Bio-C - UK

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 1/10

Bio-C concentrate SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier

Trade name/designation:

Bio-C concentrate

Article No.: 56-1503, 56-1525, 56-1506 UFI: A693-RNSC-C80F-DUN3

1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture: Organic breakdown agent with odor neutraliser

Relevant identified uses:

Life cycle stage [LCS] PW: Widespread use by professional workers Product Categories [PC] PC 28: Perfumes, fragrances PC 37: Water treatment chemicals

1.3. Details of the supplier of the safety data sheet Supplier (manufacturer/importer/only representative/downstream user/distributor): Vaportek Europe Logistic Sarl 6 Route du Grand Lancy 1211 Genève 26 Switzerland Telephone: +41 22 342 2145 E-mail: vaportek@gmail.com

E-mail (competent person): vaportek@gmail.com

1.4. Emergency telephone number 24h: NHS (National Health Service): 111

SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Hazard classes and hazard categories

Hazard statements

Classification procedure

Hazardous to the aquatic environment H412: Harmful to aquatic life with long Calculation method.

(Aquatic Chronic 3) lasting effects.

2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP]

According to EC directives or the corresponding national regulations, the product does not have to be labelled.

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 2/10

Bio-C concentrate Hazard components for labelling: (R)-p-mentha-1,8-diene

Hazard statements for environmental hazards H412

Harmful to aquatic life with long lasting effects.

Supplemental hazard information EUH208

Contains (R)-p-mentha-1,8-diene. May produce an allergic reaction.

Precautionary statements Prevention P273

Avoid release to the environment.

Precautionary statements Disposal P501

Dispose of contents/container to an appropriate recycling or disposal facility.

* 2.3. Other hazards

Adverse physicochemical effects: No further relevant information available.

Adverse human health effects and symptoms: The product contains a substance that is identified as having endocrine disrupting properties. p-Menth-1-en-8-ol CAS: 98-55-5 ; EC: 202-680-6 Adverse environmental effects: The product contains a substance that is identified as having endocrine disrupting properties. p-Menth-1-en-8-ol CAS: 98-55-5 ; EC: 202-680-6 The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII. Other adverse effects: No further relevant information available.

SECTION 3: Composition/information on ingredients 3.2. Mixtures

Description: Organic breakdown agent with odor neutraliser Hazardous ingredients / Hazardous impurities / Stabilisers: Product identifiers CAS No.: 7732-18-5 EC No.: 231-791-2

Substance name Concentration Classification according to Regulation (EC) No. 1272/2008 [CLP] water The substance is classified as not hazardous according to regulation (EC) No. 1272/2008 [CLP].

30 – ≤ 60 weight-%

Alcohols, C6-10, ethoxylated propoxylated Aquatic Chronic 2 (H411), Eye Irrit. 2 (H319)

1–≤5 weight-%

CAS No.: 5989-27-5 EC No.: 227-813-5 Index No.: 601-096-00-2

(R)-p-mentha-1,8-diene Aquatic Acute 1 (H400), Aquatic Chronic 3 (H412), Asp. Tox. 1 (H304), Flam. Liq. 3 (H226), Skin Irrit. 2 (H315), Skin Sens. 1B (H317)

0–<1 weight-%

CAS No.: 123-92-2 EC No.: 204-662-3 Index No.: 607-130-00-2

isopentyl acetate Flam. Liq. 3 (H226)

0 – < 0.1 weight-%

CAS No.: 68987-81-5 EC No.: 691-266-2

Warning

Danger M-factor (acute): 1

Warning EUH066 Full text of H- and EUH-phrases: see section 16.

SECTION 4: First aid measures 4.1. Description of first aid measures

General information: In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible).

Remove victim out of the danger area.

Remove contaminated, saturated clothing. according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 3/10

Bio-C concentrate If unconscious but breathing normally, place in recovery position and seek medical advice. Do not leave affected person unattended.

Following inhalation: Provide fresh air.

In case of skin contact: After contact with skin, wash immediately with plenty of water and soap.

If skin irritation or rash occurs: Get medical advice/attention.

After eye contact: Rinse cautiously with water for several minutes.

If eye irritation persists: Get medical advice/attention. Remove contact lenses, if present and easy to do.

Continue rinsing.

Following ingestion: Rinse mouth.

Get medical advice/attention if you feel unwell.

4.2. Most important symptoms and effects, both acute and delayed No data available

4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically.

SECTION 5: Firefighting measures 5.1. Extinguishing media

Suitable extinguishing media: Co-ordinate fire-fighting measures to the fire surroundings.

5.2. Special hazards arising from the substance or mixture The product itself does not burn.

Hazardous combustion products: In case of fire: Gases/vapours, harmful

5.3. Advice for firefighters

Wear a self-contained breathing apparatus and chemical protective clothing.

