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TheMetalOxidesBookSeriesEditedbyGhenadiiKorotcenkov ForthcomingTitles l PalladiumOxidesMaterialProperties,SynthesisandProcessingMethods,andApplications,Alexander M.Samoylov,VasilyN.Popov,9780128192238
l MetalOxidesforNon-volatileMemory,PanagiotisDimitrakis,IliaValov,StefanTappertzhofen, 9780128146293
l MetalOxideNanostructuredPhosphors,H.Nagabhushana,DarukaPrasad,S.C.Sharma,9780128118528
l MultifunctionalPiezoelectricOxideNanostructures,Sang-JaeKim,NagamalleswaraRaoAlluri,Yuvasree Purusothaman,9780128193327
l TransparentConductiveOxides,MirelaPetrutaSuchea,PetronelaPascariu,EmmanouelKoudoumas, 9780128206317
l MetalOxide-CarbonHybridMaterials,MuhammadAkram,RafaqatHussain,FaheemKButt,9780128226940
l MetalOxide-basedheterostructures,NaveenKumar,BernabeMariSoucase,9780323852418
l MetalOxidesandRelatedSolidsforElectrocatalyticWaterSplitting,JunleiQi,9780323857352
l AdvancesinMetalOxidesandTheirCompositesforEmergingApplications,SagarDelekar,9780323857055
l MetallicGlassesandTheirOxidation,XinyunWang,MaoZhang,9780323909976
l SolutionMethodsforMetalOxideNanostructures,RajaramS.Mane,VijaykumarJadhav,AbdullahM.AlEnizi,9780128243534
l MetalOxideDefects,VijayKumar,SudiptaSom,VishalSharma,HendrikSwart,9780323855884
l RenewablePolymersandPolymer-MetalOxideComposites,SajjadHaider,AdnanHaider,9780323851558
l MetalOxidesforOptoelectronicsandOptics-basedMedicalApplications,SureshSagadevan,JibanPodder, FaruqMohammad,9780323858243
PublishedTitles l Metal-oxidesforBiomedicalandBiosensorApplications,KunalMondal,9780128230336
l NanostructuredZincOxide,KamlendraAwasthi,9780128189009
l Metaloxide-basednanofibersandtheirapplications,VincenzoEsposito,DeboraMarani,9780128206294
l GrapheneOxide-MetalOxideandOtherGrapheneOxide-BasedCompositesinPhotocatalysisand Electrocatalysis,JiaguoYu,LiuyangZhang,PanyongKuang,9780128245262
l MetalOxidesinNanocomposite-BasedElectrochemicalSensorsforToxicChemicals,AlagarsamyPandikumar,PerumalRameshkumar,9780128207277
l MetalOxide-BasedNanostructuredElectrocatalystsforFuelCells,Electrolyzers,andMetal-AirBatteries, TekoNapporn,YaoviHolade,9780128184967
l TitaniumDioxide(TiO2)andItsApplications,LeonardoPalmisano,FrancescoParrino,9780128199602
l SolutionProcessedMetalOxideThinFilmsforElectronicApplications,ZhengCui,9780128149300
l MetalOxidePowderTechnologies,YarubAl-Douri,9780128175057
l ColloidalMetalOxideNanoparticles,SabuThomas,AnuTresaSunny,PrajithaV,9780128133576
l CeriumOxide,SalvatoreScire,LeonardoPalmisano,9780128156612
l TinOxideMaterials,MarceloOrnaghiOrlandi,9780128159248
l MetalOxideGlassNanocomposites,SanjibBhattacharya,9780128174586
l GasSensorsBasedonConductingMetalOxides,NicolaeBarsan,KlausSchierbaum,9780128112243
l MetalOxidesinEnergyTechnologies,YupingWu,9780128111673
l MetalOxideNanostructures,DanielaNunes,LidiaSantos,AnaPimentel,PedroBarquinha,LuisPereira, ElviraFortunato,RodrigoMartins,9780128115121
l GalliumOxide,StephenPearton,FanRen,MichaelMastro,9780128145210
l MetalOxide-BasedPhotocatalysis,AdrianaZaleska-Medynska,9780128116340
l MetalOxidesinHeterogeneousCatalysis,JacquesC.Vedrine,9780128116319
l Magnetic,Ferroelectric,andMultiferroicMetalOxides,BiljanaStojanovic,9780128111802
l IronOxideNanoparticlesforBiomedicalApplications,SophieLaurent,MortezaMahmoudi,9780081019252
l TheFutureofSemiconductorOxidesinNext-GenerationSolarCells,MonicaLira-Cantu,9780128111659
l MetalOxide-BasedThinFilmStructures,NiniPryds,VincenzoEsposito,9780128111666
l MetalOxidesinSupercapacitors,DeepakDubal,PedroGomez-Romero,9780128111697
l TransitionMetalOxideThinFilm-BasedChromogenicsandDevices,PandurangAshrit,9780081018996
