River Itchen Sustainability Study WATER QUALITY Phase III Discussion Meeting with Watercress Growers Association Alresford 25 September 2003
Contents • Estuary stratification, ammonia, dissolved oxygen and temperature • River RE 1 in MU6 – precautions • River Phosphorus – standards, current conditions, potential problems and possible solutions
Requirements for Target Species – Water Quality Issues • RE 1 (salmon) DO - 80% saturation (10 %ile) BOD - 2.5 mg/l (90 %ile) Ammonia - 0.25 mg/l (90 %ile) • Suspended solids - 10 mg/l annual average. Also <10% silt in surface sediments (salmon) • Orthophosphate - <0.06 mg/l - annual average (eutrophication) • Other issue – endocrine disrupters?
Flow Balance – September 1992
Designated Shellfish Water
G r a ve l s i lt a t io n E g g s / A le v in s P a rr S m o lts A d u lt s e n t e r ri ve r S p a w n i n g m i g ra t io n S p a w ni ng
Critical
Being Assessed
December
November
October
September
August
July
June
May
April
March
February
January
SALMON - Criticality of Seasonal Monthly River Flow for Key Life Stages
Water Quality Standards – Fluvial/Marine DO River GQA Grade A Freshwater Fish Directive – Salmonid Standard Estuary (proposed)
80% sat. 10%ile 9 mg/l 50%ile 6 mg/l absolute limit 80% annual average 5 mg/l 5%ile (Bedford 2003)
BOD (ATU) 5d 20°C 2.5 mg/l 90%ile
Ammonium 0.25 mg N/l 90%ile 1 mg/l 0.78 mg N/l Derogation to 3 mg NH4/l if healthy fish population 0.86 mg N/l 95%ile
Unionised ammonia
0.025 mg/l 0.02 mg N/l
0.025 mg NH3/l NH3, 0.021 mg N/l equivalent to NH4 at 15°C, 0.4 salinity (Nixon et al. 1995, Alabaster & Lloyd 1982))
Temp.
21.5 °C 98%ile
Cobden Bridge – Salinity – Neap Tide
Cobden Bridge - Temperature Temperature 25 Cobden Br.
Temperature deg. C
20
15
10
5
0 11-Aug-87
07-May-90
31-Jan-93
28-Oct-95 Time
24-Jul-98
19-Apr-01
14-Jan-04
Cobden Bridge - Ammonia Itchen Estuary - Cobden Bridge 2.5 Ammonia Linear (Ammonia)
Ammonia N mg/l
2
1.5
1
0.5
y = -0.0128x + 0.6678 R2 = 0.1004
0 0
5
10
15
20 Salinity psu
25
30
35
40
Cobden Bridge – Ammonia – Neap Tide
Model Boundary Conditions July 1994 Inputs
July 1994 model
River flow m3/s Test 9.27 Itchen 4.95 Hamble 0.42
BOD org N NH4 NO3 PO4 DO % SS Algal C
Concs. Portswood mg/l 5 5 20 0.5 5 50 20 0
Mean tidal ranges m Spring m 4 Neap m 1.9
Itchen mg/l 2 1 0.07 5 0.3 100 15 0
Loads Portswood kg/d 130 130 518 13 130 130 518 0
River kg/d 855 428 30 2138 128 4277 6415 0
STW flow m3/s Portswood 0.3
Ratio R/STW 6.60 3.30 0.06 165.00 0.99 33.00 12.38
Portswood STW Effluent/River Mixing Portswood STW Effluent/River Mixing
2.50
Concentration mg/l
100.00
Ammonium BOD DO low DO high
95.00 90.00
2.00
85.00
1.50
80.00 75.00
1.00
70.00 0.50
65.00
0.00
60.00 0
1
2
3
4
Fluvial Discharge m3/s
5
6
7
% saturation
3.00
Cobden Bridge – DO % sat. Itchen Estuary - Cobden Bridge 180
Dissolved Oxygen % sat.
