MATERIALSAFETYDATASHEET CHLORINATED PARAFFIN CP50/52
SECTION I: Identification of the Substance and the Company
1 Identification:
Product form : Substance
Substance name : CHLORINATED PARAFFIN CP50/52
CAS-No : 85535-85-9
Formula :Alkanes,C14-17,chloro
2 Recommended Use and Restriction of Use:
Use of the substance/mixture : Industrial Use
Use of the substance/mixture :As fire proof plasticizer in rubber, vinyl and acrylic paints and PVC formulations , as flame retardant in synthetic clothes and in cable insulations and sheets In general, it is used as a flame retardant additive in the manufacture of many substances.
3 Supplier Details:
Company name: BizinBizTechnologies Pvt Ltd
CompanyAddress:A-448, Pocket 2, Sector 8, Rohini, New Delhi, Pin Code: 110085, India
Company Web Site: www elchemy com
Mobile number: +919867099519
Email Id: info@elchemy.com
SECTION II: Hazards Identification
1. Classification of substance or mixture:
Classification (EC 1272/2008)
Physical hazards: Not Classified
Health hazards Lact - H362
Environmental hazardsAquaticAcute 1 - H400Aquatic Chronic 1 - H410
2 Label Elements:
Signal word: Warning
Hazard statements:
H362 May cause harm to breast-fed children.
H410 Very toxic to aquatic life with long lasting effects
Precautionary statements
P201 Obtain special instructions before use.
P263Avoid contact during pregnancy/ while nursing
P264 Wash contaminated skin thoroughly after handling
P273Avoid release to the environment.
P308+P313 IF exposed or concerned: Get medical advice/ attention
P501 Dispose of contents/ container in accordance with national regulations
Supplemental label information: EUH066 Repeated exposure may cause skin dryness or cracking
Contains: alkanes, C14-17, chloro
3. Other hazards:
This product does not contain any substances classified as PBTor vPvB
4 UnknownAcute Toxicity:
Not applicable
SECTION III: Composition/Information on Ingredients
Mixtures:
alkanes, C14-17, chloro: 95-100%
CAS number: 85535-85-9
EC number: 287-477-0
M factor (Acute) = 1
M factor (Chronic) = 1
SECTION IV: FirstAid Measures
1. Description of necessary first aid measures:
a First-aid measures general : Get medical attention immediately Show this Safety Data Sheet to the medical personnel.
b First-aid measures after inhalation : Remove affected person from source of contamination. Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing Maintain an open airway
Loosen tight clothing such as collar, tie or belt When breathing is difficult, properly trained personnel may assist affected person by administering oxygen Place unconscious person on their side in the recovery position and ensure breathing can take place
c. First-aid measures after skin contact : Rinse with water.
d. First-aid measures after eye contact : Rinse with water. Remove contact lenses, if present and easy to do Continue rinsing for at least 10 minutes
e. First-aid measures after ingestion : Rinse mouth thoroughly with water. Remove any dentures Give a few small glasses of water or milk to drink Stop if the affected person feels sick as vomiting may be dangerous Do not induce vomiting unless under the direction of medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs Never give anything by mouth to an unconscious person Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing Place unconscious person on their side in the recovery position and ensure breathing can take place Maintain an open airway Loosen tight clothing such as collar, tie or belt.
Most important symptoms and effects, both acute and delayed:
a. Symptoms/effects after inhalation : Prolonged inhalation of high concentrations may damage respiratory system
b. Symptoms/effects after skin contact : Repeated exposure may cause skin dryness or cracking
c Symptoms/effects after eye contact : May cause temporary eye irritation
d Symptoms/effects after ingestion : Gastrointestinal symptoms, including upset stomach Fumes from the stomach contents may be inhaled, resulting in the same symptoms as inhalation.
e Chronic symptoms : No effects known
2 Indication of any immediate medical attention and special treatment needed: Treat symptomatically
SECTION V: Fire Fighting Measures
1. Extinguishing Media:
a Suitable extinguishing media : The product is not flammable Extinguish with alcohol-resistant foam, carbon dioxide, drynpowder or water fog. Use fire-extinguishing media suitable for the surrounding fire
b. Unsuitable extinguishing media : Do not use water jet as an extinguisher, as this will spread the fire
2. Special hazards arising from the substance or mixture:
a Fire hazard : Containers can burst violently or explode when heated, due to excessive pressure build-up.