MetalOxidesfor Optoelectronics andOptics-Based MedicalApplications SeriesEditor GhenadiiKorotcenkov
Editedby
SureshSagadevan
Nanotechnology&CatalysisResearchCentre,University ofMalaya,KualaLumpur,Malaysia
JibanPodder
DepartmentofPhysics,BangladeshUniversityofEngineeringandTechnology(BUET),Dhaka,Bangladesh
FaruqMohammad
SurfactantsResearchChair,DepartmentofChemistry, CollegeofScience,KingSaudUniversity,Riyadh,Saudi Arabia
Elsevier
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YasminBintiAbdulWahab,MuhammadAsif,andSureshSagadevan
4Futureaspectsandapplications
4Metaloxide-basedopticalfibers(preparation,composition, composition-linkedproperties,physicalparameters,and theoreticalcalculations)73
ShahlaImteyaz 1Introduction
2Fabricationofopticalfibers
4Applicationsofopticalfiber
SectionBOptoelectronicandphotonicapplications95
5Metaloxide-basedLEDandLASER:Theoreticalconcepts, conventionaldevices,andLEDbasedonquantumdots97
WaqarAhmed,ShahidMehmood,NorAzwadiCheSidik, andSureshSagadevan 1Introduction
2Differentmetaloxidenanostructuresforlight-emittingdiodes (LEDs)andUVdetectors 99
3Metaloxide-basedLASERdiodes
4QuantumdotsusedforLEDs,LASERs, andconventionaldevices
6Metaloxide-basedphotodetectors(fromIRtoUV)117
ZhongMa,JingZhang,HanbaiLyu,XinyuPing,LijiaPan, andYiShi
1Introduction
2Basicmechanismofmetaloxide-basedphotodetection
3Fundamentalparametersofmetaloxide-basedphotodetectors
4Metaloxide-basedphotodetectors:Materialselection,devicedesign, andphotosensingperformances 121
5Biomedicalapplicationsofmetaloxide-basedphotodetectors
7Opticalandoptoelectronicmetaloxide-basedsensors; (opticalsensors,principle,computationalmodeling, andapplication-baseddevelopment)151
NurAmalinaSyahirahMohdIdris,ShamsuAbubakar, AhmedLateefKhalaf,Mohd.HanifYaacob,SureshSagadevan, andSuriatiPaiman
8Passiveoptoelectronicelements165
MarlindaAbRahman,NoorAzrinaTalik,MohdArifMohdSarjidan, andGregorySoonHowThien
1Introductiontothefundamentalsofpassiveoptoelectronics
9Metaloxidephotoniccrystalsandtheirapplication (designing,properties,andapplications)191 TanvirArfin,VinodKumarAlam,andPareshkumarG.Moradeeya
10Heavymetaloxideglassesandtheiroptoelectronicapplications (infraredtransmission,luminescence,nonlinearoptical susceptibilities,etc.)205
S.Mahalakshmi,J.Mayandi,SureshSagadevan,P.Vajeeston, andV.Venkatachalapathy
1Introduction
2Opticalpropertiesofrare-earthion-dopedbismuthandlead-containingborateglasses
3Opticalpropertiesandapplicationsoflead(II)
11Integratedoptoelectronics241
SureshSagadevan,J.AnitaLett,IsFatimah,SuriatiPaiman, JibanPodder,andMohd.RafieJohan
2Electroopticalphenomena
12Metaloxide-basedfibertechnologyinthepharmaceutical andmedicalchemistry259
LakshmipathyMuthukrishnan,SureshSagadevan, andM.A.MotalibHossain
13Metaloxide-involvedphotocatalytictechnologyincosmetics andbeautyproducts301 IbrahimB.Bwatanglang,PrasannaKumarObulapuram, FaruqMohammad,AieshaN.Albalawi,MurthyChavali, HamadA.Al-Lohedan,andTomaIbrahim
KamrunNaharFatemaandWon-ChunOh
Contributors MarlindaAbRahman Nanotechnology&CatalysisResearchCentre,Universityof Malaya,KualaLumpur,Malaysia
YasminBintiAbdulWahab Nanotechnology&CatalysisResearchCentre, UniversityofMalaya,KualaLumpur,Malaysia
ShamsuAbubakar DepartmentofPhysics,FacultyofScience,UniversitiPutra Malaysia,Serdang,Selangor,Malaysia
WaqarAhmed InstituteforAdvancedStudies,UniversityofMalaya;Takasago i-Kohza,Malaysia-JapanInternationalInstituteofTechnology,UniversitiTeknologi Malaysia,KualaLumpur,Malaysia
VinodKumarAlam CSIR-NationalEnvironmentalEngineeringResearchInstitute (CSIR-NEERI),HyderabadZonalCentre,Hyderabad,Telangana,India
AieshaN.Albalawi HaqlCollege,UniversityofTabuk,Tabuk,Kingdomof SaudiArabia
