SAFETY DATA
SAFETY DATA SHEET Aqua Clean
Section 1. Identification GHS product identifier
: Aqua Clean
Product type
: Liquid
Relevant identified uses of the substance or mixture and uses advised against Not applicable. Supplier's details
: Pur-O-Zone Company P.O. Box 727 Lawrence, KS 66044 Phone: 785-843-0771
Emergency telephone number (with hours of operation)
: 800-843-6174 (24 Hours)
Section 2. Hazards identification OSHA/HCS status
Classification of the substance or mixture
: While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this MSDS contains valuable information critical to the safe handling and proper use of the product. This MSDS should be retained and available for employees and other users of this product. : Not classified.
GHS label elements Signal word
: No signal word.
Hazard statements
: No known significant effects or critical hazards.
Precautionary statements General Prevention
: Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. : Not applicable
Response
: Not applicable
Storage Disposal Hazards not otherwise classified
: Not applicable : Not applicable : None known.
Section 3. Composition/information on ingredients Substance/mixture
: Mixture
Other means of identification
: Not available
CAS number/other identifiers CAS number
: Not applicable
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Date of issue/Date of revision
: 3/2/2015.
Date of previous issue
: No previous validation.
Version
: 0.01
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Section 3. Composition/information on ingredients There are no ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8.
Section 4. First aid measures Description of necessary first aid measures Eye contact
Inhalation Skin contact Ingestion
: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur. : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. : Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur.
Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact
: No known significant effects or critical hazards.
Inhalation
: No known significant effects or critical hazards.
Skin contact
: No known significant effects or critical hazards.
Ingestion
: No known significant effects or critical hazards.
Over-exposure signs/symptoms Eye contact Inhalation Skin contact
: No specific data. : No specific data. : No specific data.
Ingestion
: No specific data.
Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Specific treatments
: Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. : No specific treatment.
Protection of first-aiders
: No action shall be taken involving any personal risk or without suitable training.
See toxicological information (Section 11)
Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical
Date of issue/Date of revision
: Use an extinguishing agent suitable for the surrounding fire. : None known.
: In a fire or if heated, a pressure increase will occur and the container may burst.
: 3/2/2015.
Date of previous issue
: No previous validation.
Version
: 0.01
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Section 5. Fire-fighting measures Hazardous thermal decomposition products
Special protective actions for fire-fighters Special protective equipment for fire-fighters
: Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency personnel
: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel". Environmental precautions
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
Section 7. Handling and storage Precautions for safe handling Protective measures
: Put on appropriate personal protective equipment (see Section 8).
Advice on general occupational hygiene
: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, including any incompatibilities
Date of issue/Date of revision
: Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. : 3/2/2015.
Date of previous issue
: No previous validation.
Version
: 0.01
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Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits None. Appropriate engineering controls
: Good general ventilation should be sufficient to control worker exposure to airborne contaminants.
Environmental exposure controls
: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures Hygiene measures
Eye/face protection
: Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with sideshields.
Skin protection Hand protection
Body protection
Other skin protection
Respiratory protection
: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Section 9. Physical and chemical properties Appearance Physical state
: Liquid
Color
: Green
Odor Odor threshold pH
: Fresh : Not available
Melting point
: 6.5 to 7.5 : 0°C (32°F)
Boiling point
: 100°C (212°F)
Flash point
: Closed cup: >93.334°C (>200°F)
Evaporation rate
: Not available
Flammability (solid, gas)
: Not available
Date of issue/Date of revision
: 3/2/2015.
Date of previous issue
: No previous validation.
Version
: 0.01
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Section 9. Physical and chemical properties Lower and upper explosive (flammable) limits
: Not available
Vapor pressure
: <4 kPa (<30 mm Hg) [room temperature]
Vapor density Specific gravity
: <1 [Air = 1] : 1 g/cm続
Solubility
: Not available
Partition coefficient: noctanol/water
: Not available
Auto-ignition temperature
: Not available
Viscosity
: Not available
VOC content
: 0%
VOCs are calculated following the requirements under 40 CFR, Part 59, Subpart C for Consumer Products and Subpart D for Architectural Coatings.
Section 10. Stability and reactivity Reactivity
: No specific test data related to reactivity available for this product or its ingredients.
Chemical stability
: The product is stable.
Possibility of hazardous reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid
: No specific data.
Incompatible materials
: No specific data.
Hazardous decomposition products
: Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Section 11. Toxicological information Information on toxicological effects Acute toxicity Not available. Irritation/Corrosion Not available. Sensitization Not available. Mutagenicity Not available. Carcinogenicity Not available. Reproductive toxicity Not available. Teratogenicity Date of issue/Date of revision
: 3/2/2015.
Date of previous issue
: No previous validation.
Version
: 0.01
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Section 11. Toxicological information Not available. Specific target organ toxicity (single exposure) Not available. Specific target organ toxicity (repeated exposure) Not available. Aspiration hazard Not available. Information on the likely routes of exposure
: Not available
Potential acute health effects Eye contact : No known significant effects or critical hazards. Inhalation
: No known significant effects or critical hazards.
Skin contact
: No known significant effects or critical hazards.
Ingestion
: No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics Eye contact : No specific data. Inhalation
: No specific data.
Skin contact
: No specific data.
Ingestion
: No specific data.
Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate : Not available effects Potential delayed effects Long term exposure Potential immediate effects Potential delayed effects
: Not available : Not available : Not available
Potential chronic health effects Not available. General
: No known significant effects or critical hazards.
Carcinogenicity
: No known significant effects or critical hazards.
Mutagenicity
: No known significant effects or critical hazards.
Teratogenicity
: No known significant effects or critical hazards.
Developmental effects
: No known significant effects or critical hazards.
Fertility effects
: No known significant effects or critical hazards.
Numerical measures of toxicity Acute toxicity estimates Not available.
Date of issue/Date of revision
: 3/2/2015.
Date of previous issue
: No previous validation.
Version
: 0.01
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Section 11. Toxicological information Section 12. Ecological information Toxicity Not available. Persistence and degradability Not available. Bioaccumulative potential Not available. Mobility in soil Soil/water partition coefficient (KOC)
: Not available
Other adverse effects
: No known significant effects or critical hazards.
Section 13. Disposal considerations Disposal methods
: The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Section 14. Transport information DOT Classification
IMDG
IATA
UN number
Not regulated
Not regulated
Not regulated
UN proper shipping name
-
-
-
Transport hazard class(es)
-
-
-
Packing group
-
-
-
Environmental hazards
No.
No.
No.
Additional information
-
-
-
Date of issue/Date of revision
: 3/2/2015.
Date of previous issue
: No previous validation.
Version
: 0.01
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Section 14. Transport information Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
: Not available.
Section 15. Regulatory information U.S. Federal regulations
: United States inventory (TSCA 8b): All components are listed or exempted.
Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) SARA 311/312 Classification
: Not listed
: Not applicable
Composition/information on ingredients No products were found. State regulations International regulations Canada inventory
: All components are listed or exempted.
Section 16. Other information Hazardous Material Information System (U.S.A.) Health
1
Flammability
0
Physical hazards
0
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. National Fire Protection Association (U.S.A.) Flammability
0 Health
0
0
Instability/Reactivity Special
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.
Date of issue/Date of revision
: 3/2/2015.
Date of previous issue
: No previous validation.
Version
: 0.01
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Section 16. Other information Copyright Š2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. History Date of printing
: 3/2/2015.
Date of issue/Date of revision Date of previous issue
: 3/2/2015. : No previous validation.
Key to abbreviations
: ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations References : Not available Indicates information that has changed from previously issued version. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Date of issue/Date of revision
: 3/2/2015.
Date of previous issue
: No previous validation.
Version
: 0.01
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Safety Data Sheet Issue Date: 01-Oct-2002
Revision Date: 13-May-2015
Version 1
1. IDENTIFICATION Product Identifier Product Name
Applause
Other means of identification SDS #
POZ-002
Recommended use of the chemical and restrictions on use Recommended Use Hand soap. Details of the supplier of the safety data sheet Manufacturer Address Pur-O-Zone, Inc. 345 N. Iowa Street Lawrence, KS 66044 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr)
1-785-843-0771 1-800-535-5053
2. HAZARDS IDENTIFICATION Appearance Light pink liquid
Physical State Liquid
Odor Almond
Classification Carcinogenicity
Category 2
Signal Word Warning Hazard Statements Suspected of causing cancer
Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Precautionary Statements - Response If exposed or concerned: Get medical advice/attention Precautionary Statements - Storage Store locked up
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Revision Date: 13-May-2015
POZ-002 - Applause Hand Soap
_____________________________________________________________________________________________ Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Ethyl Alcohol Magnesium Nitrate Diethanolamine
CAS No 64-17-5 10377-60-3 111-42-2
Weight-% <5 <5 <1
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**
4. FIRST-AID MEASURES First Aid Measures General Advice
If exposed or concerned: Get medical advice/attention.
Eye Contact
Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician.
Skin Contact
Wash off immediately with plenty of water for at least 15 minutes.
Inhalation
Remove to fresh air.
Ingestion
Drink gelatin solution, egg whites or two to three large glasses of water. Call a physician.
Most important symptoms and effects Symptoms
Suspected of causing cancer.
Indication of any immediate medical attention and special treatment needed Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES _____________________________________________________________________________________________ Page 2 / 8
Revision Date: 13-May-2015
POZ-002 - Applause Hand Soap
_____________________________________________________________________________________________ Personal precautions, protective equipment and emergency procedures Personal Precautions
Use personal protective equipment as required.
Methods and material for containment and cleaning up Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up
Collect and reuse if possible, absorb with inert material (sand, sawdust, etc.), or flush to sewer with large quantity of water if permitted by all local, state and federal regulations.
7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required.
Conditions for safe storage, including any incompatibilities Storage Conditions
Store locked up.
Incompatible Materials
None known based on information supplied.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name Ethyl Alcohol 64-17-5
ACGIH TLV STEL: 1000 ppm
Diethanolamine 111-42-2
TWA: 1 mg/m3 inhalable fraction and vapor S*
OSHA PEL TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 (vacated) TWA: 3 ppm (vacated) TWA: 15 mg/m3
NIOSH IDLH IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3 TWA: 3 ppm TWA: 15 mg/m3
Appropriate engineering controls Engineering Controls
Showers. Eyewash stations. Ventilation systems.
Individual protection measures, such as personal protective equipment Eye/Face Protection
Avoid contact with eyes.
Skin and Body Protection
Wear suitable protective clothing.
Respiratory Protection
Ensure adequate ventilation, especially in confined areas.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Appearance Color
Liquid Light pink liquid Light pink
Odor Odor Threshold
Almond Not determined
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Revision Date: 13-May-2015
POZ-002 - Applause Hand Soap
_____________________________________________________________________________________________ Property pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties
Values Not determined Not available 100 °C / 212 °F None Not established Liquid-Not applicable Not available Not available Not established Not established 1.0015 Completely soluble Not determined Not determined Not determined Not determined Not determined Not determined Not determined Not determined
Remarks • Method
(Water = 1)
10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization
Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to Avoid Keep out of reach of children. Incompatible Materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied.
11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact
Avoid contact with eyes.
Skin Contact
Avoid contact with skin.
Inhalation
Do not inhale.
Ingestion
Do not ingest.
_____________________________________________________________________________________________ Page 4 / 8
Revision Date: 13-May-2015
POZ-002 - Applause Hand Soap
_____________________________________________________________________________________________ Component Information Chemical Name Ethyl Alcohol 64-17-5 Sodium Chloride 7647-14-5 Magnesium Nitrate 10377-60-3 Sodium Sulfate 7757-82-6 Diethanolamine 111-42-2
Oral LD50 = 7060 mg/kg ( Rat )
Dermal LD50 -
Inhalation LC50 = 124.7 mg/L ( Rat ) 4 h
= 3 g/kg ( Rat )
> 10 g/kg ( Rabbit )
> 42 g/m3 ( Rat ) 1 h
= 5440 mg/kg ( Rat )
-
-
> 10000 mg/kg ( Rat )
-
-
= 620 ÂľL/kg ( Rat ) = 0.62 mL/kg ( Rat )
= 7640 ÂľL/kg ( Rabbit )
-
Information on physical, chemical and toxicological effects Symptoms
Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity
Suspected of causing cancer. Nitrate or nitrite ingested under conditions that result in endogenous nitrosation are considered IARC group 2A carcinogens. Ethanol has been shown to be carcinogenic in long-term studies only when consumed as an alcoholic beverage.
Chemical Name Ethyl Alcohol 64-17-5 Magnesium Nitrate 10377-60-3 Diethanolamine 111-42-2 Legend
ACGIH A3
IARC Group 1
A3
NTP Known
OSHA X
Group 2A
X
Group 2B
X
ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 2A - Probably Carcinogenic to Humans Group 2B - Possibly Carcinogenic to Humans NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present
Numerical measures of toxicity Not determined
12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information Chemical Name Ethyl Alcohol 64-17-5
Algae/aquatic plants
Fish
Toxicity to Crustacea microorganisms 12.0 - 16.0: 96 h EC50 = 34634 mg/L 30 min 9268 - 14221: 48 h Daphnia Oncorhynchus mykiss mL/L EC50 = 35470 mg/L 5 min magna mg/L LC50 2: 48 h LC50 static 13400 - 15100: Daphnia magna mg/L EC50 96 h Pimephales promelas Static 10800: 24 h Daphnia mg/L LC50 flow-through 100: magna mg/L EC50 96 h Pimephales promelas mg/L LC50 static
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Revision Date: 13-May-2015
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_____________________________________________________________________________________________ Sodium Chloride 7647-14-5
Sodium Sulfate 7757-82-6
Diethanolamine 111-42-2
5560 - 6080: 96 h Lepomis macrochirus mg/L LC50 flow-through 12946: 96 h Lepomis macrochirus mg/L LC50 static 6020 - 7070: 96 h Pimephales promelas mg/L LC50 static 7050: 96 h Pimephales promelas mg/L LC50 semi-static 6420 6700: 96 h Pimephales promelas mg/L LC50 static 4747 - 7824: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 13500 - 14500: 96 h Pimephales promelas mg/L LC50 13500: 96 h Lepomis macrochirus mg/L LC50 6800: 96 h Pimephales promelas mg/L LC50 static 3040 - 4380: 96 h Lepomis macrochirus mg/L LC50 static 7.8: 72 h Desmodesmus 4460 - 4980: 96 h subspicatus mg/L EC50 2.1 - Pimephales promelas mg/L 2.3: 96 h Pseudokirchneriella LC50 flow-through 1200 subcapitata mg/L EC50 1580: 96 h Pimephales promelas mg/L LC50 static 600 - 1000: 96 h Lepomis macrochirus mg/L LC50 static
1000: 48 h Daphnia magna mg/L EC50 340.7 - 469.2: 48 h Daphnia magna mg/L EC50 Static
2564: 48 h Daphnia magna mg/L EC50 630: 96 h Daphnia magna mg/L EC50
EC50 = 73 mg/L 5 min EC50 > 16 mg/L 16 h
55: 48 h Daphnia magna mg/L EC50
Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Chemical Name Ethyl Alcohol 64-17-5 Diethanolamine 111-42-2
Partition Coefficient -0.32 -2.18
Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
California Hazardous Waste Status
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Revision Date: 13-May-2015
POZ-002 - Applause Hand Soap
_____________________________________________________________________________________________ Chemical Name Ethyl Alcohol 64-17-5 Magnesium Nitrate 10377-60-3
California Hazardous Waste Status Toxic Ignitable Ignitable Reactive
14. TRANSPORT INFORMATION Note
Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.
DOT
Not regulated
IATA
Not regulated
IMDG
Not regulated
15. REGULATORY INFORMATION International Inventories
Chemical Name Ethyl Alcohol Magnesium Nitrate
TSCA Present Present
DSL X X
Diethanolamine
Present
X
NDSL
EINECS Present Present
ELINCS
Present
ENCS Present Present
IECSC X X
KECL Present Present
PICCS X X
AICS X X
Present
X
Present
X
X
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations CERCLA Chemical Name Diethanolamine 111-42-2
Hazardous Substances RQs 100 lb
CERCLA/SARA RQ
Reportable Quantity (RQ) RQ 100 lb final RQ RQ 45.4 kg final RQ
SARA 313 Chemical Name
CAS No
Weight-%
Magnesium Nitrate - 10377-60-3 Diethanolamine - 111-42-2
10377-60-3 111-42-2
<5 <1
SARA 313 - Threshold Values % 1.0 1.0
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Revision Date: 13-May-2015
POZ-002 - Applause Hand Soap
_____________________________________________________________________________________________ CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals. Chemical Name Ethyl Alcohol - 64-17-5
California Proposition 65 Carcinogen Developmental Carcinogen
Diethanolamine - 111-42-2
U.S. State Right-to-Know Regulations Chemical Name Ethyl Alcohol 64-17-5 Magnesium Nitrate 10377-60-3 Sodium Sulfate 7757-82-6 Diethanolamine 111-42-2
New Jersey X
Massachusetts X
Pennsylvania X
X
X
X
X
X
X
X
X
16. OTHER INFORMATION NFPA HMIS Issue Date: Revision Date: Revision Note:
Health Hazards Not determined Health Hazards 1
Flammability Not determined Flammability 0
Instability Not determined Physical Hazards 0
Special Hazards Not determined Personal Protection Not determined
01-Oct-2002 13-May-2015 New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet
_____________________________________________________________________________________________ Page 8 / 8
Safety Data Sheet Issue Date: 01-Oct-2002
Revision Date: 13-May-2015
Version 1
1. IDENTIFICATION Product Identifier Product Name
Crystal
Other means of identification SDS #
POZ-005
Recommended use of the chemical and restrictions on use Recommended Use Ammoniated glass cleaner. Details of the supplier of the safety data sheet Manufacturer Address Pur-O-Zone, Inc. 345 N. Iowa Street Lawrence, KS 66044 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr)
1-785-843-0771 1-800-535-5053
2. HAZARDS IDENTIFICATION Appearance Blue liquid
Physical State Liquid
Odor Alcohol
Classification Serious eye damage/eye irritation Specific target organ toxicity (single exposure)
Category 2 Category 1
Hazards Not Otherwise Classified (HNOC) May be harmful if swallowed Causes mild skin irritation Signal Word Danger Hazard Statements Causes serious eye irritation Causes damage to organs
_____________________________________________________________________________________________ Page 1 / 9
Revision Date: 13-May-2015
POZ-005 - Crystal Glass
_____________________________________________________________________________________________ Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear eye/face protection Do not breathe dust/fume/gas/mist/vapors/spray Do not eat, drink or smoke when using this product
Precautionary Statements - Response IF exposed: Call a POISON CENTER or doctor/physician IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Isopropanol Methanol Ethylene Glycol Monobutyl Ether
CAS No 67-63-0 67-56-1 111-76-2
Weight-% 1-10 <5 <5
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**
4. FIRST-AID MEASURES First Aid Measures General Advice
IF exposed: Call a POISON CENTER or doctor/physician.
Eye Contact
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Skin Contact
Wash off immediately with plenty of water for at least 15 minutes.
Inhalation
Remove to fresh air.
Ingestion
Drink two to three large glasses of water. Call a physician.
Most important symptoms and effects Symptoms
May be harmful if swallowed. Causes mild skin irritation. Causes serious eye irritation. Causes damage to organs.
Indication of any immediate medical attention and special treatment needed Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES _____________________________________________________________________________________________ Page 2 / 9
Revision Date: 13-May-2015
POZ-005 - Crystal Glass
_____________________________________________________________________________________________ Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions
Use personal protective equipment as required.
Methods and material for containment and cleaning up Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up
Collect and reuse if possible, absorb with inert material (sand, sawdust, etc.), or flush to sewer with large quantity of water if permitted by all local, state and federal regulations.
7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice. Wash face, hands, and any exposed skin thoroughly after handling. Wear eye/face protection. Do not breathe dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product.
Conditions for safe storage, including any incompatibilities Storage Conditions
Store locked up.
Incompatible Materials
None known based on information supplied.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name Isopropanol 67-63-0
ACGIH TLV STEL: 400 ppm TWA: 200 ppm
Methanol 67-56-1
STEL: 250 ppm TWA: 200 ppm S*
OSHA PEL TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m3 TWA: 200 ppm TWA: 260 mg/m3 (vacated) TWA: 200 ppm (vacated) TWA: 260 mg/m3 (vacated) STEL: 250 ppm (vacated) STEL: 325 mg/m3 (vacated) S*
NIOSH IDLH IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 IDLH: 6000 ppm TWA: 200 ppm TWA: 260 mg/m3 STEL: 250 ppm STEL: 325 mg/m3
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Revision Date: 13-May-2015
POZ-005 - Crystal Glass
_____________________________________________________________________________________________ Ethylene Glycol Monobutyl Ether 111-76-2
TWA: 20 ppm
TWA: 50 ppm TWA: 240 mg/m3 (vacated) TWA: 25 ppm (vacated) TWA: 120 mg/m3 (vacated) S* S*
IDLH: 700 ppm TWA: 5 ppm TWA: 24 mg/m3
Appropriate engineering controls Engineering Controls
Showers. Eyewash stations. Ventilation systems.
Individual protection measures, such as personal protective equipment Eye/Face Protection
Safety glasses or goggles recommended.
Skin and Body Protection
Rubber apron and gloves.
Respiratory Protection
Ensure adequate ventilation, especially in confined areas.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Appearance Color
Liquid Blue liquid Blue
Property pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties
Values Not determined Not available 97.8 °C / 208 °F None >1 Liquid-Not applicable Not available Not available <30 <1 1.00 Completely soluble Not determined Not determined Not determined Not determined Not determined Not determined Not determined Not determined
Odor Odor Threshold
Alcohol Not determined
Remarks • Method
(Water = 1)
10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions.
_____________________________________________________________________________________________ Page 4 / 9
Revision Date: 13-May-2015
POZ-005 - Crystal Glass
_____________________________________________________________________________________________ Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization
Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to Avoid Keep out of reach of children. Incompatible Materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied.
11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact
Causes serious eye irritation.
Skin Contact
Causes mild skin irritation.
Inhalation
Do not inhale.
Ingestion
May be harmful if swallowed.
Component Information Chemical Name Isopropanol 67-63-0 Methanol 67-56-1 Ethylene Glycol Monobutyl Ether 111-76-2 Sodium Sulfate 7757-82-6
Oral LD50 = 1870 mg/kg ( Rat )
Dermal LD50 = 4059 mg/kg ( Rabbit )
Inhalation LC50 = 72600 mg/m3 ( Rat ) 4 h
= 6200 mg/kg ( Rat )
= 15800 mg/kg ( Rabbit )
= 470 mg/kg ( Rat )
= 99 mg/kg ( Rabbit )
= 22500 ppm ( Rat ) 8 h = 64000 ppm ( Rat ) 4 h = 450 ppm ( Rat ) 4 h
> 10000 mg/kg ( Rat )
-
-
Information on physical, chemical and toxicological effects Symptoms
Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity
Chemical Name Isopropanol 67-63-0 Ethylene Glycol Monobutyl Ether 111-76-2 Legend
Isopropyl Alcohol (IPA) is an IARC Monograph Group 3 chemical. IPA is a Group 1 when manufactured by the strong-acid process. Group 3 IARC components are "not classifiable as human carcinogens". ACGIH
IARC Group 3
A3
Group 3
NTP
OSHA X
ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 3 IARC components are "not classifiable as human carcinogens"
_____________________________________________________________________________________________ Page 5 / 9
Revision Date: 13-May-2015
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_____________________________________________________________________________________________ OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present
STOT - single exposure
Causes damage to organs.
Numerical measures of toxicity Not determined
12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information Chemical Name
Algae/aquatic plants
Fish
Isopropanol 67-63-0
1000: 96 h Desmodesmus subspicatus mg/L EC50 1000: 72 h Desmodesmus subspicatus mg/L EC50
9640: 96 h Pimephales promelas mg/L LC50 flowthrough 1400000: 96 h Lepomis macrochirus Âľg/L LC50 11130: 96 h Pimephales promelas mg/L LC50 static 28200: 96 h Pimephales promelas mg/L LC50 flowthrough 18 - 20: 96 h Oncorhynchus mykiss mL/L LC50 static 19500 - 20700: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 13500 - 17600: 96 h Lepomis macrochirus mg/L LC50 flow-through 100: 96 h Pimephales promelas mg/L LC50 static 1490: 96 h Lepomis macrochirus mg/L LC50 static 2950: 96 h Lepomis macrochirus mg/L LC50 13500 - 14500: 96 h Pimephales promelas mg/L LC50 13500: 96 h Lepomis macrochirus mg/L LC50 6800: 96 h Pimephales promelas mg/L LC50 static 3040 - 4380: 96 h Lepomis macrochirus mg/L LC50 static
Methanol 67-56-1
Ethylene Glycol Monobutyl Ether 111-76-2 Sodium Sulfate 7757-82-6
Toxicity to microorganisms
Crustacea 13299: 48 h Daphnia magna mg/L EC50
1000: 48 h Daphnia magna mg/L EC50 1698 - 1940: 24 h Daphnia magna mg/L EC50 2564: 48 h Daphnia magna mg/L EC50 630: 96 h Daphnia magna mg/L EC50
Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Chemical Name Isopropanol 67-63-0 Methanol 67-56-1
Partition Coefficient 0.05 -0.77
_____________________________________________________________________________________________ Page 6 / 9
Revision Date: 13-May-2015
POZ-005 - Crystal Glass
_____________________________________________________________________________________________ Ethylene Glycol Monobutyl Ether 111-76-2
0.81
Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
US EPA Waste Number Chemical Name Methanol 67-56-1
RCRA
RCRA - Basis for Listing Included in waste stream: F039
RCRA - D Series Wastes
RCRA - U Series Wastes U154
California Hazardous Waste Status Chemical Name Isopropanol 67-63-0 Methanol 67-56-1
California Hazardous Waste Status Toxic Ignitable Toxic Ignitable
14. TRANSPORT INFORMATION Note
Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.
