FULBAT MSDS - Lithium Battery

Page 1


Version 4.0

Lithium Iron Phosphate Battery

According to Regulation (EU) No 2020/878

According to Regulation (EC) No 1272/2008

1.PRODUCT AND COMPANYIDENTIFICATION COMPANY IDENTIFICATION

Product identifier:

ProductForm: Article

Issue date: 14/04/2018

Update date : 15/11/2022

Productname: FLTSeries-Lithium-IronPhosphate(LiFePO4)batteries

Models: FLTK01(24Wh)-FLTX4L/5L/FLTZ5S/6S(25.6Wh)-FLTX7L/FLTZ7S (38.4Wh)-FLT7B/9B(51.2Wh)-FLTX7A/9/12/14/FLTZ10S/12S/14S (64Wh)-FLT12B/14B(76.8Wh)-FLTX20HL(153.6Wh)-FLTX20H (153.6Wh)-FLTX30HL(230.4Wh)

UFIcode: N/A

Relevant identified uses of the substance and uses advised against: Identified uses: Motorcycleandpowersportstarterbattery Uses advised against: Notavailable.

Details of the supplier of the safety data sheet:

Supplier: FULBAT S.a.s

Address: 30RuePasteur 92150 Suresnes France

Telephone: (France)+3318362 4555

Emergencytelephone Number:

CHEMTREC(US,Canada&Mexico) 0086-1-800-424-9300

CHEMTREC(International) 0086-1-703-527-3887

Availableoutsideofficehours? YES NO X

2.HAZARDS IDENTIFICATION

Forthebatterycell,chemicalmaterialsarestoredinahermeticallysealedAluminumlaminatedcase, designedtowithstandtemperaturesandpressuresencounteredduringnormaluse.Asaresult,during normal use, there is no physical danger of ignition or explosion and chemical danger of hazardous materials' leakage. This product meets the definition of an “article” and is not subject to the hazards normallyassociatedwiththeindividualcomponentswhenusedasintended. However,thisSafetyDataSheet(SDS)containsvaluableinformationcriticaltothesafehandlingand

properuseofthisproduct.ThisSDSshouldberetainedandavailableforemployeesandotherusers ofthisproduct.Alwaysbeawareoftheriskoffire,explosionorburns.Donotshortcircuittheterminals withanyothermetals.Donotdisassembleormodifythebattery.Donotsolderabatterydirectly.Keep awayfromfireoropenflame.

3.COMPOSITION / INFORMATIONON INGREDIENTS

IMPORTANTNOTE:Thebatterycellshouldnotbeopenedorexposedtoheatbecauseexposureto thefollowingingredientscontainedwithincouldbeharmfulundersomecircumstances.

Weight% listed is based on approximate percent of the averageweight of the battery

4.

FIRST-AID MEASURES

Spilled internal cellmaterials

・Inhalation:

Makethevictimblowhis/hernose,gargle.Seekmedicalattentionifnecessary.

・Skincontact:

Removecontaminatedclothesandshoesimmediately.Washextraneousmatterorcontactregionwith soapandplentyofwaterimmediately.

・Eyecontact:

Donotrubone’seyes.Immediatelyflusheyeswithwatercontinuouslyforatleast15minutes. Seekmedicalattentionimmediately.

A battery cell and spilled internal cell materials

・Ingestion:

Makethevictimvomit.Whenitisimpossibleorthefeelingisnotwellaftervomiting,seek medicalattention.

5.FIRE-FIGHTING MEASURE

・Suitableextinguishingmedia:Plentyofwater,carbondioxidegas,nitrogengas,chemicalpowder fireextinguishingmediumandfirefoam

・Specifichazards:Corrosivegasmaybeemittedduringfire.

・Specificmethodsoffirefighting:Whenthebatteryburnswithothercombustibles

simultaneously,takefireextinguishingmethodwhichcorrespondtothecombustibles.Extinguisha firefromthewindwardasmuchaspossible.

・Specialprotectiveequipmentforfirefighters:

Respiratoryprotection:Respiratoryequipmentofagascylinderstyleorprotection-against-dustmask.

Handprotection:Protectivegloves

Eyeprotection:GoggleorprotectiveglassesdesignedtoprotectagainstliquidsplashesSkinand bodyprotection:Protectivecloth

6. ACCIDENTALRELEASE MEASURES

Spilledinternalcellmaterials,suchaselectrolyteleakedfromabatterycell,arecarefullydealtwith accordingtothefollowings.

・Precautionsforhumanbody: Removespilledmaterialswithprotectiveequipment(protectiveglassesandprotectivegloves).Do notinhalethegasasmuchaspossible.Moreover,avoidtouchingasmuchaspossible.

