SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 1 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 1/13
Berry SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier
Trade name/designation:
Berry
Other means of identification: FIBER: 56-1925, 56-1730, 56-1724, 56-1339 CORRUGATED MEMBRANES AND CARTRIDGES: 56-1369, 56-1465 UFI: JDA3-UNEW-N80D-NMT0
1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture: aromatisation
Relevant identified uses:
Life cycle stage [LCS] PW: Widespread use by professional workers Product Categories [PC] PC 28: Perfumes, fragrances
1.3. Details of the supplier of the safety data sheet Supplier (manufacturer/importer/only representative/downstream user/distributor): Vaportek Europe Logistic Sarl 6 Route du Grand Lancy 1211 Genève 26 Switzerland Telephone: +41 22 342 2145 E-mail: vaportek@gmail.com
E-mail (competent person): vaportek@gmail.com
1.4. Emergency telephone number 24h: NHS (National Health Service): 111
SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Hazard classes and hazard categories
Hazard statements
Classification procedure
flammable liquids (Flam. Liq. 3)
Skin corrosion/irritation (Skin Irrit. 2)
H226: Flammable liquid and vapour.
On basis of test data.
Respiratory or skin sensitisation (Skin Sens. 1)
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
Calculation method.
Serious eye damage/eye irritation (Eye Dam. 1)
H318: Causes serious eye damage.
Calculation method.
Calculation method.
Hazardous to the aquatic environment H400: Very toxic to aquatic life. (Aquatic Acute 1)
Calculation method.
Hazardous to the aquatic environment H411: Toxic to aquatic life with long (Aquatic Chronic 2) lasting effects.
Calculation method.
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 1 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 2/13
Berry 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms:
GHS02
GHS05
Flame
Corrosion
GHS07
Exclamation mark
Signal word: Danger Hazard components for labelling: methyl salicylate; CITRONELLA OIL; benzaldehyde; pin-2(3)-ene
GHS09
Environment
Hazard statements for physical hazards H226
Flammable liquid and vapour.
Hazard statements for health hazards H315
Causes skin irritation.
H318
Causes serious eye damage.
H317
May cause an allergic skin reaction.
Hazard statements for environmental hazards H400 H411
Very toxic to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements Prevention P210
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P273
Avoid release to the environment.
P264 P280
Wash hands thoroughly after handling.
Wear protective gloves and eye/face protection.
Precautionary statements Response
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 P391
If eye irritation persists: Get medical advice/attention. Collect spillage.
Precautionary statements Disposal P501
Dispose of contents/container to an appropriate recycling or disposal facility.
* 2.3. Other hazards
Adverse physicochemical effects: No further relevant information available. Adverse human health effects and symptoms: The product contains a substance that is identified as having endocrine disrupting properties. α-Terpineol 98-55-5 204-263-4 Adverse environmental effects: The product contains a substance that is identified as having endocrine disrupting properties. α-Terpineol 98-55-5 204-263-4 The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII. Other adverse effects: No further relevant information available.
