Linen - UK

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 1/12

LINEN SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier

Trade name/designation:

LINEN

Other means of identification: FIBER: 56-1954, 56-1991 UFI: PTA3-CNVW-580V-YAQA

1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture: aromatisation

Relevant identified uses:

Life cycle stage [LCS] PW: Widespread use by professional workers Product Categories [PC] PC 28: Perfumes, fragrances

1.3. Details of the supplier of the safety data sheet Supplier (manufacturer/importer/only representative/downstream user/distributor): Vaportek Europe Logistic Sarl 6 Route du Grand Lancy 1211 Genève 26 Switzerland Telephone: +41 22 342 2145 E-mail: vaportek@gmail.com

E-mail (competent person): vaportek@gmail.com

1.4. Emergency telephone number 24h: NHS (National Health Service): 111

SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Hazard classes and hazard categories

Hazard statements

Classification procedure

Skin corrosion/irritation (Skin Irrit. 2) Respiratory or skin sensitisation (Skin Sens. 1)

H315: Causes skin irritation.

Calculation method.

Serious eye damage/eye irritation (Eye Irrit. 2)

H317: May cause an allergic skin reaction.

H319: Causes serious eye irritation.

Berechnungsmethode

Hazardous to the aquatic environment H411: Toxic to aquatic life with long (Aquatic Chronic 2) lasting effects.

Berechnungsmethode

Berechnungsmethode

2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms:

GHS07

Exclamation mark

GHS09

Environment

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 2/12

LINEN Signal word: Warning Hazard components for labelling: 1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one; coumarin; ?-hexylcinnamaldehyde; 7-hydroxycitronellal Hazard statements for health hazards H315

Causes skin irritation.

H319

Causes serious eye irritation.

H317

May cause an allergic skin reaction.

Hazard statements for environmental hazards H411

Toxic to aquatic life with long lasting effects.

Precautionary statements Prevention P280

Wear protective gloves and eye/face protection.

Precautionary statements Response P301 + P310 P302 + P352

IF SWALLOWED: Immediately call a POISON CENTER. IF ON SKIN: Wash with plenty of soap and water.

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Precautionary statements Disposal P501

Dispose of contents/container to an appropriate recycling or disposal facility.

* 2.3. Other hazards

Adverse physicochemical effects: No further relevant information available.

Adverse human health effects and symptoms: The product contains a substance that is identified as having endocrine disrupting properties.

1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one 1506-02-1 1506-02-1 Benzyl salicylate 118-58-1 204-262-9 [3R-(3α,3aβ,7β,8aα)]-1-(2,3,4,7,8,8a-hexahydro-3,6,8,8-tetramethyl-1H-3a,7-methanoazulen-5yl)ethan-1-one 32388-55-9 251-020-3 α-Terpineol 98-55-5 204-263-4 Adverse environmental effects: The product contains a substance that is identified as having endocrine disrupting properties.

1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one 1506-02-1 1506-02-1 Benzyl salicylate 118-58-1 204-262-9 [3R-(3α,3aβ,7β,8aα)]-1-(2,3,4,7,8,8a-hexahydro-3,6,8,8-tetramethyl-1H-3a,7-methanoazulen-5yl)ethan-1-one 32388-55-9 251-020-3 α-Terpineol 98-55-5 204-263-4 The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII. Other adverse effects: No further relevant information available.

SECTION 3: Composition/information on ingredients 3.2. Mixtures

Hazardous ingredients / Hazardous impurities / Stabilisers: Product identifiers CAS No.: 101-86-0 EC No.: 202-983-3 CAS No.: 134-20-3 EC No.: 205-132-4

Substance name Concentration Classification according to Regulation (EC) No. 1272/2008 [CLP] ?-hexylcinnamaldehyde 10 – ≤ 15 Aquatic Acute 1 (H400), Aquatic Chronic 2 (H411), Skin Sens. 1B (H317) weight-% Warning

methyl anthranilate Eye Irrit. 2 (H319) Warning

according to Regulation (EC) No. 2020/878 (REACH)

5 – ≤ 12 weight-%

en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 3/12

LINEN Product identifiers

Substance name Concentration Classification according to Regulation (EC) No. 1272/2008 [CLP] 7-hydroxycitronellal Eye Irrit. 2 (H319), Skin Sens. 1B (H317)

