Issuu

MSDS INDEX

WAX DEPT

The British Wax Refining Co. Ltd SAFETY DATA SHEET According to 1907/2006/EC, Article 31 Revision Date of issue Supersedes

1584, 1584W, 1584S Slush Casting Wax

3 10/10/2019 13/10/2014

SECTION 1: Identification of the Substance and of the Company 1.1.

Product Identifier British Wax Product Code Product Trade Name Chemical Type Chemical Description

1584, 1584W, 1584S Slush Casting Wax Mixture Proprietary blend Straight and branch chain hydrocarbons, long chain saturated and unsaturated alkanes, esters, alcohols, acids. -

CAS Number EC Number Reach registration number

1.2.

Relevant identified uses of the substance or mixture and uses advised against

1.2.1.

Relevant identified uses

Main use category

Casting Wax

1.2.2.

Uses advised against

1.3.

Details of the supplier of the safety data sheet The British Wax Refining Company Ltd 62 Holmethorpe Avenue, Redhill, Surrey RH1 2NL, United Kingdom T: +44 1737 761242 F: +44 1737 761472 wax@britishwax.com www.britishwax.com Emergency telephone +44 7725 231120 numbers (24 hours) +44 7885 409308

SECTION 2: Hazards Identification 2.1

Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP] The substance is not classified according to the CLP regulation. Not classified Classification according to Directive 67/548/EEC or 1999/45/EC Not applicable Not classified Adverse physicochemical, human health and environmental effects No additional information available

2.2

Label elements

Labelling to EC 1272/2008 [CLP] Signal word Precautionary Statements

2.3

No labelling applicable

Other Hazards

SECTION 3: Composition / information on ingredients 3.1

Substances

Chemical name Not applicable

3.2

CAS No. Not applicable

EC No. Not applicable

% Not applicable

Classification according to Directive 67/548/EC Not applicable

CAS No.

EC No.

Classification according to Directive 67/548/EC

Mixtures

Chemical name

Page 1 of 6

1584, 1584W, 1584S Slush Casting Wax

Date of issue

10/10/2019

SECTION 4: First aid measures 4.1

Description of first aid measures

First aid measures general First aid measures after inhalation First aid measures after skin contact

In case of serious or persistent conditions, call a doctor or seek emergency medical care. Remove to fresh air. Obtain medical attention if symptoms persist. Cold material: wash with soap, hand cleaner and water. Hot material: flush skin with cold water to cool as quickly as possible. Cover with clean cotton. Do not attempt to remove substance from a burn as this can result in tissue loss.Obtain prompt medical attention Cold material: wash eyes thoroughly with liberal amounts of water. Heated material: Rinse with cool water to dissipate heat, do not try to remove substance. Obtain prompt medical attention. Wash the mouth with water. If large amounts are swallowed obtain prompt medical attention.

First aid measures after eye contact First aid measures after ingestion

4.2

Most important symptoms and effects, both acute and delayed

Symptoms / Injuries

4.3

If inhaled or ingested, there may be some irritation of the throat with a feeling of tightness in the chest. Drowsiness or mental confusion may occur.

Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5: Firefighting measures 5.1

Extinguishing media

Suitable extinguishing media Unsuitable extinguishing media

5.2

Dry chemical, CO2, foam. Water jet. This will cause the fire to spread.

Special hazards arising from the substance or mixture

Incomplete combustion and thermolysis may produce gases of varying toxicity such as carbon monoxide, carbon dioxide, various hydrocarbons and soot. These may be highly dangerous if inhaled in confined spaces or at high concentration.

5.3

Advice for firefighters

Firefighting instructions Protection during firefighting Other information

No further relevant information available. Breathing apparatus and protective gloves. No further relevant information available.

SECTION 6: Accidental release measures 6.1

Personal precautions, protective equipment and emergency procedures

General measures Protective equipment Emergency procedures

6.2

Remove persons from danger area. Wear protective equipment as described in Section 8 of this SDS. In case of spills, beware of slippery floors. Remove ignition sources. Provide aqequate ventilation.

Environmental precautions

Keep away from drains, surface and ground water. Spillages or uncontrolled discharges into the watercourse must be IMMEDIATELY alerted to the appropriate regulatory body.

6.3

Methods and material for containment and cleaning up

Methods for cleaning up

6.4

If molten, allow to solidify, scrape up and dispose of as solid combustible material. Contain liquid with sand, earth or similar absorbent material.

Reference to other sections

PPE - Section 8. Waste Disposal - Section 13.

Page 2 of 6

1584, 1584W, 1584S Slush Casting Wax

Date of issue

10/10/2019

SECTION 7: Handling and storage 7.1

Precautions for safe handling Avoid spilling, skin and eye contact. Avoid inhalation of vapours.

Precautions for safe handing

7.2

Conditions for safe storage, including any incompatibilities No special measures required. Store in a cool, dry place.Keep away from combustion source. Protect from exposure to sunlight. No further relevant information. Below 30 °C

Technical measures Storage conditions Incompatible products Storage temperature

7.3

Specific end use(s)

Specific identified uses for this product are detailed in Section 1.2

SECTION 8: Exposure controls / personal protection 8.1

Control parameters

According to our experience and to the information provided to us, the product does not have any harmful effects if it is used and handled as specified.

DNEL (Workers): Short Exposure Identification

Long Exposure

Systemic

Local

Systemic

Local

Slush Casting Wax

Oral

n/a

CAS: -

Dermal

n/a

EC: -

Inhalation

n/a

DNEL (Populations): Short Exposure Identification

Long Exposure

Systemic

Local

Systemic

Local

Slush Casting Wax

Oral

n/a

CAS: -

Dermal

n/a

EC: -

Inhalation

n/a

Slush Casting Wax

STP

n/a

Fresh water

n/a

CAS: -

Soil

n/a

Marine water

n/a

EC: -

Intermittent

n/a

Sediment (Fresh water)

n/a

Oral

n/a

Sediment (Marine water)

n/a

PNEC: Identification

8.2

Exposure controls

Protective equipment

Appropriate engineering controls Hand protection Eye protection Skin and body protection Respiratory protection

Provide adequate ventilation, including appropriate local extraction, to ensure that the defined exposure limit is not exceeded. No special precautions other than protection from splashing or contact with molten material. Safety glasses, chemical goggles (if splashing possible). Heated wax should be handled with caution and suitable protective clothing worn. Adequate ventilation

Page 3 of 6

1584, 1584W, 1584S Slush Casting Wax

Date of issue

10/10/2019

SECTION 9: Physical and chemical properties 9.1

Information on basic physical and chemical properties

Physical state Colour Melting point / range, °C Congealing point / range, °C Boiling point / range, °C Flash point, °C Autoignition point, °C Relative density Solubility

9.2

Waxy solid Green n/a 60 - 70 > 200 n/a Water: Insoluble Ethanol: Insoluble Ether: Soluble

Other information

SECTION 10: Stability and reactivity 10.1

Reactivity

Stable under normal conditions.

10.2

Chemical stability

Stable under normal conditions.

10.3

Possibility of hazardous reactions

No decomposition if used according to instructions in SDS.

10.4

Conditions to avoid

Avoid heat, flames and other sources of igntion.

10.5

Incompatible materials

Strong oxidising agents. Strong acids.

10.6

Hazardous decomposition products

SECTION 11: Toxicological information 11.1

Information on toxicological effects

Acute toxicity Skin corrosion / irritation Serious eye damage / irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxcity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard

No data available No irritating effect No irritating effect No sensitizing effects known No data available No data available No data available No data available No data available No data available

SECTION 12: Ecological information 12.1

Toxicity

No data available

Page 4 of 6

1584, 1584W, 1584S Slush Casting Wax

12.2

10/10/2019

Persistence and degradability

12.3

Date of issue

No data available

Bioaccumulative potential

No data available

12.4

Mobility in soil

No data available

12.5

Results of PBT and vPvB assessment

Not classified as PBT/vPvB by current EU criteria

12.6

Other adverse effects

None known.

SECTION 13: Disposal considerations 13.1

Waste treatment methods

Ecology – waste materials European waste catalogue Uncleaned packaging

Recommendation: Smaller quantities can be disposed of with household waste. 05 01 06 Oily sludges from maintenance operations of the plant or equipment. 07 01 99 Wastes not otherwise specified. 12 01 12 Spent waxes and fats Recommendation: Disposal must be made according to official regulations.

SECTION 14: Transport information General information The product is not covered by international regulation on the transport of dangerous goods (ADR/RID, IMDG, IATA)

14.1 ADR/RID

14.2 ADR/RID

14.3 ADR/RID

14.4 ADR/RID

14.5 ADR/RID

UN Number No information required

IMDG

No information required

IATA

No information required

IATA

No information required

IMDG

No information required

IATA

No information required

IMDG

No information required

IATA

No information required

IATA

No information required

UN Proper Shipping name No information required

IMDG

Transport hazard class(es) No information required

Packing group No information required

Environmental hazards No information required

IMDG

14.6

Special precautions for user

14.7

Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

No information required

14.8

Additional information

Page 5 of 6

1584, 1584W, 1584S Slush Casting Wax

Date of issue

10/10/2019

SECTION 15: Regulatory information 15.1

Safety, health and environmental regulations / legislation specific for the substance or mixture

15.1.1 EU regulations

15.1.2 National regulations 15.2

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. UK Regulatory References. Health and Safety at Work Act 1974. The Control of Substances Hazardous to Health Regulations 2002 (S.I. 2002 No. 2677) with amendments.

Chemical safety assessment

A chemical safety assessment has not been carried out.

SECTION 16: Other information

Legal Disclaimer This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. In view of the fact that the application of this information is outside our control, we disclaim any liability incurred in connection with its application or use. It should not therefore be construed as guaranteeing any specific property of the product.

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Revision date: 11/05/2018

Revision: 3

Supersedes date: 06/06/2017

SAFETY DATA SHEET BARTOLINE - Methylated Spirits According to Regulation (EC) No 1907/2006 Annex II as amended by Regulation (EU) 2015/830.

SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name

BARTOLINE - Methylated Spirits

REACH registration notes

No REACH registration number required as this product is a mixture.

1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses

Fuel for camping stoves and fondues. Glass cleaner.

Uses advised against

Not to be used for cleaning skin as this may lead to skin disorders.

1.3. Details of the supplier of the safety data sheet Supplier

Bartoline Limited Barmston Close Beverley East Yorkshire HU17 0LW 01482 678710 info@bartoline.co.uk

Contact person

Product Compliance Manager

1.4. Emergency telephone number Emergency telephone

01482 678710 (8.30am - 4.45pm Monday to Friday) or NHS 111 (General Public) (24 Hour service)

National emergency telephone National Poisons Information Service (24hours) 0844 892 0111 number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards

Flam. Liq. 2 - H225

Health hazards

Not Classified

Environmental hazards

Not Classified

Physicochemical

Highly Flammable

2.2. Label elements Pictogram

Signal word

Danger 1/19

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BARTOLINE - Methylated Spirits Hazard statements

H225 Highly flammable liquid and vapour.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P243 Take action to prevent static discharges. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P403+P235 Store in a well-ventilated place. Keep cool. P102 Keep out of reach of children. P101 If medical advice is needed, have product container or label at hand. P501 Dispose of contents/container to hazardous waste collection point.

Supplemental label information

TO AVOID THE RISK OF SPILLAGE ALWAYS ENSURE THE LID IS SECURE AND THE CONTAINER IS SECURED UPRIGHT DURING TRANSPORTATION AND STORAGE.

Contains

ethanol

2.3. Other hazards SECTION 3: Composition/information on ingredients 3.2. Mixtures ethanol CAS number: 64-17-5

>=90% EC number: 200-578-6

REACH registration number: 012119457610-43-XXXX

Classification Flam. Liq. 2 - H225 propan-2-ol CAS number: 67-63-0

≥1<5% EC number: 200-661-7

Classification Flam. Liq. 2 - H225 Eye Irrit. 2 - H319 STOT SE 3 - H336 butanone CAS number: 78-93-3

≥1<5% EC number: 201-159-0

REACH registration number: 012119457290-43-XXXX

Classification Flam. Liq. 2 - H225 Eye Irrit. 2 - H319 STOT SE 3 - H336 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. Composition comments

This product complies with the Denatured Alcohol Regulations 2013.

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Revision: 3

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BARTOLINE - Methylated Spirits SECTION 4: First aid measures 4.1. Description of first aid measures General information

IN CASE OF SERIOUS OR PERSISTENT CONDITIONS, CALL A DOCTOR OR THE NHS 111 SERVICE. Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Keep affected person away from heat, sparks and flames. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. Never give anything by mouth to an unconscious person. Treat symptomatically.

Inhalation

Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Place unconscious person on their side in the recovery position and ensure breathing can take place. It may be dangerous for first aid personnel to carry out mouth-tomouth resuscitation. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. Get medical attention if any discomfort continues.

Ingestion

Rinse mouth thoroughly with water. Promptly get affected person to drink large volumes of water to dilute the swallowed chemical. Get medical attention.

Skin contact

Remove contamination with soap and water or recognised skin cleansing agent. Do not use organic solvents. Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention if symptoms are severe or persist after washing.

Eye contact

Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. Continue to rinse for at least 15 minutes and get medical attention.

Protection of first aiders

First aid personnel should wear appropriate protective equipment during any rescue. It may be dangerous for first aid personnel to carry out mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it from the affected person, or wear gloves.

4.2. Most important symptoms and effects, both acute and delayed General information

The severity of the symptoms described will vary dependent on the concentration and the length of exposure. Treat symptomatically.

Inhalation

May cause respiratory irritation. Vapours inhaled in strong concentration have a narcotic effect on the central nervous system. Irritation of the respiratory tract due to excessive fume, causes headache, drowsiness or other effects to the central nervous system, loss of consciousness.

Ingestion

May cause nausea, headache, dizziness and intoxication. Ingestion of large amounts may cause unconsciousness.

Skin contact

Prolonged or repeated contact may cause irritation and dry skin.

Eye contact

This product is moderately irritating. Irritation and redness, followed by blurred vision.

4.3. Indication of any immediate medical attention and special treatment needed Notes for the doctor

Treat symptomatically.

Specific treatments

No specific chemical antidote is known to be required after exposure to this product.

SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media

Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog.

Unsuitable extinguishing media

Do not use water jet as an extinguisher, as this will spread the fire.

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BARTOLINE - Methylated Spirits 5.2. Special hazards arising from the substance or mixture Specific hazards

The product is highly flammable. Severe explosion hazard when vapours are exposed to flames. Vapours may be ignited by a spark, a hot surface or an ember. May form explosive mixture with air at very high concentration. Vapours are heavier than air and may spread near ground and travel a considerable distance to a source of ignition and flash back. Vapours are heavier than air and may travel along the floor and accumulate in the bottom of containers. Risk of re-ignition after fire has been extinguished. Containers can burst violently or explode when heated, due to excessive pressure build-up. Fire-water run-off in sewers may create fire or explosion hazard.

Hazardous combustion products

Incomplete combustion and thermolysis may produce gases of varying toxicity such as carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot. These may be highly dangerous if inhaled in confined spaces or at high concentrations.

5.3. Advice for firefighters Protective actions during firefighting

Avoid breathing fire vapours. Cool containers exposed to flames with water until well after the fire is out. Keep run-off water out of sewers and water sources. Dike for water control. Containers close to fire should be removed or cooled with water.

Special protective equipment for firefighters

In case of a large fire or in confined or poorly ventilated spaces, wear full fire resistant protective clothing and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions

Keep unnecessary and unprotected personnel away from the spillage. No smoking, sparks, flames or other sources of ignition near spillage. Do not touch or walk into spilled material. Do not enter storage areas or confined spaces unless adequately ventilated. Wear protective clothing as described in Section 8 of this safety data sheet. Treat the spilled material according to the instructions in the clean-up section.

For emergency responders

Wear protective clothing as described in Section 8 of this safety data sheet. See section 11 for additional information on health hazards. For waste disposal, see section 13.

6.2. Environmental precautions Environmental precautions

The product contains a substance which may cause long-term adverse effects in the aquatic environment. The product contains substances which are water-soluble and may spread in water systems. The product is biodegradable but it must not be discharged into drains without permission from the authorities. Volatile substances are degraded in the atmosphere within a few days. Avoid the spillage or runoff entering drains, sewers or watercourses. To prevent release, place container with damaged side up. Spillages or uncontrolled discharges into watercourses must be reported immediately to the Environmental Agency or other appropriate regulatory body.

6.3. Methods and material for containment and cleaning up

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BARTOLINE - Methylated Spirits Methods for cleaning up

Stop leak if safe to do so. Eliminate all ignition sources if safe to do so. No smoking, sparks, flames or other sources of ignition near spillage. To prevent release, place container with damaged side up. Do not touch or walk into spilled material. Cover large spillages with alcohol-resistant foam. Allow small quantities to evaporate to the atmosphere in a safe, open place. Large Spillages: Contain spillage with sand, earth or other suitable non-combustible material. Absorb in vermiculite, dry sand or earth and place into containers. Containers with collected spillage must be properly labelled with correct contents and hazard symbol. Waste, residues, empty containers, discarded work clothes and contaminated cleaning materials should be collected in designated containers, labelled with their contents. Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority. For waste disposal, see Section 13. Wash thoroughly after dealing with a spillage.

6.4. Reference to other sections Reference to other sections

For personal protection, see Section 8. For waste disposal, see Section 13. See Section 11 for additional information on health hazards. See Section 12 for additional information on ecological hazards.

SECTION 7: Handling and storage 7.1. Precautions for safe handling Usage precautions

Avoid contact with skin and eyes. Keep away from heat, sparks and open flame. Eliminate all sources of ignition. Use explosion proof electric equipment. Storage tanks and other containers must be grounded. Wear full protective clothing for prolonged exposure and/or high concentrations. Contaminated clothing and shoes must be discarded. Contaminated rags and cloths must be put in fireproof containers for disposal. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. Avoid spilling and release to the environment such as drains and watercourses.

Advice on general occupational hygiene

Persons with impaired lung function should not handle this product.. Do not eat, drink or smoke when using this product. Provide eyewash station. Wash promptly with soap and water if skin becomes contaminated. Take off immediately all contaminated clothing and wash it before reuse. Promptly remove any clothing that becomes wet or contaminated. Remove contaminated clothing and protective equipment before entering eating areas. Wash at the end of each work shift and before eating, smoking and using the toilet. Use appropriate hand lotion to prevent defatting and cracking of skin.

7.2. Conditions for safe storage, including any incompatibilities Storage precautions

Store in tightly-closed, original container in a dry, cool and well-ventilated place. Keep container tightly sealed when not in use. Keep locked up and out of the reach of children. Store in a demarcated bunded area to prevent release to drains and/or watercourses. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Avoid contact with oxidising agents. Keep away from food, drink and animal feeding stuffs. Use containers made of the following materials: Mild steel. Stainless steel. High-density polyethylene (HDPE) Polyethylene terephthalate (PET)

Storage class

Flammable liquid storage.

7.3. Specific end use(s) Specific end use(s)

The identified uses for this product are detailed in Section 1.2.

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BARTOLINE - Methylated Spirits Usage description

In General: Keep containers closed when not in use. Keep containers upright. Use only in well ventilated areas, ideally outdoors. Open containers slowly in order to release any pressure build up that may occur. Keep out of reach of children. Apply "common sense" measures when using this product. When using transfer required amount to a suitable container such as glass, metal or HDPE. Avoid all contact with skin and eyes.

SECTION 8: Exposure Controls/personal protection 8.1. Control parameters Occupational exposure limits ethanol Long-term exposure limit (8-hour TWA): WEL 1000 ppm 1920 mg/m3 vapour Short term exposure limit (STEL) 15 Min - No Standard in EH40 propan-2-ol Long-term exposure limit (8-hour TWA): WEL 400 ppm 999 mg/m3 Short-term exposure limit (15-minute): WEL 500 ppm 1250 mg/m3 butanone Long-term exposure limit (8-hour TWA): WEL 200 ppm 600 mg/m³ Short-term exposure limit (15-minute): WEL 300 ppm 899 mg/m3 Sk WEL = Workplace Exposure Limit Sk = Can be absorbed through the skin. Ingredient comments

There is no data for the product as a whole, see comments on individual constituents. ethanol (CAS: 64-17-5)

DNEL

Workers - Inhalation; Short term local effects: 1900 mg/m³ Workers - Inhalation; Long term systemic effects: 950 mg/m³ General population - Inhalation; Short term local effects: 950 mg/m³ General population - Inhalation; Long term systemic effects: 114 mg/m³ Workers - Dermal; Long term systemic effects: 343 mg/kg/day General population - Dermal; Long term systemic effects: 206 mg/kg/day General population - Oral; Long term systemic effects: 87 mg/kg/day

PNEC

Industry - Fresh water; Long term 0.96 mg/l Industry - Marine water; Long term 0.79 mg/l Industry - Sediment (Freshwater); Long term 3.6 mg/kg sediment dw Industry - Soil; Long term 0.63 mg/kg soil dw Industry - Intermittent release; Long term 2.75 mg/l Industry - STP; Long term 580 mg/l butanone (CAS: 78-93-3)

Biological limit values

70micromol per litre

DNEL

Industry - Dermal; Long term systemic effects: 1161 mg/kg/day Industry - Inhalation; Long term systemic effects: 600 mg/m³ Consumer - Oral; Long term systemic effects: 31 mg/kg/day Consumer - Dermal; Long term systemic effects: 412 mg/kg/day Consumer - Inhalation; Long term systemic effects: 106 mg/kg/day 6/19

Revision date: 11/05/2018

Revision: 3

Supersedes date: 06/06/2017

BARTOLINE - Methylated Spirits PNEC

Industry - Fresh water; Long term 55.8 mg/l Industry - Marine water; Long term 55.8 mg/l Industry - Sediment (Freshwater); Long term 284.7 mg/kg Industry - Sediment (Marinewater); Long term 287.7 mg/kg Industry - Soil; Long term 22.5 mg/kg propan-2-ol (CAS: 67-63-0)

DNEL

Industry - Dermal; Long term systemic effects: 888 mg/kg/day Industry - Inhalation; Long term systemic effects: 500 mg/m³ Consumer - Dermal; Long term systemic effects: 319 mg/kg/day Consumer - Inhalation; Long term systemic effects: 89 mg/m³ Consumer - Oral; Long term systemic effects: 26 mg/kg/day

PNEC

Industry - Fresh water; Long term 140.9 mg/l Industry - Marine water; Long term 140.9 mg/l Industry - Sediment; Long term 552 mg/kg Industry - Soil; Long term 28 mg/kg Industry - STP; Long term 2251 mg/l

8.2. Exposure controls Protective equipment

Appropriate engineering controls

Use process enclosures, local exhaust ventilation or other engineering controls as the primary means to minimise worker exposure. Good general ventilation should be adequate to control worker exposure to airborne contaminants. Personal protective equipment should only be used if worker exposure cannot be controlled adequately by the engineering control measures.

Personal protection

Protective engineering solutions should be implemented and in use before Personal Protective Equipment (PPE) is considered.

Eye/face protection

Wear EN 166 approved chemical safety goggles where eye exposure is reasonably probable.

Hand protection

Chemical-resistant, impervious gloves complying with an approved standard should be worn if a risk assessment indicates skin contact is possible. The most suitable glove should be chosen in consultation with the glove supplier/manufacturer, who can provide information about the breakthrough time of the glove material. To protect hands from chemicals, gloves should comply with European Standard EN374. It is recommended that gloves are made of the following material: Nitrile rubber. Rubber (natural, latex). Viton rubber (fluoro rubber). It should be noted that liquid may penetrate the gloves. Frequent changes are recommended.

Other skin and body protection

Given the identified use of the product additional skin and body protection should not be required.

Hygiene measures

Wash hands thoroughly after handling. Wash promptly with soap and water if skin becomes contaminated. Care should be taken to avoid contact with contaminants when removing contaminated clothing. Promptly remove any clothing that becomes wet or contaminated. Remove contaminated clothing and protective equipment before entering eating areas. Wash at the end of each work shift and before eating, smoking and using the toilet. Do not eat, drink or smoke when using this product.

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BARTOLINE - Methylated Spirits Respiratory protection

Respiratory protection complying with an approved standard should be worn if a risk assessment indicates inhalation of contaminants is possible. Respirator selection must be based on exposure levels, the hazards of the product and the safe working limits of the selected respirator. Ensure all respiratory protective equipment is suitable for its intended use and is ‘CE’-marked. Full face mask respirators with replaceable filter cartridges should comply with European Standard EN136. Half mask and quarter mask respirators with replaceable filter cartridges should comply with European Standard EN140. Gas and combination filter cartridges should comply with European Standard EN14387. Check that the respirator fits tightly and the filter is changed regularly.

Environmental exposure controls

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Store in a demarcated bunded area to prevent release to drains and/or watercourses. Residues and empty containers should be taken care of as hazardous waste according to local and national provisions.

SECTION 9: Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Appearance

Coloured liquid.

Colour

Violet.

Odour

Alcoholic.

Odour threshold

No specific test data are available.

Not available.

Melting point

Not available.

Initial boiling point and range

78°C @ 1013 hPa

Flash point

~ 12°C Closed cup.

Evaporation rate

~ 3.4 (butyl acetate = 1)

Evaporation factor

Not available.

Upper/lower flammability or explosive limits

Lower flammable/explosive limit: 3.5 % Upper flammable/explosive limit: 19 %

Vapour pressure

5.8 kPa @ 20°C

Vapour density

~ 1.03

Relative density

~ 0.800 - 0.820 @ 20°C

Solubility(ies)

Soluble in water.

Auto-ignition temperature

363°C

Decomposition Temperature

Not available.

Viscosity

1.2 mPa s @ 20°C

Explosive properties

Not available.

Oxidising properties

The mixture itself has not been tested but none of the ingredient substances meet the criteria for classification as oxidising.

Comments

Information declared as "Not available" or "Not applicable" is not considered to be relevant to the implementation of the proper control measures.

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Supersedes date: 06/06/2017

BARTOLINE - Methylated Spirits 9.2. Other information Refractive index

1.3614

Molecular weight

46.07

Volatile organic compound

This product contains a maximum VOC content of 820 .

SECTION 10: Stability and reactivity 10.1. Reactivity Reactivity

May react with: Strong acids. Strong oxidising agents.

10.2. Chemical stability Stability

Stable at normal ambient temperatures and when used as recommended.

10.3. Possibility of hazardous reactions Possibility of hazardous reactions

The following materials may react with the product: Strong acids. Oxidising agents.

10.4. Conditions to avoid Conditions to avoid

Avoid the following conditions: Heat, sparks, flames.

10.5. Incompatible materials Materials to avoid

Strong acids. Oxidising materials.

10.6. Hazardous decomposition products Hazardous decomposition products

Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.

SECTION 11: Toxicological information 11.1. Information on toxicological effects Toxicological effects

No data for the product as a whole. See information on individual substances below.

Toxicological information on ingredients. ethanol Acute toxicity - oral Acute toxicity oral (LD₅₀ mg/kg)

10,470.0

Species

Rat

ATE oral (mg/kg)

10,470.0

Acute toxicity - dermal Acute toxicity dermal (LD₅₀ 15,800.0 mg/kg) Species

Rabbit

ATE dermal (mg/kg)

15,800.0

Acute toxicity - inhalation Acute toxicity inhalation (LC₅₀ vapours mg/l)

124.7

Species

Rat 9/19

Revision date: 11/05/2018

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BARTOLINE - Methylated Spirits ATE inhalation (vapours mg/l)

124.7

Skin corrosion/irritation Animal data

Erythema/eschar score: No erythema (0). Oedema score: No oedema (0).

Serious eye damage/irritation Serious eye damage/irritation

Irritation of eyes is assumed.

Respiratory sensitisation Respiratory sensitisation

Guinea pig: Not sensitising.

Skin sensitisation Skin sensitisation

Guinea pig maximization test (GPMT) - Guinea pig: Not sensitising.

Germ cell mutagenicity Genotoxicity - in vitro

Negative.

Carcinogenicity Carcinogenicity

Based on available data the classification criteria are not met.

Reproductive toxicity Reproductive toxicity fertility

Based on available data the classification criteria are not met.

Reproductive toxicity development

This substance has no evidence of toxicity to reproduction.

Specific target organ toxicity - repeated exposure STOT - repeated exposure NOAEL 1730 mg/kg, Oral, Rat Aspiration hazard Aspiration hazard

Not anticipated to present an aspiration hazard, based on chemical structure.

Inhalation

Vapours inhaled in strong concentrations have a narcotic effect on the central nervous system. Irritation of the respiratory tract due to excessive fume. Causes headache, drowsiness or other effects to the central nervous system, loss of consciousness.

Ingestion

Liquid irritates mucous membranes and may cause abdominal pain if swallowed. Gastrointestinal symptoms, including upset stomach. Irritating. May be absorbed in the body and cause dizziness, nausea and vomiting.

Skin contact

Prolonged or repeated contact may dry skin and cause irritation. Frequent or prolonged skin contact destroys the lipacid cutaneous layer and may cause dermatitis.

Eye contact

Extreme irritation of eyes and mucous membranes, including burning and tearing. Although not classified as irritating to eyes there is a risk of corneal damage.

Route of exposure

Inhalation Ingestion Skin and/or eye contact

Target organs

Central nervous system Eyes Gastro-intestinal tract Skin

10/19

Revision date: 11/05/2018

Revision: 3

Supersedes date: 06/06/2017

BARTOLINE - Methylated Spirits Medical symptoms

Symptoms following overexposure may include the following: Behavioural changes. Central nervous system depression. Irritation of eyes and mucous membranes. Visual disturbances, including blurred vision. Headache. Nausea, vomiting.

Medical considerations

The following pre-existing or historic medical conditions of the worker may lead to an increased risk of adverse health effects following exposure to this product: History of alcoholism. History of smoking. Skin disorders and allergies. propan-2-ol

Acute toxicity - oral Acute toxicity oral (LD₅₀ mg/kg)

5,840.0

Species

Rat

ATE oral (mg/kg)

5,840.0

Acute toxicity - dermal ATE dermal (mg/kg)

2,000.1

Acute toxicity - inhalation ATE inhalation (vapours mg/l)

20.1

Skin corrosion/irritation Animal data

Primary dermal irritation index: 0 Based on available data the classification criteria are not met.

Serious eye damage/irritation Serious eye damage/irritation

Irritation of eyes is assumed.

Respiratory sensitisation Respiratory sensitisation

Guinea pig: Not sensitising.

Skin sensitisation Skin sensitisation

Buehler test - Guinea pig: Not sensitising. One group of 20 test animals was treated with undiluted Isopropyl alcohol for a period of 6 hours weekly for 3 induction exposures. The test animals and control animals were challenged with undiluted Isopropyl alcohol. No skin reactions were observed in the test and control animals therefore, it was concluded that Isopropyl alcohol is not a sensitizer.

Germ cell mutagenicity Genotoxicity - in vitro

Gene mutation: Negative.

Genotoxicity - in vivo

Chromosome aberration: Negative.

Carcinogenicity Carcinogenicity

NOAEL 5000 ppm, Inhalation, Based on available data the classification criteria are not met.

Reproductive toxicity Reproductive toxicity fertility

Based on available data the classification criteria are not met.

butanone 11/19

Revision date: 11/05/2018

Revision: 3

Supersedes date: 06/06/2017

BARTOLINE - Methylated Spirits Acute toxicity - oral Acute toxicity oral (LD₅₀ mg/kg)

3,460.0

Species

Rat

ATE oral (mg/kg)

3,460.0

Acute toxicity - dermal Acute toxicity dermal (LD₅₀ 6,480.0 mg/kg) Species

Rabbit

ATE dermal (mg/kg)

6,480.0

Serious eye damage/irritation Serious eye damage/irritation

Irritation of eyes is assumed.

Respiratory sensitisation Respiratory sensitisation

No specific test data are available.

Skin sensitisation Skin sensitisation

Undiluted methyl ethyl ketone elicited a slight erythematous response in one of the test animals following the challenge application. This response was deemed inconclusive. The results for the remaining guinea pigs were negative. Under the conditions of the study, MEK was not considered to be a skin sensitiser in guinea pigs.

Carcinogenicity Carcinogenicity

Based on available data the classification criteria are not met.

IARC carcinogenicity

Not listed.

Specific target organ toxicity - single exposure STOT - single exposure

A single exposure may cause the following adverse effects: Vapours may cause drowsiness and dizziness.

SECTION 12: Ecological Information Ecotoxicity

There is no Ecotoxicity data for the product as a whole. See data for individual constituents below.

Ecological information on ingredients. ethanol Ecotoxicity

The product is not expected to be hazardous to the environment. However, large or frequent spills may have hazardous effects on the environment.

12.1. Toxicity Ecological information on ingredients. ethanol Acute aquatic toxicity

12/19

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BARTOLINE - Methylated Spirits Acute toxicity - fish

EC₅₀, 96 hours: 14,200 mg/l, Pimephales promelas (Fat-head Minnow) In a well reported 96 hour acute toxicity study, fathead minnows (Pimephales promelas) were exposed to ethanol at actual concentrations up to 20g/l using a flow through method. An LC50 of 14.2g/l was established. Based on the results of this study, ethanol would be not be classified toxic to the environment according to the classification system of the EU. This toxicity study is classified as acceptable as a supporting study the acute fish toxicity end point.

Acute toxicity - aquatic invertebrates

LC₅₀, 48 hours: 5012 mg/l, Ceriodaphnia dubia

Acute toxicity - aquatic plants

EC₅₀, 72 hour: 275 mg/l, Algae

Acute toxicity microorganisms

EC₅₀, 48 hour: 11963 mg/l, Tetrahymena pyriformis.

Acute toxicity - terrestrial

LC₅₀, 48 hour: 0.1-1.0 mg/cm², Soil macroorganisms except arthropods propan-2-ol

Acute aquatic toxicity Acute toxicity - fish

LC₈₀, 48 hours: 9280 mg/l, Leuciscus idus (Golden orfe)

Acute toxicity - aquatic invertebrates

LC₈₀, 24 hours: >10000 mg/l, Daphnia magna

Acute toxicity microorganisms

Not determined.

Acute toxicity - terrestrial

IC₅₀, 3 days: 95 %, Lactuca sativa butanone

Acute aquatic toxicity Acute toxicity - fish

LC₈₀, 96 hours: 2993 mg/l, Pimephales promelas (Fat-head Minnow)

Acute toxicity - aquatic invertebrates

EC₈₀, 48 hours: 308 mg/l, Daphnia magna

Acute toxicity - aquatic plants

EC₈₀, 48 hours: 1726-2278 mg/l, Pseudokirchneriella subcapitata

12.2. Persistence and degradability Ecological information on ingredients. ethanol Persistence and degradability

The product is biodegradable. The product is degraded completely by photochemical oxidation.

