PSC Rolling Mill Products - Konasol Brochure

Page 1

KONASOL

To make people happy with nanotechnology

KOREA NANO SOLUSION

KO : Korea

NA : Nano

Korea’s Leading Position in the world, Pursuing the World Top 5 from the poorest country, Realized High-Speed Growth in short period of time, The Image of Most Successful Country

Achieved the Highest level of National Brand, A Country of Cultural Advancement with K-POP including BTS, K-CULTURE, and K-FOOD

Nano Science Technology, Nano Material

Material component with one-hundredth of a millionth of the thickness of a hair The core technology of 4th industrial revolution developing Nano Technology and its utilization

A Scientific Technology of future material creating higher value scientifically and engineeringly

SOL : Solution

Provide Solutions to the problems of human being and customers’ Technical Difficulties (Solution Provider)

Provide Solutions to difficult problems in each field.

02
KO
Nano
korea NA
SOL Solution
Green means Blue Global Environment
Red means that if you transfer golden material into nano-sized particles, it turns red
Blue means that Science and Technology solve the difficulties of human life

Powder Metallurgy

Alloy Steel

Casting RESISTARⓇ

03
Isostatic Press)
Alloy-TiCⓇ
18p 28p
Currently Equipped Facility Sales Reference
HIP (Hot
Hi-Max
Contents 08p
34p 40p 45p 49p

Company overview

MAIN BUSINESS

Alloy-TiC, powder steel, rolling mill, guide roll, tube mill, transfer rate, mold, extruding grinding, construction facility component, heating furnace, roll, transfer, control facility, magnet for industrial purpose, scrap steel cut, vehicle component, piston pin

HEAD OFFICE

17-60, Saneopdanji-gil, Myeoncheon-myeon, Dangjin-si, Chungcheongnam-do, Republic of Korea

Tel. +82-41-359-6600

Fax.+82-41-359-6609

17-60, Saneopdanji-gil, Myeoncheon-myeon, Dangjin-si, Chungcheongnam-do, Republic of Korea

HWASEONG PLANT

711-63, Mannyeon-ro, Jeongnam-myeon, Hwaseong-si, Gyeonggi-do, Republic of Korea

04

Founded Myeong Jun Industry

Changed to Alloytic Co., Ltd.

Appointed as a corporation for special cases on military service, business venture

Designated as a corporation eligible for export support

Established a company-affiliated research institute

Qualified for ISO 9001:2000 certification, EM Mark(quality certification)

Patent qualification(No. 0340800), selected as an expert company in component material

Patent qualification(No. 10-0587495), promising export company, INNO-BIZ

Renamed Daehwa Alloy Tech Co., Ltd. as a result of M&A with Daehwa Precision Manufacturing Co., Ltd.

Selected as a company of innovative management(No. 080501-01086)

KOTRA-guaranteed brand(Seal of Excellence) certification qualification

Awarded the 3 Million Dollar Export Tower Award

Patent application(complex hammer bits/composite rolling mill/vessel engine nozzle)

Install HIP(Hot Isostatic Pressing)(maximum size in Korea)

Patent application(piston pin for vehicle /nano lubrication additives) dispersion)

Promoted as a middle standing company by the Federation of Korean Industries

(10 out of 4,000 companies designated)

Awarded the 10 Million Dollar Export Tower Award

Certification of vehicle non-engine oil driving to be the longest record in Korea (Korea Record Institute)

(Add nanorex - obtain new record from the existing 837Km to 1,309Km)

Relocated head office / first factory to Dangjin Myeoncheon Industrial Complex

Awarded the Minister of Trade, Industry, and Energy Prize

Selected as a youth-friendly small hidden champion(Ministry of Employment and Labor

Confirmed as root company, increased investment from external institutes (2.8 billion won of capital)

May - Renamed DAT Advanced Material Co., Ltd.

