Benzoyl peroxide (Dibenzoyl peroxide) [C14H10O4]

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Citations (59)

References

1

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With sodium hydroxide; dihydrogen peroxide in 1,1,2-Trichloro-1,2,2trifluoroethane

T=0 - 5°C;

Rakhimov, A. I.; Androsyuk, E. R.; Shelyazhenko, S. V.; Yagupol'skii, L. M.

Journal of Organic Chemistry USSR (English Translation), 1981 , p. 1470 - 1475 Zhurnal Organicheskoi Khimii, 1981 , vol. 17, # 8 p. 1652 - 1657 Title/Abstract

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With dihydrogen peroxide; sodium carbonate

McKee

Patent: DE540588 , 1926 ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 17, p. 478 Full Text Show Details

With sodium peroxide

Schwyzer,J.

Die Fabrikation pharmazeutischer und chemisch-technischer Produkte <Berlin 1931>, S. 179 Full Text Show Details

With sodium peroxide

Nencki; Zaleski

Hoppe-Seyler's Zeitschrift fuer Physiologische Chemie, 1899 , vol. 27, p. 493 Full Text Show Details

With barium peroxide

Brodie

Jahresbericht ueber die Fortschritte der Chemie und Verwandter Theile Anderer Wissenschaften, 1863 , p. 317 Full Text View citing articles Show Details

Brodie

Journal of the Chemical Society, 1864 , vol. 17, p. 269 Ann. d. Physik, 1864 , vol. 121, p. 377 Full Text Show Details

With sodium hydroxide; dihydrogen peroxide

Baeyer; Villiger

Chemische Berichte, 1900 , vol. 33, p. 1581 Full Text View citing articles Show Details

v. Pechmann; Vanino Chemische Berichte, 1894 , vol. 27, p. 1511 Full Text Show Details

With (2S)-N-methyl-1-phenylpropan-2-amine hydrate; sodium peroxide; acetone

Gambarjan

Chemische Berichte, 1909 , vol. 42, p. 4010 Full Text View citing articles Show Details

With barium peroxide; water

Orndorff; White

Zeitschrift fuer Physikalische Chemie, Stoechiometrie und Verwandtschaftslehre, 1893 , vol. 12, p. 68 Full Text Show Details

Sonnenschein

Monatshefte fuer Chemie, 1886 , vol. 7, p. 522 Anm. Full Text Show Details

With sodium peroxide; water

T=0°C;

Prileshajew

Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, 1910 , vol. 42, p. 1409 Chem. Zentralbl., 1911 , vol. 82, # I p. 1280 Full Text View citing articles Show Details

Nencki; Zaleski

Hoppe-Seyler's Zeitschrift fuer Physiologische Chemie, 1899 , vol. 27, p. 493 Full Text Show Details

With sodium hydroxide; dihydrogen peroxide

D'Ans et al.

Angewandte Chemie, 1953 , vol. 65, p. 57 Full Text View citing articles Show Details

With dihydrogen peroxide; sodium dodecylsulfate; sodium hydroxide in water

T=0°C; 2.5 h; Hide Experimental Procedure

Chen, Huan-Huan; Wang, Guang-Zu; Han, Jin; Xu, Meng-Yu; Zhao, Yong-Qiang; Xu, Hua-Jian

Tetrahedron, 2014 , vol. 70, # 2 p. 212 - 217 Title/Abstract

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1:4.1 Preparation of benzoyl peroxide analogs 15

General procedure: Benzoyl peroxide analogs were prepared according to literature procedure.

Sodium hydroxide (1.75 g) and 15 mL water were added into a round-bottom flask, 2.0 mL hydrogen peroxide and 0.025 g sodium dodecyl sulfate were added dropwise at 0 °C, 0.013 mol benzoyl chloride analogs were added dropwise slowly under stirring.

The reaction mixture was allowed to stir an additional 2.5 h.

White solid could be obtained in this reaction.

The solid was filtered out and washed with methanol/water (1:1).

Then, it was placed in vacuum oven to dry 24 h.

