SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 2 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 1/14
SUMMER ORANGE SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier
Trade name/designation:
SUMMER ORANGE
Other means of identification: FIBER: 56-1996, 56-1707-04, 56-1752, 56-1334 CORRUGATED MEMBRANES AND CARTRIDGES: 56-1757 UFI: TRA3-VN6G-V80D-9048
1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture: aromatisation
Relevant identified uses:
Life cycle stage [LCS] PW: Widespread use by professional workers Product Categories [PC] PC 28: Perfumes, fragrances
1.3. Details of the supplier of the safety data sheet Supplier (manufacturer/importer/only representative/downstream user/distributor): Vaportek Europe Logistic Sarl 6 Route du Grand Lancy 1211 Genève 26 Switzerland Telephone: +41 22 342 2145 E-mail: vaportek@gmail.com
E-mail (competent person): vaportek@gmail.com
1.4. Emergency telephone number 24h: NHS (National Health Service): 111
SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Hazard classes and hazard categories
Hazard statements
Classification procedure Calculation method.
Skin corrosion/irritation (Skin Irrit. 2)
H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
Calculation method. Calculation method.
H318: Causes serious eye damage.
Calculation method.
Hazardous to the aquatic environment H411: Toxic to aquatic life with long (Aquatic Chronic 2) lasting effects.
Calculation method.
Aspiration hazard (Asp. Tox. 1)
Respiratory or skin sensitisation (Skin Sens. 1)
Serious eye damage/eye irritation (Eye Dam. 1)
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 2 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 2/14
SUMMER ORANGE 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms:
GHS05
GHS07
Corrosion
Exclamation mark
GHS08
Health hazard
GHS09
Environment
Signal word: Danger Hazard components for labelling: allyl (3-methylbutoxy)acetate; CITRONELLA OIL; geraniol; allyl heptanoate Hazard statements for health hazards H304
May be fatal if swallowed and enters airways.
H317
May cause an allergic skin reaction.
H315 H318
Causes skin irritation.
Causes serious eye damage.
Hazard statements for environmental hazards H411
Toxic to aquatic life with long lasting effects.
Precautionary statements Prevention P280
Wear protective gloves and eye/face protection.
Precautionary statements Response P301 + P310 P302 + P352
IF SWALLOWED: Immediately call a POISON CENTER. IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Precautionary statements Disposal P501
Dispose of contents/container to an appropriate recycling or disposal facility.
* 2.3. Other hazards
Adverse physicochemical effects: No further relevant information available. Adverse human health effects and symptoms: The product contains a substance that is identified as having endocrine disrupting properties. p-Menth-1-en-8-ol CAS: 98-55-5 ; EC: 202-680-6 2,6-Di-tert-butyl-p-cresol CAS: 128-37-0 ; EC: 204-881-4 Adverse environmental effects: The product contains a substance that is identified as having endocrine disrupting properties. p-Menth-1-en-8-ol CAS: 98-55-5 ; EC: 202-680-6 2,6-Di-tert-butyl-p-cresol CAS: 128-37-0 ; EC: 204-881-4 The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII. Other adverse effects: No further relevant information available.
