Trade Parts Xpress Product Digital Catalogue

Page 1


AIR DUSTER

Description

Blasts dust, grime and fluff from hard to reach areas. Helps to clean, sanitise and remove dust and dirt particles from those hard to reach places. The product once dispersed evaporates in seconds leaving a clean fresh surface.

Key Features

DESCRIPTION

Protective

Clothing Please ensure all protective clothing is worn at all times.

Gloves

Materials

Procedure

Shake the can for 60 seconds. Remove the cap protector. Insert the straw.

Press and hold the trigger.

Move the nozzle back and forth as you clean.

AIR FRESHENER RANGE

Description

A new concentrate air freshener designed to eradicate odours from vehicles. This fast acting formula will give instant results.

Key Features

Protective Clothing Please ensure all protective clothing is worn at all times.

Gloves

Materials

Air Freshener 1ltr Trigger

Procedure

Pour the air freshener fluid into spray bottle.

Close the spray bottle securely.

Spray a small amount to check the mist.

ALLOY WHEEL CLEANER

Description

A powerful acid free highly concentrated alloy wheel cleaner designed to quickly remove brake dust and debris from lacquered alloy wheels.

NOTE: To ascertain suitability before use, test in a small inconspicuous area. Not to be used on wheels which are corroded/ damaged to the surface/lacquer.

Key Features

Cleans & degreases

Powerful fast evaporating formula

DESCRIPTION

Protective

Clothing Please ensure all protective clothing is worn at all times.

Materials

1ltr Trigger Microfibre Cloth

Procedure

Pour the desired amount into the trigger bottle.

Dilute with correct ratio of water.

Spray on, leave for no more than 1 minute.

Agitate and wash off.

25ltr Barrel
5ltr Bottle
Funnel
Unscrew bottle cap. Place funnel into bottle.

ATMOSPHERIC SANITISER

Description

Creates a state of cleanliness in your vehicle significantly greater than traditional methods by killing more than 99% of germs and bacteria present in the cabin and air-conditioning system.

Key Features

DESCRIPTION

Sanitises

Protective

Clothing Please ensure all protective clothing is worn at all times.

Materials

Procedure

Turn car on and ensure it’s running.

Set the temp to the lowest setting.

Set fans to fastest setting. Select recycle air.

Push down the nozzle, exit the vehicle and close door.

After 10 minutes, turn car off, open doors and air out the car for 30 minutes.

Mask
Gloves

AQUA FREE ENHANCER

Description

Rapid detailer, cleans, shines and protects leaving no streaks. This can be used on all surfaces including paintwork, black plastics, dashes, chrome and mirrors.

Key Features

Suitable for all paint finishes

DESCRIPTION

Aqua Free Enhancer
Aqua Free Enhancer
High gloss shine

Protective

Clothing Please ensure all protective clothing is worn at all times.

Materials

Procedure

1ltr

Pour the desired amount into the trigger bottle.

Spray over the bodywork. Buff the area to a shine with a clean, dry cloth.

25ltr Barrel
Eyewear
Shoes
Trousers
5ltr Bottle
Trigger Microfibre Cloth
Funnel
Unscrew bottle cap. Place funnel into bottle.

AQUA RINSE AID

Description

A concentrated hot wax, which protects paintwork and livery and leaves a glossy, streak-free finish. Contains unique dirt repellent to inhibit resoling. Suitable for use with all forecourt systems.

Key Features

Quick application

Prolongs time between washes

DESCRIPTION

Aqua Rinse Aid

Protective

Clothing Please ensure all protective clothing is worn at all times.

Materials

Procedure

Pour into the power washer’s container.

Spread the Aqua Rinse Aid across the paint.

Rinse with clean water and buff the surface.

Attach the power washer.

25ltr Barrel Eyewear Shoes
5ltr Bottle
Unscrew bottle cap.
Jet Washer Sponge

BIRD DROPPING & BUG REMOVER

Description

The soapy mousse will rehydrate the deposit, creating a solution that can be easily wiped off the paintwork.

NOTE: This product will not help restore paintwork that has already been contaminated with bird lime. Do not use when bodywork or glass is very hot. Do not allow to dry before washing off.

DESCRIPTION

Key Features

Easy to use foam

Neutralises nitric acid in birdlime deposits

Bird Dropping And Bug Remover

Protective Clothing Please ensure all protective clothing is worn at all times.

Materials

Procedure

Apply to affected areas. Allow the product to rehydrate debris.

Rinse the car with water to remove any residue.

Dry the cleaned areas with a clean, dry cloth.

Gently wipe the area with a microfibre cloth.

Microfibre Cloth

BODY POLISH - STANDARD

Description

A durable, easy to use premium car polish with a low dust formula. Contains carnauba wax for high gloss, long lasting, durable, detergent resistant finish.

Suitable for new and used cars.

DESCRIPTION

Standard Body Polish

Key Features

Long lasting formula

Durable finish

Protective Clothing Please ensure all protective clothing is worn at all times.

Materials

5ltr Bottle

Procedure

Wash and dry the car thoroughly to remove dirt.

Remove residue with microfibre cloth.

Dab a small amount onto the polishing pad.

Move in circular motions with light pressure.

Microfibre Cloth

CUTTING COMPOUND FINE

Description

Revitalises tired oxidised paintwork, removes traffic film, superficial contamination and aged and chalky deposits.

Cleans, and conditions surfaces for further treatments.

DESCRIPTION

Cutting Compound Fine 500ml

Key Features

Revitalises paintwork

Cleans & conditions

Protective Clothing Please ensure all protective clothing is worn at all times.

Materials

Procedure

Wash and dry the car thoroughly to remove dirt.

Move in circular motions with light pressure.

Shake the bottle for 60 seconds.

Remove residue with microfibre cloth.

Dab a small amount onto the polishing pad.

Polishing Machine
500ml Bottle
Microfibre Cloth

CUTTING COMPOUND MEDIUM

Description

Revitalises tired oxidised paintwork, removes traffic film, superficial contamination and aged and chalky deposits.

Cleans, and conditions surfaces for further treatments.

Key Features

Revitalises paintwork

Cleans & conditions

DESCRIPTION

Protective Clothing Please ensure all protective clothing is worn at all times.

Materials

Procedure

Wash and dry the car thoroughly to remove dirt.

Move in circular motions with light pressure.

Shake the bottle for 60 seconds.

Remove residue with microfibre cloth.

Dab a small amount onto the polishing pad.

Polishing Machine
500ml Bottle
Microfibre Cloth

CUTTING COMPOUND COARSE

Description

Revitalises tired oxidised paintwork, removes traffic film, superficial contamination and aged and chalky deposits.

Cleans, and conditions surfaces for further treatments.

Key Features

Revitalises paintwork

Cleans & conditions

DESCRIPTION

Cutting Compound Coarse

Protective Clothing Please ensure all protective clothing is worn at all times.

Materials

Procedure

Wash and dry the car thoroughly to remove dirt.

Move in circular motions with light pressure.

Shake the bottle for 60 seconds.

Remove residue with microfibre cloth.

Dab a small amount onto the polishing pad.

Polishing Machine
500ml Bottle
Microfibre Cloth

CONCENTRATED SHAMPOO

Description

This highly concentrated shampoo is effective for removing dirt and grime from everyday road use and cleans leaving a glossy, streak free finish.

Key Features

DESCRIPTION

Streak free finish
High gloss shine

Protective Clothing Please ensure all protective clothing is worn at all times.

Materials

Procedure

Fill the foamer canon with shampoo.

Use the jet wash to cover the car with shampoo.

Attach the foamer canon to the jet washer.

Rub over with a sponge or mit.

Spray the car with water to remove loose dirt.

Rinse with clean water and dry.

25ltr Barrel Jet Washer Sponge 5ltr Bottle

CARPET DYE

Description

An excellent way to renovate and rejuvenate a multitude of fabric and textile surfaces offering a flexible good as new finish. Touch dry in 15 minutes, re-coat where required in 20 minutes. Excellent coverage and adhesion.

DESCRIPTION

Key Features Accurate spray coverage

Carpet Dye

Protective Clothing Please ensure all protective clothing is worn at all times. Materials

Procedure

Vacuum mats thoroughly. Shake the aerosol well for even application.

Allow to dry completely before reinstalling.

Apply light, even coats from about 6 inches away.

DASH & DOOR CLEANER

Description

A silicone free, high active cleansing spray that will quickly clean and finish all vinyl, rubber & plastic interior surfaces.

Key Features

Suitable for use on multiple surfaces

DESCRIPTION

Dash & Door Cleaner
Satin finish

Protective Clothing Please ensure all protective clothing is worn at all times.

Materials

5ltr Bottle

Procedure

Pour the desired amount into the trigger bottle.

Adjust the spray pattern by turning the nozzle.

Apply directly to the surface or microfibre cloth.

Wipe with a dry cloth for a streak-free finish.

1ltr Trigger Microfibre Cloth
Funnel
Unscrew bottle cap. Place funnel into bottle.

DIESEL TREATMENT

Description

Improves engine performance. Improves cold starting.

Reduces noxious exhaust emissions. Restores injector spray patterns. Controls fuel oxidation, gum, varnish and acid formation. Lubricates and extends the life of injectors and fuel pumps.

Key Features

Increases MPG Cleans fuel system

DESCRIPTION

Protective Clothing Please ensure all protective clothing is worn at all times.

Materials

Procedure

Pour the treatment into the empty fuel tank.

Fill up with petrol to mix the treatment.

Funnel 150ml Can
Unscrew and pull the plastic tab from lid of can.
Unscrew lid of can.
Pull the plastic tab from lid of can.

ENGINE FLUSH

Description

Improves engine performance. Improves fuel economy. Helps remove sludge and varnish from all lubrication faces. Helps form a suspension or solution of contaminants assisting in optimum drainage. Contains lubricant and extreme pressure additives to provide temporary protection whilst in use. Helps prevent contamination of fresh oil.

DESCRIPTION

Key Features

Prolongs oil life

Improves performance

Protective Clothing Please ensure all protective clothing is worn at all times.

Gloves

Materials

150ml Can

Procedure

Unscrew lid of can.

Pour the product into the engine oil filler.

Pull the plastic tab from lid of can.

Idle for 10-15 minutes to circulate the flush.

Unscrew the engine oil filler cap.

Turn engine off, drain the old oil and refill.

Funnel

EXTERIOR SHINE PLUS

Description

A high active cleansing spray that will quickly clean and finish all paintwork and plastics.

Key Features Colourless

Non-staining

DESCRIPTION

Exterior

Protective Clothing Please ensure all protective clothing is worn at all times.

Gloves

Materials

500ml Aerosol Can

Procedure

Shake can thoroughly. Apply a fine mist onto paintwork and plastics.

Allow to dry for a glossy finish.

Use a microfibre cloth to spread and buff.

Microfibre Cloth

GLASS CLEANER

Description

This powerful cleaner breaks through even the toughest dirt and grime on windows and mirrors, leaving a sparkling streak free finish.

Key Features

DESCRIPTION

Fast evaporating formula
Streak free finish

Protective Clothing Please ensure all protective clothing is worn at all times.

Gloves

Materials

5ltr Bottle

Procedure

1ltr Trigger Microfibre Cloth Funnel

Pour glass cleaner from the container into spray bottle.

Apply a fine mist onto the the glass.

Buff in with a microfibre cloth.

Unscrew bottle cap. Place funnel into bottle.

HAND BARRIER CREAM

Description

This hand barrier cream is a must-have shield for your hands. Formulated to protect, nourish, and strengthen your skin, it forms a proactive defence against irritants.

Key Features

Strong molecular coating

Provides protection and nourishment for your skin

DESCRIPTION

Protective

Clothing Please ensure all protective clothing is worn at all times.

Materials

Procedure

Unscrew bottle cap. Screw on rubber nozzle. Pour product into the top of the container.

Lock the container in place. Ensure the cap is secure. Insert the container into the dispenser.

5ltr Bottle Dispenser

HAND CLEANER

Description

Advanced formulation, solvent-free heavy duty hand cleanser containing non-abrasive scrubbers for a deep-down cleaning action and moisturiser to help care for the skin. Removes ingrained oil, grease and general grime.

Key Features

Heavy duty hand cleanser

Non-abrasive scrubbers

DESCRIPTION

Hand Cleaner

Protective Clothing Please ensure all protective clothing is worn at all times.

Materials

Procedure

Unscrew bottle cap. Screw on rubber nozzle. Pour product into the top of the container.

Lock the container in place. Ensure the cap is secure. Insert the container into the dispenser.

5ltr Bottle Dispenser

INTERIOR SILK PLUS

Description

Car interior protection and seatbelt care. Fully synthetic surface care with highly lubricating microfilm. Has an anti-static effect with UV protection even on plastic and rubber.

Key Features Colourless

Excellent lubrication

DESCRIPTION

Interior

Protective

Clothing Please ensure all protective clothing is worn at all times.

Gloves

Materials

500ml Aerosol Can

Procedure

Shake thoroughly before use.

Perfect for hard to access areas.

To avoid overspray insert straw to nozzle.

Apply directly to the component.

Microfibre Cloth

LEATHER CLEANER

Description

Fast and effective cleaner for all finished leather surfaces. Leather cleaner, cleans, conditions, and protects. This pH neutral formula has a deep cleansing action whilst being gentle enough to use on interior Leather surfaces.

Note: Not suitable for untreated raw or suede leather.

Key Features

Cleans & conditions

Gentle non-abrasive formula

DESCRIPTION

Leather Cleaner

Protective Clothing Please ensure all protective clothing is worn at all times.

Materials

Procedure

Pour leather cleaner into the 1ltr bottle.

Gently clean with a cloth and let it dry.

1ltr Trigger Microfibre Cloth

Follow instructions for proper dilution ratio. Apply cleaner onto the leather surface.

Ensure the product is disposed of as per MSDS.

5ltr Bottle
Funnel

MULTI-PURPOSE CLEANER

Key Features

A heavy duty formulated product for hard surface cleaning. Effective at removing oil & dirt from engines and to assist in the removal of stains from your interior.

Description DESCRIPTION

Cleans & degreases

Powerful fast evaporating formula

Protective

Clothing Please ensure all protective clothing is worn at all times.

Materials

1ltr Trigger

Procedure

Spray directly onto the hard surface or stain.

Wipe away residue with a clean, damp cloth.

Pour the product into a clean trigger spray bottle.

25ltr Barrel
Trousers
Mask
5ltr Bottle
Microfibre Cloth
Funnel
Unscrew bottle cap. Place funnel into bottle.

PETROL TREATMENT

Description

Improves engine performance. Improves fuel economy. Cleans fuel system components. Removes lacquer, varnish and carbon deposits from injectors. Restores efficient fuel delivery to the combustion chamber. Neutralises harmful acids.

Key Features

Increases MPG Cleans fuel system

DESCRIPTION

Protective Clothing Please ensure all protective clothing is worn at all times.

Materials

Procedure

Pour the treatment into the empty fuel tank.

Fill up with petrol to mix the treatment.

Funnel
Unscrew and pull the plastic tab from lid of can.
Unscrew lid of can.
Pull the plastic tab from lid of can.

PLASTIC DRESSING - EXTERIOR

Description

This exterior plastic rubber coating helps to refreshen black plastics and rubbers as well as rejuvenate tyre walls. This product can be brushed or sponged onto the surface easily leaving a showroom finish.

DESCRIPTION

Key Features

Silicone coating
Restores plastics & trims

Protective

Clothing Please ensure all protective clothing is worn at all times.

Materials Gloves

Procedure

Pour the product into a clean trigger spray bottle.

Apply to the plastic trim or cloth.

Use a microfibre cloth and buff.

5ltr Bottle
1ltr Trigger Microfibre Cloth Funnel
Unscrew bottle cap.
Place funnel into bottle.

SCENT CYCLONE

Description

Highly effective against a wide range of bad odours such as pet odours and sulphurous smells. Scent Cyclone does not merely mask the odour with a fragrance, but forms a chemical complex with the organic odor molecules, removing them from the air.

Key Features

DESCRIPTION

Protective Clothing Please ensure all protective clothing is worn at all times.

Materials

150ml Aerosol Can

Procedure

150ml Aerosol Can

Turn car on and ensure it’s running.

Set the temp to the lowest setting.

Set fans to fastest setting. Select recycle air.

Push down the nozzle, exit the vehicle and close door.

After 10 minutes, turn car off, open doors and air out the car for 30 minutes.

SILICONE FREE TYRE DRESSING

Description

Water resistant coating has been carefully formulated for the renovation of all plastics, PVC, rubber etc. throughout your vehicle.

Key Features

Prevents cracking and ageing

dirt from tyre wall

DESCRIPTION

Repels

Protective

Clothing Please ensure all protective clothing is worn at all times.

Materials

5ltr Bottle

Procedure

Apply a fine mist onto the tyre surface.

Trigger

Pour the product into a clean trigger spray bottle.

Rub over the sidewall of the tyre, allow to dry.

1ltr
Microfibre Cloth Funnel
Unscrew bottle cap. Place funnel into bottle.

SNOW FOAM

Description

Snow Foam produces a satisfyingly thick foam, giving your car an even coating of foam. This makes sure that every inch of your car is covered in the snow foam giving an effective, deep clean. It’s ideal for heavy detailing sessions or for quickly sprucing up your car paintwork.

Key Features

Cleans & degreases

Powerful fast acting formula

DESCRIPTION

Snow Foam
Snow Foam

Protective Clothing Please ensure all protective clothing is worn at all times.

Materials

Procedure

Fill the foamer canon with snow foam.

Use the jet wash to cover the car with shampoo.

Attach the foamer canon to the jet washer.

Rub over with a sponge or mit.

Spray the car with water to remove loose dirt.

Rinse with clean water and dry.

25ltr Barrel Shoes
Trousers
Power Washer Canon
5ltr Bottle Sponge Jet Washer

TAR & GLUE REMOVER

Description DESCRIPTION

Key Features

Our high concentrated formula dissolves adhesives and tar quickly whilst not damaging the paintwork. Perfect for getting rid of all those sticky marks left by stickers and signs on paintwork.

Dissolves adhesives

Does not damage paintwork

& Glue Remover

Protective

Clothing Please ensure all protective clothing is worn at all times.

Materials

5ltr Bottle

Procedure

Spray on, allow the product to sit for a few minutes to break down residue. Trousers

1ltr Trigger Microfibre Cloth

Place funnel into bottle.

Use a cloth to remove the residue, then rinse if needed.

Pour the product into a clean trigger spray bottle.

25ltr Barrel Eyewear Shoes
Funnel
Unscrew bottle cap.

TYRE INFLATOR

Description

This product has been carefully designed to temporarily reduce the loss of air pressure from a punctured tyre in order to get you safely off the road to a repair shop for a more permanent repair, or tyre replacement if necessary.

Key Features

Seals in minutes

No tools required

DESCRIPTION

Tyre Inflator

Protective

Clothing Please ensure all protective clothing is worn at all times.

Gloves

Materials

500ml Aerosol Can

Procedure

Turn tyre so puncture is at the 6 o’clock position. least 60 seconds.

Attach nozzle from the can to the tyre valve.

Purge the full contents of the can into the tyre.

Pull the protective tab off.

Unscrew the filling hose and replace the dust cap.

TYRE DRESSING - CONCENTRATED

Description

Highly concentrated water resistant coating that has been carefully formulated to renovated tyres and exterior trim.

Key Features

Prevents cracking and ageing

Repels dirt from tyre wall

DESCRIPTION SIZE

Concentrated Tyre Dressing 5ltr

Concentrated Tyre Dressing 25ltr

Protective Clothing Please ensure all protective clothing is worn at all times.

Materials

1ltr Trigger Microfibre Cloth

Procedure

Unscrew bottle cap. Place funnel into bottle.

Apply a fine mist onto the tyre surface.

Rub over the sidewall of the tyre, allow to dry.

Pour the tyre dressing into a clean trigger spray bottle.

25ltr Barrel
5ltr Bottle
Funnel

UPHOLSTERY FOAM CLEANER

Description

Gently removes stains from carpets and upholstery. Penetrates deep into the fibres to lift stains to the surface and ease the removal of the most stubborn marks.

Key Features

Provides plenty of foam

Easy to spray on & wipe off

DESCRIPTION

Protective Clothing Please ensure all protective clothing is worn at all times.

Gloves

Materials

500ml Aerosol Can

Procedure

Shake thoroughly before use.

Use a microfibre cloth to work in the cleaner.

Apply to the entire upholstery surface.

Allow to dry.

Let the foam settle.

Microfibre Cloth

UPHOLSTERY CLEANER

Description

Gently removes stains from carpets and upholstery. Penetrates deep into the fibres to lift stains to the surface & ease the removal of the most stubborn marks.

NOTE: Due to the many variations of upholstery, always test the cleaner on a hidden area of the material to be treated before commencing stain removal.

DESCRIPTION

Key Features

Gently removes dirt & water marks

Water based solution

Protective

Clothing Please ensure all protective clothing is worn at all times.

Materials

5ltr Bottle

Procedure

1ltr Trigger

Unscrew bottle cap. Place funnel into bottle. Pour the product into bottle.

Spray over the entire upholstery surface.

Allow to dry. Use a microfibre cloth to work in the cleaner.

Microfibre Cloth
Funnel

AIR DUSTER MSDS

AIR DUSTER Safety

Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878 Issue date: 10/20/2021 Revision date: 3/25/2025 Supersedes version of: 10/20/2021 Version: 2.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product form

Product name

Product code

Vaporizer

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.2.1. Relevant identified uses

Intended for general public

1.2.2. Uses advised against No additional information available

1.3. Details of the supplier of the safety data sheet

1.4. Emergency telephone number

Emergency number : 01416335933

Country/Area

United Kingdom National Poisons Information

(Birmingham Centre) City Hospital

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Aerosol, Category 1 H222;H229

Full text of H- and EUH-statements: see section 16

Adverse physicochemical, human health and environmental effects

Pressurised container: May burst if heated. Extremely flammable aerosol.

2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP]

Hazard pictograms (CLP) : GHS02

Signal word (CLP) : Danger

Hazard statements (CLP) : H222 - Extremely flammable aerosol. H229 - Pressurised container: May burst if heated.

2.3. Other hazards

AIR DUSTER Safety Data

Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

Precautionary statements (CLP) : P102 - Keep out of reach of children.

P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P211 - Do not spray on an open flame or other ignition source.

P251 - Do not pierce or burn, even after use.

P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.

Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII

SECTION 3: Composition/information on ingredients

3.1. Substances

Not applicable

3.2. Mixtures

Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP]

PETROLEUM GASES, LIQUEFIED

CAS-No.: 68476-85-7

EC-No.: 270-704-2

EC Index-No.: 649-202-00-6

100 Flam. Gas 1, H220

Product subject to CLP Annex I, item 1.1.3.7. The disclosure rules of the components is modified in this case.

Full text of H- and EUH-statements: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures general

First-aid measures after inhalation

: If you feel unwell, seek medical advice.

: Remove person to fresh air and keep comfortable for breathing.

First-aid measures after skin contact : Wash skin with plenty of water.

First-aid measures after eye contact : Rinse eyes with water as a precaution.

First-aid measures after ingestion

: Call a poison center or a doctor if you feel unwell.

First-aid measures for first aider : First aid workers will be equipped with suitable personal protective equipment.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms/effects after inhalation

: None under normal conditions.

Symptoms/effects after skin contact : None under normal conditions.

Symptoms/effects after eye contact : None under normal conditions.

Symptoms/effects after ingestion

: None under normal conditions.

4.3. Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide.

Unsuitable extinguishing media : Do not use a heavy water stream.

AIR DUSTER Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

5.2. Special hazards arising from the substance or mixture

Fire hazard

: Extremely flammable aerosol.

Explosion hazard : Pressurised container: May burst if heated.

Hazardous decomposition products in case of fire : Toxic fumes may be released.

5.3. Advice for firefighters

Firefighting instructions

Protection during firefighting

: Fight fire from safe distance and protected location. Do not enter fire area without proper protective equipment, including respiratory protection.

: Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

General measures

6.1.1. For non-emergency personnel

Protective equipment

Emergency procedures

6.1.2. For emergency responders

Protective equipment

Emergency procedures

6.2. Environmental precautions

Avoid release to the environment.

: Stop leak if safe to do so. Notify authorities if product enters sewers or public waters. Absorb spillage to prevent material damage.

: Wear recommended personal protective equipment.

: Ventilate spillage area. No open flames, no sparks, and no smoking.

: Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection".

: Evacuate unnecessary personnel. Stop leak if safe to do so.

6.3. Methods and material for containment and cleaning up

For containment

Methods for cleaning up

Other information

6.4. Reference to other sections

For further information refer to section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Additional hazards when processed

Precautions for safe handling

Hygiene measures

: Absorb spilled material with sand or earth. Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. Stop leak without risks if possible.

: Mechanically recover the product.

: Dispose of materials or solid residues at an authorized site.

: Not expected to present a significant hazard under anticipated conditions of normal use.

: Ensure good ventilation of the work station. Wear personal protective equipment. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use.

: Do not eat, drink or smoke when using this product. Always wash hands after handling the product.

7.2. Conditions for safe storage, including any incompatibilities

Technical measures

Storage conditions

Packaging materials

: Keep in a cool, well-ventilated place away from heat.

: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F.

: Store always product in container of same material as original container.

AIR DUSTER Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

7.3. Specific end use(s)

No additional information available

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

8.1.1 National occupational exposure and biological limit values

PETROLEUM GASES, LIQUEFIED (68476-85-7)

United Kingdom - Occupational Exposure Limits

WEL TWA (OEL TWA)

< 1750 mg/m³

WEL STEL (OEL STEL) < 2180 mg/m³

8.1.2. Recommended monitoring procedures

No additional information available

8.1.3. Air contaminants formed

No additional information available

8.1.4. DNEL and PNEC

No additional information available

8.1.5. Control banding

No additional information available

8.2. Exposure controls

8.2.1. Appropriate engineering controls

Appropriate engineering controls: Ensure good ventilation of the work station.

8.2.2. Personal protection equipment

Personal protective equipment:

Wear recommended personal protective equipment. Personal protective equipment symbol(s):

8.2.2.1. Eye and face protection

Eye protection: Safety glasses

8.2.2.2. Skin protection

Skin and body protection:

Wear suitable protective clothing

Hand protection: Protective gloves

8.2.2.3. Respiratory protection

Respiratory protection:

In case of insufficient ventilation, wear suitable respiratory equipment

8.2.2.4. Thermal hazards

No additional information available

AIR DUSTER Safety Data

Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

8.2.3. Environmental exposure controls

Environmental exposure controls: Avoid release to the environment.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state

: Liquid

Colour : Colourless.

Odour : odourless.

Odour threshold

pH

: No data available

: No data available

Relative evaporation rate (butylacetate=1) : No data available

Melting point

Freezing point

Boiling point

Flash point

Auto-ignition temperature

Decomposition temperature

Flammability (solid, gas)

Vapour pressure

Relative vapour density at 20°C

Relative density

Solubility

: Not applicable

: No data available

: No data available

: < 23 °C

: No data available

: No data available

: Extremely flammable aerosol.

: No data available

: No data available

: No data available

: No data available

Partition coefficient n-octanol/water (Log Pow) : No data available

Viscosity, kinematic

Viscosity, dynamic

Explosive properties

Oxidising properties

Explosive limits

9.2. Other information

No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity

: No data available

: No data available

: Pressurised container: May burst if heated.

: No data available

: No data available

Extremely flammable aerosol. Pressurised container: May burst if heated.

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

No dangerous reactions known under normal conditions of use.

10.4. Conditions to avoid

Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition.

10.5. Incompatible materials

No additional information available

10.6. Hazardous decomposition products

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

AIR DUSTER Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity (oral)

Acute toxicity (dermal)

Acute toxicity (inhalation)

Skin corrosion/irritation

Serious eye damage/irritation

Respiratory or skin sensitisation

Germ cell mutagenicity

Carcinogenicity

Reproductive toxicity

STOT-single exposure

STOT-repeated exposure

Aspiration hazard

: Not classified

: Not classified

: Not classified

: Not classified

: Not classified

: Not classified

: Not classified

: Not classified

: Not classified

: Not classified

: Not classified

: Not classified

SUPAGARD STONEACRE AIR DUSTER - ZAD500MLAEROSTONE NPD11022

Vaporizer Aerosol

SECTION 12: Ecological information

12.1. Toxicity

Ecology - general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment.

Hazardous to the aquatic environment, short–term (acute) : Not classified

Hazardous to the aquatic environment, long–term (chronic) : Not classified

12.2. Persistence and degradability

SUPAGARD STONEACRE AIR DUSTER - ZAD500MLAEROSTONE NPD11022

Persistence and degradability Not rapidly degradable

PETROLEUM GASES, LIQUEFIED (68476-85-7)

Persistence and degradability Not rapidly degradable

12.3. Bioaccumulative potential

No additional information available

12.4. Mobility in soil

No additional information available

12.5. Results of PBT and vPvB assessment

No additional information available

12.6. Other adverse effects

No additional information available

AIR DUSTER

Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Regional waste regulation

: Disposal must be done according to official regulations.

Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions.

Sewage disposal recommendations : Disposal must be done according to official regulations.

Product/Packaging disposal recommendations : Disposal must be done according to official regulations.

Additional information : Do not re-use empty containers.

SECTION 14: Transport information

In accordance with ADR

14.1. UN number

14.2. UN proper shipping name

Transport document description UN 1950 AEROSOLS, 2.1, (D)

14.3. Transport hazard class(es)

14.4. Packing group

14.5. Environmental hazards

No supplementary information available

14.6. Special precautions for user

Overland transport

Not applicable

Dangerous for the environment: No

Classification code (ADR) : 5F

Special provisions (ADR) : 190, 327, 344, 625

Limited quantities (ADR) : 1l

Excepted quantities (ADR) : E0

Packing instructions (ADR) : P207, LP200

Special packing provisions (ADR) : PP87, RR6, L2

Mixed packing provisions (ADR) : MP9

Transport category (ADR) : 2

Special provisions for carriage - Packages (ADR) : V14

Special provisions for carriage - Loading, unloading and handling (ADR) : CV9, CV12

Special provisions for carriage - Operation (ADR) : S2

Tunnel restriction code (ADR) : D

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

Not applicable

AIR DUSTER Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1. EU-Regulations

REACH Annex XVII (Restriction List)

Contains no substance(s) listed on REACH Annex XVII (Restriction Conditions)

REACH Annex XIV (Authorisation List)

Contains no substance(s) listed on REACH Annex XIV (Authorisation List)

REACH Candidate List (SVHC)

Contains no substance(s) listed on the REACH Candidate List

PIC Regulation (Prior Informed Consent)

Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)

POP Regulation (Persistent Organic Pollutants)

Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)

Ozone Regulation (2024/590)

Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 2024/590 on substances that deplete the ozone layer)

Council Regulation (EC) for the control of dual-use items

Contains no substance subject to the COUNCIL REGULATION (EC) for the control of dual-use items

Explosives Precursors Regulation (2019/1148)

Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)

Drug Precursors Regulation (273/2004)

Contains no substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain substances used in the illicit manufacture of narcotic drugs and psychotropic substances)

15.1.2. National regulations No additional information available

15.2. Chemical safety assessment

No chemical safety assessment has been carried out

SECTION 16: Other information

Abbreviations and acronyms:

ACGIH American Conference of Government Industrial Hygienists

ADN European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways

ADR European Agreement concerning the International Carriage of Dangerous Goods by Road

ATE Acute Toxicity Estimate

BCF Bioconcentration factor

BLV Biological limit value

BOD Biochemical oxygen demand (BOD)

CAS-No. Chemical Abstract Service number

CLP Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008

COD Chemical oxygen demand (COD)

CSA Chemical safety assessment

AIR DUSTER Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

Abbreviations and acronyms:

DMEL Derived Minimal Effect level

DNEL Derived-No Effect Level

EC-No. European Community number

EC50 Median effective concentration

ED Endocrine disruptor

EN European Standard

EWC European waste catalogue

IARC International Agency for Research on Cancer

IATA International Air Transport Association

IMDG International Maritime Dangerous Goods

LC50 Median lethal concentration

LD50 Median lethal dose

LOAEL Lowest Observed Adverse Effect Level

Log Kow Partition coefficient n-octanol/water (Log Kow)

Log Pow Partition coefficient n-octanol/water (Log Pow)

MAK maximum workplace concentration

NOAEC No-Observed Adverse Effect Concentration

NOAEL No-Observed Adverse Effect Level

NOEC No-Observed Effect Concentration

N.O.S. Not Otherwise Specified

OECD Organisation for Economic Co-operation and Development

OEL Occupational Exposure Limit

OSHA Occupational Safety Health Administration

PBT Persistent Bioaccumulative Toxic

PNEC Predicted No-Effect Concentration

PPE Personal protection equipment

RID Regulations concerning the International Carriage of Dangerous Goods by Rail

SDS Safety Data Sheet

STP Sewage treatment plant

TF Technical function

ThOD Theoretical oxygen demand (ThOD)

TLM Median Tolerance Limit

TWA Time Weighted Average

VOC Volatile Organic Compounds

vPvB Very Persistent and Very Bioaccumulative

UFI Unique Formula Identifier

AIR DUSTER Safety Data

Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

Full text of H- and EUH-statements:

Flam. Gas 1 Flammable gases, Category 1

H220

Extremely flammable gas.

H222 Extremely flammable aerosol.

H229 Pressurised container: May burst if heated.

Safety Data Sheet (SDS), EU

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

AIR FRESHENER RANGE

MSDS

SAFETY DATA SHEET

according to Regulation (EU) 2020/878

Cherry Air Freshener

SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking

1.1.Productidentifier

Productname Cherry Air Freshener

1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst

ProductUse

[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC3]Aircare products;

[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC3]Aircareproducts;

Description CherryAirFreshener.

1.3.Detailsofthesupplierofthesafetydatasheet

Company SUPAGARDLIMITED

Address 19-27GavintonStreet Muirend Glasgow G443EF

Web www.supagard.com

Telephone 01416335933

Fax 01416377219

Email James.Smyth@supagard.com

Emailaddressofthe competentperson James.Smyth@supagard.com

1.4.Emergencytelephonenumber

Emergencytelephonenumber01416335933 8.30amto5.00pm

FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)

Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org

SECTION2:Hazardsidentification

2.1.Classificationofthesubstanceormixture

2.1.2.Classification-EC 1272/2008 Thisproductdoesnotmeetthecriteriaforclassificationinanyhazardclassaccordingto Regulation(EC)No.1272/2008onclassification,labellingandpackagingofsubstancesand mixtures.

2.2.Labelelements

PrecautionaryStatement: Prevention P102-Keepoutofreachofchildren.

PrecautionaryStatement: Response P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.

2.2.Labelelements

Cherry Air Freshener

P337+P313-Ifeyeirritationpersists:Getmedicaladvice/attention.

HazardStatement NoSignificantHazard

SUPPLEMENTALHAZARD INFORMATION

IngredientsasrequiredbyRegulation(EC)No648/2004:. Lessthan5%Non-ionicSurfactants,Parfum,Preservative:Benzisothiazolinone,Benzaldehyde, Eugenol.

Contents-DenaturedEthanol,Isopropylideneglycerol.

2.3.Otherhazards

Otherhazards Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.

Furtherinformation

RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.

SECTION3:Composition/informationoningredients

3.2.Mixtures

EC1272/2008

ChemicalName

Ethanol:EthylAlcohol(Ethanol) 64-17-5200-578-601-2119457610-43

Flam.Liq.2:H225;EyeIrrit. 2:H319; 1-10% 2,2-dimethyl-1,3-dioxolan-4-ylmetha nol 100-79-8202-888-701-2120066005-66 EyeIrrit.2:H319;0-0.5%

SECTION4:Firstaidmeasures

4.1.Descriptionoffirstaidmeasures

Inhalation Movetheexposedpersontofreshair.

Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved.

Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution.

Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed

Inhalation Maycauseirritationtorespiratorysystem.

Eyecontact Maycauseirritationtoeyes.

Skincontact Maycauseskindrynessandirritation.

Ingestion Maycauseirritationtomucousmembranes.

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded TREATSYMPTOMATICALLY.

Inhalation Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.

Eyecontact Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.

Skincontact Seekmedicalattentionifirritationorsymptomspersist.

Ingestion Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.

Generalinformation

Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.

SECTION5:Firefightingmeasures

5.1.Extinguishingmedia

Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.

5.2.Specialhazardsarisingfromthesubstanceormixture

Cherry Air Freshener

5.2.Specialhazardsarisingfromthesubstanceormixture

Noneknown.

5.3.Adviceforfirefighters

Furtherinformation

Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.

Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.

SECTION6:Accidentalreleasemeasures

6.1.Personalprecautions,protectiveequipmentandemergencyprocedures

6.2.Environmentalprecautions

Wearsuitableprotectiveequipment.

Adviselocalauthoritiesiflargespillscannotbecontained.

6.3.Methodsandmaterialforcontainmentandcleaningup

Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.

6.4.Referencetoothersections

Seesection2,7,8,13forfurtherinformation.

SECTION7:Handlingandstorage

7.1.Precautionsforsafehandling

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.

7.2.Conditionsforsafestorage,includinganyincompatibilities

Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.

7.3.Specificenduse(s)

Suitablepackaging

CherryAirFreshener.

Plasticcontainers.

SECTION8:Exposurecontrols/personalprotection

8.1.Controlparameters

8.1.1.ExposureLimitValues

Ethanol:EthylAlcohol(Ethanol)

DNEL:Derivedno-effectlevel.

Occupationalexposurecontrols.

WEL8-hrlimitppm:1000

WEL8-hrlimitmg/m3:1920

WEL15minlimitppm:- WEL15minlimitmg/m3:-

WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -

Cherry Air Freshener

ExposurePattern-Workers

Ethanol:EthylAlcohol Long-term-inhalation-Systemic effects 950mg/m³

Long-term-inhalation-Local effects 1900mg/m³

ExposurePattern-Generalpopulation

Ethanol:EthylAlcohol Long-term-inhalation-Systemic effects 114mg/m³

Long-term-inhalation-Local effects 950mg/m³

Long-term-oral-Systemic effects 87mg/kg

Long-term-dermal-Systemic effects 343mg/kg

Long-term-dermal-Systemic effects 206mg/kg

8.2.Exposurecontrols

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.

8.2.1.Appropriateengineering controls

Eye/faceprotection

Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.

Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields.

SkinprotectionHandprotection Rubbergloves.

Respiratoryprotection

8.2.3.Environmentalexposure controls

Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.

Preventfurtherleakageorspillageifsafetodoso.

SECTION9:Physicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties

Cherry Air Freshener

9.1.Informationonbasicphysicalandchemicalproperties

AppearanceLiquid ColourClear

OdourPerfumes

OdourthresholdNodataavailable pH6-8

MeltingpointNodataavailable

InitialboilingpointNodataavailable EvaporationrateNodataavailable Flammability(solid,gas)Nodataavailable VapourpressureNodataavailable

RelativeVapourDensityNodataavailable Density/RelativeDensity0.995-1.01

PartitioncoefficientNodataavailable

AutoignitiontemperatureNodataavailable Viscosity<50centipoise

ExplosivepropertiesNodataavailable

OxidisingpropertiesNodataavailable SolubilitySolubleinwater

9.2.Otherinformation

ConductivityNodataavailable SurfacetensionNodataavailable

GasgroupNodataavailable BenzeneContentNodataavailable

LeadcontentNodataavailable

VOC(Volatileorganic compounds) Nodataavailable

AtomicnumberNodataavailable MassnumberNodataavailable

ChemicalSymbolNodataavailable PhysicalHalfLifeNodataavailable SpecificActivityNodataavailable ActivityNodataavailable PrincipleEmissionsBetaNodataavailable PrincipleEmissionsGammaNodataavailable PrincipleEmissionsAlphaNodataavailable PrincipleEmissionsNeutronNodataavailable

9.2.1.Informationwithregardtophysicalhazardclasses Nodataavailable.

9.2.2.Othersafetycharacteristics Nodataavailable.

10.4.Conditionstoavoid

10.5.Incompatiblematerials

Cherry Air Freshener

Protectfromfrost.

Noincompatiblegroupsnoted.

10.6.Hazardousdecompositionproducts

NoHazardousdecompositionproductswhenstoredandhandledcorrectly.

SECTION11:Toxicologicalinformation

11.1Informationonhazardclasses

Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedfromrawmaterialsupplierLD50andAcuteToxicityEstimates(ATE)asoutlinedinthe Regulation(EC)No.1272/2008(CLP)asamendedbyUKlaw.

Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

OralATE=>10,000mg/kg.

VapoursATE=>20mg/l.

Inhalation-Dust/MistATE=>20mg/l.

Skincorrosion/irritation basedonavailabledatatheclassificationcriteriaarenotmet.

Seriouseyedamage/irritationbasedonavailabledatatheclassificationcriteriaarenotmet.

Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.

Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet.

Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.

Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.

Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet.

Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.

11.1.2.Mixtures

11.1.3.HazardInformation

11.1.4.ToxicologicalInformation

Ethanol:EthylAlcohol

11.2Informationonotherhazards

Nodataavailable.

Nodataavailable.

OralRatLD50:10470.0mg/kg

InhalationRatLC50/4h:>20mg/l

Nodataavailable.

SECTION12:Ecologicalinformation

12.1.Toxicity

Ethanol:EthylAlcohol

DaphniaEC50/48h:12340.0000mg/l

GreenAlgaeEC50/48h:>100mg/l

RainbowtroutLC50/96h:13000mg/l

NOEC/EC10formarineor freshwaterorganisms 9.6000mg/l

DermalRabbitLD50:15800.0mg/kg

AlgaeEC50/72h:275mg/l

FatheadminnowsLC50/96h:14200mg/l

GoldenorfeLC50/48h:>100mg/l

12.2.Persistenceanddegradability

SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD

Cherry Air Freshener

12.2.Persistenceanddegradability guidelines.

12.3.Bioaccumulativepotential

Nodataisavailableonthisproduct. Partitioncoefficient

StoneacreCherryAirFreshenerNodataavailable

Ethanol:EthylAlcohol-0.35logP

12.4.Mobilityinsoil

Nodataisavailableonthisproduct.

12.6Endocrinedisruptingproperties

Nodataavailable.

12.7.Otheradverseeffects

Nodataisavailableonthisproduct.

SECTION13:Disposalconsiderations

13.1.Wastetreatmentmethods

Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements. Generalinformation

Disposeofincompliancewithalllocalandnationalrequirements. Disposalofpackaging

DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.

SECTION14:Transportinformation

14.1.UNnumber

14.2.UNpropershippingname

14.3.Transporthazardclass(es)

14.4.Packinggroup

14.5.Environmentalhazards

14.6.Specialprecautionsforuser

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

14.7MaritimeTransportinbulkaccordingtoIMOinstruments

Theproductisnotclassifiedasdangerousforcarriage.

SECTION15:Regulatoryinformation

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC

Cherry Air Freshener

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.AsretainedandamendedinUKlaw.

COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.Asretainedand amendedinUKlaw.

COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).AsretainedandamendedinUK law.

15.2.Chemicalsafetyassessment

Noinformationavailable.

SECTION16:Otherinformation

Otherinformation

Revision

Datasources

TextofHazardStatementsin

Section3

Furtherinformation

Thisdocumentdiffersfromthepreviousversioninthefollowingareas:. 2-SUPPLEMENTALHAZARDINFORMATION. 12-12.1.Toxicity. 16-Datasources.

GBMandatoryClassificationandLabellingList. ECHAClassificationandLabellingInventory(CLI).Keyliteraturereferencesandsourcesfordata:. SupplierSDSsforingredientscontainedinthemixture.

Flam.Liq.2:H225-Highlyflammableliquidandvapour. EyeIrrit.2:H319-Causesseriouseyeirritation.

TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.

SAFETY DATA SHEET

according to Regulation (EU) 2020/878

Fresh Linen Air Freshener

SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking

1.1.Productidentifier

Productname Fresh Linen Air Freshener

1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst

ProductUse

[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC3]Aircare products;

[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC3]Aircareproducts;

Description FreshLinenAirFreshener.

1.3.Detailsofthesupplierofthesafetydatasheet Company SUPAGARDLIMITED

Address 19-27GavintonStreet Muirend Glasgow G443EF

Web www.supagard.com

Telephone 01416335933

Fax 01416377219

Email James.Smyth@supagard.com

Emailaddressofthe competentperson James.Smyth@supagard.com

1.4.Emergencytelephonenumber

Emergencytelephonenumber01416335933 8.30amto5.00pm

FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)

Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org

SECTION2:Hazardsidentification

2.1.Classificationofthesubstanceormixture

2.1.2.Classification-EC 1272/2008 EUH208;

2.1.2.Classification-EC 1272/2008

2.2.Labelelements

Thisproductdoesnotmeetthecriteriaforclassificationinanyhazardclassaccordingto Regulation(EC)No.1272/2008onclassification,labellingandpackagingofsubstancesand mixtures.

HazardStatement EUH208-Containslinalool.Mayproduceanallergicreaction.

Fresh Linen Air Freshener

2.2.Labelelements

PrecautionaryStatement: Prevention P102-Keepoutofreachofchildren.

PrecautionaryStatement: Response

SUPPLEMENTALHAZARD INFORMATION

2.3.Otherhazards

Otherhazards

Furtherinformation

P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing. P337+P313-Ifeyeirritationpersists:Getmedicaladvice/attention.

IngredientsasrequiredbyRegulation(EC)No648/2004:.

Lessthan5%Non-ionicSurfactants,Parfum,Preservative:Benzisothiazolinone,Linalool,Hexyl Cinnamal,BenzylSalicylate,Hexamethylindanopyran,Terpineol,AmylSalicylate,Tetramethyl Acetyloctahydronaphthalenes,CitrusAurantiumPeelOil,DimethylPhenethylAcetate,Limonene, alpha-Isomethylionone.

Contents-DenaturedEthanol,2,2-dimethyl-1,3-dioxolan-4-ylmethanol,Linalool.

Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.

RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.

SECTION3:Composition/informationoningredients

3.2.Mixtures

EC1272/2008

ChemicalName

Ethanol:EthylAlcohol(Ethanol)

2,2-dimethyl-1,3-dioxolan-4-ylmetha nol

3,7-Dimethylocta-1,6-dien-3-ol

SECTION4:Firstaidmeasures

4.1.Descriptionoffirstaidmeasures

64-17-5200-578-601-2119457610-43

100-79-8202-888-701-2120066005-66

78-70-6201-134-401-2119474016-42

Inhalation Movetheexposedpersontofreshair.

Flam.Liq.2:H225;EyeIrrit. 2:H319; 1-10%

EyeIrrit.2:H319;0-0.5%

SkinIrrit.2:H315;SkinSens. 1:H317;EyeIrrit.2:H319; 0-0.5%

Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved.

Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution.

Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed

Inhalation Maycauseirritationtorespiratorysystem.

Eyecontact Maycauseirritationtoeyes.

Skincontact Maycauseskindrynessandirritation.

Ingestion Maycauseirritationtomucousmembranes.

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded TREATSYMPTOMATICALLY.

Inhalation

Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.

Eyecontact Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.

Skincontact Seekmedicalattentionifirritationorsymptomspersist.

Ingestion Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.

Generalinformation

Fresh Linen Air Freshener

Generalinformation

Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically. SECTION5:Firefightingmeasures

5.1.Extinguishingmedia

Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.

5.2.Specialhazardsarisingfromthesubstanceormixture

Noneknown.

5.3.Adviceforfirefighters

Furtherinformation

Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.

Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.

6.1.Personalprecautions,protectiveequipmentandemergencyprocedures

6.2.Environmentalprecautions

Wearsuitableprotectiveequipment.

Adviselocalauthoritiesiflargespillscannotbecontained.

6.3.Methodsandmaterialforcontainmentandcleaningup

Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.

6.4.Referencetoothersections

Seesection2,7,8,13forfurtherinformation.

SECTION7:Handlingandstorage

7.1.Precautionsforsafehandling

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.

7.2.Conditionsforsafestorage,includinganyincompatibilities

Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.

7.3.Specificenduse(s)

Suitablepackaging

FreshLinenAirFreshener.

Plasticcontainers.

SECTION8:Exposurecontrols/personalprotection

8.1.Controlparameters

8.1.1.ExposureLimitValues

Occupationalexposurecontrols.

8.1.1.ExposureLimitValues

Ethanol:EthylAlcohol(Ethanol)

Fresh Linen Air Freshener

WEL8-hrlimitppm:1000

WEL15minlimitppm:-

WEL8-hrlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: -

WEL8-hrlimitmg/m3:1920

WEL15minlimitmg/m3:-

WEL15minlimitmg/m3total inhalabledust: -

WEL15minlimitmg/m3total respirabledust: -

DNEL:Derivedno-effectlevel.

ExposurePattern-Workers

Ethanol:EthylAlcohol

Long-term-inhalation-Systemic effects 950mg/m³

Long-term-inhalation-Local effects 1900mg/m³

ExposurePattern-Generalpopulation

Ethanol:EthylAlcohol

8.2.Exposurecontrols

8.2.1.Appropriateengineering controls

Long-term-inhalation-Systemic effects 114mg/m³

Long-term-inhalation-Local effects 950mg/m³

Long-term-oral-Systemic effects 87mg/kg

Long-term-dermal-Systemic effects 343mg/kg

Long-term-dermal-Systemic effects 206mg/kg

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.

Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.

Eye/faceprotection Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields.

SkinprotectionHandprotection Rubbergloves.

Respiratoryprotection Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.

8.2.3.Environmentalexposure controls Preventfurtherleakageorspillageifsafetodoso.

SECTION9:Physicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties

Fresh Linen Air Freshener

9.1.Informationonbasicphysicalandchemicalproperties

AppearanceLiquid ColourClear

OdourPerfumes

OdourthresholdNodataavailable pH6-8

MeltingpointNodataavailable

InitialboilingpointNodataavailable

EvaporationrateNodataavailable Flammability(solid,gas)Nodataavailable VapourpressureNodataavailable

RelativeVapourDensityNodataavailable

Density/RelativeDensity1-1.01

PartitioncoefficientNodataavailable

AutoignitiontemperatureNodataavailable Viscosity<50centipoise

ExplosivepropertiesNodataavailable

OxidisingpropertiesNodataavailable SolubilitySolubleinwater

9.2.Otherinformation

ConductivityNodataavailable SurfacetensionNodataavailable GasgroupNodataavailable BenzeneContentNodataavailable

LeadcontentNodataavailable

VOC(Volatileorganic compounds) Nodataavailable

AtomicnumberNodataavailable MassnumberNodataavailable

ChemicalSymbolNodataavailable PhysicalHalfLifeNodataavailable SpecificActivityNodataavailable ActivityNodataavailable PrincipleEmissionsBetaNodataavailable PrincipleEmissionsGammaNodataavailable PrincipleEmissionsAlphaNodataavailable PrincipleEmissionsNeutronNodataavailable

9.2.1.Informationwithregardtophysicalhazardclasses Nodataavailable.

9.2.2.Othersafetycharacteristics Nodataavailable.

10.4.Conditionstoavoid

10.5.Incompatiblematerials

Fresh Linen Air Freshener

Protectfromfrost.

Noincompatiblegroupsnoted.

10.6.Hazardousdecompositionproducts

NoHazardousdecompositionproductswhenstoredandhandledcorrectly.

SECTION11:Toxicologicalinformation

11.1Informationonhazardclasses

Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedfromrawmaterialsupplierLD50andAcuteToxicityEstimates(ATE)asoutlinedinthe Regulation(EC)No.1272/2008(CLP)asamendedbyUKlaw.

Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

Skincorrosion/irritation basedonavailabledatatheclassificationcriteriaarenotmet.

Seriouseyedamage/irritationbasedonavailabledatatheclassificationcriteriaarenotmet.

Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.

Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet.

Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.

Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.

Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet.

Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.

11.1.2.Mixtures

11.1.3.HazardInformation

11.1.4.ToxicologicalInformation

Ethanol:EthylAlcohol

11.2Informationonotherhazards

Nodataavailable.

Nodataavailable.

OralRatLD50:10470.0mg/kg

InhalationRatLC50/4h:>20mg/l

Nodataavailable.

SECTION12:Ecologicalinformation

12.1.Toxicity

Ethanol:EthylAlcohol

12.2.Persistenceanddegradability

12.3.Bioaccumulativepotential

DaphniaEC50/48h:12340.0000mg/l

GreenAlgaeEC50/48h:>100mg/l

RainbowtroutLC50/96h:13000mg/l

NOEC/EC10formarineor freshwaterorganisms 9.6000mg/l

DermalRabbitLD50:15800.0mg/kg

AlgaeEC50/72h:275mg/l

FatheadminnowsLC50/96h:14200mg/l

GoldenorfeLC50/48h:>100mg/l

SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.