HamadA.Al-Lohedan SurfactantsResearchChair,DepartmentofChemistry, CollegeofScience,KingSaudUniversity,Riyadh,SaudiArabia
TanvirArfin CSIR-NationalEnvironmentalEngineeringResearchInstitute (CSIR-NEERI),HyderabadZonalCentre,Hyderabad,Telangana,India
MuhammadAsif NationalUniversityofSciencesandTechnology(NUST), Islamabad,Pakistan
MuhammadAzhar NationalUniversityofSciencesandTechnology(NUST), Islamabad,Pakistan
IbrahimB.Bwatanglang DepartmentofPureandAppliedChemistry,Facultyof Science,AdamawaStateUniversityMubi,Mubi,Nigeria
MurthyChavali ShreeVelagapudiRamakrishnaMemorialCollege(SVRMC-PG Studies),Guntur,AndhraPradesh,India
KamrunNaharFatema DepartmentofAdvancedMaterialsScience&Engineering, HanseoUniversity,Seosan-si,Chungnam,Korea
IsFatimah DepartmentofChemistry,FacultyofMathematicsandNaturalSciences, UniversitasIslamIndonesia,Yogyakarta,Indonesia
M.A.MotalibHossain Nanotechnology&CatalysisResearchCentre,Universityof Malaya,KualaLumpur,Malaysia
TomaIbrahim DepartmentofBiochemistry,FacultyofScience,AdamawaState UniversityMubi,Mubi,Nigeria
NurAmalinaSyahirahMohdIdris DepartmentofPhysics,FacultyofScience, UniversitiPutraMalaysia,Serdang,Selangor,Malaysia
ShahlaImteyaz DepartmentofChemistry,AligarhMuslimUniversity,Aligarh,India
VictorienJeux UniversitedetechnologiedeCompie ` gne,ESCOM,TIMR(Integrated TransformationsofRenewableMatter),CentrederechercheRoyallieu—CS, Compie ` gneCedex,France
Mohd.RafieJohan Nanotechnology&CatalysisResearchCentre,Universityof Malaya,KualaLumpur,Malaysia
AhmedLateefKhalaf DepartmentofComputerEngineeringTechniques, Al-Ma’moonUniversityCollege,Baghdad,Iraq
EstelleLeonard UniversitedetechnologiedeCompie ` gne,ESCOM,TIMR (IntegratedTransformationsofRenewableMatter),CentrederechercheRoyallieu— CS,Compie ` gneCedex,France
J.AnitaLett DepartmentofPhysics,SathyabamaInstituteofScienceand Technology,Chennai,TamilNadu,India
HanbaiLyu PhysicsDepartment,YaleUniversity,NewHaven,CT,UnitedStates
ZhongMa CollaborativeInnovationCenterofAdvancedMicrostructures,Schoolof ElectronicScienceandEngineering,NanjingUniversity,Nanjing,China
S.Mahalakshmi DepartmentofPhysics,R.D.Govt.ArtsCollege,Alagappa University,Karaikudi,TamilNadu,India
J.Mayandi DepartmentofMaterialScience,SchoolofChemistry,MaduraiKamaraj University,Madurai,TamilNadu,India
ShahidMehmood MicroNanosystemCentre,SchoolofInformationScienceand Technology,FudanUniversity,Shanghai,China
FaruqMohammad SurfactantsResearchChair,DepartmentofChemistry,College ofScience,KingSaudUniversity,Riyadh,SaudiArabia
MohdArifMohdSarjidan LowDimensionalMaterialsResearchCentre, DepartmentofPhysics,FacultyofScience,UniversityofMalaya,KualaLumpur, Malaysia
PareshkumarG.Moradeeya CSIR-NationalEnvironmentalEngineeringResearch Institute(CSIR-NEERI),HyderabadZonalCentre,Hyderabad,Telangana,India
LakshmipathyMuthukrishnan DepartmentofConservativeDentistry& Endodontics,SaveethaDentalCollege&Hospitals,SaveethaInstituteofMedicaland TechnicalSciences,Chennai,TamilNadu,India
MuhammadNihalNaseer NationalUniversityofSciencesandTechnology(NUST), Islamabad,Pakistan;DepartmentofMechanicalEngineering,CollegeofEngineering, SeoulNationalUniversity,Seoul,RepublicofKorea
PrasannaKumarObulapuram WitsAdvancedDrugDeliveryPlatformResearch Unit,DepartmentofPharmacyandPharmacology,SchoolofTherapeuticSciences, FacultyofHealthSciences,UniversityoftheWitwatersrand,Johannesburg,South Africa
Won-ChunOh DepartmentofAdvancedMaterialsScience&Engineering,Hanseo University,Seosan-si,Chungnam,Korea;AnhuiInternationalJointResearchCenter forNanoCarbon-basedMaterialsandEnvironmentalHealth,CollegeofMaterials ScienceandEngineering,AnhuiUniversityofScience&Technology,Huainan, PRChina
