MSDS Eccellente milk system cleaner by Everlake

accordingtoRegulation(EC)No.1907/2006(REACH)

ArticleNo.:520.256.1382 Printdate:01.07.2016 Version:2-0

Eccellentemelksysteem Revisiondate:01.07.2016 199999EN Issuedate:01.07.2016 Page1/8

SECTION1:Identificationofthesubstance/mixtureandofthecompany/undertaking

1.1.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst ArticleNo.(manufacturer/supplier): Identificationofthesubstanceormixture 520.256.1382 Eccellentemelksysteem reiniger

1.2.Detailsofthesupplierofthesafetydatasheet

Relevantidentifieduses forcleaning Usesadvisedagainst Thereisnoinformationavailableforuseisdiscouragedfacing.

1.3.Detailsofthesupplierofthesafetydatasheet supplier(manufacturer/importer/downstreamuser/distributor) Everlake Steenhouwerstraat2 NL-8601WDSneek TheNetherlands

Telephone:+31(0)515712085 Telefax: E-mailcontact@everlake.eu Homepage:www.everlake.eu Dept.responsibleforinformation:

E-mail(competentperson) contact@everlake.eu

1.4.Emergencytelephonenumber

NationalPoisonphonenumberInformation Centrum(NVIC): +3130-2748888

Exclusivelyintendedforhealthcareprofessionalsinacutepoisoning.

*Datachangedcomparedwiththepreviousversion

SECTION2:Hazardsidentification

2.1.Classificationofthesubstanceormixture

ClassificationaccordingtoRegulation(EC)No1272/2008[CLP]

Thismixtureisclassifiedashazardousaccordingtoregulation(EC)No1272/2008[CLP].

SkinCorr.1/H314skincorrosion/irritation

Causessevereskinburnsandeyedamage. EyeDam.1/H318Seriouseyedamage/eyeirritationCausesseriouseyedamage.

*Datachangedcomparedwiththepreviousversion

2.2.Labelelements

TheproductisclassifiedandlabelledaccordingtoECdirectivesorcorrespondingnationallaws.

LabellingaccordingtoRegulation(EC)No.1272/2008[CLP]

Hazardpictograms

Danger

Hazardstatements

H314 Causessevereskinburnsandeyedamage.

*Datachangedcomparedwiththepreviousversion

Precautionarystatements

P101 Ifmedicaladviceisneeded,haveproductcontainerorlabelathand.

P102 Keepoutofthereachofchildren.

P103 Readlabelbeforeuse.

P264 Washhandsthoroughlyafterhandling.

P302+P352IFONSKIN:Washwithplentyofsoapandwater.

P305+P351+P338IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontactlenses,ifpresentand easytodo.Continuerinsing.

P310 Immediatelycalladoctor.

P332+P313Ifskinirritationoccurs:Getmedicaladvice/attention.

P362+P364Takeoffcontaminatedclothingandwashitbeforereuse.

SafetyDataSheet

ArticleNo.:520.256.1382 Printdate:01.07.2016 Version:2-0

Eccellentemelksysteem Revisiondate:01.07.2016 199999EN Issuedate:01.07.2016 Page2/8

*Datachangedcomparedwiththepreviousversion contains: ethoxylatedfattyalcohol

*Datachangedcomparedwiththepreviousversion

SupplementalHazardinformation(EU) notapplicable

*Datachangedcomparedwiththepreviousversion

3.1.

Notapplicable.

Productdescription/chemicalcharacterization

DescriptionCleaningagent,alkaline

Hazardousingredients

ClassificationaccordingtoRegulation(EC)No1272/2008[CLP]

CASNo. INDEXNo.

REACHNo.

Wt%

12,5-20 205-483-3 141-43-5 603-030-00-8

160875-66-1ethoxylatedfattyalcohol AcuteTox.4H302/EyeDam.1H318

01-2119486455-28-0000 2-aminoethanol AcuteTox.4H332/AcuteTox.4H312/AcuteTox.4H302/SkinCorr. 1BH314

1-2,5 215-687-4 1344-09-8 01-2119448725-31-xxxx sodiumsilicate(MR>3.2) SkinIrrit.2H315/EyeDam.1H318

0,5-1

SafetyDataSheet accordingtoRegulation(EC)No.1907/2006(REACH)

2.3.Otherhazards SECTION3:Composition/informationoningredients

Substances

3.2.Mixtures

ECNo.

