Investigation of Tribological Properties of Cotton Seed Oil By Adding MoS2 and SiO2 as a Additives

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Investigation of Tribological Properties of Cotton Seed Oil By Adding MoS2 and SiO2 as a Additives

1Scholar, Dept. of Mechanical Engineering, SRCOE, Maharashtra, India

2 Principal, SRCOE, Maharashtra, India

3Professor, Dept. of Mechanical Engineering, SRCOE, Maharashtra, India ***

Abstract - Forthehighqualityandenvironment friendly operationofancaratrunningstipulationsrequiresperfect lubrication between the shifting components so that the componentsslideeasilyovereveryother.Toreducestrength losses,discountofputonandfrictionhasakeysignificance inenginesandpressuretrains.InICenginesfromalengthy time mineral oilshavebeen usedasa lubricant.However, Mineraloilisaproductofthedistillationofcrudeoil,sothat itcanbeusedtillcrudeoilisavailable.Also,thedisposalof mineral oils leads the hassle of air pollution in aquatic as properly as in terrestrial ecosystems. In addition, the combustionofmineraloillubricantshavebeenemittracesof metalsaszinc,calcium,magnesiumphosphorousandiron nanoparticles.Today,thedepletionofreservesofcrudeoil, thedevelopingexpendituresofcrudeoil,andproblemabout defending the surroundings in opposition to air pollution havedevelopedtheactivityinthedirectionofenvironmentfriendly lubricants as a replacements for mineral oils in engines.

Key Words: cottonseedoil,Transesterification,Additives, Tribologicalproperties

1.INTRODUCTION

Nowadays nanoscience is one of the most expansively creatingspheresofworld’sscienceanditsachievementscan be utilized in special areas of science and technology. For instancenanomaterials,presentintheshapeofsoknownas nanostructures (nanotubes, nanowires, nanopowders and others) that are wider and wider used in many fields of human undertaking - from most cancers cure thru to engineeredtextilesorelectricitystoragetorocketpropellant andexplosives.Anditispastadoubtthatseveranewfields ofnanostructuressoftwarewilloccurinthenearesttime.One ofthemlookstobetheunexploredregionofnanostructures useascomponentsenhancinghomes(especiallytribological) oflubricatingorreducingoils.

1.1 Lubrication Theory

Lubricationisthemethodemployedtominimizeputonof oneoreachsurfacesincontact,andtransferringrelativeto every other, via interposing a substance referred to as lubricantbetweenthesurfacestoelevateortoassistraise

the load between the opposing surfaces. Functions of lubricantareasfollows

Itreducesthefrictionbetweenthecontactingsurface

Itdecreasethewear

Itraiseawaythefrictionalheat

Itprotectsthesurfacesinoppositiontocorrosion

It prevents the entry of overseas particles like grime and dust,tothecontactzone.

1.2 Basic Modes of Lubrication

In lubrication, two contacting surfaces which haveactionrelativetoeachdifferentareseparatedbyway ofaexcessivestrainmovieof lubricant. Based on theapproachofgrowingtheexcessivestressmovieof lubricant between the contacting surfaces, the lubrication canbecategorizedinto4types

•Hydrodynamic lubrication

•Hydrostatic lubrication

•Electrohydrodynamic lubrication

•Solidmovielubrication

2.PROBLEM STATEMENT

The traditional lubricants used for a number mechanical structures consist of specific sorts of traditional additives. Thecomponentsassisttoenhancethelubricatingandantiwear homes of the lubricant. But these traditional componentshavesureboundariesatheavyloads.Theyare nownotinapositiontopreservetheiruniquehousesandfor that reason exhibit negative lubricating and anti-wear residences at these heavy loads. So there have to be improvement in the components so as to make bigger the workingvaryofthelubricantbyusingtheusageofMoS2and SiO2 nanoparticles for my part and with the aid of mixing thematarangeofattentionofnanoparticles.

