SURFACTANS FOR COSMETICS & PERSONAL CARE PRODUCTS

SURFACTANS FOR COSMETICS & PERSONAL CARE PRODUCTS Sustainable technologies

EXOLcareline version 2015.1

EXOLcareline TM

PCC EXOL Specialized surfactants used in the production of personal care products and cosmetics.

Surfactant...sounding strange, sophisticated word. Besides, hides so many surprising contents. Accompanies us in everyday life, making them better, healthier, more enjoyable. Surfactants are an integral part of our lives and influence its quality. They are used in composing various goods, being indicators of modern lifestyle. We use them during daily activities such as bathing or relaxing care of body and hair. This is the part of the world of chemistry that surrounds us from all sides, always...

EXOLCARELINE/02

EXOLcareline TM TM

INTRODUCTION

PCC Exol SA was created by merge of PCC Exol SA and Surfactants Business Unit of PCC Rokita SA. The Company’s core scope of operation is the manufacture and sale of surfactants. The company is headquartered in Brzeg Dolny, where is located manufacturing unit of anionic and nonionic surfactants. Moreover, in 2011, there was start-up of new production unit of nonionic surfactants (ethoxylation plant) in Płock. The flexibility of production allows to offer a wide range of anionic and nonionic surfactants according to the current needs of our customers. As one of the leading manufacturers of chemical products, the company is continuing to undertake investment activities with using modern technologies and based on the principle of sustainable development.

Our strategic investor is the German company PCC SE, which operates internationally in three divisions: Chemicals, Energy and Logistics. Today, more than 70 subsidiaries and associated companies working within the PCC Group employ about 2 500 staff in 16 countries. Group strategy is focused on growth and profitability in the core activities as well as on diversification into new segments.

PCC GROUP (Poland)

Chemicals

PCC Consumer Products SA (Warsaw, Poland)

PCC Consumer Product Kosmet Sp. z o.o.

(Brzeg Dolny, Poland)

PCC Prodex Sp. z o.o.

(Warsaw, Poland)

Navigator (Belarus)

Logistics

PCC Exol SA - Brzeg Dolny, Poland - Płock, Poland

PCC Rokita SA (Brzeg Dolny, Poland)

FZ „Czechowice” SA (Czechowice, Poland)

Kosmet Navigator JLtd. (Belarus)

Energy

Tensis Sp. z o.o.

(Brzeg Dolny, Poland)

PCC Synteza SA

PCC Chemax, Inc. (S.C.) (Piedmont, USA)

S.C. EURO URETHANE SRL

PCC Exol Kimya Sanayi (Turkey)

PCC Exol Philippines Inc.

PCC Consumer Products (Russia)

Surfactants offered by our company are widely used in various industries applications. In addition to use in personal care and cosmetics industry, our surfactants are used in different branches such as: household chemicals, textile, agrochemicals, metalworking, oilfield industry, construction industry, paints & coatings, pulp and paper, and the other.

Over the years, PCC Exol has developed core competencies in manufacturing specialty surfactants. We meet our customers’ needs with a unique and versatile product portfolio, a broad expertise in surfactants chemistry and a high degree of flexibility. Through intimate customer relationships and by maximising synergies of customers’ application experience and our chemistry knowledge, we continuously strive to offer tailor-made products and system solutions that contribute to your success. We are continuously expanding our product range with new surfactants, focusing on safe chemistry, friendly to people and environment.

EXOLCARELINE/03

EXOLcareline TM

ESSENTIAL ADDITIVES FOR EVERYDAY PRODUCTS

Personal Care market is rapidly changing. Use of wide range of personal hygiene products is nowdays inextricably linked with our lifestyle. Growing number of new type of formulations requires new range of ingredients ensuring satisfying effect in the formulation and ultimately, safety to the customer.

PCC Exols EXOLcareline range was created, and is continously expanding to enable our clients to create formulations tailor made to market trends and client needs.