July - Established 100% self-sufficient powder for our company at the Daejeon factory

Products selected by Korea Energy certified

Awarded the Minister of Trade, Industry, and Energy Prize(Nano Korea 2020)

Awarded by Korea Prime minister for Machinery and Robotic Development

Selected as a specialized company in material, parts and equipment by Korea Government

New Company Name of KONASOL

05 1990 1997 1998 2000 2001 2002 2004 2006 2007 2008 2009 2010 2011 2012 2013 2014 2016 2017 2019 2020 2021 2022

Products

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07 01
03
Alloy Steel FT-9
FT-10
FT-23 Casting RESISTARⓇ Hi-Max HIP (Hot Isostatic Press) Alloy-TiCⓇ FT-1
FT-2
FT-4
FT-5 04 05
02
Powder Metallurgy
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Alloy-TiCⓇ
FT-1 FT-2 FT-4 FT-5

Alloy-TiCⓇ

Overview of Alloy-TiC®

Alloy-TiC is one of the metal matrix composites having TiC (titanium carbide) as raw material and high hardness, with minute circular titanium carbide sprayed uniformly all over the alloy steel. Alloy-Tic is produced after mixing and molding the alloy steel and TiC powder and sintered in a vacuum furnace and then processed to HIP. The TiC (Hv:3,200) particle shows over 30% higher hardness than WC (Hv:2,400) particle, but Alloy-TiC can be racked, milled, and polished in annealing state, which is advantageous for the hardening process of up to HRc 68-72.

Advantages of Alloy-TiC®

1. Excellent wear resistance

Wear resistance is one of the widely known advantages of Alloy-TiC. The TiC particle on a surface after wrapping and polishing is a circular HRc92 with 30% or higher hardness and lower friction coefficient than WC hardness; hence the minimized pick-up, galling, and chipping phenomena and little or no wear loss upon contact with other metals.

2. Low density of Alloy TiC offers cost reduction effect

Alloyteel (6.5g/cm3) has relatively low ratio than WC hard metal (14.5g/cm3) or tool steel (8g/cm3) that, if applied to the same volume as WC hard metal or tool steel, it is cheaper in price and, if used instead of WC hard metal, the maintenance and change costs of components are relatively low.

3. Alloy-TiC is the only machinable carbide composite

Alloy-TiC can be processed with general machining process with HRc43-45 in annealing state, becoming hard metal of HRc68-72 after heating process. In addition, before and after the heating process, its size strain is relatively stable.

4. Alloy-TiC is zero-defect sintered carbide composite

Alloy-TiC is zero-defect composite without bubbles inside thanks to the HIP process.

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Alloy-TiC FT-1 Magnification(X750) Titanium Carbide Micrograins Tungsten Carbide WC-120Co(X2,000)

Alloy-TiCⓇ FT-1

Characteristic

Alloy-TiC FT-1 is a sintered product after spraying approximately 45% of high-hardness circular TiC (Titanium Carbide) particle, which has hardness within the powder matrix of steel alloy as HRc 92; thus it is a hard metal available for mechanical process that can endure severe repetitive friction

• Excellent wear resistance using high hardness(HRc 02) circular TiC particle

• Friction during the drawing process due to the excellent lubrication property of TiC particle

• Minimally improve quality(prevent picking up, scratch)

• Easy to process with common mechanical process prior to heating process

• Size stability before and after heating process(strain ±0.0002mm)

• Heat proof, impact resistance, and corrosion resistance can be added by the composite of steel alloy

• Can contain up to 70% TiC to improve wear resistance and can have higher hardness by nitriding

• Same with Ferro-TiC CM

Composition

11
Properties Rockwell “C” Hardness Expansion Ratio (10-6mm·℃-1·mm-1) Density (g/cm3)6.5 45 ~ 48 Annealing 68 ~ 70 Hardening 6.38 20 ~ 100℃ 8.67 20 ~ 550℃
CompostionCrMoAl (wt%)9.73NiTiC(vol%) Fe -45Bal Properties Transverse Rupture Strength TRS(kg/mm2) Compressive Strength(kg/mm2)200 4.52 Impact Strength(mm·kg/mm2) 12 180 Conductivity(Wattm-1℃) Properties Alloy-TiC Ⓡ P / M Alloy Steel Casting RESISTAR Ⓡ HIP Hi-Max Sales Reference Current status of equipped facility

Alloy-TiCⓇ FT-2

Characteristic

Alloy-TiC FT-2 is a product with 45% of TiC (Titanium Carbide) circular particles with high hardness of HRc 92 within the powder matrix of stainless 400-type alloy spread and sintered; thus, it is a hard metal available for general mechanical process that can endure extreme repetitive friction

• Excellent wear resistance using TiC circular particles with high hardness(HRc 92) - 5- to 20-fold wear resistance compared to Stainless Steel/ Monel