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 2 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 3/14
SUMMER ORANGE SECTION 3: Composition/information on ingredients 3.2. Mixtures
Hazardous ingredients / Hazardous impurities / Stabilisers: Product identifiers
Substance name Concentration Classification according to Regulation (EC) No. 1272/2008 [CLP] Orange, sweet, ext. Aquatic Chronic 2 (H411), Asp. Tox. 1 (H304), Flam. Liq. 3 (H226), Skin Irrit. 2 (H315), Skin Sens. 1 (H317)
12 – ≤ 25 weight-%
CAS No.: 5392-40-5 EC No.: 226-394-6 Index No.: 605-019-00-3
citral Skin Irrit. 2 (H315), Skin Sens. 1 (H317)
10 – ≤ 20 weight-%
CAS No.: 134-20-3 EC No.: 205-132-4
methyl anthranilate Eye Irrit. 2 (H319)
5 – ≤ 15 weight-%
CAS No.: 78-70-6 EC No.: 201-134-4
Linalool: 3,7-Dimethyl- 1,6-octadien-3-ol; DL-Linalool Eye Irrit. 2 (H319), Skin Irrit. 2 (H315), Skin Sens. 1B (H317)
5 – ≤ 15 weight-%
CAS No.: 112-31-2 EC No.: 203-957-4
decanal Aquatic Chronic 3 (H412), Eye Irrit. 2 (H319)
5 – ≤ 10 weight-%
CAS No.: 8000-29-1 EC No.: 616-771-7
CITRONELLA OIL Asp. Tox. 1 (H304), Eye Dam. 1 (H318), Skin Irrit. 2 (H315), Skin Sens. 1 (H317)
1–≤5 weight-%
CAS No.: 58430-94-7 EC No.: 261-245-9
3,5,5-trimethylhexyl acetate Aquatic Chronic 2 (H411), Skin Irrit. 2 (H315)
1–≤5 weight-%
CAS No.: 98-55-5 EC No.: 202-680-6
p-menth-1-en-8-ol Eye Irrit. 2 (H319), Skin Irrit. 2 (H315)
1–≤5 weight-%
CAS No.: 106-24-1 EC No.: 203-377-1
geraniol Eye Dam. 1 (H318), Skin Irrit. 2 (H315), Skin Sens. 1 (H317)
1–≤5 weight-%
CAS No.: 115-95-7 EC No.: 204-116-4
linalyl acetate Eye Irrit. 2 (H319), Skin Irrit. 2 (H315), Skin Sens. 1B (H317)
1–≤3 weight-%
CAS No.: 124-13-0 EC No.: 204-683-8
octanal Aquatic Chronic 2 (H411), Eye Irrit. 2 (H319), Flam. Liq. 3 (H226), Skin Irrit. 2 (H315)
1–≤3 weight-%
CAS No.: 106-22-9 EC No.: 203-375-0
citronellol Eye Irrit. 2 (H319), Skin Irrit. 2 (H315), Skin Sens. 1B (H317)
1–≤2 weight-%
CAS No.: 5413-60-5 EC No.: 226-501-6
3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-6-yl acetate Aquatic Chronic 3 (H412)
1–≤2 weight-%
CAS No.: 8028-48-6 EC No.: 232-433-8
Danger
Warning
Warning
Warning
Warning
Danger
Warning
Warning
Danger
Warning
Warning
CAS No.: 6259-76-3 EC No.: 228-408-6
CAS No.: 61792-11-8 EC No.: 263-214-5
Warning
hexyl salicylate Aquatic Chronic 1 (H410), Skin Sens. 1B (H317) Warning M-factor (chronic): 1
3,7-dimethylnona-2,6-dienenitrile Aquatic Chronic 2 (H411)
according to Regulation (EC) No. 2020/878 (REACH)
1–≤2 weight-%
≤1 weight-%
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 2 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 4/14
SUMMER ORANGE Product identifiers CAS No.: 128-37-0 EC No.: 204-881-4
CAS No.: 20407-84-5 EC No.: 243-797-2
CAS No.: 142-19-8 EC No.: 205-527-1
Substance name Concentration Classification according to Regulation (EC) No. 1272/2008 [CLP] 2,6-di-tert-butyl-p-cresol Aquatic Chronic 1 (H410)
≤1 weight-%
(E)-dodec-2-en-1-al Aquatic Acute 1 (H400), Eye Irrit. 2 (H319), Skin Irrit. 2 (H315), Skin Sens. 1B (H317)
≤1 weight-%
allyl heptanoate Acute Tox. 3 (H301, H311, H331), Aquatic Acute 1 (H400), Aquatic Chronic 3 (H412)
≤1 weight-%
Warning M-factor (acute): 1
Warning M-factor (acute): 1
Danger
CAS No.: 101-86-0 EC No.: 202-983-3
Hexyl Cinnamal ≤ 0.5 Aquatic Acute 1 (H400), Aquatic Chronic 2 (H411), Skin Sens. 1B (H317) weight-%
CAS No.: 67634-00-8 EC No.: 266-803-5
allyl (3-methylbutoxy)acetate Acute Tox. 2 (H330), Acute Tox. 4 (H302), Aquatic Chronic 1 (H410)
≤ 0.5 weight-%
CAS No.: 32210-23-4 EC No.: 250-954-9
4-tert-butylcyclohexyl acetate Skin Sens. 1B (H317)
≤ 0.2 weight-%
Warning
Danger
Warning Full text of H- and EUH-phrases: see section 16.
