Planika material safety data sheet

PLANIKA Sp. z o.o.

86-061 Brzoza, ul. Bydgoska 38 Tel. +48 52 364-11-60 Fax +48 52 364-11-70

FANOLA PREMIUM Date of issue: 14.10.2013 /

Version 2.0/EN

MATERIAL SAFETY DATA SHEET Basis: EC ordinance No. 453/2010, 20.05.2010

1. Substance/product and manufacturer identification : 1.1.

Commercial name : FANOLA PREMIUM solvent Chemical formula : compound 1.2.

Application : Ecological Cleanser/Degreaser, Natural fragrances, substances and paint diluter For a decorative fire, Used to start a fire.

1.3.

Manufacturer’s name and address : PLANIKA Sp. z o.o. ul. Bydgoska 38 86-061 Brzoza REGON No. : 093115222 VAT No. : PL5542520460 1.4.

Telephone : local emergency telephone number +48 52 364-11-60 emergency number 08:00-16:00 Fax : +48 52 364-11-70 2. Composition and information on ingredients : 2.1 Classification according to the (WE)Regulation no. 1272/2008 : Flam.Liq. 2 H 225 – Highly flammable liquid and vapor (WE) Directive 67/548/EWG – mixture is classified according to its hazardous properties F – Highly flammable liquid R11 – Highly flammable product 2.2 Label elements The product labeled in accordance with the current labeling regulations Warning sign – danger Pictogram : GHS02

Phrase indicating the type of threat: H225 Precautionary statements: - prevention: P210 - Keep away from heat / sparks / open flames / hot surface - No smoking.

P233 - Keep container tightly closed P240 – Ground/bond container and receiving equipment P241 – Use explosion-proof electrical/ventilating/light equipment P243 - Take precautionary measures against static discharge P280 - Wear protective gloves/protective clothing/eye protection/face protection - response: P303+P361+P353 – If on skin (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P403+P235 - Store in a well-ventilated place. Keep cool - removal: P501 – Dispose of contents/container with local / regional / national / international regulations.

Page 1 of 6

PLANIKA Sp. z o.o.

86-061 Brzoza, ul. Bydgoska 38 Tel. +48 52 364-11-60 Fax +48 52 364-11-70

FANOLA PREMIUM

MSDS-version 2.0/EN 3. Ingredients properties.

Hazardous substance

Content

Ethanol

89-93 %

CAS Registry Number

WE Number

64-17-5

200578-6

20115-0 Methyl ethyl ketone

<1

Acetone

2-4%

Index

Reach Number

Clasification

60300200-5

01-211945761043-0000

F;R11

60600200-3

No data

F;R11; Xi

200662-2

60600100-8

01-211947133049-0000

F;R11;Xi;R36;R66/6 7

Denatonium benzoate 0,001%

3734-33-6

Flam.Liq.2

Flam.Liq.2

Return Code

H225

H225 H319

Eye Irrit.2

78-93-3

67-64-1

Hazard Code

223095-2

No data

No data

R22;Xn;R20;Xi R36/37/38

Flam.Liq.2

H225

Eye Irrrit.2 Stot SE 3

H319 H336

Acute Tox.4 Eye Irrit.2 Stot SE 3 Skin Irrit.2

H332 H319 H336 H315

4. First Aid Procedures 4.1 Description of first aid measures Routes of Exposure: inhalation, ingestion, skin contact, eye contact.

The consequences of inhalation: Remove casualty to fresh air and lay down. If needed provide artificial respiration and get medical help.

The consequences of ingestion: Due to the presence of contaminants in ethanol industries, it is essential to provide the casualty plenty of water to drink, do not induce vomiting. In case of serious poisoning take the patient to the hospital for further observation and treatment.

Contact with eyes: In case of contact with eyes, rinse immediately with plenty of water with wide open lids for at least 15 minutes, remove contact lenses, in case of irritation ensure ophthalmologist.

Contact with skin: In the event of contact with skin, remove soaked clothing and shoes, wash immediately with plenty of water. If needed ensure medical assistance and dermatologistâ&#x20AC;&#x2122;s advice.

4.2 Acute and delayed symptoms and effects of exposure: In contact with the eye may cause redness and tearing leading to irritation. Inhalation may cause coughing and difficulty breathing, dizziness and disorders of the central nervous system.

If swallowed, may cause irritation of the mouth, throat and stomach.

4.3 Indication of any immediate medical attention and special treatment needed If swallowed, do not induce vomiting. Treat symptomatically.

For specialist advice physicians should contact the National Poisons Information Service.

Page 2 of 6

PLANIKA Sp. z o.o.

86-061 Brzoza, ul. Bydgoska 38 Tel. +48 52 364-11-60 Fax +48 52 364-11-70

FANOLA PREMIUM

MSDS-version 2.0/EN

5. Fire fighting measures: 5.1 Special hazards: Product inflammable. There is a probability of arising explosive compound when mixed with air.

Partial combustion products may contain carbon oxide and carbon dioxide.