ADDITIVES FOR EVERYDAY PRODUCTS

Ceteareth-6

ROKAnol T10

Ceteareth-10

ROKAnol T12

Ceteareth-12

ROKAnol T18

Ceteareth-18

ROKAnol O3

Oleth-3

ROKAnol O18

Oleth-18

Others

• • • • • •

•

•

• • • • • •

• • • •

•

•

•

•

•

•

•

•

• Shaving Cream/Foam

Face Cleansing

Baby Bath Wash

Bath products

• • • • • • • • • • • • • • • •

Liquid Soap

• • • • • •

•

•

•

•

•

•

•

•

•

•

• •

•

•

ROKAnol T6

ROKAnol NL8P4

Baby shampoo

• • • • • • • • •

•

C12-C15 Pareth-7

•

ROKAnol DB7W

•

C12-C15 Pareth-7

•

ROKAnol DB7

•

Deceth-3

-

EXOLCARELINE/04

•

Laureth-10

ROKAnol D3W

•

ROKAnol L10/80

•

Laureth-10

•

Laureth-7

ROKAnol L10

•

ROKAnol L7W

•

Laureth-7 C12-C16 Pareth-7

•

ROKAnol L7A

•

ROKAnol L7

Laureth-4 C12-C16 Pareth-5

•

ROKAnol L5A

•

ROKAnol L4

•

C12-C16 Pareth-3

•

Laureth-3

ROKAnol L3A

•

ROKAnol LK3

•

Laureth-2

•

Laureth-2

ROKAnol LK2A

•

ROKAnol LK2

•

Laureth-1

•

ROKAnol LK1

•

Disodium Laureth-3 Sulfosuccinate

•

Sodium Laureth-3 Sulfate

SULFOSUCCINATE L3/40

•

SULFOROKAnol L370/1

•

Sodium Laureth-3 Sulfate

•

Sodium Laureth-3 Sulfate

SULFOROKAnol L370

•

SULFOROKAnol L327

•

Sodium Laureth-2 Sulfate

•

Sodium Laureth-2 Sulfate

SULFOROKAnol L270/1A

•

SULFOROKAnol L270/1

•

Sodium Laureth-2 Sulfate

•

Sodium Laureth-1 Sulfate

SULFOROKAnol L225/1

•

SULFOROKAnol L170/1

•

Ammonium Lauryl Sulfate

•

Sodium Decyl Sulfate

ROSULFAN A

•

ROSULFAN D

•

Sodium Lauryl Sulfate

Face

•

ROSULFAN L

INCI Name

Body

•

Product

Shampoo

Hair

EXOLcareline TM

ADDITIVES FOR EVERYDAY PRODUCTS

Others

•

•

•

•

Shaving Cream/Foam

Face Cleansing

•

•

•

•

•

•

•

Baby Bath Wash

Bath products

Liquid Soap

Baby shampoo

•

• • • • •

• • • •

•

•

Cetearyl alcohol

ExoAlc 1698 pills

Cetyl alcohol

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

• • • •

•

• •

•

•

•

•

•

•

• •

ExoAlc 1618 pills

•

Sodium Laureth Sulfate, Cocamidopropyl Betaine, Coco-Glucoside

•

EXOcare PC60

•

Sodium Laureth Sulfate, Cocamide DEA, Glycol Distearate

•

EXOpearl

•

Cocamidopropyl Betaine

•

ROKAmina K40HC

•

Cocamidopropyl Betaine

•

ROKAmina K40

•

Cocamidopropyl Betaine

•

ROKAmina K30E

•

Coco Betaine

•

ROKAmina K30B

•

Cocamidopropyl Betaine

•

ROKAmina K30

•

Oleamide DEA

•

ROKAmid RAD

•

Cocamide DEA

•

ROKAmid KAD

•

PEG-8

•

POLIkol 400

•

PEG-6

•

POLIkol 300

•

PEG-4

•

POLIkol 200

•

PEG-20 sorbitan monooleate

•

ROKwinol 80

•

PEG-20 sorbitan monostearate

•

ROKwinol 60

•

Sorbitan monooleate

•

ROKwin 80

•

Sorbitan monostearate

•

ROKwin 60

•

PEG-7 Glyceryl Cocoate

•

ROKAcet KO300G

•

PEG-24 Stearate

•

ROKAcet S24

•

PEG-7 Stearate

•

ROKAcet S7

•

PEG-75 Lanolin

•

ROKAnol LN75/50

•

PPG-5 Laureth-5

•

ROKAnol L5P5

•

PPG-4 Laureth-5

Face

•

ROKAnol L4P5

Body

•

-

•

ROKAnol LP2529

•

-

•

ROKAnol LP2024

•

-

•

ROKAnol LP27

•

INCI Name

•

Product

Shampoo

Hair

EXOLCARELINE/05

EXOLcareline TM

The specific function of the surfactant in the formulation stems from its chemical structure. Portion and structure of hydrophilic and lypophilic parts of surfactant - intrictic for every surface active agent enables classification into different application function. Below table divides main surfactants classes, that form PCC Exol portfolio into funcion it plays in the end product.

ADDITIVES FOR EVERYDAY PRODUCTS

Viscosity Modifier

• •

Foam Booster

• •

Stabilizing Agent

Wetting Agent

Solubilizer

Humectant

Delivery System

•

Emolient

Dispersant

•

W/O Emulsifier

• •

•

•

•

•

• •

•

•

•

•

• • •

•

• •

•

• • •

•

• •

•

• •

•

EXOLCARELINE/06

•

Alcohols

•

Polyoxyethylene Glycols (PEGs)

•

Betaines

O/W Emulsifier

Co-Surfactants

Sorbitan Esters

•

Ethoxylated Fatty Acids

•

Ethoxylated Fatty Alcohols

•

Sulfosuccinates

•

•

Sulfated Ethoxylated Fatty Alcohols

•

Sulfated Fatty Alcohols

•

Product

Base Surfactants

Function in formulation

EXOLcareline TM

PRIMARY SURFACTANTS AND FOAMING AGENTS PRIMARY SURFACTANTS AND FOAMING AGENTS

-

SULFOROKAnol L225/1

68891-38-3

A

Liquid

-

SULFOROKAnol L270/1

68891-38-3

A

Paste/liquid gel

-

SULFOROKAnol L270/1A

68891-38-3

A

Paste/liquid gel

-

SULFOROKAnol L327

125301-92-0

A

Liquid

-

SULFOROKAnol L327/1

13150-00-0

A

Liquid

SULFOROKAnol L370

125301-92-0

A

SULFOROKAnol L370/1

13150-00-0

ROSULfan A

Sodium Laureth Sulfate + 1 EO Sodium Laureth Sulfate + 2 EO Sodium Laureth Sulfate + 2 EO Sodium Laureth Sulfate + 2 EO

68-72

-

•

25-27

-

•

68-72

-

•

68-72

-

•

Sodium Pareth Sulfate + 3 EO

26-28

-

•

-

Sodium Laureth Sulfate + 3 EO

27-29

-

•

Paste/liquid gel

-

Sodium Pareth Sulfate + 3 EO

68-72

-

•

A

Paste/liquid gel

-

Sodium Laureth Sulfate + 3 EO

68-72

-

•

90583-11-2

A

Liquid

-

Ammonium Lauryl Sulfate

ROSULfan D

142-87-0

A

Liquid

-

Sodium Decyl Sulfate

ROSULfan L

85586-07-8

A

Liquid

-

SULFOSUCCINATE L3/40

68815-56-5

A

Liquid

-

N

Liquid

ROKAmid KAD

-

•

35-40

-

•

Sodium Lauryl Sulfate

27.5 – 30.0

-

•

-

Disodium Laureth Sulfosuccinate

min.

25.0

-

-

Cocamide DEA

min.

90.0

-

26-28

Sorbitan esters

Paste/liquid gel

Fatty amines ethoxylated

A

Fatty acid amide ethoxylated

68891-38-3

Polyethylene Glycols

SULFOROKAnol L170/1

Description

Ethoxylated fatty acids

HLB

Betaines

Physical form

Alkoxylated fatty alcohols

Ionic character

Sulphosuccinates

CAS number

Product

Cloud point [˚C], Cloud point Tanaka [˚C]1); SaponiActive fication value2) content [mgKOH/g]; (%) Amine value3) [mgKOH/g]; Hydroxyl value4) [mgKOH/g]

Alkylsulphates

Product group

Alkylethersulphates

Product characteristic

• •

Production of reach and long lasting foam accompanies all hygiene activities and is perceived as a sign of cleansing action. Foamability and stability of foam is related to surfactant structure and is a domain of base surfactants. Products belonging to this class are a basic ingredient of all wash-off formulations and make cleansing products what they are.

EXOLCARELINE/07

EXOLcareline TM

SECONDARY SURFACTANTS AND EMULSIFIERS SECONDARY SURFACTANTS AND EMULSIFIERS

Description

68815-56-5

A

Liquid

-

Disodium Laureth Sulfosuccinate

min.

25.0

-

ROKAmina K30

-

Amph

Liquid

-

Cocamidopropyl Betaine

29-32

-

•

ROKAmina K30B

-

Amph

Liquid

-

Coco Betaine

29-32

-

•

ROKAmina K30E

-

Amph

Liquid

-

Cocamidopropyl Betaine

29-32

-

•

ROKAmina K40

-

Amph

Liquid

-

Cocamidopropyl Betaine

min.

37.0

-

•

ROKAmina K40HC

-

Amph

Liquid

-

Cocamidopropyl Betaine

min.

37.0

-

•

ROKAnol C7

68213-23-0

N

Liquid

11.9

Alcohols, C1218 + 7 EO

min.

95.5

106-112 4)

•

ROKAnol DB3

68131-33-5

N

Liquid/ Paste

7.8

Alcohols, C1215 + 3 EO

min.

99.7

164-172 3)

•

ROKAnol DB5

68131-33-5

N

Liquid

10.2

Alcohols, C1215 + 5 EO

min.

99.5

65-72 D

•

ROKAnol DB7

68131-39-5

N

Liquid/ Paste

12.0

Alcohols, C1215 + 7 EO

min.

99.5

100-114 3)

•

ROKAnol DB7W

68131-39-5

N

Oily liquid

12.0

Alcohols, C1215 + 7 EO

min.

90.0

100-114 3)

•

min.

99.5

50-57 A

•

min.

99.0

78-85 A

•

min.

99.0

43-48 E

•

min.

99.0

60-65 E

•

min.