SECTION 4: First aid measures 4.1. Description of first aid measures
General information: In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). Remove victim out of the danger area. Remove contaminated, saturated clothing. If unconscious but breathing normally, place in recovery position and seek medical advice. Do not leave affected person unattended. Warning First aider: Pay attention to self-protection! Following inhalation: Provide fresh air. In case of respiratory tract irritation, consult a physician. In case of skin contact: After contact with skin, wash immediately with plenty of water and soap. Take off immediately all contaminated clothing. If skin irritation or rash occurs: Get medical advice/ attention. After eye contact: In case of contact with eyes, rinse immediately thoroughly with plenty of edible oil and consult an ophthalmologist. Following ingestion: Ingestion of the mixture / product is hardly possible. Rinse mouth. Get medical advice/attention if you feel unwell. Do NOT induce vomiting. Observe risk of aspiration if vomiting occurs. Get immediate medical advice/ attention. Self-protection of the first aider: Use personal protection equipment.
4.2. Most important symptoms and effects, both acute and delayed
Causes skin irritation. Allergic reactions Serious eye damage/eye irritation Pneumonia Pulmonary oedema Skin corrosion/irritation
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 2 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 5/14
SUMMER ORANGE 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically.
SECTION 5: Firefighting measures 5.1. Extinguishing media
Suitable extinguishing media: alcohol resistant foam Extinguishing powder Carbon dioxide (CO2) Unsuitable extinguishing media: Full water jet
5.2. Special hazards arising from the substance or mixture Hazardous combustion products: Gases/vapours, irritant
5.3. Advice for firefighters
Wear a self-contained breathing apparatus and chemical protective clothing.
5.4. Additional information
Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.
SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Personal precautions: Remove persons to safety. Protective equipment: Wear protective gloves/protective clothing/eye protection/face protection.
6.1.2. For emergency responders
Personal protection equipment: Personal protection equipment: see section 8
6.2. Environmental precautions
Do not allow to enter into surface water or drains.
6.3. Methods and material for containment and cleaning up
For containment: Absorb with liquid-binding material (sand, diatomaceous earth, acid- or universal binding agents). For cleaning up: Take up mechanically, placing in appropriate containers for disposal. Solvents/Thinner
6.4. Reference to other sections
Safe handling: see section 7 Personal protection equipment: see section 8 Disposal: see section 13
6.5. Additional information
Use appropriate container to avoid environmental contamination.
SECTION 7: Handling and storage 7.1. Precautions for safe handling Protective measures
Advices on safe handling: Wear personal protection equipment (refer to section 8). Fire prevent measures: Take precautionary measures against static discharge. Keep away from sources of ignition - No smoking.
Advices on general occupational hygiene When using do not eat, drink or smoke. Avoid contact with eyes and skin.
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 2 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 6/14
SUMMER ORANGE 7.2. Conditions for safe storage, including any incompatibilities
Technical measures and storage conditions: Keep container tightly closed in a cool, well-ventilated place. Storage class (TRGS 510, Germany): 10 – Combustible liquids that cannot be assigned to any of the above storage classes
7.3. Specific end use(s) No data available
SECTION 8: Exposure controls/personal protection 8.1. Control parameters
8.1.1. Occupational exposure limit values
① Long-term occupational exposure limit value ② Short-term occupational exposure limit value ③ Instantaneous value ④ Monitoring and observation processes ⑤ Remark ① 10 mg/m³
Limit value type Substance name (country of origin)
WEL (GB)
2,6-di-tert-butyl-p-cresol CAS No.: 128-37-0 EC No.: 204-881-4
8.1.2. Biological limit values No data available
8.1.3. DNEL-/PNEC-values No data available
8.2. Exposure controls 8.2.1. Appropriate engineering controls No data available
8.2.2. Personal protection equipment
Eye/face protection: Eye glasses with side protection EN 166 Skin protection: Tested protective gloves must be worn EN ISO 374 Suitable material: NBR (Nitrile rubber), In the case of wanting to use the gloves again, clean them before taking off and air them well. Breakthrough times and swelling properties of the material must be taken into consideration. Respiratory protection: Usually no personal respirative protection necessary. Respiratory protection necessary at: Handling larger quantities,
8.2.3. Environmental exposure controls No data available
SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state: Liquid Odour: fruity
Safety relevant basis data
Colour: dark yellow Odour threshold: not determined
Parameter
Value
pH
not applicable
Melting point
Freezing point according to Regulation (EC) No. 2020/878 (REACH)
① Method ② Remark
not determined not determined en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 2 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 7/14
SUMMER ORANGE Parameter
① Method ② Remark
Value
Initial boiling point and boiling range not determined Decomposition temperature
not determined
Evaporation rate
not determined
Flash point
Auto-ignition temperature
Upper/lower flammability or explosive limits Vapour pressure
72 °C not determined not determined not determined
Vapour density
not determined
Density
not determined
Relative density
not determined
Bulk density
not determined
Water solubility
practically insoluble
Dynamic viscosity
not determined
Partition coefficient: n-octanol/water not determined Kinematic viscosity
not determined
9.2. Other information
Solid, inert fiber block soaked with liquid mixture for odour neutralisation. The properties listed relate to the liquid.