5.4. Additional information

Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.

SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Personal precautions: Remove persons to safety.

Protective equipment: Wear protective gloves/protective clothing/eye protection/face protection.

6.1.2. For emergency responders

Personal protection equipment: Personal protection equipment: see section 8

6.2. Environmental precautions

Do not allow to enter into surface water or drains.

6.3. Methods and material for containment and cleaning up

For containment: Absorb with liquid-binding material (sand, diatomaceous earth, acid- or universal binding agents).

For cleaning up: Water (with cleaning agent)

6.4. Reference to other sections

Safe handling: see section 7 Personal protection equipment: see section 8 Disposal: see section 13

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 4/10

Bio-C concentrate 6.5. Additional information

Use appropriate container to avoid environmental contamination.

SECTION 7: Handling and storage 7.1. Precautions for safe handling Protective measures

Advices on safe handling: Wear personal protection equipment (refer to section 8).

Fire prevent measures: Usual measures for fire prevention.

Measures to prevent aerosol and dust generation: Avoid: aerosol or mist formation Environmental precautions: Do not contaminate water with the product or its container (Do not clean application equipment near surface water/Avoid contamination via drains from farmyards and roads).

Advices on general occupational hygiene

When using do not eat, drink or smoke. Avoid contact with eyes and skin.

7.2. Conditions for safe storage, including any incompatibilities

Technical measures and storage conditions: Keep container tightly closed in a cool, well-ventilated place.

Packaging materials: Keep/Store only in original container.

Storage class (TRGS 510, Germany): 10 – Combustible liquids that cannot be assigned to any of the above storage classes

7.3. Specific end use(s) No data available

SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.1.1. Occupational exposure limit values

propane-1,2-diol CAS No.: 57-55-6 EC No.: 200-338-0

① Long-term occupational exposure limit value ② Short-term occupational exposure limit value ③ Instantaneous value ④ Monitoring and observation processes ⑤ Remark ① 10 mg/m³ ⑤ (particulates)

isopentyl acetate CAS No.: 123-92-2 EC No.: 204-662-3

① 50 ppm (270 mg/m³) ② 100 ppm (540 mg/m³)

Limit value type Substance name (country of origin)

WEL (GB) WEL (GB) IOELV (EU)

propane-1,2-diol CAS No.: 57-55-6 EC No.: 200-338-0

WEL (GB) isopentyl acetate from 21 Aug 2018 CAS No.: 123-92-2 EC No.: 204-662-3

① 150 ppm (474 mg/m³) ⑤ (total vapour & particulates)

① 50 ppm (270 mg/m³) ② 100 ppm (541 mg/m³)

8.1.2. Biological limit values No data available

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 5/10

Bio-C concentrate 8.1.3. DNEL-/PNEC-values

① DNEL type ② Exposure route ① DNEL worker ② Long-term – inhalation, systemic effects

Substance name

DNEL value

propane-1,2-diol CAS No.: 57-55-6 EC No.: 200-338-0

168 mg/m³

propane-1,2-diol CAS No.: 57-55-6 EC No.: 200-338-0

50 mg/m³

① DNEL Consumer ② Long-term – inhalation, systemic effects

Substance name

PNEC Value

propane-1,2-diol CAS No.: 57-55-6 EC No.: 200-338-0

260 mg/L

① PNEC type ① PNEC aquatic, freshwater

8.2. Exposure controls 8.2.1. Appropriate engineering controls No data available

8.2.2. Personal protection equipment

Eye/face protection: Eye glasses with side protection EN 166 Skin protection: Tested protective gloves must be worn EN ISO 374 Suitable material: PVC (polyvinyl chloride), NBR (Nitrile rubber), Butyl caoutchouc (butyl rubber) In the case of wanting to use the gloves again, clean them before taking off and air them well.

Breakthrough times and swelling properties of the material must be taken into consideration.

Respiratory protection: Usually no personal respirative protection necessary.

8.2.3. Environmental exposure controls No data available

SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state: Liquid Odour: not determined

Safety relevant basis data

Colour: yellow Odour threshold: not determined

Parameter

Value

pH

5–8

Melting point

① Method ② Remark

not determined

Freezing point

not determined

Decomposition temperature

not determined

Evaporation rate

not determined

Initial boiling point and boiling range not determined Flash point

Auto-ignition temperature

Upper/lower flammability or explosive limits Vapour pressure Vapour density Density

Relative density Bulk density

according to Regulation (EC) No. 2020/878 (REACH)

> 100 °C not determined not determined not determined not determined not determined not determined not determined en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 6/10

Bio-C concentrate Parameter

Value

Water solubility

completely miscible

Dynamic viscosity

not determined

① Method ② Remark

Partition coefficient: n-octanol/water not determined Kinematic viscosity

not determined

9.2. Other information No data available

SECTION 10: Stability and reactivity 10.1. Reactivity

This material is considered to be non-reactive under normal use conditions. The product itself does not burn.