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 1 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 3/13
Berry SECTION 3: Composition/information on ingredients 3.2. Mixtures
Hazardous ingredients / Hazardous impurities / Stabilisers: Product identifiers
Substance name Concentration Classification according to Regulation (EC) No. 1272/2008 [CLP] isobutyl acetate Flam. Liq. 2 (H225)
10 – ≤ 20 weight-%
CAS No.: 77-83-8 EC No.: 201-061-8
ethyl 2,3-epoxy-3-phenylbutyrate Aquatic Chronic 2 (H411), Skin Sens. 1 (H317)
6 – ≤ 15 weight-%
CAS No.: 8050-15-5 EC No.: 232-476-2
Resin acids and Rosin acids, hydrogenated, Me esters Aquatic Chronic 3 (H412)
3 – ≤ 10 weight-%
CAS No.: 119-36-8 EC No.: 204-317-7
methyl salicylate Acute Tox. 4 (H302), Eye Dam. 1 (H318)
2–≤5 weight-%
CAS No.: 100-52-7 EC No.: 202-860-4 Index No.: 605-012-00-5
benzaldehyde Acute Tox. 4 (H302)
2–≤5 weight-%
CAS No.: 5989-27-5 EC No.: 227-813-5 Index No.: 601-096-00-2
(R)-p-mentha-1,8-diene Aquatic Acute 1 (H400), Aquatic Chronic 3 (H412), Asp. Tox. 1 (H304), Flam. Liq. 3 (H226), Skin Irrit. 2 (H315), Skin Sens. 1B (H317)
1–≤5 weight-%
CAS No.: 104-55-2 EC No.: 203-213-9
cinnamaldehyde Aquatic Chronic 3 (H412), Eye Irrit. 2 (H319), Skin Irrit. 2 (H315), Skin Sens. 1 (H317)
1 – ≤ 2.5 weight-%
CAS No.: 123-92-2 EC No.: 204-662-3 Index No.: 607-130-00-2
isopentyl acetate Flam. Liq. 3 (H226)
1 – ≤ 2.5 weight-%
CAS No.: 80-56-8 EC No.: 201-291-9
pin-2(3)-ene Acute Tox. 4 (H302), Aquatic Chronic 1 (H410), Asp. Tox. 1 (H304), Flam. Liq. 3 (H226), Skin Irrit. 2 (H315), Skin Sens. 1 (H317)
≤ 1.5 weight-%
Linalool: 3,7-Dimethyl- 1,6-octadien-3-ol; DL-Linalool Eye Irrit. 2 (H319), Skin Irrit. 2 (H315), Skin Sens. 1B (H317)
≤ 1.5 weight-%
CAS No.: 8000-34-8
Patchouly Oil Asp. Tox. 1 (H304), Eye Irrit. 2 (H319), Skin Sens. 1 (H317)
≤ 1.5 weight-%
CAS No.: 4180-23-8 EC No.: 203-205-5
Anethol Aquatic Chronic 3 (H412), Skin Sens. 1 (H317)
≤1 weight-%
CAS No.: 121-33-5 EC No.: 204-465-2
vanillin Eye Irrit. 2 (H319)
≤1 weight-%
CAS No.: 8000-29-1 EC No.: 616-771-7
CITRONELLA OIL Asp. Tox. 1 (H304), Eye Dam. 1 (H318), Skin Irrit. 2 (H315), Skin Sens. 1 (H317)
≤1 weight-%
CAS No.: 110-19-0 EC No.: 203-745-1 Index No.: 607-026-00-7
CAS No.: 98-55-5 EC No.: 204-263-4
Danger EUH066
Warning
α-Terpineol Eye Irrit. 2 (H319), Skin Irrit. 2 (H315) Warning
Danger
Warning
Danger M-factor (acute): 1
2–≤5 weight-%
Warning
CAS No.: 78-70-6 EC No.: 201-134-4
Warning EUH066
Danger M-factor (acute): 1 M-factor (chronic): 1
Warning
Danger
Warning
Warning
Danger
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 1 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 4/13
Berry Product identifiers
Substance name Concentration Classification according to Regulation (EC) No. 1272/2008 [CLP] Eucalyptusöl Aquatic Chronic 2 (H411), Asp. Tox. 1 (H304), Flam. Liq. 3 (H226), Skin Irrit. 2 (H315), Skin Sens. 1 (H317)
≤ 0.5 weight-%
CAS No.: 91-64-5 EC No.: 202-086-7
coumarin Acute Tox. 4 (H302), Aquatic Chronic 3 (H412), Skin Sens. 1 (H317)
≤ 0.5 weight-%
CAS No.: 8008-57-9
CITRUS AURANTIUM DULCIS OIL Asp. Tox. 1 (H304), Flam. Liq. 3 (H226), Skin Irrit. 2 (H315), Skin Sens. 1 (H317)
≤ 0.1 weight-%
CAS No.: 8000-48-4
Danger
Warning
Danger Full text of H- and EUH-phrases: see section 16.
