Griffy Lake Limited Sediment Characterization Investigation by Bloomington, Indiana Parks and Recreation Department

Griffy Lake Limited Sediment Characterization Investigation (Addendum) Griffy Reservoir, Bloomington, Indiana

Prepared for: City of Bloomington Parks & Recreation 401 North Morton Street Suite 250 PO Box 848 Bloomington, Indiana 47402 Prepared by:

Date: February 24, 2012 Project Number: 09-02.07

SITE

Fields Environmental, Inc.

1309 West Vernal Pike Bloomington, IN 47404 Phone: (812) 333-5333 www.fieldsenvironmentalinc.com

Figure 1 Griffy Lake, Bloomington, Indiana Area Map For: City of Bloomington

Date: 2– 1 – 12

Project # 09-02.07

Graphics obtained from: The United States Geological Survey (http://usgs.gov)

GS-5 28"-29" ARSENIC 18

GS-6 28"-30" ARSENIC 17

GS-4 25" ARSENIC 19

GS-1 20"-24" ARSENIC 5.5

GS-2 24" ARSENIC 7.2

GS-3 24"-26" ARSENIC 11

LEGEND 100 = DETECTION EXCEEDS IDEM RISC RESIDENTIAL DEFAULT CLOSURE LEVEL 100 = DETECTION EXCEEDS IDEM RISC INDUSTRIAL DEFAULT CLOSURE LEVEL

ONLY RESULTS THAT EXCEED APPLICABLE CRITERIA SHOWN

GRAPHICS OBTAINED FROM: INDIANA UNIVERSITY SPATIAL DATA SERVICE

Figure 2 SEDIMENT SAMPLING RESULTS, 2010 AERIAL PHOTOGRAPH

Table 2. Sediment Analytical Results (Estimated Results) - Griffy Lake Bloomington, Monroe County, Indiana Sediment Sampling Event - January 2012

Constituents Results in mg/Kg CAS # 83-32-9 208-96-8 120-12-7 56-55-3 50-32-8 205-99-2 191-24-2 207-08-9 218-01-9 53-70-3 206-44-0 86-73-7 193-39-5 91-20-3 85-01-8 129-00-0 CAS # 120-82-1 95-50-1 541-73-1 106-46-7 108-60-1 95-95-4 95 95 4 88-06-2 120-83-2 105-67-9 51-28-5 121-14-2 606-20-2 91-58-7 95-57-8 91-57-6 95-48-7 88-74-4 88-75-5 91-94-1 * 99-09-2 534-52-1 101-55-3 59-50-7 7005-72-3 100-01-6 100-02-7 100-51-6 111-91-1 111-44-4 117-81-7 85-68-7 86-74-8 132-64-9

SVOCs - Method 8270D LL (GC/MS) - Low Level Acenaphthene Acenaphthylene Anthracene Benzo(A)Anthracene Benzo(A)Pyrene Benzo(B)Fluoranthene Benzo(G,H,I)Perylene Benzo(K)Fluoranthene Chrysene Dibenz(A,H)Anthracene Fluoranthene Fluorene Indeno (1,2,3-C,D) Pyrene Naphthalene Phenanthrene Pyrene SVOCs - Method 8270D (GC/MS) 1,2,4-Trichlorobenzene 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 2,2'-Oxybis(1-Chloropropane) 2 4 5-Trichlorophenol 2,4,5 Trichlorophenol 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2-Chloronaphthalene 2-Chlorophenol 2-Methylnaphthalene 2-Methylphenol 2-Nitroaniline 2-Nitrophenol 3,3'-Dichlorobenzidine 3 & 4 Methylphenol 3-Nitroaniline 4,6-Dinitro-2-Methylphenol 4-Bromophenyl Phenyl Ether 4-Chloro-3-Methylphenol 4-Chlorophenyl Phenyl Ether 4-Nitroaniline 4-Nitrophenol Benzyl Alcohol Bis(2-Chloroethoxy) Methane Bis(2-Chloroethyl)Ether Bis(2-Ethyhexyl)Phthalate Butyl Benzyl Phthalate Carbazole Dibenzofuran

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IDEM RISC Default Closure GS-1 Levels 20"-24"

GS-2 24"

GS-3 24"-26"

GS-4 25"

GS-5 28"-29"

GS-6 28"-30"

Industrial

Residential

1/10/12

1800 180 2000 15 1.5 15 ** 39 1500 1.5 2000 1100 15 170 170 2000

130 18 2000 5 0.5 5 ** 50 500 0.5 2000 170 5 0.7 13 2000

<0.023 <0.023 <0.023 0.064 0.097 0.13 0.08 0.057 0.12 <0.023 0.18 <0.023 0.066 <0.023 0.044 0.14