SECTION 10: Stability and reactivity 10.1. Reactivity
This material is considered to be non-reactive under normal use conditions.
10.2. Chemical stability
The product is stable under storage at normal ambient temperatures.
10.3. Possibility of hazardous reactions No known hazardous reactions.
10.4. Conditions to avoid
Stable under recommended storage and handling conditions.
10.5. Incompatible materials
No further relevant information available.
10.6. Hazardous decomposition products
Thermal decomposition can lead to the escape of irritating gases and vapours.
SECTION 11: Toxicological information 11.1. Information on hazard classes as defined in Regulation (EC) No. 1272/2008 citral
CAS No.: 5392-40-5 EC No.: 226-394-6
LD50 oral: =6,800 mg/kg
LD50 dermal: >2,000 mg/kg
p-menth-1-en-8-ol
CAS No.: 98-55-5 EC No.: 202-680-6
LD50 oral: =4,300 mg/kg
LD50 dermal: >2,000 mg/kg
linalyl acetate
CAS No.: 115-95-7 EC No.: 204-116-4
LD50 oral: >9,000 mg/kg
3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-6-yl acetate LD50 oral: 5,400 mg/kg
3,7-dimethylnona-2,6-dienenitrile LD50 oral: >2,000 mg/kg
according to Regulation (EC) No. 2020/878 (REACH)
CAS No.: 5413-60-5 EC No.: 226-501-6
CAS No.: 61792-11-8 EC No.: 263-214-5
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 2 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 8/14
SUMMER ORANGE 2,6-di-tert-butyl-p-cresol
CAS No.: 128-37-0 EC No.: 204-881-4
LD50 oral: >6,000 mg/kg (Rat)
LD50 dermal: >2,000 mg/kg (Rat)
allyl (3-methylbutoxy)acetate
CAS No.: 67634-00-8 EC No.: 266-803-5
LD50 oral: 500 mg/kg
LD50 dermal: >2,000 mg/kg
LC50 Acute inhalation toxicity (dust/mist): 0.43 mg/L
4-tert-butylcyclohexyl acetate
CAS No.: 32210-23-4 EC No.: 250-954-9
LD50 oral: 3,323 mg/kg
Acute oral toxicity: Based on available data, the classification criteria are not met. Acute dermal toxicity: Based on available data, the classification criteria are not met. Acute inhalation toxicity: Based on available data, the classification criteria are not met. Skin corrosion/irritation: Causes skin irritation. Serious eye damage/irritation: Causes serious eye damage. Respiratory or skin sensitisation: May cause an allergic skin reaction. Germ cell mutagenicity: Based on available data, the classification criteria are not met. Carcinogenicity: Based on available data, the classification criteria are not met. Reproductive toxicity: Based on available data, the classification criteria are not met. STOT-single exposure: Based on available data, the classification criteria are not met. STOT-repeated exposure: Based on available data, the classification criteria are not met. Aspiration hazard: May be fatal if swallowed and enters airways. Additional information: No data available
11.2. Information on other hazards
Endocrine disrupting properties: The product contains a substance that is identified as having endocrine disrupting properties. p-Menth-1-en-8-ol CAS: 98-55-5 ; EC: 202-680-6 2,6-Di-tert-butyl-p-cresol CAS: 128-37-0 ; EC: 204-881-4
SECTION 12: Ecological information 12.1. Toxicity Orange, sweet, ext.
