Doc 117 b p s xi chemistry iit jee advanced study package 2014 15

Page 256

reagent R

←  2

 1 →

R1 and R2 are – (A) Cold alkaline KMnO4, OsO4/H2O2 (C) Cold alkaline KMnO4, CH3–O–O–CH3

Q.47

(B) Cold alkaline KMnO4, HCO3H (D) C6H5CO3H, HCO3H

CH 3 | H−C alkaline KMnO ||    4 → A, which is true about this reaction? H−C | CH 3

(A) A is meso 2, 3–butan–di–ol formed by syn addition (B) A is meso 2, 3–butan–di–ol formed by anti addition (C) A is a racemic mixture of d and l, 2, 3–butan–di–ol formed by anti addition (D) A is a racemic mixture of d and l 2,3–butan–di–ol formed by syn addition +

O3 / H 2O / Zn Con . H SO + CH3MgBr H 3O  → C → A  24 → B 

Q.48

A, B and C are – A

B

C

(A)

(B)

(C)

(D)

Q.49

A → ∆

A can be – (A) Conc. H2SO4

(B) alcoholic KOH

(C) Et3N

12

(D) t-BuOK

Page 12 of 40 HYDROCARBONS

reagent R

Q.46


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