54 kg

With dihydrogen peroxide; sodium dodecylsulfate; sodium hydroxide in water

T=-5 - 5°C; 2.5 h; HeatingLarge scale; ConcentrationSolventReagent/catalyst; Hide Experimental Procedure

jiangsu wanchuan healthcare industry group co ltd; Liu, Hui; Wang, Peng; Chen, Zailing; Sun, Jue

Patent: CN105924378 A, 2016 ; Location in patent: Paragraph 0045-0048 ; Title/Abstract

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2:

The method for synthesizing peroxybenzoyl provided by the present embodiment comprises, in particular, the following steps:S21, 150 g of sodium dodecyl sulfate was dissolved in 120 kg of water at room temperature, stirred for 30 minutes, and then 18.5 kg of sodium hydroxide was added to stir to dissolve to obtain a solution which kept the solution temperature between -5 and 5 ° C, And add 24kg mass fraction of 30percent hydrogen peroxide, drop after the completion of insulation and stirring for 1 hour, to be fully reacted, the sodium peroxide solution;S22, the temperature of the sodium peroxide solution is maintained between -5 and 5 ° C, and then 50 kg of benzoyl chloride is added dropwise. After completion of the dropwise addition, the mixture is allowed to warm and stirred for 1 hour. The solution after the reaction is centrifuged, and the centrifuged solid And washed with water to obtain 54 kg of benzoyl peroxide product.

14.1 kg

With dihydrogen peroxide; ammonium bicarbonate

Jiangsu Sinobiopharma Co., Ltd.; Huang, Lequn; Chen, Quan

Patent: CN106349139 A, 2017 ;

T=30°C; 3.5 h; Large scale; Temperature; Hide Experimental Procedure

Location in patent: Paragraph 0014; 0015; 0016; 0017; 0018; 0019 ; Title/Abstract

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2:Example 2

(1) synthetic process:A. 22 kg of 30percent hydrogen peroxide was added to a 50 L reactor,Open the stir,Then add 13.5 kg of ammonium bicarbonate,15 kg of benzoyl chloride was slowly added dropwise,The temperature inside the reactor is 30 degrees Celsius,Reaction time is 3.5 hours;B. The reaction solution was filtered and filtered to obtain a filter cake. The filter cake was beaten and washed in a mixed solvent of 30 kg of ethanol and 30 kg of water for 40 minutes,C. Wash with 45kg of water for 20 minutes, repeated beating washing 3 times;. D finally rinsed with 45kg of water, drained, benzoyl peroxide to give a crude white; (2) purification process:E. Add the crude benzoyl benzoate into a 200 L autoclave, add 52.5 kg of dichloromethane to the autoclave, control the temperature inside the autoclave at 30 ° C, stir to dissolve;F. 105kg of ethanol pressure filter to the high position, room temperature drop of ethanol, open the cooling, the reaction solution temperature dropped to -5 degrees Celsius, cooling crystallization 2.5 hours;G. After the crystallization is complete, the filter is filtered and the filter cake is removed and beaten with water for 20 minutes.Repeated beating washing 3 times,And finally 14.1 kg of white high purity benzoyl peroxide was obtained.The purity of benzoyl peroxide prepared in this example was 99.5percent.

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Rx-ID: 45977436 Find similar reactions

With eosin Y disodium salt in acetonitrile

24 h; Irradiation;

Štrukil, Vjekoslav; Sajko, Igor

Chemical Communications, 2017 , vol. 53, # 65 p. 9101 - 9104 Title/Abstract

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3

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Rx-ID: 6718970 Find similar reactions

Norac Pharma

Patent: US2012/64135 A1, 2012 ; Title/Abstract

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2:Example 2

Example 2 A benzoyl peroxide in cocoa butter composition is prepared.

Cocoa butter (4.0 g) and Tween 20 (12 mL) and deionized water (235 mL) are added together and heated to 40-45° C. with overhead stirring.

The mixture is stirred for 1 h.

Then benzoyl peroxide (25.0 g, 74.6percent by wt) is added portionwise to the cocoa butter solution.

The mixture is allowed to stir at 40-45° C. for 45 minutes then at ambient temperature overnight.

