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Description
Blasts dust, grime and fluff from hard to reach areas. Helps to clean, sanitise and remove dust and dirt particles from those hard to reach places. The product once dispersed evaporates in seconds leaving a clean fresh surface.
Key Features
DESCRIPTION
Clothing Please ensure all protective clothing is worn at all times.

Gloves

Procedure



Shake the can for 60 seconds. Remove the cap protector. Insert the straw.

Press and hold the trigger.

Move the nozzle back and forth as you clean.

Description
A new concentrate air freshener designed to eradicate odours from vehicles. This fast acting formula will give instant results.
Protective Clothing Please ensure all protective clothing is worn at all times.

Gloves


Air Freshener 1ltr Trigger
Procedure

Pour the air freshener fluid into spray bottle.

Close the spray bottle securely.

Spray a small amount to check the mist.


Description
A powerful acid free highly concentrated alloy wheel cleaner designed to quickly remove brake dust and debris from lacquered alloy wheels.
NOTE: To ascertain suitability before use, test in a small inconspicuous area. Not to be used on wheels which are corroded/ damaged to the surface/lacquer.
Cleans & degreases
Powerful fast evaporating formula
DESCRIPTION
Clothing Please ensure all protective clothing is worn at all times.










1ltr Trigger Microfibre Cloth



Pour the desired amount into the trigger bottle.

Dilute with correct ratio of water.

Spray on, leave for no more than 1 minute.

Agitate and wash off.

Description
Creates a state of cleanliness in your vehicle significantly greater than traditional methods by killing more than 99% of germs and bacteria present in the cabin and air-conditioning system.
DESCRIPTION
Clothing Please ensure all protective clothing is worn at all times.




Turn car on and ensure it’s running.

Set the temp to the lowest setting.


Set fans to fastest setting. Select recycle air.

Push down the nozzle, exit the vehicle and close door.

After 10 minutes, turn car off, open doors and air out the car for 30 minutes.


Description
Rapid detailer, cleans, shines and protects leaving no streaks. This can be used on all surfaces including paintwork, black plastics, dashes, chrome and mirrors.
Suitable for all paint finishes
DESCRIPTION
Clothing Please ensure all protective clothing is worn at all times.








1ltr




Pour the desired amount into the trigger bottle.


Spray over the bodywork. Buff the area to a shine with a clean, dry cloth.


Description
A concentrated hot wax, which protects paintwork and livery and leaves a glossy, streak-free finish. Contains unique dirt repellent to inhibit resoling. Suitable for use with all forecourt systems.
Quick application
Prolongs time between washes
DESCRIPTION
Clothing Please ensure all protective clothing is worn at all times.










Pour into the power washer’s container.

Spread the Aqua Rinse Aid across the paint.

Rinse with clean water and buff the surface.

Attach the power washer.

The soapy mousse will rehydrate the deposit, creating a solution that can be easily wiped off the paintwork.
NOTE: This product will not help restore paintwork that has already been contaminated with bird lime. Do not use when bodywork or glass is very hot. Do not allow to dry before washing off.
DESCRIPTION
Easy to use foam
Neutralises nitric acid in birdlime deposits
Protective Clothing Please ensure all protective clothing is worn at all times.

Materials




Apply to affected areas. Allow the product to rehydrate debris.

Rinse the car with water to remove any residue.

Dry the cleaned areas with a clean, dry cloth.

Gently wipe the area with a microfibre cloth.

Description
A durable, easy to use premium car polish with a low dust formula. Contains carnauba wax for high gloss, long lasting, durable, detergent resistant finish.
Suitable for new and used cars.
DESCRIPTION
Standard Body Polish
Key Features
Long lasting formula
Durable finish
Protective Clothing Please ensure all protective clothing is worn at all times.




5ltr Bottle



Wash and dry the car thoroughly to remove dirt.

Remove residue with microfibre cloth.

Dab a small amount onto the polishing pad.

Move in circular motions with light pressure.

Description
Revitalises tired oxidised paintwork, removes traffic film, superficial contamination and aged and chalky deposits.
Cleans, and conditions surfaces for further treatments.
DESCRIPTION
Cutting Compound Fine 500ml
Revitalises paintwork
Cleans & conditions
Protective Clothing Please ensure all protective clothing is worn at all times.



Materials




Wash and dry the car thoroughly to remove dirt.

Move in circular motions with light pressure.

Shake the bottle for 60 seconds.

Remove residue with microfibre cloth.

Dab a small amount onto the polishing pad.

Description
Revitalises tired oxidised paintwork, removes traffic film, superficial contamination and aged and chalky deposits.
Cleans, and conditions surfaces for further treatments.
Revitalises paintwork
Cleans & conditions
DESCRIPTION
Protective Clothing Please ensure all protective clothing is worn at all times.



Materials



Procedure

Wash and dry the car thoroughly to remove dirt.

Move in circular motions with light pressure.

Shake the bottle for 60 seconds.

Remove residue with microfibre cloth.

Dab a small amount onto the polishing pad.

Description
Revitalises tired oxidised paintwork, removes traffic film, superficial contamination and aged and chalky deposits.
Cleans, and conditions surfaces for further treatments.
Revitalises paintwork
Cleans & conditions
DESCRIPTION
Cutting Compound Coarse
Protective Clothing Please ensure all protective clothing is worn at all times.



Materials



Procedure

Wash and dry the car thoroughly to remove dirt.

Move in circular motions with light pressure.

Shake the bottle for 60 seconds.

Remove residue with microfibre cloth.

Dab a small amount onto the polishing pad.


Description
This highly concentrated shampoo is effective for removing dirt and grime from everyday road use and cleans leaving a glossy, streak free finish.
Key Features
DESCRIPTION
Protective Clothing Please ensure all protective clothing is worn at all times.




Fill the foamer canon with shampoo.

Use the jet wash to cover the car with shampoo.



Attach the foamer canon to the jet washer.

Rub over with a sponge or mit.

Spray the car with water to remove loose dirt.

Rinse with clean water and dry.

Description
An excellent way to renovate and rejuvenate a multitude of fabric and textile surfaces offering a flexible good as new finish. Touch dry in 15 minutes, re-coat where required in 20 minutes. Excellent coverage and adhesion.
DESCRIPTION
Key Features Accurate spray coverage




Protective Clothing Please ensure all protective clothing is worn at all times. Materials



Vacuum mats thoroughly. Shake the aerosol well for even application.

Allow to dry completely before reinstalling.


Apply light, even coats from about 6 inches away.

Description
A silicone free, high active cleansing spray that will quickly clean and finish all vinyl, rubber & plastic interior surfaces.
Suitable for use on multiple surfaces
DESCRIPTION
Protective Clothing Please ensure all protective clothing is worn at all times.





5ltr Bottle



Pour the desired amount into the trigger bottle.

Adjust the spray pattern by turning the nozzle.

Apply directly to the surface or microfibre cloth.

Wipe with a dry cloth for a streak-free finish.

Description
Improves engine performance. Improves cold starting.
Reduces noxious exhaust emissions. Restores injector spray patterns. Controls fuel oxidation, gum, varnish and acid formation. Lubricates and extends the life of injectors and fuel pumps.
Increases MPG Cleans fuel system
DESCRIPTION
Protective Clothing Please ensure all protective clothing is worn at all times.







Pour the treatment into the empty fuel tank.

Fill up with petrol to mix the treatment.

Description
Improves engine performance. Improves fuel economy. Helps remove sludge and varnish from all lubrication faces. Helps form a suspension or solution of contaminants assisting in optimum drainage. Contains lubricant and extreme pressure additives to provide temporary protection whilst in use. Helps prevent contamination of fresh oil.
DESCRIPTION
Prolongs oil life
Improves performance
Protective Clothing Please ensure all protective clothing is worn at all times.

Gloves

150ml Can


Unscrew lid of can.

Pour the product into the engine oil filler.

Pull the plastic tab from lid of can.

Idle for 10-15 minutes to circulate the flush.

Unscrew the engine oil filler cap.

Turn engine off, drain the old oil and refill.

Description
A high active cleansing spray that will quickly clean and finish all paintwork and plastics.
Key Features Colourless
Non-staining
DESCRIPTION
Exterior
Protective Clothing Please ensure all protective clothing is worn at all times.

Gloves

500ml Aerosol Can



Shake can thoroughly. Apply a fine mist onto paintwork and plastics.

Allow to dry for a glossy finish.

Use a microfibre cloth to spread and buff.

Description
This powerful cleaner breaks through even the toughest dirt and grime on windows and mirrors, leaving a sparkling streak free finish.
Key Features
DESCRIPTION
Protective Clothing Please ensure all protective clothing is worn at all times.

Gloves

5ltr Bottle



1ltr Trigger Microfibre Cloth Funnel



Pour glass cleaner from the container into spray bottle.

Apply a fine mist onto the the glass.

Buff in with a microfibre cloth.

Description
This hand barrier cream is a must-have shield for your hands. Formulated to protect, nourish, and strengthen your skin, it forms a proactive defence against irritants.
Key Features
Strong molecular coating
Provides protection and nourishment for your skin
DESCRIPTION
Clothing Please ensure all protective clothing is worn at all times.





Unscrew bottle cap. Screw on rubber nozzle. Pour product into the top of the container.



Lock the container in place. Ensure the cap is secure. Insert the container into the dispenser.

Description
Advanced formulation, solvent-free heavy duty hand cleanser containing non-abrasive scrubbers for a deep-down cleaning action and moisturiser to help care for the skin. Removes ingrained oil, grease and general grime.
Heavy duty hand cleanser
Non-abrasive scrubbers
DESCRIPTION
Hand Cleaner
Protective Clothing Please ensure all protective clothing is worn at all times.





Unscrew bottle cap. Screw on rubber nozzle. Pour product into the top of the container.



Lock the container in place. Ensure the cap is secure. Insert the container into the dispenser.

Description
Car interior protection and seatbelt care. Fully synthetic surface care with highly lubricating microfilm. Has an anti-static effect with UV protection even on plastic and rubber.
Key Features Colourless
Excellent lubrication
DESCRIPTION
Clothing Please ensure all protective clothing is worn at all times.

Gloves

500ml Aerosol Can
Procedure


Shake thoroughly before use.

Perfect for hard to access areas.

To avoid overspray insert straw to nozzle.

Apply directly to the component.

Description
Fast and effective cleaner for all finished leather surfaces. Leather cleaner, cleans, conditions, and protects. This pH neutral formula has a deep cleansing action whilst being gentle enough to use on interior Leather surfaces.
Note: Not suitable for untreated raw or suede leather.
Cleans & conditions
Gentle non-abrasive formula
DESCRIPTION
Leather Cleaner
Protective Clothing Please ensure all protective clothing is worn at all times.




Pour leather cleaner into the 1ltr bottle.

Gently clean with a cloth and let it dry.


1ltr Trigger Microfibre Cloth


Follow instructions for proper dilution ratio. Apply cleaner onto the leather surface.

Ensure the product is disposed of as per MSDS.


A heavy duty formulated product for hard surface cleaning. Effective at removing oil & dirt from engines and to assist in the removal of stains from your interior.
Description DESCRIPTION
Cleans & degreases
Powerful fast evaporating formula
Clothing Please ensure all protective clothing is worn at all times.









1ltr Trigger



Spray directly onto the hard surface or stain.

Wipe away residue with a clean, damp cloth.


Pour the product into a clean trigger spray bottle.

Description
Improves engine performance. Improves fuel economy. Cleans fuel system components. Removes lacquer, varnish and carbon deposits from injectors. Restores efficient fuel delivery to the combustion chamber. Neutralises harmful acids.
Key Features
Increases MPG Cleans fuel system
DESCRIPTION
Protective Clothing Please ensure all protective clothing is worn at all times.








Pour the treatment into the empty fuel tank.

Fill up with petrol to mix the treatment.

Description
This exterior plastic rubber coating helps to refreshen black plastics and rubbers as well as rejuvenate tyre walls. This product can be brushed or sponged onto the surface easily leaving a showroom finish.
DESCRIPTION
Key Features
Clothing Please ensure all protective clothing is worn at all times.










Pour the product into a clean trigger spray bottle.

Apply to the plastic trim or cloth.

Use a microfibre cloth and buff.


Description
Highly effective against a wide range of bad odours such as pet odours and sulphurous smells. Scent Cyclone does not merely mask the odour with a fragrance, but forms a chemical complex with the organic odor molecules, removing them from the air.
DESCRIPTION
Protective Clothing Please ensure all protective clothing is worn at all times.


Materials

150ml Aerosol Can
Procedure

150ml Aerosol Can

Turn car on and ensure it’s running.

Set the temp to the lowest setting.


Set fans to fastest setting. Select recycle air.

Push down the nozzle, exit the vehicle and close door.

After 10 minutes, turn car off, open doors and air out the car for 30 minutes.

Description
Water resistant coating has been carefully formulated for the renovation of all plastics, PVC, rubber etc. throughout your vehicle.
Prevents cracking and ageing
dirt from tyre wall
DESCRIPTION
Clothing Please ensure all protective clothing is worn at all times.




5ltr Bottle


Apply a fine mist onto the tyre surface.




Trigger



Pour the product into a clean trigger spray bottle.

Rub over the sidewall of the tyre, allow to dry.


Description
Snow Foam produces a satisfyingly thick foam, giving your car an even coating of foam. This makes sure that every inch of your car is covered in the snow foam giving an effective, deep clean. It’s ideal for heavy detailing sessions or for quickly sprucing up your car paintwork.
Cleans & degreases
Powerful fast acting formula
DESCRIPTION
Protective Clothing Please ensure all protective clothing is worn at all times.






Fill the foamer canon with snow foam.

Use the jet wash to cover the car with shampoo.




Attach the foamer canon to the jet washer.

Rub over with a sponge or mit.

Spray the car with water to remove loose dirt.

Rinse with clean water and dry.




Description DESCRIPTION
Our high concentrated formula dissolves adhesives and tar quickly whilst not damaging the paintwork. Perfect for getting rid of all those sticky marks left by stickers and signs on paintwork.
Dissolves adhesives
Does not damage paintwork
& Glue Remover
Clothing Please ensure all protective clothing is worn at all times.





5ltr Bottle







Spray on, allow the product to sit for a few minutes to break down residue. Trousers

1ltr Trigger Microfibre Cloth

Place funnel into bottle.

Use a cloth to remove the residue, then rinse if needed.

Pour the product into a clean trigger spray bottle.

Description
This product has been carefully designed to temporarily reduce the loss of air pressure from a punctured tyre in order to get you safely off the road to a repair shop for a more permanent repair, or tyre replacement if necessary.
Seals in minutes
No tools required
DESCRIPTION
Clothing Please ensure all protective clothing is worn at all times.

Gloves

500ml Aerosol Can

Turn tyre so puncture is at the 6 o’clock position. least 60 seconds.


Attach nozzle from the can to the tyre valve.

Purge the full contents of the can into the tyre.

Pull the protective tab off.

Unscrew the filling hose and replace the dust cap.


Description
Highly concentrated water resistant coating that has been carefully formulated to renovated tyres and exterior trim.
Key Features
Prevents cracking and ageing
Repels dirt from tyre wall
DESCRIPTION SIZE
Concentrated Tyre Dressing 5ltr
Concentrated Tyre Dressing 25ltr
Protective Clothing Please ensure all protective clothing is worn at all times.










1ltr Trigger Microfibre Cloth


Unscrew bottle cap. Place funnel into bottle.

Apply a fine mist onto the tyre surface.

Rub over the sidewall of the tyre, allow to dry.

Pour the tyre dressing into a clean trigger spray bottle.

Description
Gently removes stains from carpets and upholstery. Penetrates deep into the fibres to lift stains to the surface and ease the removal of the most stubborn marks.
Key Features
Provides plenty of foam
Easy to spray on & wipe off
DESCRIPTION
Protective Clothing Please ensure all protective clothing is worn at all times.

Gloves

500ml Aerosol Can


Shake thoroughly before use.

Use a microfibre cloth to work in the cleaner.

Apply to the entire upholstery surface.

Allow to dry.

Let the foam settle.

Gently removes stains from carpets and upholstery. Penetrates deep into the fibres to lift stains to the surface & ease the removal of the most stubborn marks.
NOTE: Due to the many variations of upholstery, always test the cleaner on a hidden area of the material to be treated before commencing stain removal.
DESCRIPTION
Gently removes dirt & water marks
Water based solution
Clothing Please ensure all protective clothing is worn at all times.


5ltr Bottle


1ltr Trigger




Unscrew bottle cap. Place funnel into bottle. Pour the product into bottle.

Spray over the entire upholstery surface.


Allow to dry. Use a microfibre cloth to work in the cleaner.


according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878 Issue date: 10/20/2021 Revision date: 3/25/2025 Supersedes version of: 10/20/2021 Version: 2.0
1.1. Product identifier
Product form
Product name
Product code
Vaporizer
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Intended for general public
1.2.2. Uses advised against No additional information available
1.3. Details of the supplier of the safety data sheet

1.4. Emergency telephone number
Emergency number : 01416335933
Country/Area
United Kingdom National Poisons Information
(Birmingham Centre) City Hospital
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Aerosol, Category 1 H222;H229
Full text of H- and EUH-statements: see section 16
Adverse physicochemical, human health and environmental effects
Pressurised container: May burst if heated. Extremely flammable aerosol.
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS02

Signal word (CLP) : Danger
Hazard statements (CLP) : H222 - Extremely flammable aerosol. H229 - Pressurised container: May burst if heated.
2.3. Other hazards
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878
Precautionary statements (CLP) : P102 - Keep out of reach of children.
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P211 - Do not spray on an open flame or other ignition source.
P251 - Do not pierce or burn, even after use.
P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP]
PETROLEUM GASES, LIQUEFIED
CAS-No.: 68476-85-7
EC-No.: 270-704-2
EC Index-No.: 649-202-00-6
100 Flam. Gas 1, H220
Product subject to CLP Annex I, item 1.1.3.7. The disclosure rules of the components is modified in this case.
Full text of H- and EUH-statements: see section 16
4.1. Description of first aid measures
First-aid measures general
First-aid measures after inhalation
: If you feel unwell, seek medical advice.
: Remove person to fresh air and keep comfortable for breathing.
First-aid measures after skin contact : Wash skin with plenty of water.
First-aid measures after eye contact : Rinse eyes with water as a precaution.
First-aid measures after ingestion
: Call a poison center or a doctor if you feel unwell.
First-aid measures for first aider : First aid workers will be equipped with suitable personal protective equipment.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after inhalation
: None under normal conditions.
Symptoms/effects after skin contact : None under normal conditions.
Symptoms/effects after eye contact : None under normal conditions.
Symptoms/effects after ingestion
: None under normal conditions.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
5.1. Extinguishing media
Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide.
Unsuitable extinguishing media : Do not use a heavy water stream.
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878
5.2. Special hazards arising from the substance or mixture
Fire hazard
: Extremely flammable aerosol.
Explosion hazard : Pressurised container: May burst if heated.
Hazardous decomposition products in case of fire : Toxic fumes may be released.
5.3. Advice for firefighters
Firefighting instructions
Protection during firefighting
: Fight fire from safe distance and protected location. Do not enter fire area without proper protective equipment, including respiratory protection.
: Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing.
6.1. Personal precautions, protective equipment and emergency procedures
General measures
6.1.1. For non-emergency personnel
Protective equipment
Emergency procedures
6.1.2. For emergency responders
Protective equipment
Emergency procedures
6.2. Environmental precautions
Avoid release to the environment.
: Stop leak if safe to do so. Notify authorities if product enters sewers or public waters. Absorb spillage to prevent material damage.
: Wear recommended personal protective equipment.
: Ventilate spillage area. No open flames, no sparks, and no smoking.
: Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection".
: Evacuate unnecessary personnel. Stop leak if safe to do so.
6.3. Methods and material for containment and cleaning up
For containment
Methods for cleaning up
Other information
6.4. Reference to other sections
For further information refer to section 13.
7.1. Precautions for safe handling
Additional hazards when processed
Precautions for safe handling
Hygiene measures
: Absorb spilled material with sand or earth. Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. Stop leak without risks if possible.
: Mechanically recover the product.
: Dispose of materials or solid residues at an authorized site.
: Not expected to present a significant hazard under anticipated conditions of normal use.
: Ensure good ventilation of the work station. Wear personal protective equipment. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use.
: Do not eat, drink or smoke when using this product. Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures
Storage conditions
Packaging materials
: Keep in a cool, well-ventilated place away from heat.
: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F.
: Store always product in container of same material as original container.
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878
7.3. Specific end use(s)
No additional information available
8.1. Control parameters
8.1.1 National occupational exposure and biological limit values
PETROLEUM GASES, LIQUEFIED (68476-85-7)
United Kingdom - Occupational Exposure Limits
WEL TWA (OEL TWA)
< 1750 mg/m³
WEL STEL (OEL STEL) < 2180 mg/m³
8.1.2. Recommended monitoring procedures
No additional information available
8.1.3. Air contaminants formed
No additional information available
8.1.4. DNEL and PNEC
No additional information available
8.1.5. Control banding
No additional information available
8.2. Exposure controls
8.2.1. Appropriate engineering controls
Appropriate engineering controls: Ensure good ventilation of the work station.
8.2.2. Personal protection equipment
Personal protective equipment:
Wear recommended personal protective equipment. Personal protective equipment symbol(s):



8.2.2.1. Eye and face protection
Eye protection: Safety glasses
8.2.2.2. Skin protection
Skin and body protection:
Wear suitable protective clothing
Hand protection: Protective gloves
8.2.2.3. Respiratory protection
Respiratory protection:
In case of insufficient ventilation, wear suitable respiratory equipment
8.2.2.4. Thermal hazards
No additional information available
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878
8.2.3. Environmental exposure controls
Environmental exposure controls: Avoid release to the environment.
9.1. Information on basic physical and chemical properties
Physical state
: Liquid
Colour : Colourless.
Odour : odourless.
Odour threshold
pH
: No data available
: No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point
Freezing point
Boiling point
Flash point
Auto-ignition temperature
Decomposition temperature
Flammability (solid, gas)
Vapour pressure
Relative vapour density at 20°C
Relative density
Solubility
: Not applicable
: No data available
: No data available
: < 23 °C
: No data available
: No data available
: Extremely flammable aerosol.
: No data available
: No data available
: No data available
: No data available
Partition coefficient n-octanol/water (Log Pow) : No data available
Viscosity, kinematic
Viscosity, dynamic
Explosive properties
Oxidising properties
Explosive limits
9.2. Other information
No additional information available
10.1. Reactivity
: No data available
: No data available
: Pressurised container: May burst if heated.
: No data available
: No data available
Extremely flammable aerosol. Pressurised container: May burst if heated.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4. Conditions to avoid
Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878
11.1 Information on toxicological effects
Acute toxicity (oral)
Acute toxicity (dermal)
Acute toxicity (inhalation)
Skin corrosion/irritation
Serious eye damage/irritation
Respiratory or skin sensitisation
Germ cell mutagenicity
Carcinogenicity
Reproductive toxicity
STOT-single exposure
STOT-repeated exposure
Aspiration hazard
: Not classified
: Not classified
: Not classified
: Not classified
: Not classified
: Not classified
: Not classified
: Not classified
: Not classified
: Not classified
: Not classified
: Not classified
SUPAGARD STONEACRE AIR DUSTER - ZAD500MLAEROSTONE NPD11022
Vaporizer Aerosol
12.1. Toxicity
Ecology - general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment.
Hazardous to the aquatic environment, short–term (acute) : Not classified
Hazardous to the aquatic environment, long–term (chronic) : Not classified
12.2. Persistence and degradability
SUPAGARD STONEACRE AIR DUSTER - ZAD500MLAEROSTONE NPD11022
Persistence and degradability Not rapidly degradable
PETROLEUM GASES, LIQUEFIED (68476-85-7)
Persistence and degradability Not rapidly degradable
12.3. Bioaccumulative potential
No additional information available
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
No additional information available
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878
13.1. Waste treatment methods
Regional waste regulation
: Disposal must be done according to official regulations.
Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions.
Sewage disposal recommendations : Disposal must be done according to official regulations.
Product/Packaging disposal recommendations : Disposal must be done according to official regulations.
Additional information : Do not re-use empty containers.
In accordance with ADR
14.1. UN number
14.2. UN proper shipping name
Transport document description UN 1950 AEROSOLS, 2.1, (D)
14.3. Transport hazard class(es)

14.4. Packing group
14.5. Environmental hazards
No supplementary information available
14.6. Special precautions for user
Overland transport
Not applicable
Dangerous for the environment: No
Classification code (ADR) : 5F
Special provisions (ADR) : 190, 327, 344, 625
Limited quantities (ADR) : 1l
Excepted quantities (ADR) : E0
Packing instructions (ADR) : P207, LP200
Special packing provisions (ADR) : PP87, RR6, L2
Mixed packing provisions (ADR) : MP9
Transport category (ADR) : 2
Special provisions for carriage - Packages (ADR) : V14
Special provisions for carriage - Loading, unloading and handling (ADR) : CV9, CV12
Special provisions for carriage - Operation (ADR) : S2
Tunnel restriction code (ADR) : D
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
REACH Annex XVII (Restriction List)
Contains no substance(s) listed on REACH Annex XVII (Restriction Conditions)
REACH Annex XIV (Authorisation List)
Contains no substance(s) listed on REACH Annex XIV (Authorisation List)
REACH Candidate List (SVHC)
Contains no substance(s) listed on the REACH Candidate List
PIC Regulation (Prior Informed Consent)
Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)
POP Regulation (Persistent Organic Pollutants)
Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)
Ozone Regulation (2024/590)
Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 2024/590 on substances that deplete the ozone layer)
Council Regulation (EC) for the control of dual-use items
Contains no substance subject to the COUNCIL REGULATION (EC) for the control of dual-use items
Explosives Precursors Regulation (2019/1148)
Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)
Drug Precursors Regulation (273/2004)
Contains no substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain substances used in the illicit manufacture of narcotic drugs and psychotropic substances)
15.1.2. National regulations No additional information available
15.2. Chemical safety assessment
No chemical safety assessment has been carried out
Abbreviations and acronyms:
ACGIH American Conference of Government Industrial Hygienists
ADN European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
ADR European Agreement concerning the International Carriage of Dangerous Goods by Road
ATE Acute Toxicity Estimate
BCF Bioconcentration factor
BLV Biological limit value
BOD Biochemical oxygen demand (BOD)
CAS-No. Chemical Abstract Service number
CLP Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
COD Chemical oxygen demand (COD)
CSA Chemical safety assessment
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878
Abbreviations and acronyms:
DMEL Derived Minimal Effect level
DNEL Derived-No Effect Level
EC-No. European Community number
EC50 Median effective concentration
ED Endocrine disruptor
EN European Standard
EWC European waste catalogue
IARC International Agency for Research on Cancer
IATA International Air Transport Association
IMDG International Maritime Dangerous Goods
LC50 Median lethal concentration
LD50 Median lethal dose
LOAEL Lowest Observed Adverse Effect Level
Log Kow Partition coefficient n-octanol/water (Log Kow)
Log Pow Partition coefficient n-octanol/water (Log Pow)
MAK maximum workplace concentration
NOAEC No-Observed Adverse Effect Concentration
NOAEL No-Observed Adverse Effect Level
NOEC No-Observed Effect Concentration
N.O.S. Not Otherwise Specified
OECD Organisation for Economic Co-operation and Development
OEL Occupational Exposure Limit
OSHA Occupational Safety Health Administration
PBT Persistent Bioaccumulative Toxic
PNEC Predicted No-Effect Concentration
PPE Personal protection equipment
RID Regulations concerning the International Carriage of Dangerous Goods by Rail
SDS Safety Data Sheet
STP Sewage treatment plant
TF Technical function
ThOD Theoretical oxygen demand (ThOD)
TLM Median Tolerance Limit
TWA Time Weighted Average
VOC Volatile Organic Compounds
vPvB Very Persistent and Very Bioaccumulative
UFI Unique Formula Identifier
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878
Full text of H- and EUH-statements:
Flam. Gas 1 Flammable gases, Category 1
H220
Extremely flammable gas.
H222 Extremely flammable aerosol.
H229 Pressurised container: May burst if heated.
Safety Data Sheet (SDS), EU
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.


according to Regulation (EU) 2020/878
SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking
1.1.Productidentifier
Productname Cherry Air Freshener
1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst
ProductUse
[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC3]Aircare products;
[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC3]Aircareproducts;
Description CherryAirFreshener.
1.3.Detailsofthesupplierofthesafetydatasheet
Company SUPAGARDLIMITED
Address 19-27GavintonStreet Muirend Glasgow G443EF
Web www.supagard.com
Telephone 01416335933
Fax 01416377219
Email James.Smyth@supagard.com
Emailaddressofthe competentperson James.Smyth@supagard.com
1.4.Emergencytelephonenumber
Emergencytelephonenumber01416335933 8.30amto5.00pm
FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)
Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org
SECTION2:Hazardsidentification
2.1.Classificationofthesubstanceormixture
2.1.2.Classification-EC 1272/2008 Thisproductdoesnotmeetthecriteriaforclassificationinanyhazardclassaccordingto Regulation(EC)No.1272/2008onclassification,labellingandpackagingofsubstancesand mixtures.
2.2.Labelelements
PrecautionaryStatement: Prevention P102-Keepoutofreachofchildren.
PrecautionaryStatement: Response P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.

2.2.Labelelements
P337+P313-Ifeyeirritationpersists:Getmedicaladvice/attention.
HazardStatement NoSignificantHazard
SUPPLEMENTALHAZARD INFORMATION
IngredientsasrequiredbyRegulation(EC)No648/2004:. Lessthan5%Non-ionicSurfactants,Parfum,Preservative:Benzisothiazolinone,Benzaldehyde, Eugenol.
Contents-DenaturedEthanol,Isopropylideneglycerol.
2.3.Otherhazards
Otherhazards Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.
Furtherinformation
RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.
3.2.Mixtures
EC1272/2008
ChemicalName
Ethanol:EthylAlcohol(Ethanol) 64-17-5200-578-601-2119457610-43
Flam.Liq.2:H225;EyeIrrit. 2:H319; 1-10% 2,2-dimethyl-1,3-dioxolan-4-ylmetha nol 100-79-8202-888-701-2120066005-66 EyeIrrit.2:H319;0-0.5%
4.1.Descriptionoffirstaidmeasures
Inhalation Movetheexposedpersontofreshair.
Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved.
Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution.
Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.
4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed
Inhalation Maycauseirritationtorespiratorysystem.
Eyecontact Maycauseirritationtoeyes.
Skincontact Maycauseskindrynessandirritation.
Ingestion Maycauseirritationtomucousmembranes.
4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded TREATSYMPTOMATICALLY.
Inhalation Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.
Eyecontact Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.
Skincontact Seekmedicalattentionifirritationorsymptomspersist.
Ingestion Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.
Generalinformation
Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.
5.1.Extinguishingmedia
Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.
5.2.Specialhazardsarisingfromthesubstanceormixture

5.2.Specialhazardsarisingfromthesubstanceormixture
Noneknown.
5.3.Adviceforfirefighters
Furtherinformation
Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.
Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.
SECTION6:Accidentalreleasemeasures
6.1.Personalprecautions,protectiveequipmentandemergencyprocedures
6.2.Environmentalprecautions
Wearsuitableprotectiveequipment.
Adviselocalauthoritiesiflargespillscannotbecontained.
6.3.Methodsandmaterialforcontainmentandcleaningup
Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.
6.4.Referencetoothersections
Seesection2,7,8,13forfurtherinformation.
7.1.Precautionsforsafehandling
AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.
7.2.Conditionsforsafestorage,includinganyincompatibilities
Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.
7.3.Specificenduse(s)
Suitablepackaging
CherryAirFreshener.
Plasticcontainers.
8.1.Controlparameters
8.1.1.ExposureLimitValues
Ethanol:EthylAlcohol(Ethanol)
DNEL:Derivedno-effectlevel.
Occupationalexposurecontrols.
WEL8-hrlimitppm:1000
WEL8-hrlimitmg/m3:1920
WEL15minlimitppm:- WEL15minlimitmg/m3:-
WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -

ExposurePattern-Workers
Ethanol:EthylAlcohol Long-term-inhalation-Systemic effects 950mg/m³
Long-term-inhalation-Local effects 1900mg/m³
ExposurePattern-Generalpopulation
Ethanol:EthylAlcohol Long-term-inhalation-Systemic effects 114mg/m³
Long-term-inhalation-Local effects 950mg/m³
Long-term-oral-Systemic effects 87mg/kg
Long-term-dermal-Systemic effects 343mg/kg
Long-term-dermal-Systemic effects 206mg/kg
8.2.Exposurecontrols


AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.
8.2.1.Appropriateengineering controls
Eye/faceprotection
Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.
Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields.
SkinprotectionHandprotection Rubbergloves.
Respiratoryprotection
8.2.3.Environmentalexposure controls
Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.
Preventfurtherleakageorspillageifsafetodoso.
9.1.Informationonbasicphysicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties
AppearanceLiquid ColourClear
OdourPerfumes
OdourthresholdNodataavailable pH6-8
MeltingpointNodataavailable
InitialboilingpointNodataavailable EvaporationrateNodataavailable Flammability(solid,gas)Nodataavailable VapourpressureNodataavailable
RelativeVapourDensityNodataavailable Density/RelativeDensity0.995-1.01
PartitioncoefficientNodataavailable
AutoignitiontemperatureNodataavailable Viscosity<50centipoise
ExplosivepropertiesNodataavailable
OxidisingpropertiesNodataavailable SolubilitySolubleinwater
9.2.Otherinformation
ConductivityNodataavailable SurfacetensionNodataavailable
GasgroupNodataavailable BenzeneContentNodataavailable
LeadcontentNodataavailable
VOC(Volatileorganic compounds) Nodataavailable
AtomicnumberNodataavailable MassnumberNodataavailable
ChemicalSymbolNodataavailable PhysicalHalfLifeNodataavailable SpecificActivityNodataavailable ActivityNodataavailable PrincipleEmissionsBetaNodataavailable PrincipleEmissionsGammaNodataavailable PrincipleEmissionsAlphaNodataavailable PrincipleEmissionsNeutronNodataavailable
9.2.1.Informationwithregardtophysicalhazardclasses Nodataavailable.
9.2.2.Othersafetycharacteristics Nodataavailable.

10.4.Conditionstoavoid
10.5.Incompatiblematerials
Protectfromfrost.
Noincompatiblegroupsnoted.
10.6.Hazardousdecompositionproducts
NoHazardousdecompositionproductswhenstoredandhandledcorrectly.
11.1Informationonhazardclasses
Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedfromrawmaterialsupplierLD50andAcuteToxicityEstimates(ATE)asoutlinedinthe Regulation(EC)No.1272/2008(CLP)asamendedbyUKlaw.
Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
OralATE=>10,000mg/kg.
VapoursATE=>20mg/l.
Inhalation-Dust/MistATE=>20mg/l.
Skincorrosion/irritation basedonavailabledatatheclassificationcriteriaarenotmet.
Seriouseyedamage/irritationbasedonavailabledatatheclassificationcriteriaarenotmet.
Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.
Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet.
Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.
Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.
Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet.
Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.
11.1.2.Mixtures
11.1.3.HazardInformation
11.1.4.ToxicologicalInformation
Ethanol:EthylAlcohol
11.2Informationonotherhazards
Nodataavailable.
Nodataavailable.
OralRatLD50:10470.0mg/kg
InhalationRatLC50/4h:>20mg/l
Nodataavailable.
SECTION12:Ecologicalinformation
12.1.Toxicity
Ethanol:EthylAlcohol
DaphniaEC50/48h:12340.0000mg/l
GreenAlgaeEC50/48h:>100mg/l
RainbowtroutLC50/96h:13000mg/l
NOEC/EC10formarineor freshwaterorganisms 9.6000mg/l
DermalRabbitLD50:15800.0mg/kg
AlgaeEC50/72h:275mg/l
FatheadminnowsLC50/96h:14200mg/l
GoldenorfeLC50/48h:>100mg/l
12.2.Persistenceanddegradability
SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD

12.2.Persistenceanddegradability guidelines.
12.3.Bioaccumulativepotential
Nodataisavailableonthisproduct. Partitioncoefficient
StoneacreCherryAirFreshenerNodataavailable
Ethanol:EthylAlcohol-0.35logP
12.4.Mobilityinsoil
Nodataisavailableonthisproduct.
12.6Endocrinedisruptingproperties
Nodataavailable.
12.7.Otheradverseeffects
Nodataisavailableonthisproduct.
13.1.Wastetreatmentmethods
Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements. Generalinformation
Disposeofincompliancewithalllocalandnationalrequirements. Disposalofpackaging
DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.
14.1.UNnumber
14.2.UNpropershippingname
14.3.Transporthazardclass(es)
14.4.Packinggroup
14.5.Environmentalhazards
14.6.Specialprecautionsforuser
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
14.7MaritimeTransportinbulkaccordingtoIMOinstruments
Theproductisnotclassifiedasdangerousforcarriage.
15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.AsretainedandamendedinUKlaw.
COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.Asretainedand amendedinUKlaw.
COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).AsretainedandamendedinUK law.
15.2.Chemicalsafetyassessment
Noinformationavailable.
SECTION16:Otherinformation
Otherinformation
Revision
Datasources
TextofHazardStatementsin
Section3
Furtherinformation
Thisdocumentdiffersfromthepreviousversioninthefollowingareas:. 2-SUPPLEMENTALHAZARDINFORMATION. 12-12.1.Toxicity. 16-Datasources.
GBMandatoryClassificationandLabellingList. ECHAClassificationandLabellingInventory(CLI).Keyliteraturereferencesandsourcesfordata:. SupplierSDSsforingredientscontainedinthemixture.
Flam.Liq.2:H225-Highlyflammableliquidandvapour. EyeIrrit.2:H319-Causesseriouseyeirritation.
TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.


according to Regulation (EU) 2020/878
SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking
1.1.Productidentifier
Productname Fresh Linen Air Freshener
1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst
ProductUse
[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC3]Aircare products;
[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC3]Aircareproducts;
Description FreshLinenAirFreshener.
1.3.Detailsofthesupplierofthesafetydatasheet Company SUPAGARDLIMITED
Address 19-27GavintonStreet Muirend Glasgow G443EF
Web www.supagard.com
Telephone 01416335933
Fax 01416377219
Email James.Smyth@supagard.com
Emailaddressofthe competentperson James.Smyth@supagard.com
1.4.Emergencytelephonenumber
Emergencytelephonenumber01416335933 8.30amto5.00pm
FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)
Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org
SECTION2:Hazardsidentification
2.1.Classificationofthesubstanceormixture
2.1.2.Classification-EC 1272/2008 EUH208;
2.1.2.Classification-EC 1272/2008
2.2.Labelelements
Thisproductdoesnotmeetthecriteriaforclassificationinanyhazardclassaccordingto Regulation(EC)No.1272/2008onclassification,labellingandpackagingofsubstancesand mixtures.
HazardStatement EUH208-Containslinalool.Mayproduceanallergicreaction.

2.2.Labelelements
PrecautionaryStatement: Prevention P102-Keepoutofreachofchildren.
PrecautionaryStatement: Response
SUPPLEMENTALHAZARD INFORMATION
2.3.Otherhazards
Otherhazards
Furtherinformation
P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing. P337+P313-Ifeyeirritationpersists:Getmedicaladvice/attention.
IngredientsasrequiredbyRegulation(EC)No648/2004:.
Lessthan5%Non-ionicSurfactants,Parfum,Preservative:Benzisothiazolinone,Linalool,Hexyl Cinnamal,BenzylSalicylate,Hexamethylindanopyran,Terpineol,AmylSalicylate,Tetramethyl Acetyloctahydronaphthalenes,CitrusAurantiumPeelOil,DimethylPhenethylAcetate,Limonene, alpha-Isomethylionone.
Contents-DenaturedEthanol,2,2-dimethyl-1,3-dioxolan-4-ylmethanol,Linalool.
Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.
RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.
SECTION3:Composition/informationoningredients
3.2.Mixtures
EC1272/2008
ChemicalName
Ethanol:EthylAlcohol(Ethanol)
2,2-dimethyl-1,3-dioxolan-4-ylmetha nol
3,7-Dimethylocta-1,6-dien-3-ol
4.1.Descriptionoffirstaidmeasures
64-17-5200-578-601-2119457610-43
100-79-8202-888-701-2120066005-66
78-70-6201-134-401-2119474016-42
Inhalation Movetheexposedpersontofreshair.
Flam.Liq.2:H225;EyeIrrit. 2:H319; 1-10%
EyeIrrit.2:H319;0-0.5%
SkinIrrit.2:H315;SkinSens. 1:H317;EyeIrrit.2:H319; 0-0.5%
Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved.
Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution.
Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.
4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed
Inhalation Maycauseirritationtorespiratorysystem.
Eyecontact Maycauseirritationtoeyes.
Skincontact Maycauseskindrynessandirritation.
Ingestion Maycauseirritationtomucousmembranes.
4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded TREATSYMPTOMATICALLY.
Inhalation
Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.
Eyecontact Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.
Skincontact Seekmedicalattentionifirritationorsymptomspersist.
Ingestion Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.
Generalinformation

Generalinformation
Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically. SECTION5:Firefightingmeasures
5.1.Extinguishingmedia
Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.
5.2.Specialhazardsarisingfromthesubstanceormixture
Noneknown.
5.3.Adviceforfirefighters
Furtherinformation
Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.
Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.
6.1.Personalprecautions,protectiveequipmentandemergencyprocedures
6.2.Environmentalprecautions
Wearsuitableprotectiveequipment.
Adviselocalauthoritiesiflargespillscannotbecontained.
6.3.Methodsandmaterialforcontainmentandcleaningup
Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.
6.4.Referencetoothersections
Seesection2,7,8,13forfurtherinformation.
SECTION7:Handlingandstorage
7.1.Precautionsforsafehandling
AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.
7.2.Conditionsforsafestorage,includinganyincompatibilities
Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.
7.3.Specificenduse(s)
Suitablepackaging
FreshLinenAirFreshener.
Plasticcontainers.
SECTION8:Exposurecontrols/personalprotection
8.1.Controlparameters
8.1.1.ExposureLimitValues
Occupationalexposurecontrols.

8.1.1.ExposureLimitValues
Ethanol:EthylAlcohol(Ethanol)
WEL8-hrlimitppm:1000
WEL15minlimitppm:-
WEL8-hrlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: -
WEL8-hrlimitmg/m3:1920
WEL15minlimitmg/m3:-
WEL15minlimitmg/m3total inhalabledust: -
WEL15minlimitmg/m3total respirabledust: -
DNEL:Derivedno-effectlevel.
ExposurePattern-Workers
Ethanol:EthylAlcohol
Long-term-inhalation-Systemic effects 950mg/m³
Long-term-inhalation-Local effects 1900mg/m³
ExposurePattern-Generalpopulation
Ethanol:EthylAlcohol
8.2.Exposurecontrols
8.2.1.Appropriateengineering controls
Long-term-inhalation-Systemic effects 114mg/m³
Long-term-inhalation-Local effects 950mg/m³
Long-term-oral-Systemic effects 87mg/kg


Long-term-dermal-Systemic effects 343mg/kg
Long-term-dermal-Systemic effects 206mg/kg
AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.
Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.
Eye/faceprotection Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields.
SkinprotectionHandprotection Rubbergloves.
Respiratoryprotection Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.
8.2.3.Environmentalexposure controls Preventfurtherleakageorspillageifsafetodoso.
9.1.Informationonbasicphysicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties
AppearanceLiquid ColourClear
OdourPerfumes
OdourthresholdNodataavailable pH6-8
MeltingpointNodataavailable
InitialboilingpointNodataavailable
EvaporationrateNodataavailable Flammability(solid,gas)Nodataavailable VapourpressureNodataavailable
RelativeVapourDensityNodataavailable
Density/RelativeDensity1-1.01
PartitioncoefficientNodataavailable
AutoignitiontemperatureNodataavailable Viscosity<50centipoise
ExplosivepropertiesNodataavailable
OxidisingpropertiesNodataavailable SolubilitySolubleinwater
9.2.Otherinformation
ConductivityNodataavailable SurfacetensionNodataavailable GasgroupNodataavailable BenzeneContentNodataavailable
LeadcontentNodataavailable
VOC(Volatileorganic compounds) Nodataavailable
AtomicnumberNodataavailable MassnumberNodataavailable
ChemicalSymbolNodataavailable PhysicalHalfLifeNodataavailable SpecificActivityNodataavailable ActivityNodataavailable PrincipleEmissionsBetaNodataavailable PrincipleEmissionsGammaNodataavailable PrincipleEmissionsAlphaNodataavailable PrincipleEmissionsNeutronNodataavailable
9.2.1.Informationwithregardtophysicalhazardclasses Nodataavailable.
9.2.2.Othersafetycharacteristics Nodataavailable.

10.4.Conditionstoavoid
10.5.Incompatiblematerials
Protectfromfrost.
Noincompatiblegroupsnoted.
10.6.Hazardousdecompositionproducts
NoHazardousdecompositionproductswhenstoredandhandledcorrectly.
11.1Informationonhazardclasses
Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedfromrawmaterialsupplierLD50andAcuteToxicityEstimates(ATE)asoutlinedinthe Regulation(EC)No.1272/2008(CLP)asamendedbyUKlaw.
Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
Skincorrosion/irritation basedonavailabledatatheclassificationcriteriaarenotmet.
Seriouseyedamage/irritationbasedonavailabledatatheclassificationcriteriaarenotmet.
Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.
Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet.
Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.
Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.
Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet.
Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.
11.1.2.Mixtures
11.1.3.HazardInformation
11.1.4.ToxicologicalInformation
Ethanol:EthylAlcohol
11.2Informationonotherhazards
Nodataavailable.
Nodataavailable.
OralRatLD50:10470.0mg/kg
InhalationRatLC50/4h:>20mg/l
Nodataavailable.
SECTION12:Ecologicalinformation
12.1.Toxicity
Ethanol:EthylAlcohol
12.2.Persistenceanddegradability
12.3.Bioaccumulativepotential
DaphniaEC50/48h:12340.0000mg/l
GreenAlgaeEC50/48h:>100mg/l
RainbowtroutLC50/96h:13000mg/l
NOEC/EC10formarineor freshwaterorganisms 9.6000mg/l
DermalRabbitLD50:15800.0mg/kg
AlgaeEC50/72h:275mg/l
FatheadminnowsLC50/96h:14200mg/l
GoldenorfeLC50/48h:>100mg/l
SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.

12.3.Bioaccumulativepotential
Nodataisavailableonthisproduct. Partitioncoefficient
StoneacreFreshLinenAir Freshener Nodataavailable Ethanol:EthylAlcohol-0.35logP
12.4.Mobilityinsoil
Nodataisavailableonthisproduct.
12.6Endocrinedisruptingproperties
Nodataavailable.
12.7.Otheradverseeffects
Nodataisavailableonthisproduct.
13.1.Wastetreatmentmethods
Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements. Generalinformation
Disposeofincompliancewithalllocalandnationalrequirements. Disposalofpackaging
DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.
14.1.UNnumber
14.2.UNpropershippingname
14.3.Transporthazardclass(es)
14.4.Packinggroup
14.5.Environmentalhazards
14.6.Specialprecautionsforuser
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
14.7MaritimeTransportinbulkaccordingtoIMOinstruments
Theproductisnotclassifiedasdangerousforcarriage.
15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC,

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture 93/105/ECand2000/21/EC.AsretainedandamendedinUKlaw.
COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.Asretainedand amendedinUKlaw.
COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).AsretainedandamendedinUK law.
15.2.Chemicalsafetyassessment
Noinformationavailable.
SECTION16:Otherinformation
Otherinformation
Revision
Datasources
TextofHazardStatementsin Section3
Furtherinformation
Thisdocumentdiffersfromthepreviousversioninthefollowingareas:. 2-SUPPLEMENTALHAZARDINFORMATION. 12-12.1.Toxicity. 16-Datasources.
Keyliteraturereferencesandsourcesfordata:. ECHAClassificationandLabellingInventory(CLI).GBMandatoryClassificationandLabellingList. SupplierSDSsforingredientscontainedinthemixture.
Flam.Liq.2:H225-Highlyflammableliquidandvapour.
EyeIrrit.2:H319-Causesseriouseyeirritation.
SkinIrrit.2:H315-Causesskinirritation.
SkinSens.1:H317-Maycauseanallergicskinreaction.
TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.


accordingtoRegulation(EU)2020/878
SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking
1.1.Productidentifier
Productname AirFreshenerNewCarScent
Productcode QADP1215v3
1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst
ProductUse
[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC3]Aircare products;
[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC3]Aircareproducts;
Description AirFreshenerDropper.
1.3.Detailsofthesupplierofthesafetydatasheet
Company SUPAGARDLIMITED
Address 19-27GavintonStreet Muirend Glasgow G443EF
Web www.supagard.com
Telephone 01416335933
Fax 01416377219
Email James.Smyth@supagard.com
Emailaddressofthe competentperson James.Smyth@supagard.com
1.4.Emergencytelephonenumber
Emergencytelephonenumber01416335933 8.30amto5.00pm
FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)
Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org
SECTION2:Hazardsidentification
2.1.Classificationofthesubstanceormixture
2.1.2.Classification-EC 1272/2008 SkinSens.1:H317;EyeIrrit.2:H319;AquaticChronic2:H411;
2.2.Labelelements

2.2.Labelelements
Hazardpictograms


SignalWord Warning
HazardStatement
SkinSens.1:H317-Maycauseanallergicskinreaction.
EyeIrrit.2:H319-Causesseriouseyeirritation.
AquaticChronic2:H411-Toxictoaquaticlifewithlonglastingeffects.
PrecautionaryStatement: Prevention P102-Keepoutofreachofchildren.
PrecautionaryStatement: Response
SUPPLEMENTALHAZARD INFORMATION
2.3.Otherhazards
Otherhazards
Furtherinformation
P302+P352-IFONSKIN:Washwithplentyofwater/. P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.
P333+P313-Ifskinirritationorrashoccurs:Getmedicaladvice/attention.
P337+P313-Ifeyeirritationpersists:Getmedicaladvice/attention.
Ingredients-Parfum,HexylCinnamal,Limonene,Coumarin,Linalool,Eugenol,Citronellol,Benzyl benzoate.
Contains-Isopropylideneglycerol,Diethylphthalate,4-Tert-ButylcyclohexylAcetate, Dihydromyrcenol,Beta-Caryophyllene,CedrylAcetate,HexylCinnamal,Limonene,Coumarin, 2-T-Butylcyclohexyloxybutanol,LinalylAcetate,Linalool,Eugenol, Trimethyl-Propylcyclohexanepropanol,Beta-Pinenes.
Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.
RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.
SECTION3:Composition/informationoningredients
3.2.Mixtures

3.2.Mixtures
EC1272/2008
ChemicalName IndexNo.
2,2-dimethyl-1,3-dioxolan-4-ylmetha nol
Diethylphthalate
4-tert-Butylcyclohexylacetate
2,6-Dimethyloct-7-en-2-ol
4,11,11-Trimethyl-8-methylenebicyc lo[7.2.0]undec-4-ene
[3R-(3α,3aβ,6α,7β,8aα)] -octahydro-3,6,8,8-tetramethyl-1H-3 a,7-methanoazulen-5-ylacetate
2-Benzylideneoctanal
D-Limonene
2H-Chromen-2-one
1-[(2-tert-butyl)cyclohexyloxy]-2butanol
1,5-Dimethyl-1-vinylhex-4-en-1-yl acetate
3,7-Dimethylocta-1,6-dien-3-ol
4-Allyl-2-methoxyphenol
1-(2,2,6-Trimethylcyclohexyl) -3-hexanol
6,6-Dimethyl-2-methylenebicyclo[3. 1.1]heptane
100-79-8202-888-701-2120066005-66
EyeIrrit.2:H319;10-20%
84-66-2201-550-601-2119486682-2720-30%
32210-23-4250-954-901-2119976286-24
18479-58-8242-362-4
87-44-5201-746-1
77-54-3201-036-1
101-86-0202-983-3
601-029-00-75989-27-5227-813-5
91-64-5202-086-7
139504-68-0412-300-2
115-95-7204-116-401-2119454789-19
78-70-6201-134-401-2119474016-42
97-53-0202-589-1
70788-30-6274-892-7
127-91-3204-872-5
SkinSens.1:H317;10-20%
SkinIrrit.2:H315;EyeIrrit.2: H319; 1-10%
Asp.Tox.1:H304;Skin Sens.1:H317;Aquatic Chronic4:H413; 1-10%
SkinSens.1:H317;Aquatic Chronic1:H410; 1-10%
SkinSens.1:H317;Aquatic Acute1:H400;Aquatic Chronic2:H411; 1-10%
Flam.Liq.3:H226;Asp.Tox. 1:H304;SkinIrrit.2:H315; SkinSens.1:H317;Aquatic Acute1:H400;Aquatic Chronic1:H410; 1-10%
AcuteTox.4:H302;Skin Sens.1:H317;Aquatic Chronic3:H412; 1-10%
EyeIrrit.2:H319;Aquatic Chronic2:H411; 1-10%
SkinIrrit.2:H315;SkinSens. 1:H317;EyeIrrit.2:H319; 0.5-1%
SkinIrrit.2:H315;SkinSens. 1:H317;EyeIrrit.2:H319; 0-0.5%
SkinSens.1:H317;EyeIrrit. 2:H319; 0-0.5%
SkinSens.1:H317;Aquatic Acute1:H400;Aquatic Chronic1:H410; 0-0.5%
Flam.Liq.3:H226;Asp.Tox. 1:H304;SkinIrrit.2:H315; SkinSens.1:H317;Aquatic Chronic1:H410; 0-0.5%
[3R-(3α,3aβ,6α,7β,8aα)]-octahydro-3,6,8,8-tetramethyl-1H-3a,7-methanoazulen-5-ylacetate,CAS No.77-54-3-MFactor(Chronic)=1.
2-Benzylideneoctanal,CASNo.101-86-0-MFactor(Acute)=1.
D-Limonene,CASNo.5989-27-5-MFactor(Acute/Chronic)=1.
1-(2,2,6-Trimethylcyclohexyl)-3-hexanol,CASNo.70788-30-6-MFactor(Acute/Chronic)=1. 6,6-Dimethyl-2-methylenebicyclo[3.1.1]heptane,CASNo.127-91-3-MFactor(Chronic)=1.
2H-Chromen-2-oneATE(Dermal,Rat)-293mg/kg.
2H-Chromen-2-oneATE(Oral,Rat)-500mg/kg.
6,6-Dimethyl-2-methylenebicyclo[3.1.1]heptaneATE(Dermal,Rat)-133848.9mg/kg.
6,6-Dimethyl-2-methylenebicyclo[3.1.1]heptaneATE(Oral,Rat)-37287.23mg/kg.
SECTION4:Firstaidmeasures
4.1.Descriptionoffirstaidmeasures
Inhalation Movetheexposedpersontofreshair. Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved. Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution. Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.
4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed Inhalation Maycauseirritationtorespiratorysystem.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed Eyecontact Causesseriouseyeirritation.
Skincontact Maycauseanallergicskinreaction.
Ingestion Maycauseirritationtomucousmembranes.
4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded
Inhalation Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.
Eyecontact Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.
Skincontact Seekmedicalattentionifirritationorsymptomspersist.
Ingestion Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.
Generalinformation
Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.
5.1.Extinguishingmedia
Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.
5.2.Specialhazardsarisingfromthesubstanceormixture
Noneknown.
5.3.Adviceforfirefighters
Furtherinformation
Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.
Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.
6.1.Personalprecautions,protectiveequipmentandemergencyprocedures
6.2.Environmentalprecautions
Wearsuitableprotectiveequipment.
Adviselocalauthoritiesiflargespillscannotbecontained.
6.3.Methodsandmaterialforcontainmentandcleaningup
Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.
6.4.Referencetoothersections
Seesection2,7,8,13forfurtherinformation.
7.1.Precautionsforsafehandling
AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.
7.2.Conditionsforsafestorage,includinganyincompatibilities
Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.
7.3.Specificenduse(s)
AirFreshenerDropper.