12.3.Bioaccumulativepotential

Fresh Linen Air Freshener

Nodataisavailableonthisproduct. Partitioncoefficient

StoneacreFreshLinenAir Freshener Nodataavailable Ethanol:EthylAlcohol-0.35logP

12.4.Mobilityinsoil

Nodataisavailableonthisproduct.

12.6Endocrinedisruptingproperties

Nodataavailable.

12.7.Otheradverseeffects

Nodataisavailableonthisproduct.

SECTION13:Disposalconsiderations

13.1.Wastetreatmentmethods

Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements. Generalinformation

Disposeofincompliancewithalllocalandnationalrequirements. Disposalofpackaging

DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.

SECTION14:Transportinformation

14.1.UNnumber

14.2.UNpropershippingname

14.3.Transporthazardclass(es)

14.4.Packinggroup

14.5.Environmentalhazards

14.6.Specialprecautionsforuser

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

14.7MaritimeTransportinbulkaccordingtoIMOinstruments

Theproductisnotclassifiedasdangerousforcarriage.

SECTION15:Regulatoryinformation

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC,

Fresh Linen Air Freshener

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture 93/105/ECand2000/21/EC.AsretainedandamendedinUKlaw.

COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.Asretainedand amendedinUKlaw.

COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).AsretainedandamendedinUK law.

15.2.Chemicalsafetyassessment

Noinformationavailable.

SECTION16:Otherinformation

Otherinformation

Revision

Datasources

TextofHazardStatementsin Section3

Furtherinformation

Thisdocumentdiffersfromthepreviousversioninthefollowingareas:. 2-SUPPLEMENTALHAZARDINFORMATION. 12-12.1.Toxicity. 16-Datasources.

Keyliteraturereferencesandsourcesfordata:. ECHAClassificationandLabellingInventory(CLI).GBMandatoryClassificationandLabellingList. SupplierSDSsforingredientscontainedinthemixture.

Flam.Liq.2:H225-Highlyflammableliquidandvapour.

EyeIrrit.2:H319-Causesseriouseyeirritation.

SkinIrrit.2:H315-Causesskinirritation.

SkinSens.1:H317-Maycauseanallergicskinreaction.

TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.

SAFETYDATASHEET

accordingtoRegulation(EU)2020/878

AirFreshenerNewCarScent

SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking

1.1.Productidentifier

Productname AirFreshenerNewCarScent

Productcode QADP1215v3

1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst

ProductUse

[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC3]Aircare products;

[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC3]Aircareproducts;

Description AirFreshenerDropper.

1.3.Detailsofthesupplierofthesafetydatasheet

Company SUPAGARDLIMITED

Address 19-27GavintonStreet Muirend Glasgow G443EF

Web www.supagard.com

Telephone 01416335933

Fax 01416377219

Email James.Smyth@supagard.com

Emailaddressofthe competentperson James.Smyth@supagard.com

1.4.Emergencytelephonenumber

Emergencytelephonenumber01416335933 8.30amto5.00pm

FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)

Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org

SECTION2:Hazardsidentification

2.1.Classificationofthesubstanceormixture

2.1.2.Classification-EC 1272/2008 SkinSens.1:H317;EyeIrrit.2:H319;AquaticChronic2:H411;

2.2.Labelelements

2.2.Labelelements

Hazardpictograms

SignalWord Warning

HazardStatement

SkinSens.1:H317-Maycauseanallergicskinreaction.

EyeIrrit.2:H319-Causesseriouseyeirritation.

AquaticChronic2:H411-Toxictoaquaticlifewithlonglastingeffects.

PrecautionaryStatement: Prevention P102-Keepoutofreachofchildren.

PrecautionaryStatement: Response

SUPPLEMENTALHAZARD INFORMATION

2.3.Otherhazards

Otherhazards

Furtherinformation

P302+P352-IFONSKIN:Washwithplentyofwater/. P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.

P333+P313-Ifskinirritationorrashoccurs:Getmedicaladvice/attention.

P337+P313-Ifeyeirritationpersists:Getmedicaladvice/attention.

Ingredients-Parfum,HexylCinnamal,Limonene,Coumarin,Linalool,Eugenol,Citronellol,Benzyl benzoate.

Contains-Isopropylideneglycerol,Diethylphthalate,4-Tert-ButylcyclohexylAcetate, Dihydromyrcenol,Beta-Caryophyllene,CedrylAcetate,HexylCinnamal,Limonene,Coumarin, 2-T-Butylcyclohexyloxybutanol,LinalylAcetate,Linalool,Eugenol, Trimethyl-Propylcyclohexanepropanol,Beta-Pinenes.

Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.

RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.

SECTION3:Composition/informationoningredients

3.2.Mixtures

3.2.Mixtures

EC1272/2008

ChemicalName IndexNo.

2,2-dimethyl-1,3-dioxolan-4-ylmetha nol

Diethylphthalate

4-tert-Butylcyclohexylacetate

2,6-Dimethyloct-7-en-2-ol

4,11,11-Trimethyl-8-methylenebicyc lo[7.2.0]undec-4-ene

[3R-(3α,3aβ,6α,7β,8aα)] -octahydro-3,6,8,8-tetramethyl-1H-3 a,7-methanoazulen-5-ylacetate

2-Benzylideneoctanal

D-Limonene

2H-Chromen-2-one

1-[(2-tert-butyl)cyclohexyloxy]-2butanol

1,5-Dimethyl-1-vinylhex-4-en-1-yl acetate

3,7-Dimethylocta-1,6-dien-3-ol

4-Allyl-2-methoxyphenol

1-(2,2,6-Trimethylcyclohexyl) -3-hexanol

6,6-Dimethyl-2-methylenebicyclo[3. 1.1]heptane

AirFreshenerNewCarScent

100-79-8202-888-701-2120066005-66

EyeIrrit.2:H319;10-20%

84-66-2201-550-601-2119486682-2720-30%

32210-23-4250-954-901-2119976286-24

18479-58-8242-362-4

87-44-5201-746-1

77-54-3201-036-1

101-86-0202-983-3

601-029-00-75989-27-5227-813-5

91-64-5202-086-7

139504-68-0412-300-2

115-95-7204-116-401-2119454789-19

78-70-6201-134-401-2119474016-42

97-53-0202-589-1

70788-30-6274-892-7

127-91-3204-872-5

SkinSens.1:H317;10-20%

SkinIrrit.2:H315;EyeIrrit.2: H319; 1-10%

Asp.Tox.1:H304;Skin Sens.1:H317;Aquatic Chronic4:H413; 1-10%

SkinSens.1:H317;Aquatic Chronic1:H410; 1-10%

SkinSens.1:H317;Aquatic Acute1:H400;Aquatic Chronic2:H411; 1-10%

Flam.Liq.3:H226;Asp.Tox. 1:H304;SkinIrrit.2:H315; SkinSens.1:H317;Aquatic Acute1:H400;Aquatic Chronic1:H410; 1-10%

AcuteTox.4:H302;Skin Sens.1:H317;Aquatic Chronic3:H412; 1-10%

EyeIrrit.2:H319;Aquatic Chronic2:H411; 1-10%

SkinIrrit.2:H315;SkinSens. 1:H317;EyeIrrit.2:H319; 0.5-1%

SkinIrrit.2:H315;SkinSens. 1:H317;EyeIrrit.2:H319; 0-0.5%

SkinSens.1:H317;EyeIrrit. 2:H319; 0-0.5%

SkinSens.1:H317;Aquatic Acute1:H400;Aquatic Chronic1:H410; 0-0.5%

Flam.Liq.3:H226;Asp.Tox. 1:H304;SkinIrrit.2:H315; SkinSens.1:H317;Aquatic Chronic1:H410; 0-0.5%

[3R-(3α,3aβ,6α,7β,8aα)]-octahydro-3,6,8,8-tetramethyl-1H-3a,7-methanoazulen-5-ylacetate,CAS No.77-54-3-MFactor(Chronic)=1.

2-Benzylideneoctanal,CASNo.101-86-0-MFactor(Acute)=1.

D-Limonene,CASNo.5989-27-5-MFactor(Acute/Chronic)=1.

1-(2,2,6-Trimethylcyclohexyl)-3-hexanol,CASNo.70788-30-6-MFactor(Acute/Chronic)=1. 6,6-Dimethyl-2-methylenebicyclo[3.1.1]heptane,CASNo.127-91-3-MFactor(Chronic)=1.

2H-Chromen-2-oneATE(Dermal,Rat)-293mg/kg.

2H-Chromen-2-oneATE(Oral,Rat)-500mg/kg.

6,6-Dimethyl-2-methylenebicyclo[3.1.1]heptaneATE(Dermal,Rat)-133848.9mg/kg.

6,6-Dimethyl-2-methylenebicyclo[3.1.1]heptaneATE(Oral,Rat)-37287.23mg/kg.

SECTION4:Firstaidmeasures

4.1.Descriptionoffirstaidmeasures

Inhalation Movetheexposedpersontofreshair. Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved. Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution. Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed Inhalation Maycauseirritationtorespiratorysystem.

AirFreshenerNewCarScent

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed Eyecontact Causesseriouseyeirritation.

Skincontact Maycauseanallergicskinreaction.

Ingestion Maycauseirritationtomucousmembranes.

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded

Inhalation Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.

Eyecontact Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.

Skincontact Seekmedicalattentionifirritationorsymptomspersist.

Ingestion Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.

Generalinformation

Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.

SECTION5:Firefightingmeasures

5.1.Extinguishingmedia

Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.

5.2.Specialhazardsarisingfromthesubstanceormixture

Noneknown.

5.3.Adviceforfirefighters

Furtherinformation

Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.

Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.

SECTION6:Accidentalreleasemeasures

6.1.Personalprecautions,protectiveequipmentandemergencyprocedures

6.2.Environmentalprecautions

Wearsuitableprotectiveequipment.

Adviselocalauthoritiesiflargespillscannotbecontained.

6.3.Methodsandmaterialforcontainmentandcleaningup

Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.

6.4.Referencetoothersections

Seesection2,7,8,13forfurtherinformation.

SECTION7:Handlingandstorage

7.1.Precautionsforsafehandling

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.

7.2.Conditionsforsafestorage,includinganyincompatibilities

Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.

7.3.Specificenduse(s)

AirFreshenerDropper.

Suitablepackaging

Plasticcontainers.

SECTION8:Exposurecontrols/personalprotection

8.1.Controlparameters

8.1.1.ExposureLimitValues

1-

(3-Methoxypropoxy)propan-1-ol ((2-methoxymethylethoxy) propanol)

6,6-Dimethyl-2-methylenebicyclo [3.1.1]heptane

Occupationalexposurecontrols.

WEL8-hrlimitppm:50

WEL15minlimitppm:-

WEL8-hrlimitmg/m3:308

WEL15minlimitmg/m3:-

WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -

WEL8-hrlimitppm:25

WEL15minlimitppm:50

Diethylphthalate

DNEL:Derivedno-effectlevel.

ExposurePattern-Workers

1(3-Methoxypropoxy)propan-1-ol

WEL8-hrlimitmg/m3:140

WEL15minlimitmg/m3:300

WEL8-hrlimitmg/m3total inhalabledust: WEL15minlimitmg/m3total inhalabledust:

WEL8-hrlimitmg/m3total respirabledust: WEL15minlimitmg/m3total respirabledust:

WEL8-hrlimitppm:-

WEL15minlimitppm:-

WEL8-hrlimitmg/m3:5

WEL15minlimitmg/m3:10

WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -

Long-term-inhalation-Systemic effects 308mg/kg

Long-term-dermal-Systemic effects 283mg/kg

ExposurePattern-Generalpopulation

1(3-Methoxypropoxy)propan-1-ol

Long-term-inhalation-Systemic effects 37.2mg/m³

Long-term-dermal-Systemic effects 121mg/kg

Long-term-oral-Systemiceffects36mg/kg

8.2.Exposurecontrols AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.

AirFreshenerNewCarScent

8.2.Exposurecontrols

8.2.1.Appropriateengineering controls

Eye/faceprotection

SkinprotectionHandprotection

Respiratoryprotection

Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.

Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields. Eyewearcomplyingwithanapprovedstandardshouldbewornifariskassessmentindicateseye contactispossible.Thefollowingprotectionshouldbeworn:Wearchemicalsplashgoggles. PersonalprotectiveequipmentforeyeandfaceprotectionshouldcomplywithEuropeanStandard EN166.

Rubbergloves.Chooseglovestoprotecthandsagainstchemicalsdependingontheconcentration andquantityofthehazardoussubstanceandspecifictoplaceofwork.Forspecialapplications, werecommendclarifyingtheresistancetochemicalsoftheaforementionedprotectivegloveswith theglovemanufacturer.

Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.

8.2.3.Environmentalexposure controls Preventfurtherleakageorspillageifsafetodoso.

SECTION9:Physicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties

AppearanceLiquid ColourClear OdourPerfumes

OdourthresholdNodataavailable pHNodataavailable MeltingpointNodataavailable

InitialboilingpointNodataavailable EvaporationrateNodataavailable Flammability(solid,gas)Nodataavailable VapourpressureNodataavailable RelativeVapourDensityNodataavailable Density/RelativeDensityNodataavailable PartitioncoefficientNodataavailable AutoignitiontemperatureNodataavailable ViscosityNodataavailable

ExplosivepropertiesNodataavailable OxidisingpropertiesNodataavailable SolubilityInsolubleinwater

9.2.Otherinformation

ConductivityNodataavailable SurfacetensionNodataavailable GasgroupNodataavailable BenzeneContentNodataavailable

LeadcontentNodataavailable VOC(Volatileorganic compounds) Nodataavailable

9.2.1.Informationwithregardtophysicalhazardclasses Nodataavailable.

9.2.2.Othersafetycharacteristics Nodataavailable.

SECTION10:Stabilityandreactivity

10.1.Reactivity

10.2.Chemicalstability

Stableundernormalconditions.

Stableundernormalconditions.

10.3.Possibilityofhazardousreactions

Nodataisavailableonthisproduct.

10.4.Conditionstoavoid

10.5.Incompatiblematerials

Noneknown.

Strongacids.Strongoxidisingagents.

10.6.Hazardousdecompositionproducts

NoHazardousdecompositionproductswhenstoredandhandledcorrectly.

SECTION11:Toxicologicalinformation

11.1Informationonhazardclasses

Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedusingthemethodsoutlinedinRegulation(EC)No1272/2008(CLP).

Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet. OralATE=>10,000mg/kg.

Inhalation-Dust/MistATE=>20mg/l.

Skincorrosion/irritation basedonavailabledatatheclassificationcriteriaarenotmet.

Seriouseyedamage/irritationEyeIrrit.2:H319-Causesseriouseyeirritation.

Respiratoryorskin sensitisation

SkinSens.1:H317-Maycauseanallergicskinreaction.

Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet.

Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.

Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.

Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet.

Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.

11.1.2.Mixtures

11.1.3.HazardInformation

11.1.4.ToxicologicalInformation

1(3-Methoxypropoxy)propan-1-ol

2,2-dimethyl-1,3-dioxolan-4-ylme thanol

2H-Chromen-2-one

6,6-Dimethyl-2-methylenebicyclo [3.1.1]heptane

Nodataavailable.

Nodataavailable.

OralRatLD50:5000.0

InhalationRatLC50/4h:3.35

DermalRatLD50:>2000mg/kg

InhalationRatLC50/4h:>5.11mg/l

DermalRatLD50:293mg/kg

DermalRatLD50:133848.9mg/kg

DermalRabbitLD50:9510.0

OralRatLD50:7000mg/kg

OralRatLD50:500mg/kg

OralRatLD50:37287.23mg/kg

11.2Informationonotherhazards

Nodataavailable.

SECTION12:Ecologicalinformation

12.1.Toxicity

1(3-Methoxypropoxy)propan-1-ol

2,2-dimethyl-1,3-dioxolan-4-ylme thanol

12.2.Persistenceanddegradability

12.3.Bioaccumulativepotential

Partitioncoefficient

12.4.Mobilityinsoil

DaphniaEC50/48h:1919.0000mg/l

AlgaeEC50/72h:6999

NOEC/EC10formarineor freshwaterorganisms 0.5mg/l

DaphniaEC50/48h:96.0000mg/l

FatheadminnowsLC50/96h:16.7mg/l

FishLC50/96h:10000.0000mg/l

AlgaeEC50/72h:>92mg/l

SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.

Nodataisavailableonthisproduct.

AirFreshenerNewCarScentNodataavailable1-(3-Methoxypropoxy)propan-1-ol1.01

Nodataisavailableonthisproduct.

12.5.ResultsofPBTandvPvBassessment

Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.

12.6Endocrinedisruptingproperties

Thesubstance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.

12.7.Otheradverseeffects

Nodataisavailableonthisproduct.

SECTION13:Disposalconsiderations

13.1.Wastetreatmentmethods

Generalinformation

Disposalofpackaging

Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.

Disposeofincompliancewithalllocalandnationalrequirements.

DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.

SECTION14:Transportinformation

Hazardpictograms

14.1.UNnumber

AirFreshenerNewCarScent

14.1.UNnumber UN3082

14.2.UNpropershippingname ENVIRONMENTALLYHAZARDOUSSUBSTANCE,LIQUID,N.O.S.(Contains 4-tert-Butylcyclohexylacetate)

14.3.Transporthazardclass(es)

ADR/RID 9

SubsidiaryriskIMDG 9

SubsidiaryriskIATA 9

Subsidiaryrisk -

14.4.Packinggroup

Packinggroup III

14.5.Environmentalhazards

Environmentalhazards Yes

Marinepollutant Yes

14.6.Specialprecautionsforuser Noadditionalspecialprecautions.

14.7MaritimeTransportinbulkaccordingtoIMOinstruments Notapplicable.

ADR/RID

HazardID 90

TunnelCategory (E)

IMDG

EmSCode F-AS-F

IATA

PackingInstruction(Cargo)964

Maximumquantity 450L

PackingInstruction (Passenger) 964

Maximumquantity 450L

SECTION15:Regulatoryinformation

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.

COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture

COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).

15.2.Chemicalsafetyassessment

Noinformationavailable.

SECTION16:Otherinformation

Otherinformation

Datasources ClassificationandProcedureusedtoderivetheclassificationformixturesaccordingtoRegulation (EC)No.1272/2008,asretainedandamendedinUKlaw.

SkinSens.1:H317-Maycauseanallergicskinreaction.-CalculationMethod.

EyeIrrit.2:H319-Causesseriouseyeirritation.-CalculationMethod.

AquaticChronic2:H411-Toxictoaquaticlifewithlonglastingeffects.-CalculationMethod.

TextofHazardStatementsin

Section3

Furtherinformation

EyeIrrit.2:H319-Causesseriouseyeirritation.

SkinSens.1:H317-Maycauseanallergicskinreaction.

SkinIrrit.2:H315-Causesskinirritation.

Asp.Tox.1:H304-Maybefatalifswallowedandentersairways.

AquaticChronic4:H413-Maycauselonglastingharmfuleffectstoaquaticlife.

AquaticChronic1:H410-Verytoxictoaquaticlifewithlonglastingeffects.

AquaticAcute1:H400-Verytoxictoaquaticlife.

AquaticChronic2:H411-Toxictoaquaticlifewithlonglastingeffects.

Flam.Liq.3:H226-Flammableliquidandvapour.

AcuteTox.4:H302-Harmfulifswallowed.

AquaticChronic3:H412-Harmfultoaquaticlifewithlonglastingeffects.

TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.

ALLOY WHEEL CLEANER MSDS

SAFETY DATA SHEET

according to Regulation (EU) 2020/878

Concentrated Wheel Cleaner

SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking

1.1.Productidentifier

Productname Concentrated Wheel Cleaner

1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst

ProductUse [SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC35]Washingandcleaningproducts(includingsolventbasedproducts); Description VehicleWheelCleaner.

1.3.Detailsofthesupplierofthesafetydatasheet

Company SUPAGARDLIMITED

Address 19-27GavintonStreet Muirend Glasgow G443EF

Web www.supagard.com

Telephone 01416335933

Fax 01416377219

Email James.Smyth@supagard.com

Emailaddressofthe competentperson James.Smyth@supagard.com

1.4.Emergencytelephonenumber

Emergencytelephonenumber01416335933 8.30amto5.00pm

FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)

Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org

SECTION2:Hazardsidentification

2.1.Classificationofthesubstanceormixture

2.1.2.Classification-EC 1272/2008 SkinCorr.1A:H314;

2.2.Labelelements

Hazardpictograms

SignalWord Danger

HazardStatement SkinCorr.1A:H314-Causessevereskinburnsandeyedamage.

Concentrated Wheel Cleaner

2.2.Labelelements

PrecautionaryStatement: Prevention P280-Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection.

PrecautionaryStatement: Response

P303+P361+P353-IFONSKIN(orhair):Takeoffimmediatelyallcontaminatedclothing.Rinse skinwithwater/shower.

P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.

PrecautionaryStatement: Storage P405-Storelockedup.

PrecautionaryStatement: Disposal

SUPPLEMENTALHAZARD INFORMATION

P501-Disposeofcontents/containertoanapproveddisposalsite,inaccordancewithlocal regulations.

IngredientsasrequiredbyRegulation(EC)No648/2004:. SodiumHydroxide,5-15%AmphotericSurfactants.

Contains-1-Propanaminium,3-amino-N-(carboxymethyl)-N-N-dimethyl-N-C8-C18(even numbered)acylderivs,hydroxides,innersalts,sodiumhydroxide,2-butoxyethanol.

2.3.Otherhazards

Otherhazards Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.

Furtherinformation

RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.

SECTION3:Composition/informationoningredients

3.2.Mixtures

EC1272/2008

ChemicalName IndexNo.CASNo.ECNo.

1-Propanaminium,3-amino-N(carboxymethyl) -N,N-dimethyl-,N-C8-C18(even numbered)acylderivs.,hydroxides, innersalts

SodiumHydroxide

97862-59-4931-296-801-2119488533-30

EyeDam.1:H318;Aquatic Chronic3:H412; 1-10%

1310-73-2215-185-501-2119457892-27

Met.Corr.1:H290;SkinCorr. 1A:H314; 10-20% 2-butoxyethanol

603-014-00-0111-76-2203-905-001-2119475108-36

SECTION4:Firstaidmeasures

4.1.Descriptionoffirstaidmeasures

Inhalation Movetheexposedpersontofreshair.

AcuteTox.4:H332;Acute Tox.4:H312;AcuteTox.4: H302;EyeIrrit.2:H319;Skin Irrit.2:H315; 1-10%

Eyecontact Rinseimmediatelywithplentyofwaterfor15minutesholdingtheeyelidsopen.Contactlenses shouldberemoved.

Skincontact

Removecontaminatedclothing.Washoffimmediatelywithplentyofsoapandwater.

Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.Drinkplentyofwatertodiluteingested product.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed

Inhalation Causesburns.

Eyecontact Causesburns.Riskofseriousdamagetoeyes.

Skincontact Causesburns.

Ingestion Causesburns.

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded

Inhalation

Eyecontact

Skincontact

Ingestion

Generalinformation

Movetheexposedpersontofreshair.Incaseofaccidentorifyoufeelunwell,seekmedical adviceimmediately(showthelabelwherepossible).Seekmedicalattention.Showthissafetydata sheettothedoctorinattendance.

Rinseimmediatelywithplentyofwaterfor15minutesholdingtheeyelidsopen.Contactlenses shouldberemoved.Seekmedicalattention.Showthissafetydatasheettothedoctorin attendance.

Removecontaminatedclothingimmediately.Rinseimmediatelywithplentyofwater.Seekmedical attention.Showthissafetydatasheettothedoctorinattendance.

Drink1to2glassesofwater.Seekmedicalattention.Showthissafetydatasheettothedoctorin attendance.

Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.

SECTION5:Firefightingmeasures

5.1.Extinguishingmedia

Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.

5.2.Specialhazardsarisingfromthesubstanceormixture

Burningproducesirritating,toxicandobnoxiousfumes.

5.3.Adviceforfirefighters

Furtherinformation

Wearsuitablerespiratoryequipmentwhennecessary.Firefightersshouldwearselfcontained positivepressurebreathingapparatus(SCBA)andfullturnoutgear.

Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.

SECTION6:Accidentalreleasemeasures

6.1.Personalprecautions,protectiveequipmentandemergencyprocedures

6.2.Environmentalprecautions

Wearsuitableprotectiveequipment.

Adviselocalauthoritiesiflargespillscannotbecontained.

6.3.Methodsandmaterialforcontainmentandcleaningup

Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.

6.4.Referencetoothersections

Seesection2,7,8,13forfurtherinformation.

SECTION7:Handlingandstorage

7.1.Precautionsforsafehandling

Avoidcontactwitheyesandskin.Donotbreathevapoursorspraymist.AdoptbestManual Handlingconsiderationswhenhandling,carryinganddispensing.

7.2.Conditionsforsafestorage,includinganyincompatibilities

Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.

7.3.Specificenduse(s)

VehicleWheelCleaner.

Suitablepackaging

Concentrated Wheel Cleaner

Plasticcontainers.

SECTION8:Exposurecontrols/personalprotection

8.1.Controlparameters

8.1.1.ExposureLimitValues

2-butoxyethanol

SodiumHydroxide

Occupationalexposurecontrols.

WEL8-hrlimitppm:25

WEL15minlimitppm:50

WEL8-hrlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3:123

WEL15minlimitmg/m3:101.2

WEL15minlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -

WEL8-hrlimitppm:-

WEL8-hrlimitmg/m3:WEL15minlimitppm:- WEL15minlimitmg/m3:2

WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -

DNEL:Derivedno-effectlevel.

ExposurePattern-Workers

2-butoxyethanol

SodiumHydroxide

Acuteinhalation-Systemic effects 1091mg/m³

Acuteinhalation-Localeffects246mg/m³

Long-term-inhalation-Systemic effects 98mg/m³

Acuteinhalation-Localeffects2mg/m³

Acutedermal-Localeffects2mg/m³

ExposurePattern-Generalpopulation

2-butoxyethanol

SodiumHydroxide

8.2.Exposurecontrols

Acuteinhalation-Systemic effects 426mg/m³

Acutedermal-Systemiceffects89mg/kg

Long-term-inhalation-Systemic effects 59mg/m³

Long-term-dermal-Systemic effects 75mg/kg

Long-term-inhalation-Local effects 1mg/m³

Acutedermal-Systemiceffects89mg/kg

Long-term-dermal-Systemic effects 125mg/kg

Long-term-inhalation-Local effects 1mg/m³

Acuteoral-Systemiceffects26.7mg/kg

Long-term-inhalation-Local effects 147mg/m³

Long-term-oral-Systemiceffects6.3mg/kg

Concentrated

8.2.Exposurecontrols

8.2.1.Appropriateengineering controls

Eye/faceprotection

SkinprotectionHandprotection

Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.

Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields. Eyewearcomplyingwithanapprovedstandardshouldbewornifariskassessmentindicateseye contactispossible.Thefollowingprotectionshouldbeworn:Wearchemicalsplashgoggles. PersonalprotectiveequipmentforeyeandfaceprotectionshouldcomplywithEuropeanStandard EN166.

Rubbergloves.Chooseglovestoprotecthandsagainstchemicalsdependingontheconcentration andquantityofthehazardoussubstanceandspecifictoplaceofwork.Forspecialapplications, werecommendclarifyingtheresistancetochemicalsoftheaforementionedprotectivegloveswith theglovemanufacturer.

Skinprotection-Other Wearsuitableprotectiveclothing.

Respiratoryprotection Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.

8.2.3.Environmentalexposure controls

Preventfurtherleakageorspillageifsafetodoso.

SECTION9:Physicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties

AppearanceLiquid ColourClear OdourNodataavailable OdourthresholdNodataavailable pH>11.5

MeltingpointNodataavailable InitialboilingpointNodataavailable FlashpointNodataavailable EvaporationrateNodataavailable Flammability(solid,gas)Nodataavailable VapourpressureNodataavailable RelativeVapourDensityNodataavailable Density/RelativeDensity1.008-1.15

PartitioncoefficientNodataavailable AutoignitiontemperatureNotapplicable. Viscosity<75centipoise ExplosivepropertiesNodataavailable OxidisingpropertiesNodataavailable SolubilitySolubleinwater

9.2.Otherinformation

ConductivityNodataavailable SurfacetensionNodataavailable GasgroupNodataavailable BenzeneContentNodataavailable LeadcontentNodataavailable VOC(Volatileorganic compounds) Nodataavailable

9.2.1.Informationwithregardtophysicalhazardclasses Nodataisavailableonthisproduct.

9.2.2.Othersafetycharacteristics

9.2.2.Othersafetycharacteristics

Concentrated Wheel Cleaner

Nodataisavailableonthisproduct.

SECTION10:Stabilityandreactivity

10.1.Reactivity

10.2.Chemicalstability

Stableundernormalconditions.

Stableundernormalconditions.

10.3.Possibilityofhazardousreactions

Strongacids.Strongoxidisingagents.

10.4.Conditionstoavoid

10.5.Incompatiblematerials

Protectfromfrost.AvoidstoringindirectSunLight.

Strongacids.Strongoxidisingagents.

10.6.Hazardousdecompositionproducts

NoHazardousdecompositionproductswhenstoredandhandledcorrectly.

SECTION11:Toxicologicalinformation

11.1Informationonhazardclasses

Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedusingthemethodsoutlinedinRegulation(EC)No1272/2008(CLP).

Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

OralATE=>10,000mg/kg.

DermalATE=>10,000mg/kg.

Inhalation-Dust/MistATE=275mg/l.

Skincorrosion/irritation SkinCorr.1A:H314-Causessevereskinburnsandeyedamage.ExtremepH-≥11.5.

Seriouseyedamage/irritationCausesseriouseyedamage.

Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.

Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet. Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.

Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.

Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet.

Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.

11.1.2.Mixtures

11.1.3.HazardInformation

11.1.4.ToxicologicalInformation

2-butoxyethanol

SodiumHydroxide

Nodataavailable.

Nodataavailable.

InhalationRatLC50/1h:>3.1mg/l

OralRatLD50:1200mg/kg

OralRatLD50:>500mg/kg (Rabbit)

DermalRatLD50:>2000mg/kg

InhalationRatLC50/4h:11.0mg/l (vapours)

Concentrated

11.2Informationonotherhazards

Nodataisavailableonthisproduct.

SECTION12:Ecologicalinformation

12.1.Toxicity

2-butoxyethanol

12.2.Persistenceanddegradability

12.3.Bioaccumulativepotential

Partitioncoefficient

12.4.Mobilityinsoil

DaphniaEC50/48h:1550.0000mg/l

RainbowtroutLC50/96h:1474mg/l

DaphniaEC50/48h:40.4000mg/l

RainbowtroutLC50/96h:45.5mg/l

AlgaeEC50/72h:1840mg/

FishLC50/96h:33.0000mg/l

BluegillsunfishLC50/96h:125mg/l

SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.

Theproductisnotbioaccumulating.

StoneacreConcentratedWheel Cleaner Nodataavailable SodiumHydroxideNodataavailable 2-butoxyethanol0.81logP

Thisproductissolubleinwater.

12.5.ResultsofPBTandvPvBassessment

Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.

12.6Endocrinedisruptingproperties

Nodataisavailableonthisproduct.

12.7.Otheradverseeffects

Nodataisavailableonthisproduct.

SECTION13:Disposalconsiderations

13.1.Wastetreatmentmethods

Generalinformation

Disposalofpackaging

Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.

Disposeofincompliancewithalllocalandnationalrequirements.

DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.

SECTION14:Transportinformation

Hazardpictograms

Concentrated

14.1.UNnumber

14.2.UNpropershippingname

14.3.Transporthazardclass(es)

UN1760

CORROSIVELIQUID,N.O.S.(ContainsSodiumHydroxide)

ADR/RID 8

SubsidiaryriskIMDG 8

SubsidiaryriskIATA 8

Subsidiaryrisk -

14.4.Packinggroup

Packinggroup II

14.5.Environmentalhazards

Environmentalhazards No Marinepollutant No

14.6.Specialprecautionsforuser Noadditionalspecialprecautions.

14.7MaritimeTransportinbulkaccordingtoIMOinstruments Notapplicable.

ADR/RID

HazardID 80

TunnelCategory (E)

IMDG

EmSCode F-AS-B

IATA

PackingInstruction(Cargo)855

Maximumquantity 30L

PackingInstruction (Passenger) 851

Maximumquantity 1L

SECTION15:Regulatoryinformation

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.

COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.

Concentrated

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture

COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).

15.2.Chemicalsafetyassessment

Noinformationavailable.

SECTION16:Otherinformation

Otherinformation

Revision

Thisdocumentdiffersfromthepreviousversioninthefollowingareas:.

9-9.1.Informationonbasicphysicalandchemicalproperties(Density/RelativeDensity). 9-9.1.Informationonbasicphysicalandchemicalproperties(Viscosity).

Datasources ClassificationandProcedureusedtoderivetheclassificationformixturesaccordingtoRegulation (EC)No.1272/2008,asretainedandamendedinUKlaw.

TextofHazardStatementsin

Section3

Furtherinformation

SkinCorr.1A:H314-Causessevereskinburnsandeyedamage.-ExtremepH-≥11.5.

EyeDam.1:H318-Causesseriouseyedamage.

AquaticChronic3:H412-Harmfultoaquaticlifewithlonglastingeffects.

Met.Corr.1:H290-Maybecorrosivetometals.

SkinCorr.1A:H314-Causessevereskinburnsandeyedamage.

AcuteTox.4:H302+H312+H332-Harmfulifswallowed,incontactwithskinorifinhaled

SkinIrrit.2:H315-Causesskinirritation.

EyeIrrit.2:H319-Causesseriouseyeirritation.

TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.

ATMOSPHERIC SANITISER

MSDS

SAFETY DATASHEET

AIR CON SANITISER LINEN Page: 1

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name: AIR CON SANITISER LINEN

Product code: HC8523

Synonyms: PD1000

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of substance / mixture: Aerosol air freshener.

1.3. Details of the supplier of the safetydata sheet

Companyname: SUPAGARD LIMITED

23 Gavinton Street

Muirend Glasgow Scotland G44 3EF

Tel: 0141 633 5933

Email: james@supagard.co.uk

1.4. Emergencytelephone number

Emergencytel: 0141 633 5933 (office hours only)

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Classification under CLP: Flam. Aerosol 1: H222; -: H229

Compilation date: 28/02/2024

Revision No: 1

Most important adverse effects: Extremely flammable aerosol. Pressurised container: May burst if heated.

2.2. Label elements

Label elements:

Hazard statements: H222: Extremely flammable aerosol.

H229: Pressurised container: May burst if heated.

Hazard pictograms: GHS02: Flame

Signal words: Danger

Precautionarystatements: P102: Keep out of reach of children. P261: Avoid breathing spray.

AIR CON SANITISER LINEN

P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P211: Do not spray on an open flame or other ignition source.

P251: Do not pierce or burn, even after use.

P410+P412: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.

P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Haz. ingredients (label): Contains: LIQUIFIED PETROLEUMGAS PROPELLANT

2.3. Other hazards

Other hazards: In use, may form flammable / explosive vapour-air mixture. Contains no PBT/vPvB substances >/= 0.1% assessed in accordance with REACH AnnexXIII. This mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine distrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0.1%.

PBT: This product is not identified as a PBT/vPvB substance.

Section 3: Composition/information on ingredients

3.2. Mixtures

Hazardous ingredients:

ETHANOL - REACH registered number(s): 01-2119457610-43-XXXX

64-17-5 Substance with a Community workplace exposure limit.

Liq. 2: H225

<0.1% 1,3 BUTADIENE - REACH registered number(s): 01-2119474691-32-XXXX 203-448-7 106-97-8 Substance with a Community workplace exposure limit. Flam. Gas 1: H220; Press. Gas: H280 10-30% PROPANE, <0.1% 1,3 BUTADIENE - REACH registered number(s): 01-2119486944-21-XXXX

200-827-9 74-98-6

Substance with a Community workplace exposure limit. Flam. Gas 1: H220; Press. Gas: H280 10-30%

AIR CON SANITISER LINEN

N-(3-AMINOPROPYL)-N-DODECYLPROPANE-1,3,DIAMINE - REACH registered number(s): 01-2119980592-29

219-145-8

2372-82-9 -

Section 4: First aid measures

4.1. Description of first aid measures

Acute Tox. 3: H301; Skin Corr. 1B: H314; Eye Dam. 1: H318; STOT RE 2: H373; Aquatic Acute 1: H400; Aquatic Chronic 1: H410

Skin contact: Wash immediately with plenty of soap and water.

Eye contact: Bathe the eye with running water for 15 minutes.

Ingestion: Wash out mouth with water.

Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so.

4.2. Most important symptoms and effects, both acute and delayed

Skin contact: There may be mild irritation at the site of contact.

Eye contact: There may be irritation and redness.

Ingestion: There may be irritation of the throat.

Inhalation: No symptoms.

4.3. Indication of anyimmediate medical attention and special treatment needed

Immediate / special treatment: Not applicable.

Section 5: Fire-fighting measures

5.1. Extinguishing media

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers.

5.2. Special hazards arising from the substance or mixture

Exposure hazards: In combustion emits toxic fumes.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergencyprocedures

Personal precautions: Refer to section 8 of SDS for personal protection details. Turn leaking containers leakside up to prevent the escape of liquid.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

AIR CON SANITISER LINEN

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method.

6.4. Reference to other sections

Reference to other sections: Refer to section 8 of SDS.

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements: Smoking is forbidden. Use non-sparking tools. Ensure there is sufficient ventilation of the area. Do not handle in a confined space.

7.2. Conditions for safe storage, including anyincompatibilities

Storage conditions: Store in a cool, well ventilated area. Keep container tightly closed.

7.3. Specific end use(s)

Specific end use(s): No data available.

Section 8: Exposure controls/personal protection

8.1. Control parameters

Hazardous ingredients:

DNEL/PNEC Values

Hazardous ingredients:

AIR CON SANITISER LINEN

DNEL Dermal 0.54mg/kg bw/day

Consumers Systemic

DNEL Oral 0.2mg/kg bw/day Consumers Systemic

PNEC Fresh water 0.001mg/L - -

PNEC Marine water 0.0001mg/L

PNEC Fresh water sediments 8.5mg/kg dry weight

PNEC Marine sediments 0.85mg/kg dry weight

PNEC Soil (agricultural) 45.34mg/kg dry weigh

PNEC Microorganisms in sewage treatment 1.33mg/L

8.2. Exposure controls

Engineering measures: Ensure there is sufficient ventilation of the area. Ensure lighting and electrical equipment are not a source of ignition.

Respiratoryprotection: Respiratory protection not required.

Hand protection: Protective gloves.

Eye protection: Safety glasses. Ensure eye bath is to hand.

Skin protection: Protective clothing.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State: Aerosol

Colour: Colourless

Odour: Perfumed

Evaporation rate: Fast

Solubilityin water: Soluble

Viscosity: Non-viscous

Boiling point/range°C: No data available.

Melting point/range°C: No data available.

Flammabilitylimits %:lower: 0.9 upper: 9.0

Flash point°C: -40

Autoflammability°C: >230

Relative density: No data available.

VOC g/l: No data available.

9.2. Other information

Other information: No data available.

Section 10: Stabilityand reactivity

10.1. Reactivity

Part.coeff. n-octanol/water: Not applicable.

Vapour pressure: No data available.

pH: Not applicable.

Reactivity: Stable under recommended transport or storage conditions.

10.2. Chemical stability

AIR CON SANITISER LINEN

Chemical stability: Stable under normal conditions.

10.3. Possibilityof hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions. Decomposition may occur on exposure to conditions or materials listed below.

10.4. Conditions to avoid

Conditions to avoid: Heat.

10.5. Incompatible materials

Materials to avoid: Strong oxidising agents. Strong acids.

10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

Section 11: Toxicological information

11.1. Information on toxicological effects

Hazardous ingredients:

Toxicityvalues: No data available.

Symptoms / routes of exposure

Skin contact: There may be mild irritation at the site of contact.

Eye contact: There may be irritation and redness.

Ingestion: There may be irritation of the throat.

Inhalation: No symptoms.

Section 12: Ecological information

12.1. Toxicity

Hazardous ingredients:

AIR CON SANITISER LINEN

N-(3-AMINOPROPYL)-N-DODECYLPROPANE-1,3,DIAMINE

Daphnia magna

GREEN ALGA (Selenastrum capricornutum)

ZEBRAFISH (Brachydanio rerio)

12.2. Persistence and degradability

Persistence and degradability: Biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: No bioaccumulation potential.

12.4. Mobilityin soil

Mobility: Readily absorbed into soil.

12.5. Results of PBT and vPvB assessment

EC50

ErC50

LC50

mg/l

mg/l

PBT identification: This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects: Negligible ecotoxicity.

Section 13: Disposal considerations

13.1. Waste treatment methods

Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.

Recoveryoperations: Recycling/reclamation of metals and metal compounds.

Waste code number: 16 05 05

Disposal of packaging: Dispose of as normal industrial waste. Empty cans must not be burned because of explosion hazard.

NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.

Section 14: Transport information

14.1. UN number

UN number: UN1950

14.2. UN proper shipping name

Shipping name: AEROSOLS

14.3. Transport hazard class(es)

Transport class: 2

14.4. Packing group

14.5. Environmental hazards

Environmentallyhazardous: No

14.6. Special precautions for user

AIR

Special precautions: No special precautions.

Tunnel code: D

Transport category: 2

Section 15: Regulatoryinformation

Marine pollutant: No

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Specific regulations: This product is not, nor does it contain a persistant organic pollutant (POP) according to Regulation (EC) 2019/1021 and subsequent revisions. This product is not, nor does it contain any candidate on the REACH SVHC list acording to Regulation (EC) 2006/1907 and subsequent revisions. This product is not, nor does it contain, any candidate on the Endocrine Disruptor list, and any subsequent revisions, classified for human health cat 2 or environmental cat 2, in accordance with EC1272/2008 (ammended 2022)

15.2. Chemical SafetyAssessment

Chemical safetyassessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.

Section 16: Other information

Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 2015/830.

All substances in this preparation are registered within UK/EU/EFTA countries under the REACH (UK/EC) (ammended) regulations, EC 1907/2006

*indicates text in the SDS which has changed since the last revision.

Phrases used in s.2 and s.3: H220: Extremely flammable gas.

H222: Extremely flammable aerosol.

H225: Highly flammable liquid and vapour.

H229: Pressurised container: May burst if heated.

H301: Toxic if swallowed.

H314: Causes severe skin burns and eye damage.

H318: Causes serious eye damage.

H373: May cause damage to organs through prolonged or repeated exposure.

H400: Very toxic to aquatic life.

H410: Very toxic to aquatic life with long lasting effects.

Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.

AQUA FREE ENHANCER MSDS

SAFETY DATA SHEET

according to Regulation (EU) 2020/878

Aqua Free Enhancer

SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking

1.1.Productidentifier

Productname Aqua Free Enhancer

1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst

ProductUse

[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC35]Washingandcleaningproducts(includingsolventbasedproducts);

[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC35]Washingand cleaningproducts(includingsolventbasedproducts);

Description Nowaterorshampoorequired.Thisactiveblendofcrosslinkingpolymerscreatesabarriertohelp preventbuild-upoftrafficfilm.Theformulationhasbeenspeciallydevelopedtocreatelubricity, coatingparticlesofdirtandtrappingthemwithinthemicrofibrecloth,whilstleavingahighgloss finish.

1.3.Detailsofthesupplierofthesafetydatasheet

Company SUPAGARDLIMITED

Address 19-27GavintonStreet Muirend Glasgow G443EF

Web www.supagard.com

Telephone 01416335933

Fax 01416377219

Email James.Smyth@supagard.com

Emailaddressofthe competentperson James.Smyth@supagard.com

1.4.Emergencytelephonenumber

Emergencytelephonenumber01416335933

8.30amto5.00pm

FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)

Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org

SECTION2:Hazardsidentification

2.1.Classificationofthesubstanceormixture

2.1.2.Classification-EC 1272/2008 Thisproductdoesnotmeetthecriteriaforclassificationinanyhazardclassaccordingto Regulation(EC)No.1272/2008onclassification,labellingandpackagingofsubstancesand mixtures.

2.2.Labelelements

Aqua Free Enhancer

2.2.Labelelements

PrecautionaryStatement: Response P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.

P337+P313-Ifeyeirritationpersists:Getmedicaladvice/attention.

HazardStatement NoSignificantHazard

SUPPLEMENTALHAZARD INFORMATION Ingredients-Parfum. Contains-DenaturedAlcohol.

2.3.Otherhazards

Otherhazards

Furtherinformation

Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.

RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.

SECTION3:Composition/informationoningredients

3.2.Mixtures

EC1272/2008

ChemicalName

Ethanol:EthylAlcohol(Ethanol) 64-17-5200-578-601-2119457610-43

SECTION4:Firstaidmeasures

4.1.Descriptionoffirstaidmeasures

Inhalation

Movetheexposedpersontofreshair.

Flam.Liq.2:H225;EyeIrrit. 2:H319; 1-10%

Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved.

Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution.

Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed

Inhalation Maycauseirritationtorespiratorysystem.

Eyecontact Maycauseirritationtoeyes.

Skincontact Maycauseskindrynessandirritation.

Ingestion Maycauseirritationtomucousmembranes.

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded TREATSYMPTOMATICALLY.

Inhalation

Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.

Eyecontact Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.

Skincontact Seekmedicalattentionifirritationorsymptomspersist.

Ingestion Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.

Generalinformation

Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.

SECTION5:Firefightingmeasures

5.1.Extinguishingmedia

Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.

5.2.Specialhazardsarisingfromthesubstanceormixture Noneknown.

5.3.Adviceforfirefighters

Furtherinformation

Aqua Free Enhancer

Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.

Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.

SECTION6:Accidentalreleasemeasures

6.1.Personalprecautions,protectiveequipmentandemergencyprocedures

6.2.Environmentalprecautions

Wearsuitableprotectiveequipment.

Adviselocalauthoritiesiflargespillscannotbecontained.

6.3.Methodsandmaterialforcontainmentandcleaningup

Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.

6.4.Referencetoothersections

Seesection2,7,8,13forfurtherinformation.

SECTION7:Handlingandstorage

7.1.Precautionsforsafehandling

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.

7.2.Conditionsforsafestorage,includinganyincompatibilities

Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.

7.3.Specificenduse(s)

Suitablepackaging

Nowaterorshampoorequired.Thisactiveblendofcrosslinkingpolymerscreatesabarriertohelp preventbuild-upoftrafficfilm.Theformulationhasbeenspeciallydevelopedtocreatelubricity, coatingparticlesofdirtandtrappingthemwithinthemicrofibrecloth,whilstleavingahighgloss finish.

Plasticcontainers.

SECTION8:Exposurecontrols/personalprotection

8.1.Controlparameters

8.1.1.ExposureLimitValues

Ethanol:EthylAlcohol(Ethanol)

DNEL:Derivedno-effectlevel.

ExposurePattern-Workers

Occupationalexposurecontrols.

WEL8-hrlimitppm:1000

WEL8-hrlimitmg/m3:1920

WEL15minlimitppm:- WEL15minlimitmg/m3:-

WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust:WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -

Aqua Free Enhancer

ExposurePattern-Workers

Ethanol:EthylAlcohol Long-term-inhalation-Systemic effects 950mg/m³

Long-term-inhalation-Local effects 1900mg/m³

ExposurePattern-Generalpopulation

Ethanol:EthylAlcohol Long-term-inhalation-Systemic effects 114mg/m³

Long-term-inhalation-Local effects 950mg/m³

Long-term-oral-Systemic effects 87mg/kg

Long-term-dermal-Systemic effects 343mg/kg

Long-term-dermal-Systemic effects 206mg/kg

8.2.Exposurecontrols

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.

8.2.1.Appropriateengineering controls

Eye/faceprotection

Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.

Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields.

SkinprotectionHandprotection Rubbergloves.

Respiratoryprotection

8.2.3.Environmentalexposure controls

Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.

Preventfurtherleakageorspillageifsafetodoso.

SECTION9:Physicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties

Aqua Free Enhancer

9.1.Informationonbasicphysicalandchemicalproperties

AppearanceLiquid

ColourOffwhite

OdourPerfumes

OdourthresholdNodataavailable pH5.8-7.8

MeltingpointNotapplicable.

InitialboilingpointNodataavailable Flashpoint62°C

EvaporationrateNodataavailable Flammability(solid,gas)Notapplicable.

VapourpressureNodataavailable RelativeVapourDensityNodataavailable Density/RelativeDensity0.98-1g/cm3

PartitioncoefficientNodataavailable

AutoignitiontemperatureNodataavailable

Viscosity<50centipoise

ExplosivepropertiesNodataavailable OxidisingpropertiesNodataavailable SolubilitySolubleinwater

9.2.Otherinformation

ConductivityNodataavailable SurfacetensionNodataavailable GasgroupNodataavailable

BenzeneContentNotapplicable.

LeadcontentNotapplicable.

9.2.1.Informationwithregardtophysicalhazardclasses

Nodataisavailableonthisproduct.

9.2.2.Othersafetycharacteristics

Nodataisavailableonthisproduct.

SECTION10:Stabilityandreactivity

10.1.Reactivity

10.2.Chemicalstability

Stableundernormalconditions.

Stableundernormalconditions.

10.3.Possibilityofhazardousreactions

Strongacids.Strongoxidisingagents.

10.4.Conditionstoavoid

10.5.Incompatiblematerials

Protectfromfrost.

Noincompatiblegroupsnoted.

10.6.Hazardousdecompositionproducts

NoHazardousdecompositionproductswhenstoredandhandledcorrectly.

SECTION11:Toxicologicalinformation

11.1Informationonhazardclasses

Aqua Free Enhancer

11.1Informationonhazardclasses

Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedusingthemethodsoutlinedinRegulation(EC)No1272/2008(CLP).

Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet. OralATE=>10,000mg/kg.

DermalATE=>10,000mg/kg. Inhalation-Dust/MistATE=>5,000mg/l.

Skincorrosion/irritation basedonavailabledatatheclassificationcriteriaarenotmet. Seriouseyedamage/irritationbasedonavailabledatatheclassificationcriteriaarenotmet. Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.

Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet. Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.

Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.

Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet. Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.

11.1.2.Mixtures

11.1.3.HazardInformation

11.1.4.ToxicologicalInformation

Nodataavailable.

Nodataavailable.

Nodataavailable

11.2Informationonotherhazards

Nodataisavailableonthisproduct.

SECTION12:Ecologicalinformation

12.1.Toxicity

Nodataavailable

12.2.Persistenceanddegradability

SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.

12.3.Bioaccumulativepotential

Partitioncoefficient

12.4.Mobilityinsoil

Theproductisnotbioaccumulating.

StoneacreAquafreeEnhancerNodataavailable Ethanol:EthylAlcohol-0.35logP

Thisproductissolubleinwater.

12.5.ResultsofPBTandvPvBassessment

Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.

12.6Endocrinedisruptingproperties

Nodataisavailableonthisproduct.

12.7.Otheradverseeffects

Aqua Free Enhancer

Nodataisavailableonthisproduct.

SECTION13:Disposalconsiderations

13.1.Wastetreatmentmethods

Generalinformation

Disposalofpackaging

Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.

Disposeofincompliancewithalllocalandnationalrequirements.

DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.

SECTION14:Transportinformation

14.1.UNnumber

14.2.UNpropershippingname

14.3.Transporthazardclass(es)

14.4.Packinggroup

14.5.Environmentalhazards

14.6.Specialprecautionsforuser

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

14.7MaritimeTransportinbulkaccordingtoIMOinstruments

Theproductisnotclassifiedasdangerousforcarriage.

SECTION15:Regulatoryinformation

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations

REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.

COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.

COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).

15.2.Chemicalsafetyassessment

Noinformationavailable.

Aqua Free Enhancer

SECTION16:Otherinformation

Otherinformation

Revision

TextofHazardStatementsin Section3

Furtherinformation

Thisdocumentdiffersfromthepreviousversioninthefollowingareas:. 2-Otherhazards.

2-Furtherinformation.

2-SUPPLEMENTALHAZARDINFORMATION.

5-5.2.Specialhazardsarisingfromthesubstanceormixture. 9-9.2.2.Othersafetycharacteristics.

9-9.2.1.Informationwithregardtophysicalhazardclasses. 10-10.2.Chemicalstability.

10-10.1.Reactivity.

11-11.2Informationonotherhazards.

12-12.6Endocrinedisruptingproperties. 12-12.7.Otheradverseeffects.

15-Regulations.

Flam.Liq.2:H225-Highlyflammableliquidandvapour. EyeIrrit.2:H319-Causesseriouseyeirritation.

TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.

AQUA RINSE AID

MSDS

SAFETY DATA SHEET

according to Regulation (EU) 2020/878

Aqua Rinse Aid

SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking

1.1.Productidentifier

Productname Aqua Rinse Aid

1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst

ProductUse

[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC35]Washingandcleaningproducts(includingsolventbasedproducts);

[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC35]Washingand cleaningproducts(includingsolventbasedproducts);

Description CarRinseAid.