DOT
Not regulated
IATA
Not regulated
IMDG
Not regulated
15. REGULATORY INFORMATION International Inventories
Chemical Name Isopropanol Methanol
TSCA Present Present
DSL X X
Ethylene Glycol Monobutyl Ether
Present
X
NDSL
EINECS Present Present
ELINCS
Present
ENCS Present Present
IECSC X X
KECL Present Present
PICCS X X
AICS X X
Present
X
Present
X
X
Legend:
_____________________________________________________________________________________________ Page 7 / 9
Revision Date: 13-May-2015
POZ-005 - Crystal Glass
_____________________________________________________________________________________________ TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations CERCLA Chemical Name Methanol 67-56-1
Hazardous Substances RQs 5000 lb
CERCLA/SARA RQ
Reportable Quantity (RQ) RQ 5000 lb final RQ RQ 2270 kg final RQ
SARA 313 Chemical Name
CAS No
Weight-%
Isopropanol - 67-63-0 Methanol - 67-56-1 Ethylene Glycol Monobutyl Ether - 111-76-2
67-63-0 67-56-1 111-76-2
1-10 <5 <5
SARA 313 - Threshold Values % 1.0 1.0 1.0
CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals. Chemical Name Methanol - 67-56-1
California Proposition 65 Developmental
U.S. State Right-to-Know Regulations Chemical Name Isopropanol 67-63-0 Methanol 67-56-1 Ethylene Glycol Monobutyl Ether 111-76-2 Sodium Sulfate 7757-82-6
New Jersey X
Massachusetts X
Pennsylvania X
X
X
X
X
X
X
X
X
_____________________________________________________________________________________________ Page 8 / 9
Revision Date: 13-May-2015
POZ-005 - Crystal Glass
_____________________________________________________________________________________________
16. OTHER INFORMATION
NFPA HMIS Issue Date: Revision Date: Revision Note:
Health Hazards Not determined Health Hazards 1
Flammability Not determined Flammability 0
Instability Not determined Physical Hazards 0
Special Hazards Not determined Personal Protection Not determined
01-Oct-2002 13-May-2015 New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet
_____________________________________________________________________________________________ Page 9 / 9
Safety Data Sheet Issue Date: 01-Oct-2002
Revision Date: 13-May-2015
Version 1
1. IDENTIFICATION Product Identifier Product Name
Destroyer II
Other means of identification SDS #
POZ-007
Recommended use of the chemical and restrictions on use Recommended Use Non-butyl Cleaner/Degreaser. Details of the supplier of the safety data sheet Manufacturer Address Pur-O-Zone, Inc. 345 N. Iowa Street Lawrence, KS 66044 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr)
1-785-843-0771 1-800-535-5053
2. HAZARDS IDENTIFICATION Appearance Bright yellow liquid
Physical State Liquid
Odor Typical solvent odor
Classification Skin corrosion/irritation Serious eye damage/eye irritation Skin sensitization
Category 2 Category 2 Category 1
Signal Word Warning Hazard Statements Causes skin irritation Causes serious eye irritation May cause an allergic skin reaction
Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Avoid breathing dust/fume/gas/mist/vapors/spray Contaminated work clothing should not be allowed out of the workplace
_____________________________________________________________________________________________ Page 1 / 8
Revision Date: 13-May-2015
POZ-007 - Destroyer II
_____________________________________________________________________________________________ Precautionary Statements - Response
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water Take off contaminated clothing and wash it before reuse If skin irritation or rash occurs: Get medical advice/attention Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Other Hazards Toxic to aquatic life with long lasting effects Unknown Acute Toxicity 1.28% of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name d-Limonene Sodium metasilicate Isopropanol
CAS No 5989-27-5 6834-92-0 67-63-0
Weight-% <5 <5 <1
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**
4. FIRST-AID MEASURES First Aid Measures Eye Contact
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Skin Contact
Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation or rash occurs: Get medical advice/attention.
Inhalation
Remove to fresh air.
Ingestion
Drink two to three large glasses of water. Do not induce vomiting. Call a physician.
Most important symptoms and effects Symptoms
Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction.
Indication of any immediate medical attention and special treatment needed Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
_____________________________________________________________________________________________ Page 2 / 8
Revision Date: 13-May-2015
POZ-007 - Destroyer II
_____________________________________________________________________________________________ Unsuitable Extinguishing Media Not determined.
Specific Hazards Arising from the Chemical Not determined. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions
Use personal protective equipment as required.
Methods and material for containment and cleaning up Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up
Collect and reuse if possible, absorb with inert material (sand, sawdust, etc.), or flush to sewer with large quantity of water if permitted by all local, state and federal regulations.
7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice. Wash face, hands, and any exposed skin thoroughly after handling. Wear protective gloves/protective clothing and eye/face protection. Avoid breathing dust/fume/gas/mist/vapors/spray. Contaminated work clothing should not be allowed out of the workplace.
Conditions for safe storage, including any incompatibilities Storage Conditions
Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible Materials
Strong acids. Strong oxidizers.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name Sodium metasilicate 6834-92-0 Isopropanol 67-63-0
ACGIH TLV 2 mg/m3
OSHA PEL 2 mg/m3
NIOSH IDLH -
STEL: 400 ppm TWA: 200 ppm
TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m3
IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3
Appropriate engineering controls Engineering Controls
Showers. Eyewash stations. Ventilation systems.
Individual protection measures, such as personal protective equipment Eye/Face Protection
Chemical splash goggles.
_____________________________________________________________________________________________ Page 3 / 8
Revision Date: 13-May-2015
POZ-007 - Destroyer II
_____________________________________________________________________________________________ Skin and Body Protection
Use rubber gloves and apron.
Respiratory Protection
None normally required with adequate room ventilation.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Appearance Color
Liquid Bright yellow liquid Bright yellow
Property pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties
Values Not determined Not available 98.9-104.4 °C / 210-220 °F Non-flammable aqueous solution >1 Liquid-Not applicable Not available Not available <30 <1 1.01 Completely soluble Not determined Not determined Not determined Not determined Not determined Not determined Not determined Not determined
Odor Odor Threshold
Typical solvent odor Not determined
Remarks • Method
(Water = 1)
(Water = 1)
10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization
Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to Avoid Keep out of reach of children. Incompatible Materials Strong acids. Strong oxidizers. Hazardous Decomposition Products None known based on information supplied.
11. TOXICOLOGICAL INFORMATION _____________________________________________________________________________________________ Page 4 / 8
Revision Date: 13-May-2015
POZ-007 - Destroyer II
_____________________________________________________________________________________________ Information on likely routes of exposure Product Information Eye Contact
Causes serious eye irritation.
Skin Contact
Causes skin irritation.
Inhalation
Do not inhale.
Ingestion
Do not ingest.
Component Information Chemical Name Nonylphenol Ethoxylate 127087-87-0 d-Limonene 5989-27-5 1,2 Propanediol 57-55-6 Sodium xylenesulfonate 1300-72-7 Sodium metasilicate 6834-92-0 Sodium Tripolyphosphate Anhydrous 7758-29-4 Isopropanol 67-63-0 Sodium Sulfate 7757-82-6
Oral LD50 = 1310 mg/kg ( Rat )
Dermal LD50 -
Inhalation LC50 -
= 4400 mg/kg ( Rat )
> 5 g/kg ( Rabbit )
-
= 20000 mg/kg ( Rat )
= 20800 mg/kg ( Rabbit )
-
= 1000 mg/kg ( Rat )
-
-
= 600 mg/kg ( Rat )
-
-
= 3100 mg/kg ( Rat )
> 7940 mg/kg ( Rabbit )
-
= 1870 mg/kg ( Rat )
= 4059 mg/kg ( Rabbit )
= 72600 mg/m3 ( Rat ) 4 h
> 10000 mg/kg ( Rat )
-
-
Information on physical, chemical and toxicological effects Symptoms
Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization
May cause an allergic skin reaction.
Carcinogenicity
Isopropyl Alcohol (IPA) is an IARC Monograph Group 3 chemical. IPA is a Group 1 when manufactured by the strong-acid process.
Chemical Name d-Limonene 5989-27-5 Isopropanol 67-63-0 Legend
ACGIH
IARC Group 2A
NTP
Group 3
OSHA X X
IARC (International Agency for Research on Cancer) Group 3 IARC components are "not classifiable as human carcinogens" OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present
Numerical measures of toxicity Not determined Unknown Acute Toxicity
1.28% of the mixture consists of ingredient(s) of unknown toxicity.
_____________________________________________________________________________________________ Page 5 / 8
Revision Date: 13-May-2015
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_____________________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Ecotoxicity Toxic to aquatic life with long lasting effects. Component Information Chemical Name
Algae/aquatic plants
d-Limonene 5989-27-5
1,2 Propanediol 57-55-6
19000: 96 h Pseudokirchneriella subcapitata mg/L EC50
Sodium metasilicate 6834-92-0 Sodium Tripolyphosphate Anhydrous 7758-29-4 Isopropanol 67-63-0
1000: 96 h Desmodesmus subspicatus mg/L EC50 1000: 72 h Desmodesmus subspicatus mg/L EC50
Sodium Sulfate 7757-82-6
Fish 0.619 - 0.796: 96 h Pimephales promelas mg/L LC50 flow-through 35: 96 h Oncorhynchus mykiss mg/L LC50 51400: 96 h Pimephales promelas mg/L LC50 static 710: 96 h Pimephales promelas mg/L LC50 51600: 96 h Oncorhynchus mykiss mg/L LC50 static 41 - 47: 96 h Oncorhynchus mykiss mL/L LC50 static 210: 96 h Brachydanio rerio mg/L LC50 semi-static 210: 96 h Brachydanio rerio mg/L LC50 1650: 48 h Leuciscus idus mg/L LC50
Toxicity to microorganisms
9640: 96 h Pimephales promelas mg/L LC50 flowthrough 1400000: 96 h Lepomis macrochirus Âľg/L LC50 11130: 96 h Pimephales promelas mg/L LC50 static 13500 - 14500: 96 h Pimephales promelas mg/L LC50 13500: 96 h Lepomis macrochirus mg/L LC50 6800: 96 h Pimephales promelas mg/L LC50 static 3040 - 4380: 96 h Lepomis macrochirus mg/L LC50 static
Crustacea
1000: 48 h Daphnia magna mg/L EC50 Static 10000: 24 h Daphnia magna mg/L EC50
216: 96 h Daphnia magna mg/L EC50
13299: 48 h Daphnia magna mg/L EC50
2564: 48 h Daphnia magna mg/L EC50 630: 96 h Daphnia magna mg/L EC50
Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Chemical Name Isopropanol 67-63-0
Partition Coefficient 0.05
Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS _____________________________________________________________________________________________ Page 6 / 8
Revision Date: 13-May-2015
POZ-007 - Destroyer II
_____________________________________________________________________________________________ Waste Treatment Methods Disposal of Wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
California Hazardous Waste Status Chemical Name d-Limonene 5989-27-5 Isopropanol 67-63-0
California Hazardous Waste Status Toxic Toxic Ignitable
14. TRANSPORT INFORMATION Note
Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.
DOT
Not regulated
IATA
Not regulated
IMDG Marine Pollutant
This material may meet the definition of a marine pollutant
15. REGULATORY INFORMATION International Inventories
Chemical Name d-Limonene
TSCA Present
DSL X
Sodium metasilicate
Present
X
Isopropanol
Present
X
NDSL
EINECS Present
ELINCS
ENCS Present
IECSC X
KECL Present
PICCS X
AICS X
Present
Present
X
Present
X
X
Present
Present
X
Present
X
X
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations
_____________________________________________________________________________________________ Page 7 / 8
Revision Date: 13-May-2015
POZ-007 - Destroyer II
_____________________________________________________________________________________________ CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 313 Chemical Name
CAS No
Weight-%
Isopropanol - 67-63-0
67-63-0
<1
SARA 313 - Threshold Values % 1.0
CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name 1,2 Propanediol 57-55-6 Sodium Tripolyphosphate Anhydrous 7758-29-4 Isopropanol 67-63-0 Sodium Sulfate 7757-82-6
New Jersey X
Massachusetts
Pennsylvania X
X
X
X
X
X
X
X
16. OTHER INFORMATION NFPA HMIS Issue Date: Revision Date: Revision Note:
Health Hazards Not determined Health Hazards 1
Flammability Not determined Flammability 0
Instability Not determined Physical Hazards 0
Special Hazards Not determined Personal Protection Not determined
01-Oct-2002 13-May-2015 New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet
_____________________________________________________________________________________________ Page 8 / 8
Safety Data Sheet Issue Date: 15-Oct-2008
Revision Date: 13-May-2015
Version 1
1. IDENTIFICATION Product Identifier Product Name
Isopropyl Alcohol
Other means of identification SDS #
POZ-024
UN/ID No
UN1219
Recommended use of the chemical and restrictions on use Recommended Use For industrial use. Details of the supplier of the safety data sheet Manufacturer Address Pur-O-Zone, Inc. 345 N. Iowa Street Lawrence, KS 66044 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr)
1-785-843-0771 1-800-535-5053
2. HAZARDS IDENTIFICATION Appearance Colorless liquid
Physical State Liquid
Odor Alcohol
Classification Acute toxicity - Oral Serious eye damage/eye irritation Specific target organ toxicity (single exposure) Flammable Liquids
Category 4 Category 2 Category 3 Category 2
Hazards Not Otherwise Classified (HNOC) May be harmful in contact with skin May be harmful if inhaled Signal Word Danger Hazard Statements Harmful if swallowed Causes serious eye irritation May cause drowsiness or dizziness Highly flammable liquid and vapor
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_____________________________________________________________________________________________ Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. â&#x20AC;&#x201D; No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof equipment Use only non-sparking tools Take precautionary measures against static discharge Wear protective gloves/protective clothing/eye protection/face protection Keep cool Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a poison center or doctor/physician if you feel unwell IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth IN CASE OF FIRE: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Storage Store in a well-ventilated place. Keep container tightly closed Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Isopropanol
CAS No 67-63-0
Weight-% 90-100
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**
4. FIRST-AID MEASURES First Aid Measures Eye Contact
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Skin Contact
Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse.
Inhalation
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center or doctor/physician if you feel unwell.
Ingestion
Call a poison center or doctor/physician if you feel unwell. Rinse mouth.
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_____________________________________________________________________________________________ Most important symptoms and effects Symptoms
May be harmful in contact with skin. May be harmful if inhaled. Harmful if swallowed. Causes serious eye irritation. May cause drowsiness or dizziness.
Indication of any immediate medical attention and special treatment needed Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function, but will be less effective. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Container may vent and/or rupture due to fire. When product is stored in closed containers, a flammable atmosphere can develop. Electrically ground and bond all equipment. Flammable mixtures of this product are readily ignited even by static discharge. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Flammable concentrations of vapor can accumulate at temperatures above the flash point. Hazardous Combustion Products Carbon monoxide. Carbon dioxide (CO2). Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep people away. Isolate fire and deny unnecessary entry. Stay upwind. Keep out of low areas where gases (fumes) can accumulate. Burning liquids may be extinguished by dilution with water. Do not use direct water stream. May spread fire. Eliminate ignition sources. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage.
6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions
Isolate area. Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Check area with combustible gas detector before reentering area. Ground and bond all containers and handling equipment. Keep upwind of spill. Keep personnel out of low areas. For large spills, warn public of downwind explosion hazard. Keep unnecessary and unprotected personnel from entering the area. No smoking in area. Ventilate area of leak or spill. Vapor explosion hazard. Keep out of sewers. Keep personnel out of confined or poorly ventilated areas. Only trained and properly protected personnel must be involved in clean-up operations. Confined space entry procedures must be followed before entering the area. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection. Refer to Section 7, Handling, for additional precautionary measures.
Environmental Precautions
Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information.
Methods and material for containment and cleaning up Methods for Containment
Prevent further leakage or spillage if safe to do so.
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_____________________________________________________________________________________________ Methods for Clean-Up
Contain spilled material if possible. Collect in suitable and properly labeled containers. apply vapor suppression foams until spill can be cleaned up. Ground and bond all containers and handling equipment. pump with explosion-proof equipment. If available, use foam to smother or suppress. See section 13, Disposal Considerations, for additional information.
7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice. Wash face, hands, and any exposed skin thoroughly after handling. Do not eat, drink or smoke when handling this product. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Keep away from heat/sparks/open flames/hot surfaces. â&#x20AC;&#x201D; No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion proof equipment. Use only non-sparking tools. Take precautionary measures against static discharges. Wear protective gloves/protective clothing and eye/face protection. Keep cool.
Conditions for safe storage, including any incompatibilities Storage Conditions
Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Incompatible Materials
Aldehydes. Halogenated organics. Halogens. Strong acids. Strong oxidizers.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name Isopropanol 67-63-0
ACGIH TLV STEL: 400 ppm TWA: 200 ppm
OSHA PEL TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m3
NIOSH IDLH IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3
Appropriate engineering controls Engineering Controls
Showers. Eyewash stations. Ventilation systems.
Individual protection measures, such as personal protective equipment Eye/Face Protection
Goggles or face shield.
Skin and Body Protection
Impervious gloves. Clean body covering.
Respiratory Protection
Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use an approved respirator. When respiratory protection is required, use an approved positive-pressure self-contained breathing apparatus or positive-pressure airline with auxiliary self-contained air supply. For emergency conditions, use an approved positive-pressure self-contained breathing apparatus. In confined or poorly ventilated areas, use an approved self-contained breathing apparatus or positive pressure air line with auxiliary self-contained air supply.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES _____________________________________________________________________________________________ Page 4 / 9
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POZ-024 - Alcohol Isopropyl 99
_____________________________________________________________________________________________ Information on basic physical and chemical properties Physical State Appearance Color
Liquid Colorless liquid Colorless
Property pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity
Values No test data available -89 °C / -128 °F 82 °C / 180 °F 12 °C / 54 °F Not determined Liquid-Not applicable 12.0% 2.0% 33 mmHg 2.1 0.787 100% @ 20°C Not determined Not determined 399 °C / 750 °F No test data available Not determined 2.4 cps
Explosive Properties Oxidizing Properties
Not determined Not determined
Odor Odor Threshold
Alcohol Not determined
Remarks • Method Literature value Literature value Tag Closed Cup
@ 20°C (68°F) Literature value (Air=1) Literature value (Water = 1) Literature value Literature value
@ 20 °C
10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization
Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to Avoid Heat, flames and sparks. Incompatible Materials. Incompatible Materials Aldehydes. Halogenated organics. Halogens. Strong acids. Strong oxidizers. Hazardous Decomposition Products Carbon monoxide. Carbon dioxide (CO2).
11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact
Causes serious eye irritation.
Skin Contact
May be harmful in contact with skin.
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POZ-024 - Alcohol Isopropyl 99
_____________________________________________________________________________________________ Inhalation
May be harmful if inhaled.
Ingestion
Harmful if swallowed.
Component Information Chemical Name Isopropanol 67-63-0
Oral LD50 = 1870 mg/kg ( Rat )
Dermal LD50 = 4059 mg/kg ( Rabbit )
Inhalation LC50 = 72600 mg/m3 ( Rat ) 4 h
Information on physical, chemical and toxicological effects Symptoms
Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity
Isopropyl Alcohol (IPA) is an IARC Monograph Group 3 chemical. IPA is a Group 1 when manufactured by the strong-acid process.
Chemical Name Isopropanol 67-63-0 Legend
ACGIH
IARC Group 3
NTP
OSHA X
IARC (International Agency for Research on Cancer) Group 3 IARC components are "not classifiable as human carcinogens" OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present
STOT - single exposure
May cause drowsiness or dizziness.
Numerical measures of toxicity Not determined
12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information Chemical Name
Algae/aquatic plants
Fish
Isopropanol 67-63-0
1000: 96 h Desmodesmus subspicatus mg/L EC50 1000: 72 h Desmodesmus subspicatus mg/L EC50
9640: 96 h Pimephales promelas mg/L LC50 flowthrough 1400000: 96 h Lepomis macrochirus Âľg/L LC50 11130: 96 h Pimephales promelas mg/L LC50 static
Toxicity to microorganisms
Crustacea 13299: 48 h Daphnia magna mg/L EC50
Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Chemical Name
Partition Coefficient
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POZ-024 - Alcohol Isopropyl 99
_____________________________________________________________________________________________ Isopropanol 67-63-0
0.05
Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
California Hazardous Waste Status Chemical Name Isopropanol 67-63-0
California Hazardous Waste Status Toxic Ignitable
14. TRANSPORT INFORMATION Note
Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.
DOT UN/ID No Proper Shipping Name Hazard Class Packing Group
UN1219 Isopropanol 3 II
IATA UN/ID No Proper Shipping Name Hazard Class Packing Group
UN1219 Isopropanol 3 II
IMDG UN/ID No Proper Shipping Name Hazard Class Packing Group
UN1219 Isopropanol 3 II
15. REGULATORY INFORMATION International Inventories
Chemical Name Isopropanol
TSCA Present
DSL X
NDSL
EINECS Present
ELINCS
ENCS Present
IECSC X
KECL Present
PICCS X
AICS X
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_____________________________________________________________________________________________ Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 313 Chemical Name
CAS No
Weight-%
Isopropanol - 67-63-0
67-63-0
90-100
SARA 313 - Threshold Values % 1.0
CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name Isopropanol 67-63-0
New Jersey X
Massachusetts X
Pennsylvania X
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POZ-024 - Alcohol Isopropyl 99
_____________________________________________________________________________________________
16. OTHER INFORMATION
NFPA HMIS Issue Date: Revision Date: Revision Note:
Health Hazards 1 Health Hazards Not determined
Flammability 3 Flammability Not determined
Instability 0 Physical Hazards Not determined
Special Hazards Not determined Personal Protection Not determined
15-Oct-2008 13-May-2015 New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet
_____________________________________________________________________________________________ Page 9 / 9
Safety Data Sheet Issue Date: 01-Oct-2002
Revision Date: 13-May-2015
Version 1
1. IDENTIFICATION Product Identifier Product Name
Jet Blast Off
Other means of identification SDS #
POZ-008
Recommended use of the chemical and restrictions on use Recommended Use Concentrated detergent. Details of the supplier of the safety data sheet Manufacturer Address Pur-O-Zone, Inc. 345 N. Iowa Street Lawrence, KS 66044 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr)
1-785-843-0771 1-800-535-5053
2. HAZARDS IDENTIFICATION Appearance Blue liquid
Physical State Liquid
Odor Fresh
Classification This chemical does not meet the hazardous criteria set forth by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). However, this Safety Data Sheet (SDS) contains valuable information critical to the safe handling and proper use of this product. This SDS should be retained and available for employees and other users of this product.
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Sodium carbonate Sodium pyrophosphate
CAS No 497-19-8 7722-88-5
Weight-% <5 <5
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**
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_____________________________________________________________________________________________
4. FIRST-AID MEASURES
First Aid Measures Eye Contact
Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician.
Skin Contact
Wash off immediately with plenty of water for at least 15 minutes.
Inhalation
Remove to fresh air.
Ingestion
Drink gelatin solution, egg whites or two to three large glasses of water. Call a physician.
Most important symptoms and effects Symptoms
May cause eye irritation. Prolonged or repeated skin contact may cause irritation. May cause severe irritation of gastrointestinal tract, nausea, vomiting, diarrhea. Mists created by spray application may irritate respiratory tract.
Indication of any immediate medical attention and special treatment needed Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions
Use personal protective equipment as required.
Methods and material for containment and cleaning up Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up
Collect and reuse if possible, absorb with inert material (sand, sawdust, etc.), or flush to sewer with large quantity of water if permitted by all local, state and federal regulations.
7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice.
Conditions for safe storage, including any incompatibilities
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_____________________________________________________________________________________________ Storage Conditions
Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible Materials
None known based on information supplied.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name Sodium pyrophosphate 7722-88-5 Sodium metasilicate 6834-92-0
ACGIH TLV -
OSHA PEL (vacated) TWA: 5 mg/m3
NIOSH IDLH TWA: 5 mg/m3
2 mg/m3
2 mg/m3
-
Appropriate engineering controls Engineering Controls
Showers. Eyewash stations. Ventilation systems.
Individual protection measures, such as personal protective equipment Eye/Face Protection
Safety glasses or goggles recommended.
Skin and Body Protection
Use rubber gloves and apron.
Respiratory Protection
Ensure adequate ventilation, especially in confined areas.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Appearance Color
Liquid Blue liquid Blue
Property pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties
Values Not determined Not available 100 °C / 212 °F None >1 Liquid-Not applicable Not available Not available <30 <1 Not determined Completely soluble Not determined Not determined Not determined Not determined Not determined Not determined Not determined Not determined
Odor Odor Threshold
Fresh Not determined
Remarks • Method
(Water = 1)
10. STABILITY AND REACTIVITY _____________________________________________________________________________________________ Page 3 / 7
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POZ-008 - Jet Blast Off
_____________________________________________________________________________________________ Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization
Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to Avoid Keep out of reach of children. Incompatible Materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied.
11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact
Avoid contact with eyes.
Skin Contact
Avoid contact with skin.
Inhalation
Do not inhale.
Ingestion
Do not ingest.
Component Information Chemical Name Nonylphenol Ethoxylate 127087-87-0 Sodium carbonate 497-19-8 Sodium pyrophosphate 7722-88-5 Sodium metasilicate 6834-92-0 Tetrasodium EDTA 64-02-8 Sodium xylenesulfonate 1300-72-7
Oral LD50 = 1310 mg/kg ( Rat )
Dermal LD50 -
Inhalation LC50 -
= 4090 mg/kg ( Rat )
-
= 2300 mg/m3 ( Rat ) 2 h
1000 - 3000 mg/kg ( Rat )
-
-
= 600 mg/kg ( Rat )
-
-
= 1658 mg/kg ( Rat ) = 10 g/kg ( Rat ) = 1000 mg/kg ( Rat )
-
-
-
-
Information on physical, chemical and toxicological effects Symptoms
Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity
Based on the information provided, this product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP.
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_____________________________________________________________________________________________ Numerical measures of toxicity Not determined
12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information Chemical Name
Algae/aquatic plants
Fish
Sodium carbonate 497-19-8
242: 120 h Nitzschia mg/L EC50
300: 96 h Lepomis macrochirus mg/L LC50 static 310 - 1220: 96 h Pimephales promelas mg/L LC50 static 210: 96 h Brachydanio rerio mg/L LC50 semi-static 210: 96 h Brachydanio rerio mg/L LC50 41: 96 h Lepomis macrochirus mg/L LC50 static 59.8: 96 h Pimephales promelas mg/L LC50 static
Sodium metasilicate 6834-92-0 Tetrasodium EDTA 64-02-8
1.01: 72 h Desmodesmus subspicatus mg/L EC50
Toxicity to microorganisms
Crustacea 265: 48 h Daphnia magna mg/L EC50
216: 96 h Daphnia magna mg/L EC50 610: 24 h Daphnia magna mg/L EC50
Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Not determined Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
California Hazardous Waste Status Chemical Name Sodium carbonate 497-19-8
California Hazardous Waste Status Corrosive
14. TRANSPORT INFORMATION _____________________________________________________________________________________________ Page 5 / 7
Revision Date: 13-May-2015
POZ-008 - Jet Blast Off
_____________________________________________________________________________________________ Please see current shipping paper for most up to date shipping information, including Note exemptions and special circumstances.
