Issuu

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 1/11

Ecoz Linen concentrate SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier

Trade name/designation:

Ecoz Linen concentrate

Article No.: 56-1510, 56-1511, 56-1550 UFI: NU83-RN0S-480G-RG9U

1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture: Water soluble odour neutralising liquid concentrate

Relevant identified uses:

Life cycle stage [LCS] PW: Widespread use by professional workers Product Categories [PC] PC 28: Perfumes, fragrances

1.3. Details of the supplier of the safety data sheet Supplier (manufacturer/importer/only representative/downstream user/distributor): Vaportek Europe Logistic Sarl 6 Route du Grand Lancy 1211 Genève 26 Switzerland Telephone: +41 22 342 2145 E-mail: vaportek@gmail.com

E-mail (competent person): vaportek@gmail.com

1.4. Emergency telephone number 24h: NHS (National Health Service): 111

SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Hazard classes and hazard categories

Serious eye damage/eye irritation (Eye Irrit. 2)

Hazard statements

Classification procedure

H319: Causes serious eye irritation.

Calculation method.

Hazardous to the aquatic environment H412: Harmful to aquatic life with long Calculation method. (Aquatic Chronic 3) lasting effects.

2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms:

GHS07

Exclamation mark

Signal word: Warning

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 2/11

Ecoz Linen concentrate Hazard components for labelling: 1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one; coumarin; α-hexylcinnamaldehyde; 7-hydroxycitronellal Hazard statements for health hazards H319

Causes serious eye irritation.

Hazard statements for environmental hazards H412

Harmful to aquatic life with long lasting effects.

Supplemental hazard information EUH208

Contains 7-hydroxycitronellal, 4-tert-butylcyclohexyl acetate, ?-hexylcinnamaldehyde, Patchouly Oil, benzyl salicylate, coumarin, 3-p-cumenyl-2-methylpropionaldehyde. May produce an allergic reaction.

Precautionary statements Prevention P264

Wash hands thoroughly after handling.

P280

Wear protective gloves and eye/face protection.

P273

Avoid release to the environment.

Precautionary statements Response

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 P391

If eye irritation persists: Get medical advice/attention. Collect spillage.

Precautionary statements Disposal P501

Dispose of contents/container to an appropriate recycling or disposal facility.

* 2.3. Other hazards

Adverse physicochemical effects: No further relevant information available. Adverse human health effects and symptoms: The product contains a substance that is identified as having endocrine disrupting properties. 1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one 1506-02-1 1506-02-1 Benzyl salicylate 118-58-1 204-262-9 [3R-(3α,3aβ,7β,8aα)]-1-(2,3,4,7,8,8a-hexahydro-3,6,8,8-tetramethyl-1H-3a,7-methanoazulen-5yl)ethan-1-one 32388-55-9 251-020-3 α-Terpineol 98-55-5 204-263-4 Adverse environmental effects: The product contains a substance that is identified as having endocrine disrupting properties. 1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one 1506-02-1 1506-02-1 Benzyl salicylate 118-58-1 204-262-9 [3R-(3α,3aβ,7β,8aα)]-1-(2,3,4,7,8,8a-hexahydro-3,6,8,8-tetramethyl-1H-3a,7-methanoazulen-5yl)ethan-1-one 32388-55-9 251-020-3 α-Terpineol 98-55-5 204-263-4 The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII. Other adverse effects: No further relevant information available.

SECTION 3: Composition/information on ingredients 3.2. Mixtures

Description: Water soluble odour neutralising liquid concentrate

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 3/11

Ecoz Linen concentrate Hazardous ingredients / Hazardous impurities / Stabilisers: Product identifiers CAS No.: 7732-18-5 EC No.: 231-791-2 CAS No.: 68987-81-5 EC No.: 691-266-2

Substance name Concentration Classification according to Regulation (EC) No. 1272/2008 [CLP] water The substance is classified as not hazardous according to regulation (EC) No. 1272/2008 [CLP]. Alcohols, C6-10, ethoxylated propoxylated Aquatic Chronic 2 (H411), Eye Irrit. 2 (H319) Warning