Suitablepackaging
Plasticcontainers.
8.1.Controlparameters
8.1.1.ExposureLimitValues
1-
(3-Methoxypropoxy)propan-1-ol ((2-methoxymethylethoxy) propanol)
6,6-Dimethyl-2-methylenebicyclo [3.1.1]heptane
Occupationalexposurecontrols.
WEL8-hrlimitppm:50
WEL15minlimitppm:-
WEL8-hrlimitmg/m3:308
WEL15minlimitmg/m3:-
WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -
WEL8-hrlimitppm:25
WEL15minlimitppm:50
Diethylphthalate
DNEL:Derivedno-effectlevel.
ExposurePattern-Workers
1(3-Methoxypropoxy)propan-1-ol
WEL8-hrlimitmg/m3:140
WEL15minlimitmg/m3:300
WEL8-hrlimitmg/m3total inhalabledust: WEL15minlimitmg/m3total inhalabledust:
WEL8-hrlimitmg/m3total respirabledust: WEL15minlimitmg/m3total respirabledust:
WEL8-hrlimitppm:-
WEL15minlimitppm:-
WEL8-hrlimitmg/m3:5
WEL15minlimitmg/m3:10
WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -
Long-term-inhalation-Systemic effects 308mg/kg
Long-term-dermal-Systemic effects 283mg/kg
ExposurePattern-Generalpopulation
1(3-Methoxypropoxy)propan-1-ol
Long-term-inhalation-Systemic effects 37.2mg/m³
Long-term-dermal-Systemic effects 121mg/kg


Long-term-oral-Systemiceffects36mg/kg
8.2.Exposurecontrols AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.

8.2.Exposurecontrols
8.2.1.Appropriateengineering controls
Eye/faceprotection
SkinprotectionHandprotection
Respiratoryprotection
Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.
Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields. Eyewearcomplyingwithanapprovedstandardshouldbewornifariskassessmentindicateseye contactispossible.Thefollowingprotectionshouldbeworn:Wearchemicalsplashgoggles. PersonalprotectiveequipmentforeyeandfaceprotectionshouldcomplywithEuropeanStandard EN166.
Rubbergloves.Chooseglovestoprotecthandsagainstchemicalsdependingontheconcentration andquantityofthehazardoussubstanceandspecifictoplaceofwork.Forspecialapplications, werecommendclarifyingtheresistancetochemicalsoftheaforementionedprotectivegloveswith theglovemanufacturer.
Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.
8.2.3.Environmentalexposure controls Preventfurtherleakageorspillageifsafetodoso.
9.1.Informationonbasicphysicalandchemicalproperties
AppearanceLiquid ColourClear OdourPerfumes
OdourthresholdNodataavailable pHNodataavailable MeltingpointNodataavailable
InitialboilingpointNodataavailable EvaporationrateNodataavailable Flammability(solid,gas)Nodataavailable VapourpressureNodataavailable RelativeVapourDensityNodataavailable Density/RelativeDensityNodataavailable PartitioncoefficientNodataavailable AutoignitiontemperatureNodataavailable ViscosityNodataavailable
ExplosivepropertiesNodataavailable OxidisingpropertiesNodataavailable SolubilityInsolubleinwater
9.2.Otherinformation
ConductivityNodataavailable SurfacetensionNodataavailable GasgroupNodataavailable BenzeneContentNodataavailable
LeadcontentNodataavailable VOC(Volatileorganic compounds) Nodataavailable
9.2.1.Informationwithregardtophysicalhazardclasses Nodataavailable.
9.2.2.Othersafetycharacteristics Nodataavailable.

10.1.Reactivity
10.2.Chemicalstability
Stableundernormalconditions.
Stableundernormalconditions.
10.3.Possibilityofhazardousreactions
Nodataisavailableonthisproduct.
10.4.Conditionstoavoid
10.5.Incompatiblematerials
Noneknown.
Strongacids.Strongoxidisingagents.
10.6.Hazardousdecompositionproducts
NoHazardousdecompositionproductswhenstoredandhandledcorrectly.
11.1Informationonhazardclasses
Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedusingthemethodsoutlinedinRegulation(EC)No1272/2008(CLP).
Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet. OralATE=>10,000mg/kg.
Inhalation-Dust/MistATE=>20mg/l.
Skincorrosion/irritation basedonavailabledatatheclassificationcriteriaarenotmet.
Seriouseyedamage/irritationEyeIrrit.2:H319-Causesseriouseyeirritation.
Respiratoryorskin sensitisation
SkinSens.1:H317-Maycauseanallergicskinreaction.
Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet.
Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.
Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.
Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet.
Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.
11.1.2.Mixtures
11.1.3.HazardInformation
11.1.4.ToxicologicalInformation
1(3-Methoxypropoxy)propan-1-ol
2,2-dimethyl-1,3-dioxolan-4-ylme thanol
2H-Chromen-2-one
6,6-Dimethyl-2-methylenebicyclo [3.1.1]heptane
Nodataavailable.
Nodataavailable.
OralRatLD50:5000.0
InhalationRatLC50/4h:3.35
DermalRatLD50:>2000mg/kg
InhalationRatLC50/4h:>5.11mg/l
DermalRatLD50:293mg/kg
DermalRatLD50:133848.9mg/kg

DermalRabbitLD50:9510.0
OralRatLD50:7000mg/kg
OralRatLD50:500mg/kg
OralRatLD50:37287.23mg/kg
11.2Informationonotherhazards
Nodataavailable.
12.1.Toxicity
1(3-Methoxypropoxy)propan-1-ol
2,2-dimethyl-1,3-dioxolan-4-ylme thanol
12.2.Persistenceanddegradability
12.3.Bioaccumulativepotential
Partitioncoefficient
12.4.Mobilityinsoil
DaphniaEC50/48h:1919.0000mg/l
AlgaeEC50/72h:6999
NOEC/EC10formarineor freshwaterorganisms 0.5mg/l
DaphniaEC50/48h:96.0000mg/l
FatheadminnowsLC50/96h:16.7mg/l
FishLC50/96h:10000.0000mg/l
AlgaeEC50/72h:>92mg/l
SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.
Nodataisavailableonthisproduct.
AirFreshenerNewCarScentNodataavailable1-(3-Methoxypropoxy)propan-1-ol1.01
Nodataisavailableonthisproduct.
12.5.ResultsofPBTandvPvBassessment
Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.
12.6Endocrinedisruptingproperties
Thesubstance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.
12.7.Otheradverseeffects
Nodataisavailableonthisproduct.
13.1.Wastetreatmentmethods
Generalinformation
Disposalofpackaging
Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.
Disposeofincompliancewithalllocalandnationalrequirements.
DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.
SECTION14:Transportinformation
Hazardpictograms


14.1.UNnumber

14.1.UNnumber UN3082
14.2.UNpropershippingname ENVIRONMENTALLYHAZARDOUSSUBSTANCE,LIQUID,N.O.S.(Contains 4-tert-Butylcyclohexylacetate)
14.3.Transporthazardclass(es)
ADR/RID 9
SubsidiaryriskIMDG 9
SubsidiaryriskIATA 9
Subsidiaryrisk -
14.4.Packinggroup
Packinggroup III
14.5.Environmentalhazards
Environmentalhazards Yes
Marinepollutant Yes
14.6.Specialprecautionsforuser Noadditionalspecialprecautions.
14.7MaritimeTransportinbulkaccordingtoIMOinstruments Notapplicable.
ADR/RID
HazardID 90
TunnelCategory (E)
IMDG
EmSCode F-AS-F
IATA
PackingInstruction(Cargo)964
Maximumquantity 450L
PackingInstruction (Passenger) 964
Maximumquantity 450L
SECTION15:Regulatoryinformation
15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.
COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture
COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).
15.2.Chemicalsafetyassessment
Noinformationavailable.
SECTION16:Otherinformation
Otherinformation
Datasources ClassificationandProcedureusedtoderivetheclassificationformixturesaccordingtoRegulation (EC)No.1272/2008,asretainedandamendedinUKlaw.
SkinSens.1:H317-Maycauseanallergicskinreaction.-CalculationMethod.
EyeIrrit.2:H319-Causesseriouseyeirritation.-CalculationMethod.
AquaticChronic2:H411-Toxictoaquaticlifewithlonglastingeffects.-CalculationMethod.
TextofHazardStatementsin
Section3
Furtherinformation
EyeIrrit.2:H319-Causesseriouseyeirritation.
SkinSens.1:H317-Maycauseanallergicskinreaction.
SkinIrrit.2:H315-Causesskinirritation.
Asp.Tox.1:H304-Maybefatalifswallowedandentersairways.
AquaticChronic4:H413-Maycauselonglastingharmfuleffectstoaquaticlife.
AquaticChronic1:H410-Verytoxictoaquaticlifewithlonglastingeffects.
AquaticAcute1:H400-Verytoxictoaquaticlife.
AquaticChronic2:H411-Toxictoaquaticlifewithlonglastingeffects.
Flam.Liq.3:H226-Flammableliquidandvapour.
AcuteTox.4:H302-Harmfulifswallowed.
AquaticChronic3:H412-Harmfultoaquaticlifewithlonglastingeffects.
TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.



according to Regulation (EU) 2020/878
SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking
1.1.Productidentifier
Productname Concentrated Wheel Cleaner
1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst
ProductUse [SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC35]Washingandcleaningproducts(includingsolventbasedproducts); Description VehicleWheelCleaner.
1.3.Detailsofthesupplierofthesafetydatasheet
Company SUPAGARDLIMITED
Address 19-27GavintonStreet Muirend Glasgow G443EF
Web www.supagard.com
Telephone 01416335933
Fax 01416377219
Email James.Smyth@supagard.com
Emailaddressofthe competentperson James.Smyth@supagard.com
1.4.Emergencytelephonenumber
Emergencytelephonenumber01416335933 8.30amto5.00pm
FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)
Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org
SECTION2:Hazardsidentification
2.1.Classificationofthesubstanceormixture
2.1.2.Classification-EC 1272/2008 SkinCorr.1A:H314;
2.2.Labelelements
Hazardpictograms

SignalWord Danger
HazardStatement SkinCorr.1A:H314-Causessevereskinburnsandeyedamage.

2.2.Labelelements
PrecautionaryStatement: Prevention P280-Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection.
PrecautionaryStatement: Response
P303+P361+P353-IFONSKIN(orhair):Takeoffimmediatelyallcontaminatedclothing.Rinse skinwithwater/shower.
P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.
PrecautionaryStatement: Storage P405-Storelockedup.
PrecautionaryStatement: Disposal
SUPPLEMENTALHAZARD INFORMATION
P501-Disposeofcontents/containertoanapproveddisposalsite,inaccordancewithlocal regulations.
IngredientsasrequiredbyRegulation(EC)No648/2004:. SodiumHydroxide,5-15%AmphotericSurfactants.
Contains-1-Propanaminium,3-amino-N-(carboxymethyl)-N-N-dimethyl-N-C8-C18(even numbered)acylderivs,hydroxides,innersalts,sodiumhydroxide,2-butoxyethanol.
2.3.Otherhazards
Otherhazards Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.
Furtherinformation
RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.
SECTION3:Composition/informationoningredients
3.2.Mixtures
EC1272/2008
ChemicalName IndexNo.CASNo.ECNo.
1-Propanaminium,3-amino-N(carboxymethyl) -N,N-dimethyl-,N-C8-C18(even numbered)acylderivs.,hydroxides, innersalts
SodiumHydroxide
97862-59-4931-296-801-2119488533-30
EyeDam.1:H318;Aquatic Chronic3:H412; 1-10%
1310-73-2215-185-501-2119457892-27
Met.Corr.1:H290;SkinCorr. 1A:H314; 10-20% 2-butoxyethanol
603-014-00-0111-76-2203-905-001-2119475108-36
SECTION4:Firstaidmeasures
4.1.Descriptionoffirstaidmeasures
Inhalation Movetheexposedpersontofreshair.
AcuteTox.4:H332;Acute Tox.4:H312;AcuteTox.4: H302;EyeIrrit.2:H319;Skin Irrit.2:H315; 1-10%
Eyecontact Rinseimmediatelywithplentyofwaterfor15minutesholdingtheeyelidsopen.Contactlenses shouldberemoved.
Skincontact
Removecontaminatedclothing.Washoffimmediatelywithplentyofsoapandwater.
Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.Drinkplentyofwatertodiluteingested product.
4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed
Inhalation Causesburns.
Eyecontact Causesburns.Riskofseriousdamagetoeyes.
Skincontact Causesburns.
Ingestion Causesburns.
4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded
Inhalation
Eyecontact
Skincontact
Ingestion
Generalinformation
Movetheexposedpersontofreshair.Incaseofaccidentorifyoufeelunwell,seekmedical adviceimmediately(showthelabelwherepossible).Seekmedicalattention.Showthissafetydata sheettothedoctorinattendance.
Rinseimmediatelywithplentyofwaterfor15minutesholdingtheeyelidsopen.Contactlenses shouldberemoved.Seekmedicalattention.Showthissafetydatasheettothedoctorin attendance.
Removecontaminatedclothingimmediately.Rinseimmediatelywithplentyofwater.Seekmedical attention.Showthissafetydatasheettothedoctorinattendance.
Drink1to2glassesofwater.Seekmedicalattention.Showthissafetydatasheettothedoctorin attendance.
Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.
5.1.Extinguishingmedia
Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.
5.2.Specialhazardsarisingfromthesubstanceormixture
Burningproducesirritating,toxicandobnoxiousfumes.
5.3.Adviceforfirefighters
Furtherinformation
Wearsuitablerespiratoryequipmentwhennecessary.Firefightersshouldwearselfcontained positivepressurebreathingapparatus(SCBA)andfullturnoutgear.
Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.
6.1.Personalprecautions,protectiveequipmentandemergencyprocedures
6.2.Environmentalprecautions
Wearsuitableprotectiveequipment.
Adviselocalauthoritiesiflargespillscannotbecontained.
6.3.Methodsandmaterialforcontainmentandcleaningup
Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.
6.4.Referencetoothersections
Seesection2,7,8,13forfurtherinformation.
7.1.Precautionsforsafehandling
Avoidcontactwitheyesandskin.Donotbreathevapoursorspraymist.AdoptbestManual Handlingconsiderationswhenhandling,carryinganddispensing.
7.2.Conditionsforsafestorage,includinganyincompatibilities
Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.
7.3.Specificenduse(s)
VehicleWheelCleaner.

Suitablepackaging
Plasticcontainers.
8.1.Controlparameters
8.1.1.ExposureLimitValues
2-butoxyethanol
SodiumHydroxide
Occupationalexposurecontrols.
WEL8-hrlimitppm:25
WEL15minlimitppm:50
WEL8-hrlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3:123
WEL15minlimitmg/m3:101.2
WEL15minlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -
WEL8-hrlimitppm:-
WEL8-hrlimitmg/m3:WEL15minlimitppm:- WEL15minlimitmg/m3:2
WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -
DNEL:Derivedno-effectlevel.
ExposurePattern-Workers
2-butoxyethanol
SodiumHydroxide
Acuteinhalation-Systemic effects 1091mg/m³
Acuteinhalation-Localeffects246mg/m³
Long-term-inhalation-Systemic effects 98mg/m³
Acuteinhalation-Localeffects2mg/m³
Acutedermal-Localeffects2mg/m³
ExposurePattern-Generalpopulation
2-butoxyethanol
SodiumHydroxide
8.2.Exposurecontrols
Acuteinhalation-Systemic effects 426mg/m³
Acutedermal-Systemiceffects89mg/kg
Long-term-inhalation-Systemic effects 59mg/m³
Long-term-dermal-Systemic effects 75mg/kg
Long-term-inhalation-Local effects 1mg/m³



Acutedermal-Systemiceffects89mg/kg
Long-term-dermal-Systemic effects 125mg/kg
Long-term-inhalation-Local effects 1mg/m³
Acuteoral-Systemiceffects26.7mg/kg
Long-term-inhalation-Local effects 147mg/m³
Long-term-oral-Systemiceffects6.3mg/kg
8.2.Exposurecontrols
8.2.1.Appropriateengineering controls
Eye/faceprotection
SkinprotectionHandprotection
Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.
Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields. Eyewearcomplyingwithanapprovedstandardshouldbewornifariskassessmentindicateseye contactispossible.Thefollowingprotectionshouldbeworn:Wearchemicalsplashgoggles. PersonalprotectiveequipmentforeyeandfaceprotectionshouldcomplywithEuropeanStandard EN166.
Rubbergloves.Chooseglovestoprotecthandsagainstchemicalsdependingontheconcentration andquantityofthehazardoussubstanceandspecifictoplaceofwork.Forspecialapplications, werecommendclarifyingtheresistancetochemicalsoftheaforementionedprotectivegloveswith theglovemanufacturer.
Skinprotection-Other Wearsuitableprotectiveclothing.
Respiratoryprotection Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.
8.2.3.Environmentalexposure controls
Preventfurtherleakageorspillageifsafetodoso.
9.1.Informationonbasicphysicalandchemicalproperties
AppearanceLiquid ColourClear OdourNodataavailable OdourthresholdNodataavailable pH>11.5
MeltingpointNodataavailable InitialboilingpointNodataavailable FlashpointNodataavailable EvaporationrateNodataavailable Flammability(solid,gas)Nodataavailable VapourpressureNodataavailable RelativeVapourDensityNodataavailable Density/RelativeDensity1.008-1.15
PartitioncoefficientNodataavailable AutoignitiontemperatureNotapplicable. Viscosity<75centipoise ExplosivepropertiesNodataavailable OxidisingpropertiesNodataavailable SolubilitySolubleinwater
9.2.Otherinformation
ConductivityNodataavailable SurfacetensionNodataavailable GasgroupNodataavailable BenzeneContentNodataavailable LeadcontentNodataavailable VOC(Volatileorganic compounds) Nodataavailable
9.2.1.Informationwithregardtophysicalhazardclasses Nodataisavailableonthisproduct.
9.2.2.Othersafetycharacteristics

9.2.2.Othersafetycharacteristics
Nodataisavailableonthisproduct.
SECTION10:Stabilityandreactivity
10.1.Reactivity
10.2.Chemicalstability
Stableundernormalconditions.
Stableundernormalconditions.
10.3.Possibilityofhazardousreactions
Strongacids.Strongoxidisingagents.
10.4.Conditionstoavoid
10.5.Incompatiblematerials
Protectfromfrost.AvoidstoringindirectSunLight.
Strongacids.Strongoxidisingagents.
10.6.Hazardousdecompositionproducts
NoHazardousdecompositionproductswhenstoredandhandledcorrectly.
SECTION11:Toxicologicalinformation
11.1Informationonhazardclasses
Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedusingthemethodsoutlinedinRegulation(EC)No1272/2008(CLP).
Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
OralATE=>10,000mg/kg.
DermalATE=>10,000mg/kg.
Inhalation-Dust/MistATE=275mg/l.
Skincorrosion/irritation SkinCorr.1A:H314-Causessevereskinburnsandeyedamage.ExtremepH-≥11.5.
Seriouseyedamage/irritationCausesseriouseyedamage.
Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.
Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet. Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.
Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.
Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet.
Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.
11.1.2.Mixtures
11.1.3.HazardInformation
11.1.4.ToxicologicalInformation
2-butoxyethanol
SodiumHydroxide
Nodataavailable.
Nodataavailable.
InhalationRatLC50/1h:>3.1mg/l
OralRatLD50:1200mg/kg
OralRatLD50:>500mg/kg (Rabbit)

DermalRatLD50:>2000mg/kg
InhalationRatLC50/4h:11.0mg/l (vapours)
11.2Informationonotherhazards
Nodataisavailableonthisproduct.
12.1.Toxicity
2-butoxyethanol
12.2.Persistenceanddegradability
12.3.Bioaccumulativepotential
Partitioncoefficient
12.4.Mobilityinsoil
DaphniaEC50/48h:1550.0000mg/l
RainbowtroutLC50/96h:1474mg/l
DaphniaEC50/48h:40.4000mg/l
RainbowtroutLC50/96h:45.5mg/l
AlgaeEC50/72h:1840mg/
FishLC50/96h:33.0000mg/l
BluegillsunfishLC50/96h:125mg/l
SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.
Theproductisnotbioaccumulating.
StoneacreConcentratedWheel Cleaner Nodataavailable SodiumHydroxideNodataavailable 2-butoxyethanol0.81logP
Thisproductissolubleinwater.
12.5.ResultsofPBTandvPvBassessment
Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.
12.6Endocrinedisruptingproperties
Nodataisavailableonthisproduct.
12.7.Otheradverseeffects
Nodataisavailableonthisproduct.
13.1.Wastetreatmentmethods
Generalinformation
Disposalofpackaging
Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.
Disposeofincompliancewithalllocalandnationalrequirements.
DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.
Hazardpictograms


14.1.UNnumber
14.2.UNpropershippingname
14.3.Transporthazardclass(es)
UN1760
CORROSIVELIQUID,N.O.S.(ContainsSodiumHydroxide)
ADR/RID 8
SubsidiaryriskIMDG 8
SubsidiaryriskIATA 8
Subsidiaryrisk -
14.4.Packinggroup
Packinggroup II
14.5.Environmentalhazards
Environmentalhazards No Marinepollutant No
14.6.Specialprecautionsforuser Noadditionalspecialprecautions.
14.7MaritimeTransportinbulkaccordingtoIMOinstruments Notapplicable.
ADR/RID
HazardID 80
TunnelCategory (E)
IMDG
EmSCode F-AS-B
IATA
PackingInstruction(Cargo)855
Maximumquantity 30L
PackingInstruction (Passenger) 851
Maximumquantity 1L
15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.
COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture
COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).
15.2.Chemicalsafetyassessment
Noinformationavailable.
Otherinformation
Revision
Thisdocumentdiffersfromthepreviousversioninthefollowingareas:.
9-9.1.Informationonbasicphysicalandchemicalproperties(Density/RelativeDensity). 9-9.1.Informationonbasicphysicalandchemicalproperties(Viscosity).
Datasources ClassificationandProcedureusedtoderivetheclassificationformixturesaccordingtoRegulation (EC)No.1272/2008,asretainedandamendedinUKlaw.
TextofHazardStatementsin
Section3
Furtherinformation
SkinCorr.1A:H314-Causessevereskinburnsandeyedamage.-ExtremepH-≥11.5.
EyeDam.1:H318-Causesseriouseyedamage.
AquaticChronic3:H412-Harmfultoaquaticlifewithlonglastingeffects.
Met.Corr.1:H290-Maybecorrosivetometals.
SkinCorr.1A:H314-Causessevereskinburnsandeyedamage.
AcuteTox.4:H302+H312+H332-Harmfulifswallowed,incontactwithskinorifinhaled
SkinIrrit.2:H315-Causesskinirritation.
EyeIrrit.2:H319-Causesseriouseyeirritation.
TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.



SAFETY DATASHEET
AIR CON SANITISER LINEN Page: 1
Section 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name: AIR CON SANITISER LINEN
Product code: HC8523
Synonyms: PD1000
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of substance / mixture: Aerosol air freshener.
1.3. Details of the supplier of the safetydata sheet
Companyname: SUPAGARD LIMITED
23 Gavinton Street
Muirend Glasgow Scotland G44 3EF
Tel: 0141 633 5933
Email: james@supagard.co.uk
1.4. Emergencytelephone number
Emergencytel: 0141 633 5933 (office hours only)
Section 2: Hazards identification
2.1. Classification of the substance or mixture
Classification under CLP: Flam. Aerosol 1: H222; -: H229
Compilation date: 28/02/2024
Revision No: 1
Most important adverse effects: Extremely flammable aerosol. Pressurised container: May burst if heated.
2.2. Label elements
Label elements:
Hazard statements: H222: Extremely flammable aerosol.
H229: Pressurised container: May burst if heated.
Hazard pictograms: GHS02: Flame

Signal words: Danger
Precautionarystatements: P102: Keep out of reach of children. P261: Avoid breathing spray.
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P211: Do not spray on an open flame or other ignition source.
P251: Do not pierce or burn, even after use.
P410+P412: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Haz. ingredients (label): Contains: LIQUIFIED PETROLEUMGAS PROPELLANT
2.3. Other hazards
Other hazards: In use, may form flammable / explosive vapour-air mixture. Contains no PBT/vPvB substances >/= 0.1% assessed in accordance with REACH AnnexXIII. This mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine distrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0.1%.
PBT: This product is not identified as a PBT/vPvB substance.
Section 3: Composition/information on ingredients
3.2. Mixtures
Hazardous ingredients:
ETHANOL - REACH registered number(s): 01-2119457610-43-XXXX
64-17-5 Substance with a Community workplace exposure limit.
Liq. 2: H225
<0.1% 1,3 BUTADIENE - REACH registered number(s): 01-2119474691-32-XXXX 203-448-7 106-97-8 Substance with a Community workplace exposure limit. Flam. Gas 1: H220; Press. Gas: H280 10-30% PROPANE, <0.1% 1,3 BUTADIENE - REACH registered number(s): 01-2119486944-21-XXXX
200-827-9 74-98-6
Substance with a Community workplace exposure limit. Flam. Gas 1: H220; Press. Gas: H280 10-30%
N-(3-AMINOPROPYL)-N-DODECYLPROPANE-1,3,DIAMINE - REACH registered number(s): 01-2119980592-29
219-145-8
2372-82-9 -
Section 4: First aid measures
4.1. Description of first aid measures
Acute Tox. 3: H301; Skin Corr. 1B: H314; Eye Dam. 1: H318; STOT RE 2: H373; Aquatic Acute 1: H400; Aquatic Chronic 1: H410
Skin contact: Wash immediately with plenty of soap and water.
Eye contact: Bathe the eye with running water for 15 minutes.
Ingestion: Wash out mouth with water.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so.
4.2. Most important symptoms and effects, both acute and delayed
Skin contact: There may be mild irritation at the site of contact.
Eye contact: There may be irritation and redness.
Ingestion: There may be irritation of the throat.
Inhalation: No symptoms.
4.3. Indication of anyimmediate medical attention and special treatment needed
Immediate / special treatment: Not applicable.
Section 5: Fire-fighting measures
5.1. Extinguishing media
Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers.
5.2. Special hazards arising from the substance or mixture
Exposure hazards: In combustion emits toxic fumes.
5.3. Advice for fire-fighters
Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.
Section 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergencyprocedures
Personal precautions: Refer to section 8 of SDS for personal protection details. Turn leaking containers leakside up to prevent the escape of liquid.
6.2. Environmental precautions
Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.
6.3. Methods and material for containment and cleaning up
Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method.
6.4. Reference to other sections
Reference to other sections: Refer to section 8 of SDS.
Section 7: Handling and storage
7.1. Precautions for safe handling
Handling requirements: Smoking is forbidden. Use non-sparking tools. Ensure there is sufficient ventilation of the area. Do not handle in a confined space.
7.2. Conditions for safe storage, including anyincompatibilities
Storage conditions: Store in a cool, well ventilated area. Keep container tightly closed.
7.3. Specific end use(s)
Specific end use(s): No data available.
Section 8: Exposure controls/personal protection
8.1. Control parameters
Hazardous ingredients:
DNEL/PNEC Values
Hazardous ingredients:
DNEL Dermal 0.54mg/kg bw/day
Consumers Systemic
DNEL Oral 0.2mg/kg bw/day Consumers Systemic
PNEC Fresh water 0.001mg/L - -
PNEC Marine water 0.0001mg/L
PNEC Fresh water sediments 8.5mg/kg dry weight
PNEC Marine sediments 0.85mg/kg dry weight
PNEC Soil (agricultural) 45.34mg/kg dry weigh
PNEC Microorganisms in sewage treatment 1.33mg/L
8.2. Exposure controls
Engineering measures: Ensure there is sufficient ventilation of the area. Ensure lighting and electrical equipment are not a source of ignition.
Respiratoryprotection: Respiratory protection not required.
Hand protection: Protective gloves.
Eye protection: Safety glasses. Ensure eye bath is to hand.
Skin protection: Protective clothing.
Section 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
State: Aerosol
Colour: Colourless
Odour: Perfumed
Evaporation rate: Fast
Solubilityin water: Soluble
Viscosity: Non-viscous
Boiling point/range°C: No data available.
Melting point/range°C: No data available.
Flammabilitylimits %:lower: 0.9 upper: 9.0
Flash point°C: -40
Autoflammability°C: >230
Relative density: No data available.
VOC g/l: No data available.
9.2. Other information
Other information: No data available.
Section 10: Stabilityand reactivity
10.1. Reactivity
Part.coeff. n-octanol/water: Not applicable.
Vapour pressure: No data available.
pH: Not applicable.
Reactivity: Stable under recommended transport or storage conditions.
10.2. Chemical stability
Chemical stability: Stable under normal conditions.
10.3. Possibilityof hazardous reactions
Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions. Decomposition may occur on exposure to conditions or materials listed below.
10.4. Conditions to avoid
Conditions to avoid: Heat.
10.5. Incompatible materials
Materials to avoid: Strong oxidising agents. Strong acids.
10.6. Hazardous decomposition products
Haz. decomp. products: In combustion emits toxic fumes.
Section 11: Toxicological information
11.1. Information on toxicological effects
Hazardous ingredients:
Toxicityvalues: No data available.
Symptoms / routes of exposure
Skin contact: There may be mild irritation at the site of contact.
Eye contact: There may be irritation and redness.
Ingestion: There may be irritation of the throat.
Inhalation: No symptoms.
Section 12: Ecological information
12.1. Toxicity
Hazardous ingredients:
N-(3-AMINOPROPYL)-N-DODECYLPROPANE-1,3,DIAMINE
Daphnia magna
GREEN ALGA (Selenastrum capricornutum)
ZEBRAFISH (Brachydanio rerio)
12.2. Persistence and degradability
Persistence and degradability: Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential: No bioaccumulation potential.
12.4. Mobilityin soil
Mobility: Readily absorbed into soil.
12.5. Results of PBT and vPvB assessment
EC50
ErC50
LC50
mg/l
mg/l
PBT identification: This product is not identified as a PBT/vPvB substance.
12.6. Other adverse effects
Other adverse effects: Negligible ecotoxicity.
Section 13: Disposal considerations
13.1. Waste treatment methods
Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.
Recoveryoperations: Recycling/reclamation of metals and metal compounds.
Waste code number: 16 05 05
Disposal of packaging: Dispose of as normal industrial waste. Empty cans must not be burned because of explosion hazard.
NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.
Section 14: Transport information
14.1. UN number
UN number: UN1950
14.2. UN proper shipping name
Shipping name: AEROSOLS
14.3. Transport hazard class(es)
Transport class: 2
14.4. Packing group
14.5. Environmental hazards
Environmentallyhazardous: No
14.6. Special precautions for user
CON SANITISER LINEN
Special precautions: No special precautions.
Tunnel code: D
Transport category: 2
Section 15: Regulatoryinformation
Marine pollutant: No
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Specific regulations: This product is not, nor does it contain a persistant organic pollutant (POP) according to Regulation (EC) 2019/1021 and subsequent revisions. This product is not, nor does it contain any candidate on the REACH SVHC list acording to Regulation (EC) 2006/1907 and subsequent revisions. This product is not, nor does it contain, any candidate on the Endocrine Disruptor list, and any subsequent revisions, classified for human health cat 2 or environmental cat 2, in accordance with EC1272/2008 (ammended 2022)
15.2. Chemical SafetyAssessment
Chemical safetyassessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.
Section 16: Other information
Other information
Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 2015/830.
All substances in this preparation are registered within UK/EU/EFTA countries under the REACH (UK/EC) (ammended) regulations, EC 1907/2006
*indicates text in the SDS which has changed since the last revision.
Phrases used in s.2 and s.3: H220: Extremely flammable gas.
H222: Extremely flammable aerosol.
H225: Highly flammable liquid and vapour.
H229: Pressurised container: May burst if heated.
H301: Toxic if swallowed.
H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
H373: May cause damage to organs through prolonged or repeated exposure.
H400: Very toxic to aquatic life.
H410: Very toxic to aquatic life with long lasting effects.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.


according to Regulation (EU) 2020/878
SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking
1.1.Productidentifier
Productname Aqua Free Enhancer
1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst
ProductUse
[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC35]Washingandcleaningproducts(includingsolventbasedproducts);
[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC35]Washingand cleaningproducts(includingsolventbasedproducts);
Description Nowaterorshampoorequired.Thisactiveblendofcrosslinkingpolymerscreatesabarriertohelp preventbuild-upoftrafficfilm.Theformulationhasbeenspeciallydevelopedtocreatelubricity, coatingparticlesofdirtandtrappingthemwithinthemicrofibrecloth,whilstleavingahighgloss finish.
1.3.Detailsofthesupplierofthesafetydatasheet
Company SUPAGARDLIMITED
Address 19-27GavintonStreet Muirend Glasgow G443EF
Web www.supagard.com
Telephone 01416335933
Fax 01416377219
Email James.Smyth@supagard.com
Emailaddressofthe competentperson James.Smyth@supagard.com
1.4.Emergencytelephonenumber
Emergencytelephonenumber01416335933
8.30amto5.00pm
FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)
Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org
SECTION2:Hazardsidentification
2.1.Classificationofthesubstanceormixture
2.1.2.Classification-EC 1272/2008 Thisproductdoesnotmeetthecriteriaforclassificationinanyhazardclassaccordingto Regulation(EC)No.1272/2008onclassification,labellingandpackagingofsubstancesand mixtures.
2.2.Labelelements

2.2.Labelelements
PrecautionaryStatement: Response P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.
P337+P313-Ifeyeirritationpersists:Getmedicaladvice/attention.
HazardStatement NoSignificantHazard
SUPPLEMENTALHAZARD INFORMATION Ingredients-Parfum. Contains-DenaturedAlcohol.
2.3.Otherhazards
Otherhazards
Furtherinformation
Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.
RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.
3.2.Mixtures
EC1272/2008
ChemicalName
Ethanol:EthylAlcohol(Ethanol) 64-17-5200-578-601-2119457610-43
SECTION4:Firstaidmeasures
4.1.Descriptionoffirstaidmeasures
Inhalation
Movetheexposedpersontofreshair.
Flam.Liq.2:H225;EyeIrrit. 2:H319; 1-10%
Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved.
Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution.
Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.
4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed
Inhalation Maycauseirritationtorespiratorysystem.
Eyecontact Maycauseirritationtoeyes.
Skincontact Maycauseskindrynessandirritation.
Ingestion Maycauseirritationtomucousmembranes.
4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded TREATSYMPTOMATICALLY.
Inhalation
Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.
Eyecontact Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.
Skincontact Seekmedicalattentionifirritationorsymptomspersist.
Ingestion Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.
Generalinformation
Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.
5.1.Extinguishingmedia
Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.
5.2.Specialhazardsarisingfromthesubstanceormixture Noneknown.

5.3.Adviceforfirefighters
Furtherinformation
Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.
Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.
6.1.Personalprecautions,protectiveequipmentandemergencyprocedures
6.2.Environmentalprecautions
Wearsuitableprotectiveequipment.
Adviselocalauthoritiesiflargespillscannotbecontained.
6.3.Methodsandmaterialforcontainmentandcleaningup
Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.
6.4.Referencetoothersections
Seesection2,7,8,13forfurtherinformation.
7.1.Precautionsforsafehandling
AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.
7.2.Conditionsforsafestorage,includinganyincompatibilities
Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.
7.3.Specificenduse(s)
Suitablepackaging
Nowaterorshampoorequired.Thisactiveblendofcrosslinkingpolymerscreatesabarriertohelp preventbuild-upoftrafficfilm.Theformulationhasbeenspeciallydevelopedtocreatelubricity, coatingparticlesofdirtandtrappingthemwithinthemicrofibrecloth,whilstleavingahighgloss finish.
Plasticcontainers.
8.1.Controlparameters
8.1.1.ExposureLimitValues
Ethanol:EthylAlcohol(Ethanol)
DNEL:Derivedno-effectlevel.
ExposurePattern-Workers
Occupationalexposurecontrols.
WEL8-hrlimitppm:1000
WEL8-hrlimitmg/m3:1920
WEL15minlimitppm:- WEL15minlimitmg/m3:-
WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust:WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -

ExposurePattern-Workers
Ethanol:EthylAlcohol Long-term-inhalation-Systemic effects 950mg/m³
Long-term-inhalation-Local effects 1900mg/m³
ExposurePattern-Generalpopulation
Ethanol:EthylAlcohol Long-term-inhalation-Systemic effects 114mg/m³
Long-term-inhalation-Local effects 950mg/m³
Long-term-oral-Systemic effects 87mg/kg
Long-term-dermal-Systemic effects 343mg/kg
Long-term-dermal-Systemic effects 206mg/kg
8.2.Exposurecontrols


AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.
8.2.1.Appropriateengineering controls
Eye/faceprotection
Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.
Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields.
SkinprotectionHandprotection Rubbergloves.
Respiratoryprotection
8.2.3.Environmentalexposure controls
Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.
Preventfurtherleakageorspillageifsafetodoso.
9.1.Informationonbasicphysicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties
AppearanceLiquid
ColourOffwhite
OdourPerfumes
OdourthresholdNodataavailable pH5.8-7.8
MeltingpointNotapplicable.
InitialboilingpointNodataavailable Flashpoint62°C
EvaporationrateNodataavailable Flammability(solid,gas)Notapplicable.
VapourpressureNodataavailable RelativeVapourDensityNodataavailable Density/RelativeDensity0.98-1g/cm3
PartitioncoefficientNodataavailable
AutoignitiontemperatureNodataavailable
Viscosity<50centipoise
ExplosivepropertiesNodataavailable OxidisingpropertiesNodataavailable SolubilitySolubleinwater
9.2.Otherinformation
ConductivityNodataavailable SurfacetensionNodataavailable GasgroupNodataavailable
BenzeneContentNotapplicable.
LeadcontentNotapplicable.
9.2.1.Informationwithregardtophysicalhazardclasses
Nodataisavailableonthisproduct.
9.2.2.Othersafetycharacteristics
Nodataisavailableonthisproduct.
SECTION10:Stabilityandreactivity
10.1.Reactivity
10.2.Chemicalstability
Stableundernormalconditions.
Stableundernormalconditions.
10.3.Possibilityofhazardousreactions
Strongacids.Strongoxidisingagents.
10.4.Conditionstoavoid
10.5.Incompatiblematerials
Protectfromfrost.
Noincompatiblegroupsnoted.
10.6.Hazardousdecompositionproducts
NoHazardousdecompositionproductswhenstoredandhandledcorrectly.
SECTION11:Toxicologicalinformation
11.1Informationonhazardclasses

11.1Informationonhazardclasses
Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedusingthemethodsoutlinedinRegulation(EC)No1272/2008(CLP).
Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet. OralATE=>10,000mg/kg.
DermalATE=>10,000mg/kg. Inhalation-Dust/MistATE=>5,000mg/l.
Skincorrosion/irritation basedonavailabledatatheclassificationcriteriaarenotmet. Seriouseyedamage/irritationbasedonavailabledatatheclassificationcriteriaarenotmet. Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.
Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet. Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.
Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.
Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet. Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.
11.1.2.Mixtures
11.1.3.HazardInformation
11.1.4.ToxicologicalInformation
Nodataavailable.
Nodataavailable.
Nodataavailable
11.2Informationonotherhazards
Nodataisavailableonthisproduct.
SECTION12:Ecologicalinformation
12.1.Toxicity
Nodataavailable
12.2.Persistenceanddegradability
SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.
12.3.Bioaccumulativepotential
Partitioncoefficient
12.4.Mobilityinsoil
Theproductisnotbioaccumulating.
StoneacreAquafreeEnhancerNodataavailable Ethanol:EthylAlcohol-0.35logP
Thisproductissolubleinwater.
12.5.ResultsofPBTandvPvBassessment
Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.
12.6Endocrinedisruptingproperties
Nodataisavailableonthisproduct.

12.7.Otheradverseeffects
Nodataisavailableonthisproduct.
13.1.Wastetreatmentmethods
Generalinformation
Disposalofpackaging
Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.
Disposeofincompliancewithalllocalandnationalrequirements.
DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.
14.1.UNnumber
14.2.UNpropershippingname
14.3.Transporthazardclass(es)
14.4.Packinggroup
14.5.Environmentalhazards
14.6.Specialprecautionsforuser
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
14.7MaritimeTransportinbulkaccordingtoIMOinstruments
Theproductisnotclassifiedasdangerousforcarriage.
15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations
REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.
COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.
COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).
15.2.Chemicalsafetyassessment
Noinformationavailable.

Otherinformation
Revision
TextofHazardStatementsin Section3
Furtherinformation
Thisdocumentdiffersfromthepreviousversioninthefollowingareas:. 2-Otherhazards.
2-Furtherinformation.
2-SUPPLEMENTALHAZARDINFORMATION.
5-5.2.Specialhazardsarisingfromthesubstanceormixture. 9-9.2.2.Othersafetycharacteristics.
9-9.2.1.Informationwithregardtophysicalhazardclasses. 10-10.2.Chemicalstability.
10-10.1.Reactivity.
11-11.2Informationonotherhazards.
12-12.6Endocrinedisruptingproperties. 12-12.7.Otheradverseeffects.
15-Regulations.
Flam.Liq.2:H225-Highlyflammableliquidandvapour. EyeIrrit.2:H319-Causesseriouseyeirritation.
TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.



according to Regulation (EU) 2020/878
SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking
1.1.Productidentifier
Productname Aqua Rinse Aid
1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst
ProductUse
[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC35]Washingandcleaningproducts(includingsolventbasedproducts);
[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC35]Washingand cleaningproducts(includingsolventbasedproducts);
Description CarRinseAid.
1.3.Detailsofthesupplierofthesafetydatasheet Company SUPAGARDLIMITED
Address 19-27GavintonStreet Muirend Glasgow G443EF
Web www.supagard.com
Telephone 01416335933
Fax 01416377219
Email James.Smyth@supagard.com
Emailaddressofthe competentperson James.Smyth@supagard.com
1.4.Emergencytelephonenumber
Emergencytelephonenumber01416335933 8.30amto5.00pm
FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)
Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org
SECTION2:Hazardsidentification
2.1.Classificationofthesubstanceormixture
2.1.2.Classification-EC 1272/2008 SkinCorr.1B:H314;AquaticChronic2:H411;
2.2.Labelelements
Hazardpictograms



2.2.Labelelements
SignalWord Danger
HazardStatement
PrecautionaryStatement: Prevention
PrecautionaryStatement: Response
PrecautionaryStatement: Disposal
SUPPLEMENTALHAZARD INFORMATION
SkinCorr.1B:H314-Causessevereskinburnsandeyedamage. AquaticChronic2:H411-Toxictoaquaticlifewithlonglastingeffects.
P102-Keepoutofreachofchildren.
P260-Donotbreathedust/fume/gas/mist/vapours/spray.
P302+P350-IFONSKIN:Gentlywashwithplentyofsoapandwater.
P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.
P501-Disposeofcontents/containertoanapproveddisposalsite,inaccordancewithlocal regulations.
IngredientsasrequiredbyRegulation(EC)No648/2004:. Preservative:Benzisothiazolinone.
Contains-Distillates(petroleum),straight-runmiddle,DicocdimethylAmmoniumChloride,2,2'(octadec-9-enylimino)bisethanol,2-(2-butoxyethoxy)ethanol(2-(2-Butoxyethoxy)ethanol).
2.3.Otherhazards
Otherhazards Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.
Furtherinformation
RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.
SECTION3:Composition/informationoningredients
3.2.Mixtures
EC1272/2008
ChemicalName
Distillates(Petroleum),straight-run middle
64741-44-2265-044-701-2119486889-09
AcuteTox.4:H302+H332; STOTRE2:H373;Aquatic Chronic2:H411; 1-10% DicocdimethylAmmoniumChloride
61789-77-3263-087-601-2119486994-16
AcuteTox.4:H302;Skin Corr.1B:H314;Aquatic Acute1:H400;Aquatic Chronic2:H411; 1-10% 2,2'(octadec-9-enylimino)bisethanol
25307-17-9246-807-3
AcuteTox.4:H302;Skin Corr.1B:H314;Aquatic Chronic1:H410;Aquatic Chronic2:H411; 1-10% 2-(2-butoxyethoxy)ethanol(2(2-Butoxyethoxy)ethanol)
603-096-00-8112-34-5203-961-6
EyeIrrit.2:H319;1-10%
2,2'(octadec-9-enylimino)bisethanol,CASNo.25307-17-9-MFactor(Acute)=10,MFactor (Chronic)=1.
SECTION4:Firstaidmeasures
4.1.Descriptionoffirstaidmeasures
Inhalation
Movetheexposedpersontofreshair.
Eyecontact Rinseimmediatelywithplentyofwaterfor15minutesholdingtheeyelidsopen.Contactlenses shouldberemoved.
Skincontact
Removecontaminatedclothing.Washoffimmediatelywithplentyofsoapandwater.
Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.Drinkplentyofwatertodiluteingested product.
4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed
Inhalation Maycauseirritationtorespiratorysystem. Eyecontact Causesburns.Riskofseriousdamagetoeyes.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed
Skincontact Causesburns.
Ingestion Maycauseirritationtomucousmembranes.
4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded
Inhalation
Eyecontact
Skincontact
Ingestion
Generalinformation
Movetheexposedpersontofreshair.Incaseofaccidentorifyoufeelunwell,seekmedical adviceimmediately(showthelabelwherepossible).Seekmedicalattention.Showthissafetydata sheettothedoctorinattendance.
Rinseimmediatelywithplentyofwaterfor15minutesholdingtheeyelidsopen.Contactlenses shouldberemoved.Seekmedicalattention.Showthissafetydatasheettothedoctorin attendance.
Removecontaminatedclothingimmediately.Rinseimmediatelywithplentyofwater.Seekmedical attention.Showthissafetydatasheettothedoctorinattendance.
Drink1to2glassesofwater.Seekmedicalattention.Showthissafetydatasheettothedoctorin attendance.
Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.
5.1.Extinguishingmedia
Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.
5.2.Specialhazardsarisingfromthesubstanceormixture
Burningproducesirritating,toxicandobnoxiousfumes.
5.3.Adviceforfirefighters
Furtherinformation
Wearsuitablerespiratoryequipmentwhennecessary.Firefightersshouldwearselfcontained positivepressurebreathingapparatus(SCBA)andfullturnoutgear.
Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.
6.1.Personalprecautions,protectiveequipmentandemergencyprocedures
6.2.Environmentalprecautions
Wearsuitableprotectiveequipment.
Adviselocalauthoritiesiflargespillscannotbecontained.
6.3.Methodsandmaterialforcontainmentandcleaningup
Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.
6.4.Referencetoothersections
Seesection2,7,8,13forfurtherinformation.
7.1.Precautionsforsafehandling
Avoidcontactwitheyesandskin.Donotbreathevapoursorspraymist.AdoptbestManual Handlingconsiderationswhenhandling,carryinganddispensing.
7.2.Conditionsforsafestorage,includinganyincompatibilities
Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein

7.2.Conditionsforsafestorage,includinganyincompatibilities originalcontainer.
7.3.Specificenduse(s) CarRinseAid.
Suitablepackaging
Plasticcontainers.
8.1.Controlparameters
8.1.1.ExposureLimitValues
2-(2-butoxyethoxy)ethanol(2(2-Butoxyethoxy)ethanol)
8.2.Exposurecontrols
Occupationalexposurecontrols.
WEL8-hrlimitppm:10
WEL15minlimitppm:15
8.2.1.Appropriateengineering controls
Eye/faceprotection
SkinprotectionHandprotection
Respiratoryprotection
8.2.3.Environmentalexposure controls
WEL8-hrlimitmg/m3:67.5
WEL15minlimitmg/m3:101.2
WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -


AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.
Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.
Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields. Eyewearcomplyingwithanapprovedstandardshouldbewornifariskassessmentindicateseye contactispossible.Thefollowingprotectionshouldbeworn:Wearchemicalsplashgoggles. PersonalprotectiveequipmentforeyeandfaceprotectionshouldcomplywithEuropeanStandard EN166.
Rubbergloves.Chooseglovestoprotecthandsagainstchemicalsdependingontheconcentration andquantityofthehazardoussubstanceandspecifictoplaceofwork.Forspecialapplications, werecommendclarifyingtheresistancetochemicalsoftheaforementionedprotectivegloveswith theglovemanufacturer.
Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.
Preventfurtherleakageorspillageifsafetodoso.
SECTION9:Physicalandchemicalproperties
9.1.Informationonbasicphysicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties
AppearanceLiquid ColourClear
OdourCharacteristic
InitialboilingpointNodataavailable
FlashpointNodataavailable EvaporationrateNodataavailable Flammability(solid,gas)Nodataavailable VapourpressureNodataavailable RelativeVapourDensityNodataavailable Density/RelativeDensity0.98-0.99
PartitioncoefficientNodataavailable AutoignitiontemperatureNodataavailable Viscosity<50centipoise
ExplosivepropertiesNodataavailable
OxidisingpropertiesNodataavailable
OdourthresholdNodataavailable pH7-9
MeltingpointNodataavailable SolubilitySolubleinwater
9.2.Otherinformation
ConductivityNodataavailable SurfacetensionNodataavailable GasgroupNodataavailable
BenzeneContentNodataavailable
LeadcontentNodataavailable
VOC(Volatileorganic compounds) Nodataavailable
9.2.1.Informationwithregardtophysicalhazardclasses
Nodataisavailableonthisproduct.
9.2.2.Othersafetycharacteristics
Nodataisavailableonthisproduct.
SECTION10:Stabilityandreactivity
10.1.Reactivity
10.2.Chemicalstability
Stableundernormalconditions.
Stableundernormalconditions.
10.3.Possibilityofhazardousreactions
Strongacids.Strongoxidisingagents.
10.4.Conditionstoavoid
10.5.Incompatiblematerials
Protectfromfrost.AvoidstoringindirectSunLight.
Strongacids.Strongoxidisingagents.
10.6.Hazardousdecompositionproducts
NoHazardousdecompositionproductswhenstoredandhandledcorrectly.