CAS No.: 8028-48-6 EC No.: 232-433-8
EC50: 1.1 mg/L 2 d (crustaceans)
3,5,5-trimethylhexyl acetate LC50: 7.7 mg/L 4 d (fish)
p-menth-1-en-8-ol
CAS No.: 58430-94-7 EC No.: 261-245-9
CAS No.: 98-55-5 EC No.: 202-680-6
LC50: =70 mg/L 4 d (fish)
linalyl acetate
CAS No.: 115-95-7 EC No.: 204-116-4
LC50: 11 mg/L 4 d (fish)
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
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SUMMER ORANGE octanal
CAS No.: 124-13-0 EC No.: 204-683-8
LC50: 7.9 mg/L 4 d (fish)
3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-6-yl acetate LC50: 18 mg/L 4 d (fish)
hexyl salicylate
CAS No.: 5413-60-5 EC No.: 226-501-6
CAS No.: 6259-76-3 EC No.: 228-408-6
LC50: 1.34 mg/L 4 d (fish)
3,7-dimethylnona-2,6-dienenitrile LC50: 2.4 mg/L 4 d (fish)
2,6-di-tert-butyl-p-cresol
CAS No.: 61792-11-8 EC No.: 263-214-5
CAS No.: 128-37-0 EC No.: 204-881-4
EC50: 0.48 mg/L 2 d (crustaceans, Daphnia magna (Big water flea))
(E)-dodec-2-en-1-al
CAS No.: 20407-84-5 EC No.: 243-797-2
LC50: 0.718 mg/L 4 d (fish)
allyl (3-methylbutoxy)acetate
CAS No.: 67634-00-8 EC No.: 266-803-5
4-tert-butylcyclohexyl acetate
CAS No.: 32210-23-4 EC No.: 250-954-9
LC50: 0.77 mg/L
LC50: 8.6 mg/L 4 d (fish)
Aquatic toxicity: Toxic to aquatic life with long lasting effects. Assessment/classification: No further relevant information available.
12.2. Persistence and degradability Orange, sweet, ext.
CAS No.: 8028-48-6 EC No.: 232-433-8
Biodegradation: Yes, rapidly
citral
CAS No.: 5392-40-5 EC No.: 226-394-6
Biodegradation: Yes, rapidly
methyl anthranilate
CAS No.: 134-20-3 EC No.: 205-132-4
Biodegradation: Yes, rapidly
Linalool: 3,7-Dimethyl- 1,6-octadien-3-ol; DL-Linalool Biodegradation: Yes, rapidly
decanal
CAS No.: 78-70-6 EC No.: 201-134-4
CAS No.: 112-31-2 EC No.: 203-957-4
Biodegradation: Yes, rapidly
CITRONELLA OIL
CAS No.: 8000-29-1 EC No.: 616-771-7
Biodegradation: Yes, rapidly
3,5,5-trimethylhexyl acetate
Biodegradation: Yes, rapidly
p-menth-1-en-8-ol
CAS No.: 58430-94-7 EC No.: 261-245-9
CAS No.: 98-55-5 EC No.: 202-680-6
Biodegradation: Yes, rapidly
geraniol
CAS No.: 106-24-1 EC No.: 203-377-1
Biodegradation: Yes, rapidly
linalyl acetate
CAS No.: 115-95-7 EC No.: 204-116-4
Biodegradation: Yes, rapidly
octanal
CAS No.: 124-13-0 EC No.: 204-683-8
Biodegradation: Yes, slowly
citronellol
CAS No.: 106-22-9 EC No.: 203-375-0
Biodegradation: Yes, rapidly
3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-6-yl acetate Biodegradation: Yes, rapidly
according to Regulation (EC) No. 2020/878 (REACH)
CAS No.: 5413-60-5 EC No.: 226-501-6
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 2 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 10/14
SUMMER ORANGE hexyl salicylate
CAS No.: 6259-76-3 EC No.: 228-408-6
Biodegradation: Yes, rapidly
3,7-dimethylnona-2,6-dienenitrile Biodegradation: Yes, slowly
2,6-di-tert-butyl-p-cresol
CAS No.: 61792-11-8 EC No.: 263-214-5
CAS No.: 128-37-0 EC No.: 204-881-4
Biodegradation: Yes, slowly
(E)-dodec-2-en-1-al
CAS No.: 20407-84-5 EC No.: 243-797-2
Biodegradation: Yes, rapidly
Hexyl Cinnamal
CAS No.: 101-86-0 EC No.: 202-983-3
Biodegradation: Yes, rapidly
allyl (3-methylbutoxy)acetate
CAS No.: 67634-00-8 EC No.: 266-803-5
4-tert-butylcyclohexyl acetate
CAS No.: 32210-23-4 EC No.: 250-954-9
Biodegradation: Yes, rapidly Biodegradation: Yes, rapidly
Biodegradation: Part of the components is biodegradable.