After stirring, the mixture is allowed to stand for 1 h.

Then the aqueous layer is decanted away.

The solids are filtered and dried, resulting in a white solid (21.4 g, 70.0percent benzoyl peroxide retention).

The solids are analyzed by HPLC to determine the solids contain approximately 60.6percent benzoyl peroxide (by weight).

56%

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FMC Corporation

Patent: US4235780 A1, 1980 ;

Title/Abstract

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9.b:b. b.

Use of benzoyl peroxide as the initiator A mixture of 1.0 g (7.93 mmol) of 3,4-dihydro-4,4-dimethyl-2H-pyran-2-one and 6.29 g (31.7 mmol) of bromotrichloromethane was heated to 100° C. Heating was maintained at 100° C. for 12 hours.

During this time 600 mg (2.48 mmol) of benzoyl peroxide was added in six 100 mg portions; a 100 mg portion being added approximately every 2 hours.

The reaction mixture was cooled and placed on a silica gel packed chromatography column.

Elution with 20:1 hexane:ethyl acetate mixture afforded 1.45 g, 56percent yield, of 5-bromo-3,4,5,6-tetrahydro-3,3-dimethyl-6-trichloromethyl-2H-pyran-2-one.

Staab,H.A. et al.

Chemische Berichte, 1965 , vol. 98, p. 1122 - 1127 Full Text View citing articles Show Details

Staab et al.

Chemische Berichte, 1965 , vol. 98, p. 1128,1132 Full Text View citing articles Show Details

Staab

Angewandte Chemie, 1962 , vol. 74, p. 407,417 Full Text Show Details

Ramirez et al.

Journal of the American Chemical Society, 1960 , vol. 82, p. 5763 Full Text View citing articles Show Details

Le Berre; Berguer

Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1965 , vol. 260, p. 1995 Full Text Show Details

Koppers Co.

Patent: GB1156573 , 1967 ; Chem.Abstr., 1969 , vol. 71, # 61023x Full Text Show Details

Pfizer; Chas and Co.; Inc.

Patent: US3438882 , 1964 ; Chem.Abstr., 1969 , vol. 71, # 12843f Full Text Show Details

Berre; Bergue

Bulletin de la Societe Chimique de France, 1966 , p. 2368,2373 Full Text Show Details

Ol'dekop et al.

Journal of Organic Chemistry USSR (English Translation), 1966 , vol. 2, p. 2133 Zhurnal Organicheskoi Khimii, 1966 , vol. 2, p. 2175 Full Text Show Details

Ivanov; Bagira

J. Appl. Chem. USSR (Engl. Transl.), 1975 , vol. 48, p. 243,243 Full Text Show Details Johnson Tetrahedron Letters, 1976 , p. 331 Full Text View citing articles Show Details Otsuka et al.

Journal of the American Chemical Society, 1972 , vol. 94, p. 3761,3767 Full Text Show Details Greene; Kazan Journal of Organic Chemistry, 1963 , vol. 28, p. 2168,2169 Full Text Show Details Ol'dekop; El'nizkii J. Gen. Chem. USSR (Engl. Transl.), 1964 , vol. 34, p. 3478,3520 Full Text Show Details Voronkov et al.

Soobshcheniya Akademii Nauk Gruzinskoi SSR, 1979 , vol. 93, # 1 p. 61,62,63,64 Full Text Show Details Sprecher; Nativ Tetrahedron Letters, 1968 , p. 4405 Full Text View citing articles Show Details

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Popp, Karl F.; Stiefel, Brent D.

Patent: US6433024 B1, 2002 ; Title/Abstract

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3:EXAMPLE 3

EXAMPLE 3 The following benzoyl peroxide creamy wash is prepared in accordance with the procedures set forth in Example 1.

The lactic acid is added along with the glycolic acid.

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Popp, Karl F.; Stiefel, Brent D.

Patent: US6433024 B1, 2002 ; Title/Abstract

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4:EXAMPLE 4

EXAMPLE 4 The following benzoyl peroxide creamy wash is prepared in accordance with the procedures set forth in Example 1.