SECTION 4: First aid measures 4.1. Description of first aid measures
General information: In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). Remove victim out of the danger area. Remove contaminated, saturated clothing. If unconscious but breathing normally, place in recovery position and seek medical advice. Do not leave affected person unattended. Warning First aider: Pay attention to self-protection! Following inhalation: Provide fresh air. In case of respiratory tract irritation, consult a physician. In case of skin contact: After contact with skin, wash immediately with plenty of water and soap. Take off immediately all contaminated clothing. If skin irritation or rash occurs: Get medical advice/ attention. After eye contact: In case of contact with eyes, rinse immediately thoroughly with plenty of edible oil and consult an ophthalmologist. Following ingestion: Ingestion of the mixture / product is hardly possible. Rinse mouth. Get medical advice/attention if you feel unwell. Let water be drunken in little sips (dilution effect). Self-protection of the first aider: Use personal protection equipment.
4.2. Most important symptoms and effects, both acute and delayed Causes skin irritation. Allergic reactions Serious eye damage/eye irritation Skin corrosion/irritation
4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically.
SECTION 5: Firefighting measures 5.1. Extinguishing media
Suitable extinguishing media: alcohol resistant foam Extinguishing powder Carbon dioxide (CO2) Water spray jet Unsuitable extinguishing media: Full water jet
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 1 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 5/13
Berry 5.2. Special hazards arising from the substance or mixture Combustible Hazardous combustion products: Gases/vapours, irritant In case of fire: Gases/vapours, toxic
5.3. Advice for firefighters
Wear a self-contained breathing apparatus and chemical protective clothing.
5.4. Additional information
Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.
SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Personal precautions: Remove persons to safety. Protective equipment: Wear protective gloves/protective clothing/eye protection/face protection.
6.1.2. For emergency responders
Personal protection equipment: Personal protection equipment: see section 8
6.2. Environmental precautions
Do not allow to enter into surface water or drains.
6.3. Methods and material for containment and cleaning up
For containment: Absorb with liquid-binding material (sand, diatomaceous earth, acid- or universal binding agents). For cleaning up: Take up mechanically, placing in appropriate containers for disposal. Solvents/Thinner
6.4. Reference to other sections
Safe handling: see section 7 Personal protection equipment: see section 8 Disposal: see section 13
6.5. Additional information
Use appropriate container to avoid environmental contamination.
SECTION 7: Handling and storage 7.1. Precautions for safe handling Protective measures
Advices on safe handling: Wear personal protection equipment (refer to section 8). Fire prevent measures: Take precautionary measures against static discharge. Keep away from sources of ignition - No smoking.
Advices on general occupational hygiene When using do not eat, drink or smoke. Avoid contact with eyes and skin.
