEPM (1999) Schedule B(3) (Method 501)
Method
Matrix
Method Descriptions
ED007PR
SOIL
EG048PR
SOIL
Rayment & Higginson (1992) method 15A1. A 1M NH4Cl extraction by end over end tumbling at a ratio of 1:20. There is no pretreatment for soluble salts. Extracts can be run by ICP for cations. USEPA SW846, Method 3060A.
EK025 PR
SOIL
EK026PR EK040T-PR EN020PR
SOIL SOIL SOIL
APHA 21st ed., 4500 CN C & N. Cyanides in the soil are directly distilled from the soil at natural pH using a steam distillation aparatus. APHA 21st ed., 4500 CN- C & N. Samples are extracted by end-over-end tumbling with NaOH. (In-house) Samples are fused with Sodium Carbonate / Potassium Carbonate flux. In house
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16 of 22 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Preparation Methods
1:5 solid / water leach for soluble analytes Hot Block Digest for metals in soils sediments and sludges
Organic Matter Methanolic Extraction of Soils for Purge and Trap Methanolic Extraction of Soils Ultra-trace. Tumbler Extraction of Solids - VIC EPA Screen Tumbler Extraction of Solids (Option B Non-concentrating)
Method
Matrix
Method Descriptions
EN34
SOIL
EN69
SOIL
EP004-PR
SOIL
ORG16
SOIL
ORG16-UT
SOIL
ORG17A-EM
SOIL
ORG17B
SOIL
10 g of soil is mixed with 50 mL of distilled water and tumbled end over end for 1 hour. Water soluble salts are leached from the soil by the continuous suspension. Samples are settled and the water filtered off for analysis. USEPA 200.2 Mod. Hot Block Acid Digestion 1.0g of sample is heated with Nitric and Hydrochloric acids, then cooled. Peroxide is added and samples heated and cooled again before being filtered and bulked to volume for analysis. Digest is appropriate for determination of selected metals in sludge, sediments, and soils. This method is compliant with NEPM (1999) Schedule B(3) (Method 202) AS1289.4.1.1 - 1997., Dichromate oxidation method after Walkley and Black. This method is compliant with NEPM (1999) Schedule B(3) (Method 105) (USEPA SW 846 - 5030A) 5g of solid is shaken with surrogate and 10mL methanol prior to analysis by Purge and Trap - GC/MS. (USEPA SW 846 - 5030A) 5g of solid is shaken with surrogate and 10mL methanol prior to analysis by Purge and Trap - GC/MS. In-house, Mechanical agitation (tumbler). 20g of sample, Na2SO4 and surrogate are extracted with 150mL 1:1 DCM/Acetone by end over end tumble. The solvent is decanted, dehydrated and concentrated (by KD) to the desired volume for analysis. In-house, Mechanical agitation (tumbler). 10g of sample, Na2SO4 and surrogate are extracted with 20mL 1:1 DCM/Acetone by end over end tumble. The solvent is transferred directly to a GC vial for analysis.
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17 of 22 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Summary of Outliers Outliers : Quality Control Samples The following report highlights outliers flagged in the Quality Control (QC) Report. Surrogate recovery limits are static and based on USEPA SW 846 or ALS-QWI/EN/38 (in the absence of specific USEPA limits). This report displays QC Outliers (breaches) only.
Duplicates, Method Blanks, Laboratory Control Samples and Matrix Spikes Matrix: SOIL Compound Group Name
Laboratory Sample ID
Client Sample ID
Analyte
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons
EM1008731-025
TP6 (0-0.1)
Fluoranthene
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons
EM1008731-025
TP6 (0-0.1)
Pyrene
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons
EM1008731-025
TP6 (0-0.1)
Benz(a)anthracene
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons
EM1008731-025
TP6 (0-0.1)
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons
EM1008731-025
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons
CAS Number
Data
Limits
206-44-0
57.1 %
0-20%
RPD exceeds LOR based limits
129-00-0
65.7 %
0-20%
RPD exceeds LOR based limits
56-55-3
59.0 %
0-50%
RPD exceeds LOR based limits
Chrysene
218-01-9
61.0 %
0-50%
RPD exceeds LOR based limits
TP6 (0-0.1)
Benzo(b)fluoranthene
205-99-2
78.2 %
0-20%
RPD exceeds LOR based limits
EM1008731-025
TP6 (0-0.1)
Benzo(a)pyrene
50-32-8
82.9 %
0-20%
RPD exceeds LOR based limits
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons
EM1008731-025
TP6 (0-0.1)
Indeno(1.2.3.cd)pyrene
193-39-5
76.4 %
0-50%
RPD exceeds LOR based limits
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons
EM1008731-025
TP6 (0-0.1)
Benzo(g.h.i)perylene
191-24-2
76.8 %
0-50%
RPD exceeds LOR based limits
EP075B: Polynuclear Aromatic Hydrocarbons
EM1008731-003
TP1 (1.5-1.6)
Phenanthrene
85-01-8
120 %
0-20%
RPD exceeds LOR based limits
EP075B: Polynuclear Aromatic Hydrocarbons
EM1008731-003
TP1 (1.5-1.6)
Fluoranthene
206-44-0
107 %
0-20%
RPD exceeds LOR based limits
EP075B: Polynuclear Aromatic Hydrocarbons
EM1008731-003
TP1 (1.5-1.6)
Pyrene
129-00-0
113 %
0-20%
RPD exceeds LOR based limits
EP075B: Polynuclear Aromatic Hydrocarbons
EM1008731-003
TP1 (1.5-1.6)
Benz(a)anthracene
56-55-3
105 %
0-20%
RPD exceeds LOR based limits
EP075B: Polynuclear Aromatic Hydrocarbons
EM1008731-003
TP1 (1.5-1.6)
Chrysene
218-01-9
108 %
0-20%
RPD exceeds LOR based limits
EP075B: Polynuclear Aromatic Hydrocarbons
EM1008731-003
TP1 (1.5-1.6)
205-99-2 207-08-9
84.3 %
0-20%
RPD exceeds LOR based limits
EP075B: Polynuclear Aromatic Hydrocarbons
EM1008731-003
TP1 (1.5-1.6)
Benzo(b) & Benzo(k)fluoranthene Benzo(a)pyrene
50-32-8
99.6 %
0-20%
RPD exceeds LOR based limits
EP075B: Polynuclear Aromatic Hydrocarbons
EM1008731-003
TP1 (1.5-1.6)
Indeno(1.2.3.cd)pyrene
193-39-5
101 %
0-20%
RPD exceeds LOR based limits
EP075B: Polynuclear Aromatic Hydrocarbons
EM1008731-003
TP1 (1.5-1.6)
Benzo(g.h.i)perylene
191-24-2
102 %
0-20%
RPD exceeds LOR based limits
EP074I: Volatile Halogenated Compounds
1690337-001
----
Hexachlorobutadiene
87-68-3
66.4 %
68.4-118%
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons
1690583-005
----
Benzo(g.h.i)perylene
191-24-2
134 %
59-123%
Recovery greater than upper control limit
EG005T: Total Metals by ICP-AES
EM1008731-052
TP11 (1.7-1.8)
Copper
7440-50-8
Not Determined
----
EG005T: Total Metals by ICP-AES
EM1008731-026
TP6 (0.4-0.5)
Copper
7440-50-8
----
EG005T: Total Metals by ICP-AES
EM1008731-052
TP11 (1.7-1.8)
Lead
Not Determined 7439-92-1 Not Determined
EG005T: Total Metals by ICP-AES
EM1008731-026
TP6 (0.4-0.5)
Zinc
7440-66-6
----
MS recovery not determined, background level greater than or equal to 4x spike level. Matrix spike recovery not determined due to sample matrix interference. MS recovery not determined, background level greater than or equal to 4x spike level. MS recovery not determined, background level greater than or equal to 4x spike level.
Comment
Duplicate (DUP) RPDs
Laboratory Control Spike (LCS) Recoveries Recovery less than lower control limit
Matrix Spike (MS) Recoveries
Not Determined
----
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18 of 22 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Matrix: SOIL Compound Group Name
Laboratory Sample ID
Client Sample ID
Analyte
CAS Number
Data
Limits
EG005T: Total Metals by ICP-AES
EM1008731-052
TP11 (1.7-1.8)
Zinc
7440-66-6
Not Determined
----
EG048: Hexavalent Chromium (Alkaline Digest)
EM1008731-008
TP2 (1.9-2.0)
Hexavalent Chromium
18540-29-9
39.5 %
70-130%
EP066: Polychlorinated Biphenyls (PCB)
EM1008731-013
TP3 (1.4-1.5)
Total Polychlorinated biphenyls
----
45.0 %
67-123%
EP075A: Phenolic Compounds (Halogenated)
EM1008731-008
TP2 (1.9-2.0)
2-Chlorophenol
95-57-8
63.8 %
70-130%
EP075A: Phenolic Compounds (Halogenated)
EM1008731-008
TP2 (1.9-2.0)
4-Chloro-3-Methylphenol
59-50-7
69.8 %
70-130%
EP075A: Phenolic Compounds (Halogenated)
EM1008731-008
TP2 (1.9-2.0)
Pentachlorophenol
87-86-5
13.3 %
70-130%
EP075A: Phenolic Compounds (Non-halogenated)
EM1008731-008
TP2 (1.9-2.0)
Phenol
108-95-2
58.9 %
70-130%
EP075A: Phenolic Compounds (Non-halogenated)
EM1008731-008
TP2 (1.9-2.0)
2-Nitrophenol
88-75-5
48.6 %
70-130%
EP075B: Polynuclear Aromatic Hydrocarbons
EM1008731-008
TP2 (1.9-2.0)
Acenaphthene
83-32-9
65.2 %
70-130%
EP080/071: Total Petroleum Hydrocarbons
EM1008731-069
TP11 (2.9-3.0)
C29 - C36 Fraction
Not Determined
----
Laboratory Sample ID
Client Sample ID
Analyte
Data
Limits
EP066S: PCB Surrogate
EM1008731-052
TP11 (1.7-1.8)
Decachlorobiphenyl
2051-24-3
41.0 %
EP074S: VOC Surrogates
EM1008731-008
TP2 (1.9-2.0)
1.2-Dichloroethane-D4
17060-07-0
127 %
EP074S: VOC Surrogates
EM1008731-020
TP4 (2.1-2.2)
Toluene-D8
2037-26-5
74.1 %
EP074S: VOC Surrogates
EM1008731-052
TP11 (1.7-1.8)
Toluene-D8
2037-26-5
79.8 %
EP074S: VOC Surrogates
EM1008731-020
TP4 (2.1-2.2)
4-Bromofluorobenzene
460-00-4
41.0 %
EP075(SIM)S: Phenolic Compound Surrogates
EM1008731-018
TP4 (1.4-1.5)
2-Chlorophenol-D4
93951-73-6
45.6 %
EP075(SIM)S: Phenolic Compound Surrogates
EM1008731-040
TP9 (0.9-1.0)
2-Chlorophenol-D4
93951-73-6
43.6 %
EP075(SIM)S: Phenolic Compound Surrogates
EM1008731-018
TP4 (1.4-1.5)
2.4.6-Tribromophenol
118-79-6
9.6 %
42.4-131 % 80.0-120 % 81.0-117 % 81.0-117 % 74.0-121 % 51.8-129.7 % 51.8-129.7 % 26.8-126.6 %
Comment
Matrix Spike (MS) Recoveries - Continued
l
----
MS recovery not determined, background level greater than or equal to 4x spike level. Recovery less than lower data quality objective Recovery less than lower data quality objective Recovery less than lower data quality objective Recovery less than lower data quality objective Recovery less than lower data quality objective Recovery less than lower data quality objective Recovery less than lower data quality objective Recovery less than lower data quality objective Matrix spike recovery not determined due to sample matrix interference.
For all matrices, no Method Blank value outliers occur.
Regular Sample Surrogates Sub-Matrix: SOIL Compound Group Name
CAS Number
Comment
Samples Submitted Recovery less than lower data quality objective Recovery greater than upper data quality objective Recovery less than lower data quality objective Recovery less than lower data quality objective Recovery less than lower data quality objective Recovery less than lower data quality objective Recovery less than lower data quality objective Recovery less than lower data quality objective
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Sub-Matrix: SOIL Compound Group Name
Laboratory Sample ID
Client Sample ID
Analyte
EP075(SIM)S: Phenolic Compound Surrogates
EM1008731-040
TP9 (0.9-1.0)
2.4.6-Tribromophenol
EP075(SIM)T: PAH Surrogates
EM1008731-040
TP9 (0.9-1.0)
EP075(SIM)T: PAH Surrogates
EM1008731-040
EP075S: Acid Extractable Surrogates
CAS Number
Data
Limits
118-79-6
25.4 %
Anthracene-d10
1719-06-8
33.8 %
TP9 (0.9-1.0)
4-Terphenyl-d14
1718-51-0
54.4 %
EM1008731-052
TP11 (1.7-1.8)
2-Fluorophenol
367-12-4
EP075S: Acid Extractable Surrogates
EM1008731-003
TP1 (1.5-1.6)
2-Fluorophenol
367-12-4
EP075S: Acid Extractable Surrogates
EM1008731-013
TP3 (1.4-1.5)
2-Fluorophenol
367-12-4
EP075S: Acid Extractable Surrogates
EM1008731-041
TP9 (1.9-2.0)
2-Fluorophenol
367-12-4
EP075S: Acid Extractable Surrogates
EM1008731-061
TP13 (1.5-1.6)
2-Fluorophenol
367-12-4
EP075S: Acid Extractable Surrogates
EM1008731-068
TP5 (2.0-2.1)
2-Fluorophenol
367-12-4
EP075S: Acid Extractable Surrogates
EM1008731-052
TP11 (1.7-1.8)
Phenol-d6
13127-88-3
EP075S: Acid Extractable Surrogates
EM1008731-003
TP1 (1.5-1.6)
Phenol-d6
13127-88-3
EP075S: Acid Extractable Surrogates
EM1008731-013
TP3 (1.4-1.5)
Phenol-d6
13127-88-3
EP075S: Acid Extractable Surrogates
EM1008731-041
TP9 (1.9-2.0)
Phenol-d6
13127-88-3
EP075S: Acid Extractable Surrogates
EM1008731-061
TP13 (1.5-1.6)
Phenol-d6
13127-88-3
EP075S: Acid Extractable Surrogates
EM1008731-068
TP5 (2.0-2.1)
Phenol-d6
13127-88-3
EP075S: Acid Extractable Surrogates
EM1008731-052
TP11 (1.7-1.8)
2-Chlorophenol-D4
93951-73-6
EP075S: Acid Extractable Surrogates
EM1008731-003
TP1 (1.5-1.6)
2-Chlorophenol-D4
93951-73-6
EP075S: Acid Extractable Surrogates
EM1008731-013
TP3 (1.4-1.5)
2-Chlorophenol-D4
93951-73-6
EP075S: Acid Extractable Surrogates
EM1008731-041
TP9 (1.9-2.0)
2-Chlorophenol-D4
93951-73-6
EP075S: Acid Extractable Surrogates
EM1008731-061
TP13 (1.5-1.6)
2-Chlorophenol-D4
93951-73-6
EP075S: Acid Extractable Surrogates
EM1008731-068
TP5 (2.0-2.1)
2-Chlorophenol-D4
93951-73-6
EP075S: Acid Extractable Surrogates
EM1008731-020
TP4 (2.1-2.2)
2.4.6-Tribromophenol
Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined
26.8-126.6 % 62.6-135.5 % 63.7-135.2 % ----
Comment
Samples Submitted - Continued
118-79-6
-------------------------------------------------------
Recovery less than lower data quality objective Recovery less than lower data quality objective Recovery less than lower data quality objective Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences
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Sub-Matrix: SOIL Compound Group Name
Laboratory Sample ID
Client Sample ID
Analyte
CAS Number
EP075S: Acid Extractable Surrogates
EM1008731-052
TP11 (1.7-1.8)
2.4.6-Tribromophenol
118-79-6
EP075S: Acid Extractable Surrogates
EM1008731-003
TP1 (1.5-1.6)
2.4.6-Tribromophenol
118-79-6
EP075S: Acid Extractable Surrogates
EM1008731-013
TP3 (1.4-1.5)
2.4.6-Tribromophenol
118-79-6
EP075S: Acid Extractable Surrogates
EM1008731-041
TP9 (1.9-2.0)
2.4.6-Tribromophenol
118-79-6
EP075S: Acid Extractable Surrogates
EM1008731-061
TP13 (1.5-1.6)
2.4.6-Tribromophenol
118-79-6
EP075S: Acid Extractable Surrogates
EM1008731-068
TP5 (2.0-2.1)
2.4.6-Tribromophenol
118-79-6
EP075T: Base/Neutral Extractable Surrogates
EM1008731-052
TP11 (1.7-1.8)
Nitrobenzene-D5
4165-60-0
EP075T: Base/Neutral Extractable Surrogates
EM1008731-003
TP1 (1.5-1.6)
Nitrobenzene-D5
4165-60-0
EP075T: Base/Neutral Extractable Surrogates
EM1008731-013
TP3 (1.4-1.5)
Nitrobenzene-D5
4165-60-0
EP075T: Base/Neutral Extractable Surrogates
EM1008731-041
TP9 (1.9-2.0)
Nitrobenzene-D5
4165-60-0
EP075T: Base/Neutral Extractable Surrogates
EM1008731-061
TP13 (1.5-1.6)
Nitrobenzene-D5
4165-60-0
EP075T: Base/Neutral Extractable Surrogates
EM1008731-068
TP5 (2.0-2.1)
Nitrobenzene-D5
4165-60-0
EP075T: Base/Neutral Extractable Surrogates
EM1008731-052
TP11 (1.7-1.8)
1.2-Dichlorobenzene-D4
2199-69-1
EP075T: Base/Neutral Extractable Surrogates
EM1008731-003
TP1 (1.5-1.6)
1.2-Dichlorobenzene-D4
2199-69-1
EP075T: Base/Neutral Extractable Surrogates
EM1008731-013
TP3 (1.4-1.5)
1.2-Dichlorobenzene-D4
2199-69-1
EP075T: Base/Neutral Extractable Surrogates
EM1008731-041
TP9 (1.9-2.0)
1.2-Dichlorobenzene-D4
2199-69-1
EP075T: Base/Neutral Extractable Surrogates
EM1008731-061
TP13 (1.5-1.6)
1.2-Dichlorobenzene-D4
2199-69-1
EP075T: Base/Neutral Extractable Surrogates
EM1008731-068