PakornOpaprakasit SchoolofBio-ChemicalEngineeringandTechnology, SirindhornInternationalInstituteofTechnology(SIIT),ThammasatUniversity, PathumThani,Thailand
SuriatiPaiman DepartmentofPhysics,FacultyofScience;Functional NanotechnologyDevicesLaboratory(FNDL),InstituteofNanoscienceand Nanotechnology,UniversitiPutraMalaysia,Serdang,Selangor,Malaysia
LijiaPan CollaborativeInnovationCenterofAdvancedMicrostructures,Schoolof ElectronicScienceandEngineering,NanjingUniversity,Nanjing,China
XinyuPing SchoolofArtsandSciences,UniversityofPennsylvania,Philadelphia, PA,UnitedStates
JibanPodder DepartmentofPhysics,BangladeshUniversityofEngineeringand Technology(BUET),Dhaka,Bangladesh
SureshSagadevan Nanotechnology&CatalysisResearchCentre,Universityof Malaya,KualaLumpur,Malaysia
K.TamizhSelvi DepartmentofPhysics,VelTechHighTechDr.Rangarajan Dr.SakunthalaEngineeringCollege,Chennai,India
MehmoodShahid CenterofMicro-NanoSystem,SchoolofInformationScienceand Technology,FudanUniversity,Shanghai,China;SchoolofBio-Chemical EngineeringandTechnology,SirindhornInternationalInstituteofTechnology (SIIT),ThammasatUniversity,PathumThani,Thailand
YiShi CollaborativeInnovationCenterofAdvancedMicrostructures,Schoolof ElectronicScienceandEngineering,NanjingUniversity,Nanjing,China
NorAzwadiCheSidik Takasagoi-Kohza,Malaysia-JapanInternationalInstituteof Technology,UniversitiTeknologiMalaysia,KualaLumpur,Malaysia
NoorAzrinaTalik LowDimensionalMaterialsResearchCentre,Departmentof Physics,FacultyofScience,UniversityofMalaya,KualaLumpur,Malaysia
GregorySoonHowThien LowDimensionalMaterialsResearchCentre,Department ofPhysics,FacultyofScience,UniversityofMalaya,KualaLumpur;Centrefor AdvancedDevicesandSystems,FacultyofEngineering,MultimediaUniversity, Selangor,Malaysia
P.Vajeeston CentreforMaterialsScienceandNanotechnologyChemistry, DepartmentofChemistry,UniversityofOslo,Oslo,Norway
V.Venkatachalapathy DepartmentofPhysics/CentreforMaterialsScienceand Nanotechnology,UniversityofOslo,Oslo,Norway;DepartmentofMaterials Science,NationalResearchNuclearUniversity,Moscow,RussianFederation
Mohd.HanifYaacob WirelessandPhotonicsNetworkResearchCentre,Engineering andTechnologyComplex,UniversitiPutraMalaysia,Serdang,Selangor,Malaysia
AsadA.Zaidi DepartmentofMechanicalEngineering,FacultyofEngineering ScienceandTechnology,HamdardUniversity,Madinatal-Hikmah,Hakim MohammadSaidRoad,Karachi,Pakistan
YiqiangZhan CenterofMicro-NanoSystem,SchoolofInformationScienceand Technology,FudanUniversity,Shanghai,China
JingZhang CollaborativeInnovationCenterofAdvancedMicrostructures,Schoolof ElectronicScienceandEngineering,NanjingUniversity,Nanjing,China
Serieseditorbiography GhenadiiKorotcenkov receivedhisPhDinPhysicsandTechnologyofSemiconductorMaterials andDevicesin1976andhisDoctorofScience Degree(DoctorHabilitate)inPhysicsofSemiconductorsandDielectricsin1990.Hehasmore than45yearsofexperienceasateacherandscientificresearcher.Foralongtimehewasaleaderof thegassensorgroupandmanagerofvarious nationalandinternationalscientificandengineeringprojectscarriedoutintheLaboratoryof Micro-andOptoelectronics,TechnicalUniversity ofMoldova,Chisinau,Moldova.Hisresearchhas receivedfinancialsupportfrominternational foundationsandprogramssuchastheCRDF, theMRDA,theICTP,theINTAS,theINCO-COPERNICUS,theCOST,andNATO. From2007to2008,hewasaninvitedscientistattheKoreaInstituteofEnergy Research(Daejeon);followingwhich,until2017,Dr.Korotcenkovwasaresearch professorintheSchoolofMaterialsScienceandEngineeringatGwangjuInstitute ofScienceandTechnology(GIST)inKorea.Currently,Dr.Korotcenkovisachief scientificresearcheratMoldovaStateUniversity,Chisinau,Moldova.