The lactic acid is added at the point were the glyolic acid is added in Example 1.

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Asahi Denka Kogyo K. K.

Patent: US5929290 A1, 1999 ; Title/Abstract

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6:Example 6

Example 6 A reactor equipped with a reflux condenser, a stirrer, a dropping funnel and a thermometer was charged with 100 g of xylene and the system was purged with nitrogen.

Separately, a mixed solution comprising 150 g of butyl acrylate, 5 g of methacrylic acid, 15 g of the resin reforming agent of the present invention: (1-b), (5-b), (11)-(15), (17-b), (22-b) or (26), or the comparative compound (1)-(3), 2 g of benzoyl peroxide, and 0.5 g of di-tertiary butyl peroxide was prepared and it was continuously added to the reactor dropwise at a reaction temperature of 130° C. over a period of 2 hours.

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National Starch and Chemical Investment Holding Corporation

Patent: EP913445 A1, 1999 ; Title/Abstract

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1:EXAMPLE 1

EXAMPLE 1 An initial charge containing 2.1 g t-octyl acrylamide, 16.76 g butyl acrylate, 5.0 g vinyl acetate, 1.0 g acrylic acid, 39.9 g ethyl acetate (solvent) and 0.04 g benzoyl peroxide (polymerization initiator) was prepared and charged to a 1-liter four-neck round bottom flask equipped with stainless steel stirrer, thermometer, condenser, water bath, slow addition funnels.

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Nitto Denko Corporation

Patent: US2010/15210 A1, 2010 ; Title/Abstract

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2:Example 2

Example 2 In the same manner as in Example 1 except that 0.3 part by weight of dibenzoyl peroxide was used instead of 0.2 part by weight thereof, a patch was prepared.

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Nitto Denko Corporation

Patent: US2010/15210 A1, 2010 ; Title/Abstract

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3:Example 3

Example 3 In the same manner as in Example 1 except that 0.35 part by weight of dibenzoyl peroxide was used instead of 0.2 part by weight thereof, a patch was prepared.

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Nitto Denko Corporation

Patent: US2010/15210 A1, 2010 ; Title/Abstract

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4:Example 4

Example 4 In the same manner as in Example 1 except that 0.4 part by weight of dibenzoyl peroxide was used instead of 0.2 part by weight thereof, a patch was prepared.

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Nitto Denko Corporation

Patent: US2010/15210 A1, 2010 ; Title/Abstract

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6:Example 6

Example 6 In the same manner as in Example 5 except that 0.4 part by weight of dibenzoyl peroxide was used instead of 0.3 part by weight thereof, a patch was prepared.

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Nitto Denko Corporation

Patent: US2010/15210 A1, 2010 ; Title/Abstract

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C.1:Comparative Example 1 Comparative Example 1 In the same manner as in Example 10 except that 0 part by weight of dibenzoyl peroxide was used instead of 0.2 part by weight thereof, a patch was prepared.

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Nitto Denko Corporation

Patent: US2010/15210 A1, 2010 ; Title/Abstract

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C.2:Comparative Example 2 Comparative Example 2 In the same manner as in Example 10 except that 60 parts by weight of polybutadiene was used instead of polybutadiene and 1 part by weight of dibenzoyl peroxide was used instead of 0.2 part by weight thereof, a patch was prepared.

4

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Norac Pharma

Patent: US2012/64135 A1, 2012 ; Title/Abstract

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8:Example 8

Example 8 A benzoyl peroxide and tretinoin in cocoa butter melt is prepared.

Cocoa butter (1.7 g) is stirred at 40-45° C. for 20 minutes.

Benzoyl peroxide (5.0 g, 74.6percent by wt) is introduced and the melt is mixed for an additional 20 min, followed by tretinoin (1.3 g) and the melt is stirred for 30 min at 40° C. The mixture is allowed to cool.

The solids are allowed to air dry which results in an off-white solid (8.0 g).

5

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Norac Pharma

Patent: US2012/64135 A1, 2012 ; Title/Abstract

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7:Example 7

Example 7 A benzoyl peroxide and tazarotene in cocoa butter melt is prepared.