Chemicalname classification://Remark

Additionalinformation Fulltextofclassification:seesection16 Hazardousingredients *Datachangedcomparedwiththepreviousversion Labellingforcontentsaccordingtoregulation(EC)No.648/2004: Wt% Ingredient(Designation) 5-15%non-ionicsurfactants <5% anionicsurfactants *Datachangedcomparedwiththepreviousversion SECTION4:Firstaidmeasures 4.1.Descriptionoffirstaidmeasures Generalinformation Takeoffimmediatelyallcontaminatedclothing.Incaseofunconsciousnessgivenothingbymouth,placeinrecoveryposition andseekmedicaladvice.Inallcasesofdoubt,orwhensymptomspersist,seekmedicaladvice. Incaseofinhalation Removecasualtytofreshairandkeepwarmandatrest.Providefreshair.Whenindoubtorifsymptomsareobserved,get medicaladvice. Followingskincontact Takeoffimmediatelyallcontaminatedclothing.Rinseskinwithwater/shower.Ifskinirritationoccurs:Getmedical advice/attention. Aftereyecontact

accordingtoRegulation(EC)No.1907/2006(REACH)

ArticleNo.:520.256.1382

Printdate:01.07.2016

Version:2-0

Eccellentemelksysteem Revisiondate:01.07.2016 199999EN Issuedate:01.07.2016 Page3/8

IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontactlenses,ifpresentandeasytodo.Continue rinsing.Incaseofeyeirritationconsultanophthalmologist.

Afteringestion

Ifswallowed,rinsemouthwithwater(onlyifthepersonisconscious).Keepvictimcalm.DoNOTinducevomiting.Calla physicianimmediately.Ifmedicaladviceisneeded,haveproductcontainerorlabelathand.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed

Inallcasesofdoubt,orwhensymptomspersist,seekmedicaladvice.

4.3.Mammaliancells(withmetabolicactivation)

Nodataavailable *

*Datachangedcomparedwiththepreviousversion

SECTION5:Firefightingmeasures

5.1.Extinguishingmedia

Suitableextinguishingmedia:

Extinguishingpowder,Carbondioxide(CO2),spraymist,(water)

Extinguishingmediawhichmustnotbeusedforsafetyreasons: strongwaterjet

5.2.Specialhazardsarisingfromthesubstanceormixture

Inhalinghazardousdecomposingproductscancauseserioushealthdamage.

5.3.Adviceforfirefighters

Wearsuitableprotectiveclothing.

*Datachangedcomparedwiththepreviousversion

SECTION6:Accidentalreleasemeasures

6.1.Personalprecautions,protectiveequipmentandemergencyprocedures

Usepersonalprotectionequipment.Donotbreathevapours.Seeprotectivemeasuresunderpoint7and8.

6.2.Environmentalprecautions

Donotallowtoenterintosurfacewaterordrains.Iftheproductcontaminateslakes,riversorsewages,informcompetent authoritiesinaccordancewithlocalregulations.

6.3.Methodsandmaterialforcontainmentandcleaningup

Isolateleakedmaterialusingnon-flammableabsorptionagent(e.g.sand,earth,vermiculit,diatomaceousearth)andcollectit fordisposalinappropriatecontainersinaccordancewiththelocalregulations(seesection13).Treattherecoveredmaterial asprescribedinthesectiononwastedisposal.Provideadequateventilation.

SafetyDataSheet

6.4.Referencetoothersections Observeprotectiveprovisions(seechapter7and8). *Datachangedcomparedwiththepreviousversion SECTION7:Handlingandstorage 7.1.Precautionsforsafehandling Advicesonsafehandling Precautionsagainstfireandexplosion: non-combustibleliquidsthatcannotbeassignedtoanyoftheabovestorageclasses 7.2.Conditionsforsafestorage,includinganyincompatibilities Requirementsforstorageroomsandvessels Stablewhenapplyingtherecommendedregulationsforstorageandhandling.Furtherinformationoncorrectstorage:referto chapter7.Keepcontainertightlyclosed.Donotemptycontainerswithpressure-nopressurevessel!Smokingisforbidden. Accessonlyforauthorisedpersons.Storecarefullyclosedcontainersuprighttopreventanyleaks. Hintsonjointstorage Keepawayfromstronglyacidicandalkalinematerialsaswellasoxidizers. Furtherinformationonstorageconditions Takecareofinstructionsonlabel.Storeinawell-ventilatedanddryroomattemperaturesbetween20°Cand20°C.Protect fromheatanddirectsunlight.Keepcontainertightlyclosed.Removeallsourcesofignition.Smokingisforbidden.Access onlyforauthorisedpersons.Storecarefullyclosedcontainersuprighttopreventanyleaks.