40 – ≤ 80 weight-% 10 – ≤ 20 weight-%

CAS No.: 101-86-0 EC No.: 202-983-3

α-hexylcinnamaldehyde 0–≤1 Aquatic Acute 1 (H400), Aquatic Chronic 2 (H411), Skin Sens. 1B (H317) weight-%

CAS No.: 107-75-5 EC No.: 203-518-7

7-hydroxycitronellal Eye Irrit. 2 (H319), Skin Sens. 1B (H317)

0–≤1 weight-%

CAS No.: 1506-02-1 EC No.: 216-133-4

1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2naphthyl)ethan-1-one Acute Tox. 4 (H302), Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410)

0–<1 weight-%

CAS No.: 103-95-7 EC No.: 203-161-7

3-p-cumenyl-2-methylpropionaldehyde Aquatic Chronic 3 (H412), Skin Irrit. 2 (H315), Skin Sens. 1B (H317)

0–<1 weight-%

CAS No.: 91-64-5 EC No.: 202-086-7

coumarin Acute Tox. 4 (H302), Aquatic Chronic 3 (H412), Skin Sens. 1 (H317)

0–<1 weight-%

CAS No.: 32210-23-4 EC No.: 250-954-9

4-tert-butylcyclohexyl acetate Skin Sens. 1B (H317)

0–<1 weight-%

CAS No.: 118-58-1 EC No.: 204-262-9

benzyl salicylate Aquatic Chronic 3 (H412), Eye Irrit. 2 (H319), Skin Sens. 1B (H317)

0–<1 weight-%

CAS No.: 8000-34-8

Patchouly Oil Asp. Tox. 1 (H304), Eye Irrit. 2 (H319), Skin Sens. 1 (H317)

0–<1 weight-%

Warning

Danger Full text of H- and EUH-phrases: see section 16.

SECTION 4: First aid measures 4.1. Description of first aid measures

General information: In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). Remove victim out of the danger area. Remove contaminated, saturated clothing. If unconscious but breathing normally, place in recovery position and seek medical advice. Do not leave affected person unattended. Following inhalation: Provide fresh air. In case of respiratory tract irritation, consult a physician. In case of skin contact: After contact with skin, wash immediately with plenty of water and soap. If skin irritation or rash occurs: Get medical advice/attention. After eye contact: Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention. Remove contact lenses, if present and easy to do. Continue rinsing. Following ingestion: Rinse mouth. according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 4/11

Ecoz Linen concentrate Get medical advice/attention if you feel unwell. Self-protection of the first aider: Use personal protection equipment.

4.2. Most important symptoms and effects, both acute and delayed Serious eye damage/eye irritation Allergic reactions

4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically.

SECTION 5: Firefighting measures 5.1. Extinguishing media

Suitable extinguishing media: Water spray jet alcohol resistant foam Extinguishing powder Carbon dioxide (CO2)

5.2. Special hazards arising from the substance or mixture Combustible Hazardous combustion products: In case of fire: Gases/vapours, harmful

5.3. Advice for firefighters

Wear a self-contained breathing apparatus and chemical protective clothing.

5.4. Additional information

Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.

SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Personal precautions: Remove persons to safety. Protective equipment: Wear protective gloves/protective clothing/eye protection/face protection.

6.1.2. For emergency responders

Personal protection equipment: Personal protection equipment: see section 8

6.2. Environmental precautions

Do not allow to enter into surface water or drains.

6.3. Methods and material for containment and cleaning up

For containment: Absorb with liquid-binding material (sand, diatomaceous earth, acid- or universal binding agents). For cleaning up: Water (with cleaning agent)

6.4. Reference to other sections

Safe handling: see section 7 Personal protection equipment: see section 8 Disposal: see section 13

6.5. Additional information

Use appropriate container to avoid environmental contamination.

SECTION 7: Handling and storage 7.1. Precautions for safe handling Protective measures

Advices on safe handling: Wear personal protection equipment (refer to section 8). Fire prevent measures: Usual measures for fire prevention. according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 5/11

Ecoz Linen concentrate Measures to prevent aerosol and dust generation: Avoid: aerosol or mist formation Environmental precautions: Do not contaminate water with the product or its container (Do not clean application equipment near surface water/Avoid contamination via drains from farmyards and roads).