TP5 (2.0-2.1)
1.2-Dichlorobenzene-D4
2199-69-1
EP075T: Base/Neutral Extractable Surrogates
EM1008731-052
TP11 (1.7-1.8)
2-Fluorobiphenyl
321-60-8
EP075T: Base/Neutral Extractable Surrogates
EM1008731-003
TP1 (1.5-1.6)
2-Fluorobiphenyl
321-60-8
EP075T: Base/Neutral Extractable Surrogates
EM1008731-013
TP3 (1.4-1.5)
2-Fluorobiphenyl
321-60-8
EP075T: Base/Neutral Extractable Surrogates
EM1008731-041
TP9 (1.9-2.0)
2-Fluorobiphenyl
321-60-8
Data
Limits
Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined
----
Comment
Samples Submitted - Continued
----------------------------------------------------------------
Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences
Page Work Order Client Project
: : : :
21 of 22 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Sub-Matrix: SOIL Compound Group Name
Laboratory Sample ID
Client Sample ID
Analyte
CAS Number
EP075T: Base/Neutral Extractable Surrogates
EM1008731-061
TP13 (1.5-1.6)
2-Fluorobiphenyl
321-60-8
EP075T: Base/Neutral Extractable Surrogates
EM1008731-068
TP5 (2.0-2.1)
2-Fluorobiphenyl
321-60-8
EP075T: Base/Neutral Extractable Surrogates
EM1008731-052
TP11 (1.7-1.8)
Anthracene-d10
1719-06-8
EP075T: Base/Neutral Extractable Surrogates
EM1008731-003
TP1 (1.5-1.6)
Anthracene-d10
1719-06-8
EP075T: Base/Neutral Extractable Surrogates
EM1008731-013
TP3 (1.4-1.5)
Anthracene-d10
1719-06-8
EP075T: Base/Neutral Extractable Surrogates
EM1008731-041
TP9 (1.9-2.0)
Anthracene-d10
1719-06-8
EP075T: Base/Neutral Extractable Surrogates
EM1008731-061
TP13 (1.5-1.6)
Anthracene-d10
1719-06-8
EP075T: Base/Neutral Extractable Surrogates
EM1008731-068
TP5 (2.0-2.1)
Anthracene-d10
1719-06-8
EP075T: Base/Neutral Extractable Surrogates
EM1008731-052
TP11 (1.7-1.8)
4-Terphenyl-d14
1718-51-0
EP075T: Base/Neutral Extractable Surrogates
EM1008731-003
TP1 (1.5-1.6)
4-Terphenyl-d14
1718-51-0
EP075T: Base/Neutral Extractable Surrogates
EM1008731-013
TP3 (1.4-1.5)
4-Terphenyl-d14
1718-51-0
EP075T: Base/Neutral Extractable Surrogates
EM1008731-041
TP9 (1.9-2.0)
4-Terphenyl-d14
1718-51-0
EP075T: Base/Neutral Extractable Surrogates
EM1008731-061
TP13 (1.5-1.6)
4-Terphenyl-d14
1718-51-0
EP075T: Base/Neutral Extractable Surrogates
EM1008731-068
TP5 (2.0-2.1)
4-Terphenyl-d14
1718-51-0
Data
Limits
Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined Not Determined
----
Comment
Samples Submitted - Continued
----------------------------------------
Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences Surrogate recovery not determined due to (target or non-target) matrix interferences
Outliers : Analysis Holding Time Compliance This report displays Holding Time breaches only. Only the respective Extraction / Preparation and/or Analysis component is/are displayed. Matrix: SOIL Extraction / Preparation
Method
Analysis
Date extracted
Due for extraction
Days overdue
Date analysed
Due for analysis
Days overdue
TP10 (1.8-1.9)
19-AUG-2010
10-AUG-2010
9
----
----
----
TP10 (1.8-1.9)
19-AUG-2010
10-AUG-2010
9
----
----
----
Container / Client Sample ID(s)
EA029-A: pH Measurements Snap Lock Bag TP4 (2.1-2.2), EA029-B: Acidity Trail Snap Lock Bag TP4 (2.1-2.2), EA029-C: Sulfur Trail
Page Work Order Client Project
: : : :
22 of 22 EM1008731 Amendment 1 ENVIRONMENTAL EARTH SCIENCES 210061
Matrix: SOIL Extraction / Preparation
Method
Analysis
Date extracted
Due for extraction
Days overdue
Date analysed
Due for analysis
Days overdue
TP10 (1.8-1.9)
19-AUG-2010
10-AUG-2010
9
----
----
----
TP10 (1.8-1.9)
19-AUG-2010
10-AUG-2010
9
----
----
----
TP10 (1.8-1.9)
19-AUG-2010
10-AUG-2010
9
----
----
----
TP10 (1.8-1.9)
19-AUG-2010
10-AUG-2010
9
----
----
----
TP10 (1.8-1.9)
19-AUG-2010
10-AUG-2010
9
----
----
----
TP10 (1.8-1.9)
19-AUG-2010
10-AUG-2010
9
----
----
----
TP10 (1.8-1.9)
19-AUG-2010
10-AUG-2010
9
----
----
----
TP10 (1.8-1.9)
19-AUG-2010
10-AUG-2010
9
----
----
----
TP10 (1.8-1.9)
19-AUG-2010
10-AUG-2010
9
----
----
----
TP10 (1.8-1.9)
19-AUG-2010
10-AUG-2010
9
----
----
----
TP10 (1.8-1.9)
19-AUG-2010
10-AUG-2010
9
----
----
----
Container / Client Sample ID(s)
EA029-C: Sulfur Trail - Analysis Holding Time Compliance Snap Lock Bag TP4 (2.1-2.2), EA029-D: Calcium Values Snap Lock Bag TP4 (2.1-2.2), EA029-E: Magnesium Values Snap Lock Bag TP4 (2.1-2.2), EA029-F: Excess Acid Neutralising Capacity Snap Lock Bag TP4 (2.1-2.2), EA029-G: Retained Acidity Snap Lock Bag TP4 (2.1-2.2), EA029-H: Acid Base Accounting Snap Lock Bag TP4 (2.1-2.2), EA033-A: Actual Acidity Snap Lock Bag TP4 (2.1-2.2), EA033-B: Potential Acidity Snap Lock Bag TP4 (2.1-2.2), EA033-C: Acid Neutralising Capacity Snap Lock Bag TP4 (2.1-2.2), EA033-D: Retained Acidity Snap Lock Bag TP4 (2.1-2.2), EA033-E: Acid Base Accounting Snap Lock Bag TP4 (2.1-2.2),
Outliers : Frequency of Quality Control Samples The following report highlights breaches in the Frequency of Quality Control Samples.
l
No Quality Control Sample Frequency Outliers exist.
AUSTRALIAN SAFER ENVIRONMENT & TECHNOLOGY PTY LTD ABN 36 088 095 112
Our ref : ASET22916/ 26096 / 1 - 7 Your ref :EM1008731 NATA Accreditation No: 14484 16 August 2010 Australian Laboratory Services Pty Ltd 4, Westal Road, Springvale, VIC 3171 Attn: Mr Steven Mcgrath Dear Steven, Asbestos Identification This report presents the results of seven samples, forwarded by Australian Laboratory Services Pty Ltd on 13 August 2010, for analysis for asbestos. 1.Introduction:Seven samples forwarded were examined and analysed for the presence of asbestos. 2. Methods : The samples were examined under a Stereo Microscope and selected fibres were analysed by Polarized Light Microscopy in conjunction with Dispersion Staining Method (Safer Environment Method 1.) 3. Results :
Sample No. 1. ASET22916 / 26096 / 1. EM1008731 - 002. Approx dimensions 5.0 cm x 5.25 cm x 0.45 cm The sample consisted of a mixture of clayish soil, stones, plant matter and fragments of plaster. No asbestos detected. Sample No. 2. ASET22916 / 26096 / 2. EM1008731 - 021. Approx dimensions 6.5 cm x 7.0 cm x 1.2 cm The sample consisted of a mixture of clayish soil, stones, plant matter and fragments of plaster and brick. No asbestos detected. Sample No. 3. ASET22916 / 26096 / 3. EM1008731 - 021. Approx dimensions 7.0 cm x 6.0 cm x 1.25 cm The sample consisted of a mixture of soil, stones, plant matter, fibres^, fragments of plaster, cement, brick, corroded metal, coal like material, bitumin and glass. Chrysotile^ asbestos detected. Sample No. 4. ASET22916 / 26096 / 4. EM1008731 - 032. Approx dimensions 8.0 cm x 6.5 cm x 3.0 cm The sample consisted of a mixture of clayish soil, stones, fibres^, plant matter and fragments of plaster, cement, bitumin and brick. Chrysotile^ asbestos and Crocidolite^ asbestos detected.
SUITE 710 / 90 GEORGE STREET, HORNSBY NSW 2077 – P.O. BOX 1644 HORNSBY WESTFIELD NSW 1635 PHONE: (02) 99872183 FAX: (02)99872151 EMAIL: aset@bigpond.net.au WEBSITE: www.Ausset.com.au OCCUPATIONAL HEALTH & SAFETY STUDIES • INDOOR AIR QUALITY SURVEYS • HAZARDOUS MATERIAL SURVEYS • RADIATION SURVEYS • ASBESTOS SURVEYS ASBESTOS DETECTION & IDENTIFICATION • REPAIR & CALIBRATION OF SCIENTIFIC EQUIPMENT • AIRBORNE FIBRE & SILICA MONITORING
Page 1 of 2
Sample No. 5. ASET22916 / 26096 / 5. EM1008731 - 039. Approx dimensions 6.0 cm x 7.0 cm x 1.0 cm The sample consisted of a mixture of clayish soil, stones, fibres^, fragments of plaster, bitumin, brick and glass. Chrysotile^ asbestos detected. Sample No. 6. ASET22916 / 26096 / 6. EM1008731 - 050. Approx dimensions 7.0 cm x 6.5 cm x 1.2 cm The sample consisted of a mixture of clayish soil, stones, fibres^, plant matter and fragments of plaster, cement and brick. Chrysotile^ asbestos detected. Sample No. 7. ASET22916 / 26096 / 7. EM1008731 - 060. Approx dimensions 6.0 cm x 6.5 cm x 1.25 cm The sample consisted of a mixture of clayish soil, stones, plant matter and fragments of plaster, bitumin, corroded metal and brick. No asbestos detected. Analysed and reported by,
Mahen De Silva . BSc. MSc. Grad Dip (Occ Hyg) Occupational Hygienist / Approved Signatory. Approved Identifier.
This document is issued in accordance with NATAâ&#x20AC;&#x2122;s Accreditation requirements. Accredited for compliance with ISO/IEC 17025.
Page 2 of 2
Certificate of Analysis Environmental and Earth Sciences P.O Box 1090 St Kilda South Victoria 3182
NATA Accredited Laboratory Number 1645 The tests covered by this document have been performed in accordance with NATA and ISO/IES 17025 and are traceable to national standards of measurement. This document shall not be reproduced, except in full.
Attention: Jordan Fraser
Project Client Reference Received Date
273205 210061 (Yarraville) Aug 12, 2010
Customer Sample ID
SPLIT 1
SPLIT 2
SPLIT 3
Sample Matrix
Soil
Soil
Soil
mgt-Labmark Sample No.
10-AU21450
10-AU21451
10-AU21452
Date Sampled
Aug 09, 2010
Aug 09, 2010
Aug 09, 2010
Test/Reference
PQL
Unit
TRH C6-C9 Fraction by GC
20
mg/kg
< 20
< 20
< 20
TRH C10-C14 Fraction by GC
10
mg/kg
< 10
50
< 10
TRH C15-C28 Fraction by GC
20
mg/kg
130
610
61
TRH C29-C36 Fraction by GC
20
mg/kg
100
480
58
Acenaphthene
0.5
mg/kg
< 0.5
< 0.5
< 0.5
Acenaphthylene
0.5
mg/kg
< 0.5
< 0.5
< 0.5
Anthracene
0.5
mg/kg
< 0.5
< 0.5
< 0.5
Benz(a)anthracene
0.5
mg/kg
< 0.5
< 0.5
< 0.5
Benzo(a)pyrene
0.5
mg/kg
< 0.5
< 0.5
< 0.5
Benzo(b)fluoranthene & Benzo(k)fluoranthene1
mg/kg
<1
<1
<1
Benzo(g.h.i)perylene
0.5
mg/kg
< 0.5
< 0.5
< 0.5
Chrysene
0.5
mg/kg
< 0.5
< 0.5
< 0.5
Dibenz(a.h)anthracene
0.5
mg/kg
< 0.5
< 0.5
< 0.5
Fluoranthene
0.5
mg/kg
< 0.5
< 0.5
< 0.5
Fluorene
0.5
mg/kg
< 0.5
< 0.5
< 0.5
Indeno(1.2.3-cd)pyrene
0.5
mg/kg
< 0.5
< 0.5
< 0.5
Naphthalene
0.5
mg/kg
< 0.5
< 0.5
< 0.5
Phenanthrene
0.5
mg/kg
< 0.5
< 0.5
< 0.5
Pyrene
0.5
mg/kg
< 0.5
< 0.5
0.7
Total PAH
0.5
mg/kg
<1
<1
0.70
Anthracene-d10 (surr.)
1
%
109
106
100
p-Terphenyl-d14 (surr.)
1
%
102
101
99
2-Fluorobiphenyl (surr.)
1
%
104
105
104
2-Chlorophenol
0.5
mg/kg
-
< 0.5
< 0.5
2-Methylphenol (o-Cresol)
0.5
mg/kg
-
< 0.5
< 0.5
2.3-Dichlorophenol
1
mg/kg
-
<1
<1
2.3.4-Trichlorophenol
0.5
mg/kg
-
< 0.5
< 0.5
2.3.4.6-Tetrachlorophenol
1
mg/kg
-
<1
<1
2.3.5-Trichlorophenol
0.5
mg/kg
-
< 0.5
< 0.5
2.3.5.6-Tetrachlorophenol
1
mg/kg
-
<1
<1
2.3.6-Trichlorophenol
0.5
mg/kg
-
< 0.5
< 0.5
2.4 & 2.5-Dichlorophenol
2
mg/kg
-
<2
<2
2.4.6-Trichlorophenol
0.5
mg/kg
-
< 0.5
< 0.5
2.6-Dichlorophenol
0.5
mg/kg
-
< 0.5
< 0.5
3&4-Methylphenol (m&p-Cresol)
1
mg/kg
-
<1
<1
3-Chlorophenol & 4-Chlorophenol
1
mg/kg
-
<1
<1
3.4-Dichlorophenol
0.5
mg/kg
-
< 0.5
< 0.5
3.5-Dichlorophenol
0.5
mg/kg
-
< 0.5
< 0.5
4-Chloro-3-methylphenol
0.5
mg/kg
-
< 0.5
< 0.5
Pentachlorophenol
1
mg/kg
-
<1
<1
Total Recoverable Hydrocarbons
Polycyclic Aromatic Hydrocarbons
Individual Phenols (standard list)
First Reported: Aug 18, 2010 Date Printed: Aug 18, 2010
mgt-LabMark 1868 Dandenong Rd, Clayton, VIC Australia 3168 ABN : 50 005 085 521 Telephone: +61 3 9538 2277 Facsimile: +61 3 9538 2278
Page 1 of 8 Report Number: 273205-S
Customer Sample ID
SPLIT 1
SPLIT 2
SPLIT 3
Sample Matrix
Soil
Soil
Soil
mgt-Labmark Sample No.
10-AU21450
10-AU21451
10-AU21452
Date Sampled
Aug 09, 2010
Aug 09, 2010
Aug 09, 2010
Test/Reference
PQL
Unit
Phenol
0.5
mg/kg
-
< 0.5
< 0.5
2.4.6-Tribromophenol (surr.)
1
%
-
108
78
Benzene
0.5
mg/kg
< 0.5
< 0.5
< 0.5
o-Xylene
1
mg/kg
<1
<1
<1
Total m+p-Xylenes
2
mg/kg
<2
<2
<2
Toluene
1
mg/kg
<1
<1
<1
Ethylbenzene
1
mg/kg
<1
<1
<1
Xylenes(ortho.meta and para)
3
mg/kg
<3
<3
<3
4-Bromofluorobenzene (surr.)
1
%
85
86
73
% Moisture
0.1
%
18
34
29
Cyanide (free)
0.1
mg/kg
-
< 0.1
-
Cyanide (total)
0.1
mg/kg
-
1.5
-
Arsenic
2
mg/kg
68
77
37
Cadmium
2
mg/kg
13
5.2
<2
Chromium
2
mg/kg
49
130
32
Copper
2
mg/kg
72
2000
38
Lead
2
mg/kg
100
230
73
Nickel
2
mg/kg
45
110
32
Zinc
2
mg/kg
450
1200
370
Mercury
0.01
mg/kg
0.17
0.26
0.15
BTEX
Metals (8)
Sample History Where samples are submitted/analysed over several days, the last date of extraction and analysis is reported.
Description Total Recoverable Hydrocarbons
Testing Site Clayton
Extracted Aug 13, 2010
Analysed Aug 16, 2010
Clayton
Aug 13, 2010
Aug 16, 2010
Clayton
Aug 13, 2010
Aug 16, 2010
Clayton
Aug 13, 2010
Aug 16, 2010
Clayton Clayton Clayton
Aug 13, 2010 Aug 13, 2010 Aug 13, 2010
Aug 16, 2010 Aug 18, 2010 Aug 18, 2010
Clayton
Aug 13, 2010
Aug 17, 2010
- Method: LM-LTM-ORG-2000
Polycyclic Aromatic Hydrocarbons - Method: LM-LTM-ORG-20000
Individual Phenols (standard list) - Method: LM-LTM-ORG-20000
BTEX
- Method: LM-LTM-ORG-1100: Determination of BTEX & Volatile Alkanes (C6-C9) in Soils & Waters by Purge & Trap / GCMS
% Moisture Cyanide (free) Cyanide (total) - Method: INO-4270
Metals (8) - Method: LM-LTM-MET-3100
First Reported: Aug 18, 2010 Date Printed: Aug 18, 2010
mgt-LabMark 1868 Dandenong Rd, Clayton, VIC Australia 3168 ABN : 50 005 085 521 Telephone: +61 3 9538 2277 Facsimile: +61 3 9538 2278
Page 2 of 8 Report Number: 273205-S
mgt-Labmark Internal Quality Control Review General 1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on request. 2. All soil results are reported on a dry basis, unless otherwise stated. 3. Actual PQLs are matrix dependant. Quoted PQLs may be raised where sample extracts are diluted due to interferences. 4. Result are uncorrected for matrix spikes or surrogate recoveries. 5. SVOC analysis on water are performed on homogenized, unfiltered sample, unless noted otherwise. 6. Samples were analysed on an as received basis. 7. This report replaces any interim results previously issued.
Holding Times Please refer to 'Sampling and Preservation Chart for Soils & Waters' for holding times. (LM-FOR-ADM-020) For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample Receipt Acknowledgment. If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitability qualified results may still be reported. Holding times apply from the date of sampling, therefore compliance to these my be outside the laboratory's control. **NOTE: pH duplicates are reported as a range NOT as an RPD
UNITS mg/kg:milligrams per Kilogram
mg/l:milligrams per litre
ug/l: micrograms per litre
ppm: Parts per million
ppb: Parts per billion
%: Percentage
org/100ml: Organisms per 100 millilitres
NTU: Units
TERMS Dry:
Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR:
Limit of Reporting.
SPIKE:
Addition of the analyte to the sample and reported as percentage recovery.
RPD:
Relative Percent Difference between two Duplicate pieces of analysis.
LCS:
Laboratory Control Sample - reported as percent recovery.
CRM:
Certified Reference Material - reported as percent recovery.
Method Blank:
In the case of solid samples these are performed on laboratory certified clean sands. In the case of water samples these are performed on de-ionised water.