10.2. Chemical stability

The product is chemically stable under recommended conditions of storage, use and temperature.

10.3. Possibility of hazardous reactions No known hazardous reactions.

10.4. Conditions to avoid

No further relevant information available.

10.5. Incompatible materials

No further relevant information available.

10.6. Hazardous decomposition products

No known hazardous decomposition products.

Decomposition products in case of fire: see section 5.

SECTION 11: Toxicological information 11.1. Information on hazard classes as defined in Regulation (EC) No. 1272/2008 Alcohols, C6-10, ethoxylated propoxylated LD50 oral: >2,380 mg/kg

CAS No.: 68987-81-5 EC No.: 691-266-2

LD50 dermal: >2,000 mg/kg

LC50 Acute inhalation toxicity (vapour): >50 mg/L 4 h

(R)-p-mentha-1,8-diene

CAS No.: 5989-27-5 EC No.: 227-813-5

LD50 oral: >2,000 mg/kg (Rat) OECD 423

isopentyl acetate

CAS No.: 123-92-2 EC No.: 204-662-3

LD50 oral: >7,400 mg/kg

Acute oral toxicity: Based on available data, the classification criteria are not met.

Acute dermal toxicity: Based on available data, the classification criteria are not met.

Acute inhalation toxicity: Based on available data, the classification criteria are not met.

Skin corrosion/irritation: Based on available data, the classification criteria are not met.

Serious eye damage/irritation: Based on available data, the classification criteria are not met.

Respiratory or skin sensitisation: Contains (R)-p-mentha-1,8-diene. May produce an allergic reaction.

Germ cell mutagenicity: Based on available data, the classification criteria are not met.

Carcinogenicity: Based on available data, the classification criteria are not met. according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 7/10

Bio-C concentrate Reproductive toxicity: Based on available data, the classification criteria are not met.

STOT-single exposure: Based on available data, the classification criteria are not met.

STOT-repeated exposure: Based on available data, the classification criteria are not met.

Aspiration hazard: Based on available data, the classification criteria are not met.

Additional information: No data available

11.2. Information on other hazards

Endocrine disrupting properties: The product contains a substance that is identified as having endocrine disrupting properties. p-Menth-1-en-8-ol CAS: 98-55-5 ; EC: 202-680-6

SECTION 12: Ecological information 12.1. Toxicity Alcohols, C6-10, ethoxylated propoxylated LC50: 1 – 10 mg/L 4 d (fish)

CAS No.: 68987-81-5 EC No.: 691-266-2

EC50: 1 – 10 mg/L 2 d (crustaceans)

EC50: 1 – 10 mg/L 4 d (Algae/water plant) 120h

(R)-p-mentha-1,8-diene

CAS No.: 5989-27-5 EC No.: 227-813-5

LC50: 0.72 mg/L 4 d (fish, Pimephales promelas (fathead minnow)) OECD 203

isopentyl acetate

CAS No.: 123-92-2 EC No.: 204-662-3

LC50: >22 mg/L (fish)

Aquatic toxicity: Harmful to aquatic life with long lasting effects.

Assessment/classification: There are no data available on the mixture itself.

12.2. Persistence and degradability Alcohols, C6-10, ethoxylated propoxylated Biodegradation: Yes, slowly

(R)-p-mentha-1,8-diene

CAS No.: 68987-81-5 EC No.: 691-266-2

CAS No.: 5989-27-5 EC No.: 227-813-5

Biodegradation: Yes, rapidly

isopentyl acetate

CAS No.: 123-92-2 EC No.: 204-662-3

Biodegradation: Yes, rapidly

Biodegradation: There are no data available on the mixture itself.

12.3. Bioaccumulative potential (R)-p-mentha-1,8-diene Log KOW: 4.83

CAS No.: 5989-27-5 EC No.: 227-813-5

Accumulation / Evaluation: There are no data available on the mixture itself.

12.4. Mobility in soil

There are no data available on the mixture itself.

12.5. Results of PBT and vPvB assessment Alcohols, C6-10, ethoxylated propoxylated

CAS No.: 68987-81-5 EC No.: 691-266-2

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 8/10

Bio-C concentrate (R)-p-mentha-1,8-diene

CAS No.: 5989-27-5 EC No.: 227-813-5

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

isopentyl acetate

CAS No.: 123-92-2 EC No.: 204-662-3

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.