99.0

51-56 A

•

SULFOSUCCINATE L3/40

ROKAnol NL6

68439-45-2

N

Liquid

12.3

ROKAnol NL8

68439-45-2

N

Liquid

13.8

ROKAnol UD3

127036-24-2

N

Liquid

8.7

ROKAnol UD5

127036-24-2

N

Liquid

11.0

ROKAnol UD7

127036-24-2

N

Liquid

12.3

Alcohols, C911, branched and linear + 6 EO Alcohols, C911, branched and linear + 8 EO Alcohols, C11, branched + 3 EO Alcohols, C11, branched + 5 EO Alcohols, C11, branched, + 7 EO

EXOLCARELINE/08

•

Sorbitan esters

HLB

Fatty amines ethoxylated

Physical form

Fatty acid amide ethoxylated

Ionic character

Polyethylene Glycols

CAS number

Product

Ethoxylated fatty acids

Betaines

Alkoxylated fatty alcohols

Sulphosuccinates

Cloud point [˚C], Cloud point Tanaka [˚C]1); SaponiActive fication value2) content [mgKOH/g]; (%) Amine value3) [mgKOH/g]; Hydroxyl value4) [mgKOH/g]

Alkylsulphates

Product group

Alkylethersulphates

Product characteristic

EXOLcareline TM

Differentiation of products and obtaining specific applications and aesthetic properties is achieved through use of co-surfactants. Application of secondary surfactant can have a synergistic effect on foaming, foam stability, rheology building properties and improve mildness of the formulation.

Dispersion of hydrophobic ingredients in water solution is achieved through application of surface tension reducers.

Emulsifiers arrange themselves at the water/oil interfaces and allow solubilization of oils.

SECONDARY SURFACTANTS AND EMULSIFIERS

Description

ROKAnol LK2

68439-50-9

N

Liquid

6.3

Alcohols, C1214 + 2 EO

min.

99.7

192-204 4)

•

ROKAnol LK2A

68439-50-9

N

Liquid

6.2

Alcohols, C1216 + 2 EO

min.

99.9

196-204 4)

•

ROKAnol LK3

68002-97-1

N

Liquid/ Paste

8.0

Alcohols, C1214 + 3 EO

min.

99.5

165-173 4)

•

ROKAnol L7

103819-01-8

N

Liquid

12.9

Alcohols, C1214 + 7 EO

min.

99.5

30-40 C

•

ROKAnol L7A

68551-12-2

N

Liquid

12.9

Alcohols, C1216 + 7 EO

min.

99.5

56-62 A

•

ROKAnol L7W

103819-01-8

N

Liquid

12.9

Alcohols, C1214 + 7 EO

89-92

30-40 C

•

ROKAnol L3A

68551-12-2

N

Liquid

8.0

Alcohols, C1216 + 3 EO

min.

99.5

53-55 E

•

ROKAnol L4

68002-97-1

N

Liquid

10.0

Alcohols, C1214 + 4 EO

min.

99.5

59-63 E

•

ROKAnol L10

68551-12-2

N

Paste

13.8

Alcohols, C1216 + 10 EO

min.

99.7

59-63 C

•

ROKAnol L10/80

6540-99-4

N

Viscous liquid

13.8

Alcohols, C1214 + 10 EO

min.

80.0

59-63 C

•

ROKAnol L22

68551-12-2

N

Wax

17.0

Alcohols, C1214 + 22 EO

min.

99.7

46-52 4)

•

ROKAnol LN75/50

61790-81-6

N

Viscous liquid

17.8

Lanolin + 75 EO

48-52

-

•

ROKAnol LN75K

61790-81-6

N

Solid

17.8

Lanolin + 75 EO

min.

99.0

-

•

ROKAnol O3

9004-98-2

N

Liquid

min.

99.0

37-41 E

•

ROKAnol O18

9004-98-2

N

Paste

min.

99.0

70-74 C

•

ROKAnol T10

68439-49-6

N

Wax

min.

99.5

85-95 4)

•

Alcohols, C1618 unsaturated + 3 EO Alcohols, C1615.6 18 unsaturated + 22 EO 6.6

11.7

Alcohols, C1618, + 10 EO

EXOLCARELINE/09

Sorbitan esters

HLB

Fatty amines ethoxylated

Physical form

Fatty acid amide ethoxylated

Ionic character

Polyethylene Glycols

CAS number

Product

Ethoxylated fatty acids

Betaines

Alkoxylated fatty alcohols

Sulphosuccinates

Cloud point [˚C], Cloud point Tanaka [˚C]1); SaponiActive fication value2) content [mgKOH/g]; (%) Amine value3) [mgKOH/g]; Hydroxyl value4) [mgKOH/g]

Alkylsulphates

Product group

Alkylethersulphates

Product characteristic

EXOLcareline

SECONDARY SURFACTANTS AND EMULSIFIERS

HLB

Description

ROKAnol T12

68439-49-6

N

Wax

13.5

Alcohols, C1618, + 10 EO

min.

99.5

85-100 A

•

ROKAnol T18

68439-49-6

N

Wax

16.3

Alcohols, C1618, + 18 EO

min.

99.0

74-77 C

•

ROKAnol T6

68439-49-6

N

Wax

10.0

Alcohols, C1618, + 6 EO

min.

99.5

105-115 4)

•

ROKAcet S7

9004-99-3

N

Paste

10.6

Stearate + 7 EO

min.

99.0

92-97 2)

•

ROKAcet S24

9004-99-3

N

Wax

15.8

Stearate + 24 EO

min.

99.0

40-45 2)

•

Glycerides, coco monoand di-, ethoxylated

min.

99.0

90-100 2)

•

Alcohols

Physical form

Sorbitan esters

Ionic character

Fatty amines ethoxylated

CAS number

Product

Fatty acid amide ethoxylated

Polyethylene Glycols

Ethoxylated fatty acids

Betaines

Alkoxylated fatty alcohols

Sulphosuccinates

Cloud point [˚C], Cloud point Tanaka [˚C]1); SaponiActive fication value2) content [mgKOH/g]; (%) Amine value3) [mgKOH/g]; Hydroxyl value4) [mgKOH/g]

Alkylsulphates

Product group

Alkylethersulphates

Product characteristic

ROKAcet KO300G

68201-46-7

N

Liquid

-

ROKwin 60

1338-41-6

N

Solid

4.7

Sorbitan monostearate

min.

99.0

145-160 2)

•

ROKwinol 60

9005-67-8

N

Liquid

PEG-20 sorbi14.9 tan monostearate

min.

99.0

15-55 2)

•

ROKwin 80

1338-43-8

N

Liquid

4.3

Sorbitan monooleate

min.

99.0

145-170 2)

•

ROKwinol 80

9005-65-6

N

Liquid

PEG-20 15.0 sorbitan monooleate

min.

99.0

45-55 2)

•

ExoAlc 1618 pills

67762-27-0

N

Solid in pills form

-

Alcohols, C1618 (30/70)

min.

99.0

210-220 4)

•

ExoAlc 1698 pills

36653-82-4

N

Solid in pills form

-

Alcohol C16

min.

99.0

228-233 4)

•

EXOLCARELINE/10

EXOLcareline

THICKENERS AND RHEOLOGY MODIFIERS

For some products, due to composition of surfactant system and/or specific requirements of the formulation use of special thickeners is required. The example could be delicate formulations like baby care products, where low concentration of sodium chloride and Sulfate free formulations are a market standard.