DOT
Not regulated
IATA
Not regulated
IMDG
Not regulated
15. REGULATORY INFORMATION International Inventories
Chemical Name Sodium carbonate Sodium pyrophosphate
TSCA Present Present
DSL X X
NDSL
EINECS Present Present
ELINCS
ENCS Present
IECSC X X
KECL Present Present
PICCS X X
AICS X X
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name
New Jersey
Massachusetts
Pennsylvania
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_____________________________________________________________________________________________ Sodium pyrophosphate 7722-88-5
X
X
X
16. OTHER INFORMATION NFPA HMIS Issue Date: Revision Date: Revision Note:
Health Hazards Not determined Health Hazards 1
Flammability Not determined Flammability 0
Instability Not determined Physical Hazards 0
Special Hazards Not determined Personal Protection Not determined
01-Oct-2002 13-May-2015 New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet
_____________________________________________________________________________________________ Page 7 / 7
Safety Data Sheet Issue Date: 01-Oct-2002
Revision Date: 13-May-2015
Version 1
1. IDENTIFICATION Product Identifier Product Name
Lem-Ayd
Other means of identification SDS #
POZ-025
Recommended use of the chemical and restrictions on use Recommended Use Water soluble deodorant. Details of the supplier of the safety data sheet Manufacturer Address Pur-O-Zone, Inc. 345 N. Iowa Street Lawrence, KS 66044 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr)
1-785-843-0771 1-800-535-5053
2. HAZARDS IDENTIFICATION Appearance Yellow liquid
Physical State Liquid
Odor Lemon
Classification Skin sensitization
Category 1
Signal Word Warning Hazard Statements May cause an allergic skin reaction
Precautionary Statements - Prevention Avoid breathing dust/fume/gas/mist/vapors/spray Contaminated work clothing should not be allowed out of the workplace Wear protective gloves Precautionary Statements - Response IF ON SKIN: Wash with plenty of soap and water Wash contaminated clothing before reuse If skin irritation or rash occurs: Get medical advice/attention
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_____________________________________________________________________________________________ Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Unknown Acute Toxicity 2.94% of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Isopropanol Citral
CAS No 67-63-0 5392-40-5
Weight-% <1 <1
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**
4. FIRST-AID MEASURES First Aid Measures Eye Contact
Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician.
Skin Contact
Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical advice/attention.
Inhalation
Remove to fresh air.
Ingestion
Clean mouth with water and drink afterwards plenty of water.
Most important symptoms and effects Symptoms
May cause an allergic skin reaction.
Indication of any immediate medical attention and special treatment needed Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES _____________________________________________________________________________________________ Page 2 / 8
Revision Date: 13-May-2015
POZ-025 - Lem-Ayd
_____________________________________________________________________________________________ Personal precautions, protective equipment and emergency procedures Personal Precautions
Use personal protective equipment as required.
Environmental Precautions
See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up
Collect and reuse if possible, absorb with inert material (sand, sawdust, etc.), or flush to sewer with large quantity of water if permitted by all local, state and federal regulations.
7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice. Avoid breathing dust/fume/gas/mist/vapors/spray. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves.
Conditions for safe storage, including any incompatibilities Storage Conditions
Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible Materials
None known based on information supplied.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name Isopropanol 67-63-0
ACGIH TLV STEL: 400 ppm TWA: 200 ppm
Dipropylene Glycol Monomethyl Ether (DPM) 34590-94-8
STEL: 150 ppm TWA: 100 ppm S*
Citral 5392-40-5
TWA: 5 ppm inhalable fraction and vapor S*
OSHA PEL TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m3 TWA: 100 ppm TWA: 600 mg/m3 (vacated) TWA: 100 ppm (vacated) TWA: 600 mg/m3 (vacated) STEL: 150 ppm (vacated) STEL: 900 mg/m3 (vacated) S* S* -
NIOSH IDLH IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 IDLH: 600 ppm TWA: 100 ppm TWA: 600 mg/m3 STEL: 150 ppm STEL: 900 mg/m3
-
Appropriate engineering controls Engineering Controls
Showers. Eyewash stations. Ventilation systems.
Individual protection measures, such as personal protective equipment Eye/Face Protection
Goggles or face shield.
Skin and Body Protection
Rubber gloves. Rubber apron.
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_____________________________________________________________________________________________ Respiratory Protection
Ensure adequate ventilation, especially in confined areas.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Appearance Color
Liquid Yellow liquid Yellow
Property pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties
Values Not determined Not available 60-82.2 °C / 140-180 °F Non-flammable aqueous solution <1 Liquid-Not applicable Not available Not available 31 0.98 0.99 Completely soluble Not determined Not determined Not determined Not determined Not determined Not determined Not determined Not determined
Odor Odor Threshold
Lemon Not determined
Remarks • Method
(Water = 1)
(Water = 1)
10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization
Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to Avoid Keep out of reach of children. Incompatible Materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied.
11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure
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_____________________________________________________________________________________________ Product Information Eye Contact
Avoid contact with eyes.
Skin Contact
Avoid contact with skin.
Inhalation
Do not inhale.
Ingestion
Do not ingest.
Component Information Chemical Name Isopropanol 67-63-0 Sodium xylenesulfonate 1300-72-7 1,2 Propanediol 57-55-6 Dipropylene Glycol Monomethyl Ether (DPM) 34590-94-8 Citral 5392-40-5
Oral LD50 = 1870 mg/kg ( Rat )
Dermal LD50 = 4059 mg/kg ( Rabbit )
Inhalation LC50 = 72600 mg/m3 ( Rat ) 4 h
= 1000 mg/kg ( Rat )
-
-
= 20000 mg/kg ( Rat )
= 20800 mg/kg ( Rabbit )
-
= 5230 mg/kg ( Rat )
= 9500 mg/kg ( Rabbit )
-
= 4950 mg/kg ( Rat )
= 2250 mg/kg ( Rabbit )
-
Information on physical, chemical and toxicological effects Symptoms
Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization
May cause an allergic skin reaction.
Carcinogenicity
Group 3 IARC components are "not classifiable as human carcinogens".
Chemical Name Isopropanol 67-63-0 Legend
ACGIH
IARC Group 3
NTP
OSHA X
IARC (International Agency for Research on Cancer) Group 3 IARC components are "not classifiable as human carcinogens" OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present
Numerical measures of toxicity Not determined Unknown Acute Toxicity
2.94% of the mixture consists of ingredient(s) of unknown toxicity.
12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information Chemical Name
Algae/aquatic plants
Fish
Toxicity to microorganisms
Crustacea
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_____________________________________________________________________________________________ Isopropanol 67-63-0
1000: 96 h Desmodesmus subspicatus mg/L EC50 1000: 72 h Desmodesmus subspicatus mg/L EC50
1,2 Propanediol 57-55-6
19000: 96 h Pseudokirchneriella subcapitata mg/L EC50
Dipropylene Glycol Monomethyl Ether (DPM) 34590-94-8 Citral 5392-40-5
9640: 96 h Pimephales promelas mg/L LC50 flowthrough 1400000: 96 h Lepomis macrochirus Âľg/L LC50 11130: 96 h Pimephales promelas mg/L LC50 static 51400: 96 h Pimephales promelas mg/L LC50 static 710: 96 h Pimephales promelas mg/L LC50 51600: 96 h Oncorhynchus mykiss mg/L LC50 static 41 - 47: 96 h Oncorhynchus mykiss mL/L LC50 static 10000: 96 h Pimephales promelas mg/L LC50 static
13299: 48 h Daphnia magna mg/L EC50
1000: 48 h Daphnia magna mg/L EC50 Static 10000: 24 h Daphnia magna mg/L EC50
1919: 48 h Daphnia magna mg/L LC50
16: 72 h Desmodesmus 4.6 - 10: 96 h Leuciscus idus EC50 = 2100 mg/L 30 min 7: 48 h Daphnia magna mg/L subspicatus mg/L EC50 19: mg/L LC50 static EC50 96 h Desmodesmus subspicatus mg/L EC50
Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Chemical Name Isopropanol 67-63-0 Dipropylene Glycol Monomethyl Ether (DPM) 34590-94-8 Citral 5392-40-5
Partition Coefficient 0.05 -0.064 2.76
Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
California Hazardous Waste Status Chemical Name Isopropanol 67-63-0
California Hazardous Waste Status Toxic Ignitable
14. TRANSPORT INFORMATION _____________________________________________________________________________________________ Page 6 / 8
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_____________________________________________________________________________________________ Please see current shipping paper for most up to date shipping information, including Note exemptions and special circumstances.
DOT
Not regulated
IATA
Not regulated
IMDG
Not regulated
15. REGULATORY INFORMATION International Inventories
Chemical Name Isopropanol Citral
TSCA Present Present
DSL X X
NDSL
EINECS Present Present
ELINCS
ENCS Present Present
IECSC X X
KECL Present Present
PICCS X X
AICS X X
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name
CAS No
Weight-%
Isopropanol - 67-63-0 Dipropylene Glycol Monomethyl Ether (DPM) - 34590-94-8
67-63-0 34590-94-8
<1 <1
SARA 313 - Threshold Values % 1.0 1.0
CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals.
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_____________________________________________________________________________________________ U.S. State Right-to-Know Regulations Chemical Name Isopropanol 67-63-0 1,2 Propanediol 57-55-6 Dipropylene Glycol Monomethyl Ether (DPM) 34590-94-8
New Jersey X
Massachusetts X
X
Pennsylvania X X
X
X
X
16. OTHER INFORMATION NFPA HMIS Issue Date: Revision Date: Revision Note:
Health Hazards Not determined Health Hazards 1
Flammability Not determined Flammability 1
Instability Not determined Physical Hazards 0
Special Hazards Not determined Personal Protection Not determined
01-Oct-2002 13-May-2015 New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet
_____________________________________________________________________________________________ Page 8 / 8
Safety Data Sheet Issue Date: 01-Oct-2002
Revision Date: 13-May-2015
Version 1
1. IDENTIFICATION Product Identifier Product Name
Magnum
Other means of identification SDS #
POZ-009
UN/ID No
UN1760
Recommended use of the chemical and restrictions on use Recommended Use heavy duty speed stripper. Details of the supplier of the safety data sheet Manufacturer Address Pur-O-Zone, Inc. 345 N. Iowa Street Lawrence, KS 66044 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr)
1-785-843-0771 1-800-535-5053
2. HAZARDS IDENTIFICATION Appearance Light brown paste
Physical State Liquid
Odor Typical solvent odor
Classification Skin corrosion/irritation Serious eye damage/eye irritation Carcinogenicity
Category 1 Sub-category B Category 1 Category 2
Hazards Not Otherwise Classified (HNOC) May be harmful if swallowed May be harmful in contact with skin Signal Word Danger Hazard Statements Causes severe skin burns and eye damage Suspected of causing cancer
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_____________________________________________________________________________________________ Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Do not breathe dust/fume/gas/mist/vapors/spray Wash face, hands and any exposed skin thoroughly after handling
Precautionary Statements - Response Immediately call a poison center or doctor/physician IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a poison center or doctor/physician IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately call a poison center or doctor/physician IF SWALLOWED: Rinse mouth. Do NOT induce vomiting Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Ethylene Glycol Monobutyl Ether Monoethanolamine Diethanolamine
CAS No 111-76-2 141-43-5 111-42-2
Weight-% 10-20 1-10 <1
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**
4. FIRST-AID MEASURES First Aid Measures General Advice
Immediately call a poison center or doctor/physician.
Eye Contact
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician.
Skin Contact
Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse.
Inhalation
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a poison center or doctor/physician.
Ingestion
Rinse mouth. Do not induce vomiting.
Most important symptoms and effects Symptoms
May be harmful if swallowed. May be harmful in contact with skin. Causes severe skin burns and eye damage. Suspected of causing cancer.
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_____________________________________________________________________________________________ Indication of any immediate medical attention and special treatment needed Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions
Use personal protective equipment as required.
Environmental Precautions
See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up
Collect and reuse if possible, absorb with inert material (sand, sawdust, etc.), or flush to sewer with large quantity of water if permitted by all local, state and federal regulations.
7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Do not breathe dust/fume/gas/mist/vapors/spray. Wash face, hands, and any exposed skin thoroughly after handling.
Conditions for safe storage, including any incompatibilities Storage Conditions
Store locked up.
Incompatible Materials
Strong acids. Strong oxidizers.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name
ACGIH TLV
OSHA PEL
NIOSH IDLH
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_____________________________________________________________________________________________ Ethylene Glycol Monobutyl Ether 111-76-2
TWA: 20 ppm
Monoethanolamine 141-43-5
STEL: 6 ppm TWA: 3 ppm
Sodium metasilicate 6834-92-0 Caustic Soda 1310-73-2 Diethanolamine 111-42-2
2 mg/m3
Glycerol 56-81-5
TWA: 50 ppm TWA: 240 mg/m3 (vacated) TWA: 25 ppm (vacated) TWA: 120 mg/m3 (vacated) S* S* TWA: 3 ppm TWA: 6 mg/m3 (vacated) TWA: 3 ppm (vacated) TWA: 8 mg/m3 (vacated) STEL: 6 ppm (vacated) STEL: 15 mg/m3 2 mg/m3
Ceiling: 2 mg/m3 TWA: 1 mg/m3 inhalable fraction and vapor S* -
IDLH: 700 ppm TWA: 5 ppm TWA: 24 mg/m3
IDLH: 30 ppm TWA: 3 ppm TWA: 8 mg/m3 STEL: 6 ppm STEL: 15 mg/m3 -
TWA: 2 mg/m3 (vacated) Ceiling: 2 mg/m3 (vacated) TWA: 3 ppm (vacated) TWA: 15 mg/m3
IDLH: 10 mg/m3 Ceiling: 2 mg/m3 TWA: 3 ppm TWA: 15 mg/m3
TWA: 15 mg/m3 mist, total particulate TWA: 5 mg/m3 mist, respirable fraction (vacated) TWA: 10 mg/m3 mist, total particulate (vacated) TWA: 5 mg/m3 mist, respirable fraction
-
Appropriate engineering controls Engineering Controls
Showers. Eyewash stations. Ventilation systems.
Individual protection measures, such as personal protective equipment Eye/Face Protection
Chemical splash goggles.
Skin and Body Protection
Rubber gloves. Full cover clothing. Rubber apron.
Respiratory Protection
None normally required with adequate room ventilation.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Appearance Color
Liquid Light brown paste Light brown
Property pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility
Values Not determined Not available 100 °C / 212 °F Non-flammable aqueous solution >1 Liquid-Not applicable Not available Not available >30 Not established 1.051 Completely soluble
Odor Odor Threshold
Typical solvent odor Not determined
Remarks • Method
(Water = 1)
(Water = 1)
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_____________________________________________________________________________________________ Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties
Not determined Not determined Not determined Not determined Not determined Not determined Not determined Not determined
10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization
Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to Avoid Keep out of reach of children. Incompatible Materials Strong acids. Strong oxidizers. Hazardous Decomposition Products None known based on information supplied.
11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact
Causes severe eye damage.
Skin Contact
Causes severe skin burns.
Inhalation
Do not inhale.
Ingestion
May be harmful if swallowed.
Component Information Chemical Name Ethylene Glycol Monobutyl Ether 111-76-2 Monoethanolamine 141-43-5 Nonylphenol Ethoxylate 127087-87-0 Sodium metasilicate 6834-92-0 Caustic Soda 1310-73-2 Coconut Diethanolamide 8051-30-7
Oral LD50 = 470 mg/kg ( Rat )
Dermal LD50 = 99 mg/kg ( Rabbit )
Inhalation LC50 = 450 ppm ( Rat ) 4 h
= 1720 mg/kg ( Rat )
-
= 1310 mg/kg ( Rat )
= 1 mL/kg ( Rabbit ) = 1000 mg/kg ( Rabbit ) -
= 600 mg/kg ( Rat )
-
-
-
= 1350 mg/kg ( Rabbit )
-
> 2000 mg/kg ( Rat )
-
-
-
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_____________________________________________________________________________________________ p-Toluenesulfonic acid 104-15-4 Tetrasodium EDTA 64-02-8 Diethanolamine 111-42-2 Dimethylbenzenesulfonic acid 25321-41-9 Glycerol 56-81-5
= 1410 mg/kg ( Rat )
-
-
= 1658 mg/kg ( Rat ) = 10 g/kg ( Rat ) = 620 ÂľL/kg ( Rat ) = 0.62 mL/kg ( Rat ) = 7200 mg/kg ( Rat )
-
-
= 7640 ÂľL/kg ( Rabbit )
-
-
-
= 12600 mg/kg ( Rat )
> 10 g/kg ( Rabbit )
> 570 mg/m3 ( Rat ) 1 h
Information on physical, chemical and toxicological effects Symptoms
Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity
Suspected of causing cancer.
Chemical Name Ethylene Glycol Monobutyl Ether 111-76-2 Diethanolamine 111-42-2 Legend
ACGIH A3
IARC Group 3
A3
Group 2B
NTP
OSHA
X
ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 2B - Possibly Carcinogenic to Humans Group 3 IARC components are "not classifiable as human carcinogens" OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present
Numerical measures of toxicity Not determined
12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information Chemical Name
Algae/aquatic plants
Ethylene Glycol Monobutyl Ether 111-76-2 Monoethanolamine 141-43-5
15: 72 h Desmodesmus subspicatus mg/L EC50
Fish 1490: 96 h Lepomis macrochirus mg/L LC50 static 2950: 96 h Lepomis macrochirus mg/L LC50 200: 96 h Oncorhynchus mykiss mg/L LC50 flowthrough 114 - 196: 96 h Oncorhynchus mykiss mg/L LC50 static 3684: 96 h Brachydanio rerio mg/L LC50 static 300 - 1000: 96 h Lepomis macrochirus mg/L LC50 static 227: 96 h Pimephales promelas mg/L LC50 flow-through
Toxicity to microorganisms
Crustacea 1000: 48 h Daphnia magna mg/L EC50 1698 - 1940: 24 h Daphnia magna mg/L EC50 65: 48 h Daphnia magna mg/L EC50
_____________________________________________________________________________________________ Page 6 / 10
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_____________________________________________________________________________________________ Sodium metasilicate 6834-92-0
Caustic Soda 1310-73-2 Coconut Diethanolamide 8051-30-7 p-Toluenesulfonic acid 104-15-4 Tetrasodium EDTA 64-02-8 Diethanolamine 111-42-2
Glycerol 56-81-5
210: 96 h Brachydanio rerio mg/L LC50 semi-static 210: 96 h Brachydanio rerio mg/L LC50 45.4: 96 h Oncorhynchus mykiss mg/L LC50 static 5.4: 96 h Brachydanio rerio mg/L LC50 semi-static
216: 96 h Daphnia magna mg/L EC50
41: 96 h Lepomis macrochirus mg/L LC50 static 59.8: 96 h Pimephales promelas mg/L LC50 static 7.8: 72 h Desmodesmus 4460 - 4980: 96 h subspicatus mg/L EC50 2.1 - Pimephales promelas mg/L 2.3: 96 h Pseudokirchneriella LC50 flow-through 1200 subcapitata mg/L EC50 1580: 96 h Pimephales promelas mg/L LC50 static 600 - 1000: 96 h Lepomis macrochirus mg/L LC50 static 51 - 57: 96 h Oncorhynchus mykiss mL/L LC50 static
610: 24 h Daphnia magna mg/L EC50
2.3: 96 h Scenedesmus acutus mg/L EC50 245000: 24 h Chlorella vulgaris mg/L EC50 1.01: 72 h Desmodesmus subspicatus mg/L EC50
5.4: 24 h Daphnia magna mg/L EC50
EC50 = 73 mg/L 5 min EC50 > 16 mg/L 16 h
55: 48 h Daphnia magna mg/L EC50
500: 24 h Daphnia magna mg/L EC50
Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Chemical Name Ethylene Glycol Monobutyl Ether 111-76-2 Monoethanolamine 141-43-5 p-Toluenesulfonic acid 104-15-4 Diethanolamine 111-42-2 Glycerol 56-81-5
Partition Coefficient 0.81 -1.91 0.784 -2.18 -1.76
Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
California Hazardous Waste Status Chemical Name
California Hazardous Waste Status
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_____________________________________________________________________________________________ Caustic Soda 1310-73-2
Toxic Corrosive
14. TRANSPORT INFORMATION Note
Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.
DOT UN/ID No Proper Shipping Name Hazard Class Packing Group
UN1760 Corrosive liquids, n.o.s. (Monoethanolamine, Ethylene glycol monobutyl ether) 8 II
IATA UN/ID No Proper Shipping Name Hazard Class Packing Group
UN1760 Corrosive liquids, n.o.s. (Monoethanolamine, Ethylene glycol monobutyl ether) 8 II
IMDG UN/ID No Proper Shipping Name Hazard Class Packing Group
UN1760 Corrosive liquids, n.o.s. (Monoethanolamine, Ethylene glycol monobutyl ether) 8 II
15. REGULATORY INFORMATION International Inventories
Chemical Name Ethylene Glycol Monobutyl Ether Monoethanolamine Diethanolamine
TSCA Present
DSL X
Present Present
X X
NDSL
EINECS Present
ELINCS
Present Present
ENCS Present
IECSC X
KECL Present
PICCS X
AICS X
Present Present
X X
Present Present
X X
X X
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations CERCLA Chemical Name
Hazardous Substances RQs
CERCLA/SARA RQ
Reportable Quantity (RQ)
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_____________________________________________________________________________________________ Caustic Soda 1310-73-2 Diethanolamine 111-42-2
1000 lb
RQ 1000 lb final RQ RQ 454 kg final RQ RQ 100 lb final RQ RQ 45.4 kg final RQ
100 lb
SARA 313 Chemical Name
CAS No
Weight-%
Ethylene Glycol Monobutyl Ether - 111-76-2 Diethanolamine - 111-42-2
111-76-2 111-42-2
10-20 <1
SARA 313 - Threshold Values % 1.0 1.0
CWA (Clean Water Act) Chemical Name Caustic Soda
CWA - Reportable Quantities 1000 lb
CWA - Toxic Pollutants CWA - Priority Pollutants
CWA - Hazardous Substances X
US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals. Chemical Name Diethanolamine - 111-42-2
California Proposition 65 Carcinogen
U.S. State Right-to-Know Regulations Chemical Name Ethylene Glycol Monobutyl Ether 111-76-2 Monoethanolamine 141-43-5 Caustic Soda 1310-73-2 p-Toluenesulfonic acid 104-15-4 Diethanolamine 111-42-2 Glycerol 56-81-5
New Jersey X
Massachusetts X
Pennsylvania X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
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_____________________________________________________________________________________________
16. OTHER INFORMATION
NFPA HMIS Issue Date: Revision Date: Revision Note:
Health Hazards Not determined Health Hazards 2
Flammability Not determined Flammability 0
Instability Not determined Physical Hazards 0
Special Hazards Not determined Personal Protection Not determined
01-Oct-2002 13-May-2015 New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet
_____________________________________________________________________________________________ Page 10 / 10
Safety Data Sheet Issue Date: 01-Oct-2002
Revision Date: 13-May-2015
Version 1
1. IDENTIFICATION Product Identifier Product Name
No Ghost
Other means of identification SDS #
POZ-010
Recommended use of the chemical and restrictions on use Recommended Use Liquid blackboard cleaner. Details of the supplier of the safety data sheet Manufacturer Address Pur-O-Zone, Inc. 345 N. Iowa Street Lawrence, KS 66044 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr)
1-785-843-0771 1-800-535-5053
2. HAZARDS IDENTIFICATION Appearance Clear, white as water liquid
Physical State Liquid
Odor No odor
Classification This chemical does not meet the hazardous criteria set forth by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). However, this Safety Data Sheet (SDS) contains valuable information critical to the safe handling and proper use of this product. This SDS should be retained and available for employees and other users of this product.
3. COMPOSITION/INFORMATION ON INGREDIENTS The product contains no substances which, at their given concentration, are considered to be hazardous to health. However, additional component information is available in subsequent sections of this SDS.
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_____________________________________________________________________________________________
4. FIRST-AID MEASURES
First Aid Measures Eye Contact
Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician.
Skin Contact
Wash off immediately with plenty of water for at least 15 minutes.
Inhalation
Remove to fresh air.
Ingestion
Drink gelatin solution, egg whites or two to three large glasses of water. Call a physician.
Most important symptoms and effects Symptoms
May cause eye irritation. Prolonged or repeated exposure may cause skin irritation. May cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. Mists created by spray application may irritate respiratory tract.
Indication of any immediate medical attention and special treatment needed Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions
Use personal protective equipment as required.
Environmental Precautions
See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up
Collect and reuse if possible, absorb with inert material (sand, sawdust, etc.), or flush to sewer with large quantity of water if permitted by all local, state and federal regulations.
7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice.
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_____________________________________________________________________________________________ Conditions for safe storage, including any incompatibilities Storage Conditions
Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible Materials
None known based on information supplied.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines
This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies
Appropriate engineering controls Engineering Controls
Showers. Eyewash stations. Ventilation systems.
Individual protection measures, such as personal protective equipment Eye/Face Protection
Use safety glasses or goggles.
Skin and Body Protection
Rubber gloves. Rubber apron.
Respiratory Protection
Ensure adequate ventilation, especially in confined areas.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Appearance Color
Liquid Clear, white as water liquid Clear, water white, colorless
Property pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties
Values Not determined Not available 100 °C / 212 °F None 1.0 Liquid-Not applicable Not available Not available Not established Not established 1.0 Completely soluble Not determined Not determined Not determined Not determined Not determined Not determined Not determined Not determined
Odor Odor Threshold
No odor Not determined
Remarks • Method
(Water = 1)
(Water = 1)
10. STABILITY AND REACTIVITY Reactivity
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_____________________________________________________________________________________________ Not reactive under normal conditions.
Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization
Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to Avoid Keep out of reach of children. Incompatible Materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied.
11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact
Avoid contact with eyes.
Skin Contact
Avoid contact with skin.
Inhalation
Do not inhale.
Ingestion
Do not ingest.
Component Information Chemical Name Nonylphenol Ethoxylate 127087-87-0 Propylene Glycol 57-55-6
Oral LD50 = 1310 mg/kg ( Rat )
Dermal LD50 -
Inhalation LC50 -
= 20000 mg/kg ( Rat )
= 20800 mg/kg ( Rabbit )
-
Information on physical, chemical and toxicological effects Symptoms
Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity
Based on the information provided, this product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP.
Numerical measures of toxicity Not determined
12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.