1.3.Detailsofthesupplierofthesafetydatasheet Company SUPAGARDLIMITED

Address 19-27GavintonStreet Muirend Glasgow G443EF

Web www.supagard.com

Telephone 01416335933

Fax 01416377219

Email James.Smyth@supagard.com

Emailaddressofthe competentperson James.Smyth@supagard.com

1.4.Emergencytelephonenumber

Emergencytelephonenumber01416335933 8.30amto5.00pm

FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)

Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org

SECTION2:Hazardsidentification

2.1.Classificationofthesubstanceormixture

2.1.2.Classification-EC 1272/2008 SkinCorr.1B:H314;AquaticChronic2:H411;

2.2.Labelelements

Hazardpictograms

2.2.Labelelements

SignalWord Danger

HazardStatement

PrecautionaryStatement: Prevention

PrecautionaryStatement: Response

PrecautionaryStatement: Disposal

SUPPLEMENTALHAZARD INFORMATION

Aqua Rinse Aid

SkinCorr.1B:H314-Causessevereskinburnsandeyedamage. AquaticChronic2:H411-Toxictoaquaticlifewithlonglastingeffects.

P102-Keepoutofreachofchildren.

P260-Donotbreathedust/fume/gas/mist/vapours/spray.

P302+P350-IFONSKIN:Gentlywashwithplentyofsoapandwater.

P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.

P501-Disposeofcontents/containertoanapproveddisposalsite,inaccordancewithlocal regulations.

IngredientsasrequiredbyRegulation(EC)No648/2004:. Preservative:Benzisothiazolinone.

Contains-Distillates(petroleum),straight-runmiddle,DicocdimethylAmmoniumChloride,2,2'(octadec-9-enylimino)bisethanol,2-(2-butoxyethoxy)ethanol(2-(2-Butoxyethoxy)ethanol).

2.3.Otherhazards

Otherhazards Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.

Furtherinformation

RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.

SECTION3:Composition/informationoningredients

3.2.Mixtures

EC1272/2008

ChemicalName

Distillates(Petroleum),straight-run middle

64741-44-2265-044-701-2119486889-09

AcuteTox.4:H302+H332; STOTRE2:H373;Aquatic Chronic2:H411; 1-10% DicocdimethylAmmoniumChloride

61789-77-3263-087-601-2119486994-16

AcuteTox.4:H302;Skin Corr.1B:H314;Aquatic Acute1:H400;Aquatic Chronic2:H411; 1-10% 2,2'(octadec-9-enylimino)bisethanol

25307-17-9246-807-3

AcuteTox.4:H302;Skin Corr.1B:H314;Aquatic Chronic1:H410;Aquatic Chronic2:H411; 1-10% 2-(2-butoxyethoxy)ethanol(2(2-Butoxyethoxy)ethanol)

603-096-00-8112-34-5203-961-6

EyeIrrit.2:H319;1-10%

2,2'(octadec-9-enylimino)bisethanol,CASNo.25307-17-9-MFactor(Acute)=10,MFactor (Chronic)=1.

SECTION4:Firstaidmeasures

4.1.Descriptionoffirstaidmeasures

Inhalation

Movetheexposedpersontofreshair.

Eyecontact Rinseimmediatelywithplentyofwaterfor15minutesholdingtheeyelidsopen.Contactlenses shouldberemoved.

Skincontact

Removecontaminatedclothing.Washoffimmediatelywithplentyofsoapandwater.

Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.Drinkplentyofwatertodiluteingested product.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed

Inhalation Maycauseirritationtorespiratorysystem. Eyecontact Causesburns.Riskofseriousdamagetoeyes.

Aqua Rinse Aid

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed

Skincontact Causesburns.

Ingestion Maycauseirritationtomucousmembranes.

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded

Inhalation

Eyecontact

Skincontact

Ingestion

Generalinformation

Movetheexposedpersontofreshair.Incaseofaccidentorifyoufeelunwell,seekmedical adviceimmediately(showthelabelwherepossible).Seekmedicalattention.Showthissafetydata sheettothedoctorinattendance.

Rinseimmediatelywithplentyofwaterfor15minutesholdingtheeyelidsopen.Contactlenses shouldberemoved.Seekmedicalattention.Showthissafetydatasheettothedoctorin attendance.

Removecontaminatedclothingimmediately.Rinseimmediatelywithplentyofwater.Seekmedical attention.Showthissafetydatasheettothedoctorinattendance.

Drink1to2glassesofwater.Seekmedicalattention.Showthissafetydatasheettothedoctorin attendance.

Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.

SECTION5:Firefightingmeasures

5.1.Extinguishingmedia

Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.

5.2.Specialhazardsarisingfromthesubstanceormixture

Burningproducesirritating,toxicandobnoxiousfumes.

5.3.Adviceforfirefighters

Furtherinformation

Wearsuitablerespiratoryequipmentwhennecessary.Firefightersshouldwearselfcontained positivepressurebreathingapparatus(SCBA)andfullturnoutgear.

Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.

SECTION6:Accidentalreleasemeasures

6.1.Personalprecautions,protectiveequipmentandemergencyprocedures

6.2.Environmentalprecautions

Wearsuitableprotectiveequipment.

Adviselocalauthoritiesiflargespillscannotbecontained.

6.3.Methodsandmaterialforcontainmentandcleaningup

Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.

6.4.Referencetoothersections

Seesection2,7,8,13forfurtherinformation.

SECTION7:Handlingandstorage

7.1.Precautionsforsafehandling

Avoidcontactwitheyesandskin.Donotbreathevapoursorspraymist.AdoptbestManual Handlingconsiderationswhenhandling,carryinganddispensing.

7.2.Conditionsforsafestorage,includinganyincompatibilities

Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein

Aqua Rinse Aid

7.2.Conditionsforsafestorage,includinganyincompatibilities originalcontainer.

7.3.Specificenduse(s) CarRinseAid.

Suitablepackaging

Plasticcontainers.

SECTION8:Exposurecontrols/personalprotection

8.1.Controlparameters

8.1.1.ExposureLimitValues

2-(2-butoxyethoxy)ethanol(2(2-Butoxyethoxy)ethanol)

8.2.Exposurecontrols

Occupationalexposurecontrols.

WEL8-hrlimitppm:10

WEL15minlimitppm:15

8.2.1.Appropriateengineering controls

Eye/faceprotection

SkinprotectionHandprotection

Respiratoryprotection

8.2.3.Environmentalexposure controls

WEL8-hrlimitmg/m3:67.5

WEL15minlimitmg/m3:101.2

WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.

Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.

Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields. Eyewearcomplyingwithanapprovedstandardshouldbewornifariskassessmentindicateseye contactispossible.Thefollowingprotectionshouldbeworn:Wearchemicalsplashgoggles. PersonalprotectiveequipmentforeyeandfaceprotectionshouldcomplywithEuropeanStandard EN166.

Rubbergloves.Chooseglovestoprotecthandsagainstchemicalsdependingontheconcentration andquantityofthehazardoussubstanceandspecifictoplaceofwork.Forspecialapplications, werecommendclarifyingtheresistancetochemicalsoftheaforementionedprotectivegloveswith theglovemanufacturer.

Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.

Preventfurtherleakageorspillageifsafetodoso.

SECTION9:Physicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties

Aqua Rinse Aid

9.1.Informationonbasicphysicalandchemicalproperties

AppearanceLiquid ColourClear

OdourCharacteristic

InitialboilingpointNodataavailable

FlashpointNodataavailable EvaporationrateNodataavailable Flammability(solid,gas)Nodataavailable VapourpressureNodataavailable RelativeVapourDensityNodataavailable Density/RelativeDensity0.98-0.99

PartitioncoefficientNodataavailable AutoignitiontemperatureNodataavailable Viscosity<50centipoise

ExplosivepropertiesNodataavailable

OxidisingpropertiesNodataavailable

OdourthresholdNodataavailable pH7-9

MeltingpointNodataavailable SolubilitySolubleinwater

9.2.Otherinformation

ConductivityNodataavailable SurfacetensionNodataavailable GasgroupNodataavailable

BenzeneContentNodataavailable

LeadcontentNodataavailable

VOC(Volatileorganic compounds) Nodataavailable

9.2.1.Informationwithregardtophysicalhazardclasses

Nodataisavailableonthisproduct.

9.2.2.Othersafetycharacteristics

Nodataisavailableonthisproduct.

SECTION10:Stabilityandreactivity

10.1.Reactivity

10.2.Chemicalstability

Stableundernormalconditions.

Stableundernormalconditions.

10.3.Possibilityofhazardousreactions

Strongacids.Strongoxidisingagents.

10.4.Conditionstoavoid

10.5.Incompatiblematerials

Protectfromfrost.AvoidstoringindirectSunLight.

Strongacids.Strongoxidisingagents.

10.6.Hazardousdecompositionproducts

NoHazardousdecompositionproductswhenstoredandhandledcorrectly.

Aqua Rinse Aid

SECTION11:Toxicologicalinformation

11.1Informationonhazardclasses

Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedusingthemethodsoutlinedinRegulation(EC)No1272/2008(CLP).

Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet. OralATE=>10,000mg/kg.

Inhalation-Dust/MistATE=55.6044mg/l.

Skincorrosion/irritation SkinCorr.1B:H314-Causessevereskinburnsandeyedamage. Seriouseyedamage/irritationCausesseriouseyedamage.

Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.

Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet.

Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.

Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.

Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet.

Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.

11.1.2.Mixtures

11.1.3.HazardInformation

11.1.4.ToxicologicalInformation

Nodataavailable.

Nodataavailable.

Nodataavailable

11.2Informationonotherhazards

Nodataisavailableonthisproduct.

SECTION12:Ecologicalinformation

12.1.Toxicity

Nodataavailable

12.2.Persistenceanddegradability

SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.

12.3.Bioaccumulativepotential

Theproductisnotbioaccumulating.

Partitioncoefficient SupagardAquaRinseAidNodataavailable

12.4.Mobilityinsoil

Thisproductissolubleinwater.

12.5.ResultsofPBTandvPvBassessment

Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.

12.6Endocrinedisruptingproperties

Nodataisavailableonthisproduct.

12.7.Otheradverseeffects

Aqua Rinse Aid

Nodataisavailableonthisproduct.

SECTION13:Disposalconsiderations

13.1.Wastetreatmentmethods

Generalinformation

Disposalofpackaging

Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.

Disposeofincompliancewithalllocalandnationalrequirements.

DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.

SECTION14:Transportinformation

Hazardpictograms

14.1.UNnumber

14.2.UNpropershippingname

14.3.Transporthazardclass(es)

CORROSIVELIQUID,N.O.S.(ContainsMINERALSEALOIL;DICOCODIMETHYLAMMONIUM CHLORIDE;ETHOXYLATEDOLEYLAMINE)

14.5.Environmentalhazards

Environmentalhazards Yes Marinepollutant Yes

14.6.Specialprecautionsforuser

Noadditionalspecialprecautions.

14.7MaritimeTransportinbulkaccordingtoIMOinstruments

Notapplicable.

Aqua Rinse Aid

PackingInstruction(Cargo)856

Maximumquantity 60L

PackingInstruction (Passenger) 852

Maximumquantity 5L

SECTION15:Regulatoryinformation

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture

Regulations

REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.

COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.

COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).

15.2.Chemicalsafetyassessment

Noinformationavailable.

SECTION16:Otherinformation

Otherinformation

Revision

Thisdocumentdiffersfromthepreviousversioninthefollowingareas:.

2-Otherhazards.

2-Hazardpictograms.

2-Furtherinformation.

2-SUPPLEMENTALHAZARDINFORMATION.

9-9.2.2.Othersafetycharacteristics.

9-9.2.1.Informationwithregardtophysicalhazardclasses. 11-11.2Informationonotherhazards.

12-12.6Endocrinedisruptingproperties. 12-12.7.Otheradverseeffects. 15-Regulations.

Datasources ClassificationandProcedureusedtoderivetheclassificationformixturesaccordingtoRegulation (EC)No.1272/2008,asretainedandamendedinUKlaw.

SkinCorr.1B:H314-Causessevereskinburnsandeyedamage.-CalculationMethod.

AquaticChronic2:H411-Toxictoaquaticlifewithlonglastingeffects.-CalculationMethod,See Section3forapplicableMFactors.

TextofHazardStatementsin

Section3

AcuteTox.4:H302+H332-Harmfulifswallowedorifinhaled STOTRE2:H373-Maycausedamagetoorgansthroughprolongedorrepeatedexposure.

AquaticChronic2:H411-Toxictoaquaticlifewithlonglastingeffects.

AcuteTox.4:H302-Harmfulifswallowed.

SkinCorr.1B:H314-Causessevereskinburnsandeyedamage.

AquaticAcute1:H400-Verytoxictoaquaticlife.

AquaticChronic1:H410-Verytoxictoaquaticlifewithlonglastingeffects.

EyeIrrit.2:H319-Causesseriouseyeirritation.

Aqua Rinse Aid

TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.

BIRD DROPPING & BUG REMOVER MSDS

SAFETY DATA SHEET

according to Regulation (EU) 2020/878

Bird & Bug Remover

SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking

1.1.Productidentifier

Productname Bird & Bug Remover

1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst

ProductUse

[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC35]Washingand cleaningproducts(includingsolventbasedproducts);

[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC35]Washingandcleaningproducts(includingsolventbasedproducts);

Description Acombinationofsurfactantswhichneutralisetheacidinbirdlime.

1.3.Detailsofthesupplierofthesafetydatasheet

Company SUPAGARDLIMITED

Address 19-27GavintonStreet Muirend Glasgow G443EF

Web www.supagard.com

Telephone 01416335933

Fax 01416377219

Email James.Smyth@supagard.com

Emailaddressofthe competentperson

1.4.Emergencytelephonenumber

James.Smyth@supagard.com

Emergencytelephonenumber01416335933 8.30amto5.00pm

FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)

Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org

SECTION2:Hazardsidentification

2.1.Classificationofthesubstanceormixture

2.1.2.Classification-EC 1272/2008

2.2.Labelelements

Thisproductdoesnotmeetthecriteriaforclassificationinanyhazardclassaccordingto Regulation(EC)No.1272/2008onclassification,labellingandpackagingofsubstancesand mixtures.

PrecautionaryStatement: Prevention P102-Keepoutofreachofchildren.

PrecautionaryStatement: Response P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.

2.2.Labelelements

HazardStatement

SUPPLEMENTALHAZARD INFORMATION

Bird & Bug Remover

NoSignificantHazard

IngredientsasrequiredbyRegulation(EC)No648/2004:. Lessthan5%Non-ionicsurfactants.

Contains-2,2',2"-Nitrilotriethanol,Amines,C12-14(evennumbered)-alkyldimethyl,N-oxides, DenaturedEthanol,2-butoxyethanol.

2.3.Otherhazards

Otherhazards Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.

Furtherinformation

RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.

SECTION3:Composition/informationoningredients

3.2.Mixtures

EC1272/2008

ChemicalName

2,2',2''-Nitrilotriethanol

Amines,C12-14(evennumbered) -alkyldimethyl,N-oxides

Diethanolamine

Ethanol:EthylAlcohol(Ethanol)

102-71-6203-049-801-2119486482-311-10%

308062-28-4931-292-601-2119490061-47

111-42-2203-868-001-2119488930-28

64-17-5200-578-601-2119457610-43

AcuteTox.4:H302;SkinIrrit. 2:H315;EyeDam.1:H318; AquaticAcute1:H400; AquaticChronic2:H411;

AcuteTox.4:H302;SkinIrrit. 2:H315;EyeDam.1:H318; Repr.2:H361fd;STOTRE2: H373; 0-0.5%

Flam.Liq.2:H225;EyeIrrit. 2:H319; 1-10% 2-butoxyethanol

603-014-00-0111-76-2203-905-001-2119475108-36

AcuteTox.4:H332;Acute Tox.4:H312;AcuteTox.4: H302;EyeIrrit.2:H319;Skin Irrit.2:H315; 1-10%

Amines,C12-14(evennumbered)-alkyldimethyl,N-oxides(CASNo.308062-28-4)-MFactor (Acute)=1.

SECTION4:Firstaidmeasures

4.1.Descriptionoffirstaidmeasures

Inhalation

Movetheexposedpersontofreshair.

Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved.

Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution.

Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed

Inhalation Maycauseirritationtorespiratorysystem.

Eyecontact Maycauseirritationtoeyes.

Skincontact Maycauseskindrynessandirritation.

Ingestion Maycauseirritationtomucousmembranes.

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded TREATSYMPTOMATICALLY.

Inhalation Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.

Eyecontact Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.

Bird & Bug Remover

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded Skincontact Seekmedicalattentionifirritationorsymptomspersist. Ingestion Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.

Generalinformation

Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.

SECTION5:Firefightingmeasures

5.1.Extinguishingmedia

Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.

5.2.Specialhazardsarisingfromthesubstanceormixture

Noneknown.

5.3.Adviceforfirefighters

Furtherinformation

Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.

Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.

SECTION6:Accidentalreleasemeasures

6.1.Personalprecautions,protectiveequipmentandemergencyprocedures

6.2.Environmentalprecautions

Wearsuitableprotectiveequipment.

Adviselocalauthoritiesiflargespillscannotbecontained.

6.3.Methodsandmaterialforcontainmentandcleaningup

Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.

6.4.Referencetoothersections

Seesection2,7,8,13forfurtherinformation.

SECTION7:Handlingandstorage

7.1.Precautionsforsafehandling

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.

7.2.Conditionsforsafestorage,includinganyincompatibilities

Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.

7.3.Specificenduse(s)

Suitablepackaging

Acombinationofsurfactantswhichneutralisetheacidinbirdlime.

Plasticcontainers.

SECTION8:Exposurecontrols/personalprotection

8.1.Controlparameters

Occupationalexposurecontrols.

8.1.1.ExposureLimitValues

2-butoxyethanol

Ethanol:EthylAlcohol(Ethanol)

Bird & Bug Remover

WEL8-hrlimitppm:25

WEL15minlimitppm:50

WEL8-hrlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: -

WEL8-hrlimitppm:1000

WEL15minlimitppm:-

WEL8-hrlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: -

DNEL:Derivedno-effectlevel.

ExposurePattern-Workers

2,2',2''-Nitrilotriethanol

2-butoxyethanol

Ethanol:EthylAlcohol

Long-term-inhalation-Local effects 5mg/m³

Long-term-dermal-Systemic effects 6.3mg/kg

Acuteinhalation-Systemic effects 1091mg/m³

Acuteinhalation-Localeffects246mg/m³

Long-term-inhalation-Systemic effects 98mg/m³

Long-term-inhalation-Systemic effects 950mg/m³

Long-term-inhalation-Local effects 1900mg/m³

ExposurePattern-Generalpopulation

2,2',2''-Nitrilotriethanol

2-butoxyethanol

Ethanol:EthylAlcohol

8.2.Exposurecontrols

Long-term-inhalation-Local effects 1.25mg/m³

Long-term-dermal-Systemic effects 3.1mg/kg

Acuteinhalation-Systemic effects 426mg/m³

Acutedermal-Systemiceffects89mg/kg

Long-term-inhalation-Systemic effects 59mg/m³

Long-term-dermal-Systemic effects 89mg/kg

Long-term-inhalation-Systemic effects 114mg/m³

Long-term-inhalation-Local effects 950mg/m³

Long-term-oral-Systemic effects 87mg/kg

WEL8-hrlimitmg/m3:123

WEL15minlimitmg/m3:101.2

WEL15minlimitmg/m3total inhalabledust: -

WEL15minlimitmg/m3total respirabledust: -

WEL8-hrlimitmg/m3:1920

WEL15minlimitmg/m3:-

WEL15minlimitmg/m3total inhalabledust: -

WEL15minlimitmg/m3total respirabledust: -

Acutedermal-Systemiceffects89mg/kg

Long-term-dermal-Systemic effects 125mg/kg

Long-term-dermal-Systemic effects 343mg/kg

Long-term-oral-Systemiceffects13mg/kg

Acuteoral-Systemiceffects26.7mg/kg

Long-term-inhalation-Local effects 147mg/m³

Long-term-oral-Systemiceffects6.3mg/kg

Long-term-dermal-Systemic effects 206mg/kg

8.2.Exposurecontrols

8.2.1.Appropriateengineering controls

Bird & Bug Remover

appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.

Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.

Eye/faceprotection Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields.

SkinprotectionHandprotection Rubbergloves.

Respiratoryprotection Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.

8.2.3.Environmentalexposure controls Preventfurtherleakageorspillageifsafetodoso.

SECTION9:Physicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties

AppearanceLiquid

ColourClear

OdourCharacteristic

OdourthresholdNodataavailable pH8-10

MeltingpointNotapplicable.

InitialboilingpointNodataavailable

Flashpoint62°C

EvaporationrateNodataavailable

Flammability(solid,gas)Nodataavailable

VapourpressureNodataavailable

RelativeVapourDensityNodataavailable Density/RelativeDensityNodataavailable

PartitioncoefficientNodataavailable

AutoignitiontemperatureNodataavailable

Viscosity<50centipoise ExplosivepropertiesNodataavailable OxidisingpropertiesNotapplicable.

SolubilitySolubleinwater

9.2.Otherinformation

ConductivityNotapplicable. SurfacetensionNodataavailable

Specificgravity1-1.01g/cm³

GasgroupNodataavailable BenzeneContentNotapplicable. LeadcontentNotapplicable.

9.2.1.Informationwithregardtophysicalhazardclasses Nodataisavailableonthisproduct.

9.2.2.Othersafetycharacteristics Nodataisavailableonthisproduct.

SECTION10:Stabilityandreactivity

10.1.Reactivity

Stableundernormalconditions.Nospecificreactivityhazardsassociatedwiththisproduct.

10.2.Chemicalstability

Bird & Bug Remover

Stableundernormalconditions.Noparticularstabilityconcerns.

10.3.Possibilityofhazardousreactions

Strongacids.Strongoxidisingagents.

10.4.Conditionstoavoid

10.5.Incompatiblematerials

Protectfromfrost.

Noincompatiblegroupsnoted.

10.6.Hazardousdecompositionproducts

NoHazardousdecompositionproductswhenstoredandhandledcorrectly.

SECTION11:Toxicologicalinformation

11.1Informationonhazardclasses

Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedfromrawmaterialsupplierLD50andAcuteToxicityEstimates(ATE)asoutlinedinthe Regulation(EC)No.1272/2008(CLP)asamendedbyUKlaw.

Acutetoxicity

basedonavailabledatatheclassificationcriteriaarenotmet.

OralATE=>10,000mg/kg.

DermalATE=>10,000mg/kg.

Inhalation-Dust/MistATE=>20mg/l.

Skincorrosion/irritation basedonavailabledatatheclassificationcriteriaarenotmet.

Seriouseyedamage/irritationbasedonavailabledatatheclassificationcriteriaarenotmet.

Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.

Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet.

Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.

Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.

Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet.

Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.

11.1.2.Mixtures

11.1.3.HazardInformation

11.1.4.ToxicologicalInformation

2,2',2''-Nitrilotriethanol

2-butoxyethanol

Ethanol:EthylAlcohol

11.2Informationonotherhazards

Nodataavailable.

Nodataavailable.

OralRatLD50:4190mg/kg

OralRatLD50:1200mg/kg

InhalationRatLC50/4h:2.2mg/l

OralRatLD50:10470.0mg/kg

InhalationRatLC50/4h:>20mg/l

Nodataisavailableonthisproduct.

SECTION12:Ecologicalinformation

12.1.Toxicity

DermalRabbitLD50:>20,000mg/kg

DermalRabbitLD50:>2000mg/kg

DermalRabbitLD50:15800.0mg/kg

12.1.Toxicity

2,2',2''-Nitrilotriethanol

2-butoxyethanol

Ethanol:EthylAlcohol

12.2.Persistenceanddegradability

12.3.Bioaccumulativepotential

Partitioncoefficient

12.4.Mobilityinsoil

Bird & Bug Remover

GreenalgaeEC50/96h:169mg/l

FatheadminnowsLC50/96h:10600-13000 mg/l

DaphniaEC50/48h:1550.0000mg/l

Lepomis_MacrochirusLC50/96h:1490-2950mg/l

EC50formarineorfreshwater organisms >100.0000mg/l

DaphniaEC50/48h:12340.0000mg/l

GreenAlgaeEC50/48h:>100mg/l

RainbowtroutLC50/96h:13000mg/l

NOEC/EC10formarineor freshwaterorganisms 9.6000mg/l

AlgaeEC50/72h:216mg/l

Lepomis_MacrochirusLC50/96h:450-1000mg/l

AlgaeEC50/72h:911mg/l

(Pseudokirchnerie llasubcapitata)

LC50formarineorfreshwater organisms >100.0000mg/l

AlgaeEC50/72h:275mg/l

FatheadminnowsLC50/96h:14200mg/l

GoldenorfeLC50/48h:>100mg/l

SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.

Theproductisnotbioaccumulating.

ArnoldClarkBird&BugRemoverNodataavailable 2,2',2''-Nitrilotriethanol-2.53LogPow Ethanol:EthylAlcohol-0.35logP 2-butoxyethanol0.81logP

Thisproductissolubleinwater.

12.5.ResultsofPBTandvPvBassessment

Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.

12.6Endocrinedisruptingproperties

Nodataisavailableonthisproduct.

12.7.Otheradverseeffects

Nodataisavailableonthisproduct.

SECTION13:Disposalconsiderations

13.1.Wastetreatmentmethods

Generalinformation

Disposalofpackaging

Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.

Disposeofincompliancewithalllocalandnationalrequirements.

DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.

SECTION14:Transportinformation

14.1.UNnumber

14.2.UNpropershippingname

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

14.3.Transporthazardclass(es)

14.4.Packinggroup

14.5.Environmentalhazards

14.6.Specialprecautionsforuser

Bird & Bug Remover

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

14.7MaritimeTransportinbulkaccordingtoIMOinstruments

Theproductisnotclassifiedasdangerousforcarriage.

SECTION15:Regulatoryinformation

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations

REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.AsretainedandamendedinUKlaw.

COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.Asretainedand amendedinUKlaw.

COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).AsretainedandamendedinUK law.

15.2.Chemicalsafetyassessment

Noinformationavailable.

SECTION16:Otherinformation

Otherinformation

Revision

TextofHazardStatementsin

Section3

Furtherinformation

Thisdocumentdiffersfromthepreviousversioninthefollowingareas:. 12-12.1.Toxicity.

AcuteTox.4:H302-Harmfulifswallowed. SkinIrrit.2:H315-Causesskinirritation.

EyeDam.1:H318-Causesseriouseyedamage.

AquaticAcute1:H400-Verytoxictoaquaticlife.

AquaticChronic2:H411-Toxictoaquaticlifewithlonglastingeffects. Repr.2:H361fd-Suspectedofdamagingfertility.Suspectedofdamagingtheunbornchild. STOTRE2:H373-Maycausedamagetoorgansthroughprolongedorrepeatedexposure. Flam.Liq.2:H225-Highlyflammableliquidandvapour.

EyeIrrit.2:H319-Causesseriouseyeirritation.

AcuteTox.4:H302+H312+H332-Harmfulifswallowed,incontactwithskinorifinhaled

TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand

Bird & Bug Remover

beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.

BODY POLISH - STANDARD MSDS

Standard Polish Safety Data Sheet

according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878 Issue date: 8/12/2022 Version: 1.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product form

Product name Product code :Mixture :Standard Polish :STOBD001

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.2.1. Relevant identified uses

Main use category : Industrial use,Professional use,Consumer use

Use of the substance/mixture : Cleaning/washing agents and additives

1.2.2. Uses advised against

No additional information available

1.3. Details of the supplier of the safety data sheet

SUPAGARD LIMITED

19-29 Gavinton Street, Muirend Glasgow G44 3EF

Web - www.supagard.com

Email - james.smyth@supagard.com

Telephone - 0141 633 5933

1.4. Emergency telephone number

01416335933, 8.30am to 5.00pm

For medical advice or information, you should contact your GP or NHS 111 (or NHS 24 in Scotland) on 111 (for 24-hour health advice)

If you are a healthcare professional with an enquiry please visit www.TOXBASE.org

Country

United Kingdom National Poisons Information Service Dudley Road

0344 892 0111 Only for healthcare (Birmingham Centre) B18 7QH Birmingham professionals City Hospital

United Kingdom National Poisons Information Service Penlan Road 0344 892 0111 Only for healthcare (Cardiff Centre) CF64 2XX Llandough professionals University Hospital Llandough

United Kingdom National Poisons Information Service Little France Crescent 0344 892 0111 Only for healthcare (Edinburgh Centre) EH16 4SA Edinburgh professionals Royal Infirmary of Edinburgh

United Kingdom Guy's & St Thomas' Poisons Unit Avonley Road +44 20 7188 7188 Medical Toxicology Unit, Guy's & St SE14 5ER London Thomas' Hospital Trust

United Kingdom National Poisons Information Service Grosvenor Road 0344 892 0111 Only for healthcare (Belfast Centre) BT12 6BA Belfast professionals Royal Victoria Hospital

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Hazardous to the aquatic environment Chronic Hazard, Category 3 H412 Full text of H- and EUH-statements: see section 16

Adverse physicochemical, human health and environmental effects

Harmful to aquatic life with long lasting effects.

8/12/2022 (Issue date)

Standard Polish

Safety Data Sheet

according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP]

Signal word (CLP) : -

Hazard statements (CLP) : H412 - Harmful to aquatic life with long lasting effects.

Precautionary statements (CLP) : P273 - Avoid release to the environment. P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

2.3. Other hazards

Contains no PBT/vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII

The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605

SECTION 3: Composition/information on ingredients

3.1. Substances

Not applicable

3.2. Mixtures

Name

HYDROCARBONS, C9-11, N-ALKANES,

ISOALKANES, CYCLICS, <2% AROMATICS

HYDROCARBONS, C9,AROMATICS

1,2-BENZISOTHIAZOL-3(2H)-ONE

EC-No.: 919-857-5 <15

REACH-no: 01-2119463258-

33

EC-No.: 918-668-5

REACH-no: 01-2119455851-

35

CAS-No.: 2634-33-5

EC-No.: 220-120-9

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Flam. Liq. 3, H226

STOT SE 3, H336

Asp. Tox. 1, H304

≤5 Flam. Liq. 3, H226

Asp. Tox. 1, H304

STOT SE 3, H336

STOT SE 3, H335

Aquatic Chronic 2, H411 (M=0)

<0.05

Acute Tox. 4 (Oral), H302

Acute Tox. 1 (Inhalation), H330

Skin Irrit. 2, H315

Eye Dam. 1, H318

Skin Sens. 1, H317

Aquatic Acute 1, H400

Aquatic Chronic 2, H411

A MIXTURE OF: 5-CHLORO-2-METHYL-2H-

CAS-No.: 55965-84-9

<0.0001

Acute Tox. 2 (Inhalation), H330 ISOTHIAZOL-3-ONE [EC NO 247-500-7] AND 2- EC Index-No.: 613-167-00-5

Acute Tox. 2 (Dermal), H310 METHYL-2H-ISOTHIAZOL-3-ONE [EC NO 220-239-

Acute Tox. 3 (Oral), H301 6]

Skin Corr. 1C, H314

Eye Dam. 1, H318

Skin Sens. 1A, H317

Aquatic Acute 1, H400 (M=100)

Aquatic Chronic 1, H410 (M=100)

Standard Polish

Safety Data Sheet

according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

Specific concentration limits:

Name Product identifier Specific concentration limits

A MIXTURE OF: 5-CHLORO-2-METHYL-2H-

CAS-No.: 55965-84-9 ( 0.0015 ≤C ≤ 100) Skin Sens. 1A, H317

ISOTHIAZOL-3-ONE [EC NO 247-500-7] AND 2- EC Index-No.: 613-167-00-5 ( 0.06 ≤C < 0.6) Skin Irrit. 2, H315 METHYL-2H-ISOTHIAZOL-3-ONE [EC NO 220-239- ( 0.06 ≤C < 0.6) Eye Irrit. 2, H319 6] ( 0.6 ≤C ≤ 100) Skin Corr. 1C, H314 ( 0.6 ≤C ≤ 100) Eye Dam. 1, H318

Full text of H- and EUH-statements: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures after inhalation

First-aid measures after skin contact

First-aid measures after eye contact

First-aid measures after ingestion

: Remove person to fresh air and keep comfortable for breathing.

: Wash skin with plenty of water.

: Rinse eyes with water as a precaution.

: Call a poison center or a doctor if you feel unwell.

4.2. Most important symptoms and effects, both acute and delayed

No additional information available

4.3. Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media

: Water spray. Dry powder. Foam. Carbon dioxide.

5.2. Special hazards arising from the substance or mixture

Hazardous decomposition products in case of fire : Toxic fumes may be released.

5.3. Advice for firefighters

Protection during firefighting

: Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

Emergency procedures

6.1.2. For emergency responders

Protective equipment

6.2. Environmental precautions

Avoid release to the environment.

: Ventilate spillage area.

: Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection".

6.3. Methods and material for containment and cleaning up

Methods for cleaning up

: Take up liquid spill into absorbent material. Other information : Dispose of materials or solid residues at an authorized site.

Standard Polish

Safety Data Sheet

according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

6.4. Reference to other sections

For further information refer to section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Ensure good ventilation of the work station. Wear personal protective equipment. Hygiene measures : Do not eat, drink or smoke when using this product. Always wash hands after handling the product.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions

7.3. Specific end use(s)

No additional information available

: Store in a well-ventilated place. Keep cool.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

8.1.1 National occupational exposure and biological limit values

No additional information available

8.1.2. Recommended monitoring procedures

No additional information available

8.1.3. Air contaminants formed

No additional information available

8.1.4. DNEL and PNEC

No additional information available

8.1.5. Control banding

No additional information available

8.2. Exposure controls

8.2.1. Appropriate engineering controls

Appropriate engineering controls: Ensure good ventilation of the work station.

8.2.2. Personal protection equipment

Personal protective equipment:

Gloves. Safety glasses. Protective clothing. Personal protective equipment symbol(s):

8.2.2.1. Eye and face protection

Eye protection: Safety glasses

8.2.2.2. Skin protection

Skin and body protection:

Wear suitable protective clothing

Standard Polish

Safety Data Sheet

according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

Hand protection:

Protective gloves

8.2.2.3. Respiratory protection

Respiratory protection:

In case of insufficient ventilation, wear suitable respiratory equipment

8.2.2.4. Thermal hazards

No additional information available

8.2.3. Environmental exposure controls

Environmental exposure controls: Avoid release to the environment.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state

Colour

Odour

Odour threshold

Melting point

Freezing point

Boiling point

Flammability

Explosive limits

Lower explosion limit

Upper explosion limit

Flash point

Auto-ignition temperature

Decomposition temperature

: Liquid

: Various colours.

: Pleasant.

: Not available

: Not applicable

: Not available

: Not available

: Non flammable.

: Not available

: Not available

: Not available

: > 93 °C

: Not available

: Not available

Viscosity, kinematic : ≈ 10000 mm²/s

Solubility

Partition coefficient n-octanol/water (Log Kow)

Vapour pressure

Vapour pressure at 50 °C

Density

Relative density

Relative vapour density at 20 °C

Particle characteristics

9.2. Other information

: Not available

: Not available

: Not available

: Not available

: Not available

: Not available

: Not available

: Not applicable

9.2.1. Information with regard to physical hazard classes

No additional information available

9.2.2. Other safety characteristics

No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity

The product is non-reactive under normal conditions of use, storage and transport.

10.2. Chemical stability

Stable under normal conditions.

Standard Polish

Safety Data Sheet

according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

10.3. Possibility of hazardous reactions

No dangerous reactions known under normal conditions of use.

10.4. Conditions to avoid

None under recommended storage and handling conditions (see section 7).

10.5. Incompatible materials

No additional information available

10.6. Hazardous decomposition products

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

SECTION 11: Toxicological information

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

Acute toxicity (oral) : Not classified

Acute toxicity (dermal) : Not classified

Acute toxicity (inhalation) : Not classified

HYDROCARBONS, C9-11, N-ALKANES, ISOALKANES, CYCLICS, <2% AROMATICS

LD50 oral rat

LD50 dermal rat

>5000 mg/kg

>2000 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 402 (Acute Dermal Toxicity)

LD50 dermal rabbit ≥ 3160 mg/kg bodyweight Animal: rabbit, Guideline: OECD Guideline 402 (Acute Dermal Toxicity)

LD50 dermal >5000 mg/kg

HYDROCARBONS, C9,AROMATICS

LD50 dermal rabbit

LC50 Inhalation - Rat

>3160 mg/kg bodyweight Animal: rabbit, Guideline: OECD Guideline 402 (Acute Dermal Toxicity)

>6.193 mg/l air Animal: rat, Guideline: OECD Guideline 403 (Acute Inhalation Toxicity)

A MIXTURE OF: 5-CHLORO-2-METHYL-2H-ISOTHIAZOL-3-ONE [EC NO 247-500-7] AND 2-METHYL-2H-ISOTHIAZOL-3-

ONE [EC NO 220-239-6] (55965-84-9)

LD50 oral rat 53 mg/kg

LD50 oral 60 mg/kg

1,2-BENZISOTHIAZOL-3(2H)-ONE (2634-33-5)

LD50 dermal rat > 2000 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 402 (Acute Dermal Toxicity)

Skin corrosion/irritation

Serious eye damage/irritation

Respiratory or skin sensitisation

Germ cell mutagenicity

Carcinogenicity

Reproductive toxicity

1,2-BENZISOTHIAZOL-3(2H)-ONE (2634-33-5)

NOAEL (animal/female, F1)

STOT-single exposure

8/12/2022

: Not classified pH: ≈ 7

: Not classified pH: ≈ 7

: Not classified

: Not classified

: Not classified

: Not classified

56.6 mg/kg bodyweight Animal: rat, Animal sex: female, Guideline: EPA OPPTS 870.3800 (Reproduction and Fertility Effects)

: Not classified

Standard Polish

Safety Data Sheet

according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

HYDROCARBONS, C9-11, N-ALKANES, ISOALKANES, CYCLICS, <2% AROMATICS

STOT-single exposure

HYDROCARBONS, C9,AROMATICS

STOT-single exposure

May cause drowsiness or dizziness.

May cause drowsiness or dizziness. May cause respiratory irritation.

STOT-repeated exposure : Not classified

HYDROCARBONS, C9,AROMATICS

NOAEL (oral, rat, 90 days)

600 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 408 (Repeated Dose 90Day Oral Toxicity in Rodents)

Aspiration hazard : Not classified

GLAZE - Final Polish

Viscosity, kinematic ≈ 10000 mm²/s

HYDROCARBONS, C9-11, N-ALKANES, ISOALKANES, CYCLICS, <2% AROMATICS

Viscosity, kinematic 1.33 mm²/s Temp.: '20°C' Parameter: 'kinematic viscosity (in mm²/s)'

HYDROCARBONS, C9,AROMATICS

Viscosity, kinematic 1.06 mm²/s Temp.: '20°C' Parameter: 'cStcSt'

11.2. Information on other hazards

No additional information available

SECTION 12: Ecological information

12.1. Toxicity

Ecology - general

Hazardous to the aquatic environment, shortterm (acute)

Hazardous to the aquatic environment, long-term (chronic)

Not rapidly degradable

: Harmful to aquatic life with long lasting effects.

: Not classified

: Harmful to aquatic life with long lasting effects.

HYDROCARBONS, C9-11, N-ALKANES, ISOALKANES, CYCLICS, <2% AROMATICS

LC50 - Fish [1]

>1000 mg/l

EC50 - Other aquatic organisms [1] >1000 mg/l

HYDROCARBONS, C9,AROMATICS

EC50 72h - Algae [1]

EC50 72h - Algae [2]

1,2-BENZISOTHIAZOL-3(2H)-ONE (2634-33-5)

0.42 mg/l Test organisms (species): Pseudokirchneriella subcapitata (previous names: Raphidocelis subcapitata, Selenastrum capricornutum)

0.29 mg/l Test organisms (species): Pseudokirchneriella subcapitata (previous names: Raphidocelis subcapitata, Selenastrum capricornutum)

LC50 - Fish [1] ≈ 16.7 mg/l Test organisms (species): Cyprinodon variegatus

LC50 - Fish [2]

EC50 - Crustacea [1]

EC50 - Crustacea [2]

12.2. Persistence and degradability

No additional information available

8/12/2022

2.15 mg/l Test organisms (species): Oncorhynchus mykiss (previous name: Salmo gairdneri)

2.94 mg/l Test organisms (species): Daphnia magna

2.9 mg/l Test organisms (species): Daphnia magna

Standard Polish

Safety Data Sheet

according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

12.3. Bioaccumulative potential

No additional information available

12.4. Mobility in soil

No additional information available

12.5. Results of PBT and vPvB assessment

No additional information available

12.6. Endocrine disrupting properties

No additional information available

12.7. Other adverse effects

No additional information available

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions.

SECTION 14: Transport information

In accordance with ADR / IMDG / IATA / ADN / RID

14.1. UN number or ID number

14.2. UN proper shipping name

14.3. Transport hazard class(es)

14.4. Packing group

14.5. Environmental hazards

14.6. Special precautions for user

Overland transport

Not regulated

Transport by sea

Not regulated

Air transport Not regulated

Inland waterway transport

Not regulated

Standard Polish

Safety Data Sheet

according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

Rail transport

Not regulated

14.7. Maritime transport in bulk according to IMO instruments

Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1. EU-Regulations

REACH Annex XVII (Restriction List)

Contains no REACH substances with Annex XVII restrictions

REACH Annex XIV (Authorisation List)

Contains no REACH Annex XIV substances

REACH Candidate List (SVHC)

Contains no substance on the REACH candidate list

PIC Regulation (Prior Informed Consent)

Contains no substance subject to Regulation (EU) No 649/2012 of the European Parliament and of the Council of 4 July 2012 concerning the export and import of hazardous chemicals.

POP Regulation (Persistent Organic Pollutants)

Contains no substance subject to Regulation (EU) No 2019/1021 of the European Parliament and of the Council of 20 June 2019 on persistent organic pollutants

Ozone Regulation (1005/2009)

Contains no substance subject to REGULATION (EU) No 1005/2009 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 September 2009 on substances that deplete the ozone layer.

Explosives Precursors Regulation (2019/1148)

Contains substance subject to Regulation (EU) 2019/1148 of the European Parliament and of the Council of 20 June 2019 on the marketing and use of explosives precursors.

ANNEX II REPORTABLE EXPLOSIVES PRECURSORS

List of substances on their own or in mixtures or in substances for which suspicious transactions and significant disappearances and thefts are to be reported to the relevant national contact point within 24 hours.

Name CAS-No. Combined Combined Nomenclature code for mixture without Nomenclature constituents which would determine classification under code (CN) another CN code

Please see https://ec.europa.eu/home-affairs/system/files/2021-11/list_of_competent_authorities_and_national_contact_points_en.pdf

Drug Precursors Regulation (273/2004)

Contains no substance subject to Regulation (EC) 273/2004 of the European Parliament and of the Council of 11 February 2004 on the manufacture and the placing on market of certain substances used in the illicit manufacture of narcotic drugs and psychotropic substances.

Standard Polish

Safety Data Sheet

according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

15.1.2. National regulations

France

Occupational diseases

Code Description

RG 65

Eczematiform lesions of allergic mechanism

RG 66 Occupational rhinitis and asthma

RG 84 Conditions caused by liquid organic solvents for professional use: saturated or unsaturated aliphatic or cyclic liquid hydrocarbons and mixtures thereof; liquid halogenated hydrocarbons; nitrated derivatives of aliphatic hydrocarbons; alcohols; glycols, glycol ethers; ketones; aldehydes; aliphatic and cyclic ethers, including tetrahydrofuran; esters; dimethylformamide and dimethylacetamine; acetonitrile and propionitrile; pyridine; dimethylsulfone and dimethylsulfoxide

Germany

Employment restrictions

: Observe restrictions according Act on the Protection of Working Mothers (MuSchG). Observe restrictions according Act on the Protection of Young People in Employment (JArbSchG).

Water hazard class (WGK) : WGK 3, Highly hazardous to water (Classification according to AwSV, Annex 1).

Hazardous Incident Ordinance (12. BImSchV) : Is not subject of the Hazardous Incident Ordinance (12. BImSchV)

Netherlands

SZW-lijst van kankerverwekkende stoffen : None of the components are listed

SZW-lijst van mutagene stoffen : None of the components are listed

SZW-lijst van reprotoxische stoffen – Borstvoeding : None of the components are listed

SZW-lijst van reprotoxische stoffen – : None of the components are listed

Vruchtbaarheid

SZW-lijst van reprotoxische stoffen – Ontwikkeling : None of the components are listed

Denmark

Classification remarks : Emergency management guidelines for the storage of flammable liquids must be followed Danish National Regulations : Pregnant/breastfeeding women working with the product must not be in direct contact with the product

Switzerland

Storage class (LK) : LK 10/12 - Liquids

15.2. Chemical safety assessment

No chemical safety assessment has been carried out

SECTION 16: Other information

Abbreviations and acronyms:

ADN European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways

ADR European Agreement concerning the International Carriage of Dangerous Goods by Road

ATE Acute Toxicity Estimate

BCF Bioconcentration factor

BLV Biological limit value

BOD Biochemical oxygen demand (BOD)

COD Chemical oxygen demand (COD)

DMEL Derived Minimal Effect level

DNEL Derived-No Effect Level

EC-No. European Community number

Standard Polish

Safety Data Sheet

according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

Abbreviations and acronyms:

EC50 Median effective concentration

EN European Standard

IARC International Agency for Research on Cancer

IATA International Air Transport Association

IMDG International Maritime Dangerous Goods

LC50 Median lethal concentration

LD50 Median lethal dose

LOAEL Lowest Observed Adverse Effect Level

NOAEC No-Observed Adverse Effect Concentration

NOAEL No-Observed Adverse Effect Level

NOEC No-Observed Effect Concentration

OECD Organisation for Economic Co-operation and Development

OEL Occupational Exposure Limit

PBT Persistent Bioaccumulative Toxic

PNEC Predicted No-Effect Concentration

RID Regulations concerning the International Carriage of Dangerous Goods by Rail

SDS Safety Data Sheet

STP Sewage treatment plant

ThOD Theoretical oxygen demand (ThOD)

TLM Median Tolerance Limit

VOC Volatile Organic Compounds

CAS-No. Chemical Abstract Service number

N.O.S. Not Otherwise Specified

vPvB Very Persistent and Very Bioaccumulative

ED Endocrine disrupting properties

Full text of H- and EUH-statements:

Acute Tox. 1 (Inhalation) Acute toxicity (inhal.), Category 1

Acute Tox. 2 (Dermal) Acute toxicity (dermal), Category 2

Acute Tox. 2 (Inhalation) Acute toxicity (inhal.), Category 2

Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3

Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4

Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1

Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category 1

Aquatic Chronic 2 Hazardous to the aquatic environment Chronic Hazard, Category 2

Asp. Tox. 1 Aspiration hazard, Category 1

Eye Dam. 1

Eye Irrit. 2

Serious eye damage/eye irritation, Category 1

Serious eye damage/eye irritation, Category 2

Flam. Liq. 3 Flammable liquids, Category 3

Standard Polish

Safety Data Sheet

according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

Full text of H- and EUH-statements:

H226 Flammable liquid and vapour.

H301 Toxic if swallowed.

H302 Harmful if swallowed.

H304 May be fatal if swallowed and enters airways.

H310 Fatal in contact with skin.

H314 Causes severe skin burns and eye damage.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H318 Causes serious eye damage.

H319 Causes serious eye irritation.

H330 Fatal if inhaled.

H335 May cause respiratory irritation.

H336 May cause drowsiness or dizziness.

H400 Very toxic to aquatic life.

H410 Very toxic to aquatic life with long lasting effects.

H411 Toxic to aquatic life with long lasting effects.

H412 Harmful to aquatic life with long lasting effects.

Skin Corr. 1C

Skin Irrit. 2

Skin Sens. 1

Skin Sens. 1A

STOT SE 3

Safety Data Sheet (SDS), EU

Skin corrosion/irritation, Category 1, Sub-Category 1C

Skin corrosion/irritation, Category 2

Skin sensitisation, Category 1

Skin sensitisation, category 1A

Specific target organ toxicity Single exposure, Category 3, Narcosis

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

CUTTING COMPOUND - FINE MSDS

Revision Date 03/01/2018

Supersedes date 07/12/2016

SAFETY DATA SHEET FINE CUTTING COMPOUND

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier

Product name

Product No.

REACH Registration number

FINE CUTTING COMPOUND

000998083012

Mixture - not applicable

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses

As product description

1.3. Details of the supplier of the safety data sheet

SUPAGARD LIMITED

Supplier 23, Gavinton Street, Muirend, Glasgow, Scotland, G44 3EF 0141 633 5933 0141 637 7219 james@supagard.co.uk

1.4. Emergency telephone number

SECTION 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)

Physical and Chemical HazardsNot classified. Human health Not classified. Environment Not classified.

2.2. Label elements

Label In Accordance With (EC) No. 1272/2008

No pictogram required.

Precautionary Statements

P102

P260

P280

P501

2.3. Other hazards

Keep out of reach of children.

Do not breathe vapours.

Wear protective gloves.

Dispose of contents/container in accordance with local regulations.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixtures

EC No.: 919-857-5

Classification (EC 1272/2008)

Flam. Liq. 3 - H226

EUH066

STOT SE 3 - H336

Asp. Tox. 1 - H304

FINE CUTTING COMPOUND

Classification (67/548/EEC) Xn;R65. R10,R66,R67.

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

REACH Registration numberMixture - not applicable

SECTION 4: FIRST AID MEASURES

4.1. Description of first aid measures

Inhalation

Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. Ingestion

NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Rinse mouth thoroughly. Drink plenty of water. Get medical attention if any discomfort continues.

Skin contact

Wash skin thoroughly with soap and water. Get medical attention if any discomfort continues. Eye contact

Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.

4.2. Most important symptoms and effects, both acute and delayed

General information

Mixture is not classified - none noted

4.3. Indication of any immediate medical attention and special treatment needed

See section 4.1

SECTION 5: FIREFIGHTING MEASURES

5.1. Extinguishing media

Extinguishing media

This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials.

5.2. Special hazards arising from the substance or mixture

Hazardous combustion products

During a fire, CO and CO2 may be formed.

5.3. Advice for firefighters

Special Fire Fighting Procedures

No specific fire fighting procedure given.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

In case of spills, beware of slippery floors and surfaces.

6.2. Environmental precautions

Not relevant considering the small amounts used.

6.3. Methods and material for containment and cleaning up

Stop leak if possible without risk. Absorb in vermiculite, dry sand or earth and place into containers. Flush with plenty of water to clean spillage area.

6.4. Reference to other sections

Collect and dispose of spillage as indicated in section 13.

SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Avoid spilling, skin and eye contact.

7.2. Conditions for safe storage, including any incompatibilities

Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container.

7.3. Specific end use(s)

The identified uses for this product are detailed in Section 1.2.

Usage Description

Use as instructed on the product label.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Ingredient Comments

Where an allergen is named in Section 2, follow appropriate measures in Sections 8 and 11.

8.2. Exposure controls

Protective equipment

Engineering measures

Provide adequate general and local exhaust ventilation. Hand protection

For prolonged or repeated skin contact use suitable protective gloves.

Eye protection

Wear approved chemical safety goggles where eye exposure is reasonably probable. Other Protection

Wear appropriate clothing to prevent any possibility of skin contact.

Hygiene measures

DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated. Use appropriate skin cream to prevent drying of skin. When using do not eat, drink or smoke.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance Liquid

Colour Typical

Odour Characteristic.

9.2. Other information

None to note.

SECTION 10: STABILITY AND REACTIVITY

10.1. Reactivity

There are no known reactivity hazards associated with this product.

10.2. Chemical stability

Stable under normal temperature conditions.

10.3. Possibility of hazardous reactions

Not applicable.

10.4. Conditions to avoid

Avoid excessive heat for prolonged periods of time. Avoid frost.

10.5. Incompatible materials

Materials To Avoid

Strong alkalis. Strong acids.

10.6. Hazardous decomposition products

Fire creates: Carbon monoxide (CO). Carbon dioxide (CO2).

SECTION 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Inhalation

Gas or vapour may irritate respiratory system.

Ingestion

Gastrointestinal symptoms, including upset stomach.

Skin contact

Prolonged contact may cause dryness of the skin.

Eye contact

Irritating to eyes.

Health Warnings

No specific health warnings noted.

Route of entry

Ingestion. Inhalation. Skin and/or eye contact.

SECTION 12: ECOLOGICAL INFORMATION

Ecotoxicity

Not regarded as dangerous for the environment.

12.1. Toxicity

Data set not currently available.