Rheology modifying products find an application where high viscosity of the formulation is required in order to achieve desirable effect. These are perlizers, capsule or shimmer suspensions and soap dispensers.

THICKENERS AND RHEOLOGY MODIFIERS – PRODUCT LIST

Alcohols

Sorbitan esters

Fatty amines ethoxylated

Fatty acid amide ethoxylated

Polyethylene Glycols

Ethoxylated fatty acids

Betaines

Alkoxylated fatty alcohols

Sulphosuccinates

Cloud point [˚C], Cloud point Tanaka [˚C]1); SaponiActive fication value2) content [mgKOH/g]; (%) Amine value3) [mgKOH/g]; Hydroxyl value4) [mgKOH/g]

Alkylethersulphates

Product group

Alkylsulphates

Product characteristic

CAS number

Ionic character

Physical form

HLB

Description

ROKAnol LK2

68439-50-9

N

Liquid

6.3

Alcohols, C1214 + 2 EO

min.

99.7

192-204 4)

•

ROKAnol LK2A

68439-50-9

N

Liquid

6.2

Alcohols, C1216 + 2 EO

min.

99.9

196-204 4)

•

ROKAnol LK3

68002-97-1

N

Liquid/Paste

8.0

Alcohols, C1214 + 3 EO

min.

99.5

165-173 4)

•

ROKAcet K7

61791-29-5

N

Liquid

11.6

Cocoate + 7 EO

min.

99.0

104-112 4)

•

ROKAcet R40

61791-12-6

N

Paste

13.0

Castor oil + 40 EO

min.

99.0

55-64 4)

•

ROKAmid KAD

-

N

Liquid

-

Cocamide DEA

min.

99.0

-

•

ROKAmid RAD

68603-38-3

N

Liquid

-

Oleamide DEA

min.

90.0

-

•

ROKwin 60

1338-41-6

N

Solid

4.7

Sorbitan monostearate

min.

99.0

145-160 2)

•

ROKwinol 60

9005-67-8

N

Liquid

14.9

PEG-20 sorbitan monostearate

min.

99.0

15-55 2)

•

ROKwin 80

1338-43-8

N

Liquid

4.3

Sorbitan monooleate

min.

99.0

145-170 2)

•

ROKwinol 80

9005-65-6

N

Liquid

15.0

PEG-20 sorbitan monooleate

min.

99.0

45-55 2)

•

ExoAlc 1618 pills

67762-27-0

N

Solid in pills form

-

Alcohols, C1618 (30/70)

min.

99.0

210-220 4)

•

ExoAlc 1698 pills

36653-82-4

N

Solid in pills form

-

Alcohol C16

min.

99.0

228-233 4)

•

Product

EXOLCARELINE/11

EXOLcareline

WETTING AGENTS AND OTHER ADDITIVES

Activity in lowering surface tension between solids and liquids is achieved by application of wetting agents. This is necessary in various types of formulations such as shampoos or colourisation compositions. Better spreading of the dying product on hair ensures good pigment distribution and better final effect. From the other side, good hair wetting efficiency results in satisfying washing and supplementation as well if applied in hair care products.

WETTING AGENTS AND OTHER ADDITIVES – PRODUCT LIST

Paste

-

ROKAnol D3W

68002-97-1

N

Liquid

8.6

Alcohol C10 + 3 EO

min.

90.0

190-205 4)

•

ROKAnol NL8P4

154518-36-2

N

Liquid

9.5

Alcohols, C911-iso, C10rich + EO/PO

min.

99.0

38-48 A

•

ROKAnol LP2024

37251-67-5

N

Liquid

6.3

Alcohols, C10 + EO/PO

min.

99.0

20-24 A

•

ROKAnol LP2529

68551-13-3

N

Liquid

3.5

Alcohols, C1215 + EO/PO

min.

99.0

25-29 A

•

ROKAnol LP27

68439-51-0

N

Liquid

6.0

Alcohols, C1214 + EO/PO

min.

99.0

27-31 A

•

ROKAnol L4P5

68439-51-0

N

Liquid

5.3

Alcohols, C1214 + EO/PO

min.

99.0

98-108 4)

•

ROKAnol L5P5

68439-51-0

N

Liquid

6.0

Alcohols, C1214 + EO/PO

min.

99.0

27-31 A

•

POLIkol 200

25322-68-3

N

Liquid

-

Polyoxyethylene glycol

min.

99.0

530-590 4)

•

POLIkol 300

25322-68-3

N

Liquid

-

Polyoxyethylene glycol

min.

99.0

360-390 4)

•

POLIkol 400

25322-68-3

N

Liquid

-

Polyoxyethylene glycol

min.

99.0

270-300 4)

•

EXOLCARELINE/12

•

Sorbitan esters

•

-

EXOpearl

Fatty amines ethoxylated

-

-

Sodium Laureth Sulfate, Cocamide DEA, Glycol Distearate

Fatty acid amide ethoxylated

min. 40 % (dry matter)

Polyethylene Glycols

Description

Ethoxylated fatty acids

HLB

Betaines

Physical form

Alkoxylated fatty alcohols

Ionic character

Sulphosuccinates

CAS number

Cloud point [˚C], Cloud point Tanaka [˚C]1); SaponiActive fication value2) content [mgKOH/g]; (%) Amine value 3) [mgKOH/g]; Hydroxyl value4) [mgKOH/g]

Alkylsulphates

Product

Product group

Alkylethersulphates

Product characteristic

EXOLcareline

BETAINES

Betaines are surfactants belonging to a class of amphoteric surface active agents displaying excellent skin mildness profile, very good foam characteristics and viscosity building properties.

A combination of favourable application parameters like abundant foam formation, compatibility with a wide range of surfactant systems and an increased safety made betaines one of the most widely used surfactants in all wash-off applications.

Following market trends and an ever-growing interest in surfactants displaying mildness to skin and efficiency in cosmetic formulations, Rokamina product range was developed.

A cutting edge technology applied by PCC Exol in the production process allows achieving unparalleled quality parameters that meet the highest standards of customer safety.

Function in formulation

Application

Co-surfactants

Baby Shampoo

Foam booster

Liquid Soap

Viscosity modifier

Bubble Baths

Shampoo

Mild Shower Gels Baby Bath Wash Face Cleansing Shaving Cream/Foam

Added value in formulating

Benefits

Reduces irritancy of surfactants

Foam boosting

Good skin compatibility in combination with anionic surfactants

Hair and skin conditioning effects

Mild surfactant (cleansing effect)

Better skin feel, soft and smooth Richer and more luxurious foam High performance viscosity builder in Ether sulfate based formulations

EXOLCARELINE/13

Exceptionally effective viscosity increasing agent (highly responsive to salt) Readily biodegradable Compatible with anionic cationic amphoteric and nonionic surfactant

EXOLcareline

PCC EXOL SA has developed two classes of betaines surfactants: Cocamidopropyl Betaines and Coco-Betaine whose parameters are summarized in the below table.

Rokamina K30, K30E, K40, and K40HC belong to the same chemical class, whereas Rokamina K30B is a single representative of another class. The single thing in common for Rokamina K30B, K30E and K40HC is their supreme purity making them suitable for all products where the sensitiveness of the product is paramount. These products find application in: - cosmetics for babies, - dermocosmetics, - high quality cosmetics.