Advices on general occupational hygiene

When using do not eat, drink or smoke. Avoid contact with eyes and skin.

7.2. Conditions for safe storage, including any incompatibilities

Technical measures and storage conditions: Keep container tightly closed in a cool, well-ventilated place. Packaging materials: Keep/Store only in original container. Storage class (TRGS 510, Germany): 10 – Combustible liquids that cannot be assigned to any of the above storage classes

7.3. Specific end use(s) No data available

SECTION 8: Exposure controls/personal protection 8.1. Control parameters No data available

8.2. Exposure controls 8.2.1. Appropriate engineering controls No data available

8.2.2. Personal protection equipment

Eye/face protection: Eye glasses with side protection EN 166 Skin protection: Tested protective gloves must be worn EN ISO 374 Suitable material: PVC (polyvinyl chloride), NBR (Nitrile rubber), Butyl caoutchouc (butyl rubber) In the case of wanting to use the gloves again, clean them before taking off and air them well. Breakthrough times and swelling properties of the material must be taken into consideration. Breakthrough time: min Respiratory protection: Usually no personal respirative protection necessary.

8.2.3. Environmental exposure controls No data available

SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state: Liquid Odour: fruity

Safety relevant basis data

Colour: yellow Odour threshold: not determined

Parameter

Value

>5–<8

Melting point

① Method ② Remark

not determined

Freezing point

not determined

Decomposition temperature

not determined

Evaporation rate

not determined

Initial boiling point and boiling range not determined Flash point

according to Regulation (EC) No. 2020/878 (REACH)

> 65 °C en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 6/11

Ecoz Linen concentrate Parameter

Value

Auto-ignition temperature

not determined

Upper/lower flammability or explosive limits

① Method ② Remark

not determined

Vapour pressure

not determined

Vapour density

not determined

Relative density

not determined

Density

≈ 1 kg/L

Bulk density

not determined

Water solubility

completely miscible

Dynamic viscosity

not determined

Partition coefficient: n-octanol/water not determined Kinematic viscosity

not determined

9.2. Other information No data available

SECTION 10: Stability and reactivity 10.1. Reactivity

Combustible This material is considered to be non-reactive under normal use conditions.

10.2. Chemical stability

The product is chemically stable under recommended conditions of storage, use and temperature.

10.3. Possibility of hazardous reactions No known hazardous reactions.

10.4. Conditions to avoid

No further relevant information available.

10.5. Incompatible materials

No further relevant information available.

10.6. Hazardous decomposition products

No known hazardous decomposition products. Decomposition products in case of fire: see section 5.

SECTION 11: Toxicological information 11.1. Information on hazard classes as defined in Regulation (EC) No. 1272/2008 Alcohols, C6-10, ethoxylated propoxylated LD50 oral: >2,380 mg/kg