12.2. Persistence and degradability

The majority of the constituents are readily degradeable.

12.3. Bioaccumulative potential

Bioaccumulative potential

No data available on bioaccumulation.

12.4. Mobility in soil

Mobility:

Mobile.

12.5. Results of PBT and vPvB assessment

Not Classified as PBT/vPvB by current EU criteria.

12.6. Other adverse effects

Not applicable.

SECTION 13: DISPOSAL CONSIDERATIONS

General information

Dispose of in accordance with Local Authority guidelines.

13.1. Waste treatment methods

Dispose of waste and residues in accordance with local authority requirements.

SECTION 14: TRANSPORT INFORMATION

General

The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID).

Rail Transport Notes Not classified.

Sea Transport Notes Not classified.

Air Transport Notes Not classified.

14.1. UN number

Not applicable.

14.2. UN proper shipping name

Not applicable.

14.3. Transport hazard class(es)

Transport Labels

14.4. Packing group

Not applicable.

14.5. Environmental hazards

No transport warning sign required.

Environmentally Hazardous Substance/Marine Pollutant No.

14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Not applicable.

SECTION 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Guidance Notes

Workplace Exposure Limits EH40.

Introduction to Local Exhaust Ventilation HS(G)37.

EU Legislation

Regulation (EC) No.1272/2008 The Classification, Labelling and Packaging of substances and mixtures Regulations

Regulation (EC) No. 1907/2006 The Registration, Evaluation, Authorisation and Restriction of Chemicals Regulations (REACH) 2001/95/EC The General Product Safety Directive (GPSD)

Commission Regulation (EU) 2015/830 Requirements for the compilation of safety data sheets (amending REACH)

Authorisations (Title VII Regulation 1907/2006)

No specific authorisations are noted for this product.

Restrictions (Title VIII Regulation 1907/2006)

No specific restrictions of use are noted for this product.

15.2. Chemical Safety Assessment

Not currently available.

SECTION 16: OTHER INFORMATION

Information Sources

Dangerous Properties of Industrial Materials Report, N.Sax et.al.

FINE CUTTING COMPOUND

Revision Date 03/01/2018

Revision 4

Supersedes date 07/12/2016

Hazard Statements In Full

EUH066 Repeated exposure may cause skin dryness or cracking. , H226 Flammable liquid and vapour. , H304 May be fatal if swallowed and enters airways. , H336 May cause drowsiness or dizziness.

CUTTING COMPOUND - MEDIUM MSDS

Revision Date 03/01/2018

Supersedes date 16/08/2016

SAFETY DATA SHEET

MEDIUM CUTTING COMPOUND

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier

Product name

Product No.

MEDIUM CUTTING COMPOUND 000998083011

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.3. Details of the supplier of the safety data sheet

SUPAGARD LIMITED

Supplier 23, Gavinton Street, Muirend, Glasgow, Scotland, G44 3EF 0141 633 5933 0141 637 7219 james@supagard.co.uk

1.4. Emergency telephone number

SECTION 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)

Physical and Chemical HazardsNot classified. Human health Skin Sens. 1 - H317 Environment Not classified.

2.2. Label elements Contains PINE OIL 90

Label In Accordance With (EC) No. 1272/2008

Signal Word Warning Hazard Statements

H317 May cause an allergic skin reaction. Precautionary Statements

P102

Keep out of reach of children.

P280 Wear protective gloves.

P261 Avoid breathing vapour/spray.

P302+352

IF ON SKIN: Wash with plenty of soap and water.

P333+313 If skin irritation or rash occurs: Get medical advice/attention. Supplementary Precautionary Statements

P363

P501

2.3. Other hazards

Wash contaminated clothing before reuse.

Dispose of contents/container in accordance with local regulations.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Mixtures

CAS-No.: 64742-52-5

Classification (EC 1272/2008) Not classified.

ODOURLESS KEROSENE

CAS-No.: 64742-47-8

Classification (EC 1272/2008)

EUH066

Asp. Tox. 1 - H304

EC No.: 265-155-0

Registration Number: 01-2119467170-45-XXXX

Classification (67/548/EEC) Not classified.

EC No.: 926-141-6

Registration Number: 01-2119456620-43-XXXX

Classification (67/548/EEC) Xn;R65. R66.

CAS-No.: 8000-41-7

Classification (EC 1272/2008)

Flam. Liq. 3 - H226

Skin Irrit. 2 - H315

Eye Irrit. 2 - H319

Skin Sens. 1 - H317

Asp. Tox. 1 - H304

Aquatic Chronic 2 - H411

EC No.: 232-268-1

Registration Number: 01-2119553062-49-XXXX, 01-211

Classification (67/548/EEC) Xn;R65. Xi;R36/38. N;R51/53. R10,R43.

CAS-No.: 7632-00-0

Classification (EC 1272/2008)

Ox. Sol. 3 - H272

Acute Tox. 3 - H301

Aquatic Acute 1 - H400

EC No.: 231-555-9

Registration Number: 01-2119471836-27-XXXX

Classification (67/548/EEC)

O;R8

T;R25

N;R50

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: FIRST AID MEASURES

4.1. Description of first aid measures

Inhalation

Move the exposed person to fresh air at once. Rinse nose and mouth with water. Get medical attention if any discomfort continues. Ingestion

Remove victim immediately from source of exposure. Rinse mouth thoroughly. Drink plenty of water. Get medical attention.

Skin contact

Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention if irritation persists after washing.

Eye contact

Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.

4.2. Most important symptoms and effects, both acute and delayed

4.3. Indication of any immediate medical attention and special treatment needed

SECTION 5: FIREFIGHTING MEASURES

5.1. Extinguishing media

Extinguishing media

This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials.

5.2. Special hazards arising from the substance or mixture

5.3. Advice for firefighters

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

Wear necessary protective equipment. Absorb in vermiculite, dry sand or earth and place into containers. Do not contaminate water sources or sewer. Flush with plenty of water to clean spillage area.

6.4. Reference to other sections

SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Avoid spilling, skin and eye contact.

7.2. Conditions for safe storage, including any incompatibilities

Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container.

7.3. Specific end use(s)

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

ODOURLESS KEROSENE

Ingredient Comments

WEL = Workplace Exposure Limits

8.2. Exposure controls

Protective equipment

Engineering measures

No particular ventilation requirements.

Respiratory equipment

No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational exposure limit. Use chemical cartridge protection with appropriate cartridge. Hand protection

Use protective gloves.

Eye protection

Use approved safety goggles or face shield.

Other Protection

Wear appropriate clothing to prevent any possibility of skin contact.

Hygiene measures

DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance Liquid

Colour Typical

Odour Characteristic.

Solubility Soluble in water.

9.2. Other information

SECTION 10: STABILITY AND REACTIVITY

10.1. Reactivity

10.2. Chemical stability

Stable under normal temperature conditions.

10.3. Possibility of hazardous reactions

10.4. Conditions to avoid

Avoid contact with acids.

10.5. Incompatible materials

10.6. Hazardous decomposition products

No specific hazardous decomposition products noted.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Inhalation

May cause irritation to the respiratory system.

Ingestion

May cause burns in mucous membranes, throat, oesophagus and stomach. May cause stomach pain or vomiting.

Skin contact

Irritating to skin. Prolonged or repeated exposure may cause severe irritation. Acts as a defatting agent on skin. May cause cracking of skin, and eczema. May cause allergic contact eczema. May cause sensitisation by skin contact.

Eye contact

May cause severe irritation to eyes. Risk of serious damage to eyes. Surfactant or detergent eye injury due to liquid splashes or dust.

Route of entry

Ingestion. Skin and/or eye contact.

SECTION

12: ECOLOGICAL INFORMATION

Ecotoxicity

Dangerous for the environment if discharged into watercourses.

12.1. Toxicity

12.2. Persistence and degradability

12.3. Bioaccumulative potential

12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment

12.6. Other adverse effects

SECTION 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Dispose of waste and residues in accordance with local authority requirements.

SECTION 14: TRANSPORT INFORMATION

14.1. UN number

14.2. UN proper shipping name

14.3. Transport hazard class(es)

ADR/RID/ADN Class Not classified for transportation. Transport Labels

No transport warning sign required.

14.4. Packing group

14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant No.

14.6. Special precautions for user

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

SECTION 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Guidance Notes

Workplace Exposure Limits EH40. Introduction to Local Exhaust Ventilation HS(G)37. EU Legislation Regulation (EC) No.1272/2008 The Classification, Labelling and Packaging of substances and mixtures Regulations Regulation (EC) No. 1907/2006 The Registration, Evaluation, Authorisation and Restriction of Chemicals Regulations (REACH) 2001/95/EC The General Product Safety Directive (GPSD) Commission Regulation (EU) 2015/830 Requirements for the compilation of safety data sheets (amending REACH) Authorisations (Title VII Regulation 1907/2006) No specific authorisations are noted for this product. Restrictions (Title VIII Regulation 1907/2006)

No specific restrictions of use are noted for this product.

15.2. Chemical Safety Assessment

SECTION 16: OTHER INFORMATION

Revision Date 03/01/2018

Revision 4

Supersedes date 16/08/2016

Hazard Statements In Full

EUH066 Repeated exposure may cause skin dryness or cracking. , H226 Flammable liquid and vapour. , H272 May intensify fire; oxidiser. , H301 Toxic if swallowed. , H304 May be fatal if swallowed and enters airways. , H315 Causes skin irritation. , H317 May cause an allergic skin reaction. , H319 Causes serious eye irritation. , H400 Very toxic to aquatic life. , H411 Toxic to aquatic life with long lasting effects.

CUTTING COMPOUND - COARSE

MSDS

Revision Date 03/01/2018

Supersedes date 16/08/2016

SAFETY DATA SHEET COARSE CUTTING COMPOUND

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier

Product name Product No.

COARSE CUTTING COMPOUND 000998083010

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.3. Details of the supplier of the safety data sheet

SUPAGARD LIMITED

Supplier 23, Gavinton Street, Muirend, Glasgow, Scotland, G44 3EF 0141 633 5933 0141 637 7219 james@supagard.co.uk

1.4. Emergency telephone number

SECTION 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)

Physical and Chemical HazardsNot classified.

Human health Skin Sens. 1 - H317 Environment Not classified.

2.2. Label elements Contains PINE OIL 90

Label In Accordance With (EC) No. 1272/2008

Signal Word Warning Hazard Statements

H317

May cause an allergic skin reaction. Precautionary Statements

P102

P272

Keep out of reach of children.

Contaminated work clothing should not be allowed out of the workplace.

P261 Avoid breathing vapour/spray.

P280 Wear protective gloves.

P302+352 IF ON SKIN: Wash with plenty of soap and water.

P333+313 If skin irritation or rash occurs: Get medical advice/attention.

Supplementary Precautionary Statements

P363

P501

2.3. Other hazards

Wash contaminated clothing before reuse.

Dispose of contents/container in accordance with local regulations.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Mixtures

CAS-No.: 64742-52-5

Classification (EC 1272/2008) Not classified.

ODOURLESS KEROSENE

CAS-No.: 64742-47-8

Classification (EC 1272/2008)

EUH066

Asp. Tox. 1 - H304

COARSE CUTTING

EC No.: 265-155-0

Registration Number: 01-2119467170-45-XXXX

Classification (67/548/EEC) Not classified.

EC No.: 926-141-6

Registration Number: 01-2119456620-43-XXXX

Classification (67/548/EEC) Xn;R65. R66.

CAS-No.: 8000-41-7

Classification (EC 1272/2008)

Flam. Liq. 3 - H226

Skin Irrit. 2 - H315

Eye Irrit. 2 - H319

Skin Sens. 1 - H317

Asp. Tox. 1 - H304

Aquatic Chronic 2 - H411

EC No.: 232-268-1

Registration Number: 01-2119553062-49-XXXX, 01-211

Classification (67/548/EEC) Xn;R65. Xi;R36/38. N;R51/53. R10,R43.

CAS-No.: 7632-00-0

Classification (EC 1272/2008)

Ox. Sol. 3 - H272

Acute Tox. 3 - H301

Aquatic Acute 1 - H400

EC No.: 231-555-9

Registration Number: 01-2119471836-27-XXXX

Classification (67/548/EEC)

O;R8

T;R25

N;R50

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: FIRST AID MEASURES

4.1. Description of first aid measures

Inhalation

Move the exposed person to fresh air at once. Rinse nose and mouth with water. Get medical attention if any discomfort continues. Ingestion

Remove victim immediately from source of exposure. Rinse mouth thoroughly. Drink plenty of water. Get medical attention.

Skin contact

Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention if irritation persists after washing.

Eye contact

Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.

4.2. Most important symptoms and effects, both acute and delayed

4.3. Indication of any immediate medical attention and special treatment needed

SECTION 5: FIREFIGHTING MEASURES

5.1. Extinguishing media

Extinguishing media

This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials.

5.2. Special hazards arising from the substance or mixture

5.3. Advice for firefighters

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

Wear necessary protective equipment. Absorb in vermiculite, dry sand or earth and place into containers. Do not contaminate water sources or sewer. Flush with plenty of water to clean spillage area.

6.4. Reference to other sections

SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Avoid spilling, skin and eye contact.

7.2. Conditions for safe storage, including any incompatibilities

Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container.

7.3. Specific end use(s)

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

ODOURLESS KEROSENE

Ingredient Comments

WEL = Workplace Exposure Limits

8.2. Exposure controls

Protective equipment

Engineering measures

No particular ventilation requirements.

Respiratory equipment

No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational exposure limit. Use chemical cartridge protection with appropriate cartridge. Hand protection

Use protective gloves.

Eye protection

Use approved safety goggles or face shield.

Other Protection

Wear appropriate clothing to prevent any possibility of skin contact.

Hygiene measures

DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance Liquid

Colour Typical

Odour Characteristic.

Solubility Soluble in water.

9.2. Other information

SECTION 10: STABILITY AND REACTIVITY

10.1. Reactivity

10.2. Chemical stability

Stable under normal temperature conditions.

10.3. Possibility of hazardous reactions

10.4. Conditions to avoid

Avoid contact with acids.

10.5. Incompatible materials

10.6. Hazardous decomposition products

No specific hazardous decomposition products noted.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Inhalation

May cause irritation to the respiratory system.

Ingestion

May cause burns in mucous membranes, throat, oesophagus and stomach. May cause stomach pain or vomiting.

Skin contact

Irritating to skin. Prolonged or repeated exposure may cause severe irritation. Acts as a defatting agent on skin. May cause cracking of skin, and eczema. May cause allergic contact eczema. May cause sensitisation by skin contact.

Eye contact

May cause severe irritation to eyes. Risk of serious damage to eyes. Surfactant or detergent eye injury due to liquid splashes or dust.

Route of entry

Ingestion. Skin and/or eye contact.

SECTION 12: ECOLOGICAL INFORMATION

Ecotoxicity

Dangerous for the environment if discharged into watercourses.

12.1. Toxicity

12.2. Persistence and degradability

12.3. Bioaccumulative potential

12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment

12.6. Other adverse effects

SECTION 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Dispose of waste and residues in accordance with local authority requirements.

SECTION 14: TRANSPORT INFORMATION

14.1. UN number

14.2. UN proper shipping name

14.3. Transport hazard class(es)

ADR/RID/ADN Class Not classified for transportation. Transport Labels

No transport warning sign required.

14.4. Packing group

14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant No.

14.6. Special precautions for user

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

SECTION 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Guidance Notes

Workplace Exposure Limits EH40. Introduction to Local Exhaust Ventilation HS(G)37. EU Legislation Regulation (EC) No.1272/2008 The Classification, Labelling and Packaging of substances and mixtures Regulations Regulation (EC) No. 1907/2006 The Registration, Evaluation, Authorisation and Restriction of Chemicals Regulations (REACH) 2001/95/EC The General Product Safety Directive (GPSD) Commission Regulation (EU) 2015/830 Requirements for the compilation of safety data sheets (amending REACH) Authorisations (Title VII Regulation 1907/2006) No specific authorisations are noted for this product. Restrictions (Title VIII Regulation 1907/2006)

No specific restrictions of use are noted for this product.

15.2. Chemical Safety Assessment

SECTION 16: OTHER INFORMATION

Revision Date 03/01/2018

Revision 4

Supersedes date 16/08/2016

Hazard Statements In Full

EUH066 Repeated exposure may cause skin dryness or cracking. , H226 Flammable liquid and vapour. , H272 May intensify fire; oxidiser. , H301 Toxic if swallowed. , H304 May be fatal if swallowed and enters airways. , H315 Causes skin irritation. , H317 May cause an allergic skin reaction. , H319 Causes serious eye irritation. , H400 Very toxic to aquatic life. , H411 Toxic to aquatic life with long lasting effects.

CONCENTRATED SHAMPOO MSDS

SAFETY DATA SHEET

according to Regulation (EU) 2020/878

Concentrated Shampoo

SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking

1.1.Productidentifier

Productname Concentrated Shampoo

1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst ProductUse [SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers); [SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);

Description CarShampoo.

1.3.Detailsofthesupplierofthesafetydatasheet

Company SUPAGARDLIMITED

Address 19-27GavintonStreet Muirend Glasgow G443EF

Web www.supagard.com

Telephone 01416335933

Fax 01416377219

Email James.Smyth@supagard.com

Emailaddressofthe competentperson James.Smyth@supagard.com

1.4.Emergencytelephonenumber

Emergencytelephonenumber01416335933 8.30amto5.00pm

FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)

Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org

SECTION2:Hazardsidentification

2.1.Classificationofthesubstanceormixture

2.1.2.Classification-EC 1272/2008 EyeIrrit.2:H319;

2.2.Labelelements

Hazardpictograms

2.2.Labelelements

HazardStatement

PrecautionaryStatement: Prevention

PrecautionaryStatement: Response

Concentrated Shampoo

EyeIrrit.2:H319-Causesseriouseyeirritation.

P102-Keepoutofreachofchildren.

P264-Washhandsthoroughlyafterhandling.

P280-Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection.

P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.

P337+P313-Ifeyeirritationpersists:Getmedicaladvice/attention.

SUPPLEMENTALHAZARD INFORMATION IngredientsasrequiredbyRegulation(EC)No648/2004:. 5-15%AnionicSurfactants,CI16035,Parfum,AmylCinnamal,Geraniol,Limonene.

Contains-BenzenesulphonicAcidMonoC10-C13AlkylDerivsSodiumSalts.

2.3.Otherhazards

Otherhazards

Furtherinformation

Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.

RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.

SECTION3:Composition/informationoningredients

3.2.Mixtures

EC1272/2008

ChemicalName

BenzenesulphonicAcidMono C10-C13AlkylDervisSodiumSalts

SECTION4:Firstaidmeasures

4.1.Descriptionoffirstaidmeasures

Inhalation

68411-30-3270-115-001-2119489428-22

Movetheexposedpersontofreshair.

AcuteTox.4:H302;SkinIrrit. 2:H315;EyeDam.1:H318; AquaticChronic3:H412;

Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved.

Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution.

Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed

Inhalation Maycauseirritationtorespiratorysystem.

Eyecontact Causesseriouseyeirritation.

Skincontact Maycauseirritationtoskin.

Ingestion Maycauseirritationtomucousmembranes.

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded

Inhalation

Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.

Eyecontact Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.

Skincontact Seekmedicalattentionifirritationorsymptomspersist.

Ingestion Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.

Generalinformation

Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.

SECTION5:Firefightingmeasures

5.1.Extinguishingmedia

5.1.Extinguishingmedia

Concentrated Shampoo

Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.

5.2.Specialhazardsarisingfromthesubstanceormixture

Noneknown.

5.3.Adviceforfirefighters

Furtherinformation

Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.

Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.

6.1.Personalprecautions,protectiveequipmentandemergencyprocedures

6.2.Environmentalprecautions

Wearsuitableprotectiveequipment.

Adviselocalauthoritiesiflargespillscannotbecontained.

6.3.Methodsandmaterialforcontainmentandcleaningup

Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.

6.4.Referencetoothersections

Seesection2,7,8,13forfurtherinformation.

SECTION7:Handlingandstorage

7.1.Precautionsforsafehandling

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.

7.2.Conditionsforsafestorage,includinganyincompatibilities

Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.

7.3.Specificenduse(s)

Suitablepackaging

8.1.Controlparameters

8.2.Exposurecontrols

Occupationalexposurecontrols. Noworkplaceexposurelimitsapplicable.

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face

8.2.Exposurecontrols protection.

8.2.1.Appropriateengineering controls

Concentrated Shampoo

Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.

Eye/faceprotection Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields.

SkinprotectionHandprotection Rubbergloves.

Respiratoryprotection Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.

8.2.3.Environmentalexposure controls Preventfurtherleakageorspillageifsafetodoso.

SECTION9:Physicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties

AppearanceLiquid ColourRed OdourCharacteristic

OdourthresholdNodataavailable pH7

MeltingpointNodataavailable

InitialboilingpointNodataavailable EvaporationrateNodataavailable Flammability(solid,gas)Nodataavailable VapourpressureNodataavailable

RelativeVapourDensityNodataavailable

Density/RelativeDensity1.025-1.03g/cm3

PartitioncoefficientNodataavailable

AutoignitiontemperatureNodataavailable Viscosity<1000centipoise

ExplosivepropertiesNodataavailable

OxidisingpropertiesNodataavailable

SolubilitySolubleinwater

9.2.Otherinformation

ConductivityNodataavailable SurfacetensionNodataavailable

GasgroupNodataavailable BenzeneContentNodataavailable

LeadcontentNodataavailable

VOC(Volatileorganic compounds) Nodataavailable

9.2.1.Informationwithregardtophysicalhazardclasses Nodataisavailableonthisproduct.

9.2.2.Othersafetycharacteristics Nodataisavailableonthisproduct.

SECTION10:Stabilityandreactivity

10.1.Reactivity

10.2.Chemicalstability

Stableundernormalconditions.

10.2.Chemicalstability

Concentrated Shampoo

Stableundernormalconditions.

10.3.Possibilityofhazardousreactions

Strongacids.Strongoxidisingagents.

10.4.Conditionstoavoid

10.5.Incompatiblematerials

Protectfromfrost.

Noincompatiblegroupsnoted.

10.6.Hazardousdecompositionproducts

NoHazardousdecompositionproductswhenstoredandhandledcorrectly.

SECTION11:Toxicologicalinformation

11.1Informationonhazardclasses

Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedusingthemethodsoutlinedinRegulation(EC)No1272/2008(CLP).

Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

OralATE=>10,000mg/kg.

Inhalation-Dust/MistATE=>10,000mg/l.

Skincorrosion/irritation basedonavailabledatatheclassificationcriteriaarenotmet.

Seriouseyedamage/irritationEyeIrrit.2:H319-Causesseriouseyeirritation.

Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.

Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet. Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet. Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet. STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet. Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet. Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.

11.1.2.Mixtures

11.1.3.HazardInformation

11.1.4.ToxicologicalInformation

Nodataavailable.

Nodataavailable.

Nodataavailable

11.2Informationonotherhazards

Nodataisavailableonthisproduct.

12.1.Toxicity

Nodataavailable

12.2.Persistenceanddegradability

SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.

12.3.Bioaccumulativepotential

12.3.Bioaccumulativepotential

Concentrated Shampoo

Theproductisnotbioaccumulating. Partitioncoefficient

StoneacreConcentratedRed Shampoo Nodataavailable

12.4.Mobilityinsoil

Thisproductissolubleinwater.

12.5.ResultsofPBTandvPvBassessment

Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.

12.6Endocrinedisruptingproperties

Nodataisavailableonthisproduct.

12.7.Otheradverseeffects

Nodataisavailableonthisproduct.

SECTION13:Disposalconsiderations

13.1.Wastetreatmentmethods

Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements. Generalinformation

Disposeofincompliancewithalllocalandnationalrequirements. Disposalofpackaging

DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.

SECTION14:Transportinformation

14.1.UNnumber

14.2.UNpropershippingname

14.3.Transporthazardclass(es)

14.4.Packinggroup

14.5.Environmentalhazards

14.6.Specialprecautionsforuser

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

14.7MaritimeTransportinbulkaccordingtoIMOinstruments

Theproductisnotclassifiedasdangerousforcarriage.

SECTION15:Regulatoryinformation

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC 2022-12-02Printdate Poweredby Copyright©2022ChemSoft.Allrightsreserved.

Concentrated Shampoo

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.

COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.

COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).

15.2.Chemicalsafetyassessment

Noinformationavailable.

SECTION16:Otherinformation

Otherinformation

Revision

Thisdocumentdiffersfromthepreviousversioninthefollowingareas:.

2-Otherhazards.

2-Furtherinformation.

2-SUPPLEMENTALHAZARDINFORMATION.

5-5.2.Specialhazardsarisingfromthesubstanceormixture.

5-5.3.Adviceforfirefighters.

9-9.2.2.Othersafetycharacteristics.

9-9.2.1.Informationwithregardtophysicalhazardclasses. 10-10.2.Chemicalstability.

10-10.6.Hazardousdecompositionproducts. 10-10.1.Reactivity.

11-Acutetoxicity.

11-Repeatedorprolongedexposure.

11-11.2Informationonotherhazards.

12-12.1.Toxicity.

12-12.4.Mobilityinsoil.

12-12.3.Bioaccumulativepotential.

12-12.5.ResultsofPBTandvPvBassessment. 12-12.6Endocrinedisruptingproperties.

12-12.7.Otheradverseeffects.

15-Regulations.

Datasources ClassificationandProcedureusedtoderivetheclassificationformixturesaccordingtoRegulation (EC)No.1272/2008,asretainedandamendedinUKlaw.

TextofHazardStatementsin Section3

Furtherinformation

EyeIrrit.2:H319-Causesseriouseyeirritation.-CalculationMethod.

AcuteTox.4:H302-Harmfulifswallowed. SkinIrrit.2:H315-Causesskinirritation.

EyeDam.1:H318-Causesseriouseyedamage. AquaticChronic3:H412-Harmfultoaquaticlifewithlonglastingeffects.

TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.

CARPET DYE MSDS

Compilation date: 03/10/2023

Revision No: 1

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name: BLACK CARPET DYE

Product code: CARPET DYE RESTORER

Synonyms: CARPET DYE RESTORER

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of substance / mixture: PC9a: Coatings and paints, thinners, paint removers.

1.3. Details of the supplier of the safetydata sheet

Companyname: SUPAGARD LIMITED

23 Gavinton Street Muirend Glasgow Scotland G44 3EF

Tel: 0141 633 5933

Email: james@supagard.co.uk

1.4. Emergencytelephone number

Emergencytel: 0141 633 5933 (office hours only)

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Classification under CLP: STOT RE 2: H373; Acute Tox. 4: H302+H332; Aquatic Chronic 3: H412; Eye Irrit. 2: H319; Flam. Liq. 3: H226; Lact.: H362; Skin Irrit. 2: H315; STOT SE 3: H335

Most important adverse effects: Flammable liquid and vapour. Harmful if swallowed or if inhaled Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause harm to breast-fed children. May cause damage to organs through prolonged or repeated exposure. Harmful to aquatic life with long lasting effects.

2.2. Label elements

Label elements:

Hazard statements: H226: Flammable liquid and vapour.

H302+H332: Harmful if swallowed or if inhaled

H315: Causes skin irritation.

H319: Causes serious eye irritation.

H335: May cause respiratory irritation.

SAFETY DATA SHEET

BLACK CARPET DYE

H362: May cause harm to breast-fed children.

H373: May cause damage to organs through prolonged or repeated exposure.

H412: Harmful to aquatic life with long lasting effects.

Hazard pictograms: GHS02: Flame

GHS07: Exclamation mark

GHS08: Health hazard

Signal words: Warning

Precautionarystatements: P201: Obtain special instructions before use.

P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P240: Ground and bond container and receiving equipment.

P241: Use explosion-proof equipment.

P242: Use non-sparking tools.

P243: Take action to prevent static discharges.

P260: Do not breathe dust/fume/gas/mist/vapours/spray.

P261: Avoid breathing vapours.

P263: Avoid contact during pregnancy and while nursing.

P270: Do not eat, drink or smoke when using this product.

P271: Use only outdoors or in a well-ventilated area.

P273: Avoid release to the environment.

P280: Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310: IF SWALLOWED: Immediately call a doctor.

P302+P352: IF ON SKIN: Wash with plenty of soap and water.

P308+P313: IF exposed or concerned: Get medical advice.

P332+P313: If skin irritation occurs: Get medical advice/attention.

P337+P313: If eye irritation persists: Get medical advice/attention.

P362+P364: Take off contaminated clothing and wash it before reuse.

P370+P378: In case of fire: Use dry extinguishing powder to extinguish.

Haz. ingredients (label): Contains: XYLENE; 2-BUTOXYETHANOL; CHLORINATED PARAFFIN

2.3. Other hazards

Other hazards: In use, may form flammable / explosive vapour-air mixture.

PBT: This product is not identified as a PBT/vPvB substance.

Section 3: Composition/information on ingredients

3.2. Mixtures

SAFETY DATA SHEET

BLACK CARPET DYE

Hazardous ingredients:

XYLENE - REACH registered number(s): 01-2119488216-32-XXXX

EINECS CAS PBT / WEL

215-535-7

1330-20-7 -

Flam. Liq. 3: H226; Acute Tox. 4: H332; Acute Tox. 4: H312; Skin Irrit. 2: H315

2-BUTOXYETHANOL - REACH registered number(s): 01-2119475108-36-XXXX

203-905-0 111-76-2 -

ALKANES, C14-17, CHLORO

287-477-0

Acute Tox. 4: H332; Acute Tox. 4: H312; Acute Tox. 4: H302; Eye Irrit. 2: H319; Skin Irrit. 2: H315

85535-85-9 - Lact.: H362; Aquatic Chronic 1: H410; Aquatic Acute 1: H400

ISODECYLOXPROPYLAMINE ACETATE - 28701-67-9 - Acute Tox. 4: H302; Skin Corr. 1: H314; Eye Dam. 1: H318; Aquatic Chronic 1: H410

Section 4: First aid measures

4.1. Description of first aid measures

Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench the affected skin with running water for 10 minutes or longer if substance is still on skin.

Eye contact: Bathe the eye with running water for 15 minutes. Consult a doctor.

Ingestion: Wash out mouth with water. Do not induce vomiting. Drink a large amount of water, and seek medical advice. Consult a doctor.

Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Consult a doctor in case of complaints

4.2. Most important symptoms and effects, both acute and delayed

Skin contact: There may be irritation and redness at the site of contact.

Eye contact: There may be irritation and redness. The eyes may water profusely.

Ingestion: There may be soreness and redness of the mouth and throat. Nausea and stomach pain may occur. There may be vomiting.

Inhalation: There may be irritation of the throat with a feeling of tightness in the chest.

Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

4.3. Indication of anyimmediate medical attention and special treatment needed

Immediate / special treatment: Not applicable.

Section 5: Fire-fighting measures

SAFETY DATA SHEET

BLACK CARPET DYE

5.1. Extinguishing media

Extinguishing media: Alcohol or polymer foam. Carbon dioxide. Dry chemical powder. Use water spray to cool containers.

5.2. Special hazards arising from the substance or mixture

Exposure hazards: Flammable. In combustion emits toxic fumes. Forms explosive air-vapour mixture.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergencyprocedures

Personal precautions: Refer to section 8 of SDS for personal protection details. If outside do not approach from downwind. If outside keep bystanders upwind and away from danger point. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Turn leaking containers leak-side up to prevent the escape of liquid. Eliminate all sources of ignition.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method. Do not use equipment in clean-up procedure which may produce sparks.

6.4. Reference to other sections

Reference to other sections: Refer to section 8 of SDS.

Section 7: Handling and

storage

7.1. Precautions for safe handling

Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Avoid the formation or spread of mists in the air. Smoking is forbidden. Use non-sparking tools.

7.2. Conditions for safe storage, including anyincompatibilities

Storage conditions: Store in a cool, well ventilated area. Keep container tightly closed. Keep away from sources of ignition. Prevent the build up of electrostatic charge in the immediate area. Ensure lighting and electrical equipment are not a source of ignition.

7.3. Specific end use(s)

Specific end use(s): No data available.

SAFETY DATA SHEET

BLACK CARPET DYE

Section 8: Exposure controls/personal protection

8.1. Control parameters

Hazardous ingredients:

Workplace exposure limits:

DNEL/PNEC Values

DNEL / PNEC No data available.

8.2. Exposure controls

Respirable dust:

Engineering measures: Ensure there is sufficient ventilation of the area. Ensure lighting and electrical equipment are not a source of ignition.

Respiratoryprotection: Self-contained breathing apparatus must be available in case of emergency.

Hand protection: Impermeable gloves.

Eye protection: Safety glasses. Ensure eye bath is to hand.

Skin protection: Impermeable protective clothing.

Environmental: Prevent from entering in public sewers or the immediate environment.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State: Liquid

Colour: Black

Odour: Solvents,mixed.

Evaporation rate: Moderate

Oxidising: Non-oxidising (by EC criteria)

Solubilityin water: Not miscible

Also soluble in: Most organic solvents.

Viscosity: Non-viscous

Boiling point/range°C: 117 - 181

Flash point°C: 30

pH: Not applicable.

9.2. Other information

Other information: No data available.

Flammabilitylimits %:lower: 0.8

Relative density: 1.03

VOC g/l: 600 max

SAFETY DATA SHEET

BLACK CARPET DYE

Section 10: Stabilityand reactivity

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

10.2. Chemical stability

Chemical stability: Stable under normal conditions. Stable at room temperature.

10.3. Possibilityof hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions. Decomposition may occur on exposure to conditions or materials listed below.

10.4. Conditions to avoid

Conditions to avoid: Heat. Hot surfaces. Sources of ignition. Flames.

10.5. Incompatible materials

Materials to avoid: Strong oxidising agents. Strong acids.

10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

Section 11: Toxicological information

11.1. Information on toxicological effects

Hazardous ingredients:

Relevant hazards for product:

Acute toxicity (ac. tox. 4)

Skin corrosion/irritation

Serious eye damage/irritation

STOT-single exposure

calculated

calculated

calculated

calculated

STOT-repeated exposure

Excluded hazards for substance:

Germ cell mutagenicity

SAFETY DATA SHEET

BLACK CARPET DYE

- Hazardous: calculated

- Based on available data the classification criteria are not met

Carcinogenicity - Based on available data the classification criteria are not met

Reproductive toxicity - Based on available data the classification criteria are not met

Symptoms / routes of exposure

Skin contact: There may be irritation and redness at the site of contact.

Eye contact: There may be irritation and redness. The eyes may water profusely.

Ingestion: There may be soreness and redness of the mouth and throat. Nausea and stomach pain may occur. There may be vomiting.

Inhalation: There may be irritation of the throat with a feeling of tightness in the chest.

Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

Section 12: Ecological information

12.1. Toxicity

Ecotoxicityvalues: No data available.

12.2. Persistence and degradability

Persistence and degradability: Biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: No bioaccumulation potential.

12.4. Mobilityin soil

Mobility: Readily absorbed into soil.

12.5. Results of PBT and vPvB assessment

PBT identification: This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects: May cause long term adverse effects to aquatic organisms in continuous exposure conditions.

Section 13: Disposal considerations

13.1. Waste treatment methods

Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.

Waste code number: 20 01 27

SAFETY DATA SHEET

BLACK CARPET DYE

Disposal of packaging: Disposal of waste containers must be done in accordance with local and / or national regulations.

NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.

Section 14: Transport information

14.1. UN number

UN number: UN1263

14.2. UN proper shipping name

Shipping name: PAINT

14.3. Transport hazard class(es)

Transport class: 3

14.4. Packing group

Packing group: III

14.5. Environmental hazards

Environmentallyhazardous: No

14.6. Special precautions for user

Special precautions: No special precautions.

Tunnel code: D/E

Transport category: 3

Section 15: Regulatoryinformation

Marine pollutant: Yes

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Specific regulations: Not applicable.

15.2. Chemical SafetyAssessment

Chemical safetyassessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.

Section 16: Other information

Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 2015/830.

All substances in this preparation are registered within UK/EU/EFTA countries under the REACH (UK/EC) (ammended) regulations, EC 1907/2006

*indicates text in the SDS which has changed since the last revision.

IMPORTANT NOTE:

Risk phases in this section belowrelate to the INDIVIDUAL COMPONENTS in the

SAFETY DATA SHEET

BLACK CARPET DYE

formulation when used at their FULL CONCENTRATIONS, and not at the reduced levels in the mixed product.

Phrases used in s.2 and s.3: H226: Flammable liquid and vapour.

H302: Harmful if swallowed.

H302+H332: Harmful if swallowed or if inhaled

H312: Harmful in contact with skin.

H314: Causes severe skin burns and eye damage.

H315: Causes skin irritation.

H318: Causes serious eye damage.

H319: Causes serious eye irritation.

H332: Harmful if inhaled.

H335: May cause respiratory irritation.

H362: May cause harm to breast-fed children.

H373: May cause damage to organs through prolonged or repeated exposure.

H410: Very toxic to aquatic life with long lasting effects.

H412: Harmful to aquatic life with long lasting effects.

Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.

DASH & DOOR CLEANER MSDS

SAFETY DATA SHEET

according to Regulation (EU) 2020/878

Silicone Free Dash & Door

SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking

1.1.Productidentifier

Productname Silicone Free Dash & Door

1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst

ProductUse

[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC35]Washingand cleaningproducts(includingsolventbasedproducts);

[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC35]Washingandcleaningproducts(includingsolventbasedproducts); Description VehicleDash&DoorCleaner.

1.3.Detailsofthesupplierofthesafetydatasheet

Company SUPAGARDLIMITED

Address 19-27GavintonStreet Muirend Glasgow G443EF

Web www.supagard.com

Telephone 01416335933

Fax 01416377219

Email James.Smyth@supagard.com

Emailaddressofthe competentperson James.Smyth@supagard.com

1.4.Emergencytelephonenumber

Emergencytelephonenumber01416335933 8.30amto5.00pm

FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)

Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org

SECTION2:Hazardsidentification

2.1.Classificationofthesubstanceormixture

2.1.2.Classification-EC 1272/2008

2.2.Labelelements

Thisproductdoesnotmeetthecriteriaforclassificationinanyhazardclassaccordingto Regulation(EC)No.1272/2008onclassification,labellingandpackagingofsubstancesand mixtures.

PrecautionaryStatement: Prevention P102-Keepoutofreachofchildren.

PrecautionaryStatement: Response P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.

2.2.Labelelements

Silicone Free Dash & Door

P337+P313-Ifeyeirritationpersists:Getmedicaladvice/attention.

HazardStatement NoSignificantHazard

SUPPLEMENTALHAZARD INFORMATION ingredients-Lessthan5%Non-ionicSurfactants,Preservative:Benzisothiazolinone,Parfum, Linalool.

Contains-Glycerol,2-butoxyethanol.

2.3.Otherhazards

Otherhazards Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.

Furtherinformation

RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.

SECTION3:Composition/informationoningredients

3.2.Mixtures

EC1272/2008 ChemicalName

603-014-00-0111-76-2203-905-001-2119475108-36

SECTION4:Firstaidmeasures

4.1.Descriptionoffirstaidmeasures

Inhalation

Movetheexposedpersontofreshair.

AcuteTox.4:H332;Acute Tox.4:H312;AcuteTox.4: H302;EyeIrrit.2:H319;Skin Irrit.2:H315; 1-10%

Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved.

Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution.

Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed

Inhalation Maycauseirritationtorespiratorysystem.

Eyecontact Maycauseirritationtoeyes.

Skincontact Maycauseskindrynessandirritation.

Ingestion Maycauseirritationtomucousmembranes.

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded TREATSYMPTOMATICALLY.

Inhalation Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.

Eyecontact Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.

Skincontact Seekmedicalattentionifirritationorsymptomspersist.

Ingestion Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.

Generalinformation

Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.

SECTION5:Firefightingmeasures

5.1.Extinguishingmedia

Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.

Silicone Free Dash & Door

5.2.Specialhazardsarisingfromthesubstanceormixture

Noneknown.

5.3.Adviceforfirefighters

Furtherinformation

Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.

Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.

SECTION6:Accidentalreleasemeasures

6.1.Personalprecautions,protectiveequipmentandemergencyprocedures

6.2.Environmentalprecautions

Wearsuitableprotectiveequipment.

Adviselocalauthoritiesiflargespillscannotbecontained.

6.3.Methodsandmaterialforcontainmentandcleaningup

Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.

6.4.Referencetoothersections

Seesection2,7,8,13forfurtherinformation.

SECTION7:Handlingandstorage

7.1.Precautionsforsafehandling

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.

7.2.Conditionsforsafestorage,includinganyincompatibilities

Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.

7.3.Specificenduse(s)

Suitablepackaging

VehicleDash&DoorCleaner.

Plasticcontainers.

SECTION8:Exposurecontrols/personalprotection

8.1.Controlparameters

8.1.1.ExposureLimitValues

Occupationalexposurecontrols.

8.1.1.ExposureLimitValues

2-butoxyethanol

Glycerol(Glycerol,mist)

Silicone Free Dash & Door

WEL8-hrlimitppm:25

WEL15minlimitppm:50

WEL8-hrlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: -

WEL8-hrlimitppm:-

WEL15minlimitppm:-

WEL8-hrlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: -

DNEL:Derivedno-effectlevel.

ExposurePattern-Workers

2-butoxyethanol

Glycerol

Acuteinhalation-Systemic effects 1091mg/m³

Acuteinhalation-Localeffects246mg/m³

Long-term-inhalation-Systemic effects 98mg/m³

Long-term-inhalation-Local effects 56mg/m³

ExposurePattern-Generalpopulation

2-butoxyethanol

Glycerol

8.2.Exposurecontrols

Acuteinhalation-Systemic effects 426mg/m³

Acutedermal-Systemiceffects89mg/kg

Long-term-inhalation-Systemic effects 59mg/m³

Long-term-dermal-Systemic effects 75mg/kg

Long-term-inhalation-Local effects 33mg/m³

Long-term-oral-Systemic effects 229mg/kg

8.2.1.Appropriateengineering controls

Eye/faceprotection

WEL8-hrlimitmg/m3:123

WEL15minlimitmg/m3:101.2

WEL15minlimitmg/m3total inhalabledust: -

WEL15minlimitmg/m3total respirabledust: -

WEL8-hrlimitmg/m3:10

WEL15minlimitmg/m3:-

WEL15minlimitmg/m3total inhalabledust: -

WEL15minlimitmg/m3total respirabledust: -

Acutedermal-Systemiceffects89mg/kg

Long-term-dermal-Systemic effects 125mg/kg

Acuteoral-Systemiceffects26.7mg/kg

Long-term-inhalation-Local effects 147mg/m³

Long-term-oral-Systemiceffects6.3mg/kg

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.

Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.

Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields. Eyewearcomplyingwithanapprovedstandardshouldbewornifariskassessmentindicateseye contactispossible.Thefollowingprotectionshouldbeworn:Wearchemicalsplashgoggles. PersonalprotectiveequipmentforeyeandfaceprotectionshouldcomplywithEuropeanStandard EN166.

8.2.Exposurecontrols

SkinprotectionHandprotection

Silicone Free Dash & Door

Rubbergloves.Chooseglovestoprotecthandsagainstchemicalsdependingontheconcentration andquantityofthehazardoussubstanceandspecifictoplaceofwork.Forspecialapplications, werecommendclarifyingtheresistancetochemicalsoftheaforementionedprotectivegloveswith theglovemanufacturer.

Skinprotection-Other Wearsuitablegloves. Respiratoryprotection Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.

8.2.3.Environmentalexposure controls

Preventfurtherleakageorspillageifsafetodoso.

SECTION9:Physicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties

AppearanceLiquid

ColourWhite/Offwhite OdourPleasant

InitialboilingpointNodataavailable

FlashpointNodataavailable

EvaporationrateNodataavailable

Flammability(solid,gas)Nodataavailable

VapourpressureNodataavailable

RelativeVapourDensityNodataavailable Density/RelativeDensity1-1.01(H2O=1@20°C)

PartitioncoefficientNodataavailable

AutoignitiontemperatureNodataavailable

Viscosity<100centipoise

ExplosivepropertiesNodataavailable

OxidisingpropertiesNodataavailable OdourthresholdNodataavailable pH4-6

MeltingpointNodataavailable

SolubilitySolubleinwater

9.2.Otherinformation

ConductivityNodataavailable

SurfacetensionNodataavailable GasgroupNodataavailable BenzeneContentNodataavailable

LeadcontentNodataavailable

VOC(Volatileorganic compounds) Nodataavailable

9.2.1.Informationwithregardtophysicalhazardclasses Nodataavailable.

9.2.2.Othersafetycharacteristics Nodataavailable.

SECTION10:Stabilityandreactivity

10.1.Reactivity

10.2.Chemicalstability

Stableundernormalconditions.

10.2.Chemicalstability

Silicone

Stableundernormalconditions.

10.3.Possibilityofhazardousreactions

Noneknown.

10.4.Conditionstoavoid

10.5.Incompatiblematerials

Protectfromfrost.

Strongacids.Strongoxidisingagents.

10.6.Hazardousdecompositionproducts

NoHazardousdecompositionproductswhenstoredandhandledcorrectly.

SECTION11:Toxicologicalinformation

11.1Informationonhazardclasses

Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedusingthemethodsoutlinedinRegulation(EC)No1272/2008(CLP).

Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

OralATE=>10,000mg/kg.

DermalATE=>10,000mg/kg.

Inhalation-Dust/MistATE=>20mg/l.

Inhalation-VapoursATE=>20mg/l.

Skincorrosion/irritation basedonavailabledatatheclassificationcriteriaarenotmet.

Seriouseyedamage/irritationbasedonavailabledatatheclassificationcriteriaarenotmet.

Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.

Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet.

Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.

Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet. STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.

Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet.

Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.

11.1.2.Mixtures

11.1.3.HazardInformation

11.1.4.ToxicologicalInformation 2-butoxyethanol

Glycerol

11.2Informationonotherhazards

Nodataavailable.

Nodataavailable.

InhalationRatLC50/1h:>3.1mg/l

OralRatLD50:1200mg/kg

OralRatLD50:27,200.0mg/kg

Nodataavailable.

12.1.Toxicity

DermalRatLD50:>2000mg/kg

InhalationRatLC50/4h:11.0mg/l (vapours)

12.1.Toxicity

2-butoxyethanol

Glycerol

12.2.Persistenceanddegradability

12.3.Bioaccumulativepotential

Partitioncoefficient

Silicone Free Dash & Door

DaphniaEC50/48h:1550.0000mg/l

RainbowtroutLC50/96h:1474mg/l

EC50formarineorfreshwater organisms >100.0000mg/l

DaphniaEC50/48h:10000.0000mg/l

FatheadminnowsLC50/96h= >=885mg/l:

AlgaeEC50/72h:1840mg/

LC50formarineorfreshwater organisms >100.0000mg/l

AlgaeEC50/72h:>2900mg/l

RainbowtroutLC50/96h:54000mg/l

SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.

Nodataisavailableonthisproduct.

12.4.Mobilityinsoil

Thisproductissolubleinwater.

12.6Endocrinedisruptingproperties

Nodataavailable.

12.7.Otheradverseeffects

Nodataisavailableonthisproduct.

SECTION13:Disposalconsiderations

13.1.Wastetreatmentmethods

Generalinformation

Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.

Disposeofincompliancewithalllocalandnationalrequirements. Disposalofpackaging

DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.

SECTION14:Transportinformation

14.1.UNnumber

14.2.UNpropershippingname

14.3.Transporthazardclass(es)

14.4.Packinggroup

14.5.Environmentalhazards

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Silicone Free Dash & Door

14.6.Specialprecautionsforuser

Theproductisnotclassifiedasdangerousforcarriage.

14.7MaritimeTransportinbulkaccordingtoIMOinstruments

Theproductisnotclassifiedasdangerousforcarriage.

SECTION15:Regulatoryinformation

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations

REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.

COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.

COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).

15.2.Chemicalsafetyassessment

Noinformationavailable.

SECTION16:Otherinformation

Otherinformation

TextofHazardStatementsin Section3

Furtherinformation

AcuteTox.4:H302+H312+H332-Harmfulifswallowed,incontactwithskinorifinhaled

SkinIrrit.2:H315-Causesskinirritation.

EyeIrrit.2:H319-Causesseriouseyeirritation.

TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.

DIESEL TREATMENT MSDS

SAFETY DATASHEET

Compilation date: 24/11/2021

Revision date: 14/05/2024

DIESEL FUEL ADDITIVE Page: 1

Revision No: 3

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name: DIESEL FUEL ADDITIVE

Product code: HC1713

Synonyms: PD0418

HC1713 / SUP

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of substance / mixture: PC13: Fuels.

1.3. Details of the supplier of the safetydata sheet

Companyname: SUPAGARD LIMITED

23 Gavinton Street Muirend Glasgow Scotland G44 3EF

Tel: 0141 633 5933

Email: james@supagard.co.uk

1.4. Emergencytelephone number

Emergencytel: 0141 633 5933 (office hours only)

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Classification under CLP: Aquatic Chronic 3: H412; Skin Sens. 1B: H317; STOT SE 3: H336; Asp. Tox. 1: H304

Most important adverse effects: May be fatal if swallowed and enters airways. May cause an allergic skin reaction. May cause drowsiness or dizziness. Harmful to aquatic life with long lasting effects.

2.2. Label elements

Label elements:

Hazard statements: H304: May be fatal if swallowed and enters airways.

H317: May cause an allergic skin reaction.

H336: May cause drowsiness or dizziness.

H412: Harmful to aquatic life with long lasting effects.

Hazard pictograms: GHS07: Exclamation mark

GHS08: Health hazard

DIESEL FUEL ADDITIVE

Signal words: Danger

Precautionarystatements: P102: Keep out of reach of children.

P280: Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor.

P331: Do NOT induce vomiting.

P302+P350: IF ON SKIN: Gently wash with plenty of soap and water.

P403+P233: Store in a well-ventilated place. Keep container tightly closed.

P501: Dispose of contents and container to a hazardous or special waste collection point.

Haz. ingredients (label): HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS; HYDROCARBONS, C10, AROMATICS, >1% NAPHTHALENE; 1H-BENZOTRIAZOLE-1-METHANAMINE (MIXED REACTION MASS ISOMERS)

2.3. Other hazards

PBT: This product is not identified as a PBT/vPvB substance.

Section 3: Composition/information on ingredients

3.2. Mixtures

Hazardous ingredients: HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS - REACH registered number(s): 01-2119456620-43XXXX

926-141-6 64742-47-8 - Asp. Tox. 1: H304; -: EUH066

HYDROCARBONS, C10, AROMATICS, >1% NAPHTHALENE - REACH registered number(s): 01-2119463588-24-XXXX

919-284-0 - - STOT SE 3: H336; Aquatic Chronic 2: H411; Carc. 2: H351; Asp. Tox. 1: H304

C7-9-ALKYL-3-(3,5-DI-TET-BUTYL-4-HYDOXYPHENYL)PROPIONATE - REACH registered number(s): 012119873226-29-XXXX - 125643-6110 - Aquatic Chronic 4: H413

2-ETHYLHEXAN-1-OL - REACH registered number(s): 1-2119487289-20-XXXX

203-234-3 104-76-7 - Skin Irrit. 2: H315; STOT SE 3: H335; Acute Tox. 4: H332; Eye Irrit. 2: H319

1H-BENZOTRIAZOLE-1-METHANAMINE (MIXED REACTION MASS ISOMERS) - REACH registered number(s): 12119982395-25-XXXX

939-700-4 - -

Section 4: First aid measures

4.1. Description of first aid measures

Skin Irrit. 2: H315; Skin Sens. 1B: H317; Aquatic Acute 1: H400; Aquatic Chronic 2: H411

Skin contact: Wash immediately with plenty of soap and water.

Eye contact: Bathe the eye with running water for 15 minutes.

Ingestion: Wash out mouth with water. Do not induce vomiting. If conscious, give half a litre of water to drink immediately. Transfer to hospital as soon as possible.

Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Move to fresh air in case of accidental inhalation of vapours. Consult a doctor.

4.2. Most important symptoms and effects, both acute and delayed

Skin contact: There may be mild irritation at the site of contact.

Eye contact: There may be irritation and redness.

Ingestion: There may be soreness and redness of the mouth and throat. There may be difficulty swallowing. Nausea and stomach pain may occur. There may be vomiting.

Inhalation: Absorption through the lungs can occur causing symptoms similar to those of ingestion.

4.3. Indication of anyimmediate medical attention and special treatment needed

Section 5: Fire-fighting measures

5.1. Extinguishing media

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers.

5.2. Special hazards arising from the substance or mixture

Exposure hazards: In combustion emits toxic fumes.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergencyprocedures

Personal precautions: Refer to section 8 of SDS for personal protection details. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Turn leaking containers leak-side up to prevent the escape of liquid.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method. Wash the ground with an appropriate selfemulsifying solvent.