Phototransformation

Water - Half-life : 11.5 hours

Stability (hydrolysis)

Ethanol is stable to hydrolysis in water. The estimated half life in the absence of biodegradation is around 1 -36 years. It should be noted that since ethanol is readily biodegradable, this is not an issue of concern.

13/19

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BARTOLINE - Methylated Spirits Biodegradation

The biodegradation of ethanol was assessed at a number of concentrations using a non-adapted domestic sewage innoculum in a freshwater medium using a 20 day study. Rapid degradation was observed. Based on the results of this study, ethanol meets the criteria to be classified as readily biodegradable. This study is classified as acceptable and satisfies the guideline requirement for a ready biodegradation study.

Biological oxygen demand BOD5 74 % Chemical oxygen demand 95 % propan-2-ol Persistence and degradability

The product is readily biodegradable. A BOD5/COD ratio ≥ 0.5 is considered as indicative of rapid degradation. Thus, a substance which passes this screening test is considered likely to biodegrade 'rapidly' in the aquatic environment, and is thus unlikely to be persistent.

Biological oxygen demand ≥ 1.72 g O₂/g substance butanone Biodegradation

The substance is readily biodegradable.

12.3. Bioaccumulative potential Ecological information on ingredients. ethanol Bioaccumulative potential

Not available.

Partition coefficient

log Pow: ~ 0.35 butanone

Bioaccumulative potential

The product is not bioaccumulating.

Partition coefficient

log Pow: 0.3

12.4. Mobility in soil Ecological information on ingredients. ethanol Mobility

The product is water-soluble and may spread in water systems. Large volumes may penetrate soil and could contaminate groundwater. If product enters soil it will be mobile and may contaminate groundwater.

Adsorption/desorption coefficient

Not available.

Henry's law constant

Not available.

Surface tension

Not available. butanone

14/19

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BARTOLINE - Methylated Spirits Mobility

Surface tension

24.8 mN/m @ 20°C

12.5. Results of PBT and vPvB assessment Ecological information on ingredients. ethanol Results of PBT and vPvB assessment

This substance is considered not to be PBT and vPvB.

propan-2-ol Results of PBT and vPvB assessment

This substance is considered not to be PBT and vPvB.

butanone Results of PBT and vPvB assessment

Not Classified as PBT/vPvB by current EU criteria.

12.6. Other adverse effects Ecological information on ingredients. ethanol Other adverse effects

The product contains volatile organic compounds (VOCs) which have a photochemical ozone creation potential.

SECTION 13: Disposal considerations 13.1. Waste treatment methods General information

The generation of waste should be minimised or avoided wherever possible. Waste, residues, empty containers, discarded work clothes and contaminated cleaning materials should be collected in designated containers, labelled with their contents. Waste material and any included combustible absorbent and containers should be suitable for incineration at an approved facility.

Disposal methods

Allow small quantities to evaporate to the atmosphere in a safe, open place. Waste material and any included combustible absorbent and containers should be suitable for incineration at an approved facility.

15/19

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Revision: 3

Supersedes date: 06/06/2017

BARTOLINE - Methylated Spirits Waste class

Unused Liquid waste: 07 01 04* Other organic solvents, washing liquids and mother liquors. Empty used containers should be disposed of as waste code 15 01 10 packaging containing residues of or contaminated by dangerous substances. Note For a waste container to be classed as a packaging waste (15 01) it must be effectively ‘empty’. It is usually obvious if a container is ‘empty’, for example a half empty tin of solidified paint is not empty, but where there is a small amount of residual material a container will not be empty if that residual material can be removed by physical or mechanical means by applying normal industry standards or processes. This means that all reasonable efforts must have been made to remove any left-over contents from the container. This may involve for example washing, draining or scraping. The method of emptying will depend on the container and the type of material it contains. Note: if the design of the packaging, its aperture, or the adherent nature of the material does not permit it to be emptied then it will not be a packaging waste. If a container is not ‘empty’ it is not packaging waste. It should be classified on the basis of its contents and the source or activity that produced it. For example 08 01 11* waste paint and varnish containing organic solvents or other dangerous substances. Any absorbents used for clearing up spills should be disposed of using waste code:

SECTION 14: Transport information 14.1. UN number UN No. (ADR/RID)

1170

UN No. (IMDG)

1170

UN No. (ICAO)

1170

UN No. (ADN)

1170

14.2. UN proper shipping name Proper shipping name (ADR/RID)

ETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)

Proper shipping name (IMDG) ETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION) Proper shipping name (ICAO) ETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION) Proper shipping name (ADN)

ETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)

14.3. Transport hazard class(es) ADR/RID class

ADR/RID classification code

ADR/RID label

IMDG class

ICAO class/division

ADN class

Transport labels

16/19

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BARTOLINE - Methylated Spirits 14.4. Packing group ADR/RID packing group

IMDG packing group

ADN packing group

ICAO packing group

14.5. Environmental hazards Environmentally hazardous substance/marine pollutant No. 14.6. Special precautions for user EmS

F-E, S-D

ADR transport category

Emergency Action Code

•2YE

Hazard Identification Number (ADR/RID)

Tunnel restriction code

(D/E)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code Transport in bulk according to Cat Z Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations

Control of Substances Hazardous to Health Regulations 2002 (as amended). Dangerous Substances and Explosive Atmospheres Regulations 2002. EH40/2005 Workplace exposure limits. Health and Safety at Work etc. Act 1974 (as amended). The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2009 (SI 2009 No. 1348) (as amended) ["CDG 2009"]. The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (SI 2009 No. 716). Users of this product are reminded of their duties under the current Control of Substances Hazardous to Health Regulations and a suitable and sufficient assessment of all the risk should be undertaken before using this product. The guidelines given in the HSE publication COSHH ESSENTIALS - Easy Steps To Control Chemicals gives sound advice for deciding safe working control measures.

EU legislation

Commission Decision 2000/532/EC as amended by Decision 2001/118/EC establishing a list of wastes and hazardous waste pursuant to Council Directive 75/442/EEC on waste and Directive 91/689/EEC on hazardous waste with amendments. Commission Regulation (EU) No 453/2010 of 20 May 2010. Dangerous Substances Directive 67/548/EEC. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures (as amended). Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (as amended). 17/19

Revision date: 11/05/2018

Revision: 3

Supersedes date: 06/06/2017

BARTOLINE - Methylated Spirits Guidance

CHIP for everyone HSG228. Workplace Exposure Limits EH40.

Authorisations (Title VII Regulation 1907/2006)

No specific authorisations are known for this product.

Restrictions (Title VIII Regulation 1907/2006)

No specific restrictions on use are known for this product.

15.2. Chemical safety assessment No chemical safety assessment has been carried out. Inventories EU - EINECS/ELINCS All the ingredients are listed or exempt. Canada - DSL/NDSL All the ingredients are listed or exempt. US - TSCA All the ingredients are listed or exempt. US - TSCA 12(b) Export Notification All the ingredients are listed or exempt. Australia - AICS All the ingredients are listed or exempt. Philippines – PICCS All the ingredients are listed or exempt. New Zealand - NZIOC All the ingredients are listed or exempt. SECTION 16: Other information General information

This product complies with the Denatured Alcohol Regulations 2013

Classification procedures according to Regulation (EC) 1272/2008

: On basis of test data.

Training advice

The information on directions for use can be found on the product label. It is important to ensure that anyone using this product in the workplace has been adequately trained and in particular: The use of personal protective equipment, methods of cleaning up and disposal of waste. The basic first aid arrangements.

Revision comments

DUE TO CHANGE OF CLASSIFICATION DATABASE THE REVISION NUMBERING HAS BEEN RESET. You should therefore look at the revision date rather than the revision number to ensure you have the most up to date version. NOTE: Lines within the margin indicate significant changes from the previous revision.

Issued by

Product Compliance Manager

Revision date

11/05/2018

Revision

Supersedes date

06/06/2017

18/19

Revision date: 11/05/2018

Revision: 3

Supersedes date: 06/06/2017

BARTOLINE - Methylated Spirits SDS number

4665

SDS status

Approved.

Hazard statements in full

H225 Highly flammable liquid and vapour. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness.

The information contained in this data sheet is provided in accordance with the requirements of the Regulation (EC) No 1907/2006 Annex II as amended by Regulation (EU) 2015/830 and Regulation (EC) No 1272/2008 (CLP). The product should not be used for purposes other than those shown in Section 1.2. As the specific conditions of use are outside the supplier's control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. The information contained in this safety data sheet is based on the present knowledge and the current EU and UK Legislation. It provides guidance on health, safety and environmental aspects of the product and should not be taken as a product specification. 19/19

The British Wax Refining Co. Ltd (incorporating Speciality Waxes) 62 Holmethorpe Avenue, Redhill, Surrey, RH1 2NL, United Kingdom Tel: +44 1737 761242 Fax : +44 1737 761472 www.britishwax.com wax@britishwax.com

MATERIAL SAFETY DATA SHEET 1.

Identification of the substance 2007 Microcrystalline Wax

Name

Composition / Information on Ingredients

Chemical Name and Synonyms Chemical Family CAS Number EINECS Number List of Dangerous Ingredients

Hazard Identification

Inhalation Eyes Skin Ingestion

Skin Ingestion

Fire and Explosion Hazards Fire Class according to DIN-EN 2:

If molten, allow to solidify, scrape up and dispose of as solid combustible material. Do not wash solid or molten wax into drains.

Special Storage and Handling Precautions

Storage Handling Protection

>250 Requires exposure to high temperature and naked flame. Dry chemical, CO2, foam. Wear self contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Slight when exposure to heat and flames.

Accidental Release Measures

In Case of Spill

Remove to fresh air. Obtain medical attention if symptoms persist. Cold wax. Wash eyes thoroughly with water. Heated wax. Rinse with cool water to dissipate heat, do not try to remove wax. Obtain prompt medical attention. Cold wax. Wash with soap, hand cleaner and water. Hot wax. Flush skin with cold water to cool as quickly as possible. Cover with clean cotton or gause. Do not attempt to remove wax from a burn as this can result in tissue loss. Obtain prompt medical atten Wash the mouth with water. If large amounts are swallowed obtain prompt medical attention.

Fire and Explosion Hazard Data

Flash Point, °C Flammable Limits Extinguishing Media Special Fire Fighting Procedures

Mist or fumes may cause irritation or coughing. Harmless when cold, heated wax may cause burns. Harmless to skin when cold, heated wax may cause burns. Harmless if swallowed in small doses, but larger amounts may cause nausea and diarrhoea. Low order of toxicity.

First Aid Measures

Inhalation Eyes

Saturated hydrocarbon mixture Straight and branch chain saturated hydrocarbons 64742-60-5 265-163-4 None. This product contains no dangerous ingredients

Store away from boilers and hot pipes. No special precautions other than protection from splashing or contact with molten material.

Exposure Control / Personal Protection Information

Exposure Limits Eye Protection Skin Protection Respiratory Protection Ventilation

A threshold value of 1mg/m3 is recommended for wax fumes. Safety glasses, chemical goggles (if splashing possible). Heated wax should be handled with caution and suitable protective clothing worn. Adequate ventilation Normal ventilation

CONTINUES… Page 1 of 2

CONTINUED FROM PAGE 1 9.

Physical Data

Physical state at room temperature Form supplied Colour Odour in physical state Odour in molten state Density at 20°C Congealing Point, °C Drop Melting Point, °C Ring and Ball Softening Point, °C Viscosity at 100°C, cSt Penetration at 25°C Acid Value Saponification Value

Waxy solid Slab White to Off-White Practically odourless Characteristic Waxy Odour n/a 75 – 85 n/a n/a n/a 20 – 40 0 0

10. Reactivity Data Stability Hazardous Decomposition Products Hazardous Polymerisation Incompatibility - materials to avoid

Stable None Will not occur None

11. Toxicological Data Toxicology Health Effects

No data available None expected

12. Ecological Information Unlikely to cause any environmental hazards. Degrades very slowly at ambient temperatures.

13. Disposal Considerations Disposal of waste product WC-Code Disposal of packaging – pallets Disposal of packaging – cartons

Treat as solid combustible materials and dispose in accordance with local regulations. 12 01 12 Spent waxes and fats Pallets can be returned to supplier via haulier / forwarding agent Cartons may be returned to the appropriate used paper recycling point.

14. Transportation Designation Special Precautions

Non-hazardous None

15. Regulatory Information There is no regulatory material available.

16. Other Information Further reading

Ullmans's Encylopedia of Industrial Chemistry, 5th Edition, Vol. A28, Chapter "Waxes", Verlag Chemie, 1996 Shubik et al., Toxicol. Appl. Pharmacol, 4, Suppl. 1-62, 1962

Last Revision

Thursday, 24 November 2011

Although the information contained herein is presented in good faith and to the best of The British Wax Refining Company’s knowledge and experience, it is made without any warranty or guarantee whatsoever. Every care has been taken to compile this information accurately. In view of the fact that the application of this information is outside our control, we disclaim any liability incurred in connection with its application or use.

Page 1 of 2

SHELL DEPT

SAFETY DATA SHEET

according to Regulation (EU) 2015/830 Page

1/7

Ranco-Sil (TM) fused silica [NA] Revision

Revision date 2021-07-21

SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name

Ranco-Sil (TM) fused silica [NA]

1.2. Relevant identified uses of the substance or mixture and uses advised against Description

Foundry material.

1.3. Details of the supplier of the safety data sheet Company

Ransom & Randolph

Address

3535 Briarfield Boulevard, PO Box 1570 Maumee, Ohio 43537 USA

Web

www.ransom-randolph.com

Telephone

+1 (419) 865-9497

Fax

+1 (419) 865-9997

SDS@ransom-randolph.com

Email address of the competent person

dyouel@ransom-randolph.com

1.4. Emergency telephone number Emergency telephone number

USA +1 419 865 9497

Company

Ransom & Randolph Co. 08:00-17:00 (US Eastern Std. / GMT minus 5)

SECTION 2: Hazards identification 2.1. Classification of the substance or mixture 2.1.2. Classification - EC 1272/2008

Carc. 1A: H350;

2.2. Label elements This substance / mixture has been classified in accordance with the US Federal OSHA Hazard Communication Standard 29CFR 1910.1200. Substance concentration band-ranges are presented, and minor ingredient composition maybe withheld, to protect trade secrets. Hazard pictograms

Signal Word

Danger

Hazard Statement

Carc. 1A: H350 - May cause cancer inhalation.

Precautionary Statement: Prevention

P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P280 - Wear protective gloves/protective clothing/eye protection/face protection.

Precautionary Statement: Response

P308+P313 - IF exposed or concerned: Get medical advice/attention.

Print date 2021-07-21

REMET FUSED SILICA (ALL GRADES) Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 Issue date: 27/06/2017 Revision date: 08/01/2021 Supersedes version of: 02/01/2020 Version: 3.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name

: Mixture : REMET FUSED SILICA (ALL GRADES)

1.2. Relevant identified uses of the substance or mixture and uses advised against 1.2.1. Relevant identified uses Industrial/Professional use spec Use of the substance/mixture

: Industrial : tiles and ceramics

1.2.2. Uses advised against No additional information available

1.3. Details of the supplier of the safety data sheet Remet UK Ltd 44 Riverside II Sir Thomas Longley Road ME2 4DP Rochester, Kent - United Kingdom

1.4. Emergency telephone number Emergency number

: +44 1634 226 240

SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU > 2015: According to Regulation (EU) 2015/830, 2020/878 (REACH Annex II) Not classified Adverse physicochemical, human health and environmental effects No additional information available

2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] EUH-statements

: EUH210 - Safety data sheet available on request.

2.3. Other hazards No additional information available

SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable

3.2. Mixtures Name

Product identifier

Classification according to Regulation (EC) No. 1272/2008 [CLP]

FUSED SILICA

(CAS-No.) 60676-86-0

≥ 50

Not classified

QUARTZ (CAS-No.) 14808-60-7 substance with a Community workplace exposure limit (EC-No.) 238-878-4

< 10

Not classified

08/01/2021 (Version: 3.0)

EN (English)

1/7

REMET FUSED SILICA (ALL GRADES) Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion

: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Allow affected person to breathe fresh air. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water (for at least 15 minutes). Obtain medical attention if pain, blinking or redness persists. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.

4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects after inhalation Symptoms/effects after skin contact Symptoms/effects after eye contact Symptoms/effects after ingestion

: : : :

May cause shortness of breath, tightness of the chest, a sore throat and cough. Causes mild skin irritation. Causes eye irritation. May cause irritation to the digestive tract.

4.3. Indication of any immediate medical attention and special treatment needed No additional information available

SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media

: Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture No additional information available

5.3. Advice for firefighters Firefighting instructions Protection during firefighting

: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment. : Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures

: Evacuate unnecessary personnel.

6.1.2. For emergency responders Protective equipment Emergency procedures

: Equip cleanup crew with proper protection. : Ventilate area.

6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.

6.3. Methods and material for containment and cleaning up Methods for cleaning up

: Minimise generation of dust. Clear up rapidly by scoop or vacuum.

6.4. Reference to other sections See Heading 8. Exposure controls and personal protection.

08/01/2021 (Version: 3.0)

EN (English)

2/7

REMET FUSED SILICA (ALL GRADES) Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling

: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour.

7.2. Conditions for safe storage, including any incompatibilities Storage conditions

: Keep container closed when not in use.

7.3. Specific end use(s) No additional information available

SECTION 8: Exposure controls/personal protection 8.1. Control parameters REMET FUSED SILICA (ALL GRADES) United Kingdom - Occupational Exposure Limits Local name

Silica, fused

WEL TWA (mg/m³)

0.08 mg/m³ respirable dust

Regulatory reference

EH40/2005 (Third edition, 2018). HSE

FUSED SILICA (60676-86-0) United Kingdom - Occupational Exposure Limits Local name

Silica, fused

WEL TWA (mg/m³)

0.08 mg/m³ respirable dust

Regulatory reference

EH40/2005 (Third edition, 2018). HSE

QUARTZ (14808-60-7) EU - Occupational Exposure Limits Local name

Silica crystaline (Quartz)

IOELV TWA (mg/m³)

0.05 mg/m³ (respirable dust)

Notes

(Year of adoption 2003)

Regulatory reference

SCOEL Recommendations

8.2. Exposure controls Appropriate engineering controls: Ensure that there is a suitable ventilation system. Personal protective equipment: Avoid all unnecessary exposure. Hand protection: Protective gloves. EN 374

Eye protection: Chemical goggles or safety glasses. EN 166. Emergency eye wash fountains should be available in the immediate vicinity of any potential exposure

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Skin and body protection: Wear suitable protective clothing

Respiratory protection: Wear appropriate mask. EN 149 Personal protective equipment symbol(s):

Other information: Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Appearance Colour Odour Odour threshold pH Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 °C Relative density Solubility Partition coefficient n-octanol/water (Log Pow) Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits

: : : : : : : : : : : : : : : : : : : : : : : :

Solid Powders. Off-white. Characteristic odour. No data available 5.5-8.0 (10% Slurry) No data available 1650°C No data available No data available No data available No data available. No data available Non flammable. No data available No data available. 2.2 Insoluble. No data available No data available No data available No data available No data available No data available

9.2. Other information No additional information available

SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available

10.2. Chemical stability Not established.

10.3. Possibility of hazardous reactions Not established. 08/01/2021 (Version: 3.0)

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10.4. Conditions to avoid Direct sunlight. Moisture.

10.5. Incompatible materials No additional information available

10.6. Hazardous decomposition products No additional information available

SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation)

: Not classified : Not classified : Not classified

Skin corrosion/irritation

Additional information Respiratory or skin sensitisation Additional information Germ cell mutagenicity Additional information Carcinogenicity Additional information

: Not classified pH: 5.5-8.0 (10% Slurry) : Based on available data, the classification criteria are not met : Not classified pH: 5.5-8.0 (10% Slurry) : Based on available data, the classification criteria are not met : Not classified : Based on available data, the classification criteria are not met : Not classified : Based on available data, the classification criteria are not met : Not classified : Based on available data, the classification criteria are not met

Reproductive toxicity Additional information

: Not classified : Based on available data, the classification criteria are not met

STOT-single exposure Additional information

: Not classified : Based on available data, the classification criteria are not met

STOT-repeated exposure Additional information

: Not classified : Based on available data, the classification criteria are not met

Aspiration hazard Additional information

: Not classified : Based on available data, the classification criteria are not met

Potential adverse human health effects and symptoms

: Based on available data, the classification criteria are not met.

Additional information Serious eye damage/irritation

SECTION 12: Ecological information 12.1. Toxicity Hazardous to the aquatic environment, short-term (acute) Hazardous to the aquatic environment, long-term (chronic)

: Not classified : Not classified

12.2. Persistence and degradability REMET FUSED SILICA (ALL GRADES) Persistence and degradability

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Not established.

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12.3. Bioaccumulative potential REMET FUSED SILICA (ALL GRADES) Bioaccumulative potential

Not established.

12.4. Mobility in soil No additional information available

12.5. Results of PBT and vPvB assessment No additional information available

12.6. Other adverse effects Additional information

: Avoid release to the environment.

SECTION 13: Disposal considerations 13.1. Waste treatment methods Product/Packaging disposal recommendations Ecology - waste materials

: Dispose in a safe manner in accordance with local/national regulations. : Avoid release to the environment.

SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN

ADR

IMDG

IATA

ADN

RID

Not applicable

14.1. UN number UN -

14.2. UN proper shipping name Not applicable

Not applicable

14.3. Transport hazard class(es) Not applicable

14.4. Packing group Not applicable

14.5. Environmental hazards Dangerous for the environment : No

No supplementary information available

14.6. Special precautions for user Overland transport No data available Transport by sea Not applicable Air transport Not applicable Inland waterway transport Not applicable Rail transport Not applicable

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14.7. Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable

SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances Contains no substance subject to Regulation (EU) No 649/2012 of the European Parliament and of the Council of 4 July 2012 concerning the export and import of hazardous chemicals. Contains no substance subject to Regulation (EU) No 2019/1021 of the European Parliament and of the Council of 20 June 2019 on persistent organic pollutants 15.1.2. National regulations No additional information available

15.2. Chemical safety assessment No chemical safety assessment has been carried out

SECTION 16: Other information Data sources

Other information

: REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. : A safety data sheet is not required for this product under Article 31 of REACH. This Product Safety Information Sheet has been created on a voluntary basis. Austria - Vergiftungsinformationszentrale (Poisons Information Centre) Tel: +43 1 406 43 43. Belgium - Centre Antipoisons-Antigifcentrum Tel: +32 70245245. Crotia - Poison Control Centre Zagreb Tel: +385 1 2348342. Czech Republic - Toxicological Information Centre Tel: +420 224 919 293. Denmark Poison Information Center Tel: +45 82 12 12 12. France - Centre Antipoison et de Toxicovigilance de Angers Tel: +33 2 41 35 33 30. Germany - + 49 (0) 231 9071 2971. Hungary - Tel: +36 80 20 11 99. Ireland - Poisons Information Centre of Ireland Tel: +353 1 837 9964. Italy - +39 06 59 94 37 33. Netherlands - Nationaal Vergiftigingen Informatie Centrum (NVIC), de Nederland Tel: +31 30 274 88 88. Poland - +48 42 63 14 724. Portugal - CIAV - Centro de Informaçao Antivenenos Tel: +351 808 250 143. Slovakia - National Toxicological Information Center Tel: +421 2 54 774 166. Spain - Instituto Nacional de Toxicologia Tel: +34 156 20420. Sweden - Giftinformationscentralen (Swedish Poisons Information Centre) Tel: +46 8 33 12 31 / 112.

Full text of H- and EUH-statements: EUH210

Safety data sheet available on request.

SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

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SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name

Ranco-Sil (TM) fused silica [NA]

1.2. Relevant identified uses of the substance or mixture and uses advised against Description

Foundry material.

1.3. Details of the supplier of the safety data sheet Company

Ransom & Randolph

Address

3535 Briarfield Boulevard, PO Box 1570 Maumee, Ohio 43537 USA

Web

www.ransom-randolph.com

Telephone

+1 (419) 865-9497

Fax

+1 (419) 865-9997

SDS@ransom-randolph.com

Email address of the competent person

dyouel@ransom-randolph.com

1.4. Emergency telephone number Emergency telephone number

USA +1 419 865 9497

Company

Ransom & Randolph Co. 08:00-17:00 (US Eastern Std. / GMT minus 5)

SECTION 2: Hazards identification 2.1. Classification of the substance or mixture 2.1.2. Classification - EC 1272/2008

Carc. 1A: H350;

Signal Word

Danger

Hazard Statement

Carc. 1A: H350 - May cause cancer inhalation.

Precautionary Statement: Prevention

Precautionary Statement: Response

P308+P313 - IF exposed or concerned: Get medical advice/attention.

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2.2. Label elements Precautionary Statement: Storage

P405 - Store locked up.

Precautionary Statement: Disposal

P501 - Dispose of contents/container to local and national regulations

2.3. Other hazards Other hazards

Portions of the amorphous silica may be converted to crystalline silica (cristobalite) when subjected to higher temperatures (1700° F / 927° C), such as when used in a mold for ferrous and other high temperature alloy castings. The exposure to crystalline silica is highest at the mold knockout stage of the casting process. Based on available data, the classification criteria are not met. PBT and vPvB assessment. Product contains crystalline silica.

SECTION 3: Composition/information on ingredients 3.2. Mixtures EC 1272/2008 Chemical Name

Index No.

REACH Registration Number

Conc. Classification (%w/w) 90 - 100%

CAS No.

EC No.

silica, viterous -- Overall product (Silica, fused respirable dust) quartz ( conc. < 1.0% )

60676-86-0

262-373-8

14808-60-7

238-878-4

0 - 0.5% Carc. 1A: H350;

Silica (cristobalite ) >/= 0.1 % conc. < 1.0 %

14464-46-1

238-455-4

0 - 0.5% Carc. 1A: H350;

Further information Full text for all Risk Phrases mentioned in this section are displayed in Section 16.

SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation

Move the exposed person to fresh air.

Eye contact

Rinse immediately with plenty of water for 15 minutes holding the eyelids open.

Skin contact

Wash with soap and water.

Ingestion

Drink 1 to 2 glasses of water. DO NOT INDUCE VOMITING.

4.2. Most important symptoms and effects, both acute and delayed Inhalation

May cause irritation to respiratory system.

Eye contact

May cause irritation to eyes.

Skin contact

May cause irritation to skin.

Ingestion

May cause irritation to mucous membranes.

4.3. Indication of any immediate medical attention and special treatment needed Inhalation

Seek medical attention if irritation or symptoms persist.

Eye contact

Seek medical attention if irritation or symptoms persist.

Skin contact

Seek medical attention if irritation or symptoms persist.

Ingestion

Seek medical attention if irritation or symptoms persist.

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5.2. Special hazards arising from the substance or mixture Burning produces irritating, toxic and obnoxious fumes. 5.3. Advice for firefighters Self-contained breathing apparatus. Wear suitable protective clothing.

SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid raising dust. Wear suitable respiratory equipment when necessary. 6.2. Environmental precautions No environmental requirements. 6.3. Methods and material for containment and cleaning up Avoid raising dust. Clean the area using a vacuum cleaner. Transfer to suitable, labelled containers for disposal. 6.4. Reference to other sections See section [2, 8 & 13] for further information.

SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid raising dust. Ensure adequate ventilation of the working area. In case of insufficient ventilation, wear suitable respiratory equipment. Do not eat, drink or smoke in areas where this product is used or stored. Wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Keep containers tightly closed. 7.3. Specific end use(s) Foundry material.

SECTION 8: Exposure controls/personal protection 8.1. Control parameters exposure limits - Silica, vitreous (fused, amorphous) 80 mg/m3 / (% Silica), TWA PEL (respirable fraction). exposure limits - Crystalline Silica, quartz 0.025 mg/m3 TWA ACGIH TLV (respirable fraction); 50 ug/m3 8 hr -TWA PEL (respirable fraction). exposure limits - Crystalline Silica, Cristobalite 0.025 mg/m3 TWA ACGIH TLV (respirable fraction); 50 ug/m3 8-hr TWA PEL (respirable fraction). 8.1.1. Exposure Limit Values silica, viterous -- Overall product (Silica, fused respirable dust)

WEL 8-hr limit ppm: -

WEL 8-hr limit mg/m3: 0.08

WEL 15 min limit ppm: -

WEL 15 min limit mg/m3: -

WEL 8-hr limit mg/m3 total inhalable dust: WEL 8-hr limit mg/m3 total respirable dust:

WEL 15 min limit mg/m3 total inhalable dust: WEL 15 min limit mg/m3 total respirable dust:

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8.2. Exposure controls

8.2.1. Appropriate engineering controls

Ensure adequate ventilation of the working area.

8.2.2. Individual protection measures

Protective clothing.

Eye / face protection

In case of splashing, wear:. Approved safety goggles. safety glasses with side-shields.

Skin protection Handprotection

Wear suitable gloves.

Respiratory protection

Suitable respiratory equipment.

8.2.3. Environmental exposure controls

Not normally required.

Occupational exposure controls

Appropriate local exhaust ventilation is required.

SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Powder Colour Off white Odour Odourless pH 4.5 - 7 Melting point No data available Freezing Point Not applicable. Initial boiling point Not applicable. Flash point Not applicable. Evaporation rate Not applicable. Flammability (solid, gas) Not applicable. Vapour pressure Not applicable. Vapour density Not applicable. Relative density 2.2 (H2O = 1 @ 20 °C) Fat Solubility Not applicable. Partition coefficient Not applicable. Autoignition temperature Not applicable. Viscosity No data available Explosive properties Not applicable. Oxidising properties Not applicable.

9.2. Other information Conductivity No data available Surface tension No data available Gas group Not applicable. Benzene Content No data available Lead content Not applicable. VOC (Volatile organic Not applicable. compounds)

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10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions No Significant Hazard. 10.5. Incompatible materials No Significant Hazard. 10.6. Hazardous decomposition products None.

SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity

Harmful by inhalation.

Skin corrosion/irritation

Prolonged or repeated exposure may cause irritation to skin and mucous membranes.

Respiratory or skin sensitisation

No sensitizaton effects reported.

Germ cell mutagenicity

No mutagenic effects reported.

Carcinogenicity

Known Human Carcinogens (Category 1).

Reproductive toxicity

No observed effect level. No observed effect concentration.

STOT-single exposure

No known adverse health effects.

STOT-repeated exposure

Chronic effects Prolonged inhalation of respirable crystalline silica In 1997, the International Agency for Research on Cancer (IARC) concluded that crystalline silica inhaled from occupational sources can cause lung cancer in humans. However it pointed out that not all industrial circumstances, nor all crystalline silica types, were to be incriminated. (IARC Monographs on the evaluation of the carcinogenic risks of chemicals to humans, Silica, silicates dust and organic fibers, 1997, Vol. 68, IARC, Lyon, France). In June 2003, the European Commission's Scientific Committee for Occupational Exposure Limits (SCOEL) concluded: "that the main effect in humans of the inhalation of respirable crystalline silica is silicosis. There is sufficient information to conclude that the relative lung cancer risk is increased in persons with silicosis (and apparently, not in employees without silicosis exposed to silica dust in quarries and in the ceramic industry). Therefore, preventing the onset of silicosis will also reduce the cancer risk. Since a clear threshold for silicosis development cannot be identified, any reduction of exposure will reduce the risk of silicosis." (SCOEL SUM Doc 94-final on respirable crystalline silica, June 2003) There is a body of evidence supporting the fact that increased cancer risk would be limited to people already suffering from silicosis. Worker protection against silicosis should be assured by respecting the existing regulatory occupational exposure limits and implementing additional risk management measures where required (see Section 16).

Aspiration hazard

No Significant Hazard.

Repeated or prolonged exposure

Inhalation may cause coughing, tightness of the chest and irritation of the respiratory system.

SECTION 12: Ecological information 12.1. Toxicity Not relevant 12.2. Persistence and degradability No data is available on this product. 12.3. Bioaccumulative potential

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12.3. Bioaccumulative potential Does not bioaccumulate. Partition coefficient Ranco-Sil (TM) fused silica Not applicable. [NA]

12.4. Mobility in soil Not determined. 12.5. Results of PBT and vPvB assessment Not determined. 12.6. Other adverse effects Not applicable.

SECTION 13: Disposal considerations 13.1. Waste treatment methods Dispose of in compliance with all. local and national regulations. Disposal methods Contact a licensed waste disposal company. Disposal of packaging Empty containers can be sent for disposal or recycling.

SECTION 14: Transport information 14.1. UN number The product is not classified as dangerous for carriage. 14.2. UN proper shipping name The product is not classified as dangerous for carriage. 14.3. Transport hazard class(es) The product is not classified as dangerous for carriage. 14.4. Packing group The product is not classified as dangerous for carriage. 14.5. Environmental hazards The product is not classified as dangerous for carriage. 14.6. Special precautions for user The product is not classified as dangerous for carriage. 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code The product is not classified as dangerous for carriage. Further information The product is not classified as dangerous for carriage.

SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Regulations

U.S. FEDERAL REGULATIONS: RANCO-SIL. CERCLA 103 Reportable Quantity: is not subject to CERCLA reporting requirements. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. SARA TITLE III:

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15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Hazard Category For Section 311/312: Chronic health Section 313 Toxic Chemicals: This product contains the following chemicals subject to Annual Release Reporting Requirements Under SARA Title III, Section 313 (40 CFR 372): None Section 302 Extremely Hazardous Substances (TPQ): None EPA Toxic Substances Control Act (TSCA) Status: All of the components of this product are listed on the TSCA inventory. U.S. STATE REGULATIONS California Proposition 65: This product contains the following substances known to the State of California to cause cancer: Crystalline Silica as Quartz (<1%) and as cistobalite (<1%) INTERNATIONAL REGULATIONS: Canadian Environmental Protection Act: All of the components in this product are listed on the Domestic Substances List (DSL). Canadian WHMIS Classification: Class D Division 2A (quartz) European Inventory of New and Existing Chemicals Substances (EINECS): All of the components in this product are listed on the EINECS inventory. Australian Inventory of Chemical Substances: All of the components in this product are listed on the AICS for Australia. China Inventory of Existing Chemicals and Chemical Substances: All of the components in this product are listed on the IECSC for China. Japanese Existing and New Chemical Substances: All of the components in this product are listed on the Japanese ENCS list. Korean Existing Chemicals List: All of the components in this product are listed on the KECL for Korea. Philippine Inventory of Chemicals and Chemical Substances: All of the components in this product are listed on the PICCS. 15.2. Chemical safety assessment No data is available on this product.