5 – ≤ 12 weight-%

1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2naphthyl)ethan-1-one Acute Tox. 4 (H302), Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410)

4 – ≤ 10 weight-%

CAS No.: 103-95-7 EC No.: 203-161-7

3-p-cumenyl-2-methylpropionaldehyde Aquatic Chronic 3 (H412), Skin Irrit. 2 (H315), Skin Sens. 1B (H317)

4 – ≤ 10 weight-%

CAS No.: 91-64-5 EC No.: 202-086-7

coumarin Acute Tox. 4 (H302), Aquatic Chronic 3 (H412), Skin Sens. 1 (H317)

2–≤5 weight-%

CAS No.: 32210-23-4 EC No.: 250-954-9

4-tert-butylcyclohexyl acetate Skin Sens. 1B (H317)

2–≤5 weight-%

CAS No.: 118-58-1 EC No.: 204-262-9

benzyl salicylate Aquatic Chronic 3 (H412), Eye Irrit. 2 (H319), Skin Sens. 1B (H317)

2–≤5 weight-%

CAS No.: 5413-60-5 EC No.: 226-501-6

3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-6-yl acetate Aquatic Chronic 3 (H412)

2–≤5 weight-%

CAS No.: 8007-35-0 EC No.: 232-357-5

Terpineol, acetate Aquatic Chronic 3 (H412)

CAS No.: 3407-42-9 EC No.: 222-294-1

3-(5,5,6-trimethylbicyclo[2.2.1]hept-2-yl)cyclohexan-1-ol Aquatic Chronic 2 (H411), Eye Irrit. 2 (H319)

≤2 weight-%

CAS No.: 106-22-9 EC No.: 203-375-0

citronellol Eye Irrit. 2 (H319), Skin Irrit. 2 (H315), Skin Sens. 1B (H317)

≤2 weight-%

CAS No.: 4707-47-5 EC No.: 225-193-0

methyl 2,4-dihydroxy-3,6-dimethylbenzoate Skin Sens. 1B (H317)

≤1 weight-%

CAS No.: 120-57-0 EC No.: 204-409-7

piperonal Skin Sens. 1 (H317)

≤1 weight-%

CAS No.: 110-41-8 EC No.: 203-765-0

2-methylundecanal Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410), Skin Irrit. 2 (H315), Skin Sens. 1B (H317)

≤ 0.2 weight-%

CAS No.: 107-75-5 EC No.: 203-518-7 CAS No.: 1506-02-1 EC No.: 216-133-4

Warning

Warning

CAS No.: 8000-34-8

Warning

Warning

Warning

Warning

Patchouly Oil Asp. Tox. 1 (H304), Eye Irrit. 2 (H319), Skin Sens. 1 (H317) Danger

CAS No.: 98-55-5 EC No.: 202-680-6

p-menth-1-en-8-ol Eye Irrit. 2 (H319), Skin Irrit. 2 (H315) Warning

Warning

Warning

Warning

Warning

1–≤3 weight-% 1–≤3 weight-% ≤2 weight-%

Warning Full text of H- and EUH-phrases: see section 16.

SECTION 4: First aid measures 4.1. Description of first aid measures

General information: In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible).

Remove victim out of the danger area. Remove contaminated, saturated clothing. according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 4/12

LINEN If unconscious but breathing normally, place in recovery position and seek medical advice. Do not leave affected person unattended.

Following inhalation: Provide fresh air. In case of respiratory tract irritation, consult a physician.

In case of skin contact: After contact with skin, wash immediately with plenty of water and soap.

Take off immediately all contaminated clothing. If skin irritation or rash occurs: Get medical advice/ attention.

After eye contact: In case of contact with eyes, rinse immediately thoroughly with plenty of edible oil and consult an ophthalmologist.

Following ingestion: Ingestion of the mixture / product is hardly possible.

Rinse mouth.

Get medical advice/attention if you feel unwell.

Let water be drunken in little sips (dilution effect).

Self-protection of the first aider: Use personal protection equipment.

4.2. Most important symptoms and effects, both acute and delayed Causes skin irritation.

Allergic reactions Serious eye damage/eye irritation Skin corrosion/irritation

4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically.

