ConformstoRegulation(EC)No.1907/2006(REACH),AnnexII,asamendedbyCommissionRegulation(EU) 2015/830-UnitedKingdom(UK)
SafetyDataSheet
SECTION1:Identificationofthesubstance/mixtureandofthecompany/ undertaking
1.1Productidentifier
Productname :
EN102IEENERO9005CASMLH
Productcode :8211534
Othermeansof identification :EN102I/25KG
1.2Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst Identifieduses
Electrostaticcoatingforuseinindustrialplants
1.3Detailsofthesupplierofthesafetydatasheet
AkzoNobelPowderCoatingsLimited StoneygateLane, Felling, Gateshead. NE100JY
UnitedKingdom
e-mailaddressofperson responsibleforthisSDS :
sdsfellinguk@akzonobel.com
1.4Emergencytelephonenumber
Nationaladvisorybody/PoisonCentre : Telephonenumber
Supplier
Telephonenumber :
Hoursofoperation :
+4401914696111
24hr
SECTION2:Hazardsidentification
2.1Classificationofthesubstanceormixture
Productdefinition :Mixture
ClassificationaccordingtoRegulation(EC)No.1272/2008[CLP/GHS]
Notclassified.
TheproductisnotclassifiedashazardousaccordingtoRegulation(EC)1272/2008asamended.
SeeSection16forthefulltextoftheHstatementsdeclaredabove.
SeeSection11formoredetailedinformationonhealtheffectsandsymptoms.
ConformstoRegulation(EC)No.1907/2006(REACH),AnnexII-UnitedKingdom(UK)
2.2Labelelements
Signalword :
Hazardstatements :
Precautionarystatements
Prevention :
Response :
Storage :
Disposal :
Supplementallabel elements
EN102IEENERO9005CASMLH : Otherhazardswhichdo notresultinclassification
Nosignalword.
Noknownsignificanteffectsorcriticalhazards.
Notapplicable.
Notapplicable. Notapplicable.
Notapplicable.
AnnexXVII-Restrictions onthemanufacture, placingonthemarketand useofcertaindangerous substances,mixturesand articles :Notapplicable.
Specialpackagingrequirements
Containerstobefitted withchild-resistant fastenings
Tactilewarningofdanger Notapplicable. : : :Notapplicable.
2.3Otherhazards
Notapplicable.
Mayformexplosibledust-airmixtureifdispersed.Handlingand/orprocessingof thismaterialmaygenerateadustwhichcancausemechanicalirritationoftheeyes, skin,noseandthroat.
SECTION3:Composition/informationoningredients
3.2Mixtures :Mixture
Therearenoingredientspresentwhich,withinthecurrentknowledgeofthesupplierandintheconcentrations applicable,areclassifiedashazardoustohealthortheenvironment,arePBTsorvPvBsorhavebeenassigneda workplaceexposurelimitandhencerequirereportinginthissection.
SECTION4:Firstaidmeasures
4.1Descriptionoffirstaidmeasures
General
Inallcasesofdoubt,orwhensymptomspersist,seekmedicalattention.Nevergive anythingbymouthtoanunconsciousperson.Ifunconscious,placeinrecovery positionandseekmedicaladvice. :
Removecontactlenses,irrigatecopiouslywithclean,freshwater,holdingthe eyelidsapartforatleast10minutesandseekimmediatemedicaladvice.
Skincontact
Eyecontact : : : :
Ingestion Inhalation
Protectionoffirst-aiders
Removetofreshair.Keeppersonwarmandatrest.Ifnotbreathing,ifbreathingis irregularorifrespiratoryarrestoccurs,provideartificialrespirationoroxygenby trainedpersonnel.
Removecontaminatedclothingandshoes.Washskinthoroughlywithsoapand wateroruserecognisedskincleanser.DoNOTusesolventsorthinners.
Ifswallowed,seekmedicaladviceimmediatelyandshowthecontainerorlabel. Keeppersonwarmandatrest.DoNOTinducevomiting.
:Noactionshallbetakeninvolvinganypersonalriskorwithoutsuitabletraining.
