College Level Organic Chemistry

Page 199

QUIZ 1. An amine called dimethyl ethylamine is what type of amine compound? a. Primary amine b. Secondary amine c. Tertiary amine d. Quaternary amine Answer: c. This amine clearly has three alkyl groups associated with it, making it a tertiary amine. A primary amine has one alkyl or aryl group, while a secondary amine has two alkyl or aryl groups attached to it. 2. What would the charge be on tetramethylammonium, which has four alkyl groups attached? a. +1 b. +2 c. +3 d. 0 Answer: a. This would be an ammonium ion that would have a single positive charge associated with it, which would essentially be no different from a regular NH4+ ammonium cation. 3. Which amine compound is charged? a. Primary amine b. Secondary amine c. Tertiary amine d. Quaternary amine Answer: d. A quaternary amine has four alkyl groups around a nitrogen compound. Because neutral nitrogen compounds have three hydrogen atoms or up to three alkyl groups, having a fourth would mean there is a positive charge on the compound.

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