SAFETY DATA SHEET
according to REACH Regulation UK SI 2019/758, as amended, and UK SI 2020/1577
Revision date: 26 Jul 2021
Print date: 10 Aug 2021
Version: 1
Page 1/14 Orchard
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Trade name/designation: Orchard
Other means of identification:
FIBER:56-1697, 56-1929, 56-1729, 56-1720, 56-1338, 56-1908, 56-1932, 56-1995
CORRUGATED MEMBRANES AND CARTRIDGES: 56-1370, 56-1466
UFI:
Q7A3-UN24-180D-AXMV
1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture: aromatisation
Relevant identified uses:
Life cycle stage [LCS]
PW: Widespread use by professional workers
Product Categories [PC]
PC 28: Perfumes, fragrances
1.3. Details of the supplier of the safety data sheet
Supplier (manufacturer/importer/only representative/downstream user/distributor): Vaportek Europe Ltd
Sterlings, Lawford House, Albert Place
N3 1QA LONDON
United Kingdom
Telephone: +41 22 342 2145
E-mail: vaportek@gmail.com
E-mail (competent person): vaportek@gmail.com
1.4. Emergency telephone number 24h:
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to GB-CLP Regulation, UK SI 2019/720 and UK SI 2020/1567:
Hazard classes and hazard categories
Aspiration hazard (Asp. Tox. 1)
Hazard statements
H304: May be fatal if swallowed and enters airways.
Calculation method.
Skin corrosion/irritation (Skin Irrit. 2)
Hazardous to the aquatic environment (Aquatic Acute 1)
Hazardous to the aquatic environment (Aquatic Chronic 2)
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H400: Very toxic to aquatic life.
H411: Toxic to aquatic life with long lasting effects.
Calculation method.
Calculation method. Respiratory or skin sensitisation (Skin Sens. 1)
Calculation method.
Calculation method.
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Classification procedure
SAFETY DATA SHEET
according to REACH Regulation UK SI 2019/758, as amended, and UK SI 2020/1577
Revision date: 26 Jul 2021
Print date: 10 Aug 2021
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Orchard
2.2. Label elements
Labelling according to GB-CLP Regulation, UK SI 2019/720 and UK SI 2020/1567
Hazard pictograms:
GHS07 Exclamation mark GHS08 Health hazard GHS09 Environment
Signal word: Danger
Hazard components for labelling: 2-(4-tert-butylbenzyl)propionaldehyde; acetic acid; benzaldehyde; 2-ethyl-3-hydroxy-4-pyrone
hazard statements for health hazards
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
Hazard statements for environmental hazards
H400 Very toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statements Prevention
P264 Wash hands thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves and eye/face protection.
Precautionary statements Response
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P391 Collect spillage.
Precautionary statements Disposal
P501
Dispose of contents/container to an appropriate recycling or disposal facility.
2.3. Other hazards
Adverse physicochemical effects:
No further relevant information available.
Adverse human health effects and symptoms: No further relevant information available.
Adverse environmental effects:
No further relevant information available.
Other adverse effects:
No further relevant information available.