SECTION 5: Firefighting measures 5.1. Extinguishing media

Suitable extinguishing media: alcohol resistant foam Extinguishing powder Carbon dioxide (CO2) Water spray jet Unsuitable extinguishing media: Full water jet

5.2. Special hazards arising from the substance or mixture Combustible Hazardous combustion products: Gases/vapours, irritant

5.3. Advice for firefighters

Wear a self-contained breathing apparatus and chemical protective clothing.

5.4. Additional information

Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.

SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Personal precautions: Remove persons to safety.

Protective equipment: Wear protective gloves/protective clothing/eye protection/face protection.

6.1.2. For emergency responders

Personal protection equipment: Personal protection equipment: see section 8

6.2. Environmental precautions

Do not allow to enter into surface water or drains.

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 5/12

LINEN 6.3. Methods and material for containment and cleaning up For cleaning up: Take up mechanically, placing in appropriate containers for disposal.

6.4. Reference to other sections

Safe handling: see section 7 Personal protection equipment: see section 8 Disposal: see section 13

6.5. Additional information

Use appropriate container to avoid environmental contamination.

SECTION 7: Handling and storage 7.1. Precautions for safe handling Protective measures

Advices on safe handling: Wear personal protection equipment (refer to section 8).

Fire prevent measures: Take precautionary measures against static discharge.

Keep away from sources of ignition - No smoking.

Advices on general occupational hygiene When using do not eat, drink or smoke.

Avoid contact with eyes and skin.

7.2. Conditions for safe storage, including any incompatibilities

Technical measures and storage conditions: Keep container tightly closed in a cool, well-ventilated place.

Storage class (TRGS 510, Germany): 10 – Combustible liquids that cannot be assigned to any of the above storage classes

7.3. Specific end use(s) No data available

SECTION 8: Exposure controls/personal protection 8.1. Control parameters No data available

8.2. Exposure controls 8.2.1. Appropriate engineering controls No data available

8.2.2. Personal protection equipment

Eye/face protection: Eye glasses with side protection EN 166 Skin protection: Tested protective gloves must be worn EN ISO 374 Suitable material: NBR (Nitrile rubber), In the case of wanting to use the gloves again, clean them before taking off and air them well.

Breakthrough times and swelling properties of the material must be taken into consideration.

Respiratory protection: Usually no personal respirative protection necessary.

Respiratory protection necessary at: Handling larger quantities,

8.2.3. Environmental exposure controls No data available

SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state: Liquid Odour: fruity

according to Regulation (EC) No. 2020/878 (REACH)

Colour: yellow Odour threshold: not determined en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 6/12

LINEN Safety relevant basis data Parameter

Value

pH

not applicable

Melting point

① Method ② Remark

not determined

Freezing point

not determined

Decomposition temperature

not determined

Evaporation rate

not determined

Initial boiling point and boiling range > 150 °C Flash point

> 93 °C

Auto-ignition temperature

not determined

Upper/lower flammability or explosive limits

not determined

Vapour pressure

not determined

Vapour density

not determined

Density

not determined

Relative density

not determined

Bulk density

not determined

Water solubility

Immiscible

Dynamic viscosity

not determined

Partition coefficient: n-octanol/water not determined Kinematic viscosity

not determined

9.2. Other information

Solid, inert fiber block soaked with liquid mixture for odour neutralisation.

The properties listed relate to the liquid.

SECTION 10: Stability and reactivity 10.1. Reactivity

This material is considered to be non-reactive under normal use conditions. Combustible

10.2. Chemical stability

The product is stable under storage at normal ambient temperatures.

10.3. Possibility of hazardous reactions No known hazardous reactions.

10.4. Conditions to avoid

Stable under recommended storage and handling conditions.

10.5. Incompatible materials

No further relevant information available.

10.6. Hazardous decomposition products

Thermal decomposition can lead to the escape of irritating gases and vapours.

SECTION 11: Toxicological information 11.1. Information on hazard classes as defined in Regulation (EC) No. 1272/2008 7-hydroxycitronellal