SECTION11:Toxicologicalinformation
11.1Informationonhazardclasses
Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedusingthemethodsoutlinedinRegulation(EC)No1272/2008(CLP).
Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet. OralATE=>10,000mg/kg.
Inhalation-Dust/MistATE=55.6044mg/l.
Skincorrosion/irritation SkinCorr.1B:H314-Causessevereskinburnsandeyedamage. Seriouseyedamage/irritationCausesseriouseyedamage.
Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.
Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet.
Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.
Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.
Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet.
Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.
11.1.2.Mixtures
11.1.3.HazardInformation
11.1.4.ToxicologicalInformation
Nodataavailable.
Nodataavailable.
Nodataavailable
11.2Informationonotherhazards
Nodataisavailableonthisproduct.
SECTION12:Ecologicalinformation
12.1.Toxicity
Nodataavailable
12.2.Persistenceanddegradability
SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.
12.3.Bioaccumulativepotential
Theproductisnotbioaccumulating.
Partitioncoefficient SupagardAquaRinseAidNodataavailable
12.4.Mobilityinsoil
Thisproductissolubleinwater.
12.5.ResultsofPBTandvPvBassessment
Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.
12.6Endocrinedisruptingproperties
Nodataisavailableonthisproduct.

12.7.Otheradverseeffects
Nodataisavailableonthisproduct.
13.1.Wastetreatmentmethods
Generalinformation
Disposalofpackaging
Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.
Disposeofincompliancewithalllocalandnationalrequirements.
DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.
SECTION14:Transportinformation
Hazardpictograms


14.1.UNnumber
14.2.UNpropershippingname
14.3.Transporthazardclass(es)
CORROSIVELIQUID,N.O.S.(ContainsMINERALSEALOIL;DICOCODIMETHYLAMMONIUM CHLORIDE;ETHOXYLATEDOLEYLAMINE)
14.5.Environmentalhazards
Environmentalhazards Yes Marinepollutant Yes
14.6.Specialprecautionsforuser
Noadditionalspecialprecautions.
14.7MaritimeTransportinbulkaccordingtoIMOinstruments
Notapplicable.

PackingInstruction(Cargo)856
Maximumquantity 60L
PackingInstruction (Passenger) 852
Maximumquantity 5L
SECTION15:Regulatoryinformation
15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture
Regulations
REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.
COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.
COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).
15.2.Chemicalsafetyassessment
Noinformationavailable.
SECTION16:Otherinformation
Otherinformation
Revision
Thisdocumentdiffersfromthepreviousversioninthefollowingareas:.
2-Otherhazards.
2-Hazardpictograms.
2-Furtherinformation.
2-SUPPLEMENTALHAZARDINFORMATION.
9-9.2.2.Othersafetycharacteristics.
9-9.2.1.Informationwithregardtophysicalhazardclasses. 11-11.2Informationonotherhazards.
12-12.6Endocrinedisruptingproperties. 12-12.7.Otheradverseeffects. 15-Regulations.
Datasources ClassificationandProcedureusedtoderivetheclassificationformixturesaccordingtoRegulation (EC)No.1272/2008,asretainedandamendedinUKlaw.
SkinCorr.1B:H314-Causessevereskinburnsandeyedamage.-CalculationMethod.
AquaticChronic2:H411-Toxictoaquaticlifewithlonglastingeffects.-CalculationMethod,See Section3forapplicableMFactors.
TextofHazardStatementsin
Section3
AcuteTox.4:H302+H332-Harmfulifswallowedorifinhaled STOTRE2:H373-Maycausedamagetoorgansthroughprolongedorrepeatedexposure.
AquaticChronic2:H411-Toxictoaquaticlifewithlonglastingeffects.
AcuteTox.4:H302-Harmfulifswallowed.
SkinCorr.1B:H314-Causessevereskinburnsandeyedamage.
AquaticAcute1:H400-Verytoxictoaquaticlife.
AquaticChronic1:H410-Verytoxictoaquaticlifewithlonglastingeffects.
EyeIrrit.2:H319-Causesseriouseyeirritation.

TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.



according to Regulation (EU) 2020/878
SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking
1.1.Productidentifier
Productname Bird & Bug Remover
1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst
ProductUse
[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC35]Washingand cleaningproducts(includingsolventbasedproducts);
[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC35]Washingandcleaningproducts(includingsolventbasedproducts);
Description Acombinationofsurfactantswhichneutralisetheacidinbirdlime.
1.3.Detailsofthesupplierofthesafetydatasheet
Company SUPAGARDLIMITED
Address 19-27GavintonStreet Muirend Glasgow G443EF
Web www.supagard.com
Telephone 01416335933
Fax 01416377219
Email James.Smyth@supagard.com
Emailaddressofthe competentperson
1.4.Emergencytelephonenumber
James.Smyth@supagard.com
Emergencytelephonenumber01416335933 8.30amto5.00pm
FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)
Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org
SECTION2:Hazardsidentification
2.1.Classificationofthesubstanceormixture
2.1.2.Classification-EC 1272/2008
2.2.Labelelements
Thisproductdoesnotmeetthecriteriaforclassificationinanyhazardclassaccordingto Regulation(EC)No.1272/2008onclassification,labellingandpackagingofsubstancesand mixtures.
PrecautionaryStatement: Prevention P102-Keepoutofreachofchildren.
PrecautionaryStatement: Response P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.

2.2.Labelelements
HazardStatement
SUPPLEMENTALHAZARD INFORMATION
NoSignificantHazard
IngredientsasrequiredbyRegulation(EC)No648/2004:. Lessthan5%Non-ionicsurfactants.
Contains-2,2',2"-Nitrilotriethanol,Amines,C12-14(evennumbered)-alkyldimethyl,N-oxides, DenaturedEthanol,2-butoxyethanol.
2.3.Otherhazards
Otherhazards Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.
Furtherinformation
RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.
SECTION3:Composition/informationoningredients
3.2.Mixtures
EC1272/2008
ChemicalName
2,2',2''-Nitrilotriethanol
Amines,C12-14(evennumbered) -alkyldimethyl,N-oxides
Diethanolamine
Ethanol:EthylAlcohol(Ethanol)
102-71-6203-049-801-2119486482-311-10%
308062-28-4931-292-601-2119490061-47
111-42-2203-868-001-2119488930-28
64-17-5200-578-601-2119457610-43
AcuteTox.4:H302;SkinIrrit. 2:H315;EyeDam.1:H318; AquaticAcute1:H400; AquaticChronic2:H411;
AcuteTox.4:H302;SkinIrrit. 2:H315;EyeDam.1:H318; Repr.2:H361fd;STOTRE2: H373; 0-0.5%
Flam.Liq.2:H225;EyeIrrit. 2:H319; 1-10% 2-butoxyethanol
603-014-00-0111-76-2203-905-001-2119475108-36
AcuteTox.4:H332;Acute Tox.4:H312;AcuteTox.4: H302;EyeIrrit.2:H319;Skin Irrit.2:H315; 1-10%
Amines,C12-14(evennumbered)-alkyldimethyl,N-oxides(CASNo.308062-28-4)-MFactor (Acute)=1.
SECTION4:Firstaidmeasures
4.1.Descriptionoffirstaidmeasures
Inhalation
Movetheexposedpersontofreshair.
Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved.
Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution.
Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.
4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed
Inhalation Maycauseirritationtorespiratorysystem.
Eyecontact Maycauseirritationtoeyes.
Skincontact Maycauseskindrynessandirritation.
Ingestion Maycauseirritationtomucousmembranes.
4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded TREATSYMPTOMATICALLY.
Inhalation Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.
Eyecontact Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded Skincontact Seekmedicalattentionifirritationorsymptomspersist. Ingestion Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.
Generalinformation
Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.
5.1.Extinguishingmedia
Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.
5.2.Specialhazardsarisingfromthesubstanceormixture
Noneknown.
5.3.Adviceforfirefighters
Furtherinformation
Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.
Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.
6.1.Personalprecautions,protectiveequipmentandemergencyprocedures
6.2.Environmentalprecautions
Wearsuitableprotectiveequipment.
Adviselocalauthoritiesiflargespillscannotbecontained.
6.3.Methodsandmaterialforcontainmentandcleaningup
Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.
6.4.Referencetoothersections
Seesection2,7,8,13forfurtherinformation.
7.1.Precautionsforsafehandling
AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.
7.2.Conditionsforsafestorage,includinganyincompatibilities
Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.
7.3.Specificenduse(s)
Suitablepackaging
Acombinationofsurfactantswhichneutralisetheacidinbirdlime.
Plasticcontainers.
SECTION8:Exposurecontrols/personalprotection
8.1.Controlparameters
Occupationalexposurecontrols.

8.1.1.ExposureLimitValues
2-butoxyethanol
Ethanol:EthylAlcohol(Ethanol)
WEL8-hrlimitppm:25
WEL15minlimitppm:50
WEL8-hrlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: -
WEL8-hrlimitppm:1000
WEL15minlimitppm:-
WEL8-hrlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: -
DNEL:Derivedno-effectlevel.
ExposurePattern-Workers
2,2',2''-Nitrilotriethanol
2-butoxyethanol
Ethanol:EthylAlcohol
Long-term-inhalation-Local effects 5mg/m³
Long-term-dermal-Systemic effects 6.3mg/kg
Acuteinhalation-Systemic effects 1091mg/m³
Acuteinhalation-Localeffects246mg/m³
Long-term-inhalation-Systemic effects 98mg/m³
Long-term-inhalation-Systemic effects 950mg/m³
Long-term-inhalation-Local effects 1900mg/m³
ExposurePattern-Generalpopulation
2,2',2''-Nitrilotriethanol
2-butoxyethanol
Ethanol:EthylAlcohol
8.2.Exposurecontrols
Long-term-inhalation-Local effects 1.25mg/m³
Long-term-dermal-Systemic effects 3.1mg/kg
Acuteinhalation-Systemic effects 426mg/m³
Acutedermal-Systemiceffects89mg/kg
Long-term-inhalation-Systemic effects 59mg/m³
Long-term-dermal-Systemic effects 89mg/kg
Long-term-inhalation-Systemic effects 114mg/m³
Long-term-inhalation-Local effects 950mg/m³
Long-term-oral-Systemic effects 87mg/kg


WEL8-hrlimitmg/m3:123
WEL15minlimitmg/m3:101.2
WEL15minlimitmg/m3total inhalabledust: -
WEL15minlimitmg/m3total respirabledust: -
WEL8-hrlimitmg/m3:1920
WEL15minlimitmg/m3:-
WEL15minlimitmg/m3total inhalabledust: -
WEL15minlimitmg/m3total respirabledust: -

Acutedermal-Systemiceffects89mg/kg
Long-term-dermal-Systemic effects 125mg/kg
Long-term-dermal-Systemic effects 343mg/kg
Long-term-oral-Systemiceffects13mg/kg
Acuteoral-Systemiceffects26.7mg/kg
Long-term-inhalation-Local effects 147mg/m³
Long-term-oral-Systemiceffects6.3mg/kg
Long-term-dermal-Systemic effects 206mg/kg
8.2.Exposurecontrols
8.2.1.Appropriateengineering controls
appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.
Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.
Eye/faceprotection Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields.
SkinprotectionHandprotection Rubbergloves.
Respiratoryprotection Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.
8.2.3.Environmentalexposure controls Preventfurtherleakageorspillageifsafetodoso.
9.1.Informationonbasicphysicalandchemicalproperties
AppearanceLiquid
ColourClear
OdourCharacteristic
OdourthresholdNodataavailable pH8-10
MeltingpointNotapplicable.
InitialboilingpointNodataavailable
Flashpoint62°C
EvaporationrateNodataavailable
Flammability(solid,gas)Nodataavailable
VapourpressureNodataavailable
RelativeVapourDensityNodataavailable Density/RelativeDensityNodataavailable
PartitioncoefficientNodataavailable
AutoignitiontemperatureNodataavailable
Viscosity<50centipoise ExplosivepropertiesNodataavailable OxidisingpropertiesNotapplicable.
SolubilitySolubleinwater
9.2.Otherinformation
ConductivityNotapplicable. SurfacetensionNodataavailable
Specificgravity1-1.01g/cm³
GasgroupNodataavailable BenzeneContentNotapplicable. LeadcontentNotapplicable.
9.2.1.Informationwithregardtophysicalhazardclasses Nodataisavailableonthisproduct.
9.2.2.Othersafetycharacteristics Nodataisavailableonthisproduct.
SECTION10:Stabilityandreactivity
10.1.Reactivity
Stableundernormalconditions.Nospecificreactivityhazardsassociatedwiththisproduct.

10.2.Chemicalstability
Stableundernormalconditions.Noparticularstabilityconcerns.
10.3.Possibilityofhazardousreactions
Strongacids.Strongoxidisingagents.
10.4.Conditionstoavoid
10.5.Incompatiblematerials
Protectfromfrost.
Noincompatiblegroupsnoted.
10.6.Hazardousdecompositionproducts
NoHazardousdecompositionproductswhenstoredandhandledcorrectly.
11.1Informationonhazardclasses
Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedfromrawmaterialsupplierLD50andAcuteToxicityEstimates(ATE)asoutlinedinthe Regulation(EC)No.1272/2008(CLP)asamendedbyUKlaw.
Acutetoxicity
basedonavailabledatatheclassificationcriteriaarenotmet.
OralATE=>10,000mg/kg.
DermalATE=>10,000mg/kg.
Inhalation-Dust/MistATE=>20mg/l.
Skincorrosion/irritation basedonavailabledatatheclassificationcriteriaarenotmet.
Seriouseyedamage/irritationbasedonavailabledatatheclassificationcriteriaarenotmet.
Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.
Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet.
Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.
Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.
Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet.
Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.
11.1.2.Mixtures
11.1.3.HazardInformation
11.1.4.ToxicologicalInformation
2,2',2''-Nitrilotriethanol
2-butoxyethanol
Ethanol:EthylAlcohol
11.2Informationonotherhazards
Nodataavailable.
Nodataavailable.
OralRatLD50:4190mg/kg
OralRatLD50:1200mg/kg
InhalationRatLC50/4h:2.2mg/l
OralRatLD50:10470.0mg/kg
InhalationRatLC50/4h:>20mg/l
Nodataisavailableonthisproduct.
12.1.Toxicity
DermalRabbitLD50:>20,000mg/kg
DermalRabbitLD50:>2000mg/kg
DermalRabbitLD50:15800.0mg/kg

12.1.Toxicity
2,2',2''-Nitrilotriethanol
2-butoxyethanol
Ethanol:EthylAlcohol
12.2.Persistenceanddegradability
12.3.Bioaccumulativepotential
Partitioncoefficient
12.4.Mobilityinsoil
GreenalgaeEC50/96h:169mg/l
FatheadminnowsLC50/96h:10600-13000 mg/l
DaphniaEC50/48h:1550.0000mg/l
Lepomis_MacrochirusLC50/96h:1490-2950mg/l
EC50formarineorfreshwater organisms >100.0000mg/l
DaphniaEC50/48h:12340.0000mg/l
GreenAlgaeEC50/48h:>100mg/l
RainbowtroutLC50/96h:13000mg/l
NOEC/EC10formarineor freshwaterorganisms 9.6000mg/l
AlgaeEC50/72h:216mg/l
Lepomis_MacrochirusLC50/96h:450-1000mg/l
AlgaeEC50/72h:911mg/l
(Pseudokirchnerie llasubcapitata)
LC50formarineorfreshwater organisms >100.0000mg/l
AlgaeEC50/72h:275mg/l
FatheadminnowsLC50/96h:14200mg/l
GoldenorfeLC50/48h:>100mg/l
SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.
Theproductisnotbioaccumulating.
ArnoldClarkBird&BugRemoverNodataavailable 2,2',2''-Nitrilotriethanol-2.53LogPow Ethanol:EthylAlcohol-0.35logP 2-butoxyethanol0.81logP
Thisproductissolubleinwater.
12.5.ResultsofPBTandvPvBassessment
Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.
12.6Endocrinedisruptingproperties
Nodataisavailableonthisproduct.
12.7.Otheradverseeffects
Nodataisavailableonthisproduct.
13.1.Wastetreatmentmethods
Generalinformation
Disposalofpackaging
Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.
Disposeofincompliancewithalllocalandnationalrequirements.
DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.
14.1.UNnumber
14.2.UNpropershippingname
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.

14.3.Transporthazardclass(es)
14.4.Packinggroup
14.5.Environmentalhazards
14.6.Specialprecautionsforuser
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
14.7MaritimeTransportinbulkaccordingtoIMOinstruments
Theproductisnotclassifiedasdangerousforcarriage.
15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations
REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.AsretainedandamendedinUKlaw.
COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.Asretainedand amendedinUKlaw.
COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).AsretainedandamendedinUK law.
15.2.Chemicalsafetyassessment
Noinformationavailable.
SECTION16:Otherinformation
Otherinformation
Revision
TextofHazardStatementsin
Section3
Furtherinformation
Thisdocumentdiffersfromthepreviousversioninthefollowingareas:. 12-12.1.Toxicity.
AcuteTox.4:H302-Harmfulifswallowed. SkinIrrit.2:H315-Causesskinirritation.
EyeDam.1:H318-Causesseriouseyedamage.
AquaticAcute1:H400-Verytoxictoaquaticlife.
AquaticChronic2:H411-Toxictoaquaticlifewithlonglastingeffects. Repr.2:H361fd-Suspectedofdamagingfertility.Suspectedofdamagingtheunbornchild. STOTRE2:H373-Maycausedamagetoorgansthroughprolongedorrepeatedexposure. Flam.Liq.2:H225-Highlyflammableliquidandvapour.
EyeIrrit.2:H319-Causesseriouseyeirritation.
AcuteTox.4:H302+H312+H332-Harmfulifswallowed,incontactwithskinorifinhaled
TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand

beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.



according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878 Issue date: 8/12/2022 Version: 1.0
1.1. Product identifier
Product form
Product name Product code :Mixture :Standard Polish :STOBD001
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Main use category : Industrial use,Professional use,Consumer use
Use of the substance/mixture : Cleaning/washing agents and additives
1.2.2. Uses advised against
No additional information available
1.3. Details of the supplier of the safety data sheet
SUPAGARD LIMITED
19-29 Gavinton Street, Muirend Glasgow G44 3EF
Web - www.supagard.com
Email - james.smyth@supagard.com
Telephone - 0141 633 5933
1.4. Emergency telephone number
01416335933, 8.30am to 5.00pm
For medical advice or information, you should contact your GP or NHS 111 (or NHS 24 in Scotland) on 111 (for 24-hour health advice)
If you are a healthcare professional with an enquiry please visit www.TOXBASE.org
Country
United Kingdom National Poisons Information Service Dudley Road
0344 892 0111 Only for healthcare (Birmingham Centre) B18 7QH Birmingham professionals City Hospital
United Kingdom National Poisons Information Service Penlan Road 0344 892 0111 Only for healthcare (Cardiff Centre) CF64 2XX Llandough professionals University Hospital Llandough
United Kingdom National Poisons Information Service Little France Crescent 0344 892 0111 Only for healthcare (Edinburgh Centre) EH16 4SA Edinburgh professionals Royal Infirmary of Edinburgh
United Kingdom Guy's & St Thomas' Poisons Unit Avonley Road +44 20 7188 7188 Medical Toxicology Unit, Guy's & St SE14 5ER London Thomas' Hospital Trust
United Kingdom National Poisons Information Service Grosvenor Road 0344 892 0111 Only for healthcare (Belfast Centre) BT12 6BA Belfast professionals Royal Victoria Hospital
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Hazardous to the aquatic environment Chronic Hazard, Category 3 H412 Full text of H- and EUH-statements: see section 16
Adverse physicochemical, human health and environmental effects
Harmful to aquatic life with long lasting effects.
8/12/2022 (Issue date)
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Signal word (CLP) : -
Hazard statements (CLP) : H412 - Harmful to aquatic life with long lasting effects.
Precautionary statements (CLP) : P273 - Avoid release to the environment. P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
2.3. Other hazards
Contains no PBT/vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name
HYDROCARBONS, C9-11, N-ALKANES,
ISOALKANES, CYCLICS, <2% AROMATICS
HYDROCARBONS, C9,AROMATICS
1,2-BENZISOTHIAZOL-3(2H)-ONE
EC-No.: 919-857-5 <15
REACH-no: 01-2119463258-
33
EC-No.: 918-668-5
REACH-no: 01-2119455851-
35
CAS-No.: 2634-33-5
EC-No.: 220-120-9
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flam. Liq. 3, H226
STOT SE 3, H336
Asp. Tox. 1, H304
≤5 Flam. Liq. 3, H226
Asp. Tox. 1, H304
STOT SE 3, H336
STOT SE 3, H335
Aquatic Chronic 2, H411 (M=0)
<0.05
Acute Tox. 4 (Oral), H302
Acute Tox. 1 (Inhalation), H330
Skin Irrit. 2, H315
Eye Dam. 1, H318
Skin Sens. 1, H317
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
A MIXTURE OF: 5-CHLORO-2-METHYL-2H-
CAS-No.: 55965-84-9
<0.0001
Acute Tox. 2 (Inhalation), H330 ISOTHIAZOL-3-ONE [EC NO 247-500-7] AND 2- EC Index-No.: 613-167-00-5
Acute Tox. 2 (Dermal), H310 METHYL-2H-ISOTHIAZOL-3-ONE [EC NO 220-239-
Acute Tox. 3 (Oral), H301 6]
Skin Corr. 1C, H314
Eye Dam. 1, H318
Skin Sens. 1A, H317
Aquatic Acute 1, H400 (M=100)
Aquatic Chronic 1, H410 (M=100)
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
Specific concentration limits:
Name Product identifier Specific concentration limits
A MIXTURE OF: 5-CHLORO-2-METHYL-2H-
CAS-No.: 55965-84-9 ( 0.0015 ≤C ≤ 100) Skin Sens. 1A, H317
ISOTHIAZOL-3-ONE [EC NO 247-500-7] AND 2- EC Index-No.: 613-167-00-5 ( 0.06 ≤C < 0.6) Skin Irrit. 2, H315 METHYL-2H-ISOTHIAZOL-3-ONE [EC NO 220-239- ( 0.06 ≤C < 0.6) Eye Irrit. 2, H319 6] ( 0.6 ≤C ≤ 100) Skin Corr. 1C, H314 ( 0.6 ≤C ≤ 100) Eye Dam. 1, H318
Full text of H- and EUH-statements: see section 16
4.1. Description of first aid measures
First-aid measures after inhalation
First-aid measures after skin contact
First-aid measures after eye contact
First-aid measures after ingestion
: Remove person to fresh air and keep comfortable for breathing.
: Wash skin with plenty of water.
: Rinse eyes with water as a precaution.
: Call a poison center or a doctor if you feel unwell.
4.2. Most important symptoms and effects, both acute and delayed
No additional information available
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
5.1. Extinguishing media
Suitable extinguishing media
: Water spray. Dry powder. Foam. Carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Hazardous decomposition products in case of fire : Toxic fumes may be released.
5.3. Advice for firefighters
Protection during firefighting
: Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing.
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures
6.1.2. For emergency responders
Protective equipment
6.2. Environmental precautions
Avoid release to the environment.
: Ventilate spillage area.
: Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection".
6.3. Methods and material for containment and cleaning up
Methods for cleaning up
: Take up liquid spill into absorbent material. Other information : Dispose of materials or solid residues at an authorized site.
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
6.4. Reference to other sections
For further information refer to section 13.
7.1. Precautions for safe handling
Precautions for safe handling : Ensure good ventilation of the work station. Wear personal protective equipment. Hygiene measures : Do not eat, drink or smoke when using this product. Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions
7.3. Specific end use(s)
No additional information available
: Store in a well-ventilated place. Keep cool.
8.1. Control parameters
8.1.1 National occupational exposure and biological limit values
No additional information available
8.1.2. Recommended monitoring procedures
No additional information available
8.1.3. Air contaminants formed
No additional information available
8.1.4. DNEL and PNEC
No additional information available
8.1.5. Control banding
No additional information available
8.2. Exposure controls
8.2.1. Appropriate engineering controls
Appropriate engineering controls: Ensure good ventilation of the work station.
8.2.2. Personal protection equipment
Personal protective equipment:
Gloves. Safety glasses. Protective clothing. Personal protective equipment symbol(s):

8.2.2.1. Eye and face protection
Eye protection: Safety glasses
8.2.2.2. Skin protection
Skin and body protection:
Wear suitable protective clothing
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
Hand protection:
Protective gloves
8.2.2.3. Respiratory protection
Respiratory protection:
In case of insufficient ventilation, wear suitable respiratory equipment
8.2.2.4. Thermal hazards
No additional information available
8.2.3. Environmental exposure controls
Environmental exposure controls: Avoid release to the environment.
9.1. Information on basic physical and chemical properties
Physical state
Colour
Odour
Odour threshold
Melting point
Freezing point
Boiling point
Flammability
Explosive limits
Lower explosion limit
Upper explosion limit
Flash point
Auto-ignition temperature
Decomposition temperature
: Liquid
: Various colours.
: Pleasant.
: Not available
: Not applicable
: Not available
: Not available
: Non flammable.
: Not available
: Not available
: Not available
: > 93 °C
: Not available
: Not available
Viscosity, kinematic : ≈ 10000 mm²/s
Solubility
Partition coefficient n-octanol/water (Log Kow)
Vapour pressure
Vapour pressure at 50 °C
Density
Relative density
Relative vapour density at 20 °C
Particle characteristics
9.2. Other information
: Not available
: Not available
: Not available
: Not available
: Not available
: Not available
: Not available
: Not applicable
9.2.1. Information with regard to physical hazard classes
No additional information available
9.2.2. Other safety characteristics
No additional information available
10.1. Reactivity
The product is non-reactive under normal conditions of use, storage and transport.
10.2. Chemical stability
Stable under normal conditions.
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
10.3. Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4. Conditions to avoid
None under recommended storage and handling conditions (see section 7).
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
HYDROCARBONS, C9-11, N-ALKANES, ISOALKANES, CYCLICS, <2% AROMATICS
LD50 oral rat
LD50 dermal rat
>5000 mg/kg
>2000 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 402 (Acute Dermal Toxicity)
LD50 dermal rabbit ≥ 3160 mg/kg bodyweight Animal: rabbit, Guideline: OECD Guideline 402 (Acute Dermal Toxicity)
LD50 dermal >5000 mg/kg
HYDROCARBONS, C9,AROMATICS
LD50 dermal rabbit
LC50 Inhalation - Rat
>3160 mg/kg bodyweight Animal: rabbit, Guideline: OECD Guideline 402 (Acute Dermal Toxicity)
>6.193 mg/l air Animal: rat, Guideline: OECD Guideline 403 (Acute Inhalation Toxicity)
A MIXTURE OF: 5-CHLORO-2-METHYL-2H-ISOTHIAZOL-3-ONE [EC NO 247-500-7] AND 2-METHYL-2H-ISOTHIAZOL-3-
ONE [EC NO 220-239-6] (55965-84-9)
LD50 oral rat 53 mg/kg
LD50 oral 60 mg/kg
1,2-BENZISOTHIAZOL-3(2H)-ONE (2634-33-5)
LD50 dermal rat > 2000 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 402 (Acute Dermal Toxicity)
Skin corrosion/irritation
Serious eye damage/irritation
Respiratory or skin sensitisation
Germ cell mutagenicity
Carcinogenicity
Reproductive toxicity
1,2-BENZISOTHIAZOL-3(2H)-ONE (2634-33-5)
NOAEL (animal/female, F1)
STOT-single exposure
8/12/2022
: Not classified pH: ≈ 7
: Not classified pH: ≈ 7
: Not classified
: Not classified
: Not classified
: Not classified
56.6 mg/kg bodyweight Animal: rat, Animal sex: female, Guideline: EPA OPPTS 870.3800 (Reproduction and Fertility Effects)
: Not classified
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
HYDROCARBONS, C9-11, N-ALKANES, ISOALKANES, CYCLICS, <2% AROMATICS
STOT-single exposure
HYDROCARBONS, C9,AROMATICS
STOT-single exposure
May cause drowsiness or dizziness.
May cause drowsiness or dizziness. May cause respiratory irritation.
STOT-repeated exposure : Not classified
HYDROCARBONS, C9,AROMATICS
NOAEL (oral, rat, 90 days)
600 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 408 (Repeated Dose 90Day Oral Toxicity in Rodents)
Aspiration hazard : Not classified
GLAZE - Final Polish
Viscosity, kinematic ≈ 10000 mm²/s
HYDROCARBONS, C9-11, N-ALKANES, ISOALKANES, CYCLICS, <2% AROMATICS
Viscosity, kinematic 1.33 mm²/s Temp.: '20°C' Parameter: 'kinematic viscosity (in mm²/s)'
HYDROCARBONS, C9,AROMATICS
Viscosity, kinematic 1.06 mm²/s Temp.: '20°C' Parameter: 'cStcSt'
11.2. Information on other hazards
No additional information available
12.1. Toxicity
Ecology - general
Hazardous to the aquatic environment, shortterm (acute)
Hazardous to the aquatic environment, long-term (chronic)
Not rapidly degradable
: Harmful to aquatic life with long lasting effects.
: Not classified
: Harmful to aquatic life with long lasting effects.
HYDROCARBONS, C9-11, N-ALKANES, ISOALKANES, CYCLICS, <2% AROMATICS
LC50 - Fish [1]
>1000 mg/l
EC50 - Other aquatic organisms [1] >1000 mg/l
HYDROCARBONS, C9,AROMATICS
EC50 72h - Algae [1]
EC50 72h - Algae [2]
1,2-BENZISOTHIAZOL-3(2H)-ONE (2634-33-5)
0.42 mg/l Test organisms (species): Pseudokirchneriella subcapitata (previous names: Raphidocelis subcapitata, Selenastrum capricornutum)
0.29 mg/l Test organisms (species): Pseudokirchneriella subcapitata (previous names: Raphidocelis subcapitata, Selenastrum capricornutum)
LC50 - Fish [1] ≈ 16.7 mg/l Test organisms (species): Cyprinodon variegatus
LC50 - Fish [2]
EC50 - Crustacea [1]
EC50 - Crustacea [2]
12.2. Persistence and degradability
No additional information available
8/12/2022
2.15 mg/l Test organisms (species): Oncorhynchus mykiss (previous name: Salmo gairdneri)
2.94 mg/l Test organisms (species): Daphnia magna
2.9 mg/l Test organisms (species): Daphnia magna
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
12.3. Bioaccumulative potential
No additional information available
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Endocrine disrupting properties
No additional information available
12.7. Other adverse effects
No additional information available
13.1. Waste treatment methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions.
In accordance with ADR / IMDG / IATA / ADN / RID
14.1. UN number or ID number
14.2. UN proper shipping name
14.3. Transport hazard class(es)
14.4. Packing group
14.5. Environmental hazards
14.6. Special precautions for user
Overland transport
Not regulated
Transport by sea
Not regulated
Air transport Not regulated
Inland waterway transport
Not regulated
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
Rail transport
Not regulated
14.7. Maritime transport in bulk according to IMO instruments
Not applicable
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
REACH Annex XVII (Restriction List)
Contains no REACH substances with Annex XVII restrictions
REACH Annex XIV (Authorisation List)
Contains no REACH Annex XIV substances
REACH Candidate List (SVHC)
Contains no substance on the REACH candidate list
PIC Regulation (Prior Informed Consent)
Contains no substance subject to Regulation (EU) No 649/2012 of the European Parliament and of the Council of 4 July 2012 concerning the export and import of hazardous chemicals.
POP Regulation (Persistent Organic Pollutants)
Contains no substance subject to Regulation (EU) No 2019/1021 of the European Parliament and of the Council of 20 June 2019 on persistent organic pollutants
Ozone Regulation (1005/2009)
Contains no substance subject to REGULATION (EU) No 1005/2009 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 September 2009 on substances that deplete the ozone layer.
Explosives Precursors Regulation (2019/1148)
Contains substance subject to Regulation (EU) 2019/1148 of the European Parliament and of the Council of 20 June 2019 on the marketing and use of explosives precursors.
ANNEX II REPORTABLE EXPLOSIVES PRECURSORS
List of substances on their own or in mixtures or in substances for which suspicious transactions and significant disappearances and thefts are to be reported to the relevant national contact point within 24 hours.
Name CAS-No. Combined Combined Nomenclature code for mixture without Nomenclature constituents which would determine classification under code (CN) another CN code
Please see https://ec.europa.eu/home-affairs/system/files/2021-11/list_of_competent_authorities_and_national_contact_points_en.pdf
Drug Precursors Regulation (273/2004)
Contains no substance subject to Regulation (EC) 273/2004 of the European Parliament and of the Council of 11 February 2004 on the manufacture and the placing on market of certain substances used in the illicit manufacture of narcotic drugs and psychotropic substances.
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
15.1.2. National regulations
France
Occupational diseases
Code Description
RG 65
Eczematiform lesions of allergic mechanism
RG 66 Occupational rhinitis and asthma
RG 84 Conditions caused by liquid organic solvents for professional use: saturated or unsaturated aliphatic or cyclic liquid hydrocarbons and mixtures thereof; liquid halogenated hydrocarbons; nitrated derivatives of aliphatic hydrocarbons; alcohols; glycols, glycol ethers; ketones; aldehydes; aliphatic and cyclic ethers, including tetrahydrofuran; esters; dimethylformamide and dimethylacetamine; acetonitrile and propionitrile; pyridine; dimethylsulfone and dimethylsulfoxide
Germany
Employment restrictions
: Observe restrictions according Act on the Protection of Working Mothers (MuSchG). Observe restrictions according Act on the Protection of Young People in Employment (JArbSchG).
Water hazard class (WGK) : WGK 3, Highly hazardous to water (Classification according to AwSV, Annex 1).
Hazardous Incident Ordinance (12. BImSchV) : Is not subject of the Hazardous Incident Ordinance (12. BImSchV)
Netherlands
SZW-lijst van kankerverwekkende stoffen : None of the components are listed
SZW-lijst van mutagene stoffen : None of the components are listed
SZW-lijst van reprotoxische stoffen – Borstvoeding : None of the components are listed
SZW-lijst van reprotoxische stoffen – : None of the components are listed
Vruchtbaarheid
SZW-lijst van reprotoxische stoffen – Ontwikkeling : None of the components are listed
Denmark
Classification remarks : Emergency management guidelines for the storage of flammable liquids must be followed Danish National Regulations : Pregnant/breastfeeding women working with the product must not be in direct contact with the product
Switzerland
Storage class (LK) : LK 10/12 - Liquids
15.2. Chemical safety assessment
No chemical safety assessment has been carried out
Abbreviations and acronyms:
ADN European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
ADR European Agreement concerning the International Carriage of Dangerous Goods by Road
ATE Acute Toxicity Estimate
BCF Bioconcentration factor
BLV Biological limit value
BOD Biochemical oxygen demand (BOD)
COD Chemical oxygen demand (COD)
DMEL Derived Minimal Effect level
DNEL Derived-No Effect Level
EC-No. European Community number
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
Abbreviations and acronyms:
EC50 Median effective concentration
EN European Standard
IARC International Agency for Research on Cancer
IATA International Air Transport Association
IMDG International Maritime Dangerous Goods
LC50 Median lethal concentration
LD50 Median lethal dose
LOAEL Lowest Observed Adverse Effect Level
NOAEC No-Observed Adverse Effect Concentration
NOAEL No-Observed Adverse Effect Level
NOEC No-Observed Effect Concentration
OECD Organisation for Economic Co-operation and Development
OEL Occupational Exposure Limit
PBT Persistent Bioaccumulative Toxic
PNEC Predicted No-Effect Concentration
RID Regulations concerning the International Carriage of Dangerous Goods by Rail
SDS Safety Data Sheet
STP Sewage treatment plant
ThOD Theoretical oxygen demand (ThOD)
TLM Median Tolerance Limit
VOC Volatile Organic Compounds
CAS-No. Chemical Abstract Service number
N.O.S. Not Otherwise Specified
vPvB Very Persistent and Very Bioaccumulative
ED Endocrine disrupting properties

Full text of H- and EUH-statements:
Acute Tox. 1 (Inhalation) Acute toxicity (inhal.), Category 1
Acute Tox. 2 (Dermal) Acute toxicity (dermal), Category 2
Acute Tox. 2 (Inhalation) Acute toxicity (inhal.), Category 2
Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1
Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category 1
Aquatic Chronic 2 Hazardous to the aquatic environment Chronic Hazard, Category 2
Asp. Tox. 1 Aspiration hazard, Category 1
Eye Dam. 1
Eye Irrit. 2
Serious eye damage/eye irritation, Category 1
Serious eye damage/eye irritation, Category 2
Flam. Liq. 3 Flammable liquids, Category 3
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
Full text of H- and EUH-statements:
H226 Flammable liquid and vapour.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H310 Fatal in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H330 Fatal if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
Skin Corr. 1C
Skin Irrit. 2
Skin Sens. 1
Skin Sens. 1A
STOT SE 3

Safety Data Sheet (SDS), EU
Skin corrosion/irritation, Category 1, Sub-Category 1C
Skin corrosion/irritation, Category 2
Skin sensitisation, Category 1
Skin sensitisation, category 1A
Specific target organ toxicity Single exposure, Category 3, Narcosis
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.


Revision Date 03/01/2018
Supersedes date 07/12/2016
SAFETY DATA SHEET FINE CUTTING COMPOUND
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product name
Product No.
REACH Registration number
FINE CUTTING COMPOUND
000998083012
Mixture - not applicable
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
As product description
1.3. Details of the supplier of the safety data sheet
SUPAGARD LIMITED
Supplier 23, Gavinton Street, Muirend, Glasgow, Scotland, G44 3EF 0141 633 5933 0141 637 7219 james@supagard.co.uk
1.4. Emergency telephone number
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification (EC 1272/2008)
Physical and Chemical HazardsNot classified. Human health Not classified. Environment Not classified.
2.2. Label elements
Label In Accordance With (EC) No. 1272/2008
No pictogram required.
Precautionary Statements
P102
P260
P280
P501
2.3. Other hazards
Keep out of reach of children.
Do not breathe vapours.
Wear protective gloves.
Dispose of contents/container in accordance with local regulations.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
EC No.: 919-857-5
Classification (EC 1272/2008)
Flam. Liq. 3 - H226
EUH066
STOT SE 3 - H336
Asp. Tox. 1 - H304
Classification (67/548/EEC) Xn;R65. R10,R66,R67.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
REACH Registration numberMixture - not applicable
4.1. Description of first aid measures
Inhalation
Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. Ingestion
NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Rinse mouth thoroughly. Drink plenty of water. Get medical attention if any discomfort continues.
Skin contact
Wash skin thoroughly with soap and water. Get medical attention if any discomfort continues. Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General information
Mixture is not classified - none noted
4.3. Indication of any immediate medical attention and special treatment needed
See section 4.1
5.1. Extinguishing media
Extinguishing media
This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
During a fire, CO and CO2 may be formed.
5.3. Advice for firefighters
Special Fire Fighting Procedures
No specific fire fighting procedure given.
6.1. Personal precautions, protective equipment and emergency procedures
In case of spills, beware of slippery floors and surfaces.
6.2. Environmental precautions
Not relevant considering the small amounts used.
6.3. Methods and material for containment and cleaning up
Stop leak if possible without risk. Absorb in vermiculite, dry sand or earth and place into containers. Flush with plenty of water to clean spillage area.
6.4. Reference to other sections
Collect and dispose of spillage as indicated in section 13.
7.1. Precautions for safe handling
Avoid spilling, skin and eye contact.
7.2. Conditions for safe storage, including any incompatibilities
Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
Usage Description
Use as instructed on the product label.
8.1. Control parameters
Ingredient Comments
Where an allergen is named in Section 2, follow appropriate measures in Sections 8 and 11.
8.2. Exposure controls
Protective equipment


Engineering measures
Provide adequate general and local exhaust ventilation. Hand protection
For prolonged or repeated skin contact use suitable protective gloves.
Eye protection
Wear approved chemical safety goggles where eye exposure is reasonably probable. Other Protection
Wear appropriate clothing to prevent any possibility of skin contact.
Hygiene measures
DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated. Use appropriate skin cream to prevent drying of skin. When using do not eat, drink or smoke.
9.1. Information on basic physical and chemical properties
Appearance Liquid
Colour Typical
Odour Characteristic.
9.2. Other information
None to note.
10.1. Reactivity
There are no known reactivity hazards associated with this product.
10.2. Chemical stability
Stable under normal temperature conditions.
10.3. Possibility of hazardous reactions
Not applicable.
10.4. Conditions to avoid
Avoid excessive heat for prolonged periods of time. Avoid frost.
10.5. Incompatible materials
Materials To Avoid
Strong alkalis. Strong acids.
10.6. Hazardous decomposition products
Fire creates: Carbon monoxide (CO). Carbon dioxide (CO2).
11.1. Information on toxicological effects
Inhalation
Gas or vapour may irritate respiratory system.
Ingestion
Gastrointestinal symptoms, including upset stomach.
Skin contact
Prolonged contact may cause dryness of the skin.
Eye contact
Irritating to eyes.
Health Warnings
No specific health warnings noted.
Route of entry
Ingestion. Inhalation. Skin and/or eye contact.
Ecotoxicity
Not regarded as dangerous for the environment.
12.1. Toxicity
Data set not currently available.
12.2. Persistence and degradability
The majority of the constituents are readily degradeable.
12.3. Bioaccumulative potential
Bioaccumulative potential
No data available on bioaccumulation.
12.4. Mobility in soil
Mobility:
Mobile.
12.5. Results of PBT and vPvB assessment
Not Classified as PBT/vPvB by current EU criteria.
12.6. Other adverse effects
Not applicable.
General information
Dispose of in accordance with Local Authority guidelines.
13.1. Waste treatment methods
Dispose of waste and residues in accordance with local authority requirements.
SECTION 14: TRANSPORT INFORMATION
General
The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID).
Rail Transport Notes Not classified.
Sea Transport Notes Not classified.
Air Transport Notes Not classified.
14.1. UN number
Not applicable.
14.2. UN proper shipping name
Not applicable.
14.3. Transport hazard class(es)
Transport Labels
14.4. Packing group
Not applicable.
14.5. Environmental hazards
No transport warning sign required.
Environmentally Hazardous Substance/Marine Pollutant No.
14.6. Special precautions for user
Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Guidance Notes
Workplace Exposure Limits EH40.
Introduction to Local Exhaust Ventilation HS(G)37.
EU Legislation
Regulation (EC) No.1272/2008 The Classification, Labelling and Packaging of substances and mixtures Regulations
Regulation (EC) No. 1907/2006 The Registration, Evaluation, Authorisation and Restriction of Chemicals Regulations (REACH) 2001/95/EC The General Product Safety Directive (GPSD)
Commission Regulation (EU) 2015/830 Requirements for the compilation of safety data sheets (amending REACH)
Authorisations (Title VII Regulation 1907/2006)
No specific authorisations are noted for this product.
Restrictions (Title VIII Regulation 1907/2006)
No specific restrictions of use are noted for this product.
15.2. Chemical Safety Assessment
Not currently available.
SECTION 16: OTHER INFORMATION
Information Sources
Dangerous Properties of Industrial Materials Report, N.Sax et.al.
Revision Date 03/01/2018
Revision 4
Supersedes date 07/12/2016
Hazard Statements In Full
EUH066 Repeated exposure may cause skin dryness or cracking. , H226 Flammable liquid and vapour. , H304 May be fatal if swallowed and enters airways. , H336 May cause drowsiness or dizziness.

Revision Date 03/01/2018
Supersedes date 16/08/2016

SAFETY DATA SHEET
MEDIUM CUTTING COMPOUND
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product name
Product No.
MEDIUM CUTTING COMPOUND 000998083011
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.3. Details of the supplier of the safety data sheet
SUPAGARD LIMITED
Supplier 23, Gavinton Street, Muirend, Glasgow, Scotland, G44 3EF 0141 633 5933 0141 637 7219 james@supagard.co.uk
1.4. Emergency telephone number
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification (EC 1272/2008)
Physical and Chemical HazardsNot classified. Human health Skin Sens. 1 - H317 Environment Not classified.
2.2. Label elements Contains PINE OIL 90
Label In Accordance With (EC) No. 1272/2008
Signal Word Warning Hazard Statements
H317 May cause an allergic skin reaction. Precautionary Statements
P102
Keep out of reach of children.
P280 Wear protective gloves.
P261 Avoid breathing vapour/spray.
P302+352
IF ON SKIN: Wash with plenty of soap and water.
P333+313 If skin irritation or rash occurs: Get medical advice/attention. Supplementary Precautionary Statements
P363
P501
2.3. Other hazards
Wash contaminated clothing before reuse.
Dispose of contents/container in accordance with local regulations.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
CAS-No.: 64742-52-5
Classification (EC 1272/2008) Not classified.
ODOURLESS KEROSENE
CAS-No.: 64742-47-8
Classification (EC 1272/2008)
EUH066
Asp. Tox. 1 - H304
EC No.: 265-155-0
Registration Number: 01-2119467170-45-XXXX
Classification (67/548/EEC) Not classified.
EC No.: 926-141-6
Registration Number: 01-2119456620-43-XXXX
Classification (67/548/EEC) Xn;R65. R66.
CAS-No.: 8000-41-7
Classification (EC 1272/2008)
Flam. Liq. 3 - H226
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319
Skin Sens. 1 - H317
Asp. Tox. 1 - H304
Aquatic Chronic 2 - H411
EC No.: 232-268-1
Registration Number: 01-2119553062-49-XXXX, 01-211
Classification (67/548/EEC) Xn;R65. Xi;R36/38. N;R51/53. R10,R43.
CAS-No.: 7632-00-0
Classification (EC 1272/2008)
Ox. Sol. 3 - H272
Acute Tox. 3 - H301
Aquatic Acute 1 - H400
EC No.: 231-555-9
Registration Number: 01-2119471836-27-XXXX
Classification (67/548/EEC)
O;R8
T;R25
N;R50
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
4.1. Description of first aid measures
Inhalation
Move the exposed person to fresh air at once. Rinse nose and mouth with water. Get medical attention if any discomfort continues. Ingestion
Remove victim immediately from source of exposure. Rinse mouth thoroughly. Drink plenty of water. Get medical attention.
Skin contact
Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention if irritation persists after washing.
Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed
5.1. Extinguishing media
Extinguishing media
This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials.
5.2. Special hazards arising from the substance or mixture
5.3. Advice for firefighters
6.1. Personal precautions, protective equipment and emergency procedures
6.2. Environmental precautions
6.3. Methods and material for containment and cleaning up
Wear necessary protective equipment. Absorb in vermiculite, dry sand or earth and place into containers. Do not contaminate water sources or sewer. Flush with plenty of water to clean spillage area.
6.4. Reference to other sections
7.1. Precautions for safe handling
Avoid spilling, skin and eye contact.
7.2. Conditions for safe storage, including any incompatibilities
Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container.
7.3. Specific end use(s)
8.1. Control parameters
ODOURLESS KEROSENE
Ingredient Comments
WEL = Workplace Exposure Limits
8.2. Exposure controls
Protective equipment


Engineering measures
No particular ventilation requirements.
Respiratory equipment
No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational exposure limit. Use chemical cartridge protection with appropriate cartridge. Hand protection
Use protective gloves.
Eye protection
Use approved safety goggles or face shield.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact.
Hygiene measures
DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke.
9.1. Information on basic physical and chemical properties
Appearance Liquid
Colour Typical
Odour Characteristic.
Solubility Soluble in water.
9.2. Other information
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity
10.2. Chemical stability
Stable under normal temperature conditions.
10.3. Possibility of hazardous reactions
10.4. Conditions to avoid
Avoid contact with acids.
10.5. Incompatible materials
10.6. Hazardous decomposition products
No specific hazardous decomposition products noted.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Inhalation
May cause irritation to the respiratory system.
Ingestion
May cause burns in mucous membranes, throat, oesophagus and stomach. May cause stomach pain or vomiting.
Skin contact
Irritating to skin. Prolonged or repeated exposure may cause severe irritation. Acts as a defatting agent on skin. May cause cracking of skin, and eczema. May cause allergic contact eczema. May cause sensitisation by skin contact.
Eye contact
May cause severe irritation to eyes. Risk of serious damage to eyes. Surfactant or detergent eye injury due to liquid splashes or dust.
Route of entry
Ingestion. Skin and/or eye contact.
12: ECOLOGICAL INFORMATION
Ecotoxicity
Dangerous for the environment if discharged into watercourses.
12.1. Toxicity
12.2. Persistence and degradability
12.3. Bioaccumulative potential
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
12.6. Other adverse effects
13.1. Waste treatment methods
Dispose of waste and residues in accordance with local authority requirements.
14.1. UN number
14.2. UN proper shipping name
14.3. Transport hazard class(es)
ADR/RID/ADN Class Not classified for transportation. Transport Labels
No transport warning sign required.
14.4. Packing group
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant No.
14.6. Special precautions for user
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Guidance Notes
Workplace Exposure Limits EH40. Introduction to Local Exhaust Ventilation HS(G)37. EU Legislation Regulation (EC) No.1272/2008 The Classification, Labelling and Packaging of substances and mixtures Regulations Regulation (EC) No. 1907/2006 The Registration, Evaluation, Authorisation and Restriction of Chemicals Regulations (REACH) 2001/95/EC The General Product Safety Directive (GPSD) Commission Regulation (EU) 2015/830 Requirements for the compilation of safety data sheets (amending REACH) Authorisations (Title VII Regulation 1907/2006) No specific authorisations are noted for this product. Restrictions (Title VIII Regulation 1907/2006)
No specific restrictions of use are noted for this product.
15.2. Chemical Safety Assessment
Revision Date 03/01/2018
Revision 4
Supersedes date 16/08/2016
Hazard Statements In Full
EUH066 Repeated exposure may cause skin dryness or cracking. , H226 Flammable liquid and vapour. , H272 May intensify fire; oxidiser. , H301 Toxic if swallowed. , H304 May be fatal if swallowed and enters airways. , H315 Causes skin irritation. , H317 May cause an allergic skin reaction. , H319 Causes serious eye irritation. , H400 Very toxic to aquatic life. , H411 Toxic to aquatic life with long lasting effects.