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_____________________________________________________________________________________________ Component Information Chemical Name
Algae/aquatic plants
Fish
Propylene Glycol 57-55-6
19000: 96 h Pseudokirchneriella subcapitata mg/L EC50
51400: 96 h Pimephales promelas mg/L LC50 static 710: 96 h Pimephales promelas mg/L LC50 51600: 96 h Oncorhynchus mykiss mg/L LC50 static 41 - 47: 96 h Oncorhynchus mykiss mL/L LC50 static
Toxicity to microorganisms
Crustacea 1000: 48 h Daphnia magna mg/L EC50 Static 10000: 24 h Daphnia magna mg/L EC50
Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Not determined Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
14. TRANSPORT INFORMATION Note
Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.
DOT
Not regulated
IATA
Not regulated
IMDG
Not regulated
15. REGULATORY INFORMATION International Inventories All ingredients are listed or exempt from listing on Chemical Substance Inventory
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_____________________________________________________________________________________________ Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name Propylene Glycol 57-55-6
New Jersey X
Massachusetts
Pennsylvania X
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_____________________________________________________________________________________________
16. OTHER INFORMATION
NFPA HMIS Issue Date: Revision Date: Revision Note:
Health Hazards Not determined Health Hazards 1
Flammability Not determined Flammability 0
Instability Not determined Physical Hazards 0
Special Hazards Not determined Personal Protection Not determined
01-Oct-2002 13-May-2015 New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet
_____________________________________________________________________________________________ Page 7 / 7
Safety Data Sheet Issue Date: 19-Apr-2001
Revision Date: 13-May-2015
Version 1
1. IDENTIFICATION Product Identifier Product Name
pH Down
Other means of identification SDS #
POZ-011
Recommended use of the chemical and restrictions on use Recommended Use pH Neutralizer. Details of the supplier of the safety data sheet Manufacturer Address Pur-O-Zone, Inc. 345 N. Iowa Street Lawrence, KS 66044 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr)
1-785-843-0771 1-800-535-5053
2. HAZARDS IDENTIFICATION Appearance Off-white, bead-like
Physical State Solid
Odor Odorless
Classification Serious eye damage/eye irritation
Category 1
Hazards Not Otherwise Classified (HNOC) May be harmful if swallowed Signal Word Danger Hazard Statements Causes serious eye damage
Precautionary Statements - Prevention Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a poison center or doctor/physician
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_____________________________________________________________________________________________
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Sodium bisulfate
CAS No 7681-38-1
Weight-% 90-100
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**
4. FIRST-AID MEASURES First Aid Measures Eye Contact
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician.
Skin Contact
Wash off immediately with plenty of water for at least 15 minutes.
Inhalation
Remove to fresh air.
Ingestion
Call a physician immediately. Drink at least 2 glasses of water. Do not induce vomiting.
Most important symptoms and effects Symptoms
May be harmful if swallowed. Causes serious eye damage.
Indication of any immediate medical attention and special treatment needed Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Hazardous Combustion Products Oxides of carbon. Oxides of sulfur. Oxides of sodium. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Cool containers exposed to extreme heat with large quantities of water.
6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures
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_____________________________________________________________________________________________ Personal Precautions
Use personal protective equipment as required.
Environmental Precautions
See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up
Contain spill and ventilate area. Sweep up and put in container for disposal. Flush any remaining spill with water.
7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice. Wear protective gloves/protective clothing and eye/face protection.
Conditions for safe storage, including any incompatibilities Storage Conditions
Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible Materials
Acids. Bases. Metals.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines
This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies
Appropriate engineering controls Engineering Controls
Showers. Eyewash stations. Ventilation systems.
Individual protection measures, such as personal protective equipment Eye/Face Protection
Chemical splash goggles.
Skin and Body Protection
Rubber gloves. Full cover clothing. Rubber apron.
Respiratory Protection
None normally required with adequate room ventilation.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Appearance Color
Solid Off-white, bead-like Off-white
Property pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate
Values Not determined 176.7 °C / 350 °F Not available Not available Not available
Odor Odor Threshold
Odorless Not determined
Remarks • Method
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_____________________________________________________________________________________________ Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties
Not determined 7 1 Not available Not available Not available Soluble Not determined Not determined Not determined Not determined Not determined Not determined Not determined Not determined
10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization
Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to Avoid Heat, flames and sparks. Incompatible Materials. Incompatible Materials Acids. Bases. Metals. Hazardous Decomposition Products Oxides of carbon. Oxides of sulfur. Oxides of sodium.
11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact
Causes serious eye damage.
Skin Contact
Avoid contact with skin.
Inhalation
Do not inhale.
Ingestion
May be harmful if swallowed.
Component Information Chemical Name Sodium bisulfate 7681-38-1
Oral LD50 = 2490 mg/kg ( Rat )
Dermal LD50 -
Inhalation LC50 -
Information on physical, chemical and toxicological effects
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_____________________________________________________________________________________________ Symptoms
Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity
Based on the information provided, this product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP.
Numerical measures of toxicity Not determined
12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information Chemical Name
Algae/aquatic plants
Fish
Sodium bisulfate 7681-38-1
Toxicity to microorganisms
Crustacea 190: 48 h Daphnia magna mg/L EC50
Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Not determined Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
14. TRANSPORT INFORMATION Note
Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.
DOT
Not regulated
IATA
Not regulated
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_____________________________________________________________________________________________ IMDG
Not regulated
15. REGULATORY INFORMATION International Inventories
Chemical Name Sodium bisulfate
TSCA Present
DSL X
NDSL
EINECS Present
ELINCS
ENCS Present
IECSC X
KECL Present
PICCS X
AICS X
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations This product does not contain any substances regulated under applicable state right-to-know regulations
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_____________________________________________________________________________________________
16. OTHER INFORMATION
NFPA HMIS Issue Date: Revision Date: Revision Note:
Health Hazards Not determined Health Hazards 2
Flammability Not determined Flammability 2
Instability Not determined Physical Hazards 2
Special Hazards Not determined Personal Protection Not determined
19-Apr-2001 13-May-2015 New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet
_____________________________________________________________________________________________ Page 7 / 7
Safety Data Sheet Issue Date: 01-Oct-2002
Revision Date: 13-May-2015
Version 1
1. IDENTIFICATION Product Identifier Product Name
pH Up
Other means of identification SDS #
POZ-012
Recommended use of the chemical and restrictions on use Recommended Use pH Neutralizer. Details of the supplier of the safety data sheet Manufacturer Address Pur-O-Zone, Inc. 345 N. Iowa Street Lawrence, KS 66044 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr)
1-785-843-0771 1-800-535-5053
2. HAZARDS IDENTIFICATION Appearance White granular
Physical State Solid
Odor Odorless
Classification Acute toxicity - Inhalation (Dusts/Mists) Serious eye damage/eye irritation
Category 4 Category 2
Hazards Not Otherwise Classified (HNOC) May be harmful if swallowed May be harmful if inhaled Signal Word Warning Hazard Statements Harmful if inhaled Causes serious eye irritation
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_____________________________________________________________________________________________ Precautionary Statements - Prevention Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Wash face, hands and any exposed skin thoroughly after handling Wear eye/face protection Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a poison center or doctor/physician if you feel unwell
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Sodium carbonate
CAS No 497-19-8
Weight-% 90-100
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**
4. FIRST-AID MEASURES First Aid Measures Eye Contact
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Skin Contact
Wash off immediately with plenty of water for at least 15 minutes.
Inhalation
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center or doctor/physician if you feel unwell.
Ingestion
Clean mouth with water and drink afterwards plenty of water.
Most important symptoms and effects Symptoms
May be harmful if swallowed. May be harmful if inhaled. Harmful if inhaled. Causes serious eye irritation.
Indication of any immediate medical attention and special treatment needed Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined.
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_____________________________________________________________________________________________ Specific Hazards Arising from the Chemical Not determined.
Hazardous Combustion Products Oxides of carbon. Oxides of sodium. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Cool containers exposed to extreme heat with large quantities of water.
6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions
Use personal protective equipment as required.
Environmental Precautions
See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up
Contain spill and ventilate area. Sweep up and put in container for disposal. Flush any remaining spill with water.
7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wash face, hands, and any exposed skin thoroughly after handling. Wear eye/face protection.
Conditions for safe storage, including any incompatibilities Storage Conditions
Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible Materials
Halogens. Acids. Metals.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines
This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies
Appropriate engineering controls Engineering Controls
Showers. Eyewash stations. Ventilation systems.
Individual protection measures, such as personal protective equipment Eye/Face Protection
Chemical splash goggles.
Skin and Body Protection
Rubber gloves. Full cover clothing. Rubber apron.
Respiratory Protection
Ensure adequate ventilation, especially in confined areas.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
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_____________________________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties Physical State Appearance Color
Solid White granular White
Property pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties
Values Not determined 851.1 °C / 1564 °F Not available Not available Not available Not determined 7 1 Not available Not available 2.509 33.2 maximum Not determined Not determined Not determined Not determined Not determined Not determined Not determined Not determined
Odor Odor Threshold
Odorless Not determined
Remarks • Method
(Water = 1)
10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization
Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to Avoid Heat, flames and sparks. Incompatible Materials. Incompatible Materials Halogens. Acids. Metals. Hazardous Decomposition Products Oxides of carbon. Oxides of sodium.
11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact
Causes serious eye irritation.
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_____________________________________________________________________________________________ Skin Contact
Avoid contact with skin.
Inhalation
Harmful if inhaled.
Ingestion
May be harmful if swallowed.
Component Information Chemical Name Sodium carbonate 497-19-8
Oral LD50 = 4090 mg/kg ( Rat )
Dermal LD50 -
Inhalation LC50 = 2300 mg/m3 ( Rat ) 2 h
Information on physical, chemical and toxicological effects Symptoms
Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity
Based on the information provided, this product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP.
Numerical measures of toxicity Not determined
12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information Chemical Name
Algae/aquatic plants
Fish
Sodium carbonate 497-19-8
242: 120 h Nitzschia mg/L EC50
300: 96 h Lepomis macrochirus mg/L LC50 static 310 - 1220: 96 h Pimephales promelas mg/L LC50 static
Toxicity to microorganisms
Crustacea 265: 48 h Daphnia magna mg/L EC50
Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Not determined Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS Waste Treatment Methods
_____________________________________________________________________________________________ Page 5 / 7
Revision Date: 13-May-2015
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_____________________________________________________________________________________________ Disposal of Wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
California Hazardous Waste Status Chemical Name Sodium carbonate 497-19-8
California Hazardous Waste Status Corrosive
14. TRANSPORT INFORMATION Note
Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.
DOT
Not regulated
IATA
Not regulated
IMDG
Not regulated
15. REGULATORY INFORMATION International Inventories
Chemical Name Sodium carbonate
TSCA Present
DSL X
NDSL
EINECS Present
ELINCS
ENCS Present
IECSC X
KECL Present
PICCS X
AICS X
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
_____________________________________________________________________________________________ Page 6 / 7
Revision Date: 13-May-2015
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_____________________________________________________________________________________________ CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations This product does not contain any substances regulated under applicable state right-to-know regulations
16. OTHER INFORMATION NFPA HMIS Issue Date: Revision Date: Revision Note:
Health Hazards Not determined Health Hazards 2
Flammability Not determined Flammability 2
Instability Not determined Physical Hazards 2
Special Hazards Not determined Personal Protection Not determined
01-Oct-2002 13-May-2015 New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet
_____________________________________________________________________________________________ Page 7 / 7
Safety Data Sheet Issue Date: 01-Oct-2002
Revision Date: 13-May-2015
Version 1
1. IDENTIFICATION Product Identifier Product Name
Prime All
Other means of identification SDS #
POZ-013
Recommended use of the chemical and restrictions on use Recommended Use Seal/base coat. Details of the supplier of the safety data sheet Manufacturer Address Pur-O-Zone, Inc. 345 N. Iowa Street Lawrence, KS 66044 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr)
1-785-843-0771 1-800-535-5053
2. HAZARDS IDENTIFICATION Appearance Milky white liquid
Physical State Liquid
Odor Slight ammonia
Classification Reproductive toxicity
Category 1B
Signal Word Danger Hazard Statements May damage fertility or the unborn child
Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Precautionary Statements - Response If exposed or concerned: Get medical advice/attention Precautionary Statements - Storage Store locked up
_____________________________________________________________________________________________ Page 1 / 8
Revision Date: 13-May-2015
POZ-013 - Prime All
_____________________________________________________________________________________________ Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Other Hazards Harmful to aquatic life with long lasting effects
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Dibutyl phthalate Ethyl Alcohol
CAS No 84-74-2 64-17-5
Weight-% <5 <1
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**
4. FIRST-AID MEASURES First Aid Measures General Advice
If exposed or concerned: Get medical advice/attention.
Eye Contact
Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician.
Skin Contact
Wash off immediately with plenty of water for at least 15 minutes.
Inhalation
Remove to fresh air.
Ingestion
Drink two large glasses of water. Do not induce vomiting. Call a physician.
Most important symptoms and effects Symptoms
May damage fertility or the unborn child.
Indication of any immediate medical attention and special treatment needed Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES _____________________________________________________________________________________________ Page 2 / 8
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_____________________________________________________________________________________________ Personal precautions, protective equipment and emergency procedures Personal Precautions
Use personal protective equipment as required.
Environmental Precautions
See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up
Collect and reuse if possible, absorb with inert material (sand, sawdust, etc.), or flush to sewer with large quantity of water if permitted by all local, state and federal regulations.
7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required.
Conditions for safe storage, including any incompatibilities Storage Conditions
Store locked up.
Incompatible Materials
None known based on information supplied.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name Dibutyl phthalate 84-74-2 Ethyl Alcohol 64-17-5
ACGIH TLV TWA: 5 mg/m3 STEL: 1000 ppm
OSHA PEL TWA: 5 mg/m3 (vacated) TWA: 5 mg/m3 TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3
NIOSH IDLH IDLH: 4000 mg/m3 TWA: 5 mg/m3 IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3
Appropriate engineering controls Engineering Controls
Showers. Eyewash stations. Ventilation systems.
Individual protection measures, such as personal protective equipment Eye/Face Protection
Avoid contact with eyes.
Skin and Body Protection
Rubber gloves. Rubber apron.
Respiratory Protection
None normally required with adequate room ventilation.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State
Liquid
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_____________________________________________________________________________________________ Appearance Color
Milky white liquid Milky white
Odor Odor Threshold
Property pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties
Values Not determined Not available 100 °C / 212 °F Non-flammable aqueous solution <1 Liquid-Not applicable Not available Not available <30 <1 1.028 Miscible emulsion Not determined Not determined Not determined Not determined Not determined Not determined Not determined Not determined
Remarks • Method
Slight ammonia Not determined
(Water = 1)
(Water = 1)
10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization
Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to Avoid Keep out of reach of children. Incompatible Materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied.
11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact
Avoid contact with eyes.
Skin Contact
Avoid contact with skin.
Inhalation
Do not inhale.
Ingestion
Do not ingest.
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Revision Date: 13-May-2015
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_____________________________________________________________________________________________ Component Information Chemical Name Di(ethylene glycol) ethyl ether 111-90-0 Dibutyl phthalate 84-74-2 Ethyl Alcohol 64-17-5
Oral LD50 = 1920 mg/kg ( Rat )
Inhalation LC50 > 5240 mg/m3 ( Rat ) 4 h
= 6300 mg/kg ( Rat )
Dermal LD50 = 6 mL/kg ( Rat ) = 4200 ÂľL/kg ( Rabbit ) > 20000 mg/kg ( Rabbit )
= 7060 mg/kg ( Rat )
-
= 124.7 mg/L ( Rat ) 4 h
> 15.68 mg/L ( Rat ) 4 h
Information on physical, chemical and toxicological effects Symptoms
Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity
Ethanol has been shown to be carcinogenic in long-term studies only when consumed as an alcoholic beverage.
Chemical Name Ethyl Alcohol 64-17-5 Legend
ACGIH A3
IARC Group 1
NTP Known
OSHA X
Toxicity to microorganisms
Crustacea
ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present
Reproductive toxicity
May damage fertility or the unborn child.
Numerical measures of toxicity Not determined
12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life with long lasting effects. Component Information Chemical Name Di(ethylene glycol) ethyl ether 111-90-0
Algae/aquatic plants
Fish 10000: 96 h Lepomis macrochirus mg/L LC50 static 19100 - 23900: 96 h Lepomis macrochirus mg/L LC50 flow-through 11400 15700: 96 h Oncorhynchus mykiss mg/L LC50 flowthrough 11600 - 16700: 96 h Pimephales promelas mg/L LC50 flow-through 13400: 96 h Salmo gairdneri mg/L LC50 flow-through
3940 - 4670: 48 h Daphnia magna mg/L EC50
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Revision Date: 13-May-2015
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_____________________________________________________________________________________________ Dibutyl phthalate 84-74-2
Ethyl Alcohol 64-17-5
1.2: 72 h Desmodesmus 0.71 - 1.2: 96 h Pimephales subspicatus mg/L EC50 0.4: promelas mg/L LC50 flow96 h Pseudokirchneriella through 0.31 - 5.45: 96 h subcapitata mg/L EC50 Pimephales promelas mg/L static LC50 static 1.24: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 1.24 - 5.3: 96 h Oncorhynchus mykiss mg/L LC50 static 1.38 - 1.74: 96 h Lepomis macrochirus mg/L LC50 flow-through 0.42 - 1.28: 96 h Lepomis macrochirus mg/L LC50 static 12.0 - 16.0: 96 h Oncorhynchus mykiss mL/L LC50 static 13400 - 15100: 96 h Pimephales promelas mg/L LC50 flow-through 100: 96 h Pimephales promelas mg/L LC50 static
EC50 = 10.9 mg/L 30 min EC50 = 10.9 mg/L 5 min EC50 = 11.1 mg/L 15 min EC50 = 2.2 mg/L 24 h
2.99: 48 h Daphnia magna mg/L EC50 Static 3.4: 48 h Daphnia magna mg/L EC50
EC50 = 34634 mg/L 30 min 9268 - 14221: 48 h Daphnia EC50 = 35470 mg/L 5 min magna mg/L LC50 2: 48 h Daphnia magna mg/L EC50 Static 10800: 24 h Daphnia magna mg/L EC50
Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Chemical Name Di(ethylene glycol) ethyl ether 111-90-0 Dibutyl phthalate 84-74-2 Ethyl Alcohol 64-17-5
Partition Coefficient -0.8 5.38 -0.32
Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
US EPA Waste Number Chemical Name Dibutyl phthalate 84-74-2
RCRA
RCRA - Basis for Listing Included in waste stream: F039
RCRA - D Series Wastes
RCRA - U Series Wastes U069
California Hazardous Waste Status Chemical Name
California Hazardous Waste Status
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Revision Date: 13-May-2015
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_____________________________________________________________________________________________ Ethyl Alcohol 64-17-5
Toxic Ignitable
14. TRANSPORT INFORMATION Note
Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.
DOT
Not regulated
IATA
Not regulated
IMDG Marine Pollutant
This material may meet the definition of a marine pollutant
15. REGULATORY INFORMATION International Inventories
Chemical Name Dibutyl phthalate Ethyl Alcohol
TSCA Present Present
DSL X X
NDSL
EINECS Present Present
ELINCS
ENCS Present Present
IECSC X X
KECL Present Present
PICCS X X
AICS X X
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations CERCLA Chemical Name Dibutyl phthalate 84-74-2
Hazardous Substances RQs 10 lb
CERCLA/SARA RQ
Reportable Quantity (RQ) RQ 10 lb final RQ RQ 4.54 kg final RQ
SARA 313 Chemical Name
CAS No
Weight-%
Di(ethylene glycol) ethyl ether - 111-90-0 Dibutyl phthalate - 84-74-2
111-90-0 84-74-2
<5 <5
SARA 313 - Threshold Values % 1.0 1.0
CWA (Clean Water Act) Chemical Name
CWA - Reportable Quantities
CWA - Toxic Pollutants CWA - Priority Pollutants
CWA - Hazardous Substances
_____________________________________________________________________________________________ Page 7 / 8
Revision Date: 13-May-2015
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_____________________________________________________________________________________________ Dibutyl phthalate
10 lb
X
X
X
US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals. Chemical Name Dibutyl phthalate - 84-74-2
California Proposition 65 Developmental Female Reproductive Male Reproductive Carcinogen Developmental
Ethyl Alcohol - 64-17-5
U.S. State Right-to-Know Regulations Chemical Name Di(ethylene glycol) ethyl ether 111-90-0 Dibutyl phthalate 84-74-2 Ethyl Alcohol 64-17-5
New Jersey X
Massachusetts
Pennsylvania X
X
X
X
X
X
X
16. OTHER INFORMATION NFPA HMIS Issue Date: Revision Date: Revision Note:
Health Hazards Not determined Health Hazards 1
Flammability Not determined Flammability 0
Instability Not determined Physical Hazards 0
Special Hazards Not determined Personal Protection Not determined
01-Oct-2002 13-May-2015 New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet
_____________________________________________________________________________________________ Page 8 / 8
SAFETY DATA SHEET Quick Prep
Section 1. Identification GHS product identifier
: Quick Prep
Product type
: Liquid
Relevant identified uses of the substance or mixture and uses advised against Not applicable. Supplier's details
: Pur-O-Zone Company P.O. Box 727 Lawrence, KS 66044 Phone: 785-843-0771
Emergency telephone number (with hours of operation)
: 800-843-6174 (24 Hours)
Section 2. Hazards identification OSHA/HCS status Classification of the substance or mixture
: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). : SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2
GHS label elements Hazard pictograms
:
Signal word
: Warning
Hazard statements
: May cause an allergic skin reaction. Suspected of causing cancer.
Precautionary statements General Prevention
Response
Storage Disposal Hazards not otherwise classified
Date of issue/Date of revision
: Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Wear protective gloves. Avoid breathing vapor. Contaminated work clothing should not be allowed out of the workplace. : IF exposed or concerned: Get medical attention. IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical attention. : Store locked up. : Dispose of contents and container in accordance with all local, regional, national and international regulations. : None known.
: 11/14/2014.
Date of previous issue
: No previous validation.
Version
: 0.01
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Section 3. Composition/information on ingredients Substance/mixture
: Mixture
Other means of identification
: Not available
CAS number/other identifiers CAS number
: Not applicable
Ingredient name
%
CAS number
Coconut oil diethanolamide d-Limonene Diethanolamine
1-5 0-1 0-1
68603-42-9 5989-27-5 111-42-2
Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8.
Section 4. First aid measures Description of necessary first aid measures Eye contact
Inhalation
Skin contact
Ingestion
: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. : Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact
: No known significant effects or critical hazards.
Inhalation
: No known significant effects or critical hazards.
Skin contact
: May cause an allergic skin reaction.
Ingestion
: No known significant effects or critical hazards.
Over-exposure signs/symptoms Eye contact Date of issue/Date of revision
: No specific data. : 11/14/2014.
Date of previous issue
: No previous validation.
Version
: 0.01
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Section 4. First aid measures Inhalation
: No specific data.
Skin contact
: Adverse symptoms may include the following: irritation redness : No specific data.
Ingestion
Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Specific treatments Protection of first-aiders
: Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. : No specific treatment. : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
See toxicological information (Section 11)
Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing media
: Use an extinguishing agent suitable for the surrounding fire.
Unsuitable extinguishing media
: None known.
Specific hazards arising from the chemical Hazardous thermal decomposition products
Special protective actions for fire-fighters Special protective equipment for fire-fighters
: In a fire or if heated, a pressure increase will occur and the container may burst. : Decomposition products may include the following materials: carbon dioxide carbon monoxide : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency personnel
: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel". Environmental precautions
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up Date of issue/Date of revision
: 11/14/2014.
Date of previous issue
: No previous validation.
Version
: 0.01
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Section 6. Accidental release measures Small spill
Large spill
: Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. : Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
Section 7. Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general occupational hygiene
Conditions for safe storage, including any incompatibilities
: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. : Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.
Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits Ingredient name
Exposure limits
Diethanolamine
OSHA PEL 1989 (United States, 3/1989). TWA: 3 ppm 8 hours. TWA: 15 mg/m続 8 hours. NIOSH REL (United States, 10/2013). TWA: 3 ppm 10 hours. TWA: 15 mg/m続 10 hours. ACGIH TLV (United States, 6/2013). Absorbed through skin. TWA: 1 mg/m続 8 hours. Form: Inhalable fraction and vapor
Date of issue/Date of revision
: 11/14/2014.
Date of previous issue
: No previous validation.
Version
: 0.01
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Section 8. Exposure controls/personal protection Appropriate engineering controls Environmental exposure controls
: If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures Hygiene measures
Eye/face protection
: Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with sideshields.
Skin protection Hand protection
Body protection
Other skin protection
Respiratory protection
: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Section 9. Physical and chemical properties Appearance Physical state Color Odor Odor threshold pH
: Liquid : Light Yellow : Citrus : Not available
Melting point
: 9.7 to 10.7 : 0°C (32°F)
Boiling point
: 100°C (212°F)
Flash point
: Closed cup: >98.89°C (>210°F) [No sustained combustion under required test conditions listed in DOT 173.120(3).] : Not available : Not available
Evaporation rate Flammability (solid, gas) Date of issue/Date of revision
: 11/14/2014.
Date of previous issue
: No previous validation.
Version
: 0.01
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Section 9. Physical and chemical properties Lower and upper explosive (flammable) limits
: Not available
Vapor pressure
: <4 kPa (<30 mm Hg) [room temperature]
Vapor density Specific gravity
: <1 [Air = 1] : 1 g/cm続
Solubility
: Not available
Partition coefficient: noctanol/water
: Not available
Auto-ignition temperature
: Not available
Viscosity
: Not available
VOC content
: 1.4%
VOCs are calculated following the requirements under 40 CFR, Part 59, Subpart C for Consumer Products and Subpart D for Architectural Coatings.
Section 10. Stability and reactivity Reactivity
: No specific test data related to reactivity available for this product or its ingredients.
Chemical stability
: The product is stable.
Possibility of hazardous reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid
: No specific data.
Incompatible materials
: No specific data.
Hazardous decomposition products
: Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Section 11. Toxicological information Information on toxicological effects Acute toxicity Product/ingredient name
Result
Species
Coconut oil diethanolamide
LD50 Dermal LD50 Oral LD50 Dermal LD50 Oral LD50 Dermal LD50 Oral
Rabbit Rat Rabbit Rat Rabbit Rat
d-Limonene Diethanolamine
Dose
Exposure
12200 mg/kg 1600 mg/kg >5000 mg/kg 4400 mg/kg 12200 mg/kg 710 mg/kg
-
Irritation/Corrosion
Date of issue/Date of revision
: 11/14/2014.
Date of previous issue
: No previous validation.