Surr - Surrogate: The addition of a like compound to the analyte target and reported as percentage recovery. Duplicate:
A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
Batch Duplicate: A second piece of analysis from a sample outside of the clients batch of samples but run within the laboratory batch of analysis. Batch SPIKE:
Spike recovery reported on a sample from outside of the clients batch of samples but run within the laboratory batch of analysis.
USEPA:
United States Environment Protection Authority
APHA:
American Public Health Association
ASLP:
Australian Standard Leaching Procedure (AS4439.3)
TCLP:
Toxicity Characteristic Leaching Procedure
COC:
Chain of Custody
SRA:
Sample Receipt Advice
QC - ACCEPTANCE CRITERIA RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable: Results <10 times the LOR : No Limit Results between 10-20 times LOR : RPD must lie between 0-50% Results >20 times LOR : RPD must lie between 0-20% Surrogate Recoveries : Recoveries must lie between 50-150% - Phenols 20-130%.
QC DATA GENERAL COMMENTS 1. Where a result is reported as a less than (<), higher than the nominated LOR this is due to either Matrix Interference, extract dilution required due to interferences or contaminant levels within the sample, high moisture content or insufficient sample provided. 2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch a 1:10 ratio. The Parent and Duplicate data shown is not data from your samples. 3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS. 4. Orgaonchlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike. 5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported in the C10-C14 cell of the Report. 6. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte. 7. Polychlorinated Biphenyls are spiked only using Arochlor 1260 in Matrix Spikes and LCS's. 8. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample. 9. Duplicate RPD's are calculated from raw analytical data thus it is possible to have two two sets of data below the LOR with a positive RPD - eg: LOR 0.1, Result A = <0.1 (raw data is 0.02) & Result B = <0.1 (raw data is 0.03) resulting in a RPD of 40% calculated from the raw data.
First Reported: Aug 18, 2010 Date Printed: Aug 18, 2010
mgt-LabMark 1868 Dandenong Rd, Clayton, VIC Australia 3168 ABN : 50 005 085 521 Telephone: +61 3 9538 2277 Facsimile: +61 3 9538 2278
Page 3 of 8 Report Number: 273205-S
Quality Control Results
Sample, Test, Result Reference
Units
Result 1
Acceptance Limits
Pass Qualifying Codes Limits
Method Blank Total Recoverable Hydrocarbons LM-LTM-ORG-2000 TRH C6-C9 Fraction by GC mg/kg < 20 20 Pass TRH C10-C14 Fraction by GC mg/kg < 10 10 Pass TRH C15-C28 Fraction by GC mg/kg < 20 20 Pass TRH C29-C36 Fraction by GC mg/kg < 20 20 Pass Method Blank Polycyclic Aromatic Hydrocarbons LM-LTM-ORG-20000 Acenaphthene mg/kg < 0.5 0.5 Pass Acenaphthylene mg/kg < 0.5 0.5 Pass Anthracene mg/kg < 0.5 0.5 Pass Benz(a)anthracene mg/kg < 0.5 0.5 Pass Benzo(a)pyrene mg/kg < 0.5 0.5 Pass Benzo(b)fluoranthene & Benzo(k)fluoranthene mg/kg <1 1 Pass Benzo(g.h.i)perylene mg/kg < 0.5 0.5 Pass Chrysene mg/kg < 0.5 0.5 Pass Dibenz(a.h)anthracene mg/kg < 0.5 0.5 Pass Fluoranthene mg/kg < 0.5 0.5 Pass Fluorene mg/kg < 0.5 0.5 Pass Indeno(1.2.3-cd)pyrene mg/kg < 0.5 0.5 Pass Naphthalene mg/kg < 0.5 0.5 Pass Phenanthrene mg/kg < 0.5 0.5 Pass Pyrene mg/kg < 0.5 0.5 Pass Method Blank Individual Phenols (standard list) LM-LTM-ORG-20000 2-Chlorophenol mg/kg < 0.5 0.5 Pass 2-Methylphenol (o-Cresol) mg/kg < 0.5 0.5 Pass 2.3-Dichlorophenol mg/kg <1 1 Pass 2.3.4-Trichlorophenol mg/kg < 0.5 0.5 Pass 2.3.4.6-Tetrachlorophenol mg/kg <1 1 Pass 2.3.5-Trichlorophenol mg/kg < 0.5 0.5 Pass 2.3.5.6-Tetrachlorophenol mg/kg <1 1 Pass 2.3.6-Trichlorophenol mg/kg < 0.5 0.5 Pass 2.4 & 2.5-Dichlorophenol mg/kg <2 2 Pass 2.4.6-Trichlorophenol mg/kg < 0.5 0.5 Pass 2.6-Dichlorophenol mg/kg < 0.5 0.5 Pass 3&4-Methylphenol (m&p-Cresol) mg/kg <1 1 Pass 3-Chlorophenol & 4-Chlorophenol mg/kg <1 1 Pass 3.4-Dichlorophenol mg/kg < 0.5 0.5 Pass 3.5-Dichlorophenol mg/kg < 0.5 0.5 Pass 4-Chloro-3-methylphenol mg/kg < 0.5 0.5 Pass Pentachlorophenol mg/kg <1 1 Pass Phenol mg/kg < 0.5 0.5 Pass Method Blank BTEX LM-LTM-ORG-1100: Determination of BTEX & Volatile Alkanes (C6-C9) in Soils & Waters by Purge & Trap / GCMS Benzene mg/kg < 0.5 0.5 Pass o-Xylene mg/kg <1 1 Pass Total m+p-Xylenes mg/kg <2 2 Pass Toluene mg/kg <1 1 Pass Ethylbenzene mg/kg <1 1 Pass Xylenes(ortho.meta and para) mg/kg <3 3 Pass Method Blank Cyanide (free) Cyanide (total) Method Blank Metals (8) LM-LTM-MET-3100 Arsenic Cadmium Chromium Copper Lead Nickel Zinc
First Reported: Aug 18, 2010 Date Printed: Aug 18, 2010
mg/kg mg/kg
< 0.1 < 0.1
0.1 0.1
Pass Pass
mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg
<2 <2 <2 <2 <2 <2 <2
2 2 2 2 2 2 2
Pass Pass Pass Pass Pass Pass Pass
mgt-LabMark 1868 Dandenong Rd, Clayton, VIC Australia 3168 ABN : 50 005 085 521 Telephone: +61 3 9538 2277 Facsimile: +61 3 9538 2278
Page 4 of 8 Report Number: 273205-S
Sample, Test, Result Reference Mercury LCS - % Recovery
Units
Result 1
Acceptance Limits
mg/kg
< 0.01
0.01
Pass
% % % %
Result 1 86 101 100 92
70-130 70-130 70-130 70-130
Pass Pass Pass Pass
% % % % % % % % % % % % % %
Result 1 102 100 110 103 98 85 94 85 94 102 87 100 102 100
70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130
Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass
% % % % % % % % % % % % % % %
Result 1 90 96 93 94 87 96 92 91 89 91 96 93 93 103 94
30-130 30-130 30-130 30-130 30-130 30-130 30-130 30-130 30-130 30-130 30-130 30-130 30-130 30-130 30-130
Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass
Total Recoverable Hydrocarbons LM-LTM-ORG-2000
TRH C6-C9 Fraction by GC TRH C10-C14 Fraction by GC TRH C15-C28 Fraction by GC TRH C29-C36 Fraction by GC LCS - % Recovery
Polycyclic Aromatic Hydrocarbons LM-LTM-ORG-20000
Acenaphthene Acenaphthylene Anthracene Benz(a)anthracene Benzo(a)pyrene Benzo(g.h.i)perylene Chrysene Dibenz(a.h)anthracene Fluoranthene Fluorene Indeno(1.2.3-cd)pyrene Naphthalene Phenanthrene Pyrene LCS - % Recovery Individual Phenols (standard list) LM-LTM-ORG-20000
2-Chlorophenol 2-Methylphenol (o-Cresol) 2.3.4-Trichlorophenol 2.3.5-Trichlorophenol 2.3.6-Trichlorophenol 2.4 & 2.5-Dichlorophenol 2.4.6-Trichlorophenol 2.6-Dichlorophenol 3&4-Methylphenol (m&p-Cresol) 3-Chlorophenol & 4-Chlorophenol 3.4-Dichlorophenol 3.5-Dichlorophenol 4-Chloro-3-methylphenol Pentachlorophenol Phenol LCS - % Recovery
Pass Qualifying Limits Codes
BTEX LM-LTM-ORG-1100: Determination of BTEX & Volatile Alkanes Result (C6-C9) 1 in Soils & Waters by Purge & Trap / GCMS
Benzene Toluene Ethylbenzene Xylenes(ortho.meta and para) LCS - % Recovery
% % % %
103 85 80 100
70-130 70-130 70-130 70-130
Pass Pass Pass Pass
Cyanide (free) Cyanide (total) LCS - % Recovery Metals (8) LM-LTM-MET-3100 Arsenic Cadmium Chromium Copper Lead Nickel Zinc Mercury [Duplicate of 10-AU21296 - BATCH] Total Recoverable Hydrocarbons TRH C6-C9 Fraction by GC TRH C10-C14 Fraction by GC TRH C15-C28 Fraction by GC TRH C29-C36 Fraction by GC
% %
Result 1 100 86
70-130 70-130
Pass Pass
% % % % % % % %
Result 1 94 91 91 91 94 88 94 105
70-130 70-130 70-130 70-130 70-130 70-130 70-130 70-130
Pass Pass Pass Pass Pass Pass Pass Pass
mg/kg mg/kg mg/kg mg/kg
Result 1 < 20 < 10 130 100
30% 30% 30% 30%
Pass Pass Pass Pass
First Reported: Aug 18, 2010 Date Printed: Aug 18, 2010
Result 2 < 20 < 10 100 83
RPD <1 <1 25 23
mgt-LabMark 1868 Dandenong Rd, Clayton, VIC Australia 3168 ABN : 50 005 085 521 Telephone: +61 3 9538 2277 Facsimile: +61 3 9538 2278
Page 5 of 8 Report Number: 273205-S
Sample, Test, Result Reference
Units
[Duplicate of 10-AU21450] Polycyclic Aromatic Hydrocarbons Acenaphthene mg/kg Acenaphthylene mg/kg Anthracene mg/kg Benz(a)anthracene mg/kg Benzo(a)pyrene mg/kg Benzo(b)fluoranthene & Benzo(k)fluoranthene mg/kg Benzo(g.h.i)perylene mg/kg Chrysene mg/kg Dibenz(a.h)anthracene mg/kg Fluoranthene mg/kg Fluorene mg/kg Indeno(1.2.3-cd)pyrene mg/kg Naphthalene mg/kg Phenanthrene mg/kg Pyrene mg/kg [Duplicate of 10-AU21296 - BATCH] BTEX Benzene mg/kg o-Xylene mg/kg Total m+p-Xylenes mg/kg Toluene mg/kg Ethylbenzene mg/kg Xylenes(ortho.meta and para) mg/kg [Duplicate of 10-AU21450] Metals (8) Arsenic mg/kg Cadmium mg/kg Chromium mg/kg Copper mg/kg Lead mg/kg Nickel mg/kg Zinc mg/kg Mercury mg/kg [Duplicate of 10-AU21430 - BATCH] Individual Phenols (standard list) 2-Chlorophenol mg/kg 2-Methylphenol (o-Cresol) mg/kg 2.3-Dichlorophenol mg/kg 2.3.4-Trichlorophenol mg/kg 2.3.4.6-Tetrachlorophenol mg/kg 2.3.5-Trichlorophenol mg/kg 2.3.5.6-Tetrachlorophenol mg/kg 2.3.6-Trichlorophenol mg/kg 2.4 & 2.5-Dichlorophenol mg/kg 2.4.6-Trichlorophenol mg/kg 2.6-Dichlorophenol mg/kg 3&4-Methylphenol (m&p-Cresol) mg/kg 3-Chlorophenol & 4-Chlorophenol mg/kg 3.4-Dichlorophenol mg/kg 3.5-Dichlorophenol mg/kg 4-Chloro-3-methylphenol mg/kg Pentachlorophenol mg/kg Phenol mg/kg [Duplicate of 10-AU21032 - BATCH] Cyanide (free) Cyanide (total) [Spike of 10-AU21450] - % Recovery Total Recoverable Hydrocarbons TRH C6-C9 Fraction by GC TRH C10-C14 Fraction by GC TRH C15-C28 Fraction by GC TRH C29-C36 Fraction by GC [Spike of 10-AU21450] - % Recovery
First Reported: Aug 18, 2010 Date Printed: Aug 18, 2010
Acceptance Limits
Result 1
Pass Qualifying Limits Codes
Result 1 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 <1 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5
Result 2 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 <1 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5
RPD <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30%
Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass
Result 1 < 0.5 <1 <2 <1 <1 <3
Result 2 < 0.5 <1 <2 <1 <1 <3
RPD <1 <1 <1 <1 <1 <1
30% 30% 30% 30% 30% 30%
Pass Pass Pass Pass Pass Pass
Result 1 68 13 49 72 100 45 450 0.17
Result 2 84 17 55 91 120 45 430 0.22
RPD 22 22 12 23 14 1.0 5.0 26
30% 30% 30% 30% 30% 30% 30% 30%
Pass Pass Pass Pass Pass Pass Pass Pass
Result 1 < 0.5 < 0.5 <1 < 0.5 <1 < 0.5 <1 < 0.5 <2 < 0.5 < 0.5 <1 <1 < 0.5 < 0.5 < 0.5 <1 < 0.5
Result 2 < 0.5 < 0.5 <1 < 0.5 <1 < 0.5 <1 < 0.5 <2 < 0.5 < 0.5 <1 <1 < 0.5 < 0.5 < 0.5 <1 < 0.5
RPD <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30% 30%
Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass
mg/kg mg/kg
Result 1 < 0.1 0.20
Result 2 < 0.1 0.20
RPD <1 <1
30% 30%
Pass Pass
% % % %
Result 1 71 97 103 80
70 - 130 70 - 130 70 - 130 70 - 130
Pass Pass Pass Pass
mgt-LabMark 1868 Dandenong Rd, Clayton, VIC Australia 3168 ABN : 50 005 085 521 Telephone: +61 3 9538 2277 Facsimile: +61 3 9538 2278
Page 6 of 8 Report Number: 273205-S
Sample, Test, Result Reference
Units
Polycyclic Aromatic Hydrocarbons Acenaphthene % Acenaphthylene % Anthracene % Benz(a)anthracene % Benzo(a)pyrene % Benzo(b)fluoranthene & Benzo(k)fluoranthene% Benzo(g.h.i)perylene % Chrysene % Dibenz(a.h)anthracene % Fluoranthene % Fluorene % Indeno(1.2.3-cd)pyrene % Naphthalene % Phenanthrene % Pyrene % [Spike of 10-AU21430 - BATCH] - % Recovery Individual Phenols (standard list) 2-Chlorophenol % 2.3-Dichlorophenol % 2.3.4-Trichlorophenol % 2.3.5-Trichlorophenol % 2.3.5.6-Tetrachlorophenol % 2.3.6-Trichlorophenol % 2.4 & 2.5-Dichlorophenol % 2.4.6-Trichlorophenol % 2.6-Dichlorophenol % 3&4-Methylphenol (m&p-Cresol) % 3-Chlorophenol & 4-Chlorophenol % 3.4-Dichlorophenol % 3.5-Dichlorophenol % 4-Chloro-3-methylphenol % Pentachlorophenol % Phenol % [Spike of 10-AU21450] - % Recovery BTEX Benzene % o-Xylene % Total m+p-Xylenes % Toluene % Ethylbenzene % Xylenes(ortho.meta and para) % [Spike of 10-AU21032 - BATCH] - % Recovery Cyanide (free) Cyanide (total) [Spike of 10-AU21450] - % Recovery Metals (8) Arsenic Cadmium Chromium Copper Lead Nickel Zinc Mercury
First Reported: Aug 18, 2010 Date Printed: Aug 18, 2010
Result 1
Acceptance Limits
Pass Qualifying Limits Codes
Result 1 100 110 116 122 125 127 86 98 87 114 99 92 100 110 113
70 - 130 70 - 130 70 - 130 70 - 130 70 - 130 70 - 130 70 - 130 70 - 130 70 - 130 70 - 130 70 - 130 70 - 130 70 - 130 70 - 130 70 - 130
Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass
Result 1 84 75 97 96 101 86 90 91 88 87 94 102 95 85 83 92
30 - 130 30 - 130 30 - 130 30 - 130 30 - 130 30 - 130 30 - 130 30 - 130 30 - 130 30 - 130 30 - 130 30 - 130 30 - 130 30 - 130 30 - 130 30 - 130
Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass Pass
Result 1 79 75 78 80 75 77
70 - 130 70 - 130 70 - 130 70 - 130 70 - 130 70 - 130
Pass Pass Pass Pass Pass Pass
% %
Result 1 100 100
70 - 130 70 - 130
Pass Pass
% % % % % % % %
Result 1 127 91 95 84 80 104 104 94
70 - 130 70 - 130 70 - 130 70 - 130 70 - 130 70 - 130 70 - 130 70 - 130
Pass Pass Pass Pass Pass Pass Pass Pass
mgt-LabMark 1868 Dandenong Rd, Clayton, VIC Australia 3168 ABN : 50 005 085 521 Telephone: +61 3 9538 2277 Facsimile: +61 3 9538 2278
Page 7 of 8 Report Number: 273205-S
Sample Integrity Custody Seals Intact (if used)
N/A
Attempt to Chill was evident
Yes
Sample correctly preserved
Yes
Organic samples had Teflon liners
Yes
Samples received with Zero Headspace
No
Samples received within HoldingTime
Yes
Some samples have been subcontracted
No
Authorised By
Glenn Jackson Final report - this Report replaces any previously issued Report - Indicates Not Requested * Indicates NATA accreditation does not cover the performance of this service mgt-Labmark shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Glenn Jackson mgt-Labmark be liable for consequential damages including, but not limited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
NATA Signatory
Final report - this Report replaces any previously issued Report - Indicates Not Requested * Indicates NATA accreditation does not cover the performance of this service mgt-Labmark shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall mgt-Labmark be liable for consequential damages including, but not limited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
First Reported: Aug 18, 2010 Date Printed: Aug 18, 2010
mgt-LabMark 1868 Dandenong Rd, Clayton, VIC Australia 3168 ABN : 50 005 085 521 Telephone: +61 3 9538 2277 Facsimile: +61 3 9538 2278
Page 8 of 8 Report Number: 273205-S
EM1009164 False
CERTIFICATE OF ANALYSIS EM1009164
Page
: 1 of 10
: ENVIRONMENTAL EARTH SCIENCES
Laboratory
: Environmental Division Melbourne
: MR JORDAN FRASER
Contact
: Steven McGrath
: P.O.BOX 2253
Address
: 4 Westall Rd Springvale VIC Australia 3171
Work Order
:
Client
Contact Address
FOOTSCRAY VIC, AUSTRALIA 3011 E-mail
: jfraser@eesi.biz
: steven.mcgrath@alsenviro.com
Telephone
: +61 03 96871666
Telephone
: +61-3-8549 9600
Facsimile
: +61 03 96871844
Facsimile
: +61-3-8549 9601
Project
: 210061 REBATCH OF EM1008731
QC Level
: NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Order number
: ----
C-O-C number
: ----
Date Samples Received
: 23-AUG-2010
Sampler
: ----
Issue Date
: 02-SEP-2010
Site
: YARRAVILLE
Quote number
: EN/010/10
No. of samples received
: 16
No. of samples analysed
: 16
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. All pages of this report have been checked and approved for release. This Certificate of Analysis contains the following information: l General Comments l Analytical Results l Surrogate Control Limits NATA Accredited Laboratory 825 This document is issued in accordance with NATA accreditation requirements. Accredited for compliance with ISO/IEC 17025.