SpecialistsfromtheformerSovietUnionknowG.Korotcenkov’sresearchresults inthefieldofstudyofSchottkybarriers,MOSstructures,nativeoxides,andphotoreceiversonthebasisofIII–VscompoundssuchasInP,GaP,AlGaAs,andInGaAs. Hispresentscientificinterests,startingfrom1995,includematerialsscience,focusing onmetaloxidefilmdepositionandcharacterization(In2O3,SnO2,TiO2),surfacescience,thermoelectricconversion,anddesignofphysicalandchemicalsensors,includingthinfilmgassensors.
Dr.Korotcenkovistheauthororeditorof45booksandspecialissues,includingthe 11-volume“ChemicalSensors”seriespublishedbyMomentumPress,15-volume “ChemicalSensors”seriespublishedbyHarbinInstituteofTechnologyPress,China, three-volume“PorousSilicon:FromFormationtoApplication”issuepublishedby CRCPress,two-volume“HandbookofGasSensorMaterials”publishedbySpringer, three-volume“HandbookofHumidityMeasurements”publishedbyCRCPress,and sixproceedingsofinternationalconferencespublishedbyTransTechPubl.,Elsevier, andEDPSciences.Currentlyheisaserieseditorofthe“MetalOxides”bookseries
publishedbyElsevier.Sinceitsinceptionin2017,morethan24volumeshavealready beenpublishedwithintheframeworkofthatseries.
Dr.Korotcenkovisauthorandcoauthorofmorethan650scientificpublications including31reviewpapers,38bookchapters,andmorethan200peer-reviewedarticlespublishedinscientificjournals(h-factor ¼ 41(WebofScience),h ¼ 43(Scopus), andh ¼ 57(Googlescholarcitation)),andisaholderof17patents.Hehasalsopresentedmorethan250reportstonationalandinternationalconferences,including17 invitedtalks.G.Korotcenkov,asacochairmanoramemberofprogram,scientific, andsteeringcommittees,hasparticipatedintheorganizationofmorethan30internationalscientificconferences.Dr.Korotcenkovisamemberofeditorialboardsin fivescientificinternationaljournals.Hisnameandactivitieshavebeenlistedbymany biographicalpublicationsincludingWho’sWho.Hisresearchactivitieshavebeen honoredbytheHonoraryDiplomaoftheGovernmentoftheRepublicofMoldova (2020),anAwardoftheAcademyofSciencesofMoldova(2019),anAwardof theSupremeCouncilofScienceandAdvancedTechnologyoftheRepublicofMoldova(2004),thePrizeofthePresidentsoftheUkrainian,Belarus,andMoldovan AcademiesofSciences(2003),SeniorResearchExcellenceAwardoftheTechnical UniversityofMoldova(2001;2003;2005),andtheNationalYouthPrizeofthe RepublicofMoldovaintheFieldofScienceandTechnology(1980),amongothers. Dr.KorotcenkovhasalsoreceivedfellowshipsfromtheInternationalResearch ExchangeBoard(IREX,UnitedStates,1998),BrainKorea21Program(2008–2012),andBrainPoolProgram(Korea,2007–2008and2015–2017).
https://www.scopus.com/authid/detail.uri?authorId¼6701490962 https://publons.com/researcher/1490013/ghenadii-korotcenkov/ https://scholar.google.com/citations?user¼XR3RNhAAAAAJ&hl https://www.researchgate.net/profile/G_Korotcenkov
Prefacetotheseries Thefieldofsynthesis,study,andapplicationofmetaloxidesisoneofthemostrapidly progressingareasofscienceandtechnology.MetaloxidesareoneofthemostubiquitouscompoundgroupsonEarth,andhaveawidevarietyofchemicalcompositions, atomicstructures,andcrystallineshapes.Inaddition,metaloxidesareknownto possessuniquefunctionalitiesthatareabsentorinferiorinothersolidmaterials.In particular,metaloxidesrepresentavariedandappealingclassofmaterialsthatexhibit afullspectrumofelectronicproperties—frominsulatingtosemiconducting,metallic, andsuperconducting.Moreover,almostalltheknowneffects,includingsuperconductivity,thermoelectriceffects,photoelectricaleffects,luminescence,andmagnetism canbeobservedinmetaloxides.Therefore,metaloxideshaveemergedasanimportantclassofmultifunctionalmaterialswitharichcollectionofpropertiesthathave greatpotentialfornumerousdeviceapplications.