accordingtoRegulation(EC)No.1907/2006(REACH)

ArticleNo.:520.256.1382

Printdate:01.07.2016

Version:2-0

7.3.Specificenduse(s)

Eccellentemelksysteem Revisiondate:01.07.2016 199999EN Issuedate:01.07.2016 Page4/8

Observetechnicaldatasheet.Observeinstructionsforuse,Noticethedirectionsforuseonthelabel.

*Datachangedcomparedwiththepreviousversion

SECTION8:Exposurecontrols/personalprotection

8.1.Controlparameters

Occupationalexposurelimitvalues

2-aminoethanol

INDEXNo.603-030-00-8/ECNo.205-483-3/CASNo.141-43-5

WEL,TWA:2,5mg/m3;1ppm

WEL,STEL:7,6mg/m3;3ppm

Additionalinformation

TWA:long-termoccupationalexposurelimitvalue

STEL:short-termoccupationalexposurelimitvalue

Ceiling:peaklimitation

*Datachangedcomparedwiththepreviousversion

8.2.Exposurecontrols

Providegoodventilation.Thiscanbeachievedwithlocalorroomsuction.

Occupationalexposurecontrols

Respiratoryprotection

Usuallynopersonalrespirativeprotectionnecessary.

Handprotection

Forprolongedorrepeatedhandlingthefollowingglovematerialmustbeused:NBR(Nitrilerubber)/NBR(Nitrile rubber)Observetheinstructionsanddetailsforuse,storage,maintenanceandreplacementprovidedbytheprotectiveglove manufacturer.Penetrationtimeofglovematerialdependingonintensityanddurationofexposuretoskin:Recommended glovearticlesDINEN374Barriercreamscanhelpprotectingexposedskinareas.Innocaseshouldtheybeusedafter contact.

Eyeprotection

Wearcloselyfittingprotectiveglassesincaseofsplashes.

Protectiveclothing

Wearprotectiveglovesandprotectiveclothing.

Protectivemeasures

Aftercontactcleanskinthoroughlywithwaterandsoaporuseappropriatecleanser.

Environmentalexposurecontrols

Donotallowtoenterintosurfacewaterordrains.Seechapter7.Noadditionalmeasuresnecessary.

SafetyDataSheet

SECTION9:Physicalandchemicalproperties 9.1.Informationonbasicphysicalandchemicalproperties * Appearance: Physicalstate: liquid Colour: refertolabel Odour: characteristic Odourthreshold: notdetermined pHat20°C: 11,65 Meltingpoint/freezingpoint: notdetermined Initialboilingpointandboilingrange:notdetermined Flashpoint: >100°C Evaporationrate: notdetermined Flammability(solid,gas): burningtime(s): notdetermined Upper/lowerflammabilityorexplosivelimits: Lowerexplosionlimit: notdetermined

accordingtoRegulation(EC)No.1907/2006(REACH)

ArticleNo.:520.256.1382

Printdate:01.07.2016 Version:2-0

Eccellentemelksysteem Revisiondate:01.07.2016 199999EN Issuedate:01.07.2016 Page5/8

Upperexplosionlimit: notdetermined

Vapourpressureat20°C: 33,2544mbar

Vapourdensity: notdetermined

Relativedensity: Densityat20°C: 1,03g/cm³ Method:ISO2811,part1

Solubility(ies):

Watersolubility(g/L)at20°C: completelymiscible

Partitioncoefficient:n-octanol/water:Seesection12.

Auto-ignitiontemperature: notdetermined

Decompositiontemperature: notdetermined

Viscosityat20°C: >12s4mm Method:DIN53211

Explosiveproperties: notapplicable

Oxidisingproperties: notapplicable

9.2.Otherinformation *

Solidcontent(%): 6,89Wt%

solventcontent: Organicsolvents: 1Wt% Water: 69Wt%

Solventseparationtest(%): <3Wt%(ADR/RID)

Nodataavailable

*Datachangedcomparedwiththepreviousversion

SECTION10:Stabilityandreactivity

10.1.Reactivity

10.2.