CAS No.: 68987-81-5 EC No.: 691-266-2

LD50 dermal: >2,000 mg/kg

LC50 Acute inhalation toxicity (vapour): >50 mg/L 4 h

7-hydroxycitronellal

CAS No.: 107-75-5 EC No.: 203-518-7

LD50 oral: >6,400 mg/kg

LD50 dermal: >2,000 mg/kg

3-p-cumenyl-2-methylpropionaldehyde LD50 oral: 3,810 mg/kg

coumarin

CAS No.: 103-95-7 EC No.: 203-161-7

CAS No.: 91-64-5 EC No.: 202-086-7

LD50 oral: 520 mg/kg

4-tert-butylcyclohexyl acetate LD50 oral: 3,323 mg/kg

CAS No.: 32210-23-4 EC No.: 250-954-9

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 7/11

Ecoz Linen concentrate benzyl salicylate

CAS No.: 118-58-1 EC No.: 204-262-9

LD50 oral: >3,000 mg/kg

LD50 dermal: >2,000 mg/kg

Acute oral toxicity: Based on available data, the classification criteria are not met. Acute dermal toxicity: Based on available data, the classification criteria are not met. Acute inhalation toxicity: Based on available data, the classification criteria are not met. Skin corrosion/irritation: Based on available data, the classification criteria are not met. Serious eye damage/irritation: Causes serious eye irritation. Respiratory or skin sensitisation: Contains 7-hydroxycitronellal, 4-tert-butylcyclohexyl acetate, ?-hexylcinnamaldehyde, Patchouly Oil, benzyl salicylate, coumarin, 3-p-cumenyl-2-methylpropionaldehyde. May produce an allergic reaction. Germ cell mutagenicity: Based on available data, the classification criteria are not met. Carcinogenicity: Based on available data, the classification criteria are not met. Reproductive toxicity: Based on available data, the classification criteria are not met. STOT-single exposure: Based on available data, the classification criteria are not met. STOT-repeated exposure: Based on available data, the classification criteria are not met. Aspiration hazard: Based on available data, the classification criteria are not met. Additional information: No data available

11.2. Information on other hazards

Endocrine disrupting properties: The product contains a substance that is identified as having endocrine disrupting properties. 1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one 1506-02-1 1506-02-1 Benzyl salicylate 118-58-1 204-262-9 [3R-(3α,3aβ,7β,8aα)]-1-(2,3,4,7,8,8a-hexahydro-3,6,8,8-tetramethyl-1H-3a,7-methanoazulen-5yl)ethan-1-one 32388-55-9 251-020-3 α-Terpineol 98-55-5 204-263-4

SECTION 12: Ecological information 12.1. Toxicity Alcohols, C6-10, ethoxylated propoxylated LC50: 1 – 10 mg/L 4 d (fish)

CAS No.: 68987-81-5 EC No.: 691-266-2

EC50: 1 – 10 mg/L 2 d (crustaceans)

EC50: 1 – 10 mg/L 4 d (Algae/water plant) 120h

3-p-cumenyl-2-methylpropionaldehyde LC50: 1 mg/L 4 d (fish)

4-tert-butylcyclohexyl acetate LC50: 8.6 mg/L 4 d (fish)

benzyl salicylate

CAS No.: 103-95-7 EC No.: 203-161-7

CAS No.: 32210-23-4 EC No.: 250-954-9

CAS No.: 118-58-1 EC No.: 204-262-9

LC50: 1.03 mg/L 4 d (fish)

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 8/11

Ecoz Linen concentrate Aquatic toxicity: Harmful to aquatic life with long lasting effects. Assessment/classification: There are no data available on the mixture itself.

12.2. Persistence and degradability Alcohols, C6-10, ethoxylated propoxylated Biodegradation: Yes, slowly

α-hexylcinnamaldehyde

CAS No.: 68987-81-5 EC No.: 691-266-2

CAS No.: 101-86-0 EC No.: 202-983-3

Biodegradation: Yes, rapidly

7-hydroxycitronellal

CAS No.: 107-75-5 EC No.: 203-518-7

Biodegradation: Yes, rapidly

3-p-cumenyl-2-methylpropionaldehyde Biodegradation: Yes, rapidly

coumarin

CAS No.: 103-95-7 EC No.: 203-161-7

CAS No.: 91-64-5 EC No.: 202-086-7

Biodegradation: Yes, rapidly

4-tert-butylcyclohexyl acetate Biodegradation: Yes, rapidly

benzyl salicylate

CAS No.: 32210-23-4 EC No.: 250-954-9

CAS No.: 118-58-1 EC No.: 204-262-9

Biodegradation: Yes, rapidly

Patchouly Oil

CAS No.: 8000-34-8

Biodegradation: Yes, rapidly

Biodegradation: There are no data available on the mixture itself.

12.3. Bioaccumulative potential

Accumulation / Evaluation: There are no data available on the mixture itself.

12.4. Mobility in soil

There are no data available on the mixture itself.

12.5. Results of PBT and vPvB assessment Alcohols, C6-10, ethoxylated propoxylated

CAS No.: 68987-81-5 EC No.: 691-266-2