b Hazardous decomposition products in case of fire : Thermal
decomposition or combustion products may include the following substances: Harmful gases or vapours
3. Advice for firefighters:
a Precautionary measures fire : Avoid breathing fire gases or vapours
Evacuate area. Cool containers exposed to heat with water spray and remove them from the fire area if it can be done without risk Cool containers exposed to flames with water until well after the fire is out If a leak or spill has not ignited, use water spray to disperse vapours and protect men stopping the leak Avoid discharge to the aquatic environment Control run-off water by containing and keeping it out of sewers and watercourses If risk of water pollution occurs, notify appropriate authorities.
b. Protection during firefighting : Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing Firefighter's clothing conforming to European standard EN469 (including helmets, protective boots and gloves) will provide a basic level of protection for chemical incidents
SECTION VI:Accidental Release Measures
1 Personal precautions, protective equipment and emergency procedures:
No action shall be taken without appropriate training or involving any personal risk. Keep unnecessary and unprotected personnel away from the spillage Wear protective clothing as described in Section 8 of this safety data sheet Follow precautions for safe handling
described in this safety data sheet Wash thoroughly after dealing with a spillage Ensure procedures and training for emergency decontamination and disposal are in place. Do not touch or walk into spilled material
2. Environmental precautions:
Immiscible with water.Aquatic toxicity is unlikely to occur. However, large or frequent spills may have hazardous effects on the environment Absorb spillage with non-combustible, absorbent material Avoid discharge into drains or watercourses or onto the ground.Avoid discharge to the aquatic environment. Large Spillages: Inform the relevant authorities if environmental pollution occurs (sewers, waterways, soil or air)
3 Methods and materials for containment and cleaning up:
Wear protective clothing as described in Section 8 of this safety data sheet. Clear up spills immediately and dispose of waste safely Approach the spillage from upwind Small Spillages: If the product is soluble in water, dilute the spillage with water and
mop it up.Alternatively, or if it is not water-soluble, absorb the spillage with an inert, dry material and place it in a suitable waste disposal container Large Spillages: If leakage cannot be stopped, evacuate area Flush spilled material into an effluent treatment plant, or proceed as follows. Contain and absorb spillage with sand, earth or other non-combustible material Place waste in labelled, sealed containers Clean contaminated objects and areas thoroughly, observing environmental regulations The contaminated absorbent may pose the same hazard as the spilled material. Flush contaminated area with plenty of water Wash thoroughly after dealing with a spillage Dangerous for the environment Do not empty into drains Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste DisposalAuthority
4. Reference to other sections:
For personal protection, see Section 8 See Section 11 for additional information on health hazards. See Section 12 for additional information on ecological hazards. For waste disposal, see Section 13
SECTION VII: Handling and Storage
1 Precautions for safe handling:
a. Precautions for safe handling : Read and follow manufacturer's recommendations Wear protective clothing as described in Section 8 of this safety data sheet Keep away from food, drink and animal feeding stuffs Handle all packages and containers carefully to minimise spills. Keep container tightly sealed when not in use Avoid the formation of mists Avoid discharge to the aquatic environment Do not handle until all safety precautions have been read and understood Do not handle broken packages without protective equipment. Do not reuse empty containers.
b Hygiene measures : Wash promptly if skin becomes contaminated Take off contaminated clothing. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product Wash at the end of each work shift and before eating, smoking and using the toilet Change work clothing daily before leaving workplace.
2. Conditions for safe storage, including any incompatibilities:
Store in accordance with local regulations Keep only in the original container Keep container tightly closed, in a cool, well ventilated place. Keep containers upright Protect containers from damage Bund storage facilities to prevent soil and water pollution in the event of spillage The storage area floor should be leak-tight, jointless and not absorbent.
SECTION VIII: Exposure Controls
1. Control parameters: Occupational exposure limits
DNEL:1.6mg/m3
2 Appropriate engineering controls: Provide adequate ventilation Personal, workplace environment or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Use process enclosures, local exhaust ventilation or other engineering controls as the primary means to minimise worker exposure Personal protective equipment should only be used if worker exposure cannot be controlled adequately by the engineering control measures Ensure control measures are regularly inspected and maintained Ensure operatives are trained to minimise exposure
3 Individual protection measures, such as personal protective equipment:
a. Personal protective equipment: Safety glasses. Gloves. Heatproof clothing.