Version
: 0.01
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Section 11. Toxicological information Product/ingredient name
Result
Species
Score
Exposure
Observation
Coconut oil diethanolamide
Eyes - Severe irritant
Rabbit
-
-
Skin - Moderate irritant
Rabbit
-
d-Limonene
Skin - Mild irritant
Rabbit
-
Diethanolamine
Eyes - Severe irritant
Rabbit
-
Eyes - Severe irritant
Rabbit
-
Skin - Mild irritant
Rabbit
-
Skin - Mild irritant
Rabbit
-
100 microliters 300 microliters 24 hours 10 Percent 24 hours 750 Micrograms 5500 milligrams 24 hours 500 milligrams 50 milligrams
-
Sensitization Not available. Mutagenicity Not available. Carcinogenicity Not available. Classification Product/ingredient name
OSHA
IARC
NTP
Coconut oil diethanolamide d-Limonene Diethanolamine
-
2B 3 2B
-
Reproductive toxicity Not available. Teratogenicity Not available. Specific target organ toxicity (single exposure) Not available. Specific target organ toxicity (repeated exposure) Not available. Aspiration hazard Name
Result
d-Limonene
ASPIRATION HAZARD - Category 1
Information on the likely routes of exposure
: Not available
Potential acute health effects Eye contact : No known significant effects or critical hazards. Inhalation Skin contact Ingestion
Date of issue/Date of revision
: No known significant effects or critical hazards. : May cause an allergic skin reaction. : No known significant effects or critical hazards.
: 11/14/2014.
Date of previous issue
: No previous validation.
Version
: 0.01
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Section 11. Toxicological information Symptoms related to the physical, chemical and toxicological characteristics Eye contact : No specific data. Inhalation
: No specific data.
Skin contact
: Adverse symptoms may include the following: irritation redness : No specific data.
Ingestion
Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate : Not available effects Potential delayed effects Long term exposure Potential immediate effects Potential delayed effects
: Not available : Not available : Not available
Potential chronic health effects Not available. General
Mutagenicity
: Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. : No known significant effects or critical hazards.
Teratogenicity
: No known significant effects or critical hazards.
Developmental effects
: No known significant effects or critical hazards.
Fertility effects
: No known significant effects or critical hazards.
Carcinogenicity
Numerical measures of toxicity Acute toxicity estimates Route
ATE value
Oral
96383.4 mg/kg
Section 12. Ecological information Toxicity Product/ingredient name
Result
Species
Exposure
d-Limonene
Acute EC50 421 µg/l Fresh water Acute EC50 688 µg/l Fresh water
48 hours 96 hours
Diethanolamine
Acute EC50 12 mg/l Fresh water
Daphnia - Daphnia magna Fish - Pimephales promelas Juvenile (Fledgling, Hatchling, Weanling) Algae - Pseudokirchneriella subcapitata Crustaceans - Ceriodaphnia dubia - Neonate Daphnia - Daphnia pulex Fish - Pimephales promelas -
Acute LC50 28800 µg/l Fresh water Acute LC50 2150 µg/l Fresh water Acute LC50 100 mg/l Fresh water Date of issue/Date of revision
: 11/14/2014.
Date of previous issue
: No previous validation.
Version
96 hours 48 hours 48 hours 96 hours : 0.01
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Section 12. Ecological information Juvenile (Fledgling, Hatchling, Weanling) Persistence and degradability Not available. Bioaccumulative potential Product/ingredient name
LogPow
BCF
Potential
d-Limonene Diethanolamine
4.38 -1.43
1022 -
high low
Mobility in soil Soil/water partition coefficient (KOC)
: Not available
Other adverse effects
: No known significant effects or critical hazards.
Section 13. Disposal considerations Disposal methods
: The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Section 14. Transport information DOT Classification
IMDG
IATA
UN number
Not regulated
Not regulated
Not regulated
UN proper shipping name
-
-
-
Transport hazard class(es)
-
-
-
Packing group
-
-
-
Environmental hazards
No.
No.
No.
Additional information
-
-
-
Date of issue/Date of revision
: 11/14/2014.
Date of previous issue
: No previous validation.
Version
: 0.01
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Section 14. Transport information Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
: Not available.
Section 15. Regulatory information U.S. Federal regulations
: United States inventory (TSCA 8b): All components are listed or exempted.
Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs)
: Not listed
SARA 311/312 Classification
: Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients Name
%
Fire Sudden hazard release of pressure
Reactive
Immediate (acute) health hazard
Delayed (chronic) health hazard
Coconut oil diethanolamide d-Limonene Diethanolamine
1-5 0-1 0-1
No. Yes. No.
No. No. No.
Yes. Yes. Yes.
Yes. No. Yes.
No. No. No.
State regulations California Prop. 65 WARNING: This product contains a chemical known to the State of California to cause cancer. Ingredient name
Cancer
Reproductive
No significant risk level
Maximum acceptable dosage level
Coconut oil diethanolamide Diethanolamine
Yes. Yes.
No. No.
No. No.
No. No.
International regulations Canada inventory
: All components are listed or exempted.
Section 16. Other information Hazardous Material Information System (U.S.A.) Health
*
2
Flammability
0
Physical hazards
0
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. Date of issue/Date of revision
: 11/14/2014.
Date of previous issue
: No previous validation.
Version
: 0.01
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Section 16. Other information The customer is responsible for determining the PPE code for this material. National Fire Protection Association (U.S.A.) Flammability
0 Health
2
0
Instability/Reactivity Special
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright Š1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright Š2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. History Date of printing
: 11/14/2014.
Date of issue/Date of revision Date of previous issue
: 11/14/2014.
Key to abbreviations
References
: No previous validation. : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations : Not available
Indicates information that has changed from previously issued version. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Date of issue/Date of revision
: 11/14/2014.
Date of previous issue
: No previous validation.
Version
: 0.01
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11/11
Safety Data Sheet Issue Date: 01-Oct-2002
Revision Date: 13-May-2015
Version 1
1. IDENTIFICATION Product Identifier Product Name
Quickso
Other means of identification SDS #
POZ-026
Recommended use of the chemical and restrictions on use Recommended Use Neutral concentrated detergent. Details of the supplier of the safety data sheet Manufacturer Address Pur-O-Zone, Inc. 345 N. Iowa Street Lawrence, KS 66044 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr)
1-785-843-0771 1-800-535-5053
2. HAZARDS IDENTIFICATION Appearance Red liquid
Physical State Liquid
Odor Fresh fragrance
Classification Serious eye damage/eye irritation
Category 1
Signal Word Danger Hazard Statements Causes serious eye damage
Precautionary Statements - Prevention Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a poison center or doctor/physician
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_____________________________________________________________________________________________ Other Hazards Harmful to aquatic life with long lasting effects
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Tetrasodium EDTA
CAS No 64-02-8
Weight-% <5
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**
4. FIRST-AID MEASURES First Aid Measures Eye Contact
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician.
Skin Contact
Wash off immediately with plenty of water for at least 15 minutes.
Inhalation
Remove to fresh air.
Ingestion
Clean mouth with water and drink afterwards plenty of water.
Most important symptoms and effects Symptoms
Causes serious eye damage.
Indication of any immediate medical attention and special treatment needed Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions
Use personal protective equipment as required.
Environmental Precautions
See Section 12 for additional Ecological Information.
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_____________________________________________________________________________________________ Methods and material for containment and cleaning up Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up
Collect and reuse if possible, absorb with inert material (sand, sawdust, etc.), or flush to sewer with large quantity of water if permitted by all local, state and federal regulations.
7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice. Wear protective gloves/protective clothing and eye/face protection.
Conditions for safe storage, including any incompatibilities Storage Conditions
Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible Materials
None known based on information supplied.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines
This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies
Appropriate engineering controls Engineering Controls
Showers. Eyewash stations. Ventilation systems.
Individual protection measures, such as personal protective equipment Eye/Face Protection
Use safety glasses or goggles.
Skin and Body Protection
Rubber gloves. Rubber apron.
Respiratory Protection
Ensure adequate ventilation, especially in confined areas.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Appearance Color
Liquid Red liquid Red
Property pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure
Values Not determined Not available 100 °C / 212 °F Non flammable aqueous solution >1 Liquid-Not applicable Not available Not available Not established
Odor Odor Threshold
Fresh fragrance Not determined
Remarks • Method
(Water = 1)
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_____________________________________________________________________________________________ Vapor Density Specific Gravity Water Solubility Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties
Not established 1.0506 Completely soluble Not determined Not determined Not determined Not determined Not determined Not determined Not determined Not determined
(Water = 1)
10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization
Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to Avoid Keep out of reach of children. Incompatible Materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied.
11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact
Causes serious eye damage.
Skin Contact
Avoid contact with skin.
Inhalation
Do not inhale.
Ingestion
Do not ingest.
Component Information Chemical Name Tetrasodium EDTA 64-02-8 nonylphenol ethoxylate 9016-45-9
Oral LD50 Dermal LD50 = 1658 mg/kg ( Rat ) = 10 g/kg ( Rat ) = 2590 mg/kg ( Rat ) = 1310 mg/kg = 1780 ÂľL/kg ( Rabbit ) = 2 mL/kg ( ( Rat ) Rabbit )
Inhalation LC50 -
Information on physical, chemical and toxicological effects Symptoms
Please see section 4 of this SDS for symptoms.
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_____________________________________________________________________________________________ Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity
Based on the information provided, this product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP.
Numerical measures of toxicity Not determined
12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life with long lasting effects. Component Information Chemical Name
Algae/aquatic plants
Fish
Tetrasodium EDTA 64-02-8
1.01: 72 h Desmodesmus subspicatus mg/L EC50
41: 96 h Lepomis macrochirus mg/L LC50 static 59.8: 96 h Pimephales promelas mg/L LC50 static
Toxicity to microorganisms
Crustacea 610: 24 h Daphnia magna mg/L EC50
Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Not determined Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
14. TRANSPORT INFORMATION Note
Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.
DOT
Not regulated
IATA
Not regulated
IMDG
_____________________________________________________________________________________________ Page 5 / 7
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_____________________________________________________________________________________________ Marine Pollutant
This material may meet the definition of a marine pollutant
15. REGULATORY INFORMATION International Inventories
Chemical Name Tetrasodium EDTA
TSCA Present
DSL X
NDSL
EINECS Present
ELINCS
ENCS Present
IECSC X
KECL Present
PICCS X
AICS X
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations This product does not contain any substances regulated under applicable state right-to-know regulations
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_____________________________________________________________________________________________
16. OTHER INFORMATION
NFPA HMIS Issue Date: Revision Date: Revision Note:
Health Hazards Not determined Health Hazards 1
Flammability Not determined Flammability 0
Instability Not determined Physical Hazards 0
Special Hazards Not determined Personal Protection Not determined
01-Oct-2002 13-May-2015 New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet
_____________________________________________________________________________________________ Page 7 / 7
Safety Data Sheet Issue Date: 01-Oct-2002
Revision Date: 13-May-2015
Version 1
1. IDENTIFICATION Product Identifier Product Name
RX-2050
Other means of identification SDS #
POZ-014
Recommended use of the chemical and restrictions on use Recommended Use Cleaner/Degreaser. Details of the supplier of the safety data sheet Manufacturer Address Pur-O-Zone, Inc. 345 N. Iowa Street Lawrence, KS 66044 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr)
1-785-843-0771 1-800-535-5053
2. HAZARDS IDENTIFICATION Appearance Blue liquid
Physical State Liquid
Odor Fresh scent
Classification Skin corrosion/irritation Serious eye damage/eye irritation
Category 2 Category 2
Signal Word Warning Hazard Statements Causes skin irritation Causes serious eye irritation
Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention
_____________________________________________________________________________________________ Page 1 / 8
Revision Date: 13-May-2015
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_____________________________________________________________________________________________ IF ON SKIN: Wash with plenty of soap and water Take off contaminated clothing and wash it before reuse If skin irritation occurs: Get medical advice/attention
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Ethylene Glycol Monobutyl Ether Sodium carbonate Monoethanolamine Sodium pyrophosphate
CAS No 111-76-2 497-19-8 141-43-5 7722-88-5
Weight-% <5 <5 <5 <5
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**
4. FIRST-AID MEASURES First Aid Measures Eye Contact
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Skin Contact
Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention.
Inhalation
Remove to fresh air.
Ingestion
Drink two to three large glasses of water. Do not induce vomiting. Call a physician.
Most important symptoms and effects Symptoms
Causes skin irritation. Causes serious eye irritation.
Indication of any immediate medical attention and special treatment needed Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
_____________________________________________________________________________________________ Page 2 / 8
Revision Date: 13-May-2015
POZ-014 - RX-2050
_____________________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures Personal Precautions
Use personal protective equipment as required.
Environmental Precautions
See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up
Collect and reuse if possible, absorb with inert material (sand, sawdust, etc.), or flush to sewer with large quantity of water if permitted by all local, state and federal regulations.
7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice. Wash face, hands, and any exposed skin thoroughly after handling. Wear protective gloves/protective clothing and eye/face protection.
Conditions for safe storage, including any incompatibilities Storage Conditions
Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible Materials
Strong acids. Strong oxidizers.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name Ethylene Glycol Monobutyl Ether 111-76-2
ACGIH TLV TWA: 20 ppm
Monoethanolamine 141-43-5
STEL: 6 ppm TWA: 3 ppm
Sodium pyrophosphate 7722-88-5 Sodium metasilicate 6834-92-0
-
OSHA PEL TWA: 50 ppm TWA: 240 mg/m3 (vacated) TWA: 25 ppm (vacated) TWA: 120 mg/m3 (vacated) S* S* TWA: 3 ppm TWA: 6 mg/m3 (vacated) TWA: 3 ppm (vacated) TWA: 8 mg/m3 (vacated) STEL: 6 ppm (vacated) STEL: 15 mg/m3 (vacated) TWA: 5 mg/m3
2 mg/m3
2 mg/m3
NIOSH IDLH IDLH: 700 ppm TWA: 5 ppm TWA: 24 mg/m3
IDLH: 30 ppm TWA: 3 ppm TWA: 8 mg/m3 STEL: 6 ppm STEL: 15 mg/m3 TWA: 5 mg/m3 -
Appropriate engineering controls Engineering Controls
Showers. Eyewash stations. Ventilation systems.
Individual protection measures, such as personal protective equipment Eye/Face Protection
Chemical splash goggles.
Skin and Body Protection
Rubber gloves. Full cover clothing. Rubber apron.
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_____________________________________________________________________________________________ Respiratory Protection
None normally required with adequate room ventilation.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Appearance Color
Liquid Blue liquid Blue
Property pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties
Values Not determined Not available 100 °C / 212 °F Non-flammable aqueous solution >1 Liquid-Not applicable Not available Not available <30 <1 1.048 Completely soluble Not determined Not determined Not determined Not determined Not determined Not determined Not determined Not determined
Odor Odor Threshold
Fresh scent Not determined
Remarks • Method
(Water = 1)
10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization
Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to Avoid Keep out of reach of children. Incompatible Materials Strong acids. Strong oxidizers. Hazardous Decomposition Products None known based on information supplied.
11. TOXICOLOGICAL INFORMATION _____________________________________________________________________________________________ Page 4 / 8
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POZ-014 - RX-2050
_____________________________________________________________________________________________ Information on likely routes of exposure Product Information Eye Contact
Causes serious eye irritation.
Skin Contact
Causes skin irritation.
Inhalation
Do not inhale.
Ingestion
Do not ingest.
Component Information Chemical Name Nonylphenol Ethoxylate 127087-87-0 Ethylene Glycol Monobutyl Ether 111-76-2 Sodium carbonate 497-19-8 Monoethanolamine 141-43-5 Sodium pyrophosphate 7722-88-5 Sodium metasilicate 6834-92-0 Sodium xylenesulfonate 1300-72-7 Tetrasodium EDTA 64-02-8
Oral LD50 = 1310 mg/kg ( Rat )
Dermal LD50 -
Inhalation LC50 -
= 470 mg/kg ( Rat )
= 99 mg/kg ( Rabbit )
= 450 ppm ( Rat ) 4 h
= 4090 mg/kg ( Rat )
-
= 2300 mg/m3 ( Rat ) 2 h
= 1720 mg/kg ( Rat )
-
1000 - 3000 mg/kg ( Rat )
= 1 mL/kg ( Rabbit ) = 1000 mg/kg ( Rabbit ) -
= 600 mg/kg ( Rat )
-
-
= 1000 mg/kg ( Rat )
-
-
= 1658 mg/kg ( Rat ) = 10 g/kg ( Rat )
-
-
-
Information on physical, chemical and toxicological effects Symptoms
Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity Chemical Name Ethylene Glycol Monobutyl Ether 111-76-2 Legend
Group 3 IARC components are "not classifiable as human carcinogens". ACGIH A3
IARC Group 3
NTP
OSHA
ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 3 IARC components are "not classifiable as human carcinogens"
Numerical measures of toxicity Not determined
12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information
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_____________________________________________________________________________________________ Chemical Name
Algae/aquatic plants
Ethylene Glycol Monobutyl Ether 111-76-2
Fish
1490: 96 h Lepomis macrochirus mg/L LC50 static 2950: 96 h Lepomis macrochirus mg/L LC50 242: 120 h Nitzschia mg/L 300: 96 h Lepomis EC50 macrochirus mg/L LC50 static 310 - 1220: 96 h Pimephales promelas mg/L LC50 static 15: 72 h Desmodesmus 200: 96 h Oncorhynchus subspicatus mg/L EC50 mykiss mg/L LC50 flowthrough 114 - 196: 96 h Oncorhynchus mykiss mg/L LC50 static 3684: 96 h Brachydanio rerio mg/L LC50 static 300 - 1000: 96 h Lepomis macrochirus mg/L LC50 static 227: 96 h Pimephales promelas mg/L LC50 flow-through 210: 96 h Brachydanio rerio mg/L LC50 semi-static 210: 96 h Brachydanio rerio mg/L LC50 1.01: 72 h Desmodesmus 41: 96 h Lepomis subspicatus mg/L EC50 macrochirus mg/L LC50 static 59.8: 96 h Pimephales promelas mg/L LC50 static
Sodium carbonate 497-19-8
Monoethanolamine 141-43-5
Sodium metasilicate 6834-92-0 Tetrasodium EDTA 64-02-8
Toxicity to microorganisms
Crustacea
1000: 48 h Daphnia magna mg/L EC50 1698 - 1940: 24 h Daphnia magna mg/L EC50 265: 48 h Daphnia magna mg/L EC50
65: 48 h Daphnia magna mg/L EC50
216: 96 h Daphnia magna mg/L EC50 610: 24 h Daphnia magna mg/L EC50
Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Chemical Name Ethylene Glycol Monobutyl Ether 111-76-2 Monoethanolamine 141-43-5
Partition Coefficient 0.81 -1.91
Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
California Hazardous Waste Status Chemical Name
California Hazardous Waste Status
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POZ-014 - RX-2050
_____________________________________________________________________________________________ Sodium carbonate 497-19-8
Corrosive
14. TRANSPORT INFORMATION Note
Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.
DOT
Not regulated
IATA
Not regulated
IMDG
Not regulated
15. REGULATORY INFORMATION International Inventories
Chemical Name Ethylene Glycol Monobutyl Ether Sodium carbonate Monoethanolamine
TSCA Present
DSL X
NDSL
EINECS Present
Present Present
X X
Present Present
Sodium pyrophosphate
Present
X
Present
ELINCS
ENCS Present
IECSC X
KECL Present
PICCS X
AICS X
Present Present
X X
Present Present
X X
X X
X
Present
X
X
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name
CAS No
Weight-%
Ethylene Glycol Monobutyl Ether - 111-76-2
111-76-2
<5
SARA 313 - Threshold Values % 1.0
CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)
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_____________________________________________________________________________________________ US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name Ethylene Glycol Monobutyl Ether 111-76-2 Monoethanolamine 141-43-5 Sodium pyrophosphate 7722-88-5
New Jersey X
Massachusetts X
Pennsylvania X
X
X
X
X
X
X
16. OTHER INFORMATION NFPA HMIS Issue Date: Revision Date: Revision Note:
Health Hazards Not determined Health Hazards 2
Flammability Not determined Flammability 0
Instability Not determined Physical Hazards 0
Special Hazards Not determined Personal Protection Not determined
01-Oct-2002 13-May-2015 New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet
_____________________________________________________________________________________________ Page 8 / 8
Safety Data Sheet Issue Date: 01-May-2002
Revision Date: 13-May-2015
Version 1
1. IDENTIFICATION Product Identifier Product Name
Sani-Sorb
Other means of identification SDS #
POZ-015
Recommended use of the chemical and restrictions on use Recommended Use Vomit absorbent. Details of the supplier of the safety data sheet Manufacturer Address Pur-O-Zone, Inc. 345 N. Iowa Street Lawrence, KS 66044 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr)
1-785-843-0771 1-800-535-5053
2. HAZARDS IDENTIFICATION Appearance Coarse, gray, granular
Physical State Solid
Odor Floral
Classification Acute toxicity - Oral Skin corrosion/irritation Serious eye damage/eye irritation
Category 4 Category 2 Category 1
Signal Word Danger Hazard Statements Harmful if swallowed Causes skin irritation Causes serious eye damage
Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Wear protective gloves/protective clothing/eye protection/face protection
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_____________________________________________________________________________________________ Precautionary Statements - Response
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a poison center or doctor/physician IF ON SKIN: Wash with plenty of soap and water Take off contaminated clothing and wash it before reuse If skin irritation occurs: Get medical advice/attention IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Didecyldimethylammonium chloride Alkyl dimethyl benzyl ammonium chloride (C12-16) Ethyl Alcohol
CAS No 7173-51-5 68424-85-1 64-17-5
Weight-% <5 <5 <1
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**
4. FIRST-AID MEASURES First Aid Measures Eye Contact
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician.
Skin Contact
Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention.
Inhalation
Remove to fresh air.
Ingestion
Call a poison center or doctor/physician if you feel unwell. Rinse mouth.
Most important symptoms and effects Symptoms
Harmful if swallowed. Causes skin irritation. Causes serious eye damage.
Indication of any immediate medical attention and special treatment needed Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined.
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_____________________________________________________________________________________________ Specific Hazards Arising from the Chemical Not determined.
Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions
Use personal protective equipment as required.
Environmental Precautions
See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up
Collect and reuse if possible. Sweep up excess. Flush remainder to sewer with large quantity of water as permitted by all local, state and federal regulations.
7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice. Wash face, hands, and any exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing and eye/face protection.
Conditions for safe storage, including any incompatibilities Storage Conditions
Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible Materials
None known based on information supplied.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name Ethyl Alcohol 64-17-5
ACGIH TLV STEL: 1000 ppm
OSHA PEL TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3
NIOSH IDLH IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3
Appropriate engineering controls Engineering Controls
Showers. Eyewash stations. Ventilation systems.
Individual protection measures, such as personal protective equipment Eye/Face Protection
Face shield or goggles.
Skin and Body Protection
Rubber gloves. Full cover clothing.
Respiratory Protection
None normally required with adequate room ventilation.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
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_____________________________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Appearance Color
Solid Coarse, gray, granular Gray
Property pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties
Values Not determined Not available Not available Non-flammable Not available Not determined Not available Not available Not available Not available Not available Non-soluble Not determined Not determined Not determined Not determined Not determined Not determined Not determined Not determined
Odor Odor Threshold
Floral Not determined
Remarks â&#x20AC;˘ Method
10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization
Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to Avoid Keep out of reach of children. Incompatible Materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied.
11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information
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_____________________________________________________________________________________________ Eye Contact
Causes serious eye damage.
Skin Contact
Causes skin irritation.
Inhalation
Do not inhale.
Ingestion
Harmful if swallowed.
Component Information Chemical Name Didecyldimethylammonium chloride 7173-51-5 Alkyl dimethyl benzyl ammonium chloride (C12-16) 68424-85-1 Ethyl Alcohol 64-17-5
Oral LD50 = 84 mg/kg ( Rat )
Dermal LD50 -
Inhalation LC50 -
= 426 mg/kg ( Rat )
-
-
= 7060 mg/kg ( Rat )
-
= 124.7 mg/L ( Rat ) 4 h
Information on physical, chemical and toxicological effects Symptoms
Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity
Ethanol has been shown to be carcinogenic in long-term studies only when consumed as an alcoholic beverage.
Chemical Name Ethyl Alcohol 64-17-5 Legend
ACGIH A3
IARC Group 1
NTP Known
OSHA X
ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present
Numerical measures of toxicity Not determined
12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information Chemical Name Ethyl Alcohol 64-17-5
Algae/aquatic plants
Fish
Toxicity to Crustacea microorganisms 12.0 - 16.0: 96 h EC50 = 34634 mg/L 30 min 9268 - 14221: 48 h Daphnia Oncorhynchus mykiss mL/L EC50 = 35470 mg/L 5 min magna mg/L LC50 2: 48 h LC50 static 13400 - 15100: Daphnia magna mg/L EC50 96 h Pimephales promelas Static 10800: 24 h Daphnia mg/L LC50 flow-through 100: magna mg/L EC50 96 h Pimephales promelas mg/L LC50 static
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_____________________________________________________________________________________________ Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Chemical Name Ethyl Alcohol 64-17-5
Partition Coefficient -0.32
Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
California Hazardous Waste Status Chemical Name Ethyl Alcohol 64-17-5
California Hazardous Waste Status Toxic Ignitable
14. TRANSPORT INFORMATION Note
Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.
DOT
Not regulated
IATA
Not regulated
IMDG
Not regulated
15. REGULATORY INFORMATION International Inventories
Chemical Name TSCA Didecyldimethylammonium Present chloride Alkyl dimethyl benzyl Present ammonium chloride (C12-16) Ethyl Alcohol Present
DSL X
NDSL
EINECS Present
ELINCS
ENCS Present
IECSC X
KECL Present
PICCS X
AICS X
X
Present
Present
X
Present
X
X
X
Present
Present
X
Present
X
X
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Revision Date: 13-May-2015
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_____________________________________________________________________________________________ Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals. Chemical Name Ethyl Alcohol - 64-17-5
California Proposition 65 Carcinogen Developmental
U.S. State Right-to-Know Regulations Chemical Name Ethyl Alcohol 64-17-5
New Jersey X
Massachusetts X
Pennsylvania X
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_____________________________________________________________________________________________
16. OTHER INFORMATION
NFPA HMIS Issue Date: Revision Date: Revision Note:
Health Hazards Not determined Health Hazards 1
Flammability Not determined Flammability 0
Instability Not determined Physical Hazards 0
Special Hazards Not determined Personal Protection Not determined
01-May-2002 13-May-2015 New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet
_____________________________________________________________________________________________ Page 8 / 8
Safety Data Sheet Issue Date: 01-Oct-2002
Revision Date: 13-May-2015
Version 1
1. IDENTIFICATION Product Identifier Product Name
Shyne
Other means of identification SDS #
POZ-016
Recommended use of the chemical and restrictions on use Recommended Use Concentrated liquid detergent. Details of the supplier of the safety data sheet Manufacturer Address Pur-O-Zone, Inc. 345 N. Iowa Street Lawrence, KS 66044 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr)
1-785-843-0771 1-800-535-5053
2. HAZARDS IDENTIFICATION Appearance Green liquid
Physical State Liquid
Odor Lime
Classification Carcinogenicity
Category 2
Signal Word Warning Hazard Statements Suspected of causing cancer
Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Precautionary Statements - Response If exposed or concerned: Get medical advice/attention Precautionary Statements - Storage Store locked up
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_____________________________________________________________________________________________ Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Ethyl Alcohol Diethanolamine
CAS No 64-17-5 111-42-2
Weight-% <5 <1
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**
4. FIRST-AID MEASURES First Aid Measures General Advice
If exposed or concerned: Get medical advice/attention.