Cocoa butter (1.7 g) is stirred at 40-45° C. for 20 minutes.

Benzoyl peroxide (5.0 g, 74.6percent by wt) is introduced and the melt is mixed for an additional 20 min, followed by tazarotene (3.3 g) and the melt is stirred for 30 min at 40° C. The mixture is allowed to cool.

The solids are allowed to air dry which results in an off-white solid (10.0 g).

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With sodium hydroxide; dihydrogen peroxide; trimethyloctadecylammonium chloride in butanone

T=15°C; 0.5 h; Title compound not separated from byproducts;

Moorhoff, Cornelis M.; Braybrook, Carl

Journal of Chemical Research, Miniprint, 2003 , # 3 p. 339 - 361 Title/Abstract

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With sodium hydroxide; dihydrogen peroxide; trimethyloctadecylammonium chloride in butanone

T=15°C; 0.5 h; Title compound not separated from byproducts;

Moorhoff, Cornelis M.; Braybrook, Carl

Journal of Chemical Research, Miniprint, 2003 , # 3 p. 339 - 361 Title/Abstract

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With sodium hydroxide; dihydrogen peroxide; trimethyloctadecylammonium chloride in butanone

T=15°C; 0.5 h; Title compound not separated from byproducts;

Moorhoff, Cornelis M.; Braybrook, Carl

Journal of Chemical Research, Miniprint, 2003 , # 3 p. 339 - 361 Title/Abstract

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With sodium hydroxide; dihydrogen peroxide; trimethyloctadecylammonium chloride; ortho-toluoyl chloride in butanone

T=15°C; 0.5 h; Title compound not separated from byproducts;

Moorhoff, Cornelis M.; Braybrook, Carl

Journal of Chemical Research, Miniprint, 2003 , # 3 p. 339 - 361 Title/Abstract

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10

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Asahi Denka Kogyo K. K.

Patent: US5929290 A1, 1999 ; Title/Abstract

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5:Example 5

Example 5 A reactor equipped with a reflux condenser, a stirrer, a dropping funnel and a thermometer was charged with 100 g of xylene and the system was purged with nitrogen.

Separately, a mixed solution comprising of 150 g of styrene, 7.5 g of the resin reforming agent of the present invention: (1-b), (5-b), (11)-(15), (17-b), (22-b), or (26), or the comparative compound (1)-(3), 2 g of benzoyl peroxide, and 1 g of di-tertiary butyl peroxide was prepared and continuously added to the reactor dropwise at a reaction temperature of 130° C. over a period of 2 hours.

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With potassium hydroxide; dihydrogen peroxide

E. I. du Pont de Nemours and Company Patent: US5831131 A1, 1998 ;

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Title/Abstract

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53.A:Ultrasonic Batch Reaction of Benzoyl Chloride A. Giving Benzoyl Peroxide as Major Product: A beaker was loaded with 1.23 g ~85percent KOH pellets (19 mmoles) dissolved up to 15.9 ml with water, 2.04 ml of 30percent aqueous hydrogen peroxide (20 mmoles), 50 ml of Freon.(R). E1, and 2.32 ml of benzoyl chloride (20 mmoles) with ice bath cooling.

An ultrasonic horn connected to a 40 Khz, 150 watt Dukane power source was started up at maximum power and lowered into the reaction mixture.

After 25 seconds, ultrasonication was stopped, the solids filtered off, washed with water, and sucked dry on the filter.

This gave 1.52 g of white solid, a 63percent yield of benzoyl peroxide based on starting benzoyl chloride.

The filtrate was brought to pH ~1 by the addition of concentrated sulfuric acid and then extracted three times with methylene chloride.

The three methylene chloride extracts had a combined volume of 80 ml, 10.0 ml of which took 0.2 ml of 0.1N thiosulfate in iodometric peroxide titration.

The failure to find significant amounts of peroxide in the methylene chloride extracts indicates that little if any benzoyl hydroperoxide C6 H5 (C=O)OOH! was formed during the reaction.