4.2Mostimportantsymptomsandeffects,bothacuteanddelayed
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EN102IEENERO9005CASMLH
Therearenodataavailableonthemixtureitself.Themixturehasbeenassessedfollowingtheconventionalmethod oftheCLPRegulation(EC)No1272/2008andisclassifiedfortoxicologicalpropertiesaccordingly.SeeSections2 and3fordetails.
Thistakesintoaccount,whereknown,delayedandimmediateeffectsandalsochroniceffectsofcomponentsfrom short-termandlong-termexposurebyoral,inhalationanddermalroutesofexposureandeyecontact. Coatingpowderscancauselocalisedskinirritationinfoldsoftheskinorundertightclothing.
4.3Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded
Notestophysician
Specifictreatments
Treatsymptomatically.Contactpoisontreatmentspecialistimmediatelyiflarge quantitieshavebeeningestedorinhaled. :
Nospecifictreatment.:
Seetoxicologicalinformation(Section11)
SECTION5:Firefightingmeasures
Suitableextinguishing media :
Unsuitableextinguishing media :
Recommended:alcohol-resistantfoam,CO₂blanket,watersprayormist.
Donotusewaterjet.
Donotuseinertgasunderhighpressure(e.g.CO2).
5.2Specialhazardsarisingfromthesubstanceormixture
Hazardsfromthe substanceormixture
Hazardousthermal decompositionproducts
5.3Adviceforfirefighters
Specialprotectiveactions forfire-fighters :
5.1Extinguishingmedia : : :
Specialprotective equipmentforfire-fighters
Firewillproducedenseblacksmoke.Exposuretodecompositionproductsmay causeahealthhazard.
Decompositionproductsmayincludethefollowingmaterials:carbonmonoxide, carbondioxide,smoke,oxidesofnitrogen.
Coolclosedcontainersexposedtofirewithwater.Donotreleaserunofffromfireto drainsorwatercourses.
Appropriatebreathingapparatusmayberequired.
SECTION6:Accidentalreleasemeasures
6.1Personalprecautions,protectiveequipmentandemergencyprocedures
Fornon-emergency personnel :
Excludesourcesofignitionandventilatethearea.Avoidbreathingdust.Referto protectivemeasureslistedinsections7and8.
Foremergencyresponders:Ifspecialisedclothingisrequiredtodealwiththespillage,takenoteofany informationinSection8onsuitableandunsuitablematerials.Seealsothe informationin"Fornon-emergencypersonnel". :
6.2Environmental precautions
Donotallowtoenterdrainsorwatercourses.Iftheproductcontaminateslakes, rivers,orsewers,informtheappropriateauthoritiesinaccordancewithlocal regulations.
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6.3Methodsandmaterial forcontainmentand cleaningup
6.4Referencetoother sections
Containandcollectspillagewithanelectricallyprotectedvacuumcleanerorbywetbrushingandplaceincontainerfordisposalaccordingtolocalregulations(see section13).Donotuseadrybrushasdustcloudsorstaticcanbecreated.
SeeSection1foremergencycontactinformation.
SeeSection8forinformationonappropriatepersonalprotectiveequipment. SeeSection13foradditionalwastetreatmentinformation.
SECTION7:Handlingandstorage
Theinformationinthissectioncontainsgenericadviceandguidance.ThelistofIdentifiedUsesinSection1shouldbe consultedforanyavailableuse-specificinformationprovidedintheExposureScenario(s).
Adviceshouldbetakenfromacompetentoccupationalhealthpractitionerontheassessmentofemployees withskinorrespiratorycomplaintsbeforetheindividualisexposedtotheuncuredproduct.
7.1Precautionsforsafe handling :
Precautionsshouldbetakentopreventtheformationofdustsinconcentrations aboveflammable,explosiveoroccupationalexposurelimits.
Electricalequipmentandlightingshouldbeprotectedtoappropriatestandardsto preventdustcomingintocontactwithhotsurfaces,sparksorotherignitionsources. Mixturemaychargeelectrostatically:alwaysuseearthingleadswhentransferring fromonecontainertoanother.
Operatorsshouldwearantistaticfootwearandclothingandfloorsshouldbeofthe conductingtype.
Keepawayfromheat,sparksandflame.
Avoidcontactwithskinandeyes.Avoidtheinhalationofdust,particulates,sprayor mistarisingfromtheapplicationofthismixture.Avoidinhalationofdustfrom sanding.