<0.025 <0.025 <0.025 0.06 0.099 0.13 0.08 0.064 0.13 <0.025 0.22 <0.025 0.066 <0.025 0.064 0.17

<0.022 <0.022 <0.022 0.022 0.032 0.037 0.023 <0.022 0.039 <0.022 0.061 <0.022 <0.022 <0.022 0.024 0.055

<0.031 <0.031 <0.031 0.093 0.14 0.2 0.11 0.1 0.19 <0.031 0.34 <0.031 0.093 <0.031 0.11 0.27

<0.023 <0.023 <0.023 <0.023 <0.023 0.023 <0.023 <0.023 0.028 <0.023 0.042 <0.023 <0.023 <0.023 <0.023 0.039

<0.022 <0.022 <0.022 0.024 0.035 0.049 0.028 0.022 0.048 <0.022 0.075 <0.022 0.023 <0.022 0.03 0.069

77 220 8.9 3.4 0.26 690 0.2 3 25 0.82 ** ** 560 10 42 39 1.9 ** 0.21 3 ** ** ** ** ** ** ** 140 ** 0.012 980 310 20 65

5.3 17 2.3 2.2 0.027 250 0.07 1.1 9 0.29 ** ** 42 0.75 3.1 14 0.67 ** 0.062 1.1 ** ** ** ** ** ** ** 48 ** 0.0007 300 310 5.9 4.9

<0.56 <0.56 <0.56 <0.56 <0.084 <0 56 <0.56 <0.56 <0.56 <0.56 <0.42 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.43 <0.56 <0.22 <0.56 <2.9 <2.9 <0.56 <0.56 <0.56 <2.9 <2.9 <0.56 <0.56 <0.074 <0.56 <0.56 <0.56 <0.56

<0.61 <0.61 <0.61 <0.61 <0.61 <0 61 <0.61 <0.61 <0.61 <0.61 <3.1 <0.61 <0.61 <0.61 <0.61 <0.61 <0.61 <3.1 <0.61 <1.2 <0.61 <3.1 <3.1 <0.61 <0.61 <0.61 <3.1 <3.1 <0.61 <0.61 <0.61 <0.61 <0.61 <0.61 <0.61

<0.54 <0.54 <0.54 <0.54 <0.54 <0 54 <0.54 <0.54 <0.54 <0.54 <2.8 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <2.8 <0.54 <1.1 <0.54 <2.8 <2.8 <0.54 <0.54 <0.54 <2.8 <2.8 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54

<0.76 <0.76 <0.76 <0.76 <0.76 <0 76 <0.76 <0.76 <0.76 <0.76 <3.9 <0.76 <0.76 <0.76 <0.76 <0.76 <0.76 <3.9 <0.76 <1.5 <0.76 <3.9 <3.9 <0.76 <0.76 <0.76 <3.9 <3.9 <0.76 <0.76 <0.76 <0.76 <0.76 <0.76 <0.76

<0.56 <0.56 <0.56 <0.56 <0.56 <0 56 <0.56 <0.56 <0.56 <0.56 <2.9 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <2.9 <0.56 <1.1 <0.56 <2.9 <2.9 <0.56 <0.56 <0.56 <2.9 <2.9 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56

<0.55 <0.55 <0.55 <0.55 <0.55 <0 55 <0.55 <0.55 <0.55 <0.55 <2.8 <0.55 <0.55 <0.55 <0.55 <0.55 <0.55 <2.8 <0.55 <1.1 <0.55 <2.8 <2.8 <0.55 <0.55 <0.55 <2.8 <2.8 <0.55 <0.55 <0.55 <0.55 <0.55 <0.55 <0.55

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Table 1. Sediment Analytical Results (Estimated Results) - Griffy Lake Bloomington, Monroe County, Indiana Sediment Sampling Event - January 2012

Constituents Results in mg/Kg 84-66-2 131-11-3 84-74-2 117-84-0 87-68-3 118-74-1 77-47-4 67-72-1 78-59-1 98-95-3 62-75-9 621-64-7 86-30-6 106-47-8 87-86-5 108-95-2 CAS # 72-54-8 72-55-9 50-29-3 309-00-2 319-84-6 5103-71-9 319-85-7 57-74-9 319-86-8 60-57-1 959-98-8 33213-65-9 1031-07-8 72-20-8 7421-93-4 53494-70-5 58-89-9 76-44-8 1024-57-3 72-43-5 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5 8001-35-2 CAS # 93-76-5 94-75-7 75-99-0 1918-00-9 120-36-5 88-85-7 94-74-6 93-65-2 87-86-5 1918-02-1 93-72-1