Revision Date 03/01/2018
Supersedes date 16/08/2016

SAFETY DATA SHEET COARSE CUTTING COMPOUND
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product name Product No.
COARSE CUTTING COMPOUND 000998083010
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.3. Details of the supplier of the safety data sheet
SUPAGARD LIMITED
Supplier 23, Gavinton Street, Muirend, Glasgow, Scotland, G44 3EF 0141 633 5933 0141 637 7219 james@supagard.co.uk
1.4. Emergency telephone number
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification (EC 1272/2008)
Physical and Chemical HazardsNot classified.
Human health Skin Sens. 1 - H317 Environment Not classified.
2.2. Label elements Contains PINE OIL 90
Label In Accordance With (EC) No. 1272/2008
Signal Word Warning Hazard Statements
H317
May cause an allergic skin reaction. Precautionary Statements
P102
P272
Keep out of reach of children.
Contaminated work clothing should not be allowed out of the workplace.
P261 Avoid breathing vapour/spray.
P280 Wear protective gloves.
P302+352 IF ON SKIN: Wash with plenty of soap and water.
P333+313 If skin irritation or rash occurs: Get medical advice/attention.
Supplementary Precautionary Statements
P363
P501
2.3. Other hazards
Wash contaminated clothing before reuse.
Dispose of contents/container in accordance with local regulations.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
CAS-No.: 64742-52-5
Classification (EC 1272/2008) Not classified.
ODOURLESS KEROSENE
CAS-No.: 64742-47-8
Classification (EC 1272/2008)
EUH066
Asp. Tox. 1 - H304
EC No.: 265-155-0
Registration Number: 01-2119467170-45-XXXX
Classification (67/548/EEC) Not classified.
EC No.: 926-141-6
Registration Number: 01-2119456620-43-XXXX
Classification (67/548/EEC) Xn;R65. R66.
CAS-No.: 8000-41-7
Classification (EC 1272/2008)
Flam. Liq. 3 - H226
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319
Skin Sens. 1 - H317
Asp. Tox. 1 - H304
Aquatic Chronic 2 - H411
EC No.: 232-268-1
Registration Number: 01-2119553062-49-XXXX, 01-211
Classification (67/548/EEC) Xn;R65. Xi;R36/38. N;R51/53. R10,R43.
CAS-No.: 7632-00-0
Classification (EC 1272/2008)
Ox. Sol. 3 - H272
Acute Tox. 3 - H301
Aquatic Acute 1 - H400
EC No.: 231-555-9
Registration Number: 01-2119471836-27-XXXX
Classification (67/548/EEC)
O;R8
T;R25
N;R50
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
4.1. Description of first aid measures
Inhalation
Move the exposed person to fresh air at once. Rinse nose and mouth with water. Get medical attention if any discomfort continues. Ingestion
Remove victim immediately from source of exposure. Rinse mouth thoroughly. Drink plenty of water. Get medical attention.
Skin contact
Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention if irritation persists after washing.
Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed
5.1. Extinguishing media
Extinguishing media
This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials.
5.2. Special hazards arising from the substance or mixture
5.3. Advice for firefighters
6.1. Personal precautions, protective equipment and emergency procedures
6.2. Environmental precautions
6.3. Methods and material for containment and cleaning up
Wear necessary protective equipment. Absorb in vermiculite, dry sand or earth and place into containers. Do not contaminate water sources or sewer. Flush with plenty of water to clean spillage area.
6.4. Reference to other sections
7.1. Precautions for safe handling
Avoid spilling, skin and eye contact.
7.2. Conditions for safe storage, including any incompatibilities
Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container.
7.3. Specific end use(s)
8.1. Control parameters
ODOURLESS KEROSENE
Ingredient Comments
WEL = Workplace Exposure Limits
8.2. Exposure controls
Protective equipment


Engineering measures
No particular ventilation requirements.
Respiratory equipment
No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational exposure limit. Use chemical cartridge protection with appropriate cartridge. Hand protection
Use protective gloves.
Eye protection
Use approved safety goggles or face shield.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact.
Hygiene measures
DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke.
9.1. Information on basic physical and chemical properties
Appearance Liquid
Colour Typical
Odour Characteristic.
Solubility Soluble in water.
9.2. Other information
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity
10.2. Chemical stability
Stable under normal temperature conditions.
10.3. Possibility of hazardous reactions
10.4. Conditions to avoid
Avoid contact with acids.
10.5. Incompatible materials
10.6. Hazardous decomposition products
No specific hazardous decomposition products noted.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Inhalation
May cause irritation to the respiratory system.
Ingestion
May cause burns in mucous membranes, throat, oesophagus and stomach. May cause stomach pain or vomiting.
Skin contact
Irritating to skin. Prolonged or repeated exposure may cause severe irritation. Acts as a defatting agent on skin. May cause cracking of skin, and eczema. May cause allergic contact eczema. May cause sensitisation by skin contact.
Eye contact
May cause severe irritation to eyes. Risk of serious damage to eyes. Surfactant or detergent eye injury due to liquid splashes or dust.
Route of entry
Ingestion. Skin and/or eye contact.
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity
Dangerous for the environment if discharged into watercourses.
12.1. Toxicity
12.2. Persistence and degradability
12.3. Bioaccumulative potential
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
12.6. Other adverse effects
13.1. Waste treatment methods
Dispose of waste and residues in accordance with local authority requirements.
14.1. UN number
14.2. UN proper shipping name
14.3. Transport hazard class(es)
ADR/RID/ADN Class Not classified for transportation. Transport Labels
No transport warning sign required.
14.4. Packing group
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant No.
14.6. Special precautions for user
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Guidance Notes
Workplace Exposure Limits EH40. Introduction to Local Exhaust Ventilation HS(G)37. EU Legislation Regulation (EC) No.1272/2008 The Classification, Labelling and Packaging of substances and mixtures Regulations Regulation (EC) No. 1907/2006 The Registration, Evaluation, Authorisation and Restriction of Chemicals Regulations (REACH) 2001/95/EC The General Product Safety Directive (GPSD) Commission Regulation (EU) 2015/830 Requirements for the compilation of safety data sheets (amending REACH) Authorisations (Title VII Regulation 1907/2006) No specific authorisations are noted for this product. Restrictions (Title VIII Regulation 1907/2006)
No specific restrictions of use are noted for this product.
15.2. Chemical Safety Assessment
Revision Date 03/01/2018
Revision 4
Supersedes date 16/08/2016
Hazard Statements In Full
EUH066 Repeated exposure may cause skin dryness or cracking. , H226 Flammable liquid and vapour. , H272 May intensify fire; oxidiser. , H301 Toxic if swallowed. , H304 May be fatal if swallowed and enters airways. , H315 Causes skin irritation. , H317 May cause an allergic skin reaction. , H319 Causes serious eye irritation. , H400 Very toxic to aquatic life. , H411 Toxic to aquatic life with long lasting effects.


according to Regulation (EU) 2020/878
SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking
1.1.Productidentifier
Productname Concentrated Shampoo
1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst ProductUse [SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers); [SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);
Description CarShampoo.
1.3.Detailsofthesupplierofthesafetydatasheet
Company SUPAGARDLIMITED
Address 19-27GavintonStreet Muirend Glasgow G443EF
Web www.supagard.com
Telephone 01416335933
Fax 01416377219
Email James.Smyth@supagard.com
Emailaddressofthe competentperson James.Smyth@supagard.com
1.4.Emergencytelephonenumber
Emergencytelephonenumber01416335933 8.30amto5.00pm
FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)
Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org
SECTION2:Hazardsidentification
2.1.Classificationofthesubstanceormixture
2.1.2.Classification-EC 1272/2008 EyeIrrit.2:H319;
2.2.Labelelements
Hazardpictograms


2.2.Labelelements
HazardStatement
PrecautionaryStatement: Prevention
PrecautionaryStatement: Response
EyeIrrit.2:H319-Causesseriouseyeirritation.
P102-Keepoutofreachofchildren.
P264-Washhandsthoroughlyafterhandling.
P280-Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection.
P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.
P337+P313-Ifeyeirritationpersists:Getmedicaladvice/attention.
SUPPLEMENTALHAZARD INFORMATION IngredientsasrequiredbyRegulation(EC)No648/2004:. 5-15%AnionicSurfactants,CI16035,Parfum,AmylCinnamal,Geraniol,Limonene.
Contains-BenzenesulphonicAcidMonoC10-C13AlkylDerivsSodiumSalts.
2.3.Otherhazards
Otherhazards
Furtherinformation
Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.
RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.
SECTION3:Composition/informationoningredients
3.2.Mixtures
EC1272/2008
ChemicalName
BenzenesulphonicAcidMono C10-C13AlkylDervisSodiumSalts
SECTION4:Firstaidmeasures
4.1.Descriptionoffirstaidmeasures
Inhalation
68411-30-3270-115-001-2119489428-22
Movetheexposedpersontofreshair.
AcuteTox.4:H302;SkinIrrit. 2:H315;EyeDam.1:H318; AquaticChronic3:H412;
Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved.
Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution.
Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.
4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed
Inhalation Maycauseirritationtorespiratorysystem.
Eyecontact Causesseriouseyeirritation.
Skincontact Maycauseirritationtoskin.
Ingestion Maycauseirritationtomucousmembranes.
4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded
Inhalation
Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.
Eyecontact Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.
Skincontact Seekmedicalattentionifirritationorsymptomspersist.
Ingestion Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.
Generalinformation
Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.
5.1.Extinguishingmedia

5.1.Extinguishingmedia
Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.
5.2.Specialhazardsarisingfromthesubstanceormixture
Noneknown.
5.3.Adviceforfirefighters
Furtherinformation
Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.
Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.
6.1.Personalprecautions,protectiveequipmentandemergencyprocedures
6.2.Environmentalprecautions
Wearsuitableprotectiveequipment.
Adviselocalauthoritiesiflargespillscannotbecontained.
6.3.Methodsandmaterialforcontainmentandcleaningup
Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.
6.4.Referencetoothersections
Seesection2,7,8,13forfurtherinformation.
SECTION7:Handlingandstorage
7.1.Precautionsforsafehandling
AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.
7.2.Conditionsforsafestorage,includinganyincompatibilities
Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.
7.3.Specificenduse(s)
Suitablepackaging
8.1.Controlparameters
8.2.Exposurecontrols
Occupationalexposurecontrols. Noworkplaceexposurelimitsapplicable.


AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face

8.2.Exposurecontrols protection.
8.2.1.Appropriateengineering controls
Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.
Eye/faceprotection Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields.
SkinprotectionHandprotection Rubbergloves.
Respiratoryprotection Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.
8.2.3.Environmentalexposure controls Preventfurtherleakageorspillageifsafetodoso.
9.1.Informationonbasicphysicalandchemicalproperties
AppearanceLiquid ColourRed OdourCharacteristic
OdourthresholdNodataavailable pH7
MeltingpointNodataavailable
InitialboilingpointNodataavailable EvaporationrateNodataavailable Flammability(solid,gas)Nodataavailable VapourpressureNodataavailable
RelativeVapourDensityNodataavailable
Density/RelativeDensity1.025-1.03g/cm3
PartitioncoefficientNodataavailable
AutoignitiontemperatureNodataavailable Viscosity<1000centipoise
ExplosivepropertiesNodataavailable
OxidisingpropertiesNodataavailable
SolubilitySolubleinwater
9.2.Otherinformation
ConductivityNodataavailable SurfacetensionNodataavailable
GasgroupNodataavailable BenzeneContentNodataavailable
LeadcontentNodataavailable
VOC(Volatileorganic compounds) Nodataavailable
9.2.1.Informationwithregardtophysicalhazardclasses Nodataisavailableonthisproduct.
9.2.2.Othersafetycharacteristics Nodataisavailableonthisproduct.
10.1.Reactivity
10.2.Chemicalstability
Stableundernormalconditions.

10.2.Chemicalstability
Stableundernormalconditions.
10.3.Possibilityofhazardousreactions
Strongacids.Strongoxidisingagents.
10.4.Conditionstoavoid
10.5.Incompatiblematerials
Protectfromfrost.
Noincompatiblegroupsnoted.
10.6.Hazardousdecompositionproducts
NoHazardousdecompositionproductswhenstoredandhandledcorrectly.
11.1Informationonhazardclasses
Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedusingthemethodsoutlinedinRegulation(EC)No1272/2008(CLP).
Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
OralATE=>10,000mg/kg.
Inhalation-Dust/MistATE=>10,000mg/l.
Skincorrosion/irritation basedonavailabledatatheclassificationcriteriaarenotmet.
Seriouseyedamage/irritationEyeIrrit.2:H319-Causesseriouseyeirritation.
Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.
Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet. Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet. Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet. STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet. Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet. Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.
11.1.2.Mixtures
11.1.3.HazardInformation
11.1.4.ToxicologicalInformation
Nodataavailable.
Nodataavailable.
Nodataavailable
11.2Informationonotherhazards
Nodataisavailableonthisproduct.
12.1.Toxicity
Nodataavailable
12.2.Persistenceanddegradability
SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.
12.3.Bioaccumulativepotential

12.3.Bioaccumulativepotential
Theproductisnotbioaccumulating. Partitioncoefficient
StoneacreConcentratedRed Shampoo Nodataavailable
12.4.Mobilityinsoil
Thisproductissolubleinwater.
12.5.ResultsofPBTandvPvBassessment
Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.
12.6Endocrinedisruptingproperties
Nodataisavailableonthisproduct.
12.7.Otheradverseeffects
Nodataisavailableonthisproduct.
13.1.Wastetreatmentmethods
Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements. Generalinformation
Disposeofincompliancewithalllocalandnationalrequirements. Disposalofpackaging
DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.
14.1.UNnumber
14.2.UNpropershippingname
14.3.Transporthazardclass(es)
14.4.Packinggroup
14.5.Environmentalhazards
14.6.Specialprecautionsforuser
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
14.7MaritimeTransportinbulkaccordingtoIMOinstruments
Theproductisnotclassifiedasdangerousforcarriage.
15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC 2022-12-02Printdate Poweredby Copyright©2022ChemSoft.Allrightsreserved.

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.
COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.
COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).
15.2.Chemicalsafetyassessment
Noinformationavailable.
SECTION16:Otherinformation
Otherinformation
Revision
Thisdocumentdiffersfromthepreviousversioninthefollowingareas:.
2-Otherhazards.
2-Furtherinformation.
2-SUPPLEMENTALHAZARDINFORMATION.
5-5.2.Specialhazardsarisingfromthesubstanceormixture.
5-5.3.Adviceforfirefighters.
9-9.2.2.Othersafetycharacteristics.
9-9.2.1.Informationwithregardtophysicalhazardclasses. 10-10.2.Chemicalstability.
10-10.6.Hazardousdecompositionproducts. 10-10.1.Reactivity.
11-Acutetoxicity.
11-Repeatedorprolongedexposure.
11-11.2Informationonotherhazards.
12-12.1.Toxicity.
12-12.4.Mobilityinsoil.
12-12.3.Bioaccumulativepotential.
12-12.5.ResultsofPBTandvPvBassessment. 12-12.6Endocrinedisruptingproperties.
12-12.7.Otheradverseeffects.
15-Regulations.
Datasources ClassificationandProcedureusedtoderivetheclassificationformixturesaccordingtoRegulation (EC)No.1272/2008,asretainedandamendedinUKlaw.
TextofHazardStatementsin Section3
Furtherinformation
EyeIrrit.2:H319-Causesseriouseyeirritation.-CalculationMethod.
AcuteTox.4:H302-Harmfulifswallowed. SkinIrrit.2:H315-Causesskinirritation.
EyeDam.1:H318-Causesseriouseyedamage. AquaticChronic3:H412-Harmfultoaquaticlifewithlonglastingeffects.
TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.



Compilation date: 03/10/2023
Revision No: 1
Section 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name: BLACK CARPET DYE
Product code: CARPET DYE RESTORER
Synonyms: CARPET DYE RESTORER
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of substance / mixture: PC9a: Coatings and paints, thinners, paint removers.
1.3. Details of the supplier of the safetydata sheet
Companyname: SUPAGARD LIMITED
23 Gavinton Street Muirend Glasgow Scotland G44 3EF
Tel: 0141 633 5933
Email: james@supagard.co.uk
1.4. Emergencytelephone number
Emergencytel: 0141 633 5933 (office hours only)
Section 2: Hazards identification
2.1. Classification of the substance or mixture
Classification under CLP: STOT RE 2: H373; Acute Tox. 4: H302+H332; Aquatic Chronic 3: H412; Eye Irrit. 2: H319; Flam. Liq. 3: H226; Lact.: H362; Skin Irrit. 2: H315; STOT SE 3: H335
Most important adverse effects: Flammable liquid and vapour. Harmful if swallowed or if inhaled Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause harm to breast-fed children. May cause damage to organs through prolonged or repeated exposure. Harmful to aquatic life with long lasting effects.
2.2. Label elements
Label elements:
Hazard statements: H226: Flammable liquid and vapour.
H302+H332: Harmful if swallowed or if inhaled
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
SAFETY DATA SHEET
BLACK CARPET DYE
H362: May cause harm to breast-fed children.
H373: May cause damage to organs through prolonged or repeated exposure.
H412: Harmful to aquatic life with long lasting effects.
Hazard pictograms: GHS02: Flame
GHS07: Exclamation mark
GHS08: Health hazard



Signal words: Warning
Precautionarystatements: P201: Obtain special instructions before use.
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P240: Ground and bond container and receiving equipment.
P241: Use explosion-proof equipment.
P242: Use non-sparking tools.
P243: Take action to prevent static discharges.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P261: Avoid breathing vapours.
P263: Avoid contact during pregnancy and while nursing.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310: IF SWALLOWED: Immediately call a doctor.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P308+P313: IF exposed or concerned: Get medical advice.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P337+P313: If eye irritation persists: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P370+P378: In case of fire: Use dry extinguishing powder to extinguish.
Haz. ingredients (label): Contains: XYLENE; 2-BUTOXYETHANOL; CHLORINATED PARAFFIN
2.3. Other hazards
Other hazards: In use, may form flammable / explosive vapour-air mixture.
PBT: This product is not identified as a PBT/vPvB substance.
Section 3: Composition/information on ingredients
3.2. Mixtures
SAFETY DATA SHEET
BLACK CARPET DYE
Hazardous ingredients:
XYLENE - REACH registered number(s): 01-2119488216-32-XXXX
EINECS CAS PBT / WEL
215-535-7
1330-20-7 -
Flam. Liq. 3: H226; Acute Tox. 4: H332; Acute Tox. 4: H312; Skin Irrit. 2: H315
2-BUTOXYETHANOL - REACH registered number(s): 01-2119475108-36-XXXX
203-905-0 111-76-2 -
ALKANES, C14-17, CHLORO
287-477-0
Acute Tox. 4: H332; Acute Tox. 4: H312; Acute Tox. 4: H302; Eye Irrit. 2: H319; Skin Irrit. 2: H315
85535-85-9 - Lact.: H362; Aquatic Chronic 1: H410; Aquatic Acute 1: H400
ISODECYLOXPROPYLAMINE ACETATE - 28701-67-9 - Acute Tox. 4: H302; Skin Corr. 1: H314; Eye Dam. 1: H318; Aquatic Chronic 1: H410
Section 4: First aid measures
4.1. Description of first aid measures
Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench the affected skin with running water for 10 minutes or longer if substance is still on skin.
Eye contact: Bathe the eye with running water for 15 minutes. Consult a doctor.
Ingestion: Wash out mouth with water. Do not induce vomiting. Drink a large amount of water, and seek medical advice. Consult a doctor.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Consult a doctor in case of complaints
4.2. Most important symptoms and effects, both acute and delayed
Skin contact: There may be irritation and redness at the site of contact.
Eye contact: There may be irritation and redness. The eyes may water profusely.
Ingestion: There may be soreness and redness of the mouth and throat. Nausea and stomach pain may occur. There may be vomiting.
Inhalation: There may be irritation of the throat with a feeling of tightness in the chest.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.
4.3. Indication of anyimmediate medical attention and special treatment needed
Immediate / special treatment: Not applicable.
Section 5: Fire-fighting measures
SAFETY DATA SHEET
BLACK CARPET DYE
5.1. Extinguishing media
Extinguishing media: Alcohol or polymer foam. Carbon dioxide. Dry chemical powder. Use water spray to cool containers.
5.2. Special hazards arising from the substance or mixture
Exposure hazards: Flammable. In combustion emits toxic fumes. Forms explosive air-vapour mixture.
5.3. Advice for fire-fighters
Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.
6.1. Personal precautions, protective equipment and emergencyprocedures
Personal precautions: Refer to section 8 of SDS for personal protection details. If outside do not approach from downwind. If outside keep bystanders upwind and away from danger point. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Turn leaking containers leak-side up to prevent the escape of liquid. Eliminate all sources of ignition.
6.2. Environmental precautions
Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.
6.3. Methods and material for containment and cleaning up
Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method. Do not use equipment in clean-up procedure which may produce sparks.
6.4. Reference to other sections
Reference to other sections: Refer to section 8 of SDS.
storage
7.1. Precautions for safe handling
Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Avoid the formation or spread of mists in the air. Smoking is forbidden. Use non-sparking tools.
7.2. Conditions for safe storage, including anyincompatibilities
Storage conditions: Store in a cool, well ventilated area. Keep container tightly closed. Keep away from sources of ignition. Prevent the build up of electrostatic charge in the immediate area. Ensure lighting and electrical equipment are not a source of ignition.
7.3. Specific end use(s)
Specific end use(s): No data available.
SAFETY DATA SHEET
BLACK CARPET DYE
Section 8: Exposure controls/personal protection
8.1. Control parameters
Hazardous ingredients:
Workplace exposure limits:
DNEL/PNEC Values
DNEL / PNEC No data available.
8.2. Exposure controls
Respirable dust:
Engineering measures: Ensure there is sufficient ventilation of the area. Ensure lighting and electrical equipment are not a source of ignition.
Respiratoryprotection: Self-contained breathing apparatus must be available in case of emergency.
Hand protection: Impermeable gloves.
Eye protection: Safety glasses. Ensure eye bath is to hand.
Skin protection: Impermeable protective clothing.
Environmental: Prevent from entering in public sewers or the immediate environment.
Section 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
State: Liquid
Colour: Black
Odour: Solvents,mixed.
Evaporation rate: Moderate
Oxidising: Non-oxidising (by EC criteria)
Solubilityin water: Not miscible
Also soluble in: Most organic solvents.
Viscosity: Non-viscous
Boiling point/range°C: 117 - 181
Flash point°C: 30
pH: Not applicable.
9.2. Other information
Other information: No data available.
Flammabilitylimits %:lower: 0.8
Relative density: 1.03
VOC g/l: 600 max
SAFETY DATA SHEET
BLACK CARPET DYE
Section 10: Stabilityand reactivity
10.1. Reactivity
Reactivity: Stable under recommended transport or storage conditions.
10.2. Chemical stability
Chemical stability: Stable under normal conditions. Stable at room temperature.
10.3. Possibilityof hazardous reactions
Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions. Decomposition may occur on exposure to conditions or materials listed below.
10.4. Conditions to avoid
Conditions to avoid: Heat. Hot surfaces. Sources of ignition. Flames.
10.5. Incompatible materials
Materials to avoid: Strong oxidising agents. Strong acids.
10.6. Hazardous decomposition products
Haz. decomp. products: In combustion emits toxic fumes.
Section 11: Toxicological information
11.1. Information on toxicological effects
Hazardous ingredients:
Relevant hazards for product:
Acute toxicity (ac. tox. 4)
Skin corrosion/irritation
Serious eye damage/irritation
STOT-single exposure
calculated
calculated
calculated
calculated
STOT-repeated exposure
Excluded hazards for substance:
Germ cell mutagenicity
BLACK CARPET DYE
- Hazardous: calculated
- Based on available data the classification criteria are not met
Carcinogenicity - Based on available data the classification criteria are not met
Reproductive toxicity - Based on available data the classification criteria are not met
Symptoms / routes of exposure
Skin contact: There may be irritation and redness at the site of contact.
Eye contact: There may be irritation and redness. The eyes may water profusely.
Ingestion: There may be soreness and redness of the mouth and throat. Nausea and stomach pain may occur. There may be vomiting.
Inhalation: There may be irritation of the throat with a feeling of tightness in the chest.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.
Section 12: Ecological information
12.1. Toxicity
Ecotoxicityvalues: No data available.
12.2. Persistence and degradability
Persistence and degradability: Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential: No bioaccumulation potential.
12.4. Mobilityin soil
Mobility: Readily absorbed into soil.
12.5. Results of PBT and vPvB assessment
PBT identification: This product is not identified as a PBT/vPvB substance.
12.6. Other adverse effects
Other adverse effects: May cause long term adverse effects to aquatic organisms in continuous exposure conditions.
Section 13: Disposal considerations
13.1. Waste treatment methods
Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.
Waste code number: 20 01 27
SAFETY DATA SHEET
BLACK CARPET DYE
Disposal of packaging: Disposal of waste containers must be done in accordance with local and / or national regulations.
NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.
Section 14: Transport information
14.1. UN number
UN number: UN1263
14.2. UN proper shipping name
Shipping name: PAINT
14.3. Transport hazard class(es)
Transport class: 3
14.4. Packing group
Packing group: III
14.5. Environmental hazards
Environmentallyhazardous: No
14.6. Special precautions for user
Special precautions: No special precautions.
Tunnel code: D/E
Transport category: 3
Section 15: Regulatoryinformation
Marine pollutant: Yes
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Specific regulations: Not applicable.
15.2. Chemical SafetyAssessment
Chemical safetyassessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.
Section 16: Other information
Other information
Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 2015/830.
All substances in this preparation are registered within UK/EU/EFTA countries under the REACH (UK/EC) (ammended) regulations, EC 1907/2006
*indicates text in the SDS which has changed since the last revision.
IMPORTANT NOTE:
Risk phases in this section belowrelate to the INDIVIDUAL COMPONENTS in the
SAFETY DATA SHEET
BLACK CARPET DYE
formulation when used at their FULL CONCENTRATIONS, and not at the reduced levels in the mixed product.
Phrases used in s.2 and s.3: H226: Flammable liquid and vapour.
H302: Harmful if swallowed.
H302+H332: Harmful if swallowed or if inhaled
H312: Harmful in contact with skin.
H314: Causes severe skin burns and eye damage.
H315: Causes skin irritation.
H318: Causes serious eye damage.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
H362: May cause harm to breast-fed children.
H373: May cause damage to organs through prolonged or repeated exposure.
H410: Very toxic to aquatic life with long lasting effects.
H412: Harmful to aquatic life with long lasting effects.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.


according to Regulation (EU) 2020/878
SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking
1.1.Productidentifier
Productname Silicone Free Dash & Door
1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst
ProductUse
[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC35]Washingand cleaningproducts(includingsolventbasedproducts);
[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC35]Washingandcleaningproducts(includingsolventbasedproducts); Description VehicleDash&DoorCleaner.
1.3.Detailsofthesupplierofthesafetydatasheet
Company SUPAGARDLIMITED
Address 19-27GavintonStreet Muirend Glasgow G443EF
Web www.supagard.com
Telephone 01416335933
Fax 01416377219
Email James.Smyth@supagard.com
Emailaddressofthe competentperson James.Smyth@supagard.com
1.4.Emergencytelephonenumber
Emergencytelephonenumber01416335933 8.30amto5.00pm
FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)
Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org
SECTION2:Hazardsidentification
2.1.Classificationofthesubstanceormixture
2.1.2.Classification-EC 1272/2008
2.2.Labelelements
Thisproductdoesnotmeetthecriteriaforclassificationinanyhazardclassaccordingto Regulation(EC)No.1272/2008onclassification,labellingandpackagingofsubstancesand mixtures.
PrecautionaryStatement: Prevention P102-Keepoutofreachofchildren.
PrecautionaryStatement: Response P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.

2.2.Labelelements
P337+P313-Ifeyeirritationpersists:Getmedicaladvice/attention.
HazardStatement NoSignificantHazard
SUPPLEMENTALHAZARD INFORMATION ingredients-Lessthan5%Non-ionicSurfactants,Preservative:Benzisothiazolinone,Parfum, Linalool.
Contains-Glycerol,2-butoxyethanol.
2.3.Otherhazards
Otherhazards Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.
Furtherinformation
RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.
SECTION3:Composition/informationoningredients
3.2.Mixtures
EC1272/2008 ChemicalName
603-014-00-0111-76-2203-905-001-2119475108-36
SECTION4:Firstaidmeasures
4.1.Descriptionoffirstaidmeasures
Inhalation
Movetheexposedpersontofreshair.
AcuteTox.4:H332;Acute Tox.4:H312;AcuteTox.4: H302;EyeIrrit.2:H319;Skin Irrit.2:H315; 1-10%
Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved.
Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution.
Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.
4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed
Inhalation Maycauseirritationtorespiratorysystem.
Eyecontact Maycauseirritationtoeyes.
Skincontact Maycauseskindrynessandirritation.
Ingestion Maycauseirritationtomucousmembranes.
4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded TREATSYMPTOMATICALLY.
Inhalation Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.
Eyecontact Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.
Skincontact Seekmedicalattentionifirritationorsymptomspersist.
Ingestion Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.
Generalinformation
Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.
5.1.Extinguishingmedia
Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.

5.2.Specialhazardsarisingfromthesubstanceormixture
Noneknown.
5.3.Adviceforfirefighters
Furtherinformation
Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.
Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.
SECTION6:Accidentalreleasemeasures
6.1.Personalprecautions,protectiveequipmentandemergencyprocedures
6.2.Environmentalprecautions
Wearsuitableprotectiveequipment.
Adviselocalauthoritiesiflargespillscannotbecontained.
6.3.Methodsandmaterialforcontainmentandcleaningup
Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.
6.4.Referencetoothersections
Seesection2,7,8,13forfurtherinformation.
7.1.Precautionsforsafehandling
AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.
7.2.Conditionsforsafestorage,includinganyincompatibilities
Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.
7.3.Specificenduse(s)
Suitablepackaging
VehicleDash&DoorCleaner.
Plasticcontainers.
8.1.Controlparameters
8.1.1.ExposureLimitValues
Occupationalexposurecontrols.

8.1.1.ExposureLimitValues
2-butoxyethanol
Glycerol(Glycerol,mist)
WEL8-hrlimitppm:25
WEL15minlimitppm:50
WEL8-hrlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: -
WEL8-hrlimitppm:-
WEL15minlimitppm:-
WEL8-hrlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: -
DNEL:Derivedno-effectlevel.
ExposurePattern-Workers
2-butoxyethanol
Glycerol
Acuteinhalation-Systemic effects 1091mg/m³
Acuteinhalation-Localeffects246mg/m³
Long-term-inhalation-Systemic effects 98mg/m³
Long-term-inhalation-Local effects 56mg/m³
ExposurePattern-Generalpopulation
2-butoxyethanol
Glycerol
8.2.Exposurecontrols
Acuteinhalation-Systemic effects 426mg/m³
Acutedermal-Systemiceffects89mg/kg
Long-term-inhalation-Systemic effects 59mg/m³
Long-term-dermal-Systemic effects 75mg/kg
Long-term-inhalation-Local effects 33mg/m³
Long-term-oral-Systemic effects 229mg/kg


8.2.1.Appropriateengineering controls
Eye/faceprotection
WEL8-hrlimitmg/m3:123
WEL15minlimitmg/m3:101.2
WEL15minlimitmg/m3total inhalabledust: -
WEL15minlimitmg/m3total respirabledust: -
WEL8-hrlimitmg/m3:10
WEL15minlimitmg/m3:-
WEL15minlimitmg/m3total inhalabledust: -
WEL15minlimitmg/m3total respirabledust: -
Acutedermal-Systemiceffects89mg/kg
Long-term-dermal-Systemic effects 125mg/kg
Acuteoral-Systemiceffects26.7mg/kg
Long-term-inhalation-Local effects 147mg/m³
Long-term-oral-Systemiceffects6.3mg/kg
AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.
Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.
Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields. Eyewearcomplyingwithanapprovedstandardshouldbewornifariskassessmentindicateseye contactispossible.Thefollowingprotectionshouldbeworn:Wearchemicalsplashgoggles. PersonalprotectiveequipmentforeyeandfaceprotectionshouldcomplywithEuropeanStandard EN166.

8.2.Exposurecontrols
SkinprotectionHandprotection
Rubbergloves.Chooseglovestoprotecthandsagainstchemicalsdependingontheconcentration andquantityofthehazardoussubstanceandspecifictoplaceofwork.Forspecialapplications, werecommendclarifyingtheresistancetochemicalsoftheaforementionedprotectivegloveswith theglovemanufacturer.
Skinprotection-Other Wearsuitablegloves. Respiratoryprotection Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.
8.2.3.Environmentalexposure controls
Preventfurtherleakageorspillageifsafetodoso.
9.1.Informationonbasicphysicalandchemicalproperties
AppearanceLiquid
ColourWhite/Offwhite OdourPleasant
InitialboilingpointNodataavailable
FlashpointNodataavailable
EvaporationrateNodataavailable
Flammability(solid,gas)Nodataavailable
VapourpressureNodataavailable
RelativeVapourDensityNodataavailable Density/RelativeDensity1-1.01(H2O=1@20°C)
PartitioncoefficientNodataavailable
AutoignitiontemperatureNodataavailable
Viscosity<100centipoise
ExplosivepropertiesNodataavailable
OxidisingpropertiesNodataavailable OdourthresholdNodataavailable pH4-6
MeltingpointNodataavailable
SolubilitySolubleinwater
9.2.Otherinformation
ConductivityNodataavailable
SurfacetensionNodataavailable GasgroupNodataavailable BenzeneContentNodataavailable
LeadcontentNodataavailable
VOC(Volatileorganic compounds) Nodataavailable
9.2.1.Informationwithregardtophysicalhazardclasses Nodataavailable.
9.2.2.Othersafetycharacteristics Nodataavailable.
10.1.Reactivity
10.2.Chemicalstability
Stableundernormalconditions.

10.2.Chemicalstability
Stableundernormalconditions.
10.3.Possibilityofhazardousreactions
Noneknown.
10.4.Conditionstoavoid
10.5.Incompatiblematerials
Protectfromfrost.
Strongacids.Strongoxidisingagents.
10.6.Hazardousdecompositionproducts
NoHazardousdecompositionproductswhenstoredandhandledcorrectly.
11.1Informationonhazardclasses
Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedusingthemethodsoutlinedinRegulation(EC)No1272/2008(CLP).
Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
OralATE=>10,000mg/kg.
DermalATE=>10,000mg/kg.
Inhalation-Dust/MistATE=>20mg/l.
Inhalation-VapoursATE=>20mg/l.
Skincorrosion/irritation basedonavailabledatatheclassificationcriteriaarenotmet.
Seriouseyedamage/irritationbasedonavailabledatatheclassificationcriteriaarenotmet.
Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.
Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet.
Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.
Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet. STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.
Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet.
Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.
11.1.2.Mixtures
11.1.3.HazardInformation
11.1.4.ToxicologicalInformation 2-butoxyethanol
Glycerol
11.2Informationonotherhazards
Nodataavailable.
Nodataavailable.
InhalationRatLC50/1h:>3.1mg/l
OralRatLD50:1200mg/kg
OralRatLD50:27,200.0mg/kg
Nodataavailable.
12.1.Toxicity

DermalRatLD50:>2000mg/kg
InhalationRatLC50/4h:11.0mg/l (vapours)
12.1.Toxicity
2-butoxyethanol
Glycerol
12.2.Persistenceanddegradability
12.3.Bioaccumulativepotential
Partitioncoefficient
DaphniaEC50/48h:1550.0000mg/l
RainbowtroutLC50/96h:1474mg/l
EC50formarineorfreshwater organisms >100.0000mg/l
DaphniaEC50/48h:10000.0000mg/l
FatheadminnowsLC50/96h= >=885mg/l:
AlgaeEC50/72h:1840mg/
LC50formarineorfreshwater organisms >100.0000mg/l
AlgaeEC50/72h:>2900mg/l
RainbowtroutLC50/96h:54000mg/l
SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.
Nodataisavailableonthisproduct.
12.4.Mobilityinsoil
Thisproductissolubleinwater.
12.6Endocrinedisruptingproperties
Nodataavailable.
12.7.Otheradverseeffects
Nodataisavailableonthisproduct.
13.1.Wastetreatmentmethods
Generalinformation
Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.
Disposeofincompliancewithalllocalandnationalrequirements. Disposalofpackaging
DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.
14.1.UNnumber
14.2.UNpropershippingname
14.3.Transporthazardclass(es)
14.4.Packinggroup
14.5.Environmentalhazards
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.

14.6.Specialprecautionsforuser
Theproductisnotclassifiedasdangerousforcarriage.
14.7MaritimeTransportinbulkaccordingtoIMOinstruments
Theproductisnotclassifiedasdangerousforcarriage.
15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations
REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.
COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.
COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).
15.2.Chemicalsafetyassessment
Noinformationavailable.
SECTION16:Otherinformation
Otherinformation
TextofHazardStatementsin Section3
Furtherinformation
AcuteTox.4:H302+H312+H332-Harmfulifswallowed,incontactwithskinorifinhaled
SkinIrrit.2:H315-Causesskinirritation.
EyeIrrit.2:H319-Causesseriouseyeirritation.
TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.



SAFETY DATASHEET
Compilation date: 24/11/2021
Revision date: 14/05/2024
DIESEL FUEL ADDITIVE Page: 1
Revision No: 3
Section 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name: DIESEL FUEL ADDITIVE
Product code: HC1713
Synonyms: PD0418
HC1713 / SUP
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of substance / mixture: PC13: Fuels.
1.3. Details of the supplier of the safetydata sheet
Companyname: SUPAGARD LIMITED
23 Gavinton Street Muirend Glasgow Scotland G44 3EF
Tel: 0141 633 5933
Email: james@supagard.co.uk
1.4. Emergencytelephone number
Emergencytel: 0141 633 5933 (office hours only)
Section 2: Hazards identification
2.1. Classification of the substance or mixture
Classification under CLP: Aquatic Chronic 3: H412; Skin Sens. 1B: H317; STOT SE 3: H336; Asp. Tox. 1: H304
Most important adverse effects: May be fatal if swallowed and enters airways. May cause an allergic skin reaction. May cause drowsiness or dizziness. Harmful to aquatic life with long lasting effects.
2.2. Label elements
Label elements:
Hazard statements: H304: May be fatal if swallowed and enters airways.
H317: May cause an allergic skin reaction.
H336: May cause drowsiness or dizziness.
H412: Harmful to aquatic life with long lasting effects.
Hazard pictograms: GHS07: Exclamation mark
GHS08: Health hazard
DIESEL FUEL ADDITIVE


Signal words: Danger
Precautionarystatements: P102: Keep out of reach of children.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor.
P331: Do NOT induce vomiting.
P302+P350: IF ON SKIN: Gently wash with plenty of soap and water.
P403+P233: Store in a well-ventilated place. Keep container tightly closed.
P501: Dispose of contents and container to a hazardous or special waste collection point.
Haz. ingredients (label): HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS; HYDROCARBONS, C10, AROMATICS, >1% NAPHTHALENE; 1H-BENZOTRIAZOLE-1-METHANAMINE (MIXED REACTION MASS ISOMERS)
2.3. Other hazards
PBT: This product is not identified as a PBT/vPvB substance.
Section 3: Composition/information on ingredients
3.2. Mixtures
Hazardous ingredients: HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS - REACH registered number(s): 01-2119456620-43XXXX
926-141-6 64742-47-8 - Asp. Tox. 1: H304; -: EUH066
HYDROCARBONS, C10, AROMATICS, >1% NAPHTHALENE - REACH registered number(s): 01-2119463588-24-XXXX
919-284-0 - - STOT SE 3: H336; Aquatic Chronic 2: H411; Carc. 2: H351; Asp. Tox. 1: H304
C7-9-ALKYL-3-(3,5-DI-TET-BUTYL-4-HYDOXYPHENYL)PROPIONATE - REACH registered number(s): 012119873226-29-XXXX - 125643-6110 - Aquatic Chronic 4: H413
2-ETHYLHEXAN-1-OL - REACH registered number(s): 1-2119487289-20-XXXX
203-234-3 104-76-7 - Skin Irrit. 2: H315; STOT SE 3: H335; Acute Tox. 4: H332; Eye Irrit. 2: H319
1H-BENZOTRIAZOLE-1-METHANAMINE (MIXED REACTION MASS ISOMERS) - REACH registered number(s): 12119982395-25-XXXX
939-700-4 - -
Section 4: First aid measures
4.1. Description of first aid measures
Skin Irrit. 2: H315; Skin Sens. 1B: H317; Aquatic Acute 1: H400; Aquatic Chronic 2: H411
Skin contact: Wash immediately with plenty of soap and water.
Eye contact: Bathe the eye with running water for 15 minutes.
Ingestion: Wash out mouth with water. Do not induce vomiting. If conscious, give half a litre of water to drink immediately. Transfer to hospital as soon as possible.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Move to fresh air in case of accidental inhalation of vapours. Consult a doctor.
4.2. Most important symptoms and effects, both acute and delayed
Skin contact: There may be mild irritation at the site of contact.
Eye contact: There may be irritation and redness.
Ingestion: There may be soreness and redness of the mouth and throat. There may be difficulty swallowing. Nausea and stomach pain may occur. There may be vomiting.
Inhalation: Absorption through the lungs can occur causing symptoms similar to those of ingestion.
4.3. Indication of anyimmediate medical attention and special treatment needed
Section 5: Fire-fighting measures
5.1. Extinguishing media
Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers.
5.2. Special hazards arising from the substance or mixture
Exposure hazards: In combustion emits toxic fumes.
5.3. Advice for fire-fighters
Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.
Section 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergencyprocedures
Personal precautions: Refer to section 8 of SDS for personal protection details. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Turn leaking containers leak-side up to prevent the escape of liquid.
6.2. Environmental precautions
Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.
6.3. Methods and material for containment and cleaning up
Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method. Wash the ground with an appropriate selfemulsifying solvent.
6.4. Reference to other sections
Section 7: Handling and storage
7.1. Precautions for safe handling
Handling requirements: Avoid the formation or spread of mists in the air. Avoid direct contact with the substance.
7.2. Conditions for safe storage, including anyincompatibilities
Storage conditions: Store in a cool, well ventilated area. Keep container tightly closed.
7.3. Specific end use(s)
Section 8: Exposure controls/personal protection
8.1. Control parameters
Hazardous ingredients:
HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS
Workplace exposure limits:
1200 mg/cm3
HYDROCARBONS, C10, AROMATICS, >1%NAPHTHALENE
UK Not established
DNEL/PNEC Values
DNEL / PNEC No data available.
8.2. Exposure controls
Respirable dust:
Engineering measures: Ensure there is sufficient ventilation of the area.
Respiratoryprotection: Respiratory protection not required.
Hand protection: Protective gloves.
Eye protection: Safety glasses. Ensure eye bath is to hand.
Skin protection: Protective clothing.
Section 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
State: Liquid
Colour: Pale yellow
Odour: Paraffinic
Evaporation rate: Slow
Solubilityin water: Insoluble
Viscosity: Non-viscous
Boiling point/range°C: >100
Melting point/range°C: No data available.
Flammabilitylimits %:lower: 0.6 upper: 7.0
Flash point°C: 68
Autoflammability°C: No data available.
pH: Not applicable.
Part.coeff. n-octanol/water: No data available.
Relative density: 0.810
VOC g/l: No data available.
9.2. Other information
Other information: No data available.
Section 10: Stabilityand reactivity
10.1. Reactivity
Reactivity: Stable under recommended transport or storage conditions.
10.2. Chemical stability
Chemical stability: Stable under normal conditions.
10.3. Possibilityof hazardous reactions
Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.
10.4. Conditions to avoid
Conditions to avoid: Heat.
10.5. Incompatible materials
Materials to avoid: Strong oxidising agents. Strong acids.
10.6. Hazardous decomposition products
Haz. decomp. products: In combustion emits toxic fumes.
Section 11: Toxicological information
11.1. Information on toxicological effects
Hazardous ingredients:
HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS
ORAL RAT
mg/kg
VAPOURS RAT 4H LC50 >5000 mg/kg
HYDROCARBONS, C10, AROMATICS, >1%NAPHTHALENE
DERMAL HMN LD50 Lowacute -
ORAL HMN LD50 Lowacute -
VAPOURS HMN LD50 Lowacute -
Relevant hazards for product:
Respiratory/skin sensitisation - Hazardous: calculated
STOT-single exposure - Hazardous: calculated
Aspiration hazard - Hazardous: calculated
Symptoms / routes of exposure
Skin contact: There may be mild irritation at the site of contact.
Eye contact: There may be irritation and redness.
Ingestion: There may be soreness and redness of the mouth and throat. There may be difficulty swallowing. Nausea and stomach pain may occur. There may be vomiting.
Inhalation: Absorption through the lungs can occur causing symptoms similar to those of ingestion.
Section 12: Ecological information
12.1. Toxicity
Hazardous ingredients:
HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS
Daphnia magna 48H EC50 >250 mg/l
RAINBOW TROUT (Oncorhynchus mykiss) 96H LC50 >1000 mg/l
HYDROCARBONS, C10, AROMATICS, >1%NAPHTHALENE
DAPHNIA 48H EC50 <10 mg/l
RAINBOW TROUT (Oncorhynchus mykiss) 96H LC50
12.2. Persistence and degradability
Persistence and degradability: Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential: No bioaccumulation potential.
12.4. Mobilityin soil
mg/l
Mobility: Readily absorbed into soil. Volatile. Insoluble in water. Floats on water. Vapour is heavier than air.
DIESEL FUEL ADDITIVE
12.5. Results of PBT and vPvB assessment
PBT identification: This product is not identified as a PBT/vPvB substance.
12.6. Other adverse effects
Other adverse effects: Harmful to aquatic organisms.
Section 13: Disposal considerations
13.1. Waste treatment methods
Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.
Recoveryoperations: Solvent reclamation/regeneration.
Waste code number: 20 01 13
Disposal of packaging: Dispose of as normal industrial waste. Clean with water.
NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.
Section 14: Transport information
Transport class: This product does not require a classification for transport.
Section 15: Regulatoryinformation
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Specific regulations: Not applicable.
15.2. Chemical SafetyAssessment
Chemical safetyassessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.
Section 16: Other information
Other information
Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 2015/830.
IMPORTANT NOTE:
Risk phases in this section belowrelate to the INDIVIDUAL COMPONENTS in the formulation when used at their FULL CONCENTRATIONS, and not at the reduced levels in the mixed product.
See sections 2 and 3 for the calculated hazard and risk phrases for the blended product. Phrases used in s.2 and s.3: EUH066: Repeated exposure may cause skin dryness or cracking.
H304: May be fatal if swallowed and enters airways.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
H336: May cause drowsiness or dizziness.
H351: Suspected of causing cancer (if inhaled).
H400: Very toxic to aquatic life.
H411: Toxic to aquatic life with long lasting effects.
H412: Harmful to aquatic life with long lasting effects.
H413: May cause long lasting harmful effects to aquatic life.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.