CAS No.: 107-75-5 EC No.: 203-518-7

LD50 oral: >6,400 mg/kg

LD50 dermal: >2,000 mg/kg

3-p-cumenyl-2-methylpropionaldehyde LD50 oral: 3,810 mg/kg

coumarin

CAS No.: 103-95-7 EC No.: 203-161-7

CAS No.: 91-64-5 EC No.: 202-086-7

LD50 oral: 520 mg/kg

4-tert-butylcyclohexyl acetate LD50 oral: 3,323 mg/kg

CAS No.: 32210-23-4 EC No.: 250-954-9

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 7/12

LINEN benzyl salicylate

CAS No.: 118-58-1 EC No.: 204-262-9

LD50 oral: >3,000 mg/kg

LD50 dermal: >2,000 mg/kg

3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-6-yl acetate LD50 oral: 5,400 mg/kg

p-menth-1-en-8-ol

CAS No.: 5413-60-5 EC No.: 226-501-6

CAS No.: 98-55-5 EC No.: 202-680-6

LD50 oral: =4,300 mg/kg

LD50 dermal: >2,000 mg/kg

Acute oral toxicity: Based on available data, the classification criteria are not met.

Acute dermal toxicity: Based on available data, the classification criteria are not met.

Acute inhalation toxicity: Based on available data, the classification criteria are not met.

Skin corrosion/irritation: Causes skin irritation.

Serious eye damage/irritation: Causes serious eye irritation.

Respiratory or skin sensitisation: May cause an allergic skin reaction.

Germ cell mutagenicity: Based on available data, the classification criteria are not met.

Carcinogenicity: Based on available data, the classification criteria are not met.

Reproductive toxicity: Based on available data, the classification criteria are not met.

STOT-single exposure: Based on available data, the classification criteria are not met.

STOT-repeated exposure: Based on available data, the classification criteria are not met.

Aspiration hazard: Based on available data, the classification criteria are not met.

Additional information: No data available

11.2. Information on other hazards

Endocrine disrupting properties: The product contains a substance that is identified as having endocrine disrupting properties.

1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one 1506-02-1 1506-02-1 Benzyl salicylate 118-58-1 204-262-9 [3R-(3α,3aβ,7β,8aα)]-1-(2,3,4,7,8,8a-hexahydro-3,6,8,8-tetramethyl-1H-3a,7-methanoazulen-5yl)ethan-1-one 32388-55-9 251-020-3 α-Terpineol 98-55-5 204-263-4

SECTION 12: Ecological information 12.1. Toxicity 3-p-cumenyl-2-methylpropionaldehyde LC50: 1 mg/L 4 d (fish)

4-tert-butylcyclohexyl acetate LC50: 8.6 mg/L 4 d (fish)

benzyl salicylate

CAS No.: 103-95-7 EC No.: 203-161-7

CAS No.: 32210-23-4 EC No.: 250-954-9

CAS No.: 118-58-1 EC No.: 204-262-9

LC50: 1.03 mg/L 4 d (fish)

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 8/12

LINEN 3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-6-yl acetate LC50: 18 mg/L 4 d (fish)

p-menth-1-en-8-ol

CAS No.: 5413-60-5 EC No.: 226-501-6

CAS No.: 98-55-5 EC No.: 202-680-6

LC50: =70 mg/L 4 d (fish)

Aquatic toxicity: Toxic to aquatic life with long lasting effects.

Assessment/classification: No further relevant information available.

12.2. Persistence and degradability ?-hexylcinnamaldehyde

CAS No.: 101-86-0 EC No.: 202-983-3

Biodegradation: Yes, rapidly

methyl anthranilate

CAS No.: 134-20-3 EC No.: 205-132-4

7-hydroxycitronellal

CAS No.: 107-75-5 EC No.: 203-518-7

Biodegradation: Yes, rapidly Biodegradation: Yes, rapidly

3-p-cumenyl-2-methylpropionaldehyde Biodegradation: Yes, rapidly

coumarin

CAS No.: 103-95-7 EC No.: 203-161-7

CAS No.: 91-64-5 EC No.: 202-086-7

Biodegradation: Yes, rapidly

4-tert-butylcyclohexyl acetate Biodegradation: Yes, rapidly

benzyl salicylate

CAS No.: 32210-23-4 EC No.: 250-954-9

CAS No.: 118-58-1 EC No.: 204-262-9

Biodegradation: Yes, rapidly

3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-6-yl acetate Biodegradation: Yes, rapidly