• Excellent corrosion resistance with Stainless 400 type

• (US) FDA-certified material

• Easy to process with common mechanical process prior to heating process

• Minimize friction due to excellent lubrication of TiC particles(prevent picking up, scratches)

12
CompostionCrMoAlNiTiC(vol%) Fe (wt%)180.5--45Bal
Composition
Properties Rockwell "C" Hardness (HRc) Expansion Ratio (10-6mm·℃-1·mm-1) Density (g/cm3)6.50 45 ~ 49 Annealing 68 ~ 72 Hardening 5.56 20 ~ 90℃ 6.75 20 ~ 315℃ Properties Transverse Rupture Strength TRS(kg/mm2) Compressive Strength(kg/mm2) Impact Strength(mm·kg/mm2)3.54 15 Conductivity(Wattm-1℃) 170 323 Properties

Alloy-TiCⓇ FT-4

• Same as Ferro-TiC C, applied at tool, die, and worn components, excellent oscillation damping during annealing state.

• Alloy-TiC FT-4 is widely used for general mechanical tools, gauges, and other wear resistance components.

13 Characteristic Composition CompostionCrMo AlNiTiC(vol%) Fe (wt%)3.13.1 --45Bal
Properties Rockwell "C" Hardness (HRc) Expansion Ratio (10-6mm·℃-1·mm-1) Density (g/cm3)6.6 45 ~ 48 Annealing 68 ~ 70 Hardening 9.2 20 ~ 100℃ 9.8 20 ~ 550℃ Properties Transverse Rupture Strength TRS(kg/mm2) Compressive Strength(kg/mm2) Impact Strength(mm·kg/mm2)6.72 20.5 Conductivity(Wattm-1℃) 150 380 Properties Alloy-TiC Ⓡ P / M Alloy Steel Casting RESISTAR Ⓡ HIP Hi-Max Sales Reference Current status of equipped facility

Alloy-TiCⓇ FT-5

Alloy-TiC FT-5 is a precipitation reinforcement-type nickel base high heat resistance alloy and is a product where high-hardness TiC circular particles are spread and sintered at the matrix, which can be applied to the tool steel used for general use or to other materials such as in a situation of corrosion and oxidation at high temperature. This product can be used up to 980ºC regardless of strength loss at approximately 700ºC.

In addition, because of the circular particles of TiC, it has low friction coefficient, resulting in excellent wear resistance after pick-up, galling, chipping, and related phenomena occurring upon contact at high speed or high temperature due to low friction coefficient as friction works are minimized.

14 Characteristic Composition CompostionCrMoAlNiTiC(vol%) Fe (wt%)12.8-0.7Bal43Bal Properties Expansion Ratio (10-6mm·℃-1·mm-1) Density (g/cm3)6.7 45 ~ 49 Annealing 50 ~ 54 Hardening 4.2 20 ~ 90℃ 6.1 20 ~ 537℃ Properties Transverse Rupture Strength TRS(kg/mm2) Compressive Strength(kg/mm2) Impact Strength(mm·kg/mm2)6.72 15 Conductivity(Wattm-1℃) 150 380 Properties
Rockwell "C" Hardness (HRc)

Alloy-TiC FT-5 and Inconel X-750 comparison

Inconel X-750 property comparison

Inconel X-750 is a precipitation reinforcement-type Ni-base superalloy with high temperature strength, corrosion resistance, and oxidation resistance. Its use is for jet engine and rocket components. It can be used up to 700ºC regardless of strength loss at approximately 650ºC.

Comparing the mechanical properties between Alloy-TiC FT-5 and Inconel X-750 as shown in picture 1, Alloy-TiC FT-5 shows 1.7-fold hardness compared to Inconel X-750 at 650ºC; thus, as shown in picture 2, it has 2-fold wear resistance. Therefore, if it is applied to the same extruding die, lifespan is expected to increase 2-fold compared to Inconel.