10.3.

10.4.

Nodataavailable

Stablewhenapplyingtherecommendedregulationsforstorageandhandling.Furtherinformationoncorrectstorage:referto chapter7.

Keepawayfromstrongacids,strongbasesandstrongoxidizingagentstoavoidexothermicreactions.

Stablewhenapplyingtherecommendedregulationsforstorageandhandling.Furtherinformationoncorrectstorage:referto chapter7.Hazardousdecompositionbyproductsmayformwithexposuretohightemperatures.

10.5.

10.6.

Nodataavailable

SECTION11:Toxicologicalinformation

ClassificationaccordingtoRegulation(EC)No1272/2008[CLP]

Nodataonpreparationitselfavailable.

11.1.

*Datachangedcomparedwiththepreviousversion

Acutetoxicity

ethoxylatedfattyalcohol oral,LD50,Rat:>500mg/kg

*Datachangedcomparedwiththepreviousversion skincorrosion/irritation;Seriouseyedamage/eyeirritation ethoxylatedfattyalcohol

SafetyDataSheet

Chemicalstability

Possibilityofhazardousreactions

Conditionstoavoid

Incompatiblematerials

Hazardousdecompositionproducts none

Informationontoxicologicaleffects

accordingtoRegulation(EC)No.1907/2006(REACH)

ArticleNo.:520.256.1382

Printdate:01.07.2016

Version:2-0

eyes

Eccellentemelksysteem Revisiondate:01.07.2016 199999EN Issuedate:01.07.2016 Page6/8

*Datachangedcomparedwiththepreviousversion

Respiratoryorskinsensitisation

Toxicologicaldataarenotavailable.

*Datachangedcomparedwiththepreviousversion

CMReffects(carcinogenicity,mutagenicityandtoxicityforreproduction)

Toxicologicaldataarenotavailable.

*Datachangedcomparedwiththepreviousversion

Specifictargetorgantoxicity

Toxicologicaldataarenotavailable.

*Datachangedcomparedwiththepreviousversion

Aspirationhazard

Toxicologicaldataarenotavailable.

*Datachangedcomparedwiththepreviousversion

Practicalexperience/humanevidence

Otherobservations:

Noknownsymptomstodate.Solventsmaycausesomeoftheaforementionedeffectsthroughskinresorption.Repeatedor prolongedcontactwiththepreparationmaycauseremovalofnaturalfatfromtheskinresultinginnon-allergiccontact dermatitisand/orabsorptionthroughskin.Splashingmaycauseeyeirritationandreversibledamage.

OverallAssessmentonCMRproperties

TheingredientsinthismixturedonotmeetthecriteriaforclassificationasCMRcategory1Aor1BaccordingtoCLP. Remark

Thereisnoinformationavailableonthepreparationitself.

SECTION12:Ecologicalinformation

overallevaluation

ClassificationaccordingtoRegulation(EC)No1272/2008[CLP]

Thereisnoinformationavailableonthepreparationitself. Donotallowtoenterintosurfacewaterordrains.

*Datachangedcomparedwiththepreviousversion

12.1.Toxicity

ethoxylatedfattyalcohol

Daphniatoxicity,EC50:10-100mg/L(48h)

*Datachangedcomparedwiththepreviousversion

Long-termEcotoxicity

Toxicologicaldataarenotavailable.

*Datachangedcomparedwiththepreviousversion

12.2.Persistenceanddegradability

ethoxylatedfattyalcohol :>60%(28D)

Method:OECD301B/ISO9439/EEC92/69/V,C.4-C

*Datachangedcomparedwiththepreviousversion

12.3.Bioaccumulativepotential

Toxicologicaldataarenotavailable.

*Datachangedcomparedwiththepreviousversion Bioconcentrationfactor(BCF)

Toxicologicaldataarenotavailable.

*Datachangedcomparedwiththepreviousversion

SafetyDataSheet

accordingtoRegulation(EC)No.1907/2006(REACH)

ArticleNo.:520.256.1382 Printdate:01.07.2016 Version:2-0

12.4.Mobilityinsoil

Eccellentemelksysteem Revisiondate:01.07.2016 199999EN Issuedate:01.07.2016 Page7/8

Toxicologicaldataarenotavailable.

*Datachangedcomparedwiththepreviousversion

12.5.ResultsofPBTandvPvBassessment

ThesubstancesinthemixturedonotmeetthePBT/vPvBcriteriaaccordingtoREACH,annexXIII.