6.4. Reference to other sections

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements: Avoid the formation or spread of mists in the air. Avoid direct contact with the substance.

7.2. Conditions for safe storage, including anyincompatibilities

Storage conditions: Store in a cool, well ventilated area. Keep container tightly closed.

7.3. Specific end use(s)

Section 8: Exposure controls/personal protection

8.1. Control parameters

Hazardous ingredients:

HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS

Workplace exposure limits:

1200 mg/cm3

HYDROCARBONS, C10, AROMATICS, >1%NAPHTHALENE

UK Not established

DNEL/PNEC Values

DNEL / PNEC No data available.

8.2. Exposure controls

Respirable dust:

Engineering measures: Ensure there is sufficient ventilation of the area.

Respiratoryprotection: Respiratory protection not required.

Hand protection: Protective gloves.

Eye protection: Safety glasses. Ensure eye bath is to hand.

Skin protection: Protective clothing.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State: Liquid

Colour: Pale yellow

Odour: Paraffinic

Evaporation rate: Slow

Solubilityin water: Insoluble

Viscosity: Non-viscous

Boiling point/range°C: >100

Melting point/range°C: No data available.

Flammabilitylimits %:lower: 0.6 upper: 7.0

Flash point°C: 68

Autoflammability°C: No data available.

pH: Not applicable.

Part.coeff. n-octanol/water: No data available.

Relative density: 0.810

VOC g/l: No data available.

9.2. Other information

Other information: No data available.

Section 10: Stabilityand reactivity

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

10.2. Chemical stability

Chemical stability: Stable under normal conditions.

10.3. Possibilityof hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.

10.4. Conditions to avoid

Conditions to avoid: Heat.

10.5. Incompatible materials

Materials to avoid: Strong oxidising agents. Strong acids.

10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

Section 11: Toxicological information

11.1. Information on toxicological effects

Hazardous ingredients:

HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS

ORAL RAT

DIESEL FUEL ADDITIVE

mg/kg

VAPOURS RAT 4H LC50 >5000 mg/kg

HYDROCARBONS, C10, AROMATICS, >1%NAPHTHALENE

DERMAL HMN LD50 Lowacute -

ORAL HMN LD50 Lowacute -

VAPOURS HMN LD50 Lowacute -

Relevant hazards for product:

Respiratory/skin sensitisation - Hazardous: calculated

STOT-single exposure - Hazardous: calculated

Aspiration hazard - Hazardous: calculated

Symptoms / routes of exposure

Skin contact: There may be mild irritation at the site of contact.

Eye contact: There may be irritation and redness.

Ingestion: There may be soreness and redness of the mouth and throat. There may be difficulty swallowing. Nausea and stomach pain may occur. There may be vomiting.

Inhalation: Absorption through the lungs can occur causing symptoms similar to those of ingestion.

Section 12: Ecological information

12.1. Toxicity

Hazardous ingredients:

HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS

Daphnia magna 48H EC50 >250 mg/l

RAINBOW TROUT (Oncorhynchus mykiss) 96H LC50 >1000 mg/l

HYDROCARBONS, C10, AROMATICS, >1%NAPHTHALENE

DAPHNIA 48H EC50 <10 mg/l

RAINBOW TROUT (Oncorhynchus mykiss) 96H LC50

12.2. Persistence and degradability

Persistence and degradability: Biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: No bioaccumulation potential.

12.4. Mobilityin soil

mg/l

Mobility: Readily absorbed into soil. Volatile. Insoluble in water. Floats on water. Vapour is heavier than air.

DIESEL FUEL ADDITIVE

12.5. Results of PBT and vPvB assessment

PBT identification: This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects: Harmful to aquatic organisms.

Section 13: Disposal considerations

13.1. Waste treatment methods

Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.

Recoveryoperations: Solvent reclamation/regeneration.

Waste code number: 20 01 13

Disposal of packaging: Dispose of as normal industrial waste. Clean with water.

NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.

Section 14: Transport information

Transport class: This product does not require a classification for transport.

Section 15: Regulatoryinformation

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Specific regulations: Not applicable.

15.2. Chemical SafetyAssessment

Chemical safetyassessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.

Section 16: Other information

Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 2015/830.

IMPORTANT NOTE:

Risk phases in this section belowrelate to the INDIVIDUAL COMPONENTS in the formulation when used at their FULL CONCENTRATIONS, and not at the reduced levels in the mixed product.

See sections 2 and 3 for the calculated hazard and risk phrases for the blended product. Phrases used in s.2 and s.3: EUH066: Repeated exposure may cause skin dryness or cracking.

H304: May be fatal if swallowed and enters airways.

H315: Causes skin irritation.

H317: May cause an allergic skin reaction.

H319: Causes serious eye irritation.

H332: Harmful if inhaled.

H335: May cause respiratory irritation.

H336: May cause drowsiness or dizziness.

H351: Suspected of causing cancer (if inhaled).

H400: Very toxic to aquatic life.

H411: Toxic to aquatic life with long lasting effects.

H412: Harmful to aquatic life with long lasting effects.

H413: May cause long lasting harmful effects to aquatic life.

Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.

ENGINE FLUSH MSDS

ENGINE FLUSH

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name: ENGINE FLUSH

Product code: HC1714

Synonyms: HC1714 / SUP PD0408

1.2. Relevant identified uses of the substance or mixture and uses advised against

Page: 1

Compilation date: 24/11/2021

Revision date: 14/05/2024

Revision No: 2

Use of substance / mixture: PC35: Washing and cleaning products (including solvent based products).

1.3. Details of the supplier of the safetydata sheet

Companyname: SUPAGARD LIMITED 23 Gavinton Street Muirend Glasgow Scotland G44 3EF

Tel: 0141 633 5933

Email: james@supagard.co.uk

1.4. Emergencytelephone number

Emergencytel: 0141 633 5933 (office hours only)

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Classification under CLP: Asp. Tox. 1: H304; -: EUH066

Most important adverse effects: Repeated exposure may cause skin dryness or cracking. May be fatal if swallowed and enters airways.

2.2. Label elements

Label elements:

Hazard statements: EUH066: Repeated exposure may cause skin dryness or cracking. H304: May be fatal if swallowed and enters airways.

Hazard pictograms: GHS08: Health hazard

ENGINE FLUSH

Signal words: Danger

Precautionarystatements: P102: Keep out of reach of children.

P260: Do not breathe vapours.

P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor.

P331: Do NOT induce vomiting.

P302+P350: IF ON SKIN: Gently wash with plenty of soap and water.

P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Haz. ingredients (label): Contains: HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS

2.3. Other hazards

PBT: This product is not identified as a PBT/vPvB substance.

Section 3: Composition/information on ingredients

3.2. Mixtures

Hazardous ingredients:

HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS - REACH registered number(s): 01-2119456620-43XXXX

64742-47-8 - Asp. Tox. 1: H304; -: EUH066

(2-METHOXY METHYL ETHOXY) PROPANOL - REACH registered number(s): 01-2119450011-60-XXXX 252-104-2 34590-94-8 Substance with a Community workplace exposure limit. -

Section 4: First aid measures

4.1. Description of first aid measures

Skin contact: Wash immediately with plenty of soap and water.

Eye contact: Bathe the eye with running water for 15 minutes.

Ingestion: Wash out mouth with water. Do not induce vomiting. If conscious, give half a litre of water to drink immediately. Transfer to hospital as soon as possible.

Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Move to fresh air in case of accidental inhalation of vapours. Consult a doctor.

4.2. Most important symptoms and effects, both acute and delayed

Skin contact: There may be mild irritation at the site of contact.

Eye contact: There may be irritation and redness.

Ingestion: There may be soreness and redness of the mouth and throat. There may be difficulty swallowing. Nausea and stomach pain may occur. There may be vomiting.

Inhalation: Absorption through the lungs can occur causing symptoms similar to those of ingestion.

4.3. Indication of anyimmediate medical attention and special treatment needed

Section 5: Fire-fighting measures

5.1. Extinguishing media

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers.

5.2. Special hazards arising from the substance or mixture

Exposure hazards: In combustion emits toxic fumes.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergencyprocedures

Personal precautions: Refer to section 8 of SDS for personal protection details. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Turn leaking containers leak-side up to prevent the escape of liquid.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method. Wash the spillage site with large amounts of water.

6.4. Reference to other sections

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements: Avoid the formation or spread of mists in the air. Avoid direct contact with the substance.

7.2. Conditions for safe storage, including anyincompatibilities

Storage conditions: Store in a cool, well ventilated area. Keep container tightly closed.

7.3. Specific end use(s)

Section 8: Exposure controls/personal protection

8.1. Control parameters

ENGINE FLUSH

Hazardous ingredients:

HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS

Workplace exposure limits: State

UK 1200 mg/cm3

(2-METHOXY METHYL ETHOXY) PROPANOL

UK 308mg/m3(50ppm)

DNEL/PNEC Values

DNEL / PNEC No data available.

8.2. Exposure controls

Respirable dust:

Engineering measures: Ensure there is sufficient ventilation of the area.

Respiratoryprotection: Respiratory protection not required.

Hand protection: Protective gloves.

Eye protection: Safety glasses. Ensure eye bath is to hand.

Skin protection: Protective clothing.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State: Liquid

Colour: Colourless

Odour: Paraffinic

Evaporation rate: Slow

Solubilityin water: Emulsifiable

Viscosity: Non-viscous

Boiling point/range°C: 190 - 280

Melting point/range°C: No data available.

Flammabilitylimits %:lower: 0.9 upper: 9.0

Flash point°C: 60 - 93

Autoflammability°C: >200

Part.coeff. n-octanol/water: No data available.

Vapour pressure: No data available.

Relative density: 0.815 pH: Not applicable.

VOC g/l: No data available.

9.2. Other information

Other information: No data available.

Section 10: Stabilityand reactivity

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

10.2. Chemical stability

Chemical stability: Stable under normal conditions.

10.3. Possibilityof hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.

10.4. Conditions to avoid

Conditions to avoid: Heat.

10.5. Incompatible materials

Materials to avoid: Strong oxidising agents. Strong acids.

10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

Section 11: Toxicological information

11.1. Information on toxicological effects

Hazardous ingredients:

HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS

DERMAL RBT LD50 >5000 mg/kg

ORAL RAT LD50 >5000 mg/kg

VAPOURS RAT 4H LC50 >5000 mg/kg

(2-METHOXY METHYL ETHOXY) PROPANOL

ORL RAT

Relevant hazards for product:

Aspiration hazard - Hazardous: calculated

Symptoms / routes of exposure

Skin contact: There may be mild irritation at the site of contact.

Eye contact: There may be irritation and redness.

Ingestion: There may be soreness and redness of the mouth and throat. There may be difficulty swallowing. Nausea and stomach pain may occur. There may be vomiting.

Inhalation: Absorption through the lungs can occur causing symptoms similar to those of ingestion.

Section 12: Ecological information

12.1. Toxicity

Hazardous ingredients:

HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS

Daphnia magna

RAINBOW TROUT (Oncorhynchus mykiss)

(2-METHOXY METHYL ETHOXY) PROPANOL BLUEGILLS

12.2. Persistence and degradability

Persistence and degradability: Biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: No bioaccumulation potential.

12.4. Mobilityin soil

EC50

Mobility: Readily absorbed into soil. Volatile. Soluble in water. Vapour is heavier than air.

12.5. Results of PBT and vPvB assessment

PBT identification: This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects: Negligible ecotoxicity.

Section 13: Disposal considerations

13.1. Waste treatment methods

Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.

Recoveryoperations: Solvent reclamation/regeneration.

Waste code number: 20 01 13

Disposal of packaging: Dispose of as normal industrial waste. Clean with water.

NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.

Section 14: Transport information

Transport class: This product does not require a classification for transport.

Section 15: Regulatoryinformation

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Specific regulations: Not applicable.

15.2. Chemical SafetyAssessment

Chemical safetyassessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.

ENGINE FLUSH

ENGINE FLUSH

Section 16: Other information

Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 2015/830.

IMPORTANT NOTE:

Risk phases in this section belowrelate to the INDIVIDUAL COMPONENTS in the formulation when used at their FULL CONCENTRATIONS, and not at the reduced levels in the mixed product.

See sections 2 and 3 for the calculated hazard and risk phrases for the blended product.

Phrases used in s.2 and s.3: EUH066: Repeated exposure may cause skin dryness or cracking.

H304: May be fatal if swallowed and enters airways.

Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.

EXTERIOR SHINE PLUS MSDS

SAFETY DATASHEET

EXTERIOR SHINE PLUS Page: 1

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name: EXTERIOR SHINE PLUS

Product code: HC8560

Synonyms: HC8560

PD1137

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of substance / mixture: Aerosol cleaner and polish.

1.3. Details of the supplier of the safetydata sheet

Companyname: SUPAGARD LIMITED

23 Gavinton Street

Muirend Glasgow Scotland G44 3EF

Tel: 0141 633 5933

Email: james@supagard.co.uk

1.4. Emergencytelephone number

Emergencytel: 0141 633 5933 (office hours only)

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Classification under CLP: Flam. Aerosol 1: H222; -: EUH066; -: EUH208; -: H229

Compilation date: 19/11/2024

Revision No: 1

Most important adverse effects: Repeated exposure may cause skin dryness or cracking. Contains perfume (containing: linalool,linalyl acetate, benzyl salicylate, limonene). May produce an allergic reaction. Extremely flammable aerosol. Pressurised container: May burst if heated.

2.2. Label elements

Label elements:

Hazard statements: EUH066: Repeated exposure may cause skin dryness or cracking.

EUH208: Contains perfume (containing: linalool,linalyl acetate, benzyl salicylate, limonene). May produce an allergic reaction.

H222: Extremely flammable aerosol.

H229: Pressurised container: May burst if heated.

EXTERIOR SHINE PLUS

Hazard pictograms: GHS02: Flame

Signal words: Danger

Precautionarystatements: P102: Keep out of reach of children.

P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P211: Do not spray on an open flame or other ignition source.

P251: Do not pierce or burn, even after use.

P410+P412: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.

2.3. Other hazards

Other hazards: In use, may form flammable / explosive vapour-air mixture.

PBT: This product is not identified as a PBT/vPvB substance.

Section 3: Composition/information on ingredients

3.2. Mixtures

Hazardous ingredients:

HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS - REACH registered number(s): 01-2119456620-43XXXX

BUTANE, <0.1% 1,3 BUTADIENE - REACH registered number(s): 01-2119474691-32-XXXX 203-448-7 106-97-8 Substance with a Community workplace exposure limit.

PROPANE, <0.1% 1,3 BUTADIENE - REACH registered number(s): 01-2119486944-21-XXXX

200-827-9 74-98-6 Substance with a Community workplace exposure limit. Flam. Gas 1: H220; Press. Gas: H280

PERFUME NEW CAR 445 (CONTAINING: LINALOOL,LINALYL ACETATE, BENZYL SALICYLATE, LIMONENE)

- - - Skin Sens. 1: H317; Aquatic Chronic 2: H411; Skin Irrit. 2: H315; Eye Irrit. 2: H319; Asp. Tox. 1: H304

Section 4: First aid measures

4.1. Description of first aid measures

Skin contact: Wash immediately with plenty of soap and water. Eye contact: Bathe the eye with running water for 15 minutes.

Ingestion: Wash out mouth with water. Do not induce vomiting. If conscious, give half a litre of water to drink immediately.

EXTERIOR SHINE PLUS

Inhalation: Consult a doctor in case of complaints

4.2. Most important symptoms and effects, both acute and delayed

Skin contact: There may be mild irritation at the site of contact.

Eye contact: There may be irritation and redness.

Ingestion: There may be irritation of the throat.

Inhalation: No symptoms.

4.3. Indication of anyimmediate medical attention and special treatment needed

Immediate / special treatment: Not applicable.

Section 5: Fire-fighting measures

5.1. Extinguishing media

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers. Alcohol resistant foam. Carbon dioxide.

5.2. Special hazards arising from the substance or mixture

Exposure hazards: In combustion emits toxic fumes. Highly flammable.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergencyprocedures

Personal precautions: Refer to section 8 of SDS for personal protection details. Turn leaking containers leakside up to prevent the escape of liquid.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method.

6.4. Reference to other sections

Reference to other sections: Refer to section 8 of SDS.

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements: Smoking is forbidden. Use non-sparking tools. Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Avoid the formation or spread of mists in the air.

EXTERIOR SHINE PLUS

7.2. Conditions for safe storage, including anyincompatibilities

Storage conditions: Store in a cool, well ventilated area. Keep container tightly closed.

7.3. Specific end use(s)

Specific end use(s): No data available.

Section 8: Exposure controls/personal protection

8.1. Control parameters

Hazardous ingredients:

HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS

Workplace

Respirable dust:

<0.1%1,3 BUTADIENE

<0.1%1,3 BUTADIENE UK Asphyxiating Asphyxiating

DNEL/PNEC Values

DNEL / PNEC No data available.

8.2. Exposure controls

Engineering measures: Ensure there is sufficient ventilation of the area. Ensure lighting and electrical equipment are not a source of ignition.

Respiratoryprotection: Respiratory protection not required.

Hand protection: Protective gloves.

Eye protection: Safety glasses. Ensure eye bath is to hand.

Skin protection: Protective clothing.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State: Aerosol

Colour: White

Odour: Perfumed

Evaporation rate: Slow

Solubilityin water: Emulsifiable

Viscosity: Non-viscous

Boiling point/range°C: No data available.

Melting point/range°C: No data available.

Flammabilitylimits %:lower: 0.9 upper: 9.0

Flash point°C: -40

Autoflammability°C: >230

EXTERIOR SHINE PLUS

Part.coeff. n-octanol/water: No data available.

Vapour pressure: No data available.

Relative density: No data available. pH: Not applicable.

VOC g/l: No data available.

9.2. Other information

Other information: No data available.

Section 10: Stabilityand reactivity

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

10.2. Chemical stability

Chemical stability: Stable under normal conditions.

10.3. Possibilityof hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions. Decomposition may occur on exposure to conditions or materials listed below.

10.4. Conditions to avoid

Conditions to avoid: Heat. Sources of ignition. Flames.

10.5. Incompatible materials

Materials to avoid: Strong oxidising agents. Strong acids.

10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

Section 11: Toxicological information

11.1. Information on toxicological effects

Hazardous ingredients: HYDROCARBONS,

Toxicityvalues: No data available.

Symptoms / routes of exposure

Skin contact: There may be mild irritation at the site of contact.

Eye contact: There may be irritation and redness.

Ingestion: There may be irritation of the throat.

Inhalation: No symptoms.

EXTERIOR SHINE PLUS

Section 12: Ecological information

12.1. Toxicity

Hazardous ingredients:

HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS

Daphnia magna

RAINBOW TROUT (Oncorhynchus mykiss)

12.2. Persistence and degradability

Persistence and degradability: Biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: No bioaccumulation potential.

12.4. Mobilityin soil

EC50

LC50

Mobility: Readily absorbed into soil.

12.5. Results of PBT and vPvB assessment

PBT identification: This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects: Negligible ecotoxicity.

Section 13: Disposal considerations

13.1. Waste treatment methods

Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.

Recoveryoperations: Recycling/reclamation of metals and metal compounds.

Waste code number: 16 05 05

Disposal of packaging: Dispose of as normal industrial waste. Empty cans must not be burned because of explosion hazard.

NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.

Section 14: Transport information

14.1. UN number

UN number: UN1950

14.2. UN proper shipping name

Shipping name: AEROSOLS

EXTERIOR SHINE PLUS

14.3. Transport hazard class(es)

Transport class: 2

14.4. Packing group

14.5. Environmental hazards

Environmentallyhazardous: No

14.6. Special precautions for user

Special precautions: No special precautions.

Tunnel code: D

Transport category: 2

Section 15: Regulatoryinformation

Marine pollutant: No

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Specific regulations: Not applicable.

15.2. Chemical SafetyAssessment

Chemical safetyassessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.

Section 16: Other information

Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 2015/830.

IMPORTANT NOTE:

Risk phases in this section belowrelate to the INDIVIDUAL COMPONENTS in the formulation when used at their FULL CONCENTRATIONS, and not at the reduced levels in the mixed product.

See sections 2 and 3 for the calculated hazard and risk phrases for the blended product.

Phrases used in s.2 and s.3: EUH066: Repeated exposure may cause skin dryness or cracking.

EUH208: Contains perfume (containing: linalool,linalyl acetate, benzyl salicylate, limonene). May produce an allergic reaction.

H220: Extremely flammable gas.

H222: Extremely flammable aerosol.

H229: Pressurised container: May burst if heated.

H304: May be fatal if swallowed and enters airways.

H315: Causes skin irritation.

H317: May cause an allergic skin reaction.

H319: Causes serious eye irritation.

H411: Toxic to aquatic life with long lasting effects.

EXTERIOR SHINE PLUS

Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.

GLASS CLEANER MSDS

SAFETY DATA SHEET

according to Regulation (EU) 2020/878

Glass Cleaner

SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking

1.1.Productidentifier

Productname Glass Cleaner

1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst

ProductUse

[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC35]Washingand cleaningproducts(includingsolventbasedproducts);

[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC35]Washingandcleaningproducts(includingsolventbasedproducts);

Description Thispowerfulcleanerbreaksthrougheventhetoughestdirtandgrimeonscreens,windowsand mirrors,leavingasparklingstreakfreefinish.

1.3.Detailsofthesupplierofthesafetydatasheet

Company SUPAGARDLIMITED

Address 19-27GavintonStreet Muirend Glasgow G443EF

Web www.supagard.com

Telephone 01416335933

Fax 01416377219

Email James.Smyth@supagard.com

Emailaddressofthe competentperson James.Smyth@supagard.com

1.4.Emergencytelephonenumber

Emergencytelephonenumber01416335933 8.30amto5.00pm

FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)

Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org

SECTION2:Hazardsidentification

2.1.Classificationofthesubstanceormixture

2.1.2.Classification-EC 1272/2008 Flam.Liq.3:H226;EyeIrrit.2:H319;

2.2.Labelelements

2.2.Labelelements

Hazardpictograms

SignalWord Warning

Glass Cleaner

HazardStatement Flam.Liq.3:H226-Flammableliquidandvapour. EyeIrrit.2:H319-Causesseriouseyeirritation.

PrecautionaryStatement: Prevention

P102-Keepoutofreachofchildren.

P210-Keepawayfromheat,hotsurfaces,sparks,openflamesandotherignitionsources.No smoking.

P264-Washhandsandothercontactedskinthoroughlyafterhandling.

PrecautionaryStatement: Response P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.

PrecautionaryStatement: Storage P403+P235-Storeinawell-ventilatedplace.Keepcool.

PrecautionaryStatement: Disposal

SUPPLEMENTALHAZARD INFORMATION

2.3.Otherhazards

Otherhazards

Furtherinformation

P501-Disposeofcontents/containertoanapproveddisposalsite,inaccordancewithlocal regulations.

IngredientsasrequiredbyRegulation(EC)No648/2004:. IsopropylAlcohol,ButyleneGlycol,Lessthan5%Non-ionicSurfactants.

Contains-Propan-2-ol,2-butoxyethanol.

Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.

RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.

SECTION3:Composition/informationoningredients

3.2.Mixtures

EC1272/2008

ChemicalName IndexNo.CASNo.ECNo.

propan-2-ol

603-117-00-067-63-0200-661-701-2119457558-25

Flam.Liq.2:H225;EyeIrrit. 2:H319;STOTSE3:H336; 1-10% 2-butoxyethanol 603-014-00-0111-76-2203-905-001-2119475108-36

AcuteTox.4:H332;Acute Tox.4:H312;AcuteTox.4: H302;EyeIrrit.2:H319;Skin Irrit.2:H315; 1-10%

SECTION4:Firstaidmeasures

4.1.Descriptionoffirstaidmeasures

Inhalation Movetheexposedpersontofreshair.

Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved. Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution.

Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed

Inhalation Highconcentrationofvapourinenclosedspacemaycauseirritation,headachesandnausea.May causeirritationtorespiratorysystem.

Eyecontact Irritatingtoeyes.

Skincontact Maycauseskindrynessandirritation.Prolongedcontactmaycausedefattingoftheskin.

Glass Cleaner

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed Ingestion Maycauseirritationtomucousmembranes.

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded TREATSYMPTOMATICALLY.

Inhalation

Eyecontact

Skincontact

Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.

Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.

Seekmedicalattentionifirritationorsymptomspersist.

Ingestion Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.

Generalinformation

Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.

SECTION5:Firefightingmeasures

5.1.Extinguishingmedia

Flammableliquid.Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthe surroundingenvironment.

5.2.Specialhazardsarisingfromthesubstanceormixture

Flammableliquidandvapour.

5.3.Adviceforfirefighters

Furtherinformation

Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.

Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.

SECTION6:Accidentalreleasemeasures

6.1.Personalprecautions,protectiveequipmentandemergencyprocedures

Wearsuitableprotectiveequipment.Flammableliquid.Avoidsparks,flames,heatandsourcesof ignition.

6.2.Environmentalprecautions

Adviselocalauthoritiesiflargespillscannotbecontained.

6.3.Methodsandmaterialforcontainmentandcleaningup

Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelledcontainersfor disposal.Avoidsparks,flames,heatandsourcesofignition.

6.4.Referencetoothersections

Seesection2,7,8,13forfurtherinformation.

SECTION7:Handlingandstorage

7.1.Precautionsforsafehandling

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.

7.2.Conditionsforsafestorage,includinganyincompatibilities

Flammableliquid.Avoidsparks,flames,heatandsourcesofignition.AvoidstoringindirectSun Light.Storeinawell-ventilatedplace.Keepcool.Storeinoriginalcontainer.Keepcontainertightly closed.Keepawayfromcombustiblematerial.Keepoutofthereachofchildren.

7.3.Specificenduse(s)

Thispowerfulcleanerbreaksthrougheventhetoughestdirtandgrimeonscreens,windowsand

Glass Cleaner

7.3.Specificenduse(s)

mirrors,leavingasparklingstreakfreefinish. Suitablepackaging

Plasticcontainers.

SECTION8:Exposurecontrols/personalprotection

8.1.Controlparameters

8.1.1.ExposureLimitValues

2-butoxyethanol

propan-2-ol

Occupationalexposurecontrols.

WEL8-hrlimitppm:25

WEL15minlimitppm:50

WEL8-hrlimitmg/m3:123

WEL15minlimitmg/m3:101.2

WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -

WEL8-hrlimitppm:400

WEL15minlimitppm:500

WEL8-hrlimitmg/m3:999

WEL15minlimitmg/m3:1250

WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -

DNEL:Derivedno-effectlevel.

ExposurePattern-Workers

2-butoxyethanol

propan-2-ol

Acuteinhalation-Systemic effects 1091mg/m³

Acuteinhalation-Localeffects246mg/m³

Long-term-inhalation-Systemic effects 98mg/m³

Long-term-inhalation-Systemic effects 500mg/m³

Long-term-dermal-Systemic effects 888mg/kg

ExposurePattern-Generalpopulation

2-butoxyethanol

propan-2-ol

8.2.Exposurecontrols

Acuteinhalation-Systemic effects 426mg/m³

Acutedermal-Systemiceffects89mg/kg

Long-term-inhalation-Systemic effects 59mg/m³

Long-term-dermal-Systemic effects 75mg/kg

Long-term-inhalation-Systemic effects 89mg/m³

Long-term-dermal-Systemic effects 319mg/kg

Acutedermal-Systemiceffects89mg/kg

Long-term-dermal-Systemic effects 125mg/kg

Acuteoral-Systemiceffects26.7mg/kg

Long-term-inhalation-Local effects 147mg/m³

Long-term-oral-Systemiceffects6.3mg/kg

Long-term-oral-Systemiceffects26mg/kg

8.2.Exposurecontrols

8.2.1.Appropriateengineering controls

Glass Cleaner

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.

Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.

Eye/faceprotection Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields.

SkinprotectionHandprotection Rubbergloves.

Respiratoryprotection Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.

8.2.3.Environmentalexposure controls Preventfurtherleakageorspillageifsafetodoso.

SECTION9:Physicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties

AppearanceLiquid ColourClear/Blue

OdourAlcoholic pH6-9

MeltingpointNodataavailable

Viscosity<50centipoise

ExplosivepropertiesNodataavailable OxidisingpropertiesNodataavailable

InitialboilingpointNodataavailable Flashpoint40°C

EvaporationrateNodataavailable Flammability(solid,gas)Nodataavailable

VapourFlammabilityNodataavailable VapourpressureNodataavailable RelativeVapourDensityNodataavailable Density/RelativeDensityNodataavailable PartitioncoefficientNodataavailable

AutoignitiontemperatureNodataavailable SolubilitySolubleinwater

9.2.Otherinformation

ConductivityNodataavailable SurfacetensionNodataavailable Specificgravity0.98-0.99g/cm³ GasgroupNotapplicable. BenzeneContentNotapplicable. LeadcontentNotapplicable. VOC(Volatileorganic compounds) Nodataavailable

Watersolubility Soluble.

9.2.1.Informationwithregardtophysicalhazardclasses Nodataisavailableonthisproduct.

9.2.2.Othersafetycharacteristics

Nodataisavailableonthisproduct.

SECTION10:Stabilityandreactivity

10.1.Reactivity

10.2.Chemicalstability

Flammableliquid.Stableundernormalconditions.

Flammableliquid.Stableundernormalconditions.

10.3.Possibilityofhazardousreactions

Oxidisingagents.Combustiblematerials.

10.4.Conditionstoavoid

10.5.Incompatiblematerials

Avoidsparks,flames,heatandsourcesofignition.AvoidstoringindirectSunLight.

Oxidisingagents.

10.6.Hazardousdecompositionproducts

NoHazardousdecompositionproductswhenstoredandhandledcorrectly.

SECTION11:Toxicologicalinformation

11.1Informationonhazardclasses

Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedusingthemethodsoutlinedinRegulation(EC)No1272/2008(CLP).

Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

OralATE=>10,000mg/kg.

DermalATE=>10,000mg/kg.

Inhalation-Dust/MistATE=>20mg/l.

Skincorrosion/irritation basedonavailabledatatheclassificationcriteriaarenotmet.

Seriouseyedamage/irritationEyeIrrit.2:H319-Causesseriouseyeirritation.

Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.

Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet.

Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.

Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.

Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet.

Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.

11.1.2.Mixtures

11.1.3.HazardInformation

11.1.4.ToxicologicalInformation

2-butoxyethanol

Nodataavailable.

Nodataavailable.

DermalRatLD50:1100mg/kg

InhalationRatLC50/4h:11.0mg/l propan-2-ol

InhalationRatLC50/6h:>10000ppm

DermalRabbitLD50:13900mg/kg

OralRatLD50:1300mg/kg

OralRatLD50:5840mg/kg

11.2Informationonotherhazards

Nodataisavailableonthisproduct.

SECTION12:Ecologicalinformation

12.1.Toxicity

2-butoxyethanol

12.2.Persistenceanddegradability

12.3.Bioaccumulativepotential

Partitioncoefficient

DaphniaEC50/48h:1550.0000mg/l

RainbowtroutLC50/96h:1474mg/l

DaphniaEC50/48h:10000.0000mg/l

FatheadminnowsLC50/96h:9640mg/l

AlgaeEC50/72h:1840mg/

FishLC50/96h:4200.0000mg/l

12.4.Mobilityinsoil

SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.

Theproductisnotbioaccumulating.

StoneacreGlassCleanerNodataavailable propan-2-ol0.05logP 2-butoxyethanol0.8logP

Thisproductissolubleinwater.

12.5.ResultsofPBTandvPvBassessment

Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.

12.6Endocrinedisruptingproperties

Nodataisavailableonthisproduct.

12.7.Otheradverseeffects

Nodataisavailableonthisproduct.

SECTION13:Disposalconsiderations

13.1.Wastetreatmentmethods

Generalinformation

Disposalofpackaging

Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.

Disposeofincompliancewithalllocalandnationalrequirements.

DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.

SECTION14:Transportinformation

Hazardpictograms

14.1.UNnumber

Glass Cleaner

14.1.UNnumber UN1993

14.2.UNpropershippingname

14.3.Transporthazardclass(es)

ADR/RID 3

SubsidiaryriskIMDG 3

SubsidiaryriskIATA 3

Subsidiaryrisk -

14.4.Packinggroup

Packinggroup III

14.5.Environmentalhazards

Environmentalhazards No

Marinepollutant No

14.6.Specialprecautionsforuser

Noadditionalspecialprecautions.

14.7MaritimeTransportinbulkaccordingtoIMOinstruments

Notapplicable.

ADR/RID

HazardID 30

TunnelCategory (D/E)

IMDG

EmSCode F-ES-E

IATA

PackingInstruction(Cargo)366

Maximumquantity 220L

PackingInstruction (Passenger) 355

Maximumquantity 60L

SECTION15:Regulatoryinformation

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations

REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.

COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.

Glass Cleaner

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture

COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).

15.2.Chemicalsafetyassessment

Noinformationavailable.

SECTION16:Otherinformation

Otherinformation

Revision

Thisdocumentdiffersfromthepreviousversioninthefollowingareas:. 2-Otherhazards.

2-Furtherinformation.

2-SUPPLEMENTALHAZARDINFORMATION. 9-9.2.2.Othersafetycharacteristics.

9-9.2.1.Informationwithregardtophysicalhazardclasses. 11-Acutetoxicity.

11-Repeatedorprolongedexposure.

11-11.2Informationonotherhazards. 12-12.1.Toxicity.

12-12.6Endocrinedisruptingproperties. 12-12.7.Otheradverseeffects.

15-Regulations.

Datasources ClassificationandProcedureusedtoderivetheclassificationformixturesaccordingtoRegulation (EC)No.1272/2008,asretainedandamendedinUKlaw.

Flam.Liq.3:H226-Flammableliquidandvapour.-FlashPoint-40degC. EyeIrrit.2:H319-Causesseriouseyeirritation.-CalculationMethod.

TextofHazardStatementsin Section3

Flam.Liq.2:H225-Highlyflammableliquidandvapour. EyeIrrit.2:H319-Causesseriouseyeirritation.

STOTSE3:H336-Maycausedrowsinessordizziness.

AcuteTox.4:H302+H312+H332-Harmfulifswallowed,incontactwithskinorifinhaled SkinIrrit.2:H315-Causesskinirritation.

Furtherinformation

TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.

HAND BARRIER CREAM MSDS

SAFETY DATA SHEET

according to Regulation (EU) 2015/830

Hand Barrier Cream

SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking

1.1.Productidentifier

Productname Productcode Hand Barrier Cream H090

1.3.Detailsofthesupplierofthesafetydatasheet

Company Address

Web Telephone Fax

Email

Emailaddressofthe competentperson

1.4.Emergencytelephonenumber

SUPAGARD LTD 19-29 GAVINTON STREET MUIREND GLASGOW G44 3EF

WWW.SUPAGARD.COM +0141 633 5933

james.smyth@supagard.com james.smyth@supagard.com

Emergencytelephonenumber 0141 633 5933 8.30 am - 5.30 pm

SECTION2:Hazardsidentification

2.1.Classificationofthesubstanceormixture

2.1.2.Classification-EC 1272/2008

2.2.Labelelements

Hazardpictograms

EyeIrrit.2:H319;AquaticChronic3:H412;

SignalWord Warning

HazardStatement EyeIrrit.2:H319-Causesseriouseyeirritation. AquaticChronic3:H412-Harmfultoaquaticlifewithlonglastingeffects.

PrecautionaryStatement: Prevention P264-Washthoroughlyafterhandling. P273-Avoidreleasetotheenvironment. P280-Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection.

PrecautionaryStatement: Response P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.

2.2.Labelelements

PrecautionaryStatement: Disposal

Hand Barrier Cream

P337+P313-Ifeyeirritationpersists:Getmedicaladvice/attention.

P501-Disposeofcontents/containerto

SECTION3:Composition/informationoningredients

3.2.Mixtures

EC1272/2008

SECTION4:Firstaidmeasures

4.1.Descriptionoffirstaidmeasures

Eyecontact

Maycauseirritationtoeyes.Rinseimmediatelywithplentyofwaterfor15minutesholdingthe eyelidsopen.Seekmedicalattentionifirritationorsymptomspersist.

Skincontact Noirritationexpected.Maycauseallergicreactionsinsusceptiblepeople.Washoffimmediately withplentyofsoapandwater.Seekmedicalattentionifirritationorsymptomspersist.

Ingestion

Maycauseirritationtomucousmembranes.DONOTINDUCEVOMITING.Seekmedicalattention ifirritationorsymptomspersist.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed

Inhalation

Nosensitizatoneffectsreported.

Skincontact Washwithwater.

Ingestion

Ifswallowed,donotinducevomiting:seekmedicaladviceimmediatelyandshowthiscontaineror label.

SECTION5:Firefightingmeasures

5.1.Extinguishingmedia

Useextinguishingmediaappropriatetothesurroundingfireconditions.

5.2.Specialhazardsarisingfromthesubstanceormixture

Burningproducesirritating,toxicandobnoxiousfumes.

5.3.Adviceforfirefighters

Wearsuitablerespiratoryequipmentwhennecessary.

SECTION6:Accidentalreleasemeasures

6.1.Personalprecautions,protectiveequipmentandemergencyprocedures

6.2.Environmentalprecautions

Ensureadequateventilationoftheworkingarea.

Donotallowproducttoenterdrains.Preventfurtherspillageifsafe.

6.3.Methodsandmaterialforcontainmentandcleaningup

Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelledcontainersfor disposal.Cleanspillageareathoroughlywithplentyofwater.

SECTION7:Handlingandstorage

Hand Barrier Cream

7.1.Precautionsforsafehandling

Avoidcontactwitheyes.AdoptbestManualHandlingconsiderationswhenhandling,carryingand dispensing.

7.2.Conditionsforsafestorage,includinganyincompatibilities

Keepinacool,dry,wellventilatedarea.Keepcontainerstightlyclosed.Storeincorrectlylabelled containers.

7.3.Specificenduse(s)

Furtherinformation

Avoidcontactwitheyes.Keepoutofthereachofchildren.

Astheapplicationofproductsisoutsideourcontrol,theinformationisgivenwithoutlegal resposibility.

SECTION8:Exposurecontrols/personalprotection

8.1.Controlparameters

8.1.1.ExposureLimitValues

Glycerol(Glycerol,mist)

8.2.Exposurecontrols

Eye/faceprotection

WEL8-hrlimitppm:-

WEL15minlimitppm:-

WEL8-hrlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: -

Incaseofsplashing,wear:.Approvedsafetygoggles.

SECTION9:Physicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties

AppearanceViscousliquid.

ColourWhite OdourOdourless

OdourthresholdNotapplicable. pH6.5-7.5

MeltingpointNotdetermined

InitialboilingpointNotdetermined

FlashpointNotapplicable. EvaporationrateNotdetermined

Flammability(solid,gas)Notapplicable.

VapourpressureNotapplicable. VapourdensityNotapplicable. Relativedensity0.9-1

PartitioncoefficientNodataavailable

AutoignitiontemperatureNotapplicable. ViscosityNotdetermined

ExplosivepropertiesNotapplicable. OxidisingpropertiesNodataavailable

SolubilitySlightlymiscibleinwater

9.2.Otherinformation

WEL8-hrlimitmg/m3:10

WEL15minlimitmg/m3:-

WEL15minlimitmg/m3total inhalabledust: -

WEL15minlimitmg/m3total respirabledust: -

Hand Barrier Cream

9.2.Otherinformation

ConductivityNotdetermined

SurfacetensionNotdetermined

GasgroupNotapplicable.

BenzeneContentNotapplicable.

LeadcontentNotapplicable. VOC(Volatileorganic compounds) Notapplicable.

SECTION10:Stabilityandreactivity

10.2.Chemicalstability

Stableundernormalconditions.

10.3.Possibilityofhazardousreactions

NoSignificantHazard.

10.4.Conditionstoavoid

10.5.Incompatiblematerials

DoNOTallowtofreeze.Protectfromfrost.

NoSignificantHazard.

10.6.Hazardousdecompositionproducts

Willnotdecomposeifstoredandusedasrecommended.

SECTION11:Toxicologicalinformation

11.1.Informationontoxicologicaleffects

Noknownadversehealtheffects.

Skincorrosion/irritation Noirritationexpected.NoSignificantHazard.

Seriouseyedamage/irritationMaycauseirritationtoeyes.

Respiratoryorskin sensitisation Nosensitizatoneffectsreported.NoSignificantHazard.

Germcellmutagenicity Nomutageniceffectsreported.

Carcinogenicity Nocarcinogeniceffectsreported.

Reproductivetoxicity Noteratogeniceffectsreported. Repeatedorprolonged exposure Noirritationexpected.

SECTION12:Ecologicalinformation

12.2.Persistenceanddegradability

Nodataisavailableonthisproduct.

12.3.Bioaccumulativepotential

Partitioncoefficient

12.4.Mobilityinsoil

Nodataisavailableonthisproduct.

No data available

Nodataisavailableonthisproduct.

12.5.ResultsofPBTandvPvBassessment Notdetermined.

12.6.Otheradverseeffects

Hand Barrier Cream

onlyappliestoproductinverylargebulkquantities.Maycauselong-termadverseeffectsinthe environment.

SECTION13:Disposalconsiderations

Generalinformation

Disposalmethods

Disposalofpackaging

Disposeofincompliancewithalllocalandnationalregulations.

Forsmallquantities:.Theproductisclassifiedasnonhazardous.onlyappliestoproductinvery largebulkquantities.Donotemptyintodrains;disposeofthismaterialanditscontainerinasafe way.

Canberecycledifincompliancewith.localandnationalregulations.

SECTION14:Transportinformation

14.1.UNnumber

14.2.UNpropershippingname

14.3.Transporthazardclass(es)

14.4.Packinggroup

14.5.Environmentalhazards

14.6.Specialprecautionsforuser

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage. Noprecautionsrequiredtobementioned.

14.7.TransportinbulkaccordingtoAnnexIIofMARPOL73/78andtheIBCCode

Theproductisnotclassifiedasdangerousforcarriage. Notnormallyrequired.

Furtherinformation

Theproductisnotclassifiedasdangerousforcarriage.

SECTION15:Regulatoryinformation

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.REGULATION(EC) No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCILof18December2006 concerningtheRegistration,Evaluation,AuthorisationandRestrictionofChemicals(REACH), establishingaEuropeanChemicalsAgency,amendingDirective1999/45/ECandrepealing CouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94aswellas CouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand 2000/21/EC.ThisproductMSDShasbeencompiledinrelationtoECNo:1272/2008CLP Regulations.

Hand Barrier Cream

SECTION16:Otherinformation

Otherinformation

Revision

TextofHazardStatementsin

Section3

Furtherinformation

Thisdocumentdiffersfromthepreviousversioninthefollowingareas:. 11-Seriouseyedamage/irritation. 12-12.6.Otheradverseeffects. 13-Disposalmethods.

EyeDam.1:H318-Causesseriouseyedamage. AquaticChronic1:H410-Verytoxictoaquaticlifewithlonglastingeffects.

TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.

HAND CLEANER MSDS

SAFETY DATA SHEET

according to Regulation (EU) 2015/830

HAND CLEANER

SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking

1.1.Productidentifier

Productname Productcode HAND CLEANER H058

1.3.Detailsofthesupplierofthesafetydatasheet Company Address

Web Telephone Fax

Email

Emailaddressofthe competentperson 19-29 GAVINTON STREET MUIREND GLASGOW G44 3EF WWW.SUPAGARD.COM + 0141 633 5933

james.smyth@supagard.com james.smyth@supagard.com

1.4.Emergencytelephonenumber

Emergencytelephonenumber +44 (0)1939 232326 9.00 am - 5.00 pm

SECTION2:Hazardsidentification

2.1.Classificationofthesubstanceormixture

2.1.2.Classification-EC 1272/2008

AcuteTox.4:H302;EyeIrrit.2:H319;AquaticChronic3:H412; 2.2.Labelelements

Hazardpictograms

SignalWord Warning

HazardStatement

PrecautionaryStatement: Prevention

AcuteTox.4:H302-Harmfulifswallowed. EyeIrrit.2:H319-Causesseriouseyeirritation. AquaticChronic3:H412-Harmfultoaquaticlifewithlonglastingeffects.

P264 - Wash thoroughly after handling.

P270 - Do no eat, drink or smoke when using this product. P273 - Avoid release to the environment.

P280 - Wear protective clothing.

2.2.Labelelements

PrecautionaryStatement: Response

PrecautionaryStatement: Disposal

HAND CLEANER

P301+P312-IFSWALLOWED:CallaPOISONCENTER/doctor//ifyoufeelunwell.

P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing. P330-Rinsemouth.

P337+P313-Ifeyeirritationpersists:Getmedicaladvice/attention.

P501-Disposeofcontents/containertoanapprovedlandfillsite(inaccordancewith local/regional/national/internationalregulation).

SECTION3:Composition/informationoningredients

3.2.Mixtures

EC1272/2008

EyeIrrit.2:H319;1-10%

EyeIrrit.2:H319;1-10%

Sens.1:H317; 0-0.5%

Hazardousingredients

Nonhazardous.

SECTION4:Firstaidmeasures

4.1.Descriptionoffirstaidmeasures

Inhalation

Eyecontact

Skincontact

Ingestion

Maycauseirritationtomucousmembranes.Movetheexposedpersontofreshair.

Maycauseirritationtoeyes.Rinseimmediatelywithplentyofwaterfor15minutesholdingthe eyelidsopen.Seekmedicalattentionifirritationorsymptomspersist.

Maycausesensitisationbyskincontact.Noirritationexpected.Washwithwater.Seekmedical attentionifirritationorsymptomspersist.

Maycauseirritationtomucousmembranes.DONOTINDUCEVOMITING.Seekmedicalattention ifirritationorsymptomspersist.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed

Inhalation Noirritationexpected.

Eyecontact

Rinseimmediatelywithplentyofwaterfor15minutesholdingtheeyelidsopen.Seekmedical attentionifirritationorsymptomspersist.

Skincontact Washwithwater.

Ingestion

Ingestionmaycausenauseaandvomiting.Ifswallowed,donotinducevomiting:seekmedical adviceimmediatelyandshowthiscontainerorlabel.

SECTION5:Firefightingmeasures

5.1.Extinguishingmedia

Useextinguishingmediaappropriatetothesurroundingfireconditions.

5.2.Specialhazardsarisingfromthesubstanceormixture

Burningproducesirritating,toxicandobnoxiousfumes.

5.3.Adviceforfirefighters

Wearsuitablerespiratoryequipmentwhennecessary.

SECTION6:Accidentalreleasemeasures

HAND CLEANER

6.1.Personalprecautions,protectiveequipmentandemergencyprocedures

6.2.Environmentalprecautions

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.

Donotallowproducttoenterdrains.Preventfurtherspillageifsafe.

6.3.Methodsandmaterialforcontainmentandcleaningup

Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelledcontainersfor disposal.Cleanspillageareathoroughlywithplentyofwater.

6.4.Referencetoothersections

Noknownadverseenvironmentaleffects.Noknownadversehealtheffects.NoSignificantHazard.

SECTION7:Handlingandstorage

7.1.Precautionsforsafehandling

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.

7.2.Conditionsforsafestorage,includinganyincompatibilities

Keepinacool,dry,wellventilatedarea.Keepcontainerstightlyclosed.Storeincorrectlylabelled containers.

7.3.Specificenduse(s)

Cleaning.

SECTION8:Exposurecontrols/personalprotection

8.2.Exposurecontrols

8.2.1.Appropriateengineering controls Ensureadequateventilationoftheworkingarea.

8.2.2.Individualprotection measures

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.

Eye/faceprotection Incaseofsplashing,wear:.Approvedsafetygoggles. SkinprotectionHandprotection Noprecautionsrequiredtobementioned.

SECTION9:Physicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties

AppearanceViscousliquid.

ColourOrange OdourPleasant

pH6.0+/-0.5

MeltingpointNotdetermined

InitialboilingpointNotdetermined

FlashpointNotdetermined

EvaporationrateNodataavailable

Flammability(solid,gas)Nodataavailable

VapourpressureNotdetermined

VapourdensityNotdetermined

Relativedensity0.95

PartitioncoefficientNodataavailable

AutoignitiontemperatureNotdetermined

ViscosityNotdetermined

ExplosivepropertiesNotdetermined

OxidisingpropertiesNodataavailable

9.2.Otherinformation

HAND CLEANER

9.2.Otherinformation

ConductivityNotdetermined

SurfacetensionNotdetermined

GasgroupNotdetermined

BenzeneContentNotapplicable.

LeadcontentNotapplicable.

VOC(Volatileorganic compounds) Nodataavailable

Watersolubility

Slightlysolubleinwater.

SECTION10:Stabilityandreactivity

10.1.Reactivity

10.2.Chemicalstability

Notdetermined.

Stableundernormalconditions.

10.3.Possibilityofhazardousreactions

NoSignificantHazard.

10.4.Conditionstoavoid

10.5.Incompatiblematerials

DoNOTallowtofreeze.

NoSignificantHazard.

10.6.Hazardousdecompositionproducts

Nodataisavailableonthisproduct.

SECTION11:Toxicologicalinformation

11.1.4.ToxicologicalInformation

OrangeTerpenes

OralRatLD50:4400mg/kg

Noknownadversehealtheffects.

SECTION12:Ecologicalinformation

12.1.Toxicity

Noknownadverseenvironmentaleffects.

12.2.Persistenceanddegradability

Nodataisavailableonthisproduct.

12.3.Bioaccumulativepotential

Nodataisavailableonthisproduct. Partitioncoefficient

OrangePumiceHandCleanserNodataavailable

DermalRabbitLD50:>2000mg/kg

12.4.Mobilityinsoil

Nodataisavailableonthisproduct.

12.5.ResultsofPBTandvPvBassessment

Nodataavailable.

12.6.Otheradverseeffects

HAND CLEANER

Noknownadverseenvironmentaleffects.

SECTION13:Disposalconsiderations

Generalinformation

Disposeofincompliancewithalllocalandnationalregulations. Disposalmethods

Forsmallquantities:.Flushdownthedrainwithplentyofwater. Disposalofpackaging

Emptycontainerscanbesentfordisposalorrecycling.

SECTION14:Transportinformation

14.1.UNnumber

14.2.UNpropershippingname

14.3.Transporthazardclass(es)

14.4.Packinggroup

14.5.Environmentalhazards

14.6.Specialprecautionsforuser

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

14.7.TransportinbulkaccordingtoAnnexIIofMARPOL73/78andtheIBCCode

Theproductisnotclassifiedasdangerousforcarriage. Furtherinformation

Theproductisnotclassifiedasdangerousforcarriage.

SECTION15:Regulatoryinformation

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.REGULATION(EC) No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCILof18December2006 concerningtheRegistration,Evaluation,AuthorisationandRestrictionofChemicals(REACH), establishingaEuropeanChemicalsAgency,amendingDirective1999/45/ECandrepealing CouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94aswellas CouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand 2000/21/EC.ThisproductMSDShasbeencompiledinrelationtoECNo:1272/2008CLP Regulations.

SECTION16:Otherinformation

Thisdocumentdiffersfromthepreviousversioninthefollowingareas:.

Otherinformation

TextofHazardStatementsin Section3

HAND CLEANER

2-PrecautionaryStatement:Prevention.

AcuteTox.4:H302-Harmfulifswallowed. EyeIrrit.2:H319-Causesseriouseyeirritation. AquaticChronic3:H412-Harmfultoaquaticlifewithlonglastingeffects. Flam.Liq.3:H226-Flammableliquidandvapour. SkinSens.1:H317-Maycauseanallergicskinreaction.

Furtherinformation

Astheapplicationofproductsisoutsideourcontrol,theinformationisgivenwithoutlegal resposibility.Customersshouldtestundertheirownconditionstoensuretheproductsaresuitable fortheirownrequirements.TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyas guidanceforthesafeuse,storageandhandlingoftheproduct.Thisinformationiscorrecttothe bestofourknowledgeandbeliefatthedateofpublicationhowevernoguaranteeismadetoits accuracy.Thisinformationrelatesonlytothespecificmaterialdesignatedandmaynotbevalidfor suchmaterialusedincombinationwithanyothermaterialsorinanyotherprocess.

INTERIOR SILK PLUS MSDS

SAFETY DATASHEET

INTERIOR SILK PLUS

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name: INTERIOR SILK PLUS

Product code: HC8477

Synonyms: HC8477

PD0650-5

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of substance / mixture: Aerosol cleaner and polish.