2.1 Objectives

Thehassledeclarationshowstheeagerwantofimproventof componentssoas toenhance thelubricatinghomes ofthe

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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 10 Issue: 06 | Jun 2023 www.irjet.net p-ISSN: 2395-0072

lubricant.Thiscanbeperformedbymeansoftheusageofthe new rising cloth i.e. nanoparticles as components in the lubricant.Sothefundamentalintentionofthisworkistotest feasibilityandtoinspectthetribologicalresidencesofspecial kinds of nanoparticle components so as to enhance the lubricating and anti-wear properties. The targets of this recordcanbeenlistedasfollows, •TofindoutabouttheSurfaceModificationofTCSOwith MoS2andSiO2.

• To find out about the impact of components on scar diameterandcoefficientoffrictionofTCSO.

3. EXPERIMENTAL SETUP FOR WEAR TEST

We havechosenatrendy4balltrying outlaptopwith standardizedcheckingouttechniquei.e.AmericanSocietyfor Testing and Materials (ASTM). DUCOM’s4ball tester TR30householdis designed todecideput onpreventive (WP),excessivestrain(EP) and shearbalanceconductof lubricants.Apparatusmeasuresthecoefficientoffriction,put onscar diameter and load carryingpotentialof lubricating oilsbeneathwidespreadworkingconditions.Themechanical testerconsistsofspindleassembly,motor,ballpotassembly, loadingarrangement.Thereisabuilt-inaccentstorageand balltraytomaintaincheckballs.Also,thecheckrigconsists ofsensors,PCbased totally desktop control, records acquisitionmachineanddisplay.

4. Ballpotheightfromfloor 1230mm

5. LoadingArmLength 935mm

6. Loadingarmratio 1:15

7. MaximumLoad 9999N

8. MinimumLoad 60N

9. Deadweights In steps of 1, 2 and5Kg

10. MotorHeightfromfloor 1580mm

11. Spindlespeed Min 1000 rpm and Max 3000 rpm

12. PulleyRatio 1:1

13. Overall sizes of the machine L×W×H 660×935×1650 mm

14. WeightoftheMachine 388Kg

15. FloorSizeL×W 2500×1500mm

4. NANOPARTICLES USED

Thedifferenttypesofnanoparticlesusedinthisworkareas follows,

1) Molybdenumdisulphide(MoS2)

2) Silicon Dioxidenanoparticles(SiO2)

4.1 Molybdenum disulphide (MoS2)

 Appearance: shinydarkgray

 Purity:99.9%(metalbasis)

 Morphology:spherical

 Truedensity:5.06g/cm3

 CrystallographicStructure:cubic

 MakingMethod:Laserevaporating

4.2 Silicon Dioxide nanoparticles (SiO2)

 Appearance:brownblackpowder

 Purity:99%(metalbasis)

 APS:25-55nm

 SSA:13.98m2/g

 Morphology:nearlyspherical

 Bulkdensity:0.79g/cm3

 Truedensity:6.4g/m3

5. EXPERIMENTATION

5.1 Sample Preparation

Thepatternorganizedabout20 mlby means ofquantityasprovenin fig. the weight ofcomponentsis measuredondigitalweighingcomputerhavingaccuracyin milligrams. The magnetic stirrer is used for dispersion of nano-particleinoil.

International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 10 Issue: 06 | Jun 2023 www.irjet.net p-ISSN: 2395-0072 © 2023, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page111
3.1 Four -Ball Test Rig Figure5.2:Ducom TR30LFourBallTestRig
Sr. No. Part Details Range 1. CollectDiameter 12.7mm 2. Baseplateheightfromfloor 924mm 3. LoadingArmheightfromFloor 1050
3.2 Mechanical Specifications Table3.1:Mechanicalspecificationsoffourballtester
mm

Table5.1:Testsamples

As the addition of SiO2 nanoparticle in trans-esterified cotton seed oil at the 1% of nanoparticle to thecompletepatternhaving theminimumcoefficient of frictionhoweveraftersubsequentstage 1.5% addition of nanoparticlecoefficientoffrictionenlargesothe1%ofSiO2 nanoparticleisreallyhelpfulforutilitypurpose.