7.2. Conditions for safe storage, including any incompatibilities Technical measures and storage conditions: Keep container tightly closed in a cool, well-ventilated place. Storage class (TRGS 510, Germany): 4.1B – Flammable solids
7.3. Specific end use(s) No data available
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 1 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 6/13
Berry SECTION 8: Exposure controls/personal protection 8.1. Control parameters
8.1.1. Occupational exposure limit values
isobutyl acetate CAS No.: 110-19-0 EC No.: 203-745-1
① Long-term occupational exposure limit value ② Short-term occupational exposure limit value ③ Instantaneous value ④ Monitoring and observation processes ⑤ Remark ① 150 ppm (724 mg/m³) ② 187 ppm (903 mg/m³)
isopentyl acetate CAS No.: 123-92-2 EC No.: 204-662-3
① 50 ppm (270 mg/m³) ② 100 ppm (540 mg/m³)
Limit value type Substance name (country of origin)
WEL (GB)
IOELV (EU) isobutyl acetate from 20 Nov 2019 CAS No.: 110-19-0 EC No.: 203-745-1
① 50 ppm (241 mg/m³) ② 150 ppm (723 mg/m³)
WEL (GB) isopentyl acetate from 21 Aug 2018 CAS No.: 123-92-2 EC No.: 204-662-3
① 50 ppm (270 mg/m³) ② 100 ppm (541 mg/m³)
IOELV (EU)
8.1.2. Biological limit values No data available
8.1.3. DNEL-/PNEC-values No data available
8.2. Exposure controls 8.2.1. Appropriate engineering controls No data available
8.2.2. Personal protection equipment
Eye/face protection: Eye glasses with side protection EN 166 Skin protection: Tested protective gloves must be worn EN ISO 374 Suitable material: NBR (Nitrile rubber), In the case of wanting to use the gloves again, clean them before taking off and air them well. Breakthrough times and swelling properties of the material must be taken into consideration. Breakthrough time: min Respiratory protection: Usually no personal respirative protection necessary. Respiratory protection necessary at: Handling larger quantities, Filtering device with filter or ventilator filtering device of type: AX
8.2.3. Environmental exposure controls No data available
SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state: Liquid Odour: fruity
according to Regulation (EC) No. 2020/878 (REACH)
Colour: yellow Odour threshold: nicht bestimmt
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 1 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 7/13
Berry Safety relevant basis data Parameter
Value
pH
not applicable
Melting point
① Method ② Remark
not determined
Freezing point
not determined
Decomposition temperature
not determined
Evaporation rate
not determined
Initial boiling point and boiling range 117 Flash point
Auto-ignition temperature
Upper/lower flammability or explosive limits Vapour pressure
42.8 °C not determined not determined not determined
Vapour density
not determined
Relative density
not determined
Density
≈ 0.96 g/cm³
Bulk density
not determined
Water solubility
Immiscible
Dynamic viscosity
not determined
Partition coefficient: n-octanol/water not determined Kinematic viscosity
not determined
9.2. Other information
Solid, inert fiber block soaked with liquid mixture for odour neutralisation. The properties listed relate to the liquid.
SECTION 10: Stability and reactivity 10.1. Reactivity
Flammable liquid and vapour. This material is considered to be non-reactive under normal use conditions.
10.2. Chemical stability
The product is stable under storage at normal ambient temperatures.
10.3. Possibility of hazardous reactions No known hazardous reactions.
10.4. Conditions to avoid
Stable under recommended storage and handling conditions.
10.5. Incompatible materials
No further relevant information available.
10.6. Hazardous decomposition products
Thermal decomposition can lead to the escape of irritating gases and vapours.
SECTION 11: Toxicological information 11.1. Information on hazard classes as defined in Regulation (EC) No. 1272/2008 methyl salicylate
CAS No.: 119-36-8 EC No.: 204-317-7
isopentyl acetate
CAS No.: 123-92-2 EC No.: 204-662-3
LD50 oral: =887 mg/kg
LD50 oral: >7,400 mg/kg
pin-2(3)-ene
CAS No.: 80-56-8 EC No.: 201-291-9
LD50 oral: 500 mg/kg
LD50 dermal: >2,000 mg/kg according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 1 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 8/13