INCI

Active matter (%)

Physical state

pH*

Surface tension (mN/m)

ROKAmina K30

Cocamidopropyl Betaine

29-32

Liquid

5.0-7.0

31

Free

76.3%

Market Benchmark

ROKAmina K30E

Cocamidopropyl Betaine

29-32

Liquid

4.0-5.5

28

Sodium benzoate

76.3%

Supreme Quality

ROKAmina K30B

Coco Betaine

29-32

Liquid

4.5-7.5

30

Free

Expected to be biodegradable based on the literature data

Supreme Quality

ROKAmina K40HC

Cocamidopropyl Betaine

37-42

Liquid

4.5-5.5

25

Free

76.3%

Supreme Quality

ROKAmina K40

Cocamidopropyl Betaine

37-42

Liquid

4.5-5.5

28

Free

76.3%

Market Benchmark

Product name

* 1% solution **According EU ECC C.4-E Closed Bottle Test

EXOLCARELINE/14

Preservative Biodegradability**

Purity

EXOLcareline

THICKENING PROPERTY

Addition of betaines to a standard anionic surfactant system not only optimizes a viscosity profile and a response to salt but also improves cleansing power and mildness of the final formulation.

A synergistic effect of an anionic surfactant-betaines system gives a formulator a powerful tool in creating value added formulations.

Viscosity building properties of a surfactant system comprising of Sodium Laureth Sulfate and different Betaines types was plotted on the below graph as a function of salt concentration.

Basic Formulation Sulforokanol L270/1 (Sodium Laureth Sulfate, 70%)

13%

Rokamina (K30B, K30E, K40HC) (Coco-Betaine, Cocamidopropyl Betaine)

8%

NaCl

1-3%

Water

up to 100%

Thickening ability 35000

30000

Viscosity, cP

25000

20000

15000

10000

5000

0 1.0%

1.2%

1.4%

1.6%

1.8%

2.0%

2.2%

2.4%

2.6%

2.8%

3.0%

% NaCl Rokamina K30B

Rokamina K40HC

Rokamina K30E

Reference, Coco-Betaine, 30%

Reference, Cocamidopropyl Betaine, 40%

Reference, Cocamidopropyl Betaine, 30%

EXOLCARELINE/15

EXOLcareline

FOAMING CAPABILITY

There is a wide possibility to formulate products that are characterized by outstanding foam using blends of anionic and amphoteric surfactants. It also implies that the surfactant system has different foam properties than the anionic alone.

This explains why betaines are so commonly used in personal care formulation. They improve foam - an attribute that is very important to the consumer.

Determination of the foaming capability was preformed according to PN-ISO 696:1994 (the modified Ross-Miles method) for the betaines solutions with a concentration of 1.0 g/l in distilled water at a temperature of 25째C.

Foaming capability in distilled water for betaines

Rokamina K40HC

300 s 180 s Rokamina K30B 30 s

Rokamina K30E

250

260

270

280

290

300

310

320

330

340

Foam volume [ml]

Foaming capability in hard water for betaines

Rokamina K40HC

300 s 180 s Rokamina K30B 30 s

Rokamina K30E

0

50

100

150

200

Foam volume [ml]

EXOLCARELINE/16

250

300

350

EXOLcareline

The foaming property of a basic formulation is shown in a graph below.

Basic Formulation Sulforokanol L270/1 (Sodium Laureth Sulfate, 70%)

13%

Rokamina (K30B, K30E, K40HC), (Coco-Betaine, Cocamidopropyl Betaine)

8%

NaCl

1.4-2.6%

Water

up to 100%

Foaming capability for basic formulation with Coco-Betaine

Reference product, 30%

300 s 30 s Rokamina K30B

240

250

260

270

280

290

300

310

Foam volume [ml]

Foaming capability for basic formulation with Cocamidopropyl Betaine

Reference product, 40%

Rokamina K40HC 300 s 30 s

Reference product, 30%

Rokamina K30E

240

250

260

270

280

Foam volume [ml]

EXOLCARELINE/17

290

300

310

EXOLcareline

SURFACE TENSION

Surface tension according to PN-EN 14370:2004, determined with a use of the Wilhelmy plate method, at a temperature of 25°C, concentration of 0.1%.

Surface tension [mN/m] Product name Demineralized water

Hard water (17°d)

ROKAmina K30E

28

28

ROKAmina K30B

30

30

ROKAmina K40HC

25

25

Pure water has a relatively high surface tension at room temperature (~72.4 mN/m) and hence cleans poorly. In the cleaning process, surface tension must be reduced so water can spread and wet surfaces. Addition of a surfactant decreases the surface tension and consequently increases solubilisation. Surfactants are said to make water “wetter”. The lower the surface tension the better the wettability, hence the ability to dissolve and remove residues.

WETTING CAPABILITY

In a large number of applications (especially for shampoos) the capability of effective wetting is a desirable property of surfactants. The shorter the time of wetting the better the wetting and cleaning agent. The capability of wetting a cotton fabric was determined according to EN 1772:2001.

The wetting time (time in seconds necessary for wetting the textile material) was measured for a betaines solution with concentration of 1.0 g/l, 2.0 g/l and 5.0 g/l in deionized water at a temperature of 20°C.

Rokamina K40HC

5.0 g/l Rokamina K30B

2.0 g/l 1.0 g/l

Rokamina K30E

0

50

100

150

200

Wetting time [s]

EXOLCARELINE/18

250

300

350

EXOLcareline

EXAMPLE FORMULATIONS Cleansing gel Sulforokanol L270/1 (Sodium Laureth Sulfate, 70%)

13.00 %

Rokamina K40HC (Cocamidopropyl Betaine)

6.00%

Rokamid KAD (Cocamide DEA)

1.50%

Rokacet KO300G (PEG-7 Glyceryl Cocoate)

0.30%

Glycerine

2.50%

Citric acid

0.50%

EDTA

0.20%

NaCl

1.20%

Water

74.30%

Viscosity, cP

~7 400

Liquid hand soap Sulforokanol L270/1 (Sodium Laureth Sulfate, 70%)

13.00 %

Rokamina K30B (Coco-Betaine)

6.00%

Rokanol LN75/50 (PEG-75 Lanolin)

3.00%

Rokamid KAD (Cocamide DEA)

2.00%

EDTA

0.10%

Urea

1.00%

NaCl

1.00%

Demineralized Water Viscosity, cP

73.90% 2 000 - 3 000

Shampoo Sulforokanol L270/1 (Sodium Laureth Sulfate, 70%)

13.50 %

Rokamina K30B (Coco-Betaine)

6.00%

Rokamid KAD (Cocamide DEA)

1.50%

EDTA

0.10%

Citric acid

0.05%

NaCl

1.00%

Water

77.85%

Viscosity, cP

~6 100

EXOLCARELINE/19

EXOLcareline

EXOcare PC60 MULTIFUNCTIONAL SURFACTANTS BLEND FOR COSMETIC CLEANSING FORMULATION

EXOcare PC60 was developed to meet expectations of our customers for universal and cost effective product in the area of personal care applications.

Carefully selected and formulated blend of Alkyl Glucoside, Cocamidopropyl Betaine and Laureth Sulfate gave a unique product suitable as a primary surfactant for all cleansing applications.