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SAFETY DATA SHEET
according to REACH Regulation UK SI 2019/758, as amended, and UK SI 2020/1577
Revision date: 26 Jul 2021
Print date: 10 Aug 2021
Version: 1
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Orchard
SECTION 3: Composition / information on ingredients
3.2. Mixtures
Hazardous ingredients / Hazardous impurities / Stabilisers: product identifiers
name Classification according to GB-CLP Regulation, UK SI 2019/720 and UK SI 2020/1567
acetate
CAS No.: 5989-27-5
No.: 227-813-5
CAS No.: 64742-48-9 EC No.: 265-150-3
Index No.: 649-327-00-6
H411
(R)-p-mentha-1,8-diene Aquatic Acute 1, Aquatic Chronic 1, Flam. Liq. 3, Skin Irrit. 2, Skin Sens. 1
H226-H315-H317-H410
Naphtha (petroleum), hydrotreated heavy Asp. Tox. 1, STOT SE 3 H304-H336
CAS No.: 122-40-7 EC No.: 204-541-5
CAS No.: 101-86-0
EC No.: 202-983-3
CAS No.: 118-58-1
EC No.: 204-262-9
CAS No.: 107-75-5
EC No.: 203-518-7
H317
2-benzylideneheptanal Aquatic Acute 1, Aquatic Chronic 2
Warning H400-H411 M-factor (acute): 1
Hexyl Cinnamal Skin Sens. 1
Warning H317
benzyl salicylate
Aquatic Chronic 3, Eye Irrit. 2, Skin Sens. 1B
Warning H317-H319-H412
7-hydroxycitronellal Eye Irrit. 2, Skin Sens. 1B
Warning H317-H319
1
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Concentration
EC
2-tert-butylcyclohexyl
Aquatic Chronic 2 Warning
9 – ≤
weight-%
Substance
CAS No.: 88-41-5
No.: 201-828-7
15
EC
Warning
9 – ≤
weight-%
15
6
CAS No.: 77-83-8 EC No.: 201-061-8 ethyl 2,3-epoxy-3-phenylbutyrate Aquatic Chronic 2, Skin Sens. 1 Warning H317-H411 3 – ≤ 7 weight-% CAS No.: 140-11-4 EC No.: 205-399-7 benzyl acetate Aquatic Chronic 3 H412 2 – ≤ 5 weight-% CAS No.: 98-55-5 EC No.: 202-680-6 p-menth-1-en-8-ol Eye Irrit. 2, Skin Irrit. 2 Warning H315 2 – ≤ 5 weight-% CAS No.: 5413-60-5 EC No.: 226-501-6 3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-6-yl
Aquatic Chronic 3 H412 1 – ≤ 4 weight-% CAS No.: 105-87-3 EC No.: 203-341-5 geranyl acetate Aquatic Chronic 3, Skin Irrit. 2,
Warning H315-H317-H412 1 – ≤ 2 weight-% CAS No.: 100-52-7 EC No.: 202-860-4 benzaldehyde Acute Tox. 4 Warning H302 1 – ≤ 2 weight-% CAS No.: 4940-11-8 EC No.: 225-582-5 2-ethyl-3-hydroxy-4-pyrone Acute Tox. 4 Warning H302 ≤ 1.5 weight-% CAS No.: 120-57-0 EC No.: 204-409-7
Warning
≤
weight-%
– ≤ 12 weight-%
acetate
Skin Sens. 1
piperonal Skin Sens. 1
1.5
≤
weight-%
1.5
≤
weight-%
weight-%
≤ 1
weight-%
≤ 1
SAFETY DATA SHEET
according to REACH Regulation UK SI 2019/758, as amended, and UK SI 2020/1577
Revision date: 26 Jul 2021
Print date: 10 Aug 2021
Version: 1
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Orchard
product identifiers
CAS No.: 78-70-6
EC No.: 201-134-4
CAS No.: 115-95-7
EC No.: 204-116-4
CAS No.: 6728-26-3
EC No.: 229-778-1
Substance name
Classification according to GB-CLP Regulation, UK SI 2019/720 and UK SI 2020/1567
Linalool: 3,7-Dimethyl- 1,6-octadien-3-ol; DL-Linalool
Eye Irrit. 2, Skin Irrit. 2, Skin Sens. 1B
linalyl acetate
Eye Irrit. 2, Skin Irrit. 2, Skin Sens. 1B
Concentration
≤ 0.5
Warning H315-H317-H319 weight-%
trans-hex-2-enal
Acute Tox. 4, Aquatic Chronic 2, Eye Irrit. 2, Skin Irrit. 2, Skin Sens. 1A
≤ 0.5
Warning H302-H315-H317-H319-H411 weight-%
4-(4-Hydroxy-4-methylpentyl)cyclohex-3-en-1-carbaldehyd
Skin Sens. 1A
EC No.: 250-863-4
EC No.: 203-093-8
EC No.: 201-289-8
CAS No.: 68039-49-6
EC No.: 268-264-1
CAS No.: 84929-61-3
EC No.: 284-545-1
CAS No.: 64-19-7
EC No.: 200-580-7
Warning H317
methyl cinnamate
Skin Sens. 1
Warning H317
2-(4-tert-butylbenzyl)propionaldehyde
Acute Tox. 4, Aquatic Chronic 2, Repr. 2, Skin Sens. 1
Warning H302-H317-H361-H411
2,4-dimethylcyclohex-3-ene-1-carbaldehyde
Aquatic Chronic 2, Skin Irrit. 2, Skin Sens. 1B
Warning H315-H317-H411
Carrot, ext.