160 140 120 100 80 60 40 20 0 01-Jan-90
01-Jan-92
01-Jan-94
01-Jan-96
01-Jan-98
01-Jan-00
01-Jan-02
Cobden Bridge – DO v Salinity Itchen Estuary - Cobden Bridge 180 160 140
DO % sat.
120 100
y = -0.461x + 93.001 R2 = 0.0892
80 60 40 20 0 0
5
10
15
20 Salinity psu
25
30
35
40
Cobden Bridge – DO – Neap Tide
Dissolved Oxygen – Itchen Estuary 140 130 120 110 100 90 80 70 60 50 40 30 20 10 0
60000 DO %
Conductivity
50000 40000 30000 20000 10000 0
Conductivity (uS/cm) .
Dissolved Oxygen (% sat)
Dissolved Oxygen, and Conductivity at Cobden Bridge - (Sept 5th - Sept 21st 2003)
Requirements for Target Species – Water Quality Issues • RE 1 (salmon) DO - 80% saturation (10 %ile) BOD - 2.5 mg/l (90 %ile) Ammonia - 0.25 mg/l (90 %ile) • Suspended solids - 10 mg/l annual average. Also <10% silt in surface sediments (salmon) • Orthophosphate - <0.06 mg/l - annual average (eutrophication) • Other issue – endocrine disrupters?
Ammonia - Gaters Mill R. Itchen, Gaters Mill 0.5 0.45 0.4
Ammonia N mg/l
0.35 0.3 0.25 0.2 0.15 0.1 0.05 0 28/07/01 00:00
07/08/01 00:00
17/08/01 00:00
27/08/01 00:00
06/09/01 00:00 Time
16/09/01 00:00
26/09/01 00:00
06/10/01 00:00
DO Gaters Mill August 2002 Turbidity (FTU) and Dissolved Oxygen (% sat)
Turbidity, Dissolved Oxygen, and Conductivity at Gaters Mill - August 2002 120 110 100 90 80 70 60 50 40 30 20 10 0
1000 800 700 600 500 400 300 200 100 0
DO %
Turbidity
Conductivity
Conductivity (uS/cm)
900
Dissolved Oxygen - Easton 140 130 120 110 100 90 80 70 60 50 40 30 20 10 0
1000 900 800 700 600 500 400 300 200 DO %
Conductivity
100 0
Conductivity (uS/cm) .
Dissolved Oxygen (% sat)
Dissolved Oxygen, and Conductivity at Easton - (July 31st - August 14th 2003)
Itc he n
by pa ss
Ea st on
LOCATION
Av er ag e
Ab ba Br s oo FF k, Bo ro ug h Itc Br he id n ge Na Ar vi ga le ,D tio ro n, ve G ar La ni ne er Rd Itc ,W he Ca in n ch rr ,G ie es ar ro te ni fI r e tc rR he d n, ,W Itc in he ch n es Va te lle r y Co Itc un he try n, Itc Ri Pa ve he rk rI n nn Na ,B vi ga is ho tio ps n, to u/ ke s Ch ic he nh al lS TW
Ca nd ov er
Al re sf or d
d/ s
d/ s
Itc he n
Itc he n
DO % sat.