Laureth-2 Sulfate Cocamidopropyl Betaine Alkyl Glucoside

Favorable dermatological properties, excellent foaming and thickening properties make EXOcare PC60 surfactant of choice where mildness and outstanding performance in final formulation is required. The product was formulated in a form of a viscous liquid ensuring ease of handling and formulation into a final preparation whether shampoo, shower gel, bubble bath or any other skin and hair cleansing product.

Product Specifications: Active Substance, (m/m)

60-63%

Apperance (20-25°C)

Paste

Anionic Substance, (m/m)

42-45%

Color

Colorless to Light Yellow

Specific Gravity

0.9-1.19 g/ml at 20°C

Water Solubility

Completely Soluble

pH(a)

10.0-11.5

Viscosity, cP

3000 – 8000 Brookfield

(a) 10% Aqueous Solution

Viscosity Profile EXOcare PC60: Water 6000

Viscosity, cP

5000

4000

3000

2000

1000

0 10:90

20:80

30:70

EXOcare PC60: Water

EXOLCARELINE/20

40:60

EXOLcareline

Viscosity Profile 20째C vs Salt Concentration (EXOcare PC60:Water 30:70) 35000

30000

Viscosity, cP

25000

20000

15000

10000

5000

0 0.00

0.50

1.00

2.00

1.50

% NaCl

Viscosity Profile 20째C vs Salt Concentration (EXOcare PC60:Water 30:70) 35000

30000

Viscosity, cP

25000

20000

15000

10000

5000

0 0.00

0.50

1.00

1.20

1.40

% NaCl

EXOLCARELINE/21

1.50

2.00

EXOLcareline

Example Formulation: Liquid Shampoo: PCC Exol recommends to use EXOcare PC60 in the concentration ranging from 20-30% (w/w). The exact dose of our product depends on the individual characteristics of the product, that formulator would like to achieve.

Part A: Demineralized Water Citric Acid DiSodium EDTA

60% 0.05% 0.1%

Part B: Demineralized Water 11% Rokacet KO300G 0.6% ExoAlc 1698 1.1%

Part C: EXOcare PC60

25%

Part D: Natural Extracts Colors

0.35% 0.09%

Part E: Sodium Chloride

1.55%

Procedure: Add demineralized water to the mixing kettle. Begin mixing. Add remaining part A. Heat the mixing kettle contents to 77-79°C. Add part B Ingredients to the mixing kettle. Reduce mixer speed, Mix until uniform. Maintain temperature at 77-79°C. Once the batch is uniform, turn off the heat. Cool the batch to 42-47°C. Premix and separately add ingredients from part D. Add part E – mix until uniform and cool to 30-35°C

pH

Viscosity (Brookfield S34, 4 RPM)

6

7500 cP

Product parameters:

The given data are suggestions without any guarantee aimed to support customers’ development. PCC Exol doesn’t assume any liability or risk involved in the use of its products as the conditions of use are beyond its control. The information on product specification provided in this document is binding to the extent confirmed in a written sales agreement.

EXOLCARELINE/22

EXOLcareline

NOTES FOR GUIDANCE CONCERNING THE FUNCTIONAL PARAMETERS AND NOTATION USED IN THE CATALOGUE HLB

The Hydrophilic-Lipophilic Balance (HLB) is a parameter defining the ratio of the content of the hydrophilic and hydrophobic group of the molecule. The HLB range for non-ionic surfactants is between 0 and 20 and expresses the percentage of the hydrophilic part of the molecule.

HLB by Griffin:

HLB=20 *

molecular weight of hydrophilic part molecular weight of the product

HLB for ester-type compounds (ethoxylated fatty acids):

HLB=20 * (1 - SV ) AV where: SV AV - acid value of acids subjected to ethoxylation in mgKOH/g HLB value

Content of EO in product %

Product application

1-3

5-15

Antifoamer

4-6

20-30

W/O emulsifier

7-11

35-55

Wetting agent

8-18

40-90

O/W emulsifier

10-15

50-75

Detergent

10-18

50-90

Solubilizer

Cloud point

An indicator determining the behaviour of nonionic surfactants (obtained in the process of condensation with ethylene oxide) in water or in mixtures consisting of water and organic solvents.

In water or in mixtures of water and organic solvents, solutions of surfactants become cloudy at certain temperaturewhen heated. The process is reversible and the substance becomes clear when cooled is referred to as the cloud point.

Depending on the temperature at which the solution becomes cloudy, there are five methods of determination of cloud point: Method A – aqueous solution (10-90°C) Method B – 50 g/l NaCl solution (>90°C) Method C – 100 g/l NaCl solution (>90°C) Method D – 5 g + 45 g of 25% butyldiglycol / aqueous solution (<10°C) Method E – 5 g + 25 g of 25% butyldiglycol / aqueous solution (<10°C)

EXOLCARELINE/23

EXOLcareline

REACH

Regulation deals with the safe use of chemicals by Registration, Evaluation and in some cases Authorization and restriction of trade in some Chemicals.

REACH Regulation has already come into force. It is considered one of the greatest and most complex legal acts ever implemented in Europe. Not only did it cause significant changes in the polish chemical industry, but it also affects the activity of other users of chemicals and it obliges them to take appropriate actions.

REACH package is designed to broaden our knowledge about the chemical substances we use, oblige the manufacturersto prove that the chemical substance is safe for use and even prohibit the use of the most hazardous chemicals.

PCC Exol SA, as a large chemical company, will meet this new challenge. Not only we do provide declarations that we have already pre-registered and registered the substances we manufacture and distribute, but we also actively participate in Substance Information Exchange Forum (SIEF) and form consortia with other chemical companies with a view to joint submission of registration dossier. We are the exclusive representative of the chemical manufacturers in UE Community and we are in constant contact with our suppliers and customers.

According to Regulation (EC) No. 1907/2006 (REACH), the manufacture or import of chemical substances in volumesexceeding 1 ton per year must be registered at the European Chemicals Agency (ECHA) in Helsinki. REACH registration is related to substances and not products, e.g. preparations/formulations of substances. Production, import and marketing of a REACH-substance will be restricted to those uses evaluated in its registration dossier. The REACH process starts with preregistration (1st June 2008 until 1st December 2008), which ensures the availability of preregistered substances to the registration date. The date of registration depends on the production volume of the substance and lies between 2010 and 2018. We confirm that we will, pursuant to REACH requirements, pre-register all substances manufactured by PCC Exol SA Functional Chemicals Division in the EU or imported in the EU, that are relevant for the products listed in this brochure.

However, no guarantee can be given that PCC Exol SA will offer all listed products in the future, if REACH registration requirements lead to unacceptable costs, PCC Exol SA will contact its customers to find an appropriate solution.

