Chemicals Guidance

Page 69

Trisubstituted tin organic compounds

Required limit value:

Should not be present in products.

CAS RN:

Tributyltin Tributyltin Tributyltin Tributyltin Tributyltin Tributyltin

Properties:

Bactericides. Tributyltin compounds are different chemical substances that are toxic and dangerous for the environment. Bioaccumulative and persistent.

Use in textile and leather:

Antibacterial agent to counteract noxious odours in clothes and shoes. Preservative, fungicide and antifouling agent.

Comments:

The alternative to antibacterial agents during use is satisfactory washing.

chloride:1461-22-9 fluoride: 1983-10-4 methacrylate: 2155-70-6 benzoate: 4342-36-3 linoleate: 24124-25-2 naphthenate: 85409-17-2

If use of biocidal agents is essential, folpet, chlorocresol, propiconazole, azoxystrobin and fludioxonil are approved for PT9 according to the Biocidal Product Regulation (EU 528/2012). Legal background:

Legal Limit: 0.1% by weight. All tri-substituted organostannic compounds such as tributyltin (TBT) are restricted in articles in annex XVII of the Regulation (EC) No 1907/2006 (REACH), entry 20. The seven TBT compounds listed above are also included in the Rotterdam convention. Tributyltin oxide (TBTO) 56-35-9 and Dibutyltin dichloride (DBTC), 683-18-1 are listed on the Candidate List of Substances of Very High Concern for authorization of the Regulation (EC) No 1907/2006 of the European Parliament and of the Council (REACH).

Test method:

EN ISO 22744 (textiles) Test equipment: GC-MS. EN ISO17353 (water and sediment). LOQ: 0.2 mg/kg

CHEMICALS GUIDANCE | Edition: January 2020 | © 2020 Textilimportörerna/Swedish Chemicals Group - RISE IVF

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