Specificproperties,suchasthewidevarietyofmaterialswithdifferent electrophysical,optical,andchemicalcharacteristics,theirhighthermalandtemporal stability,andtheirabilitytofunctioninharshenvironments,makemetaloxideshighly suitablematerialsfordesigningtransparentelectrodes,high-mobilitytransistors,gas sensors,actuators,acousticaltransducers,photovoltaicandphotonicdevices,photoandheterogeneouscatalysts,solid-statecoolers,high-frequencyandmicromechanical devices,energy-harvestingandstoragedevices,nonvolatilememorydevices,and manyotherapplicationsintheelectronics,energy,andhealthsectors.Inthesedevices, metaloxidescanbesuccessfullyusedassensingoractivelayers,substrates,electrodes,promoters,structuremodifiers,membranes,andfibers,i.e.,canbeusedasboth activeandpassivecomponents.
Amongotheradvantagesofmetaloxidesarethelowfabricationcostandrobustnessinpracticalapplications.Furthermore,metaloxidescanbepreparedinvarious forms,suchasceramics,thickfilms,andthinfilms.Furthermore,thinfilmdeposition techniquescanbeusedformetaloxidesthatarecompatiblewithstandardmicroelectronictechnology.Thislastfactorisveryimportantforlarge-scaleproduction, becausethemicroelectronicapproachpromoteslowcostformassproduction,offers thepossibilityofmanufacturingdevicesonachip,andguaranteesgoodreproducibility.Variousmetaloxidenanostructures,includingnanowires,nanotubes,nanofibers, core-shellstructures,andhollownanostructurescanalsobesynthesized.Asaconsequence,thefieldofmetaloxidenanostructuredmorphologies(e.g.,nanowires, nanorods,nanotubes,etc.)hasbecomeoneofthemostactiveresearchareaswithin thenanosciencecommunity.
Theabilitytocreateavarietyofmetaloxide-basedcompositesandtheabilityto synthesizevariousmulticomponentcompoundssignificantlyexpandstherangeof propertiesthatmetaloxide-basedmaterialscanhave,makingmetaloxidesatruly
versatilemultifunctionalmaterialforwidespreaduse.Itisknownthatsmallchanges intheirchemicalcompositionandatomicstructurecanbeaccompaniedbyspectacularvariationinthepropertiesandbehaviorofmetaloxides;andevennow,advances insynthesizingandcharacterizingtechniquesarerevealingnumerousnewfunctions ofmetaloxides.
Takingintoaccounttheimportanceofmetaloxidesforprogressinmicroelectronics,optoelectronics,photonics,energyconversion,sensors,andcatalysis,alarge andvariedrangeofbooksdevotedtothisclassofmaterialshavebeenpublished.However,oneshouldnotethatsomebooksfromthislistaretoogeneral,somebooksare collectionsofvariousoriginalworkswithoutanygeneralizations,andotheroneswere publishedmanyyearsago.Nonetheless,duringthepastdecadegreatprogresshas beenmadeonthesynthesisaswellasonthestructural,physical,chemicalcharacterization,andapplicationofmetaloxidesinvariousdevices,andalargenumberof papershavebeenpublishedonmetaloxides.Inaddition,untilnow,manyimportant topicsrelatedtometaloxides’studyandapplicationhadnotbeendiscussed.Toremedythissituation,wedecidedtogeneralizeandsystematizetheresultsofresearchin thisfieldandtopublishaseriesofbooksdevotedtometaloxides.
Oneshouldnotethattheproposedbookseries“MetalOxides”isthefirstone devotedsolelytoconsiderationofmetaloxides.Webelievethatcombiningbooks onmetaloxidesinaseriescouldhelpreadersinfindingrequiredinformationon thesubject.Inparticular,weintendthatthebooksfromourseries,whichhavea clearspecializationofcontent,willprovideinterdisciplinarydiscussionforvarious oxidematerialswithawiderangeoftopics,frommaterialsynthesisanddeposition tocharacterizations,processing,andtodevicefabricationsandapplications.This seriesofbooksispreparedbyateamofhighlyqualifiedexperts,whichguarantees itahighdegreeofquality.