ENGINE FLUSH
Section 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name: ENGINE FLUSH
Product code: HC1714
Synonyms: HC1714 / SUP PD0408
1.2. Relevant identified uses of the substance or mixture and uses advised against
Page: 1
Compilation date: 24/11/2021
Revision date: 14/05/2024
Revision No: 2
Use of substance / mixture: PC35: Washing and cleaning products (including solvent based products).
1.3. Details of the supplier of the safetydata sheet
Companyname: SUPAGARD LIMITED 23 Gavinton Street Muirend Glasgow Scotland G44 3EF
Tel: 0141 633 5933
Email: james@supagard.co.uk
1.4. Emergencytelephone number
Emergencytel: 0141 633 5933 (office hours only)
Section 2: Hazards identification
2.1. Classification of the substance or mixture
Classification under CLP: Asp. Tox. 1: H304; -: EUH066
Most important adverse effects: Repeated exposure may cause skin dryness or cracking. May be fatal if swallowed and enters airways.
2.2. Label elements
Label elements:
Hazard statements: EUH066: Repeated exposure may cause skin dryness or cracking. H304: May be fatal if swallowed and enters airways.
Hazard pictograms: GHS08: Health hazard

ENGINE FLUSH
Signal words: Danger
Precautionarystatements: P102: Keep out of reach of children.
P260: Do not breathe vapours.
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor.
P331: Do NOT induce vomiting.
P302+P350: IF ON SKIN: Gently wash with plenty of soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Haz. ingredients (label): Contains: HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS
2.3. Other hazards
PBT: This product is not identified as a PBT/vPvB substance.
Section 3: Composition/information on ingredients
3.2. Mixtures
Hazardous ingredients:
HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS - REACH registered number(s): 01-2119456620-43XXXX
64742-47-8 - Asp. Tox. 1: H304; -: EUH066
(2-METHOXY METHYL ETHOXY) PROPANOL - REACH registered number(s): 01-2119450011-60-XXXX 252-104-2 34590-94-8 Substance with a Community workplace exposure limit. -
Section 4: First aid measures
4.1. Description of first aid measures
Skin contact: Wash immediately with plenty of soap and water.
Eye contact: Bathe the eye with running water for 15 minutes.
Ingestion: Wash out mouth with water. Do not induce vomiting. If conscious, give half a litre of water to drink immediately. Transfer to hospital as soon as possible.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Move to fresh air in case of accidental inhalation of vapours. Consult a doctor.
4.2. Most important symptoms and effects, both acute and delayed
Skin contact: There may be mild irritation at the site of contact.
Eye contact: There may be irritation and redness.
Ingestion: There may be soreness and redness of the mouth and throat. There may be difficulty swallowing. Nausea and stomach pain may occur. There may be vomiting.
Inhalation: Absorption through the lungs can occur causing symptoms similar to those of ingestion.
4.3. Indication of anyimmediate medical attention and special treatment needed
Section 5: Fire-fighting measures
5.1. Extinguishing media
Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers.
5.2. Special hazards arising from the substance or mixture
Exposure hazards: In combustion emits toxic fumes.
5.3. Advice for fire-fighters
Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.
Section 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergencyprocedures
Personal precautions: Refer to section 8 of SDS for personal protection details. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Turn leaking containers leak-side up to prevent the escape of liquid.
6.2. Environmental precautions
Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.
6.3. Methods and material for containment and cleaning up
Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method. Wash the spillage site with large amounts of water.
6.4. Reference to other sections
Section 7: Handling and storage
7.1. Precautions for safe handling
Handling requirements: Avoid the formation or spread of mists in the air. Avoid direct contact with the substance.
7.2. Conditions for safe storage, including anyincompatibilities
Storage conditions: Store in a cool, well ventilated area. Keep container tightly closed.
7.3. Specific end use(s)
Section 8: Exposure controls/personal protection
8.1. Control parameters
ENGINE FLUSH
Hazardous ingredients:
HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS
Workplace exposure limits: State
UK 1200 mg/cm3
(2-METHOXY METHYL ETHOXY) PROPANOL
UK 308mg/m3(50ppm)
DNEL/PNEC Values
DNEL / PNEC No data available.
8.2. Exposure controls
Respirable dust:
Engineering measures: Ensure there is sufficient ventilation of the area.
Respiratoryprotection: Respiratory protection not required.
Hand protection: Protective gloves.
Eye protection: Safety glasses. Ensure eye bath is to hand.
Skin protection: Protective clothing.
Section 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
State: Liquid
Colour: Colourless
Odour: Paraffinic
Evaporation rate: Slow
Solubilityin water: Emulsifiable
Viscosity: Non-viscous
Boiling point/range°C: 190 - 280
Melting point/range°C: No data available.
Flammabilitylimits %:lower: 0.9 upper: 9.0
Flash point°C: 60 - 93
Autoflammability°C: >200
Part.coeff. n-octanol/water: No data available.
Vapour pressure: No data available.
Relative density: 0.815 pH: Not applicable.
VOC g/l: No data available.
9.2. Other information
Other information: No data available.
Section 10: Stabilityand reactivity
10.1. Reactivity
Reactivity: Stable under recommended transport or storage conditions.
10.2. Chemical stability
Chemical stability: Stable under normal conditions.
10.3. Possibilityof hazardous reactions
Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.
10.4. Conditions to avoid
Conditions to avoid: Heat.
10.5. Incompatible materials
Materials to avoid: Strong oxidising agents. Strong acids.
10.6. Hazardous decomposition products
Haz. decomp. products: In combustion emits toxic fumes.
Section 11: Toxicological information
11.1. Information on toxicological effects
Hazardous ingredients:
HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS
DERMAL RBT LD50 >5000 mg/kg
ORAL RAT LD50 >5000 mg/kg
VAPOURS RAT 4H LC50 >5000 mg/kg
(2-METHOXY METHYL ETHOXY) PROPANOL
ORL RAT
Relevant hazards for product:
Aspiration hazard - Hazardous: calculated
Symptoms / routes of exposure
Skin contact: There may be mild irritation at the site of contact.
Eye contact: There may be irritation and redness.
Ingestion: There may be soreness and redness of the mouth and throat. There may be difficulty swallowing. Nausea and stomach pain may occur. There may be vomiting.
Inhalation: Absorption through the lungs can occur causing symptoms similar to those of ingestion.
Section 12: Ecological information
12.1. Toxicity
Hazardous ingredients:
HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS
Daphnia magna
RAINBOW TROUT (Oncorhynchus mykiss)
(2-METHOXY METHYL ETHOXY) PROPANOL BLUEGILLS
12.2. Persistence and degradability
Persistence and degradability: Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential: No bioaccumulation potential.
12.4. Mobilityin soil
EC50
Mobility: Readily absorbed into soil. Volatile. Soluble in water. Vapour is heavier than air.
12.5. Results of PBT and vPvB assessment
PBT identification: This product is not identified as a PBT/vPvB substance.
12.6. Other adverse effects
Other adverse effects: Negligible ecotoxicity.
Section 13: Disposal considerations
13.1. Waste treatment methods
Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.
Recoveryoperations: Solvent reclamation/regeneration.
Waste code number: 20 01 13
Disposal of packaging: Dispose of as normal industrial waste. Clean with water.
NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.
Section 14: Transport information
Transport class: This product does not require a classification for transport.
Section 15: Regulatoryinformation
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Specific regulations: Not applicable.
15.2. Chemical SafetyAssessment
Chemical safetyassessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.
Section 16: Other information
Other information
Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 2015/830.
IMPORTANT NOTE:
Risk phases in this section belowrelate to the INDIVIDUAL COMPONENTS in the formulation when used at their FULL CONCENTRATIONS, and not at the reduced levels in the mixed product.
See sections 2 and 3 for the calculated hazard and risk phrases for the blended product.
Phrases used in s.2 and s.3: EUH066: Repeated exposure may cause skin dryness or cracking.
H304: May be fatal if swallowed and enters airways.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.


SAFETY DATASHEET
EXTERIOR SHINE PLUS Page: 1
Section 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name: EXTERIOR SHINE PLUS
Product code: HC8560
Synonyms: HC8560
PD1137
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of substance / mixture: Aerosol cleaner and polish.
1.3. Details of the supplier of the safetydata sheet
Companyname: SUPAGARD LIMITED
23 Gavinton Street
Muirend Glasgow Scotland G44 3EF
Tel: 0141 633 5933
Email: james@supagard.co.uk
1.4. Emergencytelephone number
Emergencytel: 0141 633 5933 (office hours only)
Section 2: Hazards identification
2.1. Classification of the substance or mixture
Classification under CLP: Flam. Aerosol 1: H222; -: EUH066; -: EUH208; -: H229
Compilation date: 19/11/2024
Revision No: 1
Most important adverse effects: Repeated exposure may cause skin dryness or cracking. Contains perfume (containing: linalool,linalyl acetate, benzyl salicylate, limonene). May produce an allergic reaction. Extremely flammable aerosol. Pressurised container: May burst if heated.
2.2. Label elements
Label elements:
Hazard statements: EUH066: Repeated exposure may cause skin dryness or cracking.
EUH208: Contains perfume (containing: linalool,linalyl acetate, benzyl salicylate, limonene). May produce an allergic reaction.
H222: Extremely flammable aerosol.
H229: Pressurised container: May burst if heated.
EXTERIOR SHINE PLUS
Hazard pictograms: GHS02: Flame

Signal words: Danger
Precautionarystatements: P102: Keep out of reach of children.
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P211: Do not spray on an open flame or other ignition source.
P251: Do not pierce or burn, even after use.
P410+P412: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
2.3. Other hazards
Other hazards: In use, may form flammable / explosive vapour-air mixture.
PBT: This product is not identified as a PBT/vPvB substance.
Section 3: Composition/information on ingredients
3.2. Mixtures
Hazardous ingredients:
HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS - REACH registered number(s): 01-2119456620-43XXXX
BUTANE, <0.1% 1,3 BUTADIENE - REACH registered number(s): 01-2119474691-32-XXXX 203-448-7 106-97-8 Substance with a Community workplace exposure limit.
PROPANE, <0.1% 1,3 BUTADIENE - REACH registered number(s): 01-2119486944-21-XXXX
200-827-9 74-98-6 Substance with a Community workplace exposure limit. Flam. Gas 1: H220; Press. Gas: H280
PERFUME NEW CAR 445 (CONTAINING: LINALOOL,LINALYL ACETATE, BENZYL SALICYLATE, LIMONENE)
- - - Skin Sens. 1: H317; Aquatic Chronic 2: H411; Skin Irrit. 2: H315; Eye Irrit. 2: H319; Asp. Tox. 1: H304
Section 4: First aid measures
4.1. Description of first aid measures
Skin contact: Wash immediately with plenty of soap and water. Eye contact: Bathe the eye with running water for 15 minutes.
Ingestion: Wash out mouth with water. Do not induce vomiting. If conscious, give half a litre of water to drink immediately.
EXTERIOR SHINE PLUS
Inhalation: Consult a doctor in case of complaints
4.2. Most important symptoms and effects, both acute and delayed
Skin contact: There may be mild irritation at the site of contact.
Eye contact: There may be irritation and redness.
Ingestion: There may be irritation of the throat.
Inhalation: No symptoms.
4.3. Indication of anyimmediate medical attention and special treatment needed
Immediate / special treatment: Not applicable.
Section 5: Fire-fighting measures
5.1. Extinguishing media
Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers. Alcohol resistant foam. Carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Exposure hazards: In combustion emits toxic fumes. Highly flammable.
5.3. Advice for fire-fighters
Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.
Section 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergencyprocedures
Personal precautions: Refer to section 8 of SDS for personal protection details. Turn leaking containers leakside up to prevent the escape of liquid.
6.2. Environmental precautions
Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.
6.3. Methods and material for containment and cleaning up
Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method.
6.4. Reference to other sections
Reference to other sections: Refer to section 8 of SDS.
Section 7: Handling and storage
7.1. Precautions for safe handling
Handling requirements: Smoking is forbidden. Use non-sparking tools. Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Avoid the formation or spread of mists in the air.
EXTERIOR SHINE PLUS
7.2. Conditions for safe storage, including anyincompatibilities
Storage conditions: Store in a cool, well ventilated area. Keep container tightly closed.
7.3. Specific end use(s)
Specific end use(s): No data available.
Section 8: Exposure controls/personal protection
8.1. Control parameters
Hazardous ingredients:
Workplace
Respirable dust:
<0.1%1,3 BUTADIENE
<0.1%1,3 BUTADIENE UK Asphyxiating Asphyxiating
DNEL/PNEC Values
DNEL / PNEC No data available.
8.2. Exposure controls
Engineering measures: Ensure there is sufficient ventilation of the area. Ensure lighting and electrical equipment are not a source of ignition.
Respiratoryprotection: Respiratory protection not required.
Hand protection: Protective gloves.
Eye protection: Safety glasses. Ensure eye bath is to hand.
Skin protection: Protective clothing.
Section 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
State: Aerosol
Colour: White
Odour: Perfumed
Evaporation rate: Slow
Solubilityin water: Emulsifiable
Viscosity: Non-viscous
Boiling point/range°C: No data available.
Melting point/range°C: No data available.
Flammabilitylimits %:lower: 0.9 upper: 9.0
Flash point°C: -40
Autoflammability°C: >230
EXTERIOR SHINE PLUS
Part.coeff. n-octanol/water: No data available.
Vapour pressure: No data available.
Relative density: No data available. pH: Not applicable.
VOC g/l: No data available.
9.2. Other information
Other information: No data available.
Section 10: Stabilityand reactivity
10.1. Reactivity
Reactivity: Stable under recommended transport or storage conditions.
10.2. Chemical stability
Chemical stability: Stable under normal conditions.
10.3. Possibilityof hazardous reactions
Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions. Decomposition may occur on exposure to conditions or materials listed below.
10.4. Conditions to avoid
Conditions to avoid: Heat. Sources of ignition. Flames.
10.5. Incompatible materials
Materials to avoid: Strong oxidising agents. Strong acids.
10.6. Hazardous decomposition products
Haz. decomp. products: In combustion emits toxic fumes.
Section 11: Toxicological information
11.1. Information on toxicological effects
Hazardous ingredients: HYDROCARBONS,
Toxicityvalues: No data available.
Symptoms / routes of exposure
Skin contact: There may be mild irritation at the site of contact.
Eye contact: There may be irritation and redness.
Ingestion: There may be irritation of the throat.
Inhalation: No symptoms.
EXTERIOR SHINE PLUS
Section 12: Ecological information
12.1. Toxicity
Hazardous ingredients:
HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS
Daphnia magna
RAINBOW TROUT (Oncorhynchus mykiss)
12.2. Persistence and degradability
Persistence and degradability: Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential: No bioaccumulation potential.
12.4. Mobilityin soil
EC50
LC50
Mobility: Readily absorbed into soil.
12.5. Results of PBT and vPvB assessment
PBT identification: This product is not identified as a PBT/vPvB substance.
12.6. Other adverse effects
Other adverse effects: Negligible ecotoxicity.
Section 13: Disposal considerations
13.1. Waste treatment methods
Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.
Recoveryoperations: Recycling/reclamation of metals and metal compounds.
Waste code number: 16 05 05
Disposal of packaging: Dispose of as normal industrial waste. Empty cans must not be burned because of explosion hazard.
NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.
Section 14: Transport information
14.1. UN number
UN number: UN1950
14.2. UN proper shipping name
Shipping name: AEROSOLS
14.3. Transport hazard class(es)
Transport class: 2
14.4. Packing group
14.5. Environmental hazards
Environmentallyhazardous: No
14.6. Special precautions for user
Special precautions: No special precautions.
Tunnel code: D
Transport category: 2
Section 15: Regulatoryinformation
Marine pollutant: No
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Specific regulations: Not applicable.
15.2. Chemical SafetyAssessment
Chemical safetyassessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.
Section 16: Other information
Other information
Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 2015/830.
Risk phases in this section belowrelate to the INDIVIDUAL COMPONENTS in the formulation when used at their FULL CONCENTRATIONS, and not at the reduced levels in the mixed product.
See sections 2 and 3 for the calculated hazard and risk phrases for the blended product.
Phrases used in s.2 and s.3: EUH066: Repeated exposure may cause skin dryness or cracking.
EUH208: Contains perfume (containing: linalool,linalyl acetate, benzyl salicylate, limonene). May produce an allergic reaction.
H220: Extremely flammable gas.
H222: Extremely flammable aerosol.
H229: Pressurised container: May burst if heated.
H304: May be fatal if swallowed and enters airways.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H411: Toxic to aquatic life with long lasting effects.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.


according to Regulation (EU) 2020/878
SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking
1.1.Productidentifier
Productname Glass Cleaner
1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst
ProductUse
[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC35]Washingand cleaningproducts(includingsolventbasedproducts);
[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC35]Washingandcleaningproducts(includingsolventbasedproducts);
Description Thispowerfulcleanerbreaksthrougheventhetoughestdirtandgrimeonscreens,windowsand mirrors,leavingasparklingstreakfreefinish.
1.3.Detailsofthesupplierofthesafetydatasheet
Company SUPAGARDLIMITED
Address 19-27GavintonStreet Muirend Glasgow G443EF
Web www.supagard.com
Telephone 01416335933
Fax 01416377219
Email James.Smyth@supagard.com
Emailaddressofthe competentperson James.Smyth@supagard.com
1.4.Emergencytelephonenumber
Emergencytelephonenumber01416335933 8.30amto5.00pm
FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)
Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org
SECTION2:Hazardsidentification
2.1.Classificationofthesubstanceormixture
2.1.2.Classification-EC 1272/2008 Flam.Liq.3:H226;EyeIrrit.2:H319;
2.2.Labelelements

2.2.Labelelements
Hazardpictograms

SignalWord Warning

HazardStatement Flam.Liq.3:H226-Flammableliquidandvapour. EyeIrrit.2:H319-Causesseriouseyeirritation.
PrecautionaryStatement: Prevention
P102-Keepoutofreachofchildren.
P210-Keepawayfromheat,hotsurfaces,sparks,openflamesandotherignitionsources.No smoking.
P264-Washhandsandothercontactedskinthoroughlyafterhandling.
PrecautionaryStatement: Response P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.
PrecautionaryStatement: Storage P403+P235-Storeinawell-ventilatedplace.Keepcool.
PrecautionaryStatement: Disposal
SUPPLEMENTALHAZARD INFORMATION
2.3.Otherhazards
Otherhazards
Furtherinformation
P501-Disposeofcontents/containertoanapproveddisposalsite,inaccordancewithlocal regulations.
IngredientsasrequiredbyRegulation(EC)No648/2004:. IsopropylAlcohol,ButyleneGlycol,Lessthan5%Non-ionicSurfactants.
Contains-Propan-2-ol,2-butoxyethanol.
Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.
RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.
SECTION3:Composition/informationoningredients
3.2.Mixtures
EC1272/2008
ChemicalName IndexNo.CASNo.ECNo.
propan-2-ol
603-117-00-067-63-0200-661-701-2119457558-25
Flam.Liq.2:H225;EyeIrrit. 2:H319;STOTSE3:H336; 1-10% 2-butoxyethanol 603-014-00-0111-76-2203-905-001-2119475108-36
AcuteTox.4:H332;Acute Tox.4:H312;AcuteTox.4: H302;EyeIrrit.2:H319;Skin Irrit.2:H315; 1-10%
SECTION4:Firstaidmeasures
4.1.Descriptionoffirstaidmeasures
Inhalation Movetheexposedpersontofreshair.
Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved. Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution.
Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.
4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed
Inhalation Highconcentrationofvapourinenclosedspacemaycauseirritation,headachesandnausea.May causeirritationtorespiratorysystem.
Eyecontact Irritatingtoeyes.
Skincontact Maycauseskindrynessandirritation.Prolongedcontactmaycausedefattingoftheskin.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed Ingestion Maycauseirritationtomucousmembranes.
4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded TREATSYMPTOMATICALLY.
Inhalation
Eyecontact
Skincontact
Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.
Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.
Seekmedicalattentionifirritationorsymptomspersist.
Ingestion Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.
Generalinformation
Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.
5.1.Extinguishingmedia
Flammableliquid.Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthe surroundingenvironment.
5.2.Specialhazardsarisingfromthesubstanceormixture
Flammableliquidandvapour.
5.3.Adviceforfirefighters
Furtherinformation
Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.
Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.
SECTION6:Accidentalreleasemeasures
6.1.Personalprecautions,protectiveequipmentandemergencyprocedures
Wearsuitableprotectiveequipment.Flammableliquid.Avoidsparks,flames,heatandsourcesof ignition.
6.2.Environmentalprecautions
Adviselocalauthoritiesiflargespillscannotbecontained.
6.3.Methodsandmaterialforcontainmentandcleaningup
Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelledcontainersfor disposal.Avoidsparks,flames,heatandsourcesofignition.
6.4.Referencetoothersections
Seesection2,7,8,13forfurtherinformation.
SECTION7:Handlingandstorage
7.1.Precautionsforsafehandling
AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.
7.2.Conditionsforsafestorage,includinganyincompatibilities
Flammableliquid.Avoidsparks,flames,heatandsourcesofignition.AvoidstoringindirectSun Light.Storeinawell-ventilatedplace.Keepcool.Storeinoriginalcontainer.Keepcontainertightly closed.Keepawayfromcombustiblematerial.Keepoutofthereachofchildren.
7.3.Specificenduse(s)
Thispowerfulcleanerbreaksthrougheventhetoughestdirtandgrimeonscreens,windowsand

7.3.Specificenduse(s)
mirrors,leavingasparklingstreakfreefinish. Suitablepackaging
Plasticcontainers.
8.1.Controlparameters
8.1.1.ExposureLimitValues
2-butoxyethanol
propan-2-ol
Occupationalexposurecontrols.
WEL8-hrlimitppm:25
WEL15minlimitppm:50
WEL8-hrlimitmg/m3:123
WEL15minlimitmg/m3:101.2
WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -
WEL8-hrlimitppm:400
WEL15minlimitppm:500
WEL8-hrlimitmg/m3:999
WEL15minlimitmg/m3:1250
WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -
DNEL:Derivedno-effectlevel.
ExposurePattern-Workers
2-butoxyethanol
propan-2-ol
Acuteinhalation-Systemic effects 1091mg/m³
Acuteinhalation-Localeffects246mg/m³
Long-term-inhalation-Systemic effects 98mg/m³
Long-term-inhalation-Systemic effects 500mg/m³
Long-term-dermal-Systemic effects 888mg/kg
ExposurePattern-Generalpopulation
2-butoxyethanol
propan-2-ol
8.2.Exposurecontrols
Acuteinhalation-Systemic effects 426mg/m³
Acutedermal-Systemiceffects89mg/kg
Long-term-inhalation-Systemic effects 59mg/m³
Long-term-dermal-Systemic effects 75mg/kg
Long-term-inhalation-Systemic effects 89mg/m³
Long-term-dermal-Systemic effects 319mg/kg



Acutedermal-Systemiceffects89mg/kg
Long-term-dermal-Systemic effects 125mg/kg
Acuteoral-Systemiceffects26.7mg/kg
Long-term-inhalation-Local effects 147mg/m³
Long-term-oral-Systemiceffects6.3mg/kg
Long-term-oral-Systemiceffects26mg/kg
8.2.Exposurecontrols
8.2.1.Appropriateengineering controls
AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.
Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.
Eye/faceprotection Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields.
SkinprotectionHandprotection Rubbergloves.
Respiratoryprotection Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.
8.2.3.Environmentalexposure controls Preventfurtherleakageorspillageifsafetodoso.
9.1.Informationonbasicphysicalandchemicalproperties
AppearanceLiquid ColourClear/Blue
OdourAlcoholic pH6-9
MeltingpointNodataavailable
Viscosity<50centipoise
ExplosivepropertiesNodataavailable OxidisingpropertiesNodataavailable
InitialboilingpointNodataavailable Flashpoint40°C
EvaporationrateNodataavailable Flammability(solid,gas)Nodataavailable
VapourFlammabilityNodataavailable VapourpressureNodataavailable RelativeVapourDensityNodataavailable Density/RelativeDensityNodataavailable PartitioncoefficientNodataavailable
AutoignitiontemperatureNodataavailable SolubilitySolubleinwater
9.2.Otherinformation
ConductivityNodataavailable SurfacetensionNodataavailable Specificgravity0.98-0.99g/cm³ GasgroupNotapplicable. BenzeneContentNotapplicable. LeadcontentNotapplicable. VOC(Volatileorganic compounds) Nodataavailable
Watersolubility Soluble.
9.2.1.Informationwithregardtophysicalhazardclasses Nodataisavailableonthisproduct.

9.2.2.Othersafetycharacteristics
Nodataisavailableonthisproduct.
SECTION10:Stabilityandreactivity
10.1.Reactivity
10.2.Chemicalstability
Flammableliquid.Stableundernormalconditions.
Flammableliquid.Stableundernormalconditions.
10.3.Possibilityofhazardousreactions
Oxidisingagents.Combustiblematerials.
10.4.Conditionstoavoid
10.5.Incompatiblematerials
Avoidsparks,flames,heatandsourcesofignition.AvoidstoringindirectSunLight.
Oxidisingagents.
10.6.Hazardousdecompositionproducts
NoHazardousdecompositionproductswhenstoredandhandledcorrectly.
SECTION11:Toxicologicalinformation
11.1Informationonhazardclasses
Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedusingthemethodsoutlinedinRegulation(EC)No1272/2008(CLP).
Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
OralATE=>10,000mg/kg.
DermalATE=>10,000mg/kg.
Inhalation-Dust/MistATE=>20mg/l.
Skincorrosion/irritation basedonavailabledatatheclassificationcriteriaarenotmet.
Seriouseyedamage/irritationEyeIrrit.2:H319-Causesseriouseyeirritation.
Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.
Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet.
Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.
Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.
Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet.
Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.
11.1.2.Mixtures
11.1.3.HazardInformation
11.1.4.ToxicologicalInformation
2-butoxyethanol
Nodataavailable.
Nodataavailable.
DermalRatLD50:1100mg/kg
InhalationRatLC50/4h:11.0mg/l propan-2-ol
InhalationRatLC50/6h:>10000ppm
DermalRabbitLD50:13900mg/kg

OralRatLD50:1300mg/kg
OralRatLD50:5840mg/kg
11.2Informationonotherhazards
Nodataisavailableonthisproduct.
12.1.Toxicity
2-butoxyethanol
12.2.Persistenceanddegradability
12.3.Bioaccumulativepotential
Partitioncoefficient
DaphniaEC50/48h:1550.0000mg/l
RainbowtroutLC50/96h:1474mg/l
DaphniaEC50/48h:10000.0000mg/l
FatheadminnowsLC50/96h:9640mg/l
AlgaeEC50/72h:1840mg/
FishLC50/96h:4200.0000mg/l
12.4.Mobilityinsoil
SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.
Theproductisnotbioaccumulating.
StoneacreGlassCleanerNodataavailable propan-2-ol0.05logP 2-butoxyethanol0.8logP
Thisproductissolubleinwater.
12.5.ResultsofPBTandvPvBassessment
Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.
12.6Endocrinedisruptingproperties
Nodataisavailableonthisproduct.
12.7.Otheradverseeffects
Nodataisavailableonthisproduct.
13.1.Wastetreatmentmethods
Generalinformation
Disposalofpackaging
Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.
Disposeofincompliancewithalllocalandnationalrequirements.
DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.
SECTION14:Transportinformation
Hazardpictograms

14.1.UNnumber

14.1.UNnumber UN1993
14.2.UNpropershippingname
14.3.Transporthazardclass(es)
ADR/RID 3
SubsidiaryriskIMDG 3
SubsidiaryriskIATA 3
Subsidiaryrisk -
14.4.Packinggroup
Packinggroup III
14.5.Environmentalhazards
Environmentalhazards No
Marinepollutant No
14.6.Specialprecautionsforuser
Noadditionalspecialprecautions.
14.7MaritimeTransportinbulkaccordingtoIMOinstruments
Notapplicable.
ADR/RID
HazardID 30
TunnelCategory (D/E)
IMDG
EmSCode F-ES-E
IATA
PackingInstruction(Cargo)366
Maximumquantity 220L
PackingInstruction (Passenger) 355
Maximumquantity 60L
SECTION15:Regulatoryinformation
15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations
REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.
COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture
COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).
15.2.Chemicalsafetyassessment
Noinformationavailable.
SECTION16:Otherinformation
Otherinformation
Revision
Thisdocumentdiffersfromthepreviousversioninthefollowingareas:. 2-Otherhazards.
2-Furtherinformation.
2-SUPPLEMENTALHAZARDINFORMATION. 9-9.2.2.Othersafetycharacteristics.
9-9.2.1.Informationwithregardtophysicalhazardclasses. 11-Acutetoxicity.
11-Repeatedorprolongedexposure.
11-11.2Informationonotherhazards. 12-12.1.Toxicity.
12-12.6Endocrinedisruptingproperties. 12-12.7.Otheradverseeffects.
15-Regulations.
Datasources ClassificationandProcedureusedtoderivetheclassificationformixturesaccordingtoRegulation (EC)No.1272/2008,asretainedandamendedinUKlaw.
Flam.Liq.3:H226-Flammableliquidandvapour.-FlashPoint-40degC. EyeIrrit.2:H319-Causesseriouseyeirritation.-CalculationMethod.
TextofHazardStatementsin Section3
Flam.Liq.2:H225-Highlyflammableliquidandvapour. EyeIrrit.2:H319-Causesseriouseyeirritation.
STOTSE3:H336-Maycausedrowsinessordizziness.
AcuteTox.4:H302+H312+H332-Harmfulifswallowed,incontactwithskinorifinhaled SkinIrrit.2:H315-Causesskinirritation.
Furtherinformation
TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.



according to Regulation (EU) 2015/830
SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking
1.1.Productidentifier
Productname Productcode Hand Barrier Cream H090
1.3.Detailsofthesupplierofthesafetydatasheet
Company Address
Web Telephone Fax
Emailaddressofthe competentperson
1.4.Emergencytelephonenumber
SUPAGARD LTD 19-29 GAVINTON STREET MUIREND GLASGOW G44 3EF
WWW.SUPAGARD.COM +0141 633 5933
james.smyth@supagard.com james.smyth@supagard.com
Emergencytelephonenumber 0141 633 5933 8.30 am - 5.30 pm
SECTION2:Hazardsidentification
2.1.Classificationofthesubstanceormixture
2.1.2.Classification-EC 1272/2008
2.2.Labelelements
Hazardpictograms
EyeIrrit.2:H319;AquaticChronic3:H412;

SignalWord Warning
HazardStatement EyeIrrit.2:H319-Causesseriouseyeirritation. AquaticChronic3:H412-Harmfultoaquaticlifewithlonglastingeffects.
PrecautionaryStatement: Prevention P264-Washthoroughlyafterhandling. P273-Avoidreleasetotheenvironment. P280-Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection.
PrecautionaryStatement: Response P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.
2.2.Labelelements
PrecautionaryStatement: Disposal
P337+P313-Ifeyeirritationpersists:Getmedicaladvice/attention.
P501-Disposeofcontents/containerto
SECTION3:Composition/informationoningredients
3.2.Mixtures
EC1272/2008
4.1.Descriptionoffirstaidmeasures
Eyecontact
Maycauseirritationtoeyes.Rinseimmediatelywithplentyofwaterfor15minutesholdingthe eyelidsopen.Seekmedicalattentionifirritationorsymptomspersist.
Skincontact Noirritationexpected.Maycauseallergicreactionsinsusceptiblepeople.Washoffimmediately withplentyofsoapandwater.Seekmedicalattentionifirritationorsymptomspersist.
Ingestion
Maycauseirritationtomucousmembranes.DONOTINDUCEVOMITING.Seekmedicalattention ifirritationorsymptomspersist.
4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed
Inhalation
Nosensitizatoneffectsreported.
Skincontact Washwithwater.
Ingestion
Ifswallowed,donotinducevomiting:seekmedicaladviceimmediatelyandshowthiscontaineror label.
SECTION5:Firefightingmeasures
5.1.Extinguishingmedia
Useextinguishingmediaappropriatetothesurroundingfireconditions.
5.2.Specialhazardsarisingfromthesubstanceormixture
Burningproducesirritating,toxicandobnoxiousfumes.
5.3.Adviceforfirefighters
Wearsuitablerespiratoryequipmentwhennecessary.
SECTION6:Accidentalreleasemeasures
6.1.Personalprecautions,protectiveequipmentandemergencyprocedures
6.2.Environmentalprecautions
Ensureadequateventilationoftheworkingarea.
Donotallowproducttoenterdrains.Preventfurtherspillageifsafe.
6.3.Methodsandmaterialforcontainmentandcleaningup
Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelledcontainersfor disposal.Cleanspillageareathoroughlywithplentyofwater.
SECTION7:Handlingandstorage
7.1.Precautionsforsafehandling
Avoidcontactwitheyes.AdoptbestManualHandlingconsiderationswhenhandling,carryingand dispensing.
7.2.Conditionsforsafestorage,includinganyincompatibilities
Keepinacool,dry,wellventilatedarea.Keepcontainerstightlyclosed.Storeincorrectlylabelled containers.
7.3.Specificenduse(s)
Furtherinformation
Avoidcontactwitheyes.Keepoutofthereachofchildren.
Astheapplicationofproductsisoutsideourcontrol,theinformationisgivenwithoutlegal resposibility.
SECTION8:Exposurecontrols/personalprotection
8.1.Controlparameters
8.1.1.ExposureLimitValues
Glycerol(Glycerol,mist)
8.2.Exposurecontrols
Eye/faceprotection
WEL8-hrlimitppm:-
WEL15minlimitppm:-
WEL8-hrlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: -
Incaseofsplashing,wear:.Approvedsafetygoggles.
SECTION9:Physicalandchemicalproperties
9.1.Informationonbasicphysicalandchemicalproperties
AppearanceViscousliquid.
ColourWhite OdourOdourless
OdourthresholdNotapplicable. pH6.5-7.5
MeltingpointNotdetermined
InitialboilingpointNotdetermined
FlashpointNotapplicable. EvaporationrateNotdetermined
Flammability(solid,gas)Notapplicable.
VapourpressureNotapplicable. VapourdensityNotapplicable. Relativedensity0.9-1
PartitioncoefficientNodataavailable
AutoignitiontemperatureNotapplicable. ViscosityNotdetermined
ExplosivepropertiesNotapplicable. OxidisingpropertiesNodataavailable
SolubilitySlightlymiscibleinwater
9.2.Otherinformation
WEL8-hrlimitmg/m3:10
WEL15minlimitmg/m3:-
WEL15minlimitmg/m3total inhalabledust: -
WEL15minlimitmg/m3total respirabledust: -
9.2.Otherinformation
ConductivityNotdetermined
SurfacetensionNotdetermined
GasgroupNotapplicable.
BenzeneContentNotapplicable.
LeadcontentNotapplicable. VOC(Volatileorganic compounds) Notapplicable.
SECTION10:Stabilityandreactivity
10.2.Chemicalstability
Stableundernormalconditions.
10.3.Possibilityofhazardousreactions
NoSignificantHazard.
10.4.Conditionstoavoid
10.5.Incompatiblematerials
DoNOTallowtofreeze.Protectfromfrost.
NoSignificantHazard.
10.6.Hazardousdecompositionproducts
Willnotdecomposeifstoredandusedasrecommended.
SECTION11:Toxicologicalinformation
11.1.Informationontoxicologicaleffects
Noknownadversehealtheffects.
Skincorrosion/irritation Noirritationexpected.NoSignificantHazard.
Seriouseyedamage/irritationMaycauseirritationtoeyes.
Respiratoryorskin sensitisation Nosensitizatoneffectsreported.NoSignificantHazard.
Germcellmutagenicity Nomutageniceffectsreported.
Carcinogenicity Nocarcinogeniceffectsreported.
Reproductivetoxicity Noteratogeniceffectsreported. Repeatedorprolonged exposure Noirritationexpected.
SECTION12:Ecologicalinformation
12.2.Persistenceanddegradability
Nodataisavailableonthisproduct.
12.3.Bioaccumulativepotential
Partitioncoefficient
12.4.Mobilityinsoil
Nodataisavailableonthisproduct.
No data available
Nodataisavailableonthisproduct.
12.5.ResultsofPBTandvPvBassessment Notdetermined.
12.6.Otheradverseeffects
onlyappliestoproductinverylargebulkquantities.Maycauselong-termadverseeffectsinthe environment.
Generalinformation
Disposalmethods
Disposalofpackaging
Disposeofincompliancewithalllocalandnationalregulations.
Forsmallquantities:.Theproductisclassifiedasnonhazardous.onlyappliestoproductinvery largebulkquantities.Donotemptyintodrains;disposeofthismaterialanditscontainerinasafe way.
Canberecycledifincompliancewith.localandnationalregulations.
14.1.UNnumber
14.2.UNpropershippingname
14.3.Transporthazardclass(es)
14.4.Packinggroup
14.5.Environmentalhazards
14.6.Specialprecautionsforuser
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage. Noprecautionsrequiredtobementioned.
14.7.TransportinbulkaccordingtoAnnexIIofMARPOL73/78andtheIBCCode
Theproductisnotclassifiedasdangerousforcarriage. Notnormallyrequired.
Furtherinformation
Theproductisnotclassifiedasdangerousforcarriage.
15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.REGULATION(EC) No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCILof18December2006 concerningtheRegistration,Evaluation,AuthorisationandRestrictionofChemicals(REACH), establishingaEuropeanChemicalsAgency,amendingDirective1999/45/ECandrepealing CouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94aswellas CouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand 2000/21/EC.ThisproductMSDShasbeencompiledinrelationtoECNo:1272/2008CLP Regulations.
Otherinformation
Revision
TextofHazardStatementsin
Section3
Furtherinformation
Thisdocumentdiffersfromthepreviousversioninthefollowingareas:. 11-Seriouseyedamage/irritation. 12-12.6.Otheradverseeffects. 13-Disposalmethods.
EyeDam.1:H318-Causesseriouseyedamage. AquaticChronic1:H410-Verytoxictoaquaticlifewithlonglastingeffects.
TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.


according to Regulation (EU) 2015/830
SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking
1.1.Productidentifier
Productname Productcode HAND CLEANER H058
1.3.Detailsofthesupplierofthesafetydatasheet Company Address
Web Telephone Fax
Emailaddressofthe competentperson 19-29 GAVINTON STREET MUIREND GLASGOW G44 3EF WWW.SUPAGARD.COM + 0141 633 5933
james.smyth@supagard.com james.smyth@supagard.com
1.4.Emergencytelephonenumber
Emergencytelephonenumber +44 (0)1939 232326 9.00 am - 5.00 pm
SECTION2:Hazardsidentification
2.1.Classificationofthesubstanceormixture
2.1.2.Classification-EC 1272/2008
AcuteTox.4:H302;EyeIrrit.2:H319;AquaticChronic3:H412; 2.2.Labelelements
Hazardpictograms

SignalWord Warning
HazardStatement
PrecautionaryStatement: Prevention
AcuteTox.4:H302-Harmfulifswallowed. EyeIrrit.2:H319-Causesseriouseyeirritation. AquaticChronic3:H412-Harmfultoaquaticlifewithlonglastingeffects.
P264 - Wash thoroughly after handling.
P270 - Do no eat, drink or smoke when using this product. P273 - Avoid release to the environment.
P280 - Wear protective clothing.
2.2.Labelelements
PrecautionaryStatement: Response
PrecautionaryStatement: Disposal
P301+P312-IFSWALLOWED:CallaPOISONCENTER/doctor//ifyoufeelunwell.
P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing. P330-Rinsemouth.
P337+P313-Ifeyeirritationpersists:Getmedicaladvice/attention.
P501-Disposeofcontents/containertoanapprovedlandfillsite(inaccordancewith local/regional/national/internationalregulation).
SECTION3:Composition/informationoningredients
3.2.Mixtures
EC1272/2008
EyeIrrit.2:H319;1-10%
EyeIrrit.2:H319;1-10%
Sens.1:H317; 0-0.5%
Hazardousingredients
Nonhazardous.
SECTION4:Firstaidmeasures
4.1.Descriptionoffirstaidmeasures
Inhalation
Eyecontact
Skincontact
Ingestion
Maycauseirritationtomucousmembranes.Movetheexposedpersontofreshair.
Maycauseirritationtoeyes.Rinseimmediatelywithplentyofwaterfor15minutesholdingthe eyelidsopen.Seekmedicalattentionifirritationorsymptomspersist.
Maycausesensitisationbyskincontact.Noirritationexpected.Washwithwater.Seekmedical attentionifirritationorsymptomspersist.
Maycauseirritationtomucousmembranes.DONOTINDUCEVOMITING.Seekmedicalattention ifirritationorsymptomspersist.
4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed
Inhalation Noirritationexpected.
Eyecontact
Rinseimmediatelywithplentyofwaterfor15minutesholdingtheeyelidsopen.Seekmedical attentionifirritationorsymptomspersist.
Skincontact Washwithwater.
Ingestion
Ingestionmaycausenauseaandvomiting.Ifswallowed,donotinducevomiting:seekmedical adviceimmediatelyandshowthiscontainerorlabel.
5.1.Extinguishingmedia
Useextinguishingmediaappropriatetothesurroundingfireconditions.
5.2.Specialhazardsarisingfromthesubstanceormixture
Burningproducesirritating,toxicandobnoxiousfumes.
5.3.Adviceforfirefighters
Wearsuitablerespiratoryequipmentwhennecessary.
SECTION6:Accidentalreleasemeasures
6.1.Personalprecautions,protectiveequipmentandemergencyprocedures
6.2.Environmentalprecautions
AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.
Donotallowproducttoenterdrains.Preventfurtherspillageifsafe.
6.3.Methodsandmaterialforcontainmentandcleaningup
Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelledcontainersfor disposal.Cleanspillageareathoroughlywithplentyofwater.
6.4.Referencetoothersections
Noknownadverseenvironmentaleffects.Noknownadversehealtheffects.NoSignificantHazard.
SECTION7:Handlingandstorage
7.1.Precautionsforsafehandling
AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.
7.2.Conditionsforsafestorage,includinganyincompatibilities
Keepinacool,dry,wellventilatedarea.Keepcontainerstightlyclosed.Storeincorrectlylabelled containers.
7.3.Specificenduse(s)
Cleaning.
SECTION8:Exposurecontrols/personalprotection
8.2.Exposurecontrols
8.2.1.Appropriateengineering controls Ensureadequateventilationoftheworkingarea.
8.2.2.Individualprotection measures
AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.
Eye/faceprotection Incaseofsplashing,wear:.Approvedsafetygoggles. SkinprotectionHandprotection Noprecautionsrequiredtobementioned.
9.1.Informationonbasicphysicalandchemicalproperties
AppearanceViscousliquid.
ColourOrange OdourPleasant
pH6.0+/-0.5
MeltingpointNotdetermined
InitialboilingpointNotdetermined
FlashpointNotdetermined
EvaporationrateNodataavailable
Flammability(solid,gas)Nodataavailable
VapourpressureNotdetermined
VapourdensityNotdetermined
Relativedensity0.95
PartitioncoefficientNodataavailable
AutoignitiontemperatureNotdetermined
ViscosityNotdetermined
ExplosivepropertiesNotdetermined
OxidisingpropertiesNodataavailable
9.2.Otherinformation
9.2.Otherinformation
ConductivityNotdetermined
SurfacetensionNotdetermined
GasgroupNotdetermined
BenzeneContentNotapplicable.
LeadcontentNotapplicable.
VOC(Volatileorganic compounds) Nodataavailable
Watersolubility
Slightlysolubleinwater.
SECTION10:Stabilityandreactivity
10.1.Reactivity
10.2.Chemicalstability
Notdetermined.
Stableundernormalconditions.
10.3.Possibilityofhazardousreactions
NoSignificantHazard.
10.4.Conditionstoavoid
10.5.Incompatiblematerials
DoNOTallowtofreeze.
NoSignificantHazard.
10.6.Hazardousdecompositionproducts
Nodataisavailableonthisproduct.
SECTION11:Toxicologicalinformation
11.1.4.ToxicologicalInformation
OrangeTerpenes
OralRatLD50:4400mg/kg
Noknownadversehealtheffects.
SECTION12:Ecologicalinformation
12.1.Toxicity
Noknownadverseenvironmentaleffects.
12.2.Persistenceanddegradability
Nodataisavailableonthisproduct.
12.3.Bioaccumulativepotential
Nodataisavailableonthisproduct. Partitioncoefficient
OrangePumiceHandCleanserNodataavailable
DermalRabbitLD50:>2000mg/kg
12.4.Mobilityinsoil
Nodataisavailableonthisproduct.
12.5.ResultsofPBTandvPvBassessment
Nodataavailable.
12.6.Otheradverseeffects
Noknownadverseenvironmentaleffects.
Generalinformation
Disposeofincompliancewithalllocalandnationalregulations. Disposalmethods
Forsmallquantities:.Flushdownthedrainwithplentyofwater. Disposalofpackaging
Emptycontainerscanbesentfordisposalorrecycling.
14.1.UNnumber
14.2.UNpropershippingname
14.3.Transporthazardclass(es)
14.4.Packinggroup
14.5.Environmentalhazards
14.6.Specialprecautionsforuser
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
14.7.TransportinbulkaccordingtoAnnexIIofMARPOL73/78andtheIBCCode
Theproductisnotclassifiedasdangerousforcarriage. Furtherinformation
Theproductisnotclassifiedasdangerousforcarriage.
15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.REGULATION(EC) No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCILof18December2006 concerningtheRegistration,Evaluation,AuthorisationandRestrictionofChemicals(REACH), establishingaEuropeanChemicalsAgency,amendingDirective1999/45/ECandrepealing CouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94aswellas CouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand 2000/21/EC.ThisproductMSDShasbeencompiledinrelationtoECNo:1272/2008CLP Regulations.
SECTION16:Otherinformation
Thisdocumentdiffersfromthepreviousversioninthefollowingareas:.
Otherinformation
TextofHazardStatementsin Section3
2-PrecautionaryStatement:Prevention.
AcuteTox.4:H302-Harmfulifswallowed. EyeIrrit.2:H319-Causesseriouseyeirritation. AquaticChronic3:H412-Harmfultoaquaticlifewithlonglastingeffects. Flam.Liq.3:H226-Flammableliquidandvapour. SkinSens.1:H317-Maycauseanallergicskinreaction.
Furtherinformation
Astheapplicationofproductsisoutsideourcontrol,theinformationisgivenwithoutlegal resposibility.Customersshouldtestundertheirownconditionstoensuretheproductsaresuitable fortheirownrequirements.TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyas guidanceforthesafeuse,storageandhandlingoftheproduct.Thisinformationiscorrecttothe bestofourknowledgeandbeliefatthedateofpublicationhowevernoguaranteeismadetoits accuracy.Thisinformationrelatesonlytothespecificmaterialdesignatedandmaynotbevalidfor suchmaterialusedincombinationwithanyothermaterialsorinanyotherprocess.