SECTION 16: Other information Other information Text of Hazard Statements in Section 3

Carc. 1A: H350 - May cause cancer .

Further information Training Workers must be informed of the presence of crystalline silica and trained in the proper use and handling of this product as required under applicable regulations. The information supplied in this Safety Data Sheet is designed only as guidance for the safe use, storage and handling of the product. This information is correct to the best of our knowledge and belief at the date of publication however no guarantee is made to its accuracy. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process.

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SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name

Ranco-Sil (TM) fused silica [NA]

1.2. Relevant identified uses of the substance or mixture and uses advised against Description

Foundry material.

1.3. Details of the supplier of the safety data sheet Company

Ransom & Randolph

Address

3535 Briarfield Boulevard, PO Box 1570 Maumee, Ohio 43537 USA

Web

www.ransom-randolph.com

Telephone

+1 (419) 865-9497

Fax

+1 (419) 865-9997

SDS@ransom-randolph.com

Email address of the competent person

dyouel@ransom-randolph.com

1.4. Emergency telephone number Emergency telephone number

USA +1 419 865 9497

Company

Ransom & Randolph Co. 08:00-17:00 (US Eastern Std. / GMT minus 5)

SECTION 2: Hazards identification 2.1. Classification of the substance or mixture 2.1.2. Classification - EC 1272/2008

Carc. 1A: H350;

Signal Word

Danger

Hazard Statement

Carc. 1A: H350 - May cause cancer inhalation.

Precautionary Statement: Prevention

Precautionary Statement: Response

P308+P313 - IF exposed or concerned: Get medical advice/attention.

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2.2. Label elements Precautionary Statement: Storage

P405 - Store locked up.

Precautionary Statement: Disposal

P501 - Dispose of contents/container to local and national regulations

2.3. Other hazards Other hazards

SECTION 3: Composition/information on ingredients 3.2. Mixtures EC 1272/2008 Chemical Name

Index No.

REACH Registration Number

Conc. Classification (%w/w) 90 - 100%

CAS No.

EC No.

silica, viterous -- Overall product (Silica, fused respirable dust) quartz ( conc. < 1.0% )

60676-86-0

262-373-8

14808-60-7

238-878-4

0 - 0.5% Carc. 1A: H350;

Silica (cristobalite ) >/= 0.1 % conc. < 1.0 %

14464-46-1

238-455-4

0 - 0.5% Carc. 1A: H350;

Further information Full text for all Risk Phrases mentioned in this section are displayed in Section 16.

SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation

Move the exposed person to fresh air.

Eye contact

Rinse immediately with plenty of water for 15 minutes holding the eyelids open.

Skin contact

Wash with soap and water.

Ingestion

Drink 1 to 2 glasses of water. DO NOT INDUCE VOMITING.

4.2. Most important symptoms and effects, both acute and delayed Inhalation

May cause irritation to respiratory system.

Eye contact

May cause irritation to eyes.

Skin contact

May cause irritation to skin.

Ingestion

May cause irritation to mucous membranes.

4.3. Indication of any immediate medical attention and special treatment needed Inhalation

Seek medical attention if irritation or symptoms persist.

Eye contact

Seek medical attention if irritation or symptoms persist.

Skin contact

Seek medical attention if irritation or symptoms persist.

Ingestion

Seek medical attention if irritation or symptoms persist.

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WEL 8-hr limit ppm: -

WEL 8-hr limit mg/m3: 0.08

WEL 15 min limit ppm: -

WEL 15 min limit mg/m3: -

WEL 8-hr limit mg/m3 total inhalable dust: WEL 8-hr limit mg/m3 total respirable dust:

WEL 15 min limit mg/m3 total inhalable dust: WEL 15 min limit mg/m3 total respirable dust:

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8.2. Exposure controls

8.2.1. Appropriate engineering controls

Ensure adequate ventilation of the working area.

8.2.2. Individual protection measures

Protective clothing.

Eye / face protection

In case of splashing, wear:. Approved safety goggles. safety glasses with side-shields.

Skin protection Handprotection

Wear suitable gloves.

Respiratory protection

Suitable respiratory equipment.

8.2.3. Environmental exposure controls

Not normally required.

Occupational exposure controls

Appropriate local exhaust ventilation is required.

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SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity

Harmful by inhalation.

Skin corrosion/irritation

Prolonged or repeated exposure may cause irritation to skin and mucous membranes.

Respiratory or skin sensitisation

No sensitizaton effects reported.

Germ cell mutagenicity

No mutagenic effects reported.

Carcinogenicity

Known Human Carcinogens (Category 1).

Reproductive toxicity

No observed effect level. No observed effect concentration.

STOT-single exposure

No known adverse health effects.

STOT-repeated exposure

Aspiration hazard

No Significant Hazard.

Repeated or prolonged exposure

Inhalation may cause coughing, tightness of the chest and irritation of the respiratory system.

SECTION 12: Ecological information 12.1. Toxicity Not relevant 12.2. Persistence and degradability No data is available on this product. 12.3. Bioaccumulative potential

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12.3. Bioaccumulative potential Does not bioaccumulate. Partition coefficient Ranco-Sil (TM) fused silica Not applicable. [NA]

12.4. Mobility in soil Not determined. 12.5. Results of PBT and vPvB assessment Not determined. 12.6. Other adverse effects Not applicable.

SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Regulations

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SECTION 16: Other information Other information Text of Hazard Statements in Section 3

Carc. 1A: H350 - May cause cancer .

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2.2. Label elements Precautionary Statement: Storage

P405 - Store locked up.

Precautionary Statement: Disposal

P501 - Dispose of contents/container to local and national regulations

2.3. Other hazards Other hazards

SECTION 3: Composition/information on ingredients 3.2. Mixtures EC 1272/2008 Chemical Name

Index No.

REACH Registration Number

Conc. Classification (%w/w) 90 - 100%

CAS No.

EC No.

silica, viterous -- Overall product (Silica, fused respirable dust) quartz ( conc. < 1.0% )

60676-86-0

262-373-8

14808-60-7

238-878-4

0 - 0.5% Carc. 1A: H350;

Silica (cristobalite ) >/= 0.1 % conc. < 1.0 %

14464-46-1

238-455-4

0 - 0.5% Carc. 1A: H350;

Further information Full text for all Risk Phrases mentioned in this section are displayed in Section 16.

SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation

Move the exposed person to fresh air.

Eye contact

Rinse immediately with plenty of water for 15 minutes holding the eyelids open.

Skin contact

Wash with soap and water.

Ingestion

Drink 1 to 2 glasses of water. DO NOT INDUCE VOMITING.

4.2. Most important symptoms and effects, both acute and delayed Inhalation

May cause irritation to respiratory system.

Eye contact

May cause irritation to eyes.

Skin contact

May cause irritation to skin.

Ingestion

May cause irritation to mucous membranes.

4.3. Indication of any immediate medical attention and special treatment needed Inhalation

Seek medical attention if irritation or symptoms persist.

Eye contact

Seek medical attention if irritation or symptoms persist.

Skin contact

Seek medical attention if irritation or symptoms persist.

Ingestion

Seek medical attention if irritation or symptoms persist.

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WEL 8-hr limit ppm: -

WEL 8-hr limit mg/m3: 0.08

WEL 15 min limit ppm: -

WEL 15 min limit mg/m3: -

WEL 8-hr limit mg/m3 total inhalable dust: WEL 8-hr limit mg/m3 total respirable dust:

WEL 15 min limit mg/m3 total inhalable dust: WEL 15 min limit mg/m3 total respirable dust:

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8.2. Exposure controls

8.2.1. Appropriate engineering controls

Ensure adequate ventilation of the working area.

8.2.2. Individual protection measures

Protective clothing.

Eye / face protection

In case of splashing, wear:. Approved safety goggles. safety glasses with side-shields.

Skin protection Handprotection

Wear suitable gloves.

Respiratory protection

Suitable respiratory equipment.

8.2.3. Environmental exposure controls

Not normally required.

Occupational exposure controls

Appropriate local exhaust ventilation is required.

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SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity

Harmful by inhalation.

Skin corrosion/irritation

Prolonged or repeated exposure may cause irritation to skin and mucous membranes.

Respiratory or skin sensitisation

No sensitizaton effects reported.

Germ cell mutagenicity

No mutagenic effects reported.

Carcinogenicity

Known Human Carcinogens (Category 1).

Reproductive toxicity

No observed effect level. No observed effect concentration.

STOT-single exposure

No known adverse health effects.

STOT-repeated exposure

Aspiration hazard

No Significant Hazard.

Repeated or prolonged exposure

Inhalation may cause coughing, tightness of the chest and irritation of the respiratory system.

SECTION 12: Ecological information 12.1. Toxicity Not relevant 12.2. Persistence and degradability No data is available on this product. 12.3. Bioaccumulative potential

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12.3. Bioaccumulative potential Does not bioaccumulate. Partition coefficient Ranco-Sil (TM) fused silica Not applicable. [NA]

12.4. Mobility in soil Not determined. 12.5. Results of PBT and vPvB assessment Not determined. 12.6. Other adverse effects Not applicable.

SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Regulations

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SECTION 16: Other information Other information Text of Hazard Statements in Section 3

Carc. 1A: H350 - May cause cancer .

Print date 2021-07-21

SAFETY DATA SHEET

according to Regulation (EU) 2015/830 Page

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SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name

SuspendaSlurry FS material

Product code

SuspendaSlurry FS material 021017 R480

1.2. Relevant identified uses of the substance or mixture and uses advised against Description

Foundry material.

1.3. Details of the supplier of the safety data sheet Company

Ransom & Randolph

Address

3535 Briarfield Boulevard, PO Box 1570 Maumee, Ohio 43537 USA

Web

www.ransom-randolph.com

Telephone

+1 (419) 865-9497

Fax

+1 (419) 865-9997

RR.SDS@dentsply.com

Email address of the competent person

RR.SDS@dentsply.com

1.4. Emergency telephone number Emergency telephone number

USA +1 419 865 9497

Company

Ransom & Randolph Co. 07:30 to 16:30 (Eastern Std. / GMT minus 5)

SECTION 2: Hazards identification 2.1. Classification of the substance or mixture 2.1.2. Classification - EC 1272/2008

Carc. 1A: H350;

2.2. Label elements This substance / mixture has been classified in accordance with the US Federal OSHA Hazard Communication Standard 29CFR 1910.1200. Substance concentration band-ranges are presented, and minor ingredient compostion maybe wihtheld, to protect trade secrets. Hazard pictograms

Signal Word

Danger

Hazard Statement

Carc. 1A: H350 - May cause cancer inhalation.

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2.2. Label elements Precautionary Statement: Prevention

Precautionary Statement: Response

P308+P313 - IF exposed or concerned: Get medical advice/attention.

Precautionary Statement: Storage

P405 - Store locked up.

Precautionary Statement: Disposal

P501 - Dispose of contents/container to local and national regulations

2.3. Other hazards Other hazards

This LIQUID product contains less than one-percent (<1%) crystalline silica. Amorphous silica may be converted to crystalline silica (cristobalite) when subjected to very high temperatures (1700° F). Exposure to respirable crystalline silica may cause lung disease.

Further information Not applicable. PBT and vPvB assessment.

SECTION 3: Composition/information on ingredients 3.2. Mixtures EC 1272/2008 Chemical Name

Index No.

REACH Registration Number

Conc. Classification (%w/w) 50 - 60%

CAS No.

EC No.

silica, viterous -- Overall product (Silica, fused respirable dust) quartz (conc. >/= 1.0% )

60676-86-0

262-373-8

14808-60-7

238-878-4

quartz ( conc. < 1.0% )

14808-60-7

238-878-4

0 - 0.5% Carc. 1A: H350; STOT RE 1: H372; 0.5 - 1% Carc. 1A: H350;

Silica (cristobalite ) >/= 0.1 % conc. < 1.0 %

14464-46-1

238-455-4

0.5 - 1% Carc. 1A: H350;

Further information Full text for all Risk Phrases mentioned in this section are displayed in Section 16.

SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation

Move the exposed person to fresh air.

Eye contact

Rinse immediately with plenty of water for 15 minutes holding the eyelids open.

Skin contact

Wash with soap and water.

Ingestion

Drink 1 to 2 glasses of water. DO NOT INDUCE VOMITING.

4.2. Most important symptoms and effects, both acute and delayed Inhalation

May cause irritation to respiratory system.

Eye contact

May cause irritation to eyes.

Skin contact

May cause irritation to skin.

Ingestion

May cause irritation to mucous membranes.

Seek medical attention if irritation or symptoms persist. Powered by

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4.3. Indication of any immediate medical attention and special treatment needed Eye contact

Seek medical attention if irritation or symptoms persist.

Skin contact

Seek medical attention if irritation or symptoms persist.

Ingestion

Seek medical attention if irritation or symptoms persist.

SECTION 5: Firefighting measures 5.1. Extinguishing media Use extinguishing media appropriate to the surrounding fire conditions. 5.2. Special hazards arising from the substance or mixture Burning produces irritating, toxic and obnoxious fumes. 5.3. Advice for firefighters Self-contained breathing apparatus. Wear suitable protective clothing.

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8.1.1. Exposure Limit Values WEL 8-hr limit ppm: -

silica, viterous -- Overall product (Silica, fused respirable dust)

WEL 8-hr limit mg/m3: 0.08

WEL 15 min limit ppm: -

WEL 15 min limit mg/m3: -

WEL 8-hr limit mg/m3 total inhalable dust: WEL 8-hr limit mg/m3 total respirable dust:

WEL 15 min limit mg/m3 total inhalable dust: WEL 15 min limit mg/m3 total respirable dust:

8.2. Exposure controls

8.2.1. Appropriate engineering controls

Ensure adequate ventilation of the working area.

8.2.2. Individual protection measures

Protective clothing.

Eye / face protection

In case of splashing, wear:. Approved safety goggles. safety glasses with side-shields.

Skin protection Handprotection

Wear suitable gloves.

Respiratory protection

Suitable respiratory equipment.

8.2.3. Environmental exposure controls

Not normally required.

Occupational exposure controls

Appropriate local exhaust ventilation is required.

SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Viscous liquid. Colour Yellow Odour Slight pH 9 - 11 Relative density 1.2 - 1.8 (H2O = 1 @ 20 °C) Initial boiling point No data available Evaporation rate No data available Vapour pressure No data available Vapour density No data available Partition coefficient No data available Viscosity No data available Freezing Point ≈ 0 °C Fat Solubility Not applicable. Melting point Not applicable. Solubility Miscible in water

9.2. Other information

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9.2. Other information Conductivity No data available Surface tension No data available Gas group Not applicable. Benzene Content Not applicable. Lead content Not applicable. VOC (Volatile organic Not applicable. compounds)

SECTION 10: Stability and reactivity 10.1. Reactivity Not applicable. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions No Significant Hazard. 10.4. Conditions to avoid Moisture. 10.5. Incompatible materials No Significant Hazard. 10.6. Hazardous decomposition products Hazardous Decomposition Products (silica): Crystalline silica will dissolve in hydrofluoric acid and produce silicone tetrafluoride. Reaction with water or acids generates heat.

SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity

Based on available data, the classification criteria are not met.

Skin corrosion/irritation

Prolonged or repeated exposure may cause irritation to skin and mucous membranes.

Serious eye damage/irritation

No irritation expected.

Respiratory or skin sensitisation

No sensitizaton effects reported.

Germ cell mutagenicity

No mutagenic effects reported.

Carcinogenicity

Known Human Carcinogens (Category 1).

Reproductive toxicity

No observed effect level. No observed effect concentration.

STOT-single exposure

No known adverse health effects.

STOT-repeated exposure

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11.1. Information on toxicological effects silicosis (and apparently, not in employees without silicosis exposed to silica dust in quarries and in the ceramic industry). Therefore, preventing the onset of silicosis will also reduce the cancer risk. Since a clear threshold for silicosis development cannot be identified, any reduction of exposure will reduce the risk of silicosis." (SCOEL SUM Doc 94-final on respirable crystalline silica, June 2003) There is a body of evidence supporting the fact that increased cancer risk would be limited to people already suffering from silicosis. Worker protection against silicosis should be assured by respecting the existing regulatory occupational exposure limits and implementing additional risk management measures where required (see Section 16). Aspiration hazard

No Significant Hazard.

Repeated or prolonged exposure

Inhalation may cause coughing, tightness of the chest and irritation of the respiratory system.

11.1.4. Toxicological Information Not determined

SECTION 12: Ecological information 12.1. Toxicity Not determined 12.2. Persistence and degradability No data is available on this product. 12.3. Bioaccumulative potential Does not bioaccumulate. Partition coefficient SuspendaSlurry FS material No data available

12.4. Mobility in soil Not determined. 12.5. Results of PBT and vPvB assessment Not determined. 12.6. Other adverse effects Not applicable.

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14.1. UN number The product is not classified as dangerous for carriage. 14.2. UN proper shipping name The product is not classified as dangerous for carriage. 14.3. Transport hazard class(es) The product is not classified as dangerous for carriage. 14.4. Packing group The product is not classified as dangerous for carriage. 14.5. Environmental hazards The product is not classified as dangerous for carriage. 14.6. Special precautions for user The product is not classified as dangerous for carriage. 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code The product is not classified as dangerous for carriage. Further information The product is not classified as dangerous for carriage.

SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Regulations

U.S. FEDERAL REGULATIONS: Suspendaslurry ™. CERCLA 103 Reportable Quantity: is not subject to CERCLA reporting requirements. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. SARA TITLE III: Hazard Category For Section 311/312: None Section 313 Toxic Chemicals: This product contains the following chemicals subject to Annual Release Reporting Requirements Under SARA Title III, Section 313 (40 CFR 372): None Section 302 Extremely Hazardous Substances (TPQ): None EPA Toxic Substances Control Act (TSCA) Status: All of the components of this product are listed on the TSCA inventory. U.S. STATE REGULATIONS California Proposition 65: This product contains the following substances known to the State of California to cause cancer: Quartz < 1% INTERNATIONAL REGULATIONS: Canadian Environmental Protection Act: All of the components in this product are listed on the Domestic Substances List (DSL).

15.2. Chemical safety assessment No data is available on this product.

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Other information Revision

This document differs from the previous version in the following areas:. 2 - 2.2. Label elements.

Text of Hazard Statements in Section 3

Carc. 1A: H350 - May cause cancer . STOT RE 1: H372 - Causes damage to organs through prolonged or repeated exposure .

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MOULD DEPT

SAFETY DATA SHEET DOW CHEMICAL COMPANY LIMITED Safety Data Sheet according to Reg. (EU) No 2015/830 Product name: SILASTIC™ RTV-3481 Mould-Making Base

Revision Date: 28.08.2018 Version: 3.0 Date of last issue: 16.02.2018 Print Date: 10.10.2018 DOW CHEMICAL COMPANY LIMITED encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions.

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product identifier Product name: SILASTIC™ RTV-3481 Mould-Making Base 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses: Polymer 1.3 Details of the supplier of the safety data sheet COMPANY IDENTIFICATION DOW CHEMICAL COMPANY LIMITED STATION ROAD, BIRCH VALE, HIGH PEAK DERBYSHIRE England SK22 1BR UNITED KINGDOM Customer Information Number: Fax:

+44 (0) 1663 746518 SDSQuestion@dow.com +44 (0) 1663 746605

1.4 EMERGENCY TELEPHONE NUMBER 24-Hour Emergency Contact: 0031 115 694 982 Local Emergency Contact: 00 31 115 69 4982

SECTION 2: HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008: Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008. 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008: Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.

® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated company of Dow

Page 1 of 18

Product name: SILASTIC™ RTV-3481 Mould-Making Base

Revision Date: 28.08.2018 Version: 3.0

Supplemental information EUH210 Safety data sheet available on request. 2.3 Other hazards This product contains dodecamethylcyclohexasiloxane (D6) that has been identified by the Member State Committee of ECHA as fulfilling the vPvB criteria laid down in Annex XIII to Regulation (EC) No 1907/2006. See Section 12 for additional information. This product contains decamethylcyclopentasiloxane (D5) that has been identified by the Member State Committee of ECHA as fulfilling the vPvB criteria laid down in Annex XIII to Regulation (EC) No 1907/2006. See Section 12 for additional information. This product contains octamethylcyclotetrasiloxane (D4) that has been identified by the Member State Committee of ECHA as fulfilling the PBT and vPvB criteria laid down in Annex XIII to Regulation (EC) No 1907/2006. See Section 12 for additional information.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature: Silicone elastomer 3.2 Mixtures This product is a mixture. CASRN / EC-No. / Index-No.

REACH Registration Number

Concentration

PBT and vPvB substance CASRN _ >= 0.37 - <= 0.51 % 540-97-6 EC-No. 208-762-8 Index-No. – CASRN _ >= 0.14 - <= 0.2 % 541-02-6 EC-No. 208-764-9 Index-No. – CASRN _ >= 0.14 - <= 0.2 % 556-67-2 EC-No. 209-136-7 Index-No. 014-018-00-1 Substances with a workplace exposure limit

Component

Dodecamethyl cyclohexasiloxane

Classification: REGULATION (EC) No 1272/2008

Not classified

Decamethylcyclope Not classified ntasiloxane

octamethylcyclotetr Flam. Liq. - 3 - H226 asiloxane Repr. - 2 - H361f Aquatic Chronic - 4 - H413

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Product name: SILASTIC™ RTV-3481 Mould-Making Base

Revision Date: 28.08.2018 Version: 3.0

CASRN _ >= 9.0 - <= 13.0 % Zircon Not classified 14940-68-2 EC-No. 239-019-6 Index-No. – For the full text of the H-Statements mentioned in this Section, see Section 16.

SECTION 4: FIRST AID MEASURES 4.1 Description of first aid measures General advice: If potential for exposure exists refer to Section 8 for specific personal protective equipment. Inhalation: Move person to fresh air; if effects occur, consult a physician. Skin contact: Wash off with plenty of water. Eye contact: Flush eyes thoroughly with water for several minutes. Remove contact lenses after the initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a physician, preferably an ophthalmologist. Ingestion: No emergency medical treatment necessary. 4.2 Most important symptoms and effects, both acute and delayed: Aside from the information found under Description of first aid measures (above) and Indication of immediate medical attention and special treatment needed (below), any additional important symptoms and effects are described in Section 11: Toxicology Information. 4.3 Indication of any immediate medical attention and special treatment needed Notes to physician: No specific antidote. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient.

SECTION 5: FIREFIGHTING MEASURES 5.1 Extinguishing media Suitable extinguishing media: Water spray Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing media: None known. 5.2 Special hazards arising from the substance or mixture Hazardous combustion products: Carbon oxides Silicon oxides Unusual Fire and Explosion Hazards: Exposure to combustion products may be a hazard to health.

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Product name: SILASTIC™ RTV-3481 Mould-Making Base

Revision Date: 28.08.2018 Version: 3.0

5.3 Advice for firefighters Fire Fighting Procedures: Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Remove undamaged containers from fire area if it is safe to do so. Evacuate area. Special protective equipment for firefighters: In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.

SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Follow safe handling advice and personal protective equipment recommendations. 6.2 Environmental precautions: Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. 6.3 Methods and materials for containment and cleaning up: Soak up with inert absorbent material. Clean up remaining materials from spill with suitable absorbant. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. For large spills, provide dyking or other appropriate containment to keep material from spreading. If dyked material can be pumped, Sections 13 and 15 of this SDS provide information regarding certain local or national requirements. 6.4 Reference to other sections: See sections: 7, 8, 11, 12 and 13.

SECTION 7: HANDLING AND STORAGE 7.1 Precautions for safe handling: Avoid inhalation of vapour or mist. Do not swallow. Avoid contact with eyes. Avoid prolonged or repeated contact with skin. Take care to prevent spills, waste and minimize release to the environment. Handle in accordance with good industrial hygiene and safety practice. Use only with adequate ventilation. See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. 7.2 Conditions for safe storage, including any incompatibilities: Keep in properly labelled containers. Store locked up. Store in accordance with the particular national regulations. Do not store with the following product types: Strong oxidizing agents. Unsuitable materials for containers: None known. 7.3 Specific end use(s): See the technical data sheet on this product for further information.

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Product name: SILASTIC™ RTV-3481 Mould-Making Base

Revision Date: 28.08.2018 Version: 3.0

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters If exposure limits exist, they are listed below. If no exposure limits are displayed, then no values are applicable. Component

Regulation

Decamethylcyclopentasiloxa ne octamethylcyclotetrasiloxane Zircon

Type of listing

Value/Notation

US WEEL

TWA

US WEEL ACGIH ACGIH GB EH40 GB EH40

TWA TWA STEL TWA STEL

10 ppm

5 mg/m3 10 mg/m3 5 mg/m3 10 mg/m3

10 ppm , Zirconium , Zirconium , Zirconium , Zirconium

Derived No Effect Level Dodecamethyl cyclohexasiloxane Workers Acute systemic effects

Acute local effects

Dermal

Inhalation

Dermal

n.a.

Inhalation 6.1 mg/m3

Long-term systemic effects

Long-term local effects

Dermal

n.a.

Inhalation 11 mg/m3

n.a.

Inhalation 1.22 mg/m3

Consumers Acute systemic effects Dermal n.a.

Inhalation n.a.

Acute local effects

Oral

1.7 mg/kg bw/day

Dermal n.a.

Inhalation

1.5 mg/m3

Long-term systemic effects Dermal n.a.

Inhalation

Oral

2.7 mg/m3

1.7 mg/kg bw/day

Long-term local effects Dermal Inhalation n.a. 0.3

mg/m3

Decamethylcyclopentasiloxane Workers Acute systemic effects

Dermal

Acute local effects

Inhalation 97.3 mg/m3

n.a.

Dermal n.a.

Inhalation 24.2 mg/m3

Long-term systemic effects

Long-term local effects

Dermal

n.a.

Inhalation 97.3 mg/m3

n.a.

Inhalation 24.2 mg/m3

Consumers Acute systemic effects Dermal n.a.

Acute local effects

Inhalation

Oral

17.3 mg/m3

5 mg/kg bw/day

Dermal n.a.

Inhalation

4.3 mg/m3

Long-term systemic effects Dermal n.a.

Inhalation

Oral

17.3 mg/m3

5 mg/kg bw/day

Long-term local effects Dermal Inhalation n.a. 4.3

mg/m3

octamethylcyclotetrasiloxane Workers Acute systemic effects

Dermal n.a.

Inhalation 73 mg/m3

Acute local effects

Dermal n.a.

Inhalation 73 mg/m3

Long-term systemic effects

Long-term local effects

Dermal

n.a.

Inhalation 73 mg/m3

n.a.

Inhalation 73 mg/m3

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Revision Date: 28.08.2018 Version: 3.0

Consumers Acute systemic effects Dermal n.a.

Inhalation

Oral

13 mg/m3

3.7 mg/kg bw/day

Acute local effects Dermal n.a.

Predicted No Effect Concentration Dodecamethyl cyclohexasiloxane Compartment Fresh water sediment Marine sediment Soil Sewage treatment plant

Inhalation

13 mg/m3

Long-term systemic effects Dermal n.a.

Inhalation

Oral

13 mg/m3

3.7 mg/kg bw/day

Long-term local effects Dermal Inhalation n.a. 13

mg/m3

PNEC 2.826 mg/kg 0.282 mg/kg 3.336 mg/kg > 1.0 mg/l

Decamethylcyclopentasiloxane Compartment Fresh water Marine water Fresh water sediment Marine sediment Soil Sewage treatment plant

PNEC > 0.0012 mg/l > 0.00012 mg/l 2.4 mg/kg 0.24 mg/kg 1.1 mg/kg > 10 mg/l

octamethylcyclotetrasiloxane Compartment Fresh water Marine water Fresh water sediment Marine sediment Soil Sewage treatment plant

PNEC 0.00044 mg/l 0.000044 mg/l 0.64 mg/kg 0.064 mg/kg 0.13 mg/kg > 10 mg/l

8.2 Exposure controls Engineering controls: Use local exhaust ventilation, or other engineering controls to maintain airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, general ventilation should be sufficient for most operations. Local exhaust ventilation may be necessary for some operations. Individual protection measures Eye/face protection: Use safety glasses (with side shields). Safety glasses (with side shields) should be consistent with EN 166 or equivalent. Skin protection Hand protection: Use gloves chemically resistant to this material when prolonged or frequently repeated contact could occur. Use chemical resistant gloves classified under Standard EN374: Protective gloves against chemicals and micro-organisms. Examples of preferred glove barrier materials include: Butyl rubber. Neoprene.

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Product name: SILASTIC™ RTV-3481 Mould-Making Base

Revision Date: 28.08.2018 Version: 3.0

Nitrile/butadiene rubber ("nitrile" or "NBR"). Ethyl vinyl alcohol laminate ("EVAL"). Polyvinyl alcohol ("PVA"). Polyvinyl chloride ("PVC" or "vinyl"). Viton. Examples of acceptable glove barrier materials include: Natural rubber ("latex"). When prolonged or frequently repeated contact may occur, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes according to EN 374) is recommended. Glove thickness alone is not a good indicator of the level of protection a glove provides against a chemical substance as this level of protection is also highly dependent on the specific composition of the material that the glove is fabricated from. The thickness of the glove must, depending on model and type of material, generally be more than 0.35 mm to offer sufficient protection for prolonged and frequent contact with the substance. As an exception to this general rule it is known that multilayer laminate gloves may offer prolonged protection at thicknesses less than 0.35 mm. Other glove materials with a thickness of less than 0.35 mm may offer sufficient protection when only brief contact is expected. NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier. Other protection: When prolonged or frequently repeated contact could occur, use protective clothing chemically resistant to this material. Selection of specific items such as faceshield, boots, apron, or full-body suit will depend on the task. Respiratory protection: Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, wear respiratory protection when adverse effects, such as respiratory irritation or discomfort have been experienced, or where indicated by your risk assessment process. For most conditions, no respiratory protection should be needed; however, if handling at elevated temperatures without sufficient ventilation, use an approved air-purifying respirator. Use the following CE approved air-purifying respirator: Organic vapor cartridge with a particulate pre-filter, type AP2 (meeting standard EN 14387). Environmental exposure controls See SECTION 7: Handling and storage and SECTION 13: Disposal considerations for measures to prevent excessive environmental exposure during use and waste disposal.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Appearance Physical state viscous liquid Color off-white Odor none Odor Threshold No data available pH No data available Melting point/range No data available Freezing point No data available Boiling point (760 mmHg) > 35 °C Flash point closed cup >100.0 °C

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Product name: SILASTIC™ RTV-3481 Mould-Making Base

Evaporation Rate (Butyl Acetate = 1) Flammability (solid, gas) Lower explosion limit Upper explosion limit Vapor Pressure Relative Vapor Density (air = 1) Relative Density (water = 1) Water solubility Partition coefficient: noctanol/water Auto-ignition temperature Decomposition temperature Dynamic Viscosity Kinematic Viscosity Explosive properties Oxidizing properties 9.2 Other information Molecular weight Particle size

Revision Date: 28.08.2018 Version: 3.0

No data available Not applicable No data available No data available No data available No data available 1.213 No data available No data available No data available No data available 34,000 mPa.s No data available Not explosive The substance or mixture is not classified as oxidizing.

No data available Not applicable

NOTE: The physical data presented above are typical values and should not be construed as a specification.

SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity: Not classified as a reactivity hazard. 10.2 Chemical stability: Stable under normal conditions. 10.3 Possibility of hazardous reactions: Can react with strong oxidizing agents. 10.4 Conditions to avoid: None known. 10.5 Incompatible materials: Oxidizing agents 10.6 Hazardous decomposition products: Formaldehyde.

SECTION 11: TOXICOLOGICAL INFORMATION Toxicological information appears in this section when such data is available. 11.1 Information on toxicological effects Acute toxicity Acute oral toxicity

Page 8 of 18

Product name: SILASTIC™ RTV-3481 Mould-Making Base

Revision Date: 28.08.2018 Version: 3.0

Very low toxicity if swallowed. Harmful effects not anticipated from swallowing small amounts. As product: Single dose oral LD50 has not been determined. Based on information for component(s): Estimated. LD50, Rat, > 5,000 mg/kg Acute dermal toxicity Prolonged skin contact is unlikely to result in absorption of harmful amounts. As product: The dermal LD50 has not been determined. Based on information for component(s): Estimated. LD50, > 2,000 mg/kg Acute inhalation toxicity At room temperature, exposure to vapor is minimal due to low volatility; vapor from heated material may cause respiratory irritation. As product: The LC50 has not been determined. Skin corrosion/irritation Prolonged exposure not likely to cause significant skin irritation. Serious eye damage/eye irritation May cause slight temporary eye irritation. Corneal injury is unlikely. May cause mild eye discomfort. Sensitization For skin sensitization: Contains component(s) which did not cause allergic skin sensitization in guinea pigs. For respiratory sensitization: No relevant information found. Specific Target Organ Systemic Toxicity (Single Exposure) The substance or mixture is not classified as specific target organ toxicant, single exposure. Specific Target Organ Systemic Toxicity (Repeated Exposure) Based on available data for the component(s), repeated exposures are not anticipated to cause significant adverse effects. Carcinogenicity Based on information for component(s): Did not cause cancer in long-term animal studies which used routes of exposure considered relevant to industrial handling. Positiveresults have been reported in other studies using routes of exposure not relevant to industrial handling. Teratogenicity Based on information for component(s): Did not cause birth defects or any other fetal effects in laboratory animals. Reproductive toxicity

Page 9 of 18

Product name: SILASTIC™ RTV-3481 Mould-Making Base

Revision Date: 28.08.2018 Version: 3.0

No relevant data found. Mutagenicity Based on information for component(s): In vitro genetic toxicity studies were negative. Animal genetic toxicity studies were negative. Aspiration Hazard Based on physical properties, not likely to be an aspiration hazard. COMPONENTS INFLUENCING TOXICOLOGY: Dodecamethyl cyclohexasiloxane Acute inhalation toxicity The LC50 has not been determined. Decamethylcyclopentasiloxane Acute inhalation toxicity LC50, Rat, male and female, 4 Hour, dust/mist, 8.67 mg/l octamethylcyclotetrasiloxane Acute inhalation toxicity LC50, Rat, male and female, 4 Hour, dust/mist, 36 mg/l OECD Test Guideline 403 Zircon Acute inhalation toxicity The LC50 has not been determined.

