Fugacidad y Actividad

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EQUILIBRIO LIQUIDO VAPOR

Tabla No. 5

ECUACIÓN NRTL: CONSTANTES PARA MEZCLAS BINARIAS SISTEMA 1 2 3 4 5 6 7 8 9

Acetona (1) Agua (2) Metanol (1) Agua (2) 1-Propanol (1) Agua (2) Agua (1) 1,4-Dioxano (2) Metanol (1) Acetonitrilo (2) Acetona (1) Metanol (2) Metil acetato (1) Metanol (2) Metanol (1) Benceno (2) Etanol (1) Tolueno (2)

VOLUMEN MOLAR [cm3/mol] 74.05 18.07 40.73 18.07 75.14 18.07 18.07 85.71 40.73 66.3 74.05 40.73 79.84 40.73 40.73 89.41 58.68 106.85

PARÁMETROS NRTL b12 [cal/mol] b21 [cal/mol]

α

631.05

1,197.41

0.5343

-253.88

845.21

0.2994

500.4

1,636.57

0.5081

715.96

548.9

0.292

343.7

314.59

0.2981

184.7

222.64

0.3084

381.46

346.54

0.2965

730.09

1,175.41

0.4743

713.57

1,147.86

0.5292

Ref.: Smith, J.M.; Van Ness,H.C. & Abbott,M.M. (2001). Introduction to Chemical Engineering Thermodynamics. 6th edition.

Ing. Federico G. Salazar

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