IMTS Civil Eng. (Applied thermodynamics)

Page 76

APPLIED THERMODYNAMICS The mass of a gas dissolved in a given volume of the liquid is directly proportional to the pressure of the gas present in equilibrium with the liquid.

where 'm' is the mass of the gas dissolved in a unit volume of the solvent. p is the pressure of the gas in equilibrium with the solvent. k is the proportionality constant called Henry's law constant characteristic of the nature of the solvent and the natures of the gas, also the temperature. Dalton also concluded independently that, solubility of a gas in liquid solution is a function of the partial pressure of the gas. If mole fraction is used to represent the solubility of the gas in the solution, then

where, p is the partial pressure of the gas in solution, x is the mole fraction of the gas in solution and KH is Henry's law constant. Here are the values of Henry's Law Constant (KH) for some selected gases in water �Gas

�Temp/K

�KH/K bar

�He

�293

�144.97

�H2

�293

�69.16

�N2

�293

�76.48

�N2

�303

�88.84

�O2

�293

�34.86

�O2

�393

�46.82

S.A.Q.6 Define Molarity _____________________________________________________________________________ _____________________________________________________________________________ ______________________________________________________________

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