b. Hygiene Measures: Provide eyewash station and safety shower Contaminated work clothing should not be allowed out of the workplace Wash contaminated clothing before reuse Clean equipment and the work area every day Good personal hygiene procedures should be implemented Wash at the end of each work shift and before eating, smoking and using the toilet. When using do not eat, drink or smoke. Preventive industrial medical examinations should be carried out Warn cleaning personnel of any hazardous properties of the product
c. Hand protection: Chemical-resistant, impervious gloves complying with an approved standard should be worn if a risk assessment indicates skin contact is possible.The most suitable glove should be chosen in consultation with the glove supplier/manufacturer, who can provide information about the breakthrough time of the glove material To protect hands from chemicals, gloves should comply with European Standard EN374. Considering the data specified by the glove manufacturer, check during use that the gloves are retaining their protective properties and change them as soon as any deterioration is detected. Frequent changes are recommended.
d. Eye protection: Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. Personal protective equipment for eye and face protection should comply with European Standard EN166 Unless the assessment indicates a higher degree of protection is required, the following protection should be worn:Tight-fitting safety glasses
e. Skin and body protection: Appropriate footwear and additional protective clothing complying with an approved standard should be worn if a risk assessment indicates skin contamination is possible
f. Respiratory protection: Respiratory protection complying with an approved standard should be worn if a risk assessment indicates inhalation of contaminants is possible Ensure all respiratory protective equipment is suitable for its intended use and is ‘CE’-marked. Check that the respirator fits tightly and the filter is changed regularly Gas and combination filter cartridges should comply with European Standard EN14387 Full face mask respirators with replaceable filter cartridges should comply with European Standard EN136 Half mask and quarter mask respirators with replaceable filter cartridges should comply with European Standard EN140
g Personal protective equipment symbol(s):
SECTION IX: Physical and Chemical Properties
General Information:
Appearance: Viscous liquid Colour: SlightYellow Odour: Mild Chlorine Melting point/Freezing point: -9 °C Initial boiling point and range: > 200 °C Flash point: > 216 °C
Flammability (solid, gas) Not applicable. Vapour pressure No information available. Solubility(ies) Insoluble in water Partition coefficient No information available Auto-ignition temperature Not applicable Viscosity 12-17 poise (@25ºC) Explosive propertiesThere are no chemical groups present in the product that are associated with explosive properties. Oxidising propertiesThere are no chemical groups present in the product that are associated with oxidising properties 9 2 Other information Other information Density (@ 25 °C) : 1.265 ± 0.02 g/cm3
SECTION X: Stability and Reactivity
1 Reactivity: Reacts violently with (strong) oxidizers Reacts with (some) acids
2 Chemical stability: Stable under normal conditions
3. Possibility of hazardous reactions: No additional information available.
4 Conditions toAvoid Conditions toAvoid: No additional information available
5 Incompatible materials: No additional information available
6. Hazardous decomposition products: Under normal conditions of storage and use, hazardous decomposition products should not be produced
SECTION XI: Toxicological Information
1 Acute toxicity (oral) : Not classified
2. Acute toxicity (dermal) : Not classified
3. Acute toxicity (inhalation) : Not classified
4. LD50 oral rat: > 5991 mg/kg bodyweight (Equivalent or similar to OECD 401, Rat, Male / female, Experimental value, Oral, 14 day(s))
5 LD50 dermal rat: > 11181 mg/kg bodyweight (24 h, Rat, Male / female, Experimental value, Dermal, 14 day(s))
6 LC50 Inhalation – Rat: > 4 64 mg/l (6 h, Rat, Experimental value, Inhalation, 14 day(s))
7 Skin corrosion/irritation : Not classified
8. Serious eye damage/irritation : Not classified
9. Respiratory or skin sensitisation : Not classified
10 Germ cell mutagenicity : Not classified
11. Carcinogenicity : Not classified
12.Reproductive toxicity : Not classified
13.STOT-single exposure : Not classified
14.STOT-repeated exposure : Not classified
15.Aspiration hazard : Not classified
16.Viscosity, kinematic : 11.53 mm²/s (20 °C,ASTM D445: Capillary viscometer)
17.Potential adverse human health effects and symptoms : Non-toxic if swallowed (LD50 oral, rat > 5000 mg/kg). Not irritant to skin. Non-toxic in contact with skin (LD50 skin> 5000 mg/kg) Slightly harmful by inhalation Not irritant to eyes
18.Symptoms/effects after inhalation : EXPOSURETO HIGH CONCENTRATIONS: Coughing Central nervous system depression ON HEATING: Irritation of the respiratory tract Irritation of the nasal mucous membranes Lacrimation
19 Symptoms/effects after skin contact : No effects known Symptoms/effects after eye contact : Redness of the eye tissue
20 Symptoms/effects after ingestion : AFTER INGESTION OF HIGH QUANTITIES: Gastrointestinal complaints
21 Chronic symptoms : No effects known
SECTION XII: Ecological Information
1 Toxicity:
a. Ecology - general : Not classified as dangerous for the environment according to the criteria of Regulation (EC) No 1272/2008
b. Ecology - air : Not included in the list of substances which may contribute to the greenhouse effect (IPCC) Not included in the list of fluorinated greenhouse gases (Regulation (EU) No 517/2014) Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009).