・Environmentalprecautions:Donotthrowoutintotheenvironment.

・Methodofcleaningup: Thespilledsolidsareputintoacontainer.Theleakedplaceiswipedoffwithdrycloth.

・Preventionofsecondaryhazards: Avoidre-scattering.Donotbringthecollectedmaterialsclosetofire.

7. HANDLING ANDSTORAGE

HandlingTechnical measures

Preventionofuserexposure:Notnecessaryundernormaluse. Preventionoffireandexplosion:Notnecessaryundernormaluse. Precautionforsafehandling:Donotdamageorremovetheexternaltube. Specificsafehandlingadvice: Neverthrowoutcellsinafireorexposetohightemperatures.Donotsoakcellsinwaterorseawater. Donotexposetostrongoxidizers.Donotgiveastrongmechanicalshockorfling. Neverdisassemble, modify or deform. Do not connect the positive terminal to the negative terminal with electrically conductive material. In the case of charging, use only dedicated charger or charge according to the conditionsspecifiedbyFULBAT.

・Storage Technicalmeasures

Storageconditions(suitable,tobeavoid):Avoiddirectsunlight,hightemperature,highhumidity.Store incoolplace(temperature:-20~35degreeC,humidity:45~85%).

Incompatibleproducts:Conductivematerials,water,seawater,strongoxidizersandstrongacids Packingmaterial(recommended,notsuitable):Insulativeandtearproofmaterialsarerecommended.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

・Controlparameters: Notestablished

・Appropriateengineeringcontrols

Undernormalconditions(duringdischarge)releaseofingredientsdoesnot occur.ACGIH:AmericanConferenceofGovernmentalIndustrialHygienists,Inc.

TLV-TWA:ThresholdLimitValue-TimeWeightedAverageconcentrationBEI:

BiologicalExposureIndices

・Personalprotectiveequipment

Respiratoryprotection:Respiratorwithaircylinder,dustmaskHand protection:Protectivegloves

Eyeprotection:Goggleorprotectiveglassesdesignedtoprotectagainstliquidsplashes

Skinandbodyprotection:Workingclotheswithlongsleeveandlongtrousers

9. PHYSICAL AND CHEMICALPROPERTIES

・Appearance

Physicalstate:Solid

Form:Prismatic

Color:Metalliccolor(withouttube)

Odor:Noodor

・pH:NA

・Specifictemperatures/temperaturerangesatwhichchangesinphysicalstateoccur: Thereisnousefulinformationfortheproductasamixture.

・Flashpoint:NA

・Explosionproperties:NA

・Density:NA

・Solubility,withindicationofthesolvent(s):Insolubleinwater

10. STABILITYAND REACTIVITY

Stability:Stableundernormaluse

・Hazardousreactionsoccurringunderspecificconditions

・Conditionstoavoid:Heatabove70°orincinerate.Deform,mutilate,crush,disassemble,overcharge,shortcircuit, exposeoveralongperiodtohumidconditions.Donotputitundersunlightandhighhumiditydirectly.

・Materialstoavoid:Conductivematerials,water,seawater,strongoxidizersandstrongacids.

・Hazardousdecompositionproducts:Acridorharmfulgasisemittedduringfire.

11. TOXICOLOGICAL INFORMATION

Thereisnoavailabledataontheproductitself.Theinformationoftheinternalcellmaterialsisas follows.

Lithium Iron Phosphate– LiFePO4

Acutetoxicity:Noapplicabledata.

・Localeffects:Unknown.

・Sensitization:Thenervoussystemofrespiratoryorgansmaybestimulatedsensitively.

・Chronictoxicity/Longtermtoxicity:Noapplicabledata.

・Skincausticity:Althoughitisveryrare,therashoftheskinandallergicerythemamayresult. Aluminum

・Localeffects:Aluminumitselfhasnotoxicity.Whenitgoesintoawound,dermatitismaybecaused.

・Chronictoxicity/Longtermtoxicity:Bythelong-terminhalationofcoarseparticulateorfume,it ispossibletocausealungdamage(aluminumlungs).

Graphite

・Acutetoxicity:Unknown.

・Localeffects:Whenitgoesintoone’seyes,itstimulatesone’seyes;conjunctivitis,thickening ofcornealepitheliumoredematousinflammationpalpebramaybecaused.

・Chronictoxicity/Longtermtoxicity:Long-terminhalationmaybecomeacauseofalungdiseaseora trachealdisease.

・Carcinogenicity:Graphiteisnotrecognizedasacauseofcancerbyresearchorganizationsand naturaltoxicsubstanceresearchorganizationsofcancer.