Signatories This document has been electronically signed by the authorized signatories indicated below. Electronic signing has been carried out in compliance with procedures specified in 21 CFR Part 11. Signatories
Position
Accreditation Category
Kim McCabe Nancy Wang Terrance Hettipathirana Xingbin Lin
Senior Inorganic Chemist Senior Semivolatile Instrument Chemist Team Leader - Metals Senior Organic Chemist
Inorganics Organics Inorganics Organics
Environmental Division Melbourne 4 Westall Rd Springvale VIC Australia 3171 Tel. +61-3-8549 9600 Fax. +61-3-8549 9601 www.alsglobal.com
Page Work Order Client Project
: : : :
3 of 10 EM1009164 ENVIRONMENTAL EARTH SCIENCES 210061 REBATCH OF EM1008731
General Comments The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, developed procedures are employed in the absence of documented standards or by client request. Where moisture determination has been performed, results are reported on a dry weight basis. Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insuffient sample for analysis. Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference. When date(s) and/or time(s) are shown bracketed, these have been assumed by the laboratory for processing purposes. If the sampling time is displayed as 0:00 the information was not provided by client. Key :
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society. LOR = Limit of reporting ^ = This result is computed from individual analyte detections at or above the level of reporting
l
Analysis for TP10 (1.8-1.9) conducted by ALS Brisbane, NATA Site No. 818.
l
EP070: EM1009164_2 Poor duplicate precision due to sample heterogeneity. Confirmed by re-analysis.
l
EP070: EM1009164_4 Poor matrix spike recovery due to sample heterogeneity. Confirmed by re-analysis.
l
EP075(SIM): Insufficient sample to confirm surrogate recoveries via re-extraction.
APHA, AS and NEPM. In house
Page Work Order Client Project
: : : :
4 of 10 EM1009164 ENVIRONMENTAL EARTH SCIENCES 210061 REBATCH OF EM1008731
Analytical Results Client sample ID
Sub-Matrix: ASLP LEACHATE
Client sampling date / time Compound
CAS Number
TP6 (0-0.1)
TP9 (2.0-2.1)
TP1 (1.5-1.6)
TP2 (3.2-3.3)
TP7 (2.0-2.1)
25-AUG-2010 12:00
25-AUG-2010 12:00
25-AUG-2010 12:00
25-AUG-2010 12:00
25-AUG-2010 12:00
LOR
Unit
EM1009164-001
EM1009164-002
EM1009164-003
EM1009164-006
EM1009164-007
0.1
mg/L
----
----
----
0.7
0.5
EG005C: Leachable Metals by ICPAES Arsenic
7440-38-2
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons 91-20-3
1.0
µg/L
----
----
<1.0
----
----
208-96-8
1.0
µg/L
----
----
<1.0
----
----
Acenaphthene
83-32-9
1.0
µg/L
----
----
<1.0
----
----
Fluorene
86-73-7
1.0
µg/L
----
----
<1.0
----
----
Phenanthrene
85-01-8
1.0
µg/L
----
----
2.2
----
----
Anthracene
120-12-7
1.0
µg/L
----
----
<1.0
----
----
Fluoranthene
206-44-0
1.0
µg/L
----
----
<1.0
----
----
Pyrene
129-00-0
1.0
µg/L
----
----
<1.0
----
----
56-55-3
1.0
µg/L
----
----
<1.0
----
----
Chrysene
218-01-9
1.0
µg/L
----
----
<1.0
----
----
Benzo(b)fluoranthene
205-99-2
1.0
µg/L
----
----
<1.0
----
----
Benzo(k)fluoranthene
207-08-9
1.0
µg/L
----
----
<1.0
----
----
50-32-8
0.5
µg/L
<0.5
<0.5
<0.5
----
----
Indeno(1.2.3.cd)pyrene
193-39-5
1.0
µg/L
----
----
<1.0
----
----
Dibenz(a.h)anthracene
53-70-3
1.0
µg/L
----
----
<1.0
----
----
191-24-2
1.0
µg/L
----
----
<1.0
----
----
Phenol-d6
13127-88-3
0.1
%
22.0
24.9
16.8
----
----
2-Chlorophenol-D4
93951-73-6
0.1
%
60.6
68.9
46.3
----
----
118-79-6
0.1
%
122
102
72.1
----
----
2-Fluorobiphenyl
321-60-8
0.1
%
63.6
65.5
39.2
----
----
Anthracene-d10
1719-06-8
0.1
%
91.8
92.2
56.3
----
----
4-Terphenyl-d14
1718-51-0
0.1
%
125
150
96.8
----
----
Naphthalene Acenaphthylene
Benz(a)anthracene
Benzo(a)pyrene
Benzo(g.h.i)perylene
EP075(SIM)S: Phenolic Compound Surrogates
2.4.6-Tribromophenol
EP075(SIM)T: PAH Surrogates
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5 of 10 EM1009164 ENVIRONMENTAL EARTH SCIENCES 210061 REBATCH OF EM1008731
Analytical Results Client sample ID
Sub-Matrix: ASLP LEACHATE
Client sampling date / time Compound
CAS Number
TP10 (1.8-1.9)
----
----
----
----
25-AUG-2010 14:00
----
----
----
----
----
----
----
----
----
----
----
----
LOR
Unit
EM1009164-016
0.1
mg/L
2.6
EG005C: Leachable Metals by ICPAES Copper
7440-50-8
Page Work Order Client Project
: : : :
6 of 10 EM1009164 ENVIRONMENTAL EARTH SCIENCES 210061 REBATCH OF EM1008731
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP6 (0-0.1)
TP9 (2.0-2.1)
TP1 (1.5-1.6)
TP5 (2.0-2.1)
TP11 (1.9-2.0)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1009164-001
EM1009164-002
EM1009164-003
EM1009164-004
EM1009164-005
----
1.0
%
----
49.6
----
41.8
31.6
----
0.1
pH Unit
5.0
5.0
5.0
----
----
Initial pH
----
0.1
pH Unit
7.1
8.7
8.0
----
----
After HCl pH
----
0.1
pH Unit
1.5
1.6
1.5
----
----
Final pH
----
0.1
pH Unit
5.1
5.8
5.1
----
----
Aliphatic C16-C35
----
100
mg/kg
----
16600
----
3000
1000
Aliphatic > C35
----
100
mg/kg
----
9600
----
1900
700
Aromatic C16-C35
----
90
mg/kg
----
8590
----
2160
660
Aromatic > C35
----
100
mg/kg
----
7400
----
2700
700
2-Bromonaphthalene
580-13-2
0.1
%
----
93.1
----
101
98.0
2-Fluorobiphenyl
321-60-8
0.1
%
----
95.3
----
95.3
96.4
Compound
CAS Number
EA055: Moisture Content ^ Moisture Content (dried @ 103째C)
EN60: ASLP Leaching Procedure Extraction Fluid pH
EN60: Bottle Leaching Procedure
EP070: Total Petroleum Hydrocarbons - Speciation
EP070: Total Petroleum Hydrocarbons - Speciation
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: : : :
7 of 10 EM1009164 ENVIRONMENTAL EARTH SCIENCES 210061 REBATCH OF EM1008731
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP2 (3.2-3.3)
TP7 (2.0-2.1)
TP12 (0.4-0.5)
TP11 (0.9-1.0)
TP10 (1.4-1.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1009164-006
EM1009164-007
EM1009164-008
EM1009164-009
EM1009164-010
1.0
%
----
----
12.6
15.5
13.0
2
mg/kg
----
----
111
109
320
----
0.1
pH Unit
5.0
5.0
----
----
----
Initial pH
----
0.1
pH Unit
8.5
8.6
----
----
----
After HCl pH
----
0.1
pH Unit
1.7
1.6
----
----
----
Final pH
----
0.1
pH Unit
5.4
6.1
----
----
----
Compound
CAS Number
EA055: Moisture Content ^ Moisture Content (dried @ 103째C)
----
EG005T: Total Metals by ICP-AES Cobalt
7440-48-4
EN60: ASLP Leaching Procedure Extraction Fluid pH
EN60: Bottle Leaching Procedure
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8 of 10 EM1009164 ENVIRONMENTAL EARTH SCIENCES 210061 REBATCH OF EM1008731
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time Compound
CAS Number
TP14 (0.9-1.0)
TP2 (0.4-0.5)
TP3 (0.4-0.5)
TP5 (0.4-0.5)
TP5 (1.4-1.5)
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
LOR
Unit
EM1009164-011
EM1009164-012
EM1009164-013
EM1009164-014
EM1009164-015
1.0
%
14.7
13.6
20.3
13.9
31.5
2
mg/kg
66
183
46
61
184
EA055: Moisture Content ^ Moisture Content (dried @ 103째C)
----
EG005T: Total Metals by ICP-AES Cobalt
7440-48-4
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: : : :
9 of 10 EM1009164 ENVIRONMENTAL EARTH SCIENCES 210061 REBATCH OF EM1008731
Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP10 (1.8-1.9)
----
----
----
----
09-AUG-2010 15:00
----
----
----
----
----
----
----
----
LOR
Unit
EM1009164-016
----
0.1
pH Unit
5.0
----
----
----
----
Initial pH
----
0.1
pH Unit
7.4
----
----
----
----
After HCl pH
----
0.1
pH Unit
1.6
----
----
----
----
Final pH
----
0.1
pH Unit
5.2
----
----
----
----
Compound
CAS Number
EN60: ASLP Leaching Procedure Extraction Fluid pH
EN60: Bottle Leaching Procedure
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10 of 10 EM1009164 ENVIRONMENTAL EARTH SCIENCES 210061 REBATCH OF EM1008731
Surrogate Control Limits Sub-Matrix: ASLP LEACHATE
Recovery Limits (%)
CAS Number
Low
Phenol-d6
13127-88-3
10.0
59.3
2-Chlorophenol-D4
93951-73-6
15.2
116.3
118-79-6
14.5
137.9
2-Fluorobiphenyl
321-60-8
37.8
128.4
Anthracene-d10
1719-06-8
36.3
136.7
4-Terphenyl-d14
1718-51-0
42.1
130.1
CAS Number
Low
High
Compound
High
EP075(SIM)S: Phenolic Compound Surrogates
2.4.6-Tribromophenol
EP075(SIM)T: PAH Surrogates
Sub-Matrix: SOIL
Compound
Recovery Limits (%)
EP070: Total Petroleum Hydrocarbons - Speciation 2-Bromonaphthalene
580-13-2
70
130
2-Fluorobiphenyl
321-60-8
70
130
False
QUALITY CONTROL REPORT EM1009164
Page
: 1 of 5
: ENVIRONMENTAL EARTH SCIENCES
Laboratory
: Environmental Division Melbourne
: MR JORDAN FRASER
Contact
: Steven McGrath
: P.O.BOX 2253
Address
: 4 Westall Rd Springvale VIC Australia 3171
Work Order
:
Client
Contact Address
FOOTSCRAY VIC, AUSTRALIA 3011 E-mail
: jfraser@eesi.biz
: steven.mcgrath@alsenviro.com
Telephone
: +61 03 96871666
Telephone
: +61-3-8549 9600
Facsimile
: +61 03 96871844
Facsimile
: +61-3-8549 9601
Project
: 210061 REBATCH OF EM1008731
QC Level
: NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Site
: YARRAVILLE
C-O-C number
: ----
Date Samples Received
: 23-AUG-2010
Sampler
: ----
Issue Date
: 02-SEP-2010
Order number
: ----
Quote number
: EN/010/10
No. of samples received
: 16
No. of samples analysed
: 16
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. All pages of this report have been checked and approved for release. This Quality Control Report contains the following information: l Laboratory Duplicate (DUP) Report ; Relative Percentage Difference (RPD) and Acceptance Limits l Method Blank (MB) and Laboratory Control Spike (LCS) Report ; Recovery and Acceptance Limits l Matrix Spike (MS) Report ; Recovery and Acceptance Limits NATA Accredited Laboratory 825 This document is issued in accordance with NATA accreditation requirements. Accredited for compliance with ISO/IEC 17025.
Signatories This document has been electronically signed by the authorized signatories indicated below. Electronic signing has been carried out in compliance with procedures specified in 21 CFR Part 11. Signatories
Position
Accreditation Category
Kim McCabe Nancy Wang Terrance Hettipathirana Xingbin Lin
Senior Inorganic Chemist Senior Semivolatile Instrument Chemist Team Leader - Metals Senior Organic Chemist
Inorganics Organics Inorganics Organics
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: : : :
2 of 5 EM1009164 ENVIRONMENTAL EARTH SCIENCES 210061 REBATCH OF EM1008731
General Comments The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, developed procedures are employed in the absence of documented standards or by client request. Where moisture determination has been performed, results are reported on a dry weight basis. Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insuffient sample for analysis. Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference. Key :
Anonymous = Refers to samples which are not specifically part of this work order but formed part of the QC process lot CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society. LOR = Limit of reporting RPD = Relative Percentage Difference # = Indicates failed QC
APHA, AS and NEPM. In house
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3 of 5 EM1009164 ENVIRONMENTAL EARTH SCIENCES 210061 REBATCH OF EM1008731
Laboratory Duplicate (DUP) Report The quality control term Laboratory Duplicate refers to a randomly selected intralaboratory split. Laboratory duplicates provide information regarding method precision and sample heterogeneity. The permitted ranges for the Relative Percent Deviation (RPD) of Laboratory Duplicates are specified in ALS Method QWI -EN/38 and are dependent on the magnitude of results in comparison to the level of reporting: Result < 10 times LOR:No Limit; Result between 10 and 20 times LOR:- 0% - 50%; Result > 20 times LOR:- 0% - 20%. Laboratory Duplicate (DUP) Report
Sub-Matrix: SOIL Laboratory sample ID
Client sample ID
Method: Compound
CAS Number
LOR
Unit
Original Result
Duplicate Result
RPD (%)
Recovery Limits (%)
EA055: Moisture Content (QC Lot: 1459832) EM1009153-004
Anonymous
EA055-103: Moisture Content (dried @ 103째C)
----
1.0
%
11.9
11.7
2.1
0% - 50%
EM1009161-010
Anonymous
EA055-103: Moisture Content (dried @ 103째C)
----
1.0
%
11.3
12.5
10.0
0% - 50%
EA055-103: Moisture Content (dried @ 103째C)
----
1.0
%
14.7
13.2
10.8
0% - 50%
EA055: Moisture Content (QC Lot: 1459833) EM1009164-011
TP14 (0.9-1.0)
EG005T: Total Metals by ICP-AES (QC Lot: 1460523) EM1009131-040
Anonymous
EG005T: Cobalt
7440-48-4
2
mg/kg
25
29
14.5
0% - 50%
EM1009168-004
Anonymous
EG005T: Cobalt
7440-48-4
2
mg/kg
<2
<2
0.0
No Limit
EP070: Total Petroleum Hydrocarbons - Speciation (QC Lot: 1462067) EM1009164-002
TP9 (2.0-2.1)
EP070: Aliphatic C16-C35
----
100
mg/kg
16600
11300
# 37.7
0% - 20%
EP070: Aliphatic > C35
----
100
mg/kg
9600
7400
# 25.9
0% - 20%
EP070: Aromatic > C35
----
100
mg/kg
7400
6000
# 21.1
0% - 20%
EP070: Aromatic C16-C35
----
90
mg/kg
8590
6090
# 34.0
0% - 20%
CAS Number
LOR
Unit
Original Result
Duplicate Result
RPD (%)
Recovery Limits (%)
7440-50-8
0.1
mg/L
<0.1
<0.1
0.0
No Limit
7440-38-2
0.1
mg/L
<0.1
<0.1
0.0
No Limit
Laboratory Duplicate (DUP) Report
Sub-Matrix: WATER Laboratory sample ID
Client sample ID
Method: Compound
EG005C: Leachable Metals by ICPAES (QC Lot: 1462338) EB1014864-001
Anonymous
EG005C: Copper
EG005C: Leachable Metals by ICPAES (QC Lot: 1464311) EM1009161-016
Anonymous
EG005C: Arsenic
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4 of 5 EM1009164 ENVIRONMENTAL EARTH SCIENCES 210061 REBATCH OF EM1008731
Method Blank (MB) and Laboratory Control Spike (LCS) Report The quality control term Method / Laboratory Blank refers to an analyte free matrix to which all reagents are added in the same volumes or proportions as used in standard sample preparation. The purpose of this QC parameter is to monitor potential laboratory contamination. The quality control term Laboratory Control Sample (LCS) refers to a certified reference material, or a known interference free matrix spiked with target analytes. The purpose of this QC parameter is to monitor method precision and accuracy independent of sample matrix. Dynamic Recovery Limits are based on statistical evaluation of processed LCS. Method Blank (MB) Report
Sub-Matrix: SOIL Method: Compound
Laboratory Control Spike (LCS) Report Spike
Spike Recovery (%)
Concentration
LCS
Low
High
80
119 137
CAS Number
LOR
Unit
7440-48-4
2
mg/kg
<2
25.4 mg/kg
90.7
Result
Recovery Limits (%)
EG005T: Total Metals by ICP-AES (QCLot: 1460523) EG005T: Cobalt
EP070: Total Petroleum Hydrocarbons - Speciation (QCLot: 1462067) EP070: Aliphatic C16-C35
----
100
mg/kg
<100
5400 mg/kg
87.8
71
EP070: Aliphatic > C35
----
100
mg/kg
<100
----
----
----
----
EP070: Aromatic C16-C35
----
90
mg/kg
<90
1860 mg/kg
94.7
73
128
EP070: Aromatic > C35
----
100
mg/kg
<100
----
----
----
----
Method Blank (MB) Report
Spike
Spike Recovery (%)
Concentration
LCS
Low
High
Sub-Matrix: WATER Method: Compound
Laboratory Control Spike (LCS) Report Recovery Limits (%)
CAS Number
LOR
Unit
7440-50-8
0.1
mg/L
<0.1
1.0 mg/L
112
81
127
7440-38-2
0.1
mg/L
<0.1
1.00 mg/L
94.4
80
120
Result
EG005C: Leachable Metals by ICPAES (QCLot: 1462338) EG005C: Copper
EG005C: Leachable Metals by ICPAES (QCLot: 1464311) EG005C: Arsenic
EP075(SIM)B: Polynuclear Aromatic Hydrocarbons (QCLot: 1463907) 91-20-3
1
µg/L
<1.0
5 µg/L
65.2
38
126
208-96-8
1
µg/L
<1.0
5 µg/L
80.4
35
133
EP075(SIM): Acenaphthene
83-32-9
1
µg/L
<1.0
5 µg/L
81.3
41
127
EP075(SIM): Fluorene
86-73-7
1
µg/L
<1.0
5 µg/L
91.8
42
128
EP075(SIM): Phenanthrene
85-01-8
1
µg/L
<1.0
5 µg/L
96.2
45
131
EP075(SIM): Anthracene
120-12-7
1
µg/L
<1.0
5 µg/L
97.8
47
129
EP075(SIM): Fluoranthene
206-44-0
1
µg/L
<1.0
5 µg/L
103
42
132
EP075(SIM): Pyrene
129-00-0
1
µg/L
<1.0
5 µg/L
92.4
42
132
56-55-3
1
µg/L
<1.0
5 µg/L
89.2
30.8
145
EP075(SIM): Chrysene
218-01-9
1
µg/L
<1.0
5 µg/L
105
30.7
139
EP075(SIM): Benzo(b)fluoranthene
205-99-2
1
µg/L
<1.0
5 µg/L
123
40
144
EP075(SIM): Benzo(k)fluoranthene
207-08-9
1
µg/L
<1.0
5 µg/L
129
44
136
50-32-8
0.5
µg/L
<0.5
5 µg/L
104
43
135
EP075(SIM): Indeno(1.2.3.cd)pyrene
193-39-5
1
µg/L
<1.0
5 µg/L
84.8
47
149
EP075(SIM): Dibenz(a.h)anthracene
53-70-3
1
µg/L
<1.0
5 µg/L
82.3
47
151
191-24-2
1
µg/L
<1.0
5 µg/L
103
47
151
EP075(SIM): Naphthalene EP075(SIM): Acenaphthylene
EP075(SIM): Benz(a)anthracene
EP075(SIM): Benzo(a)pyrene
EP075(SIM): Benzo(g.h.i)perylene