Eye Contact
Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician.
Skin Contact
Wash off immediately with plenty of water for at least 15 minutes.
Inhalation
Remove to fresh air.
Ingestion
Drink gelatin solution, egg whites or two to three large glasses of water. Call a physician.
Most important symptoms and effects Symptoms
Suspected of causing cancer.
Indication of any immediate medical attention and special treatment needed Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures
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_____________________________________________________________________________________________ Personal Precautions
Use personal protective equipment as required.
Environmental Precautions
See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up
Collect and reuse if possible, absorb with inert material (sand, sawdust, etc.), or flush to sewer with large quantity of water if permitted by all local, state and federal regulations.
7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required.
Conditions for safe storage, including any incompatibilities Storage Conditions
Store locked up.
Incompatible Materials
None known based on information supplied.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name Ethyl Alcohol 64-17-5
ACGIH TLV STEL: 1000 ppm
Diethanolamine 111-42-2
TWA: 1 mg/m3 inhalable fraction and vapor S*
OSHA PEL TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 (vacated) TWA: 3 ppm (vacated) TWA: 15 mg/m3
NIOSH IDLH IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3 TWA: 3 ppm TWA: 15 mg/m3
Appropriate engineering controls Engineering Controls
Showers. Eyewash stations. Ventilation systems.
Individual protection measures, such as personal protective equipment Eye/Face Protection
Use safety glasses or goggles.
Skin and Body Protection
Rubber gloves. Rubber apron.
Respiratory Protection
None required.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Appearance
Liquid Green liquid
Odor
Lime
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_____________________________________________________________________________________________ Color
Green
Odor Threshold
Property pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties
Values Not determined Not available 96.1-100 °C / 205-212 °F None >1 Liquid-Not applicable Not available Not available Not established Not established 1.049 Completely soluble Not determined Not determined Not determined Not determined Not determined Not determined Not determined Not determined
Remarks • Method
Not determined
(Water = 1)
10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization
Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to Avoid Keep out of reach of children. Incompatible Materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied.
11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact
Avoid contact with eyes.
Skin Contact
Avoid contact with skin.
Inhalation
Do not inhale.
Ingestion
Do not ingest.
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POZ-016 - Shyne
_____________________________________________________________________________________________ Component Information Chemical Name Ethyl Alcohol 64-17-5 Diethanolamine 111-42-2
Oral LD50 = 7060 mg/kg ( Rat )
Dermal LD50 -
Inhalation LC50 = 124.7 mg/L ( Rat ) 4 h
= 620 ÂľL/kg ( Rat ) = 0.62 mL/kg ( Rat )
= 7640 ÂľL/kg ( Rabbit )
-
Information on physical, chemical and toxicological effects Symptoms
Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity
Suspected of causing cancer. Ethanol has been shown to be carcinogenic in long-term studies only when consumed as an alcoholic beverage.
Chemical Name Ethyl Alcohol 64-17-5 Diethanolamine 111-42-2 Legend
ACGIH A3
IARC Group 1
A3
Group 2B
NTP Known
OSHA X X
ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 2B - Possibly Carcinogenic to Humans NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present
Numerical measures of toxicity Not determined
12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information Chemical Name Ethyl Alcohol 64-17-5
Diethanolamine 111-42-2
Algae/aquatic plants
Fish
Toxicity to Crustacea microorganisms 12.0 - 16.0: 96 h EC50 = 34634 mg/L 30 min 9268 - 14221: 48 h Daphnia Oncorhynchus mykiss mL/L EC50 = 35470 mg/L 5 min magna mg/L LC50 2: 48 h LC50 static 13400 - 15100: Daphnia magna mg/L EC50 96 h Pimephales promelas Static 10800: 24 h Daphnia mg/L LC50 flow-through 100: magna mg/L EC50 96 h Pimephales promelas mg/L LC50 static 7.8: 72 h Desmodesmus 4460 - 4980: 96 h EC50 = 73 mg/L 5 min 55: 48 h Daphnia magna subspicatus mg/L EC50 2.1 - Pimephales promelas mg/L EC50 > 16 mg/L 16 h mg/L EC50 2.3: 96 h Pseudokirchneriella LC50 flow-through 1200 subcapitata mg/L EC50 1580: 96 h Pimephales promelas mg/L LC50 static 600 - 1000: 96 h Lepomis macrochirus mg/L LC50 static
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_____________________________________________________________________________________________ Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Chemical Name Ethyl Alcohol 64-17-5 Diethanolamine 111-42-2
Partition Coefficient -0.32 -2.18
Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
California Hazardous Waste Status Chemical Name Ethyl Alcohol 64-17-5
California Hazardous Waste Status Toxic Ignitable
14. TRANSPORT INFORMATION Note
Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.
DOT
Not regulated
IATA
Not regulated
IMDG
Not regulated
15. REGULATORY INFORMATION International Inventories
Chemical Name Ethyl Alcohol
TSCA Present
DSL X
Diethanolamine
Present
X
NDSL
EINECS Present
ELINCS
Present
ENCS Present
IECSC X
KECL Present
PICCS X
AICS X
Present
X
Present
X
X
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Revision Date: 13-May-2015
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_____________________________________________________________________________________________ Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations CERCLA Chemical Name Diethanolamine 111-42-2
Hazardous Substances RQs 100 lb
CERCLA/SARA RQ
Reportable Quantity (RQ) RQ 100 lb final RQ RQ 45.4 kg final RQ
SARA 313 Chemical Name
CAS No
Weight-%
Diethanolamine - 111-42-2
111-42-2
<1
SARA 313 - Threshold Values % 1.0
CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals. Chemical Name Ethyl Alcohol - 64-17-5
California Proposition 65 Carcinogen Developmental Carcinogen
Diethanolamine - 111-42-2
U.S. State Right-to-Know Regulations Chemical Name Ethyl Alcohol 64-17-5 Diethanolamine 111-42-2
New Jersey X
Massachusetts X
Pennsylvania X
X
X
X
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_____________________________________________________________________________________________
16. OTHER INFORMATION
NFPA HMIS Issue Date: Revision Date: Revision Note:
Health Hazards Not determined Health Hazards 1
Flammability Not determined Flammability 0
Instability Not determined Physical Hazards 0
Special Hazards Not determined Personal Protection Not determined
01-Oct-2002 13-May-2015 New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet
_____________________________________________________________________________________________ Page 8 / 8
Safety Data Sheet Issue Date: 01-Oct-2002
Revision Date: 13-May-2015
Version 1
1. IDENTIFICATION Product Identifier Product Name
Sic-Em
Other means of identification SDS #
POZ-017
Recommended use of the chemical and restrictions on use Recommended Use All purpose cleaner. Details of the supplier of the safety data sheet Manufacturer Address Pur-O-Zone, Inc. 345 N. Iowa Street Lawrence, KS 66044 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr)
1-785-843-0771 1-800-535-5053
2. HAZARDS IDENTIFICATION Appearance Blue liquid
Physical State Liquid
Odor Mild
Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Hazards Not Otherwise Classified (HNOC) Causes mild skin irritation
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Ethylene Glycol Monobutyl Ether
CAS No 111-76-2
Weight-% <5
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**
_____________________________________________________________________________________________ Page 1 / 8
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_____________________________________________________________________________________________
4. FIRST-AID MEASURES
First Aid Measures Eye Contact
Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician.
Skin Contact
Wash off immediately with plenty of water for at least 15 minutes.
Inhalation
Remove to fresh air.
Ingestion
Drink gelatin solution, egg whites or two to three large glasses of water. Call a physician.
Most important symptoms and effects Symptoms
Causes mild skin irritation.
Indication of any immediate medical attention and special treatment needed Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions
Use personal protective equipment as required.
Environmental Precautions
See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up
Collect and reuse if possible, absorb with inert material (sand, sawdust, etc.), or flush to sewer with large quantity of water if permitted by all local, state and federal regulations.
7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice.
Conditions for safe storage, including any incompatibilities
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POZ-017 - Sic-Em
_____________________________________________________________________________________________ Storage Conditions
Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible Materials
None known based on information supplied.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name Ethylene Glycol Monobutyl Ether 111-76-2
ACGIH TLV TWA: 20 ppm
Monoethanolamine 141-43-5
STEL: 6 ppm TWA: 3 ppm
Sodium pyrophosphate 7722-88-5 Sodium metasilicate 6834-92-0
-
OSHA PEL TWA: 50 ppm TWA: 240 mg/m3 (vacated) TWA: 25 ppm (vacated) TWA: 120 mg/m3 (vacated) S* S* TWA: 3 ppm TWA: 6 mg/m3 (vacated) TWA: 3 ppm (vacated) TWA: 8 mg/m3 (vacated) STEL: 6 ppm (vacated) STEL: 15 mg/m3 (vacated) TWA: 5 mg/m3
2 mg/m3
2 mg/m3
NIOSH IDLH IDLH: 700 ppm TWA: 5 ppm TWA: 24 mg/m3
IDLH: 30 ppm TWA: 3 ppm TWA: 8 mg/m3 STEL: 6 ppm STEL: 15 mg/m3 TWA: 5 mg/m3 -
Appropriate engineering controls Engineering Controls
Showers. Eyewash stations. Ventilation systems.
Individual protection measures, such as personal protective equipment Eye/Face Protection
Use safety glasses or goggles.
Skin and Body Protection
Rubber gloves. Rubber apron.
Respiratory Protection
Ensure adequate ventilation, especially in confined areas.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Appearance Color
Liquid Blue liquid Blue
Property pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility
Values Not determined Not available 100 °C / 212 °F None >1 Liquid-Not applicable Not available Not available Not established Not established 1.01 Completely soluble
Odor Odor Threshold
Mild Not determined
Remarks • Method
(Water = 1)
_____________________________________________________________________________________________ Page 3 / 8
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POZ-017 - Sic-Em
_____________________________________________________________________________________________ Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties
Not determined Not determined Not determined Not determined Not determined Not determined Not determined Not determined
10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization
Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to Avoid Keep out of reach of children. Incompatible Materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied.
11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact
Avoid contact with eyes.
Skin Contact
Causes mild skin irritation.
Inhalation
Do not inhale.
Ingestion
Do not ingest.
Component Information Chemical Name Nonylphenol Ethoxylate 127087-87-0 Ethylene Glycol Monobutyl Ether 111-76-2 Monoethanolamine 141-43-5 Sodium carbonate 497-19-8 Sodium pyrophosphate 7722-88-5 Sodium metasilicate 6834-92-0
Oral LD50 = 1310 mg/kg ( Rat )
Dermal LD50 -
Inhalation LC50 -
= 470 mg/kg ( Rat )
= 99 mg/kg ( Rabbit )
= 450 ppm ( Rat ) 4 h
= 1720 mg/kg ( Rat )
-
= 4090 mg/kg ( Rat )
= 1 mL/kg ( Rabbit ) = 1000 mg/kg ( Rabbit ) -
= 2300 mg/m3 ( Rat ) 2 h
1000 - 3000 mg/kg ( Rat )
-
-
= 600 mg/kg ( Rat )
-
-
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_____________________________________________________________________________________________ Tetrasodium EDTA 64-02-8
= 1658 mg/kg ( Rat ) = 10 g/kg ( Rat )
-
-
Information on physical, chemical and toxicological effects Symptoms
Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity
Group 3 IARC components are "not classifiable as human carcinogens".
Chemical Name Ethylene Glycol Monobutyl Ether 111-76-2 Legend
ACGIH A3
IARC Group 3
NTP
OSHA
ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 3 IARC components are "not classifiable as human carcinogens"
Numerical measures of toxicity Not determined
12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information Chemical Name Ethylene Glycol Monobutyl Ether 111-76-2 Monoethanolamine 141-43-5
Sodium carbonate 497-19-8
Sodium metasilicate 6834-92-0 Tetrasodium EDTA 64-02-8
Algae/aquatic plants
Fish
1490: 96 h Lepomis macrochirus mg/L LC50 static 2950: 96 h Lepomis macrochirus mg/L LC50 15: 72 h Desmodesmus 200: 96 h Oncorhynchus subspicatus mg/L EC50 mykiss mg/L LC50 flowthrough 114 - 196: 96 h Oncorhynchus mykiss mg/L LC50 static 3684: 96 h Brachydanio rerio mg/L LC50 static 300 - 1000: 96 h Lepomis macrochirus mg/L LC50 static 227: 96 h Pimephales promelas mg/L LC50 flow-through 242: 120 h Nitzschia mg/L 300: 96 h Lepomis EC50 macrochirus mg/L LC50 static 310 - 1220: 96 h Pimephales promelas mg/L LC50 static 210: 96 h Brachydanio rerio mg/L LC50 semi-static 210: 96 h Brachydanio rerio mg/L LC50 1.01: 72 h Desmodesmus 41: 96 h Lepomis subspicatus mg/L EC50 macrochirus mg/L LC50 static 59.8: 96 h Pimephales promelas mg/L LC50 static
Toxicity to microorganisms
Crustacea 1000: 48 h Daphnia magna mg/L EC50 1698 - 1940: 24 h Daphnia magna mg/L EC50 65: 48 h Daphnia magna mg/L EC50
265: 48 h Daphnia magna mg/L EC50
216: 96 h Daphnia magna mg/L EC50 610: 24 h Daphnia magna mg/L EC50
Persistence/Degradability Not determined.
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_____________________________________________________________________________________________ Bioaccumulation Not determined. Mobility Chemical Name Ethylene Glycol Monobutyl Ether 111-76-2 Monoethanolamine 141-43-5
Partition Coefficient 0.81 -1.91
Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
California Hazardous Waste Status Chemical Name Sodium carbonate 497-19-8
California Hazardous Waste Status Corrosive
14. TRANSPORT INFORMATION Note
Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.
DOT
Not regulated
IATA
Not regulated
IMDG
Not regulated
15. REGULATORY INFORMATION International Inventories
Chemical Name Ethylene Glycol Monobutyl Ether
TSCA Present
DSL X
NDSL
EINECS Present
ELINCS
ENCS Present
IECSC X
KECL Present
PICCS X
AICS X
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
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_____________________________________________________________________________________________ DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 313 Chemical Name
CAS No
Weight-%
Ethylene Glycol Monobutyl Ether - 111-76-2
111-76-2
<5
SARA 313 - Threshold Values % 1.0
CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name Ethylene Glycol Monobutyl Ether 111-76-2 Monoethanolamine 141-43-5 Sodium pyrophosphate 7722-88-5
New Jersey X
Massachusetts X
Pennsylvania X
X
X
X
X
X
X
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_____________________________________________________________________________________________
16. OTHER INFORMATION
NFPA HMIS Issue Date: Revision Date: Revision Note:
Health Hazards Not determined Health Hazards 1
Flammability Not determined Flammability 0
Instability Not determined Physical Hazards 0
Special Hazards Not determined Personal Protection Not determined
01-Oct-2002 13-May-2015 New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet
_____________________________________________________________________________________________ Page 8 / 8
Safety Data Sheet Issue Date: 01-Oct-2002
Revision Date: 13-May-2015
Version 1
1. IDENTIFICATION Product Identifier Product Name
Sodium Hypochlorite Solution
Other means of identification SDS #
POZ-003
UN/ID No
UN1791
Recommended use of the chemical and restrictions on use Recommended Use Cleaning agent. Details of the supplier of the safety data sheet Manufacturer Address Pur-O-Zone, Inc. 345 N. Iowa Street Lawrence, KS 66044 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr)
1-785-843-0771 1-800-535-5053
2. HAZARDS IDENTIFICATION Appearance Yellowish / Green liquid
Physical State Liquid
Odor Chlorine
Classification Skin corrosion/irritation Serious eye damage/eye irritation
Category 1 Sub-category B Category 1
Signal Word Danger Hazard Statements Causes severe skin burns and eye damage
Precautionary Statements - Prevention Do not breathe dust/fume/gas/mist/vapors/spray Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response Immediately call a poison center or doctor/physician
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_____________________________________________________________________________________________ IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a poison center or doctor/physician IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately call a poison center or doctor/physician IF SWALLOWED: Rinse mouth. Do NOT induce vomiting Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Other Hazards Very toxic to aquatic life with long lasting effects
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Sodium hypochlorite Caustic Soda
CAS No 7681-52-9 1310-73-2
Weight-% 10-20 <5
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**
4. FIRST-AID MEASURES First Aid Measures General Advice
Immediately call a poison center or doctor/physician.
Eye Contact
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician.
Skin Contact
Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse.
Inhalation
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a poison center or doctor/physician.
Ingestion
Rinse mouth. Do not induce vomiting.
Most important symptoms and effects Symptoms
Causes severe skin burns and eye damage.
Indication of any immediate medical attention and special treatment needed Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Water. Carbon dioxide (CO2). Foam. Dry chemical.
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_____________________________________________________________________________________________ Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Hazardous Combustion Products Chlorine gas. Hydrogen chloride. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions
Use personal protective equipment as required.
Methods and material for containment and cleaning up Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up
Collect and reuse if possible, absorb with inert material (sand, sawdust, etc.), or flush to sewer with large quantity of water if permitted by all local, state and federal regulations.
7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice. Do not breathe dust/fume/gas/mist/vapors/spray. Wash face, hands, and any exposed skin thoroughly after handling. Wear protective gloves/protective clothing and eye/face protection.
Conditions for safe storage, including any incompatibilities Storage Conditions
Store locked up.
Incompatible Materials
Oxidizable organic materials. Ammonia. Urea. Acids. Inorganic reducing compounds.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name Caustic Soda 1310-73-2
ACGIH TLV Ceiling: 2 mg/m3
OSHA PEL TWA: 2 mg/m3 (vacated) Ceiling: 2 mg/m3
NIOSH IDLH IDLH: 10 mg/m3 Ceiling: 2 mg/m3
Appropriate engineering controls Engineering Controls
Showers. Eyewash stations. Ventilation systems.
Individual protection measures, such as personal protective equipment Eye/Face Protection
Face shield or goggles.
Skin and Body Protection
Rubber gloves. Rubber apron.
Respiratory Protection
None normally required with adequate room ventilation.
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_____________________________________________________________________________________________ General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Appearance Color
Liquid Yellowish / Green liquid Yellowish/green
Property pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties
Values Not determined Not available 100 °C / 212 °F Non-flammable aqueous solution <1 Liquid-Not applicable Not available Not available Not established Not established 1.15 Completely soluble Not determined Not determined Not determined Not determined Not determined Not determined Not determined Not determined
Odor Odor Threshold
Chlorine Not determined
Remarks • Method
(Water = 1)
(Water = 1)
10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization
Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to Avoid Incompatible Materials. Incompatible Materials Oxidizable organic materials. Ammonia. Urea. Acids. Inorganic reducing compounds. Hazardous Decomposition Products Chlorine gas. Hydrogen chloride.
11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure
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_____________________________________________________________________________________________ Product Information Eye Contact
Causes severe eye damage.
Skin Contact
Causes severe skin burns.
Inhalation
Do not inhale.
Ingestion
Do not ingest.
Component Information Chemical Name Sodium hypochlorite 7681-52-9 Caustic Soda 1310-73-2
Oral LD50 = 8200 mg/kg ( Rat )
Dermal LD50 > 10000 mg/kg ( Rabbit )
Inhalation LC50 -
-
= 1350 mg/kg ( Rabbit )
-
Information on physical, chemical and toxicological effects Symptoms
Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity
Group 3 IARC components are "not classifiable as human carcinogens".
Chemical Name Sodium hypochlorite 7681-52-9 Legend
ACGIH
IARC Group 3
NTP
OSHA
Toxicity to microorganisms
Crustacea
IARC (International Agency for Research on Cancer) Group 3 IARC components are "not classifiable as human carcinogens"
Numerical measures of toxicity Not determined
12. ECOLOGICAL INFORMATION Ecotoxicity Very toxic to aquatic life with long lasting effects. Component Information Chemical Name
Algae/aquatic plants
Fish
Sodium hypochlorite 7681-52-9
0.095: 24 h Skeletonema costatum mg/L EC50
0.06 - 0.11: 96 h Pimephales promelas mg/L LC50 flowthrough 4.5 - 7.6: 96 h Pimephales promelas mg/L LC50 static 0.4 - 0.8: 96 h Lepomis macrochirus mg/L LC50 static 0.28 - 1: 96 h Lepomis macrochirus mg/L LC50 flow-through 0.05 0.771: 96 h Oncorhynchus mykiss mg/L LC50 flowthrough 0.03 - 0.19: 96 h Oncorhynchus mykiss mg/L LC50 semi-static 0.18 - 0.22: 96 h Oncorhynchus mykiss mg/L LC50 static 45.4: 96 h Oncorhynchus mykiss mg/L LC50 static
Caustic Soda 1310-73-2
0.033 - 0.044: 48 h Daphnia magna mg/L EC50 Static 2.1: 96 h Daphnia magna mg/L EC50
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_____________________________________________________________________________________________ Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Not determined Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
California Hazardous Waste Status Chemical Name Caustic Soda 1310-73-2
California Hazardous Waste Status Toxic Corrosive
14. TRANSPORT INFORMATION Note
Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.
DOT UN/ID No Proper Shipping Name Hazard Class Packing Group
UN1791 Hypochlorite solutions 8 II
IATA UN/ID No Proper Shipping Name Hazard Class Packing Group
UN1791 Hypochlorite solutions 8 II
IMDG UN/ID No Proper Shipping Name Hazard Class Packing Group Marine Pollutant
UN1791 Hypochlorite solutions 8 II This material may meet the definition of a marine pollutant
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_____________________________________________________________________________________________
15. REGULATORY INFORMATION
International Inventories
Chemical Name Sodium hypochlorite
TSCA Present
DSL X
Caustic Soda
Present
X
NDSL
EINECS Present
ELINCS
Present
ENCS Present
IECSC X
KECL Present
PICCS X
AICS X
Present
X
Present
X
X
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations CERCLA Chemical Name Sodium hypochlorite 7681-52-9 Caustic Soda 1310-73-2
Hazardous Substances RQs 100 lb
CERCLA/SARA RQ
1000 lb
Reportable Quantity (RQ) RQ 100 lb final RQ RQ 45.4 kg final RQ RQ 1000 lb final RQ RQ 454 kg final RQ
SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CWA (Clean Water Act) Chemical Name Sodium hypochlorite
CWA - Reportable Quantities 100 lb
Caustic Soda
1000 lb
CWA - Toxic Pollutants CWA - Priority Pollutants
CWA - Hazardous Substances X X
US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name Sodium hypochlorite 7681-52-9 Caustic Soda 1310-73-2
New Jersey X
Massachusetts X
Pennsylvania X
X
X
X
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_____________________________________________________________________________________________
16. OTHER INFORMATION
NFPA HMIS Issue Date: Revision Date: Revision Note:
Health Hazards Not determined Health Hazards 2
Flammability Not determined Flammability 10
Instability Not determined Physical Hazards 1
Special Hazards Not determined Personal Protection Not determined
01-Oct-2002 13-May-2015 New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet
_____________________________________________________________________________________________ Page 8 / 8
Safety Data Sheet Issue Date: 01-Oct-2002
Revision Date: 13-May-2015
Version 1
1. IDENTIFICATION Product Identifier Product Name
Soft Care
Other means of identification SDS #
POZ-018
Recommended use of the chemical and restrictions on use Recommended Use Concentrated lotion hand soap. Details of the supplier of the safety data sheet Manufacturer Address Pur-O-Zone, Inc. 345 N. Iowa Street Lawrence, KS 66044 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr)
1-785-843-0771 1-800-535-5053
2. HAZARDS IDENTIFICATION Appearance Pink liquid
Physical State Liquid
Odor Honey almond fragrance
Classification Carcinogenicity
Category 2
Signal Word Warning Hazard Statements Suspected of causing cancer
Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Precautionary Statements - Response If exposed or concerned: Get medical advice/attention Precautionary Statements - Storage Store locked up
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_____________________________________________________________________________________________ Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Other Hazards Harmful to aquatic life with long lasting effects
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Ethyl Alcohol Diethanolamine
CAS No 64-17-5 111-42-2
Weight-% <5 <1
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**
4. FIRST-AID MEASURES First Aid Measures General Advice
If exposed or concerned: Get medical advice/attention.
Eye Contact
Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician.
Skin Contact
Wash off immediately with plenty of water for at least 15 minutes.
Inhalation
Remove to fresh air.
Ingestion
Drink gelatin solution, egg whites or two to three large glasses of water. Call a physician.
Most important symptoms and effects Symptoms
Suspected of causing cancer.
Indication of any immediate medical attention and special treatment needed Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES _____________________________________________________________________________________________ Page 2 / 8
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_____________________________________________________________________________________________ Personal precautions, protective equipment and emergency procedures Personal Precautions
Use personal protective equipment as required.
Environmental Precautions
See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up
Collect and reuse if possible, absorb with inert material (sand, sawdust, etc.), or flush to sewer with large quantity of water if permitted by all local, state and federal regulations.
7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required.
Conditions for safe storage, including any incompatibilities Storage Conditions
Store locked up.
Incompatible Materials
None known based on information supplied.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name Ethyl Alcohol 64-17-5
ACGIH TLV STEL: 1000 ppm
Diethanolamine 111-42-2
TWA: 1 mg/m3 inhalable fraction and vapor S*
OSHA PEL TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 (vacated) TWA: 3 ppm (vacated) TWA: 15 mg/m3
NIOSH IDLH IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3 TWA: 3 ppm TWA: 15 mg/m3
Appropriate engineering controls Engineering Controls
Showers. Eyewash stations. Ventilation systems.
Individual protection measures, such as personal protective equipment Eye/Face Protection
Use safety glasses or goggles.