7. CONCLUSION

Based on the experimental learn about the following conclusioncanbedrawn:

a.TransesterifiedCSOindicateshigherantiwearhousesas evaluatetosophisticatedCSO.

b. There is no discount of WSD and COF with MoS2 as additiveduetothefactofitscorsegrainsize.

c.AsproportionofSiO2willincreaseputondecreases.

d. As examine to TCSO, WSD reduce via 18% and Cof decreasesbymeanstheof21%.

e.AsexaminetosophisticatedCSO,WSDdecreasesbymeans of33%andCOFdecreasesbywayof27%.

6. RESULTS

Thecommonvalues of theput onscar diameters and coefficientsof friction forall samplesof CSO oilandTCSO cottonseedoilandnanoparticleproportionareasprovenin Table6.1:

Table for coefficient of friction and average wear scar diameterwithnanoparticlepercentage,particlesize

f.SothereisexceptionalattainableofSiO2ascomponentsto enhancethetribologicalproperties.

REFERENCES

1. R.Chou,A.HernandezBattez,“Tribologicalbehavior of polyalphaolefin with the addition of nickel nanoparticles” Tribology International, 43, 2010, pp.2327–2332

2. Ehsan-o-llahEttefaghi,“Experimentalevaluationof engine oil properties containing copper oxide nanoparticles as a nanoadditive” International JournalofIndustrialChemistry,2013,pp.4:28

3. Juozas Padgurskas, Raimundas Rukuiza,“Tribological properties of lubricant additivesofFe,CuandConanoparticles”Tribology International,60,2013,pp.224–232

4. J.L. Viesca A. Hernandez Battez,“Anti-wear properties of carbon-coated copper nanoparticles usedasanadditiveto apolyalphaolefin”Tribology International,44,2011,pp.829–833

5. Ajinkya S. Pisal, D. S. Chavan,“Experimental InvestigationofTribologicalPropertiesofEngineoil withSiO2nanoparticles”IRDIndia,3,2014,pp.3438

International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 10 Issue: 06 | Jun 2023 www.irjet.net p-ISSN: 2395-0072 © 2023, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page112
Sample Sample Preparation Transesterified cottonseed oil (%byvol)ml Additive (% by wt)gm 1. Cottonseedoil 202. Chemically modified cottonseed oil (TCSO) 203 1%bywtofMoS2 19.82 0.1868 3. 0.25 % by wt of SiO2 19.98 0.0467 4. 0.50 % by wt of SiO 2 19.96 0.0934 5. 0.75 % by wt of SiO 2 19.94 0.1401 6. 1.00 % by wt of SiO 2 19.92 0.1868
Sr. No. Testing Samples Coefficient of Friction Average WSD (µm) 1 Cottonseedoil(CSO) 0.06361 690 2 Tranesterified cottonseedoil 0.06361 680 3 20W50oil 0.08602 401 4 TCSO1%MOS2 0.05328 654 5 TCSO SiO2(0.25%) + MOS2(0.75%) 0.04624 655 6 TCSO SiO2(0.50%) + MOS2(0.50%) 0.04335 620 7 TCSO SiO2(0.75%) + MOS2(0.25%) 0.04222 540 8 TCSO SiO2(1%) 0.04142 515

6. Shubrajit Bhaumik,“Analysis of Tribological Behavior of Carbon Nanotube Based Industrial Mineral Gear Oil 250 cSt Viscosity” Hindawi Publishing Corporation Advances in Tribology, 2014,ArticleID341365,pp.512-520

7. Mustafa Akbulut,“Nanoparticle-Based Lubrication Systems” Powder Metallurgy & Mining, 1, 2012, pp.337-340

8. Y. Y. Wu ,W. C. Tsui," Experimental analysis of tribological properties of lubricating oils with nanoparticleadditives”ScienceDirectWear,262, 2007,pp.819

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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 10 Issue: 06 | Jun 2023 www.irjet.net p-ISSN: 2395-0072 © 2023, IRJET | Impact Factor value: 8.226 | ISO 9001:2008 Certified Journal | Page113

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