SAFETY DATASHEET
INTERIOR SILK PLUS
Section 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name: INTERIOR SILK PLUS
Product code: HC8477
Synonyms: HC8477
PD0650-5
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of substance / mixture: Aerosol cleaner and polish.
1.3. Details of the supplier of the safetydata sheet
Companyname: SUPAGARD LIMITED
23 Gavinton Street Muirend Glasgow Scotland G44 3EF
Tel: 0141 633 5933
Email: james@supagard.co.uk
1.4. Emergencytelephone number
Emergencytel: 0141 633 5933 (office hours only)
Section 2: Hazards identification
2.1. Classification of the substance or mixture
Page: 1
Compilation date: 26/10/2022
Revision date: 14/05/2024
Revision No: 2
Classification under CLP: Skin Irrit. 2: H315; STOT SE 3: H336; Aquatic Chronic 2: H411; Flam. Aerosol 1: H222; Asp. Tox. 1: H304; -: EUH208; -: H229
Most important adverse effects: Contains perfume strawberry 25832 (contains methyl cinnamate, aldehyde c16). May produce an allergic reaction. Extremely flammable aerosol. Pressurised container: May burst if heated. Causes skin irritation. May cause drowsiness or dizziness. Toxic to aquatic life with long lasting effects.
2.2. Label elements
Label elements:
Hazard statements: EUH208: Contains perfume strawberry 25832 (contains methyl cinnamate, aldehyde c16). May produce an allergic reaction. H222: Extremely flammable aerosol.
SAFETY DATASHEET
INTERIOR SILK PLUS
H229: Pressurised container: May burst if heated.
H315: Causes skin irritation.
H336: May cause drowsiness or dizziness.
H411: Toxic to aquatic life with long lasting effects.
Hazard pictograms: GHS02: Flame
GHS07: Exclamation mark
GHS09: Environmental



Signal words: Danger
Precautionarystatements: P102: Keep out of reach of children.
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P211: Do not spray on an open flame or other ignition source.
P251: Do not pierce or burn, even after use.
P410+P412: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
P260: Do not breathe spray.
P302+P350: IF ON SKIN: Gently wash with plenty of soap and water.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Haz. ingredients (label): Contains:
ALIPHATIC HYDROCARBON SOLVENT BLEND
LIQUIFIED PETROLEUMGAS PROPELLANT
PERFUME (CONTAINING: METHYL CINNAMATE, ALDEHYDE C16)
2.3. Other hazards
Other hazards: In use, may form flammable / explosive vapour-air mixture.
PBT: This product is not identified as a PBT/vPvB substance.
Section 3: Composition/information on ingredients
3.2. Mixtures
Hazardous ingredients:
HYDROCARBONS C6-C7 ISOALKANES, CYCLICS, <5% N-HEXANE, <0.1% BENZENE - REACH registered number (s): 01-2119475514-35-XXXX
EINECS CAS
265-151-9 64742-49-0 -
/ WEL
Flam. Liq. 2: H225; STOT SE 3: H336; Asp. Tox. 1: H304; Aquatic Chronic 2: H411; Skin Irrit. 2: H315
BUTANE, <0.1% 1,3 BUTADIENE - REACH registered number(s): 01-2119474691-32-XXXX
203-448-7 106-97-8
Substance with a Community workplace exposure limit. Flam. Gas 1: H220; Press. Gas: H280
PROPANE, <0.1% 1,3 BUTADIENE - REACH registered number(s): 01-2119486944-21-XXXX
200-827-9 74-98-6
Substance with a Community workplace exposure limit.
1:
PERFUME STRAWBERRY25832 (CONTAINS METHYL CINNAMATE, ALDEHYDE C16) - - -
Flam. Liq. 3: H226; Skin Sens. 1A: H317; Aquatic Chronic 3: H412
Non-classified ingredients:
PERFUME CRANBERRY(CONTAINING ALDEHYDE C16, LINALOOL, BETA IONONE, CITRONELLOL) - REACH registered number(s): MIXTURE
MIXTURE - - Aquatic Chronic 3: H412; Skin Sens. 1: H317; Skin Irrit. 2: H315; Flam. Liq. 3: H226; -: EUH208
Section 4: First aid measures
4.1. Description of first aid measures
Skin contact: Wash immediately with plenty of soap and water.
Eye contact: Bathe the eye with running water for 15 minutes. Consult a doctor.
Ingestion: Wash out mouth with water.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Move to fresh air in case of accidental inhalation of vapours. Consult a doctor.
4.2. Most important symptoms and effects, both acute and delayed
Skin contact: There may be irritation and redness at the site of contact.
Eye contact: There may be irritation and redness. The eyes may water profusely.
Ingestion: There may be soreness and redness of the mouth and throat.
Inhalation: There may be irritation of the throat with a feeling of tightness in the chest. Exposure may cause coughing or wheezing.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.
INTERIOR SILK PLUS
4.3. Indication of anyimmediate medical attention and special treatment needed
Immediate / special treatment: Eye bathing equipment should be available on the premises.
Section 5: Fire-fighting measures
5.1. Extinguishing media
Extinguishing media: Alcohol resistant foam. Water spray. Carbon dioxide. Dry chemical powder. Use water spray to cool containers.
5.2. Special hazards arising from the substance or mixture
Exposure hazards: Highly flammable. In combustion emits toxic fumes. Forms explosive air-vapour mixture. Vapour may travel considerable distance to source of ignition and flash back. Aerosol cans may explode during a fire, giving a high speed projectile.
5.3. Advice for fire-fighters
Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.
Section 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergencyprocedures
Personal precautions: Refer to section 8 of SDS for personal protection details. If outside do not approach from downwind. If outside keep bystanders upwind and away from danger point. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Eliminate all sources of ignition. Cover leaking can until the discharge has stopped, before attempting cleanup operations. Spillage will create slippery surface.
6.2. Environmental precautions
Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.
6.3. Methods and material for containment and cleaning up
Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method. Do not use equipment in clean-up procedure which may produce sparks. Wash the ground with an appropriate self-emulsifying solvent.
6.4. Reference to other sections
Reference to other sections: Refer to section 8 of SDS.
Section 7: Handling and storage
7.1. Precautions for safe handling
Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Avoid the formation or spread of mists in the air. Smoking is forbidden. Use non-sparking tools.
7.2. Conditions for safe storage, including anyincompatibilities
Storage conditions: Store in a cool, well ventilated area. Keep away from sources of ignition. Keep away from direct sunlight.
7.3. Specific end use(s)
Specific end use(s): No data available.
Section 8: Exposure controls/personal protection
8.1. Control parameters
Hazardous ingredients:
HYDROCARBONS C6-C7 ISOALKANES, CYCLICS, <5%N-HEXANE, <0.1%BENZENE
Workplace exposure limits:
Respirable dust:
<0.1%1,3 BUTADIENE
PROPANE, <0.1%1,3 BUTADIENE
UK Asphyxiating Asphyxiating - -
DNEL/PNEC Values
DNEL / PNEC No data available.
8.2. Exposure controls
Engineering measures: Ensure there is sufficient ventilation of the area. Ensure lighting and electrical equipment are not a source of ignition.
Respiratoryprotection: Self-contained breathing apparatus must be available in case of emergency.
Hand protection: Protective gloves.
Eye protection: Safety glasses. Ensure eye bath is to hand.
Skin protection: Protective clothing.
Section 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
State: Aerosol
Colour: Colourless
Odour: Perfumed
Evaporation rate: Fast
Solubilityin water: Insoluble
Viscosity: Non-viscous
Boiling point/range°C: No data available.
Flammabilitylimits %:lower: 0.9
Melting point/range°C: No data available.
Flash point°C: -40
Autoflammability°C: >230
INTERIOR SILK PLUS
upper: 9.0
Part.coeff. n-octanol/water: No data available.
Vapour pressure: No data available.
Relative density: No data available. pH: Not applicable.
VOC g/l: No data available.
9.2. Other information
Other information: No data available.
Section 10: Stabilityand reactivity
10.1. Reactivity
Reactivity: Stable under recommended transport or storage conditions.
10.2. Chemical stability
Chemical stability: Stable under normal conditions. Stable at room temperature.
10.3. Possibilityof hazardous reactions
Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions. Decomposition may occur on exposure to conditions or materials listed below.
10.4. Conditions to avoid
Conditions to avoid: Heat. Hot surfaces. Sources of ignition. Flames. Direct sunlight.
10.5. Incompatible materials
Materials to avoid: Strong oxidising agents. Strong acids.
10.6. Hazardous decomposition products
Haz. decomp. products: In combustion emits toxic fumes.
Section 11: Toxicological information
11.1. Information on toxicological effects
Hazardous ingredients:
HYDROCARBONS
Relevant hazards for product:
Skin corrosion/irritation
INTERIOR SILK PLUS
STOT-single exposure - Hazardous: calculated
Aspiration hazard - Hazardous: calculated
Symptoms / routes of exposure
Skin contact: There may be irritation and redness at the site of contact.
Eye contact: There may be irritation and redness. The eyes may water profusely.
Ingestion: There may be soreness and redness of the mouth and throat.
Inhalation: There may be irritation of the throat with a feeling of tightness in the chest. Exposure may cause coughing or wheezing.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.
Section 12: Ecological information
12.1. Toxicity
Hazardous ingredients:
HYDROCARBONS C6-C7 ISOALKANES, CYCLICS, <5%N-HEXANE, <0.1%BENZENE
Daphnia magna
RAINBOW TROUT (Oncorhynchus mykiss)
12.2. Persistence and degradability
Persistence and degradability: Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential: No bioaccumulation potential.
12.4. Mobilityin soil
Mobility: Readily absorbed into soil. Volatile. Insoluble in water. Floats on water. Vapour is heavier than air.
12.5. Results of PBT and vPvB assessment
PBT identification: This product is not identified as a PBT/vPvB substance.
12.6. Other adverse effects
Other adverse effects: Toxic to aquatic organisms.
Section 13: Disposal considerations
13.1. Waste treatment methods
Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.
Recoveryoperations: Recycling/reclamation of metals and metal compounds.
Waste code number: 16 05 05
Disposal of packaging: Dispose of as normal industrial waste. Empty cans must not be burned because of explosion hazard.
NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.
14.1. UN number
UN number: UN1950
14.2. UN proper shipping name
Shipping name: AEROSOLS
14.3. Transport hazard class(es)
Transport class: 2
14.4. Packing group
14.5. Environmental hazards
Environmentallyhazardous: Yes
14.6. Special precautions for user
Special precautions: No special precautions.
Tunnel code: D
Transport category: 2
Section 15: Regulatoryinformation
Marine pollutant: No
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Specific regulations: Not applicable.
15.2. Chemical SafetyAssessment
Chemical safetyassessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.
Section 16: Other information
Other information
Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 2015/830.
All substances in this preparation are registered within UK/EU/EFTA countries under the REACH (UK/EC) (ammended) regulations, EC 1907/2006
IMPORTANT NOTE:
Risk phases in this section belowrelate to the INDIVIDUAL COMPONENTS in the formulation when used at their FULL CONCENTRATIONS, and not at the reduced levels in the mixed product.
See sections 2 and 3 for the calculated hazard and risk phrases for the blended product. Phrases used in s.2 and s.3: EUH208: Contains Linalool and Citronellol. May produce an allergic reaction.
INTERIOR SILK PLUS
EUH208: Contains perfume strawberry 25832 (contains methyl cinnamate, aldehyde c16). May produce an allergic reaction.
H220: Extremely flammable gas.
H222: Extremely flammable aerosol.
H225: Highly flammable liquid and vapour.
H226: Flammable liquid and vapour.
H229: Pressurised container: May burst if heated.
H304: May be fatal if swallowed and enters airways.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H336: May cause drowsiness or dizziness.
H411: Toxic to aquatic life with long lasting effects.
H412: Harmful to aquatic life with long lasting effects.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.


according to Regulation (EU) 2020/878
SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking
1.1.Productidentifier
Productname Leather Cleaner
1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst ProductUse
[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC35]Washingand cleaningproducts(includingsolventbasedproducts);
[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC35]Washingandcleaningproducts(includingsolventbasedproducts); Description LeatherCleaner.
1.3.Detailsofthesupplierofthesafetydatasheet Company SUPAGARDLIMITED
Address 19-27GavintonStreet Muirend Glasgow G443EF
Web www.supagard.com
Telephone 01416335933
Fax 01416377219
Email James.Smyth@supagard.com
Emailaddressofthe competentperson James.Smyth@supagard.com
1.4.Emergencytelephonenumber
Emergencytelephonenumber01416335933 8.30amto5.00pm
FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)
Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org
SECTION2:Hazardsidentification
2.1.Classificationofthesubstanceormixture
2.1.2.Classification-EC 1272/2008 EyeIrrit.2:H319;
2.2.Labelelements
Hazardpictograms


2.2.Labelelements
SignalWord Warning
HazardStatement EyeIrrit.2:H319-Causesseriouseyeirritation.
PrecautionaryStatement: Prevention P102-Keepoutofreachofchildren.
PrecautionaryStatement: Response P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing. P337+P313-Ifeyeirritationpersists:Getmedicaladvice/attention.
SUPPLEMENTALHAZARD INFORMATION
IngredientsasrequiredbyRegulation(EC)No648/2004:. Lessthan5%Non-ionicSurfactants,Lessthan5%AmphotericSurfactants,Parfum,Benzyl Alcohol.
Contains-DenaturedAlcohol,2-butoxyethanol,Amines,C8-C18(evennumbered)and C18(Unsaturated),N,N-Bis(Hydroxyethyl),Amines,C12-14(evennumbered)-alkyldimethyl, N-oxides.
2.3.Otherhazards
Otherhazards Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.
Furtherinformation
RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.
SECTION3:Composition/informationoningredients
3.2.Mixtures
EC1272/2008
ChemicalName
Amides,C8-C18(evennumbered) andC18(Unsaturated), N,N-Bis(Hydroxyethyl)
Amines,C12-14(evennumbered) -alkyldimethyl,N-oxides
Ethanol:EthylAlcohol(Ethanol)
56-81-5200-289-5
931-329-601-2119490100-53
308062-28-4931-292-601-2119490061-47
64-17-5200-578-601-2119457610-43
SkinIrrit.2:H315;EyeDam. 1:H318;AquaticChronic2: H411; 1-10%
AcuteTox.4:H302;SkinIrrit. 2:H315;EyeDam.1:H318; AquaticAcute1:H400; AquaticChronic2:H411; 0-0.5%
Flam.Liq.2:H225;EyeIrrit. 2:H319; 1-10% 2-butoxyethanol
603-014-00-0111-76-2203-905-001-2119475108-36
AcuteTox.4:H332;Acute Tox.4:H312;AcuteTox.4: H302;EyeIrrit.2:H319;Skin Irrit.2:H315; 0.5-1%
Amines,C12-14(evennumbered)-alkyldimethyl,N-oxides,CASNo.308062-28-4-MFactor (Acute)=1.
4.1.Descriptionoffirstaidmeasures
Inhalation Movetheexposedpersontofreshair.
Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved.
Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution.
Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.
4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed
Inhalation Maycauseirritationtorespiratorysystem.
Eyecontact Irritatingtoeyes.
Skincontact Maycauseirritationtoskin.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed Ingestion Maycauseirritationtomucousmembranes.
4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded Inhalation
Eyecontact
Skincontact
Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.
Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.
Seekmedicalattentionifirritationorsymptomspersist. Ingestion Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.
Generalinformation
Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.
5.1.Extinguishingmedia
Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.
5.2.Specialhazardsarisingfromthesubstanceormixture
Noneknown.
5.3.Adviceforfirefighters
Furtherinformation
Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.
Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.
SECTION6:Accidentalreleasemeasures
6.1.Personalprecautions,protectiveequipmentandemergencyprocedures
6.2.Environmentalprecautions
Wearsuitableprotectiveequipment.
Adviselocalauthoritiesiflargespillscannotbecontained.
6.3.Methodsandmaterialforcontainmentandcleaningup
Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.
6.4.Referencetoothersections
Seesection2,7,8,13forfurtherinformation.
7.1.Precautionsforsafehandling
AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.
7.2.Conditionsforsafestorage,includinganyincompatibilities
Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.
7.3.Specificenduse(s)
Suitablepackaging
LeatherCleaner.
Plasticcontainers.

8.1.Controlparameters
8.1.1.ExposureLimitValues
2-butoxyethanol
Amides,C8-C18(even numbered)and C18(Unsaturated), N,N-Bis(Hydroxyethyl)
Ethanol:EthylAlcohol(Ethanol)
Occupationalexposurecontrols.
WEL8-hrlimitppm:25
WEL15minlimitppm:50
WEL8-hrlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: -
WEL8-hrlimitppm:N/A
WEL15minlimitppm:
WEL8-hrlimitmg/m3total inhalabledust:
WEL8-hrlimitmg/m3total respirabledust:
WEL8-hrlimitppm:1000
WEL15minlimitppm:-
Glycerol(Glycerol,mist)
WEL8-hrlimitmg/m3:123
WEL15minlimitmg/m3:101.2
WEL15minlimitmg/m3total inhalabledust: -
WEL15minlimitmg/m3total respirabledust: -
WEL8-hrlimitmg/m3:
WEL15minlimitmg/m3:
WEL15minlimitmg/m3total inhalabledust:
WEL15minlimitmg/m3total respirabledust:
WEL8-hrlimitmg/m3:1920
WEL15minlimitmg/m3:-
WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -
WEL8-hrlimitppm:-
WEL15minlimitppm:-
WEL8-hrlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3:10
WEL15minlimitmg/m3:-
WEL15minlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -
DNEL:Derivedno-effectlevel.
ExposurePattern-Workers
2-butoxyethanol
Amides,C8-C18(even numbered)and C18(Unsaturated), N,N-Bis(Hydroxyethyl)
Ethanol:EthylAlcohol
Glycerol
Acuteinhalation-Systemic effects 1091mg/m³
Acuteinhalation-Localeffects246mg/m³
Long-term-inhalation-Systemic effects 98mg/m³
Long-term-inhalation-Systemic effects 73.4mg/m³
Long-term-dermal-Systemic effects 4.16<none>
Long-term-inhalation-Systemic effects 950mg/m³
Long-term-inhalation-Local effects 1900mg/m³
Long-term-inhalation-Local effects 56mg/m³
ExposurePattern-Generalpopulation
Acutedermal-Systemiceffects89mg/kg
Long-term-dermal-Systemic effects 125mg/kg
Long-term-dermal-Systemic effects 343mg/kg

ExposurePattern-Generalpopulation
2-butoxyethanol
Amides,C8-C18(even numbered)and C18(Unsaturated), N,N-Bis(Hydroxyethyl)
Ethanol:EthylAlcohol
Glycerol
8.2.Exposurecontrols
Acuteinhalation-Systemic effects 426mg/m³
Acutedermal-Systemiceffects89mg/kg
Long-term-inhalation-Systemic effects 59mg/m³
Long-term-dermal-Systemic effects 75mg/kg
Long-term-inhalation-Systemic effects 21.73mg/m³
Long-term-oral-Systemic effects 6.25mg/kg
Long-term-inhalation-Systemic effects 114mg/m³
Long-term-inhalation-Local effects 950mg/m³
Long-term-oral-Systemic effects 87mg/kg
Long-term-inhalation-Local effects 33mg/m³
Long-term-oral-Systemic effects 229mg/kg


8.2.1.Appropriateengineering controls
Eye/faceprotection
Acuteoral-Systemiceffects26.7mg/kg
Long-term-inhalation-Local effects 147mg/m³
Long-term-oral-Systemiceffects6.3mg/kg
Long-term-dermal-Systemic effects 206mg/kg
SkinprotectionHandprotection
Respiratoryprotection
8.2.3.Environmentalexposure controls
AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.
Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.
Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields. Eyewearcomplyingwithanapprovedstandardshouldbewornifariskassessmentindicateseye contactispossible.Thefollowingprotectionshouldbeworn:Wearchemicalsplashgoggles. PersonalprotectiveequipmentforeyeandfaceprotectionshouldcomplywithEuropeanStandard EN166.
Nitrilerubbergloves.Chooseglovestoprotecthandsagainstchemicalsdependingonthe concentrationandquantityofthehazardoussubstanceandspecifictoplaceofwork.Forspecial applications,werecommendclarifyingtheresistancetochemicalsoftheaforementioned protectivegloveswiththeglovemanufacturer.
Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.
Preventfurtherleakageorspillageifsafetodoso.
SECTION9:Physicalandchemicalproperties
9.1.Informationonbasicphysicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties
AppearanceLiquid
ColourColourless
OdourCharacteristic
OdourthresholdNodataavailable pH6-8
MeltingpointNodataavailable
InitialboilingpointNodataavailable
FlashpointNodataavailable
EvaporationrateNodataavailable Flammability(solid,gas)Nodataavailable
VapourpressureNodataavailable
RelativeVapourDensityNodataavailable
Density/RelativeDensity1.004-1.01
PartitioncoefficientNodataavailable
AutoignitiontemperatureNodataavailable
Viscosity<20centipoise
ExplosivepropertiesNodataavailable OxidisingpropertiesNodataavailable SolubilitySolubleinwater
9.2.Otherinformation
ConductivityNodataavailable
SurfacetensionNodataavailable
GasgroupNodataavailable
BenzeneContentNodataavailable
LeadcontentNodataavailable
VOC(Volatileorganic compounds) Nodataavailable
9.2.1.Informationwithregardtophysicalhazardclasses
Nodataisavailableonthisproduct.
9.2.2.Othersafetycharacteristics
Nodataisavailableonthisproduct.
SECTION10:Stabilityandreactivity
10.1.Reactivity
10.2.Chemicalstability
Stableundernormalconditions.
Stableundernormalconditions.
10.3.Possibilityofhazardousreactions
Strongacids.Strongoxidisingagents.
10.4.Conditionstoavoid
10.5.Incompatiblematerials
AvoidstoringindirectSunLight.
Strongacids.Strongoxidisingagents.
10.6.Hazardousdecompositionproducts
NoHazardousdecompositionproductswhenstoredandhandledcorrectly.

11.1Informationonhazardclasses
Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedusingthemethodsoutlinedinRegulation(EC)No1272/2008(CLP).
Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet. OralATE=>10,000mg/kg. DermalATE=>10,000mg/kg.
Inhalation-Dust/MistATE=148.65mg/l,Inhalation-Dust/MistATE=>1,000mg/l. Skincorrosion/irritation basedonavailabledatatheclassificationcriteriaarenotmet.
Seriouseyedamage/irritationEyeIrrit.2:H319-Causesseriouseyeirritation.
Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.
Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet. Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.
Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.
Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet.
11.1.2.Mixtures
11.1.3.HazardInformation
11.1.4.ToxicologicalInformation
2-butoxyethanol
Amides,C8-C18(even numbered)and C18(Unsaturated), N,N-Bis(Hydroxyethyl)
Ethanol:EthylAlcohol
Glycerol
11.2Informationonotherhazards
Nodataavailable.
Nodataavailable.
DermalRatLD50:1100mg/kg
InhalationRatLC50/4h:11.0mg/l
OralRatLD50:>2000mg/kg
OralRatLD50:10470.0mg/kg
InhalationRatLC50/4h:20mg/l
OralRatLD50:27,200.0mg/kg
Nodataisavailableonthisproduct.
SECTION12:Ecologicalinformation
12.1.Toxicity

OralRatLD50:1300mg/kg
DermalRabbitLD50:>2000mg/kg
DermalRabbitLD50:15800.0mg/kg
12.1.Toxicity
2-butoxyethanol
Amides,C8-C18(even numbered)and C18(Unsaturated), N,N-Bis(Hydroxyethyl)
Ethanol:EthylAlcohol
Glycerol
12.2.Persistenceanddegradability
12.3.Bioaccumulativepotential
Partitioncoefficient
12.4.Mobilityinsoil
DaphniaEC50/48h:1550.0000mg/l
RainbowtroutLC50/96h:1474mg/l
EC50formarineorfreshwater organisms >100.0000mg/l
DaphniaEC50/48h:3.2000mg/l
FishLC50/96h:2.4000mg/l
DaphniaEC50/48h:12340.0000mg/l
GreenAlgaeEC50/48h:>100mg/l
RainbowtroutLC50/96h:13000mg/l
NOEC/EC10formarineor freshwaterorganisms 9.6000mg/l
DaphniaEC50/48h:10000.0000mg/l
FatheadminnowsLC50/96h= >=885mg/l:
AlgaeEC50/72h:1840mg/
LC50formarineorfreshwater organisms >100.0000mg/l
AlgaeIC50/72h:3.9000mg/l
AlgaeEC50/72h:18.6mg/l
AlgaeEC50/72h:275mg/l
FatheadminnowsLC50/96h:14200mg/l
GoldenorfeLC50/48h:>100mg/l
AlgaeEC50/72h:>2900mg/l
RainbowtroutLC50/96h:54000mg/l
SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.
Theproductisnotbioaccumulating.
StoneacreLeatherCleanerNodataavailable
Glycerol-1.76LogPow Amides,C8-C18(evennumbered) andC18(Unsaturated), N,N-Bis(Hydroxyethyl) 3.75LogPow
Ethanol:EthylAlcohol-0.35logP
2-butoxyethanol0.8logP
Thisproductissolubleinwater.
12.5.ResultsofPBTandvPvBassessment
Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.
12.6Endocrinedisruptingproperties
Nodataisavailableonthisproduct.
12.7.Otheradverseeffects
Nodataisavailableonthisproduct.
13.1.Wastetreatmentmethods
Generalinformation
Disposalofpackaging
Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.
Disposeofincompliancewithalllocalandnationalrequirements.
DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.
SECTION14:Transportinformation

14.1.UNnumber
14.2.UNpropershippingname
14.3.Transporthazardclass(es)
14.4.Packinggroup
14.5.Environmentalhazards
14.6.Specialprecautionsforuser
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
14.7MaritimeTransportinbulkaccordingtoIMOinstruments
Theproductisnotclassifiedasdangerousforcarriage.
15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture
Regulations
REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.
COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.
COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).
15.2.Chemicalsafetyassessment
Noinformationavailable.
Revision Thisdocumentdiffersfromthepreviousversioninthefollowingareas:. 1-ProductUse. 2-Otherhazards. 2-Furtherinformation.
2-SUPPLEMENTALHAZARDINFORMATION. 3-3.2.Mixtures.
9-9.2.2.Othersafetycharacteristics. 9-9.2.1.Informationwithregardtophysicalhazardclasses. 10-10.2.Chemicalstability. 10-10.1.Reactivity. 11-Acutetoxicity. 11-11.2Informationonotherhazards.

Otherinformation
Datasources
TextofHazardStatementsin Section3
12-12.1.Toxicity.
12-12.6Endocrinedisruptingproperties. 12-12.7.Otheradverseeffects. 15-Regulations.
ClassificationandProcedureusedtoderivetheclassificationformixturesaccordingtoRegulation (EC)No.1272/2008,asretainedandamendedinUKlaw.
EyeIrrit.2:H319-Causesseriouseyeirritation.-CalculationMethod.
SkinIrrit.2:H315-Causesskinirritation.
EyeDam.1:H318-Causesseriouseyedamage.
AquaticChronic2:H411-Toxictoaquaticlifewithlonglastingeffects.
AcuteTox.4:H302-Harmfulifswallowed.
AquaticAcute1:H400-Verytoxictoaquaticlife.
Flam.Liq.2:H225-Highlyflammableliquidandvapour.
EyeIrrit.2:H319-Causesseriouseyeirritation.
AcuteTox.4:H302+H312+H332-Harmfulifswallowed,incontactwithskinorifinhaled
Furtherinformation
TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.



accordingtoRegulation(EU)2020/878
SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking
1.1.Productidentifier
Productname UniversalCleaner
1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst
ProductUse [SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);
Description Multi-purposealkalinecleaner.
1.3.Detailsofthesupplierofthesafetydatasheet
Company SUPAGARDLIMITED
Address 19-27GavintonStreet Muirend Glasgow G443EF
Web www.supagard.com
Telephone 01416335933
Fax 01416377219
Email James.Smyth@supagard.com
Emailaddressofthe competentperson James.Smyth@supagard.com
1.4.Emergencytelephonenumber
Emergencytelephonenumber01416335933 8.30amto5.00pm
FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)
Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org
SECTION2:Hazardsidentification
2.1.Classificationofthesubstanceormixture
2.1.2.Classification-EC 1272/2008 SkinIrrit.2:H315;EyeDam.1:H318;
2.2.Labelelements
Hazardpictograms

SignalWord Danger
HazardStatement
SkinIrrit.2:H315-Causesskinirritation. EyeDam.1:H318-Causesseriouseyedamage.

2.2.Labelelements
PrecautionaryStatement: Prevention
PrecautionaryStatement: Response
SUPPLEMENTALHAZARD INFORMATION
P280-Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection.
P302+P352-IFONSKIN:Washwithplentyofwater/. P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.
P332+P313-Ifskinirritationoccurs:Getmedicaladvice/attention.
P337+P313-Ifeyeirritationpersists:Getmedicaladvice/attention.
IngredientsasrequiredbyRegulation(EC)No648/2004:.
3.8%Phosphatesbyweight,5-15%AnionicSurfactants,Lessthan5%Non-IonicSurfactants,CI 45350.
Contains-C9-11Alcohol,ethoxylated,sodium(xylenesand4-ethylbenzene)sulfonate, Tetrapotassiumpyrophosphate,SodiumMetasilicatePentahydrate,2-butoxyethanol.
2.3.Otherhazards
Otherhazards
Furtherinformation
Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.
RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.
SECTION3:Composition/informationoningredients
3.2.Mixtures
EC1272/2008
ChemicalName
C9-11Alcohol,ethoxylated 68439-45-2
sodium(xylenesand 4-ethylbenzene)sulfonate
Tetrapotassiumpyrophosphate
SodiumMetasilicatePentahydrate
701-037-101-2119513350-56
7320-34-5230-785-701-2119489369-18
10213-79-3229-912-901-2119449811-37
AcuteTox.4:H302;Eye Dam.1:H318; 1-10%
EyeIrrit.2:H319;1-10%
EyeIrrit.2:H319;1-10%
Met.Corr.1:H290;SkinCorr. 1B:H314;STOTSE3:H335; 1-10% 2-butoxyethanol
603-014-00-0111-76-2203-905-001-2119475108-36
SECTION4:Firstaidmeasures
4.1.Descriptionoffirstaidmeasures
Inhalation
Movetheexposedpersontofreshair.
AcuteTox.4:H332;Acute Tox.4:H312;AcuteTox.4: H302;EyeIrrit.2:H319;Skin Irrit.2:H315; 1-10%
Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved.
Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution.
Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.
4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed
Inhalation Maycauseirritationtorespiratorysystem.
Eyecontact Causesseriouseyedamage.
Skincontact Causesskinirritation.
Ingestion Maycauseirritationtomucousmembranes.
4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded
Inhalation Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.
Eyecontact Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded Skincontact Seekmedicalattentionifirritationorsymptomspersist. Ingestion Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.
Generalinformation
Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.
5.1.Extinguishingmedia
Useextinguishingmediaappropriatetothesurroundingfireconditions.
5.2.Specialhazardsarisingfromthesubstanceormixture
Burningproducesirritating,toxicandobnoxiousfumes.
5.3.Adviceforfirefighters
Furtherinformation
Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.
Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.
6.1.Personalprecautions,protectiveequipmentandemergencyprocedures
Wearsuitableprotectiveequipment.Avoidcontactwitheyesandskin.Provideadequate ventilation.
6.2.Environmentalprecautions
Adviselocalauthoritiesiflargespillscannotbecontained.
6.3.Methodsandmaterialforcontainmentandcleaningup
Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.
6.4.Referencetoothersections
Seesection2,7,8,13forfurtherinformation.
7.1.Precautionsforsafehandling
AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact witheyesandskin.Provideadequateventilation.
7.2.Conditionsforsafestorage,includinganyincompatibilities
Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.
7.3.Specificenduse(s)
8.1.Controlparameters
Multi-purposealkalinecleaner.

8.1.Controlparameters
8.1.1.ExposureLimitValues
2-butoxyethanol
Occupationalexposurecontrols.
WEL8-hrlimitppm:25
WEL15minlimitppm:50
WEL8-hrlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3:123
WEL15minlimitmg/m3:101.2
WEL15minlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -
DNEL:Derivedno-effectlevel.
ExposurePattern-Workers
2-butoxyethanol
sodium(xylenesand 4-ethylbenzene)sulfonate
SodiumMetasilicate Pentahydrate
Acuteinhalation-Systemic effects 1091mg/m³
Acuteinhalation-Localeffects246mg/m³
Long-term-inhalation-Systemic effects 98mg/m³
Long-term-inhalation-Systemic effects 26.9mg/m³
Long-term-dermal-Systemic effects 136.25mg/kg
Long-term-inhalation-Systemic effects 6.22mg/m³
Long-term-dermal-Systemic effects 1.49mg/kg
ExposurePattern-Generalpopulation
2-butoxyethanol
sodium(xylenesand 4-ethylbenzene)sulfonate
SodiumMetasilicate Pentahydrate
8.2.Exposurecontrols
Acuteinhalation-Systemic effects 426mg/m³
Acutedermal-Systemiceffects89mg/kg
Long-term-inhalation-Systemic effects 59mg/m³
Long-term-dermal-Systemic effects 75mg/kg
Long-term-inhalation-Systemic effects 6.6mg/m³
Long-term-dermal-Systemic effects 68.1mg/kg
Long-term-oral-Systemic effects 3.8mg/kg
Long-term-inhalation-Systemic effects 1.55mg/m³
Long-term-dermal-Systemic effects 0.74mg/kg



Acutedermal-Systemiceffects89mg/kg
Long-term-dermal-Systemic effects 125mg/kg
Acuteoral-Systemiceffects26.7mg/kg
Long-term-inhalation-Local effects 147mg/m³
Long-term-oral-Systemiceffects6.3mg/kg
Long-term-dermal-Localeffects0.048mg/cm³
Long-term-oral-Systemiceffects0.74mg/kg
8.2.Exposurecontrols
8.2.1.Appropriateengineering controls
Eye/faceprotection
SkinprotectionHandprotection
Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.
Eyewearcomplyingwithanapprovedstandardshouldbewornifariskassessmentindicateseye contactispossible.Thefollowingprotectionshouldbeworn:Wearchemicalsplashgoggles. PersonalprotectiveequipmentforeyeandfaceprotectionshouldcomplywithEuropeanStandard EN166.
Chooseglovestoprotecthandsagainstchemicalsdependingontheconcentrationandquantityof thehazardoussubstanceandspecifictoplaceofwork.Forspecialapplications,werecommend clarifyingtheresistancetochemicalsoftheaforementionedprotectivegloveswiththeglove manufacturer.
Skinprotection-Other Wearsuitableprotectiveclothing. Respiratoryprotection
Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.
8.2.3.Environmentalexposure controls Preventfurtherleakageorspillageifsafetodoso.
9.1.Informationonbasicphysicalandchemicalproperties
AppearanceLiquid
ColourClear
OdourCharacteristic
OdourthresholdNodataavailable pH<11
MeltingpointNodataavailable
InitialboilingpointNodataavailable
FlashpointNodataavailable EvaporationrateNodataavailable Flammability(solid,gas)Nodataavailable
VapourpressureNodataavailable
RelativeVapourDensityNodataavailable Density/RelativeDensity1.068-1.075g/cm3
PartitioncoefficientNodataavailable
AutoignitiontemperatureNodataavailable
Viscosity<50centipoise
ExplosivepropertiesNodataavailable
OxidisingpropertiesNodataavailable SolubilitySolubleinwater
9.2.Otherinformation
ConductivityNodataavailable SurfacetensionNodataavailable GasgroupNodataavailable BenzeneContentNodataavailable
LeadcontentNodataavailable VOC(Volatileorganic compounds) Nodataavailable
9.2.1.Informationwithregardtophysicalhazardclasses Nodataisavailableonthisproduct.
9.2.2.Othersafetycharacteristics Nodataisavailableonthisproduct.

10.1.Reactivity
10.2.Chemicalstability
Stableundernormalconditions.
Stableundernormalconditions.
10.3.Possibilityofhazardousreactions
Noneknown.
10.4.Conditionstoavoid
10.5.Incompatiblematerials
Protectfromfrost.
Strongacids.Strongoxidisingagents.
10.6.Hazardousdecompositionproducts
NoHazardousdecompositionproductswhenstoredandhandledcorrectly.
11.1Informationonhazardclasses
Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedusingthemethodsoutlinedinRegulation(EC)No1272/2008(CLP).
Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
OralATE=>10,000mg/kg.
DermalATE=>10,000mg/kg.
Inhalation-Dust/MistATE=>20mg/l.
Skincorrosion/irritation SkinIrrit.2:H315-Causesskinirritation.
Seriouseyedamage/irritationEyeDam.1:H318-Causesseriouseyedamage.
Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.
Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet. Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.
Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.
Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet.
Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.
11.1.2.Mixtures
11.1.3.HazardInformation
11.1.4.ToxicologicalInformation
Nodataavailable.
Nodataavailable.

11.1.4.ToxicologicalInformation
2-butoxyethanol
C9-11Alcohol,ethoxylated
sodium(xylenesand 4-ethylbenzene)sulfonate
SodiumMetasilicate Pentahydrate
11.2Informationonotherhazards
DermalRatLD50:1100mg/kg
InhalationRatLC50/4h:11.0mg/l
DermalRatLD50:>2000mg/kg
OralRatLD50:>7200mg/kg
InhalationRatLC50/4h:>6.41mg/l
DermalRatLD50:>5,000mg/kg
Nodataisavailableonthisproduct.
SECTION12:Ecologicalinformation
12.1.Toxicity
2-butoxyethanol
sodium(xylenesand 4-ethylbenzene)sulfonate
SodiumMetasilicate Pentahydrate
12.2.Persistenceanddegradability
12.3.Bioaccumulativepotential
Partitioncoefficient
12.4.Mobilityinsoil
DaphniaEC50/48h:1550.0000mg/l
RainbowtroutLC50/96h:1474mg/l
EC50formarineorfreshwater organisms >100.0000mg/l
DaphniaEC50/48h:1000.0000mg/l
RainbowtroutLC50/96h:>1000mg/l
DaphniaEC50/48h:1700.0000mg/l
BrachydanioRerioLC50/96h:210mg/l
OralRatLD50:1300mg/kg
OralRatLD50=>300-<=2000 mg/kg:
DermalRabbitLD50:>2000mg/kg
AlgaeEC50/72h:1840mg/
LC50formarineorfreshwater organisms >100.0000mg/l
GreenalgaeEC50/96h:230mg/l
AlgaeEC50/72h:207mg/l
SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.
Theproductisreadilybiodegradable.
UniversalCleanerNodataavailable 2-butoxyethanol0.8logP
Theproductisdilutableinwater.
12.5.ResultsofPBTandvPvBassessment
Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.
12.6Endocrinedisruptingproperties
Nodataisavailableonthisproduct.
12.7.Otheradverseeffects
Nodataisavailableonthisproduct.
13.1.Wastetreatmentmethods
Generalinformation
Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.
Disposeofincompliancewithalllocalandnationalrequirements.

Disposalofpackaging
DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.
14.1.UNnumber
14.2.UNpropershippingname
14.3.Transporthazardclass(es)
14.4.Packinggroup
14.5.Environmentalhazards
14.6.Specialprecautionsforuser
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
14.7MaritimeTransportinbulkaccordingtoIMOinstruments
Theproductisnotclassifiedasdangerousforcarriage.
15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.
COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.
COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).
Thisdocumentdiffersfromthepreviousversioninthefollowingareas:.
2-Otherhazards.
2-Furtherinformation.
2-SUPPLEMENTALHAZARDINFORMATION.
9-9.2.2.Othersafetycharacteristics.
9-9.2.1.Informationwithregardtophysicalhazardclasses. 10-10.2.Chemicalstability.

Otherinformation
Datasources
TextofHazardStatementsin
Section3
Furtherinformation
10-10.6.Hazardousdecompositionproducts. 10-10.1.Reactivity. 11-Acutetoxicity.
11-Repeatedorprolongedexposure. 11-11.2Informationonotherhazards. 12-12.1.Toxicity.
12-12.6Endocrinedisruptingproperties. 12-12.7.Otheradverseeffects. 15-Regulations.
ClassificationandProcedureusedtoderivetheclassificationformixturesaccordingtoRegulation (EC)No.1272/2008,asretainedandamendedinUKlaw.
SkinIrrit.2:H315-Causesskinirritation.-CalculationMethod.
EyeDam.1:H318-Causesseriouseyedamage.-CalculationMethod.
AcuteTox.4:H302-Harmfulifswallowed.
EyeDam.1:H318-Causesseriouseyedamage.
EyeIrrit.2:H319-Causesseriouseyeirritation.
Met.Corr.1:H290-Maybecorrosivetometals.
SkinCorr.1B:H314-Causessevereskinburnsandeyedamage. STOTSE3:H335-Maycauserespiratoryirritation.
AcuteTox.4:H302+H312+H332-Harmfulifswallowed,incontactwithskinorifinhaled
SkinIrrit.2:H315-Causesskinirritation.
TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.



SAFETY DATASHEET
Compilation date: 24/11/2021
Revision date: 14/05/2024
PETROL FUEL ADDITIVE Page: 1
Revision No: 3
Section 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name: PETROL FUEL ADDITIVE
Product code: HC1712
Synonyms: PD0417 HC1712
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of substance / mixture: PC13: Fuels.
1.3. Details of the supplier of the safetydata sheet
Companyname: SUPAGARD LIMITED 23 Gavinton Street Muirend Glasgow Scotland G44 3EF
Tel: 0141 633 5933
Email: james@supagard.co.uk
1.4. Emergencytelephone number
Emergencytel: 0141 633 5933 (office hours only)
Section 2: Hazards identification
2.1. Classification of the substance or mixture
Classification under CLP: Asp. Tox. 1: H304; Skin Irrit. 2: H315; Aquatic Chronic 3: H412
Most important adverse effects: May be fatal if swallowed and enters airways. Causes skin irritation. Harmful to aquatic life with long lasting effects.
2.2. Label elements
Label elements:
Hazard statements: H304: May be fatal if swallowed and enters airways.
H315: Causes skin irritation.
H412: Harmful to aquatic life with long lasting effects.
Hazard pictograms: GHS08: Health hazard
GHS07: Exclamation mark


SAFETY DATASHEET
PETROL FUEL ADDITIVE
Signal words: Danger
Precautionarystatements: P102: Keep out of reach of children.
P273: Avoid release to the environment.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor.
P331: Do NOT induce vomiting.
P405: Store locked up.
P501: Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Haz. ingredients (label): Contains:
HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS; HYDROCARBONS, C9 -C11, ALKANES, ISOALKANES, CYCLICS, <2% AROMATICS
2.3. Other hazards
PBT: This product is not identified as a PBT/vPvB substance.
Section 3: Composition/information on ingredients
3.2. Mixtures
Hazardous ingredients:
HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS - REACH registered number(s): 01-2119456620-43XXXX
926-141-6 64742-47-8 - Asp. Tox. 1: H304; -: EUH066
HYDROCARBONS, C9-C11, ALKANES, ISOALKANES, CYCLICS, <2% AROMATICS - REACH registered number(s): 01-2119463258-33-XXXX
919-857-5 1174522-20 -3 - Flam. Liq. 3: H226; STOT SE 3: H336; Asp. Tox. 1: H304; -: EUH066
1-PROPENE, 2-METHYL-HOMOPOLYMER, AMMONIUMSALT - REACH registered number(s): 1-2119475608-26-XXXX - 337367-30-3 - Skin Irrit. 2: H315; Aquatic Chronic 3: H412 1-10%
Section 4: First aid measures
4.1. Description of first aid measures
Skin contact: Wash immediately with plenty of soap and water.
Eye contact: Bathe the eye with running water for 15 minutes.
Ingestion: Wash out mouth with water. Do not induce vomiting. If conscious, give half a litre of water to drink immediately. Transfer to hospital as soon as possible.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Move to fresh air in case of accidental inhalation of vapours. Consult a doctor.
4.2. Most important symptoms and effects, both acute and delayed
Skin contact: There may be mild irritation at the site of contact.
Eye contact: There may be irritation and redness.
Ingestion: There may be soreness and redness of the mouth and throat. There may be difficulty swallowing. Nausea and stomach pain may occur. There may be vomiting.
Inhalation: Absorption through the lungs can occur causing symptoms similar to those of ingestion.
4.3. Indication of anyimmediate medical attention and special treatment needed
5.1. Extinguishing media
Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers.
5.2. Special hazards arising from the substance or mixture
Exposure hazards: In combustion emits toxic fumes.
5.3. Advice for fire-fighters
Section
Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.
6.1. Personal precautions, protective equipment and emergencyprocedures
Personal precautions: Refer to section 8 of SDS for personal protection details. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Turn leaking containers leak-side up to prevent the escape of liquid.
6.2. Environmental precautions
Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.
6.3. Methods and material for containment and cleaning up
Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method. Wash the ground with an appropriate selfemulsifying solvent.
6.4. Reference to other sections
Section 7: Handling and storage
7.1. Precautions for safe handling
Handling requirements: Avoid the formation or spread of mists in the air. Avoid direct contact with the substance.
7.2. Conditions for safe storage, including anyincompatibilities
Storage conditions: Store in a cool, well ventilated area. Keep container tightly closed.
7.3. Specific end use(s)
Section 8: Exposure controls/personal protection
8.1. Control parameters
Hazardous ingredients:
HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS
Workplace exposure limits:
Respirable dust:
HYDROCARBONS, C9-C11, ALKANES, ISOALKANES, CYCLICS, <2%AROMATICS
DNEL/PNEC Values
DNEL / PNEC No data available.
8.2. Exposure controls
Engineering measures: Ensure there is sufficient ventilation of the area.
Respiratoryprotection: Respiratory protection not required.
Hand protection: Protective gloves.
Eye protection: Safety glasses. Ensure eye bath is to hand.
Skin protection: Protective clothing.
Section 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
State: Liquid
Colour: Pale yellow
Odour: Paraffinic
Evaporation rate: Slow
Solubilityin water: Insoluble
Viscosity: Non-viscous
Boiling point/range°C: >100
Melting point/range°C: -30
Flammabilitylimits %:lower: 0.9 upper: 4.0
Flash point°C: 60 - 93
Autoflammability°C: >200
Relative density: 0.815
VOC g/l: No data available.
9.2. Other information
Other information: No data available.
Part.coeff. n-octanol/water: No data available.
Vapour pressure: No data available.
pH: No data available.
PETROL FUEL ADDITIVE
Section 10: Stabilityand reactivity
10.1. Reactivity
Reactivity: Stable under recommended transport or storage conditions.
10.2. Chemical stability
Chemical stability: Stable under normal conditions.
10.3. Possibilityof hazardous reactions
Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.
10.4. Conditions to avoid
Conditions to avoid: Heat.
10.5. Incompatible materials
Materials to avoid: Strong oxidising agents. Strong acids.
10.6. Hazardous decomposition products
Haz. decomp. products: In combustion emits toxic fumes.
11.1. Information on toxicological effects
Hazardous ingredients:
HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS
DERMAL RBT
HYDROCARBONS, C9-C11, ALKANES, ISOALKANES, CYCLICS, <2%AROMATICS
DERMAL
Relevant hazards for product:
Skin corrosion/irritation DRM Hazardous: calculated
Aspiration hazard - Hazardous: calculated
Symptoms / routes of exposure
Skin contact: There may be mild irritation at the site of contact.
Eye contact: There may be irritation and redness.
mg/kg
mg/kg
mg/l
Ingestion: There may be soreness and redness of the mouth and throat. There may be difficulty swallowing. Nausea and stomach pain may occur. There may be vomiting.
PETROL FUEL ADDITIVE
Inhalation: Absorption through the lungs can occur causing symptoms similar to those of ingestion.
Section 12: Ecological information
12.1. Toxicity
Hazardous ingredients:
HYDROCARBONS, C11-C14, ISOALKANES, LOW AROMATICS
Daphnia magna
RAINBOW TROUT (Oncorhynchus mykiss)
EC50
LC50
HYDROCARBONS, C9-C11, ALKANES, ISOALKANES, CYCLICS, <2%AROMATICS
ALGAE
RAINBOW TROUT (Oncorhynchus mykiss)
12.2. Persistence and degradability
Persistence and degradability: Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential: No bioaccumulation potential.
12.4. Mobilityin soil
IC50
LC50
mg/l
Mobility: Readily absorbed into soil. Volatile. Insoluble in water. Floats on water. Vapour is heavier than air.
12.5. Results of PBT and vPvB assessment
PBT identification: This product is not identified as a PBT/vPvB substance.
12.6. Other adverse effects
Other adverse effects: Harmful to aquatic organisms.
Section 13: Disposal considerations
13.1. Waste treatment methods
Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.
Recoveryoperations: Solvent reclamation/regeneration.
Waste code number: 20 01 13
Disposal of packaging: Dispose of as normal industrial waste. Arrange for collection by specialised disposal company.
NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.
Section 14: Transport information
Transport class: This product does not require a classification for transport.
Section 15: Regulatoryinformation
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Specific regulations: Not applicable.
15.2. Chemical SafetyAssessment
Chemical safetyassessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.
Section 16: Other information
Other information
Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 2015/830.
IMPORTANT NOTE:
Risk phases in this section belowrelate to the INDIVIDUAL COMPONENTS in the formulation when used at their FULL CONCENTRATIONS, and not at the reduced levels in the mixed product.
See sections 2 and 3 for the calculated hazard and risk phrases for the blended product.
Phrases used in s.2 and s.3: EUH066: Repeated exposure may cause skin dryness or cracking.
H226: Flammable liquid and vapour.
H304: May be fatal if swallowed and enters airways.
H315: Causes skin irritation.
H336: May cause drowsiness or dizziness.
H412: Harmful to aquatic life with long lasting effects.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.


according to Regulation (EU) 2020/878
SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking
1.1.Productidentifier
Productname Exterior Plastic Dressing
1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst
ProductUse
[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC35]Washingandcleaningproducts(includingsolventbasedproducts);
[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC35]Washingand cleaningproducts(includingsolventbasedproducts);
Description Vehicleexteriorplasticdressing.
1.3.Detailsofthesupplierofthesafetydatasheet
Company SUPAGARDLIMITED
Address 19-27GavintonStreet Muirend Glasgow G443EF
Web www.supagard.com
Telephone 01416335933
Fax 01416377219
Email James.Smyth@supagard.com
Emailaddressofthe competentperson James.Smyth@supagard.com
1.4.Emergencytelephonenumber
Emergencytelephonenumber01416335933
8.30amto5.00pm
FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)
Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org
SECTION2:Hazardsidentification
2.1.Classificationofthesubstanceormixture
2.1.2.Classification-EC 1272/2008 Asp.Tox.1:H304;STOTSE3:H336;
2.2.Labelelements
Hazardpictograms



2.2.Labelelements
SignalWord Danger
HazardStatement Asp.Tox.1:H304-Maybefatalifswallowedandentersairways. STOTSE3:H336-Maycausedrowsinessordizziness.
PrecautionaryStatement: Prevention P102-Keepoutofreachofchildren.
PrecautionaryStatement: Response
P301+P310+P330+P331-IFSWALLOWED:ImmediatelycallaPOISONCENTER/doctor.Rinse mouth.DoNOTinducevomiting.
PrecautionaryStatement: Storage P403+P233+P235-Storeinawell-ventilatedplace.Keepcontainertightlyclosed.Keepcool.
PrecautionaryStatement: Disposal
SUPPLEMENTALHAZARD INFORMATION
2.3.Otherhazards
Otherhazards
Furtherinformation
P501-Disposeofcontents/containertoanapproveddisposalsite,inaccordancewithlocal regulations.
Ingredients-Dimethicone,HydrocarbonSolvent,Aminomethoxy-functionalpolydimethylsiloxane, Parfum,CI60730.
Contains-HydrocarbonsC9-11,N-alkanes,Isoalkanes,Cyclics,<2%Aromatic.
Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.
RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.
SECTION3:Composition/informationoningredients
3.2.Mixtures
EC1272/2008
ChemicalName
Hydrocarbons,C9-11,N-alkanes, Isoalkanes,Cyclics,<2%Aromatic
Flam.Liq.3:H226;Asp.Tox. 1:H304;STOTSE3:H336;
AcuteToxicityEstimate(Oral)->10,000mg/kg.
AcuteToxicityEstimate(Dermal)->10,000mg/kg.
AcuteToxicityEstimate(Dust/Mist)->20mg/l.
AcuteToxicityEstimate(Vapours)->20mg/l.
SECTION4:Firstaidmeasures
4.1.Descriptionoffirstaidmeasures
Inhalation
Movetheexposedpersontofreshair.
Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved.
Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution.
Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.
4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed
Inhalation Harmfulbyinhalation.Maybefatalifswallowedandentersairways.Maycausedrowsinessor dizziness.
Eyecontact Maycauseirritationtoeyes.
Skincontact Maycauseirritationtoskin.
Ingestion Harmfulifswallowed.Maybefatalifswallowedandentersairways.
4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded
Inhalation
Movetheexposedpersontofreshair.Seekmedicalattention.Showthissafetydatasheettothe doctorinattendance.
Eyecontact Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedical

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded attention.Showthissafetydatasheettothedoctorinattendance. Skincontact
Ingestion
Generalinformation
Removecontaminatedclothing.Seekmedicalattention.Showthissafetydatasheettothedoctor inattendance.
Ifswallowed,seekmedicaladviceimmediatelyandshowthiscontainerorlabel.Showthissafety datasheettothedoctorinattendance.
Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.
5.1.Extinguishingmedia
Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.
5.2.Specialhazardsarisingfromthesubstanceormixture
Burningproducesirritating,toxicandobnoxiousfumes.
5.3.Adviceforfirefighters
Furtherinformation
Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.
Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.
6.1.Personalprecautions,protectiveequipmentandemergencyprocedures
6.2.Environmentalprecautions
Wearsuitableprotectiveequipment.
Adviselocalauthoritiesiflargespillscannotbecontained.
6.3.Methodsandmaterialforcontainmentandcleaningup
Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.
6.4.Referencetoothersections
Seesection2,7,8,13forfurtherinformation.
7.1.Precautionsforsafehandling
Avoidcontactwitheyesandskin.Donotbreathevapoursorspraymist.AdoptbestManual Handlingconsiderationswhenhandling,carryinganddispensing.
7.2.Conditionsforsafestorage,includinganyincompatibilities
Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.
7.3.Specificenduse(s)
Suitablepackaging
Vehicleexteriorplasticdressing.
Plasticcontainers.
SECTION8:Exposurecontrols/personalprotection

8.1.Controlparameters
8.2.Exposurecontrols
Occupationalexposurecontrols. Noworkplaceexposurelimitsapplicable.


AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.
8.2.1.Appropriateengineering controls
Eye/faceprotection
SkinprotectionHandprotection
Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.
Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields. Eyewearcomplyingwithanapprovedstandardshouldbewornifariskassessmentindicateseye contactispossible.Thefollowingprotectionshouldbeworn:Wearchemicalsplashgoggles. PersonalprotectiveequipmentforeyeandfaceprotectionshouldcomplywithEuropeanStandard EN166.
Rubbergloves.Chooseglovestoprotecthandsagainstchemicalsdependingontheconcentration andquantityofthehazardoussubstanceandspecifictoplaceofwork.Forspecialapplications, werecommendclarifyingtheresistancetochemicalsoftheaforementionedprotectivegloveswith theglovemanufacturer.
Skinprotection-Other Wearsuitableprotectiveclothing.
Respiratoryprotection Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.
8.2.3.Environmentalexposure controls Preventfurtherleakageorspillageifsafetodoso.
9.1.Informationonbasicphysicalandchemicalproperties
AppearanceGel
ColourPurple
OdourCharacteristic
OdourthresholdNodataavailable pHNodataavailable
MeltingpointNodataavailable
InitialboilingpointNodataavailable
Flashpoint>61°C
EvaporationrateNodataavailable
Flammability(solid,gas)Nodataavailable
VapourpressureNodataavailable
RelativeVapourDensityNodataavailable
Density/RelativeDensity0.8-0.9
PartitioncoefficientNodataavailable
AutoignitiontemperatureNodataavailable
ViscosityNodataavailable
ExplosivepropertiesNodataavailable
OxidisingpropertiesNodataavailable
SolubilityNodataavailable

9.2.Otherinformation
ConductivityNodataavailable
SurfacetensionNodataavailable
GasgroupNodataavailable
BenzeneContentNodataavailable
LeadcontentNodataavailable VOC(Volatileorganic compounds) Nodataavailable
9.2.1.Informationwithregardtophysicalhazardclasses
Nodataisavailableonthisproduct.
9.2.2.Othersafetycharacteristics
Nodataisavailableonthisproduct.
10.1.Reactivity
10.2.Chemicalstability
Stableundernormalconditions.
Stableundernormalconditions.
10.3.Possibilityofhazardousreactions
Strongacids.Strongoxidisingagents.
10.4.Conditionstoavoid
10.5.Incompatiblematerials
Protectfromfrost.
Noincompatiblegroupsnoted.
10.6.Hazardousdecompositionproducts
NoHazardousdecompositionproductswhenstoredandhandledcorrectly.
11.1Informationonhazardclasses
Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedusingthemethodsoutlinedinRegulation(EC)No1272/2008(CLP).
Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
OralATE=>10,000mg/kg.
DermalATE=>10,000mg/kg.
Inhalation-VapoursATE=>20mg/l.
Inhalation-Dust/MistATE=>20mg/l.
Skincorrosion/irritation basedonavailabledatatheclassificationcriteriaarenotmet.
Seriouseyedamage/irritationbasedonavailabledatatheclassificationcriteriaarenotmet. Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.
Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet.
Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.
Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-singleexposure STOTSE3:H336-Maycausedrowsinessordizziness.
STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.
Aspirationhazard Asp.Tox.1:H304-Maybefatalifswallowedandentersairways. Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.

11.1.2.Mixtures
11.1.3.HazardInformation
11.1.4.ToxicologicalInformation
Nodataavailable.
Nodataavailable.
Nodataavailable
11.2Informationonotherhazards
Nodataisavailableonthisproduct.
SECTION12:Ecologicalinformation
12.1.Toxicity
Nodataavailable
12.2.Persistenceanddegradability
SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.
12.3.Bioaccumulativepotential
Partitioncoefficient
12.4.Mobilityinsoil
Nodataisavailableonthisproduct.
StoneacreExteriorPlastic Dressing Nodataavailable
Nodataisavailableonthisproduct.
12.5.ResultsofPBTandvPvBassessment
Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.
12.6Endocrinedisruptingproperties
Nodataisavailableonthisproduct.
12.7.Otheradverseeffects
Nodataisavailableonthisproduct.
SECTION13:Disposalconsiderations
13.1.Wastetreatmentmethods
Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements. Generalinformation
Disposeofincompliancewithalllocalandnationalrequirements. Disposalofpackaging
DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.
SECTION14:Transportinformation
14.1.UNnumber
14.2.UNpropershippingname
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.