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5 of 5 EM1009164 ENVIRONMENTAL EARTH SCIENCES 210061 REBATCH OF EM1008731
Matrix Spike (MS) Report The quality control term Matrix Spike (MS) refers to an intralaboratory split sample spiked with a representative set of target analytes. The purpose of this QC parameter is to monitor potential matrix effects on analyte recoveries. Static Recovery Limits as per laboratory Data Quality Objectives (DQOs). Ideal recovery ranges stated may be waived in the event of sample matrix interference. Matrix Spike (MS) Report
Sub-Matrix: SOIL Laboratory sample ID
Client sample ID
Method: Compound
CAS Number
Spike
Spike Recovery (%)
Concentration
MS
Low
Recovery Limits (%) High
EP070: Total Petroleum Hydrocarbons - Speciation (QCLot: 1462067) EM1009164-004
TP5 (2.0-2.1)
EP070: Aliphatic C16-C35
----
5400 mg/kg
# 60.6
70
130
EP070: Aromatic C16-C35
----
1860 mg/kg
# Not Determined
70
130
Spike
Spike Recovery (%)
Concentration
MS
Low
High
Matrix Spike (MS) Report
Sub-Matrix: WATER Laboratory sample ID
Client sample ID
Recovery Limits (%)
Method: Compound
CAS Number
EG005C: Copper
7440-50-8
1.00 mg/L
96.4
70
130
EG005C: Arsenic
7440-38-2
1.00 mg/L
96.6
70
130
EG005C: Leachable Metals by ICPAES (QCLot: 1462338) EM1009164-016
TP10 (1.8-1.9)
EG005C: Leachable Metals by ICPAES (QCLot: 1464311) EM1009161-017
Anonymous
True
INTERPRETIVE QUALITY CONTROL REPORT Work Order
: EM1009164
Page
: 1 of 7
Client
: ENVIRONMENTAL EARTH SCIENCES : MR JORDAN FRASER : P.O.BOX 2253
Laboratory Address
: Environmental Division Melbourne : Steven McGrath : 4 Westall Rd Springvale VIC Australia 3171
Contact Address
Contact
FOOTSCRAY VIC, AUSTRALIA 3011 E-mail Telephone Facsimile
: jfraser@eesi.biz : +61 03 96871666 : +61 03 96871844
E-mail Telephone Facsimile
: steven.mcgrath@alsenviro.com : +61-3-8549 9600 : +61-3-8549 9601
Project Site C-O-C number Sampler Order number
: 210061 REBATCH OF EM1008731 : YARRAVILLE : ---: ---: ----
QC Level
: NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Date Samples Received Issue Date
: 23-AUG-2010 : 02-SEP-2010
Quote number
: EN/010/10
No. of samples received No. of samples analysed
: 16 : 16
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. All pages of this report have been checked and approved for release. This Interpretive Quality Control Report contains the following information: l Analysis Holding Time Compliance
l Quality Control Parameter Frequency Compliance l Brief Method Summaries l Summary of Outliers
Environmental Division Melbourne 4 Westall Rd Springvale VIC Australia 3171 Tel. +61-3-8549 9600 Fax. +61-3-8549 9601 www.alsglobal.com
Page Work Order Client Project
: : : :
2 of 7 EM1009164 ENVIRONMENTAL EARTH SCIENCES 210061 REBATCH OF EM1008731
Analysis Holding Time Compliance The following report summarises extraction / preparation and analysis times and compares with recommended holding times. Dates reported represent first date of extraction or analysis and precludes subsequent dilutions and reruns. Information is also provided re the sample container (preservative) from which the analysis aliquot was taken. Elapsed period to analysis represents number of days from sampling where no extraction / digestion is involved or period from extraction / digestion where this is present. For composite samples, sampling date is assumed to be that of the oldest sample contributing to the composite. Sample date for laboratory produced leachates is assumed as the completion date of the leaching process. Outliers for holding time are based on USEPA SW 846, APHA, AS and NEPM (1999). A listing of breaches is provided in the Summary of Outliers. Holding times for leachate methods (excluding elutriates) vary according to the analytes being determined on the resulting solution. For non -volatile analytes, the holding time compliance assessment compares the leach date with the shortest analyte holding time for the equivalent soil method. These soil holding times are: Organics (14 days); Mercury (28 days) & other metals (180 days). A recorded breach therefore does not guarantee a breach for all non-volatile parameters. Evaluation: û = Holding time breach ; ü = Within holding time.
Matrix: SOIL Method
Extraction / Preparation
Sample Date
Container / Client Sample ID(s)
Analysis
Date extracted
Due for extraction
Evaluation
Date analysed
Due for analysis
Evaluation
09-AUG-2010
----
----
----
23-AUG-2010
16-AUG-2010
û
25-AUG-2010
25-AUG-2010
21-FEB-2011
ü
31-AUG-2010
21-FEB-2011
ü
TP7 (2.0-2.1)
25-AUG-2010
27-AUG-2010
21-FEB-2011
ü
27-AUG-2010
21-FEB-2011
ü
TP11 (0.9-1.0), TP14 (0.9-1.0), TP3 (0.4-0.5), TP5 (1.4-1.5)
09-AUG-2010
24-AUG-2010
05-FEB-2011
ü
26-AUG-2010
05-FEB-2011
ü
09-AUG-2010
---
05-FEB-2011
----
24-AUG-2010
05-FEB-2011
ü
TP7 (2.0-2.1)
09-AUG-2010
---
05-FEB-2011
----
25-AUG-2010
05-FEB-2011
ü
TP9 (2.0-2.1),
09-AUG-2010
---
23-AUG-2010
----
25-AUG-2010
23-AUG-2010
û
EA055: Moisture Content Soil Glass Jar - Unpreserved TP9 (2.0-2.1), TP11 (1.9-2.0), TP11 (0.9-1.0), TP14 (0.9-1.0), TP3 (0.4-0.5), TP5 (1.4-1.5)
TP5 (2.0-2.1), TP12 (0.4-0.5), TP10 (1.4-1.5), TP2 (0.4-0.5), TP5 (0.4-0.5),
EG005C: Leachable Metals by ICPAES Clear Plastic Bottle - Nitric Acid; Unfiltered TP10 (1.8-1.9) Clear Plastic Bottle - Nitric Acid; Unfiltered TP2 (3.2-3.3), EG005T: Total Metals by ICP-AES Soil Glass Jar - Unpreserved TP12 (0.4-0.5), TP10 (1.4-1.5), TP2 (0.4-0.5), TP5 (0.4-0.5), EN60: ASLP Leaching Procedure Lab Split: Leach for metals excl. Hg TP10 (1.8-1.9) Lab Split: Leach for metals excl. Hg TP2 (3.2-3.3), LabSplit: Leach for organics and other tests TP6 (0-0.1), TP1 (1.5-1.6)
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: : : :
3 of 7 EM1009164 ENVIRONMENTAL EARTH SCIENCES 210061 REBATCH OF EM1008731 Evaluation: û = Holding time breach ; ü = Within holding time.
Matrix: SOIL Method
Extraction / Preparation
Sample Date
Container / Client Sample ID(s)
Analysis
Date extracted
Due for extraction
Evaluation
Date analysed
Due for analysis
Evaluation
09-AUG-2010
---
05-FEB-2011
----
24-AUG-2010
05-FEB-2011
ü
TP7 (2.0-2.1)
09-AUG-2010
---
05-FEB-2011
----
25-AUG-2010
05-FEB-2011
ü
TP9 (2.0-2.1),
09-AUG-2010
---
23-AUG-2010
----
25-AUG-2010
23-AUG-2010
û
TP5 (2.0-2.1),
09-AUG-2010
25-AUG-2010
23-AUG-2010
û
27-AUG-2010
04-OCT-2010
ü
TP9 (2.0-2.1),
25-AUG-2010
26-AUG-2010
01-SEP-2010
ü
27-AUG-2010
05-OCT-2010
ü
EN60: Bottle Leaching Procedure Lab Split: Leach for metals excl. Hg TP10 (1.8-1.9) Lab Split: Leach for metals excl. Hg TP2 (3.2-3.3), LabSplit: Leach for organics and other tests TP6 (0-0.1), TP1 (1.5-1.6) EP070: Total Petroleum Hydrocarbons - Speciation Soil Glass Jar - Unpreserved TP9 (2.0-2.1), TP11 (1.9-2.0) EP075(SIM)B: Polynuclear Aromatic Hydrocarbons Amber Glass Bottle - Unpreserved TP6 (0-0.1), TP1 (1.5-1.6)
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Quality Control Parameter Frequency Compliance The following report summarises the frequency of laboratory QC samples analysed within the analytical lot(s) in which the submitted sample(s) was(where) processed. Actual rate should be greater than or equal to the expected rate. A listing of breaches is provided in the Summary of Outliers. Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Matrix: SOIL Quality Control Sample Type
QC
Regular
Actual
Rate (%) Expected
EA055-103 EG005T EP070
3 2 1
25 19 9
12.0 10.5 11.1
10.0 10.0 10.0
NEPM 1999 Schedule B(3) and ALS QCS3 requirement NEPM 1999 Schedule B(3) and ALS QCS3 requirement NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Laboratory Control Samples (LCS) Total Metals by ICP-AES TPH - Speciation
ü ü ü
EG005T EP070
1 1
19 9
5.3 11.1
5.0 5.0
NEPM 1999 Schedule B(3) and ALS QCS3 requirement NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Method Blanks (MB) Total Metals by ICP-AES TPH - Speciation
ü ü
EG005T EP070
1 1
19 9
5.3 11.1
5.0 5.0
NEPM 1999 Schedule B(3) and ALS QCS3 requirement NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Matrix Spikes (MS) Total Metals by ICP-AES TPH - Speciation
ü ü
EG005T EP070
1 1
19 9
5.3 11.1
5.0 5.0
ü ü
ALS QCS3 requirement ALS QCS3 requirement
Analytical Methods Laboratory Duplicates (DUP) Moisture Content Total Metals by ICP-AES TPH - Speciation
Count Method
Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Matrix: WATER Quality Control Sample Type
Analytical Methods Laboratory Duplicates (DUP) Leachable Metals by ICPAES
Quality Control Specification Evaluation
Count Method
QC
Regular
Actual
Rate (%) Expected
Quality Control Specification Evaluation
EG005C
2
7
28.6
10.0
ü
NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Laboratory Control Samples (LCS) Leachable Metals by ICPAES PAH/Phenols (GC/MS - SIM)
EG005C EP075(SIM)
2 1
7 7
28.6 14.3
5.0 5.0
NEPM 1999 Schedule B(3) and ALS QCS3 requirement NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Method Blanks (MB) Leachable Metals by ICPAES PAH/Phenols (GC/MS - SIM)
ü ü
EG005C EP075(SIM)
2 1
7 7
28.6 14.3
5.0 5.0
NEPM 1999 Schedule B(3) and ALS QCS3 requirement NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Matrix Spikes (MS) Leachable Metals by ICPAES
ü ü
EG005C
2
7
28.6
5.0
ü
ALS QCS3 requirement
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Brief Method Summaries The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the US EPA, APHA, AS and NEPM. In house developed procedures are employed in the absence of documented standards or by client request. The following report provides brief descriptions of the analytical procedures employed for results reported in the Certificate of Analysis. Sources from which ALS methods have been developed are provided within the Method Descriptions.
Analytical Methods
Method
Matrix
Method Descriptions
Moisture Content
EA055-103
SOIL
Leachable Metals by ICPAES
EG005C
SOIL
Total Metals by ICP-AES
EG005T
SOIL
EP070
SOIL
EP075(SIM)
SOIL
A gravimetric procedure based on weight loss over a 12 hour drying period at 103-105 degrees C. This method is compliant with NEPM (1999) Schedule B(3) (Method 102) APHA 21st ed., 3120; USEPA SW 846 - 6010 The ICPAES technique ionises leachate sample atoms emitting a characteristic spectrum. This spectrum is then compared against matrix matched standards for quantification. This method is compliant with NEPM (1999) Schedule B(3) (Appdx. 2) (APHA 21st ed., 3120; USEPA SW 846 - 6010) (ICPAES) Metals are determined following an appropriate acid digestion of the soil. The ICPAES technique ionises samples in a plasma, emitting a characteristic spectrum based on metals present. Intensities at selected wavelengths are compared against those of matrix matched standards. This method is compliant with NEPM (1999) Schedule B(3) (USEPA SW 846 - 8015A) Sample extracts are analysed by Capillary GC/FID and quantified against alkane standards over the range C10 - C36. This method is compliant with NEPM (1999) Schedule B(3) (Method 506.1) USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS in SIM Mode and quantification is by comparison against an established 5 point calibration curve. This method is compliant with NEPM (1999) Schedule B(3) (Appdx. 2)
Preparation Methods
Method
Matrix
Method Descriptions
Digestion for Total Recoverable Metals in TCLP Leachate
EN25C
SOIL
ASLP for Non & Semivolatile Analytes Hot Block Digest for metals in soils sediments and sludges
EN60a EN69
SOIL SOIL
Separatory Funnel Extraction of Liquids
ORG14
SOIL
Tumbler Extraction of Solids (Option B Non-concentrating)
ORG17-SP
SOIL
USEPA SW846-3005 Method 3005 is a Nitric/Hydrochloric acid digestion procedure used to prepare surface and ground water samples for analysis by ICPAES or ICPMS. This method is compliant with NEPM (1999) Schedule B(3) (Appdx. 2) AS4439.3 Preparation of Leachates USEPA 200.2 Mod. Hot Block Acid Digestion 1.0g of sample is heated with Nitric and Hydrochloric acids, then cooled. Peroxide is added and samples heated and cooled again before being filtered and bulked to volume for analysis. Digest is appropriate for determination of selected metals in sludge, sediments, and soils. This method is compliant with NEPM (1999) Schedule B(3) (Method 202) USEPA SW 846 - 3510B 500 mL to 1L of sample is transferred to a separatory funnel and serially extracted three times using 60mL DCM for each extract. The resultant extracts are combined, dehydrated and concentrated for analysis. This method is compliant with NEPM (1999) Schedule B(3) (Appdx. 2). ALS default excludes sediment which may be resident in the container. In-house, Mechanical agitation (tumbler). 10g of sample, Na2SO4 and surrogate are extracted with 20mL 1:1 DCM/Acetone by end over end tumble. The solvent is transferred directly to a GC vial for analysis.
TPH - Speciation PAH/Phenols (GC/MS - SIM)
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Summary of Outliers Outliers : Quality Control Samples The following report highlights outliers flagged in the Quality Control (QC) Report. Surrogate recovery limits are static and based on USEPA SW 846 or ALS-QWI/EN/38 (in the absence of specific USEPA limits). This report displays QC Outliers (breaches) only.
Duplicates, Method Blanks, Laboratory Control Samples and Matrix Spikes Matrix: SOIL Compound Group Name
Laboratory Sample ID
Client Sample ID
Analyte
EP070: Total Petroleum Hydrocarbons - Speciation
EM1009164-002
TP9 (2.0-2.1)
Aliphatic C16-C35
EP070: Total Petroleum Hydrocarbons - Speciation
EM1009164-002
TP9 (2.0-2.1)
Aliphatic > C35
EP070: Total Petroleum Hydrocarbons - Speciation
EM1009164-002
TP9 (2.0-2.1)
EP070: Total Petroleum Hydrocarbons - Speciation
EM1009164-002
EP070: Total Petroleum Hydrocarbons - Speciation EP070: Total Petroleum Hydrocarbons - Speciation
CAS Number
Data
Limits
----
37.7 %
0-20%
RPD exceeds LOR based limits
----
25.9 %
0-20%
RPD exceeds LOR based limits
Aromatic C16-C35
----
34.0 %
0-20%
RPD exceeds LOR based limits
TP9 (2.0-2.1)
Aromatic > C35
----
21.1 %
0-20%
RPD exceeds LOR based limits
EM1009164-004
TP5 (2.0-2.1)
Aliphatic C16-C35
----
60.6 %
70-130%
EM1009164-004
TP5 (2.0-2.1)
Aromatic C16-C35
----
Not Determined
----
Laboratory Sample ID
Client Sample ID
Analyte
Data
Limits
EM1009164-002
TP9 (2.0-2.1)
4-Terphenyl-d14
Comment
Duplicate (DUP) RPDs
Matrix Spike (MS) Recoveries
l
For all matrices, no Method Blank value outliers occur.
l
For all matrices, no Laboratory Control outliers occur.
Recovery less than lower data quality objective Matrix spike recovery not determined due to sample matrix interference.
Regular Sample Surrogates Sub-Matrix: ASLP LEACHATE Compound Group Name
CAS Number
Comment
Samples Submitted
EP075(SIM)T: PAH Surrogates
1718-51-0
150 %
42.1-130.1 Recovery greater than upper data quality % objective
Outliers : Analysis Holding Time Compliance This report displays Holding Time breaches only. Only the respective Extraction / Preparation and/or Analysis component is/are displayed. Matrix: SOIL Extraction / Preparation
Method Container / Client Sample ID(s)
Analysis
Date extracted
Due for extraction
Days overdue
Date analysed
Due for analysis
Days overdue
----
----
----
23-AUG-2010
16-AUG-2010
7
EA055: Moisture Content Soil Glass Jar - Unpreserved TP9 (2.0-2.1), TP11 (1.9-2.0), TP11 (0.9-1.0), TP14 (0.9-1.0), TP3 (0.4-0.5), TP5 (1.4-1.5)
TP5 (2.0-2.1), TP12 (0.4-0.5), TP10 (1.4-1.5), TP2 (0.4-0.5), TP5 (0.4-0.5),
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Matrix: SOIL Extraction / Preparation
Method
Analysis
Date extracted
Due for extraction
Days overdue
Date analysed
Due for analysis
Days overdue
TP9 (2.0-2.1),
----
----
----
25-AUG-2010
23-AUG-2010
2
TP9 (2.0-2.1),
----
----
----
25-AUG-2010
23-AUG-2010
2
TP5 (2.0-2.1),
25-AUG-2010
23-AUG-2010
2
----
----
----
Container / Client Sample ID(s)
EN60: ASLP Leaching Procedure LabSplit: Leach for organics and other tests TP6 (0-0.1), TP1 (1.5-1.6) EN60: Bottle Leaching Procedure LabSplit: Leach for organics and other tests TP6 (0-0.1), TP1 (1.5-1.6) EP070: Total Petroleum Hydrocarbons - Speciation Soil Glass Jar - Unpreserved TP9 (2.0-2.1), TP11 (1.9-2.0)
Outliers : Frequency of Quality Control Samples The following report highlights breaches in the Frequency of Quality Control Samples.
l
No Quality Control Sample Frequency Outliers exist.