12.6.Otheradverseeffects

*Datachangedcomparedwiththepreviousversion

SECTION13:Disposalconsiderations

13.1.Wastetreatmentmethods

Appropriatedisposal/Product

Recommendation

Donotallowtoenterintosurfacewaterordrains.Thismaterialanditscontainermustbedisposedofinasafeway.Waste disposalaccordingtodirective2008/98/EC,coveringwasteanddangerouswaste.

Listofproposedwastecodes/wastedesignationsinaccordancewithEWC 200129detergentscontainingdangeroussubstances

packaging

Recommendation

Non-contaminatedpackagesmayberecycled.Vesselsnotproperlyemptiedarespecialwaste.

*Datachangedcomparedwiththepreviousversion

SECTION14:Transportinformation

14.1.

notapplicable

Landtransport(ADR/RID) notapplicable

notapplicable

Transportalwaysinclosed,uprightandsafecontainers.Makesurethatpersonstransportingtheproductknowwhattodoin caseofanaccidentorleakage.

Additionalinformation

Landtransport(ADR/RID)

notapplicable

Additionalinformation:

notapplicable

SafetyDataSheet

UNnumber

14.2.UNpropershippingname 14.3.Transporthazardclass(es)

14.4.Packinggroup

14.5.Environmentalhazards

Marinepollutant

14.6.Specialprecautionsforuser

Advicesonsafehandling:seeparts6-8

tunnelrestrictioncode Seatransport(IMDG) EmS-No.

Airtransport(ICAO-TI/IATA-DGR)

Notsustainingcombustion: 0 14.7.TransportinbulkaccordingtoAnnexIIofMARPOLandtheIBCCode

accordingtoRegulation(EC)No.1907/2006(REACH)

ArticleNo.:520.256.1382 Printdate:01.07.2016 Version:2-0

Eccellentemelksysteem Revisiondate:01.07.2016 199999EN Issuedate:01.07.2016 Page8/8

SECTION15:Regulatoryinformation

15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture

EUlegislation

Regulation(EC)No.648/2004(Detergentsregulation)

*Datachangedcomparedwiththepreviousversion Directive2010/75/EUonindustrialemissions VOC-value(ing/L):170

Nationalregulations

Restrictionsofoccupation

ObserveemploymentrestrictionsundertheMaternityProtectionDirective(92/85/EEC)forexpectantornursingmothers. Observerestrictionstoemploymentforjuvenilsaccordingtothe'juvenileworkprotectionguideline'(94/33/EC).

Otherinformation

Acid-/Alkalireserve(buffercapacityformixtureswithextremepHvalues)

15.2.ChemicalSafetyAssessment

Forthefollowingsubstancesofthispreparationachemicalsafetyassessmenthasbeencarriedout: ECNo. CASNo. Chemicalname REACHNo. 215-687-4 1344-09-8 sodiumsilicate(MR>3.2) 01-2119448725-31-xxxx

*Datachangedcomparedwiththepreviousversion

SECTION16:Otherinformation

Fulltextofclassificationinsection3:

AcuteTox.4/H302Acutetoxicity(oral) Harmfulifswallowed. EyeDam.1/H318Seriouseyedamage/eyeirritationCausesseriouseyedamage. AcuteTox.4/H332Acutetoxicity(inhalative) Harmfulifinhaled. AcuteTox.4/H312Acutetoxicity(dermal) Harmfulincontactwithskin. SkinCorr.1B/H314skincorrosion/irritation Causessevereskinburnsandeyedamage. SkinIrrit.2/H315skincorrosion/irritation Causesskinirritation.

Additionalinformation ClassificationaccordingtoRegulation(EC)No1272/2008[CLP]

Theinformationsuppliedonthissafetydatasheetcomplieswithourcurrentlevelofknowledgeaswellaswithnationaland EUregulations.Withoutwrittenapproval,theproductmustnotbeusedforpurposesdifferentfromthosementionedin chapter1.Itisalwaystheuser'sdutytotakeanynecessarymeasuresformeetingtherequirementslaiddownbylocalrules andregulations.Thedetailsinthissafetydatasheetdescribethesafetyrequirementsofourproductandarenottobe regardedasguaranteedattributesoftheproduct.

*Datachangedcomparedwiththepreviousversion

SafetyDataSheet