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Picture 1. Alloy-TiC FT5 and Inconel X-750 high-temperature hardness
Alloy-TiC Ⓡ P / M Alloy Steel Casting RESISTAR Ⓡ HIP Hi-Max Sales Reference Current status of equipped facility
Picture 2. Wear state comparison between Alloy-TiC FT5 and Inconel X-750

Alloy-TiCⓇ Applications

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Crimper Roller Forming Roll Corrector Roll Indent Roller Work Roll Guide Roller
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Bonded dissimilar material
Roter Plate & Roter Pin Seat & Port 단뎀Roller Block Die Nozzle
Alloy-TiC Ⓡ P / M Alloy Steel Casting RESISTAR Ⓡ HIP Hi-Max
Reference
status of equipped facility
Tension Roller
Sales
Current

Powder Metallurgy Alloy Steel

FT-9 FT-10 FT-23

P/M FT-9

Characteristic

FT-9 is an excellent material with excellent wear resistance and toughness by spreading minute carbide evenly after being manufactured with powder alloy method and is adequate for molding during which severe wear occurs. In particular, the product has low heat expansion coefficient and aging change and has high wear resistance that it is highly suitable for semiconductor molding material.

• Spray minute vanadium carbide (VC) uniformly → high toughness and yield strength and good wear resistance

• Minute carbide → easier to reproduce and refurbish than casting high-speed steel(improve by approximately 15%)

• Manufacture into alloy-type powder → prevent one-sided wear and roll marking

• Maintain wear resistance, toughness, and hardness up to 500ºC, minimize crack occurrence

• Similar to casting high-speed steel for heating process conditions, but better with toughness and wear resistance. (improve wear resistance and lifespan by about 30% or more compared to casting high-speed steel)

Composition

20
Compostion C CrMo V Si Fe (wt%)1.855.251.309.000.90Bal
(a) casting high-speed steel (b) FT-9 (a) (b)

Properties

Wear resistance test results

21 Properties Rockwell "C" Hardness(HRc) Modulus of Elasticity(GPa.) Toughness(ft·lb) Transverse Rupture Strength TRS(MPa.) Density (g/cm3) 7.8 25 ~ 29 Annealed 54 ~ 58 Hardened 4,136 47 221
Hardness(HRc) Material type Decrease in volume(mm) FT-10 FT-10 FT-9 FT-9 SKH51(M2) SKD11 A2 SKD61 64.0 60.0 55.0 49.0 65.0 60.0 60.0 51.0 9.0 11.1 14.4 16.3 23.3 41.0 62.6 127.0 (ASTM G65, Method A) Coefficient of thermal expansion Temperature Range(℃)Expansion Coefficient(mm/mm)℃X10-6 20 ~ 100 20 ~ 260 20 ~ 430 20 ~ 540 10.7 11.5 11.8 12.3 Alloy-TiC Ⓡ P / M Alloy Steel Casting RESISTAR Ⓡ HIP Hi-Max Sales Reference Current status of equipped facility

P/M FT-10

Characteristic

FT-10 is a material with excellent wear resistance and toughness by spraying minute carbide uniformly after being manufactured with the powder alloy method, which is adequate for molding during which severe wear occurs. In particular, this product is highly suitable for semiconductor molding material due to low thermal expansion coefficient and aging change extent and high wear resistance.

• Spray minute vanadium carbide (VC) uniformly → high toughness and yield strength with good wear resistance (improve by 50% compared to the SKD11 type)

• Minute carbide → easy for polishing(improve by approximately 15%)

• Manufacture alloy-type powder → prevent one-sided wear and roll marking

• Maintain wear resistance, toughness, and hardness up to 500ºC, minimize crack occurrence

• Low heating process strain and thermal expansion coefficient and low aging change extent(compared to ASSAB ASP23)

• Improve 2-fold compared to casting high-speed steel 3.5-fold compare to SKD11, improve wear resistance and lifespan

• Show same properties with CPM 10V and low cost compared to imported products

Picture 1 shows the minute grain of casting high-speed steel and FT-10. In the case of (a), the size and distribution of carbide are not uniform. In the case of (b), minute VC is distributed uniformly.

Picture 2 shows the cutting edge and wear shape of casting high-speed steel and FT-10.

In the case of (a), minute chipping occurs, which not only makes the cutting surface dull but also wields adverse effects on the cutting surface quality of cut surface matter due to wear phenomena caused by stress.

In the case of (b), the cutting surface is very sharp, and minute chipping does not occur; thus preventing burr, etc. of cut surface matter occur to improve the quality of cutting surface.