1.3. Details of the supplier of the safetydata sheet

Companyname: SUPAGARD LIMITED

23 Gavinton Street Muirend Glasgow Scotland G44 3EF

Tel: 0141 633 5933

Email: james@supagard.co.uk

1.4. Emergencytelephone number

Emergencytel: 0141 633 5933 (office hours only)

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Page: 1

Compilation date: 26/10/2022

Revision date: 14/05/2024

Revision No: 2

Classification under CLP: Skin Irrit. 2: H315; STOT SE 3: H336; Aquatic Chronic 2: H411; Flam. Aerosol 1: H222; Asp. Tox. 1: H304; -: EUH208; -: H229

Most important adverse effects: Contains perfume strawberry 25832 (contains methyl cinnamate, aldehyde c16). May produce an allergic reaction. Extremely flammable aerosol. Pressurised container: May burst if heated. Causes skin irritation. May cause drowsiness or dizziness. Toxic to aquatic life with long lasting effects.

2.2. Label elements

Label elements:

Hazard statements: EUH208: Contains perfume strawberry 25832 (contains methyl cinnamate, aldehyde c16). May produce an allergic reaction. H222: Extremely flammable aerosol.

SAFETY DATASHEET

INTERIOR SILK PLUS

H229: Pressurised container: May burst if heated.

H315: Causes skin irritation.

H336: May cause drowsiness or dizziness.

H411: Toxic to aquatic life with long lasting effects.

Hazard pictograms: GHS02: Flame

GHS07: Exclamation mark

GHS09: Environmental

Signal words: Danger

Precautionarystatements: P102: Keep out of reach of children.

P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P211: Do not spray on an open flame or other ignition source.

P251: Do not pierce or burn, even after use.

P410+P412: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.

P260: Do not breathe spray.

P302+P350: IF ON SKIN: Gently wash with plenty of soap and water.

P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Haz. ingredients (label): Contains:

ALIPHATIC HYDROCARBON SOLVENT BLEND

LIQUIFIED PETROLEUMGAS PROPELLANT

PERFUME (CONTAINING: METHYL CINNAMATE, ALDEHYDE C16)

2.3. Other hazards

Other hazards: In use, may form flammable / explosive vapour-air mixture.

PBT: This product is not identified as a PBT/vPvB substance.

Section 3: Composition/information on ingredients

3.2. Mixtures

Hazardous ingredients:

INTERIOR SILK PLUS

HYDROCARBONS C6-C7 ISOALKANES, CYCLICS, <5% N-HEXANE, <0.1% BENZENE - REACH registered number (s): 01-2119475514-35-XXXX

EINECS CAS

265-151-9 64742-49-0 -

/ WEL

Flam. Liq. 2: H225; STOT SE 3: H336; Asp. Tox. 1: H304; Aquatic Chronic 2: H411; Skin Irrit. 2: H315

BUTANE, <0.1% 1,3 BUTADIENE - REACH registered number(s): 01-2119474691-32-XXXX

203-448-7 106-97-8

Substance with a Community workplace exposure limit. Flam. Gas 1: H220; Press. Gas: H280

PROPANE, <0.1% 1,3 BUTADIENE - REACH registered number(s): 01-2119486944-21-XXXX

200-827-9 74-98-6

Substance with a Community workplace exposure limit.

1:

PERFUME STRAWBERRY25832 (CONTAINS METHYL CINNAMATE, ALDEHYDE C16) - - -

Flam. Liq. 3: H226; Skin Sens. 1A: H317; Aquatic Chronic 3: H412

Non-classified ingredients:

PERFUME CRANBERRY(CONTAINING ALDEHYDE C16, LINALOOL, BETA IONONE, CITRONELLOL) - REACH registered number(s): MIXTURE

MIXTURE - - Aquatic Chronic 3: H412; Skin Sens. 1: H317; Skin Irrit. 2: H315; Flam. Liq. 3: H226; -: EUH208

Section 4: First aid measures

4.1. Description of first aid measures

Skin contact: Wash immediately with plenty of soap and water.

Eye contact: Bathe the eye with running water for 15 minutes. Consult a doctor.

Ingestion: Wash out mouth with water.

Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Move to fresh air in case of accidental inhalation of vapours. Consult a doctor.

4.2. Most important symptoms and effects, both acute and delayed

Skin contact: There may be irritation and redness at the site of contact.

Eye contact: There may be irritation and redness. The eyes may water profusely.

Ingestion: There may be soreness and redness of the mouth and throat.

Inhalation: There may be irritation of the throat with a feeling of tightness in the chest. Exposure may cause coughing or wheezing.

Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

INTERIOR SILK PLUS

4.3. Indication of anyimmediate medical attention and special treatment needed

Immediate / special treatment: Eye bathing equipment should be available on the premises.

Section 5: Fire-fighting measures

5.1. Extinguishing media

Extinguishing media: Alcohol resistant foam. Water spray. Carbon dioxide. Dry chemical powder. Use water spray to cool containers.

5.2. Special hazards arising from the substance or mixture

Exposure hazards: Highly flammable. In combustion emits toxic fumes. Forms explosive air-vapour mixture. Vapour may travel considerable distance to source of ignition and flash back. Aerosol cans may explode during a fire, giving a high speed projectile.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergencyprocedures

Personal precautions: Refer to section 8 of SDS for personal protection details. If outside do not approach from downwind. If outside keep bystanders upwind and away from danger point. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Eliminate all sources of ignition. Cover leaking can until the discharge has stopped, before attempting cleanup operations. Spillage will create slippery surface.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method. Do not use equipment in clean-up procedure which may produce sparks. Wash the ground with an appropriate self-emulsifying solvent.

6.4. Reference to other sections

Reference to other sections: Refer to section 8 of SDS.

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Avoid the formation or spread of mists in the air. Smoking is forbidden. Use non-sparking tools.

INTERIOR SILK PLUS

7.2. Conditions for safe storage, including anyincompatibilities

Storage conditions: Store in a cool, well ventilated area. Keep away from sources of ignition. Keep away from direct sunlight.

7.3. Specific end use(s)

Specific end use(s): No data available.

Section 8: Exposure controls/personal protection

8.1. Control parameters

Hazardous ingredients:

HYDROCARBONS C6-C7 ISOALKANES, CYCLICS, <5%N-HEXANE, <0.1%BENZENE

Workplace exposure limits:

Respirable dust:

<0.1%1,3 BUTADIENE

PROPANE, <0.1%1,3 BUTADIENE

UK Asphyxiating Asphyxiating - -

DNEL/PNEC Values

DNEL / PNEC No data available.

8.2. Exposure controls

Engineering measures: Ensure there is sufficient ventilation of the area. Ensure lighting and electrical equipment are not a source of ignition.

Respiratoryprotection: Self-contained breathing apparatus must be available in case of emergency.

Hand protection: Protective gloves.

Eye protection: Safety glasses. Ensure eye bath is to hand.

Skin protection: Protective clothing.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State: Aerosol

Colour: Colourless

Odour: Perfumed

Evaporation rate: Fast

Solubilityin water: Insoluble

Viscosity: Non-viscous

Boiling point/range°C: No data available.

Flammabilitylimits %:lower: 0.9

Melting point/range°C: No data available.

Flash point°C: -40

Autoflammability°C: >230

INTERIOR SILK PLUS

upper: 9.0

Part.coeff. n-octanol/water: No data available.

Vapour pressure: No data available.

Relative density: No data available. pH: Not applicable.

VOC g/l: No data available.

9.2. Other information

Other information: No data available.

Section 10: Stabilityand reactivity

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

10.2. Chemical stability

Chemical stability: Stable under normal conditions. Stable at room temperature.

10.3. Possibilityof hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions. Decomposition may occur on exposure to conditions or materials listed below.

10.4. Conditions to avoid

Conditions to avoid: Heat. Hot surfaces. Sources of ignition. Flames. Direct sunlight.

10.5. Incompatible materials

Materials to avoid: Strong oxidising agents. Strong acids.

10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

Section 11: Toxicological information

11.1. Information on toxicological effects

Hazardous ingredients:

HYDROCARBONS

Relevant hazards for product:

Skin corrosion/irritation

INTERIOR SILK PLUS

STOT-single exposure - Hazardous: calculated

Aspiration hazard - Hazardous: calculated

Symptoms / routes of exposure

Skin contact: There may be irritation and redness at the site of contact.

Eye contact: There may be irritation and redness. The eyes may water profusely.

Ingestion: There may be soreness and redness of the mouth and throat.

Inhalation: There may be irritation of the throat with a feeling of tightness in the chest. Exposure may cause coughing or wheezing.

Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

Section 12: Ecological information

12.1. Toxicity

Hazardous ingredients:

HYDROCARBONS C6-C7 ISOALKANES, CYCLICS, <5%N-HEXANE, <0.1%BENZENE

Daphnia magna

RAINBOW TROUT (Oncorhynchus mykiss)

12.2. Persistence and degradability

Persistence and degradability: Biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: No bioaccumulation potential.

12.4. Mobilityin soil

Mobility: Readily absorbed into soil. Volatile. Insoluble in water. Floats on water. Vapour is heavier than air.

12.5. Results of PBT and vPvB assessment

PBT identification: This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects: Toxic to aquatic organisms.

Section 13: Disposal considerations

13.1. Waste treatment methods

Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.

Recoveryoperations: Recycling/reclamation of metals and metal compounds.

Waste code number: 16 05 05

Disposal of packaging: Dispose of as normal industrial waste. Empty cans must not be burned because of explosion hazard.

INTERIOR SILK PLUS

NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.

Section 14: Transport information

14.1. UN number

UN number: UN1950

14.2. UN proper shipping name

Shipping name: AEROSOLS

14.3. Transport hazard class(es)

Transport class: 2

14.4. Packing group

14.5. Environmental hazards

Environmentallyhazardous: Yes

14.6. Special precautions for user

Special precautions: No special precautions.

Tunnel code: D

Transport category: 2

Section 15: Regulatoryinformation

Marine pollutant: No

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Specific regulations: Not applicable.

15.2. Chemical SafetyAssessment

Chemical safetyassessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.

Section 16: Other information

Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 2015/830.

All substances in this preparation are registered within UK/EU/EFTA countries under the REACH (UK/EC) (ammended) regulations, EC 1907/2006

IMPORTANT NOTE:

Risk phases in this section belowrelate to the INDIVIDUAL COMPONENTS in the formulation when used at their FULL CONCENTRATIONS, and not at the reduced levels in the mixed product.

See sections 2 and 3 for the calculated hazard and risk phrases for the blended product. Phrases used in s.2 and s.3: EUH208: Contains Linalool and Citronellol. May produce an allergic reaction.

INTERIOR SILK PLUS

EUH208: Contains perfume strawberry 25832 (contains methyl cinnamate, aldehyde c16). May produce an allergic reaction.

H220: Extremely flammable gas.

H222: Extremely flammable aerosol.

H225: Highly flammable liquid and vapour.

H226: Flammable liquid and vapour.

H229: Pressurised container: May burst if heated.

H304: May be fatal if swallowed and enters airways.

H315: Causes skin irritation.

H317: May cause an allergic skin reaction.

H336: May cause drowsiness or dizziness.

H411: Toxic to aquatic life with long lasting effects.

H412: Harmful to aquatic life with long lasting effects.

Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.

LEATHER CLEANER MSDS

SAFETY DATA SHEET

according to Regulation (EU) 2020/878

Leather Cleaner

SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking

1.1.Productidentifier

Productname Leather Cleaner

1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst ProductUse

[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC35]Washingand cleaningproducts(includingsolventbasedproducts);

[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC35]Washingandcleaningproducts(includingsolventbasedproducts); Description LeatherCleaner.

1.3.Detailsofthesupplierofthesafetydatasheet Company SUPAGARDLIMITED

Address 19-27GavintonStreet Muirend Glasgow G443EF

Web www.supagard.com

Telephone 01416335933

Fax 01416377219

Email James.Smyth@supagard.com

Emailaddressofthe competentperson James.Smyth@supagard.com

1.4.Emergencytelephonenumber

Emergencytelephonenumber01416335933 8.30amto5.00pm

FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)

Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org

SECTION2:Hazardsidentification

2.1.Classificationofthesubstanceormixture

2.1.2.Classification-EC 1272/2008 EyeIrrit.2:H319;

2.2.Labelelements

Hazardpictograms

Leather Cleaner

2.2.Labelelements

SignalWord Warning

HazardStatement EyeIrrit.2:H319-Causesseriouseyeirritation.

PrecautionaryStatement: Prevention P102-Keepoutofreachofchildren.

PrecautionaryStatement: Response P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing. P337+P313-Ifeyeirritationpersists:Getmedicaladvice/attention.

SUPPLEMENTALHAZARD INFORMATION

IngredientsasrequiredbyRegulation(EC)No648/2004:. Lessthan5%Non-ionicSurfactants,Lessthan5%AmphotericSurfactants,Parfum,Benzyl Alcohol.

Contains-DenaturedAlcohol,2-butoxyethanol,Amines,C8-C18(evennumbered)and C18(Unsaturated),N,N-Bis(Hydroxyethyl),Amines,C12-14(evennumbered)-alkyldimethyl, N-oxides.

2.3.Otherhazards

Otherhazards Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.

Furtherinformation

RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.

SECTION3:Composition/informationoningredients

3.2.Mixtures

EC1272/2008

ChemicalName

Amides,C8-C18(evennumbered) andC18(Unsaturated), N,N-Bis(Hydroxyethyl)

Amines,C12-14(evennumbered) -alkyldimethyl,N-oxides

Ethanol:EthylAlcohol(Ethanol)

56-81-5200-289-5

931-329-601-2119490100-53

308062-28-4931-292-601-2119490061-47

64-17-5200-578-601-2119457610-43

SkinIrrit.2:H315;EyeDam. 1:H318;AquaticChronic2: H411; 1-10%

AcuteTox.4:H302;SkinIrrit. 2:H315;EyeDam.1:H318; AquaticAcute1:H400; AquaticChronic2:H411; 0-0.5%

Flam.Liq.2:H225;EyeIrrit. 2:H319; 1-10% 2-butoxyethanol

603-014-00-0111-76-2203-905-001-2119475108-36

AcuteTox.4:H332;Acute Tox.4:H312;AcuteTox.4: H302;EyeIrrit.2:H319;Skin Irrit.2:H315; 0.5-1%

Amines,C12-14(evennumbered)-alkyldimethyl,N-oxides,CASNo.308062-28-4-MFactor (Acute)=1.

SECTION4:Firstaidmeasures

4.1.Descriptionoffirstaidmeasures

Inhalation Movetheexposedpersontofreshair.

Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved.

Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution.

Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed

Inhalation Maycauseirritationtorespiratorysystem.

Eyecontact Irritatingtoeyes.

Skincontact Maycauseirritationtoskin.

Leather Cleaner

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed Ingestion Maycauseirritationtomucousmembranes.

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded Inhalation

Eyecontact

Skincontact

Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.

Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.

Seekmedicalattentionifirritationorsymptomspersist. Ingestion Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.

Generalinformation

Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.

SECTION5:Firefightingmeasures

5.1.Extinguishingmedia

Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.

5.2.Specialhazardsarisingfromthesubstanceormixture

Noneknown.

5.3.Adviceforfirefighters

Furtherinformation

Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.

Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.

SECTION6:Accidentalreleasemeasures

6.1.Personalprecautions,protectiveequipmentandemergencyprocedures

6.2.Environmentalprecautions

Wearsuitableprotectiveequipment.

Adviselocalauthoritiesiflargespillscannotbecontained.

6.3.Methodsandmaterialforcontainmentandcleaningup

Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.

6.4.Referencetoothersections

Seesection2,7,8,13forfurtherinformation.

SECTION7:Handlingandstorage

7.1.Precautionsforsafehandling

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.

7.2.Conditionsforsafestorage,includinganyincompatibilities

Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.

7.3.Specificenduse(s)

Suitablepackaging

LeatherCleaner.

Plasticcontainers.

Leather Cleaner

SECTION8:Exposurecontrols/personalprotection

8.1.Controlparameters

8.1.1.ExposureLimitValues

2-butoxyethanol

Amides,C8-C18(even numbered)and C18(Unsaturated), N,N-Bis(Hydroxyethyl)

Ethanol:EthylAlcohol(Ethanol)

Occupationalexposurecontrols.

WEL8-hrlimitppm:25

WEL15minlimitppm:50

WEL8-hrlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: -

WEL8-hrlimitppm:N/A

WEL15minlimitppm:

WEL8-hrlimitmg/m3total inhalabledust:

WEL8-hrlimitmg/m3total respirabledust:

WEL8-hrlimitppm:1000

WEL15minlimitppm:-

Glycerol(Glycerol,mist)

WEL8-hrlimitmg/m3:123

WEL15minlimitmg/m3:101.2

WEL15minlimitmg/m3total inhalabledust: -

WEL15minlimitmg/m3total respirabledust: -

WEL8-hrlimitmg/m3:

WEL15minlimitmg/m3:

WEL15minlimitmg/m3total inhalabledust:

WEL15minlimitmg/m3total respirabledust:

WEL8-hrlimitmg/m3:1920

WEL15minlimitmg/m3:-

WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -

WEL8-hrlimitppm:-

WEL15minlimitppm:-

WEL8-hrlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3:10

WEL15minlimitmg/m3:-

WEL15minlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -

DNEL:Derivedno-effectlevel.

ExposurePattern-Workers

2-butoxyethanol

Amides,C8-C18(even numbered)and C18(Unsaturated), N,N-Bis(Hydroxyethyl)

Ethanol:EthylAlcohol

Glycerol

Acuteinhalation-Systemic effects 1091mg/m³

Acuteinhalation-Localeffects246mg/m³

Long-term-inhalation-Systemic effects 98mg/m³

Long-term-inhalation-Systemic effects 73.4mg/m³

Long-term-dermal-Systemic effects 4.16<none>

Long-term-inhalation-Systemic effects 950mg/m³

Long-term-inhalation-Local effects 1900mg/m³

Long-term-inhalation-Local effects 56mg/m³

ExposurePattern-Generalpopulation

Acutedermal-Systemiceffects89mg/kg

Long-term-dermal-Systemic effects 125mg/kg

Long-term-dermal-Systemic effects 343mg/kg

ExposurePattern-Generalpopulation

2-butoxyethanol

Amides,C8-C18(even numbered)and C18(Unsaturated), N,N-Bis(Hydroxyethyl)

Ethanol:EthylAlcohol

Glycerol

8.2.Exposurecontrols

Leather Cleaner

Acuteinhalation-Systemic effects 426mg/m³

Acutedermal-Systemiceffects89mg/kg

Long-term-inhalation-Systemic effects 59mg/m³

Long-term-dermal-Systemic effects 75mg/kg

Long-term-inhalation-Systemic effects 21.73mg/m³

Long-term-oral-Systemic effects 6.25mg/kg

Long-term-inhalation-Systemic effects 114mg/m³

Long-term-inhalation-Local effects 950mg/m³

Long-term-oral-Systemic effects 87mg/kg

Long-term-inhalation-Local effects 33mg/m³

Long-term-oral-Systemic effects 229mg/kg

8.2.1.Appropriateengineering controls

Eye/faceprotection

Acuteoral-Systemiceffects26.7mg/kg

Long-term-inhalation-Local effects 147mg/m³

Long-term-oral-Systemiceffects6.3mg/kg

Long-term-dermal-Systemic effects 206mg/kg

SkinprotectionHandprotection

Respiratoryprotection

8.2.3.Environmentalexposure controls

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.

Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.

Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields. Eyewearcomplyingwithanapprovedstandardshouldbewornifariskassessmentindicateseye contactispossible.Thefollowingprotectionshouldbeworn:Wearchemicalsplashgoggles. PersonalprotectiveequipmentforeyeandfaceprotectionshouldcomplywithEuropeanStandard EN166.

Nitrilerubbergloves.Chooseglovestoprotecthandsagainstchemicalsdependingonthe concentrationandquantityofthehazardoussubstanceandspecifictoplaceofwork.Forspecial applications,werecommendclarifyingtheresistancetochemicalsoftheaforementioned protectivegloveswiththeglovemanufacturer.

Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.

Preventfurtherleakageorspillageifsafetodoso.

SECTION9:Physicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties

AppearanceLiquid

ColourColourless

OdourCharacteristic

OdourthresholdNodataavailable pH6-8

MeltingpointNodataavailable

InitialboilingpointNodataavailable

FlashpointNodataavailable

EvaporationrateNodataavailable Flammability(solid,gas)Nodataavailable

VapourpressureNodataavailable

RelativeVapourDensityNodataavailable

Density/RelativeDensity1.004-1.01

PartitioncoefficientNodataavailable

AutoignitiontemperatureNodataavailable

Viscosity<20centipoise

ExplosivepropertiesNodataavailable OxidisingpropertiesNodataavailable SolubilitySolubleinwater

9.2.Otherinformation

ConductivityNodataavailable

SurfacetensionNodataavailable

GasgroupNodataavailable

BenzeneContentNodataavailable

LeadcontentNodataavailable

VOC(Volatileorganic compounds) Nodataavailable

9.2.1.Informationwithregardtophysicalhazardclasses

Nodataisavailableonthisproduct.

9.2.2.Othersafetycharacteristics

Nodataisavailableonthisproduct.

SECTION10:Stabilityandreactivity

10.1.Reactivity

10.2.Chemicalstability

Stableundernormalconditions.

Stableundernormalconditions.

10.3.Possibilityofhazardousreactions

Strongacids.Strongoxidisingagents.

10.4.Conditionstoavoid

10.5.Incompatiblematerials

AvoidstoringindirectSunLight.

Strongacids.Strongoxidisingagents.

10.6.Hazardousdecompositionproducts

NoHazardousdecompositionproductswhenstoredandhandledcorrectly.

Leather Cleaner

SECTION11:Toxicologicalinformation

11.1Informationonhazardclasses

Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedusingthemethodsoutlinedinRegulation(EC)No1272/2008(CLP).

Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet. OralATE=>10,000mg/kg. DermalATE=>10,000mg/kg.

Inhalation-Dust/MistATE=148.65mg/l,Inhalation-Dust/MistATE=>1,000mg/l. Skincorrosion/irritation basedonavailabledatatheclassificationcriteriaarenotmet.

Seriouseyedamage/irritationEyeIrrit.2:H319-Causesseriouseyeirritation.

Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.

Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet. Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.

Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.

Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet.

11.1.2.Mixtures

11.1.3.HazardInformation

11.1.4.ToxicologicalInformation

2-butoxyethanol

Amides,C8-C18(even numbered)and C18(Unsaturated), N,N-Bis(Hydroxyethyl)

Ethanol:EthylAlcohol

Glycerol

11.2Informationonotherhazards

Nodataavailable.

Nodataavailable.

DermalRatLD50:1100mg/kg

InhalationRatLC50/4h:11.0mg/l

OralRatLD50:>2000mg/kg

OralRatLD50:10470.0mg/kg

InhalationRatLC50/4h:20mg/l

OralRatLD50:27,200.0mg/kg

Nodataisavailableonthisproduct.

SECTION12:Ecologicalinformation

12.1.Toxicity

OralRatLD50:1300mg/kg

DermalRabbitLD50:>2000mg/kg

DermalRabbitLD50:15800.0mg/kg

Leather Cleaner

12.1.Toxicity

2-butoxyethanol

Amides,C8-C18(even numbered)and C18(Unsaturated), N,N-Bis(Hydroxyethyl)

Ethanol:EthylAlcohol

Glycerol

12.2.Persistenceanddegradability

12.3.Bioaccumulativepotential

Partitioncoefficient

12.4.Mobilityinsoil

DaphniaEC50/48h:1550.0000mg/l

RainbowtroutLC50/96h:1474mg/l

EC50formarineorfreshwater organisms >100.0000mg/l

DaphniaEC50/48h:3.2000mg/l

FishLC50/96h:2.4000mg/l

DaphniaEC50/48h:12340.0000mg/l

GreenAlgaeEC50/48h:>100mg/l

RainbowtroutLC50/96h:13000mg/l

NOEC/EC10formarineor freshwaterorganisms 9.6000mg/l

DaphniaEC50/48h:10000.0000mg/l

FatheadminnowsLC50/96h= >=885mg/l:

AlgaeEC50/72h:1840mg/

LC50formarineorfreshwater organisms >100.0000mg/l

AlgaeIC50/72h:3.9000mg/l

AlgaeEC50/72h:18.6mg/l

AlgaeEC50/72h:275mg/l

FatheadminnowsLC50/96h:14200mg/l

GoldenorfeLC50/48h:>100mg/l

AlgaeEC50/72h:>2900mg/l

RainbowtroutLC50/96h:54000mg/l

SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.

Theproductisnotbioaccumulating.

StoneacreLeatherCleanerNodataavailable

Glycerol-1.76LogPow Amides,C8-C18(evennumbered) andC18(Unsaturated), N,N-Bis(Hydroxyethyl) 3.75LogPow

Ethanol:EthylAlcohol-0.35logP

2-butoxyethanol0.8logP

Thisproductissolubleinwater.

12.5.ResultsofPBTandvPvBassessment

Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.

12.6Endocrinedisruptingproperties

Nodataisavailableonthisproduct.

12.7.Otheradverseeffects

Nodataisavailableonthisproduct.

SECTION13:Disposalconsiderations

13.1.Wastetreatmentmethods

Generalinformation

Disposalofpackaging

Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.

Disposeofincompliancewithalllocalandnationalrequirements.

DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.

SECTION14:Transportinformation

Leather Cleaner

14.1.UNnumber

14.2.UNpropershippingname

14.3.Transporthazardclass(es)

14.4.Packinggroup

14.5.Environmentalhazards

14.6.Specialprecautionsforuser

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

14.7MaritimeTransportinbulkaccordingtoIMOinstruments

Theproductisnotclassifiedasdangerousforcarriage.

SECTION15:Regulatoryinformation

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture

Regulations

REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.

COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.

COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).

15.2.Chemicalsafetyassessment

Noinformationavailable.

Revision Thisdocumentdiffersfromthepreviousversioninthefollowingareas:. 1-ProductUse. 2-Otherhazards. 2-Furtherinformation.

2-SUPPLEMENTALHAZARDINFORMATION. 3-3.2.Mixtures.

9-9.2.2.Othersafetycharacteristics. 9-9.2.1.Informationwithregardtophysicalhazardclasses. 10-10.2.Chemicalstability. 10-10.1.Reactivity. 11-Acutetoxicity. 11-11.2Informationonotherhazards.

Otherinformation

Datasources

TextofHazardStatementsin Section3

12-12.1.Toxicity.

12-12.6Endocrinedisruptingproperties. 12-12.7.Otheradverseeffects. 15-Regulations.

ClassificationandProcedureusedtoderivetheclassificationformixturesaccordingtoRegulation (EC)No.1272/2008,asretainedandamendedinUKlaw.

EyeIrrit.2:H319-Causesseriouseyeirritation.-CalculationMethod.

SkinIrrit.2:H315-Causesskinirritation.

EyeDam.1:H318-Causesseriouseyedamage.

AquaticChronic2:H411-Toxictoaquaticlifewithlonglastingeffects.

AcuteTox.4:H302-Harmfulifswallowed.

AquaticAcute1:H400-Verytoxictoaquaticlife.

Flam.Liq.2:H225-Highlyflammableliquidandvapour.

EyeIrrit.2:H319-Causesseriouseyeirritation.

AcuteTox.4:H302+H312+H332-Harmfulifswallowed,incontactwithskinorifinhaled

Furtherinformation

TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.

MULTI-PURPOSE CLEANER

MSDS

SAFETYDATASHEET

accordingtoRegulation(EU)2020/878

SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking

1.1.Productidentifier

Productname UniversalCleaner

1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst

ProductUse [SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);

Description Multi-purposealkalinecleaner.

1.3.Detailsofthesupplierofthesafetydatasheet

Company SUPAGARDLIMITED

Address 19-27GavintonStreet Muirend Glasgow G443EF

Web www.supagard.com

Telephone 01416335933

Fax 01416377219

Email James.Smyth@supagard.com

Emailaddressofthe competentperson James.Smyth@supagard.com

1.4.Emergencytelephonenumber

Emergencytelephonenumber01416335933 8.30amto5.00pm

FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)

Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org

SECTION2:Hazardsidentification

2.1.Classificationofthesubstanceormixture

2.1.2.Classification-EC 1272/2008 SkinIrrit.2:H315;EyeDam.1:H318;

2.2.Labelelements

Hazardpictograms

SignalWord Danger

HazardStatement

SkinIrrit.2:H315-Causesskinirritation. EyeDam.1:H318-Causesseriouseyedamage.

2.2.Labelelements

PrecautionaryStatement: Prevention

PrecautionaryStatement: Response

SUPPLEMENTALHAZARD INFORMATION

UniversalCleaner

P280-Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection.

P302+P352-IFONSKIN:Washwithplentyofwater/. P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.

P332+P313-Ifskinirritationoccurs:Getmedicaladvice/attention.

P337+P313-Ifeyeirritationpersists:Getmedicaladvice/attention.

IngredientsasrequiredbyRegulation(EC)No648/2004:.

3.8%Phosphatesbyweight,5-15%AnionicSurfactants,Lessthan5%Non-IonicSurfactants,CI 45350.

Contains-C9-11Alcohol,ethoxylated,sodium(xylenesand4-ethylbenzene)sulfonate, Tetrapotassiumpyrophosphate,SodiumMetasilicatePentahydrate,2-butoxyethanol.

2.3.Otherhazards

Otherhazards

Furtherinformation

Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.

RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.

SECTION3:Composition/informationoningredients

3.2.Mixtures

EC1272/2008

ChemicalName

C9-11Alcohol,ethoxylated 68439-45-2

sodium(xylenesand 4-ethylbenzene)sulfonate

Tetrapotassiumpyrophosphate

SodiumMetasilicatePentahydrate

701-037-101-2119513350-56

7320-34-5230-785-701-2119489369-18

10213-79-3229-912-901-2119449811-37

AcuteTox.4:H302;Eye Dam.1:H318; 1-10%

EyeIrrit.2:H319;1-10%

EyeIrrit.2:H319;1-10%

Met.Corr.1:H290;SkinCorr. 1B:H314;STOTSE3:H335; 1-10% 2-butoxyethanol

603-014-00-0111-76-2203-905-001-2119475108-36

SECTION4:Firstaidmeasures

4.1.Descriptionoffirstaidmeasures

Inhalation

Movetheexposedpersontofreshair.

AcuteTox.4:H332;Acute Tox.4:H312;AcuteTox.4: H302;EyeIrrit.2:H319;Skin Irrit.2:H315; 1-10%

Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved.

Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution.

Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed

Inhalation Maycauseirritationtorespiratorysystem.

Eyecontact Causesseriouseyedamage.

Skincontact Causesskinirritation.

Ingestion Maycauseirritationtomucousmembranes.

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded

Inhalation Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.

Eyecontact Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.

UniversalCleaner

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded Skincontact Seekmedicalattentionifirritationorsymptomspersist. Ingestion Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.

Generalinformation

Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.

SECTION5:Firefightingmeasures

5.1.Extinguishingmedia

Useextinguishingmediaappropriatetothesurroundingfireconditions.

5.2.Specialhazardsarisingfromthesubstanceormixture

Burningproducesirritating,toxicandobnoxiousfumes.

5.3.Adviceforfirefighters

Furtherinformation

Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.

Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.

SECTION6:Accidentalreleasemeasures

6.1.Personalprecautions,protectiveequipmentandemergencyprocedures

Wearsuitableprotectiveequipment.Avoidcontactwitheyesandskin.Provideadequate ventilation.

6.2.Environmentalprecautions

Adviselocalauthoritiesiflargespillscannotbecontained.

6.3.Methodsandmaterialforcontainmentandcleaningup

Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.

6.4.Referencetoothersections

Seesection2,7,8,13forfurtherinformation.

7.1.Precautionsforsafehandling

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact witheyesandskin.Provideadequateventilation.

7.2.Conditionsforsafestorage,includinganyincompatibilities

Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.

7.3.Specificenduse(s)

8.1.Controlparameters

Multi-purposealkalinecleaner.

8.1.Controlparameters

8.1.1.ExposureLimitValues

2-butoxyethanol

UniversalCleaner

Occupationalexposurecontrols.

WEL8-hrlimitppm:25

WEL15minlimitppm:50

WEL8-hrlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3:123

WEL15minlimitmg/m3:101.2

WEL15minlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -

DNEL:Derivedno-effectlevel.

ExposurePattern-Workers

2-butoxyethanol

sodium(xylenesand 4-ethylbenzene)sulfonate

SodiumMetasilicate Pentahydrate

Acuteinhalation-Systemic effects 1091mg/m³

Acuteinhalation-Localeffects246mg/m³

Long-term-inhalation-Systemic effects 98mg/m³

Long-term-inhalation-Systemic effects 26.9mg/m³

Long-term-dermal-Systemic effects 136.25mg/kg

Long-term-inhalation-Systemic effects 6.22mg/m³

Long-term-dermal-Systemic effects 1.49mg/kg

ExposurePattern-Generalpopulation

2-butoxyethanol

sodium(xylenesand 4-ethylbenzene)sulfonate

SodiumMetasilicate Pentahydrate

8.2.Exposurecontrols

Acuteinhalation-Systemic effects 426mg/m³

Acutedermal-Systemiceffects89mg/kg

Long-term-inhalation-Systemic effects 59mg/m³

Long-term-dermal-Systemic effects 75mg/kg

Long-term-inhalation-Systemic effects 6.6mg/m³

Long-term-dermal-Systemic effects 68.1mg/kg

Long-term-oral-Systemic effects 3.8mg/kg

Long-term-inhalation-Systemic effects 1.55mg/m³

Long-term-dermal-Systemic effects 0.74mg/kg

Acutedermal-Systemiceffects89mg/kg

Long-term-dermal-Systemic effects 125mg/kg

Acuteoral-Systemiceffects26.7mg/kg

Long-term-inhalation-Local effects 147mg/m³

Long-term-oral-Systemiceffects6.3mg/kg

Long-term-dermal-Localeffects0.048mg/cm³

Long-term-oral-Systemiceffects0.74mg/kg

8.2.Exposurecontrols

8.2.1.Appropriateengineering controls

Eye/faceprotection

SkinprotectionHandprotection

UniversalCleaner

Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.

Eyewearcomplyingwithanapprovedstandardshouldbewornifariskassessmentindicateseye contactispossible.Thefollowingprotectionshouldbeworn:Wearchemicalsplashgoggles. PersonalprotectiveequipmentforeyeandfaceprotectionshouldcomplywithEuropeanStandard EN166.

Chooseglovestoprotecthandsagainstchemicalsdependingontheconcentrationandquantityof thehazardoussubstanceandspecifictoplaceofwork.Forspecialapplications,werecommend clarifyingtheresistancetochemicalsoftheaforementionedprotectivegloveswiththeglove manufacturer.

Skinprotection-Other Wearsuitableprotectiveclothing. Respiratoryprotection

Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.

8.2.3.Environmentalexposure controls Preventfurtherleakageorspillageifsafetodoso.

SECTION9:Physicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties

AppearanceLiquid

ColourClear

OdourCharacteristic

OdourthresholdNodataavailable pH<11

MeltingpointNodataavailable

InitialboilingpointNodataavailable

FlashpointNodataavailable EvaporationrateNodataavailable Flammability(solid,gas)Nodataavailable

VapourpressureNodataavailable

RelativeVapourDensityNodataavailable Density/RelativeDensity1.068-1.075g/cm3

PartitioncoefficientNodataavailable

AutoignitiontemperatureNodataavailable

Viscosity<50centipoise

ExplosivepropertiesNodataavailable

OxidisingpropertiesNodataavailable SolubilitySolubleinwater

9.2.Otherinformation

ConductivityNodataavailable SurfacetensionNodataavailable GasgroupNodataavailable BenzeneContentNodataavailable

LeadcontentNodataavailable VOC(Volatileorganic compounds) Nodataavailable

9.2.1.Informationwithregardtophysicalhazardclasses Nodataisavailableonthisproduct.

9.2.2.Othersafetycharacteristics Nodataisavailableonthisproduct.

UniversalCleaner

SECTION10:Stabilityandreactivity

10.1.Reactivity

10.2.Chemicalstability

Stableundernormalconditions.

Stableundernormalconditions.

10.3.Possibilityofhazardousreactions

Noneknown.

10.4.Conditionstoavoid

10.5.Incompatiblematerials

Protectfromfrost.

Strongacids.Strongoxidisingagents.

10.6.Hazardousdecompositionproducts

NoHazardousdecompositionproductswhenstoredandhandledcorrectly.

SECTION11:Toxicologicalinformation

11.1Informationonhazardclasses

Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedusingthemethodsoutlinedinRegulation(EC)No1272/2008(CLP).

Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

OralATE=>10,000mg/kg.

DermalATE=>10,000mg/kg.

Inhalation-Dust/MistATE=>20mg/l.

Skincorrosion/irritation SkinIrrit.2:H315-Causesskinirritation.

Seriouseyedamage/irritationEyeDam.1:H318-Causesseriouseyedamage.

Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.

Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet. Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.

Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.

Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet.

Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.

11.1.2.Mixtures

11.1.3.HazardInformation

11.1.4.ToxicologicalInformation

Nodataavailable.

Nodataavailable.

11.1.4.ToxicologicalInformation

2-butoxyethanol

C9-11Alcohol,ethoxylated

sodium(xylenesand 4-ethylbenzene)sulfonate

SodiumMetasilicate Pentahydrate

11.2Informationonotherhazards

UniversalCleaner

DermalRatLD50:1100mg/kg

InhalationRatLC50/4h:11.0mg/l

DermalRatLD50:>2000mg/kg

OralRatLD50:>7200mg/kg

InhalationRatLC50/4h:>6.41mg/l

DermalRatLD50:>5,000mg/kg

Nodataisavailableonthisproduct.

SECTION12:Ecologicalinformation

12.1.Toxicity

2-butoxyethanol

sodium(xylenesand 4-ethylbenzene)sulfonate

SodiumMetasilicate Pentahydrate

12.2.Persistenceanddegradability

12.3.Bioaccumulativepotential

Partitioncoefficient

12.4.Mobilityinsoil

DaphniaEC50/48h:1550.0000mg/l

RainbowtroutLC50/96h:1474mg/l

EC50formarineorfreshwater organisms >100.0000mg/l

DaphniaEC50/48h:1000.0000mg/l

RainbowtroutLC50/96h:>1000mg/l

DaphniaEC50/48h:1700.0000mg/l

BrachydanioRerioLC50/96h:210mg/l

OralRatLD50:1300mg/kg

OralRatLD50=>300-<=2000 mg/kg:

DermalRabbitLD50:>2000mg/kg

AlgaeEC50/72h:1840mg/

LC50formarineorfreshwater organisms >100.0000mg/l

GreenalgaeEC50/96h:230mg/l

AlgaeEC50/72h:207mg/l

SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.

Theproductisreadilybiodegradable.

UniversalCleanerNodataavailable 2-butoxyethanol0.8logP

Theproductisdilutableinwater.

12.5.ResultsofPBTandvPvBassessment

Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.

12.6Endocrinedisruptingproperties

Nodataisavailableonthisproduct.

12.7.Otheradverseeffects

Nodataisavailableonthisproduct.

SECTION13:Disposalconsiderations

13.1.Wastetreatmentmethods

Generalinformation

Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.

Disposeofincompliancewithalllocalandnationalrequirements.

Disposalofpackaging

UniversalCleaner

DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.

SECTION14:Transportinformation

14.1.UNnumber

14.2.UNpropershippingname

14.3.Transporthazardclass(es)

14.4.Packinggroup

14.5.Environmentalhazards

14.6.Specialprecautionsforuser

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

14.7MaritimeTransportinbulkaccordingtoIMOinstruments

Theproductisnotclassifiedasdangerousforcarriage.

SECTION15:Regulatoryinformation

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.

COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.

COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).

Thisdocumentdiffersfromthepreviousversioninthefollowingareas:.

2-Otherhazards.

2-Furtherinformation.

2-SUPPLEMENTALHAZARDINFORMATION.

9-9.2.2.Othersafetycharacteristics.

9-9.2.1.Informationwithregardtophysicalhazardclasses. 10-10.2.Chemicalstability.

Otherinformation

Datasources

TextofHazardStatementsin

Section3

Furtherinformation

UniversalCleaner

10-10.6.Hazardousdecompositionproducts. 10-10.1.Reactivity. 11-Acutetoxicity.

11-Repeatedorprolongedexposure. 11-11.2Informationonotherhazards. 12-12.1.Toxicity.

12-12.6Endocrinedisruptingproperties. 12-12.7.Otheradverseeffects. 15-Regulations.

ClassificationandProcedureusedtoderivetheclassificationformixturesaccordingtoRegulation (EC)No.1272/2008,asretainedandamendedinUKlaw.

SkinIrrit.2:H315-Causesskinirritation.-CalculationMethod.

EyeDam.1:H318-Causesseriouseyedamage.-CalculationMethod.

AcuteTox.4:H302-Harmfulifswallowed.

EyeDam.1:H318-Causesseriouseyedamage.

EyeIrrit.2:H319-Causesseriouseyeirritation.

Met.Corr.1:H290-Maybecorrosivetometals.

SkinCorr.1B:H314-Causessevereskinburnsandeyedamage. STOTSE3:H335-Maycauserespiratoryirritation.

AcuteTox.4:H302+H312+H332-Harmfulifswallowed,incontactwithskinorifinhaled

SkinIrrit.2:H315-Causesskinirritation.

TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.

PETROL TREATMENT MSDS

SAFETY DATASHEET

Compilation date: 24/11/2021

Revision date: 14/05/2024

PETROL FUEL ADDITIVE Page: 1

Revision No: 3

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name: PETROL FUEL ADDITIVE

Product code: HC1712

Synonyms: PD0417 HC1712

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of substance / mixture: PC13: Fuels.

1.3. Details of the supplier of the safetydata sheet

Companyname: SUPAGARD LIMITED 23 Gavinton Street Muirend Glasgow Scotland G44 3EF

Tel: 0141 633 5933

Email: james@supagard.co.uk

1.4. Emergencytelephone number

Emergencytel: 0141 633 5933 (office hours only)

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Classification under CLP: Asp. Tox. 1: H304; Skin Irrit. 2: H315; Aquatic Chronic 3: H412

Most important adverse effects: May be fatal if swallowed and enters airways. Causes skin irritation. Harmful to aquatic life with long lasting effects.

2.2. Label elements

Label elements:

Hazard statements: H304: May be fatal if swallowed and enters airways.

H315: Causes skin irritation.

H412: Harmful to aquatic life with long lasting effects.

Hazard pictograms: GHS08: Health hazard

GHS07: Exclamation mark

SAFETY DATASHEET

PETROL FUEL ADDITIVE

Signal words: Danger

Precautionarystatements: P102: Keep out of reach of children.

P273: Avoid release to the environment.

P302+P352: IF ON SKIN: Wash with plenty of soap and water.

P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor.

P331: Do NOT induce vomiting.

P405: Store locked up.

P501: Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

Haz. ingredients (label): Contains:

HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS; HYDROCARBONS, C9 -C11, ALKANES, ISOALKANES, CYCLICS, <2% AROMATICS

2.3. Other hazards

PBT: This product is not identified as a PBT/vPvB substance.

Section 3: Composition/information on ingredients

3.2. Mixtures

Hazardous ingredients:

HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS - REACH registered number(s): 01-2119456620-43XXXX

926-141-6 64742-47-8 - Asp. Tox. 1: H304; -: EUH066

HYDROCARBONS, C9-C11, ALKANES, ISOALKANES, CYCLICS, <2% AROMATICS - REACH registered number(s): 01-2119463258-33-XXXX

919-857-5 1174522-20 -3 - Flam. Liq. 3: H226; STOT SE 3: H336; Asp. Tox. 1: H304; -: EUH066

1-PROPENE, 2-METHYL-HOMOPOLYMER, AMMONIUMSALT - REACH registered number(s): 1-2119475608-26-XXXX - 337367-30-3 - Skin Irrit. 2: H315; Aquatic Chronic 3: H412 1-10%

Section 4: First aid measures

4.1. Description of first aid measures

Skin contact: Wash immediately with plenty of soap and water.

Eye contact: Bathe the eye with running water for 15 minutes.

Ingestion: Wash out mouth with water. Do not induce vomiting. If conscious, give half a litre of water to drink immediately. Transfer to hospital as soon as possible.

Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Move to fresh air in case of accidental inhalation of vapours. Consult a doctor.

4.2. Most important symptoms and effects, both acute and delayed

Skin contact: There may be mild irritation at the site of contact.

Eye contact: There may be irritation and redness.

Ingestion: There may be soreness and redness of the mouth and throat. There may be difficulty swallowing. Nausea and stomach pain may occur. There may be vomiting.

Inhalation: Absorption through the lungs can occur causing symptoms similar to those of ingestion.

4.3. Indication of anyimmediate medical attention and special treatment needed

Section 5: Fire-fighting measures

5.1. Extinguishing media

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers.

5.2. Special hazards arising from the substance or mixture

Exposure hazards: In combustion emits toxic fumes.

5.3. Advice for fire-fighters

Section

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.

6: Accidental release measures

6.1. Personal precautions, protective equipment and emergencyprocedures

Personal precautions: Refer to section 8 of SDS for personal protection details. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Turn leaking containers leak-side up to prevent the escape of liquid.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method. Wash the ground with an appropriate selfemulsifying solvent.

6.4. Reference to other sections

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements: Avoid the formation or spread of mists in the air. Avoid direct contact with the substance.

7.2. Conditions for safe storage, including anyincompatibilities

Storage conditions: Store in a cool, well ventilated area. Keep container tightly closed.

PETROL FUEL ADDITIVE

7.3. Specific end use(s)

Section 8: Exposure controls/personal protection

8.1. Control parameters

Hazardous ingredients:

HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS

Workplace exposure limits:

Respirable dust:

HYDROCARBONS, C9-C11, ALKANES, ISOALKANES, CYCLICS, <2%AROMATICS

DNEL/PNEC Values

DNEL / PNEC No data available.

8.2. Exposure controls

Engineering measures: Ensure there is sufficient ventilation of the area.

Respiratoryprotection: Respiratory protection not required.

Hand protection: Protective gloves.

Eye protection: Safety glasses. Ensure eye bath is to hand.

Skin protection: Protective clothing.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State: Liquid

Colour: Pale yellow

Odour: Paraffinic

Evaporation rate: Slow

Solubilityin water: Insoluble

Viscosity: Non-viscous

Boiling point/range°C: >100

Melting point/range°C: -30

Flammabilitylimits %:lower: 0.9 upper: 4.0

Flash point°C: 60 - 93

Autoflammability°C: >200

Relative density: 0.815

VOC g/l: No data available.

9.2. Other information

Other information: No data available.

Part.coeff. n-octanol/water: No data available.

Vapour pressure: No data available.

pH: No data available.

Section 10: Stabilityand reactivity

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

10.2. Chemical stability

Chemical stability: Stable under normal conditions.

10.3. Possibilityof hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.

10.4. Conditions to avoid

Conditions to avoid: Heat.

10.5. Incompatible materials

Materials to avoid: Strong oxidising agents. Strong acids.

10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

Section 11: Toxicological information

11.1. Information on toxicological effects

Hazardous ingredients:

HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS

DERMAL RBT

HYDROCARBONS, C9-C11, ALKANES, ISOALKANES, CYCLICS, <2%AROMATICS

DERMAL

Relevant hazards for product:

Skin corrosion/irritation DRM Hazardous: calculated

Aspiration hazard - Hazardous: calculated

Symptoms / routes of exposure

Skin contact: There may be mild irritation at the site of contact.

Eye contact: There may be irritation and redness.

mg/kg

mg/kg

mg/l

Ingestion: There may be soreness and redness of the mouth and throat. There may be difficulty swallowing. Nausea and stomach pain may occur. There may be vomiting.

Inhalation: Absorption through the lungs can occur causing symptoms similar to those of ingestion.

Section 12: Ecological information

12.1. Toxicity

Hazardous ingredients:

HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS

Daphnia magna

RAINBOW TROUT (Oncorhynchus mykiss)

EC50

LC50

HYDROCARBONS, C9-C11, ALKANES, ISOALKANES, CYCLICS, <2%AROMATICS

ALGAE

RAINBOW TROUT (Oncorhynchus mykiss)

12.2. Persistence and degradability

Persistence and degradability: Biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: No bioaccumulation potential.

12.4. Mobilityin soil

IC50

LC50

mg/l

Mobility: Readily absorbed into soil. Volatile. Insoluble in water. Floats on water. Vapour is heavier than air.

12.5. Results of PBT and vPvB assessment

PBT identification: This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects: Harmful to aquatic organisms.

Section 13: Disposal considerations

13.1. Waste treatment methods

Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.

Recoveryoperations: Solvent reclamation/regeneration.

Waste code number: 20 01 13

Disposal of packaging: Dispose of as normal industrial waste. Arrange for collection by specialised disposal company.

NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.

Section 14: Transport information

Transport class: This product does not require a classification for transport.

Section 15: Regulatoryinformation

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Specific regulations: Not applicable.

15.2. Chemical SafetyAssessment

Chemical safetyassessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.

Section 16: Other information

Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 2015/830.

IMPORTANT NOTE:

Risk phases in this section belowrelate to the INDIVIDUAL COMPONENTS in the formulation when used at their FULL CONCENTRATIONS, and not at the reduced levels in the mixed product.

See sections 2 and 3 for the calculated hazard and risk phrases for the blended product.

Phrases used in s.2 and s.3: EUH066: Repeated exposure may cause skin dryness or cracking.

H226: Flammable liquid and vapour.

H304: May be fatal if swallowed and enters airways.

H315: Causes skin irritation.

H336: May cause drowsiness or dizziness.

H412: Harmful to aquatic life with long lasting effects.

Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.

PETROL FUEL ADDITIVE

PLASTIC DRESSING - EXTERIOR MSDS

SAFETY DATA SHEET

according to Regulation (EU) 2020/878

Exterior Plastic Dressing

SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking

1.1.Productidentifier

Productname Exterior Plastic Dressing

1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst

ProductUse

[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC35]Washingandcleaningproducts(includingsolventbasedproducts);

[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC35]Washingand cleaningproducts(includingsolventbasedproducts);

Description Vehicleexteriorplasticdressing.

1.3.Detailsofthesupplierofthesafetydatasheet

Company SUPAGARDLIMITED

Address 19-27GavintonStreet Muirend Glasgow G443EF

Web www.supagard.com

Telephone 01416335933

Fax 01416377219

Email James.Smyth@supagard.com

Emailaddressofthe competentperson James.Smyth@supagard.com

1.4.Emergencytelephonenumber

Emergencytelephonenumber01416335933

8.30amto5.00pm

FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)

Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org

SECTION2:Hazardsidentification

2.1.Classificationofthesubstanceormixture

2.1.2.Classification-EC 1272/2008 Asp.Tox.1:H304;STOTSE3:H336;

2.2.Labelelements

Hazardpictograms

Exterior Plastic Dressing

2.2.Labelelements

SignalWord Danger

HazardStatement Asp.Tox.1:H304-Maybefatalifswallowedandentersairways. STOTSE3:H336-Maycausedrowsinessordizziness.

PrecautionaryStatement: Prevention P102-Keepoutofreachofchildren.

PrecautionaryStatement: Response

P301+P310+P330+P331-IFSWALLOWED:ImmediatelycallaPOISONCENTER/doctor.Rinse mouth.DoNOTinducevomiting.

PrecautionaryStatement: Storage P403+P233+P235-Storeinawell-ventilatedplace.Keepcontainertightlyclosed.Keepcool.

PrecautionaryStatement: Disposal

SUPPLEMENTALHAZARD INFORMATION

2.3.Otherhazards

Otherhazards

Furtherinformation

P501-Disposeofcontents/containertoanapproveddisposalsite,inaccordancewithlocal regulations.

Ingredients-Dimethicone,HydrocarbonSolvent,Aminomethoxy-functionalpolydimethylsiloxane, Parfum,CI60730.

Contains-HydrocarbonsC9-11,N-alkanes,Isoalkanes,Cyclics,<2%Aromatic.

Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.

RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.

SECTION3:Composition/informationoningredients

3.2.Mixtures

EC1272/2008

ChemicalName

Hydrocarbons,C9-11,N-alkanes, Isoalkanes,Cyclics,<2%Aromatic

Flam.Liq.3:H226;Asp.Tox. 1:H304;STOTSE3:H336;

AcuteToxicityEstimate(Oral)->10,000mg/kg.

AcuteToxicityEstimate(Dermal)->10,000mg/kg.

AcuteToxicityEstimate(Dust/Mist)->20mg/l.

AcuteToxicityEstimate(Vapours)->20mg/l.

SECTION4:Firstaidmeasures

4.1.Descriptionoffirstaidmeasures

Inhalation

Movetheexposedpersontofreshair.

Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved.

Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution.

Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed

Inhalation Harmfulbyinhalation.Maybefatalifswallowedandentersairways.Maycausedrowsinessor dizziness.

Eyecontact Maycauseirritationtoeyes.

Skincontact Maycauseirritationtoskin.

Ingestion Harmfulifswallowed.Maybefatalifswallowedandentersairways.

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded

Inhalation

Movetheexposedpersontofreshair.Seekmedicalattention.Showthissafetydatasheettothe doctorinattendance.

