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Tin organic compounds (Organostannic compounds
from Chemicals Guidance
Required limit value:
CAS RN: Should not be present in products.
Various
Properties: Tributyltin, dibutyltin and dioctyltin compounds are different chemical substances that are toxic and dangerous for the environment. Bioaccumulative and persistent.
Use:
Comments:
Legal background: Dibutyltin compounds (DBT) and dioctyltin compounds (DOT) are used in consumer products as stabilizers (mainly PVC) or catalysts (PU and PVC). Organotin catalysts are used in a wide variety of polyurethane applications, aiding formation of the urethane bond and generally functioning as Lewis acid catalysts.
Alternative stabilizers are barium/zinc, potassium/zinc, calcium, calcium/zinc organic or methyltin stabilisers.
Alternative catalysts can be zirconate compounds (e.g. titanium 2-ethylhexanoate) or amines such as bis- (dimethyl-aminoethyl) ether (BDMAEE) and triethylenediamine (TEDA) along with organometallic compounds such as potassium acetate.
Dialkyl tin compounds represents a large family of substances that consist of the following common constituents, see list of DBTs in Annex 4.
Trialkyltin compounds are biocides, see also the section regarding Biocidal agent.
Legal Limit: 0.1% by weight Dioctyltin (DOT), dibutyltin (DBT) compounds and tri-substituted organostannic compounds such as tributyltin (TBT) shall not be used in articles. Annex XVII of the Regulation (EC) No 1907/2006 (REACH), entry 20.
Tributyltin oxide (TBTO), 56-35-9, Dibutyltin dichloride (DBTC), 683-18-1, 2-ethylhexyl 10-ethyl-4,4-dioctyl-7-oxo-8-oxa-3,5-dithia4-stannatetradecanoate (DOTE), 15571-58-1 and reaction mass of DOTE and MOTE 2 and Dibutylbis(pentane-2,4-dionato-O,O') tin, 22673-19-4 are listed on the Candidate List of Substances of Very High Concern for authorization of the Regulation (EC) No 1907/2006 (REACH).
Test method: EN ISO 22744-1 (textile) CEN ISO/TS 16179 (footwear).
Test equipment: GC-MS. LOQ: 0.2 mg/kg
2 reaction mass of 2-ethylhexyl 10-ethyl-4,4-dioctyl-7-oxo-8-oxa-3,5-dithia-4-stannatetradecanoate and 2-ethylhexyl 10-ethyl-4-[[2[(2-ethylhexyl)oxy]-2-oxoethyl]thio]-4-octyl-7-oxo-8-oxa-3,5-dithia-4-stannatetradecanoate