Early Morning Dissolved Oxygen Dissolved Oxygen 0700-0800 hrs
100 90 80 70 60 50 40 30 20 10 0
14-17 July 2003
4-7 August 2003
Upper Catchment Routine Monitoring Data: Suspended Solids SS-Q Borough Bridge, Drove Lane 96-99 1.20
40
SS- BB
35
SS DL
30
Q
1.00
0.60
20 15
0.40
10
0.20
5
08/11/99
08/08/99
08/05/99
08/02/99
08/11/98
08/08/98
08/05/98
08/02/98
08/11/97
08/08/97
08/05/97
08/02/97
08/11/96
08/08/96
0.00
08/05/96
0
Q m3/s
0.80
25
08/02/96
SS mg/l
45
Watercress Farm Suspended Solids Watercress Farm Suspended Solids 100 90 A
B
C
D
E
F
I
J
Suspended Solids mg/l
80 70 60 50 40 30 20 10 0 13-Jul-02 01-Sep-02 21-Oct-02 10-Dec-02 29-Jan-03 20-Mar-03 09-May-03 28-Jun-03
Watercress Farm Zinc Watercress Farm Zinc 200 180 160
A
B
C
D
E
F
I
J
Zinc ug Zn/l
140 120 100 80 60 40 20 0 13-Jul-02 01-Sep-02 21-Oct-02 10-Dec-02 29-Jan-03 20-Mar-03 09-May-03 28-Jun-03
Watercress Farm Malathion Watercress Farm Malathion 100 90
A
B
C
D
E
F
I
J
80
Malathion ng/l
70 60 50 40 30 20 10
0 13-Jul-02 01-Sep-02 21-Oct-02 10-Dec-02 29-Jan-03 20-Mar-03 09-May-03 28-Jun-03
P (mg/l) Values Assigned to River Types Geological 1. 2. River 3. Large class Headriver waters C Natural 0.02 0.02 0.02 Standard 0.04 0.06 0.06 Threshold 0.06 0.10 0.10 E Natural 0.02 0.03 0.03 Standard 0.06 0.10 0.10 Threshold 0.10 0.20 0.20
Itchen Guideline Standards (mg/l) • • • • • •
MU1 Cheriton MU2 Arle MU3 Candover MU4 MU5 MU6
C1 C2 C1 C2 C2 E2
0.04 0.06 0.04 0.06 0.06 0.10
Phosphorus 1997-1999
P MU1 3812 MU2 3858 MU3 52/41 Total MU4 3806 MU5 3796 MU6 3786
Q m3/s 0.5 1.6 0.5 2.6 3.8 4.8 4.8
Conc. mg/l Load g/sIncr. g/s 0.037 0.019 0.083 0.133 0.033 0.017 0.065 0.168 0.063 0.239 0.07 0.120 0.576 0.34 0.370 1.776 1.20
Q and P in River Itchen Modelled Orthophosphate Concentration and Flow in River Itchen - Average Flow (Q50) Management Unit 4
Management Unit 5
Management Unit 6
7.00
0.400 Chickenhall STW Discharge
Mill House FF Discharge
0.350 Springvale WCBF Discharge
Flow (cumecs)
5.00
4.00
Harestock STW Discharge
Avington Trout FF Abstraction
Mill House FF Abstraction
Gaters Mill PWS Abstraction Otterbourne PWS Abstraction
0.300
0.250
Test Valley FF Discharge
0.200 3.00 0.150 2.00
Avington Trout FF Discharge, Test Valley FF Abstraction
0.100
1.00
0.00 7.00
0.050
9.00
11.00
13.00
15.00
17.00
19.00
21.00
23.00
25.00
27.00
29.00
31.00
33.00
35.00
Chainage (km) Calculated Flows (Q50)
Modelled Orthophosphate Concentration (C50)
P-Standard
0.000 37.00
Orthophosphate (mg/l)
6.00
P MODELLED FOR 50%ile FLOW
6.00
1.00
5.00
0.90 0.80 0.70
4.00
0.60 0.50
3.00
0.40
2.00
0.30 0.20 0.10
1.00 0.00 7.00
12.00
17.00
22.00
27.00
32.00
Orthophosphate (mg/l)
Q (cumecs)
ITCHEN
0.00 37.00
Chainage (km) Flow Orthophosphate from C against Q plot
Modelled Orthophosphate Orthophosphate from normal dist.
