Oxygen: Friend or foe?

Phenolics react with oxygen to produce quinones which can lead to acetaldehyde creation from Ethanol. Oxidation reactions also contribute to browning or discolouration of wine and ultimately dull the aromatic components, especially Thiol groups. SO2, ascorbic acid and glutathione are wine ingredients used to protect from oxidation as are tannins, either toasted or untoasted, that provide anti-oxidative properties to wine.

The risks factor from oxygen are high on the list of the winemaker but it is important not to fully demonise oxygen. It is a critical element that is needed during the fermentation process, managing grape must before fermentation as well as combating reductive wine parameters such as Hydrogen Sulphite. The ability to measure oxygen (Head space + Dissolved Oxygen (DO)) that give Total Package Oxygen (TPO) as well as managing phenolic content through fining trials and tannin additions is critical. As too is proper gas management and inertion of tanks and most importantly the bottling process.

Nitrogen is perceived as the best method of inerting and does not react with the wine but it is lighter than air so blanketing with N is not the best choice. Carbon dioxide on the other hand is preferred as it is heavier than air and can act as a barrier between wine and the atmosphere, although correct sparging is critical due to gas turbulence and CO2 dissolves readily in wine. Argon is the best of both worlds but is more expensive. At bottling it is important to inert the bottle as well as the screw cap in a controlled and measurable way. Auditing the bottling operations is an important part of good quality management as is checking oxygen levels. This is a service we offer and our customers can arrange this with the Bruni Erben team.

NomaSense O2 analyser allows winemakers to measure oxygen levels thanks to a technology based on luminescence, combined with the use of remote sensors. The portable device measures oxygen dissolved in wine and in gas phases. Oxygen can be measured at every stage of the wine’s lifecycle, in particular during the packaging process, this allows real-time analysis. Machine settings can then be adjusted

to achieve the lowest TPO possible during bottling. ◆ Check the consistency of filling and corking heads on a bottling line ◆ Reduce variations in bottling performance between the beginning and the end of the process, limiting the difference between one bottle to the next ◆ Identification of the critical oxygen pick-up stages throughout the winemaking process ◆ Implementation of supervised strategies to reduce levels of SO2 ◆ Implementation of inerting procedures to maintain quality and reduce costs.

It is important to perform bench trials, 500ml beer bottles with swing stoppers often provide a very good format for bench trials if an Imhoff Funnel isn’t readily available. Laffort have a comprehensive range of fining agents, to treat grape must and finished wine, to assist in the wine making process. Casein based fining agents such as Casein plus, are effective in combating browning and bitterness in finished wine. Plant based fining agents such as Vegecoll have also seen good results and carry less risk of over-fining. Tannin additions on the other hand can be added to finished wine to enhance organoleptic properties as well as providing effective oxygen protection.

The new reference TPO meters for the wine industry. The only tool that allows fast and reliable TPO measurement for bottle

◆ Emission of blue light directed on the data? sensor ◆ Sensor excitation ◆ Use of QR codes to enter calibration How to measure TPO? ◆ Emission of red light captured by optical fi bre✓ Competitive advantages: ◆ Manual calibrations still possible ◆ Possibility to store up to 100 calibrations 1. Enter sample details • Volume of the bottle or the BIB The only tool that allows fast and reliable TPO measurement for bo﬙ le • Portable, usable on site Non-invasive measurement in bo﬙ le ◆ Use of sensors inside the bottle for both • Size of the headspace 2. Measure HSO in hPa 3. Measure DO in mg/L 4. Calculation of TPO in mg/L and BIB® Competitive advantages: ◆ Portable, usable on site • Accurate : 0.02 mg/L or 0.1 % O2 HSO and DO measurements ◆ Dissolved Oxygen (DO) measurement after stabilisation time Flexibili﬚ of measurements ◆ Accurate: 0.02 mg/L or 0.1 % O2 ◆ Versatile use: bottle, tank, inline• Versatile use: bottle, tank, inline◆ Only in white glass bottles ◆ Integrated TPO calculation In the tank: ◆ Use of dipping probe ◆ Direct results reading ◆ Oxygen consumption monitoring possible ◆ DO measurement ◆ Headspace oxygen (HSO) measurement ◆ Integrated Total Package Oxygen (TPO) calculation • Direct results reading Invasive measurement in bo﬙ le using the Piercing ◆ Inerting performance check During the process: ◆ Use of sight glasses ◆ Simple and fast calibration management ◆ Data saving• Headspace oxygen (HSO) measurement System ◆ Destructive HSO measurement ◆ DO measurement ◆ Inerting performance check ◆ Built-in correction for sugar and alcohol • Sensor inside the syringe At bottling: • contentIntegrated Total Package content • Any type of bottle and closures ◆ No bottle preparation Oxygen (TPO) calculation◆ TPO quality control ◆ Inerting performance ◆ Allows rapid TPO control in association ◆ Filling heads consistency • Simple and fast calibration management with the oxygen dipping probe ◆ Corking heads consistency • Data saving • Built-in correction for sugar and alcohol content

◆ PSt3: cellar measurement use ◆ PSt6: micro oxygenation measurement use

There are many routes to check and manage oxygen and being aware of the pitfalls and processes to manage O2 can give the winemaker a greater control in producing the specifi c wine sty le. For further information and services and products on off er please contact mark@erben.co.uk or telephone 07805 018677, also check out www.erben.co.uk for further products and technical insights and future events.