EXOLCARELINE/24

EXOLcareline EXOLcareline TM

CERTIFICATES & PROGRAMS CERTIFICATES EXOLcareline TM

EXOLcareline TM EXOLcareline TM

CERTIFICATES CERTIFICATES CERTIFICATES

IPPC/IED – Integrated Pollution Prevention and Control – integrated approvals since 2007 (IPPC directive - EU directive - for the integrated avoidance and reduction of environmental contamination)

IPPC – Integrated Pollution Prevention and Control – integrated approvals since 2007 (IPPC directive - EU directive - for the integrated avoidance and reduction of environmental contamination) EN ISO 14001

ISO 14001

IPPC 14001 – Integrated Pollution Prevention and Control – management integrated approvals since 2007 certification (IPPC direcEN ISO – (European environmental standard) since 2011

CERTYFIKAT

ENN ISO 9001tive

ISO

- EU directive - for the integrated avoidance and reduction of environmental contamination)

9001:2008 CERTYFIKAT

IPPC – Integrated Pollution Prevention and Control – integrated approvals since 2007 (IPPC direcCESIO/CEFIC membership EN ISO – Integrated Pollution Prevention and Control – integrated approvals since 2007 (IPPC directive -IPPC EU directive - for14001 the integrated avoidance and reduction of environmental contamination) tive - EU directive - for the integrated avoidance and reduction of environmental contamination)

ISO 14001

CERT YF IK AT

ISO 14001

ISO 14001

CERT YF IKAT

ENN ISO 9001 – (European quality management standard) certification since 2011

RSPO membership (2-0327-12-000-00)

EN ISO 14001 ENN ISO 9001 ISO 9001:2008 EN ISO 14001

CERT YF IK AT

CERT YF IKAT

ISO

ENN ISO 9001 CESIO/CEFIC membership

es

CLP 9001:2008 Regulation - Regulation (EC) No. ISO 1272/2008 ENN 9001 of the European Parliament and of the Council as of 16th December C E R T Y F I K AISO T es, amending and repealing Directives 67/548/EEC 9001:2008 CERT YF IKAT and 1999/45/EC, and amending Regulation (EC) No. 1907/2006.

CESIO/CEFIC membership

CESIO/CEFICRSPO membership membership (2-0327-12-000-00)

The regulation entered into force 20 days after its publication, i.e. on January 20, 2009. From this moment, Title XI of the CESIO/CEFIC membership dous Substances Directive was transferred to Table 3.2. in Attachment VI to the CLP Regulation.

RSPO membership (2-0327-12-000-00) RSPO membership (2-0327-12-000-00) RSPO membership (2-0327-12-000-00) es

SA participates actively in implementing the CLP Regulation. We classify chemicals encompassed by the above PCC Exol SA legal status perform changes in data sheets andNo. on labels within the CLPand Regulation - Regulation (EC) 1272/2008 ofr the European Parliament and of the Council as opean Chemicals Agency. es, amending and repealing

of 16th December Directives 67/548/EEC es Qualityand Management Systems 1999/45/EC, and amending Regulation (EC)knowledge.

No. 1907/2006. esapplication and basic paramThe information included in this publication reflects our up-to-date It describes the CLP Regulation - Regulation (EC) as No. 1272/2008 of reserve the European Parliament and ofasthe Council as of 16th December eters products, and is given estimate We right makerequirements, any changes a result of technological S of the ince our operations are conducted in values. full compliance withthe legal and other including environmental reUN Global Compact - tomembership since 2013 The regulation entered into 20 days after publication, i.e. on January 20, 2009.Directives From moment, Title XI of the progress or developments.

CLP Regulation - Regulation No.force theits European Parliament of the Council as of this 16th December es, amending and repealing 67/548/EEC quirements, the design, production(EC) and sale of1272/2008 large volumes of of specialist, often unique, chemical and products for further processdous Substances es,and amending and repealing Directives 67/548/EEC and 1999/45/EC, andnotamending Regulation (EC) specifi No. 1907/2006.

The data should be interpreted as guaranteed cuseful. product qualities.

The health currently environmental system and environmental management system prove very These areVI two systems, integrated, requirements, which enable Directive was transferred to Table 3.2. inNo. Attachment to the CLP Regulation. and 1999/45/EC, and amending Regulation (EC) 1907/2006. as well as user safety instructions, are included in material safety data sheets, available at request.

Guaranteed quality paour employees to be aware of their20 roles in reaching quality and environmental They20, know that inFrom the end, carrying out The regulation entered into force days aftercations. its publication, i.e. ontargets.

January moment, rameters in Technical Product Specifi The sale of and products in this2009. publication isthis subject to the Title XI of the their tasksare in included accordance with procedures applicable to their positions other included internal regulations, they provide our clients General Sales Terms and Conditions at PCC Exol SA. Exol SA. The regulation entered into force 20 days after its publication, i.e. on January 20, 2009.

From this moment, Title XI of the dous Substances with exactly what they expect from us, acting in conditions of legal usage of the envi ronment.

Responsible &reasonable Care and - mambership since 2014 dous Substances Directive was PCC transferred to Table 3.2. in Attachment VI to the CLP Regulation.

SA participates actively in implementing the CLP Regulation.

We classify chemicals Exol SA ment system which we present on encompassed by the above Directive legal was transferred Table 3.2. in Attachment VI toand theon CLP Regulation. status and to perform changes in data sheets labels within the r thing that really counts is how we can secure the interests of our clients, and the quality management system in use in PCC Exol

opean Chemicals Agency.

SA, supported with the environmental management system, provides us with a lot of tools aiding us in reaching this goal.

SA-participates actively inLabelling implementingand the CLP Regulation. We chemicalsand encompassed by the above PCC Exol SA CLP Classification, Packaging of classify substances mixtures Quality Management Systems SAperform participates actively ininimplementing the CLP Regulation. chemicals encompassed by the above Exoland SA legalPCC status changes in data sheets and on labels within the r We classify - basic paramThe information included this publication refl ects our up-to-date knowledge.

It describes the application and legal status and perform changes inisdata sheets and onvalues. labels within the r theChemicals opean Agency. eters of the products, and given as estimate We reserve right to make any changes as a result of technological S ince our operations are(EC) conducted in full compliance and otherParliament requirements,and including environmental reCLP Regulation - Regulation No. 1272/2008 of with thelegal European of the Council as of 16th December 2008 progress or developments. opean Chemicals Agency. quirements, the design, production and sale of large volumes of specialist, often unique, chemical products for further processQuality Management Systems on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and The information included in this publication reflects our up-to-date knowledge. It describes the application and basic paramQuality Management Systems The data should not be interpreted as guaranteed specifi c product qualities.

The health and environmental requirements, eters of the products, and is given as estimate values.

We reserve the right to make any changes as a result of technological 1999/45/EC, and amending Regulation (EC) No. 1907/2006.

The information included in this publication refl ects our up-to-date knowledge.

It describes the application and basic paramand environmental management system prove very useful.

These are two systems, currently integrated, S incesystem our operations are conducted in full compliance with legal and other requirements, including environmental re- which enable as well as user safety instructions, are included in material safety data sheets, available request. quality out paprogress or developments.

EXOLCARELINE/15 eters products, and is as We right to make any changes asatknow afor result ofGuaranteed technological our employees to begiven aware ofestimate their roles incompliance reaching quality and environmental targets.

They that in the end, recarrying quirements, the design, production and sale of large volumes ofreserve specialist, often unique, chemical products further processS of the ince our operations are conducted in values. full withthe legal and other requirements, including environmental rameters are included in Technical Product Specifi cations.

The sale of products included in this publication is subject to the progress or developments. their tasks in accordance with procedures applicable to their positions and other internal regulations, they provide our clients quirements, the design, production and sale ofat large of specialist, often unique, i.e. chemical further processTheshould regulation entered force 20 days after its publication, on products Januaryfor 20, 2009.