Diethyl Phthalate Dimethyl Phthalate Di-n-butyl phthalate Di-n-octyl phthalate Hexachlorobutadiene Hexachlorobenzene Hexachlorocyclopentadiene Hexachloroethane Isophorone Nitrobenzene N-Nitrosodimethylamine N-Nitrosodi-n-propylamine N-Nitrosodiphenylamine 4-Chloroaniline Pentachlorophenol Phenol Organochlorine Pesticides and PCBs - Method 8081B/8082A 4,4'-DDD 4,4'-DDE 4,4'-DDT Aldrin alpha-BHC alpha-Chlordane beta-BHC Chlordane (technical) delta-BHC Dieldrin Endosulfan I Endosulfan II Endosulfan sulfate Endrin Endrin aldehyde Endrin ketone gamma-BHC (Lindane) Heptachlor Heptachlor epoxide Methoxychlor PCB-1016 PCB-1221 PCB-1232 PCB-1242 PCB-1248 PCB-1254 PCB-1260 Toxaphene Herbicides - Method 8151A (GC) 2,4,5-Trichlorophenoxyacetic acid (2,4,5-T) 2,4-Dichlorophenoxyacetic acid (2,4-D) Dalapon Dicamba Dichlorprop Dinoseb MCPA MCPP Pentachlorophenol Picloram Silvex (2,4,5-TP)

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IDEM RISC Default Closure GS-1 Levels 20"-24"

GS-2 24"

GS-3 24"-26"

GS-4 25"

GS-5 28"-29"

GS-6 28"-30"

Industrial

Residential

840 1100 760 2000 66 3.9 720 7.7 18 0.34 ** 0.002 32 2.7 0.66 160

450 1100 760 2000 24 2.2 400 2.8 5.3 0.028 ** 0.0006 9.7 0.97 0.028 56

1/10/12 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.10 <0.56 <0.24 <0.56 <0.57 <0.73 <0.56

1/10/12 <0.61 <0.61 <0.61 <0.61 <0.61 <0.61 <0.61 <0.61 <0.61 <0.61 <0.61 <0.61 <0.61 <1.2 <3.1 <0.61

1/10/12 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <1.1 <2.8 <0.54

1/10/12 <0.76 <0.76 <0.76 <0.76 <0.76 <0.76 <0.76 <0.76 <0.76 <0.76 <0.76 <0.76 <0.76 <1.5 <3.9 <0.76

1/10/12 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <0.56 <1.1 <2.9 <0.56

1/10/12 <0.55 <0.55 <0.55 <0.55 <0.55 <0.55 <0.55 <0.55 <0.55 <0.55 <0.55 <0.55 <0.55 <1.1 <2.8 <0.55

120 86 86 0.8 0.024 ** 0.086 ** ** 0.15 ** ** ** 15 ** ** 0.1 2.9 1 180 5.3*** 5.3*** 5.3*** 5.3*** 5.3*** 5.3*** 5.3*** 12

28 20 20 0.25 0.0072 ** 0.026 ** ** 0.046 ** ** ** 0.99 ** ** 0.0094 0.93 0.47 160 1.8*** 1.8*** 1.8*** 1.8*** 1.8*** 1.8*** 1.8*** 3.9

<0.0056 <0.0056 <0.0056 <0.0029 <0.0029 <0 0029 <0.0029 <0.0029 <0.029 <0.0029 <0.0056 <0.0029 <0.0056 <0.0056 <0.0056 <0.0056 <0.0056 <0.0029 <0.0029 <0.0029 <0.029 <0.056 <0.11 <0.056 <0.056 <0.056 <0.056 <0.056 <0.29

<0.0061 <0.0061 <0.0061 <0.0031 <0.0031 <0 0031 <0.0031 <0.0031 <0.031 <0.0031 <0.0061 <0.0031 <0.0061 <0.0061 <0.0061 <0.0061 <0.0061 <0.0031 <0.0031 <0.0031 <0.031 <0.061 <0.12 <0.061 <0.061 <0.061 <0.061 <0.061 <0.31

<0.0054 <0.0054 <0.0054 <0.0028 <0.0028 <0 0028 <0.0028 <0.0028 <0.028 <0.0028 <0.0054 <0.0028 <0.0054 <0.0054 <0.0054 <0.0054 <0.0054 <0.0028 <0.0028 <0.0028 <0.028 <0.054 <0.11 <0.054 <0.054 <0.054 <0.054 <0.054 <0.28