Patchouly Oil

CAS No.: 5413-60-5 EC No.: 226-501-6

CAS No.: 8000-34-8

Biodegradation: Yes, rapidly

Terpineol, acetate

CAS No.: 8007-35-0 EC No.: 232-357-5

p-menth-1-en-8-ol

CAS No.: 98-55-5 EC No.: 202-680-6

Biodegradation: —

Biodegradation: Yes, rapidly

3-(5,5,6-trimethylbicyclo[2.2.1]hept-2-yl)cyclohexan-1-ol Biodegradation: Yes, rapidly

citronellol

CAS No.: 3407-42-9 EC No.: 222-294-1

CAS No.: 106-22-9 EC No.: 203-375-0

Biodegradation: Yes, rapidly

methyl 2,4-dihydroxy-3,6-dimethylbenzoate Biodegradation: Yes, rapidly

piperonal

CAS No.: 4707-47-5 EC No.: 225-193-0

CAS No.: 120-57-0 EC No.: 204-409-7

Biodegradation: Yes, rapidly

2-methylundecanal

CAS No.: 110-41-8 EC No.: 203-765-0

Biodegradation: Yes, rapidly

Biodegradation: Part of the components is biodegradable.

12.3. Bioaccumulative potential

Accumulation / Evaluation: No further relevant information available.

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 9/12

LINEN 12.4. Mobility in soil

No further relevant information available.

12.5. Results of PBT and vPvB assessment ?-hexylcinnamaldehyde

CAS No.: 101-86-0 EC No.: 202-983-3

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

methyl anthranilate

CAS No.: 134-20-3 EC No.: 205-132-4

7-hydroxycitronellal

CAS No.: 107-75-5 EC No.: 203-518-7

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII. Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one

CAS No.: 1506-02-1 EC No.: 216-133-4

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

3-p-cumenyl-2-methylpropionaldehyde

CAS No.: 103-95-7 EC No.: 203-161-7

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

coumarin

CAS No.: 91-64-5 EC No.: 202-086-7

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

4-tert-butylcyclohexyl acetate

CAS No.: 32210-23-4 EC No.: 250-954-9

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

benzyl salicylate

CAS No.: 118-58-1 EC No.: 204-262-9

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-6-yl acetate

CAS No.: 5413-60-5 EC No.: 226-501-6

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

Patchouly Oil

CAS No.: 8000-34-8

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

Terpineol, acetate

CAS No.: 8007-35-0 EC No.: 232-357-5

p-menth-1-en-8-ol

CAS No.: 98-55-5 EC No.: 202-680-6

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII. Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

3-(5,5,6-trimethylbicyclo[2.2.1]hept-2-yl)cyclohexan-1-ol

CAS No.: 3407-42-9 EC No.: 222-294-1

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

citronellol

CAS No.: 106-22-9 EC No.: 203-375-0

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

methyl 2,4-dihydroxy-3,6-dimethylbenzoate

CAS No.: 4707-47-5 EC No.: 225-193-0

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

piperonal

CAS No.: 120-57-0 EC No.: 204-409-7

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

2-methylundecanal

CAS No.: 110-41-8 EC No.: 203-765-0

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

12.6. Endocrine disrupting properties

The product contains a substance that is identified as having endocrine disrupting properties.

1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one 1506-02-1 Benzyl salicylate 118-58-1 204-262-9 [3R-(3α,3aβ,7β,8aα)]-1-(2,3,4,7,8,8a-hexahydro-3,6,8,8-tetramethyl-1H-3a,7-methanoazulen-5yl)ethan-1-one 32388-55-9 251-020-3 α-Terpineol 98-55-5 204-263-4

12.7. Other adverse effects No data available

SECTION 13: Disposal considerations 13.1. Waste treatment methods

The allocation of waste identity numbers/waste descriptions must be carried out according to the EWC, specific to the industry and process.

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 10/12

LINEN 13.1.1. Product/Packaging disposal Waste codes/waste designations according to EWC/AVV Waste code product

16 03 05 * organic wastes containing hazardous substances *: Evidence for disposal must be provided.

Waste treatment options

Appropriate disposal / Product: Consult the appropriate local waste disposal expert about waste disposal.

Appropriate disposal / Package: Non-contaminated packages may be recycled.

Completely emptied bricks, disks and membranes can be recycled.

13.2. Additional information

* = "S" In Switzerland, commercial hazardous waste shall be delivered to a disposal company.