SECTION 12: ECOLOGICAL INFORMATION Ecotoxicological information appears in this section when such data is available. 12.1 Toxicity Dodecamethyl cyclohexasiloxane Acute toxicity to algae/aquatic plants Not expected to be acutely toxic to aquatic organisms. No toxicity at the limit of solubility ErC50, Pseudokirchneriella subcapitata (green algae), 72 Hour, > 0.002 mg/l Chronic toxicity to aquatic invertebrates No toxicity at the limit of solubility NOEC, Daphnia magna (Water flea), 21 d, 0.0046 mg/l Decamethylcyclopentasiloxane Acute toxicity to fish Not expected to be acutely toxic to aquatic organisms. No toxicity at the limit of solubility LC50, Oncorhynchus mykiss (rainbow trout), 96 Hour, > 16 µg/l, OECD Test Guideline 204 or Equivalent

Page 10 of 18

Product name: SILASTIC™ RTV-3481 Mould-Making Base

Revision Date: 28.08.2018 Version: 3.0

Acute toxicity to aquatic invertebrates No toxicity at the limit of solubility EC50, Daphnia magna, 48 Hour, > 2.9 mg/l, OECD Test Guideline 202 or Equivalent Acute toxicity to algae/aquatic plants No toxicity at the limit of solubility ErC50, Pseudokirchneriella subcapitata (green algae), 96 Hour, Growth rate, > 0.012 mg/l No toxicity at the limit of solubility NOEC, Pseudokirchneriella subcapitata (green algae), 96 Hour, Growth rate, 0.012 mg/l Chronic toxicity to fish No toxicity at the limit of solubility LC50, Oncorhynchus mykiss (rainbow trout), 14 d, > 16 mg/l No toxicity at the limit of solubility NOEC, Oncorhynchus mykiss (rainbow trout), 45 d, >= 0.017 mg/l No toxicity at the limit of solubility NOEC, Oncorhynchus mykiss (rainbow trout), 90 d, >= 0.014 mg/l Chronic toxicity to aquatic invertebrates NOEC, Daphnia magna, 21 d, 0.015 mg/l Toxicity to soil-dwelling organisms This product does not have any known adverse effect on the soil organisms tested. NOEC, Eisenia fetida (earthworms), >= 76 mg/kg octamethylcyclotetrasiloxane Acute toxicity to fish Not expected to be acutely toxic to aquatic organisms. No toxicity at the limit of solubility LC50, Oncorhynchus mykiss (rainbow trout), flow-through, 96 Hour, > 0.022 mg/l No toxicity at the limit of solubility LC50, Cyprinodon variegatus (sheepshead minnow), flow-through, 14 d, > 0.0063 mg/l Acute toxicity to aquatic invertebrates No toxicity at the limit of solubility EC50, Mysidopsis bahia (opossum shrimp), flow-through test, 96 Hour, > 0.0091 mg/l No toxicity at the limit of solubility EC50, Daphnia magna (Water flea), flow-through test, 48 Hour, > 0.015 mg/l Acute toxicity to algae/aquatic plants No toxicity at the limit of solubility ErC50, Pseudokirchneriella subcapitata (green algae), 72 Hour, Growth rate, > 0.022 mg/l Chronic toxicity to fish No toxicity at the limit of solubility NOEC, Oncorhynchus mykiss (rainbow trout), 93 d, >= 0.0044 mg/l Chronic toxicity to aquatic invertebrates No toxicity at the limit of solubility NOEC, Daphnia magna (Water flea), 21 d, >= 0.0079 mg/l Zircon

Page 11 of 18

Product name: SILASTIC™ RTV-3481 Mould-Making Base

Revision Date: 28.08.2018 Version: 3.0

Acute toxicity to fish Not expected to be acutely toxic to aquatic organisms. Acute toxicity to aquatic invertebrates Based on data from similar materials EC50, Daphnia magna (Water flea), 48 Hour, > 100 mg/l Acute toxicity to algae/aquatic plants Based on data from similar materials NOEC, Chlorella vulgaris (Fresh water algae), 15 d, > 200 mg/l 12.2 Persistence and degradability Dodecamethyl cyclohexasiloxane Biodegradability: Based on stringent OECD test guidelines, this material cannot be considered as readily biodegradable; however, these results do not necessarily mean that the material is not biodegradable under environmental conditions. 10-day Window: Fail Biodegradation: 57 % Exposure time: 28 d Method: OECD Test Guideline 301B Decamethylcyclopentasiloxane Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability. 10-day Window: Not applicable Biodegradation: 0.14 % Exposure time: 28 d Method: OECD Test Guideline 310 octamethylcyclotetrasiloxane Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability. 10-day Window: Not applicable Biodegradation: 3.7 % Exposure time: 28 d Method: OECD Test Guideline 310 Stability in Water (1/2-life) Hydrolysis, DT50, 69.3 - 144 Hour, pH 7, Half-life Temperature 24.6 °C, OECD Test Guideline 111 Zircon Biodegradability: Biodegradation is not applicable. 12.3 Bioaccumulative potential Dodecamethyl cyclohexasiloxane Bioaccumulation: Bioconcentration potential is low (BCF less than 100 or log Pow greater than 7). Partition coefficient: n-octanol/water(log Pow): 8.87 Decamethylcyclopentasiloxane

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Product name: SILASTIC™ RTV-3481 Mould-Making Base

Revision Date: 28.08.2018 Version: 3.0

Bioaccumulation: Bioconcentration potential is moderate (BCF between 100 and 3000 or Log Pow between 3 and 5). Partition coefficient: n-octanol/water(log Pow): 5.2 Measured Bioconcentration factor (BCF): 2,010 Fish Estimated. octamethylcyclotetrasiloxane Bioaccumulation: Bioconcentration potential is high (BCF > 3000 or Log Pow between 5 and 7). Partition coefficient: n-octanol/water(log Pow): 6.49 Measured Bioconcentration factor (BCF): 12,400 Pimephales promelas (fathead minnow) Measured Zircon Bioaccumulation: Partitioning from water to n-octanol is not applicable. 12.4 Mobility in soil Dodecamethyl cyclohexasiloxane Potential for mobility in soil is very high (Koc between 0 and 50). Decamethylcyclopentasiloxane Expected to be relatively immobile in soil (Koc > 5000). Partition coefficient (Koc): > 5000 Estimated. octamethylcyclotetrasiloxane Expected to be relatively immobile in soil (Koc > 5000). Zircon No relevant data found. 12.5 Results of PBT and vPvB assessment Dodecamethyl cyclohexasiloxane Dodecamethyl cyclohexasiloxane (D6) meets the current REACh Annex XIII criteria for vPvB. However, D6 does not behave similarly to known PBT/vPvB substances. The weight of scientific evidence from field studies shows that D6 is not biomagnifying in aquatic and terrestrial food webs. D6 in air will degrade by reaction with naturally occurring hydroxyl radicals in the atmosphere. Any D6 in air that does not degrade by reaction with hydroxyl radicals is not expected to deposit from the air to water, to land, or to living organisms. Decamethylcyclopentasiloxane Decamethylcyclopentasiloxane (D5) meets the current REACh Annex XIII criteria for vPvB. However, D5 does not behave similarly to known PBT/vPvB substances. The weight of scientific evidence from field studies shows that D5 is not biomagnifying in aquatic and terrestrial food webs. D5 in air will degrade by reaction with naturally occurring hydroxyl radicals in the atmosphere. Any D5 in air that does not degrade by reaction with hydroxyl radicals is not expected to deposit from the air to water, to land, or to living organisms. Based on an independent scientific panel of experts, the Canadian Minister of the Environment has concluded that "D5 is not entering the environment in a quantity or concentration or under conditions that have or may have an immediate or long-term harmful effect on the environment or its biological diversity, or that constitute or may constitute a danger to the environment on which life depends". octamethylcyclotetrasiloxane

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Product name: SILASTIC™ RTV-3481 Mould-Making Base

Revision Date: 28.08.2018 Version: 3.0

Octamethylcyclotetrasiloxane (D4) meets the current REACh Annex XIII criteria for PBT and vPvB. In Canada, D4 has been assessed and deemed to meet the PiT criteria. However, D4 does not behave similarly to known PBT/vPvB substances. The weight of scientific evidence from field studies shows that D4 is not biomagnifying in aquatic and terrestrial food webs. D4 in air will degrade by reaction with naturally occurring hydroxyl radicals in the atmosphere. Any D4 in air that does not degrade by reaction with hydroxyl radicals is not expected to deposit from the air to water, to land, or to living organisms. Zircon This substance has not been assessed for persistence, bioaccumulation and toxicity (PBT). 12.6 Other adverse effects Dodecamethyl cyclohexasiloxane This substance is not on the Montreal Protocol list of substances that deplete the ozone layer. Decamethylcyclopentasiloxane This substance is not on the Montreal Protocol list of substances that deplete the ozone layer. octamethylcyclotetrasiloxane This substance is not on the Montreal Protocol list of substances that deplete the ozone layer. Zircon This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

SECTION 13: DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Do not dump into any sewers, on the ground, or into any body of water. This product, when being disposed of in its unused and uncontaminated state should be treated as a hazardous waste according to EC Directive 2008/98/EC. Any disposal practices must be in compliance with all national and provincial laws and any municipal or local by-laws governing hazardous waste. For used, contaminated and residual materials additional evaluations may be required. The definitive assignment of this material to the appropriate EWC group and thus its proper EWC code will depend on the use that is made of this material. Contact the authorized waste disposal services.

SECTION 14: TRANSPORT INFORMATION Classification for ROAD and Rail transport (ADR/RID): 14.1 UN number Not applicable 14.2 UN proper shipping name

Not regulated for transport

14.3 Transport hazard class(es)

Not applicable

14.4 Packing group

Not applicable

14.5 Environmental hazards

Not considered environmentally hazardous based on available data.

14.6 Special precautions for user No data available.

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Product name: SILASTIC™ RTV-3481 Mould-Making Base

Revision Date: 28.08.2018 Version: 3.0

Classification for SEA transport (IMO-IMDG): 14.1 UN number Not applicable 14.2 UN proper shipping name

Not regulated for transport

14.3 Transport hazard class(es)

Not applicable

14.4 Packing group

Not applicable

14.5 Environmental hazards

Not considered as marine pollutant based on available data.

14.6 Special precautions for user No data available. 14.7 Transport in bulk according to Annex I or II of MARPOL 73/78 and the IBC or IGC Code

Consult IMO regulations before transporting ocean bulk

Classification for AIR transport (IATA/ICAO): 14.1 UN number Not applicable 14.2 UN proper shipping name

Not regulated for transport

14.3 Transport hazard class(es)

Not applicable

14.4 Packing group

Not applicable

14.5 Environmental hazards

Not applicable

14.6 Special precautions for user No data available.

This information is not intended to convey all specific regulatory or operational requirements/information relating to this product. Transportation classifications may vary by container volume and may be influenced by regional or country variations in regulations. Additional transportation system information can be obtained through an authorized sales or customer service representative. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material.

SECTION 15: REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture REACh Regulation (EC) No 1907/2006 This product contains only components that have been either pre-registered, registered, are exempt from registration, are regarded as registered or are not subject to registration according to Regulation (EC) No. 1907/2006 (REACH)., The aforementioned indications of the REACH registration status are provided in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. It is the buyer´s/user´s responsibility to ensure that his/her understanding of the regulatory status of this product is correct. Restrictions on the manufacture, placing on the market and use:

Page 15 of 18

Product name: SILASTIC™ RTV-3481 Mould-Making Base

Revision Date: 28.08.2018 Version: 3.0

The following substance/s contained in this product is/are subject through Annex XVII of REACH regulation to restrictions on the manufacture, placing on the market and use when present in certain dangerous substances, mixtures and articles. Users of this product have to comply with the restrictions placed upon it by the aforementioned provision. CAS-No.: 541-02-6 Name: Decamethylcyclopentasiloxane Restriction status: listed in REACH Annex XVII Restricted uses: See Annex XVII to Regulation (EC) no 1907/2006 for Conditions of restriction CAS-No.: 556-67-2 Name: octamethylcyclotetrasiloxane Restriction status: listed in REACH Annex XVII Restricted uses: See Annex XVII to Regulation (EC) no 1907/2006 for Conditions of restriction Authorisation status under REACH: The following substance/s contained in this product might be or is/are subject to authorization in accordance with REACH: CAS-No.: 540-97-6 Name: Dodecamethyl cyclohexasiloxane Authorisation status: listed in the Candidate List of Substances of Very High Concern for Authorisation Authorisation number: Not available Sunset date: Not available Exempted (Categories of) Uses: Not available CAS-No.: 541-02-6 Name: Decamethylcyclopentasiloxane Authorisation status: listed in the Candidate List of Substances of Very High Concern for Authorisation Authorisation number: Not available Sunset date: Not available Exempted (Categories of) Uses: Not available CAS-No.: 556-67-2 Name: octamethylcyclotetrasiloxane Authorisation status: listed in the Candidate List of Substances of Very High Concern for Authorisation Authorisation number: Not available Sunset date: Not available Exempted (Categories of) Uses: Not available Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. Listed in Regulation: Not applicable 15.2 Chemical safety assessment Not applicable

SECTION 16: OTHER INFORMATION Full text of H-Statements referred to under sections 2 and 3. H226 Flammable liquid and vapour. H361f Suspected of damaging fertility. H413 May cause long lasting harmful effects to aquatic life. Classification and procedure used to derive the classification for mixtures according to Regulation (EC) No 1272/2008 This product is not classified as dangerous according to EC criteria. Revision

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Product name: SILASTIC™ RTV-3481 Mould-Making Base

Revision Date: 28.08.2018 Version: 3.0

Identification Number: 4107633 / A279 / Issue Date: 28.08.2018 / Version: 3.0 Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document. Legend ACGIH GB EH40 STEL TWA US WEEL Aquatic Chronic Flam. Liq. Repr.

USA. ACGIH Threshold Limit Values (TLV) UK. EH40 WEL - Workplace Exposure Limits Short-term exposure limit 8-hour, time-weighted average USA. Workplace Environmental Exposure Levels (WEEL) Long-term (chronic) aquatic hazard Flammable liquids Reproductive toxicity

Full text of other abbreviations ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways; ADR - European Agreement concerning the International Carriage of Dangerous Goods by Road; AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada); ECHA - European Chemicals Agency; EC-Number - European Community number; ECx Concentration associated with x% response; ELx - Loading rate associated with x% response; EmS Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RID - Regulations concerning the International Carriage of Dangerous Goods by Rail; SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; SVHC - Substance of Very High Concern; TCSI - Taiwan Chemical Substance Inventory; TRGS - Technical Rule for Hazardous Substances; TSCA - Toxic Substances Control Act (United States); UN - United Nations; vPvB - Very Persistent and Very Bioaccumulative Information Source and References This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from information supplied by internal references within our company.

Page 17 of 18

Product name: SILASTIC™ RTV-3481 Mould-Making Base

Revision Date: 28.08.2018 Version: 3.0

DOW CHEMICAL COMPANY LIMITED urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with all federal, state, provincial or local laws. The information presented here pertains only to the product as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to the proliferation of sources for information such as manufacturerspecific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current, please contact us for the most current version. GB

Page 18 of 18

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

SILASTIC™ RTV-3081-F Mould-Making Curing Agent Version 3.1

Revision Date: 09.03.2018

SDS Number: 671525-00009

Date of last issue: 14.08.2017 Date of first issue: 24.10.2014

SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name

SILASTIC™ RTV-3081-F Mould-Making Curing Agent

Product code

04107685

1.2 Relevant identified uses of the substance or mixture and uses advised against Use of the Sub: Vulcanising agents, Polymer stance/Mixture 1.3 Details of the supplier of the safety data sheet Company : DOW CHEMICAL COMPANY LIMITED STATION ROAD, BIRCH VALE, HIGH PEAK DERBYSHIRE England SK22 1BR UNITED KINGDOM

Telephone

+44 (0) 1663 746518

Telefax

+44 (0) 1663 746605

E-mail address of person responsible for the SDS

SDSQuestion@dow.com

1.4 Emergency telephone number 24-Hour Emergency Contact : Local Emergency Contact

0031 115 694 982 00 31 115 69 4982

SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification (REGULATION (EC) No 1272/2008) Reproductive toxicity, Category 2 H361d: Suspected of damaging the unborn child. Specific target organ toxicity - repeated exposure, Category 2

H373: May cause damage to organs through prolonged or repeated exposure.

2.2 Label elements Labelling (REGULATION (EC) No 1272/2008)

1 / 25

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

SILASTIC™ RTV-3081-F Mould-Making Curing Agent Version 3.1

Revision Date: 09.03.2018

SDS Number: 671525-00009

Date of last issue: 14.08.2017 Date of first issue: 24.10.2014

Hazard pictograms

Signal word

Warning

Hazard statements

H361d Suspected of damaging the unborn child. H373 May cause damage to organs through prolonged or repeated exposure.

Precautionary statements

Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: P308 + P313 attention.

IF exposed or concerned: Get medical advice/

Storage: P405 Store locked up. Hazardous components which must be listed on the label: Trimethoxyphenylsilane Dimethylbis[(1-oxoneodecyl)oxy]stannane 2.3 Other hazards Vapours may form explosive mixture with air.

SECTION 3: Composition/information on ingredients 3.2 Mixtures Chemical nature

Organotin compound

Hazardous components Chemical name

Trimethoxyphenylsilane Dimethylbis[(1oxoneodecyl)oxy]stannane

CAS-No. EC-No. Index-No. Registration number 2996-92-1 221-066-9 01-2119964479-19 68928-76-7 273-028-6

2 / 25

Classification

Flam. Liq. 3; H226 Acute Tox. 4; H302 STOT RE 2; H373 Acute Tox. 4; H302 Repr. 2; H361d STOT RE 1; H372 Aquatic Chronic 3; H412

Concentration (% w/w) >= 10 - < 20 >= 3 - < 10

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

SILASTIC™ RTV-3081-F Mould-Making Curing Agent Version 3.1

Revision Date: 09.03.2018

SDS Number: 671525-00009

Date of last issue: 14.08.2017 Date of first issue: 24.10.2014

Methanol

67-56-1 200-659-6 603-001-00-X 01-2119433307-44

Tetramethoxysilane

681-84-5 211-656-4

Flam. Liq. 2; H225 Acute Tox. 3; H301 Acute Tox. 3; H331 Acute Tox. 3; H311 STOT SE 1; H370 Flam. Liq. 3; H226 Acute Tox. 1; H330 Skin Irrit. 2; H315 Eye Dam. 1; H318 STOT RE 1; H372

>= 0.1 - < 1

For explanation of abbreviations see section 16.

SECTION 4: First aid measures 4.1 Description of first aid measures General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice. Protection of first-aiders

First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists.

If inhaled

If inhaled, remove to fresh air. Get medical attention.

In case of skin contact

In case of contact, immediately flush skin with soap and plenty of water. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.

In case of eye contact

Flush eyes with water as a precaution. Get medical attention if irritation develops and persists.

If swallowed

If swallowed, DO NOT induce vomiting. Get medical attention. Rinse mouth thoroughly with water.

4.2 Most important symptoms and effects, both acute and delayed Risks : Suspected of damaging the unborn child. May cause damage to organs through prolonged or repeated exposure. 4.3 Indication of any immediate medical attention and special treatment needed Treatment : Treat symptomatically and supportively.

3 / 25

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

SILASTIC™ RTV-3081-F Mould-Making Curing Agent Version 3.1

Revision Date: 09.03.2018

SDS Number: 671525-00009

Date of last issue: 14.08.2017 Date of first issue: 24.10.2014

SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media

Unsuitable extinguishing media

Water spray Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical

High volume water jet

5.2 Special hazards arising from the substance or mixture Specific hazards during fire- : Do not use a solid water stream as it may scatter and spread fighting fire. Flash back possible over considerable distance. Vapours may form explosive mixtures with air. Exposure to combustion products may be a hazard to health. Hazardous combustion prod- : ucts

5.3 Advice for firefighters Special protective equipment for firefighters Specific extinguishing methods

Carbon oxides Silicon oxides Formaldehyde Metal oxides

In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area.

SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions : Remove all sources of ignition. Use personal protective equipment. Follow safe handling advice and personal protective equipment recommendations. 6.2 Environmental precautions Environmental precautions

Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). 4 / 25

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

SILASTIC™ RTV-3081-F Mould-Making Curing Agent Version 3.1

Revision Date: 09.03.2018

SDS Number: 671525-00009

Date of last issue: 14.08.2017 Date of first issue: 24.10.2014

Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. 6.3 Methods and material for containment and cleaning up Methods for cleaning up : Non-sparking tools should be used. Soak up with inert absorbent material. Suppress (knock down) gases/vapours/mists with a water spray jet. For large spills, provide dyking or other appropriate containment to keep material from spreading. If dyked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements. 6.4 Reference to other sections See sections: 7, 8, 11, 12 and 13.

SECTION 7: Handling and storage 7.1 Precautions for safe handling Technical measures :

See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section.

Local/Total ventilation

Use with local exhaust ventilation.

Advice on safe handling

Avoid inhalation of vapour or mist. Do not swallow. Avoid contact with eyes. Avoid prolonged or repeated contact with skin. Handle in accordance with good industrial hygiene and safety practice, based on the results of the workplace exposure assessment Keep container tightly closed. Keep away from water. Protect from moisture. Keep away from heat and sources of ignition. Take precautionary measures against static discharges. Take care to prevent spills, waste and minimize release to the environment.

Hygiene measures

Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use. 5 / 25

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

SILASTIC™ RTV-3081-F Mould-Making Curing Agent Version 3.1

Revision Date: 09.03.2018

SDS Number: 671525-00009

Date of last issue: 14.08.2017 Date of first issue: 24.10.2014

7.2 Conditions for safe storage, including any incompatibilities Requirements for storage : Keep in properly labelled containers. Store locked up. Keep areas and containers tightly closed. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from heat and sources of ignition. Advice on common storage

7.3 Specific end use(s) Specific use(s)

Do not store with the following product types: Strong oxidizing agents Organic peroxides Explosives Gases

These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require added precautions. For further information regarding the use of silicones / organic oils in consumer aerosol applications, please refer to the guidance document regarding the use of these type of materials in consumer aerosol applications that has been developed by the silicone industry (www.SEHSC.com) or contact the Dow Chemical customer service group.

SECTION 8: Exposure controls/personal protection 8.1 Control parameters Occupational Exposure Limits Components

CAS-No.

Trimethoxyphenylsilane Dimethylbis[(1oxoneodecyl)oxy]stannan e Further information

Further information Methanol Further information Further information

Control parameters

Basis

2996-92-1

Value type (Form of exposure) TWA

50 ppm

DCC OEL

68928-76-7

TWA

0.1 mg/m3 (Tin)

GB EH40

Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity. STEL 0.2 mg/m3 GB EH40 (Tin) Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity. 67-56-1 TWA 200 ppm 2006/15/EC 260 mg/m3 Indicative, Identifies the possibility of significant uptake through the skin TWA 200 ppm GB EH40 266 mg/m3 Can be absorbed through skin. The assigned substances are those for which 6 / 25

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

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Further information

SDS Number: 671525-00009

Date of last issue: 14.08.2017 Date of first issue: 24.10.2014

there are concerns that dermal absorption will lead to systemic toxicity. STEL 250 ppm GB EH40 333 mg/m3 Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity.

Occupational exposure limits of decomposition products Components

CAS-No.

Propan-1-ol

71-23-8

Further information

Further information Methanol Further information Further information

Further information

Value type (Form of exposure) STEL

Control parameters

Basis

250 ppm GB EH40 625 mg/m3 Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity. TWA 200 ppm GB EH40 500 mg/m3 Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity. 67-56-1 TWA 200 ppm 2006/15/EC 260 mg/m3 Indicative, Identifies the possibility of significant uptake through the skin TWA 200 ppm GB EH40 266 mg/m3 Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity. STEL 250 ppm GB EH40 333 mg/m3 Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity.

Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006: Substance name

End Use

Exposure routes

Tetrapropyl orthosilicate

Workers

Inhalation

Workers

Inhalation

Workers

Skin contact

Workers

Skin contact

Consumers

Inhalation

Consumers

Inhalation

Consumers

Skin contact

Consumers

Skin contact

Consumers

Ingestion

Consumers

Ingestion 7 / 25

Potential health effects Long-term systemic effects Acute systemic effects Long-term systemic effects Acute systemic effects Long-term systemic effects Acute systemic effects Long-term systemic effects Acute systemic effects Long-term systemic effects Acute systemic ef-

Value 85 mg/m3 85 mg/m3 12 mg/kg bw/day 12 mg/kg bw/day 21 mg/m3 21 mg/m3 6 mg/kg bw/day 6 mg/kg bw/day 6 mg/kg bw/day 6 mg/kg

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Alkoxysilane

Methanol

Tetramethoxysilane

SDS Number: 671525-00009

Date of last issue: 14.08.2017 Date of first issue: 24.10.2014

Workers

Skin contact

Workers

Inhalation

Workers

Skin contact

Workers

Inhalation

Consumers

Skin contact

Consumers

Inhalation

Consumers

Ingestion

Consumers

Skin contact

Consumers

Inhalation

Workers

Inhalation

Workers

Inhalation

Workers

Inhalation

Workers

Inhalation

Workers

Skin contact

Workers

Skin contact

Consumers

Inhalation

Consumers

Inhalation

Consumers

Inhalation

Consumers

Inhalation

Consumers

Skin contact

Consumers

Skin contact

Consumers

Ingestion

Consumers

Ingestion

Workers

Inhalation

Workers

Skin contact

8 / 25

fects Acute systemic effects Acute systemic effects Long-term systemic effects Long-term systemic effects Acute systemic effects Acute systemic effects Long-term systemic effects Long-term systemic effects Long-term systemic effects Long-term systemic effects Acute systemic effects Long-term local effects Acute local effects

bw/day 2.5 mg/kg bw/day 40.2 mg/m3

Long-term systemic effects Acute systemic effects Long-term systemic effects Acute systemic effects Long-term local effects Acute local effects

40 mg/kg bw/day 40 mg/kg bw/day 50 mg/m3

Long-term systemic effects Acute systemic effects Long-term systemic effects Acute systemic effects Long-term local effects Long-term systemic effects

8 mg/kg bw/day 8 mg/kg bw/day 8 mg/kg bw/day 8 mg/kg bw/day 93 mg/m3

2.5 mg/kg bw/day 40.2 mg/m3 33.3 mg/kg bw/day 10 mg/m3 0.7 mg/kg bw/day 1.7 mg/kg bw/day 10 mg/m3 260 mg/m3 260 mg/m3 260 mg/m3 260 mg/m3

50 mg/m3 50 mg/m3 50 mg/m3

0.3 mg/kg bw/day

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Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006: Substance name Tetrapropyl orthosilicate

Alkoxysilane

Methanol

Tetramethoxysilane

Environmental Compartment Fresh water Marine water

Value 10 mg/l 1 mg/l

Fresh water sediment

11 mg/kg

Marine sediment

1.1 mg/kg

Soil

3.9 mg/kg

Sewage treatment plant

96 mg/l

Fresh water Marine water

0.24 mg/l 0.024 mg/l

Fresh water sediment

0.24 mg/kg

Marine sediment

0.024 mg/kg

Soil

0.07 mg/kg

Sewage treatment plant

74 mg/l

Fresh water Marine water

20.8 mg/l 2.08 mg/l

Intermittent use/release

1540 mg/l

Sewage treatment plant

100 mg/l

Fresh water sediment

77 mg/kg

Marine sediment

7.7 mg/kg

Soil

100 mg/kg

Fresh water Marine water

5 mg/l 0.5 mg/l

Fresh water sediment

4.44 mg/kg

Marine sediment

0.44 mg/kg

Soil

0.99 mg/kg

Sewage treatment plant

> 1 mg/l

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8.2 Exposure controls Engineering measures Processing may form hazardous compounds (see section 10). Ensure adequate ventilation, especially in confined areas. Minimize workplace exposure concentrations. Personal protective equipment Eye protection : Wear the following personal protective equipment: Safety glasses Hand protection Material

Chemical-resistant gloves

Remarks

Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Take note that the product is flammable, which may impact the selection of hand protection. Wash hands before breaks and at the end of workday.

Skin and body protection

Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Wear the following personal protective equipment: Flame retardant antistatic protective clothing, unless assessment demonstrates that the risk of explosive atmospheres or flash fires is low Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc).

Respiratory protection

Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines.

Filter type

Self-contained breathing apparatus

SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance : liquid Colour

Clear to slightly hazy, colourless

Odour

slight

Odour Threshold

No data available

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No data available

Melting point/freezing point

No data available

Initial boiling point and boiling range

> 35 °C

Flash point

64 °C Method: Pensky-Martens closed cup

Evaporation rate

No data available

Flammability (solid, gas)

Not applicable

Upper explosion limit / Upper flammability limit

No data available

Lower explosion limit / Lower flammability limit

No data available

Vapour pressure

No data available

Relative vapour density

No data available

Relative density

0.969

Solubility(ies) Water solubility

No data available

Partition coefficient: noctanol/water

No data available

Auto-ignition temperature

No data available

Decomposition temperature

No data available

Viscosity Viscosity, dynamic

40 mPa.s

Explosive properties

Not explosive

Oxidizing properties

The substance or mixture is not classified as oxidizing.

9.2 Other information Flammability (liquids)

Not applicable

Molecular weight

No data available

Particle size

Not applicable

Self-ignition

The substance or mixture is not classified as pyrophoric. The

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substance or mixture is not classified as self heating.

SECTION 10: Stability and reactivity 10.1 Reactivity Not classified as a reactivity hazard. 10.2 Chemical stability Stable under normal conditions. 10.3 Possibility of hazardous reactions Hazardous reactions : Combustible liquid. Vapours may form explosive mixture with air. Use at elevated temperatures may form highly hazardous compounds. Can react with strong oxidizing agents. Hazardous decomposition products will be formed upon contact with water or humid air. Hazardous decomposition products will be formed at elevated temperatures. 10.4 Conditions to avoid Conditions to avoid

Exposure to moisture Heat, flames and sparks.

10.5 Incompatible materials Materials to avoid

Oxidizing agents Water

10.6 Hazardous decomposition products Contact with water or humid : Propan-1-ol air Methanol Thermal decomposition

Benzene Formaldehyde

SECTION 11: Toxicological information 11.1 Information on toxicological effects Information on likely routes of : Inhalation exposure Skin contact Ingestion Eye contact Acute toxicity Not classified based on available information. 12 / 25

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Product: Acute oral toxicity

Acute toxicity estimate: > 2,000 mg/kg Method: Calculation method

Acute inhalation toxicity

Acute toxicity estimate: > 20 mg/l Exposure time: 4 h Test atmosphere: vapour Method: Calculation method

Acute dermal toxicity

Acute toxicity estimate: > 2,000 mg/kg Method: Calculation method

LD50 (Rat): 1,049 mg/kg Remarks: On basis of test data.

Components: Trimethoxyphenylsilane: Acute oral toxicity

Dimethylbis[(1-oxoneodecyl)oxy]stannane: Acute oral toxicity : LD50 (Rat): 894 mg/kg Method: OECD Test Guideline 401 Acute dermal toxicity

LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 402 Assessment: The substance or mixture has no acute dermal toxicity

Methanol: Acute oral toxicity

Acute toxicity estimate (Humans): 300 mg/kg Method: Expert judgement

Acute inhalation toxicity

Acute toxicity estimate: 3 mg/l Exposure time: 4 h Test atmosphere: vapour Method: Expert judgement Remarks: Based on harmonised classification in EU regulation 1272/2008, Annex VI

Acute dermal toxicity

Acute toxicity estimate (Humans): 300 mg/kg Method: Expert judgement

Tetramethoxysilane: Acute oral toxicity

LD50 (Rat): > 2,000 mg/kg Assessment: The substance or mixture has no acute oral toxicity Remarks: Based on data from similar materials

Acute inhalation toxicity

LC50 (Rat): 63 ppm Exposure time: 4 h Test atmosphere: vapour 13 / 25

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Remarks: On basis of test data. Acute dermal toxicity

LD50 (Rabbit): 17,544 mg/kg Assessment: The substance or mixture has no acute dermal toxicity Remarks: Information taken from reference works and the literature.

Skin corrosion/irritation Not classified based on available information. Components: Trimethoxyphenylsilane: Species: Rabbit Result: No skin irritation Remarks: On basis of test data. Dimethylbis[(1-oxoneodecyl)oxy]stannane: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Methanol: Species: Rabbit Result: No skin irritation Tetramethoxysilane: Species: Rabbit Result: Skin irritation Remarks: Based on data from similar materials Serious eye damage/eye irritation Not classified based on available information. Components: Trimethoxyphenylsilane: Species: Rabbit Result: No eye irritation Remarks: Based on data from similar materials Dimethylbis[(1-oxoneodecyl)oxy]stannane: Species: Rabbit Method: OECD Test Guideline 405 Result: No eye irritation Methanol: 14 / 25

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Species: Rabbit Result: No eye irritation Tetramethoxysilane: Result: Irreversible effects on the eye Remarks: On basis of test data. Respiratory or skin sensitisation Skin sensitisation Not classified based on available information. Respiratory sensitisation Not classified based on available information. Components: Methanol: Test Type: Maximisation Test Exposure routes: Skin contact Species: Guinea pig Result: negative Tetramethoxysilane: Assessment: Does not cause skin sensitisation. Test Type: Buehler Test Species: Guinea pig Remarks: Based on data from similar materials Germ cell mutagenicity Not classified based on available information. Components: Trimethoxyphenylsilane: Genotoxicity in vitro

Test Type: Bacterial reverse mutation assay (AMES) Result: negative Remarks: On basis of test data.

Dimethylbis[(1-oxoneodecyl)oxy]stannane: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative Methanol: Genotoxicity in vitro

Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative 15 / 25

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Test Type: In vitro mammalian cell gene mutation test Result: negative Genotoxicity in vivo

Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Species: Mouse Application Route: Intraperitoneal injection Result: negative

Tetramethoxysilane: Genotoxicity in vivo

Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Species: Rat Application Route: Inhalation Result: negative Remarks: On basis of test data.

Animal testing did not show any mutagenic effects.

