11.Phosphorus Speciation in Drinking Water Treatment Residuals

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Journal of Environment and Earth Science ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol 1, No.1, 2011 pH EC Texture O.M Available-N KCl-Al Available-P CEC

g kg -1 mg kg -1 mg kg -1 mg kg -1 cmol(+)kg

ICP-MS analysis: Aluminum (Al) Sodium (Na) Iron (Fe) Potassium (K) Magnesium (Mg) Silver (Ag) Arsenic (As) Boron (B) Calcium (Ca) Cadmium (Cd) Cobalt (Co) Chromium (Cr) Copper (Cu) Manganese (Mn) Molybdenum (Mo) Nickel (Ni) Lead (Pb) Zinc (Zn)

g kg -1 g kg -1 g kg -1 g kg -1 g kg -1 mg kg -1 mg kg -1 mg kg -1 mg kg -1 mg kg -1 mg kg -1 mg kg -1 mg kg -1 mg kg -1 mg kg -1 mg kg -1 mg kg -1 mg kg

dSm

-1

-1

-1

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9.00±0.05 1.88±0.05 nd 67.6±0.5 19.06±1.56 125.07±4.5 17.12±0.54 43.12±5.54

11.9±0.2 6.15±0.11 nd 380.2±3.2 78.09±1.05 34.67±0.58 53.99±2.51 76.00±3.5

6.27±0.12 1.05±0.07 Silty loam 20.3±0.6 23.34±0.59 75.23±1.52 26.00±4.00 10.53±0.06

12.6±0.05 0.5±0.02 121.0±4.0 0.5±0.01 12.6±0.5 <0.002 <0.1 12.30±0.58 266.07±2.28 0.05±0.00 0.44±0.04 3.83±0.08 0.86±0.10 7021.85±279.71 0.03±0.04 7.75±0.71 0.05±0.00 10.95±0.85

71.9±0.7 1.5±0.02 82.3±2.9 30.7±0.8 3.6±0.3 2.00±0.12 11.51±0.26 109.07±5.06 309.34±11.28 1.57±0.06 3.00±0.02 23.72±0.69 342.07±6.70 3321.74±63.71 4.60±0.18 30.15±0.59 29.16±0.32 190.86±0.83

71.0±0.47 <0.001 123.2±4.9 10.6±0.6 1.5±0.02 <0.002 3.80±0.19 6.55±1.05 1.61±0.06 0.37±0.03 7.53±0.37 12.82±0.59 11.34±0.60 7822.82±444.63 0.45±0.07 13.50±0.55 20.30±0.54 64.19±2.15

Table 3.Relative proportion of phosphate that best fit biosolids, WTRs, and selected WTRs-Biosolidstreated soils XANES spectra in linear combination fittinga. Treatments

Soil Kafr El-Dawar

El-Bostan

Borg Al-Arab

USA-soil

WTRs 5.07%±0.05 Al hydroxide with Psorbed 64.19%±0.07 Fe hydroxide with Psorbed

30.72%±0.02 H12IP6

10 Biosolids(B)

19.08%±0.02 Na12 I P6

47.02%±0.05 amorphous Fephosphate

31.16%±0.02 Zn3 (PO4)2

0.79%±0.02 Mn3 (PO4)2

10.93%±0.01 KH2PO4

12.63%±0.01 Al PO4

11.22%±0.04 KMgH9IP6

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17.21%±0.01 Hydroxyapatite

3.10%±0.02 Cu3(PO4)2

Biosolids

26.03%±0.01 Ba6IP6

73.09%±0.03 Cu3(PO4)2 0.89%± 0.02 Al hydroxide with Psorbed


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