Data File : Laboratory Number: Sample ID : Date Acquired :
7901012.D EM1009628-002 TP3 (1.4-1.5) 07-Sep-10, 15:40:40
Response_
Signal: 7901012.D\FID1A.CH
950000
900000
850000
800000
750000
700000
650000
600000
550000
500000
450000
400000 7.443
350000
300000
6.468
250000
200000 3.800
150000
100000
Time
C29 - C36 (6.85-7.99)
C15 - C28 (3.93-6.85)
0
C10 - C14 (1.080-3.940)
50000
0.50 1.00 1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00
Data File : Laboratory Number: Sample ID : Date Acquired :
0701002.D EM1009628-001 TP11 (1.9-2.0) 07-Sep-10, 10:24:33
Response_
Signal: 0701002.D\FID1A.CH
950000
900000
850000
800000
750000
700000
650000
600000
550000
500000
450000
400000
350000
300000
7.570
250000 6.911
200000 3.795
150000
100000
Time
0.50
1.00
1.50
2.00
2.50
3.00
3.50
4.00
4.50
5.00
5.50
C29 - C36 (6.89-8.00)
0
C15 - C28 (3.97-6.89)
C10 - C14 (1.18-3.97)
50000
6.00
6.50
7.00
7.50
8.00
8.50
9.00
Data File : Laboratory Number: Sample ID : Date Acquired :
013B0901.D EM1009628-004 TP5 (2.0-2.1) 07-Sep-2010, 10:54:47
Response_
Signal: 013B0901.D\FID2B.ch
950000
900000
850000
800000
750000
700000
650000
600000
4.559
3.587
550000
500000
450000
400000
350000 7.423
300000
250000
200000
150000
100000
Time
C29 - C36 (7.26-8.42)
C15 - C28 (4.30-7.26)
0
C10 - C14 (2.32-4.30)
50000
0.00 0.50 1.00 1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50
Data File : Laboratory Number: Sample ID : Date Acquired :
012B0801.D EM1009628-003 TP9B (2.5-2.6) 07-Sep-2010, 10:38:11
Response_
Signal: 012B0801.D\FID2B.ch
950000
900000
850000
800000
750000
700000
650000
600000
550000
4.560
3.587
500000
450000
400000
350000 7.424
300000
250000
200000
150000
100000
Time
C29 - C36 (7.26-8.42)
C15 - C28 (4.30-7.26)
0
C10 - C14 (2.32-4.30)
50000
0.50 1.00 1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50
EM1009628 False
CERTIFICATE OF ANALYSIS EM1009628
Page
: 1 of 4
: ENVIRONMENTAL EARTH SCIENCES
Laboratory
: Environmental Division Melbourne
: MR JORDAN FRASER
Contact
: Carol Walsh
: P.O.BOX 2253
Address
: 4 Westall Rd Springvale VIC Australia 3171
Work Order
:
Client
Contact Address
FOOTSCRAY VIC, AUSTRALIA 3011 E-mail
: jfraser@eesi.biz
: carol.walsh@alsenviro.com
Telephone
: +61 03 96871666
Telephone
: +61-3-8549 9608
Facsimile
: +61 03 96871844
Facsimile
: +61-3-8549 9601
Project
: 210061 REBATCH EM1008731 and EM1009164
QC Level
: NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Order number
: ----
C-O-C number
: ----
Date Samples Received
: 02-SEP-2010
Sampler
: JF
Issue Date
: 07-SEP-2010
Site
: YARRAVILLE
Quote number
: EN/010/10
No. of samples received
:4
No. of samples analysed
:4
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. All pages of this report have been checked and approved for release. This Certificate of Analysis contains the following information: l General Comments l Analytical Results NATA Accredited Laboratory 825 This document is issued in accordance with NATA accreditation requirements. Accredited for compliance with ISO/IEC 17025.
Signatories This document has been electronically signed by the authorized signatories indicated below. Electronic signing has been carried out in compliance with procedures specified in 21 CFR Part 11. Signatories
Position
Accreditation Category
Emily Yuen Herman Lin
Senior Organic Instrument Chemist Senior Inorganic Chemist
Organics Inorganics
Environmental Division Melbourne 4 Westall Rd Springvale VIC Australia 3171 Tel. +61-3-8549 9600 Fax. +61-3-8549 9601 www.alsglobal.com
Page Work Order Client Project
: : : :
2 of 4 EM1009628 ENVIRONMENTAL EARTH SCIENCES 210061 REBATCH EM1008731 and EM1009164
General Comments The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, developed procedures are employed in the absence of documented standards or by client request. Where moisture determination has been performed, results are reported on a dry weight basis. Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insuffient sample for analysis. Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference. When date(s) and/or time(s) are shown bracketed, these have been assumed by the laboratory for processing purposes. If the sampling time is displayed as 0:00 the information was not provided by client. Key :
l
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society. LOR = Limit of reporting ^ = This result is computed from individual analyte detections at or above the level of reporting
EP071: Samples were received outside of holding times for the analysis of EP071. Results should be scrutinised accordingly.
APHA, AS and NEPM. In house
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Analytical Results Client sample ID
Sub-Matrix: ASLP LEACHATE
Client sampling date / time Compound
CAS Number
LOR
Unit
TP9B (2.5-2.6)
TP5 (2.0-2.1)
----
----
----
06-SEP-2010 12:00
06-SEP-2010 12:00
----
----
----
EM1009628-003
EM1009628-004
----
----
----
EP080/071: Total Petroleum Hydrocarbons C10 - C14 Fraction
----
50
µg/L
<50
<50
----
----
----
C15 - C28 Fraction
----
100
µg/L
<100
110
----
----
----
C29 - C36 Fraction
----
50
µg/L
<50
<50
----
----
----
^ C10 - C36 Fraction (sum)
----
50
µg/L
<50
110
----
----
----
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Analytical Results Client sample ID
Sub-Matrix: SOIL
Client sampling date / time
TP11 (1.9-2.0)
TP3 (1.4-1.5)
TP9B (2.5-2.6)
TP5 (2.0-2.1)
----
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
09-AUG-2010 15:00
----
EM1009628-002
EM1009628-003
EM1009628-004
----
LOR
Unit
EM1009628-001
----
1.0
%
24.4
21.5
----
----
----
----
0.1
pH Unit
----
----
5.0
5.0
----
Initial pH
----
0.1
pH Unit
----
----
8.2
8.6
----
After HCl pH
----
0.1
pH Unit
----
----
1.6
2.1
----
Final pH
----
0.1
pH Unit
----
----
5.3
6.8
----
Compound
CAS Number
EA055: Moisture Content ^ Moisture Content (dried @ 103째C)
EN60: ASLP Leaching Procedure Extraction Fluid pH
EN60: Bottle Leaching Procedure
EP071 SG-S: Total Petroleum Hydrocarbons in Soil - Silica gel cleanup C10 - C14 Fraction
----
50
mg/kg
<50
<50
----
----
----
C15 - C28 Fraction
----
100
mg/kg
790
1090
----
----
----
C29 - C36 Fraction
----
100
mg/kg
1120
2070
----
----
----
^ C10 - C36 Fraction (sum)
----
50
mg/kg
1910
3160
----
----
----
False
QUALITY CONTROL REPORT EM1009628
Page
: 1 of 5
: ENVIRONMENTAL EARTH SCIENCES
Laboratory
: Environmental Division Melbourne
: MR JORDAN FRASER
Contact
: Carol Walsh
: P.O.BOX 2253
Address
: 4 Westall Rd Springvale VIC Australia 3171
Work Order
:
Client
Contact Address
FOOTSCRAY VIC, AUSTRALIA 3011 E-mail
: jfraser@eesi.biz
: carol.walsh@alsenviro.com
Telephone
: +61 03 96871666
Telephone
: +61-3-8549 9608
Facsimile
: +61 03 96871844
Facsimile
: +61-3-8549 9601
Project
: 210061 REBATCH EM1008731 and EM1009164
QC Level
: NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Site
: YARRAVILLE
C-O-C number
: ----
Date Samples Received
: 02-SEP-2010
Sampler
: JF
Issue Date
: 07-SEP-2010
Order number
: ----
Quote number
: EN/010/10
No. of samples received
:4
No. of samples analysed
:4
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. All pages of this report have been checked and approved for release. This Quality Control Report contains the following information: l Laboratory Duplicate (DUP) Report ; Relative Percentage Difference (RPD) and Acceptance Limits l Method Blank (MB) and Laboratory Control Spike (LCS) Report ; Recovery and Acceptance Limits l Matrix Spike (MS) Report ; Recovery and Acceptance Limits NATA Accredited Laboratory 825 This document is issued in accordance with NATA accreditation requirements. Accredited for compliance with ISO/IEC 17025.
Signatories This document has been electronically signed by the authorized signatories indicated below. Electronic signing has been carried out in compliance with procedures specified in 21 CFR Part 11. Signatories
Position
Accreditation Category
Emily Yuen Herman Lin
Senior Organic Instrument Chemist Senior Inorganic Chemist
Organics Inorganics
Environmental Division Melbourne 4 Westall Rd Springvale VIC Australia 3171 Tel. +61-3-8549 9600 Fax. +61-3-8549 9601 www.alsglobal.com
Page Work Order Client Project
: : : :
2 of 5 EM1009628 ENVIRONMENTAL EARTH SCIENCES 210061 REBATCH EM1008731 and EM1009164
General Comments The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, developed procedures are employed in the absence of documented standards or by client request. Where moisture determination has been performed, results are reported on a dry weight basis. Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insuffient sample for analysis. Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference. Key :
Anonymous = Refers to samples which are not specifically part of this work order but formed part of the QC process lot CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society. LOR = Limit of reporting RPD = Relative Percentage Difference # = Indicates failed QC
APHA, AS and NEPM. In house
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: : : :
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Laboratory Duplicate (DUP) Report The quality control term Laboratory Duplicate refers to a randomly selected intralaboratory split. Laboratory duplicates provide information regarding method precision and sample heterogeneity. The permitted ranges for the Relative Percent Deviation (RPD) of Laboratory Duplicates are specified in ALS Method QWI -EN/38 and are dependent on the magnitude of results in comparison to the level of reporting: Result < 10 times LOR:No Limit; Result between 10 and 20 times LOR:- 0% - 50%; Result > 20 times LOR:- 0% - 20%. Laboratory Duplicate (DUP) Report
Sub-Matrix: SOIL Laboratory sample ID
Client sample ID
Method: Compound
CAS Number
LOR
Unit
Original Result
Duplicate Result
RPD (%)
Recovery Limits (%)
EA055: Moisture Content (QC Lot: 1474556) EM1009496-054
Anonymous
EA055-103: Moisture Content (dried @ 103째C)
----
1.0
%
16.6
16.0
3.9
0% - 50%
EM1009496-064
Anonymous
EA055-103: Moisture Content (dried @ 103째C)
----
1.0
%
8.8
9.1
3.6
No Limit
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: : : :
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Method Blank (MB) and Laboratory Control Spike (LCS) Report The quality control term Method / Laboratory Blank refers to an analyte free matrix to which all reagents are added in the same volumes or proportions as used in standard sample preparation. The purpose of this QC parameter is to monitor potential laboratory contamination. The quality control term Laboratory Control Sample (LCS) refers to a certified reference material, or a known interference free matrix spiked with target analytes. The purpose of this QC parameter is to monitor method precision and accuracy independent of sample matrix. Dynamic Recovery Limits are based on statistical evaluation of processed LCS. Method Blank (MB) Report
Sub-Matrix: WATER Method: Compound
CAS Number
LOR
Unit
Result
Laboratory Control Spike (LCS) Report Spike
Spike Recovery (%)
Concentration
LCS
Low
Recovery Limits (%) High
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1476122) EP071: C10 - C14 Fraction
----
50
µg/L
<50
4448 µg/L
99.8
64
124
EP071: C15 - C28 Fraction
----
100
µg/L
<100
14955 µg/L
117
70
130
EP071: C29 - C36 Fraction
----
50
µg/L
<50
3118 µg/L
119
68
128
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5 of 5 EM1009628 ENVIRONMENTAL EARTH SCIENCES 210061 REBATCH EM1008731 and EM1009164
Matrix Spike (MS) Report The quality control term Matrix Spike (MS) refers to an intralaboratory split sample spiked with a representative set of target analytes. The purpose of this QC parameter is to monitor potential matrix effects on analyte recoveries. Static Recovery Limits as per laboratory Data Quality Objectives (DQOs). Ideal recovery ranges stated may be waived in the event of sample matrix interference.
l No Matrix Spike (MS) Results are required to be reported.
True
INTERPRETIVE QUALITY CONTROL REPORT Work Order
: EM1009628
Page
: 1 of 5
Client
: ENVIRONMENTAL EARTH SCIENCES : MR JORDAN FRASER : P.O.BOX 2253
Laboratory Address
: Environmental Division Melbourne : Carol Walsh : 4 Westall Rd Springvale VIC Australia 3171
Contact Address
Contact
FOOTSCRAY VIC, AUSTRALIA 3011 E-mail Telephone Facsimile
: jfraser@eesi.biz : +61 03 96871666 : +61 03 96871844
E-mail Telephone Facsimile
: carol.walsh@alsenviro.com : +61-3-8549 9608 : +61-3-8549 9601
Project Site C-O-C number Sampler Order number
: 210061 REBATCH EM1008731 and EM1009164 : YARRAVILLE : ---: JF : ----
QC Level
: NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Date Samples Received Issue Date
: 02-SEP-2010 : 07-SEP-2010
Quote number
: EN/010/10
No. of samples received No. of samples analysed
:4 :4
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. All pages of this report have been checked and approved for release. This Interpretive Quality Control Report contains the following information: l Analysis Holding Time Compliance
l Quality Control Parameter Frequency Compliance l Brief Method Summaries l Summary of Outliers
Environmental Division Melbourne 4 Westall Rd Springvale VIC Australia 3171 Tel. +61-3-8549 9600 Fax. +61-3-8549 9601 www.alsglobal.com
Page Work Order Client Project
: : : :
2 of 5 EM1009628 ENVIRONMENTAL EARTH SCIENCES 210061 REBATCH EM1008731 and EM1009164
Analysis Holding Time Compliance The following report summarises extraction / preparation and analysis times and compares with recommended holding times. Dates reported represent first date of extraction or analysis and precludes subsequent dilutions and reruns. Information is also provided re the sample container (preservative) from which the analysis aliquot was taken. Elapsed period to analysis represents number of days from sampling where no extraction / digestion is involved or period from extraction / digestion where this is present. For composite samples, sampling date is assumed to be that of the oldest sample contributing to the composite. Sample date for laboratory produced leachates is assumed as the completion date of the leaching process. Outliers for holding time are based on USEPA SW 846, APHA, AS and NEPM (1999). A listing of breaches is provided in the Summary of Outliers. Holding times for leachate methods (excluding elutriates) vary according to the analytes being determined on the resulting solution. For non -volatile analytes, the holding time compliance assessment compares the leach date with the shortest analyte holding time for the equivalent soil method. These soil holding times are: Organics (14 days); Mercury (28 days) & other metals (180 days). A recorded breach therefore does not guarantee a breach for all non-volatile parameters. Evaluation: û = Holding time breach ; ü = Within holding time.
Matrix: SOIL Method
Extraction / Preparation
Sample Date
Container / Client Sample ID(s)
Analysis
Date extracted
Due for extraction
Evaluation
Date analysed
Due for analysis
Evaluation
EA055: Moisture Content Soil Glass Jar - Unpreserved TP11 (1.9-2.0),
TP3 (1.4-1.5)
09-AUG-2010
----
----
----
03-SEP-2010
16-AUG-2010
û
TP5 (2.0-2.1)
09-AUG-2010
---
23-AUG-2010
----
06-SEP-2010
23-AUG-2010
û
TP5 (2.0-2.1)
09-AUG-2010
---
23-AUG-2010
----
06-SEP-2010
23-AUG-2010
û
Soil Glass Jar - Unpreserved TP11 (1.9-2.0)
09-AUG-2010
03-SEP-2010
23-AUG-2010
û
07-SEP-2010
13-OCT-2010
Soil Glass Jar - Unpreserved TP3 (1.4-1.5)
ü
09-AUG-2010
16-AUG-2010
23-AUG-2010
ü
07-SEP-2010
25-SEP-2010
ü
06-SEP-2010
06-SEP-2010
13-SEP-2010
ü
07-SEP-2010
16-OCT-2010
ü
EN60: ASLP Leaching Procedure LabSplit: Leach for organics and other tests TP9B (2.5-2.6), EN60: Bottle Leaching Procedure LabSplit: Leach for organics and other tests TP9B (2.5-2.6),
EP071 SG-S: Total Petroleum Hydrocarbons in Soil - Silica gel cleanup
EP080/071: Total Petroleum Hydrocarbons Amber Glass Bottle - Unpreserved TP9B (2.5-2.6),
TP5 (2.0-2.1)
Page Work Order Client Project
: : : :
3 of 5 EM1009628 ENVIRONMENTAL EARTH SCIENCES 210061 REBATCH EM1008731 and EM1009164
Quality Control Parameter Frequency Compliance The following report summarises the frequency of laboratory QC samples analysed within the analytical lot(s) in which the submitted sample(s) was(where) processed. Actual rate should be greater than or equal to the expected rate. A listing of breaches is provided in the Summary of Outliers. Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Matrix: SOIL Quality Control Sample Type
Analytical Methods Laboratory Duplicates (DUP) Moisture Content
Count Method EA055-103
QC
Regular
2
20
Rate (%) Expected
10.0
10.0
Quality Control Specification Evaluation
ü
NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Matrix: WATER Quality Control Sample Type
Analytical Methods
Actual
Count Method
QC
Regular
Actual
Rate (%) Expected
Quality Control Specification Evaluation
Laboratory Control Samples (LCS) TPH - Semivolatile Fraction
EP071
1
11
9.1
5.0
ü
NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Method Blanks (MB) TPH - Semivolatile Fraction
EP071
1
11
9.1
5.0
ü
NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Page Work Order Client Project
: : : :
4 of 5 EM1009628 ENVIRONMENTAL EARTH SCIENCES 210061 REBATCH EM1008731 and EM1009164
Brief Method Summaries The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the US EPA, APHA, AS and NEPM. In house developed procedures are employed in the absence of documented standards or by client request. The following report provides brief descriptions of the analytical procedures employed for results reported in the Certificate of Analysis. Sources from which ALS methods have been developed are provided within the Method Descriptions.