Germ cell mutagenicity- Assessment

Carcinogenicity Not classified based on available information. Components: Methanol: Species: Mouse Application Route: inhalation (vapour) Exposure time: 18 Months Result: negative Reproductive toxicity Suspected of damaging the unborn child. Components: Trimethoxyphenylsilane: Effects on fertility

Effects on foetal development

Test Type: Combined repeated dose toxicity study with the reproduction/developmental toxicity screening test Species: Rat, male and female Application Route: Ingestion Symptoms: No effects on fertility Remarks: On basis of test data.

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Reproductive toxicity - Assessment

SDS Number: 671525-00009

Date of last issue: 14.08.2017 Date of first issue: 24.10.2014

No evidence of adverse effects on sexual function and fertility, or on development, based on animal experiments.

Dimethylbis[(1-oxoneodecyl)oxy]stannane: Reproductive toxicity - As: Some evidence of adverse effects on development, based on sessment animal experiments. Methanol: Effects on fertility

Effects on foetal development

Test Type: Fertility/early embryonic development Species: Mouse Application Route: Ingestion Result: negative

Test Type: Embryo-foetal development Species: Mouse Application Route: Ingestion Result: positive Remarks: The effects were seen only at maternally toxic doses.

STOT - single exposure Not classified based on available information. Components: Methanol: Target Organs: Eyes, Central nervous system Assessment: Causes damage to organs. STOT - repeated exposure May cause damage to organs through prolonged or repeated exposure. Components: Trimethoxyphenylsilane: Exposure routes: Ingestion Target Organs: Bladder, Kidney Assessment: Shown to produce significant health effects in animals at concentrations of >10 to 100 mg/kg bw. Exposure routes: inhalation (vapour) Assessment: No significant health effects observed in animals at concentrations of 1 mg/l/6h/d or less. Dimethylbis[(1-oxoneodecyl)oxy]stannane: Exposure routes: Ingestion Target Organs: Immune system, Central nervous system Assessment: Shown to produce significant health effects in animals at concentrations of 10 mg/kg bw or less. 17 / 25

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Tetramethoxysilane: Exposure routes: inhalation (vapour) Target Organs: Respiratory system Assessment: Shown to produce significant health effects in animals at concentrations of 0.2 mg/l/6h/d or less. Repeated dose toxicity Components: Trimethoxyphenylsilane: Species: Rat Application Route: Ingestion Target Organs: Bladder, Kidney Remarks: On basis of test data. Species: Rat Application Route: inhalation (vapour) Remarks: On basis of test data. Dimethylbis[(1-oxoneodecyl)oxy]stannane: Species: Rat NOAEL: < 1.6 mg/kg Application Route: Ingestion Exposure time: 90 Days Remarks: Based on data from similar materials Methanol: Species: Rat NOAEL: 1.06 mg/l Application Route: inhalation (vapour) Exposure time: 90 Days Tetramethoxysilane: Species: Rat Application Route: inhalation (vapour) Target Organs: Respiratory system Remarks: On basis of test data. Aspiration toxicity Not classified based on available information.

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SECTION 12: Ecological information 12.1 Toxicity Components: Trimethoxyphenylsilane: Toxicity to fish

LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Remarks: Based on data from similar materials No toxicity at the limit of solubility LC50 (Oncorhynchus mykiss (rainbow trout)): > 0.20 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Remarks: On basis of test data. No toxicity at the limit of solubility

Toxicity to daphnia and other aquatic invertebrates

EC50 (Daphnia magna (Water flea)): > 0.0029 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 Remarks: On basis of test data. No toxicity at the limit of solubility

Toxicity to algae

ErC50 (Pseudokirchneriella subcapitata (green algae)): > 0.17 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Remarks: On basis of test data. No toxicity at the limit of solubility

Toxicity to microorganisms

EC50 : > 1,000 mg/l Exposure time: 3 h Method: OECD Test Guideline 209 Remarks: Based on data from similar materials

Dimethylbis[(1-oxoneodecyl)oxy]stannane: Toxicity to fish : LC50 (Danio rerio (zebra fish)): > 100 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates

EC50 (Daphnia magna (Water flea)): 17 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 Remarks: Based on data from similar materials

Toxicity to algae

ErC50 (Desmodesmus subspicatus (green algae)): 37 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 19 / 25

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Remarks: Based on data from similar materials EC10 (Desmodesmus subspicatus (green algae)): 5.7 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Remarks: Based on data from similar materials Methanol: Toxicity to fish

LC50 (Lepomis macrochirus (Bluegill sunfish)): 15,400 mg/l Exposure time: 96 h

Toxicity to daphnia and other aquatic invertebrates

EC50 (Daphnia magna (Water flea)): > 10,000 mg/l Exposure time: 48 h

Toxicity to algae

EC50 (Pseudokirchneriella subcapitata (green algae)): 22,000 mg/l Exposure time: 96 h Method: OECD Test Guideline 201

Toxicity to microorganisms

IC50 : > 1,000 mg/l Exposure time: 3 h

Toxicity to fish (Chronic toxic- : ity)

Tetramethoxysilane: Toxicity to fish

NOEC: 15,800 mg/l Exposure time: 200 h Species: Oryzias latipes (Orange-red killifish)

LC50 (Danio rerio (zebra fish)): > 245 mg/l Exposure time: 96 h Method: Directive 67/548/EEC, Annex V, C.1. Remarks: Based on data from similar materials

Toxicity to daphnia and other aquatic invertebrates

EC50 (Daphnia magna (Water flea)): > 75 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 Remarks: Based on data from similar materials No toxicity at the limit of solubility

Toxicity to algae

ErC50 (Selenastrum capricornutum (green algae)): > 22 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Remarks: No toxicity at the limit of solubility

Ecotoxicology Assessment Acute aquatic toxicity :

This product has no known ecotoxicological effects.

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12.2 Persistence and degradability Components: Trimethoxyphenylsilane: Biodegradability

Result: Not readily biodegradable. Biodegradation: 1 % Exposure time: 28 d Method: OECD Test Guideline 310 Remarks: Based on data from similar materials

Dimethylbis[(1-oxoneodecyl)oxy]stannane: Biodegradability : Result: Not readily biodegradable. Biodegradation: 3 % Exposure time: 35 d Method: OECD Test Guideline 301F Remarks: Based on data from similar materials Methanol: Biodegradability

Result: Readily biodegradable. Biodegradation: 95 % Exposure time: 20 d

Tetramethoxysilane: Stability in water

Degradation half life: < 3 min pH: 7

Species: Leuciscus idus (Golden orfe) Bioconcentration factor (BCF): < 10

log Pow: -0.77

log Pow: -0.5

12.3 Bioaccumulative potential Components: Methanol: Bioaccumulation Partition coefficient: noctanol/water Tetramethoxysilane: Partition coefficient: noctanol/water 12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment Not relevant

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12.6 Other adverse effects No data available

SECTION 13: Disposal considerations 13.1 Waste treatment methods Product

Contaminated packaging

Dispose of in accordance with local regulations. According to the European Waste Catalogue, Waste Codes are not product specific, but application specific. Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.

Empty containers should be taken to an approved waste handling site for recycling or disposal. Empty containers retain residue and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury and/or death. If not otherwise specified: Dispose of as unused product.

SECTION 14: Transport information 14.1 UN number Not regulated as a dangerous good 14.2 UN proper shipping name Not regulated as a dangerous good 14.3 Transport hazard class(es) Not regulated as a dangerous good 14.4 Packing group Not regulated as a dangerous good 14.5 Environmental hazards Not regulated as a dangerous good 14.6 Special precautions for user Not applicable 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Remarks : Not applicable for product as supplied.

SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture REACH - Candidate List of Substances of Very High : Not applicable Concern for Authorisation (Article 59). Regulation (EC) No 1005/2009 on substances that dep22 / 25

Not applicable

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lete the ozone layer Regulation (EC) No 850/2004 on persistent organic pollutants

Not applicable

Regulation (EC) No 649/2012 of the European Parliament and the Council concerning the export and import of dangerous chemicals

Not applicable

Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. Not applicable Other regulations: Take note of Directive 92/85/EEC regarding maternity protection or stricter national regulations, where applicable. Take note of Directive 94/33/EC on the protection of young people at work or stricter national regulations, where applicable. The components of this product are reported in the following inventories: NZIoC : All ingredients listed or exempt. REACH

For purchases from Dow Chemical EU legal entities, all ingredients are currently pre/registered or exempt under REACH. Please refer to section 1 for recommended uses. For purchases from non-EU Dow Chemical legal entities with the intention to export into EEA please contact your DC representative/local office.

TSCA

All chemical substances in this product are either listed on the TSCA Inventory or are in compliance with a TSCA Inventory exemption.

AICS

All ingredients listed or exempt.

IECSC

All ingredients listed or exempt.

ENCS/ISHL

All components are listed on ENCS/ISHL or exempted from inventory listing.

KECI

All ingredients listed, exempt or notified.

PICCS

All ingredients listed or exempt.

DSL

All chemical substances in this product comply with the CEPA 1999 and NSNR and are on or exempt from listing on the Canadian Domestic Substances List (DSL).

TCSI

All ingredients listed or exempt. 23 / 25

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15.2 Chemical safety assessment A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information Full text of H-Statements H225 H226 H301 H302 H311 H315 H318 H330 H331 H361d H370 H372

: : : : : : : : : : : :

H372

H373

H412

Full text of other abbreviations Acute Tox. : Aquatic Chronic : Eye Dam. : Flam. Liq. : Repr. : Skin Irrit. : STOT RE : STOT SE : 2006/15/EC : DCC OEL : GB EH40 : 2006/15/EC / TWA : DCC OEL / TWA : GB EH40 / TWA : GB EH40 / STEL :

Highly flammable liquid and vapour. Flammable liquid and vapour. Toxic if swallowed. Harmful if swallowed. Toxic in contact with skin. Causes skin irritation. Causes serious eye damage. Fatal if inhaled. Toxic if inhaled. Suspected of damaging the unborn child. Causes damage to organs. Causes damage to organs through prolonged or repeated exposure if inhaled. Causes damage to organs through prolonged or repeated exposure if swallowed. May cause damage to organs through prolonged or repeated exposure if swallowed. Harmful to aquatic life with long lasting effects. Acute toxicity Chronic aquatic toxicity Serious eye damage Flammable liquids Reproductive toxicity Skin irritation Specific target organ toxicity - repeated exposure Specific target organ toxicity - single exposure Europe. Indicative occupational exposure limit values Dow Chemical Guide UK. EH40 WEL - Workplace Exposure Limits Limit Value - eight hours Time weighted average Long-term exposure limit (8-hour TWA reference period) Short-term exposure limit (15-minute reference period)

ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways; ADR - European Agreement concerning the International Carriage of Dangerous Goods by Road; AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada); ECHA - European Chemicals Agency; EC-Number - European Community number; ECx Concentration associated with x% response; ELx - Loading rate associated with x% response; 24 / 25

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

SILASTIC™ RTV-3081-F Mould-Making Curing Agent Version 3.1

Revision Date: 09.03.2018

SDS Number: 671525-00009

Date of last issue: 14.08.2017 Date of first issue: 24.10.2014

EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx Concentration associated with x% growth rate response; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RID - Regulations concerning the International Carriage of Dangerous Goods by Rail; SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; SVHC - Substance of Very High Concern; TCSI - Taiwan Chemical Substance Inventory; TRGS - Technical Rule for Hazardous Substances; TSCA - Toxic Substances Control Act (United States); UN - United Nations; vPvB - Very Persistent and Very Bioaccumulative Further information Sources of key data used to compile the Safety Data Sheet

Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agency, http://echa.europa.eu/

Classification of the mixture:

Classification procedure:

Repr. 2

H361d

Calculation method

STOT RE 2

H373

Calculation method

Items where changes have been made to the previous version are highlighted in the body of this document by two vertical lines. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, unless specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, including an assessment of the appropriateness of the SDS material in the user’s end product, if applicable. GB / EN

25 / 25

SAFETY DATA SHEET According to article 31 and Annex II of the EU REACH Regulation Version: 2.2 Revision Date: 08.06.2012 Superseded date: 08.06.2012

SILASTIC(R) THIXO ADDITIVE TS 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY 1.1 Product name

SILASTIC(R) THIXO ADDITIVE TS

1.2 Identified uses

Additives Softeners

None known.

Dow Corning Europe S.A. rue Jules Bordet - Parc Industriel - Zone C B-7180 Seneffe Belgium

E-mail address (Safety Data Sheet)

sdseu@dowcorning.com

Customer Service

English Deutsch Français Italiano Español

Uses advised against 1.3 Company

Tel: +49 611237507 Tel: +49 611237500 Tel: +32 64511149 Tel: +32 64511170 Tel: +32 64511163 Fax: +32 64888683

1.4 Emergency Phone Number

Dow Corning (Barry U.K. 24h) Dow Corning (Wiesbaden 24h) Dow Corning (Seneffe 24h)

2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture According to EU Directives 67/548/EEC or 1999/45/EC: Not hazardous. 2.2 Label elements Labelling according to EEC Directive S-phrases

S23(V) Do not breathe vapour. S51 Use only in well-ventilated areas.

2.3 Other hazards Vapours may form explosive mixtures with air.

1 of 8

Tel: +44 1446732350 Tel: +49 61122158 Tel: +32 64 888240

SAFETY DATA SHEET According to article 31 and Annex II of the EU REACH Regulation Version: 2.2 Revision Date: 08.06.2012 Superseded date: 08.06.2012

SILASTIC(R) THIXO ADDITIVE TS 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical characterization: Organofunctional Siloxane According to EU Directives 67/548/EEC or 1999/45/EC: Name

CAS-No.

Octamethylcyclotetrasil oxane

556-67-2

Decamethylcyclopentasi 541-02-6 loxane

EINECS/ ELINCS No. 209-136-7

Classification Conc. REACH Registration (% w/w) Number 01-21195292 4.0 Xn, Toxic for reproduction - category 3. 38-36 R62 R53

208-764-9

01-21195113 1.95 67-43

Substance with a Community workplace exposure limit

According to Regulation (EC) No. 1272/2008: Name

CAS-No.

Octamethylcyclotetrasil oxane

556-67-2

EINECS/ ELINCS No. 209-136-7

Classification Conc. REACH Registration (% w/w) Number Flammable liquid: Category 3 - H226 01-21195292 4.0 Reproductive toxicity (Inhalation - vapour): 38-36 Category 2 - H361f Chronic aquatic hazard: Category 4

Decamethylcyclopentasi 541-02-6 loxane

208-764-9

01-21195113 1.95 67-43

- H413

Substance with a Community workplace exposure limit

For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section 16. CLP classifications are based on all current available data including from known international organizations. These classifications are subject to revision as more information becomes available.

4. FIRST AID MEASURES 4.1 Description of First Aid Measures: On contact with eyes

No first aid should be needed.

On skin contact

No first aid should be needed.

If inhaled

Remove to fresh air. Obtain medical attention.

On ingestion

Obtain medical attention.

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SAFETY DATA SHEET According to article 31 and Annex II of the EU REACH Regulation Version: 2.2 Revision Date: 08.06.2012 Superseded date: 08.06.2012

SILASTIC(R) THIXO ADDITIVE TS 5. FIRE-FIGHTING MEASURES 5.1 Suitable extinguishing media Unsuitable extinguishing media 5.2 Hazards during fire fighting Hazardous Combustion Products 5.3 Special protective equipment/procedures

On large fires use dry chemical, foam or water spray (fog). On small fires use carbon dioxide (CO2), dry chemical or water spray. Water can be used to cool fire exposed containers.

None known.

Vapours may form explosive mixtures with air.

Thermal breakdown of this product during fire or very high heat conditions may evolve the following decomposition products: Silica. Carbon oxides and traces of incompletely burned carbon compounds. Formaldehyde. Chlorine compounds. A self-contained respirator and protective clothing should be worn. Determine the need to evacuate or isolate the area according to your local emergency plan. Use water spray to keep fire exposed containers cool.

6. ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures

Wear proper protective equipment.

6.2 Environmental precautions

Prevent from spreading or entering into drains, ditches or rivers by using sand, earth or other appropriate barriers.

6.3 Methods and materials for : containment and cleaning up

Determine the need to evacuate or isolate the area according to your local emergency plan. Very large spills should be contained by bunding, etc... procedures. Mop, wipe or soak up with absorbent material and place in a container with a lid. The spilled product produces an extremely slippery surface.

7. HANDLING AND STORAGE 7.1 Advice on safe handling

General ventilation is required. Local ventilation is recommended. Avoid eye contact. Do not breathe vapour. Do not empty into drains.

7.2 Advice on storage

Do not store with oxidizing agents. Vapours may form explosive mixtures with air. Storage temperature: minimum 0 °C, maximum 38 °C

7.3 Specific uses

Refer to technical data sheet available on request.

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SAFETY DATA SHEET According to article 31 and Annex II of the EU REACH Regulation Version: 2.2 Revision Date: 08.06.2012 Superseded date: 08.06.2012

SILASTIC(R) THIXO ADDITIVE TS 8. EXPOSURE CONTROLS / PERSONAL PROTECTION 8.1 Control parameters Name

CAS-No.

Exposure Limits

Octamethylcyclotetrasiloxane

556-67-2

10 ppm TWA Dow Corning recommendation.

Decamethylcyclopentasiloxane

541-02-6

10 ppm TWA Dow Corning recommendation.

8.2 Exposure controls :

Ventilation : Refer to Section 7.1

Respiratory protection

Suitable respiratory protection should be worn if the product is used in large quantities, confined spaces or in other circumstances where the OEL may be approached or exceeded. Depending on the working conditions, wear a respiratory mask with filter(s) A or use a self-contained respirator. The choice of a filter type depends on the amount and type of chemical being handled in the workplace. Regarding filter characteristics, contact your respiratory protection supplier.

Hand protection

Gloves are not normally required.

Eye/face protection

Safety glasses should be worn.

Skin protection

Protective equipment is not normally necessary.

Hygiene measures

Exercise good industrial hygiene practice. Wash after handling, especially before eating, drinking or smoking.

Additional information

These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require added precautions. For further information regarding the use of silicones / organic oils in consumer aerosol applications, please refer to the guidance document regarding the use of these types of materials in consumer aerosol applications that has been developed by the silicone industry (www.SEHSC.com) or contact the Dow Corning customer service group.

Environmental exposure controls

Refer to section 6 and 12.

Engineering Controls Personal protection equipment

9. PHYSICAL AND CHEMICAL PROPERTIES Form

Liquid

Colour

Amber

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SAFETY DATA SHEET According to article 31 and Annex II of the EU REACH Regulation Version: 2.2 Revision Date: 08.06.2012 Superseded date: 08.06.2012

SILASTIC(R) THIXO ADDITIVE TS Odour

Characteristic odour

Boiling point/range

> 150 °C

Flash point

87.7 °C (Closed Cup)

Explosive properties

No Vapours may form explosive mixtures with air.

Specific Gravity

1.03

Viscosity

525 mm2/s at 25°C.

Oxidizing properties

The above information is not intended for use in preparing product specifications. Contact Dow Corning before writing specifications.

10. STABILITY AND REACTIVITY 10.1 Reactivity

None known.

10.2 Stability

Stable under normal usage conditions.

10.3 Possibility of hazardous reactions

None known.

10.4 Conditions to avoid

None established.

10.5 Materials to avoid

Can react with strong oxidising agents.

10.6 Hazardous decomposition : products

11. TOXICOLOGICAL INFORMATION Acute toxicity: On contact with eyes

May cause temporary discomfort.

On skin contact

No adverse effects are normally expected.

If inhaled

No significant effects expected from a single short-term exposure.

On ingestion

Small amounts transferred to the mouth by fingers during use should not injure.

On skin contact

No adverse effects are normally expected.

If inhaled

Suspected of damaging fertility.

Chronic toxicity:

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SAFETY DATA SHEET According to article 31 and Annex II of the EU REACH Regulation Version: 2.2 Revision Date: 08.06.2012 Superseded date: 08.06.2012

SILASTIC(R) THIXO ADDITIVE TS :

Small amounts transferred to the mouth by fingers during use should not injure.

Toxicokinetics, metabolism and distribution

No specific information is available.

Other Health Hazard Information

Octamethylcyclotetrasiloxane administered to rats by inhalation at concentrations of 500 and 700 ppm resulted in statistically significant decreases in the number of pups born and the live litter size in both the first and second generations. Prolonged estrous cycles, and decreased mating and fertility indices were observed following 700 ppm exposure in the second generation only. There were also increases in the incidence of deliveries of offspring extending over an unusually long time period (dystocia). Results from a 2 year repeated vapor inhalation exposure study to rats of octamethylcyclotetrasiloxane (D4) indicate effects (benign uterine adenomas) in the uterus of female animals. This finding occurred at the highest exposure dose (700 ppm) only. Studies to date have not demonstrated if these effects occur through pathways that are relevant to humans. Based on the available information on its potential to cause harm to human health, Health Canada, in a 2008 screening assessment, has concluded that octamethylcyclotetrasiloxane is not entering the environment in a quantity or concentration or under conditions that constitute or may constitute a danger in Canada to human life or health (http://www.ec.gc.ca/substances/ese/eng/challenge/batch2/batch2_556-67-2.cfm). Repeated exposure in rats to D4 resulted in what appears to be protoporphyrin accumulation in the liver. Without knowledge of the specific mechanism leading to the protoporphyrin accumulation the relevance of this finding to humans is unknown. Product may emit formaldehyde vapour at temperatures above 150ºC in the presence of air. Formaldehyde vapour is a suspected carcinogen, toxic by inhalation and irritating to eyes and the respiratory system. Exposure limits should be strictly respected.

On ingestion

1 2

Based on product test data. Based on test data from similar products.

12. ECOLOGICAL INFORMATION 12.1 Ecotoxicity effects No adverse effects on freshwater organisms. 12.2 Persistence and degradability Siloxanes are removed from water by sedimentation or binding to sewage sludge. In soil, siloxanes are degraded. 12.3 Bioaccumulation No bioaccumulation potential. 12.4 Release to waters / Mobility in soil Fate and effects in waste water treatment plants: No adverse effects on bacteria.

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SAFETY DATA SHEET According to article 31 and Annex II of the EU REACH Regulation Version: 2.2 Revision Date: 08.06.2012 Superseded date: 08.06.2012

SILASTIC(R) THIXO ADDITIVE TS 13. DISPOSAL CONSIDERATIONS :

Product and packaging disposal

14. TRANSPORT INFORMATION Road / Rail (ADR/RID) Not subject to ADR/RID. Sea transport (IMDG) Not subject to IMDG code. Air transport (IATA) Not subject to IATA regulations.

15. REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Status EINECS

All ingredients listed, exempt or notified (ELINCS).

TSCA

All chemical substances in this material are included on or exempted from listing on the TSCA Inventory of Chemical Substances.

IECSC

All ingredients listed or exempt.

ENCS/ISHL

All ingredients listed, exempt or notified.

DSL

All ingredients listed or exempt.

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SAFETY DATA SHEET According to article 31 and Annex II of the EU REACH Regulation Version: 2.2 Revision Date: 08.06.2012 Superseded date: 08.06.2012

SILASTIC(R) THIXO ADDITIVE TS 16. OTHER INFORMATION This product safety data sheet was prepared in compliance with article 31 and Annex II of the EU REACH Regulation as well as its relevant amendements, on the approximation of laws, regulations and administrative provisions relative to the classification, packaging and labelling of dangerous substances and preparations. It is the responsibility of persons in receipt of this Product Safety Data Sheet to ensure that the information contained herein is properly read and understood by all people who may use, handle, dispose or in any way come in contact with the product. If the recipient subsequently produces a formulation containing the Dow Corning product, it is the recipient's sole responsibility to ensure the transfer of all relevant information from the Dow Corning Product Safety Data Sheet to their own Product Safety Data Sheet in compliance with article 31 and Annex II of the EU REACH Regulation. All information and instructions provided in this Safety Data Sheet (SDS) are based on the current state of scientific and technical knowledge at the date indicated on the present SDS. Dow Corning shall not be held responsible for any defect in the product covered by this SDS , should the existence of such defect not be detectable considering the current state of scientific and technical knowledge. As stated above, this Safety Data Sheet has been prepared in compliance with applicable European law. If you purchase this material outside Europe, where compliance laws may differ, you should receive from your local Dow Corning supplier a SDS applicable to the country in which the product is sold and intended to be used. Please note that the appearance and content of the SDS may vary - even for the same product - between different countries, reflecting the different compliance requirements. Should you have any question, please refer to your local Dow Corning supplier. Source of information: Internal data and publically available information R53 May cause long-term adverse effects in the aquatic environment., R62 Possible risk of impaired fertility. H226 Flammable liquid and vapour., H361f Suspected of damaging fertility., H413 May cause long lasting harmful effects to aquatic life.

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MATERIAL SAFETY DATA SHEET (cosh115) 1.

Identification of the preparation/Supplier reference

Trade Name

P3386 Mouldmakers size

Chemical name Synonyms Supplier Emergency numbers

Potassium salt of mixed fatty acids Soft soap Potterycrafts Ltd, Campbell Road, Stoke on Trent ST4 4ET, UK +44 (0)1782 745000 - internet lab@potterycrafts.co.uk

Composition

Component composition

CAS

EINECS

% of

Potassium salt of mixed fatty acids

Health Hazard Identification

Inhalation Ingestion Eyes Skin

First Aid Measures

Inhalation Ingestion Eyes Skin

None The product is likely to be of low toxicity May cause physical irritation and inflammation Excessive exposure may cause irritation and inflammation

Not applicable Do not induce vomiting, rinse mouth with water, give water to drink, seek medical advice Wash immediately with copious amounts of water for at least 10 minutes Wash affected areas with water thoroughly

Fire Fighting Measures

Extinguishing Media Special Exposure hazard Personal protective equipment

Suitable for surrounding fire conditions In the event of a fire the product may emit harmful or toxic fumes None other than required for surrounding fire conditions

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Accidental Release Measures

Leaks & Spills Personal protective equipment

Handling & Storage

Handling Storage

Do not eat, drink, or smoke in areas where the material is used. Wash thoroughly after handling the material Store in cool dry location away from direct sunlight

Exposure Control/Personal protective Equipment

Engineering controls Personal protective equipment

Adequate ventilation should be provided so that Occupational Exposure Limits are not exceeded. Local Exhaust Ventilation is normally recommended. Protective gloves, eye protection and overalls are recommended for prolonged contact.

Physical & Chemical properties

Appearance & Odour Flash point (ºC) Flammability Explosive properties Oxidising properties Specific gravity pH value Melting point (ºC)

10.

Recollects where possible. Absorb remainder on inert non combustible binder, eg sand or earth. Sweep up and transfer to containers for subsequent waste disposal Protective clothing and gloves

Brown gel, mild odour Not applicable Not applicable Non-explosive None 1-2 >7 (soluble in water) Not applicable

Stability & Reactivity

Chemical stability Conditions/materials to avoid Hazardous decomposition products Hazardous polymerization products

11.

None

Toxicology Information

Acute toxicology Health effects

12.

The material is stable under normal conditions of use Acidic conditions will cause decomposition None

Not considered harmful by any route of exposure Prolonged or repeated exposure above Occupational Exposure Standards may cause irritation and inflammation

Ecological information

Ecotoxicity Persistence

None Readily biodegradable to harmless substances

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13.

Disposal

Dispose in accordance with current waste Disposal regulations (for UK - Control of Pollution (Special Waste) Regulations 1980). Controlled incineration or landfill may be suitable. Consult the relevant authority for waste disposal guidance

14.

Transport Information

UN/SI No. UN Class Packing group Road UK ADR Sea IMO Air ICAO

15.

Not Not Not Not Not Not Not

restricted restricted restricted restricted restricted restricted restricted

Regulatory information

EC Supply Labelling R-Phrases S-Phrases UK Occupational exposures limits*

Non hazardous None S20/21 when using do not eat, drink or smoke 3 Mg/m 8 hr TWA % in product

* refer to HSE Guidance note EH40 In accordance with HSE Approved Code of Practice for CHIP, the recipient is reminded of their obligations under both the Health and Safety at Work Act (HSWA) and the Control of Substances Hazardous to Health Regulations (COSHH), and that the information in any safety data sheet does not constitutes the user's assessment of workplace risk

16.

Other information

References COSHH ACOP

HSC approved Code of Practice for the Control of Substances Hazardous to Health Regulations 1994

CHIP 96 Regulations

Chemicals (Hazard Information and Packaging for Supply) 1996

CHIP SDS ACOPS accordance with

HSC Approved Code of Practice for Safety data Sheets in regulation 6 of the CHIP regulations

HSE EH40 used in

HSE Guidance note EH40 on Occupational Exposure Limits to be conjunction with the COSH regulations

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Footnote LIABILITY Such information is the best of Potterycrafts Ltd' s knowledge and belief accurate at the date of publication, which is the date generated automatically on the day of printing of this document. However, no representation, warranty of guarantee is made as to its accuracy, reliability of completeness. It is the user's responsibility to satisfy itself as to the suitability and completeness of such information for their own particular use. THIRD PARTY MATERIALS Insofar as materials not manufactured or supplied by Potterycrafts Ltd are used in conjunction with, or instead of Potterycrafts Ltd materials, it is the responsibility of the customer itself to obtain from the manufacturer or supplier all technical data and other properties relating to these and other materials and to obtain all necessary information relating to them. No liability can be accepted in respect of the use of Potterycrafts Ltd materials in conjunctions with other materials.

17.

National Legislation

UK Legislation SI1993/1746 Chemicals (Hazard Information and Packaging) Regulations 1993 Environmental Protection (Duty of Care) regulations 1992 SI 2839 Carriage of Dangerous goods by Road and Rail Regulations 1994 Control of pollution Act 1974 Environmental Protection Act 1990 Highly Flammable Liquids and Petroleum Spirit Regulations 1972 EH40 Occupational Exposure Limits SI1988/1657 The Control of Substances Hazardous to Health Regulations Note - This is not an exhaustive list and users should satisfy themselves that they comply with all relevant National Regulations Important notes Design CHIP-002 The material must only be used for its stated purpose and the information contained within this data sheet is offered solely for use in the evaluation of this product in respect of safety, health and environmental hazards. Further reference can be made to our standard terms and conditions of sale, a copy of which is available on request. 02 September 2009

Product safety information sheet according to REACH (article 32)

FL100 - AC100 Liquids Date of compilation: 23/04/2019

Version: 1

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1

Product identifier: FL100 - AC100 Liquids

1.2

Relevant identified uses of the substance or mixture and uses advised against: Relevant uses: Acrylic resin based coating for cement and concrete surfaces. Uses advised against: All uses not specified in this section or in section 7.3

1.3

1.4

Details of the supplier of the safety data sheet: Jesmonite Limited Challenge Court SY95DW Bishops Castle - Shropshire - United Kingdom Phone.: +44 (0)1588 630302 https://Jesmonite.com Emergency telephone number: For advice on medical emergencies, fires, spillages or chemical hazards only phone: +44 870 190 6777. National Chemical Emergency Centre (NCEC) phone: +44 (0) 1235 753654

SECTION 2: HAZARDS IDENTIFICATION 2.1

Classification of the substance or mixture: CLP Regulation (EC) No 1272/2008: The product is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

2.2

Label elements: CLP Regulation (EC) No 1272/2008: Hazard statements: Non-applicable Precautionary statements: Non-applicable Supplementary information:

2.3

EUH208: Contains Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H -isothiazol-3one [EC no. 220-239-6] (3:1), Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H isothiazol-3-one [EC no. 220-239-6] (3:1). May produce an allergic reaction Other hazards: Product contains PBT/vPvB substances: Octamethylcyclotetrasiloxane

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1

Substance: Non-applicable

3.2

Mixture: Chemical description: Acrylic resin Components: None of the substances contained in the mixture are above the values fixed in Annex II of Regulation (EC) No 1907/2006

SECTION 4: FIRST AID MEASURES 4.1

Product safety information sheet according to REACH (article 32)

FL100 - AC100 Liquids Date of compilation: 23/04/2019

Version: 1

SECTION 4: FIRST AID MEASURES (continued) By skin contact: In case of contact it is recommended to clean the affected area thoroughly with water and neutral soap. In case of changes to the skin (stinging, redness, rashes, blisters,…), seek medical advice with this Safety data Sheet By eye contact: Rinse with water until the product has been eliminated. In case of problems, consult a doctor showing the SDS for the product. By ingestion/aspiration: In case of consumption in large quantities, it is recommended to seek medical assistance. 4.2

Most important symptoms and effects, both acute and delayed: Acute and delayed effects are indicated in sections 2 and 11.

4.3

Indication of any immediate medical attention and special treatment needed: Non-applicable

SECTION 5: FIREFIGHTING MEASURES 5.1

Extinguishing media:

5.2

Product is non-flammable, with a low risk of fire due to the flammabliity characteristics of the product in normal conditions of storage, handling and use. In the case of the existence of sustained combustion as a result of improper handling, storage or use any type of extinguishing agent can be used (ABC Powder, water,...) Special hazards arising from the substance or mixture: Due to its non-flammable nature, the product does not present a fire risk under normal conditions of storage, handling and use.

5.3

Advice for firefighters: Depending on the magnitude of the fire it may be necessary to use full protective clothing and self-contained breathing apparatus (SCBA). Minimum emergency facilities and equipment should be available (fire blankets, portable first aid kit,...) in accordance with Directive 89/654/EC. Additional provisions: Act in accordance with the Internal Emergency Plan and the Information Sheets on actions to take after an accident or other emergencies. Eliminate all sources of ignition. In case of fire, cool the storage containers and tanks for products susceptible to combustion, explosion or BLEVE as a result of high temperatures. Avoid spillage of the products used to extinguish the fire into an aqueous medium.

SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1

Personal precautions, protective equipment and emergency procedures: Isolate leaks provided that there is no additional risk for the people performing this task.

6.2

Environmental precautions: This product is not classified as hazardous to the environment. Keep product away from drains, surface and ground water.

6.3

Methods and material for containment and cleaning up: It is recommended:

6.4

Absorb the spillage using sand or inert absorbent and move it to a safe place. Do not absorb in sawdust or other combustible absorbents. For any concern related to disposal consult section 13. Reference to other sections: See sections 8 and 13.