Aquatic Chronic 3, Asp. Tox. 1, Eye Irrit. 2, Skin Irrit. 2, Skin Sens. 1
Danger H304-H315-H317-H319-H412
acetic acid
Flam. Liq. 3, Skin Corr. 1A
Danger H226-H314
Specific concentration limit (SCL):
Skin Corr. 1A; H314: C ≥ 90%
Skin Corr. 1B; H314: 25% ≤ C < 90%
Skin Irrit. 2; H315: 10% ≤ C < 25%
Eye Dam. 1; H318: C ≥ 25%
Eye Irrit. 2; H319: 10% ≤ C < 25%
Full text of H- and EUH-phrases: see section 16.
SECTION 4: First aid measures
4.1. Description of first aid measures
General information:
≤
weight-%
≤
weight-%
≤ 0.25 weight-%
≤ 0.25 weight-%
≤ 0.1 weight-%
≤ 0.1 weight-%
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible).
Remove victim out of the danger area. Remove contaminated, saturated clothing.
If unconscious but breathing normally, place in recovery position and seek medical advice. Do not leave affected person unattended.
Warning First aider: Pay attention to self-protection!
Following inhalation:
Provide fresh air. In case of respiratory tract irritation, consult a physician.
In case of skin contact:
After contact with skin, wash immediately with plenty of water and soap.
Take off immediately all contaminated clothing. If skin irritation or rash occurs: Get medical advice/ attention.
After eye contact:
In case of contact with eyes, rinse immediately thoroughly with plenty of edible oil and consult an ophthalmologist.
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Warning H315 weight-%
≤ 0.5
CAS No.: 31906-04-4
0.5
CAS No.: 103-26-4
0.25
CAS No.: 80-54-6
SAFETY DATA SHEET
according to REACH Regulation UK SI 2019/758, as amended, and UK SI 2020/1577
Revision date: 26 Jul 2021
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Orchard
Following ingestion:
Ingestion of the mixture / product is hardly possible.
Rinse mouth.
Get medical advice/attention if you feel unwell.
Do NOT induce vomiting. Observe risk of aspiration if vomiting occurs. Get immediate medical advice/ attention.
Self-protection of the first aider: Use personal protection equipment.
4.2. Most important symptoms and effects, both acute and delayed
Causes skin irritation.
Allergic reactions
Serious eye damage/eye irritation
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media:
alcohol resistant foam Extinguishing powder Carbon dioxide (CO2)
Unsuitable extinguishing media:
Full water jet
5.2. Special hazards arising from the substance or mixture
Combustible
Hazardous combustion products: Gases/vapours, irritant
5.3. Advice for firefighters
Wear a self-contained breathing apparatus and chemical protective clothing.
5.4. Additional information
Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Personal precautions: Remove persons to safety.
Protective equipment:
Wear protective gloves/protective clothing/eye protection/face protection.
6.1.2. For emergency responders
Personal protection equipment:
Personal protection equipment: see section 8
6.2. Environmental precautions
Do not allow to enter into surface water or drains.
6.3. Methods and material for containment and cleaning up
For cleaning up:
Take up mechanically, placing in appropriate containers for disposal.
6.4. Reference to other sections
Safe handling: see section 7 Personal protection equipment: see section 8 Disposal: see section 13
6.5. Additional information
Use appropriate container to avoid environmental contamination.
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SAFETY DATA SHEET
according to REACH Regulation UK SI 2019/758, as amended, and UK SI 2020/1577
Revision date: 26 Jul 2021
Print date: 10 Aug 2021
Version: 1
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Orchard
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Protective measures
Advices on safe handling:
Wear personal protection equipment (refer to section 8).
Fire prevent measures:
Take precautionary measures against static discharge. Keep away from sources of ignition - No smoking.