Analytical Methods
Method
Matrix
Method Descriptions
Moisture Content
EA055-103
SOIL
EP071
SOIL
EP071SG-S
SOIL
A gravimetric procedure based on weight loss over a 12 hour drying period at 103-105 degrees C. This method is compliant with NEPM (1999) Schedule B(3) (Method 102) USEPA SW 846 - 8015A The sample extract is analysed by Capillary GC/FID and quantification is by comparison against an established 5 point calibration curve of n-Alkane standards. This method is compliant with NEPM (1999) Schedule B(3) (Appdx. 2) (USEPA SW 846 - 8015A) Sample extracts are analysed by Capillary GC/FID and quantified against alkane standards over the range C10 - C36. This method is compliant with NEPM (1999) Schedule B(3) (Method 506.1)
Preparation Methods
Method
Matrix
Method Descriptions
ASLP for Non & Semivolatile Analytes Separatory Funnel Extraction of Liquids
EN60a ORG14
SOIL SOIL
Tumbler Extraction of Solids/ Silica Gel Clean Up
ORG17A-SG
SOIL
AS4439.3 Preparation of Leachates USEPA SW 846 - 3510B 500 mL to 1L of sample is transferred to a separatory funnel and serially extracted three times using 60mL DCM for each extract. The resultant extracts are combined, dehydrated and concentrated for analysis. This method is compliant with NEPM (1999) Schedule B(3) (Appdx. 2). ALS default excludes sediment which may be resident in the container. In-house, Mechanical agitation (tumbler). 20g of sample, Na2SO4 and surrogate are extracted with 150mL 1:1 DCM/Acetone by end over end tumble. The solvent is decanted, dehydrated and concentrated (by KD) to the desired volume for analysis.
TPH - Semivolatile Fraction
TPH - Semivolatile Fraction (Silica Gel Clean Up)
Page Work Order Client Project
: : : :
5 of 5 EM1009628 ENVIRONMENTAL EARTH SCIENCES 210061 REBATCH EM1008731 and EM1009164
Summary of Outliers Outliers : Quality Control Samples The following report highlights outliers flagged in the Quality Control (QC) Report. Surrogate recovery limits are static and based on USEPA SW 846 or ALS-QWI/EN/38 (in the absence of specific USEPA limits). This report displays QC Outliers (breaches) only.
Duplicates, Method Blanks, Laboratory Control Samples and Matrix Spikes l
For all matrices, no Method Blank value outliers occur.
l
For all matrices, no Duplicate outliers occur.
l
For all matrices, no Laboratory Control outliers occur.
l
For all matrices, no Matrix Spike outliers occur.
Regular Sample Surrogates l
For all regular sample matrices, no surrogate recovery outliers occur.
Outliers : Analysis Holding Time Compliance This report displays Holding Time breaches only. Only the respective Extraction / Preparation and/or Analysis component is/are displayed. Matrix: SOIL Extraction / Preparation
Method
Analysis
Date extracted
Due for extraction
Days overdue
Date analysed
Due for analysis
Days overdue
TP3 (1.4-1.5)
----
----
----
03-SEP-2010
16-AUG-2010
18
TP5 (2.0-2.1)
----
----
----
06-SEP-2010
23-AUG-2010
14
TP5 (2.0-2.1)
----
----
----
06-SEP-2010
23-AUG-2010
14
03-SEP-2010
23-AUG-2010
11
----
----
----
Container / Client Sample ID(s)
EA055: Moisture Content Soil Glass Jar - Unpreserved TP11 (1.9-2.0), EN60: ASLP Leaching Procedure LabSplit: Leach for organics and other tests TP9B (2.5-2.6), EN60: Bottle Leaching Procedure LabSplit: Leach for organics and other tests TP9B (2.5-2.6),
EP071 SG-S: Total Petroleum Hydrocarbons in Soil - Silica gel cleanup Soil Glass Jar - Unpreserved TP11 (1.9-2.0)
Outliers : Frequency of Quality Control Samples The following report highlights breaches in the Frequency of Quality Control Samples.
l
No Quality Control Sample Frequency Outliers exist.
APPENDIX E
210061_ReportV2.doc
QUALITY ASSURANCE AND QUALITY CONTROL PROCEDURES
TABLE OF CONTENTS 1
INTRODUCTION AND BACKGROUND ........................................................................ 2 1.1
INTRODUCTION
2
1.2
BACKGROUND
3
2
DATA QUALITY OBJECTIVES...................................................................................... 3
3
QUALITY CONTROL AND QUALITY ASSURANCE .................................................... 6 3.1
6
3.1.1 Repeatability (Field collected intra-laboratory duplicates)
7
3.1.2 Precision
7
3.1.3 Accuracy
8
3.1.4 Representativeness
8
3.1.5 Completeness
9
3.1.6 Comparability
9
3.1.7 Sensitivity
9
3.1.8 Blanks
9
3.1.9 Holding times
10
3.1.10 Procedures for anomalous samples and confirmation checking
10
FIELD QA/QC
10
3.2.1 Details of sampling team
10
3.2.2
Sampling controls
10
3.2.3 Field instrument calibration
15
3.3
LABORATORY QA/QC
15
3.4
QA/QC DATA EVALUATION
15
3.2
4
MEASUREMENT DATA QUALITY OBJECTIVES
REFERENCES ............................................................................................................. 15
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1 1.1
INTRODUCTION AND BACKGROUND Introduction
The aim of a quality control and quality assurance (QA/QC) is to deliver data that is: representative of what is sampled; precise; accurate; and reproducible. As investigations involve both field and laboratory QA/QC, these are similarly divided. The objective of this document is to evaluate and identify the data quality objectives (DQOs) and the data quality indicators (DQIs), which are used to assess whether the DQOs have been met. All soil sampling procedures followed are described in full in the Soil, gas and groundwater sampling manual (Environmental Earth Sciences Pty Ltd 2005). This document should be referred to for field procedures for sampling and conveyance. Copies are available for inspection if required. The Victorian guideline documents used in the evaluation of the data set for this investigation are: Australian and New Zealand Environment and Conservation Council 1992, Australian and New Zealand Guidelines for the assessment and management of contaminated sites, Australia and New Zealand Environment Council, National Health and Medical Research Council, Melbourne, Vic; EPA Victoria 2000, Publication 441, A guide to the sampling and analysis of waters, wastewaters, soils and wastes, EPA VIC, Southbank, Vic; National Environment Protection Council (NEPC) 1999, National environment protection (assessment of site contamination) measure, National Environment Protection Council, Adelaide, SA; Standards Australia 2005, Guide to the sampling and investigation of potentially contaminated soil, Part 1: Non-volatile and semi-volatile compounds, (AS 4482.1), Standards Australia, Homebush, NSW; and Standards Australia 1999, â&#x20AC;&#x201C; Guide to the sampling and investigation of potentially contaminated soil, Part 2: Volatile substances, (AS 4482.2), Standards Australia, Homebush, NSW. Data quality is typically discussed in terms of precision, accuracy, representativeness, comparability and completeness. These are referred to as the PARCC parameters. The PARCC (and additional QA) parameters are discussed within this report. The following items form part of the QA/QC appendix: repeatability; precision; 210061 QAQC
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accuracy; representativeness; completeness; comparability; sensitivity; holding times; blanks; and procedures for anomalous samples and confirmation checking.
1.2
Background
The terms “quality assurance” and “quality control” are often confused. In any program, quality control is required before assurance can be put in place. With respect to laboratory analysis activities, these terms are defined as follows: Quality Assurance (QA): “All the planned and systematic activities implemented within the quality system and demonstrated as needed to provide adequate confidence that an entity will fulfil requirements for quality”. (ISO 8402-1995) This encompasses all actions, procedures, checks and decisions undertaken to ensure the accuracy and reliability of analysis results. It includes routine procedures which ensure proper sample control, data transfer, instrument calibration, the decisions required to select and properly train staff, select equipment and analytical methods, and the day-to day judgements resulting from regular scrutiny and maintenance of the laboratory system. Quality Control (QC): “The operational techniques and activities that are used to fulfil the requirements for quality”. (ISO 8402-1995) These are the components of QA which serve to monitor and measure the effectiveness of other QA procedures by comparison with previously decided objectives. They include measurement of the quality of reagents, cleanliness of apparatus, accuracy and precision of methods and instrumentation, and reliability of all of these factors as implemented in a given laboratory from day to day. A complete discussion of either of these terms or the steps for implementing them is beyond the scope of this document. It is widely recognised, however, that adoption of sound laboratory QA and QC procedures is essential and readers are referred to documentation available from the National Association of Testing Authorities (NATA), if further information is required.
2
DATA QUALITY OBJECTIVES
Development of data quality objectives (DQOs) for each project is a requirement of the NEPC 1999. This is based on a DQO process formulated by the USEPA for contaminated land assessment and remediation. This has not been formally adopted by the EPA Victoria, or the contaminated land industry, however, it provides sound guidance for a consistent 210061 QAQC
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approach in understanding site assessment and remediation. Many environmental practitioners are now following this process. The DQO process is defined by seven steps. Each of these steps has been given due consideration in the undertaking of this project. In brief, these steps are: Step 1: State the problem and establish the DQO team. Step 2: Determine the possible and probable actions that will resolve the problems. Step 3: Identify the informational inputs to assist in the problem resolution. Step 4: Define the boundaries of the study (geographical, temporal, etc). Step 5: Develop and define decision rules. Step 6: Specify tolerable limits to reduce probability of incorrect decisions. Step 7: Ensure the quality of the information obtained. Step 1 State the Problem The problem will be addressed directly by scientists from Environmental Earth Sciences VIC. The problem is that the site has been used for historical disposal of municipal and construction waste. Potential exists for soil and groundwater contamination to have occurred during this time through uncontrolled filling. The purpose of the investigation is to determine the chemical status of soil at the site and prepare a preliminary feasibility study. Step 2 Identify the Decision These works have been commissioned to determine if the property has been impacted by past or present potentially polluting activities, or importation of fill materials containing CoPC. A decision is required on what management action is necessary (if any) to ensure the site becomes suitable for its intended use. If the site is deemed not to be suitable for its intended use, direction will be given to determine what is considered by Environmental Earth Sciences VIC to be the most suitable path for making the site suitable. Step 3 Identify the Inputs to the Decision The study inputs included a historical investigation of the site (Section 3), a review of previous investigations (Section 5) and a soil investigation (Section 6). Step 4 Define the Study Boundaries The physical boundary of the study area is defined in Section 3. The temporal boundary of the project is restricted to the timing of the investigation. This restriction is not expected to limit the outcome of the investigation as the aim is to determine the site conditions at the time of the investigation. Step 5 Develop and Define Decision Rules Under the DQO process, it is important to nominate action levels for decision making. Initially, all analytical data will be compiled and evaluated against the appropriate criteria. Dependent upon the sampling and analysis design, statistical parameters such as arithmetic mean, standard deviation and 95% upper confidence limits (95% UCLs) may be applied to designated soil populations for particular analytes. The NEPM will be used as the primary guidance document in decision making on action levels. In the event that action levels are exceeded, a management plan, remedial action plan, and/or qualitative risk assessment (with modeling of potential groundwater impacts on the 210061 QAQC
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local receiving environment) will be required. These procedures constitute the alternative action plan. Step 6 Specify Tolerable Limits on Decision Errors Most of the procedures in the AS 4482.1 - Guide to the sampling and investigation of potentially contaminated soil (Standards Australia 1997) and NEPM (NEPC 1999) have risk probabilities associated with wrong decisions incorporated into them. It is therefore proposed that no further “tolerable limits” be investigated at this stage of the project. Acceptable limits for field data analysis (relative percent differences for primary and duplicate results) are between 50 and 150 percent (depending on the origin of the sample and volatility of the chemicals present). Acceptable limits for laboratory duplicate analysis may be affected by the heterogeneity of soil and will be set based on site specific information such as background concentrations. These are summarised in Table 1 as the measurement data quality indicators (MDQIs), which will be used to establish whether the DQOs have been met. The MDQIs are discussed further in the Quality control and quality assurance section of this report. It should be noted that Standards Australia procedures specify MDQIs for precision should be 50% RPD, however also acknowledge that low concentrations and organic compounds in particular can be acceptably outside this range. AS 4482.1 suggests that 50% RPD be used as a ‘trigger’ and values above this level of repeatability need to be noted and explained. Step 7 Optimise the Design The sample design will be undertaken with reference to the AS 4482.1 - Guide to the sampling and investigation of potentially contaminated soil (Standards Australia 1997). As well as a statistically justifiable systematic sampling design, this sampling pattern has also taken into account targeted areas of concern on the site (i.e. judgemental sampling locations). Environmental Earth Sciences VIC believes that the sampling design is optimal considering temporal limitations and access constraints. The density of the sampling pattern and the quality of the data set are suitable for determination of the suitability of the site for its proposed current and future use.
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TABLE 1
DATA PROFIT MDQIS Criteria
Parameter
Procedure
Minimum Frequency
(5 to 10x LOR4)
>10x LOR
<80-100 RPD
<50-80 RPD
1 in 20 - volatiles
<150 RPD
<130 RPD
1 in 20
<50 RPD
<30 RPD
1 in 10
60% to 140%R
80% to 120%R
1 in 20 - metals and Field Duplicates Precision Lab Replicate*
semi-volatiles
Reference Material Accuracy*
Matrix spikes Surrogate spikes Reagent Blanks
1 per batch
No detection
Holding Times*
Every sample
-
1 per batch
No detection
Every sample
LOR < ½ site criteria
Representativeness*
Trip Blank Blanks** Rinsate Blanks Sensitivity Notes: 1. 2. 3. 4. 5. 6.
3
3.1
Limit of Reporting
RPD – relative percentage difference PR – percent recovery (%R) LOR – limit of reporting 4 no limit at <5x LOR * the MDQI is usually specified in the standard method. If not, use the default values set out in this table ** only necessary when measuring dissolved metals and volatile organic compounds in water samples
QUALITY CONTROL AND QUALITY ASSURANCE Measurement data quality objectives
Step 7 of the DQO process (Section 2.0) is a focus on the quality of the information by measurement, that is, measurement data quality objectives (MDQOs). The aim of a quality control and quality assurance (QA/QC) is to deliver data that is representative of what is sampled, precise, accurate and reproducible. As investigations involve both field and laboratory QA/QC, these are similarly divided. The objective of this section is to provide the MDQOs and the measurement data quality indicators (MDQIs), which will be used to establish whether the DQOs have been met.
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All soil sampling procedures need to be undertaken according to a standard procedure, for example those procedures set out in: EPA Victoria 2000 A guide to the sampling and analysis of waters, waste-waters, soils and wastes. Publication 441. EPA Information Bulletin National Environment Protection Council (NEPC) 1999 National environment protection (assessment of site contamination) measure Standards Australia 1997 Guide to the sampling and investigation of potentially contaminated soil (Part 1: Non-volatile and semi-volatile compounds. AS 4482.1) Standards Australia 1999 Guide to the sampling and investigation of potentially contaminated soil (Part 2: Volatile substances). AS 4482.1 Measurement data quality is typically discussed in terms of precision, accuracy, representativeness, comparability and completeness. Although not necessarily considered in list order, the following items should form part of the QA/QC data evaluation: Measured Parameters: precision, accuracy, repeatability (comparability), blanks; and Assessed Parameters: completeness, representative of site conditions, sensitivity, and holding times. The laboratories used should be NATA accredited for the analytical methods performed. Containers, sample preservation (if necessary) and holding times should be consistent with industry practices as set out in NEPM and as defined by ASTM. The QA parameters selected and the criteria used to evaluate the analytical data are defined below and presented in Table 1 of this report.
3.1.1
Repeatability (Field collected intra-laboratory duplicates)
These samples provide a check on the analytical performance of the laboratory. At least 5 percent of soil samples (1 in 20) from a site are collected in duplicate. For comparability of data, it is important that there is little delay in the sample submission. For split samples, because of error associated with field splitting, an RPD of between 80 and 150% (depending on the substance) will be allowed as the MDQI. Soil heterogeneity due to the â&#x20AC;&#x153;nugget effectâ&#x20AC;? could result in significantly greater difference, particularly for metals. Consequently, samples with the most observable field homogeneity are selected. Any value >50% RPD will be noted and discussed, as per Standards Australia requirements, with respect to its acceptability for inclusion in the data-set.
3.1.2
Precision
Precision is a measure of the reproducibility of results, and is assessed on the basis of agreement between a set of replicate results obtained from duplicate analyses. The precision of a duplicate determination can be measured as relative percentage difference (RPD), and is calculated from the following equation: Where: RPD =
X1 - X2 X1 X2 2
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X1 is the first duplicate value X2 is the second duplicate value
J7
The field blind and field split duplicate results and calculated RPDs are presented in Tables 2 and 3. All results are considered to be within the acceptable range.
3.1.3
Accuracy
Accuracy is a measure of the agreement between an experimental determination and the true value of the parameter being measured. The determination of accuracy can be achieved through the analysis of known reference materials or assessed by the analysis of matrix spikes. Accuracy is measured in terms of percentage recovery as defined by the following equation:
%R
SSR SR 100 SA
where:
%R = percentage recovery of the spike SSR = spiked sample result SR = sample result (native) SA = spike added
Laboratory personnel calculate percentage recoveries of spiked compounds, which are evaluated against control or acceptance limits taken from the appropriate method or the Contract Laboratory Program Statement of Work. If the spike recovery for a sample does not fall within the prescribed control limits, laboratory based corrective action is required. Surrogate spikes consist of spiking non-target compounds into the sample prior to analysis. The spiked compounds are expected to behave during analysis in the same way as the target compounds. Every sample is spiked prior to extraction or analysis with surrogate compounds that are representative of the analysis. If surrogate spike recovery does not meet the prescribed control limits, samples should be reanalysed. For inorganic analyses, certified reference materials are analysed (for SAL this is BCSS-1).
3.1.4
Representativeness
Data Point Evaluation Representativeness expresses the degree to which sample data accurately and precisely represents a characteristic of a population, parameter variations at a sampling point, or an environmental condition. Representativeness is primarily dependent on the design and implementation of the sampling program. Representativeness of the data is partially ensured by the avoidance of contamination, adherence to sample handling and analysis protocols, and use of proper chain-of-custody and documentation procedures. Blanks, holding times and field duplicates are all QA parameters that can assist in the analysis of representativeness for data point evaluation and will need to be analysed as part of the measurement data quality assessment. Data Set Evaluation Whether the data is representative of the site is checked in part by undertaking an evaluation of the whole data set to establish the data is compatible. Data compatibility is authenticated by confirming that the laws of chemistry are upheld (i.e. nitrate is not present when Eh is 250 mV), that intra-laboratory analysis relationships are consistent (i.e. BTEX is a subset of the TPH C6-C9 fraction), that observations and field measurements are in agreement with
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other field data and the laboratory data and that results are consistent with the geology, history and logic.
3.1.5
Completeness
The following information is required to check for completeness of data sets: chain-of-custody forms (completed by Environmental Earth Sciences and the laboratory); sample receipt forms; all requested sample results reported; all blank data reported; all laboratory duplicates reported and relative percent differences (RPDs) calculated; all surrogate spike data reported; all matrix spike data reported; and NATA stamp on reports.