SECTION 7: HANDLING AND STORAGE 7.1

Precautions for safe handling: A.- Precautions for safe manipulation Comply with the current legislation concerning the prevention of industrial risks. Keep containers hermetically sealed. Control spills and residues, destroying them with safe methods (section 6). Avoid leakages from the container. Maintain order and cleanliness where dangerous products are used. - CONTINUED ON NEXT PAGE Page 2/8

Product safety information sheet according to REACH (article 32)

FL100 - AC100 Liquids Date of compilation: 23/04/2019

Version: 1

SECTION 7: HANDLING AND STORAGE (continued) B.- Technical recommendations for the prevention of fires and explosions It is recommended to transfer at a slow speed to avoid the creation of electrostatic charges that could affect flammable products. Consult section 10 for conditions and materials that should be avoided. C.- Technical recommendations to prevent ergonomic and toxicological risks Do not eat or drink during the process, washing hands afterwards with suitable cleaning products. D.- Technical recommendations to prevent environmental risks It is not necessary to take special measures to prevent environmental risks. For more information see subsection 6.2 7.2

Conditions for safe storage, including any incompatibilities: A.- Technical measures for storage Minimum Temp.:

5 ºC

Maximum Temp.:

25 ºC

Maximum time:

6 Months

B.- General conditions for storage Avoid sources of heat, radiation, static electricity and contact with food. For additional information see subsection 10.5 7.3

Specific end use(s): Except for the instructions already specified it is not necessary to provide any special recommendation regarding the uses of this product.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1

Control parameters: Substances whose occupational exposure limits have to be monitored in the workplace (EH40/2005 Workplace exposure limits): Identification

Environmental limits

Formaldehyde CAS: 50-00-0

EC: 200-001-8

WEL (8h)

2 ppm

2.5 mg/m³

WEL (15 min)

2 ppm

2.5 mg/m³

DNEL (Workers): Non-applicable DNEL (General population): Non-applicable PNEC: 8.2

Non-applicable Exposure controls: A.- General security and hygiene measures in the work place As a preventative measure it is recommended to use basic Personal Protective Equipment, with the corresponding <<CE marking>> in accordance with Directive 89/686/EC. For more information on Personal Protective Equipment (storage, use, cleaning, maintenance, class of protection,…) consult the information leaflet provided by the manufacturer. For more information see subsection 7.1. All information contained herein is a recommendation which needs some specification from the labour risk prevention services as it is not known whether the company has additional measures at its disposal. B.- Respiratory protection The use of protection equipment will be necessary if a mist forms or if the occupational exposure limits are exceeded. C.- Specific protection for the hands Pictogram

PPE

Labelling

CEN Standard

Remarks Replace gloves in case of any sign of damage. For prolonged periods of exposure to the product for professional users/industrials, we recommend using CE III gloves in line with standards EN 420 and EN 374.

Protective gloves against minor risks Mandatory hand protection

"As the product is a mixture of several substances, the resistance of the glove material can not be predicted in advance with total reliability and has therefore to be checked prior to the application" - CONTINUED ON NEXT PAGE Page 3/8

Product safety information sheet according to REACH (article 32)

FL100 - AC100 Liquids Date of compilation: 23/04/2019

Version: 1

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continued) D.- Ocular and facial protection Pictogram

PPE

Labelling

Panoramic glasses against splash/projections.

CEN Standard

Remarks

EN 166:2001 EN ISO 4007:2012

Clean daily and disinfect periodically according to the manufacturer´s instructions. Use if there is a risk of splashing.

Mandatory face protection

E.- Body protection Pictogram

PPE

Labelling

CEN Standard

Remarks

Work clothing

Replace before any evidence of deterioration. For periods of prolonged exposure to the product for professional/industrial users CE III is recommended, in accordance with the regulations in EN ISO 6529:2001, EN ISO 6530:2005, EN ISO 13688:2013, EN 464:1994.

Anti-slip work shoes

EN ISO 20347:2012

F.- Additional emergency measures It is not necessary to take additional emergency measures. Environmental exposure controls: In accordance with the community legislation for the protection of the environment it is recommended to avoid environmental spillage of both the product and its container. For additional information see subsection 7.1.D Volatile organic compounds: With regard to Directive 2010/75/EU, this product has the following characteristics: V.O.C. (Supply):

0.01 % weight

V.O.C. density at 20 ºC:

0.14 kg/m³ (0.14 g/L)

Average carbon number:

7.55

Average molecular weight:

279.56 g/mol

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1

Information on basic physical and chemical properties: For complete information see the product datasheet. Appearance: Physical state at 20 ºC:

Liquid

Appearance:

Not available

Colour:

Not available

Odour:

Not available

Odour threshold:

Non-applicable *

Volatility: Boiling point at atmospheric pressure:

100 ºC

Vapour pressure at 20 ºC:

2392 Pa

Vapour pressure at 50 ºC:

93.63 (12.48 kPa)

Evaporation rate at 20 ºC:

Non-applicable *

Product description: Density at 20 ºC:

1096.7 kg/m³

Relative density at 20 ºC:

1.097

*Not relevant due to the nature of the product, not providing information property of its hazards.

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Product safety information sheet according to REACH (article 32)

FL100 - AC100 Liquids Date of compilation: 23/04/2019

Version: 1

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (continued) Dynamic viscosity at 20 ºC:

Non-applicable *

Kinematic viscosity at 20 ºC:

Non-applicable *

Kinematic viscosity at 40 ºC:

Non-applicable *

Concentration:

Non-applicable *

pH:

Non-applicable *

Vapour density at 20 ºC:

Non-applicable *

Partition coefficient n-octanol/water 20 ºC:

Non-applicable *

Solubility in water at 20 ºC:

Non-applicable *

Solubility properties:

Non-applicable *

Decomposition temperature:

Non-applicable *

Melting point/freezing point:

Non-applicable *

Explosive properties:

Non-applicable *

Oxidising properties:

Non-applicable *

Flammability: Flash Point:

Non Flammable (>60 ºC)

Flammability (solid, gas):

Non-applicable *

Autoignition temperature:

360 ºC

Lower flammability limit:

Non-applicable *

Upper flammability limit:

Non-applicable *

Explosive:

9.2

Lower explosive limit:

Non-applicable *

Upper explosive limit:

Non-applicable *

Other information: Surface tension at 20 ºC:

Non-applicable *

Refraction index:

Non-applicable *

*Not relevant due to the nature of the product, not providing information property of its hazards.

SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity: No hazardous reactions are expected because the product is stable under recommended storage conditions. See section 7. 10.2 Chemical stability: Chemically stable under the conditions of storage, handling and use. 10.3 Possibility of hazardous reactions: Under the specified conditions, hazardous reactions that lead to excessive temperatures or pressure are not expected. 10.4 Conditions to avoid: Applicable for handling and storage at room temperature: Shock and friction

Contact with air

Increase in temperature

Sunlight

Humidity

Not applicable

Acids

Water

Oxidising materials

Combustible materials

Others

Avoid strong acids

Not applicable

Avoid alkalis or strong bases

10.5 Incompatible materials:

10.6 Hazardous decomposition products: See subsection 10.3, 10.4 and 10.5 to find out the specific decomposition products. Depending on the decomposition conditions, complex mixtures of chemical substances can be released: carbon dioxide (CO2), carbon monoxide and other organic compounds. - CONTINUED ON NEXT PAGE Page 5/8

Product safety information sheet according to REACH (article 32)

FL100 - AC100 Liquids Date of compilation: 23/04/2019

Version: 1

SECTION 11: TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects: LD50 oral > 2000 mg/kg (rat) Dangerous health implications: In case of exposure that is repetitive, prolonged or at concentrations higher than the recommended occupational exposure limits, adverse effects on health may result, depending on the means of exposure: A- Ingestion (acute effect): - Acute toxicity : Based on available data, the classification criteria are not met - Corrosivity/Irritability: Based on available data, the classification criteria are not met B- Inhalation (acute effect): - Acute toxicity : Based on available data, the classification criteria are not met - Corrosivity/Irritability: Based on available data, the classification criteria are not met C- Contact with the skin and the eyes (acute effect): - Contact with the skin: Based on available data, the classification criteria are not met - Contact with the eyes: Based on available data, the classification criteria are not met D- CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction): - Carcinogenicity: Based on available data, the classification criteria are not met IARC: Formaldehyde (1) - Mutagenicity: Based on available data, the classification criteria are not met - Reproductive toxicity: Based on available data, the classification criteria are not met E- Sensitizing effects: - Respiratory: Based on available data, the classification criteria are not met - Cutaneous: Based on available data, the classification criteria are not met F- Specific target organ toxicity (STOT) - single exposure: Based on available data, the classification criteria are not met G- Specific target organ toxicity (STOT)-repeated exposure: - Specific target organ toxicity (STOT)-repeated exposure: Based on available data, the classification criteria are not met - Skin: Based on available data, the classification criteria are not met H- Aspiration hazard: Based on available data, the classification criteria are not met Other information: Non-applicable Specific toxicology information on the substances: Not available

SECTION 12: ECOLOGICAL INFORMATION The experimental information related to the eco-toxicological properties of the product itself is not available 12.1 Toxicity: Not available 12.2 Persistence and degradability: Not available 12.3 Bioaccumulative potential: Not available 12.4 Mobility in soil: Not available 12.5 Results of PBT and vPvB assessment: - CONTINUED ON NEXT PAGE Page 6/8

Product safety information sheet according to REACH (article 32)

FL100 - AC100 Liquids Date of compilation: 23/04/2019

Version: 1

SECTION 12: ECOLOGICAL INFORMATION (continued) Product contains PBT/vPvB substances: Octamethylcyclotetrasiloxane 12.6 Other adverse effects: Not described

SECTION 13: DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods: Code 08 01 12

Description waste paint and varnish other than those mentioned in 08 01 11

Waste class (Regulation (EU) No 1357/2014) Non dangerous

Type of waste (Regulation (EU) No 1357/2014): Non-applicable Waste management (disposal and evaluation): Consult the authorized waste service manager on the assessment and disposal operations in accordance with Annex 1 and Annex 2 (Directive 2008/98/EC, The Waste Regulations 2011, 2011 No. 988). As under 15 01 (2014/955/EU) of the code and in case the container has been in direct contact with the product, it will be processed the same way as the actual product. Otherwise, it will be processed as non-dangerous residue. We do not recommended disposal down the drain. See paragraph 6.2. Regulations related to waste management: In accordance with Annex II of Regulation (EC) No 1907/2006 (REACH) the community or state provisions related to waste management are stated Community legislation: Directive 2008/98/EC, 2014/955/EU, Regulation (EU) No 1357/2014

SECTION 14: TRANSPORT INFORMATION This product is not regulated for transport (ADR/RID,IMDG,IATA)

SECTION 15: REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture: Regulation (EC) No 528/2012: contains a preservative to protect the initial properties of the treated article. Contains Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H -isothiazol-3-one [EC no. 220-239-6] (3:1), Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H -isothiazol-3-one [EC no. 220-2396] (3:1). Candidate substances for authorisation under the Regulation (EC) No 1907/2006 (REACH): Non-applicable Substances included in Annex XIV of REACH ("Authorisation List") and sunset date: Non-applicable Regulation (EC) No 1005/2009, about substances that deplete the ozone layer: Non-applicable Article 95, REGULATION (EU) No 528/2012: Non-applicable REGULATION (EU) No 649/2012, in relation to the import and export of hazardous chemical products: Non-applicable Seveso III: Non-applicable Limitations to commercialisation and the use of certain dangerous substances and mixtures (Annex XVII REACH, etc ….): Contains Octamethylcyclotetrasiloxane. 1. | Shall not be placed on the market in wash-off cosmetic products in a concentration equal to or greater than 0,1 % by weight of either substance, after 31 January 2020. | 2. | For the purposes of this entry, “washoff cosmetic products” means cosmetic products as defined in Article 2(1)(a) of Regulation (EC) No 1223/2009 that, under normal conditions of use, are washed off with water after application.’ Specific provisions in terms of protecting people or the environment: It is recommended to use the information included in this safety data sheet as a basis for conducting workplace-specific risk assessments in order to establish the necessary risk prevention measures for the handling, use, storage and disposal of this product. - CONTINUED ON NEXT PAGE Page 7/8

Product safety information sheet according to REACH (article 32)

FL100 - AC100 Liquids Date of compilation: 23/04/2019

Version: 1

SECTION 15: REGULATORY INFORMATION (continued) Other legislation: The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2009 (CDG 2009), SI 2009 No 1348 The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment (Amendment) Regulations 2011, 2011 No. 1885 Control of Substances Hazardous to Health Regulations 2002 (as amended) EH40/2005 Workplace exposure limits The Waste Regulations 2011, 2011 No. 988 15.2 Chemical safety assessment: The supplier has not carried out evaluation of chemical safety.

SECTION 16: OTHER INFORMATION Legislation related to safety data sheets: This safety data sheet has been designed in accordance with ANNEX II-Guide to the compilation of safety data sheets of Regulation (EC) No 1907/2006 (Regulation (EC) No 2015/830) Modifications related to the previous Safety Data Sheet which concerns the ways of managing risks.: Non-applicable Texts of the legislative phrases mentioned in section 3: The phrases indicated do not refer to the product itself; they are present merely for informative purposes and refer to the individual components which appear in section 3 CLP Regulation (EC) No 1272/2008: Non-applicable Classification procedure: Non-applicable Advice related to training: Minimal training is recommended in order to prevent industrial risks for staff using this product and to facilitate their comprehension and interpretation of this safety data sheet, as well as the label on the product. Principal bibliographical sources: http://echa.europa.eu http://eur-lex.europa.eu Abbreviations and acronyms: ADR: European agreement concerning the international carriage of dangerous goods by road IMDG: International maritime dangerous goods code IATA: International Air Transport Association ICAO: International Civil Aviation Organisation COD: Chemical Oxygen Demand BOD5: 5-day biochemical oxygen demand BCF: Bioconcentration factor LD50: Lethal Dose 50 LC50: Lethal Concentration 50 EC50: Effective concentration 50 Log-POW: Octanol-water partition coefficient Koc: Partition coefficient of organic carbon

Product safety information sheet prepared in accordance with Article 32 of Regulation (EC) 1907/2006 (REACH); this document does not constitute a Safety Data Sheet under Article 31 of Regulation (EC) No. 1907/2006, as a Safety Data Sheet is not mandatory for this product The information contained in this safety data sheet is based on sources, technical knowledge and current legislation at European and state level, without being able to guarantee its accuracy. This information cannot be considered a guarantee of the properties of the product, it is simply a description of the security requirements. The occupational methodology and conditions for users of this product are not within our awareness or control, and it is ultimately the responsibility of the user to take the necessary measures to obtain the legal requirements concerning the manipulation, storage, use and disposal of chemical products. The information on this safety data sheet only refers to this product, which should not be used for needs other than those specified.

- END OF SAFETY DATA SHEET Page 8/8

Product safety information sheet according to REACH (article 32)

FBJESB - Jesmonite Base Date of compilation: 23/04/2019

Version: 1

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1

Product identifier: FBJESB - Jesmonite Base Calcium sulfate

1.2

CAS:

7778-18-9

EC:

231-900-3

Index:

Non-applicable

REACH:

01-2119444918-26-XXXX

Relevant identified uses of the substance or mixture and uses advised against: Relevant uses: Molding Uses advised against: All uses not specified in this section or in section 7.3

1.3

1.4

SECTION 2: HAZARDS IDENTIFICATION 2.1

Classification of the substance or mixture: CLP Regulation (EC) No 1272/2008: The product is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

2.2

Label elements: CLP Regulation (EC) No 1272/2008: None

2.3

Other hazards: Product fails to meet PBT/vPvB criteria

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1

Substance: Chemical description: Mixture of additives, aggregates and gypsum Components: In accordance with Annex II of Regulation (EC) No 1907/2006 (point 3), the product contains: Identification

Chemical name/Classification

CAS: 7778-18-9 Calcium sulfate EC: 231-900-3 Index: Non-applicable Regulation 1272/2008 REACH: 01-2119444918-26-XXXX

Concentration Not classified 100 %

To obtain more information on the hazards of the substances consult sections 8, 11, 12, 15 and 16. 3.2

Mixture: Non-applicable

SECTION 4: FIRST AID MEASURES

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Product safety information sheet according to REACH (article 32)

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SECTION 4: FIRST AID MEASURES (continued) 4.1

Description of first aid measures: Consult a doctor in case of discomfort showing the SDS for the product. By inhalation: In case of symptoms, move the person affected into fresh air. By skin contact: In case of contact it is recommended to clean the affected area thoroughly with water and neutral soap. In case of changes to the skin (stinging, redness, rashes, blisters,…), seek medical advice with this Safety data Sheet By eye contact: Rinse with water until the product has been eliminated. In case of problems, consult a doctor showing the SDS for the product. By ingestion/aspiration: In case of consumption in large quantities, it is recommended to seek medical assistance.

4.2

Most important symptoms and effects, both acute and delayed: Acute and delayed effects are indicated in sections 2 and 11.

4.3

Indication of any immediate medical attention and special treatment needed: Non-applicable

SECTION 5: FIREFIGHTING MEASURES 5.1

Extinguishing media:

5.2

5.3

SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1

Personal precautions, protective equipment and emergency procedures: Sweep up and shovel product or collect by other means and place in container for reuse (preferred) or disposal

6.2

Environmental precautions: This product is not classified as hazardous to the environment. Keep product away from drains, surface and ground water.

6.3

Methods and material for containment and cleaning up: It is recommended: Sweep up and shovel product or collect by other means and place in container for reuse (preferred) or disposal

6.4

Reference to other sections: See sections 8 and 13.

SECTION 7: HANDLING AND STORAGE 7.1

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Product safety information sheet according to REACH (article 32)

FBJESB - Jesmonite Base Date of compilation: 23/04/2019

Version: 1

SECTION 7: HANDLING AND STORAGE (continued) A.- Precautions for safe manipulation Comply with the current legislation concerning the prevention of industrial risks. Keep containers hermetically sealed. Control spills and residues, destroying them with safe methods (section 6). Avoid leakages from the container. Maintain order and cleanliness where dangerous products are used. B.- Technical recommendations for the prevention of fires and explosions Due to its non-flammable nature, the product does not present a fire risk under normal conditions of storage, handling and use. C.- Technical recommendations to prevent ergonomic and toxicological risks Do not eat or drink during the process, washing hands afterwards with suitable cleaning products. D.- Technical recommendations to prevent environmental risks It is not necessary to take special measures to prevent environmental risks. For more information see subsection 6.2 7.2

Conditions for safe storage, including any incompatibilities: A.- Technical measures for storage Minimum Temp.:

5 ºC

Maximum Temp.:

25 ºC

Maximum time:

6 Months

B.- General conditions for storage Avoid sources of heat, radiation, static electricity and contact with food. For additional information see subsection 10.5 7.3

Specific end use(s): Except for the instructions already specified it is not necessary to provide any special recommendation regarding the uses of this product.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1

Control parameters: Substances whose occupational exposure limits have to be monitored in the workplace (EH40/2005 Workplace exposure limits): Nuisance dust: Inhalable dust 10 mg/m3 // Respirable dust 4 mg/m3 DNEL (Workers): Short exposure Identification

Systemic

Calcium sulfate

Oral

Non-applicable

CAS: 7778-18-9

Dermal

EC: 231-900-3

Inhalation

Local

Long exposure Systemic

Local

Non-applicable

5082 mg/m³

Non-applicable

21.17 mg/m³

Non-applicable

DNEL (General population): Short exposure Identification

Systemic

Local

Long exposure Systemic

Local

Calcium sulfate

Oral

Non-applicable

CAS: 7778-18-9

Dermal

EC: 231-900-3

Inhalation

Non-applicable

3811 mg/m³

Non-applicable

5.29 mg/m³

Non-applicable

Calcium sulfate

STP

100 mg/L

Fresh water

Non-applicable

CAS: 7778-18-9

Soil

Non-applicable

Marine water

Non-applicable

EC: 231-900-3

Intermittent

Non-applicable

Sediment (Fresh water)

Non-applicable

Oral

Non-applicable

Sediment (Marine water)

Non-applicable

PNEC: Identification

8.2

Exposure controls: A.- General security and hygiene measures in the work place

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SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continued) As a preventative measure it is recommended to use basic Personal Protective Equipment, with the corresponding <<CE marking>> in accordance with Directive 89/686/EC. For more information on Personal Protective Equipment (storage, use, cleaning, maintenance, class of protection,…) consult the information leaflet provided by the manufacturer. For more information see subsection 7.1. All information contained herein is a recommendation which needs some specification from the labour risk prevention services as it is not known whether the company has additional measures at its disposal. B.- Respiratory protection Pictogram

PPE

Labelling

Filter mask for particles

CEN Standard

Remarks

EN 149:2001+A1:2009

Replace when an increase in resistence to breathing is observed.

CEN Standard

Remarks

Compulsory use of face mask

C.- Specific protection for the hands Pictogram

PPE

Labelling

Replace gloves in case of any sign of damage. For prolonged periods of exposure to the product for professional users/industrials, we recommend using CE III gloves in line with standards EN 420 and EN 374.

Protective gloves against minor risks Mandatory hand protection

D.- Ocular and facial protection Pictogram

PPE

Labelling

Panoramic glasses against splash/projections.

CEN Standard

Remarks

EN 166:2001 EN ISO 4007:2012

Clean daily and disinfect periodically according to the manufacturer´s instructions. Use if there is a risk of splashing.

Mandatory face protection

E.- Body protection Pictogram

PPE

Labelling

CEN Standard

Remarks

Work clothing

Anti-slip work shoes

EN ISO 20347:2012

0 % weight

V.O.C. density at 20 ºC:

0 kg/m³ (0 g/L)

Average carbon number:

Non-applicable

Average molecular weight:

Non-applicable

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES *Not relevant due to the nature of the product, not providing information property of its hazards.

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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (continued) 9.1

Information on basic physical and chemical properties: For complete information see the product datasheet. Appearance: Physical state at 20 ºC:

Solid

Appearance:

Powdery

Colour:

Not available

Odour:

Not available

Odour threshold:

Non-applicable *

Volatility: Boiling point at atmospheric pressure:

Non-applicable *

Vapour pressure at 20 ºC:

Non-applicable *

Vapour pressure at 50 ºC:

Non-applicable *

Evaporation rate at 20 ºC:

Non-applicable *

Product description: Density at 20 ºC:

2964 kg/m³

Relative density at 20 ºC:

2.964

Dynamic viscosity at 20 ºC:

Non-applicable *

Kinematic viscosity at 20 ºC:

Non-applicable *

Kinematic viscosity at 40 ºC:

Non-applicable *

Concentration:

Non-applicable *

pH:

Non-applicable *

Vapour density at 20 ºC:

Non-applicable *

Partition coefficient n-octanol/water 20 ºC:

Non-applicable *

Solubility in water at 20 ºC:

Non-applicable *

Solubility properties:

Non-applicable *

Decomposition temperature:

Non-applicable *

Melting point/freezing point:

1450 ºC

Explosive properties:

Non-applicable *

Oxidising properties:

Non-applicable *

Flammability: Flash Point:

Non-applicable

Flammability (solid, gas):

Non-applicable *

Autoignition temperature:

Non-applicable *

Lower flammability limit:

Non-applicable *

Upper flammability limit:

Non-applicable *

Explosive:

9.2

Lower explosive limit:

Non-applicable *

Upper explosive limit:

Non-applicable *

Other information: Surface tension at 20 ºC:

Non-applicable *

Refraction index:

Non-applicable *

*Not relevant due to the nature of the product, not providing information property of its hazards.

SECTION 10: STABILITY AND REACTIVITY

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SECTION 10: STABILITY AND REACTIVITY (continued) 10.1 Reactivity: No hazardous reactions are expected because the product is stable under recommended storage conditions. See section 7. 10.2 Chemical stability: Chemically stable under the conditions of storage, handling and use. 10.3 Possibility of hazardous reactions: Under the specified conditions, hazardous reactions that lead to excessive temperatures or pressure are not expected. 10.4 Conditions to avoid: Applicable for handling and storage at room temperature: Shock and friction

Contact with air

Increase in temperature

Sunlight

Humidity

Not applicable

Acids

Water

Oxidising materials

Combustible materials

Others

Avoid strong acids

Not applicable

Avoid alkalis or strong bases

10.5 Incompatible materials:

SECTION 11: TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects: LD50 oral > 2000 mg/kg (rat) Dangerous health implications: In case of exposure that is repetitive, prolonged or at concentrations higher than the recommended occupational exposure limits, adverse effects on health may result, depending on the means of exposure: A- Ingestion (acute effect): - Acute toxicity : Based on available data, the classification criteria are not met - Corrosivity/Irritability: Based on available data, the classification criteria are not met B- Inhalation (acute effect): - Acute toxicity : Based on available data, the classification criteria are not met - Corrosivity/Irritability: Based on available data, the classification criteria are not met C- Contact with the skin and the eyes (acute effect): - Contact with the skin: Based on available data, the classification criteria are not met - Contact with the eyes: Based on available data, the classification criteria are not met D- CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction): - Carcinogenicity: Based on available data, the classification criteria are not met IARC: Non-applicable - Mutagenicity: Based on available data, the classification criteria are not met - Reproductive toxicity: Based on available data, the classification criteria are not met E- Sensitizing effects: - Respiratory: Based on available data, the classification criteria are not met - Cutaneous: Based on available data, the classification criteria are not met F- Specific target organ toxicity (STOT) - single exposure: Based on available data, the classification criteria are not met G- Specific target organ toxicity (STOT)-repeated exposure: - Specific target organ toxicity (STOT)-repeated exposure: Based on available data, the classification criteria are not met - Skin: Based on available data, the classification criteria are not met H- Aspiration hazard: - CONTINUED ON NEXT PAGE Page 6/9

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SECTION 11: TOXICOLOGICAL INFORMATION (continued) Based on available data, the classification criteria are not met Other information: Non-applicable Specific toxicology information on the substances: Identification

Acute toxicity

Calcium sulfate

LD50 oral

>2000 mg/kg

CAS: 7778-18-9

LD50 dermal

>2000 mg/kg

EC: 231-900-3

LC50 inhalation

>5 mg/L

Genus

SECTION 12: ECOLOGICAL INFORMATION 12.1 Toxicity: Not available 12.2 Persistence and degradability: Not available 12.3 Bioaccumulative potential: Not available 12.4 Mobility in soil: Not available 12.5 Results of PBT and vPvB assessment: Product fails to meet PBT/vPvB criteria 12.6 Other adverse effects: Not described

SECTION 13: DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods: Code

Description It is not possible to assign a specific code, as it depends on the intended use by the user

Waste class (Regulation (EU) No 1357/2014) Non dangerous

SECTION 14: TRANSPORT INFORMATION This product is not regulated for transport (ADR/RID,IMDG,IATA)

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FBJESB - Jesmonite Base Date of compilation: 23/04/2019

Version: 1

SECTION 15: REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture: Candidate substances for authorisation under the Regulation (EC) No 1907/2006 (REACH): Non-applicable Substances included in Annex XIV of REACH ("Authorisation List") and sunset date: Non-applicable Regulation (EC) No 1005/2009, about substances that deplete the ozone layer: Non-applicable Article 95, REGULATION (EU) No 528/2012: Non-applicable REGULATION (EU) No 649/2012, in relation to the import and export of hazardous chemical products: Non-applicable Seveso III: Non-applicable Limitations to commercialisation and the use of certain dangerous substances and mixtures (Annex XVII REACH, etc ….): Non-applicable Specific provisions in terms of protecting people or the environment: It is recommended to use the information included in this safety data sheet as a basis for conducting workplace-specific risk assessments in order to establish the necessary risk prevention measures for the handling, use, storage and disposal of this product. Other legislation: The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2009 (CDG 2009), SI 2009 No 1348 The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment (Amendment) Regulations 2011, 2011 No. 1885 Control of Substances Hazardous to Health Regulations 2002 (as amended) EH40/2005 Workplace exposure limits The Waste Regulations 2011, 2011 No. 988 15.2 Chemical safety assessment: The supplier has not carried out evaluation of chemical safety.

SECTION 16: OTHER INFORMATION Legislation related to safety data sheets: This safety data sheet has been designed in accordance with ANNEX II-Guide to the compilation of safety data sheets of Regulation (EC) No 1907/2006 (Regulation (EC) No 2015/830) Modifications related to the previous Safety Data Sheet which concerns the ways of managing risks.: Non-applicable Texts of the legislative phrases mentioned in section 3: The phrases indicated do not refer to the product itself; they are present merely for informative purposes and refer to the individual components which appear in section 3 CLP Regulation (EC) No 1272/2008: Non-applicable Advice related to training: Minimal training is recommended in order to prevent industrial risks for staff using this product and to facilitate their comprehension and interpretation of this safety data sheet, as well as the label on the product. Principal bibliographical sources: http://echa.europa.eu http://eur-lex.europa.eu Abbreviations and acronyms: ADR: European agreement concerning the international carriage of dangerous goods by road IMDG: International maritime dangerous goods code IATA: International Air Transport Association ICAO: International Civil Aviation Organisation COD: Chemical Oxygen Demand BOD5: 5-day biochemical oxygen demand BCF: Bioconcentration factor LD50: Lethal Dose 50 LC50: Lethal Concentration 50 EC50: Effective concentration 50 Log-POW: Octanol-water partition coefficient Koc: Partition coefficient of organic carbon - CONTINUED ON NEXT PAGE Page 8/9

Product safety information sheet according to REACH (article 32)

FBJESB - Jesmonite Base Date of compilation: 23/04/2019

Version: 1

- END OF SAFETY DATA SHEET Page 9/9

PATINA DEPT

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 31.07.2020

Version: 7.2

Print date: 31.07.2020

SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name/designation: Product No.: CAS No.: Index No.: REACH No.: Other means of identification:

Ammonium sulphide 20% in aqueous solution GPR RECTAPUR® 21352 not applicable not applicable This product is a mixture. REACH registration numbers see section 3. none

1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses:

General chemical reagent

1.3 Details of the supplier of the safety data sheet

United Kingdom VWR International Ltd. Street Postal code/City Telephone Telefax: E-mail (competent person)

Hunter Boulevard, Magna Park Lutterworth, LE17 4XN 0800 22 33 44 01455 55 85 86 SDS@vwr.com

1.4 Emergency phone number Telephone

+44 (0) 1270 502894 (CareChem24)

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SECTION 2: Hazard identification 2.1 2.1.1

Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [CLP]

Hazard classes and hazard categories Flammable liquid, category 2 Skin corrosion, category 1B

2.2 2.2.1

Hazard statements H225 H314

Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP]

Hazard pictograms

Signal word: Danger Hazard statements H225 H314 EUH031 Precautionary statements P210 P243 P280 P301+P330+P331 P302+P352 P304+P340 P305+P351+P338 P308+P310 P403+P235

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Contact with acids liberates toxic gas.

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Take precautionary measures against static discharge. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. IF ON SKIN: Wash with plenty of water/… IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Immediately call a POISON CENTER/doctor. Store in a well-ventilated place. Keep cool.

2.3 Other hazards The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.

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SECTION 3: Composition / information on ingredients 3.1 Substances not applicable

3.2 Mixtures Hazardous ingredients Classification according to Regulation (EC) No 1272/2008 [CLP] Substance name Ammonium sulphide

Concentration 15 - 25%

Identifier

Hazard classes and hazard categories

CAS No.: 12135-76-1 EC No.: 235-223-4 REACH No.: Not yet communicated down the supply chain.

Flam. Liq. 2 - H225 Skin Corr. 1B - H314

SECTION 4: First aid measures 4.1 General information IF exposed: Immediately call a POISON CENTRE/doctor. If unconscious but breathing normally, place in recovery position and seek medical advice. Never give anything by mouth to an unconscious person or a person with cramps. Change contaminated, saturated clothing. Do not leave affected person unattended.

After inhalation Immediately call a POISON CENTRE/doctor. Remove casualty to fresh air and keep warm and at rest. If breathing is irregular or stopped, administer artificial respiration.

In case of skin contact After contact with skin, wash immediately with plenty of water and soap. Remove contaminated, saturated clothing immediately. Immediate medical treatment required because corrosive injuries that are not treated are hard to cure.

After eye contact In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist. Protect uninjured eye. Remove contact lenses, if present and easy to do. Continue rinsing.

In case of ingestion Immediately call a POISON CENTRE/doctor. Do NOT induce vomiting. Rinse mouth thoroughly with water. Give nothing to eat or drink.

Self-protection of the first aider First aider: Pay attention to self-protection!

4.2 Most important symptoms and effects, both acute and delayed no data available

4.3 Indication of any immediate medical attention and special treatment needed no data available

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SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media Water spray ABC-powder Carbon dioxide (CO2) Nitrogen Extinguishing media which must not be used for safety reasons no restriction

5.2 Special hazards arising from the substance or mixture In case of fire may be liberated: Pyrolysis products, toxic

5.3 Advice for firefighters DO NOT fight fire when fire reaches explosives. Special protective equipment for firefighters Wear a self-contained breathing apparatus and chemical protective clothing.

Additional information Do not allow run-off from fire-fighting to enter drains or water courses. Do not inhale explosion and combustion gases. Use caution when applying carbon dioxide in confined spaces. Carbon dioxide can displace oxygen. Use water spray jet to protect personnel and to cool endangered containers. In case of fire: Evacuate area.

SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures In case of major fire and large quantities: Remove persons to safety.

6.2 Environmental precautions Discharge into the environment must be avoided.

6.3 Methods and material for containment and cleaning up Spilled product must never be returned to the original container for recycling. Collect in closed and suitable containers for disposal.

6.4 Additional information Clear spills immediately.

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SECTION 7: Handling and storage 7.1 Precautions for safe handling All work processes must always be designed so that the following is as low as possible: Inhalation skin contact Eye contact Use extractor hood (laboratory). If handled uncovered, arrangements with local exhaust ventilation have to be used. If local exhaust ventilation is not possible or not sufficient, the entire working area must be ventilated by technical means.

7.2 Conditions for safe storage, including any incompatibilities Recommended storage temperature: no data available Storage class: no data available Keep container tightly closed and in a well-ventilated place. Keep/Store only in original container.

7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated.

SECTION 8: Exposure controls/personal protection 8.1

Control parameters Does not contain substances above concentration limits fixing an occupational exposure limit.

8.2

Exposure controls

8.2.1

Appropriate engineering controls Technical measures and the application of suitable work processes have priority over personal protection equipment. If handled uncovered, arrangements with local exhaust ventilation have to be used.

