Lab+Life Scientist Feb/Mar 2022

Page 16

liquid handling

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Enhancing liquid delivery on nonwetting surfaces

In diverse processes such as fertilisation, insecticide treatment and cooling, liquid delivery is compromised by the super-repellency of the receiving surfaces, causing droplets of liquid to ‘bounce’ off these surfaces like a golf ball bouncing along a fairway. This results in issues such as pesticide overuse, soil contamination and water waste.

N

the water whirls and flows, consuming the kinetic

Another potential application of the new

energy of the water balloon. In this way, the balloon

technology is in spray cooling. The researchers

will not rebound easily.”

estimate that the technology can enhance the

Currently, special polymers are added into the

cooling rate of spray cooling fourfold, meaning

ow, mechanical engineering

droplet to modify the liquid’s interfacial properties.

only one-fourth of the amount of water or time is

researchers at The University of Hong Kong

Such polymers act like superglue to pin the droplet

required to obtain the same cooling effect. Water

(HKU) have developed a strategy to enhance

onto the surface; however, they will also mix with

droplets overlaid with liquids of a higher boiling

liquid disposition by overlaying impacting

the content and change the nature of the droplet.

point will be less easy to vaporise, and hence more

droplets with a tiny amount of lubricant (less

The new method allows a thin layer of lubricant to

readily able to come into direct contact with the

than 0.1 vol% of the droplet), to modify their

be formed on the droplet, while leaving its content

overheated surfaces — whereas in conventional

interfacial properties for easy manipulation. As

intact. The choices for the overlayers can be of a

water spraying, vaporised water will form a barrier

published in the journal Nature Communications,

wide diversity, depending on the liquid type.

inter-facially to prevent more water from reaching

the overlayers suppress the out-of-plane

“The footprint of our method can be made to

rebounds by slowing the departing droplets

be minimal, circumventing surface contamination

through viscous dissipation and sustaining

and toxification,” Dr Han said.

the heated surfaces to substantially retard the cooling process. “Imagine cooling a hot pot by spraying water,”

the droplets’ in-plane mobility through self-

“Our method enables multifunctional and

Dr Han said. “Using the technology, the water is

lubrication — a preferential state for scenarios

dynamic control of droplets that impact different

firmly deposited onto the pot, allowing fast cooling.”

such as shedding of liquid in spray cooling and

types of non-wetting surfaces. The droplet’s

“This is especially important for application

repositioning of droplets in printing.

post-deposition state can be switched between

in major catastrophic events involving high

“Analogically, the ultrathin liquid overlayer

immobilised and sliding on the surface by tuning

temperatures such as fire or overheating at power

turns the elastic golf ball into a balloon filled with

the overlayer volume, enabling rich fluid controls

plants, and in other industrial applications,”

water,” said Dr Xing Han, first author on the

on repellent surfaces, including superhydrophobic,

concluded Liqiu Wang, Chair Professor of

paper, from the HKU Department of Mechanical

superomniphobic and superheated types, similar

Thermal-Fluid Sciences and Engineering, from the

Engineering. “As the water balloon hits the ground,

to depositing golf balls on all kinds of terrain.”

Department of Mechanical Engineering.

16 | LAB+LIFE SCIENTIST - Feb/Mar 2022

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