Ihopethatourbookswillbebothusefulandeasytouse.Iwouldalsoliketohope thatreaderswillconsiderthis“MetalOxides”seriestobelikeanencyclopediaof metaloxidesthatenablesthemtounderstandthepresentstatusofmetaloxides,to estimatetheroleofmultifunctionalmetaloxidesindesignofadvanceddevices, andthen,basedonobservedknowledge,toformulatenewgoalsforfurtherresearch.
Theintendedaudienceofthepresentseriesisscientistsandresearchersworkingor planningtoworkinthefieldofmaterialsrelatedtometaloxides,i.e.,scientistsand researcherswhoseactivitiesarerelatedtoelectronics,optoelectronics,energy,catalysis,sensors,electricalengineering,ceramics,biomedicaldesigns,etc.Ibelievethat this“MetalOxides”serieswillalsobeinterestingforpracticingengineersorproject managersinindustriesandnationallaboratories,whowouldliketodesignmetal oxide-baseddevices,butdon’tknowhowtodoit,orhowtoselectoptimalmetal oxidesforspecificapplications.Withmanyreferencestothevastresourceofrecently publishedliteratureonthesubject,thisserieswillserveasasignificantandinsightful sourceofvaluableinformation,providingscientistsandengineerswithnewinsights forunderstandingandimprovingexistingmetaloxide-baseddevicesandfordesigningnewmetaloxide-basedmaterialswithnovelandunexpectedproperties.
Ibelievethatthis“MetalOxides”seriesofbookswillbeveryhelpfulforuniversity students,postdocs,andprofessors.Thestructureofthesebooksoffersabasisfor
coursesinthefieldofmaterialsciences,chemicalengineering,electronics,electrical engineering,optoelectronics,energytechnologies,environmentalcontrol,andmany others.Graduatestudentsshouldalsofindthebookseriestobeveryusefulintheir researchandinunderstandingfeaturesofmetaloxidessynthesis,study,andtheapplicationofthismultifunctionalmaterialinvariousdevices.Wearesurethatallofthe abovewillfindinformationusefulfortheiractivities.
Finally,Ithankallcontributingauthorsandeditorswhohavebeeninvolvedinthe creationofthesebooks.Iamthankfulthattheyagreedtoparticipateinthisproject andfortheireffortsinthepreparationofthesebooks.Withouttheirparticipation,this projectwouldnothavebeenpossible.IalsoexpressmygratitudetoElsevierforgiving ustheopportunitytopublishthisseries.Iespeciallythankthewholeeditorialteamat Elsevierfortheirpatienceduringthedevelopmentofthisprojectandforencouraging usduringthevariousstagesofpreparation.
GhenadiiKorotcenkov
Preface Metaloxides(MOs)arethemostprofusestablematerialsfoundintheearth’scrust. Whencomparedtoconventionalsemiconductormaterialssuchassiliconandother III–Vgroupcompounds,thepropertiesofferedbyMOsarecompletelydifferent, includingthematerialsynthesisprocess,electronicandchargetransportmechanisms, presenceofcrystaldefects,fabricationofthinfilms,andoptoelectronicproperties. Also,theyarerelativelyinexpensive,robust,lightweight,long-lasting,andbenefit fromhighmaterialsensitivityandquickresponsetimes.ThusMOsareutilizedin avarietyofrolesasindustrialalternatives.
However,thelackofbasicinformation,includingthesynthesisprocessandthe mechanismthatleadstotheirapplicationandefficiencycontrol,isamajorbottleneck forpracticality.Thereforethisbookprovidesrecentinnovativeinformationabout MOsandtheirmechanisticrolesinoptoelectronicandphotoluminescenceapplications.Thebookisalsoaimedatpresentingresearcharticlesandcomprehensive reviewstoimproveoptoelectronicefficiency.Emphasisisplacedontheprinciples andtechniquesfromsynthesischemistrytoservefieldssuchasintegrativeoptoelectronics,photoniccrystals,nonlinearphotonics,opticalfiber,bionanotechnologies, biomedicine,andothers.AnefficientsynthesisprocedurecanimproveMOphysical propertiesandreflectedsurfacechemicalchangescanaffectperformanceinvarious deviceslikelight-emittingdiodes,luminescencematerials,solarcells,biomedical probes,andothers,sothesetopicsarecoveredaswell.Further,becauseofthecomparativedevelopmentofMOstoenhanceapplicabilityinvarioussectors,thechallengesassociatedwiththehandlingandmaintenanceofMOcrystallineproperties andn-andp-typeinteractionsintheconductionbandsarealsodiscussed.Webelieve thatthisinformationwillservethoselookingtolearnmoreaboutthemanufactureof MOsasacheaperandmoreeffectivematerialinthefieldsofelectronics,photonics, biomedical,andengineering.