Eating,drinkingandsmokingshouldbeprohibitedinareaswherethismaterialis handled,storedandprocessed.
Putonappropriatepersonalprotectiveequipment(seeSection8).
Alwayskeepincontainersmadefromthesamematerialastheoriginalone. Complywiththehealthandsafetyatworklaws.
Donotallowtoenterdrainsorwatercourses.
7.2Conditionsforsafestorage,includinganyincompatibilities
Storeinaccordancewithlocalregulations. Additionalinformationonstorageconditions
Observelabelprecautions.Storeinadry,coolandwell-ventilatedarea.Keepawayfromheatanddirectsunlight. Keepcontainertightlyclosed.
Keepawayfromsourcesofignition.Nosmoking.Preventunauthorisedaccess.Containersthathavebeenopened mustbecarefullyresealedandkeptuprighttopreventleakage.
7.3Specificenduse(s)
Recommendations : :
Industrialsectorspecific solutions
Notavailable.
Notavailable.
SECTION8:Exposurecontrols/personalprotection
Theinformationinthissectioncontainsgenericadviceandguidance.Informationisprovidedbasedontypical anticipatedusesoftheproduct.Additionalmeasuresmightberequiredforbulkhandlingorotherusesthatcould significantlyincreaseworkerexposureorenvironmentalreleases.
8.1Controlparameters
Occupationalexposurelimits
Product/ingredientname
bariumsulfate
Exposurelimitvalues
EH40/2005WELs(UnitedKingdom(UK),12/2011).
TWA:10mg/m³8hours.Form:inhalabledust
TWA:4mg/m³8hours.Form:respirabledust magnesiumcarbonate
EH40/2005WELs(UnitedKingdom(UK),12/2011).
TWA:10mg/m³8hours.Form:inhalabledust
TWA:4mg/m³8hours.Form:respirabledust
Recommendedmonitoring procedures
Ifthisproductcontainsingredientswithexposurelimits,personal,workplace atmosphereorbiologicalmonitoringmayberequiredtodeterminetheeffectiveness oftheventilationorothercontrolmeasuresand/orthenecessitytouserespiratory protectiveequipment.Referenceshouldbemadetomonitoringstandards,suchas thefollowing:EuropeanStandardEN689(Workplaceatmospheres-Guidancefor theassessmentofexposurebyinhalationtochemicalagentsforcomparisonwith limitvaluesandmeasurementstrategy)EuropeanStandardEN14042(Workplace atmospheres-Guidefortheapplicationanduseofproceduresfortheassessment ofexposuretochemicalandbiologicalagents)EuropeanStandardEN482 (Workplaceatmospheres-Generalrequirementsfortheperformanceofprocedures forthemeasurementofchemicalagents)Referencetonationalguidance documentsformethodsforthedeterminationofhazardoussubstanceswillalsobe required. :
DNELs/DMELs
NoDNELs/DMELsavailable.
PNECs
NoPNECsavailable
8.2Exposurecontrols
Individualprotectionmeasures
Hygienemeasures :
Avoidbreathingdust.Wherereasonablypracticable,thisshouldbeachievedbythe useoflocalexhaustventilationandgoodgeneralextraction.Ifthesearenot sufficienttomaintainexposuretodustsbelowtheOEL,suitablerespiratory protectionmustbeworn.
Appropriateengineering controls : Washhands,forearmsandfacethoroughlyafterhandlingchemicalproducts,before eating,smokingandusingthelavatoryandattheendoftheworkingperiod. Appropriatetechniquesshouldbeusedtoremovepotentiallycontaminatedclothing. Washcontaminatedclothingbeforereusing.Ensurethateyewashstationsand safetyshowersareclosetotheworkstationlocation.
Eye/faceprotection :
Skinprotection
Handprotection
Gloves
Safetyeyewearshouldbeusedwhenthereisalikelihoodofexposure.
Forprolongedorrepeatedhandling,usethefollowingtypeofgloves: Butylgloves.(EN374). orNitrilegloves.(EN374).