5.2 Fire fighting measures: Foams resistant to alcohol of film-creating foams or water-dispersed water jets in case of large fires; small fires to be fought with fire-fighting powder, sprayed water and carbon dioxide. Do not use full streams of water. Inappropriate fire fighting measures : compact stream of water â&#x20AC;&#x201C; the risk of fire spreading 5.3 Other information: Keep adjacent containers cool by spraying of water from safe distance.

6. Accidental release measures: 6.1.Personal protection measures: - protective gloves - protective goggles 6.2 Accidental spill or leak measures: Prevent contamination of soil and water. Prevent spreading or penetration into sewage systems (explosion risk), ditches or rivers by using sand, soil or other suitable barriers. In case of small leaks, absorb the liquid or prevent from further leaking by using sand or soil. Remove ignition sources. Thin vapours by using dispersed currents.

Secure drains. Avoid direct contact with the leaking substance.

If possible, remove the leak (close the liquid flow, seal the container). In case of a large leak, surround the leak with dykes and pump away the collected liquid. Clean the contaminated spot with plentiful of water.

7. Handling and storage: Storage : Store in sealed containers in room with good ventilation, far from fire and heat sources and spark-generating tools. Do not smoke.

The proceedings: Comply with protection and safety law regulations. Do not smoke.

Avoid breathing vapors.

8. Exposure controls and personal protection: During production use following personal protection measures: Respiratory tract protection : - use in case of insufficient ventilation Hand protection : - protective gloves (e.g. PVC ) Eye protection : - tight protective goggles Technical protection measures : - ventilation of rooms Other protective equipment : Personal protection measures used in the place of work should comply with the requirements of the Ordinance of the Minister of economy as of 21 December 2005 and Directive No. 89/686/WE with subsequent amendments.

Exposure control: highest admissible concentrations: main substance Ethanol NDS = 1900 mg/m3 DNEL- inhalation - 950 mg/m3 DNEL- dermal - 343 mg / kg / day Environment exposure controls: Prevent spreading or penetration into groundwater, sewage systems or soil.

Follow the general Health and Safety Regulations.

Page 3 of 6

PLANIKA Sp. z o.o.

86-061 Brzoza, ul. Bydgoska 38 Tel. +48 52 364-11-60 Fax +48 52 364-11-70

FANOLA PREMIUM

MSDS-version 2.0/EN 09. Physical and chemical properties : General characteristics: transparent liquid with a distinct odour Ignition temperature [°C] Self-ignition temperature [°C] Upper explosive limit [% V/V] Lower explosive limit [% V/V] Density [kg/m3] at temperature 20°C Molecular mass Phase at temperature of 20°C Solubility in other solvents Solubility in water Boiling point [°C] The n-octanol/water partition coefficient Light refraction coefficient Vapour pressure at temperature of 20°C

23,5 425 14,8% 2,5% <1g/cm3 compound liquid hydrocarbons, alcohols and ethers soluble 78,3 1,3648 58 mbar(58 hPa)

10. Stability and reactivity : Stability : stable substance in normal conditions. The substance may react with strong oxidants and acids. The product vapours may create an explosive compound when mixed with air.

Combustion products : carbon dioxide, water Avoid contact of the product with strong oxidants.

11.

Not Not Not Not

Toxicological information : Corrosive sensitizing mutagenic carcinogenic

Concentration, lethal and toxic doses : Odour smelling threshold no data LD50 rat, oral 7060 mg/kg LC50 rat, inhaled 38400 mg/m3 (10h) LD50 rabbit, skin >20000 mg/kg

human 6000 mg/kg

Following considerable exposure : The liquid or vapours may cause lacrimation, conjunctivitis as well as irritate nose and throat mucous membranes. Swallowing or consumption may cause nausea, vomiting, mobile coordination disorders, headaches, dizziness, breathing difficulties.

12. Ecological information: The product is soluble in water. It is subject to evaporation from water surface. The liquid is biodegradable to a large extent, subject to quick oxidisation in water and air due to photochemical reactions.

Toxicity for fish : LC50=1300 mg/l/96h ( rainbow trout ) Toxicity for crustaceans : no data Algae growth retardation : no data 13. Waste disposal: Utilize accordingly to the effective provisions of the law. Do not store together with municipal waste, prevent from getting into the sewage system. Waste code: 020703 (chemical wastes), packaging waste code : 150102 (plastic packaging) – the classification is the manufacturer’s proposal.

Packaging emptied from all products residues shall be delivered to appropriate waste dump or for utilization accordingly to local law regulations.

14. Information on transport : road (ADR): Shipping name : Hazard class in transport acc. to ADR/RID : Classification code : Packaging group : UN No. of hazardous product: Warning label:

liquid, flammable I.N.O. class 3, F1 III 1993 3 Page 4 of 6

PLANIKA Sp. z o.o.