Berry coumarin
CAS No.: 91-64-5 EC No.: 202-086-7
LD50 oral: 520 mg/kg
Acute oral toxicity: Based on available data, the classification criteria are not met. Acute dermal toxicity: Based on available data, the classification criteria are not met. Acute inhalation toxicity: Based on available data, the classification criteria are not met. Skin corrosion/irritation: Causes skin irritation. Serious eye damage/irritation: Causes serious eye damage. Respiratory or skin sensitisation: May cause an allergic skin reaction. Germ cell mutagenicity: Based on available data, the classification criteria are not met. Carcinogenicity: Based on available data, the classification criteria are not met. Reproductive toxicity: Based on available data, the classification criteria are not met. STOT-single exposure: Based on available data, the classification criteria are not met. STOT-repeated exposure: Based on available data, the classification criteria are not met. Aspiration hazard: Based on available data, the classification criteria are not met. Additional information: No data available
11.2. Information on other hazards
Endocrine disrupting properties: The product contains a substance that is identified as having endocrine disrupting properties. α-Terpineol 98-55-5 204-263-4
SECTION 12: Ecological information 12.1. Toxicity Resin acids and Rosin acids, hydrogenated, Me esters LC50: >100 mg/L
methyl salicylate
CAS No.: 8050-15-5 EC No.: 232-476-2
CAS No.: 119-36-8 EC No.: 204-317-7
LC50: =19.8 mg/L (fish)
(R)-p-mentha-1,8-diene LC50: <1 mg/L 4 d (fish)
CAS No.: 5989-27-5 EC No.: 227-813-5
EC50: =0.307 mg/L 2 d (crustaceans)
EC50: 0.05 mg/L 3 d (Algae/water plant)
cinnamaldehyde
CAS No.: 104-55-2 EC No.: 203-213-9
isopentyl acetate
CAS No.: 123-92-2 EC No.: 204-662-3
LC50: 3.9 mg/L 4 d (fish) LC50: >22 mg/L (fish)
pin-2(3)-ene
CAS No.: 80-56-8 EC No.: 201-291-9
LC50: 0.303 mg/L 4 d (fish)
EC50: 0.475 mg/L 2 d (crustaceans)
LOEC: 0.494 mg/L 2 d (Algae/water plant) according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 1 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 9/13
Berry Anethol
CAS No.: 4180-23-8 EC No.: 203-205-5
LC50: 7 mg/L 4 d (fish)
Eucalyptusöl
CAS No.: 8000-48-4
LC50: ≈0.9 mg/L
Aquatic toxicity: Very toxic to aquatic life. Toxic to aquatic life with long lasting effects. Additional ecotoxicological information: No further relevant information available.
12.2. Persistence and degradability isobutyl acetate
CAS No.: 110-19-0 EC No.: 203-745-1
Biodegradation: Yes, rapidly
ethyl 2,3-epoxy-3-phenylbutyrate Biodegradation: Yes, rapidly
CAS No.: 77-83-8 EC No.: 201-061-8
Resin acids and Rosin acids, hydrogenated, Me esters Biodegradation: Yes, rapidly
α-Terpineol
CAS No.: 8050-15-5 EC No.: 232-476-2
CAS No.: 98-55-5 EC No.: 204-263-4
Biodegradation: Yes, rapidly
methyl salicylate
CAS No.: 119-36-8 EC No.: 204-317-7
Biodegradation: Yes, rapidly
benzaldehyde
CAS No.: 100-52-7 EC No.: 202-860-4
Biodegradation: Yes, rapidly
(R)-p-mentha-1,8-diene
CAS No.: 5989-27-5 EC No.: 227-813-5
Biodegradation: Yes, rapidly
cinnamaldehyde
CAS No.: 104-55-2 EC No.: 203-213-9
isopentyl acetate
CAS No.: 123-92-2 EC No.: 204-662-3
Biodegradation: Yes, rapidly Biodegradation: Yes, rapidly
pin-2(3)-ene
CAS No.: 80-56-8 EC No.: 201-291-9
Biodegradation: Yes, rapidly
Linalool: 3,7-Dimethyl- 1,6-octadien-3-ol; DL-Linalool Biodegradation: Yes, rapidly
Patchouly Oil
CAS No.: 78-70-6 EC No.: 201-134-4
CAS No.: 8000-34-8
Biodegradation: Yes, rapidly
Anethol
CAS No.: 4180-23-8 EC No.: 203-205-5
vanillin
CAS No.: 121-33-5 EC No.: 204-465-2
Biodegradation: Yes, rapidly Biodegradation: Yes, rapidly
CITRONELLA OIL
CAS No.: 8000-29-1 EC No.: 616-771-7
Biodegradation: Yes, rapidly
Eucalyptusöl
CAS No.: 8000-48-4
Biodegradation: Yes, rapidly
coumarin
CAS No.: 91-64-5 EC No.: 202-086-7
Biodegradation: Yes, rapidly
CITRUS AURANTIUM DULCIS OIL Biodegradation: Yes, rapidly
CAS No.: 8008-57-9
Biodegradation: Part of the components is biodegradable. according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 1 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 10/13
Berry
Additional information: No further relevant information available.