Advices on general occupational hygiene
When using do not eat, drink or smoke. Avoid contact with eyes and skin.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures and storage conditions:
Keep container tightly closed in a cool, well-ventilated place.
Storage class (TRGS 510, Germany): 11 – Combustible solids that cannot be assigned to any of the above storage classes
7.3. Specific end use(s)
No data available
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
8.1.1. Occupational exposure limit values
TRGS 900 (DE) (R)-p-mentha-1,8-diene
CAS No.: 5989-27-5
EC No.: 227-813-5
TRGS 900 (DE) Naphtha (petroleum), hydrot reated heavy
CAS No.: 64742-48-9
EC No.: 265-150-3
DFG (DE) Naphtha (petroleum), hydrot reated heavy
CAS No.: 64742-48-9
EC No.: 265-150-3
IOELV (EU) acetic acid
CAS No.: 64-19-7
EC No.: 200-580-7
TRGS 900 (DE) acetic acid
CAS No.: 64-19-7
① 5 ppm (28 mg/m³)
② 20 ppm (112 mg/m³)
⑤ (kann über die Haut aufgenommen werden)
① 300 mg/m³
② 600 mg/m³
⑤ (C9-C14 Aliphaten)
① 50 ppm (300 mg/m³)
② 100 ppm (600 mg/m³)
① 10 ppm (25 mg/m³)
② 20 ppm (50 mg/m³)
① 10 ppm (25 mg/m³)
② 20 ppm (50 mg/m³) 8.1.2.
EC No.: 200-580-7
8.2. Exposure controls
8.2.1.
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Limit value type (country of
Substance name ① Long-term occupational exposure limit value ② short-term occupational exposure limit value ③ Instantaneous value
Monitoring and observation processes ⑤ Remark
origin)
④
Biological limit values No data available 8.1.3. DNEL-/PNEC-values No data available
Appropriate engineering controls No data available
SAFETY DATA SHEET
according to REACH Regulation UK SI 2019/758, as amended, and UK SI 2020/1577
Revision date: 26 Jul 2021
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8.2.2. Personal protection equipment
Eye/face protection:
Eye glasses with side protection DIN EN 166
Skin protection:
Tested protective gloves must be worn EN ISO 374
Suitable material: NBR (Nitrile rubber),
In the case of wanting to use the gloves again, clean them before taking off and air them well. Breakthrough times and swelling properties of the material must be taken into consideration.
Respiratory protection:
Usually no personal respirative protection necessary. Respiratory protection necessary at: Handling larger quantities,
8.2.3. Environmental exposure controls
No data available
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
9.2. Other information
Solid, inert fiber block soaked with liquid mixture for odour neutralisation. The properties listed relate to the liquid.
SECTION 10: Stability and reactivity
10.1. Reactivity
Flammable liquid and vapour. This material is considered to be non-reactive under normal use conditions.
10.2. Chemical stability
The product is stable under storage at normal ambient temperatures.
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state:
Colour: yellow Odour: fruity Odour threshold: not determined Safety relevant basis data parameter at °C Method Remark pH not applicable Melting point not determined Freezing point not determined Initial boiling point and boiling range 173 Decomposition temperature not determined Flash point 61.1 °C Evaporation rate not determined Auto-ignition temperature not determined Upper/lower flammability or explosive limits not determined Vapour pressure not determined Vapour density not determined Density ≈ 0.92 g/cm³ Relative density not determined Bulk density not determined Water solubility Immiscible Partition coefficient: n-octanol/ water not determined Dynamic viscosity not determined Kinematic viscosity not determined
Appearance Physical
Liquid
SAFETY DATA SHEET
according to REACH Regulation UK SI 2019/758, as amended, and UK SI 2020/1577
Revision date: 26 Jul 2021
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10.3. Possibility of hazardous reactions
No known hazardous reactions.
10.4. Conditions to avoid
Stable under recommended storage and handling conditions.
10.5. Incompatible materials
No further relevant information available.
10.6. Hazardous decomposition products
Thermal decomposition can lead to the escape of irritating gases and vapours.