12.3. Bioaccumulative potential 2,6-di-tert-butyl-p-cresol Log KOW: 5.1
CAS No.: 128-37-0 EC No.: 204-881-4
Accumulation / Evaluation: No further relevant information available.
12.4. Mobility in soil
No further relevant information available.
12.5. Results of PBT and vPvB assessment Orange, sweet, ext.
CAS No.: 8028-48-6 EC No.: 232-433-8
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
citral
CAS No.: 5392-40-5 EC No.: 226-394-6
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
methyl anthranilate
CAS No.: 134-20-3 EC No.: 205-132-4
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
Linalool: 3,7-Dimethyl- 1,6-octadien-3-ol; DL-Linalool
CAS No.: 78-70-6 EC No.: 201-134-4
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
decanal
CAS No.: 112-31-2 EC No.: 203-957-4
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
CITRONELLA OIL
CAS No.: 8000-29-1 EC No.: 616-771-7
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
3,5,5-trimethylhexyl acetate
CAS No.: 58430-94-7 EC No.: 261-245-9
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
p-menth-1-en-8-ol
CAS No.: 98-55-5 EC No.: 202-680-6
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
geraniol
CAS No.: 106-24-1 EC No.: 203-377-1
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
linalyl acetate
CAS No.: 115-95-7 EC No.: 204-116-4
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
octanal
CAS No.: 124-13-0 EC No.: 204-683-8
Results of PBT and vPvB assessment: —
citronellol
CAS No.: 106-22-9 EC No.: 203-375-0
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
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SUMMER ORANGE 3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-6-yl acetate
CAS No.: 5413-60-5 EC No.: 226-501-6
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
hexyl salicylate
CAS No.: 6259-76-3 EC No.: 228-408-6
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
3,7-dimethylnona-2,6-dienenitrile
CAS No.: 61792-11-8 EC No.: 263-214-5
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
2,6-di-tert-butyl-p-cresol
CAS No.: 128-37-0 EC No.: 204-881-4
Results of PBT and vPvB assessment: —
(E)-dodec-2-en-1-al
CAS No.: 20407-84-5 EC No.: 243-797-2
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
allyl heptanoate
CAS No.: 142-19-8 EC No.: 205-527-1
Hexyl Cinnamal
CAS No.: 101-86-0 EC No.: 202-983-3
Results of PBT and vPvB assessment: —
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
allyl (3-methylbutoxy)acetate
CAS No.: 67634-00-8 EC No.: 266-803-5
4-tert-butylcyclohexyl acetate
CAS No.: 32210-23-4 EC No.: 250-954-9
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII. Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
12.6. Endocrine disrupting properties
The product contains a substance that is identified as having endocrine disrupting properties. p-Menth-1-en-8-ol CAS: 98-55-5 ; EC: 202-680-6 2,6-Di-tert-butyl-p-cresol CAS: 128-37-0 ; EC: 204-881-4
12.7. Other adverse effects No data available
SECTION 13: Disposal considerations 13.1. Waste treatment methods
The allocation of waste identity numbers/waste descriptions must be carried out according to the EWC, specific to the industry and process.
13.1.1. Product/Packaging disposal Waste codes/waste designations according to EWC/AVV Waste code product
16 03 05 * organic wastes containing hazardous substances *: Evidence for disposal must be provided.
Waste treatment options
Appropriate disposal / Product: Consult the appropriate local waste disposal expert about waste disposal. Appropriate disposal / Package: Non-contaminated packages may be recycled. Completely emptied bricks, disks and membranes can be recycled.
13.2. Additional information
* = "S" In Switzerland, commercial hazardous waste shall be delivered to a disposal company.