Theinstructionsandinformationprovidedbytheglovemanufactureronuse, storage,maintenanceandreplacementmustbefollowed.Barriercreamsmayhelp toprotecttheexposedareasoftheskinbutshouldnotbeappliedonceexposure hasoccurred.
Theusermustcheckthatthefinalchoiceoftypeofgloveselectedforhandlingthis productisthemostappropriateandtakesintoaccounttheparticularconditionsof use,asincludedintheuser'sriskassessment.
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EN102IEENERO9005CASMLH
Bodyprotection :
Otherskinprotection
Respiratoryprotection : :
Personnelshouldwearprotectiveclothing.Careshouldbetakenintheselectionof protectiveclothingtoensurethatinflammationandirritationoftheskinattheneck andwriststhroughcontactwiththepowderareavoided.
Appropriatefootwearandanyadditionalskinprotectionmeasuresshouldbe selectedbasedonthetaskbeingperformedandtherisksinvolvedandshouldbe approvedbyaspecialistbeforehandlingthisproduct.
Basedonthehazardandpotentialforexposure,selectarespiratorthatmeetsthe appropriatestandardorcertification.Respiratorsmustbeusedaccordingtoa respiratoryprotectionprogramtoensureproperfitting,training,andotherimportant aspectsofuse.Drysanding,flamecuttingand/orweldingofthedrypaintfilmwill giverisetodustand/orhazardousfumes.Wetsanding/flattingshouldbeused whereverpossible.Ifexposurecannotbeavoidedbytheprovisionoflocalexhaust ventilation,suitablerespiratoryprotectiveequipmentshouldbeused.
Environmentalexposure controls :
Donotallowtoenterdrainsorwatercourses.
SECTION9:Physicalandchemicalproperties
9.1Informationonbasicphysicalandchemicalproperties
Appearance
Solid.[Powder.]
Odourthreshold :Notavailable.
Meltingpoint/freezingpoint :Notavailable. Initialboilingpointand boilingrange :Notavailable.
Closedcup:Notapplicable. Notapplicable.
Evaporationrate :Notavailable. :Notavailable. Flammability(solid,gas)
Upper/lowerflammabilityor explosivelimits
Vapourpressure :Notavailable.
1.2to1.9[ISO8130-2/-3]
Notavailable. Insolubleinthefollowingmaterials:coldwaterandhotwater.
Decompositiontemperature :Notavailable.
Partitioncoefficient:n-octanol/ water :Notavailable. Notavailable.
Viscosity Notavailable.
Oxidisingproperties :
Explosiveproperties : : Notavailable.
Minimumignitionenergy(mJ):
9.2Otherinformation
Inoperationswherethepowderisrecoveredforreuse,theaverageparticlesizemaychangeandthisinturncanlead toanalterationinMIE.
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SECTION10:Stabilityandreactivity
10.1Reactivity :Nospecifictestdatarelatedtoreactivityavailableforthisproductoritsingredients.
Stableunderrecommendedstorageandhandlingconditions(seeSection7).
10.3Possibilityof hazardousreactions :
Undernormalconditionsofstorageanduse,hazardousreactionswillnotoccur.
10.4Conditionstoavoid Whenexposedtohightemperaturesmayproducehazardousdecomposition products.
10.5Incompatiblematerials:
10.2Chemicalstability : : :
10.6Hazardous decompositionproducts
Notapplicable.
Undernormalconditionsofstorageanduse,hazardousdecompositionproducts shouldnotbeproduced.
SECTION11:Toxicologicalinformation
11.1Informationontoxicologicaleffects
Therearenodataavailableonthemixtureitself.Themixturehasbeenassessedfollowingtheconventionalmethod oftheCLPRegulation(EC)No1272/2008andisclassifiedfortoxicologicalpropertiesaccordingly.SeeSections2 and3fordetails.
Thistakesintoaccount,whereknown,delayedandimmediateeffectsandalsochroniceffectsofcomponentsfrom short-termandlong-termexposurebyoral,inhalationanddermalroutesofexposureandeyecontact.
Coatingpowderscancauselocalisedskinirritationinfoldsoftheskinorundertightclothing.
Acutetoxicity
Conclusion/Summary :Notavailable.
Acutetoxicityestimates
Notavailable.
Irritation/Corrosion
Conclusion/Summary :Notavailable.