Eyecontact Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedical

Exterior Plastic Dressing

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded attention.Showthissafetydatasheettothedoctorinattendance. Skincontact

Ingestion

Generalinformation

Removecontaminatedclothing.Seekmedicalattention.Showthissafetydatasheettothedoctor inattendance.

Ifswallowed,seekmedicaladviceimmediatelyandshowthiscontainerorlabel.Showthissafety datasheettothedoctorinattendance.

Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.

SECTION5:Firefightingmeasures

5.1.Extinguishingmedia

Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.

5.2.Specialhazardsarisingfromthesubstanceormixture

Burningproducesirritating,toxicandobnoxiousfumes.

5.3.Adviceforfirefighters

Furtherinformation

Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.

Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.

SECTION6:Accidentalreleasemeasures

6.1.Personalprecautions,protectiveequipmentandemergencyprocedures

6.2.Environmentalprecautions

Wearsuitableprotectiveequipment.

Adviselocalauthoritiesiflargespillscannotbecontained.

6.3.Methodsandmaterialforcontainmentandcleaningup

Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.

6.4.Referencetoothersections

Seesection2,7,8,13forfurtherinformation.

SECTION7:Handlingandstorage

7.1.Precautionsforsafehandling

Avoidcontactwitheyesandskin.Donotbreathevapoursorspraymist.AdoptbestManual Handlingconsiderationswhenhandling,carryinganddispensing.

7.2.Conditionsforsafestorage,includinganyincompatibilities

Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.

7.3.Specificenduse(s)

Suitablepackaging

Vehicleexteriorplasticdressing.

Plasticcontainers.

SECTION8:Exposurecontrols/personalprotection

8.1.Controlparameters

8.2.Exposurecontrols

Exterior Plastic Dressing

Occupationalexposurecontrols. Noworkplaceexposurelimitsapplicable.

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.

8.2.1.Appropriateengineering controls

Eye/faceprotection

SkinprotectionHandprotection

Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.

Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields. Eyewearcomplyingwithanapprovedstandardshouldbewornifariskassessmentindicateseye contactispossible.Thefollowingprotectionshouldbeworn:Wearchemicalsplashgoggles. PersonalprotectiveequipmentforeyeandfaceprotectionshouldcomplywithEuropeanStandard EN166.

Rubbergloves.Chooseglovestoprotecthandsagainstchemicalsdependingontheconcentration andquantityofthehazardoussubstanceandspecifictoplaceofwork.Forspecialapplications, werecommendclarifyingtheresistancetochemicalsoftheaforementionedprotectivegloveswith theglovemanufacturer.

Skinprotection-Other Wearsuitableprotectiveclothing.

Respiratoryprotection Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.

8.2.3.Environmentalexposure controls Preventfurtherleakageorspillageifsafetodoso.

SECTION9:Physicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties

AppearanceGel

ColourPurple

OdourCharacteristic

OdourthresholdNodataavailable pHNodataavailable

MeltingpointNodataavailable

InitialboilingpointNodataavailable

Flashpoint>61°C

EvaporationrateNodataavailable

Flammability(solid,gas)Nodataavailable

VapourpressureNodataavailable

RelativeVapourDensityNodataavailable

Density/RelativeDensity0.8-0.9

PartitioncoefficientNodataavailable

AutoignitiontemperatureNodataavailable

ViscosityNodataavailable

ExplosivepropertiesNodataavailable

OxidisingpropertiesNodataavailable

SolubilityNodataavailable

Exterior Plastic Dressing

9.2.Otherinformation

ConductivityNodataavailable

SurfacetensionNodataavailable

GasgroupNodataavailable

BenzeneContentNodataavailable

LeadcontentNodataavailable VOC(Volatileorganic compounds) Nodataavailable

9.2.1.Informationwithregardtophysicalhazardclasses

Nodataisavailableonthisproduct.

9.2.2.Othersafetycharacteristics

Nodataisavailableonthisproduct.

SECTION10:Stabilityandreactivity

10.1.Reactivity

10.2.Chemicalstability

Stableundernormalconditions.

Stableundernormalconditions.

10.3.Possibilityofhazardousreactions

Strongacids.Strongoxidisingagents.

10.4.Conditionstoavoid

10.5.Incompatiblematerials

Protectfromfrost.

Noincompatiblegroupsnoted.

10.6.Hazardousdecompositionproducts

NoHazardousdecompositionproductswhenstoredandhandledcorrectly.

SECTION11:Toxicologicalinformation

11.1Informationonhazardclasses

Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedusingthemethodsoutlinedinRegulation(EC)No1272/2008(CLP).

Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

OralATE=>10,000mg/kg.

DermalATE=>10,000mg/kg.

Inhalation-VapoursATE=>20mg/l.

Inhalation-Dust/MistATE=>20mg/l.

Skincorrosion/irritation basedonavailabledatatheclassificationcriteriaarenotmet.

Seriouseyedamage/irritationbasedonavailabledatatheclassificationcriteriaarenotmet. Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.

Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet.

Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.

Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-singleexposure STOTSE3:H336-Maycausedrowsinessordizziness.

STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.

Aspirationhazard Asp.Tox.1:H304-Maybefatalifswallowedandentersairways. Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.

Exterior Plastic Dressing

11.1.2.Mixtures

11.1.3.HazardInformation

11.1.4.ToxicologicalInformation

Nodataavailable.

Nodataavailable.

Nodataavailable

11.2Informationonotherhazards

Nodataisavailableonthisproduct.

SECTION12:Ecologicalinformation

12.1.Toxicity

Nodataavailable

12.2.Persistenceanddegradability

SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.

12.3.Bioaccumulativepotential

Partitioncoefficient

12.4.Mobilityinsoil

Nodataisavailableonthisproduct.

StoneacreExteriorPlastic Dressing Nodataavailable

Nodataisavailableonthisproduct.

12.5.ResultsofPBTandvPvBassessment

Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.

12.6Endocrinedisruptingproperties

Nodataisavailableonthisproduct.

12.7.Otheradverseeffects

Nodataisavailableonthisproduct.

SECTION13:Disposalconsiderations

13.1.Wastetreatmentmethods

Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements. Generalinformation

Disposeofincompliancewithalllocalandnationalrequirements. Disposalofpackaging

DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.

SECTION14:Transportinformation

14.1.UNnumber

14.2.UNpropershippingname

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

14.3.Transporthazardclass(es)

14.4.Packinggroup

14.5.Environmentalhazards

14.6.Specialprecautionsforuser

Exterior Plastic Dressing

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

14.7MaritimeTransportinbulkaccordingtoIMOinstruments

Theproductisnotclassifiedasdangerousforcarriage.

SECTION15:Regulatoryinformation

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations

REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.

COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.

COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).

15.2.Chemicalsafetyassessment

Noinformationavailable.

SECTION16:Otherinformation

Otherinformation

Datasources

TextofHazardStatementsin

Section3

Furtherinformation

ClassificationandProcedureusedtoderivetheclassificationformixturesaccordingtoRegulation (EC)No.1272/2008,asretainedandamendedinUKlaw.

Asp.Tox.1:H304-Maybefatalifswallowedandentersairways.-CalculationMethod.

STOTSE3:H336-Maycausedrowsinessordizziness.-CalculationMethod.

Flam.Liq.3:H226-Flammableliquidandvapour.

Asp.Tox.1:H304-Maybefatalifswallowedandentersairways.

STOTSE3:H336-Maycausedrowsinessordizziness.

TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.

SCENT CYCLONE MSDS

SAFETY DATASHEET

ATMOSPHERIC SANITISER

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name: ATMOSPHERIC SANITISER

Product code: HC8468

Synonyms: HC8468

PD0268-10

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of substance / mixture: Aerosol air freshener.

1.3. Details of the supplier of the safetydata sheet

Companyname: SUPAGARD LIMITED

23 Gavinton Street Muirend Glasgow Scotland G44 3EF

Tel: 0141 633 5933

Email: james@supagard.co.uk

1.4. Emergencytelephone number

Emergencytel: 0141 633 5933 (office hours only)

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Classification under CLP: Flam. Aerosol 1: H222; -: H229

Page: 1

Compilation date: 24/08/2022

Revision date: 14/05/2024

Revision No: 2

Most important adverse effects: Extremely flammable aerosol. Pressurised container: May burst if heated.

2.2. Label elements

Label elements:

Hazard statements: H222: Extremely flammable aerosol.

H229: Pressurised container: May burst if heated.

Hazard pictograms: GHS02: Flame

Signal words: Danger

Precautionarystatements: P102: Keep out of reach of children.

P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P211: Do not spray on an open flame or other ignition source.

P251: Do not pierce or burn, even after use.

P410+P412: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.

P302+P350: IF ON SKIN: Gently wash with plenty of soap and water.

P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Haz. ingredients (label): Contains: ETHANOL, LIQUIFIED PETROLEUMGAS PROPELLANT

2.3. Other hazards

Other hazards: In use, may form flammable / explosive vapour-air mixture. PBT: This product is not identified as a PBT/vPvB substance.

Section 3: Composition/information on ingredients

3.2. Mixtures

Hazardous ingredients: ETHANOL - REACH registered number(s): 01-2119457610-43-XXXX

Liq. 2: H225

<0.1% 1,3 BUTADIENE - REACH registered number(s): 01-2119474691-32-XXXX 203-448-7 106-97-8 Substance with a Community workplace exposure limit. Flam. Gas 1: H220; Press. Gas: H280

PROPANE, <0.1% 1,3 BUTADIENE - REACH registered number(s): 01-2119486944-21-XXXX

200-827-9 74-98-6 Substance with a Community workplace exposure limit. Flam. Gas 1: H220; Press. Gas: H280

N-(3-AMINOPROPYL)-N-DODECYLPROPANE-1,3,DIAMINE - REACH registered number(s): 01-2119980592-29

219-145-8 2372-82-9 - Acute Tox. 3: H301; Skin Corr. 1B: H314; Eye Dam. 1: H318; STOT RE 2: H373; Aquatic Acute 1: H400; Aquatic Chronic 1: H410

Section 4: First aid measures

4.1. Description of first aid measures

Skin contact: Wash immediately with plenty of soap and water.

ATMOSPHERIC SANITISER

Eye contact: Bathe the eye with running water for 15 minutes. Consult a doctor.

Ingestion: Do not induce vomiting. If conscious, give half a litre of water to drink immediately. Consult a doctor.

Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Move to fresh air in case of accidental inhalation of vapours. Consult a doctor.

4.2. Most important symptoms and effects, both acute and delayed

Skin contact: There may be mild irritation at the site of contact.

Eye contact: There may be irritation and redness.

Ingestion: There may be irritation of the throat.

Inhalation: There may be a feeling of tightness in the chest with shortness of breath.

4.3. Indication of anyimmediate medical attention and special treatment needed

Immediate / special treatment: Not applicable.

Section 5: Fire-fighting measures

5.1. Extinguishing media

Extinguishing media: Alcohol resistant foam. Water spray. Carbon dioxide. Dry chemical powder.

5.2. Special hazards arising from the substance or mixture

Exposure hazards: Highly flammable. In combustion emits toxic fumes. Forms explosive air-vapour mixture. Vapour may travel considerable distance to source of ignition and flash back. Aerosol cans may explode during a fire, giving a high speed projectile.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergencyprocedures

Personal precautions: Refer to section 8 of SDS for personal protection details. Notify the police and fire brigade immediately. Eliminate all sources of ignition. Cover leaking can until the discharge has stopped, before attempting cleanup operations.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Do not use equipment in clean-up procedure which may produce sparks. Absorb into dry earth or sand. Clean-up should be dealt with only by qualified personnel familiar with the specific substance. Wash the spillage site with large amounts of water.

6.4. Reference to other sections

Reference to other sections: Refer to section 8 of SDS.

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements: Smoking is forbidden. Use non-sparking tools. Ensure there is sufficient ventilation of the area. Do not handle in a confined space.

7.2. Conditions for safe storage, including anyincompatibilities

Storage conditions: Store in a cool, well ventilated area. Keep away from sources of ignition. Keep away from direct sunlight.

7.3. Specific end use(s)

Specific end use(s): No data available.

Section 8: Exposure controls/personal protection

8.1. Control parameters

Hazardous ingredients: ETHANOL

Workplace exposure limits:

dust:

BUTANE, <0.1%1,3 BUTADIENE

PROPANE, <0.1%1,3 BUTADIENE

DNEL/PNEC Values

Hazardous ingredients:

ATMOSPHERIC SANITISER

PNEC Fresh water 0.001mg/L -

PNEC Marine water 0.0001mg/L - -

PNEC Fresh water sediments 8.5mg/kg dry weight - -

PNEC Marine sediments 0.85mg/kg dry weight

PNEC Soil (agricultural) 45.34mg/kg dry weigh -

PNEC Microorganisms in sewage treatment 1.33mg/L

8.2. Exposure controls

Engineering measures: Ensure there is sufficient ventilation of the area. Ensure lighting and electrical equipment are not a source of ignition.

Respiratoryprotection: Respiratory protection not required.

Hand protection: Protective gloves.

Eye protection: Safety glasses. Ensure eye bath is to hand.

Skin protection: Protective clothing.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State: Aerosol

Colour: Colourless

Odour: Perfumed

Evaporation rate: Fast

Solubilityin water: Soluble

Viscosity: Non-viscous

Boiling point/range°C: No data available.

Melting point/range°C: No data available.

Flammabilitylimits %:lower: 0.9 upper: 9.0

Flash point°C: -40

Autoflammability°C: >230

Part.coeff. n-octanol/water: Not applicable.

Vapour pressure: No data available.

Relative density: No data available. pH: Not applicable.

VOC g/l: No data available.

9.2. Other information

Other information: No data available.

Section 10: Stabilityand reactivity

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

ATMOSPHERIC SANITISER

10.2. Chemical stability

Chemical stability: Stable under normal conditions. Stable at room temperature.

10.3. Possibilityof hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions. Decomposition may occur on exposure to conditions or materials listed below.

10.4. Conditions to avoid

Conditions to avoid: Heat. Hot surfaces. Sources of ignition. Flames. Direct sunlight.

10.5. Incompatible materials

Materials to avoid: Strong oxidising agents. Strong acids.

10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

Section 11: Toxicological information

11.1. Information on toxicological effects

Hazardous ingredients:

Toxicityvalues: No data available.

Symptoms / routes of exposure

Skin contact: There may be mild irritation at the site of contact.

Eye contact: There may be irritation and redness.

Ingestion: There may be irritation of the throat.

Inhalation: There may be a feeling of tightness in the chest with shortness of breath.

Section 12: Ecological information

12.1. Toxicity

Hazardous ingredients:

ATMOSPHERIC SANITISER

N-(3-AMINOPROPYL)-N-DODECYLPROPANE-1,3,DIAMINE

Daphnia magna

GREEN ALGA (Selenastrum capricornutum)

ZEBRAFISH (Brachydanio rerio)

12.2. Persistence and degradability

Persistence and degradability: Biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: No bioaccumulation potential.

12.4. Mobilityin soil

EC50 >0.01-0.1 mg/l

ErC50

LC50

Mobility: Readily absorbed into soil. Volatile. Soluble in water. Vapour is heavier than air.

12.5. Results of PBT and vPvB assessment

PBT identification: This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects: Negligible ecotoxicity.

Section 13: Disposal considerations

13.1. Waste treatment methods

Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.

Recoveryoperations: Recycling/reclamation of metals and metal compounds.

Waste code number: 16 05 05

Disposal of packaging: Dispose of as normal industrial waste. Empty cans must not be burned because of explosion hazard.

NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.

Section 14: Transport information

14.1. UN number

UN number: UN1950

14.2. UN proper shipping name

Shipping name: AEROSOLS

14.3. Transport hazard class(es)

Transport class: 2

14.4. Packing group

ATMOSPHERIC SANITISER

14.5. Environmental hazards

Environmentallyhazardous: No

14.6. Special precautions for user

Special precautions: No special precautions.

Tunnel code: D

Transport category: 2

Section 15: Regulatoryinformation

Marine pollutant: No

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Specific regulations: Not applicable.

15.2. Chemical SafetyAssessment

Chemical safetyassessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.

Section 16: Other information

Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 2015/830.

All substances in this preparation are registered within UK/EU/EFTA countries under the REACH (UK/EC) (ammended) regulations, EC 1907/2006

IMPORTANT NOTE:

Risk phases in this section belowrelate to the INDIVIDUAL COMPONENTS in the formulation when used at their FULL CONCENTRATIONS, and not at the reduced levels in the mixed product.

See sections 2 and 3 for the calculated hazard and risk phrases for the blended product.

Phrases used in s.2 and s.3: H220: Extremely flammable gas.

H222: Extremely flammable aerosol.

H225: Highly flammable liquid and vapour.

H229: Pressurised container: May burst if heated.

H301: Toxic if swallowed.

H314: Causes severe skin burns and eye damage.

H318: Causes serious eye damage.

H373: May cause damage to organs through prolonged or repeated exposure.

H400: Very toxic to aquatic life.

H410: Very toxic to aquatic life with long lasting effects.

Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.

SAFETY DATASHEET

SCENT CYCLONE REJUVENATE

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name: SCENT CYCLONE REJUVENATE

Product code: HC8542

Synonyms: HC8542 / PD1077

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of substance / mixture: Aerosol air freshener.

1.3. Details of the supplier of the safetydata sheet

Companyname: SUPAGARD LIMITED

23 Gavinton Street

Muirend Glasgow Scotland G44 3EF

Tel: 0141 633 5933

Email: james@supagard.co.uk

1.4. Emergencytelephone number

Emergencytel: 0141 633 5933 (office hours only)

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Classification under CLP: Flam. Aerosol 1: H222; -: H229

Page: 1

Compilation date: 18/07/2024

Revision No: 1

Most important adverse effects: Extremely flammable aerosol. Pressurised container: May burst if heated.

2.2. Label elements

Label elements:

Hazard statements: H222: Extremely flammable aerosol.

H229: Pressurised container: May burst if heated.

Hazard pictograms: GHS02: Flame

Signal words: Danger

Precautionarystatements: P102: Keep out of reach of children.

P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition

SCENT CYCLONE REJUVENATE

sources. No smoking.

P211: Do not spray on an open flame or other ignition source.

P251: Do not pierce or burn, even after use.

P410+P412: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.

2.3. Other hazards

Other hazards: In use, may form flammable / explosive vapour-air mixture. Contains no PBT/vPvB substances >/= 0.1% assessed in accordance with REACH AnnexXIII. This mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine distrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0.1%.

PBT: This product is not identified as a PBT/vPvB substance.

Section 3: Composition/information on ingredients

3.2. Mixtures

Hazardous ingredients:

ETHANOL - REACH registered number(s): 01-2119457610-43-XXXX

<0.1% 1,3 BUTADIENE - REACH registered number(s): 01-2119474691-32-XXXX

with a Community workplace exposure limit.

<0.1% 1,3 BUTADIENE - REACH registered number(s): 01-2119486944-21-XXXX

Section 4: First aid measures

4.1. Description of first aid measures

Skin contact: Wash immediately with plenty of soap and water.

Eye contact: Bathe the eye with running water for 15 minutes.

Ingestion: Wash out mouth with water.

Inhalation: Consult a doctor in case of complaints

4.2. Most important symptoms and effects, both acute and delayed

Skin contact: There may be mild irritation at the site of contact.

Eye contact: There may be irritation and redness.

Ingestion: There may be irritation of the throat.

Inhalation: No symptoms.

4.3. Indication of anyimmediate medical attention and special treatment needed

Immediate / special treatment: Not applicable.

Section 5: Fire-fighting measures

5.1. Extinguishing media

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers.

5.2. Special hazards arising from the substance or mixture

Exposure hazards: In combustion emits toxic fumes.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergencyprocedures

Personal precautions: Refer to section 8 of SDS for personal protection details. Cover leaking can until the discharge has stopped, before attempting cleanup operations.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method. Extinguish all ignition sources. Ventilate area well. Avoid sparks, flames, smoking and any other heat source. Leaking material will evaporate leaving no residues.

6.4. Reference to other sections

Reference to other sections: Refer to section 8 of SDS.

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements: Smoking is forbidden. Use non-sparking tools. Ensure there is sufficient ventilation of the area. Do not handle in a confined space.

7.2. Conditions for safe storage, including anyincompatibilities

Storage conditions: Store in a cool, well ventilated area. Keep container tightly closed.

SCENT CYCLONE REJUVENATE

SCENT CYCLONE REJUVENATE

7.3. Specific end use(s)

Specific end use(s): No data available.

Section 8: Exposure controls/personal protection

8.1. Control parameters

Hazardous ingredients: ETHANOL

Workplace exposure limits:

Respirable dust:

mg/m3

BUTANE, <0.1%1,3 BUTADIENE UK

mg/m3

PROPANE, <0.1%1,3 BUTADIENE

UK Asphyxiating Asphyxiating -

DNEL/PNEC Values

DNEL / PNEC No data available.

8.2. Exposure controls

Engineering measures: Ensure there is sufficient ventilation of the area. Ensure lighting and electrical equipment are not a source of ignition.

Respiratoryprotection: Respiratory protection not required.

Hand protection: Protective gloves.

Eye protection: Safety glasses. Ensure eye bath is to hand.

Skin protection: Protective clothing.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State: Aerosol

Colour: Colourless

Odour: Perfumed

Evaporation rate: Fast

Solubilityin water: Soluble

Viscosity: Non-viscous

Boiling point/range°C: No data available.

Melting point/range°C: No data available.

Flammabilitylimits %:lower: 0.9 upper: 9.0

Flash point°C: -40

Autoflammability°C: >230

Part.coeff. n-octanol/water: Not applicable.

Vapour pressure: No data available.

Relative density: No data available. pH: Not applicable.

VOC g/l: No data available.

9.2. Other information

Other information: No data available.

Section 10: Stabilityand reactivity

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

10.2. Chemical stability

Chemical stability: Stable under normal conditions.

10.3. Possibilityof hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.

Decomposition may occur on exposure to conditions or materials listed below.

10.4. Conditions to avoid

Conditions to avoid: Heat. Hot surfaces. Sources of ignition. Flames. Direct sunlight.

10.5. Incompatible materials

Materials to avoid: Strong oxidising agents. Strong acids.

10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

Section 11: Toxicological information

11.1. Information on toxicological effects

Hazardous ingredients:

Toxicityvalues: No data available.

Symptoms / routes of exposure

Skin contact: There may be mild irritation at the site of contact.

Eye contact: There may be irritation and redness.

Ingestion: There may be irritation of the throat.

Inhalation: No symptoms.

Section 12: Ecological information

12.1. Toxicity

Ecotoxicityvalues: No data available.

SCENT CYCLONE REJUVENATE

SCENT CYCLONE REJUVENATE

12.2. Persistence and degradability

Persistence and degradability: Biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: No bioaccumulation potential.

12.4. Mobilityin soil

Mobility: Readily absorbed into soil.

12.5. Results of PBT and vPvB assessment

PBT identification: This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects: Negligible ecotoxicity.

Section 13: Disposal considerations

13.1. Waste treatment methods

Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.

Recoveryoperations: Recycling/reclamation of metals and metal compounds.

Waste code number: 16 05 05

Disposal of packaging: Empty cans must not be burned because of explosion hazard. Recycle container where permitted. Disposal of waste containers must be done in accordance with local and / or national regulations.

NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.

Section 14: Transport information

14.1. UN number

UN number: UN1950

14.2. UN proper shipping name

Shipping name: AEROSOLS

14.3. Transport hazard class(es)

Transport class: 2

14.4. Packing group

14.5. Environmental hazards

Environmentallyhazardous: No

14.6. Special precautions for user

Special precautions: No special precautions.

Tunnel code: D

Marine pollutant: No

Transport category: 2

Section 15: Regulatoryinformation

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Specific regulations: This product is not, nor does it contain a persistant organic pollutant (POP) according to Regulation (EC) 2019/1021 and subsequent revisions. This product is not, nor does it contain any candidate on the REACH SVHC list acording to Regulation (EC) 2006/1907 and subsequent revisions. This product is not, nor does it contain, any candidate on the Endocrine Disruptor list, and any subsequent revisions, classified for human health cat 2 or environmental cat 2, in accordance with EC1272/2008 (ammended 2022)

15.2. Chemical SafetyAssessment

Chemical safetyassessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.

Section 16: Other information

Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 2015/830.

All substances in this preparation are registered within UK/EU/EFTA countries under the REACH (UK/EC) (ammended) regulations, EC 1907/2006

*indicates text in the SDS which has changed since the last revision.

Phrases used in s.2 and s.3: H220: Extremely flammable gas.

H222: Extremely flammable aerosol.

H225: Highly flammable liquid and vapour.

H229: Pressurised container: May burst if heated.

Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.

SILICONE FREE TYRE DRESSING MSDS

SAFETY DATA SHEET

according to Regulation (EU) 2020/878

Tyre Dressing

SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking

1.1.Productidentifier

Productname Tyre Dressing

1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst

ProductUse

[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC35]Washingandcleaningproducts(includingsolventbasedproducts);

[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC35]Washingand cleaningproducts(includingsolventbasedproducts);

Description Thisnewwaterresistantcoatinghasbeencarefullyformulatedfortherenovationofallplastics, PVC,rubberetc,throughoutyourvehicle.

1.3.Detailsofthesupplierofthesafetydatasheet

Company SUPAGARDLIMITED

Address 19-27GavintonStreet Muirend Glasgow G443EF

Web www.supagard.com

Telephone 01416335933

Fax 01416377219

Email James.Smyth@supagard.com

Emailaddressofthe competentperson James.Smyth@supagard.com

1.4.Emergencytelephonenumber

Emergencytelephonenumber01416335933 8.30amto5.00pm

FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)

Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org

SECTION2:Hazardsidentification

2.1.Classificationofthesubstanceormixture

2.1.2.Classification-EC 1272/2008 Flam.Liq.3:H226;Asp.Tox.1:H304;STOTSE3:H336;

2.2.Labelelements

2.2.Labelelements

Hazardpictograms

SignalWord Danger

Tyre Dressing

HazardStatement Flam.Liq.3:H226-Flammableliquidandvapour.

Asp.Tox.1:H304-Maybefatalifswallowedandentersairways.

STOTSE3:H336-Maycausedrowsinessordizziness.

PrecautionaryStatement: Prevention

PrecautionaryStatement: Response

P102-Keepoutofreachofchildren.

P210-Keepawayfromheat,hotsurfaces,sparks,openflamesandotherignitionsources.No smoking.

P301+P310+P330+P331-IFSWALLOWED:ImmediatelycallaPOISONCENTER/doctor.Rinse mouth.DoNOTinducevomiting.

P302+P350-IFONSKIN:Gentlywashwithplentyofsoapandwater.

P304+P340-IFINHALED:Removepersontofreshairandkeepcomfortableforbreathing.

PrecautionaryStatement: Storage P403+P233-Storeinawell-ventilatedplace.Keepcontainertightlyclosed.

SUPPLEMENTALHAZARD INFORMATION

2.3.Otherhazards

Otherhazards

Furtherinformation

IngredientsasrequiredbyRegulation(EC)No648/2004:. Lessthan5%AromaticHydrocarbons,Dimethicone,Aminofunctionalsilicone.

Contains-Hydrocarbons,C9-11,N-alkanes,Isoalkanes,Cyclics,<2%Aromatic.

Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.

RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.

SECTION3:Composition/informationoningredients

3.2.Mixtures

EC1272/2008

ChemicalName

Hydrocarbons,C9-11,N-alkanes, Isoalkanes,Cyclics,<2%Aromatic 1174522-20-3919-857-501-2119463258-33

SECTION4:Firstaidmeasures

4.1.Descriptionoffirstaidmeasures

Inhalation Movetheexposedpersontofreshair.

Flam.Liq.3:H226;Asp.Tox. 1:H304;STOTSE3:H336; 50-60%

Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved.

Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution.

Ingestion DONOTINDUCEVOMITING.Ifswallowed,donotinducevomiting:seekmedicaladvice immediatelyandshowthiscontainerorlabel.Rinsemouththoroughly.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed

Inhalation Highconcentrationofvapourinenclosedspacemaycauseirritation,headachesandnausea.May causeirritationtorespiratorysystem.

Eyecontact Irritatingtoeyes.

Skincontact Maycauseskindrynessandirritation.Prolongedcontactmaycausedefattingoftheskin.

Ingestion Harmfulifingestedorswallowed.

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded

Tyre Dressing

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded TREATSYMPTOMATICALLY.

Inhalation

Eyecontact

Skincontact

Ingestion

Generalinformation

Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.

Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.

Seekmedicalattentionifirritationorsymptomspersist.

Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.

Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.

SECTION5:Firefightingmeasures

5.1.Extinguishingmedia

Flammableliquid.Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthe surroundingenvironment.

5.2.Specialhazardsarisingfromthesubstanceormixture

Burningproducesirritating,toxicandobnoxiousfumes.

5.3.Adviceforfirefighters

Furtherinformation

Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.

Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.

SECTION6:Accidentalreleasemeasures

6.1.Personalprecautions,protectiveequipmentandemergencyprocedures

Wearsuitableprotectiveequipment.Flammableliquid.Avoidsparks,flames,heatandsourcesof ignition.

6.2.Environmentalprecautions

Adviselocalauthoritiesiflargespillscannotbecontained.

6.3.Methodsandmaterialforcontainmentandcleaningup

Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelledcontainersfor disposal.Avoidsparks,flames,heatandsourcesofignition.

6.4.Referencetoothersections

Seesection2,7,8,13forfurtherinformation.

SECTION7:Handlingandstorage

7.1.Precautionsforsafehandling

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.

7.2.Conditionsforsafestorage,includinganyincompatibilities

Flammableliquid.Avoidsparks,flames,heatandsourcesofignition.AvoidstoringindirectSun Light.Storeinawell-ventilatedplace.Keepcool.Storeinoriginalcontainer.Keepcontainertightly closed.Keepawayfromcombustiblematerial.Keepoutofthereachofchildren.

7.3.Specificenduse(s)

Suitablepackaging

Thisnewwaterresistantcoatinghasbeencarefullyformulatedfortherenovationofallplastics, PVC,rubberetc.throughoutyourvehicle.

Suitablepackaging

Plasticcontainers.

Tyre Dressing

SECTION8:Exposurecontrols/personalprotection

8.1.Controlparameters

8.1.1.ExposureLimitValues

Ethylbenzene(ethylbenzol) (Ethylbenzene)

Occupationalexposurecontrols.

WEL8-hrlimitppm:100

WEL15minlimitppm:125

WEL8-hrlimitmg/m3:441

WEL15minlimitmg/m3:552

WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust:methanol

WEL8-hrlimitppm:200

WEL15minlimitppm:250

WEL8-hrlimitmg/m3:266

WEL15minlimitmg/m3:333

WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust:propan-2-ol

WEL8-hrlimitppm:400

WEL15minlimitppm:500

DNEL:Derivedno-effectlevel.

ExposurePattern-Workers

Ethylbenzene(ethylbenzol)

methanol

propan-2-ol

WEL8-hrlimitmg/m3:999

WEL15minlimitmg/m3:1250

WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -

Acuteinhalation-Localeffects293mg/m³

Long-term-inhalation-Systemic effects 77mg/m³

Acuteinhalation-Systemic effects 130mg/m³

Acuteinhalation-Localeffects130mg/m³

Long-term-inhalation-Systemic effects 130mg/m³

Long-term-dermal-Systemic effects 20mg/kg

Long-term-inhalation-Systemic effects 500mg/m³

Long-term-dermal-Systemic effects 888mg/kg

ExposurePattern-Generalpopulation

Long-term-dermal-Systemic effects 180mg/kg

Acutedermal-Systemiceffects20mg/kg

Long-term-inhalation-Local effects 130mg/m³

ExposurePattern-Generalpopulation

Ethylbenzene(ethylbenzol)

methanol

propan-2-ol

8.2.Exposurecontrols

Tyre Dressing

Long-term-inhalation-Systemic effects 15mg/m³

Long-term-oral-Systemic effects 1.6mg/kg

Acuteinhalation-Systemic effects 26mg/m³

Acuteinhalation-Localeffects26mg/m³

Acuteoral-Systemiceffects5mg/kg

Long-term-inhalation-Local effects 26mg/m³

Long-term-oral-Systemic effects 5mg/kg

Long-term-inhalation-Systemic effects 89mg/m³

Long-term-dermal-Systemic effects 319mg/kg

8.2.1.Appropriateengineering controls

Eye/faceprotection

Acutedermal-Systemiceffects5mg/kg

Long-term-inhalation-Systemic effects 26mg/m³

Long-term-dermal-Systemic effects 5mg/kg

Long-term-oral-Systemiceffects26mg/kg

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.

Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.

Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields.

SkinprotectionHandprotection Rubbergloves.

Respiratoryprotection

8.2.3.Environmentalexposure controls

Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.

Preventfurtherleakageorspillageifsafetodoso.

SECTION9:Physicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties

Tyre Dressing

9.1.Informationonbasicphysicalandchemicalproperties

AppearanceLiquid

ColourColourless

OdourCharacteristic

OdourthresholdNodataavailable

pHNodataavailable

MeltingpointNodataavailable

InitialboilingpointNodataavailable

Flashpoint40°C

EvaporationrateNodataavailable Flammability(solid,gas)Nodataavailable

VapourpressureNodataavailable

RelativeVapourDensityNodataavailable

Density/RelativeDensity0.8-0.825

PartitioncoefficientNodataavailable

AutoignitiontemperatureNodataavailable

ViscosityNodataavailable

ExplosivepropertiesNodataavailable OxidisingpropertiesNodataavailable

SolubilityNodataavailable

9.2.Otherinformation

ConductivityNodataavailable

SurfacetensionNodataavailable GasgroupNodataavailable

BenzeneContentNodataavailable

LeadcontentNodataavailable

VOC(Volatileorganic compounds) Nodataavailable

9.2.1.Informationwithregardtophysicalhazardclasses

Nodataisavailableonthisproduct.

9.2.2.Othersafetycharacteristics

Nodataisavailableonthisproduct.

SECTION10:Stabilityandreactivity

10.1.Reactivity

10.2.Chemicalstability

Flammableliquid.Stableundernormalconditions.

Flammableliquid.Stableundernormalconditions.

10.3.Possibilityofhazardousreactions

Oxidisingagents.Combustiblematerials.

10.4.Conditionstoavoid

10.5.Incompatiblematerials

Avoidsparks,flames,heatandsourcesofignition.AvoidstoringindirectSunLight.

Oxidisingagents.

10.6.Hazardousdecompositionproducts

NoHazardousdecompositionproductswhenstoredandhandledcorrectly.

Tyre Dressing

SECTION11:Toxicologicalinformation

11.1Informationonhazardclasses

Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedusingthemethodsoutlinedinRegulation(EC)No1272/2008(CLP).

Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet. OralATE=>10,000mg/kg.

DermalATE=>10,000mg/kg.

Inhalation-Dust/MistATE=>10,000mg/l.

Skincorrosion/irritation basedonavailabledatatheclassificationcriteriaarenotmet.

Seriouseyedamage/irritationbasedonavailabledatatheclassificationcriteriaarenotmet. Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.

Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet.

Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.

Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-singleexposure STOTSEcategory3.H336-Maycausedrowsinessordizziness.

STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.

Aspirationhazard

Repeatedorprolonged exposure

11.1.2.Mixtures

11.1.3.HazardInformation

11.1.4.ToxicologicalInformation

Ethylbenzene(ethylbenzol)

methanol

propan-2-ol

11.2Informationonotherhazards

AspirationHazardCategory1.H304-Maybefatalifswallowedandentersairways.

Prolongedcontactmaycausedefattingoftheskin.

Nodataavailable.

Nodataavailable.

OralRatLD50:3500mg/kg

InhalationRatLC50/4h:17.2mg/l

OralRatLD50:100.0mg/kg

InhalationRatLC50/4h:3.0mg/l

InhalationRatLC50/6h:>10000ppm

DermalRabbitLD50:13900mg/kg

Nodataisavailableonthisproduct.

SECTION12:Ecologicalinformation

12.1.Toxicity

Ethylbenzene(ethylbenzol)

DaphniaEC50/48h:1.8000mg/l

RainbowtroutLC50/96h:4.2mg/l methanol

DaphniaEC50/48h:18260.0000mg/l

FatheadminnowsLC50/96h:>100mg/l

Lepomis_MacrochirusLC50/96h:15400mg/l propan-2-ol

DaphniaEC50/48h:10000.0000mg/l

FatheadminnowsLC50/96h:9640mg/l

12.2.Persistenceanddegradability

12.3.Bioaccumulativepotential

DermalRabbitLD50:5001.0mg/kg

DermalRabbitLD50:300.0mg/kg

OralRatLD50:5840mg/kg

AlgaeEC50/72h:5.4mg/l

GreenalgaeEC50/96h:22000.0mg/l

BluegillsunfishLC50/96h:15400.0mg/l

FishLC50/96h:4200.0000mg/l

SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.

12.3.Bioaccumulativepotential

Partitioncoefficient

12.4.Mobilityinsoil

Tyre Dressing

Theproductisnotbioaccumulating.

StoneacreTyreDressingNodataavailable propan-2-ol0.05logP methanol-0.74LogPow Ethylbenzene(ethylbenzol)3.5

Immiscibleinwater.

12.5.ResultsofPBTandvPvBassessment

Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.

12.6Endocrinedisruptingproperties

Nodataisavailableonthisproduct.

12.7.Otheradverseeffects

Nodataisavailableonthisproduct.

SECTION13:Disposalconsiderations

13.1.Wastetreatmentmethods

Generalinformation

Disposalofpackaging

Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.

Disposeofincompliancewithalllocalandnationalrequirements.

DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.

SECTION14:Transportinformation

Hazardpictograms

14.1.UNnumber

14.2.UNpropershippingname

14.3.Transporthazardclass(es)

Packinggroup

14.5.Environmentalhazards

Tyre Dressing

14.5.Environmentalhazards

Environmentalhazards No

Marinepollutant No

14.6.Specialprecautionsforuser Noadditionalspecialprecautions.

14.7MaritimeTransportinbulkaccordingtoIMOinstruments Notapplicable.

ADR/RID

HazardID 30

TunnelCategory (D/E)

IMDG

EmSCode F-ES-D IATA

PackingInstruction(Cargo)366

SECTION15:Regulatoryinformation

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture

Regulations

REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.

COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.

COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).

Thisdocumentdiffersfromthepreviousversioninthefollowingareas:.

2-Otherhazards.

2-PrecautionaryStatement:Prevention.

2-PrecautionaryStatement:Response.

2-PrecautionaryStatement:Storage.

2-PrecautionaryStatement:Disposal.

2-Furtherinformation.

2-SUPPLEMENTALHAZARDINFORMATION.

Otherinformation

Tyre Dressing

9-9.2.2.Othersafetycharacteristics.

9-9.2.1.Informationwithregardtophysicalhazardclasses. 11-11.2Informationonotherhazards.

12-12.6Endocrinedisruptingproperties. 12-12.7.Otheradverseeffects. 15-Regulations.

Datasources ClassificationandProcedureusedtoderivetheclassificationformixturesaccordingtoRegulation (EC)No.1272/2008,asretainedandamendedinUKlaw.

Flam.Liq.3:H226-Flammableliquidandvapour.-FlashPoint-40degC.

Asp.Tox.1:H304-Maybefatalifswallowedandentersairways.-CalculationMethod.

STOTSE3:H336-Maycausedrowsinessordizziness.-CalculationMethod.

TextofHazardStatementsin Section3

Furtherinformation

Flam.Liq.3:H226-Flammableliquidandvapour.

Asp.Tox.1:H304-Maybefatalifswallowedandentersairways.

STOTSE3:H336-Maycausedrowsinessordizziness.

TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.

SNOW FOAM MSDS

SAFETY DATA SHEET

according to Regulation (EU) 2020/878

Snow Foam

SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking

1.1.Productidentifier

Productname Snow Foam

1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst ProductUse

[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC35]Washingand cleaningproducts(includingsolventbasedproducts);

[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC35]Washingandcleaningproducts(includingsolventbasedproducts); Description SnowFoam.

1.3.Detailsofthesupplierofthesafetydatasheet Company SUPAGARDLIMITED

Address 19-27GavintonStreet Muirend Glasgow G443EF

Web www.supagard.com

Telephone 01416335933

Fax 01416377219

Email James.Smyth@supagard.com

Emailaddressofthe competentperson James.Smyth@supagard.com

1.4.Emergencytelephonenumber

Emergencytelephonenumber01416335933 8.30amto5.00pm

FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)

Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org

SECTION2:Hazardsidentification

2.1.Classificationofthesubstanceormixture

2.1.2.Classification-EC 1272/2008 SkinCorr.1A:H314;

2.2.Labelelements

Hazardpictograms

2.2.Labelelements

SignalWord Danger

HazardStatement

PrecautionaryStatement: Prevention

PrecautionaryStatement: Response

PrecautionaryStatement: Disposal

SUPPLEMENTALHAZARD INFORMATION

2.3.Otherhazards

Otherhazards

Furtherinformation

Snow Foam

SkinCorr.1A:H314-Causessevereskinburnsandeyedamage.

P102-Keepoutofreachofchildren.

P264-Washhandsandothercontactedskinthoroughlyafterhandling.

P280-Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection.

P302+P350-IFONSKIN:Gentlywashwithplentyofsoapandwater.

P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.

P501-Disposeofcontents/containertoanapproveddisposalsite,inaccordancewithlocal regulations.

IngredientsasrequiredbyRegulation(EC)No648/2004:.

5-15%AnionicSurfactants,Lessthan5%AmphotericSurfactants,Lessthan5%Non-ionic Surfactants,EDTAandsaltsthereof,Parfum,Vanillin,CI74190.

Contains-Amines,C12-14(evennumbered)-alkyldimethyl,N-oxides,Alcohols,C12-14, ethoxylated,sulfates,sodiumsalts,2-butoxyethanol,EthylMethylphenylglycidate,Sodium Hydroxide.

Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.

RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.

SECTION3:Composition/informationoningredients

3.2.Mixtures

EC1272/2008

ChemicalName

ethyl 3-methyl-3-phenyloxirane-2-carbox ylate

Amines,C12-14(evennumbered) -alkyldimethyl,N-oxides

77-83-8201-061-8

308062-28-4931-292-601-2119490061-47

68891-38-3

SkinSens.1:H317;Aquatic Chronic2:H411; 0-0.5%

AcuteTox.4:H302;SkinIrrit. 2:H315;EyeDam.1:H318; AquaticAcute1:H400; AquaticChronic2:H411; 0.5-1% ALCOHOLS,C12-14, ETHOXYLATED,SULFATES, SODIUMSALTS...

603-014-00-0111-76-2203-905-001-2119475108-36

SkinIrrit.2:H315;EyeDam. 1:H318;AquaticChronic3: H412; 1-10% ButylGlycolEther (2-Butoxyethanol)

AcuteTox.4:H302+H332; SkinIrrit.2:H315;EyeIrrit.2: H319; 1-10%

Amines,C12-14(evennumbered)-alkyldimethyl,N-oxides,CASNo.308062-28-4-MFactorAcute =1.

SECTION4:Firstaidmeasures

4.1.Descriptionoffirstaidmeasures

Inhalation Movetheexposedpersontofreshair.

Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved. Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution. Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed Inhalation Maycauseirritationtorespiratorysystem. Eyecontact Causesseriouseyedamage.

Snow Foam

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed

Skincontact Causessevereburns.

Ingestion Maycauseirritationtomucousmembranes.

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded

Inhalation

Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.

Eyecontact Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.

Skincontact Seekmedicalattentionifirritationorsymptomspersist.

Ingestion Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.

Generalinformation

Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.

SECTION5:Firefightingmeasures

5.1.Extinguishingmedia

Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.

5.2.Specialhazardsarisingfromthesubstanceormixture

Noneknown.

5.3.Adviceforfirefighters

Furtherinformation

Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.

Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.

SECTION6:Accidentalreleasemeasures

6.1.Personalprecautions,protectiveequipmentandemergencyprocedures

6.2.Environmentalprecautions

Wearsuitableprotectiveequipment.

Adviselocalauthoritiesiflargespillscannotbecontained.

6.3.Methodsandmaterialforcontainmentandcleaningup

Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.

6.4.Referencetoothersections

Seesection2,7,8,13forfurtherinformation.

SECTION7:Handlingandstorage

7.1.Precautionsforsafehandling

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.

7.2.Conditionsforsafestorage,includinganyincompatibilities

Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.

7.3.Specificenduse(s) SnowFoam.

Suitablepackaging

Suitablepackaging

Plasticcontainers.

SECTION8:Exposurecontrols/personalprotection

8.1.Controlparameters

8.1.1.ExposureLimitValues

ButylGlycolEther (2-Butoxyethanol)

SodiumHydroxide

Snow Foam

Occupationalexposurecontrols.

WEL8-hrlimitppm:25

WEL15minlimitppm:50

WEL8-hrlimitmg/m3:123

WEL15minlimitmg/m3:101.2

WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -

WEL8-hrlimitppm:-

WEL15minlimitppm:-

WEL8-hrlimitmg/m3:-

WEL15minlimitmg/m3:2

WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -

DNEL:Derivedno-effectlevel.

ExposurePattern-Workers

ButylGlycolEther

SodiumHydroxide

Acuteinhalation-Systemic effects 1091mg/m³

Acuteinhalation-Localeffects246mg/m³

Long-term-inhalation-Systemic effects 98mg/m³

Acuteinhalation-Localeffects2mg/m³

Acutedermal-Localeffects2mg/m³

ExposurePattern-Generalpopulation

ButylGlycolEther

SodiumHydroxide

8.2.Exposurecontrols

Acuteinhalation-Systemic effects 426mg/m³

Acutedermal-Systemiceffects89mg/kg

Long-term-inhalation-Systemic effects 59mg/m³

Long-term-dermal-Systemic effects 75mg/kg

Long-term-inhalation-Local effects 1mg/m³

Acutedermal-Systemiceffects89mg/kg

Long-term-dermal-Systemic effects 125mg/kg

Long-term-inhalation-Local effects 1mg/m³

Acuteoral-Systemiceffects26.7mg/kg

Long-term-inhalation-Local effects 147mg/m³

Long-term-oral-Systemiceffects6.3mg/kg

8.2.Exposurecontrols

8.2.1.Appropriateengineering controls

Eye/faceprotection

SkinprotectionHandprotection

Snow Foam

Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.

Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields. Eyewearcomplyingwithanapprovedstandardshouldbewornifariskassessmentindicateseye contactispossible.Thefollowingprotectionshouldbeworn:Wearchemicalsplashgoggles. PersonalprotectiveequipmentforeyeandfaceprotectionshouldcomplywithEuropeanStandard EN166.

Rubbergloves.Chooseglovestoprotecthandsagainstchemicalsdependingontheconcentration andquantityofthehazardoussubstanceandspecifictoplaceofwork.Forspecialapplications, werecommendclarifyingtheresistancetochemicalsoftheaforementionedprotectivegloveswith theglovemanufacturer.

Skinprotection-Other Wearsuitableprotectiveclothing.

Respiratoryprotection Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.

8.2.3.Environmentalexposure controls

Preventfurtherleakageorspillageifsafetodoso.

SECTION9:Physicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties

AppearanceLiquid ColourBlue OdourCharacteristic

OdourthresholdNodataavailable pH>12

MeltingpointNodataavailable

InitialboilingpointNodataavailable Flammability(solid,gas)Nodataavailable VapourpressureNodataavailable

RelativeVapourDensityNodataavailable

Density/RelativeDensity1.04-1.05g/cm3

PartitioncoefficientNodataavailable

AutoignitiontemperatureNodataavailable

Viscosity<200centipoise

ExplosivepropertiesNodataavailable OxidisingpropertiesNodataavailable EvaporationrateNodataavailable SolubilitySolubleinwater

9.2.Otherinformation

LeadcontentNodataavailable VOC(Volatileorganic compounds) Nodataavailable

ConductivityNodataavailable SurfacetensionNodataavailable GasgroupNodataavailable BenzeneContentNodataavailable

9.2.1.Informationwithregardtophysicalhazardclasses Nodataisavailableonthisproduct.

9.2.2.Othersafetycharacteristics Nodataisavailableonthisproduct.

SECTION10:Stabilityandreactivity

10.1.Reactivity

10.2.Chemicalstability

Stableundernormalconditions.

Stableundernormalconditions.

10.3.Possibilityofhazardousreactions

Strongacids.Strongoxidisingagents.

10.4.Conditionstoavoid

10.5.Incompatiblematerials

Protectfromfrost.

Noincompatiblegroupsnoted.

10.6.Hazardousdecompositionproducts

NoHazardousdecompositionproductswhenstoredandhandledcorrectly.

SECTION11:Toxicologicalinformation

11.1Informationonhazardclasses

Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedfromrawmaterialsupplierLD50andAcuteToxicityEstimates(ATE)asoutlinedinthe Regulation(EC)No.1272/2008(CLP)asamendedbyUKlaw.

Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

OralATE=>10,000mg/kg.

ATEDust/Mist=>20mg/l.

Skincorrosion/irritation

SkinCorr.1A:H314-Causessevereskinburnsandeyedamage.ExtremepH-≥11.5. Seriouseyedamage/irritationCausesseriouseyedamage.

Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.

Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet. Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.

Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.

Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet.

Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.

11.1.2.Mixtures

11.1.3.HazardInformation

11.1.4.ToxicologicalInformation

Nodataavailable.

Nodataavailable.

Nodataavailable

11.2Informationonotherhazards

Nodataisavailableonthisproduct.

SECTION12:Ecologicalinformation

12.1.Toxicity

Nodataavailable

12.2.Persistenceanddegradability

SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.

12.3.Bioaccumulativepotential

Partitioncoefficient

12.4.Mobilityinsoil

Theproductisnotbioaccumulating.

StoneacreSnowFoamNodataavailable ButylGlycolEther0.81LogPow SodiumHydroxideNodataavailable

Thisproductissolubleinwater.

12.5.ResultsofPBTandvPvBassessment

Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.

12.6Endocrinedisruptingproperties

Nodataisavailableonthisproduct.

12.7.Otheradverseeffects

Nodataisavailableonthisproduct.

SECTION13:Disposalconsiderations

13.1.Wastetreatmentmethods

Generalinformation

Disposalofpackaging

Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.

Disposeofincompliancewithalllocalandnationalrequirements.

DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.

SECTION14:Transportinformation

Hazardpictograms

14.1.UNnumber

Snow Foam

14.4.Packinggroup

Packinggroup III

14.5.Environmentalhazards

Environmentalhazards No

Marinepollutant No

ADR/RID

HazardID 80

TunnelCategory (E)

IMDG

EmSCode F-AS-B

IATA

PackingInstruction(Cargo)856

Maximumquantity 60L

PackingInstruction (Passenger) 852

Maximumquantity 5L

SECTION15:Regulatoryinformation

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations

REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.AsretainedandamendedinUKlaw.

COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.Asretainedand amendedinUKlaw.

COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).AsretainedandamendedinUK law.

15.2.Chemicalsafetyassessment

Noinformationavailable.

SECTION16:Otherinformation

Otherinformation

Revision

Thisdocumentdiffersfromthepreviousversioninthefollowingareas:. 2-2.1.2.Classification-EC1272/2008. 2-SUPPLEMENTALHAZARDINFORMATION. 12-12.1.Toxicity.

Datasources ClassificationandProcedureusedtoderivetheclassificationformixturesaccordingtoRegulation (EC)No.1272/2008,asretainedandamendedinUKlaw.

SkinCorr.1A:H314-Causessevereskinburnsandeyedamage.-ExtremepH-≥11.5. TextofHazardStatementsin Section3 SkinSens.1:H317-Maycauseanallergicskinreaction. AquaticChronic2:H411-Toxictoaquaticlifewithlonglastingeffects.

Copyright©2024ChemSoft.Allrightsreserved.

Otherinformation

Furtherinformation

AcuteTox.4:H302-Harmfulifswallowed.

SkinIrrit.2:H315-Causesskinirritation.

EyeDam.1:H318-Causesseriouseyedamage.

AquaticAcute1:H400-Verytoxictoaquaticlife.

AquaticChronic3:H412-Harmfultoaquaticlifewithlonglastingeffects.

AcuteTox.4:H302+H332-Harmfulifswallowedorifinhaled

EyeIrrit.2:H319-Causesseriouseyeirritation.

TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.

TAR & GLUE REMOVER MSDS

SAFETY DATA SHEET

according to Regulation (EU) 2020/878

Tar & Glue Remover

SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking

1.1.Productidentifier

Productname Tar & Glue Remover

1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst

ProductUse

[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC35]Washingand cleaningproducts(includingsolventbasedproducts);

[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC35]Washingandcleaningproducts(includingsolventbasedproducts);

Description BreaksdownTar&Glueresidue.