<0.0076 <0.0076 <0.0076 <0.0039 <0.0039 <0 0039 <0.0039 <0.0039 <0.039 <0.0039 <0.0076 <0.0039 <0.0076 <0.0076 <0.0076 <0.0076 <0.0076 <0.0039 <0.0039 <0.0039 <0.039 <0.076 <0.15 <0.076 <0.076 <0.076 <0.076 <0.076 <0.39

<0.0056 <0.0056 <0.0056 <0.0029 <0.0029 <0 0029 <0.0029 <0.0029 <.029 <0.0029 <0.0056 <0.0029 <0.0056 <0.0056 <0.0056 <0.0056 <0.0056 <0.0029 <0.0029 <0.0029 <0.029 <0.056 <0.11 <0.056 <0.056 <0.056 <0.056 <0.056 <0.29

<0.0055 <0.0055 <0.0055 <0.0028 <0.0028 <0 0028 <0.0028 <0.0028 <0.028 <0.0028 <0.0055 <0.0028 <0.0055 <0.0055 <0.0055 <0.0055 <0.0055 <0.0028 0.0031 <0.0028 <0.028 <0.055 <0.11 <0.055 <0.055 <0.055 <0.055 <0.055 <0.28

6.1 5.2 ** ** ** ** ** ** 0.66 ** **

2.2 0.35 ** ** ** ** ** ** 0.028 ** **

<0.014 <0.014 <3.4 <0.034 <0.17 <0.17 <3.4 <3.4 <0.029 <0.0056 <0.014

<0.015 <0.015 <3.7 <0.037 <0.18 <0.18 <3.7 <3.7 <0.031 <0.0061 <0.015

<0.014 <0.014 <3.3 <0.033 <0.16 <0.16 <3.3 <3.3 <0.028 <0.0054 <0.014

<0.019 <0.019 <4.6 <0.046 <0.23 <0.23 <4.6 <4.6 <0.039 <0.0076 <0.019

<0.014 <0.014 <3.4 <0.034 <0.17 <0.17 <3.4 <3.4 <0.029 <0.0056 <0.014

<0.014 <0.014 <3.3 <0.033 <0.17 <0.17 <3.3 <3.3 <0.028 <0.0055 <0.014

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Table 2. Sediment Analytical Results (Estimated Results) - Griffy Lake Bloomington, Monroe County, Indiana Sediment Sampling Event - January 2012

Constituents Results in mg/Kg CAS # 7440-38-2 7440-39-3 7440-43-9 7440-47-3 7439-92-1 7782-49-2 7440-22-4 CAS # 7439-97-6 * ** *** 1

<0.0 <0.0 <0.0 100.0 100.0 100.0

Metals - Method 6010C (ICP) Arsenic (TOTAL) Barium (TOTAL) Cadmium (TOTAL) Chromium (TOTAL) Lead (TOTAL) Selenium (TOTAL) Silver (TOTAL) Mercury - Method 7471B Mercury (TOTAL)

IDEM RISC Default Closure GS-1 Levels 20"-24"

GS-2 24"

GS-3 24"-26"

GS-4 25"

GS-5 28"-29"

GS-6 28"-30"

Industrial

Residential

1/10/12

5.8 10000 77 10000 230 53 87

3.9 1600 7.5 10000 81 5.2 31

5.5 97 <0.75 19 15 <2.3 <1.5

7.7 95 <0.92 18 17 <2.8 <1.8

11 79 <0.76 17 25 <2.3 <1.5

19 86 <0.90 21 20 <2.7 <1.8

18 130 <0.67 25 16 2 <1.3

17 100 1.4 20 20 <2.1 <1.4

2.1

0.023

0.032

0.022

0.034

0.039

<2.1

=Mixture of 108-39-4 & 106-44-5. 106-44-5 RISC Default Closure Levels utilized = Criteria not found for constituent =Criteria refers to Total PCBs; analysis completed on individual Arochlors - no PCBs detected = Result is less than the Reporting limit but greater than or equal to the Method Detection Limit and the concentration is an approximate value. = Constituent not detected at reporting limit = Constituent not detected - Reporting limit exceeds IDEM RISC Residential Default Closure Level = Constituent not detected - Reporting limit exceeds IDEM RISC Industrial Default Closure Level = Detection does not exceed Screening Levels = Detection exceeds IDEM RISC Residential Default Closure Level = Detection exceeds IDEM RISC Industrial Default Closure Level

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