P Modelled for 50%ile Flow
6.00
1.00
5.00
0.90 0.80 0.70
4.00
0.60 0.50
3.00
0.40
2.00
0.30 0.20 0.10
1.00 0.00 7.00
12.00
17.00
22.00
27.00
32.00
Orthophosphate (mg/l)
Q (cumecs)
ITCHEN
0.00 37.00
Chainage (km) Flow Orthophosphate from C against Q plot
Modelled Orthophosphate Orthophosphate from normal dist.
Divert Morestead (5 mg/l) to Harestock C.4.1. Modelled P. concentration (mg/l) in R. Itchen for strategy F1 MU5
MU6
6.00
5.00
Flow (cumecs)
4.00
3.00
2.00
1.00
0.00 7.00
9.00
11.00
Flow (cumecs)
13.00
15.00
17.00
19.00
21.00
23.00
Chainage (km)
25.00
27.00
Modelled P. conc. for scenario F1 (mg/l) with scenario
29.00
31.00
33.00
35.00
0.50 0.48 0.46 0.44 0.42 0.40 0.38 0.36 0.34 0.32 0.30 0.28 0.26 0.24 0.22 0.20 0.18 0.16 0.14 0.12 0.10 0.08 0.06 0.04 0.02 0.00 37.00
Modelled P. conc for base case
Phosphorus (mg/l)
MU4
Divert Alresford (5 mg/l) to Arle Confluence C.4.2. Modelled P. concentration in R. Itchen for strategy F2 6.00
0.20 0.18 0.16 0.14
4.00
0.12 3.00
0.10 0.08
2.00
0.06 0.04
1.00
0.02 0.00 7.00
0.00 9.00 11.00 13.00 15.00 17.00 19.00 21.00 23.00 25.00 27.00 29.00 31.00 33.00 35.00 37.00
Chainage (km) Flow
Modelled P. conc. (mg/l)
Modelled P. conc. without strategy
Phosphorus (mg/l)
Flow (cumecs)
5.00
Harestock to Chickenhall – 0.5 mg/l C.4.4. Modelled P. concentration in R. Itchen for strategy H 6.00
0.13 0.12 0.11
5.00
0.09
4.00
0.08 0.07
3.00
0.06 0.05
2.00
0.04 0.03
1.00
0.02 0.01
0.00
0.00 7
9
11
13
15
17
19
21
23
25
27
29
31
33
Chainage (km) Flow
Modelled P. conc (mg/l)
35
37
Phosphorus (mg/l)
Flow (cumecs)
0.10
River Itchen Schematic Franklyns FF
: 0.737
Pinglestone WCF : 0.088
R.CANDOVER
Manor Farm WCF : 0.189 Manor Farm FF
Fobdown WCF Upper
: 0.159
: 0.038
Beds 16-19 : 0.038 Farm Avington FF
: 0.520
Test Valley FF
: 1.319
: 0.038
Borough Br. MU3
Springvale WCF : 0.084
Drove Lane MU2
Easton MU4
Lower Bishops WCF : 0.243
Alresford By-pass MU1
Harestock STW : 0.051 Mill House FF : 0.310
Otterbourne MU5 Poles Lane Stream
Nythe WCF
R.CHERITON
Otterbourne WTW Bow Lake
Intake
: 0.347
Allington Lane Stream
West Lea WCF : 0.040 : 0.530
Discharge : 0.030 Fishers Pond FF
: 0.098
Drayton WCF : 0.150
Spring Garden WCF : 0.150
: 0.080
Morelands Cope FF : 0.010
KEY HM Victualling STW : 0.001
Discharge : 0.020
Discharge to river Abstraction from river
Gaters Mill MU6 Gaters Mill WTW Intake : 0.530
R.ITCHEN
Abstraction from and discharge to river MU4
Principal flow monitoring station for management unit 4 FF: Fish farm
WCF: Watercress farm
Notes: Flows are consented discharges/abstractions (m3/s).