Copper

Acutetoxicity:60-100mgsizedcoarseparticulatecausesagastrointestinaldisturbancewithnausea andinflammation.TDLo,hypodermic-Rabbit375mg/kg

・Localeffects:Coarseparticulatestimulatesanoseandatracheal. Whenitgoesintoone’seyes, thesymptomofthereddeningandthepainiscaused.

Sensitization:Sensitizationoftheskinmaybecausedbylong-termorrepetitivecontact.

・Reproductiveeffects:TDLo,oral-Rat152mg/kg

Organic Electrolyte

・Acutetoxicity:LD50,oral-Rat2,000mg/kgormore

・Localeffects:Unknown.

・Skinirritationstudy:Rabbit–Mild

・eyeirritationstudy:Rabbit-Verysevere

12. ECOLOGICAL INFORMATION

・Persistence/degradability:donotburyorthrowoutintotheenvironment.

13. DISPOSAL CONSIDERATIONS

・Recommendedmethodsforsafeandenvironmentallypreferreddisposal: Product (waste from residues) Donotthrowoutausedbatterycell.Recycleitthroughtherecyclingcompany. Contaminated packaging Neitheracontainernorpackingiscontaminatedduringnormaluse.Wheninternalmaterialsleaked fromabatterycellcontaminates,disposeasindustrialwastessubjecttospecialcontrol.

14. TRANSPORT INFORMATION

SHIPPING BY SEA or BY ROAD (≤100Wh)

14.1UN Number : UN3480

14.2UN Proper shipping name : LITHIUM IONBATTERIES

14.3Transport Hazard class : -

14.4Packing group : -

14.5Environmental hazards :No

14.6ADR, IMDG Transport: SP188

SHIPPING BY SEA or BY ROAD (>100Wh)

14.1 UN Number : UN3480

14.2 UN Proper shipping name : LITHIUM IONBATTERIES

14.3 Transport Hazard class : 9

14.4 Packing group : II

14.5 Environmental hazards :No

14.6 IMDG Transport : P903

SHIPPING BY AIR

14.1UN Number : 3480

14.2UN Proper shipping name : LITHIUM IONBATTERIES

14.3Transport Hazard class : 9

14.4Packing group : II

14.5Environmental hazards :No

14.6IATA Transport : PI965-Section IB(≤100Wh)orPI965-SectionIA(>100Wh)

15. REGULATORYINFORMATION

《Classification,LabelingandPackagingRegulation》

《REACH(EC)1907/2006》

《DangerousGoodsRegulation》

《RecommendationsonTransportofDangerousGoodsModelRegulations》

《InternationalMaritimeDangerousGoods》

《TechnicalInstructionsfortheSafeTransportofDangerousGoods》

《Classificationandcodeofdangerousgoods》

《OccupationalSafetyandHealthAct》(OSHA)

《ToxicSubstancesControlAct》(TSCA)

《ConsumerProductSafetyAct》(CPSA)

《FederalEnvironmentalPollutionControlAct》(FEPCA)

《TheOilPollutionAct》(OPA)

《ResourceConservationandRecoveryAct》(RCRA)

《SafetyDrinkingWaterAct》(CWA)

《CodeofFederalRegulations》(CFR)

InaccordancewithallFederal,Stateandlocallaws

16. OTHER INFORMATION

・TheinformationcontainedinthisSafetydatasheetisbasedonthepresentstateofknowledgeand currentlegislation.

・Thissafetydatasheetprovidesguidanceonhealth,safetyandenvironmentalaspectsofthe productandshouldnotbeconstruedasanyguaranteeoftechnicalperformanceorsuitabilityfor particularapplications.

・Reference

Chemical substances information: Japan Advanced Information center of Safety and Health

InternationalChemicalSafetyCards(ICSCs): InternationalOccupationalSafetyandHealthInformationCentre(CIS)

2002 TLVs and BEIs: American Conference of Governmental Industrial Hygienists (ACGIH) New DangerousGoodsBestPractice008--inthe51stEditionIATADGR(2010)(witheffectfrom01January 2010)

GB/T16483-2008SafetydatasheetforchemicalproductsContentandorderofsectionsISO 11014:2009(E)Safetydatasheetforchemicalproducts–ContentandorderofsectionsIMDG Code–2008Edition:InternationalMaritimeOrganization(IMO)

RTECS(CD-ROM)

MSDSofrawmaterialspreparedbythemanufacturesFirst Edition:Feb.14/04/18

LatestEdition:15/11/2022

PreparedandapprovedbyFULBATS.a.s

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