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Compostion C CrMo V (wt%)2.455.301.309.75Bal Fe
Composition
Picture 1. Minute grain picture of casting high-speed steel and FT-10 Picture 2. Edge picture of casting high-speed steel and FT-10 (a)Casting high-speed steel (b)FT-10 (a)Casting high-speed steel (b)FT-10

Properties

Wear resistance test results

23 Properties Rockwell "C" Hardness(HRc) Modulus of Elasticity(GPa.) Toughness(ft·lb) Transverse Rupture Strength TRS(MPa.) Density (g/cm3) 7.8 25 ~ 29 Annealed 60 ~ 64 Hardened 610 ~ 630 47 221
Hardness(HRc) Material Type Decrease in volume(mm) FT-10 FT-10 FT-9 FT-9 SKH51(M2) SKD11 A2 SKD61 64.0 60.0 55.0 49.0 65.0 60.0 60.0 51.0 9.0 11.1 14.4 16.3 23.3 41.0 62.6 127.0 (ASTM G65, Method A) Coefficient of thermal expansion Temperature Range(℃)Expansion Coefficient(mm/mm)℃X10-6 20 ~ 100 20 ~ 250 20 ~ 430 20 ~ 590 10.7 11.1 11.8 12.3 Alloy-TiC Ⓡ P / M Alloy Steel Casting RESISTAR Ⓡ HIP Hi-Max Sales Reference Current status of equipped facility

P/M FT-23

Characteristic

FT-23 is a material with outstanding wear resistance, toughness, and strength by spraying minute carbide uniformly after being manufactured with the powder alloy method. In addition, the advantage of this alloy is having low strain during the heating process with good polishing. The alloy is adequate for cooling molding due to high wear resistance and extruding strength.

• Spray minute carbide uniformly → high wear resistance, toughness, and yield strength

• Minute carbide → easy polishing (improve by approximately 15%)

• Manufacture alloy-type powder → prevent one-sided wear and roll mark

• Maintain wear resistance, toughness, and hardness up to 500ºC, minimize crack occurrence

• Low heating process strain and thermal expansion coefficient, low level of aging change extent(compared to ASSAB ASP23)

• Same properties as ASP23 as same powder is imported and ASP23 is used for manufacture

• Lower cost that ASP23 import products

Picture 1 shows the minute grain of casting high-speed steel and FT-23

- In the case of (a), the size and distribution of carbide are not uniform

- In the case of (b), minute carbides are uniformly sprayed

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Composition Compostion C CrMo WV Fe (wt%)1.304.205.006.303.10Bal
Picture 1. Minute grain picture of casting high-speed steel and FT-10 (a)Casting high-speed steel (b)FT-23

P/M Manufacturing Process

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Properties Modules of Elasticity(KSI)31.620 Coefficient of thermal expansion Temperature Range(℃) Expansion Coefficient (mm/mm)℃X10-6 Density (g/cm3) 20 ~ 24 60 ~ 66 Annealing 4020 Hardening 207 8.2 Properties Rockwell "C" Hardness (HRc) Modulus of Elasticity(GPa.) Transverse Rupture Strength TRS(MPa.) 20 ~ 204 20 ~ 315 20 ~ 540 12.0 12.6 13.3
Wear resistance vs. toughness comparison
Manufacturing process Toughness → Wear Resistance → M48 T15 M62 M3:2 FT-23 FT-9 FT-10 SKH51 A2 A7 SKD61 SKD11 Conventional Tool Steel High Speed Steel P/M Steel Alloy-TiC Ⓡ P / M Alloy Steel Casting RESISTAR Ⓡ HIP Hi-Max Sales Reference Current status of equipped facility Tundish High-pressure gas head Atomization tank Powder filling Air gas P/M HSS ingot Hot Forging Hot Forging Hot Forging FULL ANNEALING PEELING P/M HSS ROUND BAR Vacuum sealing Powder Collector Gas atomization

P/M Applications

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Composite Roll Looper Roll Pinch Roll Knife Twist Roller Kocks Mill Roll Nozzle Guide Roller
Alloy-TiC Ⓡ P / M Alloy Steel Casting RESISTAR Ⓡ HIP Hi-Max Sales Reference Current status of equipped facility 27
Screw RDT Roller Crush Roll Shot Blade Paddle Transfer roller LINER Press mold

Casting RESISTARⓇ

RESISTARⓇ

Characteristic

RESISTAR of high-speed steel (HSS) type contains high-cost alloy components (Cr, Mo, W, Ni, Co, V etc.), maintains high wear resistance by minimizing hardness reduction at high temperature, and improves productivity by minimizing damages with its toughness property. In terms of client needs, its hardness is freely controlled, it has excellent performance as verified compared to conventional materials; it can also be exported to nations worldwide. In particular, it shows excellent performance in rolling mill, guide roller, and pinch roller and screw and paddles.