8.2.2

Personal protection equipment Wear suitable protective clothing. When handling with chemical substances, protective clothing with CE-labels including the four control digits must be worn. Eye/face protection Eye glasses with side protection DIN-/EN-Norms: DIN EN 166 Recommendation: VWR 111-0432 Skin protection When handling with chemical substances, protective gloves must be worn with the CE-label including the four control digits. Recommended glove articles DIN-/EN-Norms EN ISO 374 In the case of wanting to use the gloves again, clean them before taking off and air them well. By short-term hand contact Suitable material: Thickness of the glove material: Breakthrough time:: Recommended glove articles:

NBR (Nitrile rubber) 0,12 mm > 480 min VWR 112-0998

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By long-term hand contact Suitable material: Thickness of the glove material: Breakthrough time:: Recommended glove articles:

NBR (Nitrile rubber) 0,12 mm > 480 min VWR 112-0998

Respiratory protection Respiratory protection necessary at: aerosol or mist formation Suitable respiratory protection apparatus: Full-/half-/quarter-face masks (DIN EN 136/140) Recommendation: VWR 111-0206 Suitable material: ABEK2P3 Recommendation: VWR 111-0059

Additional information Wash hands before breaks and after work. Avoid contact with eyes and skin. When using do not eat, drink or smoke. Provide eye shower and label its location conspicuously. 8.2.3

Environmental exposure controls no data available

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SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties (a) Appearance Physical state: Colour: (b) Odour: (c) Odour threshold:

liquid yellow characteristic no data available

Safety relevant basic data (d) pH: (e) Melting point/freezing point: (f) Initial boiling point and boiling range: (g) Flash point: (h) Evaporation rate: (i) Flammability (solid, gas): (j) Flammability or explosive limits Lower explosion limit: Upper explosion limit: (k) Vapour pressure: (l) Vapour density: (m) Relative density: (n) Solubility(ies) Water solubility: Soluble (g/L) in Ethanol: (o) Partition coefficient: n-octanol/water: (p) Auto-ignition temperature: (q) Decomposition temperature: (r) Viscosity Kinematic viscosity: Dynamic viscosity: (s) Explosive properties: (t) Oxidising properties:

no data available no data available no data available 15 °C (closed cup) no data available Highly flammable liquid and vapour. 4 % (v/v) 46 % (v/v) 450 hPa (20 °C) no data available 0.997 g/cm³ (20 °C) soluble (20°C) no data available no data available no data available 20 °C (1013 hPa) no data available no data available not applicable not applicable

9.2 Other information Bulk density: Refraction index: Dissociation constant: Surface tension: Henry's Law Constant:

no data available no data available no data available no data available no data available

SECTION 10: Stability and reactivity 10.1 Reactivity no data available

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10.2 Chemical stability The product is chemically stable under standard ambient conditions (room temperature).

10.3 Possibility of hazardous reactions no data available

10.4 Conditions to avoid no data available

10.5 Incompatible materials no data available

10.6 Hazardous decomposition products no data available

10.7 Additional information no data available

SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute effects Acute oral toxicity: no data available Acute dermal toxicity: no data available Acute inhalation toxicity: no data available Irritant and corrosive effects Primary irritation to the skin: Causes severe skin burns and eye damage. Irritation to eyes: Causes serious eye damage. Irritation to respiratory tract: not applicable

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Respiratory or skin sensitisation In case of skin contact: not sensitising After inhalation: not sensitising STOT-single exposure not applicable STOT-repeated exposure not applicable CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction) Carcinogenicity No indication of human carcinogenicity. Germ cell mutagenicity No indications of human germ cell mutagenicity exist. Reproductive toxicity No indications of human reproductive toxicity exist. Aspiration hazard not applicable Other adverse effects no data available Additional information no data available

SECTION 12: Ecological information 12.1 Ecotoxicity Fish toxicity: no data available Daphnia toxicity: no data available Algae toxicity: no data available Bacteria toxicity: no data available

12.2 Persistence and degradability no data available

12.3 Bioaccumulative potential Partition coefficient: n-octanol/water: no data available

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12.4 Mobility in soil: no data available

12.5 Results of PBT/vPvB assessment The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.

12.6 Other adverse effects no data available

SECTION 13: Disposal considerations 13.1 Waste treatment methods Appropriate disposal / Product Dispose according to local legislation. Consult the appropriate local waste disposal expert about waste disposal. Waste code product: no data available Appropriate disposal / Package Dispose according to local legislation. Handle contaminated packages in the same way as the substance itself. Additional information no data available

SECTION 14: Transport information Land transport (ADR/RID) 14.1 14.2 14.3

14.4 14.5 14.6

UN-No.: Proper Shipping Name: Class(es): Classification code: Hazard label(s): Packing group: Environmental hazards: Special precautions for user: Hazard identification number (Kemler No.): tunnel restriction code:

2683 AMMONIUM SULPHIDE SOLUTION 8 (3, 6.1) CFT 8+3+6.1 II No 86 D/E (Passage forbidden through tunnels of category D when carried in bulk or in tanks. Passage forbidden through tunnels of category E.)

Sea transport (IMDG) 14.1 14.2 14.3

14.4

UN-No.: Proper Shipping Name: Class(es): Classification code: Hazard label(s): Packing group:

2683 AMMONIUM SULPHIDE SOLUTION 8 (3, 6.1) 8+3+6.1 II

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14.5 14.6

14.7

Environmental hazards: No Marine pollutant: No Special precautions for user: Segregation group: 2,18 EmS-No. F-E S-C Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code not relevant

Air transport (ICAO-TI / IATA-DGR) 14.1 14.2 14.3

14.4 14.5

UN-No.: Proper Shipping Name: Class(es): Classification code: Hazard label(s): Packing group: Special precautions for user:

2683 AMMONIUM SULPHIDE SOLUTION 8 (3, 6.1) 8+3+6.1 II

SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EU legislation - Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC (Text with EEA relevance) - Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 (Text with EEA relevance) - Commission Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (Text with EEA relevance) - Commission Regulation (EU) 2015/830 of 28 May 2015 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) Use restriction according to REACH annex XVII: - Number: 10 (Ammonium sulphide)

National regulations no data available Water hazard class:

hazardous to water (WGK 2)

15.2 Chemical Safety Assessment Chemical safety assessments for substances in this mixture were not carried out.

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SECTION 16: Other information Abbreviations and acronyms H225 - Highly flammable liquid and vapour. H314 - Causes severe skin burns and eye damage. ACGIH - American Conference of Governmental Industrial Hygiensts ADR - European Agreement concerning the International Carriage of Dangerous Goods by Road AGS - Committee on Hazardous Substances (Ausschuss für Gefahrstoffe) CLP - Regulation on Classification, Labelling and Packaging of Substances and Mixtures DFG - German Research Foundation (Deutsche Forschungsgemeinschaft) Gestis - Information system on hazardous substances of the German Social Accident Insurance (Gefahrstoffinformationssystem der Deutschen Gesetzlichen Unfallversicherung) IATA-DGR - International Air Transport Association-Dangerous Goods Regulations ICAO-TI - International Civil Aviation Organization-Technical Instructions IMDG - International Maritime Code for Dangerous Goods LTV - Long Term Value NIOSH - National Institute for Occupational Safety and Health OSHA - Occupational Safety & Health Administration PBT - Persistent, Bioaccumulative and Toxic RID - Regulation concerning the International Carriage of Dangerous Goods by Rail STV - Short Term Value SVHC - Substances of Very High Concern vPvB - very Persistent, very Bioaccumulative Training advice: Provide adequate information, instruction and training for operators.

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Classification according to Regulation (EC) No 1272/2008 [CLP] - Classification procedure Hazard statements

Hazard classes and hazard categories

Classification procedure

H225

Flam. Liq. 2

Data obtained by expert judgement.

H314

Skin Corr. 1B

Calculation method.

EUH031

Data obtained by expert judgement.

Additional information Indication of changes

general update If you need an explanation of the change, contact the supplier. (SDS@avantorsciences.com)

The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material.

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Revision date: 10/12/2018

Revision: 3

Supersedes date: 06/12/2010

SAFETY DATA SHEET SILVER NITRATE LRG According to Regulation (EC) No 1907/2006, Annex II, as amended.Commission Regulation (EU) No 2015/830 of 28 May 2015.

SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name

SILVER NITRATE LRG

Product number

1542

REACH registration number

01-2119513705-43-0000

CAS number

7761-88-8

EU index number

047-001-00-2

EC number

231-853-9

1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses

Laboratory reagent.

Uses advised against

No specific uses advised against are identified.

1.3. Details of the supplier of the safety data sheet Supplier Reagent Chemical Services 11b - 13 Aston Fields Road Whitehouse Industrial Estate Runcorn Cheshire WA7 3DL T: 01928 716903 (08.30 - 17.00) F: 01928 716425 E: info@reagent.co.uk 1.4. Emergency telephone number Emergency telephone

OHES Environmental Ltd 24-7 Tel. 0333 333 9939 (24 hour)

SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards

Ox. Sol. 2 - H272 Met. Corr. 1 - H290

Health hazards

Skin Corr. 1B - H314 Eye Dam. 1 - H318

Environmental hazards

Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410

2.2. Label elements EC number

231-853-9

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SILVER NITRATE LRG Pictogram

Signal word

Danger

Hazard statements

H272 May intensify fire; oxidiser. H290 May be corrosive to metals. H314 Causes severe skin burns and eye damage. H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements

P220 Keep away from combustible materials. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P273 Avoid release to the environment. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P501 Dispose of contents/ container in accordance with national regulations.

Supplementary precautionary P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No statements smoking. P221 Take any precaution to avoid mixing with combustibles. P234 Keep only in original container. P260 Do not breathe dust. P264 Wash hands thoroughly after handling. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P310 Immediately call a POISON CENTER/ doctor. P321 Specific treatment (see medical advice on this label). P370+P378 In case of fire: Use dry powder, dry sand or dry earth to extinguish. P391 Collect spillage. P363 Wash contaminated clothing before reuse. 2.3. Other hazards This substance is not classified as PBT or vPvB according to current EU criteria. SECTION 3: Composition/information on ingredients 3.1. Substances Product name

SILVER NITRATE LRG

REACH registration number

01-2119513705-43-0000

EU index number

047-001-00-2

CAS number

7761-88-8

EC number

231-853-9

SECTION 4: First aid measures 4.1. Description of first aid measures General information

Get medical attention immediately. Show this Safety Data Sheet to the medical personnel. Chemical burns must be treated by a physician.

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SILVER NITRATE LRG Inhalation

Remove affected person from source of contamination. Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. Place unconscious person on their side in the recovery position and ensure breathing can take place. Get medical attention.

Ingestion

Never give anything by mouth to an unconscious person. Rinse mouth thoroughly with water. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention immediately.

Skin contact

Take off immediately all contaminated clothing. Rinse immediately with plenty of water. Continue to rinse for at least 15 minutes and get medical attention. Chemical burns must be treated by a physician.

Eye contact

Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. Continue to rinse for at least 10 minutes. Get medical attention immediately.

Protection of first aiders

First aid personnel should wear appropriate protective equipment during any rescue.

4.2. Most important symptoms and effects, both acute and delayed General information

The severity of the symptoms described will vary dependent on the concentration and the length of exposure.

Inhalation

Symptoms following overexposure may include the following: Severe irritation of nose and throat. Corrosive to the respiratory tract.

Ingestion

May cause chemical burns in mouth, oesophagus and stomach. Severe stomach pain. Nausea, vomiting.

Skin contact

Causes severe burns. Pain or irritation. Redness.

Eye contact

Causes serious eye damage. Symptoms following overexposure may include the following: Pain. Profuse watering of the eyes. Redness.

4.3. Indication of any immediate medical attention and special treatment needed Notes for the doctor

Treat symptomatically.

Specific treatments

No specific chemical antidote is known to be required after exposure to this product.

SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media

The product is not flammable. Use fire-extinguishing media suitable for the surrounding fire. Recommended method is to flood with plenty of water if practical and safe to do so. Do not use water jet as an extinguisher, as this will spread the fire.

Unsuitable extinguishing media

Do not use water jet as an extinguisher, as this will spread the fire.

5.2. Special hazards arising from the substance or mixture Specific hazards

May cause or intensify fire; oxidiser. Severe corrosive hazard. Water used for fire extinguishing, which has been in contact with the product, may be corrosive.

Hazardous combustion products

Thermal decomposition or combustion products may include the following substances: Toxic and corrosive gases or vapours. Nitrous gases (NOx).

5.3. Advice for firefighters

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SILVER NITRATE LRG Protective actions during firefighting

Avoid breathing fire gases or vapours. Evacuate area. Keep upwind to avoid inhalation of gases, vapours, fumes and smoke. May cause or intensify fire; oxidiser. Cool containers exposed to heat with water spray and remove them from the fire area if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out. Avoid discharge to the aquatic environment. Control run-off water by containing and keeping it out of sewers and watercourses. If risk of water pollution occurs, notify appropriate authorities.

Special protective equipment for firefighters

Regular protection may not be safe. Wear chemical protective suit. Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. Firefighter's clothing conforming to European standard EN469 (including helmets, protective boots and gloves) will provide a basic level of protection for chemical incidents.

SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions

No action shall be taken without appropriate training or involving any personal risk. Keep unnecessary and unprotected personnel away from the spillage. Wear protective clothing as described in Section 8 of this safety data sheet. Follow precautions for safe handling described in this safety data sheet. Wash thoroughly after dealing with a spillage. Ensure procedures and training for emergency decontamination and disposal are in place. Do not touch or walk into spilled material. Avoid inhalation of dust. Use suitable respiratory protection if ventilation is inadequate. Avoid contact with skin and eyes. Avoid contact with contaminated tools and objects.

6.2. Environmental precautions Environmental precautions

Avoid discharge into drains or watercourses or onto the ground. Avoid discharge to the aquatic environment. Large Spillages: Inform the relevant authorities if environmental pollution occurs (sewers, waterways, soil or air).

6.3. Methods and material for containment and cleaning up Methods for cleaning up

Wear protective clothing as described in Section 8 of this safety data sheet. Clear up spills immediately and dispose of waste safely. Do not use sawdust or other combustible material. This product is corrosive. Approach the spillage from upwind. Collect spillage with a shovel and broom, or similar and reuse, if possible. Collect and place in suitable waste disposal containers and seal securely. Flush contaminated area with plenty of water. Wash thoroughly after dealing with a spillage. May generate heat. Dangerous for the environment. Do not empty into drains. Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority.

6.4. Reference to other sections Reference to other sections

For personal protection, see Section 8. See Section 11 for additional information on health hazards. See Section 12 for additional information on ecological hazards. For waste disposal, see Section 13.

SECTION 7: Handling and storage 7.1. Precautions for safe handling Usage precautions

Read and follow manufacturer's recommendations. Wear protective clothing as described in Section 8 of this safety data sheet. Keep away from food, drink and animal feeding stuffs. Keep container tightly sealed when not in use. This product is corrosive. Immediate first aid is imperative. Avoid discharge to the aquatic environment. Do not handle until all safety precautions have been read and understood. Do not handle broken packages without protective equipment. Do not reuse empty containers.

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SILVER NITRATE LRG Advice on general occupational hygiene

Wash promptly if skin becomes contaminated. Take off contaminated clothing. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Wash at the end of each work shift and before eating, smoking and using the toilet. Change work clothing daily before leaving workplace.

7.2. Conditions for safe storage, including any incompatibilities Storage precautions

Store away from incompatible materials (see Section 10). Store in accordance with local regulations. Keep away from flammable and combustible materials. Keep only in the original container. Keep container tightly closed, in a cool, well ventilated place. Keep containers upright. Protect containers from damage. Store in corrosive resistant container with a resistant inner liner. Bund storage facilities to prevent soil and water pollution in the event of spillage. The storage area floor should be leak-tight, jointless and not absorbent.

Storage class

Oxidiser storage.

7.3. Specific end use(s) Specific end use(s)

The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure Controls/personal protection 8.1. Control parameters Occupational exposure limits Long-term exposure limit (8-hour TWA): WEL

0.01 As Ag mg/m³

WEL = Workplace Exposure Limit DNEL

Workers - Inhalation; Long term systemic effects: 0.016 mg/m³ General population - Inhalation; Long term systemic effects: 0.006 mg/m³ General population - Oral; Long term systemic effects: 0.02 mg/kg/day

PNEC

- Fresh water; 0.00004 mg/l - Marine water; 0.00086 mg/l - STP; 0.025 mg/l - Sediment (Freshwater); 438.13 mg/kg - Sediment (Marinewater); 438.13 mg/kg - Soil; 1.41 mg/kg

8.2. Exposure controls Protective equipment

Appropriate engineering controls

Provide adequate ventilation. Personal, workplace environment or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Use process enclosures, local exhaust ventilation or other engineering controls as the primary means to minimise worker exposure. Personal protective equipment should only be used if worker exposure cannot be controlled adequately by the engineering control measures. Ensure control measures are regularly inspected and maintained. Ensure operatives are trained to minimise exposure.

Eye/face protection

Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. Personal protective equipment for eye and face protection should comply with European Standard EN166. Wear tight-fitting, chemical splash goggles or face shield. If inhalation hazards exist, a full-face respirator may be required instead.

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Supersedes date: 06/12/2010

SILVER NITRATE LRG Hand protection

Chemical-resistant, impervious gloves complying with an approved standard should be worn if a risk assessment indicates skin contact is possible. To protect hands from chemicals, gloves should comply with European Standard EN374. Considering the data specified by the glove manufacturer, check during use that the gloves are retaining their protective properties and change them as soon as any deterioration is detected. The selected gloves should have a breakthrough time of at least 8 hours. It is recommended that gloves are made of the following material: Butyl rubber. Nitrile rubber. Thickness: ≤ 0.2 mm The most suitable glove should be chosen in consultation with the glove supplier/manufacturer, who can provide information about the breakthrough time of the glove material. Frequent changes are recommended.

Other skin and body protection

Appropriate footwear and additional protective clothing complying with an approved standard should be worn if a risk assessment indicates skin contamination is possible.

Hygiene measures

Provide eyewash station and safety shower. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Clean equipment and the work area every day. Good personal hygiene procedures should be implemented. Wash at the end of each work shift and before eating, smoking and using the toilet. When using do not eat, drink or smoke. Preventive industrial medical examinations should be carried out. Warn cleaning personnel of any hazardous properties of the product.

Respiratory protection

Respiratory protection complying with an approved standard should be worn if a risk assessment indicates inhalation of contaminants is possible. Ensure all respiratory protective equipment is suitable for its intended use and is ‘CE’-marked. Check that the respirator fits tightly and the filter is changed regularly. Gas and combination filter cartridges should comply with European Standard EN14387. Full face mask respirators with replaceable filter cartridges should comply with European Standard EN136. Half mask and quarter mask respirators with replaceable filter cartridges should comply with European Standard EN140.

Environmental exposure controls

Keep container tightly sealed when not in use. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

SECTION 9: Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Appearance

Crystalline solid.

Colour

Colourless.

Odour

Odourless.

Odour threshold

Not determined.

pH (concentrated solution): ~7

Melting point

212°C

Initial boiling point and range

Not determined.

Flash point

Scientifically unjustified.

Evaporation rate

Not determined.

Flammability (solid, gas)

No specific test data are available.

Upper/lower flammability or explosive limits

No specific test data are available.

Vapour pressure

Scientifically unjustified.

Vapour density

Not determined. 6/12

Revision date: 10/12/2018

Revision: 3

Supersedes date: 06/12/2010

SILVER NITRATE LRG Relative density

4.35 @ 20°C

Solubility(ies)

> 710 g/l water @ 25°C

Partition coefficient

Scientifically unjustified.

Auto-ignition temperature

Scientifically unjustified.

Decomposition Temperature

~440°C

Viscosity

Scientifically unjustified.

Explosive properties

Scientifically unjustified. Not considered to be explosive.

Oxidising properties

Ox. Sol. 1 (mean burning time < that of a 3:2 mixture, by mass of potassium bromate and cellulose).

9.2. Other information Other information

None.

Molecular weight

169.87

SECTION 10: Stability and reactivity 10.1. Reactivity Reactivity

The following materials may react with the product: Reducing agents. Ammonia Flammable/combustible materials.

10.2. Chemical stability Stability

Stable at normal ambient temperatures and when used as recommended. Stable under the prescribed storage conditions.

10.3. Possibility of hazardous reactions Possibility of hazardous reactions

May generate heat. Will not polymerise.

10.4. Conditions to avoid Conditions to avoid

Avoid heat. Freezing. Avoid generation and spreading of dust. Avoid the accumulation of dust. Avoid contact with the following materials: Reducing agents.

10.5. Incompatible materials Materials to avoid

Reducing agents. Flammable/combustible materials. May be corrosive to metals.

10.6. Hazardous decomposition products Hazardous decomposition products

Does not decompose when used and stored as recommended.

SECTION 11: Toxicological information 11.1. Information on toxicological effects Toxicological effects

The toxicity of this substance has been assessed during REACH registration.

Acute toxicity - oral Notes (oral LD₅₀)

Based on available data the classification criteria are not met. LD₅₀ >2000 mg/kg, Oral, Rat

Acute toxicity - dermal Notes (dermal LD₅₀)

Based on available data the classification criteria are not met. LD₅₀ >2000 mg/kg, Dermal, Rat

Acute toxicity - inhalation

7/12

Revision date: 10/12/2018

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SILVER NITRATE LRG Notes (inhalation LC₅₀)

Based on available data the classification criteria are not met. LC50 >750µg/m3 @ 4hrs , Inhalation, Rat

Skin corrosion/irritation Skin corrosion/irritation

Corrosive to skin.

Animal data

Skin Corr. 1B - H314 Causes severe burns.

Serious eye damage/irritation Serious eye damage/irritation

Eye Dam. 1 - H318 Corrosive to skin. Corrosivity to eyes is assumed.

Respiratory sensitisation Respiratory sensitisation

Based on available data the classification criteria are not met.

Skin sensitisation Skin sensitisation

Based on available data the classification criteria are not met.

Germ cell mutagenicity Genotoxicity - in vitro

Based on available data the classification criteria are not met.

Genotoxicity - in vivo

Based on available data the classification criteria are not met.

Carcinogenicity Carcinogenicity

Based on available data the classification criteria are not met.

IARC carcinogenicity

None of the ingredients are listed or exempt.

Reproductive toxicity Reproductive toxicity - fertility

Based on available data the classification criteria are not met.

Reproductive toxicity development

Based on available data the classification criteria are not met.

Specific target organ toxicity - single exposure STOT - single exposure

Not classified as a specific target organ toxicant after a single exposure.

Specific target organ toxicity - repeated exposure STOT - repeated exposure

Not classified as a specific target organ toxicant after repeated exposure.

Aspiration hazard Aspiration hazard

Not relevant. Solid.

General information

The severity of the symptoms described will vary dependent on the concentration and the length of exposure.

Inhalation

Severe irritation of nose and throat. Symptoms following overexposure may include the following: Corrosive to the respiratory tract. Chemical burns.

Ingestion

Nausea, vomiting. Severe stomach pain. Symptoms following overexposure may include the following: May cause chemical burns in mouth, oesophagus and stomach.

Skin contact

Pain or irritation. Redness. Symptoms following overexposure may include the following: Causes severe burns. Blistering may occur.

Eye contact

Causes serious eye damage. Symptoms following overexposure may include the following: Pain. Profuse watering of the eyes. Redness.

Route of entry

Ingestion Inhalation Skin and/or eye contact

Target organs

No specific target organs known.

8/12

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SILVER NITRATE LRG SECTION 12: Ecological Information Ecotoxicity

Very toxic to aquatic life with long lasting effects.

12.1. Toxicity Toxicity

Aquatic Acute 1 - H400 Very toxic to aquatic life. Aquatic Chronic 1 - H410 Very toxic to aquatic life with long lasting effects.

Acute aquatic toxicity LE(C)₅₀

0.0001 < L(E)C50 ≤ 0.001

M factor (Acute)

1000

Acute toxicity - fish

LC₅₀, 96 hours: 0.00012 mg/l, Pimephales promelas (Fat-head Minnow)

Acute toxicity - aquatic invertebrates

LC₅₀, 48 hours: 0.00022 mg/l, Daphnia magna

Acute toxicity microorganisms

NOEC, : 0.025 mg/l,

Chronic aquatic toxicity M factor (Chronic)

100

Chronic toxicity - fish early life EC₀, 217 days: 0.19 µg/L, stage Chronic toxicity - aquatic invertebrates

, 21 days: EC10 = 2.14µg/L Silver , Daphnia magna

12.2. Persistence and degradability Persistence and degradability The product contains inorganic substances which are not biodegradable. Stability (hydrolysis)

Scientifically unjustified.

12.3. Bioaccumulative potential Bioaccumulative potential

BCF: ~ 70, Cyprinus carpio (Common carp)

Partition coefficient

Scientifically unjustified.

12.4. Mobility in soil Mobility

The product is water-soluble and may spread in water systems.

Adsorption/desorption coefficient

Soil - : Kd = 4023 L/kg (Median) @ °C

12.5. Results of PBT and vPvB assessment Results of PBT and vPvB assessment

This substance is not classified as PBT or vPvB according to current EU criteria.

12.6. Other adverse effects Other adverse effects

None known.

SECTION 13: Disposal considerations 13.1. Waste treatment methods

9/12

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SILVER NITRATE LRG General information

The generation of waste should be minimised or avoided wherever possible. Reuse or recycle products wherever possible. This material and its container must be disposed of in a safe way. Disposal of this product, process solutions, residues and by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any local authority requirements. When handling waste, the safety precautions applying to handling of the product should be considered. Care should be taken when handling emptied containers that have not been thoroughly cleaned or rinsed out. Empty containers or liners may retain some product residues and hence be potentially hazardous.

Disposal methods

Do not empty into drains. Dispose of surplus products and those that cannot be recycled via a licensed waste disposal contractor. Waste, residues, empty containers, discarded work clothes and contaminated cleaning materials should be collected in designated containers, labelled with their contents. Incineration or landfill should only be considered when recycling is not feasible.

SECTION 14: Transport information General

For limited quantity packaging/limited load information, consult the relevant modal documentation using the data shown in this section.

14.1. UN number UN No. (ADR/RID)

1493

UN No. (IMDG)

1493

UN No. (ICAO)

1493

UN No. (ADN)

1493

14.2. UN proper shipping name Proper shipping name (ADR/RID)

SILVER NITRATE

Proper shipping name (IMDG) SILVER NITRATE Proper shipping name (ICAO) SILVER NITRATE Proper shipping name (ADN)

SILVER NITRATE

14.3. Transport hazard class(es) ADR/RID class

5.1

ADR/RID classification code

ADR/RID label

5.1

IMDG class

5.1

ICAO class/division

5.1

ADN class

5.1

Transport labels

14.4. Packing group ADR/RID packing group

IMDG packing group

II 10/12

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Supersedes date: 06/12/2010

SILVER NITRATE LRG ADN packing group

ICAO packing group

14.5. Environmental hazards Environmentally hazardous substance/marine pollutant

14.6. Special precautions for user Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. EmS

F-A, S-Q

ADR transport category

Hazard Identification Number (ADR/RID)

Tunnel restriction code

(E)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code Transport in bulk according to Not applicable. Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations

Health and Safety at Work etc. Act 1974 (as amended). The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2009 (SI 2009 No. 1348) (as amended) ["CDG 2009"]. EH40/2005 Workplace exposure limits.

EU legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (as amended). Commission Regulation (EU) No 2015/830 of 28 May 2015. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures (as amended).

Authorisations (Title VII Regulation 1907/2006)

No specific authorisations are known for this product.

Restrictions (Title VIII Regulation 1907/2006)

No specific restrictions on use are known for this product.

15.2. Chemical safety assessment No chemical safety assessment has been carried out. Inventories EU - EINECS/ELINCS None of the ingredients are listed or exempt. SECTION 16: Other information 11/12

Revision date: 10/12/2018

Revision: 3

Supersedes date: 06/12/2010

SILVER NITRATE LRG Abbreviations and acronyms used in the safety data sheet

ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road. ADN: European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways. RID: European Agreement concerning the International Carriage of Dangerous Goods by Rail. IATA: International Air Transport Association. ICAO-TI: Technical Instructions for the Safe Transport of Dangerous Goods by Air. IMDG: International Maritime Dangerous Goods. CAS: Chemical Abstracts Service. ATE: Acute Toxicity Estimate. LC₅₀: Lethal Concentration to 50 % of a test population. LD₅₀: Lethal Dose to 50% of a test population (Median Lethal Dose). EC₅₀: 50% of maximal Effective Concentration. PBT: Persistent, Bioaccumulative and Toxic substance. vPvB: Very Persistent and Very Bioaccumulative.

Classification abbreviations and acronyms

Met. Corr. = Corrosive to metals Ox. Sol. = Oxidising solid Eye Dam. = Serious eye damage Skin Corr. = Skin corrosion Aquatic Acute = Hazardous to the aquatic environment (acute) Aquatic Chronic = Hazardous to the aquatic environment (chronic)

General information

This datasheet is not intended to be a replacement for a full risk assessment, these should always be carried out by competent persons.

Key literature references and sources for data

Source: European Chemicals Agency, http://echa.europa.eu/

Classification procedures according to Regulation (EC) 1272/2008

Eye Dam. 1 - H318: Skin Corr. 1B - H314: : Expert judgement. Aquatic Acute 1 - H400: Aquatic Chronic 1 - H410: : Expert judgement. Met. Corr. 1 - H290: Ox. Sol. 2 - H272: : Expert judgement.

Training advice

Only trained personnel should use this material.

Revision comments

Full revision

Revision date

10/12/2018

Revision

Supersedes date

06/12/2010

SDS number

20642

Hazard statements in full

H272 May intensify fire; oxidiser. H290 May be corrosive to metals. H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects.

This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 12/12

Safety Data Sheet According to regulation (EC) No. 1907/2006 (REACH)

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Version: 2

Identification of the Substance/Mixture and of the Company/Undertaking

1. 1.

Product Identifier

1. 2.

Product Name:

Burnt Umber, dark brown

Article No.:

40720

Printed: 27.09.2019

Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Coloring agent Uses advised against:

1. 3.

1. 4.

Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company:

Kremer Pigmente GmbH & Co. KG

Address:

Hauptstr. 41-47, 88317 Aichstetten, Germany

Tel./Fax.:

Tel +49 7565 914480, Fax +49 7565 1606

Internet:

www.kremer-pigmente.com

EMail:

info@kremer-pigmente.com

Importer:

Emergency No. Emergency No.:

1. 4. 2

Poison Center:

Hazards Identification

2. 1.

Classification of the Substance or Mixture

+49 7565 914480 (Mon-Fri 8:00 - 17:00)

Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) This product does not require classification and labelling as hazardous according to CLP/GHS. Possible Environmental Effects: 2. 2.

Label Elements Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) This product does not require classification and labelling as hazardous according to CLP/GHS. Hazard designation: Not applicable. Signal word: Hazard designation: Safety designation: Hazardous components for labelling:

2. 3.

Other Hazards

Composition/Information on Ingredients

3. 1.

Substance next page:

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Mixture Chemical Characterization:

Natural brown earth. Pigment Brown 7. CAS No. 12713-03-0

Information on Components / Hazardous Ingredients: Additional information:

First Aid Measures

4. 1.

Description of the First Aid Measures General information: No special measures required. After inhalation: Take affected person to fresh air. After skin contact: Wash with soap and rinse with plenty of water. After eye contact: Rinse open eyes with plenty of water. In case of discomfort seek medical help. After ingestion: If symptoms persist consult physician.

4. 2.

Most important Symptoms and Effects, both Acute and Delayed Symptoms: No further information available. Effects:

4. 3.

Indication of any Immediate Medical Attention and special Treatment needed Treatment: No special first-aid measures necessary.

Fire-Fighting Measures

5. 1.

Extinguishing Media Suitable extinguishing media: Use extinguishing media for surrounding fire. Product itself does not burn. Unsuitable extinguishing media:

5. 2.

Special Hazards arising from the Substance or Mixture Special hazards: Do not inhale fumes.

5. 3.

Advice for Firefighters Protective equipment: Wear self-contained respiratory protective device. Further information:

Accidential Release Measures next page:

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Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Avoid formation of dust.

6. 2.

Environmental Precautions Environmental precautions: No special measures required.

6. 3.

Methods and Material for Containment and Cleaning Up Methods and material: Clean up mechanically. Avoid dust formation.

6. 4.

Reference to other Sections

Handling and Storage

7. 1.

Precautions for Safe Handling Instructions on safe handling: Avoid formation and deposition of dust. Provide adequate ventilation. Hygienic measures: Wash hands at the end of work. Preventive skin protection recommended.

7. 2.

Conditions for Safe Storage, including any Incompatibilities Storage conditions: Store in a cool and dry place. Requirements for storage areas and containers: No special measures necessary. Information on fire and explosion protection: Do not store together with: foodstuffs, beverages and feed. Storage class: 10-13 Further Information:

7. 3.

Specific End Use(s) Further information:

Exposure Controls/Personal Protection

8. 1.

Parameters to be Controlled Parameters to be controlled (DE): TLV: 10 mg/m3 inhalable fraction (general dust limit) Parameters to be controlled: Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information:

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Exposure Controls Technical protective measures: Provide adequate ventilation. Personal Protection General protective measures: Do not inhale dust. Do not eat, drink or smoke while working. Wash hands before breaks and at the end of work. Respiratory protection: In case of formation of dust. Hand protection: Protective gloves (EN 374) Protective glove material: Eye protection: Safety glasses (EN 166) Body protection: Environmental precautions:

Physical and Chemical Properties

9. 1.

Information on Basic Physical and Chemical Properties Form:

powder

Color:

brown

Odor:

none

Odor threshold: No information available. pH-Value:

3.5 - 6

Melting temperature: not available Boiling temperature: not applicable Flash point: not combustible Evaporation rate: not applicable Flammability (solid, gas): not applicable Upper explosion limit: no information available Lower explosion limit: no information available Vapor pressure: next page:

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not applicable Vapor density: No information available. Density:

2.60 g/cm3

Solubility in water:

insoluble

Coefficient of variation (nOctanol/Water): no information available Auto-ignition temperature: not applicable Decomposition temperature: No data available. Viscosity, dynamic: not applicable Explosive properties: not applicable Oxidizing properties: no information available Bulk density: not determined 9. 2.

Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: No further information.

10.

Stability and Reactivity

10.1.

Reactivity Stable if used according to specifications.

10.2.

Chemical Stability Stable if used according to specifications.

10.3.

Possibility of Hazardous Reactions None if handled and stored according to specifications.

10.4.

Conditions to Avoid Conditions to avoid: No information available. Thermal decomposition:

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No further information available. 10.5.

Imcompatible Materials No information available.

10.6.

Hazardous Decomposition Products No information available.

10.7.

Further Information

11.

Toxicological Information

11. 1.