SECTION 11: Toxicological information
11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008
Substance name
benzyl acetate
CAS No.: 140-11-4
EC No.: 205-399-7
p-menth-1-en-8-ol
CAS No.: 98-55-5
EC No.: 202-680-6
benzyl salicylate
CAS No.: 118-58-1
EC No.: 204-262-9
7-hydroxycitronellal
CAS No.: 107-75-5
EC No.: 203-518-7
trans-hex-2-enal
CAS No.: 6728-26-3
EC No.: 229-778-1
Acute oral toxicity:
Toxicological information
LD50 oral: >2,000 mg/kg
LD50 oral: =4,300 mg/kg
LD50 dermal: >2,000 mg/kg
LD50 oral: >3,000 mg/kg
LD50 dermal: >2,000 mg/kg
LD50 oral: >6,400 mg/kg
LD50 dermal: >2,000 mg/kg
LD50 oral: 780 mg/kg
Based on available data, the classification criteria are not met.
Acute dermal toxicity:
Based on available data, the classification criteria are not met.
Acute inhalation toxicity:
Based on available data, the classification criteria are not met.
Skin corrosion/irritation:
Causes skin irritation.
Serious eye damage/irritation:
Based on available data, the classification criteria are not met.
Respiratory or skin sensitisation:
May cause an allergic skin reaction.
Germ cell mutagenicity:
Based on available data, the classification criteria are not met.
Carcinogenicity:
Based on available data, the classification criteria are not met.
Reproductive toxicity:
Based on available data, the classification criteria are not met.
STOT-single exposure:
Based on available data, the classification criteria are not met.
STOT-repeated exposure:
Based on available data, the classification criteria are not met.
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SAFETY DATA SHEET
according to REACH Regulation UK SI 2019/758, as amended, and UK SI 2020/1577
Revision date: 26 Jul 2021
Print date: 10 Aug 2021
Version: 1
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Aspiration hazard: May be fatal if swallowed and enters airways.
Additional information: No data available
11.2. Information on other hazards
No data available
SECTION 12: Ecological information
12.1. Toxicity
Substance name
(R)-p-mentha-1,8-diene
CAS No.: 5989-27-5
EC No.: 227-813-5
benzyl acetate
CAS No.: 140-11-4
EC No.: 205-399-7
p-menth-1-en-8-ol
CAS No.: 98-55-5
EC No.: 202-680-6
2-benzylideneheptanal
CAS No.: 122-40-7
EC No.: 204-541-5
benzyl salicylate
CAS No.: 118-58-1
EC No.: 204-262-9
linalyl acetate
CAS No.: 115-95-7
EC No.: 204-116-4
Toxicological information
LC50: <1 mg/l 4 d (fish)
EC50: =0.307 mg/l 2 d (crustaceans)
EC50: 0.05 mg/l 3 d (Algae/water plant)
LC50: 4 mg/l 4 d (fish)
LC50: =70 mg/l 4 d (fish)
LC50: 0.91 mg/l 4 d (fish)
LC50: 1.03 mg/l 4 d (fish)
LC50: 11 mg/l 4 d (fish)
Aquatic toxicity: Very toxic to aquatic life. Toxic to aquatic life with long lasting effects. Additional ecotoxicological information: No further relevant information available.
