South African Journal of Science Volume 110 Issue 3/4

Page 84

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South African Journal of Science

80

0.47

0.27

0.38 0.60

0.35

0.48

0.17

0.52

0.74

1.88

0.02

0.14

0.70

0.46

0.04

0.33

0.64

0.28

0.38

0.30

4.70

0.10

0.68

0.08

0.28

1.38

1.12

1.98

2.78

2.01

Marikana RSA (2008 – 2009) Maximum 3-month averages, PM10

0.13 – 1.94

0.07 – 1.12

0.00 – 1.67

0.00 – 0.73

0.11 – 1.68

0.16 – 2.39

0.02 – 14.53

0.00 – 0.07

0.00 – 0.37

0.15 – 2.27

0.00 – 1.59

0.00 – 0.16

0.00 – 1.08

0.04 – 1.48

0.01 – 0.80

0.02 – 1.92

0.01 – 2.42

0.42 – 19.01

0.01 – 0.16

0.01 – 1.26

0.00 – 0.40

0.01 – 0.45

0.43 – 4.53

0.03 – 3.25

0.31 – 2.86

0.09 – 13.57

0.13 – 7.23

Marikana RSA (2008 – 2009) Concentration range of 72-h samples, PM10

0.42

0.34

0.21

0.77

9.76

4.39

1.37

0.16

0.18

Rustenburg, RSA (2006) PM1016

0.04

0.00

0.00

0.09

0.05

0.04

1.28

0.12

0.05

0.00

0.02

1.30

1.00

2.80

Vaal Triangle, RSA (2006, 2007) PM1012

TSP, total suspended particulates

° 3-month limit value

* WHO guideline for Cr(VI) concentrations associated with an excess lifetime risk of 1:1 000 000

24-h limit value

0.0645

0.00041

0.273

0.0295

0.00315

1.18

0.0255

0.00432

5.34

1.47

Urban/industrial area in La Plata City, Argentina (1993) TSP34

WHO air quality guidelines for Europe11, b European Commission Air Quality Standards35, c National Ambient Air Quality Standards of the United States Environmental Protection Agency36, d National Air Quality Act of the South African Department of Environmental Affairs37

0.067

0.0086

0.0005

0.039

0.038

0.00012

0.35

0.03

0.043

0.132

8.80

0.185

1.90

0.10

1.70

Industrial area in Lisbon, Portugal (2001) PM1033

#

0.0149

0.000486

0.00

0.00030

0.00069

0.0545

0.0153

0.00256

0.510

0.0141

0.00355

0.002

24 Urban and industrial sites in the UK (2009) PM1032

a

Metal species that were below the detection limit 75% or less of the time during the entire sampling period are shaded; values that exceeded limits of standards are bolded.

-

-

Tl

U

0.14

-

-

Ba

Au

0.58

0.41

-

-

0.02

Se

0.35

0.03

Pd

-

1.30

0.005(a),(b)

Cd

Pt

0.26

-

0.006 (b)

As

0.49

-

-

Zn

0.18

0.33

Be

-

Cu

B

0.02 (b)

Ni

0.14

0.08

-

Co

2.54

Pb

-

Fe

0.06

0.55

0.15(a)

Mn

0.24

0.04

1(a)

2.5x104 (a) *

Cr

0.5(a),(b),(d), 0.15(c)°

1(b) #

V

0.12

1.08

Hg

-

Ti

0.68

-

-

K

Ca

1.28

-

Al

1.41

2.04

-

-

Na

Marikana RSA (2008 – 2009) Annual averages, PM10

Annual standard limit

Annual average, 3-month average and 72-h concentrations of metal species detected. All values are indicated in µg/m3. The aerosol trace metal concentrations determined in a selection of previous studies are also presented. Also indicated are the existing ambient air quality standard limit values for trace metal species.

Mg

Metal

Table 1:

Research Article Page 4 of 11 Atmospheric trace metals in the western Bushveld Igneous Complex

Volume 110 | Number 3/4 March/April 2014


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