3.1.6
Comparability
Comparability is the evaluation of the similarity of conditions (e.g. sample depth, sample homogeneity, sampling procedures) under which separate sets of data are produced to ensure minimal common error. Data comparability should be demonstrated by the use of standardised sampling and analysis procedures. Data comparability was maintained by undertaking the investigations as follows: the soil samples collected during the investigation were conducted by trained Environmental Earth Sciences field team using Environmental Earth Sciencesâ&#x20AC;&#x2122; standard operating procedures; and the same laboratories (ALS and LabMark) were used for organic and inorganic analysis for all relevant samples using the same NATA approved analytical methods.
3.1.7
Sensitivity
When interferences are present in the sample, a loss of sensitivity can occur resulting in an increase in the method detection limit. In some instances (e.g. where one or more compounds have particularly high concentrations) the sample must be diluted for analysis. This increases the method detection limit by the dilution factor. The detection limits achieved by the laboratory, when adjusted for dry weight and interferences from the presence of other chemicals within the sampled matrix, must be less than half the site criteria for all analytes tested (i.e. 2 x LOR <site criteria).
3.1.8
Blanks
To meet the QC acceptance criteria, laboratory blanks should have no detectable concentrations of the target compounds. Trip blanks (taken to and returned from the field) and rinsate blanks (taken in the field) will only be necessary for analysing dissolved metals and volatile organic compounds in water samples where the threshold value is near the detection limit for an individual compound or element.
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3.1.9
Holding times
Where standard holding times are exceeded, a discussion, using professional judgement, as to the integrity of the data will be required, taking into account such factors as field storage, laboratory storage and even sample bottle characteristics.
3.1.10
Procedures for anomalous samples and confirmation checking
All results should be checked for discrepancies by the project manager, against the anticipated results and all other results, within 8 hours of receipt of the results from the laboratory. Any result that is considered by the supervising scientist to be unusually high or at variance with other results is automatically reanalysed. A significantly different result requires immediate remedial action on the whole sample batch (retesting or using an alternative analytical method) at the laboratoryâ&#x20AC;&#x2122;s expense. After appropriate checking by laboratories, all sample analysis results work-sheets, including those of duplicates and replicate analyses, should be checked by the consultant. Soil is defined as that passing through a 2 mm sieve when air dry. The gravel fraction (that retained) is assumed to be inert. Analysis is undertaken on the less than 2 mm fraction where possible. This procedure is not possible for organics, and original laboratory sheets are reported on â&#x20AC;&#x2DC;an as receivedâ&#x20AC;&#x2122; basis unless a correction has been applied. All results of chemical analysis are analysed on an air dry weight basis and reported on an oven (105 C) dry weight basis, unless specified otherwise. All samples should be adjusted for moisture content when not reported on an oven dry basis. Once confirmation checking is completed the final laboratory report is issued. For blind duplicates, if one sample has more than two analytes exceeding the data quality objectives, the sample is carefully checked. If the error is not apparent, the sample is rejected. If more than three samples are rejected all the samples collected at that time are rejected. These samples are then re-sampled and reanalysed.
3.2 3.2.1
Field QA/QC Details of sampling team
Fieldwork was conducted over a 2-day period using the following staff: Site inspection: Jordan Fraser; and Soil sampling: Jordan Fraser.
3.2.2
Sampling controls
Decontamination procedures carried out between sampling events All sampling equipment to be re-used and which came into contact with soil samples, were thoroughly washed with detergent (Decon 90 or similar) water, then rinsed with clean water and dried before the collection of each sample. Any items accidentally contaminated were similarly washed before re-use. In addition, soil samples were collected from soil profiles removed from a excavator bucket. New nitrile gloves were used at each sampling location. To prevent cross contamination the exterior of each soil sample was cut away (effectively 210061 QAQC
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skinning the soil sample) using a clean spatula. During this process the field scientist would also determine the colour and texture of the soil sample. Sample notation details The borehole logs for each sample collected (including time, location, initials of sampler, duplicate locations, duplicate type and field screening details) are presented in Appendix C. The chemical analyses to be performed on each sample are presented on the chain of custody documentation (Attachment D) which also identify for each sample â&#x20AC;&#x201C; the sampler, nature of the sample, collection date, analyses to be performed, sample preservation method (if any), departure time from the site and dispatch courier. Duplicate sampling Duplicate samples were collected at a rate of one duplicate per twenty two samples collected (4.5%). Duplicate samples were analysed at a rate of approximately one duplicate per twenty samples analysed (5.1%). The field duplicate analysis results are presented in Tables 2 and 3. For this project three field duplicate and three split duplicate samples were analysed for a range of CoPC.
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TABLE 2
BLIND DUPLICATE RESULTS TP4
RPD
TP10
RPD
TP12
(%)
(1.9-2.0)
(%)
(2.4-2.5)
60
120.0
33
<5
---
74
54
31.3
13
<1
---
2
<1
---
1
<1
---
2
21
58
93.7
136
<2
---
97
32
100.8
Copper
5
334
59
139.9
641
8
195.1
98
47
70.3
Lead
5
337
73
128.8
231
<5
---
142
122
15.2
Nickel
2
54
47
13.9
70
<2
---
49
39
22.7
Zinc
5
745
286
89.0
720
6
196.7
472
378
22.1
Mercury
0.1
0.2
0.2
0.0
0.4
0.5
22.2
0.3
0.4
28.6
Naphthalene
0.5
<0.5
<0.5
---
<0.5
<0.5
---
<0.5
<0.5
---
Acenaphthylene
0.5
<0.5
<0.5
---
<0.5
<0.5
---
<0.5
<0.5
---
Acenaphthene
0.5
<0.5
<0.5
---
<0.5
<0.5
---
<0.5
<0.5
---
Fluorene
0.5
<0.5
<0.5
---
<0.5
<0.5
---
<0.5
<0.5
---
Phenanthrene
0.5
<0.5
<0.5
---
0.7
<0.5
---
<0.5
<0.5
---
Anthracene
0.5
<0.5
<0.5
---
<0.5
<0.5
---
<0.5
<0.5
---
Fluoranthene
0.5
<0.5
0.8
---
2
<0.5
---
<0.5
0.6
---
Pyrene
0.5
<0.5
0.9
---
1.9
<0.5
---
0.6
1
50.0
Benz(a)anthracene
0.5
<0.5
<0.5
---
1.2
<0.5
---
<0.5
<0.5
---
Chrysene
0.5
<0.5
<0.5
---
1.1
<0.5
---
<0.5
0.5
---
Benzo(b)fluoranthene
0.5
<0.5
<0.5
---
1.4
<0.5
---
<0.5
0.5
---
Benzo(k)fluoranthene
0.5
<0.5
<0.5
---
0.6
<0.5
---
<0.5
<0.5
---
Benzo(a)pyrene
0.5
<0.5
<0.5
---
1
<0.5
---
<0.5
<0.5
---
Indeno(1.2.3.cd)pyrene
0.5
<0.5
<0.5
---
0.8
<0.5
---
<0.5
<0.5
---
Dibenz(a.h)anthracene
0.5
<0.5
<0.5
---
<0.5
<0.5
---
<0.5
<0.5
---
Benzo(g.h.i)perylene
0.5
<0.5
<0.5
---
0.9
<0.5
---
<0.5
<0.5
---
Benzene
0.2
<0.2
<0.2
---
<0.2
<0.2
---
<0.2
<0.2
---
Toluene
0.5
<0.5
<0.5
---
<0.5
<0.5
---
<0.5
<0.5
---
Ethylbenzene
0.5
<0.5
<0.5
---
<0.5
<0.5
---
<0.5
<0.5
---
meta- & para-Xylene
0.5
<0.5
<0.5
---
<0.5
<0.5
---
<0.5
<0.5
---
ortho-Xylene
0.5
<0.5
<0.5
---
<0.5
<0.5
---
<0.5
<0.5
---
C6 - C9 Fraction
10
<10
<10
---
<10
<10
---
<10
<10
---
C10 - C14 Fraction
50
<50
<50
---
<50
<50
---
<50
<50
---
C15 - C28 Fraction
100
<100
140
---
340
<100
---
170
<100
---
C29 - C36 Fraction
100
<100
230
---
540
<100
---
130
<100
---
Analyte
LOR
Arsenic
5
15
Cadmium
1
Chromium
210061 QAQC
(1.4-1.5)
DUP1
DUP2
DUP3
RPD (%)
J12
TABLE 3
SPLIT DUPLICATE RESULTS TP4
RPD
TP10
RPD
TP12
(%)
(1.9-2.0)
(%)
(2.4-2.5)
68
127.7
33
77
80.0
74
37
66.7
13
13
0.0
2
5.2
88.9
1
<2
---
2
21
49
80.0
136
130
4.5
97
32
100.8
Copper
5
334
72
129.1
641
2000
102.9
98
38
88.2
Lead
5
337
100
108.5
231
230
0.4
142
73
64.2
Nickel
2
54
45
18.2
70
110
44.4
49
32
42.0
Zinc
5
745
450
49.4
720
1200
50.0
472
370
24.2
0.1
0.2
0.17
16.2
0.4
0.26
42.4
0.3
0.15
66.7
Free Cyanide
1
---
---
---
<1
<0.1
---
---
---
---
Total Cyanide
1
---
---
---
2
1.5
28.6
---
---
---
Naphthalene
0.5
<0.5
<0.5
---
<0.5
<0.5
---
<0.5
<0.5
---
Acenaphthylene
0.5
<0.5
<0.5
---
<0.5
<0.5
---
<0.5
<0.5
---
Acenaphthene
0.5
<0.5
<0.5
---
<0.5
<0.5
---
<0.5
<0.5
---
Fluorene
0.5
<0.5
<0.5
---
<0.5
<0.5
---
<0.5
<0.5
---
Phenanthrene
0.5
<0.5
<0.5
---
0.7
<0.5
---
<0.5
<0.5
---
Anthracene
0.5
<0.5
<0.5
---
<0.5
<0.5
---
<0.5
<0.5
---
Fluoranthene
0.5
<0.5
<0.5
---
2
<0.5
---
<0.5
<0.5
---
Pyrene
0.5
<0.5
0.6
---
1.9
<0.5
---
0.6
0.7
15.4
Benz(a)anthracene
0.5
<0.5
<0.5
---
1.2
<0.5
---
<0.5
<0.5
---
Chrysene
0.5
<0.5
<0.5
---
1.1
<0.5
---
<0.5
<0.5
---
Benzo(b)fluoranthene
0.5
<0.5
<0.5
---
1.4
<0.5
---
<0.5
<0.5
---
Benzo(k)fluoranthene
0.5
<0.5
<0.5
---
0.6
<0.5
---
<0.5
<0.5
---
Benzo(a)pyrene
0.5
<0.5
<0.5
---
1
<0.5
---
<0.5
<0.5
---
Indeno(1.2.3.cd)pyrene
0.5
<0.5
<0.5
---
0.8
<0.5
---
<0.5
<0.5
---
Dibenz(a.h)anthracene
0.5
<0.5
<0.5
---
<0.5
<0.5
---
<0.5
<0.5
---
Benzo(g.h.i)perylene
0.5
<0.5
<0.5
---
0.9
<0.5
---
<0.5
<0.5
---
Benzene
0.2
<0.2
<0.2
---
<0.2
<0.5
---
<0.2
<0.5
---
Toluene
0.5
<0.5
<0.5
---
<0.5
<1.0
---
<0.5
<1.0
---
Ethylbenzene
0.5
<0.5
<0.5
---
<0.5
<1.0
---
<0.5
<1.0
---
meta- & para-Xylene
0.5
<0.5
<0.5
---
<0.5
<3.0
---
<0.5
<3.0
---
ortho-Xylene
0.5
<0.5
<0.5
---
<0.5
<1.0
---
<0.5
<1.0
---
C6 - C9 Fraction
10
<10
<20
---
<10
<20
---
<10
<20
---
C10 - C14 Fraction
50
<50
<10
---
<50
50
---
<50
<10
---
C15 - C28 Fraction
100
<100
130
---
340
610
56.8
170
61
94.4
Analyte
LOR
Arsenic
5
15
Cadmium
1
Chromium
Mercury
210061 QAQC
(1.4-1.5)
SPLIT1
SPLIT2
SPLIT3
RPD (%)
J13
TABLE 3
SPLIT DUPLICATE RESULTS CONTINUED TP4
Analyte
LOR
C29 - C36 Fraction
100
<100
C10 - C36 Fraction (sum)
50
<50
Notes: 1. 2. 3. 4. 5. 6. 7.
(1.4-1.5)
RPD
TP10
(%)
(1.9-2.0)
100
---
540
230
---
880
SPLIT1
RPD
TP12
(%)
(2.4-2.5)
480
11.8
130
58
76.6
1140
25.7
300
119
86.4
SPLIT2
SPLIT3
RPD (%)
LOR – (laboratory) limit of reporting RPD relative percentage difference all units in mg/kg Acceptance Criteria (see Table 1) no limit applies to <5x MDL 80-150% for low level (5x – 10 x MDL) 50-130% for medium to high level (>10x MDL)
Table 2 and 3 indicate that soil duplicate results recorded a number RPD’s greater than 50%, ranging from 64.2% to 196.7%. Blind duplicate sample DUP2 recorded heavy metal concentrations much lower than the primary sample TP10(1.9-2.0). RPD values for Cu and Zn were recorded at 195.1% and 196.7%, respectively. These concentration discrepancies and high RPD values mainly related to blind and split duplicates 1 and 2, and are likely to be due to the heterogeneity of the fill material from which the samples were obtained. It should be noted that the highest result was used in determining the fate of these samples. Splitting of duplicate samples involved an undisturbed soil sample being removed from the excavator bucket. The outer layer of the sample was then scraped off using a spatula (to prevent cross contamination) and the sample was cut in half (lengthways) with each half being placed in separate sample jars. For samples collected from a sandy soil profile the undisturbed soil sample was removed scraped and placed immediately in two clean glass jars. The field scientists typically attempt to disturb sandy soils as little as possible due to the high potential for loss of volatiles. Blanks, spikes and rinsate samples The scope of this project did not include analysis of rinsate samples, trip and field blanks or laboratory prepared trip spikes for the soil sampling program. Environmental Earth Sciences VIC did not consider analysis of rinsate samples, trip blanks or trip spikes necessary for the following reasons: rinsate samples are a measure of potential cross contamination between samples due to contamination on sampling equipment. Rinsate samples were not collected due to the field sampling procedures which included use of new sampling gloves for each soil sample. In addition, AS4482.1 Guide to the investigation and sampling of sites with potentially contaminated soil (Australian Standards 2005) states that rinsate blanks “should be collected where the threshold value for a contaminant is near the detection limit for the contaminant.” Thus, as no analysis undertaken was for analytes where the method detection limit was near the site criteria, rinsate blank analysis was not deemed necessary. a trip blank is used to document contamination attributable to shipping procedures for volatile components. For this project shipping was closely monitored, with collected samples immediately placed upright within a chilled Esky and passed directly from the 210061 QAQC
J14
field scientist to an NMI specific courier. This process is documented within the chain of custody documentation. A field blank is used to document contamination attributable to field handling. The measurement of volatiles present within samples due to field handling procedure is a measurement of false p0.5ositives. False positives are not considered to be a major concern due to the industrial nature of the site. laboratory prepared trip spikes are used to measure potential volatile contaminant loss due to transport and field handling procedures. Environmental Earth Sciences VIC follows strict sample handling procedures and consider the potential for volatile loss during handling and transport low. Furthermore the use of laboratory prepared trip spikes is difficult to control on a site such as this where the soil matrix is considerably varied. The ability of a laboratory prepared trip spike to accurately represent the matrix of fill samples collected from the site is thought to limit the usefulness of the data. For these reasons project laboratory prepared trip spikes were not used for this project.
3.2.3
Field instrument calibration
Field equipment used for the soil investigation was appropriate for the required works and was used in the appropriate manner. A Photoionisation detector (PID) was calibrated in accordance with the manufacturer specifications and Environmental Earth Sciences VIC QA/QC documentation.
3.3
Laboratory QA/QC
All soil analysis was undertaken by Australian Laboratory Services (ALS), Labmark and Australian Safer Environment & Technology (ASET), which are all NATA accredited for the methods used. Details of this accreditation can be viewed at http://www.nata.asn.au/, while details of the samples sent to each laboratory and the analysis requested are contained in the chain of custody documentation held in Appendix D. A review of the collection date of samples, laboratory extraction date and allowable holding time indicated all analysis was completed within the allowable holding times. These reports include details of surrogates and spikes used, percent recoveries of surrogates and spikes used, the instrument detection limits, the method detection limits, the practical quantification limits and the reference samples results.
3.4
QA/QC data evaluation
Based on information presented in Sections 3.1, 3.2 and 3.3 it can be confidently stated that the MDQOâ&#x20AC;&#x2122;s for this project have been met and the data set is considered to be reliable.
4
REFERENCES
APHA 1995, Standard methods for the examination of water and waste-water 19th edition. Australian and New Zealand Environment and Conservation Council (ANZECC) 1992, Australian and New Zealand Guidelines for the assessment and management of contaminated sites Australia and New Zealand Environment Council, National Health and Medical Research Council, Melbourne, Victoria.
210061 QAQC
J15
Australian/New Zealand Standard 1998 Water Quality Sampling, Part 1: Guidance on the design of sampling programs, sampling techniques and the preservation and handling of samples New Zealand Standards Institute, Wellington, NZ. AS/NZ 5667. Environmental & Earth Sciences 2005, Soil, gas and groundwater sampling manual, unpublished. EPA Victoria 2000, A guide to the sampling and analysis of waters, waste-waters, soils and wastes. EPA Information Bulletin. Publication 441. EPA Victoria 2000, Groundwater sampling guidelines EPA Information Bulletin. Publication 669 ISO Standards 1995, Quality management and quality assurance ISO8402. National Environment Protection Council (NEPC) 1999, National environment protection (assessment of site contamination) measure Rayment & Higginson 1992, Australian laboratory handbook of soil and water chemical methods. Standards Australia 1997, Guide to the sampling and investigation of potentially contaminated soil (Part 1: Non-volatile and semi-volatile compounds) Standards Australia. AS 4482.1. Standards Australia 1999, Guide to the sampling and investigation of potentially contaminated soil (Part 2: Volatile substances) Standards Australia. AS 4482.1
210061 QAQC
J16
APPENDIX F
210061_ReportV2.doc
PROJECT TIMEFRAME
Engage an auditor Environmental audit Allow time for Auditor to review previous reports/data Possible additional soil works for 53V audit (if needed) Groundwater investigation Sampling and analysis plan (SAP) and approval Bore installation and development First round of sampling and analysis Issue GME letter to Auditor Receipt of Auditor comments Second round of sampling and analysis and reporting Soil vapour and Risk assessment and reporting Cleanup Plan Addressing Auditor comments on report and Cleanup Plan Environmental management plan (EMP)* Cap system construction Adjustments to Environmental management plan (EMP) for post works management * EMP includes site management during cleanup and ongoing future management (up to 5 years)
Month 13
Month 12
Month 11
Month 10
Month 9
Month 8
Month 7
Month 6
Month 5
Month 4
Month 3
Month 2
Work required
Month 1
Provisional Timeframe for Environmental Works