12.6. Endocrine disrupting properties

The product contains a substance that is identified as having endocrine disrupting properties. p-Menth-1-en-8-ol CAS: 98-55-5 ; EC: 202-680-6

12.7. Other adverse effects No data available

SECTION 13: Disposal considerations 13.1. Waste treatment methods

The allocation of waste identity numbers/waste descriptions must be carried out according to the EWC, specific to the industry and process.

13.1.1. Product/Packaging disposal Waste codes/waste designations according to EWC/AVV Waste code product

16 03 05 * organic wastes containing hazardous substances *: Evidence for disposal must be provided.

Waste treatment options

Appropriate disposal / Product: Consult the appropriate local waste disposal expert about waste disposal.

Appropriate disposal / Package: Non-contaminated packages may be recycled.

13.2. Additional information

* = "S" In Switzerland, commercial hazardous waste shall be delivered to a disposal company.

SECTION 14: Transport information Land transport (ADR/RID) Inland waterway craft (ADN)

Sea transport (IMDG)

Air transport (ICAO-TI / IATA-DGR)

No dangerous good in sense of these transport regulations.

No dangerous good in sense of these transport regulations.

No dangerous good in sense of these transport regulations.

No dangerous good in sense of these transport regulations.

No dangerous good in sense of these transport regulations.

No dangerous good in sense of these transport regulations.

No dangerous good in sense of these transport regulations.

No dangerous good in sense of these transport regulations.

not relevant

not relevant

not relevant

not relevant

not relevant

not relevant

not relevant

not relevant

not relevant

not relevant

not relevant

not relevant

not relevant

not relevant

not relevant

not relevant

14.1. UN number or ID number

14.2. UN proper shipping name

14.3. Transport hazard class(es) 14.4. Packing group

14.5. Environmental hazards

14.6. Special precautions for user

14.7. Maritime transport in bulk according to IMO instruments No data available

according to Regulation (EC) No. 2020/878 (REACH)

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SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 9/10

Bio-C concentrate SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU legislation

Restrictions on use: According to directive 94/33/EC, juveniles are only allowed to handle this product as long as all effects of dangerous substances are prevented.

Observe employment restrictions under the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.

Other regulations (EU): Directive 2012/18/EU on the control of major-accident hazards involving dangerous substances [SevesoIII-Directive]: This product is not assigned to a hazard category.

15.1.2. National regulations No data available

15.2. Chemical Safety Assessment

Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information 16.1. Indication of changes 2.3.

Other hazards

16.2. Abbreviations and acronyms ACGIH ADN

ADR CAS CLP DIN DNEL EC50 EN ES EWC ICAO IMDG IMO LC50 LD50 MAK NFPA NIOSH OECD OSHA PBT PC PNEC REACH RID TRGS UN VOC

American Conference of Governmental Industrial Hygienists European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways European Agreement concerning the International Carriage of Dangerous Goods by Road Chemical Abstracts Service Classification, Labelling and Packaging German Institute for Standardization / German Industrial Standard derived no-effect level Effective Concentration 50% European Standard Exposure scenario European Waste Catalogue International Civil Aviation Organization International Maritime Dangerous Goods International Maritime Organization Lethal (fatal) Concentration 50% Lethal (fatal) Dose 50% Maximum concentration in the workplace air (CH) National Fire Protection Association National Institute for Occupational Safety & Health Organisation for Economic Cooperation and Development Occupational Safety & Health Administration persistent and bioaccumulative and toxic Product category Predicted No Effect Concentration Registration, Evaluation and Authorization of Chemicals Dangerous goods regulations for transport by rail Technische Regeln für Gefahrstoffe United Nations Volatile organic compounds

16.3. Key literature references and sources for data

REACH Dissemination Portal https://echa.europa.eu/de/information-on-chemicals/registered-substances

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 10/10

Bio-C concentrate 16.4. Classification for mixtures and used evaluation method according to regulation (EC) No. 1272/2008 [CLP] Hazard classes and hazard categories

Hazard statements

Classification procedure

Hazardous to the aquatic environment H412: Harmful to aquatic life with long Calculation method.

(Aquatic Chronic 3) lasting effects.

16.5. Relevant R-, H- and EUH-phrases (Number and full text) Hazard statements H226

Flammable liquid and vapour.

H315

Causes skin irritation.

H304 H317 H319 H400 H411 H412

May be fatal if swallowed and enters airways.

May cause an allergic skin reaction.

Causes serious eye irritation.

Very toxic to aquatic life.

Toxic to aquatic life with long lasting effects.

Harmful to aquatic life with long lasting effects.

Supplemental hazard information EUH066

Repeated exposure may cause skin dryness or cracking.

16.6. Training advice No data available

16.7. Additional information No data available

* Data changed compared with the previous version.

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de