Information on Toxicological Effects Acute Toxicity LD50, oral: No information available. LD50, dermal: No information available. LC50, inhalation: No information available. Primary effects Irritant effect on skin: No irritant effect known. Irritant effect on eyes: Dust may irritate eyes. Inhalation: No information available. Ingestion: No information available Sensitization: No relevant data found. Mutagenicity: No relevant data found. Reproductive toxicity: No relevant data found. Carcinogenicity: No relevant data found. Teratogenicity: No information available. Specific target organ toxicity (STOT): No relevant data found. Additional toxicological information: Acute or chronic effects are not expected.

12.

Ecological Information next page:

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Aquatic Toxicity No toxicity expected. Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity:

12. 2.

Persistency and Degradability No information available.

12. 3.

Bioaccumulation No information available.

12. 4.

Mobility Product is not water soluble.

12. 5.

Results of PBT- und vPvP Assessment This product is neither a PBT or vPvB substance nor does it contain a PBT or vPvB substance.

12. 6.

Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: Natural product. Environmentally not hazardous. AOX Value:

13.

Disposal Considerations

13. 1.

Waste Treatment Methods Product: Dispose of according to official national and local regulations. European Waste Code (EWC): Uncleaned packaging: Uncontaminated packaging may be recycled. Waste Code No.:

14.

Transport Information

14. 1.

UN Number ADR, IMDG, IATA

14. 2.

UN Proper Shipping Name ADR/RID: No hazardous goods according to ADR (land transportation). IMDG/IATA: No hazardous goods according to IMDG.

14. 3.

Transport Hazard Classes ADR Class: next page:

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not applicable Hazard no.: Classification code: Tunnel restriction code: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: not applicable Hazard no.: 14. 4.

Packaging Group ADR/RID: not applicable IMDG: IATA:

14. 5.

Environmental Hazards None

14. 6.

Special Precautions for User Not classified as a dangerous good under transport regulations.

14. 7.

Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code

14. 8.

Further Information

15.

Regulatory Information

15. 1.

Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 0, not hazardous (German Regulation) Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality:

15. 2.

Chemical Safety Assessment Exempted from the mandatory REACH Registration (Annex V).

15. 3.

Further Information

16.

Other Information This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.

METALWORK DEPT

3D PRINTING

Conforms to Code of Practice for the Preparation of Safety Data Sheets for Hazardous Chemicals

SAFETY DATA SHEET Polymethyl methacrylate Standard

Section 1. Identification Product identifier

: Polymethyl methacrylate Standard

Part no.

: PL2020-0100, PL2020-0101, PL2020-0200, PL2020-0201, PL2020-0202, PL2020-0203, PL2022-2001, PL2022-2005, PL2022-2010, PL2022-3001, PL2022-3005, PL2022-3010, PL2022-5001, PL2022-5005, PL2022-5010, PL2022-6001, PL2022-6005, PL2022-6010, PL2022-7001, PL2022-7005, PL2022-7010, PL2022-8001, PL2022-8005, PL2022-8010, PL2022-9001, PL2022-9005, PL2022-9010, PL2023-0001, PL2023-0005, PL2023-0010, PL2023-1001, PL2023-1005, PL2023-1010, PL2023-2001, PL2023-2005, PL2023-2010, PL2023-3001, PL2023-3001,PL2023-3005, PL2023-3010, PL2023-4001, PL2023-4005, PL2023-4010, PL2023-5001, PL2023-5005, PL2023-5010, PL2023-6001, PL2023-6005, PL2023-6010, PL2023-7001, PL2023-7005, PL2023-7010, PL2023-8001, PL2023-8005, PL2023-8010, PL2023-9001, PL2023-9005, PL2023-9010, PL2024-0001, PL2024-0001, PL2024-0005, PL2024-0010, PL2024-1001, PL2024-1005, PL2024-1010, PL2024-2001, PL2024-2005, PL2024-2010 : 2-Propenoic acid, 2-methyl-, methyl ester, homopolymer

Chemical identity

Relevant identified uses of the substance or mixture and uses advised against Material uses

Date of issue/Date of revision

: Reagents and Standards for Analytical Chemistry Laboratory Use PL2020-0100 PMMA Calibration Kit M-L-10 (10 X 0.5G) PL2020-0101 PMMA Calibration Kit M-M-10 (10 X 0.5G) PL2020-0200 EasiVial PM kit 4 ml PL2020-0201 EasiVial PM 2 ml PL2020-0202 PMMA 2 ml tri-pack (90 vials) PL2020-0203 PMMA 4 ml tri-pack (90 vials) PL2022-2001 PMMA NOMINAL MP 500 1G PL2022-2005 PMMA NOMINAL MP 500 5G PL2022-2010 PMMA nominal Mp 500 10g PL2022-3001 PMMA nominal Mp 1k 1g PL2022-3005 PMMA nominal Mp 1k 5g PL2022-3010 PMMA nominal Mp 1k 10g PL2022-5001 PMMA nominal Mp 2k 1g PL2022-5005 PMMA nominal Mp 2k 5g PL2022-5010 PMMA nominal Mp 2k 10g PL2022-6001 PMMA nominal Mp 3k 1g PL2022-6005 PMMA nominal Mp 3k 5g PL2022-6010 PMMA nominal Mp 3k 10g PL2022-7001 PMMA nominal Mp 5k 1g PL2022-7005 PMMA nominal Mp 5k 5g PL2022-7010 PMMA nominal Mp 5k 10g PL2022-8001 PMMA nominal Mp 7k 1g PL2022-8005 PMMA nominal Mp 7k 5g PL2022-8010 PMMA nominal Mp 7k 10g PL2022-9001 PMMA nominal Mp 10k 1g PL2022-9005 PMMA nominal Mp 10k 5g PL2022-9010 PMMA nominal Mp 10k 10g PL2023-0001 PMMA nominal Mp 13k 1g PL2023-0005 PMMA nominal Mp 13k 5g PL2023-0010 PMMA nominal Mp 13k 10g PL2023-1001 PMMA nominal Mp 20k 1g PL2023-1005 PMMA nominal Mp 20k 5g PL2023-1010 PMMA nominal Mp 20k 10g PL2023-2001 PMMA nominal Mp 30k 1g PL2023-2005 PMMA nominal Mp 30k 5g PL2023-2010 PMMA nominal Mp 30k 10g PL2023-3001 PMMA nominal Mp 50k 1g PL2023-3005 PMMA nominal Mp 50k 5g : 25/09/2019

Date of previous issue

: 30/10/2017

Version

1/10

Polymethyl methacrylate Standard

Section 1. Identification PL2023-3010 PL2023-4001 PL2023-4005 PL2023-4010 PL2023-5001 PL2023-5005 PL2023-5010 PL2023-6001 PL2023-6005 PL2023-6010 PL2023-7001 PL2023-7005 PL2023-7010 PL2023-8001 PL2023-8005 PL2023-8010 PL2023-9001 PL2023-9005 PL2023-9010 PL2024-0001 PL2024-0005 PL2024-0010 PL2024-1001 PL2024-1005 PL2024-1010 PL2024-2001 PL2024-2005 PL2024-2010

PMMA nominal Mp 50k 10g PMMA nominal Mp 70k 1g PMMA nominal Mp 70k 5g PMMA nominal Mp 70k 10g PMMA nominal Mp 100k 1g PMMA nominal Mp 100k 5g PMMA nominal Mp 100k 10g PMMA nominal Mp 130k 1g PMMA nominal Mp 130k 5g PMMA nominal Mp 130k 10g PMMA nominal Mp 200k 1g PMMA nominal Mp 200k 5g PMMA nominal Mp 200k 10g PMMA nominal Mp 300k 1g PMMA nominal Mp 300k 5g PMMA nominal Mp 300k 10g PMMA nominal Mp 500k 1g PMMA nominal Mp 500k 5g PMMA nominal Mp 500k 10g PMMA nominal Mp 700k 1g PMMA nominal Mp 700k 5g PMMA nominal Mp 700k 10g PMMA nominal Mp 1m 1g PMMA nominal Mp 1m 5g PMMA nominal Mp 1m 10g PMMA nominal Mp 1.5m 1g PMMA nominal Mp 1.5m 5g PMMA nominal Mp 1.5m 10g

Supplier/Manufacturer

: Agilent Technologies Australia Pty Ltd 679 Springvale Road Mulgrave Victoria 3170, Australia 1800 802 402

Emergency telephone number (with hours of operation)

: CHEMTREC®: +(61)-290372994

Section 2. Hazard(s) identification Classification of the substance or mixture Not classified. GHS label elements Signal word

: No signal word.

Hazard statements

: No known significant effects or critical hazards.

Precautionary statements Prevention

: Not applicable.

Response Storage Disposal

: Not applicable. : Not applicable. : Not applicable.

Supplemental label elements Additional warning phrases

Date of issue/Date of revision

: Not applicable.

: 25/09/2019

Date of previous issue

: 30/10/2017

Version

2/10

Polymethyl methacrylate Standard

Section 2. Hazard(s) identification Other hazards which do not result in classification

: May form explosible dust-air mixture if dispersed.

Section 3. Composition and ingredient information Substance/mixture

: Substance

CAS number/other identifiers Ingredient name

% (w/w)

CAS number

2-Propenoic acid, 2-methyl-, methyl ester, homopolymer

100

9011-14-7

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures Description of necessary first aid measures Eye contact

Inhalation Skin contact Ingestion

: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur. : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. : Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur.

Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact

Skin contact

: Exposure to airborne concentrations above statutory or recommended exposure limits may cause irritation of the eyes. : Exposure to airborne concentrations above statutory or recommended exposure limits may cause irritation of the nose, throat and lungs. : No known significant effects or critical hazards.

Ingestion

: No known significant effects or critical hazards.

Inhalation

Over-exposure signs/symptoms Eye contact

Skin contact

: Adverse symptoms may include the following: irritation redness : Adverse symptoms may include the following: respiratory tract irritation coughing : No specific data.

Ingestion

: No specific data.

Inhalation

Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Specific treatments

: Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. : No specific treatment.

Protection of first-aiders

: No action shall be taken involving any personal risk or without suitable training.

Date of issue/Date of revision

: 25/09/2019

Date of previous issue

: 30/10/2017

Version

3/10

Polymethyl methacrylate Standard

Section 4. First aid measures See toxicological information (Section 11)

Section 5. Firefighting measures Extinguishing media Suitable extinguishing media

: Use dry chemical powder.

Unsuitable extinguishing media

: Avoid high pressure media which could cause the formation of a potentially explosible dust-air mixture.

Specific hazards arising from the chemical

: May form explosible dust-air mixture if dispersed.

Hazardous thermal decomposition products

: Decomposition products may include the following materials: carbon dioxide carbon monoxide

Special protective actions for fire-fighters

: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency personnel

: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing dust. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". Environmental precautions

: Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Methods and material for containment and cleaning up Methods for cleaning up

: Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Vacuum or sweep up material and place in a designated, labelled waste container. Dispose of via a licensed waste disposal contractor.

Section 7. Handling and storage Precautions for safe handling Protective measures

Date of issue/Date of revision

: Put on appropriate personal protective equipment (see Section 8). Avoid breathing dust. Avoid the creation of dust when handling and avoid all possible sources of ignition (spark or flame). Prevent dust accumulation. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Electrical equipment and lighting should be protected to appropriate standards to prevent dust coming into contact with hot surfaces, sparks or other ignition sources. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by earthing and bonding containers and equipment before transferring material.

: 25/09/2019

Date of previous issue

: 30/10/2017

Version

4/10

Polymethyl methacrylate Standard

Section 7. Handling and storage Advice on general occupational hygiene

: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Conditions for safe storage, including any incompatibilities

: Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.

Section 8. Exposure controls and personal protection Control parameters Occupational exposure limits Ingredient name

Exposure limits

2-Propenoic acid, 2-methyl-, methyl ester, homopolymer

ACGIH TLV (United States). Particulates Not Otherwise Specified (PNOS): 10 mg/m³ Form: Inhalable Particulates Not Otherwise Specified (PNOS): 3 mg/m³ Form: Respirable

Appropriate engineering controls

Environmental exposure controls

: Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapour or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures Hygiene measures

Eye/face protection

: Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields. If operating conditions cause high dust concentrations to be produced, use dust goggles.

Skin protection Hand protection

Body protection

Date of issue/Date of revision

: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

: 25/09/2019

Date of previous issue

: 30/10/2017

Version

5/10

Polymethyl methacrylate Standard

Section 8. Exposure controls and personal protection Other skin protection

Respiratory protection

: Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.

Section 9. Physical and chemical properties Appearance Physical state

: Solid. [Powder.]

Colour

: White.

Odour Odour threshold pH

: Not available. : Not available.

Melting point

: Not available. : >150°C (>302°F)

Boiling point

: Not available.

Flash point

: Closed cup: >250°C (>482°F)

Evaporation rate

: Not available.

Flammability (solid, gas)

: Not available.

Lower and upper explosive (flammable) limits

: Not available.

Vapour pressure

: Not available.

Vapour density Relative density

: Not available. : Not available.

Density

: 1.2 g/cm³

Solubility

: Insoluble in the following materials: cold water and hot water.

Partition coefficient: noctanol/water

: Not available.

Auto-ignition temperature

: Not available.

Decomposition temperature

: Not available.

Viscosity

: Not available.

Section 10. Stability and reactivity Reactivity

: No specific test data related to reactivity available for this product or its ingredients.

Chemical stability

: The product is stable.

Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Conditions to avoid

: Avoid the creation of dust when handling and avoid all possible sources of ignition (spark or flame). Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by earthing and bonding containers and equipment before transferring material. Prevent dust accumulation.

Incompatible materials

: Reactive or incompatible with the following materials: oxidizing materials Incompatible materials: Alkali. , Amine.

Date of issue/Date of revision

: 25/09/2019

Date of previous issue

: 30/10/2017

Version

6/10

Polymethyl methacrylate Standard

Section 10. Stability and reactivity Hazardous decomposition products

: Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Section 11. Toxicological information Information on toxicological effects Acute toxicity Not available. Irritation/Corrosion Not available. Sensitisation Not available. Mutagenicity Conclusion/Summary Carcinogenicity

: Not available.

Conclusion/Summary

: Not available.

Reproductive toxicity Conclusion/Summary

: Not available.

Teratogenicity Conclusion/Summary

: Not available.

Specific target organ toxicity (single exposure) Not available. Specific target organ toxicity (repeated exposure) Not available. Aspiration hazard Not available. Information on likely routes of exposure

: Not available.

Potential acute health effects Eye contact Inhalation Skin contact Ingestion

Symptoms related to the physical, chemical and toxicological characteristics Eye contact

Skin contact

: Adverse symptoms may include the following: irritation redness : Adverse symptoms may include the following: respiratory tract irritation coughing : No specific data.

Ingestion

: No specific data.

Inhalation

Delayed and immediate effects as well as chronic effects from short and long-term exposure Short term exposure Date of issue/Date of revision

: 25/09/2019

Date of previous issue

: 30/10/2017

Version

7/10

Polymethyl methacrylate Standard

Section 11. Toxicological information Potential immediate effects

: Not available.

Potential delayed effects

: Not available.

Long term exposure Potential immediate effects

: Not available.

Potential delayed effects

: Not available.

Potential chronic health effects General

: Repeated or prolonged inhalation of dust may lead to chronic respiratory irritation.

Carcinogenicity Mutagenicity Teratogenicity

: No known significant effects or critical hazards. : No known significant effects or critical hazards. : No known significant effects or critical hazards.

Developmental effects

: No known significant effects or critical hazards.

Fertility effects

: No known significant effects or critical hazards.

Numerical measures of toxicity Acute toxicity estimates N/A

Other information

: Adverse symptoms may include the following: Very slightly to slightly dangerous in case of skin contact (corrosive, irritant, sensitiser, permeator), eye contact (irritant), ingestion or inhalation.

Section 12. Ecological information Toxicity Not available. Persistence and degradability Not available. Bioaccumulative potential Not available. Mobility in soil Soil/water partition coefficient (KOC) Other adverse effects

: Not available.

: The products of degradation are more toxic than the product itself.

Section 13. Disposal considerations Disposal methods

Date of issue/Date of revision

: The generation of waste should be avoided or minimised wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and nonrecyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. : 25/09/2019

Date of previous issue

: 30/10/2017

Version

8/10

Polymethyl methacrylate Standard

Section 14. Transport information ADG / IMDG / IATA

: Not regulated as Dangerous Goods according to the ADG Code .

Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Transport in bulk according to Annex II of Marpol and the IBC Code

: Not available.

Section 15. Regulatory information Standard Uniform Schedule of Medicine and Poisons Not regulated. Model Work Health and Safety Regulations - Scheduled Substances No listed substance International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals Not listed. Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Informed Consent (PIC) Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. Inventory list Australia

: This material is listed or exempted.

Canada

: This material is listed or exempted.

China

: This material is listed or exempted.

Europe

: Not determined.

Japan

: Japan inventory (ENCS): This material is listed or exempted. Japan inventory (ISHL): This material is listed or exempted.

New Zealand

: This material is listed or exempted.

Philippines

: This material is listed or exempted.

Republic of Korea

: This material is listed or exempted.

Taiwan Thailand Turkey

: This material is listed or exempted. : Not determined. : Not determined.

United States

: This material is listed or exempted.

Viet Nam

: Not determined.

Date of issue/Date of revision

: 25/09/2019

Date of previous issue

: 30/10/2017

Version

9/10

Polymethyl methacrylate Standard

Section 16. Any other relevant information History Date of issue/Date of revision Date of previous issue

: 25/09/2019

Version

: 4

: 30/10/2017

Key to abbreviations

: ADG = Australian Dangerous Goods ADR = The European Agreement concerning the International Carriage of Dangerous Goods by Road ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SUSMP = Standard Uniform Schedule of Medicine and Poisons UN = United Nations Procedure used to derive the classification Classification

Justification

Not classified. References

: Not available.

Indicates information that has changed from previously issued version. Notice to reader Disclaimer: The information contained in this document is based on Agilent’s state of knowledge at the time of preparation. No warranty as to its accurateness, completeness or suitability for a particular purpose is expressed or implied.

Date of issue/Date of revision

: 25/09/2019

Date of previous issue

: 30/10/2017

Version

10/10

POUR DEPT

Safety Data Sheet 1907/2006/EC - REACH (GB) voxeljet - PolyPor Part - Type B waxed / unwaxed voxeljet AG 86316 Friedberg Date printed 22.09.2014, Revision 22.09.2014

Version 03. Supersedes version: 02

Page 1 / 8

SECTION 1: Identification of the substance / preparation and of the company 1.1

Product identifier

voxeljet - PolyPor Part - Type B waxed / unwaxed 1.2

Relevant identified uses of the substance or mixture and uses advised against

1.2.1 Relevant uses Investment casting, demonstration models

1.2.2 Uses advised against None known.

1.3

Details of the supplier of the safety data sheet Company

voxeljet AG Paul-Lenz-Straße 1 86316 Friedberg / GERMANY Phone +49(0)821-7483 100 Fax +49(0)821-7483 111 Homepage www.voxeljet.com E-mail info@voxeljet.de

Address enquiries to

1.4

Technical information

info@voxeljet.de

Safety Data Sheet

sdb@chemiebuero.de

Emergency phone Advisory body

+49 (0)89-19240 (24h) (english)

SECTION 2: Hazards identification 2.1

Classification of the substance or mixture

2.1.1 Classification according to Regulation (EC) No 1272/2008 [CLP] Eye Dam. 1: H318 Causes serious eye damage. Repr. 1B: H360D May damage the unborn child.

2.1.2 Classification according to Directive 67/548/EEC or 1999/45/EC 2.2

Label elements This product is an article and therefore it does not require labelling according to EC directives/GefStoffV.

2.3

Other hazards Other hazards

Further hazards were not determined with the current level of knowledge.

SECTION 3: Composition / Information on ingredients Product-type: The product is an article. Range [%] Substance 1 - < 5 N-Vinylformamide; content of formamide (CAS 75-12-7) >= 0.3 - < 0,5% CAS: 13162-05-5, EINECS/ELINCS: 236-102-9, ECB-Nr.: 01-2119472434-38-XXXX GHS/CLP: Acute Tox. 4: H302 - Eye Dam. 1: H318 - Repr. 1B: H360D EEC: Xn, R 22-41 Comment on component parts

Substances of Very High Concern - SVHC: substances are not contained or are below 0,1%. For full text of H-statements and R-phrases: see SECTION 16.

www.chemiebuero.de, Phone +49 (0)941-646 353-0, info@chemiebuero.de, 140812a

vxj00007 GB

Safety Data Sheet 1907/2006/EC - REACH (GB) voxeljet - PolyPor Part - Type B waxed / unwaxed voxeljet AG 86316 Friedberg Date printed 22.09.2014, Revision 22.09.2014

Version 03. Supersedes version: 02

Page 2 / 8

SECTION 4: First aid measures 4.1

4.2

Description of first aid measures General information

none

Inhalation

not applicable

Skin contact

When in contact with the skin, clean with soap and water. Consult a doctor if skin irritation persists.

Eye contact

In case of contact with eyes rinse thoroughly with water. In the event of symptoms seek for medical treatment.

Ingestion

Rinse out mouth and give plenty of water to drink. Induce the patient to vomit of his own accord only if fully conscious. Seek medical advice.

Most important symptoms and effects, both acute and delayed No information available.

4.3

Indication of any immediate medical attention and special treatment needed Treat symptomatically. Forward this sheet to the doctor.

SECTION 5: Fire-fighting measures 5.1

5.2

Extinguishing media Suitable extinguishing media

Water spray jet. Dry powder. Foam.

Extinguishing media that must not be used

Full water jet.

Special hazards arising from the substance or mixture Risk of formation of toxic pyrolysis products.

5.3

Advice for firefighters Use self-contained breathing apparatus. Fire residues and contaminated firefighting water must be disposed of in accordance within the local regulations.

SECTION 6: Accidental release measures 6.1

Personal precautions, protective equipment and emergency procedures No special measures necessary.

6.2

Environmental precautions No special measures necessary.

6.3

Methods and material for containment and cleaning up Take up mechanically. Avoid production of dust. Dispose of absorbed material in accordance within the regulations.

6.4

Reference to other sections See SECTION 8+13

www.chemiebuero.de, Phone +49 (0)941-646 353-0, info@chemiebuero.de, 140812a

vxj00007 GB

Safety Data Sheet 1907/2006/EC - REACH (GB) voxeljet - PolyPor Part - Type B waxed / unwaxed voxeljet AG 86316 Friedberg Date printed 22.09.2014, Revision 22.09.2014

Version 03. Supersedes version: 02

Page 3 / 8

SECTION 7: Handling and storage 7.1

Precautions for safe handling Provide suitable vacuuming at the processing machines. It is recommended that the models are burned out at a temperature of 700°C in a standard atmosphere. In these conditions, the polymer will fully oxidise to carbon dioxide and water. The emissions from the process should be extracted and vented to atmosphere in line with normal foundry best practice. Do not eat or drink when working. Wash hands before breaks and after work. Use barrier skin cream.

7.2

Conditions for safe storage, including any incompatibilities Keep only in original container. Keep container tightly closed. Keep container in a well-ventilated place.

7.3

Specific end use(s) See product use, SECTION 1.2

SECTION 8: Exposure controls / personal protection 8.1

Control parameters Ingredients with occupational exposure limits to be monitored (GB) not applicable

DNEL Range [%] Substance 1 - < 5 N-Vinylformamide; content of formamide (CAS 75-12-7) >= 0.3 - < 0,5%, CAS: 13162-05-5 Industrial, inhalative, Long-term - systemic effects: 1 mg/m³. Industrial, dermal, Long-term - systemic effects: 1,5 mg/kg bw. PNEC Range [%] Substance 1 - < 5 N-Vinylformamide; content of formamide (CAS 75-12-7) >= 0.3 - < 0,5%, CAS: 13162-05-5 sewage treatment plants (STP), 19,9 mg/l. soil, 0,0155 mg/kg. sediment (seaater), 0,021 mg/kg. sediment (freshwater), 0,21 mg/kg. seawater, 0,01 mg/l. freshwater, 0,1 mg/l.

8.2

Exposure controls Additional advice on system design

Ensure adequate ventilation on workstation.

Eye protection

Safety glasses.

Hand protection

The details concerned are recommendations. Please contact the glove supplier for further information. In full contact: Butyl rubber, >120 min (EN 374).

Skin protection

not applicable

Other

Avoid contact with eyes and skin.

Respiratory protection

not applicable

Thermal hazards

not determined

Delimitation and monitoring of the environmental exposition

See SECTION 6+7.

www.chemiebuero.de, Phone +49 (0)941-646 353-0, info@chemiebuero.de, 140812a

vxj00007 GB

Safety Data Sheet 1907/2006/EC - REACH (GB) voxeljet - PolyPor Part - Type B waxed / unwaxed voxeljet AG 86316 Friedberg Date printed 22.09.2014, Revision 22.09.2014

Version 03. Supersedes version: 02

Page 4 / 8

SECTION 9: Physical and chemical properties 9.1

Information on basic physical and chemical properties Form

solid in different forms

Color

yellowish

Odor

characteristic

Odour threshold

not determined

pH-value

not applicable

pH-value [1%]

not applicable

Boiling point [°C]

not applicable

Flash point [°C]

not applicable

Flammability [°C]

not determined

Lower explosion limit

not determined

Upper explosion limit

not determined

Oxidizing properties

Vapour pressure/gas pressure [kPa]

not determined

Density [g/ml]

0,75

Bulk density [kg/m³]

not applicable

Solubility in water

partially soluble

Partition coefficient [n-octanol/water] not determined

9.2

Viscosity

not applicable

Relative vapour density determined in air

not determined

Evaporation speed

not determined

Melting point [°C]

105

Autoignition temperature [°C]

not determined

Decomposition temperature [°C]

200

Other information none

SECTION 10: Stability and reactivity 10.1 Reactivity No dangerous reactions known if used as directed.

10.2 Chemical stability Stable under normal ambient conditions (ambient temperature).

10.3 Possibility of hazardous reactions Reactions with acids, alkalies and oxidizing agents.

10.4 Conditions to avoid See SECTION 7.2.

10.5 Incompatible materials not determined

10.6 Hazardous decomposition products No hazardous decomposition products known.

www.chemiebuero.de, Phone +49 (0)941-646 353-0, info@chemiebuero.de, 140812a

vxj00007 GB

Safety Data Sheet 1907/2006/EC - REACH (GB) voxeljet - PolyPor Part - Type B waxed / unwaxed voxeljet AG 86316 Friedberg Date printed 22.09.2014, Revision 22.09.2014

Version 03. Supersedes version: 02

Page 5 / 8

SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute toxicity Range [%] Substance 1 - < 5 N-Vinylformamide; content of formamide (CAS 75-12-7) >= 0.3 - < 0,5%, CAS: 13162-05-5 LD50, dermal, Rabbit: > 2000 mg/kg (OECD 402). LD50, oral, Rat: > 1000-< 2000 mg/kg (OECD 423). Serious eye damage/irritation

not determined

Skin corrosion/irritation

not determined

Respiratory or skin sensitisation

not determined

Specific target organ toxicity — single exposure

not determined

Specific target organ toxicity — repeated exposure

not determined

Mutagenicity

not determined

Reproduction toxicity

not determined

Carcinogenicity

not determined

General remarks No classification on the basis of the calculation procedure of the preparation directive.

SECTION 12: Ecological information 12.1 Toxicity Range [%] Substance 1 - < 5 N-Vinylformamide; content of formamide (CAS 75-12-7) >= 0.3 - < 0,5%, CAS: 13162-05-5 LC50, (96h), Leuciscus idus: > 100-< 220 mg/l. EC50, (72h), Scenedesmus subspicatus: > 100 mg/l. EC50, (48h), Daphnia magna: 142 mg/l.

12.2 Persistence and degradability not determined Behaviour in environment compartments

not determined

Behaviour in sewage plant

not determined

Biological degradability

not determined

12.3 Bioaccumulative potential not determined

12.4 Mobility in soil not determined

12.5 Results of PBT and vPvB assessment not applicable

12.6 Other adverse effects None known.

www.chemiebuero.de, Phone +49 (0)941-646 353-0, info@chemiebuero.de, 140812a

vxj00007 GB

Safety Data Sheet 1907/2006/EC - REACH (GB) voxeljet - PolyPor Part - Type B waxed / unwaxed voxeljet AG 86316 Friedberg Date printed 22.09.2014, Revision 22.09.2014

Version 03. Supersedes version: 02

Page 6 / 8

SECTION 13: Disposal considerations 13.1 Waste treatment methods Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. It is not possible to determine a waste code for this product in accordance with the European Waste Catalogue (EWC) since it is only possible to classify it according to how it is used by the customer. The waste code is to be determined within the EU in liaison with the waste-disposal operator.

Product Coordinate disposal with the disposal contractor/authorities if necessary. Waste no. (recommended)

070213

Contaminated packaging Uncontaminated packaging may be taken for recycling. Packaging that cannot be cleaned should be disposed of as for product. Waste no. (recommended)

150102

SECTION 14: Transport information 14.1 UN number See SECTION 14.2 in accordance with UN shipping name

14.2 UN proper shipping name Transport by land according to ADR/RID

NO DANGEROUS GOODS

Inland navigation (ADN)

NO DANGEROUS GOODS

Marine transport in accordance with IMDG

NOT CLASSIFIED AS "DANGEROUS GOODS"

Air transport in accordance with IATA NOT CLASSIFIED AS "DANGEROUS GOODS"

14.3 Transport hazard class(es) See SECTION 14.2 in accordance with UN shipping name

14.4 Packing group See SECTION 14.2 in accordance with UN shipping name

14.5 Environmental hazards See SECTION 14.2 in accordance with UN shipping name

14.6 Special precautions for user Relevant information under SECTION 6 to 8.

14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code not applicable

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vxj00007 GB

Safety Data Sheet 1907/2006/EC - REACH (GB) voxeljet - PolyPor Part - Type B waxed / unwaxed voxeljet AG 86316 Friedberg Date printed 22.09.2014, Revision 22.09.2014

Version 03. Supersedes version: 02

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SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EEC-REGULATIONS

1967/548 (1999/45); 1991/689 (2001/118); 1999/13; 2004/42; 648/2004; 1907/2006 (Reach); 1272/2008; 75/324/EEC (2008/47/EC); 453/2010/EC

TRANSPORT-REGULATIONS

DOT-Classification, ADR (2013); IMDG-Code (2013, 36. Amdt.); IATA-DGR (2013).

NATIONAL REGULATIONS (GB):

EH40/2005 Workplace exposure limits (Second edition, published December 2011). CHIP 3/ CHIP 4

- Observe employment restrictions for people

Observe employment restrictions for young people. Observe employment restrictions for mothers-to-be and nursing mothers.

- VOC (1999/13/CE)

<4%

15.2 Chemical safety assessment For this product a chemical safety assessment has not been carried out.

SECTION 16: Other information 16.1 R-phrases (SECTION 3) R 22: Harmful if swallowed. R 41: Risk of serious damage to eyes.

16.2 Hazard statements (SECTION 3) H360D May damage the unborn child. H318 Causes serious eye damage. H302 Harmful if swallowed.

16.3 Abbreviations and acronyms: ADR = Accord européen relatif au transport international des marchandises Dangereuses par Route RID = Règlement concernant le transport international ferroviaire de marchandises dangereuses ADN = Accord européen relatif au transport international des marchandises dangereuses par voie de navigation intérieure CAS = Chemical Abstracts Service CLP = Classification, Labelling and Packaging DMEL = Derived Minimum Effect Level DNEL = Derived No Effect Level EC50 = Median effective concentration ECB = European Chemicals Bureau EEC = European Economic Community EINECS = European Inventory of Existing Commercial Chemical Substances ELINCS = European List of Notified Chemical Substances GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC-Code = International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk IC50 = Inhibition concentration, 50% IMDG = International Maritime Code for Dangerous Goods IUCLID = International Uniform ChemicaL Information Database LC50 = Lethal concentration, 50% LD50 = Median lethal dose MARPOL = International Convention for the Prevention of Marine Pollution from Ships PBT = Persistent, Bioaccumulative and Toxic substance PNEC = Predicted No-Effect Concentration REACH = Registration, Evaluation, Authorisation and Restriction of Chemicals TLV®/TWA = Threshold limit value – time-weighted average TLV®STEL = Threshold limit value – short-time exposure limit VOC = Volatile Organic Compounds vPvB = very Persistent and very Bioaccumulative

16.4 Other information Customs Tariff

not determined

Classification procedure

Eye Dam. 1: H318 Causes serious eye damage. (Calculation method) Repr. 1B: H360D May damage the unborn child. (Calculation method)

www.chemiebuero.de, Phone +49 (0)941-646 353-0, info@chemiebuero.de, 140812a

vxj00007 GB

Safety Data Sheet 1907/2006/EC - REACH (GB) voxeljet - PolyPor Part - Type B waxed / unwaxed voxeljet AG 86316 Friedberg Date printed 22.09.2014, Revision 22.09.2014

Modified position

Version 03. Supersedes version: 02

Page 8 / 8

SECTION 2 been added: Eye Dam. 1 SECTION 2 been added: Ätzwirkung SECTION 2 been added: DANGER SECTION 2 been added: Further hazards were not determined with the current level of knowledge. SECTION 2 been added: H318 Causes serious eye damage. SECTION 2 been added: Repr. 1B SECTION 2 been added: Gesundheitsgefahr SECTION 2 been added: H360D May damage the unborn child. SECTION 2 been added: This product is an article and therefore it does not require labelling according to EC directives/GefStoffV. SECTION 15 been added: yes SECTION 15 been added: For this product a chemical safety assessment has not been carried out. SECTION 15 deleted: Storage class 11 (VCI) SECTION 15 been added: Storage class 6.1C (VCI) SECTION 15 been added: Please note BG leaflet BGI 595: Irritative substances/caustic substances when at work. SECTION 15 been added: SECTION 15 been added: SECTION 15 been added: TRGS 510: Lagerung von Gefahrstoffen in ortsbeweglichen Behältern SECTION 15 been added: TRGS 905: List of substances causing cancer, mutagenic or being dangerous to reproduction. SECTION 15 been added: 5.2.7. SECTION 15 deleted: Chemical safety assessments for substances in this mixture were not carried out. SECTION 16 been added: Observe employment restrictions for mothers-to-be and nursing mothers. SECTION 16 been added: Calculation method SECTION 16 been added: Observe employment restrictions for young people. Copyright: Chemiebüro®

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vxj00007 GB