12.2. Persistence and degradability
Substance name Biodegradation
2-tert-butylcyclohexyl acetate
CAS No.: 88-41-5
EC No.: 201-828-7
(R)-p-mentha-1,8-diene
CAS No.: 5989-27-5
EC No.: 227-813-5
Naphtha (petroleum), hydrotreated heavy
CAS No.: 64742-48-9
EC No.: 265-150-3
ethyl 2,3-epoxy-3-phenylbutyrate
CAS No.: 77-83-8
EC No.: 201-061-8
benzyl acetate
CAS No.: 140-11-4
EC No.: 205-399-7
p-menth-1-en-8-ol
CAS No.: 98-55-5
EC No.: 202-680-6
geranyl acetate
CAS No.: 105-87-3
EC No.: 203-341-5
benzaldehyde
CAS No.: 100-52-7
Yes, rapidly
Yes, rapidly
Yes, slowly
Yes, rapidly
Yes, rapidly
Yes, rapidly
Yes, rapidly
Yes, rapidly
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Remark
SAFETY DATA SHEET
according to REACH Regulation UK SI 2019/758, as amended, and UK SI 2020/1577
Revision date: 26 Jul 2021
Print date: 10 Aug 2021
Version: 1
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Orchard
Substance name
EC No.: 202-860-4
2-ethyl-3-hydroxy-4-pyrone
CAS No.: 4940-11-8
EC No.: 225-582-5
piperonal
CAS No.: 120-57-0
EC No.: 204-409-7
2-benzylideneheptanal
CAS No.: 122-40-7
EC No.: 204-541-5
Hexyl Cinnamal
CAS No.: 101-86-0
EC No.: 202-983-3
benzyl salicylate
CAS No.: 118-58-1
EC No.: 204-262-9
7-hydroxycitronellal
CAS No.: 107-75-5
EC No.: 203-518-7
Linalool: 3,7-Dimethyl- 1,6-octadien-3-ol; DL-Linalool
CAS No.: 78-70-6
EC No.: 201-134-4
linalyl acetate
CAS No.: 115-95-7
EC No.: 204-116-4
trans-hex-2-enal
CAS No.: 6728-26-3
EC No.: 229-778-1
4-(4-Hydroxy-4-methylpentyl)cyclohex-3-en-1-carbaldehy
d
CAS No.: 31906-04-4
EC No.: 250-863-4
methyl cinnamate
CAS No.: 103-26-4
EC No.: 203-093-8
2-(4-tert-butylbenzyl)propionaldehyde
CAS No.: 80-54-6
EC No.: 201-289-8
2,4-dimethylcyclohex-3-ene-1-carbaldehyde
CAS No.: 68039-49-6
EC No.: 268-264-1
Biodegradation:
Part of the components is biodegradable.
Additional information:
No further relevant information available.
12.3. Bioaccumulative potential
Accumulation / Evaluation:
No further relevant information available.
12.4. Mobility in soil
No further relevant information available.
12.5. Results of PBT and vPvB assessment
Substance name
2-tert-butylcyclohexyl acetate
CAS No.: 88-41-5
EC No.: 201-828-7
(R)-p-mentha-1,8-diene
CAS No.: 5989-27-5
Biodegradation Remark
Yes, rapidly
Yes, rapidly
Yes, rapidly
Yes, rapidly
Yes, rapidly
Yes, rapidly
Yes, rapidly
Yes, rapidly
Yes, rapidly
Yes, rapidly
Yes, slowly
Yes, rapidly
Results of PBT and vPvB assessment
The substance in the mixture does not meet the PBT/ vPvB criteria according to REACH, annex XIII.
The substance in the mixture does not meet the PBT/ vPvB criteria according to REACH, annex XIII.
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SAFETY DATA SHEET
according to REACH Regulation UK SI 2019/758, as amended, and UK SI 2020/1577
Revision date: 26 Jul 2021
Print date: 10 Aug 2021
Version: 1
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Orchard
Substance name
EC No.: 227-813-5
Naphtha (petroleum), hydrotreated heavy
CAS No.: 64742-48-9
EC No.: 265-150-3
ethyl 2,3-epoxy-3-phenylbutyrate
CAS No.: 77-83-8
EC No.: 201-061-8
benzyl acetate
CAS No.: 140-11-4
EC No.: 205-399-7
p-menth-1-en-8-ol
CAS No.: 98-55-5
EC No.: 202-680-6
geranyl acetate
CAS No.: 105-87-3
EC No.: 203-341-5
benzaldehyde
CAS No.: 100-52-7
EC No.: 202-860-4
2-ethyl-3-hydroxy-4-pyrone
CAS No.: 4940-11-8
EC No.: 225-582-5
piperonal
CAS No.: 120-57-0
EC No.: 204-409-7
2-benzylideneheptanal
CAS No.: 122-40-7
EC No.: 204-541-5
Hexyl Cinnamal
CAS No.: 101-86-0
EC No.: 202-983-3
benzyl salicylate
CAS No.: 118-58-1
EC No.: 204-262-9
7-hydroxycitronellal
CAS No.: 107-75-5
EC No.: 203-518-7
Linalool: 3,7-Dimethyl- 1,6-octadien-3-ol; DL-Linalool
CAS No.: 78-70-6
EC No.: 201-134-4
linalyl acetate
CAS No.: 115-95-7
EC No.: 204-116-4
trans-hex-2-enal
CAS No.: 6728-26-3
EC No.: 229-778-1
4-(4-Hydroxy-4-methylpentyl)cyclohex-3-en-1carbaldehyd
CAS No.: 31906-04-4
EC No.: 250-863-4
methyl cinnamate
CAS No.: 103-26-4
EC No.: 203-093-8
2-(4-tert-butylbenzyl)propionaldehyde
CAS No.: 80-54-6
EC No.: 201-289-8
2,4-dimethylcyclohex-3-ene-1-carbaldehyde
CAS No.: 68039-49-6
EC No.: 268-264-1
Results of PBT and vPvB assessment
The substance in the mixture does not meet the PBT/ vPvB criteria according to REACH, annex XIII.