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G-C Dental Industrial Corporation Patent: US4713403 A1, 1987 ; Title/Abstract

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Paste A

Quartz treated with γ-methacryloxypropyl trimethoxysilane (50 μm or less): 67.5 parts by weight Benzoyl peroxide: 1.5 parts by weight Hydroquinone monomethyl ether: 0.01 part by weight A

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With cobalt(III) acetylacetonate

T=25°C; MechanismProduct distribution;

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Lederer, Pavel; Macova, Eva; Veprek-Siska, Josef

Collection of Czechoslovak Chemical Communications, 1984 , vol. 49, # 3 p. 673 - 679 Title/Abstract

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14

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A: 6% B: 8% C: 90% D: 2%

With cobalt(III) acetylacetonate

T=24.9°C; 5 h; Ea; other metal 2,4pentandioates (Co(II), Fe(III), Mn(III), Cr(III)).; MechanismProduct distributionThermodynamic data;

Lederer, Pavel; Macova, Eva; Veprek-Siska, Josef

Collection of Czechoslovak Chemical Communications, 1984 , vol. 49, # 3 p. 673 - 679 Title/Abstract

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15

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Takeuchi, Ken'ichi; Murai, Osamu; Matsui, Shin; Inoue, Takeshi; Kitagawa, Toshikazu; Okamoto, Kunio

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , # 9 p. 1301 - 1310 Title/Abstract

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C: 83.2%

With oxygen; ozone; lithium chloride in tetrachloromethane

T=40°C;

El'nitskii, A. P.; Serrano, K. F.; Poluyan, O. S.

Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, # 8 p. 1565 - 1566 Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 8 p. 1764 Title/Abstract

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2: Na2O2

View Scheme

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Takeuchi, Ken'ichi; Murai, Osamu; Matsui, Shin; Inoue, Takeshi; Kitagawa, Toshikazu; Okamoto, Kunio

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , # 9 p. 1301 - 1310 Title/Abstract

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With barium peroxide

Brodie

Journal of the Chemical Society, 1864 , vol. 17, p. 269 Ann. d. Physik, 1864 , vol. 121, p. 377 Full Text Show Details

With potassium hydroxide; dihydrogen

Clover; Richmond

9 % Chromat.

peroxide

American Chemical Journal, 1903 , vol. 29, p. 189 Full Text View citing articles Show Details

With dioxygenbis(triphenylphosphine)platinum(0) in dichloromethane

2 h;

Aida, Shun'ichi; Ohta, Hiroyuki; Kamiya, Yoshio

Chemistry Letters, 1981 , p. 1639 - 1642 Title/Abstract

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19

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90%

With dihydrogen peroxide; dicyclohexylcarbodiimide in diethyl ether; dichloromethane

T=0°C; 2 h; Mechanism;

Rakhimov, A. I.; Androsyuk, E. R.; Shelyazhenko, S. V.; Yagupol'skii, L. M.

Journal of Organic Chemistry USSR (English Translation), 1981 , p. 1470 - 1475 Zhurnal Organicheskoi Khimii, 1981 , vol. 17, # 8 p. 1652 - 1657 Title/Abstract

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90%

With dihydrogen peroxide; dicyclohexylcarbodiimide in diethyl ether; dichloromethane

T=0 - 2°C;

Rakhimov, A. I.; Androsyuk, E. R.; Shelyazhenko, S. V.; Yagupol'skii, L. M.

Journal of Organic Chemistry USSR (English Translation), 1981 , p. 1470 - 1475 Zhurnal Organicheskoi Khimii, 1981 , vol. 17, # 8 p. 1652 - 1657 Title/Abstract

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A: 27% B: 22%

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in dichloromethane

T=-78°C; 6 h;

Tatsuno, Y.; Otsuka, Sei

Journal of the American Chemical Society, 1981 , vol. 103, # 19 p. 5832 - 5839 Title/Abstract

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Synthesize Find similar Multi-step reaction with 2 steps 1: 55 percent Chromat. / peroxobis(triphenylphosphine)platinum(II) / CH2Cl2 / 28 h 2: 9 percent Chromat. / peroxobis(triphenylphosphine)platinum(II) / CH2Cl2 / 2 h View Scheme

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Aida, Shun'ichi; Ohta, Hiroyuki; Kamiya, Yoshio

Chemistry Letters, 1981 , p. 1639 - 1642 Title/Abstract

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in dichloromethane

-70°C;

Otsuka, S.; Nakamura, A.; Tatsuno, Y.; Mike, M.