From this moment, Title XI of the General Sales Terms andexpect Conditions PCCvolumes Exol SA. Exol SA. The data be interpreted asinto guaranteed qualities.

The health and environmental requirements, withnot exactly what they fromprove us, specifi acting inproduct conditions of andcurrently legal usage of the envi ronment. system and environmental management system very cuseful.

These arereasonable two systems, integrated, which enable Reach Regulation ceased to be binding.

Harmonized classification contained in Attachment I to the Hazardous Substances as well as user safety instructions, are included in material safety data sheets, available at request.

Guaranteed quality padata should not beofinterpreted guaranteed specifi product qualities.

The health and environmental requirements, our The employees toenvironmental be aware their roles inasreaching and targets.

They know that in integrated, the end, carrying system and management systemquality prove very cenvironmental useful.

These are two systems, currently whichout enable rameters are included in Technical Product Specifi cations.

The sale of products included in this publication is subject to the as well as user safety instructions, are included in material safety data sheets, available at request.

Guaranteed quality pament system which we present on Directive was transferred to Table 3.2 in Attachment VI to the CLP Regulation. theirour tasks in accordance with procedures applicable to their positions and other internal provide ourcarrying clients out employees to be aware of their roles in reaching quality and environmental targets.regulations, They know they that in the end, General Saleswhat Terms andexpect Conditions at acting PCC Exol SA. cations.

Exol SA. in Technical Product Specifi The sale ofand products included in envi thisronment. publication is subject to the withrameters exactly they fromprocedures us, in conditions reasonable legal usage of the their tasksare in included accordance with applicable to of their positions and other internal regulations, they provide our clients General Sales Terms andexpect Conditions at acting PCC Exol SA. the interests Exol SA. thing thatthey really counts is how we can of our clients, andusage the quality management in use in PCC Exol with exactly what from us, insecure conditions of reasonable and legal of theClassification environment. system CLP introduces of GHS (Globally Harmonised andon Labelling SA, supportedthe withelements the environmental management system, provides usSystem with ament lotof ofsystem tools which aiding we us in reaching this goal. of Chemicals). present ment system which we present on thing that really counts how we can secure the interests of our clients, and theCLP quality managementWe system in use inchemicals PCC Exol PCC Exol SA isparticipates actively in implementing the Regulation. classify encompassed by the above legal SA, supported with the environmental management system, provides us with a lot tools management aiding us in reaching this goal. thing that really is howchanges we can secure the interests of our clients, theof quality systemdeadlines, in use in PCC Exol status andcounts perform in data sheets and on and labels within the required as well as notify new classification SA, supported with the environmental management system, provides us with a lot of tools aiding us in reaching this goal.

and labelling to the Classification and Labelling Inventory of the European Chemicals Agency.

The information included in this publication reflects our up-to-date knowledge. It describes the application and basic paramEXOLCARELINE/15 eters of the products, and is given as estimate values. We reserve the right to make any changes as a result of technological progress or developments.

EXOLCARELINE/15

The data should not be interpretedEXOLCARELINE/15 as guaranteed specific product qualities. The health and environmental requirements, as well as user safety instructions, are included in material safety data sheets, available at request. Guaranteed quality parameters are included in Technical Product Specifications. The sale of products included in this publication is subject to the General Sales Terms and Conditions at PCC Exol SA.

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EXOLcareline

GMP FOR COSMETIC INGREDIENTS

The ingredients of cosmetics are first and foremost the result of the efforts of many people. Specialised companies invent and produce ingredients. Carefully tested substances are then sold to cosmetics manufacturers. For purchased ingredients to find themselves in cosmetics, they must undergo many tests, have adequate quality and be completely safe for humans.

Cosmetic ingredients give cosmetics many defined and specific properties. For example, UV filters help protect the skin and hair against the harmful effects of UV rays. Additives in the form of surfactants provide washing and cleansing properties. They create an active foam during use of shampoos or body wash products such as soap or shower gels. Surfactants also have excellent thickening properties. They are used in the production of various types of emulsions and concentrates used in cosmetics.

Similarly to ready cosmetics, Good Manufacturing Practices are also applied in relation to raw materials and additives used in the production thereof. Manufacturers of cosmetics and personal hygiene products place great importance on the quality and properties of the ingredients that will affect the safety of use of the finished product.

Therefore, cosmetics companies require manufacturers of raw materials to confirm that they use Good Manufacturing Practices. This provides assurance that the components used in their formulations are safe and are always of the same quality, irrespective of the batch number.

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EXOLcareline

GOOD MANUFACTURING PRACTICES AT PCC EXOL SA GMP EFfCI Certificate Number: FR14/19163 / Brzeg Dolny GMP EFfCI Certificate Number: FR14/19164 / Płock

Why do we use Good Manufacturing Practices at our company?

One of the key priorities of PCC EXOL SA is focusing on the customers’ needs. Meeting their needs in the area of product variety, quality and safety is a major determinant of the use of Best Practices in the production of surfactants supplied to our customers in the cosmetics industry.

Good Manufacturing Practices at our plants are used to: •

ensure repeatability and homogenity of subsequent product batches

•

eliminate any situations that could potentially contaminate the product with foreign physical and chemical substances and bodies, and harmful microflora

•

prevent any accidental actions in the production processes and ensure that these processes are carried out in accordance with strict requirements in the form of instructions and procedures

The most important reason why we have implemented Good Manufacturing Practices (GMPs) in our company is to ensure the safety of users using cosmetics containing surfactants manufactured at our production plants. The use of GMP standards gives consumers greater peace of mind and assurance as to the quality and safety of the final product.

The given data are suggestions without any guarantee aimed to support customers’ development. PCC Exol doesn’t assume any liability or risk involved in the use of its products as the conditions of use are beyond its control. The information on product specification provided in this document is binding to the extent confirmed in a written sales agreement.

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PCC EXOL Sustainable technology for beauty...

Manufactured in one of PCC EXOL SA’s state of the art installations, ROKAmina K30 B and ROKAmina K40 HC are innovative products which belong to the amphoteric surface active substances group.

Specially selected raw materials and cutting-edge production technology make ROKAmina the perfect components for both adults’ and children’s shampoos. It combines with other ingredients to ensure soft and radiant hair. ROKAmina possesses excellent foam-forming properties and maintains a mild impact on skin, which ensures using shampoos is safe and highly convenient. Meeting the highest standards of quality and safety, the products manufactured by PCC EXOL SA are the base components of personal care products for many prestigious global cosmetic brands.

EXOLcareline

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EXOLcareline

Taking care for the environment, this publication of PCC Exol SA was printed on Cocoon Silk - an ecological both side coated matt paper. This paper is made of 100% wastepaper by an environment-friendly technology. FSC速 sources.

TEXT PAGES Cocoon Silk

Brand Grammage

200

Number of pages

28

COVER PAGES Cocoon Silk

Brand Grammage

250

Number of pages

4

PUBLICATION Size (cm)

21 x 29.7

Quantity

300

By using Cocoon Silk rather than a non-recycled paper, the environmental impact was reduced by:

56 8 76 2,062 129 92

kg of kg CO2 and greenhouse gases km travel in the average European car litres of water kWh of energy kg of wood

Carbon f ootprint data evaluated b y Labelia C onseil in a ccordance with t he B ilan Carbone速 methodology. Calculations are based on a comparison between the recycled paper used versus

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