14.3.Transporthazardclass(es)
14.4.Packinggroup
14.5.Environmentalhazards
14.6.Specialprecautionsforuser
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
14.7MaritimeTransportinbulkaccordingtoIMOinstruments
Theproductisnotclassifiedasdangerousforcarriage.
15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations
REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.
COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.
COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).
15.2.Chemicalsafetyassessment
Noinformationavailable.
SECTION16:Otherinformation
Otherinformation
Datasources
TextofHazardStatementsin
Section3
Furtherinformation
ClassificationandProcedureusedtoderivetheclassificationformixturesaccordingtoRegulation (EC)No.1272/2008,asretainedandamendedinUKlaw.
Asp.Tox.1:H304-Maybefatalifswallowedandentersairways.-CalculationMethod.
STOTSE3:H336-Maycausedrowsinessordizziness.-CalculationMethod.
Flam.Liq.3:H226-Flammableliquidandvapour.
Asp.Tox.1:H304-Maybefatalifswallowedandentersairways.
STOTSE3:H336-Maycausedrowsinessordizziness.
TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.



SAFETY DATASHEET
ATMOSPHERIC SANITISER
Section 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name: ATMOSPHERIC SANITISER
Product code: HC8468
Synonyms: HC8468
PD0268-10
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of substance / mixture: Aerosol air freshener.
1.3. Details of the supplier of the safetydata sheet
Companyname: SUPAGARD LIMITED
23 Gavinton Street Muirend Glasgow Scotland G44 3EF
Tel: 0141 633 5933
Email: james@supagard.co.uk
1.4. Emergencytelephone number
Emergencytel: 0141 633 5933 (office hours only)
Section 2: Hazards identification
2.1. Classification of the substance or mixture
Classification under CLP: Flam. Aerosol 1: H222; -: H229
Page: 1
Compilation date: 24/08/2022
Revision date: 14/05/2024
Revision No: 2
Most important adverse effects: Extremely flammable aerosol. Pressurised container: May burst if heated.
2.2. Label elements
Label elements:
Hazard statements: H222: Extremely flammable aerosol.
H229: Pressurised container: May burst if heated.
Hazard pictograms: GHS02: Flame

Signal words: Danger
Precautionarystatements: P102: Keep out of reach of children.
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P211: Do not spray on an open flame or other ignition source.
P251: Do not pierce or burn, even after use.
P410+P412: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
P302+P350: IF ON SKIN: Gently wash with plenty of soap and water.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Haz. ingredients (label): Contains: ETHANOL, LIQUIFIED PETROLEUMGAS PROPELLANT
2.3. Other hazards
Other hazards: In use, may form flammable / explosive vapour-air mixture. PBT: This product is not identified as a PBT/vPvB substance.
Section 3: Composition/information on ingredients
3.2. Mixtures
Hazardous ingredients: ETHANOL - REACH registered number(s): 01-2119457610-43-XXXX
Liq. 2: H225
<0.1% 1,3 BUTADIENE - REACH registered number(s): 01-2119474691-32-XXXX 203-448-7 106-97-8 Substance with a Community workplace exposure limit. Flam. Gas 1: H220; Press. Gas: H280
PROPANE, <0.1% 1,3 BUTADIENE - REACH registered number(s): 01-2119486944-21-XXXX
200-827-9 74-98-6 Substance with a Community workplace exposure limit. Flam. Gas 1: H220; Press. Gas: H280
N-(3-AMINOPROPYL)-N-DODECYLPROPANE-1,3,DIAMINE - REACH registered number(s): 01-2119980592-29
219-145-8 2372-82-9 - Acute Tox. 3: H301; Skin Corr. 1B: H314; Eye Dam. 1: H318; STOT RE 2: H373; Aquatic Acute 1: H400; Aquatic Chronic 1: H410
4.1. Description of first aid measures
Skin contact: Wash immediately with plenty of soap and water.
Eye contact: Bathe the eye with running water for 15 minutes. Consult a doctor.
Ingestion: Do not induce vomiting. If conscious, give half a litre of water to drink immediately. Consult a doctor.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Move to fresh air in case of accidental inhalation of vapours. Consult a doctor.
4.2. Most important symptoms and effects, both acute and delayed
Skin contact: There may be mild irritation at the site of contact.
Eye contact: There may be irritation and redness.
Ingestion: There may be irritation of the throat.
Inhalation: There may be a feeling of tightness in the chest with shortness of breath.
4.3. Indication of anyimmediate medical attention and special treatment needed
Immediate / special treatment: Not applicable.
5.1. Extinguishing media
Extinguishing media: Alcohol resistant foam. Water spray. Carbon dioxide. Dry chemical powder.
5.2. Special hazards arising from the substance or mixture
Exposure hazards: Highly flammable. In combustion emits toxic fumes. Forms explosive air-vapour mixture. Vapour may travel considerable distance to source of ignition and flash back. Aerosol cans may explode during a fire, giving a high speed projectile.
5.3. Advice for fire-fighters
Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.
Section 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergencyprocedures
Personal precautions: Refer to section 8 of SDS for personal protection details. Notify the police and fire brigade immediately. Eliminate all sources of ignition. Cover leaking can until the discharge has stopped, before attempting cleanup operations.
6.2. Environmental precautions
Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.
6.3. Methods and material for containment and cleaning up
Clean-up procedures: Do not use equipment in clean-up procedure which may produce sparks. Absorb into dry earth or sand. Clean-up should be dealt with only by qualified personnel familiar with the specific substance. Wash the spillage site with large amounts of water.
6.4. Reference to other sections
Reference to other sections: Refer to section 8 of SDS.
Section 7: Handling and storage
7.1. Precautions for safe handling
Handling requirements: Smoking is forbidden. Use non-sparking tools. Ensure there is sufficient ventilation of the area. Do not handle in a confined space.
7.2. Conditions for safe storage, including anyincompatibilities
Storage conditions: Store in a cool, well ventilated area. Keep away from sources of ignition. Keep away from direct sunlight.
7.3. Specific end use(s)
Specific end use(s): No data available.
Section 8: Exposure controls/personal protection
8.1. Control parameters
Hazardous ingredients: ETHANOL
Workplace exposure limits:
dust:
BUTANE, <0.1%1,3 BUTADIENE
PROPANE, <0.1%1,3 BUTADIENE
DNEL/PNEC Values
Hazardous ingredients:
ATMOSPHERIC SANITISER
PNEC Fresh water 0.001mg/L -
PNEC Marine water 0.0001mg/L - -
PNEC Fresh water sediments 8.5mg/kg dry weight - -
PNEC Marine sediments 0.85mg/kg dry weight
PNEC Soil (agricultural) 45.34mg/kg dry weigh -
PNEC Microorganisms in sewage treatment 1.33mg/L
8.2. Exposure controls
Engineering measures: Ensure there is sufficient ventilation of the area. Ensure lighting and electrical equipment are not a source of ignition.
Respiratoryprotection: Respiratory protection not required.
Hand protection: Protective gloves.
Eye protection: Safety glasses. Ensure eye bath is to hand.
Skin protection: Protective clothing.
9.1. Information on basic physical and chemical properties
State: Aerosol
Colour: Colourless
Odour: Perfumed
Evaporation rate: Fast
Solubilityin water: Soluble
Viscosity: Non-viscous
Boiling point/range°C: No data available.
Melting point/range°C: No data available.
Flammabilitylimits %:lower: 0.9 upper: 9.0
Flash point°C: -40
Autoflammability°C: >230
Part.coeff. n-octanol/water: Not applicable.
Vapour pressure: No data available.
Relative density: No data available. pH: Not applicable.
VOC g/l: No data available.
9.2. Other information
Other information: No data available.
10.1. Reactivity
Reactivity: Stable under recommended transport or storage conditions.
10.2. Chemical stability
Chemical stability: Stable under normal conditions. Stable at room temperature.
10.3. Possibilityof hazardous reactions
Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions. Decomposition may occur on exposure to conditions or materials listed below.
10.4. Conditions to avoid
Conditions to avoid: Heat. Hot surfaces. Sources of ignition. Flames. Direct sunlight.
10.5. Incompatible materials
Materials to avoid: Strong oxidising agents. Strong acids.
10.6. Hazardous decomposition products
Haz. decomp. products: In combustion emits toxic fumes.
11.1. Information on toxicological effects
Hazardous ingredients:
Toxicityvalues: No data available.
Symptoms / routes of exposure
Skin contact: There may be mild irritation at the site of contact.
Eye contact: There may be irritation and redness.
Ingestion: There may be irritation of the throat.
Inhalation: There may be a feeling of tightness in the chest with shortness of breath.
12.1. Toxicity
Hazardous ingredients:
ATMOSPHERIC SANITISER
N-(3-AMINOPROPYL)-N-DODECYLPROPANE-1,3,DIAMINE
Daphnia magna
GREEN ALGA (Selenastrum capricornutum)
ZEBRAFISH (Brachydanio rerio)
12.2. Persistence and degradability
Persistence and degradability: Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential: No bioaccumulation potential.
12.4. Mobilityin soil
EC50 >0.01-0.1 mg/l
ErC50
LC50
Mobility: Readily absorbed into soil. Volatile. Soluble in water. Vapour is heavier than air.
12.5. Results of PBT and vPvB assessment
PBT identification: This product is not identified as a PBT/vPvB substance.
12.6. Other adverse effects
Other adverse effects: Negligible ecotoxicity.
Section 13: Disposal considerations
13.1. Waste treatment methods
Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.
Recoveryoperations: Recycling/reclamation of metals and metal compounds.
Waste code number: 16 05 05
Disposal of packaging: Dispose of as normal industrial waste. Empty cans must not be burned because of explosion hazard.
NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.
Section 14: Transport information
14.1. UN number
UN number: UN1950
14.2. UN proper shipping name
Shipping name: AEROSOLS
14.3. Transport hazard class(es)
Transport class: 2
14.4. Packing group
14.5. Environmental hazards
Environmentallyhazardous: No
14.6. Special precautions for user
Special precautions: No special precautions.
Tunnel code: D
Transport category: 2
Section 15: Regulatoryinformation
Marine pollutant: No
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Specific regulations: Not applicable.
15.2. Chemical SafetyAssessment
Chemical safetyassessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.
Section 16: Other information
Other information
Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 2015/830.
All substances in this preparation are registered within UK/EU/EFTA countries under the REACH (UK/EC) (ammended) regulations, EC 1907/2006
IMPORTANT NOTE:
Risk phases in this section belowrelate to the INDIVIDUAL COMPONENTS in the formulation when used at their FULL CONCENTRATIONS, and not at the reduced levels in the mixed product.
See sections 2 and 3 for the calculated hazard and risk phrases for the blended product.
Phrases used in s.2 and s.3: H220: Extremely flammable gas.
H222: Extremely flammable aerosol.
H225: Highly flammable liquid and vapour.
H229: Pressurised container: May burst if heated.
H301: Toxic if swallowed.
H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
H373: May cause damage to organs through prolonged or repeated exposure.
H400: Very toxic to aquatic life.
H410: Very toxic to aquatic life with long lasting effects.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.

SAFETY DATASHEET
SCENT CYCLONE REJUVENATE
Section 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name: SCENT CYCLONE REJUVENATE
Product code: HC8542
Synonyms: HC8542 / PD1077
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of substance / mixture: Aerosol air freshener.
1.3. Details of the supplier of the safetydata sheet
Companyname: SUPAGARD LIMITED
23 Gavinton Street
Muirend Glasgow Scotland G44 3EF
Tel: 0141 633 5933
Email: james@supagard.co.uk
1.4. Emergencytelephone number
Emergencytel: 0141 633 5933 (office hours only)
Section 2: Hazards identification
2.1. Classification of the substance or mixture
Classification under CLP: Flam. Aerosol 1: H222; -: H229
Page: 1
Compilation date: 18/07/2024
Revision No: 1
Most important adverse effects: Extremely flammable aerosol. Pressurised container: May burst if heated.
2.2. Label elements
Label elements:
Hazard statements: H222: Extremely flammable aerosol.
H229: Pressurised container: May burst if heated.
Hazard pictograms: GHS02: Flame

Signal words: Danger
Precautionarystatements: P102: Keep out of reach of children.
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition
SCENT CYCLONE REJUVENATE
sources. No smoking.
P211: Do not spray on an open flame or other ignition source.
P251: Do not pierce or burn, even after use.
P410+P412: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
2.3. Other hazards
Other hazards: In use, may form flammable / explosive vapour-air mixture. Contains no PBT/vPvB substances >/= 0.1% assessed in accordance with REACH AnnexXIII. This mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine distrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0.1%.
PBT: This product is not identified as a PBT/vPvB substance.
Section 3: Composition/information on ingredients
3.2. Mixtures
Hazardous ingredients:
ETHANOL - REACH registered number(s): 01-2119457610-43-XXXX
<0.1% 1,3 BUTADIENE - REACH registered number(s): 01-2119474691-32-XXXX
with a Community workplace exposure limit.
<0.1% 1,3 BUTADIENE - REACH registered number(s): 01-2119486944-21-XXXX
Section 4: First aid measures
4.1. Description of first aid measures
Skin contact: Wash immediately with plenty of soap and water.
Eye contact: Bathe the eye with running water for 15 minutes.
Ingestion: Wash out mouth with water.
Inhalation: Consult a doctor in case of complaints
4.2. Most important symptoms and effects, both acute and delayed
Skin contact: There may be mild irritation at the site of contact.
Eye contact: There may be irritation and redness.
Ingestion: There may be irritation of the throat.
Inhalation: No symptoms.
4.3. Indication of anyimmediate medical attention and special treatment needed
Immediate / special treatment: Not applicable.
Section 5: Fire-fighting measures
5.1. Extinguishing media
Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers.
5.2. Special hazards arising from the substance or mixture
Exposure hazards: In combustion emits toxic fumes.
5.3. Advice for fire-fighters
Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.
Section 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergencyprocedures
Personal precautions: Refer to section 8 of SDS for personal protection details. Cover leaking can until the discharge has stopped, before attempting cleanup operations.
6.2. Environmental precautions
Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.
6.3. Methods and material for containment and cleaning up
Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method. Extinguish all ignition sources. Ventilate area well. Avoid sparks, flames, smoking and any other heat source. Leaking material will evaporate leaving no residues.
6.4. Reference to other sections
Reference to other sections: Refer to section 8 of SDS.
Section 7: Handling and storage
7.1. Precautions for safe handling
Handling requirements: Smoking is forbidden. Use non-sparking tools. Ensure there is sufficient ventilation of the area. Do not handle in a confined space.
7.2. Conditions for safe storage, including anyincompatibilities
Storage conditions: Store in a cool, well ventilated area. Keep container tightly closed.
SCENT CYCLONE REJUVENATE
7.3. Specific end use(s)
Specific end use(s): No data available.
Section 8: Exposure controls/personal protection
8.1. Control parameters
Hazardous ingredients: ETHANOL
Workplace exposure limits:
Respirable dust:
mg/m3
BUTANE, <0.1%1,3 BUTADIENE UK
mg/m3
PROPANE, <0.1%1,3 BUTADIENE
UK Asphyxiating Asphyxiating -
DNEL/PNEC Values
DNEL / PNEC No data available.
8.2. Exposure controls
Engineering measures: Ensure there is sufficient ventilation of the area. Ensure lighting and electrical equipment are not a source of ignition.
Respiratoryprotection: Respiratory protection not required.
Hand protection: Protective gloves.
Eye protection: Safety glasses. Ensure eye bath is to hand.
Skin protection: Protective clothing.
Section 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
State: Aerosol
Colour: Colourless
Odour: Perfumed
Evaporation rate: Fast
Solubilityin water: Soluble
Viscosity: Non-viscous
Boiling point/range°C: No data available.
Melting point/range°C: No data available.
Flammabilitylimits %:lower: 0.9 upper: 9.0
Flash point°C: -40
Autoflammability°C: >230
Part.coeff. n-octanol/water: Not applicable.
Vapour pressure: No data available.
Relative density: No data available. pH: Not applicable.
VOC g/l: No data available.
9.2. Other information
Other information: No data available.
Section 10: Stabilityand reactivity
10.1. Reactivity
Reactivity: Stable under recommended transport or storage conditions.
10.2. Chemical stability
Chemical stability: Stable under normal conditions.
10.3. Possibilityof hazardous reactions
Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.
Decomposition may occur on exposure to conditions or materials listed below.
10.4. Conditions to avoid
Conditions to avoid: Heat. Hot surfaces. Sources of ignition. Flames. Direct sunlight.
10.5. Incompatible materials
Materials to avoid: Strong oxidising agents. Strong acids.
10.6. Hazardous decomposition products
Haz. decomp. products: In combustion emits toxic fumes.
Section 11: Toxicological information
11.1. Information on toxicological effects
Hazardous ingredients:
Toxicityvalues: No data available.
Symptoms / routes of exposure
Skin contact: There may be mild irritation at the site of contact.
Eye contact: There may be irritation and redness.
Ingestion: There may be irritation of the throat.
Inhalation: No symptoms.
Section 12: Ecological information
12.1. Toxicity
Ecotoxicityvalues: No data available.
12.2. Persistence and degradability
Persistence and degradability: Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential: No bioaccumulation potential.
12.4. Mobilityin soil
Mobility: Readily absorbed into soil.
12.5. Results of PBT and vPvB assessment
PBT identification: This product is not identified as a PBT/vPvB substance.
12.6. Other adverse effects
Other adverse effects: Negligible ecotoxicity.
Section 13: Disposal considerations
13.1. Waste treatment methods
Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.
Recoveryoperations: Recycling/reclamation of metals and metal compounds.
Waste code number: 16 05 05
Disposal of packaging: Empty cans must not be burned because of explosion hazard. Recycle container where permitted. Disposal of waste containers must be done in accordance with local and / or national regulations.
NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.
Section 14: Transport information
14.1. UN number
UN number: UN1950
14.2. UN proper shipping name
Shipping name: AEROSOLS
14.3. Transport hazard class(es)
Transport class: 2
14.4. Packing group
14.5. Environmental hazards
Environmentallyhazardous: No
14.6. Special precautions for user
Special precautions: No special precautions.
Tunnel code: D
Marine pollutant: No
Transport category: 2
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Specific regulations: This product is not, nor does it contain a persistant organic pollutant (POP) according to Regulation (EC) 2019/1021 and subsequent revisions. This product is not, nor does it contain any candidate on the REACH SVHC list acording to Regulation (EC) 2006/1907 and subsequent revisions. This product is not, nor does it contain, any candidate on the Endocrine Disruptor list, and any subsequent revisions, classified for human health cat 2 or environmental cat 2, in accordance with EC1272/2008 (ammended 2022)
15.2. Chemical SafetyAssessment
Chemical safetyassessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.
Section 16: Other information
Other information
Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 2015/830.
All substances in this preparation are registered within UK/EU/EFTA countries under the REACH (UK/EC) (ammended) regulations, EC 1907/2006
*indicates text in the SDS which has changed since the last revision.
Phrases used in s.2 and s.3: H220: Extremely flammable gas.
H222: Extremely flammable aerosol.
H225: Highly flammable liquid and vapour.
H229: Pressurised container: May burst if heated.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.


according to Regulation (EU) 2020/878
SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking
1.1.Productidentifier
Productname Tyre Dressing
1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst
ProductUse
[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC35]Washingandcleaningproducts(includingsolventbasedproducts);
[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC35]Washingand cleaningproducts(includingsolventbasedproducts);
Description Thisnewwaterresistantcoatinghasbeencarefullyformulatedfortherenovationofallplastics, PVC,rubberetc,throughoutyourvehicle.
1.3.Detailsofthesupplierofthesafetydatasheet
Company SUPAGARDLIMITED
Address 19-27GavintonStreet Muirend Glasgow G443EF
Web www.supagard.com
Telephone 01416335933
Fax 01416377219
Email James.Smyth@supagard.com
Emailaddressofthe competentperson James.Smyth@supagard.com
1.4.Emergencytelephonenumber
Emergencytelephonenumber01416335933 8.30amto5.00pm
FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)
Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org
SECTION2:Hazardsidentification
2.1.Classificationofthesubstanceormixture
2.1.2.Classification-EC 1272/2008 Flam.Liq.3:H226;Asp.Tox.1:H304;STOTSE3:H336;
2.2.Labelelements

2.2.Labelelements
Hazardpictograms

SignalWord Danger


HazardStatement Flam.Liq.3:H226-Flammableliquidandvapour.
Asp.Tox.1:H304-Maybefatalifswallowedandentersairways.
STOTSE3:H336-Maycausedrowsinessordizziness.
PrecautionaryStatement: Prevention
PrecautionaryStatement: Response
P102-Keepoutofreachofchildren.
P210-Keepawayfromheat,hotsurfaces,sparks,openflamesandotherignitionsources.No smoking.
P301+P310+P330+P331-IFSWALLOWED:ImmediatelycallaPOISONCENTER/doctor.Rinse mouth.DoNOTinducevomiting.
P302+P350-IFONSKIN:Gentlywashwithplentyofsoapandwater.
P304+P340-IFINHALED:Removepersontofreshairandkeepcomfortableforbreathing.
PrecautionaryStatement: Storage P403+P233-Storeinawell-ventilatedplace.Keepcontainertightlyclosed.
SUPPLEMENTALHAZARD INFORMATION
2.3.Otherhazards
Otherhazards
Furtherinformation
IngredientsasrequiredbyRegulation(EC)No648/2004:. Lessthan5%AromaticHydrocarbons,Dimethicone,Aminofunctionalsilicone.
Contains-Hydrocarbons,C9-11,N-alkanes,Isoalkanes,Cyclics,<2%Aromatic.
Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.
RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.
SECTION3:Composition/informationoningredients
3.2.Mixtures
EC1272/2008
ChemicalName
Hydrocarbons,C9-11,N-alkanes, Isoalkanes,Cyclics,<2%Aromatic 1174522-20-3919-857-501-2119463258-33
SECTION4:Firstaidmeasures
4.1.Descriptionoffirstaidmeasures
Inhalation Movetheexposedpersontofreshair.
Flam.Liq.3:H226;Asp.Tox. 1:H304;STOTSE3:H336; 50-60%
Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved.
Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution.
Ingestion DONOTINDUCEVOMITING.Ifswallowed,donotinducevomiting:seekmedicaladvice immediatelyandshowthiscontainerorlabel.Rinsemouththoroughly.
4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed
Inhalation Highconcentrationofvapourinenclosedspacemaycauseirritation,headachesandnausea.May causeirritationtorespiratorysystem.
Eyecontact Irritatingtoeyes.
Skincontact Maycauseskindrynessandirritation.Prolongedcontactmaycausedefattingoftheskin.
Ingestion Harmfulifingestedorswallowed.
4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded TREATSYMPTOMATICALLY.
Inhalation
Eyecontact
Skincontact
Ingestion
Generalinformation
Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.
Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.
Seekmedicalattentionifirritationorsymptomspersist.
Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.
Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.
5.1.Extinguishingmedia
Flammableliquid.Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthe surroundingenvironment.
5.2.Specialhazardsarisingfromthesubstanceormixture
Burningproducesirritating,toxicandobnoxiousfumes.
5.3.Adviceforfirefighters
Furtherinformation
Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.
Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.
6.1.Personalprecautions,protectiveequipmentandemergencyprocedures
Wearsuitableprotectiveequipment.Flammableliquid.Avoidsparks,flames,heatandsourcesof ignition.
6.2.Environmentalprecautions
Adviselocalauthoritiesiflargespillscannotbecontained.
6.3.Methodsandmaterialforcontainmentandcleaningup
Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelledcontainersfor disposal.Avoidsparks,flames,heatandsourcesofignition.
6.4.Referencetoothersections
Seesection2,7,8,13forfurtherinformation.
7.1.Precautionsforsafehandling
AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.
7.2.Conditionsforsafestorage,includinganyincompatibilities
Flammableliquid.Avoidsparks,flames,heatandsourcesofignition.AvoidstoringindirectSun Light.Storeinawell-ventilatedplace.Keepcool.Storeinoriginalcontainer.Keepcontainertightly closed.Keepawayfromcombustiblematerial.Keepoutofthereachofchildren.
7.3.Specificenduse(s)
Suitablepackaging
Thisnewwaterresistantcoatinghasbeencarefullyformulatedfortherenovationofallplastics, PVC,rubberetc.throughoutyourvehicle.

Suitablepackaging
Plasticcontainers.
SECTION8:Exposurecontrols/personalprotection
8.1.Controlparameters
8.1.1.ExposureLimitValues
Ethylbenzene(ethylbenzol) (Ethylbenzene)
Occupationalexposurecontrols.
WEL8-hrlimitppm:100
WEL15minlimitppm:125
WEL8-hrlimitmg/m3:441
WEL15minlimitmg/m3:552
WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust:methanol
WEL8-hrlimitppm:200
WEL15minlimitppm:250
WEL8-hrlimitmg/m3:266
WEL15minlimitmg/m3:333
WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust:propan-2-ol
WEL8-hrlimitppm:400
WEL15minlimitppm:500
DNEL:Derivedno-effectlevel.
ExposurePattern-Workers
Ethylbenzene(ethylbenzol)
methanol
propan-2-ol
WEL8-hrlimitmg/m3:999
WEL15minlimitmg/m3:1250
WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -
Acuteinhalation-Localeffects293mg/m³
Long-term-inhalation-Systemic effects 77mg/m³
Acuteinhalation-Systemic effects 130mg/m³
Acuteinhalation-Localeffects130mg/m³
Long-term-inhalation-Systemic effects 130mg/m³
Long-term-dermal-Systemic effects 20mg/kg
Long-term-inhalation-Systemic effects 500mg/m³
Long-term-dermal-Systemic effects 888mg/kg
ExposurePattern-Generalpopulation

Long-term-dermal-Systemic effects 180mg/kg
Acutedermal-Systemiceffects20mg/kg
Long-term-inhalation-Local effects 130mg/m³
ExposurePattern-Generalpopulation
Ethylbenzene(ethylbenzol)
methanol
propan-2-ol
8.2.Exposurecontrols
Long-term-inhalation-Systemic effects 15mg/m³
Long-term-oral-Systemic effects 1.6mg/kg
Acuteinhalation-Systemic effects 26mg/m³
Acuteinhalation-Localeffects26mg/m³
Acuteoral-Systemiceffects5mg/kg
Long-term-inhalation-Local effects 26mg/m³
Long-term-oral-Systemic effects 5mg/kg
Long-term-inhalation-Systemic effects 89mg/m³
Long-term-dermal-Systemic effects 319mg/kg


8.2.1.Appropriateengineering controls
Eye/faceprotection
Acutedermal-Systemiceffects5mg/kg
Long-term-inhalation-Systemic effects 26mg/m³
Long-term-dermal-Systemic effects 5mg/kg
Long-term-oral-Systemiceffects26mg/kg
AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.
Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.
Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields.
SkinprotectionHandprotection Rubbergloves.
Respiratoryprotection
8.2.3.Environmentalexposure controls
Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.
Preventfurtherleakageorspillageifsafetodoso.
9.1.Informationonbasicphysicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties
AppearanceLiquid
ColourColourless
OdourCharacteristic
OdourthresholdNodataavailable
pHNodataavailable
MeltingpointNodataavailable
InitialboilingpointNodataavailable
Flashpoint40°C
EvaporationrateNodataavailable Flammability(solid,gas)Nodataavailable
VapourpressureNodataavailable
RelativeVapourDensityNodataavailable
Density/RelativeDensity0.8-0.825
PartitioncoefficientNodataavailable
AutoignitiontemperatureNodataavailable
ViscosityNodataavailable
ExplosivepropertiesNodataavailable OxidisingpropertiesNodataavailable
SolubilityNodataavailable
9.2.Otherinformation
ConductivityNodataavailable
SurfacetensionNodataavailable GasgroupNodataavailable
BenzeneContentNodataavailable
LeadcontentNodataavailable
VOC(Volatileorganic compounds) Nodataavailable
9.2.1.Informationwithregardtophysicalhazardclasses
Nodataisavailableonthisproduct.
9.2.2.Othersafetycharacteristics
Nodataisavailableonthisproduct.
SECTION10:Stabilityandreactivity
10.1.Reactivity
10.2.Chemicalstability
Flammableliquid.Stableundernormalconditions.
Flammableliquid.Stableundernormalconditions.
10.3.Possibilityofhazardousreactions
Oxidisingagents.Combustiblematerials.
10.4.Conditionstoavoid
10.5.Incompatiblematerials
Avoidsparks,flames,heatandsourcesofignition.AvoidstoringindirectSunLight.
Oxidisingagents.
10.6.Hazardousdecompositionproducts
NoHazardousdecompositionproductswhenstoredandhandledcorrectly.

11.1Informationonhazardclasses
Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedusingthemethodsoutlinedinRegulation(EC)No1272/2008(CLP).
Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet. OralATE=>10,000mg/kg.
DermalATE=>10,000mg/kg.
Inhalation-Dust/MistATE=>10,000mg/l.
Skincorrosion/irritation basedonavailabledatatheclassificationcriteriaarenotmet.
Seriouseyedamage/irritationbasedonavailabledatatheclassificationcriteriaarenotmet. Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.
Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet.
Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.
Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-singleexposure STOTSEcategory3.H336-Maycausedrowsinessordizziness.
STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.
Aspirationhazard
Repeatedorprolonged exposure
11.1.2.Mixtures
11.1.3.HazardInformation
11.1.4.ToxicologicalInformation
Ethylbenzene(ethylbenzol)
methanol
propan-2-ol
11.2Informationonotherhazards
AspirationHazardCategory1.H304-Maybefatalifswallowedandentersairways.
Prolongedcontactmaycausedefattingoftheskin.
Nodataavailable.
Nodataavailable.
OralRatLD50:3500mg/kg
InhalationRatLC50/4h:17.2mg/l
OralRatLD50:100.0mg/kg
InhalationRatLC50/4h:3.0mg/l
InhalationRatLC50/6h:>10000ppm
DermalRabbitLD50:13900mg/kg
Nodataisavailableonthisproduct.
SECTION12:Ecologicalinformation
12.1.Toxicity
Ethylbenzene(ethylbenzol)
DaphniaEC50/48h:1.8000mg/l
RainbowtroutLC50/96h:4.2mg/l methanol
DaphniaEC50/48h:18260.0000mg/l
FatheadminnowsLC50/96h:>100mg/l
Lepomis_MacrochirusLC50/96h:15400mg/l propan-2-ol
DaphniaEC50/48h:10000.0000mg/l
FatheadminnowsLC50/96h:9640mg/l
12.2.Persistenceanddegradability
12.3.Bioaccumulativepotential
DermalRabbitLD50:5001.0mg/kg
DermalRabbitLD50:300.0mg/kg
OralRatLD50:5840mg/kg
AlgaeEC50/72h:5.4mg/l
GreenalgaeEC50/96h:22000.0mg/l
BluegillsunfishLC50/96h:15400.0mg/l
FishLC50/96h:4200.0000mg/l
SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.

12.3.Bioaccumulativepotential
Partitioncoefficient
12.4.Mobilityinsoil
Theproductisnotbioaccumulating.
StoneacreTyreDressingNodataavailable propan-2-ol0.05logP methanol-0.74LogPow Ethylbenzene(ethylbenzol)3.5
Immiscibleinwater.
12.5.ResultsofPBTandvPvBassessment
Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.
12.6Endocrinedisruptingproperties
Nodataisavailableonthisproduct.
12.7.Otheradverseeffects
Nodataisavailableonthisproduct.
13.1.Wastetreatmentmethods
Generalinformation
Disposalofpackaging
Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.
Disposeofincompliancewithalllocalandnationalrequirements.
DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.
Hazardpictograms

14.1.UNnumber
14.2.UNpropershippingname
14.3.Transporthazardclass(es)
Packinggroup
14.5.Environmentalhazards

14.5.Environmentalhazards
Environmentalhazards No
Marinepollutant No
14.6.Specialprecautionsforuser Noadditionalspecialprecautions.
14.7MaritimeTransportinbulkaccordingtoIMOinstruments Notapplicable.
ADR/RID
HazardID 30
TunnelCategory (D/E)
IMDG
EmSCode F-ES-D IATA
PackingInstruction(Cargo)366
SECTION15:Regulatoryinformation
15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture
Regulations
REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.
COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.
COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).
Thisdocumentdiffersfromthepreviousversioninthefollowingareas:.
2-Otherhazards.
2-PrecautionaryStatement:Prevention.
2-PrecautionaryStatement:Response.
2-PrecautionaryStatement:Storage.
2-PrecautionaryStatement:Disposal.
2-Furtherinformation.
2-SUPPLEMENTALHAZARDINFORMATION.

Otherinformation
9-9.2.2.Othersafetycharacteristics.
9-9.2.1.Informationwithregardtophysicalhazardclasses. 11-11.2Informationonotherhazards.
12-12.6Endocrinedisruptingproperties. 12-12.7.Otheradverseeffects. 15-Regulations.
Datasources ClassificationandProcedureusedtoderivetheclassificationformixturesaccordingtoRegulation (EC)No.1272/2008,asretainedandamendedinUKlaw.
Flam.Liq.3:H226-Flammableliquidandvapour.-FlashPoint-40degC.
Asp.Tox.1:H304-Maybefatalifswallowedandentersairways.-CalculationMethod.
STOTSE3:H336-Maycausedrowsinessordizziness.-CalculationMethod.
TextofHazardStatementsin Section3
Furtherinformation
Flam.Liq.3:H226-Flammableliquidandvapour.
Asp.Tox.1:H304-Maybefatalifswallowedandentersairways.
STOTSE3:H336-Maycausedrowsinessordizziness.
TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.



according to Regulation (EU) 2020/878
SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking
1.1.Productidentifier
Productname Snow Foam
1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst ProductUse
[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC35]Washingand cleaningproducts(includingsolventbasedproducts);
[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC35]Washingandcleaningproducts(includingsolventbasedproducts); Description SnowFoam.
1.3.Detailsofthesupplierofthesafetydatasheet Company SUPAGARDLIMITED
Address 19-27GavintonStreet Muirend Glasgow G443EF
Web www.supagard.com
Telephone 01416335933
Fax 01416377219
Email James.Smyth@supagard.com
Emailaddressofthe competentperson James.Smyth@supagard.com
1.4.Emergencytelephonenumber
Emergencytelephonenumber01416335933 8.30amto5.00pm
FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)
Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org
SECTION2:Hazardsidentification
2.1.Classificationofthesubstanceormixture
2.1.2.Classification-EC 1272/2008 SkinCorr.1A:H314;
2.2.Labelelements
Hazardpictograms


2.2.Labelelements
SignalWord Danger
HazardStatement
PrecautionaryStatement: Prevention
PrecautionaryStatement: Response
PrecautionaryStatement: Disposal
SUPPLEMENTALHAZARD INFORMATION
2.3.Otherhazards
Otherhazards
Furtherinformation
SkinCorr.1A:H314-Causessevereskinburnsandeyedamage.
P102-Keepoutofreachofchildren.
P264-Washhandsandothercontactedskinthoroughlyafterhandling.
P280-Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection.
P302+P350-IFONSKIN:Gentlywashwithplentyofsoapandwater.
P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.
P501-Disposeofcontents/containertoanapproveddisposalsite,inaccordancewithlocal regulations.
IngredientsasrequiredbyRegulation(EC)No648/2004:.
5-15%AnionicSurfactants,Lessthan5%AmphotericSurfactants,Lessthan5%Non-ionic Surfactants,EDTAandsaltsthereof,Parfum,Vanillin,CI74190.
Contains-Amines,C12-14(evennumbered)-alkyldimethyl,N-oxides,Alcohols,C12-14, ethoxylated,sulfates,sodiumsalts,2-butoxyethanol,EthylMethylphenylglycidate,Sodium Hydroxide.
Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.
RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.
SECTION3:Composition/informationoningredients
3.2.Mixtures
EC1272/2008
ChemicalName
ethyl 3-methyl-3-phenyloxirane-2-carbox ylate
Amines,C12-14(evennumbered) -alkyldimethyl,N-oxides
77-83-8201-061-8
308062-28-4931-292-601-2119490061-47
68891-38-3
SkinSens.1:H317;Aquatic Chronic2:H411; 0-0.5%
AcuteTox.4:H302;SkinIrrit. 2:H315;EyeDam.1:H318; AquaticAcute1:H400; AquaticChronic2:H411; 0.5-1% ALCOHOLS,C12-14, ETHOXYLATED,SULFATES, SODIUMSALTS...
603-014-00-0111-76-2203-905-001-2119475108-36
SkinIrrit.2:H315;EyeDam. 1:H318;AquaticChronic3: H412; 1-10% ButylGlycolEther (2-Butoxyethanol)
AcuteTox.4:H302+H332; SkinIrrit.2:H315;EyeIrrit.2: H319; 1-10%
Amines,C12-14(evennumbered)-alkyldimethyl,N-oxides,CASNo.308062-28-4-MFactorAcute =1.
4.1.Descriptionoffirstaidmeasures
Inhalation Movetheexposedpersontofreshair.
Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved. Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution. Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.
4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed Inhalation Maycauseirritationtorespiratorysystem. Eyecontact Causesseriouseyedamage.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed
Skincontact Causessevereburns.
Ingestion Maycauseirritationtomucousmembranes.
4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded
Inhalation
Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.
Eyecontact Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.
Skincontact Seekmedicalattentionifirritationorsymptomspersist.
Ingestion Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.
Generalinformation
Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.
5.1.Extinguishingmedia
Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.
5.2.Specialhazardsarisingfromthesubstanceormixture
Noneknown.
5.3.Adviceforfirefighters
Furtherinformation
Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.
Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.
6.1.Personalprecautions,protectiveequipmentandemergencyprocedures
6.2.Environmentalprecautions
Wearsuitableprotectiveequipment.
Adviselocalauthoritiesiflargespillscannotbecontained.
6.3.Methodsandmaterialforcontainmentandcleaningup
Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.
6.4.Referencetoothersections
Seesection2,7,8,13forfurtherinformation.
7.1.Precautionsforsafehandling
AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.
7.2.Conditionsforsafestorage,includinganyincompatibilities
Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.
7.3.Specificenduse(s) SnowFoam.
Suitablepackaging

Suitablepackaging
Plasticcontainers.
SECTION8:Exposurecontrols/personalprotection
8.1.Controlparameters
8.1.1.ExposureLimitValues
ButylGlycolEther (2-Butoxyethanol)
SodiumHydroxide
Occupationalexposurecontrols.
WEL8-hrlimitppm:25
WEL15minlimitppm:50
WEL8-hrlimitmg/m3:123
WEL15minlimitmg/m3:101.2
WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -
WEL8-hrlimitppm:-
WEL15minlimitppm:-
WEL8-hrlimitmg/m3:-
WEL15minlimitmg/m3:2
WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -
DNEL:Derivedno-effectlevel.
ExposurePattern-Workers
ButylGlycolEther
SodiumHydroxide
Acuteinhalation-Systemic effects 1091mg/m³
Acuteinhalation-Localeffects246mg/m³
Long-term-inhalation-Systemic effects 98mg/m³
Acuteinhalation-Localeffects2mg/m³
Acutedermal-Localeffects2mg/m³
ExposurePattern-Generalpopulation
ButylGlycolEther
SodiumHydroxide
8.2.Exposurecontrols
Acuteinhalation-Systemic effects 426mg/m³
Acutedermal-Systemiceffects89mg/kg
Long-term-inhalation-Systemic effects 59mg/m³
Long-term-dermal-Systemic effects 75mg/kg
Long-term-inhalation-Local effects 1mg/m³



Acutedermal-Systemiceffects89mg/kg
Long-term-dermal-Systemic effects 125mg/kg
Long-term-inhalation-Local effects 1mg/m³

Acuteoral-Systemiceffects26.7mg/kg
Long-term-inhalation-Local effects 147mg/m³
Long-term-oral-Systemiceffects6.3mg/kg
8.2.Exposurecontrols
8.2.1.Appropriateengineering controls
Eye/faceprotection
SkinprotectionHandprotection
Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.
Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields. Eyewearcomplyingwithanapprovedstandardshouldbewornifariskassessmentindicateseye contactispossible.Thefollowingprotectionshouldbeworn:Wearchemicalsplashgoggles. PersonalprotectiveequipmentforeyeandfaceprotectionshouldcomplywithEuropeanStandard EN166.
Rubbergloves.Chooseglovestoprotecthandsagainstchemicalsdependingontheconcentration andquantityofthehazardoussubstanceandspecifictoplaceofwork.Forspecialapplications, werecommendclarifyingtheresistancetochemicalsoftheaforementionedprotectivegloveswith theglovemanufacturer.
Skinprotection-Other Wearsuitableprotectiveclothing.
Respiratoryprotection Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.
8.2.3.Environmentalexposure controls
Preventfurtherleakageorspillageifsafetodoso.
9.1.Informationonbasicphysicalandchemicalproperties
AppearanceLiquid ColourBlue OdourCharacteristic
OdourthresholdNodataavailable pH>12
MeltingpointNodataavailable
InitialboilingpointNodataavailable Flammability(solid,gas)Nodataavailable VapourpressureNodataavailable
RelativeVapourDensityNodataavailable
Density/RelativeDensity1.04-1.05g/cm3
PartitioncoefficientNodataavailable
AutoignitiontemperatureNodataavailable
Viscosity<200centipoise
ExplosivepropertiesNodataavailable OxidisingpropertiesNodataavailable EvaporationrateNodataavailable SolubilitySolubleinwater
9.2.Otherinformation
LeadcontentNodataavailable VOC(Volatileorganic compounds) Nodataavailable
ConductivityNodataavailable SurfacetensionNodataavailable GasgroupNodataavailable BenzeneContentNodataavailable
9.2.1.Informationwithregardtophysicalhazardclasses Nodataisavailableonthisproduct.
9.2.2.Othersafetycharacteristics Nodataisavailableonthisproduct.

SECTION10:Stabilityandreactivity
10.1.Reactivity
10.2.Chemicalstability
Stableundernormalconditions.
Stableundernormalconditions.
10.3.Possibilityofhazardousreactions
Strongacids.Strongoxidisingagents.
10.4.Conditionstoavoid
10.5.Incompatiblematerials
Protectfromfrost.
Noincompatiblegroupsnoted.
10.6.Hazardousdecompositionproducts
NoHazardousdecompositionproductswhenstoredandhandledcorrectly.
11.1Informationonhazardclasses
Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedfromrawmaterialsupplierLD50andAcuteToxicityEstimates(ATE)asoutlinedinthe Regulation(EC)No.1272/2008(CLP)asamendedbyUKlaw.
Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
OralATE=>10,000mg/kg.
ATEDust/Mist=>20mg/l.
Skincorrosion/irritation
SkinCorr.1A:H314-Causessevereskinburnsandeyedamage.ExtremepH-≥11.5. Seriouseyedamage/irritationCausesseriouseyedamage.
Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.
Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet. Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.
Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-singleexposure basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-repeatedexposurebasedonavailabledatatheclassificationcriteriaarenotmet.
Aspirationhazard basedonavailabledatatheclassificationcriteriaarenotmet.
Repeatedorprolonged exposure basedonavailabledatatheclassificationcriteriaarenotmet.
11.1.2.Mixtures
11.1.3.HazardInformation
11.1.4.ToxicologicalInformation
Nodataavailable.
Nodataavailable.
Nodataavailable
11.2Informationonotherhazards
Nodataisavailableonthisproduct.
SECTION12:Ecologicalinformation
12.1.Toxicity
Nodataavailable

12.2.Persistenceanddegradability
SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.
12.3.Bioaccumulativepotential
Partitioncoefficient
12.4.Mobilityinsoil
Theproductisnotbioaccumulating.
StoneacreSnowFoamNodataavailable ButylGlycolEther0.81LogPow SodiumHydroxideNodataavailable
Thisproductissolubleinwater.
12.5.ResultsofPBTandvPvBassessment
Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.
12.6Endocrinedisruptingproperties
Nodataisavailableonthisproduct.
12.7.Otheradverseeffects
Nodataisavailableonthisproduct.
13.1.Wastetreatmentmethods
Generalinformation
Disposalofpackaging
Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.
Disposeofincompliancewithalllocalandnationalrequirements.
DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.
SECTION14:Transportinformation
Hazardpictograms

14.1.UNnumber

14.4.Packinggroup
Packinggroup III
14.5.Environmentalhazards
Environmentalhazards No
Marinepollutant No
ADR/RID
HazardID 80
TunnelCategory (E)
IMDG
EmSCode F-AS-B
IATA
PackingInstruction(Cargo)856
Maximumquantity 60L
PackingInstruction (Passenger) 852
Maximumquantity 5L
15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture Regulations
REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.AsretainedandamendedinUKlaw.
COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.Asretainedand amendedinUKlaw.
COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).AsretainedandamendedinUK law.
15.2.Chemicalsafetyassessment
Noinformationavailable.
SECTION16:Otherinformation
Otherinformation
Revision
Thisdocumentdiffersfromthepreviousversioninthefollowingareas:. 2-2.1.2.Classification-EC1272/2008. 2-SUPPLEMENTALHAZARDINFORMATION. 12-12.1.Toxicity.
Datasources ClassificationandProcedureusedtoderivetheclassificationformixturesaccordingtoRegulation (EC)No.1272/2008,asretainedandamendedinUKlaw.
SkinCorr.1A:H314-Causessevereskinburnsandeyedamage.-ExtremepH-≥11.5. TextofHazardStatementsin Section3 SkinSens.1:H317-Maycauseanallergicskinreaction. AquaticChronic2:H411-Toxictoaquaticlifewithlonglastingeffects.
Copyright©2024ChemSoft.Allrightsreserved.

