2-Aminobenzoic acid sodium salt (Anthranilic acid sodium salt) [C7H6NO2·Na]

2-Aminobenzoic acid sodium salt [C7H6NO2·Na]

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2 reactions in Reaxys

2018-08-18 00h:39m:25s (UTC)

H 2N O–

1. Query Na +

O

Search as: Product, As drawn, No mixtures ) AND (IDE.RN='552-37-4') AND (IDE.INCHI='HCKKSLZDSNNSTL-UHFFFAOYSA-M') NOT (RX.RXRN=3735721))

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2018-08-18 00:42:05

2-Aminobenzoic acid sodium salt [C7H6NO2·Na]

H 2N

H 2N

O–

O

Na +

HO

O

Rx-ID: 31802197 View in Reaxys 1/2 Yield

Conditions & References

93 %

With sodium hydroxide in water, Time= 4h, T= 20 °C Amin, Muhammad Mohsin; Ali, Saqib; Shahzadi, Saira; Sharma, Saroj K.; Qanungo, Kushal; Journal of Coordination Chemistry; vol. 64; nb. 2; (2011); p. 337 - 350 View in Reaxys H 2N O– Na +

O

Rx-ID: 25388857 View in Reaxys 2/2 Yield

Conditions & References 3 : EXAMPLE 3: EXAMPLE 3: Bisanthranilato(O,N)copper(II),[Cu(II)(anthranilate) 2 ] The sodium salt of anthranilic acid (5 g 0.04 mol) was prepared as decribed in example 1 in 150 ml of H2 O with 50percent NaOH. This solution was dropped into 300 ml of a stirred aqueous solution of CuCl2 dihydrate (2.5 g, 0.016 mol).

The precipitate which formed was removed by filtration and washed with H2 O and diethylether (5*50 ml).

After drying overnight at;120° C. and 15 mm Hg the material weighed 6.1 g, 99percent yield.

A sample of this greenishblue material decomposed on heating to 240° C. and continued to decompose on heating to 290° C. Analysis Calcd. for C&14

H6 N2 O4 Cu: C,

50.07; H, 3.60; N, 8.35. Found: C, 50.07; H, 3.77; N, 8.42.

Patent; Sorenson; John R. J.; US4221785; (1980); (A) English View in Reaxys

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2018-08-18 00:42:05