JOURNYS Issue 5.1

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primary component of a battery. In short, this new ionic liquid is one truly appropriate for advanced electrochemical endeavors involving electrodeposition and, presumably, many other tasks as well. Acknowledgements: The author thanks The Welch Foundation and The University of Texas at Austin for The Welch Summer Scholar Program, which wholly supported this research. He especially thanks Dr. Sankaran Murugesan and Professor Keith J. Stevenson for sponsoring the work in spite of their busy schedules. He also acknowledges the entire Welch Summer Scholar group and staff in the Analytical Chemistry laboratory of the UT Austin Department of Chemistry and Biochemistry for their useful insights and assistance.

REFERENCES: [7]Ong, S. P., Andreussi, O., Wu, Y., Marzari, N., & Ceder, G. (2011, May). Electrochemical windows of room-temperature ionic liquids from molecular dynamics and density functional theory calculations. Chemistry of Materials, 23, 2979-86. [8]Abbott, A. P., Beyersdorff, T., Borisenko, N., Chen, P.-Y., Compton, R. C., Dalrymple, J., . . . El Abedin, S. Z. (2008). Electrodeposition from ionic liquids (F. Endres, A. P. Abbott, & D. R. MacFarlane, Eds.). Berlin, Germany: Wiley-VCH. [9]Snook, G. A., Best, A. S., Pandolfo, A. G., & Hollenkamp, A. F. (2006, June). Evaluation of a AglAg+ reference electrode for use in room temperature ionic liquids. Electrochemistry Communications, 8, 1405-11. [10]Anderson, J. L., Ding, J., Welton, T., & Armstrong, D. W. (2002, November). Characterizing ionic liquids on the basis of multiple solvation interactions. Journal of the American Chemical Society, 124, 14247-54. [11]Sakaebe, H., & Matsumoto, H. (2003, May). N-Methyl-N-propylpiperidinium bis(trifluoromethanesulfonyl)imide (PP13-TFSI): Novel electrolyte for Li battery. Electrochemistry Communications, 5, 594-98. [12]Lee, H.-H., Wang, Y.-Y., Wan, C.-C., Yang, M.-H., Wu, H.-C., & Shieh, D.-Y. (2005, February). The function of vinylene carbonate as a thermal additive to electrolyte in lithium batteries. Journal of Applied Electrochemistry, 35, 615-623.

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ORIGINAL RESEARCH

[1]Liu, Y.-S., & Pan, G.-B. (2011). Ionic liquids for the future electrochemical applications. In A. Kokorin (Ed.), Ionic liquids: Applications and perspectives (pp. 627-42). Rijeka, Croatia: InTech. [2]Matsumoto, H. (2005). Electrochemical windows of room-temperature ionic liquids. In H. Ohno (Ed.), Electrochemical aspects of ionic liquids (pp. 35-54). New York, NY: Wiley. [3]Belhocine, T., Forsyth, S. A., Nimal Gunaratne, H. Q., Nieuwenhuyzen, M., Puga, A. V., Seddon, K. R., & Whiston, K. (2010, November). New ionic liquids from azepane and 3-methylpiperidine exhibiting wide electrochemical windows. Green Chemistry, 13, 59-63. [4]Appetecchi, G. B., Scaccia, S., Tizzani, C., Alessandrini, F., & Passerini, S. (2006, July). Synthesis of hydrophobic ionic liquids for electrochemical applications. Journal of The Electrochemical Society, 153, 1685-91. [5]Matsumoto, H., Sakaebe, H., Tatsumi, K., Kikuta, M., Ishiko, E., & Kono, M. (2006, February). Fast cycling of Li/LiCoO2 cell with low-viscosity ionic liquids based on bis(fluorosulfonyl)imide [FSI]-. Journal of Power Sources, 160, 1308-1313. [6]Yoshida, Y., Muroi, K., Otsuka, A., Saito, G., Takahashi, M., & Yoko, T. (2004, January). 1-Ethyl3-methyimidazolium based ionic liquids containing cyano groups: Synthesis, characterization, and crystal structure. Inorganic Chemistry, 43, 1458-62.


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