Sensitisation
Conclusion/Summary :Notavailable.
Mutagenicity
Conclusion/Summary :Notavailable.
Carcinogenicity
Conclusion/Summary :Notavailable.
Reproductivetoxicity
Conclusion/Summary :Notavailable.
Teratogenicity
Conclusion/Summary :Notavailable.
Specifictargetorgantoxicity(singleexposure)
Notavailable.
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Specifictargetorgantoxicity(repeatedexposure)
Notavailable.
Aspirationhazard
Notavailable.
Otherinformation :
Notavailable.
SECTION12:Ecologicalinformation
12.1Toxicity
Therearenodataavailableonthemixtureitself.
Coatingpowderresiduesshouldnotbeallowedtoenterdrainsorwatercoursesorbedepositedwheretheycould affectgroundorsurfacewaters.
ThemixturehasbeenassessedfollowingthesummationmethodoftheCLPRegulation(EC)No1272/2008andis notclassifiedashazardoustotheenvironment.
Conclusion/Summary :Notavailable.
12.2Persistenceanddegradability
Conclusion/Summary :Notavailable.
12.3Bioaccumulativepotential
Notavailable.
12.4Mobilityinsoil
Soil/waterpartition coefficient(KOC)
Mobility
Notavailable.:
Notavailable.:
12.5ResultsofPBTandvPvBassessment :
PBT :Notapplicable.
vPvB :Notapplicable.
12.6Otheradverseeffects
Noknownsignificanteffectsorcriticalhazards.
SECTION13:Disposalconsiderations
Theinformationinthissectioncontainsgenericadviceandguidance.ThelistofIdentifiedUsesinSection1shouldbe consultedforanyavailableuse-specificinformationprovidedintheExposureScenario(s).
Donotallowtoenterdrainsorwatercourses. Disposeofaccordingtoallfederal,stateandlocalapplicableregulations.
Ifthisproductismixedwithotherwastes,theoriginalwasteproductcodemaynolongerapplyandtheappropriate codeshouldbeassigned.
Forfurtherinformation,contactyourlocalwasteauthority.
13.1Wastetreatmentmethods
Product
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Methodsofdisposal
:
Thegenerationofwasteshouldbeavoidedorminimisedwhereverpossible. Disposalofthisproduct,solutionsandanyby-productsshouldatalltimescomply withtherequirementsofenvironmentalprotectionandwastedisposallegislation andanyregionallocalauthorityrequirements.Disposeofsurplusandnonrecyclableproductsviaalicensedwastedisposalcontractor.Wasteshouldnotbe disposedofuntreatedtothesewerunlessfullycompliantwiththerequirementsof allauthoritieswithjurisdiction.
Hazardouswaste :
Withinthepresentknowledgeofthesupplier,thisproductisnotregardedas hazardouswaste,asdefinedbyEUDirective2008/98/EC.
Europeanwastecatalogue(EWC)
Packaging
Methodsofdisposal :
Thegenerationofwasteshouldbeavoidedorminimisedwhereverpossible.Waste packagingshouldberecycled.Incinerationorlandfillshouldonlybeconsidered whenrecyclingisnotfeasible.
Disposalconsiderations
Typeofpackaging
CEPEPaintGuidelines
:Usinginformationprovidedinthissafetydatasheet,adviceshouldbeobtainedfrom therelevantwasteauthorityontheclassificationofemptycontainers. Emptycontainersmustbescrappedorreconditioned.
Disposeofcontainerscontaminatedbytheproductinaccordancewithlocalor nationallegalprovisions.
Europeanwastecatalogue(EWC)
Specialprecautions :
Thismaterialanditscontainermustbedisposedofinasafeway.Empty containersorlinersmayretainsomeproductresidues.Avoiddispersalofspilt materialandrunoffandcontactwithsoil,waterways,drainsandsewers.
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14.6Specialprecautionsfor user
14.7Transportinbulk accordingtoAnnexIIof MarpolandtheIBCCode
Transportwithinuser’spremises:alwaystransportinclosedcontainersthatare uprightandsecure.Ensurethatpersonstransportingtheproductknowwhattodoin theeventofanaccidentorspillage. :
:Notavailable.