The substance in the mixture does not meet the PBT/ vPvB criteria according to REACH, annex XIII.
The substance in the mixture does not meet the PBT/ vPvB criteria according to REACH, annex XIII.
The substance in the mixture does not meet the PBT/ vPvB criteria according to REACH, annex XIII.
The substance in the mixture does not meet the PBT/ vPvB criteria according to REACH, annex XIII.
The substance in the mixture does not meet the PBT/ vPvB criteria according to REACH, annex XIII.
The substance in the mixture does not meet the PBT/ vPvB criteria according to REACH, annex XIII.
The substance in the mixture does not meet the PBT/ vPvB criteria according to REACH, annex XIII.
The substance in the mixture does not meet the PBT/ vPvB criteria according to REACH, annex XIII.
The substance in the mixture does not meet the PBT/ vPvB criteria according to REACH, annex XIII.
The substance in the mixture does not meet the PBT/ vPvB criteria according to REACH, annex XIII.
The substance in the mixture does not meet the PBT/ vPvB criteria according to REACH, annex XIII.
The substance in the mixture does not meet the PBT/ vPvB criteria according to REACH, annex XIII.
The substance in the mixture does not meet the PBT/ vPvB criteria according to REACH, annex XIII.
The substance in the mixture does not meet the PBT/ vPvB criteria according to REACH, annex XIII.
The substance in the mixture does not meet the PBT/ vPvB criteria according to REACH, annex XIII.
The substance in the mixture does not meet the PBT/ vPvB criteria according to REACH, annex XIII.
The substance in the mixture does not meet the PBT/ vPvB criteria according to REACH, annex XIII.
The substance in the mixture does not meet the PBT/ vPvB criteria according to REACH, annex XIII.
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
en / DE GeSi.de
SAFETY DATA SHEET
according to REACH Regulation UK SI 2019/758, as amended, and UK SI 2020/1577
Revision date: 26 Jul 2021
Print date: 10 Aug 2021
Version: 1
Page 12/14
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12.6. Endocrine disrupting properties
No data available
12.7. Other adverse effects
No data available
SECTION 13: Disposal considerations
13.1. Waste treatment methods
The allocation of waste identity numbers/waste descriptions must be carried out according to the EEC, specific to the industry and process.
13.1.1. Product/Packaging disposal
Waste codes/waste designations according to EWC/AVV
Waste code product:
16 03 05 * organic wastes containing hazardous substances
*: Evidence for disposal must be provided.
Waste treatment options
Appropriate disposal / Product:
Consult the appropriate local waste disposal expert about waste disposal.
Appropriate disposal / Package:
Non-contaminated packages may be recycled.