STW: Sewage treatment works WTW: Water treatment works
Fish Farm Effluent Orthophosphate Fish Farm Effluent Orthophosphate 0.200 0.180
Orthophosphate mg/l
0.160 0.140 0.120 0.100 0.080 0.060 0.040 0.020 0.000 A
B
C
D
E
F
G
H
I
Q and P in River Arle Modelled Orthophosphate Concentration and Flow in River Arle - Average Flow (Q50) 2.50
0.250 Pinglestone WCBF Discharge
Franklyns FF Discharge
2.00
0.200
West Lea WCBF, Nythe WCBF, Drayton WCBF Discharge
1.50
1.00
Maxwell WCBF Discharge
0.150
Lower Bishop Sutton WCBF Discharge
Franklyns FF Abstraction
0.100
0.50
0.050
0.00 0.00
0.000 1.00
2.00
3.00
4.00
5.00
Chainage (km) Calculated Flows (Q50)
Modelled Orthophosphate Concentration (C50)
P-Standard
Orthophosphate (mg/l)
Flow (cumecs)
Manor FF Abstraction & Discharge, Manor WCBF Discharge
R. Arle, 50%ile Flow
Flow (cumecs)
2.00
0.25 0.20
1.50
0.15 1.00
0.10
0.50
0.05
0.00
0.00
0.00
1.00
2.00
3.00
4.00
Orthophosphate (mg/l)
Modelled Orthophosphate Concentration and Flow in River Arle
5.00
Chainage (km)
Calculated Flow Orthophosphate - C against Q P-Standard
Modelled Orthophosphate Orthophosphate - Normal Distribution
R. Arle, 80%ile Flow
Flow (cumecs)
2.00
0.25 0.20
1.50
0.15 1.00
0.10
0.50
0.05
0.00
0.00
0.00
1.00
2.00
Calculated Flow Orthophosphate - C against Q P-Standard
3.00 Chainage (km)
4.00
Orthophosphate (mg/l)
Modelled Orthophosphate Concentration and Flow in River Arle
5.00
Modelled Orthophosphate Orthophosphate - Normal Distribution
R. Arle, 80%ile Flow, 0.060 mg.l WF
Flow (cumecs)
2.00
0.25 0.20
1.50
0.15
1.00
0.10
0.50
0.05
0.00 0.00
0.00 1.00
2.00
Calculated Flow Orthophosphate - C against Q P-Standard
3.00 Chainage (km)
4.00
Orthophosphate (mg/l)
Modelled Orthophosphate Concentration and Flow in River Arle
5.00
Modelled Orthophosphate Orthophosphate - Normal Distribution
Watercress Farm Effluent Orthophosphate Watercress Farm Effluent Orthophosphate 0.400
Orthophosphate mg/l
0.350 0.300 0.250 0.200 0.150 0.100 0.050 0.000 A
B
C
D
E
F
G
H
I
J
K
L
Watercress Farm Effluent – P Conc. Watercress Farm Orphophosphate
Orthophosphate mg P/l
0.6 0.5 0.4 0.3 0.2 0.1 0
A
B
C
D
E
F
I
J
Total/Soluble Phosphorus Ratio Phosphorus Phase 0.7
Total Phosphorus mg/l
0.6
y = 1.1536x R2 = 0.7919
0.5 0.4 0.3 0.2 0.1 0 0
0.1
0.2
0.3 Orthophosphate mg/l
0.4
0.5
0.6
Watercress Farm Effluent P Concentration and Loads Watercress Farm Effluent Phosphorus
Orthophosphate 0.200
Total Phosphorus Soluble P Load
2.50
0.160 0.140
2.00
0.120 0.100
1.50
0.080 1.00
0.060 0.040
0.50
0.020 0.000
0.00 A
B
C
D
E
F
G
H
I
J
Soluble P load t/d
Orthophosphate, Total Phosphorus mg P/l
0.180
3.00
Future Work Towards RISS • More detailed water quality modelling with ISIS – (Q input data?) • Identification of future strategies (Q/c scenarios?) • Indication of financial implications (balance cost against ecological risk)