Skin and Body Protection
Rubber gloves. Rubber apron.
Respiratory Protection
Ensure adequate ventilation, especially in confined areas.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties
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_____________________________________________________________________________________________ Physical State Appearance Color
Liquid Pink liquid Pink
Property pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties
Values Not determined Not available 98.9-101.1 °C / 210-214 °F None >1 Liquid-Not applicable Not available Not available Not established Not established 1.0029 Completely soluble Not determined Not determined Not determined Not determined Not determined Not determined Not determined Not determined
Odor Odor Threshold
Honey almond fragrance Not determined
Remarks • Method
(Water = 1)
(Water = 1)
10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization
Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to Avoid Keep out of reach of children. Incompatible Materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied.
11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact
Avoid contact with eyes.
Skin Contact
Avoid contact with skin.
Inhalation
Do not inhale.
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_____________________________________________________________________________________________ Ingestion
Do not ingest.
Component Information Chemical Name Ethyl Alcohol 64-17-5 Sodium Chloride 7647-14-5 Sodium sulfate 7757-82-6 Diethanolamine 111-42-2
Oral LD50 = 7060 mg/kg ( Rat )
Dermal LD50 -
Inhalation LC50 = 124.7 mg/L ( Rat ) 4 h
= 3 g/kg ( Rat )
> 10 g/kg ( Rabbit )
> 42 g/m3 ( Rat ) 1 h
> 10000 mg/kg ( Rat )
-
-
= 620 µL/kg ( Rat ) = 0.62 mL/kg ( Rat )
= 7640 µL/kg ( Rabbit )
-
Information on physical, chemical and toxicological effects Symptoms
Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity
Suspected of causing cancer. Ethanol has been shown to be carcinogenic in long-term studies only when consumed as an alcoholic beverage.
Chemical Name Ethyl Alcohol 64-17-5 Diethanolamine 111-42-2 Legend
ACGIH A3
IARC Group 1
A3
Group 2B
NTP Known
OSHA X X
ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 2B - Possibly Carcinogenic to Humans NTP (National Toxicology Program) Known - Known Carcinogen
Numerical measures of toxicity Not determined
12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life with long lasting effects. Component Information Chemical Name Ethyl Alcohol 64-17-5
Algae/aquatic plants
Fish
Toxicity to Crustacea microorganisms 12.0 - 16.0: 96 h EC50 = 34634 mg/L 30 min 9268 - 14221: 48 h Daphnia Oncorhynchus mykiss mL/L EC50 = 35470 mg/L 5 min magna mg/L LC50 2: 48 h LC50 static 13400 - 15100: Daphnia magna mg/L EC50 96 h Pimephales promelas Static 10800: 24 h Daphnia mg/L LC50 flow-through 100: magna mg/L EC50 96 h Pimephales promelas mg/L LC50 static
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_____________________________________________________________________________________________ Sodium Chloride 7647-14-5
Sodium sulfate 7757-82-6
Diethanolamine 111-42-2
5560 - 6080: 96 h Lepomis macrochirus mg/L LC50 flow-through 12946: 96 h Lepomis macrochirus mg/L LC50 static 6020 - 7070: 96 h Pimephales promelas mg/L LC50 static 7050: 96 h Pimephales promelas mg/L LC50 semi-static 6420 6700: 96 h Pimephales promelas mg/L LC50 static 4747 - 7824: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 13500 - 14500: 96 h Pimephales promelas mg/L LC50 13500: 96 h Lepomis macrochirus mg/L LC50 6800: 96 h Pimephales promelas mg/L LC50 static 3040 - 4380: 96 h Lepomis macrochirus mg/L LC50 static 7.8: 72 h Desmodesmus 4460 - 4980: 96 h subspicatus mg/L EC50 2.1 - Pimephales promelas mg/L 2.3: 96 h Pseudokirchneriella LC50 flow-through 1200 subcapitata mg/L EC50 1580: 96 h Pimephales promelas mg/L LC50 static 600 - 1000: 96 h Lepomis macrochirus mg/L LC50 static
1000: 48 h Daphnia magna mg/L EC50 340.7 - 469.2: 48 h Daphnia magna mg/L EC50 Static
2564: 48 h Daphnia magna mg/L EC50 630: 96 h Daphnia magna mg/L EC50
EC50 = 73 mg/L 5 min EC50 > 16 mg/L 16 h
55: 48 h Daphnia magna mg/L EC50
Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Chemical Name Ethyl Alcohol 64-17-5 Diethanolamine 111-42-2
Partition Coefficient -0.32 -2.18
Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
California Hazardous Waste Status
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_____________________________________________________________________________________________ Chemical Name Ethyl Alcohol 64-17-5
California Hazardous Waste Status Toxic Ignitable
14. TRANSPORT INFORMATION Note
Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.
DOT
Not regulated
IATA
Not regulated
IMDG Marine Pollutant
This material may meet the definition of a marine pollutant
15. REGULATORY INFORMATION International Inventories
Chemical Name Ethyl Alcohol
TSCA Present
DSL X
Diethanolamine
Present
X
NDSL
EINECS Present
ELINCS
Present
ENCS Present
IECSC X
KECL Present
PICCS X
AICS X
Present
X
Present
X
X
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations CERCLA Chemical Name Diethanolamine 111-42-2
Hazardous Substances RQs 100 lb
CERCLA/SARA RQ
Reportable Quantity (RQ) RQ 100 lb final RQ RQ 45.4 kg final RQ
SARA 313 Chemical Name
CAS No
Weight-%
Diethanolamine - 111-42-2
111-42-2
<1
SARA 313 - Threshold Values % 1.0
CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)
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_____________________________________________________________________________________________ US State Regulations
California Proposition 65 This product contains the following Proposition 65 chemicals. Chemical Name Ethyl Alcohol - 64-17-5
California Proposition 65 Carcinogen Developmental Carcinogen
Diethanolamine - 111-42-2
U.S. State Right-to-Know Regulations Chemical Name Ethyl Alcohol 64-17-5 Sodium sulfate 7757-82-6 Diethanolamine 111-42-2
New Jersey X
Massachusetts X
Pennsylvania X
X
X
X
X
X
16. OTHER INFORMATION NFPA HMIS Issue Date: Revision Date: Revision Note:
Health Hazards Not determined Health Hazards 1
Flammability Not determined Flammability 0
Instability Not determined Physical Hazards 0
Special Hazards Not determined Personal Protection Not determined
01-Oct-2002 13-May-2015 New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet
_____________________________________________________________________________________________ Page 8 / 8
Safety Data Sheet Issue Date: 01-Oct-2002
Revision Date: 13-May-2015
Version 1
1. IDENTIFICATION Product Identifier Product Name
Sparkall
Other means of identification SDS #
POZ-019
Recommended use of the chemical and restrictions on use Recommended Use Neutral cleaner. Details of the supplier of the safety data sheet Manufacturer Address Pur-O-Zone, Inc. 345 N. Iowa Street Lawrence, KS 66044 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr)
1-785-843-0771 1-800-535-5053
2. HAZARDS IDENTIFICATION Appearance Clear orange liquid
Physical State Liquid
Odor Sassafras fragrance
Classification This chemical does not meet the hazardous criteria set forth by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). However, this Safety Data Sheet (SDS) contains valuable information critical to the safe handling and proper use of this product. This SDS should be retained and available for employees and other users of this product.
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Isopropanol
CAS No 67-63-0
Weight-% <1
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**
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_____________________________________________________________________________________________
4. FIRST-AID MEASURES First Aid Measures Eye Contact
Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician.
Skin Contact
Wash off immediately with plenty of water for at least 15 minutes.
Inhalation
Remove to fresh air.
Ingestion
Drink gelatin solution, egg whites or two to three large glasses of water. Call a physician.
Most important symptoms and effects Symptoms
May cause eye irritation. Prolonged or repeated skin contact may cause irritation. May cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. Mists created by spray application may irritate respiratory tract.
Indication of any immediate medical attention and special treatment needed Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions
Use personal protective equipment as required.
Environmental Precautions
See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up
Collect and reuse if possible, absorb with inert material (sand, sawdust, etc.), or flush to sewer with large quantity of water if permitted by all local, state and federal regulations.
7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice.
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_____________________________________________________________________________________________ Conditions for safe storage, including any incompatibilities Storage Conditions
Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible Materials
None known based on information supplied.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name Isopropanol 67-63-0
ACGIH TLV STEL: 400 ppm TWA: 200 ppm
OSHA PEL TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m3
NIOSH IDLH IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3
Appropriate engineering controls Engineering Controls
Showers. Eyewash stations. Ventilation systems.
Individual protection measures, such as personal protective equipment Eye/Face Protection
Use safety glasses or goggles.
Skin and Body Protection
Rubber gloves. Rubber apron.
Respiratory Protection
Ensure adequate ventilation, especially in confined areas.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Appearance Color
Liquid Clear orange liquid Clear orange
Property pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity
Values Not determined Not available 100 °C / 212 °F None >1 Liquid-Not apllicable Not available Not available Not established Not established 1.0 Completely soluble Not determined Not determined Not determined Not determined Not determined Not determined
Odor Odor Threshold
Sassafras fragrance Not determined
Remarks • Method
(Water = 1)
(Water = 1)
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_____________________________________________________________________________________________ Explosive Properties Oxidizing Properties
Not determined Not determined
10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization
Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to Avoid Keep out of reach of children. Incompatible Materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied.
11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact
Avoid contact with eyes.
Skin Contact
Avoid contact with skin.
Inhalation
Do not inhale.
Ingestion
Do not ingest.
Component Information Chemical Name Nonylphenol Ethoxylate 127087-87-0 Nonoxynol 9016-45-9 Isopropanol 67-63-0 Methyl salicylate 119-36-8 Sodium Chloride 7647-14-5 Polyethylene glycol 25322-68-3
Oral LD50 = 1310 mg/kg ( Rat )
Dermal LD50 -
= 2590 mg/kg ( Rat ) = 1310 mg/kg = 1780 ÂľL/kg ( Rabbit ) = 2 mL/kg ( ( Rat ) Rabbit ) = 1870 mg/kg ( Rat ) = 4059 mg/kg ( Rabbit )
Inhalation LC50 = 72600 mg/m3 ( Rat ) 4 h
= 887 mg/kg ( Rat )
> 5000 mg/kg ( Rabbit )
-
= 3 g/kg ( Rat )
> 10 g/kg ( Rabbit )
> 42 g/m3 ( Rat ) 1 h
= 28 g/kg ( Rat )
> 20 mL/kg ( Rabbit ) > 20 g/kg ( Rabbit )
-
Information on physical, chemical and toxicological effects Symptoms
Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
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_____________________________________________________________________________________________ Carcinogenicity
Isopropyl Alcohol (IPA) is an IARC Monograph Group 3 chemical. IPA is a Group 1 when manufactured by the strong-acid process.
Chemical Name Isopropanol 67-63-0 Legend
ACGIH
IARC Group 3
NTP
OSHA X
IARC (International Agency for Research on Cancer) Group 3 IARC components are "not classifiable as human carcinogens" OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present
Numerical measures of toxicity Not determined
12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information Chemical Name
Algae/aquatic plants
Fish
Isopropanol 67-63-0
1000: 96 h Desmodesmus subspicatus mg/L EC50 1000: 72 h Desmodesmus subspicatus mg/L EC50
9640: 96 h Pimephales promelas mg/L LC50 flowthrough 1400000: 96 h Lepomis macrochirus Âľg/L LC50 11130: 96 h Pimephales promelas mg/L LC50 static
Methyl salicylate 119-36-8 Sodium Chloride 7647-14-5
5560 - 6080: 96 h Lepomis macrochirus mg/L LC50 flow-through 12946: 96 h Lepomis macrochirus mg/L LC50 static 6020 - 7070: 96 h Pimephales promelas mg/L LC50 static 7050: 96 h Pimephales promelas mg/L LC50 semi-static 6420 6700: 96 h Pimephales promelas mg/L LC50 static 4747 - 7824: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 5000: 24 h Carassius auratus mg/L LC50
Polyethylene glycol 25322-68-3
Toxicity to microorganisms
Crustacea 13299: 48 h Daphnia magna mg/L EC50
50: 24 h Daphnia magna mg/L EC50 1000: 48 h Daphnia magna mg/L EC50 340.7 - 469.2: 48 h Daphnia magna mg/L EC50 Static
Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Chemical Name Isopropanol 67-63-0
Partition Coefficient 0.05
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_____________________________________________________________________________________________ Methyl salicylate 119-36-8
2.55
Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
California Hazardous Waste Status Chemical Name Isopropanol 67-63-0
California Hazardous Waste Status Toxic Ignitable
14. TRANSPORT INFORMATION Note
Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.
DOT
Not regulated
IATA
Not regulated
IMDG
Not regulated
15. REGULATORY INFORMATION International Inventories
Chemical Name Isopropanol
TSCA Present
DSL X
NDSL
EINECS Present
ELINCS
ENCS Present
IECSC X
KECL Present
PICCS X
AICS X
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
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_____________________________________________________________________________________________ US Federal Regulations
CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 313 Chemical Name
CAS No
Weight-%
Isopropanol - 67-63-0
67-63-0
<1
SARA 313 - Threshold Values % 1.0
CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name Isopropanol 67-63-0 Methyl salicylate 119-36-8
New Jersey X
Massachusetts X
Pennsylvania X X
16. OTHER INFORMATION NFPA HMIS Issue Date: Revision Date: Revision Note:
Health Hazards Not determined Health Hazards 1
Flammability Not determined Flammability 0
Instability Not determined Physical Hazards 0
Special Hazards Not determined Personal Protection Not determined
01-Oct-2002 13-May-2015 New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet
_____________________________________________________________________________________________ Page 7 / 7
Safety Data Sheet Issue Date: 07-Nov-2012
Revision Date: 13-May-2015
Version 1
1. IDENTIFICATION Product Identifier Product Name
Success
Other means of identification SDS #
POZ-020
Recommended use of the chemical and restrictions on use Recommended Use High-performance floor finish. Details of the supplier of the safety data sheet Manufacturer Address Pur-O-Zone, Inc. 345 N. Iowa Street Lawrence, KS 66044 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr)
1-785-843-0771 1-800-535-5053
2. HAZARDS IDENTIFICATION Appearance White milky liquid
Physical State Liquid
Odor Typical acrylic odor
Classification Reproductive toxicity
Category 1B
Signal Word Danger Hazard Statements May damage fertility or the unborn child
Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Precautionary Statements - Response If exposed or concerned: Get medical advice/attention Precautionary Statements - Storage Store locked up
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_____________________________________________________________________________________________ Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Other Hazards Toxic to aquatic life with long lasting effects
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Dibutyl phthalate Ethyl Alcohol
CAS No 84-74-2 64-17-5
Weight-% <5 <1
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**
4. FIRST-AID MEASURES First Aid Measures General Advice
If exposed or concerned: Get medical advice/attention.
Eye Contact
Immediately flush eyes with water for at least 15 minutes while holding eyelids open.
Skin Contact
Wash off immediately with plenty of water for at least 15 minutes.
Inhalation
Remove to fresh air.
Ingestion
Never give anything by mouth to an unconscious person. Induce vomiting at the instruction of medical personnel.
Most important symptoms and effects Symptoms
May damage fertility or the unborn child.
Indication of any immediate medical attention and special treatment needed Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Foam. Carbon dioxide (CO2). Dry chemical. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES _____________________________________________________________________________________________ Page 2 / 8
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_____________________________________________________________________________________________ Personal precautions, protective equipment and emergency procedures Personal Precautions
Use personal protective equipment as required.
Environmental Precautions
See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up
Stop discharge, if it can be performed safely and contain material. If a substantial quantity is spilled, recover with pump or vacuum. Otherwise, use an absorbent material. Place contaminated material in a suitable container for disposal. Do not flush to sewer, stream or other bodies of water.
7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required.
Conditions for safe storage, including any incompatibilities Storage Conditions
Store locked up.
Incompatible Materials
Strong oxidizing agents.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name Dibutyl phthalate 84-74-2 Ethyl Alcohol 64-17-5
ACGIH TLV TWA: 5 mg/m3 STEL: 1000 ppm
OSHA PEL TWA: 5 mg/m3 (vacated) TWA: 5 mg/m3 TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3
NIOSH IDLH IDLH: 4000 mg/m3 TWA: 5 mg/m3 IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3
Appropriate engineering controls Engineering Controls
Provide sufficient ventilation to maintain exposure below TLV(s).
Individual protection measures, such as personal protective equipment Eye/Face Protection
Chemical splash goggles are advised.
Skin and Body Protection
Wear chemical resistant gloves such as nitrile rubber. Wear impervious clothing and boots.
Respiratory Protection
If TLV of the product or any component is exceeded, a NIOSH/MSHA jointly approved air supplied respirator is advised. Engineering or administrative controls should be implemented to reduce exposure.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES _____________________________________________________________________________________________ Page 3 / 8
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_____________________________________________________________________________________________ Information on basic physical and chemical properties Physical State Appearance Color
Liquid White milky liquid White milky
Property pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties VOC Content (%) VOC Content
Values Not determined Not determined 100 °C / 212 °F None Slower than n-Butyl Acetate Liquid-Not applicable Not determined Not determined Not determined Less than air 1.055 Completely soluble Not determined Not determined Not determined Not determined Not determined Not determined Not determined Not determined 75% 149 g/L (1.25 lb/gal)
Odor Odor Threshold
Typical acrylic odor Not determined
Remarks • Method
10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization
Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to Avoid Keep out of reach of children. Incompatible Materials Strong oxidizing agents. Hazardous Decomposition Products None known based on information supplied.
11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact
Avoid contact with eyes.
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_____________________________________________________________________________________________ Skin Contact
Avoid contact with skin.
Inhalation
Do not inhale.
Ingestion
Do not ingest.
Component Information Chemical Name Di(ethylene glycol) ethyl ether 111-90-0 Dibutyl phthalate 84-74-2 Ethyl Alcohol 64-17-5
Oral LD50 = 1920 mg/kg ( Rat )
Inhalation LC50 > 5240 mg/m3 ( Rat ) 4 h
= 6300 mg/kg ( Rat )
Dermal LD50 = 6 mL/kg ( Rat ) = 4200 ÂľL/kg ( Rabbit ) > 20000 mg/kg ( Rabbit )
= 7060 mg/kg ( Rat )
-
= 124.7 mg/L ( Rat ) 4 h
> 15.68 mg/L ( Rat ) 4 h
Information on physical, chemical and toxicological effects Symptoms
Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity
Ethanol has been shown to be carcinogenic in long-term studies only when consumed as an alcoholic beverage.
Chemical Name Ethyl Alcohol 64-17-5 Legend
ACGIH A3
IARC Group 1
NTP Known
OSHA X
Toxicity to microorganisms
Crustacea
ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present
Reproductive toxicity
May damage fertility or the unborn child.
Numerical measures of toxicity Not determined
12. ECOLOGICAL INFORMATION Ecotoxicity Toxic to aquatic life with long lasting effects. Component Information Chemical Name
Algae/aquatic plants
Fish
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_____________________________________________________________________________________________ Di(ethylene glycol) ethyl ether 111-90-0
Dibutyl phthalate 84-74-2
Ethyl Alcohol 64-17-5
10000: 96 h Lepomis macrochirus mg/L LC50 static 19100 - 23900: 96 h Lepomis macrochirus mg/L LC50 flow-through 11400 15700: 96 h Oncorhynchus mykiss mg/L LC50 flowthrough 11600 - 16700: 96 h Pimephales promelas mg/L LC50 flow-through 13400: 96 h Salmo gairdneri mg/L LC50 flow-through 1.2: 72 h Desmodesmus 0.71 - 1.2: 96 h Pimephales subspicatus mg/L EC50 0.4: promelas mg/L LC50 flow96 h Pseudokirchneriella through 0.31 - 5.45: 96 h subcapitata mg/L EC50 Pimephales promelas mg/L static LC50 static 1.24: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 1.24 - 5.3: 96 h Oncorhynchus mykiss mg/L LC50 static 1.38 - 1.74: 96 h Lepomis macrochirus mg/L LC50 flow-through 0.42 - 1.28: 96 h Lepomis macrochirus mg/L LC50 static 12.0 - 16.0: 96 h Oncorhynchus mykiss mL/L LC50 static 13400 - 15100: 96 h Pimephales promelas mg/L LC50 flow-through 100: 96 h Pimephales promelas mg/L LC50 static
3940 - 4670: 48 h Daphnia magna mg/L EC50
EC50 = 10.9 mg/L 30 min EC50 = 10.9 mg/L 5 min EC50 = 11.1 mg/L 15 min EC50 = 2.2 mg/L 24 h
2.99: 48 h Daphnia magna mg/L EC50 Static 3.4: 48 h Daphnia magna mg/L EC50
EC50 = 34634 mg/L 30 min 9268 - 14221: 48 h Daphnia EC50 = 35470 mg/L 5 min magna mg/L LC50 2: 48 h Daphnia magna mg/L EC50 Static 10800: 24 h Daphnia magna mg/L EC50
Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Chemical Name Di(ethylene glycol) ethyl ether 111-90-0 Dibutyl phthalate 84-74-2 Ethyl Alcohol 64-17-5
Partition Coefficient -0.8 5.38 -0.32
Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
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_____________________________________________________________________________________________ US EPA Waste Number Chemical Name Dibutyl phthalate 84-74-2
RCRA
RCRA - Basis for Listing Included in waste stream: F039
RCRA - D Series Wastes
RCRA - U Series Wastes U069
California Hazardous Waste Status Chemical Name Ethyl Alcohol 64-17-5
California Hazardous Waste Status Toxic Ignitable
14. TRANSPORT INFORMATION Note
Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.
DOT
Not regulated
IATA
Not regulated
IMDG Marine Pollutant
This material may meet the definition of a marine pollutant
15. REGULATORY INFORMATION International Inventories
Chemical Name Dibutyl phthalate
TSCA Present
DSL X
Ethyl Alcohol
Present
X
NDSL
EINECS Present
ELINCS
Present
ENCS Present
IECSC X
KECL Present
PICCS X
AICS X
Present
X
Present
X
X
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations CERCLA Chemical Name Dibutyl phthalate 84-74-2
Hazardous Substances RQs 10 lb
CERCLA/SARA RQ
Reportable Quantity (RQ) RQ 10 lb final RQ RQ 4.54 kg final RQ
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_____________________________________________________________________________________________ SARA 313
Chemical Name
CAS No
Weight-%
Di(ethylene glycol) ethyl ether - 111-90-0 Dibutyl phthalate - 84-74-2
111-90-0 84-74-2
1-10 <5
SARA 313 - Threshold Values % 1.0 1.0
CWA (Clean Water Act) Chemical Name
CWA - Reportable Quantities 10 lb
Dibutyl phthalate
CWA - Toxic Pollutants CWA - Priority Pollutants X
CWA - Hazardous Substances X
X
US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. Chemical Name Dibutyl phthalate - 84-74-2
California Proposition 65 Developmental Female Reproductive Male Reproductive Carcinogen Developmental
Ethyl Alcohol - 64-17-5
U.S. State Right-to-Know Regulations Chemical Name Di(ethylene glycol) ethyl ether 111-90-0 Dibutyl phthalate 84-74-2 Ethyl Alcohol 64-17-5
New Jersey X
Massachusetts
Pennsylvania X
X
X
X
X
X
X
16. OTHER INFORMATION NFPA HMIS Issue Date: Revision Date: Revision Note:
Health Hazards Not determined Health Hazards 1
Flammability Not determined Flammability 0
Instability Not determined Physical Hazards 0
Special Hazards Not determined Personal Protection Not determined
07-Nov-2012 13-May-2015 New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet
_____________________________________________________________________________________________ Page 8 / 8
Safety Data Sheet Issue Date: 01-Oct-2002
Revision Date: 13-May-2015
Version 1
1. IDENTIFICATION Product Identifier Product Name
Sup-R-Safe
Other means of identification SDS #
POZ-023
Recommended use of the chemical and restrictions on use Recommended Use Porcelain cleaner. Details of the supplier of the safety data sheet Manufacturer Address Pur-O-Zone, Inc. 345 N. Iowa Street Lawrence, KS 66044 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr)
1-785-843-0771 1-800-535-5053
2. HAZARDS IDENTIFICATION Appearance Light pink liquid
Physical State Liquid
Odor Sassafras fragrance
Classification Serious eye damage/eye irritation
Category 2
Hazards Not Otherwise Classified (HNOC) Causes mild skin irritation Signal Word Warning Hazard Statements Causes serious eye irritation
Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear eye/face protection Precautionary Statements - Response
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_____________________________________________________________________________________________ IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Sulfamic Acid Isopropanol
CAS No 5329-14-6 67-63-0
Weight-% 1-10 1-10
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**
4. FIRST-AID MEASURES First Aid Measures Eye Contact
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Skin Contact
Wash off immediately with plenty of water for at least 15 minutes.
Inhalation
Remove to fresh air.
Ingestion
Drink two glasses of water. Do not induce vomiting. Call a physician.
Most important symptoms and effects Symptoms
Causes mild skin irritation. Causes serious eye irritation.
Indication of any immediate medical attention and special treatment needed Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures
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_____________________________________________________________________________________________ Personal Precautions
Use personal protective equipment as required.
Environmental Precautions
See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up
Collect and reuse if possible, absorb with inert material (sand, sawdust, etc.), or flush to sewer with large quantity of water if permitted by all local, state and federal regulations.
7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice. Wash face, hands, and any exposed skin thoroughly after handling. Wear eye/face protection.
Conditions for safe storage, including any incompatibilities Storage Conditions
Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible Materials
None known based on information supplied.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name Isopropanol 67-63-0
ACGIH TLV STEL: 400 ppm TWA: 200 ppm
OSHA PEL TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m3
NIOSH IDLH IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3
Appropriate engineering controls Engineering Controls
Showers. Eyewash stations. Ventilation systems.
Individual protection measures, such as personal protective equipment Eye/Face Protection
Goggles or face shield.
Skin and Body Protection
Rubber gloves. Rubber apron.
Respiratory Protection
None normally required with adequate room ventilation.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Appearance Color
Liquid Light pink liquid Light pink
Odor Odor Threshold
Property
Values
Remarks â&#x20AC;˘ Method
Sassafras fragrance Not determined
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_____________________________________________________________________________________________ pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties
Not determined Not available Not determined 째C / 210-212 째F Non-flammable aqueous solution >1 Liquid-Not applicable Not available Not available Not established Not established 1.058 Completely soluble Not determined Not determined Not determined Not determined Not determined Not determined Not determined Not determined
(Water = 1)
(Water = 1)
10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization
Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to Avoid Keep out of reach of children. Incompatible Materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied.