Otherinformation
Furtherinformation
AcuteTox.4:H302-Harmfulifswallowed.
SkinIrrit.2:H315-Causesskinirritation.
EyeDam.1:H318-Causesseriouseyedamage.
AquaticAcute1:H400-Verytoxictoaquaticlife.
AquaticChronic3:H412-Harmfultoaquaticlifewithlonglastingeffects.
AcuteTox.4:H302+H332-Harmfulifswallowedorifinhaled
EyeIrrit.2:H319-Causesseriouseyeirritation.
TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.



according to Regulation (EU) 2020/878
SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking
1.1.Productidentifier
Productname Tar & Glue Remover
1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst
ProductUse
[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers);[PC35]Washingand cleaningproducts(includingsolventbasedproducts);
[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);[PC35]Washingandcleaningproducts(includingsolventbasedproducts);
Description BreaksdownTar&Glueresidue.
1.3.Detailsofthesupplierofthesafetydatasheet
Company SUPAGARDLIMITED
Address 19-27GavintonStreet Muirend Glasgow G443EF
Web www.supagard.com
Telephone 01416335933
Fax 01416377219
Email James.Smyth@supagard.com
Emailaddressofthe competentperson James.Smyth@supagard.com
1.4.Emergencytelephonenumber
Emergencytelephonenumber01416335933
8.30amto5.00pm
FormedicaladviceorinformationyoushouldcontactyourGPorNHS111(orNHS24in Scotland)on111(for24hourhealthadvice)
Ifyouareahealthcareprofessionalwithanenquirypleasevisitwww.TOXBASE.org
SECTION2:Hazardsidentification
2.1.Classificationofthesubstanceormixture
2.1.2.Classification-EC 1272/2008 :EUH066;Flam.Liq.3:H226;Asp.Tox.1:H304;STOTSE3:H336;STOTRE1:H372;Aquatic Chronic2:H411;
2.2.Labelelements
Hazardpictograms





2.2.Labelelements
SignalWord Danger
HazardStatement
PrecautionaryStatement: Prevention
PrecautionaryStatement: Response
PrecautionaryStatement: Storage
PrecautionaryStatement: Disposal
SUPPLEMENTALHAZARD INFORMATION
EUH066-Repeatedexposuremaycauseskindrynessorcracking.
Flam.Liq.3:H226-Flammableliquidandvapour.
Asp.Tox.1:H304-Maybefatalifswallowedandentersairways.
STOTSE3:H336-Maycausedrowsinessordizziness.
STOTRE1:H372-Causesdamagetoorgansthroughprolongedorrepeatedexposure.
AquaticChronic2:H411-Toxictoaquaticlifewithlonglastingeffects.
P102-Keepoutofreachofchildren.
P280-Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection.
P301+P310+P330+P331-IFSWALLOWED:ImmediatelycallaPOISONCENTER/doctor.Rinse mouth.DoNOTinducevomiting.
P302+P350-IFONSKIN:Gentlywashwithplentyofsoapandwater.
P403+P233+P235-Storeinawell-ventilatedplace.Keepcontainertightlyclosed.Keepcool.
P501-Disposeofcontents/containertoanapproveddisposalsite,inaccordancewithlocal regulations.
IngredientsasrequiredbyRegulation(EC)No648/2004:. 15-30%AromaticHydrocarbons.
Contains-Hydrocarbons,C9-12,n-alkanes,isoalkanes,cyclics(2-25%)aromatics,Hydrocarbons, C9-11,N-alkanes,Isoalkanes,Cyclics,<2%Aromatic,Hydrocarbons,C11-C14,n-alkanes, isoalkanes,cyclics,<2%aromatics,2-butoxyethanol.
2.3.Otherhazards
Otherhazards
Furtherinformation
Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.The substance/mixturedoesnotcontainsubstanceswithendocrinedisruptingproperties.
RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.
SECTION3:Composition/informationoningredients
3.2.Mixtures
EC1272/2008
ChemicalName
Hydrocarbons,C9-11,N-alkanes, Isoalkanes,Cyclics,<2%Aromatic
1174522-20-3919-857-501-2119463258-33
:EUH066;Flam.Liq.3: H226;Asp.Tox.1:H304; STOTSE3:H336; 10-20% Hydrocarbons,C9-12,n-alkanes, isoalkanes,cyclics(2-25%) aromatics
919-446-0
:EUH066;Flam.Liq.3: H226;Asp.Tox.1:H304; STOTSE3:H336;STOTRE 1:H372;AquaticChronic2: H411; 50-60%
Hydrocarbons,C11-C14,n-alkanes, isoalkanes,cyclics,<2%aromatics
926-141-601-2119456620-43 :EUH066;Asp.Tox.1: H304; 10-20% 2-butoxyethanol
603-014-00-0111-76-2203-905-001-2119475108-36
SECTION4:Firstaidmeasures
4.1.Descriptionoffirstaidmeasures
AcuteTox.4:H332;Acute Tox.4:H312;AcuteTox.4: H302;EyeIrrit.2:H319;Skin Irrit.2:H315; 1-10%
Inhalation Movetheexposedpersontofreshair. Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved. Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution. Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed
Inhalation
Highconcentrationofvapourinenclosedspacemaycauseirritation,headachesandnausea.May causeirritationtorespiratorysystem.Maycausedrowsinessordizziness.
Eyecontact Maycauseirritationtoeyes.
Skincontact
Ingestion
Maycauseskindrynessandirritation.Prolongedcontactmaycausedefattingoftheskin. Prolongedorrepeatedexposuremaycause:Skinirritationanddermatitis.
Maybefatalifswallowedandentersairways.
4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded TREATSYMPTOMATICALLY.
Inhalation
Eyecontact
Skincontact
Ingestion
Generalinformation
Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.
Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.
Seekmedicalattentionifirritationorsymptomspersist.
Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.
Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.
SECTION5:Firefightingmeasures
5.1.Extinguishingmedia
Flammableliquid.Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthe surroundingenvironment.
5.2.Specialhazardsarisingfromthesubstanceormixture
Vapoursareheavierthanairandmayspreadneargroundandtravelaconsiderabledistancetoa sourceofignitionandflashback.Solventvapoursmayformexplosivemixtureswithair.
Oxidesofcarbon.Thermaldecompositionorcombustionmayliberatecarbonoxidesandother toxicgasesorvapours.
5.3.Adviceforfirefighters
Furtherinformation
Firefightersshouldwearselfcontainedpositivepressurebreathingapparatus(SCBA)andfull turnoutgear.
Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.
SECTION6:Accidentalreleasemeasures
6.1.Personalprecautions,protectiveequipmentandemergencyprocedures
Wearsuitableprotectiveequipment.Flammableliquid.Avoidsparks,flames,heatandsourcesof ignition.
6.2.Environmentalprecautions
Adviselocalauthoritiesiflargespillscannotbecontained.
6.3.Methodsandmaterialforcontainmentandcleaningup
Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelledcontainersfor disposal.Avoidsparks,flames,heatandsourcesofignition.
6.4.Referencetoothersections
Seesection2,7,8,13forfurtherinformation.
7.1.Precautionsforsafehandling

7.1.Precautionsforsafehandling
AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Provide adequateventilation.Staticelectricityandformationofsparksmustbeprevented.
7.2.Conditionsforsafestorage,includinganyincompatibilities
Flammableliquid.Avoidsparks,flames,heatandsourcesofignition.AvoidstoringindirectSun Light.Storeinawell-ventilatedplace.Keepcool.Storeinoriginalcontainer.Keepcontainertightly closed.Keepawayfromcombustiblematerial.Keepoutofthereachofchildren.Storeawayfrom thefollowingmaterials:Oxidisingmaterials.
7.3.Specificenduse(s)
Suitablepackaging
BreaksdownTar&Glueresidue.
Plasticcontainers.
8.1.Controlparameters
8.1.1.ExposureLimitValues
2-butoxyethanol
Occupationalexposurecontrols.
WEL8-hrlimitppm:25
WEL15minlimitppm:50
WEL8-hrlimitmg/m3:123
WEL15minlimitmg/m3:101.2
WEL8-hrlimitmg/m3total inhalabledust: - WEL15minlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust:Hydrocarbons,C11-C14, n-alkanes,isoalkanes,cyclics, <2%aromatics
WEL8-hrlimitppm:
WEL15minlimitppm:
WEL8-hrlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3:1200
WEL15minlimitmg/m3:
WEL15minlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: - WEL15minlimitmg/m3total respirabledust: -
DNEL:Derivedno-effectlevel.
ExposurePattern-Workers
2-butoxyethanol
Acuteinhalation-Systemic effects 1091mg/m³
Acuteinhalation-Localeffects246mg/m³
Long-term-inhalation-Systemic effects 98mg/m³
ExposurePattern-Generalpopulation
2-butoxyethanol
8.2.Exposurecontrols
Acuteinhalation-Systemic effects 426mg/m³
Acutedermal-Systemiceffects89mg/kg
Long-term-inhalation-Systemic effects 59mg/m³
Long-term-dermal-Systemic effects 89mg/kg
Acutedermal-Systemiceffects89mg/kg
Long-term-dermal-Systemic effects 125mg/kg
Acuteoral-Systemiceffects26.7mg/kg
Long-term-inhalation-Local effects 147mg/m³
Long-term-oral-Systemiceffects6.3mg/kg

8.2.Exposurecontrols



AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.
8.2.1.Appropriateengineering controls
Eye/faceprotection
SkinprotectionHandprotection
Provideexhaustventilationorotherengineeringcontrolstokeeptheairborneconcentrationsof vapoursbelowthererespectivethresholdlimitvalue.Ensureeyewashstationsandsafety showersareclosetotheworkstationlocation.
Eyewearcomplyingwithanapprovedstandardshouldbewornifariskassessmentindicateseye contactispossible.Thefollowingprotectionshouldbeworn:Wearchemicalsplashgoggles. PersonalprotectiveequipmentforeyeandfaceprotectionshouldcomplywithEuropeanStandard EN166.
Chooseglovestoprotecthandsagainstchemicalsdependingontheconcentrationandquantityof thehazardoussubstanceandspecifictoplaceofwork.Forspecialapplications,werecommend clarifyingtheresistancetochemicalsoftheaforementionedprotectivegloveswiththeglove manufacturer.Chemicalresistantgloves.Nitrilerubbergloves.
Skinprotection-Other Usebarriercreamstopreventskincontact.Provideeyewashstationandsafetyshower.Wear appropriateclothingtopreventrepeatedorprolongedskincontact.
Respiratoryprotection
8.2.3.Environmentalexposure controls
Incaseofinsufficientventilation,wearsuitablerespiratoryequipment.
Preventfurtherleakageorspillageifsafetodoso.
9.1.Informationonbasicphysicalandchemicalproperties
AppearanceLiquid
ColourColourless
OdourCharacteristic
OdourthresholdNodataavailable pHNodataavailable MeltingpointNodataavailable
InitialboilingpointNodataavailable
Flashpoint53°C
EvaporationrateNodataavailable Flammability(solid,gas)Nodataavailable VapourpressureNodataavailable RelativeVapourDensityNodataavailable Density/RelativeDensityNodataavailable PartitioncoefficientNodataavailable AutoignitiontemperatureNodataavailable Viscosity<100centipoise
ExplosivepropertiesNodataavailable OxidisingpropertiesNodataavailable SolubilityInsolubleinwater
9.2.Otherinformation

9.2.Otherinformation
ConductivityNodataavailable
SurfacetensionNodataavailable
GasgroupNodataavailable
BenzeneContentNodataavailable
LeadcontentNodataavailable VOC(Volatileorganic compounds) Nodataavailable
9.2.1.Informationwithregardtophysicalhazardclasses
Nodataisavailableonthisproduct.
9.2.2.Othersafetycharacteristics
Nodataisavailableonthisproduct.
10.1.Reactivity
10.2.Chemicalstability
Flammableliquid.Stableundernormalconditions.
Flammableliquid.Stableundernormalconditions.Useasrecommended.
10.3.Possibilityofhazardousreactions
Undernormalconditionsofstorageanduse,nohazardousreactionswilloccur.
10.4.Conditionstoavoid
10.5.Incompatiblematerials
Avoidsparks,flames,heatandsourcesofignition.AvoidstoringindirectSunLight.
Strongacids.Strongoxidisingagents.
10.6.Hazardousdecompositionproducts
Thermaldecompositionorcombustionmayliberatecarbonoxidesandothertoxicgasesor vapours.
11.1Informationonhazardclasses
Thismixturehasnotbeentestedasawholeforhealtheffects.Thehealtheffectshavebeen calculatedfromrawmaterialsupplierLD50andAcuteToxicityEstimates(ATE)asoutlinedinthe Regulation(EC)No.1272/2008(CLP)asamendedbyUKlaw.
Acutetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
OralATE=>10,000mg/kg.
DermalATE=>10,000mg/kg.
InhalationDust/MistATE=550mg/l.
Skincorrosion/irritation basedonavailabledatatheclassificationcriteriaarenotmet.
Seriouseyedamage/irritationbasedonavailabledatatheclassificationcriteriaarenotmet.
Respiratoryorskin sensitisation basedonavailabledatatheclassificationcriteriaarenotmet.
Germcellmutagenicity basedonavailabledatatheclassificationcriteriaarenotmet.
Carcinogenicity basedonavailabledatatheclassificationcriteriaarenotmet.
Reproductivetoxicity basedonavailabledatatheclassificationcriteriaarenotmet.
STOT-singleexposure STOTSE3:H336-Maycausedrowsinessordizziness.
STOT-repeatedexposureSTOTRE1:H372-Causesdamagetoorgansthroughprolongedorrepeatedexposure.
Aspirationhazard Asp.Tox.1:H304-Maybefatalifswallowedandentersairways.

11.1Informationonhazardclasses
Repeatedorprolonged exposure
11.1.2.Mixtures
11.1.3.HazardInformation
11.1.4.ToxicologicalInformation
2-butoxyethanol
Hydrocarbons,C11-C14, n-alkanes,isoalkanes,cyclics, <2%aromatics
Hydrocarbons,C9-12,n-alkanes, isoalkanes,cyclics(2-25%) aromatics
11.2Informationonotherhazards
EUH066-Repeatedexposuremaycauseskindrynessorcracking.
Nodataavailable.
Nodataavailable.
OralRatLD50:1200mg/kg
InhalationRatLC50/4h:2.2mg/l
OralRatLD50:>5000mg/kg
InhalationRatLC50/4h:>5000mg/m3
InhalationRatLC50/4h:>13100mg/l
OralRatLD50:>15000mg/kg
Nodataisavailableonthisproduct.
SECTION12:Ecologicalinformation
12.1.Toxicity
2-butoxyethanol
Hydrocarbons,C11-C14, n-alkanes,isoalkanes,cyclics, <2%aromatics
Hydrocarbons,C9-12,n-alkanes, isoalkanes,cyclics(2-25%) aromatics
12.2.Persistenceanddegradability
12.3.Bioaccumulativepotential
Partitioncoefficient
12.4.Mobilityinsoil
DaphniaEC50/48h:1550.0000mg/l
Lepomis_MacrochirusLC50/96h:1490-2950mg/l
EC50formarineorfreshwater organisms >100.0000mg/l
DaphniaEC50/48h:1000.0000mg/l
AlgaeEC50/72h:1000mg/l
DaphniaEC50/48h:22.0000mg/l
AlgaeEC50/72h:10
DermalRabbitLD50:>2000mg/kg
DermalRabbitLD50:>5000mg/kg
DermalRatLD50:>3400mg/kg
AlgaeEC50/72h:911mg/l (Pseudokirchnerie llasubcapitata)
LC50formarineorfreshwater organisms >100.0000mg/l
FishLC50/96h:1000.0000mg/l
FishLC50/96h:30.0000mg/l
GreenAlgaeEC50/48h:43.98
SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.
Mayaccumulateinsoilandwatersystems.
StoneacreTar&GlueRemoverNodataavailable 2-butoxyethanol0.81logP
Theproducthaspoorwater-solubility.
12.5.ResultsofPBTandvPvBassessment

12.5.ResultsofPBTandvPvBassessment
Thissubstance/mixtureisnotclassifiedasPBTorvPvBaccordingtocurrentcriteria.
12.6Endocrinedisruptingproperties
Nodataisavailableonthisproduct.
12.7.Otheradverseeffects
Nodataisavailableonthisproduct.
13.1.Wastetreatmentmethods
Generalinformation
Disposalofpackaging
Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.
Disposeofincompliancewithalllocalandnationalrequirements.
DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.
Hazardpictograms


14.1.UNnumber
14.2.UNpropershippingname
14.3.Transporthazardclass(es)
14.5.Environmentalhazards
Environmentalhazards Yes Marinepollutant Yes
14.6.Specialprecautionsforuser Noadditionalspecialprecautions.

ADR/RID
TunnelCategory (D/E)
IMDG
EmSCode F-ES-D
IATA
PackingInstruction(Cargo)366
Maximumquantity 220L
PackingInstruction (Passenger) 355
Maximumquantity 60L
SECTION15:Regulatoryinformation
15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture
Regulations REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.AsretainedandamendedinUKlaw.
COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.Asretainedand amendedinUKlaw.
COMMISSIONREGULATION(EU)2020/878of18June2020amendingAnnexIItoRegulation (EC)No1907/2006oftheEuropeanParliamentandoftheCouncilconcerningtheRegistration, Evaluation,AuthorisationandRestrictionofChemicals(REACH).AsretainedandamendedinUK law.
15.2.Chemicalsafetyassessment
Noinformationavailable.
Revision
Thisdocumentdiffersfromthepreviousversioninthefollowingareas:. 12-12.1.Toxicity.
Datasources ClassificationandProcedureusedtoderivetheclassificationformixturesaccordingtoRegulation (EC)No.1272/2008,asretainedandamendedinUKlaw.
Flam.Liq.3:H226-Flammableliquidandvapour.-FlashPoint-55degC.
Asp.Tox.1:H304-Maybefatalifswallowedandentersairways.-CalculationMethod.
STOTSE3:H336-Maycausedrowsinessordizziness.-CalculationMethod.
STOTRE1:H372-CausesdamagetoorganscalculationMethodthroughprolongedorrepeated exposure.-.
AquaticChronic2:H411-Toxictoaquaticlifewithlonglastingeffects.-CalculationMethod. TextofHazardStatementsin Section3 EUH066-Repeatedexposuremaycauseskindrynessorcracking.
Flam.Liq.3:H226-Flammableliquidandvapour.
Asp.Tox.1:H304-Maybefatalifswallowedandentersairways.
STOTSE3:H336-Maycausedrowsinessordizziness.
STOTRE1:H372-Causesdamagetoorgansthroughprolongedorrepeatedexposure.
AquaticChronic2:H411-Toxictoaquaticlifewithlonglastingeffects.

Otherinformation
Furtherinformation
AcuteTox.4:H302+H312+H332-Harmfulifswallowed,incontactwithskinorifinhaled
SkinIrrit.2:H315-Causesskinirritation.
EyeIrrit.2:H319-Causesseriouseyeirritation.
TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.


Revision Date 02/08/2017
Revision 2
Supersedes date 20/04/2017

SAFETY DATA SHEET
TYRE REPAIR 500ML
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product name Product No.
TYRE REPAIR 500ML 000998083036
1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses
Emergency Tyre Repair
1.3. Details of the supplier of the safety data sheet
Supplier 23, Gavinton Street, Muirend, Glasgow, Scotland, G44 3EF
SUPAGARD LIMITED
0141 633 5933 0141 637 7219 james@supagard.co.uk
1.4. Emergency telephone number
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification (EC 1272/2008)
2.2. Label elements
Physical and Chemical HazardsFlam. Aerosol 1 - H222 Human health Not classified. Environment Not classified.
Label In Accordance With (EC) No. 1272/2008
Signal Word Danger Hazard Statements
H222
Extremely flammable aerosol. Precautionary Statements
P102
P210
P261
P271
P280
P305+351+338
P337+313
P501
Keep out of reach of children.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Avoid breathing vapour/spray.
Use only outdoors or in a well-ventilated area.
Wear protective gloves.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
Dispose of contents/container in accordance with local regulations. Supplementary Precautionary Statements
P211
P251
P302+352
Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use.
IF ON SKIN: Wash with plenty of soap and water.
Supplemental label information H229
2.3. Other hazards
Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122°F.
Pressurised container: May burst if heated
3.2. Mixtures
CAS-No.: 106-97-8
Classification (EC 1272/2008) Flam. Gas 1 - H220
EC No.: 203-448-7
Classification (67/548/EEC) F+;R12
CAS-No.: 75-28-5
Classification (EC 1272/2008) Flam. Gas 1 - H220
EC No.: 200-857-2
Classification (67/548/EEC) F+;R12
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
4.1. Description of first aid measures
General information
Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. Inhalation
Move the exposed person to fresh air at once. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. Keep the affected person warm and at rest. Get prompt medical attention. Ingestion
DO NOT INDUCE VOMITING! Rinse mouth thoroughly with water and give large amounts of milk or water to people not unconscious. Get medical attention if any discomfort continues.
Skin contact
Wash the skin immediately with soap and water. Get medical attention if any discomfort continues. Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General information
NOTE! Effects may be delayed. Keep affected person under observation.
4.3. Indication of any immediate medical attention and special treatment needed
No specific first aid measures noted.
5.1. Extinguishing media
Extinguishing media
Use: Powder. Dry chemicals, sand, dolomite etc. Water spray, fog or mist.
5.2. Special hazards arising from the substance or mixture
Unusual Fire & Explosion Hazards
Aerosol cans may explode in a fire.
5.3. Advice for firefighters
Special Fire Fighting Procedures
Containers close to fire should be removed or cooled with water. Use water to keep fire exposed containers cool and disperse vapours.
6.1. Personal precautions, protective equipment and emergency procedures
6.2. Environmental precautions
6.3. Methods and material for containment and cleaning up
Wear necessary protective equipment. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Let evaporate. Keep out of confined spaces because of explosion risk. If leakage cannot be stopped, evacuate area.
6.4. Reference to other sections
7.1. Precautions for safe handling
Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level.
7.2. Conditions for safe storage, including any incompatibilities
Aerosol cans: Must not be exposed to direct sunlight or temperatures above 50°C.
7.3. Specific end use(s)
8.1. Control parameters
WEL = Workplace Exposure Limit.
8.2. Exposure controls
Protective equipment


Engineering measures
Provide adequate general and local exhaust ventilation.
Respiratory equipment
No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational exposure limit. Use chemical cartridge protection with appropriate cartridge.
Hand protection
Use protective gloves.
Eye protection
Wear approved chemical safety goggles where eye exposure is reasonably probable.
Other Protection
Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact.
Hygiene measures
DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke.
9.1. Information on basic physical and chemical properties
Appearance Aerosol.
Colour Typical
Odour Characteristic.
Flammability Limit - Lower(%)0.8
Flammability Limit - Upper(%)9.0
9.2. Other information
10.1. Reactivity
No specific reactivity hazards associated with this product.
10.2. Chemical stability
Stable under normal temperature conditions.
10.3. Possibility of hazardous reactions
Not known.
10.4. Conditions to avoid
Avoid heat, flames and other sources of ignition. Avoid contact with: Strong oxidising agents. Strong alkalis. Strong mineral acids.
10.5. Incompatible materials
10.6. Hazardous decomposition products
Fire creates: Vapours/gases/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).
11.1. Information on toxicological effects
Inhalation
May cause irritation to the respiratory system. Vapours may cause headache, fatigue, dizziness and nausea. Prolonged inhalation of high concentrations may damage respiratory system.
Ingestion
May cause discomfort if swallowed. May cause stomach pain or vomiting. Gastrointestinal symptoms, including upset stomach.
Skin contact
Prolonged or repeated exposure may cause severe irritation. Acts as a defatting agent on skin. May cause cracking of skin, and eczema.
Eye contact
Irritating to eyes. May cause chemical eye burns.
Route of entry
Inhalation. Skin and/or eye contact.
Ecotoxicity
Dangerous for the environment if discharged into watercourses.
12.1. Toxicity
Data set not currently available.
12.2. Persistence and degradability
12.3. Bioaccumulative potential
Bioaccumulative potential
No data available on bioaccumulation.
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
12.6. Other adverse effects
Not known.
13.1. Waste treatment methods
Empty containers must not be burned because of explosion hazard. Dispose of waste and residues in accordance with local authority requirements.
14.1. UN number
UN No. (ADR/RID/ADN) 1950
UN No. (IMDG) 1950
UN No. (ICAO) 1950
14.2. UN proper shipping name
Proper Shipping Name AEROSOLS
14.3. Transport hazard class(es)
ADR/RID/ADN Class 2
ADR/RID/ADN Class Class 2: Gases
ADR Label No. 2.1
Transport Labels
14.4. Packing group
ADR/RID/ADN Packing groupNot Applicable
IMDG Packing group Not Applicable
ICAO Packing group Not Applicable
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant No.
14.6. Special precautions for user
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Uk Regulatory References
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2002.
The Control of Substances Hazardous to Health Regulations 2002.
Statutory Instruments
Control of Substances Hazardous to Health.
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Approved Code Of Practice
Classification and Labelling of Substances and Preparations Dangerous for Supply. Guidance Notes
Workplace Exposure Limits EH40.
Introduction to Local Exhaust Ventilation HS(G)37.
CHIP for everyone HSG(108).
15.2. Chemical Safety Assessment
Revision Date 02/08/2017
Revision 2
Supersedes date 20/04/2017
Risk Phrases In Full Extremely flammable.
R12
Hazard Statements In Full Extremely flammable gas. H220 Extremely flammable aerosol. H222


SAFETY DATA SHEET
CONCENTRATED TYRE & TRIM
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product name Product No.
CONCENTRATED TYRE & TRIM
002803070989
1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses As product description
1.3. Details of the supplier of the safety data sheet
SUPAGARD LIMITED
Supplier 23, Gavinton Street, Muirend, Glasgow, Scotland, G44 3EF 0141 633 5933 0141 637 7219 james@supagard.co.uk
1.4. Emergency telephone number
2.1. Classification of the substance or mixture
Classification (EC 1272/2008)
Physical and Chemical HazardsFlam. Liq. 3 - H226 Human health
EUH066;STOT SE 3 - H336;Asp. Tox. 1 - H304 Environment Not classified.
2.2. Label elements
Contains NAPHTHA (PETROLEUM), HYDROTREATED HEAVY
Label In Accordance With (EC) No. 1272/2008
Signal Word Danger Hazard Statements
H226
H304
Precautionary Statements
Flammable liquid and vapour.
May be fatal if swallowed and enters airways.
H336 May cause drowsiness or dizziness.
P102
P210
P271
P280
P261
P501
Supplementary Precautionary Statements
P233
P240
P241
Keep out of reach of children.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/face protection.
Avoid breathing vapour/spray.
Dispose of contents/container in accordance with local regulations.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical equipment.
Supplemental label information
2.3. Other hazards
P242
P243
P301+310
P303+361+353
P304+340
P312
P331
P370+378
P403+233
P403+235
P405
EUH066
Use only non-sparking tools.
Take precautionary measures against static discharge.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Call a POISON CENTER or doctor/physician if you feel unwell.
Do NOT induce vomiting.
In case of fire: Use foam, carbon dioxide, dry powder or water fog for extinction.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store locked up.
Repeated exposure may cause skin dryness or cracking.
3.2. Mixtures
CAS-No.: 64742-48-9
Classification (EC 1272/2008)
Flam. Liq. 3 - H226
EUH066
STOT SE 3 - H336
Asp. Tox. 1 - H304
EC No.: 919-857-5
Classification (67/548/EEC) Xn;R65. R10,R66,R67.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
4.1. Description of first aid measures
General information
NOTE! Effects may be delayed. Keep affected person under observation. NOTE! Keep affected person away from heat, sparks and flames!
Inhalation
Move the exposed person to fresh air at once. Keep the affected person warm and at rest. Get prompt medical attention. Perform artificial respiration if breathing has stopped. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen.
Ingestion
Remove victim immediately from source of exposure. Rinse mouth thoroughly. NOTE! Keep affected person away from heat, sparks and flames! DO NOT induce vomiting. Get medical attention immediately.
Skin contact
Remove affected person from source of contamination. Wash the skin immediately with soap and water. Get medical attention if any discomfort continues.
Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media
Use: Dry chemicals, sand, dolomite etc. Alcohol resistant foam. Water spray, fog or mist. Carbon dioxide (CO2).
5.2. Special hazards arising from the substance or mixture
Unusual Fire & Explosion Hazards
Vapours are heavier than air and may spread near ground to sources of ignition.
5.3. Advice for firefighters
Special Fire Fighting Procedures
Ventilate closed spaces before entering them. Move container from fire area if it can be done without risk. Use water to keep fire exposed containers cool and disperse vapours. Do not scatter spilled material with more water than needed to fight the fire. Be aware of danger for fire to re-start. Keep run-off water out of sewers and water sources. Dike for water control.
6.1. Personal precautions, protective equipment and emergency procedures
6.2. Environmental precautions
6.3. Methods and material for containment and cleaning up
Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Stop leak if possible without risk. Ventilate well. Wear necessary protective equipment. Absorb in vermiculite, dry sand or earth and place into containers.
6.4. Reference to other sections
7.1. Precautions for safe handling
Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. Risk of vapour concentration on the floor and in low-lying areas. Static electricity and formation of sparks must be prevented.
7.2. Conditions for safe storage, including any incompatibilities
Flammable/combustible - Keep away from oxidisers, heat and flames. Keep containers tightly closed.
Storage Class
Flammable liquid storage.
7.3. Specific end use(s)
8.1. Control parameters
- 15 Min
8.2. Exposure controls
Protective equipment


Process conditions
Provide eyewash station.
Engineering measures
No specific ventilation requirements noted, but forced ventilation may still be required if air contamination exceeds acceptable level.
Respiratory equipment
No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational exposure limit.
Hand protection
Use protective gloves.
Eye protection
Use eye protection.
Other Protection
Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact.
Hygiene measures
Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes contaminated. Promptly remove any clothing that becomes wet or contaminated. When using do not eat, drink or smoke. DO NOT SMOKE IN WORK AREA!
9.1. Information on basic physical and chemical properties
Appearance Liquid
Colour Typical
Odour Characteristic.
Relative density <1.0
Auto Ignition Temperature (°C)230
9.2. Other information
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity
10.2. Chemical stability
Stable under normal temperature conditions.
10.3. Possibility of hazardous reactions
10.4. Conditions to avoid
Avoid heat, flames and other sources of ignition. Avoid contact with strong oxidisers.
10.5. Incompatible materials
10.6. Hazardous decomposition products
Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).
11.1. Information on toxicological effects
Inhalation
Vapours may cause headache, fatigue, dizziness and nausea. Vapour may affect central nervous system and cause headache, discomfort, vomiting or intoxication. High concentrations of vapours may irritate respiratory system and lead to headache, fatigue, nausea and vomiting.
Ingestion
May cause stomach pain or vomiting. Gastrointestinal symptoms, including upset stomach.
Skin contact
Prolonged or repeated exposure may cause severe irritation. Acts as a defatting agent on skin. May cause cracking of skin, and eczema.
Eye contact
Irritating to eyes. Irritation, burning, lachrymation, blurred vision after liquid splash.
Health Warnings
Repeated exposure may cause chronic eye irritation. Swallowing concentrated chemical may cause severe internal injury.
Route of entry
Inhalation. Ingestion. Skin and/or eye contact.
Medical Symptoms
Irritation of eyes and mucous membranes. Dilated pupils. Rhinitis (inflammation of the nasal mucous membranes).
Ecotoxicity
Dangerous for the environment if discharged into watercourses.
12.1. Toxicity
12.2. Persistence and degradability
12.3. Bioaccumulative potential
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
12.6. Other adverse effects
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Collect on absorbent material, place in cardboard kegs and incinerate. Incinerate in suitable combustion chamber. Do not allow runoff to sewer, waterway or ground. Dispose of waste and residues in accordance with local authority requirements.
14: TRANSPORT INFORMATION
14.1. UN number
UN No. (ADR/RID/ADN) 1993
UN No. (IMDG) 1993
UN No. (ICAO) 1993
14.2. UN proper shipping name
Proper Shipping Name FLAMMABLE LIQUID, N.O.S.
14.3. Transport hazard class(es)
ADR/RID/ADN Class 3
ADR/RID/ADN Class Class 3: Flammable liquids.
ADR Label No. 3
IMDG Class 3
ICAO Class/Division 3
Transport Labels
14.4. Packing group
ADR/RID/ADN Packing groupIII
IMDG Packing group III
ICAO Packing group III
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant No.
14.6. Special precautions for user
EMS F-E, S-E
Emergency Action Code •3Y
Hazard No. (ADR) 30
Hazard No. (ADR) 30 Flammable liquid (flash-point between 23°C and 60°C, inclusive) or flammable liquid or solid in the molten state with a flash-point above 60°C, heated to a temperature equal to or above its flash-point, or self heating liquid.
Tunnel Restriction Code (D/E)
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Guidance Notes
Workplace Exposure Limits EH40.
Introduction to Local Exhaust Ventilation HS(G)37. EU Legislation
Regulation (EC) No.1272/2008 The Classification, Labelling and Packaging of substances and mixtures Regulations Regulation (EC) No. 1907/2006 The Registration, Evaluation, Authorisation and Restriction of Chemicals Regulations (REACH) 2001/95/EC The General Product Safety Directive (GPSD)
Commission Regulation (EU) 2015/830 Requirements for the compilation of safety data sheets (amending REACH)
Authorisations (Title VII Regulation 1907/2006)
No specific authorisations are noted for this product. Restrictions (Title VIII Regulation 1907/2006)
No specific restrictions of use are noted for this product.
15.2. Chemical Safety Assessment
Revision Date 10/04/2017
Revision 2
Supersedes date 06/01/2005
Hazard Statements In Full
EUH066 Repeated exposure may cause skin dryness or cracking. , H226 Flammable liquid and vapour. , H304 May be fatal if swallowed and enters airways. , H336 May cause drowsiness or dizziness.


SAFETY DATASHEET
FABRIC CLEANER
Section 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name: FABRIC CLEANER
Product code: HC8430
Synonyms: HC8430 / SUP PD0399-2
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of substance / mixture: Aerosol foaming cleanser.
1.3. Details of the supplier of the safetydata sheet
Companyname: SUPAGARD LIMITED 23 Gavinton Street Muirend Glasgow Scotland G44 3EF
Tel: 0141 633 5933
Email: james@supagard.co.uk
1.4. Emergencytelephone number
Emergencytel: 0141 633 5933 (office hours only)
Section 2: Hazards identification
2.1. Classification of the substance or mixture
Classification under CLP: Flam. Aerosol 1: H222; -: H229
Page: 1
Compilation date: 10/11/2021
Revision date: 14/05/2024
Revision No: 2
Most important adverse effects: Extremely flammable aerosol. Pressurised container: May burst if heated.
2.2. Label elements
Label elements:
Hazard statements: H222: Extremely flammable aerosol. H229: Pressurised container: May burst if heated.
Hazard pictograms: GHS02: Flame

Signal words: Danger
Precautionarystatements: P102: Keep out of reach of children.
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P211: Do not spray on an open flame or other ignition source.
P251: Do not pierce or burn, even after use.
P410+P412: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
P260: Do not breathe spray.
P302+P350: IF ON SKIN: Gently wash with plenty of soap and water.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Haz. ingredients (label): Contains:
2.3. Other hazards
Other hazards: In use, may form flammable / explosive vapour-air mixture. PBT: This product is not identified as a PBT/vPvB substance.
Section 3: Composition/information on ingredients
3.2. Mixtures
Hazardous ingredients:
- REACH registered number(s): 01-2119474691-32-XXXX
- REACH registered number(s): 01-2119486944-21-XXXX
- REACH registered number(s): 01-2119457558-25
Section 4: First aid measures
4.1. Description of first aid measures
Skin contact: Wash immediately with plenty of soap and water.
Eye contact: Bathe the eye with running water for 15 minutes. Consult a doctor.
Ingestion: Do not induce vomiting. If conscious, give half a litre of water to drink immediately. Consult a doctor.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Consult a doctor. Move to fresh air in case of accidental inhalation of vapours.
4.2. Most important symptoms and effects, both acute and delayed
Skin contact: There may be mild irritation at the site of contact.
Eye contact: There may be irritation and redness.
Ingestion: There may be irritation of the throat.
Inhalation: There may be a feeling of tightness in the chest with shortness of breath.
4.3. Indication of anyimmediate medical attention and special treatment needed
Immediate / special treatment: Not applicable.
Section 5: Fire-fighting measures
5.1. Extinguishing media
Extinguishing media: Alcohol resistant foam. Water spray. Carbon dioxide. Dry chemical powder.
5.2. Special hazards arising from the substance or mixture
Exposure hazards: Highly flammable. In combustion emits toxic fumes. Forms explosive air-vapour mixture. Vapour may travel considerable distance to source of ignition and flash back. Aerosol cans may explode during a fire, giving a high speed projectile.
5.3. Advice for fire-fighters
Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.
Section 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergencyprocedures
Personal precautions: Refer to section 8 of SDS for personal protection details. Notify the police and fire brigade immediately. Eliminate all sources of ignition. Cover leaking can until the discharge has stopped, before attempting cleanup operations.
6.2. Environmental precautions
Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.
6.3. Methods and material for containment and cleaning up
Clean-up procedures: Do not use equipment in clean-up procedure which may produce sparks. Absorb into dry earth or sand. Clean-up should be dealt with only by qualified personnel familiar with the specific substance. Wash the spillage site with large amounts of water.
6.4. Reference to other sections
Reference to other sections: Refer to section 8 of SDS.
Section 7: Handling and storage
7.1. Precautions for safe handling
Handling requirements: Smoking is forbidden. Use non-sparking tools. Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Avoid the formation or spread of mists in the air.
7.2. Conditions for safe storage, including anyincompatibilities
Storage conditions: Store in a cool, well ventilated area. Keep away from sources of ignition. Keep away from direct sunlight.
7.3. Specific end use(s)
Specific end use(s): No data available.
Section 8: Exposure controls/personal protection
8.1. Control parameters
Hazardous ingredients:
BUTANE, <0.1%1,3 BUTADIENE
Workplace exposure limits:
Respirable dust:
PROPANE, <0.1%1,3 BUTADIENE
DNEL/PNEC Values
DNEL / PNEC No data available.
8.2. Exposure controls
Engineering measures: Ensure there is sufficient ventilation of the area. Ensure lighting and electrical equipment are not a source of ignition.
Respiratoryprotection: Respiratory protection not required.
Hand protection: Protective gloves.
Eye protection: Safety glasses. Ensure eye bath is to hand.
Skin protection: Protective clothing.
Section 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
State: Aerosol
Colour: Colourless
Odour: Perfumed
Evaporation rate: Slow
Solubilityin water: Soluble
Viscosity: Non-viscous
Boiling point/range°C: No data available.
Melting point/range°C: No data available.
Flammabilitylimits %:lower: 0.9 upper: 9.0
Flash point°C: -40
Autoflammability°C: >230
Part.coeff. n-octanol/water: No data available.
Vapour pressure: No data available.
Relative density: No data available. pH: 9 - 10
VOC g/l: No data available.
9.2. Other information
Other information: No data available.
Section 10: Stabilityand reactivity
10.1. Reactivity
Reactivity: Stable under recommended transport or storage conditions.
10.2. Chemical stability
Chemical stability: Stable under normal conditions. Stable at room temperature.
10.3. Possibilityof hazardous reactions
Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions. Decomposition may occur on exposure to conditions or materials listed below.
10.4. Conditions to avoid
Conditions to avoid: Heat. Hot surfaces. Sources of ignition. Flames. Direct sunlight.
10.5. Incompatible materials
Materials to avoid: Strong oxidising agents. Strong acids.
10.6. Hazardous decomposition products
Haz. decomp. products: In combustion emits toxic fumes.
Section 11: Toxicological information
11.1. Information on toxicological effects
Hazardous ingredients:
FABRIC CLEANER
Toxicityvalues: No data available.
Symptoms / routes of exposure
Skin contact: There may be mild irritation at the site of contact.
Eye contact: There may be irritation and redness.
Ingestion: There may be irritation of the throat.
Inhalation: There may be a feeling of tightness in the chest with shortness of breath.
Section 12: Ecological information
12.1. Toxicity
Hazardous ingredients:
PROPAN-2-OL
Daphnia magna
12.2. Persistence and degradability
EC50
EC50
Persistence and degradability: Biodegradable. The surfactant(s) contained in this preparation complies (comply) with the biodegradability criteria as laid down in Regulation (EC) No. 648/2004 on detergents.
12.3. Bioaccumulative potential
Bioaccumulative potential: No bioaccumulation potential.
12.4. Mobilityin soil
Mobility: Readily absorbed into soil. Volatile. Soluble in water. Vapour is heavier than air.
12.5. Results of PBT and vPvB assessment
PBT identification: This product is not identified as a PBT/vPvB substance.
12.6. Other adverse effects
Other adverse effects: Negligible ecotoxicity.
Section 13: Disposal considerations
13.1. Waste treatment methods
Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.
Recoveryoperations: Recycling/reclamation of metals and metal compounds.
Waste code number: 16 05 05
Disposal of packaging: Empty cans must not be burned because of explosion hazard. Recycle container where permitted.
NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.
Section 14: Transport information
14.1. UN number
UN number: UN1950
14.2. UN proper shipping name
Shipping name: AEROSOLS
14.3. Transport hazard class(es)
Transport class: 2
14.4. Packing group
14.5. Environmental hazards
Environmentallyhazardous: No
14.6. Special precautions for user
Special precautions: No special precautions.
Tunnel code: D
Transport category: 2
Section 15: Regulatoryinformation
Marine pollutant: No
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Specific regulations: Not applicable.
15.2. Chemical SafetyAssessment
Chemical safetyassessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.
Section 16: Other information
Other information
Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 2015/830.
All substances in this preparation are registered within UK/EU/EFTA countries under the REACH (UK/EC) (ammended) regulations, EC 1907/2006
IMPORTANT NOTE:
Risk phases in this section belowrelate to the INDIVIDUAL COMPONENTS in the formulation when used at their FULL CONCENTRATIONS, and not at the reduced levels in the mixed product.
See sections 2 and 3 for the calculated hazard and risk phrases for the blended product.
Phrases used in s.2 and s.3: H220: Extremely flammable gas.
H222: Extremely flammable aerosol.
H225: Highly flammable liquid and vapour.
H229: Pressurised container: May burst if heated.
H319: Causes serious eye irritation.
H336: May cause drowsiness or dizziness.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.


according to Regulation (EU) 2015/830
SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking
1.1.Productidentifier
Productname Productcode Upholstery Cleaner QAFS777
1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst
ProductUse
[SU3]Industrialuses:Usesofsubstancesassuchorinpreparationsatindustrialsites;
[SU22]Professionaluses:Publicdomain(administration,education,entertainment,services, craftsmen);
[SU21]Consumeruses:Privatehouseholds(=generalpublic=consumers); Description Nodataisavailableonthisproduct.
1.3.Detailsofthesupplierofthesafetydatasheet
Company SUPAGARDLIMITED
Address 19-27GavintonStreet Muirend Glasgow G443EF
Web www.supagard.co.uk
Telephone 01416335933
Fax 01416377219
Email James.Smyth@supagard.com
Emailaddressofthe competentperson James.Smyth@supagard.com
1.4.Emergencytelephonenumber
Emergencytelephonenumber01416335933
8.30amto5.00pm
SECTION2:Hazardsidentification
2.1.Classificationofthesubstanceormixture
2.1.2.Classification-EC 1272/2008 SkinIrrit.2:H315;EyeIrrit.2:H319;AquaticChronic3:H412;
2.2.Labelelements
Hazardpictograms

SignalWord Warning
HazardStatement
SkinIrrit.2:H315-Causesskinirritation. EyeIrrit.2:H319-Causesseriouseyeirritation.

2.2.Labelelements
AquaticChronic3:H412-Harmfultoaquaticlifewithlonglastingeffects.
PrecautionaryStatement: Prevention P264-Washhandsandothercontactedskinthoroughlyafterhandling.
P280-Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection.
PrecautionaryStatement: Response P302+P352-IFONSKIN:Washwithplentyofwater/. P305+P351+P338-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontact lenses,ifpresentandeasytodo.Continuerinsing.
P332+P313-Ifskinirritationoccurs:Getmedicaladvice/attention.
P337+P313-Ifeyeirritationpersists:Getmedicaladvice/attention.
PrecautionaryStatement: Disposal P501-Disposeofcontents/containertoanapprovedwastecontractor.
2.3.Otherhazards
Otherhazards PBTnotidentifiedasaPBTsubstance.
3.2.Mixtures
67/548/EEC/1999/45/EC
ChemicalName
Quaternaryammoniumcompounds, benzyl-C12-14(evennumbered) -alkyldimethyl,chlorides
IndexNo.CASNo.ECNo.
68424-85-1939-350-201-2119970550-39
CocamidopropylBetain Xi;R41R52/531-10% 2-butoxyethanol
EC1272/2008
ChemicalName
Quaternaryammoniumcompounds, benzyl-C12-14(evennumbered) -alkyldimethyl,chlorides
603-014-00-0111-76-2203-905-001-2119475108-360.5Xn;R20/21/22Xi;R36/38 -1%
IndexNo.CASNo.ECNo.
68424-85-1939-350-201-2119970550-39
AcuteTox.4:H302;Skin Corr.1B:H314;Aquatic Acute1:H400; 0-0.5% M=1
CocamidopropylBetain EyeDam.1:H318;Aquatic Chronic3:H412; 1-10% 2-butoxyethanol
603-014-00-0111-76-2203-905-001-2119475108-36
AcuteTox.4:H332;Acute Tox.4:H312;AcuteTox.4: H302;EyeIrrit.2:H319;Skin Irrit.2:H315; 0.5-1%
Furtherinformation
ProductShelfLife RECOMMENDEDSHELFLIFE1YEARFROMDATEOFDELIVERY.
ActiveIngredients Ingredients-SodiumMetasilicatePentahydrate,Lessthan5%AmphotericSurfactants,Lessthan 5%Non-ionicSurfactants,Lessthan5%CationicSurfactants.
SECTION4:Firstaidmeasures
4.1.Descriptionoffirstaidmeasures
Inhalation Movetheexposedpersontofreshair.
Eyecontact Rinseimmediatelywithplentyofwater.Contactlensesshouldberemoved.
Skincontact Removecontaminatedclothing.Washwithwaterandsoapasaprecaution.
Ingestion DONOTINDUCEVOMITING.Rinsemouththoroughly.
4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed
Inhalation Irritatingtorespiratorysystem.
Eyecontact Irritatingtoeyes.
Skincontact Irritatingtoskin.
Ingestion Irritatingtomucousmembranes.
4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded

4.3.Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded
Inhalation
Eyecontact
Skincontact
Ingestion
Generalinformation
Movetheexposedpersontofreshair.Seekmedicalattentionifirritationorsymptomspersist.
Contactlensesshouldberemoved.Rinseimmediatelywithplentyofwater.Seekmedicalattention ifirritationorsymptomspersist.
Seekmedicalattentionifirritationorsymptomspersist.
Drink1to2glassesofwater.Seekmedicalattentionifirritationorsymptomspersist.
Ifyoufeelunwell,seekmedicaladvice(showthelabelwherepossible).Treatsymptomatically.
5.1.Extinguishingmedia
Thisproductisnotflammable.Usefire-extinguishingmediaappropriateforsurroundingmaterials.
5.2.Specialhazardsarisingfromthesubstanceormixture
Burningproducesirritating,toxicandobnoxiousfumes.
5.3.Adviceforfirefighters
Furtherinformation
Wearsuitablerespiratoryequipmentwhennecessary.
Intheeventofafireand/orexplosiondonotbreathfumes.Standardprocedureforchemicalfires. Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding environment.
6.1.Personalprecautions,protectiveequipmentandemergencyprocedures
6.2.Environmentalprecautions
Wearsuitableprotectiveequipment.
Adviselocalauthoritiesiflargespillscannotbecontained.
6.3.Methodsandmaterialforcontainmentandcleaningup
Forlargespills:.Absorbwithinert,absorbentmaterial.Sweepup.Transfertosuitable,labelled containersfordisposal.Cleanspillageareathoroughlywithplentyofwater.Forsmallspills:.Flush downthedrainwithplentyofwater.
6.4.Referencetoothersections
Seesection2,7,8,13forfurtherinformation.
7.1.Precautionsforsafehandling
AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.
7.2.Conditionsforsafestorage,includinganyincompatibilities
Storeinacool,dryarea.Keepcontainertightlyclosed.Keepoutofthereachofchildren.Storein originalcontainer.
7.3.Specificenduse(s)
Suitablepackaging
Nodataisavailableonthisproduct.
Plasticcontainers.
SECTION8:Exposurecontrols/personalprotection
8.1.Controlparameters

8.1.Controlparameters
8.1.1.ExposureLimitValues
2-butoxyethanol
DNEL:Derivedno-effectlevel.
ExposurePattern-Workers
2-butoxyethanol
Occupationalexposurecontrols.
WEL8-hrlimitppm:25
WEL15minlimitppm:50
WEL8-hrlimitmg/m3total inhalabledust: -
WEL8-hrlimitmg/m3total respirabledust: -
Long-term-inhalation-Systemic effects 98mg/m³
Long-term-inhalation-Local effects 663mg/m³
Long-term-dermal-Local effects 89mg/kg
WEL8-hrlimitmg/m3:123
WEL15minlimitmg/m3:101.2
WEL15minlimitmg/m3total inhalabledust: -
WEL15minlimitmg/m3total respirabledust: -
Long-term-dermal-Systemic effects 75mg/kg
ExposurePattern-Generalpopulation
2-butoxyethanol
Acutedermal-Localeffects13.4mg/kg
Long-term-inhalation-Systemic effects 49mg/m³
Long-term-dermal-Local effects 44.5mg/kg
Long-term-inhalation-Local effects 426mg/m³
8.2.Exposurecontrols


AdoptbestManualHandlingconsiderationswhenhandling,carryinganddispensing.Avoidcontact withskinandeyes.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Use appropriatepersonalprotectiveequipment.Wearsuitableprotectiveclothingandeye/face protection.
Eye/faceprotection Avoidcontactwitheyes.Ifsplashesarelikelytooccur,wear:safetyglasseswithside-shields.
SkinprotectionHandprotection Rubbergloves.
Respiratoryprotection Nopersonalrespiratoryprotectiveequipmentnormallyrequired.Incaseofinsufficientventilation wearsuitablerespiratoryequipment.
8.2.3.Environmentalexposure controls Preventfurtherleakageorspillageifsafetodoso.
9.1.Informationonbasicphysicalandchemicalproperties

9.1.Informationonbasicphysicalandchemicalproperties
AppearanceLiquid
ColourCream
OdourCharacteristic
OdourthresholdNodataavailable pH11-11.4
MeltingpointNodataavailable
InitialboilingpointNodataavailable
EvaporationrateNodataavailable Flammability(solid,gas)Nodataavailable VapourpressureNodataavailable
VapourdensityNodataavailable
RelativedensityNodataavailable
PartitioncoefficientNodataavailable AutoignitiontemperatureNodataavailable ExplosivepropertiesNodataavailable
OxidisingpropertiesNodataavailable
SolubilityNodataavailable
9.2.Otherinformation
ConductivityNodataavailable
SurfacetensionNodataavailable Specificgravity1.008-1.016g/cm³
GasgroupNodataavailable BenzeneContentNodataavailable
LeadcontentNodataavailable
VOC(Volatileorganic compounds) Nodataavailable
SECTION10:Stabilityandreactivity
10.1.Reactivity
10.2.Chemicalstability
Stableundernormalconditions.Nospecificreactivityhazardsassociatedwiththisproduct.
Stableundernormalconditions.Noparticularstabilityconcerns.
10.3.Possibilityofhazardousreactions
Strongacids.Strongoxidisingagents.
10.4.Conditionstoavoid
10.5.Incompatiblematerials
Protectfromfrost.
Noincompatiblegroupsnoted.
10.6.Hazardousdecompositionproducts
NoHazardousdecompositionproductswhenstoredandhandledcorrectly.Burningproduces irritating,toxicandobnoxiousfumes.
11.1.Informationontoxicologicaleffects
Skincorrosion/irritation Irritatingtoskin.
Seriouseyedamage/irritationNotanticipatedundernormalconditionsofuse.Irritatingtoeyes.

11.1.Informationontoxicologicaleffects
Respiratoryorskin sensitisation
Repeatedorprolonged exposure
11.1.2.Mixtures
11.1.3.HazardInformation
11.1.4.ToxicologicalInformation
Notanticipatedundernormalconditionsofuse.Irritatingtorespiratorysystem.Irritatingtoskin.
Prolongedcontactmaycausedefattingoftheskin.Irritatingtoeyes,respiratorysystemandskin. Irritatingtomucousmembranes.
Nodataavailable.
Nodataavailable.
Nodataavailable
SECTION12:Ecologicalinformation
12.1.Toxicity
Nodataavailable
12.2.Persistenceanddegradability
SubstancebiodegradesatamoderaterateandinherentlybiodegradableaccordingtotheOECD guidelines.
12.3.Bioaccumulativepotential
Partitioncoefficient
12.4.Mobilityinsoil
Nodataisavailableonthisproduct.
SupagardUpholsteryCleanerNodataavailable
CocamidopropylBetainNodataavailable 2-butoxyethanol0.8logP
Nodataisavailableonthisproduct.
12.5.ResultsofPBTandvPvBassessment
Nodataisavailableonthisproduct.
12.6.Otheradverseeffects
Nodataavailable.
13.1.Wastetreatmentmethods
Generalinformation
Disposalofpackaging
Disposeofwasteandresiduesinaccordancewithlocalauthorityrequirements.
Disposeofincompliancewithalllocalandnationalrequirements.
DoNOTreuseemptycontainers.Emptycontainerscanbesenttolandfillaftercleaning,ifin compliancewithlocalandnationalregulations.
SECTION14:Transportinformation
14.1.UNnumber
14.2.UNpropershippingname
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.

14.3.Transporthazardclass(es)
14.4.Packinggroup
14.5.Environmentalhazards
14.6.Specialprecautionsforuser
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
Theproductisnotclassifiedasdangerousforcarriage.
14.7.TransportinbulkaccordingtoAnnexIIofMARPOL73/78andtheIBCCode
Theproductisnotclassifiedasdangerousforcarriage.
15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture
Regulations REGULATION(EC)No1907/2006OFTHEEUROPEANPARLIAMENTANDOFTHECOUNCIL of18December2006concerningtheRegistration,Evaluation,AuthorisationandRestrictionof Chemicals(REACH),establishingaEuropeanChemicalsAgency,amendingDirective1999/45/EC andrepealingCouncilRegulation(EEC)No793/93andCommissionRegulation(EC)No1488/94 aswellasCouncilDirective76/769/EECandCommissionDirectives91/155/EEC,93/67/EEC, 93/105/ECand2000/21/EC.
COMMISSIONREGULATION(EU)No453/2010of20May2010amendingRegulation(EC)No 1907/2006oftheEuropeanParliamentandoftheCouncilontheRegistration,Evaluation, AuthorisationandRestrictionofChemicals(REACH),establishingaEuropeanChemicalsAgency, amendingDirective1999/45/ECandrepealingCouncilRegulation(EEC)No793/93and CommissionRegulation(EC)No1488/94aswellasCouncilDirective76/769/EECand CommissionDirectives91/155/EEC,93/67/EEC,93/105/ECand2000/21/EC.
15.2.Chemicalsafetyassessment
Noinformationavailable.
SECTION16:Otherinformation
Otherinformation
Revision
TextofriskphrasesinSection 3
TextofHazardStatementsin Section3
Thisdocumentdiffersfromthepreviousversioninthefollowingareas:. 2-PrecautionaryStatement:Prevention. 9-9.1.Informationonbasicphysicalandchemicalproperties(PH). 12-12.1.Toxicity.
R20/21/22-Harmfulbyinhalation,incontactwithskinandifswallowed.
R22-Harmfulifswallowed.
R34-Causesburns.
R36/38-Irritatingtoeyesandskin.
R41-Riskofseriousdamagetoeyes.
R50-Verytoxictoaquaticorganisms.
R52/53-Harmfultoaquaticorganisms,maycauselong-termadverseeffectsintheaquatic environment.
AcuteTox.4:H302-Harmfulifswallowed.
SkinCorr.1B:H314-Causessevereskinburnsandeyedamage.
AquaticAcute1:H400-Verytoxictoaquaticlife.
EyeDam.1:H318-Causesseriouseyedamage.
AquaticChronic3:H412-Harmfultoaquaticlifewithlonglastingeffects.
AcuteTox.4:H312-Harmfulincontactwithskin.
SkinIrrit.2:H315-Causesskinirritation.
EyeIrrit.2:H319-Causesseriouseyeirritation.
AcuteTox.4:H332-Harmfulifinhaled.

TheinformationsuppliedinthisSafetyDataSheetisdesignedonlyasguidanceforthesafeuse, storageandhandlingoftheproduct.Thisinformationiscorrecttothebestofourknowledgeand beliefatthedateofpublicationhowevernoguaranteeismadetoitsaccuracy.Thisinformation relatesonlytothespecificmaterialdesignatedandmaynotbevalidforsuchmaterialusedin combinationwithanyothermaterialsorinanyotherprocess.