MO-basedcompositesarealsoextremelyimportantmaterialsfrombothascientificaswellasatechnologicalviewpoint,duetotheuniquefunctionalitiesoffered bysolid-statematerials.TheMOsbelongtoanassortedandappealingclassofmaterialsinwhichtheirpropertiesexhibitafullspectrumofelectronic,structural,elastic, optical,thermal,biocompatible,andotherproperties,frominsulatingtosemiconducting,metallics,andsuperconducting.Moreover,thesematerialscanrecognize phenomenaofsuperconductivity,thermoelectriceffects,photoelectricaleffects,luminescence,andmagnetism,givingthemaneminentimportanceamongmultifunctional materialswiththeirrichcollectionofpropertieshavingstrongpotentialfornumerous deviceapplications.BasedonthepotentialrolesandadvantagesofMOs,thisbookis expectedtoserveasavitalresourceforbothprofessionalsfromindustryandacademiciansworkingintheareasofopticaldevices,lighting,displayandimaging
technologies,biomedicaldevices,andsensors.Foracademiciansinparticular,this bookcanhelpindevelopingcoursesandresearchtopicslinkedtophotonics, nanosciences,luminescence,bioimaging,andopticalmaterials.Thebookcontains 15chapterscoveringalltheareasmentionedhere,andthecontributorsarefrom diversefieldsaroundtheglobe.Thecoverageofthetopicsisdesignedinsucha waythatthereaders/subjectspecialistscaneasilyfindthediscussionsrelatedtointerdisciplinaryfieldsofoxidematerialswithawiderangeoftopics,frommaterialsynthesisanddepositiontocharacterizations,processing,anddevicefabricationand applications.
Thisbookiseditedbyateamofhighlyqualifiedexperts,guaranteeingitshigh quality.Wethankalltheauthorsfortheirvaluablecontributions,aswithouttheirsupport,ourbookideawouldnothavebecomeareality.Wealsoexpressgratitudeto Elsevierforgivingustheopportunitytoworkonthisbookseries.
SectionA Technologyandproperties Metaloxidesforoptoelectronic andphotonicapplications:A generalintroduction 1 MehmoodShahid a,b,SureshSagadevanc,WaqarAhmed d,YiqiangZhana,and PakornOpaprakasit b aCenterofMicro-NanoSystem,SchoolofInformationScienceandTechnology,Fudan University,Shanghai,China, bSchoolofBio-ChemicalEngineeringandTechnology, SirindhornInternationalInstituteofTechnology(SIIT),ThammasatUniversity, PathumThani,Thailand, cNanotechnology&CatalysisResearchCentre,Universityof Malaya,KualaLumpur,Malaysia, dInstituteforAdvancedStudies,UniversityofMalaya, KualaLumpur,Malaysia
1Introduction Metaloxidesarecrystallinesolidsthatcontainametalcationandanoxideanion.They typicallyreactwithwatertoformbasesorwithacidstoformsalts.Mostoftheoxides areformedinsoil;theseoxidemineralsaretypicallycomposedofoxides,hydroxides, oxyhydroxides,andhydratedoxides [1].Metaloxides(MOs)areafascinatingclassof compoundswithdiversepropertiesthatcovervariousaspectsofmaterialsscience, physics,andchemistry [2,3].MOsinbulkorintheformofthinfilms,oras nanostructures,behaveinahighlydiversemannerandexhibitavarietyoffunctional properties,whichenablethemtostandoutasidealcandidatesforvarioustechnologicalapplications,suchasinoptoelectronicdevices,passiveopticaldevices,catalysis, andsolarcells,forenvironmentalapplications,andasgassensors [1].Metalelements canformalargevarietyofoxidecompounds.Theseelementscanbesynthesizedwith diversestructuralgeometriesandwithadifferentelectronicstructurethatcanexhibit metallic,semiconductor,orinsulatorcharacteristics.Inthefieldoftechnological applications,MOsareemployedinfabricatingmicroelectroniccircuits,optoelectronics,piezoelectricdevices,andcatalysts.MOsbehavedifferentlyatthenanoscale,and, whencomparedtotheirbulkcounterparts,theyexhibitdifferentphysical,chemical, optical,andelectronicpropertiesatthenanoscaleduetotheavailabilityofmore surfaceatomsthaninterioratomsandquantumconfinement,whentakingpartin anyreaction.Therefore,thepracticalapplicationsofMOsdependupontheirpropertiessuchasshape,size,surfacearea,crystallinity,conductivity,andphotocatalytic activity [4,5].
Photo-dependentdevicesandapplicationsrelyonmaterialswithahighrefractive index.Therefractiveindex(n > 3)contrastbetweenaphotonicstructureandthesurroundingmediumenablesthesynthesizedmaterialtobecomeapromisingcandidate