SECTION15:Regulatoryinformation
15.1Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture
EURegulation(EC)No.1907/2006(REACH)
AnnexXIV-Listofsubstancessubjecttoauthorisation
AnnexXIV
Noneofthecomponentsarelisted.
Substancesofveryhighconcern
Noneofthecomponentsarelisted.
AnnexXVII-Restrictions onthemanufacture, placingonthemarket anduseofcertain dangeroussubstances, mixturesandarticles :
OtherEUregulations
VOC :
Notapplicable.
Notapplicable.
VOCforReady-for-Use Mixture :Notapplicable.
Europeinventory :Notdetermined.
Ozonedepletingsubstances(1005/2009/EU)
Notlisted.
PriorInformedConsent(PIC)(649/2012/EU)
Notlisted.
SevesoDirective
ThisproductisnotcontrolledundertheSevesoDirective.
Nationalregulations
Industrialuse
Internationalregulations
:Theinformationcontainedinthissafetydatasheetdoesnotconstitutetheuser’s ownassessmentofworkplacerisks,asrequiredbyotherhealthandsafety legislation.Theprovisionsofthenationalhealthandsafetyatworkregulationsapply totheuseofthisproductatwork.
ChemicalWeaponConventionListSchedulesI,II&IIIChemicals
Notlisted.
MontrealProtocol(AnnexesA,B,C,E)
Notlisted.
StockholmConventiononPersistentOrganicPollutants
Notlisted.
RotterdamConventiononPriorInformConsent(PIC)
Notlisted.
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UNECEAarhusProtocolonPOPsandHeavyMetals
Notlisted.
Internationallists
Nationalinventory
Australia :Allcomponentsarelistedorexempted.
Canada :Allcomponentsarelistedorexempted.
China :Allcomponentsarelistedorexempted.
Japan :Japaninventory(ENCS):Notdetermined. Japaninventory(ISHL):Notdetermined.
Malaysia :Notdetermined.
NewZealand :Notdetermined.
Philippines :Notdetermined.
RepublicofKorea :Allcomponentsarelistedorexempted.
Taiwan :Allcomponentsarelistedorexempted.
Turkey :Notdetermined.
UnitedStates :Allcomponentsarelistedorexempted.
15.2Chemicalsafety assessment
NoChemicalSafetyAssessmenthasbeencarriedout.:
SECTION16:Otherinformation
CEPEcode :3
Indicatesinformationthathaschangedfrompreviouslyissuedversion.
Abbreviationsand acronyms
:
ATE=AcuteToxicityEstimate
CLP=Classification,LabellingandPackagingRegulation[Regulation(EC)No. 1272/2008]
DMEL=DerivedMinimalEffectLevel
DNEL=DerivedNoEffectLevel
EUHstatement=CLP-specificHazardstatement
PBT=Persistent,BioaccumulativeandToxic PNEC=PredictedNoEffectConcentration
RRN=REACHRegistrationNumber
vPvB=VeryPersistentandVeryBioaccumulative
ProcedureusedtoderivetheclassificationaccordingtoRegulation(EC)No.1272/2008[CLP/GHS]
Notclassified.
FulltextofabbreviatedHstatements
Notapplicable.
Fulltextofclassifications[CLP/GHS]
Notapplicable.
Dateofprinting
Dateofissue/Dateof revision
Version
Dateofpreviousissue : : : : Trainingadvice :Notavailable.
Noticetoreader
TheinformationinthisSafetyDataSheetisbasedonthepresentstateofknowledgeandcurrentlegislation. Itprovidesguidanceonhealth,safetyandenvironmentalaspectsoftheproductandshouldnotbe construedasanyguaranteeoftechnicalperformanceorsuitabilityforparticularapplications.Theproduct shouldnotbeusedforpurposesotherthanthoseshowninSection1withoutfirstreferringtothesupplier andobtainingwrittenhandlinginstructions.Asthespecificconditionsofuseoftheproductareoutsidethe supplier’scontrol,theuserisresponsibleforensuringthattherequirementsofrelevantlegislationare compliedwith.Theinformationcontainedinthissafetydatasheetdoesnotconstitutetheuser’sown assessmentofworkplacerisks,asrequiredbyotherhealthandsafetylegislation.