Journal of the American Chemical Society, 1972 , vol. 94, p. 3761 - 3767 Full Text View citing articles Show Details

in dichloromethane

-70°C;

Gmelin Handbook: Ni: Org.Verb.2, 7, page 393 - 402 Full Text Show Details

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in toluene

-10°C;

Otsuka, S.; Nakamura, A.; Tatsuno, Y.; Mike, M.

Journal of the American Chemical Society, 1972 , vol. 94, p. 3761 - 3767 Full Text View citing articles Show Details

in toluene

-10°C;

Gmelin Handbook: Ni: Org.Verb.2, 7, page 393 - 402 Full Text Show Details

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With tetrachloromethane; NBromosuccinimide

Erwaermen des Reaktionsprodukts mit Natriumaethylat in Aethanol und Aether;

Paul; Tchelitcheff

Bulletin de la Societe Chimique de France, 1956 , p. 869,874 Full Text View citing articles Show Details

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T=0°C;

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Kirmse; Horner

Chemische Berichte, 1956 , vol. 89, p. 836,840 Full Text View citing articles Show Details

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T=20°C;

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Kirmse; Horner

Chemische Berichte, 1956 , vol. 89, p. 836,840 Full Text View citing articles Show Details

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T=25°C;

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Kirmse; Horner

Chemische Berichte, 1956 , vol. 89, p. 836,840 Full Text View citing articles Show Details

A

B

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28

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Rx-ID: 5721497 Find similar reactions

T=0°C;

Marvel; Nichols

Journal of Organic Chemistry, 1941 , vol. 6, p. 296,299 Full Text View citing articles Show Details

29

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Rx-ID: 26453213 Find similar reactions

With NaOH or pyridine in water

an aq. soln. of peroxophosphorous acid, from O3- or F2O-induced autoxid-ation of aq.

H3PO3, treated with NaOH or pyridine, is forming dibenzoyl-peroxide with benzoylchloride;;

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Bockemueller, W.; Goetz, T.

Liebigs Annalen der Chemie, 1934 , vol. 508, p. 263 - 297 Full Text Show Details

Gmelin Handbook: P: MVol.C, 64, page 136 - 138 Full Text Show Details

30

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Rx-ID: 7067430 Find similar reactions

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Fenton

Proceedings of the Royal Society of London, Series A: Mathematical, Physical and Engineering Sciences, 1914 , vol. 90, p. 493 Chem. Zentralbl., 1914 , vol. 85, # II p. 863 Full Text View citing articles Show Details

31

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Rx-ID: 6208710 Find similar reactions

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Gambarjan

Chemische Berichte, 1909 , vol. 42, p. 4010 Full Text View citing articles Show Details

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Nencki; Zaleski

Hoppe-Seyler's Zeitschrift fuer Physiologische Chemie, 1899 , vol. 27, p. 493 Full Text Show Details

32

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T=50°C;

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Rx-ID: 283131 Find similar reactions

Jorissen; Ringer

Journal fuer Praktische Chemie (Leipzig), 1905 , vol. <2> 72, p. 173 Chem. Zentralbl., 1905 , vol. 76, # I p. 817 Full Text View citing articles Show Details

Jorissen; Ringer

Chem. Zentralbl., 1905 , vol. 76, # I p. 817 Full Text Show Details

33

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34

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Rx-ID: 7450195 Find similar reactions

Baeyer; Villiger

Chemische Berichte, 1900 , vol. 33, p. 1581 Full Text View citing articles Show Details

Nef

Justus Liebigs Annalen der Chemie, 1897 , vol. 298, p. 322 Justus Liebigs Annalen der Chemie, 1901 , vol. 318, p. 50 Full Text View citing articles Show Details