1.3.Detailsofthesupplierofthesafetydatasheet

Company SUPAGARDLIMITED

Address 19-27GavintonStreet Muirend Glasgow G443EF

Web www.supagard.com

Telephone 01416335933

Fax 01416377219

Email James.Smyth@supagard.com

Emailaddressofthe competentperson James.Smyth@supagard.com

1.4.Emergencytelephonenumber

Emergencytelephonenumber01416335933

8.30amto5.00pm

FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)

Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org

SECTION2:Hazardsidentification

2.1.Classificationofthesubstanceormixture

2.1.2.Classification-EC 1272/2008 :EUH066;Flam.Liq.3:H226;Asp.Tox.1:H304;STOTSE3:H336;STOTRE1:H372;Aquatic Chronic2:H411;

2.2.Labelelements

Hazardpictograms

2.2.Labelelements

SignalWord Danger

HazardStatement

PrecautionaryStatement: Prevention

PrecautionaryStatement: Response

PrecautionaryStatement: Storage

PrecautionaryStatement: Disposal

SUPPLEMENTALHAZARD INFORMATION

Tar & Glue Remover

EUH066-Repeatedexposuremaycauseskindrynessorcracking.

Flam.Liq.3:H226-Flammableliquidandvapour.

Asp.Tox.1:H304-Maybefatalifswallowedandentersairways.

STOTSE3:H336-Maycausedrowsinessordizziness.

STOTRE1:H372-Causesdamagetoorgansthroughprolongedorrepeatedexposure.

AquaticChronic2:H411-Toxictoaquaticlifewithlonglastingeffects.

P102-Keepoutofreachofchildren.

P280-Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection.

P301+P310+P330+P331-IFSWALLOWED:ImmediatelycallaPOISONCENTER/doctor.Rinse mouth.DoNOTinducevomiting.

P302+P350-IFONSKIN:Gentlywashwithplentyofsoapandwater.

P403+P233+P235-Storeinawell-ventilatedplace.Keepcontainertightlyclosed.Keepcool.

P501-Disposeofcontents/containertoanapproveddisposalsite,inaccordancewithlocal regulations.

IngredientsasrequiredbyRegulation(EC)No648/2004:. 15-30%AromaticHydrocarbons.

Contains-Hydrocarbons,C9-12,n-alkanes,isoalkanes,cyclics(2-25%)aromatics,Hydrocarbons, C9-11,N-alkanes,Isoalkanes,Cyclics,<2%Aromatic,Hydrocarbons,C11-C14,n-alkanes, isoalkanes,cyclics,<2%aromatics,2-butoxyethanol.

2.3.Otherhazards

Otherhazards

Furtherinformation

Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.

RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.

SECTION3:Composition/informationoningredients

3.2.Mixtures

EC1272/2008

ChemicalName

Hydrocarbons,C9-11,N-alkanes, Isoalkanes,Cyclics,<2%Aromatic

1174522-20-3919-857-501-2119463258-33

:EUH066;Flam.Liq.3: H226;Asp.Tox.1:H304; STOTSE3:H336; 10-20% Hydrocarbons,C9-12,n-alkanes, isoalkanes,cyclics(2-25%) aromatics

919-446-0

:EUH066;Flam.Liq.3: H226;Asp.Tox.1:H304; STOTSE3:H336;STOTRE 1:H372;AquaticChronic2: H411; 50-60%

Hydrocarbons,C11-C14,n-alkanes, isoalkanes,cyclics,<2%aromatics

926-141-601-2119456620-43 :EUH066;Asp.Tox.1: H304; 10-20% 2-butoxyethanol

603-014-00-0111-76-2203-905-001-2119475108-36

SECTION4:Firstaidmeasures

4.1.Descriptionoffirstaidmeasures

AcuteTox.4:H332;Acute Tox.4:H312;AcuteTox.4: H302;EyeIrrit.2:H319;Skin Irrit.2:H315; 1-10%

Inhalation Movetheexposedpersontofreshair. Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved. Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution. Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.

Tar & Glue Remover

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed

Inhalation

Highconcentrationofvapourinenclosedspacemaycauseirritation,headachesandnausea.May causeirritationtorespiratorysystem.Maycausedrowsinessordizziness.

Eyecontact Maycauseirritationtoeyes.

Skincontact

Ingestion

Maycauseskindrynessandirritation.Prolongedcontactmaycausedefattingoftheskin. Prolongedorrepeatedexposuremaycause:Skinirritationanddermatitis.

Maybefatalifswallowedandentersairways.

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded TREATSYMPTOMATICALLY.

Inhalation

Eyecontact

Skincontact

Ingestion

Generalinformation

Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.

Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.

Seekmedicalattentionifirritationorsymptomspersist.

Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.

Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.

SECTION5:Firefightingmeasures

5.1.Extinguishingmedia

Flammableliquid.Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthe surroundingenvironment.

5.2.Specialhazardsarisingfromthesubstanceormixture

Vapoursareheavierthanairandmayspreadneargroundandtravelaconsiderabledistancetoa sourceofignitionandflashback.Solventvapoursmayformexplosivemixtureswithair.

Oxidesofcarbon.Thermaldecompositionorcombustionmayliberatecarbonoxidesandother toxicgasesorvapours.

5.3.Adviceforfirefighters

Furtherinformation

Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.

Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.

SECTION6:Accidentalreleasemeasures

6.1.Personalprecautions,protectiveequipmentandemergencyprocedures

Wearsuitableprotectiveequipment.Flammableliquid.Avoidsparks,flames,heatandsourcesof ignition.

6.2.Environmentalprecautions

Adviselocalauthoritiesiflargespillscannotbecontained.

6.3.Methodsandmaterialforcontainmentandcleaningup

Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelledcontainersfor disposal.Avoidsparks,flames,heatandsourcesofignition.

6.4.Referencetoothersections

Seesection2,7,8,13forfurtherinformation.

SECTION7:Handlingandstorage

7.1.Precautionsforsafehandling

Tar & Glue Remover

7.1.Precautionsforsafehandling

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Provide adequateventilation.Staticelectricityandformationofsparksmustbeprevented.

7.2.Conditionsforsafestorage,includinganyincompatibilities

Flammableliquid.Avoidsparks,flames,heatandsourcesofignition.AvoidstoringindirectSun Light.Storeinawell-ventilatedplace.Keepcool.Storeinoriginalcontainer.Keepcontainertightly closed.Keepawayfromcombustiblematerial.Keepoutofthereachofchildren.Storeawayfrom thefollowingmaterials:Oxidisingmaterials.

7.3.Specificenduse(s)

Suitablepackaging

BreaksdownTar&Glueresidue.

Plasticcontainers.

SECTION8:Exposurecontrols/personalprotection

8.1.Controlparameters

8.1.1.ExposureLimitValues

2-butoxyethanol

Occupationalexposurecontrols.

WEL8-hrlimitppm:25

WEL15minlimitppm:50

WEL8-hrlimitmg/m3:123

WEL15minlimitmg/m3:101.2

WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust:Hydrocarbons,C11-C14, n-alkanes,isoalkanes,cyclics, <2%aromatics

WEL8-hrlimitppm:

WEL15minlimitppm:

WEL8-hrlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3:1200

WEL15minlimitmg/m3:

WEL15minlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -

DNEL:Derivedno-effectlevel.

ExposurePattern-Workers

2-butoxyethanol

Acuteinhalation-Systemic effects 1091mg/m³

Acuteinhalation-Localeffects246mg/m³

Long-term-inhalation-Systemic effects 98mg/m³

ExposurePattern-Generalpopulation

2-butoxyethanol

8.2.Exposurecontrols

Acuteinhalation-Systemic effects 426mg/m³

Acutedermal-Systemiceffects89mg/kg

Long-term-inhalation-Systemic effects 59mg/m³

Long-term-dermal-Systemic effects 89mg/kg

Acutedermal-Systemiceffects89mg/kg

Long-term-dermal-Systemic effects 125mg/kg

Acuteoral-Systemiceffects26.7mg/kg

Long-term-inhalation-Local effects 147mg/m³

Long-term-oral-Systemiceffects6.3mg/kg

8.2.Exposurecontrols

Tar & Glue Remover

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.

8.2.1.Appropriateengineering controls

Eye/faceprotection

SkinprotectionHandprotection

Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.

Eyewearcomplyingwithanapprovedstandardshouldbewornifariskassessmentindicateseye contactispossible.Thefollowingprotectionshouldbeworn:Wearchemicalsplashgoggles. PersonalprotectiveequipmentforeyeandfaceprotectionshouldcomplywithEuropeanStandard EN166.

Chooseglovestoprotecthandsagainstchemicalsdependingontheconcentrationandquantityof thehazardoussubstanceandspecifictoplaceofwork.Forspecialapplications,werecommend clarifyingtheresistancetochemicalsoftheaforementionedprotectivegloveswiththeglove manufacturer.Chemicalresistantgloves.Nitrilerubbergloves.

Skinprotection-Other Usebarriercreamstopreventskincontact.Provideeyewashstationandsafetyshower.Wear appropriateclothingtopreventrepeatedorprolongedskincontact.

Respiratoryprotection

8.2.3.Environmentalexposure controls

Incaseofinsufficientventilation,wearsuitablerespiratoryequipment.

Preventfurtherleakageorspillageifsafetodoso.

SECTION9:Physicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties

AppearanceLiquid

ColourColourless

OdourCharacteristic

OdourthresholdNodataavailable pHNodataavailable MeltingpointNodataavailable

InitialboilingpointNodataavailable

Flashpoint53°C

EvaporationrateNodataavailable Flammability(solid,gas)Nodataavailable VapourpressureNodataavailable RelativeVapourDensityNodataavailable Density/RelativeDensityNodataavailable PartitioncoefficientNodataavailable AutoignitiontemperatureNodataavailable Viscosity<100centipoise

ExplosivepropertiesNodataavailable OxidisingpropertiesNodataavailable SolubilityInsolubleinwater

9.2.Otherinformation

Tar & Glue Remover

9.2.Otherinformation

ConductivityNodataavailable

SurfacetensionNodataavailable

GasgroupNodataavailable

BenzeneContentNodataavailable

LeadcontentNodataavailable VOC(Volatileorganic compounds) Nodataavailable

9.2.1.Informationwithregardtophysicalhazardclasses

Nodataisavailableonthisproduct.

9.2.2.Othersafetycharacteristics

Nodataisavailableonthisproduct.

SECTION10:Stabilityandreactivity

10.1.Reactivity

10.2.Chemicalstability

Flammableliquid.Stableundernormalconditions.

Flammableliquid.Stableundernormalconditions.Useasrecommended.

10.3.Possibilityofhazardousreactions

Undernormalconditionsofstorageanduse,nohazardousreactionswilloccur.

10.4.Conditionstoavoid

10.5.Incompatiblematerials

Avoidsparks,flames,heatandsourcesofignition.AvoidstoringindirectSunLight.

Strongacids.Strongoxidisingagents.

10.6.Hazardousdecompositionproducts

Thermaldecompositionorcombustionmayliberatecarbonoxidesandothertoxicgasesor vapours.

SECTION11:Toxicologicalinformation

11.1Informationonhazardclasses

Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedfromrawmaterialsupplierLD50andAcuteToxicityEstimates(ATE)asoutlinedinthe Regulation(EC)No.1272/2008(CLP)asamendedbyUKlaw.

Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

OralATE=>10,000mg/kg.

DermalATE=>10,000mg/kg.

InhalationDust/MistATE=550mg/l.

Skincorrosion/irritation basedonavailabledatatheclassificationcriteriaarenotmet.

Seriouseyedamage/irritationbasedonavailabledatatheclassificationcriteriaarenotmet.

Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.

Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet.

Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.

Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.

STOT-singleexposure STOTSE3:H336-Maycausedrowsinessordizziness.

STOT-repeatedexposureSTOTRE1:H372-Causesdamagetoorgansthroughprolongedorrepeatedexposure.

Aspirationhazard Asp.Tox.1:H304-Maybefatalifswallowedandentersairways.

11.1Informationonhazardclasses

Repeatedorprolonged exposure

11.1.2.Mixtures

11.1.3.HazardInformation

11.1.4.ToxicologicalInformation

2-butoxyethanol

Hydrocarbons,C11-C14, n-alkanes,isoalkanes,cyclics, <2%aromatics

Hydrocarbons,C9-12,n-alkanes, isoalkanes,cyclics(2-25%) aromatics

11.2Informationonotherhazards

Tar & Glue Remover

EUH066-Repeatedexposuremaycauseskindrynessorcracking.

Nodataavailable.

Nodataavailable.

OralRatLD50:1200mg/kg

InhalationRatLC50/4h:2.2mg/l

OralRatLD50:>5000mg/kg

InhalationRatLC50/4h:>5000mg/m3

InhalationRatLC50/4h:>13100mg/l

OralRatLD50:>15000mg/kg

Nodataisavailableonthisproduct.

SECTION12:Ecologicalinformation

12.1.Toxicity

2-butoxyethanol

Hydrocarbons,C11-C14, n-alkanes,isoalkanes,cyclics, <2%aromatics

Hydrocarbons,C9-12,n-alkanes, isoalkanes,cyclics(2-25%) aromatics

12.2.Persistenceanddegradability

12.3.Bioaccumulativepotential

Partitioncoefficient

12.4.Mobilityinsoil

DaphniaEC50/48h:1550.0000mg/l

Lepomis_MacrochirusLC50/96h:1490-2950mg/l

EC50formarineorfreshwater organisms >100.0000mg/l

DaphniaEC50/48h:1000.0000mg/l

AlgaeEC50/72h:1000mg/l

DaphniaEC50/48h:22.0000mg/l

AlgaeEC50/72h:10

DermalRabbitLD50:>2000mg/kg

DermalRabbitLD50:>5000mg/kg

DermalRatLD50:>3400mg/kg

AlgaeEC50/72h:911mg/l (Pseudokirchnerie llasubcapitata)

LC50formarineorfreshwater organisms >100.0000mg/l

FishLC50/96h:1000.0000mg/l

FishLC50/96h:30.0000mg/l

GreenAlgaeEC50/48h:43.98

SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.

Mayaccumulateinsoilandwatersystems.

StoneacreTar&GlueRemoverNodataavailable 2-butoxyethanol0.81logP

Theproducthaspoorwater-solubility.

12.5.ResultsofPBTandvPvBassessment

Tar & Glue Remover

12.5.ResultsofPBTandvPvBassessment

Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.

12.6Endocrinedisruptingproperties

Nodataisavailableonthisproduct.

12.7.Otheradverseeffects

Nodataisavailableonthisproduct.

SECTION13:Disposalconsiderations

13.1.Wastetreatmentmethods

Generalinformation

Disposalofpackaging

Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.

Disposeofincompliancewithalllocalandnationalrequirements.

DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.

SECTION14:Transportinformation

Hazardpictograms

14.1.UNnumber

14.2.UNpropershippingname

14.3.Transporthazardclass(es)

HYDROCARBONS,LIQUID,N.O.S.

14.5.Environmentalhazards

Environmentalhazards Yes Marinepollutant Yes

14.6.Specialprecautionsforuser Noadditionalspecialprecautions.

Tar & Glue Remover

ADR/RID

TunnelCategory (D/E)

IMDG

EmSCode F-ES-D

IATA

PackingInstruction(Cargo)366

Maximumquantity 220L

PackingInstruction (Passenger) 355

Maximumquantity 60L

SECTION15:Regulatoryinformation

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture

Regulations REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.AsretainedandamendedinUKlaw.

COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.Asretainedand amendedinUKlaw.

COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).AsretainedandamendedinUK law.

15.2.Chemicalsafetyassessment

Noinformationavailable.

Revision

Thisdocumentdiffersfromthepreviousversioninthefollowingareas:. 12-12.1.Toxicity.

Datasources ClassificationandProcedureusedtoderivetheclassificationformixturesaccordingtoRegulation (EC)No.1272/2008,asretainedandamendedinUKlaw.

Flam.Liq.3:H226-Flammableliquidandvapour.-FlashPoint-55degC.

Asp.Tox.1:H304-Maybefatalifswallowedandentersairways.-CalculationMethod.

STOTSE3:H336-Maycausedrowsinessordizziness.-CalculationMethod.

STOTRE1:H372-CausesdamagetoorganscalculationMethodthroughprolongedorrepeated exposure.-.

AquaticChronic2:H411-Toxictoaquaticlifewithlonglastingeffects.-CalculationMethod. TextofHazardStatementsin Section3 EUH066-Repeatedexposuremaycauseskindrynessorcracking.

Flam.Liq.3:H226-Flammableliquidandvapour.

Asp.Tox.1:H304-Maybefatalifswallowedandentersairways.

STOTSE3:H336-Maycausedrowsinessordizziness.

STOTRE1:H372-Causesdamagetoorgansthroughprolongedorrepeatedexposure.

AquaticChronic2:H411-Toxictoaquaticlifewithlonglastingeffects.

Otherinformation

Furtherinformation

Tar & Glue Remover

AcuteTox.4:H302+H312+H332-Harmfulifswallowed,incontactwithskinorifinhaled

SkinIrrit.2:H315-Causesskinirritation.

EyeIrrit.2:H319-Causesseriouseyeirritation.

TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.

TYRE INFLATOR MSDS

Revision Date 02/08/2017

Revision 2

Supersedes date 20/04/2017

SAFETY DATA SHEET

TYRE REPAIR 500ML

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier

Product name Product No.

TYRE REPAIR 500ML 000998083036

1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses

Emergency Tyre Repair

1.3. Details of the supplier of the safety data sheet

Supplier 23, Gavinton Street, Muirend, Glasgow, Scotland, G44 3EF

SUPAGARD LIMITED

0141 633 5933 0141 637 7219 james@supagard.co.uk

1.4. Emergency telephone number

SECTION 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)

2.2. Label elements

Physical and Chemical HazardsFlam. Aerosol 1 - H222 Human health Not classified. Environment Not classified.

Label In Accordance With (EC) No. 1272/2008

Signal Word Danger Hazard Statements

H222

Extremely flammable aerosol. Precautionary Statements

P102

P210

P261

P271

P280

P305+351+338

P337+313

P501

Keep out of reach of children.

Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

Avoid breathing vapour/spray.

Use only outdoors or in a well-ventilated area.

Wear protective gloves.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

If eye irritation persists: Get medical advice/attention.

Dispose of contents/container in accordance with local regulations. Supplementary Precautionary Statements

P211

P251

P302+352

Do not spray on an open flame or other ignition source.

Pressurized container: Do not pierce or burn, even after use.

IF ON SKIN: Wash with plenty of soap and water.

Supplemental label information H229

2.3. Other hazards

Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122°F.

Pressurised container: May burst if heated

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixtures

CAS-No.: 106-97-8

Classification (EC 1272/2008) Flam. Gas 1 - H220

EC No.: 203-448-7

Classification (67/548/EEC) F+;R12

CAS-No.: 75-28-5

Classification (EC 1272/2008) Flam. Gas 1 - H220

EC No.: 200-857-2

Classification (67/548/EEC) F+;R12

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: FIRST AID MEASURES

4.1. Description of first aid measures

General information

Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. Inhalation

Move the exposed person to fresh air at once. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. Keep the affected person warm and at rest. Get prompt medical attention. Ingestion

DO NOT INDUCE VOMITING! Rinse mouth thoroughly with water and give large amounts of milk or water to people not unconscious. Get medical attention if any discomfort continues.

Skin contact

Wash the skin immediately with soap and water. Get medical attention if any discomfort continues. Eye contact

Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.

4.2. Most important symptoms and effects, both acute and delayed

General information

NOTE! Effects may be delayed. Keep affected person under observation.

4.3. Indication of any immediate medical attention and special treatment needed

No specific first aid measures noted.

SECTION 5: FIREFIGHTING MEASURES

5.1. Extinguishing media

Extinguishing media

Use: Powder. Dry chemicals, sand, dolomite etc. Water spray, fog or mist.

5.2. Special hazards arising from the substance or mixture

Unusual Fire & Explosion Hazards

Aerosol cans may explode in a fire.

5.3. Advice for firefighters

Special Fire Fighting Procedures

Containers close to fire should be removed or cooled with water. Use water to keep fire exposed containers cool and disperse vapours.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

Wear necessary protective equipment. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Let evaporate. Keep out of confined spaces because of explosion risk. If leakage cannot be stopped, evacuate area.

6.4. Reference to other sections

SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level.

7.2. Conditions for safe storage, including any incompatibilities

Aerosol cans: Must not be exposed to direct sunlight or temperatures above 50°C.

7.3. Specific end use(s)

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

WEL = Workplace Exposure Limit.

8.2. Exposure controls

Protective equipment

Engineering measures

Provide adequate general and local exhaust ventilation.

Respiratory equipment

No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational exposure limit. Use chemical cartridge protection with appropriate cartridge.

Hand protection

Use protective gloves.

Eye protection

Wear approved chemical safety goggles where eye exposure is reasonably probable.

Other Protection

Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact.

Hygiene measures

DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance Aerosol.

Colour Typical

Odour Characteristic.

Flammability Limit - Lower(%)0.8

Flammability Limit - Upper(%)9.0

9.2. Other information

SECTION 10: STABILITY AND REACTIVITY

10.1. Reactivity

No specific reactivity hazards associated with this product.

10.2. Chemical stability

Stable under normal temperature conditions.

10.3. Possibility of hazardous reactions

Not known.

10.4. Conditions to avoid

Avoid heat, flames and other sources of ignition. Avoid contact with: Strong oxidising agents. Strong alkalis. Strong mineral acids.

10.5. Incompatible materials

10.6. Hazardous decomposition products

Fire creates: Vapours/gases/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).

SECTION 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Inhalation

May cause irritation to the respiratory system. Vapours may cause headache, fatigue, dizziness and nausea. Prolonged inhalation of high concentrations may damage respiratory system.

Ingestion

May cause discomfort if swallowed. May cause stomach pain or vomiting. Gastrointestinal symptoms, including upset stomach.

Skin contact

Prolonged or repeated exposure may cause severe irritation. Acts as a defatting agent on skin. May cause cracking of skin, and eczema.

Eye contact

Irritating to eyes. May cause chemical eye burns.

Route of entry

Inhalation. Skin and/or eye contact.

SECTION 12: ECOLOGICAL INFORMATION

Ecotoxicity

Dangerous for the environment if discharged into watercourses.

12.1. Toxicity

Data set not currently available.

12.2. Persistence and degradability

12.3. Bioaccumulative potential

Bioaccumulative potential

No data available on bioaccumulation.

12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment

12.6. Other adverse effects

Not known.

SECTION 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Empty containers must not be burned because of explosion hazard. Dispose of waste and residues in accordance with local authority requirements.

SECTION 14: TRANSPORT INFORMATION

14.1. UN number

UN No. (ADR/RID/ADN) 1950

UN No. (IMDG) 1950

UN No. (ICAO) 1950

14.2. UN proper shipping name

Proper Shipping Name AEROSOLS

14.3. Transport hazard class(es)

ADR/RID/ADN Class 2

ADR/RID/ADN Class Class 2: Gases

ADR Label No. 2.1

Transport Labels

14.4. Packing group

ADR/RID/ADN Packing groupNot Applicable

IMDG Packing group Not Applicable

ICAO Packing group Not Applicable

14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant No.

14.6. Special precautions for user

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

SECTION 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Uk Regulatory References

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2002.

The Control of Substances Hazardous to Health Regulations 2002.

Statutory Instruments

Control of Substances Hazardous to Health.

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Approved Code Of Practice

Classification and Labelling of Substances and Preparations Dangerous for Supply. Guidance Notes

Workplace Exposure Limits EH40.

Introduction to Local Exhaust Ventilation HS(G)37.

CHIP for everyone HSG(108).

15.2. Chemical Safety Assessment

SECTION 16: OTHER INFORMATION

Revision Date 02/08/2017

Revision 2

Supersedes date 20/04/2017

Risk Phrases In Full Extremely flammable.

R12

Hazard Statements In Full Extremely flammable gas. H220 Extremely flammable aerosol. H222

TYRE DRESSING - CONCENTRATED MSDS

SAFETY DATA SHEET

CONCENTRATED TYRE & TRIM

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier

Product name Product No.

CONCENTRATED TYRE & TRIM

002803070989

1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses As product description

1.3. Details of the supplier of the safety data sheet

SUPAGARD LIMITED

Supplier 23, Gavinton Street, Muirend, Glasgow, Scotland, G44 3EF 0141 633 5933 0141 637 7219 james@supagard.co.uk

1.4. Emergency telephone number

SECTION 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)

Physical and Chemical HazardsFlam. Liq. 3 - H226 Human health

EUH066;STOT SE 3 - H336;Asp. Tox. 1 - H304 Environment Not classified.

2.2. Label elements

Contains NAPHTHA (PETROLEUM), HYDROTREATED HEAVY

Label In Accordance With (EC) No. 1272/2008

Signal Word Danger Hazard Statements

H226

H304

Precautionary Statements

Flammable liquid and vapour.

May be fatal if swallowed and enters airways.

H336 May cause drowsiness or dizziness.

P102

P210

P271

P280

P261

P501

Supplementary Precautionary Statements

P233

P240

P241

Keep out of reach of children.

Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

Use only outdoors or in a well-ventilated area.

Wear protective gloves/protective clothing/eye protection/face protection.

Avoid breathing vapour/spray.

Dispose of contents/container in accordance with local regulations.

Keep container tightly closed.

Ground/bond container and receiving equipment.

Use explosion-proof electrical equipment.

Supplemental label information

2.3. Other hazards

CONCENTRATED TYRE & TRIM

P242

P243

P301+310

P303+361+353

P304+340

P312

P331

P370+378

P403+233

P403+235

P405

EUH066

Use only non-sparking tools.

Take precautionary measures against static discharge.

IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

Call a POISON CENTER or doctor/physician if you feel unwell.

Do NOT induce vomiting.

In case of fire: Use foam, carbon dioxide, dry powder or water fog for extinction.

Store in a well-ventilated place. Keep container tightly closed.

Store in a well-ventilated place. Keep cool.

Store locked up.

Repeated exposure may cause skin dryness or cracking.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixtures

CAS-No.: 64742-48-9

Classification (EC 1272/2008)

Flam. Liq. 3 - H226

EUH066

STOT SE 3 - H336

Asp. Tox. 1 - H304

EC No.: 919-857-5

Classification (67/548/EEC) Xn;R65. R10,R66,R67.

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: FIRST AID MEASURES

4.1. Description of first aid measures

General information

NOTE! Effects may be delayed. Keep affected person under observation. NOTE! Keep affected person away from heat, sparks and flames!

Inhalation

Move the exposed person to fresh air at once. Keep the affected person warm and at rest. Get prompt medical attention. Perform artificial respiration if breathing has stopped. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen.

Ingestion

Remove victim immediately from source of exposure. Rinse mouth thoroughly. NOTE! Keep affected person away from heat, sparks and flames! DO NOT induce vomiting. Get medical attention immediately.

Skin contact

Remove affected person from source of contamination. Wash the skin immediately with soap and water. Get medical attention if any discomfort continues.

Eye contact

Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.

4.2. Most important symptoms and effects, both acute and delayed

4.3. Indication of any immediate medical attention and special treatment needed

SECTION 5: FIREFIGHTING MEASURES

5.1. Extinguishing media

Extinguishing media

Use: Dry chemicals, sand, dolomite etc. Alcohol resistant foam. Water spray, fog or mist. Carbon dioxide (CO2).

5.2. Special hazards arising from the substance or mixture

Unusual Fire & Explosion Hazards

Vapours are heavier than air and may spread near ground to sources of ignition.

5.3. Advice for firefighters

Special Fire Fighting Procedures

Ventilate closed spaces before entering them. Move container from fire area if it can be done without risk. Use water to keep fire exposed containers cool and disperse vapours. Do not scatter spilled material with more water than needed to fight the fire. Be aware of danger for fire to re-start. Keep run-off water out of sewers and water sources. Dike for water control.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Stop leak if possible without risk. Ventilate well. Wear necessary protective equipment. Absorb in vermiculite, dry sand or earth and place into containers.

6.4. Reference to other sections

SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. Risk of vapour concentration on the floor and in low-lying areas. Static electricity and formation of sparks must be prevented.

7.2. Conditions for safe storage, including any incompatibilities

Flammable/combustible - Keep away from oxidisers, heat and flames. Keep containers tightly closed.

Storage Class

Flammable liquid storage.

7.3. Specific end use(s)

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

- 15 Min

8.2. Exposure controls

Protective equipment

Process conditions

Provide eyewash station.

Engineering measures

No specific ventilation requirements noted, but forced ventilation may still be required if air contamination exceeds acceptable level.

Respiratory equipment

No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational exposure limit.

Hand protection

Use protective gloves.

Eye protection

Use eye protection.

Other Protection

Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact.

Hygiene measures

Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes contaminated. Promptly remove any clothing that becomes wet or contaminated. When using do not eat, drink or smoke. DO NOT SMOKE IN WORK AREA!

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance Liquid

Colour Typical

Odour Characteristic.

Relative density <1.0

Auto Ignition Temperature (°C)230

9.2. Other information

SECTION 10: STABILITY AND REACTIVITY

10.1. Reactivity

10.2. Chemical stability

Stable under normal temperature conditions.

10.3. Possibility of hazardous reactions

10.4. Conditions to avoid

Avoid heat, flames and other sources of ignition. Avoid contact with strong oxidisers.

10.5. Incompatible materials

10.6. Hazardous decomposition products

Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).

SECTION 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Inhalation

Vapours may cause headache, fatigue, dizziness and nausea. Vapour may affect central nervous system and cause headache, discomfort, vomiting or intoxication. High concentrations of vapours may irritate respiratory system and lead to headache, fatigue, nausea and vomiting.

Ingestion

May cause stomach pain or vomiting. Gastrointestinal symptoms, including upset stomach.

Skin contact

Prolonged or repeated exposure may cause severe irritation. Acts as a defatting agent on skin. May cause cracking of skin, and eczema.

Eye contact

Irritating to eyes. Irritation, burning, lachrymation, blurred vision after liquid splash.

Health Warnings

Repeated exposure may cause chronic eye irritation. Swallowing concentrated chemical may cause severe internal injury.

Route of entry

Inhalation. Ingestion. Skin and/or eye contact.

Medical Symptoms

Irritation of eyes and mucous membranes. Dilated pupils. Rhinitis (inflammation of the nasal mucous membranes).

SECTION 12: ECOLOGICAL INFORMATION

Ecotoxicity

Dangerous for the environment if discharged into watercourses.

12.1. Toxicity

12.2. Persistence and degradability

12.3. Bioaccumulative potential

12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment

12.6. Other adverse effects

SECTION 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Collect on absorbent material, place in cardboard kegs and incinerate. Incinerate in suitable combustion chamber. Do not allow runoff to sewer, waterway or ground. Dispose of waste and residues in accordance with local authority requirements.

SECTION

14: TRANSPORT INFORMATION

14.1. UN number

UN No. (ADR/RID/ADN) 1993

UN No. (IMDG) 1993

UN No. (ICAO) 1993

14.2. UN proper shipping name

Proper Shipping Name FLAMMABLE LIQUID, N.O.S.

14.3. Transport hazard class(es)

ADR/RID/ADN Class 3

ADR/RID/ADN Class Class 3: Flammable liquids.

ADR Label No. 3

IMDG Class 3

ICAO Class/Division 3

Transport Labels

14.4. Packing group

ADR/RID/ADN Packing groupIII

IMDG Packing group III

ICAO Packing group III

14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant No.

14.6. Special precautions for user

EMS F-E, S-E

Emergency Action Code •3Y

Hazard No. (ADR) 30

Hazard No. (ADR) 30 Flammable liquid (flash-point between 23°C and 60°C, inclusive) or flammable liquid or solid in the molten state with a flash-point above 60°C, heated to a temperature equal to or above its flash-point, or self heating liquid.

Tunnel Restriction Code (D/E)

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

SECTION 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Guidance Notes

Workplace Exposure Limits EH40.

Introduction to Local Exhaust Ventilation HS(G)37. EU Legislation

Regulation (EC) No.1272/2008 The Classification, Labelling and Packaging of substances and mixtures Regulations Regulation (EC) No. 1907/2006 The Registration, Evaluation, Authorisation and Restriction of Chemicals Regulations (REACH) 2001/95/EC The General Product Safety Directive (GPSD)

Commission Regulation (EU) 2015/830 Requirements for the compilation of safety data sheets (amending REACH)

Authorisations (Title VII Regulation 1907/2006)

No specific authorisations are noted for this product. Restrictions (Title VIII Regulation 1907/2006)

No specific restrictions of use are noted for this product.

15.2. Chemical Safety Assessment

SECTION 16: OTHER INFORMATION

Revision Date 10/04/2017

Revision 2

Supersedes date 06/01/2005

Hazard Statements In Full

EUH066 Repeated exposure may cause skin dryness or cracking. , H226 Flammable liquid and vapour. , H304 May be fatal if swallowed and enters airways. , H336 May cause drowsiness or dizziness.

UPHOLSTERY FOAM CLEANER

MSDS

SAFETY DATASHEET

FABRIC CLEANER

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name: FABRIC CLEANER

Product code: HC8430

Synonyms: HC8430 / SUP PD0399-2

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of substance / mixture: Aerosol foaming cleanser.

1.3. Details of the supplier of the safetydata sheet

Companyname: SUPAGARD LIMITED 23 Gavinton Street Muirend Glasgow Scotland G44 3EF

Tel: 0141 633 5933

Email: james@supagard.co.uk

1.4. Emergencytelephone number

Emergencytel: 0141 633 5933 (office hours only)

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Classification under CLP: Flam. Aerosol 1: H222; -: H229

Page: 1

Compilation date: 10/11/2021

Revision date: 14/05/2024

Revision No: 2

Most important adverse effects: Extremely flammable aerosol. Pressurised container: May burst if heated.

2.2. Label elements

Label elements:

Hazard statements: H222: Extremely flammable aerosol. H229: Pressurised container: May burst if heated.

Hazard pictograms: GHS02: Flame

Signal words: Danger

SAFETY DATASHEET FABRIC CLEANER

Precautionarystatements: P102: Keep out of reach of children.

P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P211: Do not spray on an open flame or other ignition source.

P251: Do not pierce or burn, even after use.

P410+P412: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.

P260: Do not breathe spray.

P302+P350: IF ON SKIN: Gently wash with plenty of soap and water.

P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Haz. ingredients (label): Contains:

2.3. Other hazards

Other hazards: In use, may form flammable / explosive vapour-air mixture. PBT: This product is not identified as a PBT/vPvB substance.

Section 3: Composition/information on ingredients

3.2. Mixtures

Hazardous ingredients:

- REACH registered number(s): 01-2119474691-32-XXXX

- REACH registered number(s): 01-2119486944-21-XXXX

- REACH registered number(s): 01-2119457558-25

Section 4: First aid measures

4.1. Description of first aid measures

Skin contact: Wash immediately with plenty of soap and water.

Eye contact: Bathe the eye with running water for 15 minutes. Consult a doctor.

Ingestion: Do not induce vomiting. If conscious, give half a litre of water to drink immediately. Consult a doctor.

FABRIC CLEANER

Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Consult a doctor. Move to fresh air in case of accidental inhalation of vapours.

4.2. Most important symptoms and effects, both acute and delayed

Skin contact: There may be mild irritation at the site of contact.

Eye contact: There may be irritation and redness.

Ingestion: There may be irritation of the throat.

Inhalation: There may be a feeling of tightness in the chest with shortness of breath.

4.3. Indication of anyimmediate medical attention and special treatment needed

Immediate / special treatment: Not applicable.

Section 5: Fire-fighting measures

5.1. Extinguishing media

Extinguishing media: Alcohol resistant foam. Water spray. Carbon dioxide. Dry chemical powder.

5.2. Special hazards arising from the substance or mixture

Exposure hazards: Highly flammable. In combustion emits toxic fumes. Forms explosive air-vapour mixture. Vapour may travel considerable distance to source of ignition and flash back. Aerosol cans may explode during a fire, giving a high speed projectile.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergencyprocedures

Personal precautions: Refer to section 8 of SDS for personal protection details. Notify the police and fire brigade immediately. Eliminate all sources of ignition. Cover leaking can until the discharge has stopped, before attempting cleanup operations.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Do not use equipment in clean-up procedure which may produce sparks. Absorb into dry earth or sand. Clean-up should be dealt with only by qualified personnel familiar with the specific substance. Wash the spillage site with large amounts of water.

6.4. Reference to other sections

Reference to other sections: Refer to section 8 of SDS.

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements: Smoking is forbidden. Use non-sparking tools. Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Avoid the formation or spread of mists in the air.

7.2. Conditions for safe storage, including anyincompatibilities

Storage conditions: Store in a cool, well ventilated area. Keep away from sources of ignition. Keep away from direct sunlight.

7.3. Specific end use(s)

Specific end use(s): No data available.

Section 8: Exposure controls/personal protection

8.1. Control parameters

Hazardous ingredients:

BUTANE, <0.1%1,3 BUTADIENE

Workplace exposure limits:

Respirable dust:

PROPANE, <0.1%1,3 BUTADIENE

DNEL/PNEC Values

DNEL / PNEC No data available.

8.2. Exposure controls

Engineering measures: Ensure there is sufficient ventilation of the area. Ensure lighting and electrical equipment are not a source of ignition.

Respiratoryprotection: Respiratory protection not required.

Hand protection: Protective gloves.

Eye protection: Safety glasses. Ensure eye bath is to hand.

Skin protection: Protective clothing.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State: Aerosol

Colour: Colourless

Odour: Perfumed

FABRIC CLEANER

Evaporation rate: Slow

Solubilityin water: Soluble

Viscosity: Non-viscous

Boiling point/range°C: No data available.

Melting point/range°C: No data available.

Flammabilitylimits %:lower: 0.9 upper: 9.0

Flash point°C: -40

Autoflammability°C: >230

Part.coeff. n-octanol/water: No data available.

Vapour pressure: No data available.

Relative density: No data available. pH: 9 - 10

VOC g/l: No data available.

9.2. Other information

Other information: No data available.

Section 10: Stabilityand reactivity

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

10.2. Chemical stability

Chemical stability: Stable under normal conditions. Stable at room temperature.

10.3. Possibilityof hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions. Decomposition may occur on exposure to conditions or materials listed below.

10.4. Conditions to avoid

Conditions to avoid: Heat. Hot surfaces. Sources of ignition. Flames. Direct sunlight.

10.5. Incompatible materials

Materials to avoid: Strong oxidising agents. Strong acids.

10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

Section 11: Toxicological information

11.1. Information on toxicological effects

Hazardous ingredients:

FABRIC CLEANER

Toxicityvalues: No data available.

Symptoms / routes of exposure

Skin contact: There may be mild irritation at the site of contact.

Eye contact: There may be irritation and redness.

Ingestion: There may be irritation of the throat.

Inhalation: There may be a feeling of tightness in the chest with shortness of breath.

Section 12: Ecological information

12.1. Toxicity

Hazardous ingredients:

PROPAN-2-OL

Daphnia magna

12.2. Persistence and degradability

EC50

EC50

Persistence and degradability: Biodegradable. The surfactant(s) contained in this preparation complies (comply) with the biodegradability criteria as laid down in Regulation (EC) No. 648/2004 on detergents.

12.3. Bioaccumulative potential

Bioaccumulative potential: No bioaccumulation potential.

12.4. Mobilityin soil

Mobility: Readily absorbed into soil. Volatile. Soluble in water. Vapour is heavier than air.

12.5. Results of PBT and vPvB assessment

PBT identification: This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects: Negligible ecotoxicity.

Section 13: Disposal considerations

13.1. Waste treatment methods

Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.

Recoveryoperations: Recycling/reclamation of metals and metal compounds.

Waste code number: 16 05 05

Disposal of packaging: Empty cans must not be burned because of explosion hazard. Recycle container where permitted.

NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.

Section 14: Transport information

14.1. UN number

UN number: UN1950

14.2. UN proper shipping name

Shipping name: AEROSOLS

14.3. Transport hazard class(es)

Transport class: 2

14.4. Packing group

14.5. Environmental hazards

Environmentallyhazardous: No

14.6. Special precautions for user

Special precautions: No special precautions.

Tunnel code: D

Transport category: 2

Section 15: Regulatoryinformation

Marine pollutant: No

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Specific regulations: Not applicable.

15.2. Chemical SafetyAssessment

Chemical safetyassessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.

Section 16: Other information

Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 2015/830.

All substances in this preparation are registered within UK/EU/EFTA countries under the REACH (UK/EC) (ammended) regulations, EC 1907/2006

IMPORTANT NOTE:

Risk phases in this section belowrelate to the INDIVIDUAL COMPONENTS in the formulation when used at their FULL CONCENTRATIONS, and not at the reduced levels in the mixed product.

See sections 2 and 3 for the calculated hazard and risk phrases for the blended product.

Phrases used in s.2 and s.3: H220: Extremely flammable gas.

H222: Extremely flammable aerosol.

H225: Highly flammable liquid and vapour.

FABRIC CLEANER

FABRIC CLEANER

H229: Pressurised container: May burst if heated.

H319: Causes serious eye irritation.

H336: May cause drowsiness or dizziness.

Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.

UPHOLSTERY CLEANER MSDS

SAFETY DATA SHEET

according to Regulation (EU) 2015/830

Upholstery Cleaner

SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking

1.1.Productidentifier

Productname Productcode Upholstery Cleaner QAFS777

1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst

ProductUse

[SU3]Industrialuses:Usesofsubstancesassuchorinpreparationsatindustrialsites;

[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);

[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers); Description Nodataisavailableonthisproduct.

1.3.Detailsofthesupplierofthesafetydatasheet

Company SUPAGARDLIMITED

Address 19-27GavintonStreet Muirend Glasgow G443EF

Web www.supagard.co.uk

Telephone 01416335933

Fax 01416377219

Email James.Smyth@supagard.com

Emailaddressofthe competentperson James.Smyth@supagard.com

1.4.Emergencytelephonenumber

Emergencytelephonenumber01416335933

8.30amto5.00pm

SECTION2:Hazardsidentification

2.1.Classificationofthesubstanceormixture

2.1.2.Classification-EC 1272/2008 SkinIrrit.2:H315;EyeIrrit.2:H319;AquaticChronic3:H412;

2.2.Labelelements

Hazardpictograms

SignalWord Warning

HazardStatement

SkinIrrit.2:H315-Causesskinirritation. EyeIrrit.2:H319-Causesseriouseyeirritation.

2.2.Labelelements

Upholstery Cleaner

AquaticChronic3:H412-Harmfultoaquaticlifewithlonglastingeffects.

PrecautionaryStatement: Prevention P264-Washhandsandothercontactedskinthoroughlyafterhandling.

P280-Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection.

PrecautionaryStatement: Response P302+P352-IFONSKIN:Washwithplentyofwater/. P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.

P332+P313-Ifskinirritationoccurs:Getmedicaladvice/attention.

P337+P313-Ifeyeirritationpersists:Getmedicaladvice/attention.

PrecautionaryStatement: Disposal P501-Disposeofcontents/containertoanapprovedwastecontractor.

2.3.Otherhazards

Otherhazards PBTnotidentifiedasaPBTsubstance.

SECTION3:Composition/informationoningredients

3.2.Mixtures

67/548/EEC/1999/45/EC

ChemicalName

Quaternaryammoniumcompounds, benzyl-C12-14(evennumbered) -alkyldimethyl,chlorides

IndexNo.CASNo.ECNo.

68424-85-1939-350-201-2119970550-39

CocamidopropylBetain Xi;R41R52/531-10% 2-butoxyethanol

EC1272/2008

ChemicalName

Quaternaryammoniumcompounds, benzyl-C12-14(evennumbered) -alkyldimethyl,chlorides

603-014-00-0111-76-2203-905-001-2119475108-360.5Xn;R20/21/22Xi;R36/38 -1%

IndexNo.CASNo.ECNo.

68424-85-1939-350-201-2119970550-39

AcuteTox.4:H302;Skin Corr.1B:H314;Aquatic Acute1:H400; 0-0.5% M=1

CocamidopropylBetain EyeDam.1:H318;Aquatic Chronic3:H412; 1-10% 2-butoxyethanol

603-014-00-0111-76-2203-905-001-2119475108-36

AcuteTox.4:H332;Acute Tox.4:H312;AcuteTox.4: H302;EyeIrrit.2:H319;Skin Irrit.2:H315; 0.5-1%

Furtherinformation

ProductShelfLife RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.

ActiveIngredients Ingredients-SodiumMetasilicatePentahydrate,Lessthan5%AmphotericSurfactants,Lessthan 5%Non-ionicSurfactants,Lessthan5%CationicSurfactants.

SECTION4:Firstaidmeasures

4.1.Descriptionoffirstaidmeasures

Inhalation Movetheexposedpersontofreshair.

Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved.

Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution.

Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed

Inhalation Irritatingtorespiratorysystem.

Eyecontact Irritatingtoeyes.

Skincontact Irritatingtoskin.

Ingestion Irritatingtomucousmembranes.

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded

Upholstery Cleaner

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded

Inhalation

Eyecontact

Skincontact

Ingestion

Generalinformation

Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.

Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.

Seekmedicalattentionifirritationorsymptomspersist.

Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.

Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.

SECTION5:Firefightingmeasures

5.1.Extinguishingmedia

Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.

5.2.Specialhazardsarisingfromthesubstanceormixture

Burningproducesirritating,toxicandobnoxiousfumes.

5.3.Adviceforfirefighters

Furtherinformation

Wearsuitablerespiratoryequipmentwhennecessary.

Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.

SECTION6:Accidentalreleasemeasures

6.1.Personalprecautions,protectiveequipmentandemergencyprocedures

6.2.Environmentalprecautions

Wearsuitableprotectiveequipment.

Adviselocalauthoritiesiflargespillscannotbecontained.

6.3.Methodsandmaterialforcontainmentandcleaningup

Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.

6.4.Referencetoothersections

Seesection2,7,8,13forfurtherinformation.

SECTION7:Handlingandstorage

7.1.Precautionsforsafehandling

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.

7.2.Conditionsforsafestorage,includinganyincompatibilities

Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.

7.3.Specificenduse(s)

Suitablepackaging

Nodataisavailableonthisproduct.

Plasticcontainers.

SECTION8:Exposurecontrols/personalprotection

8.1.Controlparameters

8.1.Controlparameters

8.1.1.ExposureLimitValues

2-butoxyethanol

DNEL:Derivedno-effectlevel.

ExposurePattern-Workers

2-butoxyethanol

Upholstery Cleaner

Occupationalexposurecontrols.

WEL8-hrlimitppm:25

WEL15minlimitppm:50

WEL8-hrlimitmg/m3total inhalabledust: -

WEL8-hrlimitmg/m3total respirabledust: -

Long-term-inhalation-Systemic effects 98mg/m³

Long-term-inhalation-Local effects 663mg/m³

Long-term-dermal-Local effects 89mg/kg

WEL8-hrlimitmg/m3:123

WEL15minlimitmg/m3:101.2

WEL15minlimitmg/m3total inhalabledust: -

WEL15minlimitmg/m3total respirabledust: -

Long-term-dermal-Systemic effects 75mg/kg

ExposurePattern-Generalpopulation

2-butoxyethanol

Acutedermal-Localeffects13.4mg/kg

Long-term-inhalation-Systemic effects 49mg/m³

Long-term-dermal-Local effects 44.5mg/kg

Long-term-inhalation-Local effects 426mg/m³

8.2.Exposurecontrols

AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.

Eye/faceprotection Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields.

SkinprotectionHandprotection Rubbergloves.

Respiratoryprotection Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.

8.2.3.Environmentalexposure controls Preventfurtherleakageorspillageifsafetodoso.

SECTION9:Physicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties

Upholstery Cleaner

9.1.Informationonbasicphysicalandchemicalproperties

AppearanceLiquid

ColourCream

OdourCharacteristic

OdourthresholdNodataavailable pH11-11.4

MeltingpointNodataavailable

InitialboilingpointNodataavailable

EvaporationrateNodataavailable Flammability(solid,gas)Nodataavailable VapourpressureNodataavailable

VapourdensityNodataavailable

RelativedensityNodataavailable

PartitioncoefficientNodataavailable AutoignitiontemperatureNodataavailable ExplosivepropertiesNodataavailable

OxidisingpropertiesNodataavailable

SolubilityNodataavailable

9.2.Otherinformation

ConductivityNodataavailable

SurfacetensionNodataavailable Specificgravity1.008-1.016g/cm³

GasgroupNodataavailable BenzeneContentNodataavailable

LeadcontentNodataavailable

VOC(Volatileorganic compounds) Nodataavailable

SECTION10:Stabilityandreactivity

10.1.Reactivity

10.2.Chemicalstability

Stableundernormalconditions.Nospecificreactivityhazardsassociatedwiththisproduct.

Stableundernormalconditions.Noparticularstabilityconcerns.

10.3.Possibilityofhazardousreactions

Strongacids.Strongoxidisingagents.

10.4.Conditionstoavoid

10.5.Incompatiblematerials

Protectfromfrost.

Noincompatiblegroupsnoted.

10.6.Hazardousdecompositionproducts

NoHazardousdecompositionproductswhenstoredandhandledcorrectly.Burningproduces irritating,toxicandobnoxiousfumes.

SECTION11:Toxicologicalinformation

11.1.Informationontoxicologicaleffects

Skincorrosion/irritation Irritatingtoskin.

Seriouseyedamage/irritationNotanticipatedundernormalconditionsofuse.Irritatingtoeyes.

Upholstery Cleaner

11.1.Informationontoxicologicaleffects

Respiratoryorskin sensitisation

Repeatedorprolonged exposure

11.1.2.Mixtures

11.1.3.HazardInformation

11.1.4.ToxicologicalInformation

Notanticipatedundernormalconditionsofuse.Irritatingtorespiratorysystem.Irritatingtoskin.

Prolongedcontactmaycausedefattingoftheskin.Irritatingtoeyes,respiratorysystemandskin. Irritatingtomucousmembranes.

Nodataavailable.

Nodataavailable.

Nodataavailable

SECTION12:Ecologicalinformation

12.1.Toxicity

Nodataavailable

12.2.Persistenceanddegradability

SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.

12.3.Bioaccumulativepotential

Partitioncoefficient

12.4.Mobilityinsoil

Nodataisavailableonthisproduct.

SupagardUpholsteryCleanerNodataavailable

CocamidopropylBetainNodataavailable 2-butoxyethanol0.8logP

Nodataisavailableonthisproduct.

12.5.ResultsofPBTandvPvBassessment

Nodataisavailableonthisproduct.

12.6.Otheradverseeffects

Nodataavailable.

SECTION13:Disposalconsiderations

13.1.Wastetreatmentmethods

Generalinformation

Disposalofpackaging

Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.

Disposeofincompliancewithalllocalandnationalrequirements.

DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.

SECTION14:Transportinformation

14.1.UNnumber

14.2.UNpropershippingname

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

14.3.Transporthazardclass(es)

14.4.Packinggroup

14.5.Environmentalhazards

14.6.Specialprecautionsforuser

Upholstery Cleaner

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

Theproductisnotclassifiedasdangerousforcarriage.

14.7.TransportinbulkaccordingtoAnnexIIofMARPOL73/78andtheIBCCode

Theproductisnotclassifiedasdangerousforcarriage.

SECTION15:Regulatoryinformation

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture

Regulations REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.

COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.

15.2.Chemicalsafetyassessment

Noinformationavailable.

SECTION16:Otherinformation

Otherinformation

Revision

TextofriskphrasesinSection 3

TextofHazardStatementsin Section3

Thisdocumentdiffersfromthepreviousversioninthefollowingareas:. 2-PrecautionaryStatement:Prevention. 9-9.1.Informationonbasicphysicalandchemicalproperties(PH). 12-12.1.Toxicity.

R20/21/22-Harmfulbyinhalation,incontactwithskinandifswallowed.

R22-Harmfulifswallowed.

R34-Causesburns.

R36/38-Irritatingtoeyesandskin.

R41-Riskofseriousdamagetoeyes.

R50-Verytoxictoaquaticorganisms.

R52/53-Harmfultoaquaticorganisms,maycauselong-termadverseeffectsintheaquatic environment.

AcuteTox.4:H302-Harmfulifswallowed.

SkinCorr.1B:H314-Causessevereskinburnsandeyedamage.

AquaticAcute1:H400-Verytoxictoaquaticlife.

EyeDam.1:H318-Causesseriouseyedamage.

AquaticChronic3:H412-Harmfultoaquaticlifewithlonglastingeffects.

AcuteTox.4:H312-Harmfulincontactwithskin.

SkinIrrit.2:H315-Causesskinirritation.

EyeIrrit.2:H319-Causesseriouseyeirritation.

AcuteTox.4:H332-Harmfulifinhaled.

Upholstery Cleaner

TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.

Unit 1, Parkside, Spinners Rd, Doncaster DN2 4LT

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