SECTION 14: Transport information Land transport (ADR/RID)

Sea transport (IMDG)

Air transport (ICAO-TI / IATA-DGR)

UN 3077

UN 3077

UN 3077

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (?hexylcinnamaldehyde, 1-(5,6,7,8tetrahydro-3,5,5,6,8,8-hexamethyl-2naphthyl)ethan-1-one)

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (?hexylcinnamaldehyde, 1-(5,6,7,8tetrahydro-3,5,5,6,8,8-hexamethyl-2naphthyl)ethan-1-one)

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (?hexylcinnamaldehyde, 1-(5,6,7,8tetrahydro-3,5,5,6,8,8-hexamethyl-2naphthyl)ethan-1-one)

14.1. UN number or ID number

14.2. UN proper shipping name

14.3. Transport hazard class(es)

9

14.4. Packing group III

14.5. Environmental hazards

9 III

14.6. Special precautions for user Special Provisions: 274 | 335 | 375 | 601 Limited quantity (LQ): 5 kg Excepted Quantities (EQ): E1 Hazard identification number (Kemler No.): 90 Classification code: M7 Tunnel restriction code: (-)

9 III

MARINE POLLUTANT

Special Provisions: 274 | 335 | 966 | 967 | 969 Limited quantity (LQ): 5 kg Excepted Quantities (EQ): E1 EmS-No.: F-A, S-F

Special Provisions: A97 | A158 | A179 | A197 | A215 Limited quantity (LQ): Y956 Excepted Quantities (EQ): E1

14.7. Maritime transport in bulk according to IMO instruments Additional information: Solid, inert fiber block soaked with liquid mixture for odour neutralisation.

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 11/12

LINEN SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU legislation

Restrictions on use: According to directive 94/33/EC, juveniles are only allowed to handle this product as long as all effects of dangerous substances are prevented.

Observe employment restrictions under the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.

Other regulations (EU): Directive 2012/18/EU on the control of major-accident hazards involving dangerous substances [SevesoIII-Directive], Hazard categories: • E2 Hazardous to the Aquatic Environment in Category Chronic 2

15.1.2. National regulations No data available

15.2. Chemical Safety Assessment

Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information 16.1. Indication of changes 2.3.

Other hazards

16.2. Abbreviations and acronyms ADR CAS CLP DIN DNEL EN EWC ICAO IMDG IMO LC50 LD50 NFPA PBT PC PNEC REACH RID TRGS UN VOC

European Agreement concerning the International Carriage of Dangerous Goods by Road Chemical Abstracts Service Classification, Labelling and Packaging German Institute for Standardization / German Industrial Standard derived no-effect level European Standard European Waste Catalogue International Civil Aviation Organization International Maritime Dangerous Goods International Maritime Organization Lethal (fatal) Concentration 50% Lethal (fatal) Dose 50% National Fire Protection Association persistent and bioaccumulative and toxic Product category Predicted No Effect Concentration Registration, Evaluation and Authorization of Chemicals Dangerous goods regulations for transport by rail Technische Regeln für Gefahrstoffe United Nations Volatile organic compounds

16.3. Key literature references and sources for data

REACH Dissemination Portal https://echa.europa.eu/de/information-on-chemicals/registered-substances

16.4. Classification for mixtures and used evaluation method according to regulation (EC) No. 1272/2008 [CLP] Hazard classes and hazard categories

Hazard statements

Classification procedure

Respiratory or skin sensitisation (Skin Sens. 1)

H315: Causes skin irritation.

H317: May cause an allergic skin reaction.

Calculation method.

Skin corrosion/irritation (Skin Irrit. 2)

according to Regulation (EC) No. 2020/878 (REACH)

Berechnungsmethode

en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 12/12

LINEN Hazard classes and hazard categories

Hazard statements

Classification procedure

H319: Causes serious eye irritation.

Berechnungsmethode

Hazardous to the aquatic environment H411: Toxic to aquatic life with long (Aquatic Chronic 2) lasting effects.

Berechnungsmethode

Serious eye damage/eye irritation (Eye Irrit. 2)

16.5. Relevant R-, H- and EUH-phrases (Number and full text) Hazard statements H302

Harmful if swallowed.

H315

Causes skin irritation.

H304 H317 H319 H400 H410 H411 H412

May be fatal if swallowed and enters airways.

May cause an allergic skin reaction.

Causes serious eye irritation.

Very toxic to aquatic life.

Very toxic to aquatic life with long lasting effects.

Toxic to aquatic life with long lasting effects.

Harmful to aquatic life with long lasting effects.

16.6. Training advice No data available

16.7. Additional information No data available

* Data changed compared with the previous version.

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de