• Excellent mechanical property compared to general high-speed steel

• Increase in productivity due to excellent wear resistance

• Increase in component lifespan due to low grinding amount during reproduction

• Minimize surface pick-up phenomena

• Reduce idle time of changing components due to long lifespan

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Groove abrasion
resistance Strength
proof
cost Improve productivity Upgrade quality
Crack, break Reduction in surface absorption Reduction in maintenance/repair cost Reduction in Re-Grinding thickness
Reduction
Wear
Heat
Reduce
Prevent
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cost Improve productivity Upgrade quality DIC Severe wear Short lifespan Changing time loss WC Weak to impact High price Weak to heat RESISTAR Performance comparison C SiMo VW Co 1.5Mn -4.5 Cr 5.51.09.00.1 Ti 0.1 Ni2.00.6 0.6 MIN MAX 5.5 6.53.012.01.01.01.0 Fe BAL BAL Chemical Composition Technical Date Matrix Density(g/cc) TRS(Kgf/mm2) Elongation(%) 54 - 61 72 - 83 8.15 - 8.33 120 - 130 0.3 - 0.5 320 - 360 90 - 100 70 - 90 2 - 4 30 - 55 42 - 73 7.9 - 8.0 60 - 100 0.2 - 0.4 230 - 270 40 - 60 60 - 80 1 Tensile strength(Kg/mm2)
Performance Hardness HRC Hs High Speed Steel Ductile Cast Iron
® DCI, NCI
strength(Kg/mm2) Hardness Variation of RESISTAR® at high temperature Wear Resistance of Materials Alloy-TiC Ⓡ P / M Alloy Steel Casting RESISTAR Ⓡ HIP Hi-Max Sales Reference Current status of equipped facility
Characteristic Reduce
Toughness
CharacteristicsRESISTAR
Compressive

RESISTARⓇ Applications

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Guide Roller Kocks Mill Roll LINER Sizing Roller Mill Roll Pinch Roll QTB Nozzle Slit Roller Looper Roll

Other Applications

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CAPSTAN Cooling Nozzle Pinch Roll(T.C) Launder Lip Block Mill Roll Danieli Guide & System Leveller Roll
Alloy-TiC Ⓡ P / M Alloy Steel Casting RESISTAR Ⓡ HIP Hi-Max Sales Reference Current status of equipped facility
Welding roll

Hi-Max

Hi-Max Technology

Powder Manufacturing Process

36
Dmax<500μmDmax<140μmDmax<140μm
Technology Development of Hi-Max Powder
CPM-9V Powder (Ref.) Hi-Max Powder Hi-Max Powder (optimized mass production) Hi-Max Powder : Nano size carbide Hi-Max Powder
Gas Atomization
Process
N2
3.1. SEM observation results
pouring tundish crucible Alloy melt melting Atomizing zone Atomizer Chamber GasGas
Gas gas injection nozzle orifice

Hi-Max & FT-9 Characteristics Comparison

Hi-Max & FT-9 Characteristics Comparison

3.2 Microstructure observation results

37 Alloy-TiC Ⓡ P / M Alloy Steel Casting RESISTAR Ⓡ HIP Hi-Max Sales Reference Current status of equipped facility
0~0.25㎛ VC phase quantity : 650EA ↑ 0~0.25㎛ VC phase quantity : 950EA ↑ FT-9 Hi-Max FT-9 Hi-Max Hi-Max mill rolls have lower tendency of dimples and Hair cracks on the roll surface than FT-9 due to fine carbide of uniformed distribution. 3.1. Microstructure observation results : Hi-Max has smaller carbide size

Hi-Max Technology

Hi-Max & FT-9 characteristics comparison

3.3 Low Cycle Fatigue Test Results

Low Cycle Fatigue Condition

• Load : 46, 56 kgf

• Frequency : 2 Hz

• Wave form : Sine

• Stress ratio(R) : 1

• Temperature : RT

• Sample Size : 2.44x2.44x24 (Notch 0.3x0.27)