11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact
Causes serious eye irritation.
Skin Contact
Causes mild skin irritation.
Inhalation
Do not inhale.
Ingestion
Do not ingest.
Component Information
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_____________________________________________________________________________________________ Chemical Name Sulfamic Acid 5329-14-6 Isopropanol 67-63-0 Lauryl Alcohol 112-53-8 Sodium lauryl sulfate 151-21-3 Sodium sulfate 7757-82-6
Oral LD50 = 1450 mg/kg ( Rat )
Dermal LD50 -
Inhalation LC50 -
= 1870 mg/kg ( Rat )
= 4059 mg/kg ( Rabbit )
= 72600 mg/m3 ( Rat ) 4 h
> 5000 mg/kg ( Rat )
-
-
= 977 mg/kg ( Rat )
= 580 mg/kg ( Rabbit )
> 3900 mg/m3 ( Rat ) 1 h
> 10000 mg/kg ( Rat )
-
-
Information on physical, chemical and toxicological effects Symptoms
Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity
Isopropyl Alcohol (IPA) is an IARC Monograph Group 3 chemical. IPA is a Group 1 when manufactured by the strong-acid process.
Chemical Name Isopropanol 67-63-0 Legend
ACGIH
IARC Group 3
NTP
OSHA X
IARC (International Agency for Research on Cancer) Group 3 IARC components are "not classifiable as human carcinogens" OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present
Numerical measures of toxicity Not determined
12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information Chemical Name Sulfamic Acid 5329-14-6 Isopropanol 67-63-0
Lauryl Alcohol 112-53-8
Algae/aquatic plants
1000: 96 h Desmodesmus subspicatus mg/L EC50 1000: 72 h Desmodesmus subspicatus mg/L EC50
0.62: 96 h Desmodesmus subspicatus mg/L EC50
Fish 14.2: 96 h Pimephales promelas mg/L LC50 static 9640: 96 h Pimephales promelas mg/L LC50 flowthrough 1400000: 96 h Lepomis macrochirus Âľg/L LC50 11130: 96 h Pimephales promelas mg/L LC50 static 1.01: 96 h Pimephales promelas mg/L LC50 flowthrough 0.1855: 96 h Pimephales promelas mg/L LC50
Toxicity to microorganisms
Crustacea
13299: 48 h Daphnia magna mg/L EC50
320: 48 h Daphnia magna mg/L EC50
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_____________________________________________________________________________________________ Sodium lauryl sulfate 151-21-3
53: 72 h Desmodesmus 8 - 12.5: 96 h Pimephales subspicatus mg/L EC50 30 - promelas mg/L LC50 static 100: 96 h Desmodesmus 15 - 18.9: 96 h Pimephales subspicatus mg/L EC50 117: promelas mg/L LC50 static 96 h Pseudokirchneriella 22.1 - 22.8: 96 h Pimephales subcapitata mg/L EC50 3.59 promelas mg/L LC50 static - 15.6: 96 h 4.3 - 8.5: 96 h Oncorhynchus Pseudokirchneriella mykiss mg/L LC50 static subcapitata mg/L EC50 4.62: 96 h Oncorhynchus static mykiss mg/L LC50 flowthrough 5.8 - 7.5: 96 h Pimephales promelas mg/L LC50 static 10.2 - 22.5: 96 h Pimephales promelas mg/L LC50 semi-static 6.2 - 9.6: 96 h Pimephales promelas mg/L LC50 13.5 - 18.3: 96 h Poecilia reticulata mg/L LC50 semi-static 10.8 - 16.6: 96 h Poecilia reticulata mg/L LC50 static 1.31: 96 h Cyprinus carpio mg/L LC50 semi-static 4.2: 96 h Oncorhynchus mykiss mg/L LC50 7.97: 96 h Brachydanio rerio mg/L LC50 flow-through 9.9 - 20.1: 96 h Brachydanio rerio mg/L LC50 semi-static 4.06 - 5.75: 96 h Lepomis macrochirus mg/L LC50 static 4.2 - 4.8: 96 h Lepomis macrochirus mg/L LC50 flow-through 4.5: 96 h Lepomis macrochirus mg/L LC50 13500 - 14500: 96 h Pimephales promelas mg/L LC50 13500: 96 h Lepomis macrochirus mg/L LC50 6800: 96 h Pimephales promelas mg/L LC50 static 3040 - 4380: 96 h Lepomis macrochirus mg/L LC50 static
Sodium sulfate 7757-82-6
1.8: 48 h Daphnia magna mg/L EC50
2564: 48 h Daphnia magna mg/L EC50 630: 96 h Daphnia magna mg/L EC50
Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Chemical Name Isopropanol 67-63-0 Lauryl Alcohol 112-53-8 Sodium lauryl sulfate 151-21-3
Partition Coefficient 0.05 5.36 1.6
Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS _____________________________________________________________________________________________ Page 6 / 8
Revision Date: 13-May-2015
POZ-023 - Sup-R-Safe
_____________________________________________________________________________________________ Waste Treatment Methods Disposal of Wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
California Hazardous Waste Status Chemical Name Isopropanol 67-63-0
California Hazardous Waste Status Toxic Ignitable
14. TRANSPORT INFORMATION Note
Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.
DOT
Not regulated
IATA
Not regulated
IMDG
Not regulated
15. REGULATORY INFORMATION International Inventories
Chemical Name Sulfamic Acid
TSCA Present
DSL X
Isopropanol
Present
X
NDSL
EINECS Present
ELINCS
Present
ENCS Present
IECSC X
KECL Present
PICCS X
AICS X
Present
X
Present
X
X
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355).
_____________________________________________________________________________________________ Page 7 / 8
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POZ-023 - Sup-R-Safe
_____________________________________________________________________________________________ SARA 313
Chemical Name
CAS No
Weight-%
Isopropanol - 67-63-0
67-63-0
1-10
SARA 313 - Threshold Values % 1.0
CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name Sulfamic Acid 5329-14-6 Isopropanol 67-63-0 Sodium sulfate 7757-82-6
New Jersey X
Massachusetts
Pennsylvania
X
X
X
X
X
16. OTHER INFORMATION NFPA HMIS Issue Date: Revision Date: Revision Note:
Health Hazards Not determined Health Hazards 1
Flammability Not determined Flammability 0
Instability Not determined Physical Hazards 0
Special Hazards Not determined Personal Protection Not determined
01-Oct-2002 13-May-2015 New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet
_____________________________________________________________________________________________ Page 8 / 8
Safety Data Sheet Issue Date: 01-Oct-2002
Revision Date: 13-May-2015
Version 1
1. IDENTIFICATION Product Identifier Product Name
Sweetwood
Other means of identification SDS #
POZ-021
UN/ID No
UN3295
Recommended use of the chemical and restrictions on use Recommended Use Dust mop treatment. Details of the supplier of the safety data sheet Manufacturer Address Pur-O-Zone, Inc. 345 N. Iowa Street Lawrence, KS 66044 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr)
1-785-843-0771 1-800-535-5053
2. HAZARDS IDENTIFICATION Appearance Clear water white liquid
Physical State Liquid
Odor Spice
Classification Acute toxicity - Inhalation (Vapors) Carcinogenicity Flammable Liquids
Category 4 Category 1A Category 3
Signal Word Danger Hazard Statements Harmful if inhaled May cause cancer Flammable liquid and vapor
_____________________________________________________________________________________________ Page 1 / 8
Revision Date: 13-May-2015
POZ-021 - Sweetwood Spra-On
_____________________________________________________________________________________________ Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. â&#x20AC;&#x201D; No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof equipment Use only non-sparking tools Take precautionary measures against static discharge
Precautionary Statements - Response If exposed or concerned: Get medical advice/attention IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing IN CASE OF FIRE: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep cool Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Distillates, petroleum, solvent refined heavy paraffinic Petroleum distillates, solvent-refined light paraffinic
CAS No 64741-88-4
Weight-% 10-20
64741-89-5
1-10
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**
4. FIRST-AID MEASURES First Aid Measures General Advice
If exposed or concerned: Get medical advice/attention.
Eye Contact
Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician.
Skin Contact
Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse.
Inhalation
Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Ingestion
Clean mouth with water and drink afterwards plenty of water.
Most important symptoms and effects
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Revision Date: 13-May-2015
POZ-021 - Sweetwood Spra-On
_____________________________________________________________________________________________ Symptoms
Harmful if inhaled. May cause cancer.
Indication of any immediate medical attention and special treatment needed Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Water spray (fog). Alcohol resistant foam. Dry chemical. Carbon dioxide (CO2). Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Closed containers may explode, cool with water.
6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions
Use personal protective equipment as required.
Environmental Precautions
See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up
Eliminate all sources of ignition. Absorb spilled material with inert material (sand, sawdust, clay, etc.).
7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Keep away from heat/sparks/open flames/hot surfaces. â&#x20AC;&#x201D; No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion proof equipment. Use only non-sparking tools. Take precautionary measures against static discharges.
Conditions for safe storage, including any incompatibilities Storage Conditions
Store locked up. Store in a well-ventilated place. Keep cool.
Incompatible Materials
None known based on information supplied.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines
This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies
_____________________________________________________________________________________________ Page 3 / 8
Revision Date: 13-May-2015
POZ-021 - Sweetwood Spra-On
_____________________________________________________________________________________________ Appropriate engineering controls Engineering Controls
Showers. Eyewash stations. Ventilation systems.
Individual protection measures, such as personal protective equipment Eye/Face Protection
Goggles or face shield.
Skin and Body Protection
Rubber gloves. Rubber apron.
Respiratory Protection
Ensure adequate ventilation, especially in confined areas.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Appearance Color
Liquid Clear water white liquid Clear water white
Property pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density
Values Not determined Not available 178.9-188-9 °C / 354-372 °F 53.3 °C / 128 °F >1 Liquid-Not applicable 9.8 1.3 5.40 3
Specific Gravity Water Solubility Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties
0.76 Not soluble Not determined Not determined Not determined Not determined Not determined Not determined Not determined Not determined
Odor Odor Threshold
Spice Not determined
Remarks • Method
(Water = 1)
(calculated) at 37.8°C (100°F) (Water = 1)
10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization
Under normal conditions of storage and use, hazardous polymerization will not occur.
_____________________________________________________________________________________________ Page 4 / 8
Revision Date: 13-May-2015
POZ-021 - Sweetwood Spra-On
_____________________________________________________________________________________________ Conditions to Avoid Keep out of reach of children.
Incompatible Materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied.
11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact
Avoid contact with eyes.
Skin Contact
Avoid contact with skin.
Inhalation
Harmful if inhaled.
Ingestion
Do not ingest.
Component Information Chemical Name Distillates, petroleum, solvent refined heavy paraffinic 64741-88-4 Mineral Oil 8042-47-5 Petroleum distillates, solvent-refined light paraffinic 64741-89-5
Oral LD50 > 5000 mg/kg ( Rat )
Dermal LD50 > 2000 mg/kg ( Rabbit )
Inhalation LC50 = 2.18 mg/L ( Rat ) 4 h
> 5000 mg/kg ( Rat )
-
-
> 5000 mg/kg ( Rat )
> 5 g/kg ( Rabbit )
= 2.18 mg/L ( Rat ) 4 h
Information on physical, chemical and toxicological effects Symptoms
Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity Chemical Name Distillates, petroleum, solvent refined heavy paraffinic 64741-88-4 Petroleum distillates, solvent-refined light paraffinic 64741-89-5 Legend
May cause cancer. ACGIH A2
IARC Group 1
A2
Group 1
NTP
OSHA X
X
ACGIH (American Conference of Governmental Industrial Hygienists) A2 - Suspected Human Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present
Numerical measures of toxicity Not determined
_____________________________________________________________________________________________ Page 5 / 8
Revision Date: 13-May-2015
POZ-021 - Sweetwood Spra-On
_____________________________________________________________________________________________
12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information Chemical Name
Algae/aquatic plants
Distillates, petroleum, solvent refined heavy paraffinic 64741-88-4 Mineral Oil 8042-47-5 Petroleum distillates, solvent-refined light paraffinic 64741-89-5
Fish 5000: 96 h Oncorhynchus mykiss mg/L LC50
Toxicity to microorganisms
10000: 96 h Lepomis macrochirus mg/L LC50 5000: 96 h Oncorhynchus mykiss mg/L LC50
Crustacea 1000: 48 h Daphnia magna mg/L EC50
1000: 48 h Daphnia magna mg/L EC50
Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Chemical Name Mineral Oil 8042-47-5
Partition Coefficient >6
Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
14. TRANSPORT INFORMATION Note DOT UN/ID No Proper Shipping Name Hazard Class
Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. UN3295 Hydrocarbons, liquid, n.o.s. 3
_____________________________________________________________________________________________ Page 6 / 8
Revision Date: 13-May-2015
POZ-021 - Sweetwood Spra-On
_____________________________________________________________________________________________ Packing Group
III
IATA UN/ID No Proper Shipping Name Hazard Class Packing Group
UN3295 Hydrocarbons, liquid, n.o.s. 3 III
IMDG UN/ID No Proper Shipping Name Hazard Class Packing Group
UN3295 Hydrocarbons, liquid, n.o.s. 3 III
15. REGULATORY INFORMATION International Inventories
Chemical Name Distillates, petroleum, solvent refined heavy paraffinic Petroleum distillates, solvent-refined light paraffinic
TSCA Present
DSL X
Present
X
NDSL
EINECS Present
ELINCS
Present
ENCS Present
IECSC X
KECL Present
PICCS X
AICS X
Present
X
Present
X
X
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations
_____________________________________________________________________________________________ Page 7 / 8
Revision Date: 13-May-2015
POZ-021 - Sweetwood Spra-On
_____________________________________________________________________________________________ California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name Petroleum distillates, solvent-refined light paraffinic 64741-89-5
New Jersey
Massachusetts X
Pennsylvania
16. OTHER INFORMATION NFPA HMIS Issue Date: Revision Date: Revision Note:
Health Hazards Not determined Health Hazards 1
Flammability Not determined Flammability 2
Instability Not determined Physical Hazards 0
Special Hazards Not determined Personal Protection Not determined
01-Oct-2002 13-May-2015 New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet
_____________________________________________________________________________________________ Page 8 / 8
Safety Data Sheet Issue Date: 01-Oct-2002
Revision Date: 13-May-2015
Version 1
1. IDENTIFICATION Product Identifier Product Name
Tack Rag
Other means of identification SDS #
POZ-022
UN/ID No
UN3295
Recommended use of the chemical and restrictions on use Recommended Use Waterless Cleaner. Details of the supplier of the safety data sheet Manufacturer Address Pur-O-Zone, Inc. 345 N. Iowa Street Lawrence, KS 66044 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr)
1-785-843-0771 1-800-535-5053
2. HAZARDS IDENTIFICATION Appearance Clear water white liquid
Physical State Liquid
Odor Typical solvent odor
Classification Acute toxicity - Inhalation (Vapors) Specific target organ toxicity (repeated exposure) Aspiration toxicity Flammable Liquids
Category 4 Category 1 Category 1 Category 3
Hazards Not Otherwise Classified (HNOC) May be harmful if swallowed May be harmful in contact with skin Causes mild skin irritation Signal Word Danger Hazard Statements Harmful if inhaled Causes damage to organs through prolonged or repeated exposure May be fatal if swallowed and enters airways Flammable liquid and vapor
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Precautionary Statements - Prevention Use only outdoors or in a well-ventilated area Do not breathe dust/fume/gas/mist/vapors/spray Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Keep away from heat/sparks/open flames/hot surfaces. â&#x20AC;&#x201D; No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof equipment Use only non-sparking tools Take precautionary measures against static discharge Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response Get medical advice/attention if you feel unwell IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a poison center or doctor/physician if you feel unwell IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do not induce vomiting IN CASE OF FIRE: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep cool Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Other Hazards May be harmful if swallowed May be harmful in contact with skin Causes mild skin irritation Harmful to aquatic life with long lasting effects Harmful to aquatic life
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Aliphatic Hydrocarbon Solvent 1,2,4 Trimethylbenzene
CAS No 64742-88-7 95-63-6
Weight-% 90-100 <5
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**
4. FIRST-AID MEASURES _____________________________________________________________________________________________ Page 2 / 8
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_____________________________________________________________________________________________ First Aid Measures
General Advice
Get medical advice/attention if you feel unwell.
Eye Contact
Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician.
Skin Contact
Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse.
Inhalation
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center or doctor/physician if you feel unwell.
Ingestion
Immediately call a poison center or doctor/physician. Do not induce vomiting.
Most important symptoms and effects Symptoms
May be harmful if swallowed. May be harmful in contact with skin. Causes mild skin irritation. Harmful if inhaled. Causes damage to organs through prolonged or repeated exposure. May be fatal if swallowed and enters airways.
Indication of any immediate medical attention and special treatment needed Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Water spray (fog). Alcohol resistant foam. Dry chemical. Carbon dioxide (CO2). Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Closed containers may explode, cool with water.
6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions
Use personal protective equipment as required.
Environmental Precautions
See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up
Eliminate all sources of ignition. Absorb spilled material with inert material (sand, sawdust, clay, etc.).
7. HANDLING AND STORAGE Precautions for safe handling
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_____________________________________________________________________________________________ Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice. Use only outdoors or in a well-ventilated area. Do not breathe dust/fume/gas/mist/vapors/spray. Wash face, hands, and any exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product. Keep away from heat/sparks/open flames/hot surfaces. — No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion proof equipment. Use only non-sparking tools. Take precautionary measures against static discharges. Wear protective gloves/protective clothing and eye/face protection. Keep cool.
Conditions for safe storage, including any incompatibilities Storage Conditions
Store locked up. Store in a well-ventilated place. Keep cool.
Incompatible Materials
None known based on information supplied.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name 1,2,4 Trimethylbenzene 95-63-6
ACGIH TLV -
OSHA PEL -
NIOSH IDLH TWA: 25 ppm TWA: 125 mg/m3
Appropriate engineering controls Engineering Controls
Showers. Eyewash stations. Ventilation systems.
Individual protection measures, such as personal protective equipment Eye/Face Protection
Goggles or face shield.
Skin and Body Protection
Rubber gloves. Rubber apron.
Respiratory Protection
If TLV is exceeded, an approved air supplied respirator is advised.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Appearance Color
Liquid Clear water white liquid Clear water white
Property pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure
Values Not determined Not available 156 °C / 312 °F 41 °C / 105 °F Not established Liquid-Not applicable 6 1 2.4
Vapor Density Specific Gravity Water Solubility Solubility in other solvents
4.8 0.781 Not soluble Not determined
Odor Odor Threshold
Typical solvent odor Not determined
Remarks • Method
Tag Closed Cup
at 37.8°C (100°F) (Water = 1)
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_____________________________________________________________________________________________ Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties
Not determined Not determined Not determined Not determined Not determined Not determined Not determined
10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization
Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to Avoid Keep out of reach of children. Incompatible Materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied.
11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact
Avoid contact with eyes.
Skin Contact
Causes mild skin irritation.
Inhalation
Harmful if inhaled.
Ingestion
May be harmful if swallowed.
Component Information Chemical Name Aliphatic Hydrocarbon Solvent 64742-88-7 1,2,4 Trimethylbenzene 95-63-6
Oral LD50 > 5000 mg/kg ( Rat )
Dermal LD50 = 3000 mg/kg ( Rabbit )
Inhalation LC50 > 5.28 mg/L ( Rat ) 4 h
= 3280 mg/kg ( Rat )
> 3160 mg/kg ( Rabbit )
= 18 g/m3 ( Rat ) 4 h
Information on physical, chemical and toxicological effects Symptoms
Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
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_____________________________________________________________________________________________ Carcinogenicity
Based on the information provided, this product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP.
STOT - repeated exposure
Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard
May be fatal if swallowed and enters airways.
Numerical measures of toxicity Not determined
12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life with long lasting effects. Component Information Chemical Name
Algae/aquatic plants
Fish
Aliphatic Hydrocarbon Solvent 64742-88-7 1,2,4 Trimethylbenzene 95-63-6
450: 96 h Pseudokirchneriella subcapitata mg/L EC50
800: 96 h Pimephales promelas mg/L LC50 static
Toxicity to microorganisms
7.19 - 8.28: 96 h Pimephales promelas mg/L LC50 flowthrough
Crustacea 100: 48 h Daphnia magna mg/L EC50 6.14: 48 h Daphnia magna mg/L EC50
Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Chemical Name 1,2,4 Trimethylbenzene 95-63-6
Partition Coefficient 3.63
Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
14. TRANSPORT INFORMATION Note
Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.
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_____________________________________________________________________________________________ DOT UN/ID No Proper Shipping Name Hazard Class Packing Group
UN3295 Hydrocarbons, liquid, n.o.s. 3 III
IATA UN/ID No Proper Shipping Name Hazard Class Packing Group
UN3295 Hydrocarbons, liquid, n.o.s. 3 III
IMDG UN/ID No Proper Shipping Name Hazard Class Packing Group Marine Pollutant
UN3295 Hydrocarbons, liquid, n.o.s. 3 III This material may meet the definition of a marine pollutant
15. REGULATORY INFORMATION International Inventories
Chemical Name Aliphatic Hydrocarbon Solvent 1,2,4 Trimethylbenzene
TSCA Present
DSL X
Present
X
NDSL
EINECS Present
ELINCS
Present
ENCS Present
IECSC X
KECL Present
PICCS X
AICS X
Present
X
Present
X
X
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 313 Chemical Name
CAS No
Weight-%
1,2,4 Trimethylbenzene - 95-63-6
95-63-6
<5
SARA 313 - Threshold Values % 1.0
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_____________________________________________________________________________________________ CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name Aliphatic Hydrocarbon Solvent 64742-88-7 1,2,4 Trimethylbenzene 95-63-6
New Jersey X
Massachusetts
Pennsylvania
X
X
X
16. OTHER INFORMATION NFPA HMIS Issue Date: Revision Date: Revision Note:
Health Hazards Not determined Health Hazards 1
Flammability Not determined Flammability 2
Instability Not determined Physical Hazards 0
Special Hazards Not determined Personal Protection Not determined
01-Oct-2002 13-May-2015 New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet
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Safety Data Sheet Issue Date: 01-Oct-2002
Revision Date: 13-May-2015
Version 1
1. IDENTIFICATION Product Identifier Product Name
Total Alkalinity Up
Other means of identification SDS #
POZ-001
Recommended use of the chemical and restrictions on use Recommended Use Leavening agent, cleaner ingredient, bath salt ingredient, water softener, diaper rinse ingredient, feed additive. Details of the supplier of the safety data sheet Manufacturer Address Pur-O-Zone, Inc. 345 N. Iowa Street Lawrence, KS 66044 Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr)
1-785-843-0771 1-800-535-5053
2. HAZARDS IDENTIFICATION Appearance White crystalline
Physical State Solid
Odor Odorless
Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Hazards Not Otherwise Classified (HNOC) May be harmful if swallowed
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Sodium Bicarbonate
CAS No 144-55-8
Weight-% 90-100
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**
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4. FIRST-AID MEASURES First Aid Measures Eye Contact
Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician.
Skin Contact
Wash off immediately with plenty of water for at least 15 minutes.
Inhalation
Remove to fresh air.
Ingestion
Call a physician immediately, drink two to three glasses of water, do not induce vomiting.
Most important symptoms and effects Symptoms
May be harmful if swallowed.
Indication of any immediate medical attention and special treatment needed Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Hazardous Combustion Products Oxides of carbon. Oxides of sodium. Protective equipment and precautions for firefighters Cool containers exposed to extreme heat with large quantities of water.
6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions
Use personal protective equipment as required.
Methods and material for containment and cleaning up Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up
Contain spill and ventilate area. Sweep up and put in container for disposal. Flush any remaining spill with water.
7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Avoid breathing dusts.
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_____________________________________________________________________________________________ Conditions for safe storage, including any incompatibilities Storage Conditions
Keep container closed when not in use.
Incompatible Materials
Acids.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines
This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies
Appropriate engineering controls Engineering Controls
Showers. Eyewash stations. Ventilation systems.
Individual protection measures, such as personal protective equipment Eye/Face Protection
Chemical splash goggles.
Skin and Body Protection
Rubber gloves. Rubber apron.
Respiratory Protection
None normally required with adequate room ventilation.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Appearance Color
Solid White crystalline White
Property pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility
Values Not determined Not available Not available Not available Not available Not determined 7 1 Not available Not available 2.2 8.6 at 68°C (154.4°F) Not determined Not determined Not determined Not determined Not determined Not determined Not determined Not determined
Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties
Odor Odor Threshold
Odorless Not determined
Remarks • Method
(Water = 1)
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_____________________________________________________________________________________________ Reactivity Not reactive under normal conditions.
Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization
Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to Avoid Heat, flames and sparks. Incompatible Materials. Incompatible Materials Acids. Hazardous Decomposition Products Oxides of carbon. Oxides of sodium.
11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact
Avoid contact with eyes.
Skin Contact
Avoid contact with skin.
Inhalation
Do not inhale.
Ingestion
May be harmful if swallowed.
Component Information Chemical Name Sodium Bicarbonate 144-55-8
Oral LD50 = 4220 mg/kg ( Rat )
Dermal LD50 -
Inhalation LC50 -
Information on physical, chemical and toxicological effects Symptoms
Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity
Based on the information provided, this product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP.
Numerical measures of toxicity Not determined
12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.
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_____________________________________________________________________________________________ Component Information Chemical Name Sodium Bicarbonate 144-55-8
Algae/aquatic plants
Fish
Toxicity to microorganisms
650: 120 h Nitzschia linearis 8250 - 9000: 96 h Lepomis mg/L EC50 macrochirus mg/L LC50 static
Crustacea 2350: 48 h Daphnia magna mg/L EC50
Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Not determined Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
14. TRANSPORT INFORMATION Note
Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.
DOT
Not regulated
IATA
Not regulated
IMDG
Not regulated
15. REGULATORY INFORMATION International Inventories All ingredients are listed or exempt from listing on Chemical Substance Inventory Chemical Name Sodium Bicarbonate
TSCA Present
DSL X
NDSL
EINECS Present
ELINCS
ENCS Present
IECSC X
KECL Present
PICCS X
AICS X
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
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_____________________________________________________________________________________________ EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations This product does not contain any substances regulated under applicable state right-to-know regulations
16. OTHER INFORMATION NFPA HMIS Issue Date: Revision Date: Revision Note:
Health Hazards Not determined Health Hazards 1
Flammability Not determined Flammability 0
Instability Not determined Physical Hazards 0
Special Hazards Not determined Personal Protection Not determined
01-Oct-2002 13-May-2015 New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet
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