12.3. Bioaccumulative potential
Accumulation / Evaluation: No further relevant information available.
12.4. Mobility in soil
No further relevant information available.
12.5. Results of PBT and vPvB assessment isobutyl acetate
CAS No.: 110-19-0 EC No.: 203-745-1
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
ethyl 2,3-epoxy-3-phenylbutyrate
CAS No.: 77-83-8 EC No.: 201-061-8
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
Resin acids and Rosin acids, hydrogenated, Me esters
CAS No.: 8050-15-5 EC No.: 232-476-2
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
α-Terpineol
CAS No.: 98-55-5 EC No.: 204-263-4
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
methyl salicylate
CAS No.: 119-36-8 EC No.: 204-317-7
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
benzaldehyde
CAS No.: 100-52-7 EC No.: 202-860-4
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
(R)-p-mentha-1,8-diene
CAS No.: 5989-27-5 EC No.: 227-813-5
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
cinnamaldehyde
CAS No.: 104-55-2 EC No.: 203-213-9
isopentyl acetate
CAS No.: 123-92-2 EC No.: 204-662-3
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII. Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
pin-2(3)-ene
CAS No.: 80-56-8 EC No.: 201-291-9
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
Linalool: 3,7-Dimethyl- 1,6-octadien-3-ol; DL-Linalool
CAS No.: 78-70-6 EC No.: 201-134-4
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
Patchouly Oil
CAS No.: 8000-34-8
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
Anethol
CAS No.: 4180-23-8 EC No.: 203-205-5
vanillin
CAS No.: 121-33-5 EC No.: 204-465-2
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII. Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
CITRONELLA OIL
CAS No.: 8000-29-1 EC No.: 616-771-7
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
Eucalyptusöl
CAS No.: 8000-48-4
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
coumarin
CAS No.: 91-64-5 EC No.: 202-086-7
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
CITRUS AURANTIUM DULCIS OIL
CAS No.: 8008-57-9
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
12.6. Endocrine disrupting properties
The product contains a substance that is identified as having endocrine disrupting properties. α-Terpineol 98-55-5 204-263-4
12.7. Other adverse effects No data available
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 1 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 11/13
Berry
SECTION 13: Disposal considerations 13.1. Waste treatment methods
The allocation of waste identity numbers/waste descriptions must be carried out according to the EWC, specific to the industry and process.
13.1.1. Product/Packaging disposal Waste codes/waste designations according to EWC/AVV Waste code product
16 03 05 * organic wastes containing hazardous substances *: Evidence for disposal must be provided.
Waste treatment options
Appropriate disposal / Product: Consult the appropriate local waste disposal expert about waste disposal. Appropriate disposal / Package: Non-contaminated packages may be recycled. Completely emptied bricks, disks and membranes can be recycled.
13.2. Additional information
* = "S" In Switzerland, commercial hazardous waste shall be delivered to a disposal company.
SECTION 14: Transport information Land transport (ADR/RID)
Sea transport (IMDG)
Air transport (ICAO-TI / IATA-DGR)
UN 3175
UN 3175
UN 3175
SOLIDS CONTAINING FLAMMABLE LIQUID, N.O.S.
SOLIDS CONTAINING FLAMMABLE LIQUID, N.O.S. (ethyl 2,3-epoxy-3phenylbutyrate)
SOLIDS CONTAINING FLAMMABLE LIQUID, N.O.S.