Jorissen; Ringer

Journal fuer Praktische Chemie (Leipzig), 1905 , vol. <2> 72, p. 173 Chem. Zentralbl., 1905 , vol. 76, # I p. 817 Full Text View citing articles Show Details

Jorissen; Ringer

Chem. Zentralbl., 1905 , vol. 76, # I p. 817 Full Text Show Details

Synthesize Find similar Multi-step reaction with 2 steps 1: sand; air 2: natrium carbonate / 50 °C View Scheme

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Rx-ID: 22021698 Find similar reactions

Jorissen; Ringer

Journal fuer Praktische Chemie (Leipzig), 1905 , vol. <2> 72, p. 173 Chem. Zentralbl., 1905 , vol. 76, # I p. 817 Full Text View citing articles Show Details

Jorissen; Ringer

Chem. Zentralbl., 1905 , vol. 76, # I p. 817 Full Text Show Details

A

B

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35

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Rx-ID: 609400 Find similar reactions

Clover; Richmond

American Chemical Journal, 1903 , vol. 29, p. 189 Full Text View citing articles Show Details

A

B

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36

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With potassium hydroxide; dihydrogen peroxide

T=0°C;

Clover; Richmond

American Chemical Journal, 1903 , vol. 29, p. 189 Full Text View citing articles Show Details

A

B

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A

B

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37

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Rx-ID: 6208711 Find similar reactions

T=0°C;

Clover; Richmond

American Chemical Journal, 1903 , vol. 29, p. 189 Full Text View citing articles Show Details

38

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Rx-ID: 6208712 Find similar reactions

Clover; Richmond

American Chemical Journal, 1903 , vol. 29, p. 189 Full Text View citing articles Show Details

A

B

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39

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With water; sodium acetate

Clover; Richmond

American Chemical Journal, 1903 , vol. 29, p. 189 Full Text View citing articles Show Details

40

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Rx-ID: 609482 Find similar reactions

With sodium hydrogencarbonate

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Baeyer; Villiger

Chemische Berichte, 1900 , vol. 33, p. 1581 Full Text View citing articles Show Details

41

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Rx-ID: 6208709 Find similar reactions

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Baeyer; Villiger

Chemische Berichte, 1900 , vol. 33, p. 1581 Full Text View citing articles Show Details

A

B

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42

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Baeyer; Villiger

Chemische Berichte, 1900 , vol. 33, p. 1581 Full Text View citing articles Show Details

A

B

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43

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Nef

Justus Liebigs Annalen der Chemie, 1897 , vol. 298, p. 322 Justus Liebigs Annalen der Chemie, 1901 , vol. 318, p. 50 Full Text View citing articles Show Details

44

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Rx-ID: 6208705 Find similar reactions

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v. Pechmann; Vanino

Chemische Berichte, 1894 , vol. 27, p. 1511 Full Text Show Details

T=-5°C;

v. Pechmann; Vanino

Chemische Berichte, 1894 , vol. 27, p. 1511 Full Text Show Details

45

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Find similar Rx-ID: 6208707 Find similar reactions

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Orndorff; White

Zeitschrift fuer Physikalische Chemie, Stoechiometrie und Verwandtschaftslehre, 1893 , vol. 12, p. 68 Full Text Show Details

Sonnenschein

Monatshefte fuer Chemie, 1886 , vol. 7, p. 522 Anm. Full Text Show Details

46

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Rx-ID: 6208706 Find similar reactions

Brodie

Jahresbericht ueber die Fortschritte der Chemie und Verwandter Theile Anderer Wissenschaften, 1863 , p. 317 Full Text View citing articles Show Details

Brodie

Journal of the Chemical Society, 1864 , vol. 17, p. 269 Ann. d. Physik, 1864 , vol. 121, p. 377 Full Text Show Details

47

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Rx-ID: 6208708 Find similar reactions

Brodie

Journal of the Chemical Society, 1864 , vol. 17, p. 269 Ann. d. Physik, 1864 , vol. 121, p. 377 Full Text Show Details