Completely emptied bricks, disks and membranes can be recycled'
SECTION 14: Transport information Land
RID)
14.2. UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ((R)-pmentha-1,8-diene, 2tert-butylcyclohexyl acetate)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ((R)-pmentha-1,8-diene, 2tert-butylcyclohexyl acetate)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ((R)-pmentha-1,8-diene, 2tert-butylcyclohexyl acetate)
14.3. Transport hazard class(es) 9 9 9
14.4. Packing group III III III
14.5. Environmental hazards
en / DE GeSi.de
transport (ADR/
Sea transport (IMDG) Air transport (ICAO-
IATA-DGR)
TI /
ID number UN 3077 UN 3077 UN 3077
14.1. UN number or
MARINE POLLUTANT
SAFETY DATA SHEET
according to REACH Regulation UK SI 2019/758, as amended, and UK SI 2020/1577
Revision date: 26 Jul 2021
Print date: 10 Aug 2021
Version: 1
Page 13/14
Orchard
Land transport (ADR/ RID) Sea transport (IMDG) Air transport (ICAOTI / IATA-DGR)
14.6. Special precautions for user
Special provisions: 274 | 335 | 375 | 601
Limited quantity
(LQ): 5 kg
Excepted Quantities
(EQ): E1
Hazard identificati on number (Kemler No.): 90
Classification code:
M7
tunnel restriction code: (-)
Remark:
Special provisions: 274 | 335 | 966 | 967 | 969
Limited quantity
(LQ): 5 kg
Excepted Quantities
(EQ): E1
EmS-No.: F-A, S-F
Remark:
Special provisions: A97 | A158 | A179 | A197 | A215
Limited quantity
(LQ): Y956
Excepted Quantities
(EQ): E1
Remark:
14.7. Maritime transport in bulk according to IMO instruments
No data available
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU legislation
Restrictions on use:
According to directive 94/33/EC, juveniles are only allowed to handle this product as long as all effects of dangerous substances are prevented. Observe employment restrictions under the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.
15.1.2. National regulations [DE] National regulations
Water hazard class
WGK:
3 - stark wassergefährdend
Source: Self-classification (mixture; calculation rule).
15.2. Chemical Safety Assessment
Chemical safety assessments for substances in this mixture were not carried out.
SECTION 16: Other information
16.1. Indication of changes
No data available
en / DE GeSi.de
SAFETY DATA SHEET
according to REACH Regulation UK SI 2019/758, as amended, and UK SI 2020/1577
Revision date: 26 Jul 2021
Print date: 10 Aug 2021
Version: 1
Page 14/14
Orchard
16.2.
Abbreviations and acronyms
For abbreviations and acronyms, see table at http://abbrev.esdscom.eu
-ADR: European agreement concerning the international carriage of dangerous goods by road (Accord européen relatif transport des merchandises dangereuses par route)
-CAS: Chemical Abstract Service
-CLP: Classification, labelling and Packaging
-DNEL: Derived No Effect Level
-EC50: Effective Concentration 50%
-ECHA: European Chemical Agency
-LC50: Lethal Concentration 50%
-LD50: Lethal Dose 50%
-PBT: persistent, bioaccumulative, toxic
-PNEC: Predicted No Effect Concentration
-REACH: Registration, Evaluation and Authorization of Chemicals
-SVHC: Substance of Very High Concern
-VOC: Volatile organic compounds
-vPvB: very persistent, very bioaccumulative
16.3.
Key literature references and sources for data
REACH Dissemination Portal https://echa.europa.eu/de/information-on-chemicals/registered-substances
16.4. Classification for
mixtures
and
used evaluation
method according to GB-CLP Regulation, UK SI 2019/720 and UK SI 2020/1567
Classification according to GB-CLP Regulation, UK SI 2019/720 and UK SI 2020/1567:
Hazard classes and hazard categories
Aspiration hazard (Asp. Tox. 1)
Skin corrosion/irritation (Skin Irrit. 2)
Respiratory or skin sensitisation (Skin Sens. 1)
Hazardous to the aquatic environment (Aquatic Acute 1)
Hazardous to the aquatic environment (Aquatic Chronic 2)
Hazard statements
H304: May be fatal if swallowed and enters airways.
H315: Causes skin irritation.
Classification procedure
method.
H317: May cause an allergic skin reaction. Calculation method.
H400: Very toxic to aquatic life. Calculation method.
H411: Toxic to aquatic life with long lasting effects. Calculation method.
16.5. Relevant R-, H- and EUH-phrases (Number and full text)
Hazard statements
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H361 Suspected of damaging fertility or the unborn child.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
16.6.
Training advice
No data available
16.7. Additional information
No data available
en / DE GeSi.de
Calculation method.
Calculation