14.1. UN number or ID number
14.2. UN proper shipping name
14.3. Transport hazard class(es)
4.1
14.4. Packing group II
14.5. Environmental hazards
4.1 II
according to Regulation (EC) No. 2020/878 (REACH)
II No
14.6. Special precautions for user Special Provisions: 216 | 274 | 601 Limited quantity (LQ): 1 kg Excepted Quantities (EQ): E2 Hazard identification number (Kemler No.): 40 Classification code: F1 Tunnel restriction code: (E)
4.1
MARINE POLLUTANT
Special Provisions: 216 | 274 Limited quantity (LQ): 1 kg Excepted Quantities (EQ): E2 EmS-No.: F-A, S-I
Special Provisions: A46 Limited quantity (LQ): Y441 Excepted Quantities (EQ): E2
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 1 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 12/13
Berry
14.7. Maritime transport in bulk according to IMO instruments Additional information: Solid, inert fiber block soaked with liquid mixture for odour neutralisation.
SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU legislation
Restrictions on use: According to directive 94/33/EC, juveniles are only allowed to handle this product as long as all effects of dangerous substances are prevented. Observe employment restrictions under the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.
15.1.2. National regulations No data available
15.2. Chemical Safety Assessment
Chemical safety assessments for substances in this mixture were not carried out.
SECTION 16: Other information 16.1. Indication of changes 2.3.
Other hazards
16.2. Abbreviations and acronyms
For abbreviations and acronyms, see table on the eSDScom website -ADR: European agreement concerning the international carriage of dangerous goods by road (Accord européen relatif transport des merchandises dangereuses par route) -CAS: Chemical Abstracts Service -CLP: Classification, labelling and Packaging -DNEL: Derived No Effect Level -EC50: Effective Concentration 50% -ECHA: European Chemical Agency -LC50: Lethal Concentration 50% -LD50: Lethal Dose 50% -PBT: persistent, bioaccumulative, toxic -PNEC: Predicted No Effect Concentration -REACH: Registration, Evaluation and Authorization of Chemicals -SVHC: Substance of Very High Concern -VOC: Volatile organic compounds -vPvB: very persistent, very bioaccumulative
16.3. Key literature references and sources for data
REACH Dissemination Portal https://echa.europa.eu/de/information-on-chemicals/registered-substances
16.4. Classification for mixtures and used evaluation method according to regulation (EC) No. 1272/2008 [CLP] Hazard classes and hazard categories
Hazard statements
Classification procedure
flammable liquids (Flam. Liq. 3)
Skin corrosion/irritation (Skin Irrit. 2)
H226: Flammable liquid and vapour.
On basis of test data.
Respiratory or skin sensitisation (Skin Sens. 1)
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
Calculation method.
Serious eye damage/eye irritation (Eye Dam. 1)
H318: Causes serious eye damage.
Hazardous to the aquatic environment H400: Very toxic to aquatic life. (Aquatic Acute 1) according to Regulation (EC) No. 2020/878 (REACH)
Calculation method.
Calculation method. Calculation method.
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 1 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 13/13
Berry
Hazard classes and hazard categories
Hazard statements
Hazardous to the aquatic environment H411: Toxic to aquatic life with long (Aquatic Chronic 2) lasting effects.
Classification procedure Calculation method.
16.5. Relevant R-, H- and EUH-phrases (Number and full text) Hazard statements H225
Highly flammable liquid and vapour.
H302
Harmful if swallowed.
H226 H304 H315 H317 H318 H319 H400 H410 H411 H412
Flammable liquid and vapour.
May be fatal if swallowed and enters airways. Causes skin irritation.
May cause an allergic skin reaction. Causes serious eye damage.
Causes serious eye irritation. Very toxic to aquatic life.
Very toxic to aquatic life with long lasting effects. Toxic to aquatic life with long lasting effects.
Harmful to aquatic life with long lasting effects.
Supplemental hazard information EUH066
Repeated exposure may cause skin dryness or cracking.
16.6. Training advice No data available
16.7. Additional information No data available
* Data changed compared with the previous version.
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de