SECTION 14: Transport information Land transport (ADR/RID)
Sea transport (IMDG)
Air transport (ICAO-TI / IATA-DGR)
UN 3077
UN 3077
UN 3077
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Orange, sweet, ext., 3,5,5-trimethylhexyl acetate)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Orange, sweet, ext., 3,5,5-trimethylhexyl acetate)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Orange, sweet, ext., 3,5,5-trimethylhexyl acetate)
14.1. UN number or ID number
14.2. UN proper shipping name
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 2 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 12/14
SUMMER ORANGE Land transport (ADR/RID)
Sea transport (IMDG)
14.3. Transport hazard class(es)
9
14.4. Packing group III
14.5. Environmental hazards
9
9
III
14.6. Special precautions for user Special Provisions: 274 | 335 | 375 | 601 Limited quantity (LQ): 5 kg Excepted Quantities (EQ): E1 Hazard identification number (Kemler No.): 90 Classification code: M7 Tunnel restriction code: (-)
Air transport (ICAO-TI / IATA-DGR)
III
MARINE POLLUTANT
Special Provisions: 274 | 335 | 966 | 967 | 969 Limited quantity (LQ): 5 kg Excepted Quantities (EQ): E1 EmS-No.: F-A, S-F
Special Provisions: A97 | A158 | A179 | A197 | A215 Limited quantity (LQ): Y956 Excepted Quantities (EQ): E1
14.7. Maritime transport in bulk according to IMO instruments Additional information: Solid, inert fiber block soaked with liquid mixture for odour neutralisation.
SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU legislation
Restrictions on use: According to directive 94/33/EC, juveniles are only allowed to handle this product as long as all effects of dangerous substances are prevented. Observe employment restrictions under the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers. Other regulations (EU): Directive 2012/18/EU on the control of major-accident hazards involving dangerous substances [SevesoIII-Directive], Hazard categories: • E2 Hazardous to the Aquatic Environment in Category Chronic 2
15.1.2. National regulations No data available
15.2. Chemical Safety Assessment
Chemical safety assessments for substances in this mixture were not carried out.
SECTION 16: Other information 16.1. Indication of changes 2.3.
Other hazards
16.2. Abbreviations and acronyms
For abbreviations and acronyms, see table on the eSDScom website
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 2 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 13/14
SUMMER ORANGE -ADR: European agreement concerning the international carriage of dangerous goods by road (Accord européen relatif transport des merchandises dangereuses par route) -CAS: Chemical Abstracts Service -CLP: Classification, labelling and Packaging -DNEL: Derived No Effect Level -EC50: Effective Concentration 50% -ECHA: European Chemical Agency -LC50: Lethal Concentration 50% -LD50: Lethal Dose 50% -PBT: persistent, bioaccumulative, toxic -PNEC: Predicted No Effect Concentration -REACH: Registration, Evaluation and Authorization of Chemicals -SVHC: Substance of Very High Concern -VOC: Volatile organic compounds -vPvB: very persistent, very bioaccumulative
16.3. Key literature references and sources for data
REACH Dissemination Portal https://echa.europa.eu/de/information-on-chemicals/registered-substances
16.4. Classification for mixtures and used evaluation method according to regulation (EC) No. 1272/2008 [CLP] Hazard classes and hazard categories
Hazard statements
Classification procedure Calculation method.
Skin corrosion/irritation (Skin Irrit. 2)
H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
Calculation method. Calculation method.
H318: Causes serious eye damage.
Calculation method.
Hazardous to the aquatic environment H411: Toxic to aquatic life with long (Aquatic Chronic 2) lasting effects.
Calculation method.
Aspiration hazard (Asp. Tox. 1)
Respiratory or skin sensitisation (Skin Sens. 1)
Serious eye damage/eye irritation (Eye Dam. 1)
16.5. Relevant R-, H- and EUH-phrases (Number and full text) Hazard statements H226
Flammable liquid and vapour.
H302
Harmful if swallowed.
H301 H304 H311 H315 H317 H318 H319 H330 H331 H400 H410 H411 H412
Toxic if swallowed.
May be fatal if swallowed and enters airways. Toxic in contact with skin. Causes skin irritation.
May cause an allergic skin reaction. Causes serious eye damage.
Causes serious eye irritation. Fatal if inhaled.
Toxic if inhaled.
Very toxic to aquatic life.
Very toxic to aquatic life with long lasting effects. Toxic to aquatic life with long lasting effects.
Harmful to aquatic life with long lasting effects.
16.6. Training advice No data available
16.7. Additional information No data available
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 2 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 14/14
SUMMER ORANGE * Data changed compared with the previous version.
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de