86-061 Brzoza, ul. Bydgoska 38 Tel. +48 52 364-11-60 Fax +48 52 364-11-70

FANOLA PREMIUM

MSDS-version 2.0/EN

15. Information on legal provisions: The label contains the following signs and symbols pursuant to the Ordinance of the Minister of Health as of 2 September 2003 (Journal of Laws No. 199, item 1948 as of 24.11.2003) Warning symbols: F – highly flammable substance Hazard identification (R): R11 – highly flammable product Correct handling identification: S2 – keep out of reach of children S7 – keep in sealed containers S16 – do not store close to fire sources – do not smoke tobacco S46 – in case of swallowing, consult your doctor immediately and show this packaging or label Other information: List of R and H – phrases R20 – Harmful by inhalation R22 – Harmful if swallowed R36 – Irritating to eyes R36/37/38 – Irritating to eyes, respiratory system and skin R67 – Vapours may cause drowsiness and dizziness H225 – Highly flammable liquid and vapour H302 – Harmful if swallowed H315 – Causes skin irritation H319 – Causes serious eye irritation H332 – Harmful if inhaled H335 – May cause respiratory system irritation H336 – May cause drowsiness or dizziness -The Ordinance No. 1907/2006/WE as of 18.12.2006 on registration, assessment, granting of exemptions and application of limitations in respect of chemicals (REACH) and creation of the European Agency of Chemicals amending Directive 1999/45/WE and repealing the Council Regulation (EWG) no. 793/93 and the Commission Regulation (WE) no. 1488/94 as well as the Council Directive 76/769/EWG and the Commission Directives 91/155/EWG, 93/67/EWG, 93/105/WE and 2000/21/WE. - The Directive No. 2008/1272/WE as of 16.12.2008 applying to classification, packaging and labelling hazardous substances amending and repealing Directives No. 67/548/EWG and 1999/45/WE, and amending Regulation No. 2006/1907/WE. - The Directive No. 2009/790/WE dated 10.08.2009 adjusting to technical progress of the European Parliament and of the Council No. 1272/2008/WE as of 16.12.2008 on rapprochement of legal, executive and administrative regulations, applying to classification, packaging and labelling hazardous substances.

-The Committee Directive No. 2010/453/UE as of 20.05.2010 modifying the European Parliament Directive No. 2006/1907/WE and the Council Directive concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH).

- The Act on chemical substances and their mixtures as of 25.02.2011 (Journal of Laws No.63, pos.322).

- The Ordinance of the Minister of Health dated 20.04.2012 on the labeling of chemical substances and mixtures, and certain mixtures (Journal of Laws No.25.04.2012, pos.445).

-The Ordinance of the Minister of Health as of 10.08.2012 on the criteria and classification of chemical substances and mixtures thereof: (Journal of Laws No. 2012, pos.1018).

-The Ordinance of the Minister of Labour and Social Policy dated 29.11.2002 (Journal of Laws No. 217, pos.1833) on the maximum permissible concentrations and intensities of harmful factors in the work environment with the change of 1.10.2005 (Journal of Laws No.212, pos.1769) with a change of 30.09.2007 (Journal of Laws No. 161, pos. 1142), with a change of 16.06.2009 (Journal of Laws No. 105, pos. 873), with the change of 29.07.2010 (Journal of Laws No. 141, pos. 950), - The Act on waste of 14.12.2012 (Journal of Laws No.2013, pos.21).

Page 5 of 6

PLANIKA Sp. z o.o.

86-061 Brzoza, ul. Bydgoska 38 Tel. +48 52 364-11-60 Fax +48 52 364-11-70

FANOLA PREMIUM

MSDS-version 2.0/EN

- The Commission Directives No. 2000/39/WE dated 8.06.2000 and No. 2006/15/WE dated 7.02.2006 establishing a first and a second list of indicative occupational exposure limit values.

- The Act on Waste of 27.04.2001 (Journal of Laws No.62, pos. 628) and the ordinance of the Minister of the Environment on waste of 27.09.2001 (Journal of Laws No.112, pos. 1206) -The Act on Packaging and packaging waste from 11.05.2001 (Journal of Laws No.63, pos. 638) - The Classification of dangerous goods according to the European Agreement concerning international road transport of hazardous materials (ADR).

- The Ordinance of the Minister of Labour and Social Policy dated 26.09.1997 on general provisions of occupational safety and health (Journal of Laws No.169, pos.1650) as amended.

-The Ordinance of the Minister of Labour and Social Policy as of 30.12.2004 on highest permissible concentration and intensity of factors harmful of health in work environment (Journal of Laws 2005 No. 11, pos. 86) with subsequent amendments.

-The Decree of Minister of Economy dated 21.12.2005 regarding the general requirements for the individual protection measures. (Journal of Laws No. 259, pos. 2173).

16. Other information: The information provided in this Material Safety Data Sheet is based on our present knowledge of safety requirements as of the date of its preparation.

This Material safety Data Sheet was prepared on the basis of material safety data sheet provided by manufacturers, the Internet databases and current provisions.

Date of issue: 28.06.2013, version 1.0/EN, Planika Sp. z o.o., ul. Bydgoska 38, 86-061 Brzoza

Page 6 of 6