c Ecology – water: Harmful to crustacea Harmful to fishes Groundwater pollutant. Not harmful to activated sludge. Harmful to algae.
d LC50 - Fish [1]: 12 mg/l (EPA660/3 - 75/009, 96 h, Oncorhynchus mykiss, Flow-through system, Fresh water, Experimental value)
e ErC50 algae: 45 mg/l (Equivalent or similar to OECD 201, 72 h, Desmodesmus subspicatus, Static system, Fresh water, Experimental value, Nominal concentration)
2. Persistence and degradability:
Biodegradable in the soil Readily biodegradable in water
3. Bioaccumulative potential:
a. Partition coefficient n-octanol/water (Log Pow): 2 2 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method, 40 °C)
b. Bioaccumulative potential: Low potential for bioaccumulation (Log Kow < 4).
4. Mobility in soil:
a. Surface tension: 37 5 mN/m (20 °C)
b. Organic Carbon NormalizedAdsorption Coefficient (Log Koc): 2.34 (log Koc, OECD 121: Estimation of theAdsorption Coefficient (Koc) on Soil and on Sewage Sludge using High Performance Liquid Chromatography (HPLC), Experimental value, GLP)
c. Ecology – soil: Low potential for adsorption in soil
5 Other adverse effects:
No additional information available
SECTION XIII: Disposal Considerations
1. Disposal methods:
a Regional legislation (waste) : Disposal must be done according to official regulations.
b Sewage disposal recommendations : Disposal must be done according to official regulations.
c Product/Packaging disposal recommendations : Do not discharge into drains or the environment. Remove waste in accordance with local and/or national regulations Hazardous waste shall not be mixed together with other waste Different types of hazardous waste shall not be mixed together if this may entail a risk of pollution or create problems for the further management of the waste Hazardous waste shall be managed responsibly All entities that store, transport or handle hazardous waste shall take the necessary measures to prevent risks of pollution or damage to people or animals. Recycle by distillation Remove to an authorized waste incinerator for solvents with energy recovery Obtain the consent of pollution control authorities before discharging to wastewater treatment plants.
d Additional information : Can be considered as non hazardous waste according to Directive 2008/98/EC, as amended by Regulation (EU) No 1357/2014 and Regulation (EU) No 2017/997
SECTION XIV: Transport Information
In accordance with DOT/TDG / IMDG / IATA
1 UN Number: Not regulated for transport
2. UN proper shipping name:
Proper Shipping Name (DOT) : Not applicable
Proper Shipping Name (TDG) : Not applicable
Proper Shipping Name (IMDG) : Not applicable
Proper Shipping Name (IATA) : Not applicable
3. Transport hazard class(es):
DOTTransport hazard class(es) (DOT) : Not applicable
TDGTransport hazard class(es) (TDG) : Not applicable
IMDGTransport hazard class(es) (IMDG) : Not applicable
IATATransport hazard class(es) (IATA) : Not applicable
4. Packing Group:
Packing group (DOT) : Not applicable
Packing group (TDG) : Not applicable
Packing group (IMDG) : Not applicable
Packing group (IATA) : Not applicable
5. Environmental Hazards:
Other information : No supplementary information available.
6. Special precautions for user:
DOT: No data available
TDG: No data available
IMDG: No data available
IATA: No data available
7. Transport in bulk according toAnnex II of MARPOL73/78 and the IBC Code: NA
SECTION XV: Regulatory Information
1. US Federal regulations:
a Not subject to reporting requirements of the United States SARASection 313
b. CERCLARQ: 1000 lb
2 International regulations:
a. CANADA: Listed on the Canadian DSL(Domestic Substances List)
b. EU-Regulations: No additional information available
c. National regulations: Listed on INSQ (Mexican National Inventory of Chemical Substances)
3. US State regulations:
No additional information available
SECTION XVI: Other Information
OSHAHazard Communication Standard 29 CFR 1910.1200 (HazCom 2012)
NFPAhealth hazard : 1 - Materials that, under emergency conditions, can cause significant irritation.
NFPAfire hazard : 1 - Materials that must be preheated before ignition can occur
NFPAreactivity : 0 - Material that in themselves are normally stable, even under fire conditions.