Low Cycle Fatigue Results : Lower Tendency of Hair Cracks

56kgfFT-9Hi-MaxIncrease (%) 1st 12,19715,57428%↑

Hi-Max & FT-9 characteristics comparison

3.4 Wear Resistance Test : Pin-on Disk

Test Condition

• Load : 10N

• RPM : 622

• Rotation diameter : 11.5mm

• Wear distance : 500m (667sec)

Wear Resistance Test : Hi-Max has 2.6 times higher wear resistance than FT-9

38
Start 1 2 3 Avg. 0.9479 0.9467 0.9452 0.9443 - 0.0012 - 0.0015 - 0.0009 -0.0012 FT-9weight, gweight loss, g Start 1 2 3 Avg. 0.9373 0.9368 0.9363 0.9359 - 0.0005 - 0.0005 - 0.0004 -0.00046 Hi-Maxweight, gweight loss, g

3.1. Microstructure observation results : Hi-Max has smaller carbide size

Comparison with Cast Iron rolls :

Hi-Max mill rolls have 4 - 5 times Longer Lifetime per Groove

Comparison with HSS roll :

Hi-Max mill rolls have 2 - 2.5 longer Lifetime per Groove

Alloy-TiC Ⓡ P / M Alloy Steel Casting RESISTAR Ⓡ HIP Hi-Max Sales Reference Current status of equipped facility
39

HIP (Hot Isostatic Press)

HIP(Hot Isostatic Press)

Characteristic

Advantages of HIP

Maximum pressure

Heater, temperature zone

Maximum temperature

Applied gas

Applied space

What is HIP?

118Mpa(1,200kgf) graphite, region 3 1500℃

Ar(99.99%)

Ø560x1,300(mm)

HIP is equipment using the principle of pressurizing pressure from all directions after high pressure (1,000kg/cm2 ~ 2,000kg/cm2) is formed by gas expansion if temperature is leveled up to high temperature(Max. 2000ºC) after pressurizing constant pressure by using compressor with inert gas in the vessel(high-pressure container).

• Remove inner blowhole

• Reduce production and welding

• Improve production surface

• Lose directional properties

• Reduce defects by maintaining improvements due to high solid-state sintering

• High strength

• Improve mechanical properties

• Sinter or bond difficult in forming member

• Minute grain structure

• Improve fatigue life(2~12 folds)

• Recover scrap components

• Recycle scrap

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HIP maintenance data

Usage of HIP equipment - Sintering

Usage

• Power HSS : difficult to produce by casting

• Iron-type/Non-iron-type alloy

• High melting point metal/ceramic/cermet

• High-purity target

• Complex material

Property

• Minute grain, isostatic property

• Same or better mechanical quality than rolling or forged products

• Available for high-quality component production even for difficult materials to produce

• Manufacture soft shape reducing stress concentration

• Manufacture net or near-net shape to reduce production fee

• Improve fatigue strength

• Bond 2 or more materials by using 1 or 2 or more powder

Usage of HIP equipment - blowhole reduction

Usage

• Hard metal, cermet, ceramic, etc.

• Aluminum alloy, titanium alloy, heat-proof alloy

• Stainless cast product, resin, etc.

Property

• Improved wear resistance and flexural strength by removing air gap and minute blowhole.

• Hard metal in particular with excellent wear resistance is difficult to manufacture without air gap and minute blowhole due to its minute particles and low amount of cobalt.

• Tools, drawing dies, and rolling mills

43
core bar pinching metal powder can
Before HIP Pore After HIP Alloy-TiC Ⓡ P / M Alloy Steel Casting RESISTAR Ⓡ HIP Hi-Max Sales Reference Current status of equipped facility

HIP(Hot Static Press)

Usage of HIP equipment - Diffusion Bonding

Usage

• Products difficult to manufacture with bracing or welding(example) heterojunction between metal and ceramic

• Components with complex 3-dimensional structure

• Bond between hetero metals

• Bond between metal block and powder

• Case of bonding with part of powder

• Manufacture complex material

Applications

Property

• Layer with improved wear resistance and corrosion resistance

• High bonding strength(homo and hetero bond: Metal to metal, ceramics to metal)

• Bonding part: Seamless grain structure

• Mechanical property-uniform minute structure → similar density : Solid, Powder

• Low-process temperature(HIP temperature) : 50~70% of MP flawless: no piece/solid crack

44
assenblyVacuum
Producing partsCapsule
SealingHIPRemoving capsuleFinishing
AI / AI ALLOYINCONEL / INCONELAI / TiWC Co /
Copper/Stainless
Steel
Stainless/Al AlloyTi Alloy HollowNeutron Detector Equipment Cooling plate

Q.A equipment

Scanning electron microscope (SEM, EDS)

• Measurement rate : X5000

• Component analysis : Equipped EDS

Automatic hardness detector (Rockwell)

• Measurement method : Rockwell

• Measurement value : HRc

Nondestructive inspector

• Measurement method : UT

Metallographic microscope

• Measurement rate : X1500

• Manufacturer : Olympus

Hardness device(Rockwell)

• Measurement method : Rockwell

• Measurement value : HRc

Automatic sizing measurer

• Measurement standard : ~ø60mm

• Measurement method

: contact method

Surface profile detector

• Measurement rate : ~50mm

• Measurement method : contact method

• Measurement value : Ra(μm)

projector

• Measurement rate : X10

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Alloy-TiC Ⓡ P / M Alloy Steel Casting RESISTAR Ⓡ HIP Hi-Max Sales Reference Current status of equipped facility

Facility & equipment status

46
Processing equipment Drilling Machine CNC self • Ø900 X 3200 ~ Ø130 X 25015 25 1 1 5 1 2 3 1 2 1 1 1 self • Ø1250 X 5000 ~ Ø400 X 600 Wire cutting equipment • 400 X 750 X 260 Heating furnace with hot air
500 X 600 Brush machine • 750 X 350 Circular grinder • Ø320 X 1050 ~ Ø350 X 150 Milling • 800 X 250 X 410 • 1260 X 650 X 750 Band Saw • 700 X 500 ~ 120 X 240 Plane grinder • Ø500 X 1000 ~ Ø500 X 800 MCT • 1260 X 650 X 750
automatic grinder
Ø200 X 345
CNC

• Ø560 X 1,300

• 600W X 600H X 1300L

• Automatic 105 TON

• Manual 300 TON

• 50 ~ 225kg

• Φ600 X 650

• 550W X 550H X 1200L

• 700W X 600H X 1200L

• Ø500 X 500L

• Ø450 X 450H

• 650W X 650H X 1400L

• Ø600 X 1100

47
Material manufacturing equipment
HIP(Hot Isostatic Press) CIP(Cold Isostatic Press) No. 2 vacuum sintering furnace Oil pressurizer No. 3 vacuum sintering furnace Vacuum hearing furnace No. 1 vacuum sintering furnace Annealing - degassing furnace Applied press infiltration furnace Ball Mill Vacuum annealing furnace
Alloy-TiC Ⓡ P / M Alloy Steel Casting RESISTAR Ⓡ HIP Hi-Max Sales Reference Current status of equipped facility

Certification

Manufacturing method of sintered alloy dispersed with titanium carbide within steel base by canning-hot isostatic pressing

Wear resistance hard alloy steel bond and its manufacturing method

Wear resistance complex materials and engine piston made by the materials and its manufacturing method.

Complex roll for rolling

Materials and components expert business certification

48
Nano diamond with hydrophobic surface and its manufacturing method Cermet and its manufacturing method
Inno-Biz certification
Quality certificationQuality certification
Kore Industrial Technology associational certification
More than 20 Global Patents Registration

200 Domestic Customers110 Overseas Customers

SeAHFS

Dongkuk steel mill

ILJIN

SeAHbesteel

Alloy-TiC Ⓡ P / M Alloy Steel Casting RESISTAR Ⓡ HIP Hi-Max Sales Reference Current status of equipped facility 49
Sales Reference
SeAH CSS
electric HYUNDAI welding
CNS

To make people happy with nanotechnology

Head Office 17-60, Saneopdanji-gil, Myeoncheon-myeon, Dangjin-si, Chungcheongnam-do, Republic of Korea

Hwaseong Plant 711-63, Mannyeon-ro, Jeongnam-myeon, Hwaseong-si, Gyeonggi-do, Republic of Korea

Tel. 041-359-6600 Fax. 041-359-6609 www.millroll.com

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